16 Chapter 7

Chapter – 7

FTIR – Spectroscopic Studies

261

CHAPTER - 7

FTIR – SPECTROSCOPIC STUDIES

7.1. Introduction

Infrared spectroscopy (IR spectroscopy) is the subset of Spectroscopy that

deals with the infrared region of the electromagnetic spectrum. It covers a range of

techniques, the most common being a form of absorption spectroscopy. As with all

spectroscopic techniques, it can be used to identify compounds and investigate sample

composition. A common laboratory instrument that uses this technique is an infrared

spectro photometer. A molecule is a collection of atoms. The atom in a molecule

executes different types of vibrational motion. The energy of most of these molecular

vibrations is quantized and corresponds to that to the infrared regions of the

electromagnetic spectrum. When infra red radiation of the same frequency is allowed

fall on the molecule, the system absorbs energies, carrying the excitation of the

molecule to higher vibrational levels[123]. The molecules absorbing a quantum of

energy give rise to bands characteristic of the molecule from about 200 to 4000 cm-1.

Functional groups can be identified spectra one of the most reliable methods for

understanding the structure of the molecules [124].

The infrared portion of the electromagnetic spectrum is usually divided into

three regions; the near-, mid- and far- infrared, named for their relation to the visible

spectrum. The far-infrared, approximately 400–10 cm-1 (1000–30 µm), lying adjacent

to the microwave region, has low energy and may be used for rotational spectroscopy.

The mid-infrared, approximately 4000 – 400 cm−1 (30 – 2.5 µm) may be used to study

the fundamental vibrations and associated rotational-vibrational structure. The higher

262

energy near-IR, approximately 14000–4000 cm−1 (2.5–0.8 µm) can excite overtone or

harmonic vibrations [125]. The names and classifications of these sub regions are

merely conventions. They are neither strict division nor based on exact molecular or

electromagnetic properties.

7.2. Theory

FT-IR stands for Fourier Transform Infra Red, the preferred method of

infrared spectroscopy. It was first developed by astronomers in the early 1950s to

study the infrared spectra of distant stars, has now been developed into a very

powerful technique for the detection of very weak signals from the environment

noise. It is a simple mathematical technique to reverse a complex wave into its

frequency components. The conventional IR spectrometers are not of much use for

the far IR region (20 –400 cm-1) as the sources are weak and the detectors are

insensitive. FT-IR has made this energy limited region more accessible. It has made

the middle infrared (400 –4000 cm-1) also more useful [124].

Infrared spectroscopy exploits the fact that molecules absorb specific

frequencies that are characteristic of their structure. These absorptions are resonant

frequencies, i.e. the frequency of the absorbed radiation matches the frequency of the

bond or group that vibrates. The energies are determined by the shape of the

molecular potential energy surfaces, the masses of the atoms, and the associated

vibronic coupling.

In order for a vibrational mode in a molecule to be "IR active," it must be

associated with changes in the permanent dipole.

A molecule can vibrate in many ways, and each way is called a vibrational

mode. Linear molecules have 3N–5 degrees of vibrational modes whereas nonlinear

263

molecules have 3N–6 degrees of vibrational modes (also called vibrational degrees of

freedom). As an example H2O, a non-linear molecule, will have 3×3–6 = 3 degrees of

vibrational freedom, or modes [124].

Simple diatomic molecules have only one bond and only one vibrational band.

If the molecule is symmetrical, e.g. N2, the band is not observed in the IR spectrum,

but only in the Raman spectrum [126]. Unsymmetrical diatomic molecules, e.g. CO,

absorb in the IR spectrum. More complex molecules have many bonds, and their

vibrational spectra are correspondingly more complex, i.e. big molecules have many

peaks in their IR spectra. The atoms in a CH2 group, commonly found in organic

compounds can vibrate in six different ways: symmetric and antisymmetric stretching,

scissoring, rocking, wagging and twisting.

Using the information of FT-IR, We can determine the amount of components

in a mixture, the quality of consistency of a sample and identify unknown materials

7.3. Practical IR spectroscopy

The infrared spectrum of a sample is recorded by passing a beam of infrared

light through the sample. Heated silicon carbide rods, heated ceramic rods coated with

rare earth oxides, tungsten and carbon are used as sources of infrared radiation.

Examination of the transmitted light reveals how much energy was absorbed at each

wavelength. This can be done with a monochromatic beam, which changes in

wavelength over time, or by using a Fourier Transform instrument to measure all

wavelengths at once. From this, a transmittance or absorbance spectrum can be

produced, showing at which IR wavelengths the sample absorbs. Analysis of these

absorption characteristics reveals details about the molecular structure of the sample.

264

When the frequency of the IR is the same as the vibrational frequency of a bond,

absorption occurs. This technique works almost exclusively on samples with covalent

bonds. Simple spectra are obtained from samples with few IR active bonds and high

levels of purity. More complex molecular structures lead to more absorption bands

and more complex spectra. The technique has been used for the characterization of

very complex mixtures.

7.4. Sample preparation

In the Fourier transform infrared spectrum the samples are prepared by the

pressed pellet technique. In this technique a small amount of the ground solid sample

is mixed with about 100 times its weight of potassium bromide (KBr). The finely

ground mixture is pressed under very high pressure to form small pellet. The pellets

are then exposed to a source of continuous infrared radiation. The spectrometer

dispenses. The radiation into a spectrum and the detector converts the radiant energy

into an electrically signal which is amplified electronically and recoded by a chart

recorder.

Liquid samples can be sandwiched between two plates of a salt (commonly

sodium chloride, or common salt, although a number of other salts such as potasium

bromide or calcium fluoride are also used).[127] The plates are transparent to the

infrared light and do not introduce any lines onto the spectra. A means of ‘decoding’

the individual frequencies is required. This can be accomplished via a well known

mathematical technique called the Fourier transformation. This transmissions

performed by the computer which them presents the user with the desired spectral

information for analysis.

265

In addition to "standard" transmission FTIR we they also have the following

sample handling capabilities:

1. Horizontal ATR - attenuated total reflectance. Allows measurement of

aqueous solutions, elastic and viscous samples which are difficult to grind

2. Specular reflectance - allows measurement of thin films on metals

3. KBr Discs - allow suspension of powders in IR transparent KBr so they may

be analysed

4. Gas cells - This may be used for FTIR analysis of a gaseous sample (e.g.

headspace analysis or environmental monitoring)

5. Solution cells - for measuring liquid sample in transmission mode.

7.5. Comparison with a reference

Fig. 7.1: Schematics of a two-beam absorption spectrometer.

A beam of infrared light is produced, passed through an interferometer (not

shown), and then split into two separate beams. One is passed through the sample, the

other passed through a reference. The beams are both reflected back towards a

detector, however first they pass through a splitter, which quickly alternates which of

the two beams enters the detector. The two signals are then compared and a printout is

obtained. This "two-beam" setup gives accurate spectra even if the intensity of the

266

light source drifts over time. To take the infrared spectrum of a sample, it is necessary

to measure both the sample and a "reference" (or "control"). This is because each

measurement is affected by not only the light-absorption properties of the sample, but

also the properties of the instrument (for example, what light source is used, what

detector is used, etc.). The reference measurement makes it possible to eliminate the

instrument influence. Mathematically, the sample transmission spectrum is divided by

the reference transmission spectrum.

The appropriate "reference" depends on the measurement and its goal. The

simplest reference measurement is to simply remove the sample (replacing it by air).

However, sometimes a different reference is more useful. For example, if the sample

is a dilute solute dissolved in water in a beaker, then a good reference measurement

might be to measure pure water in the same beaker. Then the reference measurement

would cancel out not only all the instrumental properties (like what light source is

used), but also the light-absorbing and light-reflecting properties of the water and

beaker, and the final result would just show the properties of the solute (at least

approximately).

A common way to compare to a reference is sequentially: First measure the

reference, then replace the reference by the sample, then measure the sample. This

technique is not perfectly reliable: If the infrared lamp is a bit brighter during the

reference measurement, then a bit dimmer during the sample measurement, the

measurement will be distorted. More elaborate methods, such as a "two-beam" setup,

can correct for these types of effects to give very accurate results.

267

7.6. FTIR Spectroscopy

Fourier Transform infrared (FTIR) spectroscopy is a measurement

technique that allows one to record infrared spectra. Infrared light is guided through

an interferometer and then through the sample (or vice versa). A moving mirror inside

the apparatus alters the distribution of infrared light that passes through the

interferometer. The signal directly recorded, called an "interferogram", represents

light output as a function of mirror position. A data-processing technique called

Fourier Transform turns this raw data into the desired result (the sample's spectrum):

Light output as a function of infrared wavelength (or equivalently,wavenumber). As

described above, the sample's spectrum is always compared to a reference.

There is an alternate method for taking spectra (the "dispersive" or "scanning

monochromator method), where one wavelength at a time passes through the sample.

The dispersive method is more common in UV-Vis spectroscopy, but is less practical

in the infrared than the FTIR method. One reason that FTIR is favored is called

"Fellgett’s advantage" or the "multiplex advantage": The information at all

frequencies is collected simultaneously, improving both speed and signal-to-noise

ration. Another is called "Jacquinot's Throughput Advantage": A dispersive

measurement requires detecting much lower light levels than an FTIR

measurement.[128] There are other advantages, as well as some disadvantages,[128] but

virtually all modern infrared spectrometers are FTIR instruments.

7.7. Analyse of the spectra

Step 1

Look first for carbonyl C=O bend. Look for a strong band at 1820– 1660cm-1.

This band usually belongs to the most intense absorption band in a spectrum. It will

268

have medium width. If we see the carbonyl band, look for other ends associated with

functional groups that contain the carbonyl by going to step 2. If no C=O band is

present, check for alcohols and go to the step 3.

Step 2

If a C=O is present we want to determine if it is a part of an acid, an ester, or

an aldehyde or ketone. At this time we may not able to distinguish aldehyde from

ketone and you will not be asked to do so.

ACID

Look for indications that an O-H is also present. It has a broad absorption near

3300 – 2500 cm-1. This actually will overlap the C-H stretch. There will also be a C-O

single band near 1100 – 1300 cm-1. Look for the carbonyl and band near

1725 – 1700 cm-1.

ESTER

Look for C=O absorption of medium intensity near 1300 – 1000 cm-1. There

will be no O-H band.

ALDEHYDE

Look for aldehyde type C-H absorption bands. There are two weak

absorptions to the right of the C-H stretch near 2850 cm-1 and 2750 cm-1 and are

caused by the C-H band that is a part of the CHO aldehyde functional group. Look for

the carbonyl C-O band around 1725 – 1705 cm-1.

269

Step 3

If no carbonyl band appears in the spectrum looks for an alcohol O-H band.

ALCOHOL

Look for the broad OH band near 3600 – 3300 cm-1 and a C-O absorption

band near 1300 – 1000 cm-1.

Step 4

If no carbonyl band and no O-H bands are in the spectrum check for double

bands, C=C from an aromatic or an alkene.

ALKENE

Look for weak absorption near 1650 cm-1 for a double band. There will be a

C-H stretch band near 3000 cm-1.

AROMATIC

Look for the benzene C=C, double bonds which appear as medium to strong

absorption in the region 1650 –1450 cm-1. The CH stretch bond is much weaker than

in alkenes.

Step 5

If none of the previous groups can be divided, we may have an alkane.

ALKANE

The main absorption will be the C-H stretch near 3000 cm-1. The spectrum

will be simple with another band near 1450 cm-1.

270

Step 6

If the spectrum still cannot assigned we may have an alkyl bromide.

ALKYL BROMIDE

Look for the C-H stretch and a relatively simple spectrum with an absorption

to the right of 667 cm-1.

Note: Terminal C-CH2:

Absorption at 1600 – 1675 cm-1

Strong bands at 900 cm-1.

Aromatic ring breathing motions: Observed between 1450 cm-1 and 1600 cm-1

the interpretation of infrared spectra involves the correlation of absorption bands in

the spectrum of an unknown compound with the known absorption frequencies for

types of bands.

A model table is given below which is helpful for analyzing a FT-IR spectrum.

