8/9/2019 2-Chemical Structure of Materials http://slidepdf.com/reader/full/2-chemical-structure-of-materials 1/42 Chemical structure of materials 1. Types of chemical bond 2. Chemical structures of materials
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Chemical structure of
materials
1. Types of chemical bond2. Chemical structures of materials
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Types of chemical bond
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Atomic structure
• Bohr model
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Atomic structure
• Orbital
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Valence electrons
&
periodic table5
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Atomic bond
• Ftotal
– Attractive force(FA)
– Repulsive force(FR)
• Bond length
• Bond energy
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Primary bond
• Ionic bond
• Covalent bond
• Metallic bond
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Ionic bond
• Electronegativity(전기음성도) 차이가 큰 원소간 결합
– Alkali metal-halogen
• Electrostatic attraction, Coulombic force
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Ionic bond
• Potential energy versus internuclear distance
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Ionic bond
• Isotropic
• Ionic crystal
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Covalent bond
• Electronegativity(전기음성도) 차이가 적은 비금속 원소간 결합
• Valence electrons 서로 공유
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Covalent bond
• 원자중심과 공유전자 간에 존재하게 되는 힘
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Covalent bond
• Potential energy versus internuclear distance
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Covalent bond
• Three different ways to form an electron-pair bond
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Covalent bond
• Hybridization of s and p orbitals
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Covalent bond
• Hybridization of s and p orbitals
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Covalent bond
• σ bond, π bond
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Covalent bond
• σ bond, π bond
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Metallic bond
• 금속 원자간 결합
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Metallic bond
• Electron-sea model
• Isotropic
• Ion core와 전자구름 간의 정전기적 인력
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Secondary bond
• 전자의 이동이나 공유를 수반하지 않는 분자간 인력
• Primary bond에 비해 약한 결합력
• 분자적 쌍극자(dipole) : 일시적, 영구적(극성분자)
• Van der Waals bond
• Hydrogen bond
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Secondary bond
• Hydrogen bond
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Bonding energy25
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Chemical structure of materials
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Solid materials
• Rigid structure
– Component atoms, ions, or molecules are usually locked into place
• Extended three-dimensional patterns
• Allotrope
– Diamond
– Graphite – C60
– Carbon nanotubes
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Crystalline & amorphous
• Crystalline solid
– Crystal lattice : regular repeating three-dimensional structure
• Amorphous solid : “shapeless”
– No particular order
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Metallic structure
• Metallic bond
– Free electron : high conductivity (electricity, heat)
– Good mechanical properties
– Crystal lattice : high ductility, tensile strength
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Unit cell
• Seven basic unit cells
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Defect
• Real crystals
– Large numbers of defects (typically more than 104 per milligram)
• Point defect
• Line defect
• Plane defect
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Ceramic structures
• Two or more elements (compound) : ex) Al2O3
• Covalent and ionic bond, predominately ionic bonding – Stronger than metallic bond
– High hardness, high compressive strength, and chemical inertness
– Low ductility and low tensile strength
• No free electron : low conductivity (electricity, heat)• Variable structures
• Charge balance
• Glassy or crystalline
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Ceramic structures
• Ceramic glass : ex) pure
SiO2 (tetrahedrons) – Network of chain or ring
structures
– Entirely glassy structure
– No sharp melting or freezingpoint
– High T : easily slide past eachother, viscous
– Low T : rigid, hard and brittle
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Ceramic structures
• Ceramic crystalline or partially crystalline material
– Most ceramics• Metallic and nonmetallic elements with ionic or covalent bonds
– Silicate Ceramics (SiO2)
• Pyramid (tetrahedral or four-sided) units
– Cement (19~25% SiO2, 5~9% Al
2O
3, 60~64% CaO, 2~4% FeO)
• One of the main ingredients of concrete
• Solution, recrystallization, and precipitation of a silicate structure
– Nitride Ceramics
• High thermal and mechanical stability
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Cutting tools, wear-resistant parts• TiN : cubic structure
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Defect
• Electroneutrality
– Point defects• Frenkel defect
• Schottky defect
• Impurity – both substitutional and interstitial
– Linear Defects
• Dislocations
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Polymeric structure
• Monomer, repeating unit
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Polymeric structure
• Addition & condensation
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Polymeric structure
• Types by monomers
– Homopolymer – Copolymer
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Polymeric structure
• Types by structures
– Linear polymer – Branched polymer
– Network(crosslinked) polymer
– Dendrimer
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Chemical bonds – Covalent + secondary bond
• Anisotropic
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Polymeric crystal
• Crystalline, semi-crystalline, amorphous
• Crystallinity
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Others
• Carbon materials
– Crystalline :diamond, graphite, carbon nanotubes – Glassy carbon
– Pyrolytic carbon
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