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174113385-Alkali-Khaled.pdf

Apr 14, 2018

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    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 1

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    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 2

    The A lkal i Bypass

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    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 3

    Alkali Bypass

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    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 4

    Bypass - Wherefore ?

    1. Improofed plant reliability- Reduction of Alkali concentration

    - Reduction of coating build ups

    - Reduction of production cost (Personal, cleaning work)

    2. Improved clinker quality

    - Reduction of alkali content of alkalis (z. B. Low - Alkali - Clinker)- Limititation of sulfur (cement quality)

    - Limitation of Chlor content

    3. Possibility of waste material burning

    - economical interesting secondary fuels and raw materialscontents often high amount of harm components

    Alkali Bypass

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    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 5

    Cooling

    Quenching chamber

    Conditioning tower

    Separation

    Electro filter

    Dust collection

    Clean gas emission

    Alkali Bypass

    Sil R 07 J n 2002 S \Dept\A600All\A ftrag\K jafa\Training KUJAFA\Trainingonsite\3 1 Process engineers\Trainings nterlagen\05 Kiln Preheater\PreheaterpptPage 6

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    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 6

    Bypass

    Hot Gas Duct

    Quench Air

    Bypass

    Mixing

    Chamber

    Bypass

    Mixed Gas

    Polysius: Actual Bypass Design

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training KUJAFA\Trainingonsite\3 1 Process engineers\Trainingsunterlagen\05 Kiln Preheater\Preheater pptPage 7

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    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 7

    Velocity Distribution

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training KUJAFA\Trainingonsite\3.1 Process engineers\Trainingsunterlagen\05 Kiln Preheater\Preheater.pptPage 8

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    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 8

    Air blaster

    nozzles

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 9

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    p g j g_ g _ _ g g g _ _ ppg

    What are the minor elements ?

    They are chemical components of the raw materials with a

    low concentration towards the other components.

    In the cement industry, Cl, SO3, Na2O and

    K2O are, among others, particularly monitored

    Although some have no impact on the chemical process, others might lead to major

    troubles.

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 10

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    What happens in the system ?

    Raw Materials

    Raw Meal

    Grinding Heating up

    Hot Meal

    Clinker

    Clinkerization

    Volatilization

    Temperature

    Alkali Bypass

    Condensation

    Temperature

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 11

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    Low volatilization

    temperature

    Extraction from

    material

    Flowing with

    gases

    Condensation on

    cooler particles

    Increase of

    local

    concentration

    PROBLEMS

    Problem with volatile elements

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 12

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    What are some elements doing ?

    Volatilization temperature

    +Condensation temperature

    2 cycles

    Internal

    Cycle

    External

    Cycle

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 13

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    Internal and External Cycles

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 14

    Alk li B

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    Different behaviors

    Chloride start evaporate around 650C

    Alkalis start evaporate around 900C

    Sulfur start evaporate around 1000C

    Conclusion :

    The various content of element is different according

    to the analyzed area (kiln feed, meal cyclone 2, hot

    meal, clinker,).

    Nevertheless, most of the highest concentrations arelocated at the kiln inlet, depending on the salt

    formation.

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 15

    Alk li B

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    Example of decision

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 16

    Alk li B

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    0

    200

    400

    600

    800

    1000

    1200

    1400

    1600

    1800

    0 5 10 15 20 25 30

    Bypassrate (%)

    gStb/Nm3Byp.HG

    Texfa

    Yamaver

    Suezver

    Berfa

    Sakufa

    Rugver 80

    ECFA

    1

    2

    K1

    K2

    3

    Dust loading of bypass gas

    Alkali Bypass

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    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 18

    Alkali Bypass

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    Decreases the concentration of minors

    in the kiln inlet by taking out a part ofkiln gas

    Taking part of the heat

    Taking part of the production

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 19

    Alkali Bypass

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    Calculation of V Kiln

    The volume coming out of the kiln is composed by :

    1. The volume of the gas combustion - V Comb

    2. The volume of the decarbonation - V CO23. The volume of excess air - V Ex

    ExV

    COV

    CombV

    KiV

    2ln

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 20

    Alkali Bypass

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    Calculation of the bypass ratio

    Finally, knowing V Kiln and V BP

    lnKi

    Bypass

    V

    V

    RatioBypass

    Alkali Bypass

    SilzR 07 Jun 2002 S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.pptPage 21

    Alkali Bypass

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    Conclusion

    Minor elements are to be considered foroperation decisions

    Chemistry is able to help for any investigation

    concerning the process troubles

    The volatilization and cycles of the elements

    can be handled through process operation

    A good knowledge of the element circulation is

    necessary for a good trouble shooting

    Alkali Bypass