271

Table - 7.1

Analyzing a FTIR specturm

Bond Compound type Frequency range, cm-1

2960 – 2850(s) stretch

Alkanes 1470 – 1350 (v) Scissoring andbendingC –H

CH3 Umbrella Deformation1380 (m-w) Doublet – isopropy 1,t-buty1

3080–3020 (m) stretchC – H Alkanes

1000–675 9s) bend

Aromatic Rings 3100–300 (m) stretch

Phenyl Ring Substitution Bonds 870 – 675 (s) bendC – H

Phenyl ring substitution Overtones 200 – 1600 (w) – fingerprint region

3333–3267 (s) stretchC – H Alkynes

700–610 (b) bend

C =C Alkenes 1680 1640 (m,w) stretch

C = C Alkynes 2260–2100 (w, sh) stretch

C = C Aromatic Rings 1600, 1500 (w) stretch

C –OAlcohols, ketones, Carboxylic acidsEsters

1260 – 100 (s) Stretch

C = OAldehydes, ketones, Carboxylic acidsEsters

1760–1670 (2) stretch

Monomeric – Alcohols, phenols 3640–3160 (s, br) stretch

Hydrogen–bonded–alcohols, phenols3600–3200 (b) stretch

O = H

Carboxylic acids 3000–3300 (m) stretch

3500–3300 (m) bendN – H Amines

1650–1580 (m) bend

C – N Amines 1340–1020 (m) stretch

C = N Nitriles 2260–2220 (v) Stretch

NO2 Nitro Compounds 1660–1500 (s) asymmetrical stretch

V = Variable, m = Medium s – Strong W – weak sh – sharp

272

273

274

7.8. Advantages of FTIR

Some of the major advantages of FT-IR are:

Speed

Because all of the frequencies are measured simultaneously, most

measurements by FT-IR are made in a matter of seconds rather than several minutes.

Sensitivity

Sensitivity is dramatically improved with FT-IR for many reasons. The

detectors employed are much sensitive, the optical throughput is much higher which

results in much lower noise levels, and the fast scans enable the co addition of several

scans in order to reduce the random measurements noise to any desired level (referred

to as signal averaging)

Mechanical Simplicity

The moving mirror in the interferometer is the only continuously moving part

in the instrument. Thus there is very little possibility of mechanical breakdown. FTIR

can be used to identify the chemical from spills, paints, polymers, coating and drugs.

FTIR is perhaps the most powerful tool for identifying types of chemical bonds.

Organic compounds have very rich detailed spectra; inorganic compounds are usually

much simpler.

7.9. Applications

Infrared spectroscopy is widely used in both research and industry as a simple

and reliable technique for measurement, quality control and dynamic measurement. It

275

is also used in forensic analysis in both criminal and civil cases, enabling

identification of polymer degradation for example.

The instruments are now small, and can be transported, even for use in field

trials. With increasing technology in computer filtering and manipulation of the

results, samples in solution can now be measured accurately (water produces a broad

absorbance across the range of interest, and thus renders the spectra unreadable

without this computer treatment). Some instruments will also automatically tell you

what substance is being measured from a store of thousands of reference spectra held

in storage.

Infrared spectroscopy has been highly successful for applications in both

organic and inorganic chemistry. Infrared spectroscopy has also been successfully

utilized in the field of semiconductor microelectronics:[129] for example, infrared

spectroscopy can be applied to semiconductors like silicon, gallium arsenide, gallium

nitride, zinc selenide, amorphous silicon, silicon nitride, etc.

7.10. Results and Discussion

FTIR analysis of binary liquid systems

In the FTIR spectrum of binary liquid mixtures was revealed at room

temperature in the range of 400–4000cm−1. The FTIR spectrums for binary and

ternary mixtures are represented in Fig 7.1 to 7.30 and their observations are given in

tables 7.2 to 7.31. Liquid mixtures were added and few mg of the composition was

used for making pellets with KBr. The pellets were then exposed to IR radiation. The

FTIR spectrums were taken using Perkin Elmer FTIR spectrometer. The tentative

frequency assignments were made by comparing it with standard values of frequency.

The FTIR spectrum taken shows drastic changes in the frequency values for binary

276

and ternary mixtures. In the binary systems of Cyclohexanone(X1) + Hexane(X2),

Cyclohexanone(X1) + 2-Butanone(X2), Heptane(X1) + Benzaldehyde(X2),

Heptane(X1) + 2-Butanone(X2), Benzaldehyde(X1) + Benzyl Chloride(X2),

Benzaldehyde(X1) + Ethyl Acetate(X2) mixtures the maximum frequency has been

observed in the region 0.6 mole fraction of X1 and 0.4 mole fraction of X2. In

Cyclohexanone(X1) + Benzyl Chloride(X2), Heptane(X1) + Ethyl Acetate(X2),

Benzaldehyde(X1) + 2-Butanone(X2), Ethyl Acetate (X1) + 2-Butanone(X2)

combinations shows the maximum frequency has been observed in the region 0.7

mole fraction of X1 and 0.3 mole fraction of X2. In Cyclohexanone(X1) +

Heptane(X2), Hexane(X1) + Heptane(X2), Hexane(X1) + Ethyl Acetate (X2)

combinations the maximum frequency has been observed in the region 0.8 mole

fraction of X1 and 0.2 mole fraction of X2. In Cyclohexanone(X1) +

Benzaldehyde(X2), Benzaldehyde(X1) + Hexane(X2), Heptane(X1) + Benzyl

Chloride (X2) mixtures the maximum frequency has been observed in the region 0.4

mole fraction of X1 and 0.6 mole fraction of X2. In Hexane(X1) + 2-Butanone(X2),

Ethyl Acetate(X1) + Benzyl Chloride (X2) mixtures the maximum frequency has

been observed in the region 0.3 mole fraction of X1 and 0.7 mole fraction of X2. In

Cyclohexanone(X1) + Ethyl Acetate (X2), Benzyl Chloride (X1) + 2-Butanone (X2)

mixtures the maximum frequency has been observed in the region 0.5 mole fraction of

X1 and 0.5 mole fraction of X2.

FTIR analysis of ternary liquid systems

In the ternary systems, Cyclohexanone(X1) + Hexane(X2) + Heptane(X3)

mixture the maximum frequency has been observed in 0.5, 0.4 mole fractions of X1,

277

0.3,0.5 mole fractions of X2 and 0.2,0.1 mole fractions of X3. In Cyclohexanone(X1)

+ Hexane(X2) + Benzaldehyde(X3) mixture the maximum frequency has been

observed in 0.4, 0.3 mole fractions of X1, 0.2,0.3 mole fractions of X2 and 0.4,0.4

mole fractions of X3. In Cyclohexanone(X1) + Hexane(X2) + 2-Butanone(X3)



+ Hexane(X2) + Ethyl Acetate(X3) mixture the maximum frequency has been

observed in 0.4, 0.3 mole fractions of X1, 0.2,0.2 mole fractions of X2 and 0.4,0.5

mole fractions of X3. In Cyclohexanone(X1) + Heptane(X2) + 2-Butanone(X3)



+ Heptane(X2) + Ethyl Acetate(X3) mixture the maximum frequency has been

observed in 0.4 mole fraction of X1, 0.5 mole fraction of X2 and 0.1 mole fractions

of X3. In Cyclohexanone(X1) + 2-Butanone(X2) + Benzaldehyde(X3) mixture the

maximum frequency has been observed in 0.4, 0.5 mole fractions of X1, 0.2,0.1 mole

fractions of X2 and 0.4,0.4 mole fractions of X3. In Cyclohexanone(X1) +

Benzaldehyde(X2) + Ethyl Acetate(X3) mixture the maximum frequency has been

observed in 0.4,0.5,0.2 mole fractions of X1, 0.4,0.4,0.4 mole fractions of X2 and

0.2,0.1,0.4 mole fractions of X3. In Cyclohexanone(X1) + Ethyl Acetate(X2) + 2-

Butanone(X3) mixture the maximum frequency has been observed in 0.3, mole

fraction of X1, 0.4 mole fraction of X2 and 0.3 mole fraction of X3. In Ethyl

Acetate(X1) + 2-Butanone(X2) + Hexane(X3) mixture the maximum frequency has

been observed in 0.7, 0.5 mole fractions of X1, 0.1,0.2 mole fractions of X2 and

0.2,0.3 mole fractions of X3.

278

So, the observation from the VE study has been confirmed by the FTIR

spectrum measurement. The shift in the frequency values of FTIR spectrum

measurement is generally due to following observed factors:

1. Interstitial accommodation.

2. Strong interactions (H-bond type, or dipole-dipole or dipole-induced dipole

interactions).

279

For Binary systems

Fig-7.1 FTIR spectrums for Cyclohexanone + Hexane mixture:SPECTRUM

(1)CYC + (0)HEXANE

FIGURE 1

C yclohexanone.pk

CYCLON~1.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T 5 0.50

REF 400 0 7 5.82 2000 7 3.85 600344 9.1 4 9 .99 29 40.57 16.99 28 64.06 30.70 26 72.30 72.97 23 63.74 72.06234 0.7 1 7 2.4 2 206 3.8 6 7 1.9 1 187 1.5 0 74.9 8 180 5.8 6 70.4 2 171 2.0 6 1 0.9 0163 8.8 2 3 4.6 7 156 0.3 8 5 1.8 5 144 9.8 8 40.4 3 142 4.18 40.5 6 134 2.46 5 1.1 1131 1.9 9 4 3.4 5 126 4.3 3 6 8.7 4 122 2.3 5 41.5 1 111 9.0 2 44.1 7 105 3.1 2 6 2.9 7101 8.0 8 6 4.7 1 991 .42 71.38 90 7.55 62.34 864.24 6 6.33 750 .16 54.80652 .90 57.99 49 0.57 51 .01 414.18 75.32

4000.0 3000 2000 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

3449.14

2940.57

286 4. 06

2672.30

2363.74

2340. 712063.86

187 1. 50

1805.86

1712.06

1638.82

156 0. 38

1449.88

1424.18

1342.46

131 1. 99

1264.33

122 2. 35

1119.02

105 3. 12

1018.08

991.42

907.55

864.24

750 .1 6

652.90

490 .5 7

414.18

FIGURE 2

SPECTRUM

0.9 (CYC) + 0.1 (HEXANE)

SJC= Phy-

SJE497~1.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T

REF 4000 67.77 2000 66.533949.75 64.79 3771.50 63.78 3412.64 9.99 2941.57 12.872672.34 54.14 2362.22 56.70 2176.21 61.93 2063.32 61.941872.14 63.38 1806.55 50.78 1712.96 11.83 1565.33 31.391342.48 31.06 1312.47 28.92 1222.50 28.88 1119.18 29.681018.23 45.10 905.55 43.53 864.67 49.49 750.51 40.38 652.67490.81 38.81 414.20

4000.0 3000 2000 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

3949.

3771.

3412.

2941.

2865.

2672.

2362.

2176.

2063.

1974.

1872.

1806.

1712.

1565.

1423.

1342.

1312.

1222.

1119.

1054.

1018.

905.5

864.6

750.5

652.6

490.8

414.2

SPECTRUM

0.8(CYC) + 0.2 (HEXANE)

FIGURE 3

SJC=phy-

SJC_PH~1.SP 3601 4000.00 400.00 3.17 99.73 4.00 %T

REF 4000 99.39 2000 86.513937.11 94.39 3442.57 3.17 3002.55 45.49 2925.08 46.292125.50 77.40 1643.95 25.49 1565.63 50.69 1416.33 38.791224.12 84.94 1114.72 80.62 1023.16 35.30 952.89 59.12703.97 54.58 654.66

4000.0 3000 2000 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

3937.

3442.

3002.

2925.

2673.

2125.

1643.

1565.

1416.

1316.

1224.

1114.

1023.

952.8

904.6

703.9

654.6

SPECTRUM

0.7 (CYC) + 0.3 (HEXANE)

FIGURE 4

SJC= Phy-

SJ2057~1.SP 3601 4000.00 400.00 4.26 100.00 4.00 %T

REF 4000 96.52 2000 94.523946.85 90.09 3767.63 89.85 3414.47 12.99 2942.29 4.262670.75 70.86 2424.36 92.42 2335.89 88.13 2176.82 85.871969.56 88.72 1870.29 86.76 1804.88 65.07 1713.79 4.261425.86 20.60 1314.25 32.48 1223.02 30.59 1119.55 35.781019.24 63.08 902.95 56.35 866.88 68.88 750.84 53.98 652.18491.71 50.03 413.33

4000.0 3000 2000 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

3946.

3767.

3414.

2942.

2867.

2670.

2424.

2335.

2176.

2064.

1969. 1870.

1804.

1713.

1568.

1425.

1314.

1223.

1119.

1056.

1019.

902.9

866.8

750.8

652.1

491.7

413.3

SPECTRUM

0.6 (CYC) + 0.4 (HEXANE)

FIGURE 5

SJC=phy-

SJC_PH~3.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T

REF 4000 85.01 2000 84.303412.62 43.20 2939.86 20.75 2864.54 39.42 2670.80 80.231805.81 78.08 1712.49 9.96 1565.88 66.48 1425.10 50.331312.34 55.04 1222.32 53.27 1118.91 56.43 1054.23 70.92904.58 70.92 864.55 76.02 750.33 69.99 650.48 75.94 490.12411.32 79.45

4000.0 3000 2000 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

3412.

2939.

2864.

2670.2062.

1805.

1712.

1565.

1425.

1341.

1312.1222.

1118.

1054.

1018.

904.5

864.5

750.3

650.4

490.1

411.3

SPECTRUM

0.5 (CYC) + 0.5 (HEXANE)

FIGURE 6

SJC= Phy-

SJ205F~1.SP 3601 4000.00 400.00 10.00 99.99 4.00 %T

REF 4000 80.81 2000 78.543934.56 79.80 3776.88 76.00 3438.20 10.00 2943.43 60.902104.26 76.73 1635.55 38.44 1566.96 27.76 1416.20 40.181120.65 68.37 1021.85 71.61 928.97 79.75 653.20

4000.0 3000 2000 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

3934.

3776.

3438.

2943.

2362.

2104.

1635.

1566.

1416.

1347. 1120.

1021.

928.9

653.2

FTIR SPECTRUM

ACIC

St.Joseph's College ( Autonomous )

Trichy-2

Spectrum Name: SJC-.6- .4 C.sp

Date: 21-12-2009

SJ C-.6-.4 C.pk

SJ C-6-~1.SP 3601 4000.00 400.00 6.32 99.99 4.00 %T 5 1.00

REF 4000 98 .17 2000 9 4.12 60039 29.03 96.31 3457.73 6.32 3072.54 34.70 2942.22 13.72 2 866.81 27 .4027 42.57 64.87 2641.57 70.96 1976.94 92.78 1706.09 8.85 1 595.75 25 .4914 49.01 46.87 1391.70 54.89 1312.18 43.21 1230.67 36.67 1172.30 60.1811 18.21 57.75 1065.78 74.61 1020.46 81.69 904.93 84.87 8 25.70 72.1274 8.60 44.96 712.74 40.63 650.99 50.6 6 498.36 61.31

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3929.03

3457.73

3072.54

2 942.22

286 6.81

2742.57

26 41.57

1976 .94

1706.09

1595.75

1449.01

13 91.70

1312.18

1230 .67

1172.30

111 8.21

106 5.78

1020.46

904.93

825.70

748.60

712.74

65 0.99

4 98.36

FTIR SPECTRUM

ACIC

St. Joseph's College ( Autonomous )

Trichy-2

Spectrum Name: SJC-.7-.3 C.sp

Date: 21-12-2009

SJC-.7-.3 C.pk

SJC-7-~1.SP 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4 000 97.56 2000 95.26 6003928.72 95.16 3448.97 6 .33 2942.30 17.51 2866.57 30.65 2664.42 74.231975.94 93.80 1706.83 1 1.35 1595.69 13.45 1447.60 45.72 1385.60 47.601348.47 39.04 1314.81 4 5.52 1227.34 42.61 1172.14 66.61 1118.20 59.391063.59 75.58 1020.14 8 2.05 903.99 82.04 825.25 75.63 749.80 49.90713.64 48 .66 650.68 54.43 496.55 59.64

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

392 8.72

3448.97

294 2.30

2866.5 7

2664.4 2

1975.94

1706.831595.69

1447.60

1385.60

1348.47

1314.81

1 227.34

1 172.14

111 8.20

1063.59

1020.14

903.99

825.2 5

749.80

713.64

650.68

496.55

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.8-.2 C.pk

SJC-8-~1.SP 3601 4000.00 400.00 6.94 99.99 4.00 %T 5 1.00

REF 4 000 98.11 2000 96.86 6003940.59 96.47 3452.56 11.92 2941.41 12.17 2866.33 29.08 2669.38 86.882064.94 95.65 1709.48 6.94 1594.76 23.83 1447.10 46.17 1388.23 59.641345.67 46.37 1313.98 47.59 1225.04 41.95 1171.48 74.79 1118.56 59.001060.65 79.52 1019.56 85.60 904.27 81.38 862.42 85.07 825 .20 81.65750.11 55 .32 714.94 57.87 650.83 61.6 4 494.52 60.89 416.70 88.59

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.59

3 452.56 294 1.41

2866.3 3

2669.38

206 4.94

17 09.48

1594.76

1447.10

13 88.23

1345.67

1313.98

1225.04

1171.48

111 8.56

1060.65

1019.56

904.27

862.42

825.20

750.11

714 .94

65 0.83 4 94.52

416.70

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.9-.1 C.pk

SJC-9-~1.SP 3601 4000.00 400.00 8.41 100.00 4.00 %T 5 1.00

REF 4 000 98.82 2000 97.87 6003450.45 22.38 2940.82 1 6.30 2865.76 38.95 2671.73 92.85 2066.37 96.591710.56 8.39 1594.44 37.41 1446.30 57.07 1345.87 57.48 1314.29 60.331223.65 57.75 1118.69 6 8.75 1057.84 86.19 1019.04 90.36 904.21 85.71863.28 89 .48 750.68 71.01 650.95 76.54 4 93.14 71.85 415.01 93.25

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 450.45

294 0.82

2865.7 6

2 671.73

206 6.37

17 10.56

1594.44

1446.30

1345.87

1314.29

1223.65

1118.69

1057.8 4

1019.04

904.21

863.28

750.68

65 0.95

4 93.14

41 5.01

SPECTRUM

0 (CYC) + 1 (HEXANE)

FIGURE 7

FTIR

Date:

Hexane.p

Hexane.sp 3601 4000.00 400.00 3.24 99.01 4.00 %T

REF 4000 98.71 2000 89.723432.69 3.24 2969.84 72.05 2362.02 81.94 2338.24 84.341637.62 24.85 1416.40 89.27 1114.27 96.09 1018.58 97.88

4000.0 3000 2000 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

3432.

2969.

2362.

2338.

2077.

1637.

1416.

1114.

1018.

668.2

Table - 7.2

Observations of FTIR spectrums for Cyclohexanone + Hexane mixture:

1 (CH)Cm-1

0.9(CH)

+

0.1(HX)Cm-1

0.8(CH)

+

0.2(HX)Cm-1

0.7(CH)

+

0.3(HX)Cm-1

*0.6 (CH)

+

0.4(HX)

Cm-1

0.5(CH)

+

0.5(HX)Cm-1

0.4(CH)

+

0.6(HX)Cm-1

0.3(CH)

+

0.7(HX)Cm-1

0.2(CH)

+

0.8(HX)Cm-1

0.1(CH)

+

0.9(HX)Cm-1

1 (HX)Cm-1

3449.142940.572864.062672.302363.742340.712063.861871.501805.861712.061638.821560.381449.881424.181342.461311.991264.331222.351119.021053.121018.08991.42907.55864.24750.16652.90490.57414.18

3949.753771.503412.642941.572865.042672.342362.222176.212063.321974.041872.141806.551712.961565.331423.061342.481312.471222.501119.181054.061018.23905.55864.67750.51652.67490.81

414.20

3937.113442.573002.552925.082673.822125.501643.951565.631416.331316.121224.121114.721023.16952.89904.60703.97654.66

3946.853767.633414.472942.292867.142670.752424.342335.892176.8220640261969.561870.291804.881713.791568.101425.861314.251223.021119.551056.471019.24902.95866.88750.84652.18491.71413.33

3412.62

2939.86

2864.54

2670.80

2062.74

1805.81

1712.49

1565.88

1425.10

1341.35

1312.34

1222.32

1118.91

1054.23

1018.06

904.58

864.55

750.33

650.48

490.12

411.32

3934.563776.883438.202943.432362.892104.261635.551566.961416.201347.591120.651021.85928.97653.20

3943.132841.842865.332672.072366.072174.641605.421711.741638.911565.531420.731342.571312.831222.371119.201054.111019.45904.61863.42749.84652.50491.76

3917.102942.712867.492366.672085.611708.471633.931565.031417.151345.311221.891119.351022.23953.09619.88482.36

3912.542939.692864.302671.802062.931805.791712.681638.921565.121449.431425.201341.991312.041222.241118.981053.341017.93906.51864.38750.30652.47490.44411.06

3949.772968.272935.762882.462363.002339.502096.411638.551561.291464.641415.211116.581022.17928.41652.83

3432.692969.842362.022338.242077.431637.621416.401114.271018.58668.29

* Maximum shift in the frequency has been observed.

280

Fig-7.2: FTIR spectrums for Cyclohexanone + Heptane mixture:

SP E C T R U M 1 : (1 )C Y C + (0)H E P T A N E

C ycl oh ex an o n e.p k

C Y C LO N ~ 1 .S P 3 6 0 1 4 0 0 0.0 0 4 0 0.0 0 1 0.0 0 1 0 0 .0 0 4 .0 0 % T 5 0 .50

R E F 4 00 0 7 5.8 2 2 0 0 0 7 3.8 5 6 0 03 4 4 9 .1 4 9 .9 9 2 9 4 0.5 7 1 6.9 9 28 6 4 .0 6 3 0 .7 0 2 6 7 2 .3 0 7 2 .9 7 2 3 6 3 .7 4 7 2 .0 62 3 4 0 .7 1 7 2 .4 2 2 0 6 3 .8 6 7 1 .9 1 1 8 7 1 .5 0 7 4 .9 8 1 80 5 .8 6 70 .4 2 1 7 1 2 .0 6 1 0 .9 01 6 3 8 .8 2 3 4 .6 7 1 5 6 0 .3 8 5 1 .8 5 1 4 4 9 .8 8 4 0 .4 3 1 42 4 .1 8 40 .5 6 1 3 4 2 .4 6 5 1 .1 11 3 1 1 .9 9 4 3 .4 5 1 2 6 4 .3 3 6 8 .7 4 1 2 2 2 .3 5 4 1 .5 1 1 11 9 .0 2 44 .1 7 1 0 5 3 .1 2 6 2 .9 71 0 1 8 .0 8 6 4 .7 1 9 9 1 .4 2 7 1.3 8 90 7 .5 5 6 2 .34 8 6 4.2 4 6 6 .3 3 7 5 0 .1 6 5 4 .8 06 5 2 .9 0 5 7 .9 9 4 9 0.5 7 5 1 .0 1 4 1 4 .1 8 7 5 .3 2

4 000 .0 30 00 20 00 150 0 1 000 400 .0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

10 0.0

cm -1

% T

34 49 .1 4

2 94 0. 57

286 4 .0 6

267 2 .3 0

2 36 3. 74

2 34 0. 71206 3 .8 6

18 7 1. 50

1 80 5. 86

1 71 2 .0 6

16 3 8. 82

15 60 .3 8

14 49 .8 8

1 42 4. 1 8

1 34 2. 4 6

1 31 1. 99

1 26 4. 33

12 2 2. 35

1 11 9 .0 2

10 5 3. 12

10 18 .0 8

9 91 .4 2

9 07 .5 5

864 . 24

75 0 .1 6

65 2. 90

4 90 .5 7

41 4. 18

SPECTRUM 7 : 0.9 (CYC) + 0.1 (HEPTANE)

SJC= Phy-

SJ205B~1.SP 3601 4000.00 400.00 3.67 100.00 4.00 %T

REF 4000 97.302000 96.563412.54 41.25 2939.69 8.78 2864.30 24.31 2671.80 91.011805.79 87.03 1712.68 3.67 1638.92 62.60 1565.12 69.261425.20 41.46 1341.99 55.83 1312.04 45.61 1222.24 42.101053.34 75.65 1017.93 79.48 906.51 73.08 864.38 81.72 750.30652.47 81.49 490.44 62.00 411.06

4 00 0 .0 30 00 20 00 1 50 0 10 00 4 00 .0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

10 0.0

cm-1

% T

3412.

2939.

2864.

2671.

2062.

1805.

1712.

1638.

1565.

1449.

1425.

1341.

1312.

1222.

1118.

1053.

1017.

906.5

864.3

750.3

652.4

490.4

411.0


SJC= Phy-

SJC_PH~4.SP 3601 4000.00 400.00 3.60 99.05 4.00 %T

REF 4000 98.66 2000 97.053947.97 96.20 3413.37 17.48 2940.67 4.98 2865.12 13.522364.80 82.89 2176.18 92.86 2063.53 92.59 1972.86 94.981805.76 78.03 1712.73 3.60 1565.11 59.37 1425.87 25.041312.73 31.34 1222.72 29.20 1119.18 34.28 1054.54 61.71904.80 59.74 864.87 73.28 750.63 58.25 652.38 72.03 490.89411.60 90.06

4000.0 3000 2000 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

3947.

3413.

2940.

2865.

2671.

2364.

2176.

2063.

1972.1871.

1805.

1712.

1565.

1425.

1341.

131 2.

1222.

1119.

1054.

101 8.

904.8

864.8

750.6

652.3

490.8

411.6


SJC=Phy-

SJ105F~1.SP 3601 4000.00 400.00 3.16 99.99 4.00 %T

REF400097.992000 94.923443.13 3.16 2941.84 20.27 2865.33 37.18 2672.07 92.552174.64 90.80 1805.42 88.06 1711.74 18.86 1638.91 26.211420.73 23.95 1342.57 56.45 1312.83 55.00 1222.37 56.671054.11 72.17 1019.45 73.30 904.61 80.74 863.42 84.57 749.84652.50 55.49 491.76

4 000.0 3000 2000 15 00 1000 400. 0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100. 0

c m-1

% T

3443.

2941.

2865.

2672.2366.

2174.

1805.

1711.

1638.

1565.

1420.

1342.

1312.1222.

1119.

1054.

1019.

904.6

863.4

749.8

652.5491.7

SPECTRUM 4 :0.6 (CYC) + 0.4 (HEPTANE)

SJC=phy-

SJC_PH~2.SP 3601 4000.00 400.00 3.25 99.70 4.00 %T

REF4000 99.55 2000 95.243417.10 3.25 2942.71 63.39 2867.49 82.73 2366.67 92.471708.47 59.45 1633.93 31.67 1565.03 29.28 1417.15 45.431221.89 92.00 1119.35 80.63 1022.23 79.15 953.09 97.82482.36 77.26

4000.0 3000 2000 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

3417.

2942.

286 7.

236 6.2085.

1708.

1633.

1565.

1417.

1345.

1221.

111 9.

1022.

953.0

619.8

482.3


SJC= Phy-

SJ2053~1.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T

REF 4000 77.51 2000 75.643420.77 10.00 2941.90 14.59 2864.70 33.43 2672.37 74.951712.73 12.85 1637.45 36.29 1566.13 30.42 1421.81 30.861312.05 47.82 1221.93 46.61 1118.99 46.80 1053.23 63.26906.17 66.53 863.71 69.62 750.04 57.50 652.29 55.00 490.59

4000.0 3000 20 00 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

342 0.

2 941.

286 4.

267 2.

236 3.

171 2.

163 7.

156 6. 1421 .

1342.

1312 .

1221.

111 8.

10 53.

101 8.

90 6.1

86 3.7

750.0652. 2

490 .5

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJ C-.6-.4 C.pk

SJ C-6-~1.SP 3601 4000.00 400.00 6.32 99.99 4.00 %T 5 1.00

REF 4000 98 .17 2000 9 4.12 60039 29.03 96.31 3457.73 6.32 3072.54 34.70 2942.22 13.72 2 866.81 27 .4027 42.57 64.87 2641.57 70.96 1976.94 92.78 1706.09 8.85 1 595.75 25 .4914 49.01 46.87 1391.70 54.89 1312.18 43.21 1230.67 36.67 1172.30 60.1811 18.21 57.75 1065.78 74.61 1020.46 81.69 904.93 84.87 8 25.70 72.1274 8.60 44.96 712.74 40.63 650.99 50.6 6 498.36 61.31

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3929.03

3457.73

3072.54

2 942.22

286 6.81

2742.57

26 41.57

1976 .94

1706.09

1595.75

1449.01

13 91.70

1312.18

1230 .67

1172.30

111 8.21

106 5.78

1020.46

904.93

825.70

748.60

712.74

65 0.99

4 98.36

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.7-.3 C.pk

SJC-7-~1.SP 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4 000 97.56 2000 95.26 6003928.72 95.16 3448.97 6 .33 2942.30 17.51 2866.57 30.65 2664.42 74.231975.94 93.80 1706.83 1 1.35 1595.69 13.45 1447.60 45.72 1385.60 47.601348.47 39.04 1314.81 4 5.52 1227.34 42.61 1172.14 66.61 1118.20 59.391063.59 75.58 1020.14 8 2.05 903.99 82.04 825.25 75.63 749.80 49.90713.64 48 .66 650.68 54.43 496.55 59.64

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

392 8.72

3448.97

294 2.30

2866.5 7

2664.4 2

1975.94

1706.831595.69

1447.60

1385.60

1348.47

1314.81

1 227.34

1 172.14

111 8.20

1063.59

1020.14

903.99

825.2 5

749.80

713.64

650.68

496.55

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.8-.2 C.pk

SJC-8-~1.SP 3601 4000.00 400.00 6.94 99.99 4.00 %T 5 1.00

REF 4 000 98.11 2000 96.86 6003940.59 96.47 3452.56 11.92 2941.41 12.17 2866.33 29.08 2669.38 86.882064.94 95.65 1709.48 6.94 1594.76 23.83 1447.10 46.17 1388.23 59.641345.67 46.37 1313.98 47.59 1225.04 41.95 1171.48 74.79 1118.56 59.001060.65 79.52 1019.56 85.60 904.27 81.38 862.42 85.07 825 .20 81.65750.11 55 .32 714.94 57.87 650.83 61.6 4 494.52 60.89 416.70 88.59

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.59

3 452.56 294 1.41

2866.3 3

2669.38

206 4.94

17 09.48

1594.76

1447.10

13 88.23

1345.67

1313.98

1225.04

1171.48

111 8.56

1060.65

1019.56

904.27

862.42

825.20

750.11

714 .94

65 0.83 4 94.52

416.70

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.9-.1 C.pk

SJC-9-~1.SP 3601 4000.00 400.00 8.41 100.00 4.00 %T 5 1.00

REF 4 000 98.82 2000 97.87 6003450.45 22.38 2940.82 1 6.30 2865.76 38.95 2671.73 92.85 2066.37 96.591710.56 8.39 1594.44 37.41 1446.30 57.07 1345.87 57.48 1314.29 60.331223.65 57.75 1118.69 6 8.75 1057.84 86.19 1019.04 90.36 904.21 85.71863.28 89 .48 750.68 71.01 650.95 76.54 4 93.14 71.85 415.01 93.25

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 450.45

294 0.82

2865.7 6

2 671.73

206 6.37

17 10.56

1594.44

1446.30

1345.87

1314.29

1223.65

1118.69

1057.8 4

1019.04

904.21

863.28

750.68

65 0.95

4 93.14

41 5.01

SPECTRUM 2 : (0)CYC +(1)HEPTANE

Heptane.p

Heptane.sp 3601 4000.00 400.00 3.17 99.99 4.00 %T

REF4000 83.95 2000 80.083449.77 3.17 2968.27 32.42 2935.76 42.98 2882.46 57.012339.50 72.71 2096.41 78.11 1638.55 29.09 1561.29 45.851415.21 58.44 1116.58 75.81 1022.17 77.56 928.41 83.36

4000.0 3000 2000 1500 1000 400.0

0.0

5

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100.0

cm-1

%T

3449.

2968.

2935.

288 2.

236 3.

2339.

209 6.

1638.

1561.

1464.

1415.

1116.

1022.

928.4

652.8

Table - 7.3

Observations of FTIR spectrums for Cyclohexanone + Heptane mixture

1 (CH)

Cm-1

0.9 (CH)

+

0.1(HP)Cm-1

*0.8 CH)

+

0.2 (HP)

Cm-1

0.7 (CH)

+

0.3(HP)Cm-1

0.6 (CH)

+

0.4(HP)Cm-1

0.5 (CH)

+

0.5(HP)Cm-1

0.4 (CH)

+

0.6(HP)Cm-1

0.3 (CH)

+

0.7(HP)Cm-1

0.2 (CH)

+

0.8(HP)Cm-1

0.1 (CH)

+

0.9(HP)Cm-1

1 (HP)

Cm-1

3449.142940.572864.062672.302363.742340.712063.861871.501805.861712.061638.821560.381449.881424.181342.461311.991264.331222.351119.021053.121018.08991.42907.55864.24750.16652.90490.57414.18

3412.542939.692864.302671.802062.931805.791712.681638.921565.121449.431425.201341.991312.041222.241118.981053.341017.93906.51864.38750.30652.47490.44411.06

3947.97

3413.37

2940.67

2865.12

2671.83

2364.80

2176.18

2063.53

1972.86

1871.69

1805.76

1712.73

1565.11

1425.87

1341.64

1312.73

1222.72

1119.18

1054.54

1018.20

904.80

864.87

750.63

652.38

490.89

411.60

3443.132941.842865.332672.072366.072174.641805.421711.741638.911565.531420.731342.571312.831222.371119.201054.111019.45904.61863.42749.84652.50491.76

3417.102942.712867.492366.672085.611708.471633.931565.031417.151345.311221.891119.351022.23953.09619.88482.36

3420.772941.902864.702672.372363.641712.731637.451566.131421.811342.751312.051221.931118.991053.231018.76906.17863.71750.04652.29490.59

3453.132951.842855.332632.072346.072164.641808.421716.741638.911567.531428.731348.571318.831225.371116.201058.111012.45901.61869.42743.84658.50492.76

3415.532936.682867.302678.802061.921802.791714.681636.921568.121442.431424.201346.991318.041223.241116.981059.341012.93906451862.38759.30656.47492.44418.06

3425.742947.962869.732673.382366.641718.731632.441566.131424.811348.751314.021226.931117.921052.231018.76902.17868.71755.04658.29492.59

3423.132921.842825.332622.072346.072184.641845.421751.741688.911525.531430.731342.571352.831262.371169.201074.111069.45906.61867.42746.84658.50499.76

3449.772968.272935.762882.462363.002339.502096.411638.551561.291464.641415.211116.581022.17928.41652.83


281

Fig-7.3: FTIR spectrums for Cylclohexanone + Benzaldehyde mixture:

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-1.0 H.sp

Date: 21-12-2009

SJC-1.0 H.pk

SJC-10~1.SP 3601 4000.00 400.00 6.34 100.00 4.00 % T 5 1.00

REF 4000 99.03 2000 96.69 6003928.35 97.64 3435.07 6.34 2941.09 26.56 2865.37 49.20 2127.77 93.901709.99 18.80 1593.99 18.45 1444.28 63.06 1350.43 49.90 1223.13 73.491119.21 78.97 1054.80 91.51 1018.42 92.75 902.94 88.78 752.31 67.75651.49 68.80 494.06 68.15

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 28 .3 5

34 35 .0 7

29 41 .0 9

28 65 .3 7

21 27 .7 7

1 70 9.99

15 93 .9 9

14 44 .2 8

1 35 0.43

12 23 .1 3

1 11 9.21

1 05 4.8 0

10 18 .42

90 2.94

7 52 .3 1

6 51 .4 94 94 .0 6

FT IR SP ECT R UM

ACIC

St.J os eph 's C ollege ( Autonomous )

T r ichy -2

Spec trum Name: SJ C- .1- .9 C.s p

D ate: 21 -12 -2009

SJ C- .1- .9 C.pk

SJ C-1-~ 1.SP 3601 4000 .00 400.00 7.43 99.87 4.00 % T 5 1 .00

REF 4 000 99.39 2000 93.41 6003448 .46 8.12 3072.34 33 .90 2945 .26 43 .38 2820.04 41 .94 2739.45 52.931981 .63 91 .86 1914.95 92.63 182 3.61 93.26 1701.38 7.43 1595.35 13.621452 .97 58 .28 1390.29 51.78 130 8.76 44.33 1275.09 44 .40 1207.81 33.341169 .49 51 .23 1115.63 76.96 107 1.71 83.44 1016.08 85 .36 921 .99 91.46826.08 49 .43 746 .47 27 .68 692 .51 36 .62 651.13 40.19 535 .57 73.00452.34 69 .97

4 00 0. 0 30 00 20 00 15 00 10 00 4 00 .0

0 .0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

1 00 .0

cm -1

%T

3448.46

3072.34

2945.26

2820.04

2739.45

1981.63

1914.95

1823.61

1701.38

1595.35

1452.97

1390.29

1308.76

1275.09

1207.81

1169.49

1115.63

1071.71

1016.08

921.99

826.08

746.47

692.51

651.13

535.57

452.34

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.2-.8 C.pk

SJC-2-~1.SP 3601 4000.00 400.00 5.03 99.90 4.00 %T 5 1.00

REF 4 000 98.71 2000 94.94 6003443.28 5.03 2944.45 47 .23 2820.26 56.76 2739.06 69.56 2356.74 87.511983.61 94.37 1915.41 95.36 1701.81 9.41 1648.11 21.11 1594.54 11.721452.53 64.70 1387.22 55.14 1350.39 57.59 1311.25 55.35 1207.55 45.791169.54 66.14 1116.75 82.95 1071.12 89.20 1016.77 90.38 825.85 57.65746.89 33 .90 691.30 41.19 651.04 43.6 8 454.72 71.54

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3443.28

2944.45

2820.26

2739.06

235 6.74

1983.61

1915.41

17 01.81

1648.11

1594.54

1452.5 3

1387.22

1350.39

1311.25

1207.55

116 9.54

1116.75

1071.12

101 6.77

825.85

746.89

691.30

651.04

454.72

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.3-.7 C.pk

SJC-3-~1.SP 3601 4000.00 400.00 5.71 100.00 4.00 %T 5 1.00

REF 4 000 98.88 2000 94.24 6003459.33 10.05 3069.88 3 6.67 2941.90 22.79 2865.13 37.71 2739.65 60.712360.56 92.47 1978.55 9 2.73 1915.78 93.66 1703.62 5.71 1596.08 19.411450.49 51.70 1391.77 5 2.45 1309.89 41.12 1211.11 32.34 1117.95 64.631069.62 76.59 1019.47 8 2.16 908.34 89.63 826.41 57.00 747.26 31.04705.60 32 .67 651.00 43.23 526.91 66.18 4 54.25 72.51

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3459.33

3069.88

294 1.90

2865.13

2739.65

2360.56

1 978.55

1915.78

17 03.62

1596.08

1450.49

1391.77

1309.89

1211.11

1 117.95

1069.62

1019.47

908.34

826.41

747.26

70 5.60

651.00

526.91

454.25

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.4-.6 C.pk

SJC-4-~1.SP 3601 4000.00 400.00 5.03 99.95 4.00 %T 5 1.00

REF 4 000 98.02 2000 93.62 6003455.32 5.03 2943.23 22 .17 2867.49 36.69 2741.42 67.05 2644.03 76.532360.34 93.23 1979.11 92.66 1702.34 14.15 1596.17 19.09 1449.28 52.521390.13 53.94 1312.26 48.08 1221.66 43.56 1118.46 64.10 1068.11 77.621020.71 83.03 905.98 87 .80 825.64 67.20 747.51 41.19 708.66 38.87650.93 46 .69 501.66 60.43

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 455.32

294 3.23

2867.49

2741.42

2644.03

2360.34

1979.11

1702.34

1596.17

1449.28

1390.13

1312.26

1221.66

111 8.46

1068.11

102 0.71

905.98

825.64

747.51

708.66

650.93

501.66

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.5-.5 C.pk

SJC-5-~1.SP 3601 4000.00 400.00 6.32 100.00 4.00 %T 5 1.00

REF 4 000 98.65 2000 94.89 6003929.45 96.28 3450.26 6 .32 2942.44 22.24 2866.61 37.10 2741.33 68.762644.38 76.92 1977.97 9 3.82 1700.39 15.00 1594.85 19.89 1449.77 54.051389.46 54.41 1346.06 5 2.59 1312.30 48.46 1234.30 43.99 1172.10 63.521118.21 65.38 1067.27 7 8.84 1020.51 84.56 905.45 89.22 825.42 69.84748.25 43 .95 711.65 40.63 651.17 49.83 5 02.40 64.41

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 29.45

3450.26

294 2.44

2866.6 1

2741.33

2644.38

1 977.97

17 00.39

1594.85

1449.77

1389.46

1346.06

1312.30

1234.30

1172.10

1118.21

1067.27

102 0.51

905.45

825.42

748.25711.65

651.17

502.40

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJ C-.6-.4 C.pk

SJ C-6-~1.SP 3601 4000.00 400.00 6.32 99.99 4.00 %T 5 1.00

REF 4000 98 .17 2000 9 4.12 60039 29.03 96.31 3457.73 6.32 3072.54 34.70 2942.22 13.72 2 866.81 27 .4027 42.57 64.87 2641.57 70.96 1976.94 92.78 1706.09 8.85 1 595.75 25 .4914 49.01 46.87 1391.70 54.89 1312.18 43.21 1230.67 36.67 1172.30 60.1811 18.21 57.75 1065.78 74.61 1020.46 81.69 904.93 84.87 8 25.70 72.1274 8.60 44.96 712.74 40.63 650.99 50.6 6 498.36 61.31

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3929.03

3457.73

3072.54

2 942.22

286 6.81

2742.57

26 41.57

1976 .94

1706.09

1595.75

1449.01

13 91.70

1312.18

1230 .67

1172.30

111 8.21

106 5.78

1020.46

904.93

825.70

748.60

712.74

65 0.99

4 98.36

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.7-.3 C.pk

SJC-7-~1.SP 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4 000 97.56 2000 95.26 6003928.72 95.16 3448.97 6 .33 2942.30 17.51 2866.57 30.65 2664.42 74.231975.94 93.80 1706.83 1 1.35 1595.69 13.45 1447.60 45.72 1385.60 47.601348.47 39.04 1314.81 4 5.52 1227.34 42.61 1172.14 66.61 1118.20 59.391063.59 75.58 1020.14 8 2.05 903.99 82.04 825.25 75.63 749.80 49.90713.64 48 .66 650.68 54.43 496.55 59.64

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

392 8.72

3448.97

294 2.30

2866.5 7

2664.4 2

1975.94

1706.831595.69

1447.60

1385.60

1348.47

1314.81

1 227.34

1 172.14

111 8.20

1063.59

1020.14

903.99

825.2 5

749.80

713.64

650.68

496.55

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.8-.2 C.pk

SJC-8-~1.SP 3601 4000.00 400.00 6.94 99.99 4.00 %T 5 1.00

REF 4 000 98.11 2000 96.86 6003940.59 96.47 3452.56 11.92 2941.41 12.17 2866.33 29.08 2669.38 86.882064.94 95.65 1709.48 6.94 1594.76 23.83 1447.10 46.17 1388.23 59.641345.67 46.37 1313.98 47.59 1225.04 41.95 1171.48 74.79 1118.56 59.001060.65 79.52 1019.56 85.60 904.27 81.38 862.42 85.07 825 .20 81.65750.11 55 .32 714.94 57.87 650.83 61.6 4 494.52 60.89 416.70 88.59

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.59

3 452.56 294 1.41

2866.3 3

2669.38

206 4.94

17 09.48

1594.76

1447.10

13 88.23

1345.67

1313.98

1225.04

1171.48

111 8.56

1060.65

1019.56

904.27

862.42

825.20

750.11

714 .94

65 0.83 4 94.52

416.70

FTIR SPECTRUM

ACIC


Trichy-2


Date: 21-12-2009

SJC-.9-.1 C.pk

SJC-9-~1.SP 3601 4000.00 400.00 8.41 100.00 4.00 %T 5 1.00

REF 4 000 98.82 2000 97.87 6003450.45 22.38 2940.82 1 6.30 2865.76 38.95 2671.73 92.85 2066.37 96.591710.56 8.39 1594.44 37.41 1446.30 57.07 1345.87 57.48 1314.29 60.331223.65 57.75 1118.69 6 8.75 1057.84 86.19 1019.04 90.36 904.21 85.71863.28 89 .48 750.68 71.01 650.95 76.54 4 93.14 71.85 415.01 93.25

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 450.45

294 0.82

2865.7 6

2 671.73

206 6.37

17 10.56

1594.44

1446.30

1345.87

1314.29

1223.65

1118.69

1057.8 4

1019.04

904.21

863.28

750.68

65 0.95

4 93.14

41 5.01

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-1BD.sp

Date: 21-12-2009

SJC-1BD.pk

SJC-1BD.sp 3601 4000.00 400.00 6.32 99.90 4.00 %T 5 1.00

REF 4 000 99.33 2000 94.67 6003928.23 97.09 3446.84 6.32 2819.60 52.37 2738.80 63.28 2363.70 95.081982.17 93.61 1913.80 94.42 1824.00 94.71 1697.38 18.33 1594.54 10.431453.80 66.53 1387.26 52.24 1310.06 55.31 1206.73 48.10 1169.33 62.451114.11 85.01 1072.35 87.37 1015.97 88.91 924.10 93.62 825.54 55.94746.17 35 .49 690.95 41.50 651.10 43.6 5 545.73 67.86 452.91 69.90

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3928.23

3446.84

2819.60

2 738.80

236 3.70

1982.17

1913.80

18 24.00

16 97.38

1594.54

1453.8 0

13 87.26

1310.06

1206.73

116 9.33

1114.11

1072.35

1015.97

924.10

825.54

746.17

69 0.95

651 .10

545.73

452.91

Table - 7.4

Observations of FTIR spectrums for Cyclohexanone + Benzaldehyde mixture:

1(CH)

Cm-1

0.9(CH)

+ 0.1(BD)

Cm-1

0.8(CH)

+ 0.2(BD)

Cm-1

0.7(CH)

+ 0.3(BD)

Cm-1

0.6(CH)

+ 0.4(BD)

Cm-1

0.5(CH)

+ 0.5(BD)

Cm-1

*0.4(CH)

+ 0.6(BD)

Cm-1

0.3(CH)

+ 0.7(BD)

Cm-1

0.2(CH)

+ 0.8(BD)

Cm-1

0.1(CH)

+ 0.9(BD)

Cm-1

1(BD)

Cm-1

3930.873416.272940.922864.962720.592676.412063.831712.261598.041445.451355.791222.931119.111055.521018.37904.24864.54762.30651.44491.25413.81

3448.463072.342945.262820.042739.451981.631914.951823.611701.381595.351452.971390.291308.761275.091207.811169.491115.631071.711016.08921.99826.08746.47692.51651.13535.57452.34

3443.282944.452820.262739.062356.741983.611915.411701.811648.111594.541452.531387.221350.391311.251207.551169.541116.751071.121016.77825.85746.89691.30651.04454.72

3459.333069.882941.902865.132739.652360.561978.551915.781703.621596.081450.491391.771309.891211.111117.951069.621019.47908.34826.41747.26705.60651.00526.91454.25

3455.322943.232867.492741.422644.032360.341979.111702.341596.171449.281390.131312.261221.661118.461068.111020.71905.98825.64747.51708.66650.93501.66

3929.453450.262942.442866.612741.332644.381977.971700.391594.851449.771389.461346.061312.301234.301172.101118.211067.271020.51905.45825.42748.25711.65651.17502.40

3929.03

3457.733072.54

2942.22

2866.812742.57

2641.57

1976.941706.09

1595.75

1449.011391.70

1312.18

1230.671172.30

1118.21

1065.781020.46

904.93825.70

748.60

712.74650.99

498.36

3928.723448.972942.302866.572664.421975.941706.831595.691447.601385.601348.471314.811227.341172.141118.201063.591020.14903.99825.25749.80713.64650.68496.55

3940.593452.562941.412866.332669.382064.941709.481594.761447.101388.231345.671313.981225.041171.481118.561060.651019.56904.27862.42825.20750.11714.94650.83494.52416.70

3450.452940.822865.762671.732066.371710.561594.441446.301345.871314.291223.651118.691057.841019.04904.21863.28750.68650.95493.14415.01

3928.233446.842819.602738.802363.701982.171913.801824.001697.381594.541453.801387.261310.061206.731169.331114.111072.351015.97924.10825.54746.17690.95651.10545.73452.91


282

Fig-7.4: FTIR spectrums for Cylclohexanone + Benzyl Chloride mixture:

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-PH-D-13.sp

Date: 08-2-2010

SJC-PH-D-13.pk

SJ666F~1.SP 3601 4000.00 400.00 7.43 100.00 4.00 %T 5 1.00

REF 4 000 98.06 2000 95.04 6003930.87 96.55 3416.27 3 9.48 2940.92 13.42 2864.96 30.69 2720.59 91.032676.41 92.15 2063.83 9 4.22 1712.26 7.43 1598.04 15.54 1445.45 43.831355.79 28.26 1222.93 5 2.54 1119.11 60.60 1055.52 81.18 1018.37 85.37904.24 79 .06 864.54 86.10 762.30 71.15 6 51.44 84.16 491.25 69.72413.81 91 .89

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3930.87

3416.27

294 0.92

2864.9 6

2720.59

2676.412063.83

1712.26

1598.04

1445.45

1355.79

1222.93

111 9.11

1055.52

1018.37

904.24

864 .54

762.30

65 1.44

4 91.25

413.81

FTIR SPECTRUM

ACICSt.Joseph's College ( Autonomous )

Trichy-2

Spectrum Name: T5-0.1+0.9.spDate: 23-6-2010

T5-0.1+0.9.pk

T5-01_~1.SP 3601 4000.00 400.00 6.34 99.99 4.00 %T 5 1.00

REF 4000 99.26 2000 96.11 6003938.72 94.00 3429.25 6.34 2953.55 78.43 2868.05 93.06 2735.96 97.822346.29 89.15 2094.44 93.12 1963.51 94.84 1696.36 35.98 1642.59 30.101446.17 62.90 1267.71 65.07 1208.42 84.86 1077.29 88.60 692.94 14.18562.85 53.66

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3938.72

3429.25

2953.55

2868.05

2735.96

2346.29

2094.441963.51

1696.36

1642.59

1446.171267.71

1208.42

1077.29

692.94

562.85

FTIR SPECTRUM


Trichy-2


T5-0.2+0.8.pk

T5-02_~1.SP 3601 4000.00 400.00 6.36 100.00 4.00 %T 5 1.00

REF 4000 99.53 2000 95.63 6003430.60 6.36 2945.41 74.05 2337.88 94.71 2097.92 92.42 1642.25 32.131439.41 64.03 1266.68 73.56 1118.69 88.87 694.53 20.25 561.87 56.45

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3430.60

2945.41

2337.88

2097.92

1642.25

1439.41

1266.68

1118.69

694.53

561.87

FTIR SPECTRUM


Trichy-2


T5-0.3+0.7.pk

T5-03_~1.SP 3601 4000.00 400.00 6.43 100.00 4.00 %T 5 1.00

REF 4000 99.59 2000 94.75 6003961.87 93.14 3843.40 92.88 3428.60 6.43 3084.07 69.34 2942.09 37.112870.05 66.58 2672.42 97.25 2340.29 92.24 2081.12 91.26 1965.52 93.201706.87 16.91 1644.06 26.02 1443.48 46.32 1266.32 57.76 1118.65 76.37694.98 11.31 561.19 50.20

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3961.87

3843.40

3428.60

3084.07

2942.09

2870.05

2672.42

2340.29

2081.12

1965.52

1706.87

1644.06

1443.48

1266.32

1118.65

694.98

561.19

FTIR SPECTRUM


Trichy-2


T5-0.4+0.6.pk

T5-04_~1.SP 3601 4000.00 400.00 6.41 99.99 4.00 %T 5 1.00

REF 4000 99.46 2000 95.91 6003428.48 6.41 2942.64 50.23 2869.64 76.18 2341.75 93.90 2092.32 92.791705.86 30.17 1642.92 32.93 1437.36 61.09 1266.77 77.76 1118.22 85.02695.37 25.73 561.87 59.38

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3428.48

2942.64

2869.64

2341.752092.32

1705.86

1642.92

1437.36

1266.77

1118.22

695.37

561.87

FTIR SPECTRUM


Trichy-2


T5-0.5+0.5.pk

T5-05_~1.SP 3601 4000.00 400.00 10.10 99.99 4.00 %T 5 1.00

REF 4000 99.17 2000 95.95 6003954.27 95.23 3846.65 92.46 3429.92 10.10 2940.51 26.77 2672.64 96.702340.84 92.84 2160.51 92.74 1707.71 15.06 1439.70 46.83 1259.07 66.401116.77 75.84 693.78 17.89 564.90 59.29 495.10 65.64

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3954.27

3846.65

3429.92

2940.51

2672.642340.84

2160.51

1707.71

1439.70

1259.07

1116.77

693.78

564.90

495.10

FTIR SPECTRUM


Trichy-2


T5-0.6+0.4.pk

T5-06_~1.SP 3601 4000.00 400.00 6.42 100.00 4.00 %T 5 1.00

REF 4000 99.06 2000 95.57 6003427.60 6.42 2941.55 31.72 2871.24 57.77 2670.46 97.02 2338.25 93.742095.48 91.76 1708.49 19.24 1644.85 28.54 1434.46 49.21 1327.85 71.751223.61 73.43 1118.67 75.13 695.92 26.59 562.06 57.81 495.22 63.12

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3427.60

2941.55

2871.24

2670.46

2338.25

2095.48

1708.49

1644.85

1434.46

1327.851223.61

1118.67

695.92

562.06

495.22

FTIR SPECTRUM


Trichy-2


T5-0.7+0.3.pk

T5-07_~1.SP 3601 4000.00 400.00 10.07 100.00 4.00 %T 5 1.00

REF 4000 99.33 2000 96.62 6003944.24 96.24 3424.65 14.14 2940.78 11.85 2871.56 34.85 2669.55 94.902343.15 93.54 2080.23 93.77 1711.02 10.07 1439.91 39.45 1320.13 56.701223.82 59.01 1118.94 64.17 1053.16 80.22 900.83 82.99 697.16 28.24561.17 67.09 492.06 64.06

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3944.24

3424.652940.78

2871.56

2669.55

2343.15

2080.23

1711.02

1439.91

1320.13

1223.82

1118.94

1053.16900.83

697.16

561.17492.06

FTIR SPECTRUM


Trichy-2


T5-0.8+0.2.pk

T5-08_~1.SP 3601 4000.00 400.00 6.40 100.00 4.00 %T 5 1.00

REF 4000 99.35 2000 95.59 6003433.17 6.40 2939.64 15.27 2669.51 96.64 2341.31 93.50 2088.84 92.001709.04 10.13 1435.96 45.29 1323.52 63.44 1227.12 68.32 1117.88 71.81694.24 36.13 496.08 60.45

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3433.17

2939.64

2669.51

2341.31

2088.84

1709.04

1435.96

1323.52

1227.121117.88

694.24

496.08

FTIR SPECTRUM


Trichy-2


T5-0.9+0.1.pk

T5-09_~1.SP 3601 4000.00 400.00 8.23 99.96 4.00 %T 5 1.00

REF 4000 99.80 2000 96.31 6003939.40 93.21 3431.16 11.48 2939.32 12.63 2669.81 95.45 2344.19 93.642084.29 92.85 1710.49 8.22 1436.22 42.62 1323.73 57.95 1225.65 63.711117.94 67.64 1049.11 82.69 892.23 82.25 693.96 51.89 494.63 65.04

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3939.40

3431.16 2939.32

2669.81

2344.19

2084.29

1710.49

1436.22

1323.73

1225.651117.94

1049.11

892.23

693.96

494.63

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: EA+BC-11.sp

Date: 2/14/2009

EA+BC-11.pk

EA9C82~1.SP 3601 4000.00 400.00 7.08 99.91 4.00 %T 5 2.00

REF 4 000 98.47 2000 59.62 6003906.50 94.80 3772.29 83.63 3435.57 39.14 3034.41 25.24 2960.75 35.212868.60 51.22 2708.50 60.11 2336.46 56.86 1956.03 48.63 1890.06 51.791811.47 53.04 1600.22 42.75 1493.17 41.14 1451.17 26.63 1266.87 19.471207.69 41.07 1074.43 41.36 1027.31 49.25 927.39 55.87 810.55 38.57759.02 31 .11 694.99 7.08 559.37 42.03 465.12 60.85

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 06.50

3772.29

3435.57

3034.41

2960.75

2868.60

270 8.50

2336.46

1956.03

189 0.06

1811.47

1600.2 2

1493.17

1451.17

1266.87

1207.69

1 074.43

1027.31

9 27.39

810 .55

7 59.02

694.99

559.3 7

465.12

Table - 7.5

Observations of FTIR spectrums for Cyclohexanone + Benzyl Cholride mixture

1(CH)

Cm-1

0.9(CH)

+

0.1(BC)

Cm-1

0.8(CH)

+

0.2(BC)

Cm-1

*0.7(CH)

+

0.3(BC)

Cm-1

0.6(CH)

+

0.4(BC)

Cm-1

0.5(CH)

+

0.5(BC)

Cm-1

0.4(CH)

+

0.6(BC)

Cm-1

0.3(CH)

+ 0.7(BC)

Cm-1

0.2(CH)

+

0.8(BC)

Cm-1

0.1(CH)

+

0.9(BC)

Cm-1

1(BC)

Cm-1

3930.873416.272940.922864.962720.592676.412063.831712.261598.041445.451355.791222.931119.111055.521018.37904.24864.54762.30651.44491.25413.81

3938.723429.252953.552868.052735.962346.292094.441963.511696.361642.591446.171267.711208.421077.29692.94562.85

3430.602945.412337.882097.921642.251439.411266.681118.69694.53561.87

3961.87

3843.40

3428.60

3084.07

2942.09

2870.05

2672.42

2340.29

2081.12

1965.52

1706.87

1644.06

1443.48

1266.32

1118.65

694.98

561.19

3428.482942.642869.642341.752092.321705.861642.921437.361266.771118.22695.37561.87

3954.273846.653429.922940.512672.642340.842160.511707.711439.701259.071116.77693.78564.90495.10

3427.602941.552871.242670.462338.252095.481708.491644.851434.461327.851223.611118.67695.92562.06495.22

3944.243424.652940.782871.562669.552343.152080.231711.021439.911320.131223.821118.941053.16900.83697.16561.17492.06

3433.172939.642669.512341.312088.841709.041435.961323.521227.121117.88694.24496.08

3939.403431.162939.322669.812344.192084.291710.491436.221323.731225.651117.941049.11892.23693.96494.63

3906.503772.293435.573034.412960.752868.602708.502336.461956.031890.061811.471600.221493.171451.171266.871207.691074.431027.31927.39810.55759.02694.99559.37465.12


283

Fig-7.5: FTIR spectrums for Cyclohexanone + 2-Butanone mixture:

FTIR SPECTRUM

ACIC

St.Joseph'sCollege ( Autonomous )

Trichy-2

SpectrumName: CyclohexanoneDate: 08-2-2010

SJC-PH-D-13.pk

SJ666F~1.SP 3601 4000.00 400.00 7.43 100.00 4.00 %T 5 1.00

REF4000 98.062000 95.046003930.87 96.55 3416.27 39.48 2940.92 13.42 2864.96 30.69 2720.59 91.032676.41 92.15 2063.83 94.22 1712.26 7.43 1598.04 15.54 1445.45 43.831355.79 28.26 1222.93 52.54 1119.11 60.60 1055.52 81.18 1018.37 85.37904.24 79.06 864.54 86.10 762.30 71.15 651.44 84.16 491.25 69.72413.81 91.89

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3930.87

3416.27

2940.92

2864.96

2720.59

2676.41 2063.83

1712.26

1598.04

1445.45

1355.79

1222.93

1119.11

1055.52

1018.37

904.24

864.54

762.30

651.44

491.25

413.81

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-Ph-2.sp

Date: 06-1-2010

SJC-Ph-2.pk

SJC-Ph-2. sp 3601 4000.00 400.00 7.58 100.00 4.00 %T 5 1.00

REF 4 000 97.34 2000 96.37 6003941.98 95.03 3458.27 1 7.89 2940.98 11.48 2865.06 25.66 2672.01 86.932175.67 92.77 2064.23 9 3.26 1971.59 95.17 1870.28 94.51 1804.50 83.191711.76 7.57 1595.67 17.94 1447.94 40.63 1347.44 33.99 1313.97 43.781222.69 46.44 1119.11 5 2.84 1054.51 75.33 1017.94 81.43 904.48 71.63864.14 80 .18 751.38 63.17 652.02 74.78 4 91.26 58.91 412.78 86.93

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3941.98

3458.27

294 0.98

2865.0 6

2672.01

21 75.67

206 4.23

19 71.59

187 0.28

1804.50

17 11.76

1595.67

1447.94

1347.44

1313.97

1222.69

111 9.11

1054.51

1017.94

904.48

864 .14

751.38

65 2.02

4 91.26

412.7 8

FTIR SPECTRUM

ACIC


Trichy-2


Date: 06-1-2010

SJC-Ph-3.pk

SJC-Ph-3. sp 3601 4000.00 400.00 7.50 100.00 4.00 %T 5 1.00

REF 4 000 97.50 2000 96.56 6003938.83 95.20 3486.61 3 0.92 2940.72 10.73 2865.20 24.67 2671.09 85.692334.58 94.42 2175.95 9 3.18 2063.95 93.35 1971.50 94.86 1870.77 94.471805.13 82.88 1712.15 7 .50 1633.84 42.74 1596.25 41.54 1448.02 39.831343.92 44.12 1313.17 4 3.98 1222.70 43.59 1119.19 49.62 1054.56 72.081018.22 79.19 904.61 70.08 864.50 80 .10 750.74 66.53 652.39 79.62491.14 60 .66 412.30 88.11

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3938.83

3486.61

294 0.72

2865.20

2671.09

233 4.58

2175.95

2063.95

1971.50

1870.77

1805.13

17 12.15

1633.84

1596.25

1448.0 2

1343.92

1313.17

1222.70

111 9.19

1054.56

1018.22

904.61

864.50

750.74

65 2.39

4 91.14

412.30

FTIR SPECTRUM

ACIC


Trichy-2


Date: 06-1-2010

SJC-Ph-4.pk

SJC-Ph-4. sp 3601 4000.00 400.00 7.33 99.99 4.00 %T 5 1.00

REF 4 000 96.99 2000 95.42 6003941.66 93.34 3456.40 9.17 2941.69 7.88 2866.39 18.17 267 1.60 82.282425.67 95.27 2335.42 93.58 2175.98 90.55 2065.44 91.20 1970.17 93.731870.36 93.18 1712.13 7.33 1595.99 11.79 1444.77 31.21 1348.44 26.541223.16 40.77 1119.47 47.81 1055.54 71.94 1018.62 79.94 904.01 69.19864.59 79 .53 752.07 58.76 652.13 71.0 4 492.34 54.64 413.79 88.06

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3941.66

3456.40 294 1.69

2866.39

2671.60

2425.67

23 35.42

2175.9 8

2065.44

1970.17

187 0.36

1712.13

1595.99

1444.77

1348.4 4

1223.16

111 9.47

1055.5 4

1018.62

904.01

864.59

752.07

65 2.13

4 92.34

413 .79

FTIR SPECTRUM

ACIC


Trichy-2


Date: 06-1-2010

SJC-Ph-5.pk

SJC-Ph-5. sp 3601 4000.00 400.00 6.67 100.00 4.00 %T 5 1.00

REF 4 000 97.76 2000 96.65 6003930.88 94.72 3785.94 9 2.03 3425.95 7.89 2941.89 10.71 2866.21 23.762672.09 84.35 2335.31 9 4.61 2175.58 91.97 1970.58 95.29 1870.08 94.681712.54 7.87 1595.59 6.67 1444.92 34 .90 1351.48 21.97 1222.88 46.691173.09 78.85 1119.41 5 3.87 1055.78 76.45 1018.44 83.85 903.80 73.44863.95 82 .11 752.83 57.71 651.80 68.48 4 92.55 55.19 414.81 87.41

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3930.88

3785.94

3 425.95294 1.89

2866.21

26 72.09

233 5.31

2175.5 8

1970.58

1870.08

1712.54

15 95.59

1444.92

1351.48

1222.88

1173.09

111 9.41

1055.78

1 018.44

903.80

863 .95

752.83

65 1.80

4 92.55

414.8 1

FTIR SPECTRUM

ACIC


Trichy-2


Date: 06-1-2010

SJC-Ph-6.pk

SJC-Ph-6. sp 3601 4000.00 400.00 8.87 100.00 4.00 %T 5 1.00

REF 4 000 98.52 2000 97.98 6003939.27 97.31 3444.29 3 0.13 2940.14 16.16 2864.72 37.42 2672.28 93.642175.05 95.76 1711.65 8 .86 1594.77 29.37 1448.26 55.70 1347.75 50.151313.49 58.91 1222.63 6 0.68 1119.16 66.71 1054.18 86.31 1018.04 89.90905.04 83 .14 863.78 87.92 751.37 74.26 6 52.25 81.35 491.53 70.87413.13 92 .72

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3939.27

3444.29

294 0.14

2864.72

2 672.282175.0 5

17 11.65

1594.77

1448.26

1347.75

1313.49

1222.63

111 9.16

1054.18

1018.04

905.04

863.78

751.37

65 2.25

4 91.53

413.13

FT IR S PECTR UM

ACIC

St. Joseph's C ollege ( Autonomous )Tric hy-2

Spect rum Na me: SJC-Ph -7. sp

Date: 06-1-2010

SJ C-P h-7.pk

SJ C-P h-7.sp 3 601 4000. 00 400.00 7.84 100.00 4. 00 %T 5 1.00

R EF 4000 98.24 2000 97.02 6003931.83 96.15 3475.72 24. 90 2940.74 10.15 2865.95 26.13 267 0.63 89. 562357.45 90.08 2175.74 94. 14 1711.79 7. 84 1594.83 35.88 1445. 36 43.781344.36 46.70 1314.79 49. 12 1223.01 49.96 1119.28 57.24 105 5.43 79. 211018.30 85.16 904.02 75. 98 864.60 84 .36 751.08 69.37 65 2.62 78.82491. 86 64.33 413.86 90. 77

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3931.83

3475.7 2

2940.74

2865.95

2670.63

2357.45

2175.74

1711.79

1594.83

1445.36

1344.36

1314.79

1223.01

1119.2 8

105 5.43

101 8.30

90 4.02

864 .60

751.08

652.62

491.86

4 13.86

FTIR SPECTRUM

ACIC


Trichy-2


Date: 06-1-2010

SJC-Ph-8.pk

SJC-Ph-8. sp 3601 4000.00 400.00 7.26 100.00 4.00 %T 5 1.00

REF 4 000 97.86 2000 96.48 6003941.98 96.27 3458.65 1 6.44 2940.54 9.09 2865.35 23.40 2672.25 90.322175.51 93.62 1871.35 9 6.24 1804.85 87.89 1711.95 7.26 1593.26 27.471448.37 40.88 1346.95 4 0.04 1313.53 46.24 1222.78 47.11 1173.23 85.991119.36 55.09 1054.55 8 1.06 1018.04 86.59 905.44 76.63 864.25 85.20751.15 67 .93 652.42 78.65 491.75 61.55 4 12.32 90.08

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3941.98

3458.65

294 0.54

2865.35

2672.25

2175.51

1871.35

180 4.85

1711.95

1593.26

1448.371346.95

1313.53

1222.78

1173.23

111 9.36

1054.5 5

1018.04

905.44

864.25

751.15

65 2.42

4 91.75

412.3 2

FTIR SPECTRUM

ACIC


Trichy-2


Date: 06-1-2010

SJC-Ph-9.pk

SJC-Ph-9. sp 3601 4000.00 400.00 9.63 100.00 4.00 %T 5 1.00

REF 4 000 98.17 2000 97.25 6003939.57 96.80 3448.12 2 0.74 2940.50 13.18 2865.71 33.48 2672.58 92.772175.01 95.21 1711.57 9 .62 1594.84 24.68 1445.49 51.33 1351.35 44.731222.98 59.86 1119.39 6 6.51 1055.25 86.13 1018.56 90.22 904.56 83.81863.74 89 .50 752.27 74.25 651.99 80.62 4 92.42 69.00 415.02 91.60

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3939.5 7

3448.12

294 0.50

2865.71

2672.58

2175.01

17 11.57

1594.84

1445.49

1351.35

1222.98

111 9.39

1055.25

1018.56

904.56

863.74

752.27

65 1.99

4 92.42

415.02

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-Ph-10. sp

Date: 06-1-2010

SJC-Ph-10.pk

SJC-PH~1.SP 3601 4000.00 400.00 6.50 100.00 4.00 %T 5 1.00

REF 4 000 99.10 2000 98.49 6003921.39 97.01 3790.77 9 4.70 3437.07 12.79 2942.07 40.75 2863.81 63.082834.19 65.58 2721.81 8 9.94 2169.05 96.21 1710.70 30.25 1593.38 6.501449.89 70.25 1360.76 2 5.90 1222.39 83.52 1171.44 93.02 1119.54 84.701053.06 94.37 903.84 94.36 774.12 66 .41 586.34 73.54 494.26 74.79

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3921.39

379 0.77

3437.07

294 2.07

2863.8 1

2834.19

2 721.81

2169.05

17 10.70

159 3.38

1449.8 9

1360.76

1222.39

1171.44

11 19.54

1053.06

903.84

774.12

586.34

4 94.26

FTIR SPECTRUM

ACIC

St.Joseph 's College ( Autonomous )

Trichy-2

Spectrum Name: 2-Butanone

Cl-AN-11.pk

Cl-AN-11.sp 3601 4000.00 400.00 6.34 99.17 4.00 %T 5 1.00

REF 4000 88.37 2000 83.26 6003921.99 87.11 3778.25 73.94 3445.42 6.34 2930.86 71.20 2087.47 82.531815.01 86.05 1626.89 35.54 1409.75 68.12 1247.00 74.30 1117.88 55.351011.07 61.13 563.25 53.03

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3921.99

3778.25

3445.42

2930.86

2087.471815.01

1626.89

1409.75

1247.00

1117.88

1011.07

563.2

Table - 7.6

Observations of FTIR spectrums for Cyclohexanone + 2-Butanone mixture:

1(CH)

Cm-1

0.9(CH)

+ 0.1(2B)

Cm-1

0.8(CH)

+ 0.2(2B)

Cm-1

0.7(CH)

+ 0.3(2B)

Cm-1

*0.6(CH)

+ 0.4(2B)

Cm-1

0.5(CH)

+ 0.5(2B)

Cm-1

0.4(CH)

+ 0.6(2B)

Cm-1

0.3(CH)

+ 0.7(2B)

Cm-1

0.2(CH)

+ 0.8(2B)

Cm-1

0.1(CH)

+ 0.9(2B)

Cm-1

1(2B)

Cm-1

3930.873416.272940.922864.962720.592676.412063.831712.261598.041445.451355.791222.931119.111055.521018.37904.24864.54762.30651.44491.25413.81

3941.983458.272940.982865.062672.012175.672064.231971.591870.281804.501711.761595.671447.941347.441313.971222.691119.111054.511017.94904.48

864.14751.38652.02491.26412.78

3938.833486.612940.722865.202671.092334.582175.952063.951971.501870.771805.131712.151633.841596.251448.021343.921313.171222.701119.191054.561018.22904.61864.50750.74652.39

491.14412.30

3941.663456.402941.692866.392671.602425.672335.422175.982065.441970.171870.361712.131595.991444.771348.441223.161119.471055.541018.62904.01864.59752.07652.13492.34413.79

3930.88

3785.943425.95

2941.89

2866.212672.09

2335.312175.58

1970.58

1870.081712.54

1595.59

1444.921351.48

1222.88

1173.091119.41

1055.78

1018.44903.80

863.95

752.83651.80

492.55

414.81

3939.273444.292940.142864.722672.282175.051711.651594.771448.261347.751313.491222.631119.161054.181018.04905.04863.78751.37652.25491.53413.13

3931.833475.722940.742865.952670.632357.452175.741711.791594.831445.361344.361314.791223.011119.281055.431018.30904.02864.60751.08652.62491.86413.86

3941.983458.652940.542865.352672.252175.511871.351804.851711.951593.261448.371346.951313.531222.781173.231119.361054.551018.04905.44864.25751.15652.42491.75412.32

3939.573448.122940.502865.712672.582175.011711.571594.841445.491351.351222.981119.391055.251018.56904.56863.74752.27651.99492.42415.02

3921.393790.773437.072942.072863.812834.192721.812169.051710.701593.381449.891360.761222.391171.441119.541053.06903.84774.12586.34494.26

3921.993778.253445.422930.862087.471815.011626.891409.751247.001117.881011.07563.25


284

Fig-7.6: FTIR spectrums for Cyclohexanone + Ethyl Acetate mixture:

FTIR SPECTRUM

ACIC

St.Joseph'sCollege( Autonomous )

Trichy-2

SpectrumName: Cyclohexanone

Date: 08-2-2010

SJC-PH-D-13.pk

SJ666F~1.SP 3601 4000.00 400.00 7.43 100.00 4.00 %T 5 1.00

REF400098.06 200095.04 6003930.87 96.55 3416.27 39.48 2940.92 13.42 2864.96 30.69 2720.59 91.032676.41 92.15 2063.83 94.22 1712.26 7.43 1598.04 15.54 1445.45 43.831355.79 28.26 1222.93 52.54 1119.11 60.60 1055.52 81.18 1018.37 85.37904.24 79.06 864.54 86.10 762.30 71.15 651.44 84.16 491.25 69.72413.81 91.89

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3930.87

3416.27

2940.92

2864.96

2720.59

2676.41 2063.83

1712.26

1598.04

1445.45

1355.79

1222.93

1119.11

1055.52

1018.37

904.24

864.54

762.30

651.44

491.25

413.81

FTIR SPECTRUM


Trichy-2

Spectrum Name: SJ C-Ph-S-3.spDate: 09-3-2010

SJ C-Ph-S-3.pk

SJ D901~1.SP 3601 4000.00 400.00 7.48 100.00 4.00 %T 5 2.00

REF 4000 97.24 2000 96.69 6003780.79 90.13 3411.76 57.34 2941.37 9.65 2865.51 24.46 2671.56 89.812364.76 95.22 2065.06 95.03 1713.81 7.48 1447.98 38.66 1382.60 62.101340.94 52.75 1312.48 43.77 1229.67 28.35 1118.67 46.81 1053.64 57.50905.48 70.40 864.26 79.01 750.38 71.71 651.40 85.64 490.42 62.70412.01 87.97

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3780.79

3411.76

2941.37

2865.51

2671.56

2364.76 2065.06

1713.81

1447.98

1382.60

1340.94

1312.48

1229.67

1118.67

1053.64

905.48

864.26

750.38

651.40

490.42

412.01

FTIR SPECTRUM


Trichy-2


SJ C-Ph-S-4.pk

SJ D905~1.SP 3601 4000.00 400.00 7.70 99.99 4.00 %T 5 2.00

REF 4000 99.20 2000 98.63 6003779.32 92.84 3464.57 55.53 2943.02 27.47 2867.07 48.04 2672.44 94.892363.51 96.74 2088.47 96.33 1758.93 20.13 1446.45 55.59 1378.25 46.791310.99 61.03 1241.51 7.69 1114.95 62.58 1053.72 38.81 907.14 85.19849.95 79.54 751.03 86.32 638.34 88.40 490.73 81.03 412.60 96.53

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3779.32

3464.57

2943.02

2867.07

2672.44

2363.51

2088.47

1758.93

1446.45

1378.25

1310.99

1241.51

1114.95

1053.72

907.14

849.95

751.03

638.34

490.73

412.60

FTIR SPECTRUM


Trichy-2


SJ C-Ph-S-5.pk

SJ C-PH~4.SP 3601 4000.00 400.00 7.54 100.00 4.00 %T 5 2.00

REF 4000 97.61 2000 97.06 6003781.38 92.07 3497.27 48.00 2941.24 10.23 2866.49 23.76 2670.51 88.702355.74 94.20 2070.74 94.54 1714.04 7.54 1444.94 36.02 1377.64 49.611312.68 42.95 1238.06 12.43 1117.68 47.17 1052.09 41.30 904.82 69.64850.74 67.76 750.70 70.73 649.02 82.80 491.04 62.50 413.43 88.05

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3781.38

3497.27

2941.24

2866.49

2670.51

2355.74

2070.74

1714.04

1444.94

1377.64

1312.68

1238.06

1117.68

1052.09

904.82

850.74

750.70

649.02

491.04

413.43

FTIR SPECTRUM


Trichy-2


SJ C-Ph-S-6.pk

SJ C-PH~2.SP 3601 4000.00 400.00 7.81 100.00 4.00 %T 5 2.00

REF 4000 95.96 2000 95.35 6003780.24 88.11 3411.44 52.61 2941.63 8.45 2866.50 19.81 2670.81 85.202356.77 90.99 2068.86 92.99 1714.72 7.81 1445.48 30.76 1378.90 49.701313.15 37.56 1236.88 12.64 1117.99 41.06 1053.60 40.97 904.27 64.32853.79 60.72 750.64 65.05 650.16 79.81 556.60 88.18 490.88 57.85413.70 85.04

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3780.24

3411.44

2941.63

2866.50

2670.81

2356.772068.86

1714.72

1445.48

1378.90

1313.15

1236.88

1117.99

1053.60

904.27

853.79

750.64

650.16

556.60

490.88

413.70

FTIR SPECTRUM


Trichy-2


SJ C-Ph-S-7.pk

SJ C-PH~3.SP 3601 4000.00 400.00 6.19 100.00 4.00 %T 5 2.00

REF 4000 78.90 2000 78.49 6003781.77 76.22 3514.51 52.70 3409.98 53.77 2940.59 10.35 2865.74 20.222671.35 69.49 2066.97 76.33 1713.00 6.19 1447.87 28.48 1375.48 41.051342.03 38.85 1312.07 32.46 1237.99 11.62 1118.03 35.97 1051.28 32.43905.15 52.69 846.40 40.14 750.72 53.62 649.90 65.86 557.71 72.65490.84 48.89 416.18 76.61

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3781.77

3514.51

3409.98

2940.59

2865.74

2671.35

2066.97

1713.00

1447.87

1375.48

1342.03

1312.07

1237.99

1118.03

1051.28

905.15

846.40

750.72

649.90

557.71

490.84

416.18

FTIR SPECTRUM


Trichy-2


SJ C-Ph-S-8.pk

SJ E905~1.SP 3601 4000.00 400.00 7.48 99.99 4.00 %T 5 2.00

REF 4000 97.39 2000 96.89 6003778.20 89.87 3501.95 58.30 2941.59 10.65 2866.55 24.05 2671.04 88.362360.34 93.80 2068.09 95.05 1713.85 7.48 1444.69 34.89 1380.39 60.281313.24 40.80 1233.98 20.54 1118.41 45.28 1053.93 51.32 904.56 67.70863.98 77.30 750.55 69.40 651.00 83.61 490.93 60.67 413.42 86.66

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3778.20

3501.95

2941.59

2866.55

2671.04

2360.342068.09

1713.85

1444.69

1380.39

1313.24

1233.98

1118.41

1053.93

904.56

863.98

750.55

651.00

490.93

413.42

FTIR SPECTRUM


Trichy-2


SJ C-Ph-S-9.pk

SJ C-PH~1.SP 3601 4000.00 400.00 7.63 100.00 4.00 %T 5 2.00

REF 4000 97.62 2000 97.10 6003787.98 91.94 3493.45 51.82 3161.64 76.74 2942.69 19.00 2866.30 35.562671.88 92.46 2358.27 94.30 2088.74 94.47 1712.83 16.05 1449.13 43.671379.09 39.22 1311.35 50.60 1241.32 7.62 1168.92 76.15 1116.91 53.111052.40 34.81 906.23 77.10 844.94 42.72 751.06 74.33 635.35 83.92557.86 79.85 490.75 71.81 412.79 89.19

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3787.98

3493.45

3161.64

2942.69

2866.30

2671.88

2358.27

2088.74

1712.83

1449.13

1379.09

1311.35

1241.32

1168.92

1116.91

1052.40

906.23

844.94

751.06

635.35

557.86

490.75

412.79

FTIR SPECTRUM


Trichy-2


SJ C-Ph-S-10.pk

SJ AE41~1.SP 3601 4000.00 400.00 6.69 100.00 4.00 %T 5 2.00

REF 4000 75.70 2000 73.48 6003778.61 65.37 3411.21 42.81 2941.51 6.68 2865.37 17.25 2671.91 68.291714.06 7.41 1447.56 30.86 1381.89 47.86 1312.37 34.07 1231.49 21.241118.64 37.09 1053.70 43.97 905.61 54.98 864.46 61.52 750.40 56.19651.34 65.91 490.48 50.28

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3778.61

3411.21

2941.51

2865.37

2671.91

1714.06

1447.56

1381.89

1312.37

1231.49

1118.64

1053.70

905.61

864.46

750.40

651.34

490.48

FTIR SPECTRUM


Trichy-2


SJ C-Ph-S-11.pk

SJ A651~1.SP 3601 4000.00 400.00 8.26 99.99 4.00 %T 5 2.00

REF 4000 97.49 2000 96.94 6003778.66 90.23 3413.80 60.94 2940.58 14.43 2865.29 32.89 2671.56 92.241713.29 8.25 1447.89 47.51 1383.37 73.34 1340.51 60.75 1312.44 51.961225.64 42.35 1118.80 55.58 1053.54 70.66 905.41 76.75 864.52 84.16750.29 76.85 651.75 87.84 490.53 69.11 412.20 89.01

4 00 0. 0 3 00 0 2 00 0 15 00 10 00 40 0 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3778.66

3413.80

2940.58

2865.29

2671.56

1713.29

1447.89

1383.37

1340.51

1312.44

1225.64

1118.80

1053.54

905.41

864.52

750.29

651.75

490.53

412.20

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Ethyl Acetate

Cl-AN-1.pk

Cl-AN-1.sp 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 99.39 2000 97.58 6003449.55 6.33 2991.58 69.36 2489.19 98.54 2362.08 89.00 2088.87 95.421763.76 32.63 1637.15 43.78 1378.64 67.05 1242.81 18.73 1056.51 55.12928.00 97.75 622.08 69.86

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3449.55

2991.58

2489.19

2362.08

2088.87

1763.76

1637.15

1378.64

1242.81

1056.51

928.0

622.0

Table - 7.7

Observations of FTIR spectrums for Cyclohexanone + Ethyl Acetate mixture:

1(CH)

Cm-1

0.9(CH)

+

0.1(EA)

Cm-1

0.8(CH)

+

0.2(EA)

Cm-1

0.7(CH)

+

0.3(EA)

Cm-1

0.6(CH)

+

0.4(EA)

Cm-1

*0.5(CH)

+ 0.5(EA)

Cm-1

0.4(CH)

+

0.6(EA)

Cm-1

0.3(CH)

+

0.7(EA)

Cm-1

0.2(CH)

+

0.8(EA)

Cm-1

0.1(CH)

+

0.9(EA)

Cm-1

1(EA)

Cm-1

3930.87

3416.27

2940.92

2864.96

2720.59

2676.41

2063.83

1712.26

1598.04

1445.45

1355.79

1222.93

1119.11

1055.52

1018.37

904.24

864.54

762.30

651.44

491.25

413.81

3780.79

3411.76

2941.37

2865.51

2671.56

2364.76

2065.06

1713.81

1447.98

1382.60

1340.94

1312.48

1229.67

1118.67

1053.64

905.48

864.26

750.38

651.40

490.42

412.01

3779.32

3464.57

2943.02

2867.07

2672.44

2363.51

2088.47

1758.93

1446.45

1378.25

1310.99

1241.51

1114.95

1053.72

907.14

849.95

751.03

638.34

490.73

412.60

3781.38

3497.27

2941.24

2866.49

2670.51

2355.74

2070.74

1714.04

1444.94

1377.64

1312.68

1238.06

1117.68

1052.09

904.82

850.74

750.70

649.02

491.04

413.43

3780.24

3411.44

2941.63

2866.50

2670.81

2356.77

2068.86

1714.72

1445.48

1378.90

1313.15

1236.88

1117.99

1053.60

904.27

853.79

750.64

650.16

556.60

490.88

413.70

3781.77

3514.51

3409.98

2940.59

2865.74

2671.35

2066.97

1713.00

1447.87

1375.48

1342.03

1312.07

1237.99

1118.03

1051.28

905.15

846.40

750.72

649.90

557.71

490.84

416.18

3778.20

3501.95

2941.59

2866.55

2671.04

2360.34

2068.09

1713.85

1444.69

1380.39

1313.24

1233.98

1118.41

1053.93

904.56

863.98

750.55

651.00

490.93

413.42

3787.98

3493.45

3161.64

2942.69

2866.30

2671.88

2358.27

2088.74

1712.83

1449.13

1379.09

1311.35

1241.32

1168.92

1116.91

1052.40

906.23

844.94

751.06

635.35

557.86

490.75

412.79

3778.61

3411.21

2941.51

2865.37

2671.91

1714.06

1447.56

1381.89

1312.37

1231.49

1118.64

1053.70

905.61

864.46

750.40

651.34

490.48

3778.66

3413.80

2940.58

2865.29

2671.56

1713.29

1447.89

1383.37

1340.51

1312.44

1225.64

1118.80

1053.54

905.41

864.52

750.29

651.75

490.53

412.20

3449.55

2991.58

2489.19

2362.08

2088.87

1763.76

1637.15

1378.64

1242.81

1056.51

928.00

622.08


285

Fig-7.7: FTIR spectrums for Hexane + Heptane mixture:

FTIR SPECTRUM

ACIC

St.Joseph's Colleg e ( Autonomous )

Trichy-2

Spectrum Name: Hex+Bz-11. sp

Date: 2/17/2009

Hex+Bz-11.pk

HEX_BZ~4.SP 3601 4000.00 400.00 6.33 9 8.66 4.00 %T 5 1.00

REF 4000 73.80 2000 56.81 6003838.59 68.32 3750.51 65.74 3443.99 6.33 2928.53 47.34 2727.89 65.852405.48 63.83 1628.07 19.08 1415.62 34.75 1117.52 36.84 1028.23 37.71712.33 39.7 2 615.48 38.51

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3838 .59

3750.51

3443.99

2928 .53

2727.89

240 5.48

1628.07

1415.621117.52

1028.23

7 12.33

615.48

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Sample -2.sp

Date: 3/5/2008

Sample -2.pk

SAMPLE~2.SP 3601 4000.00 400.00 6.32 99.82 4.00 %T 3 0.50

REF 4000 97.36 2000 93.26 6003915.97 95.60 3764.62 85.95 3443.57 6.32 2959.60 65.39 2929.60 69.912870.02 82.87 2373.48 94.57 2338.64 96.63 2090.58 91.24 1636.19 41.181392.73 60.54 1196.69 92.30 1120.98 82.82 652.75 65.73 607.50 65.28

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 915.97

3764.62

3443.57

2959 .60

2929.60

2870.02

237 3.48

2338.64

20 90.58

1636.19

1392.73

1196.69

1120.98

652.75607.50

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/5/2008

Sample -3.pk

SAMPLE~3.SP 3601 4000.00 400.00 6.32 99.37 4.00 %T 3 0.50

REF 4000 95.61 2000 91.14 6003762.32 82.50 3445.52 6.32 2960.28 68.75 2868.43 83.93 2372.32 87.482338.30 93.95 2100.58 88.88 1636.55 37.82 1393.87 54.99 1196.25 87.871120.44 78.05 607.48 59.55

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3762.32

344 5.52

2960.28

2868 .43

2372.32

2338.30

2100.58

1636.55

1393.87

11 96.25

1120.44

607.48

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/5/2008

Sample -4.pk

SAMPLE~4.SP 3601 4000.00 400.00 6.32 99.30 4.00 %T 3 0.50

REF 4000 99.16 2000 91.99 6003444.34 6.32 2958.69 62.27 2869.55 81.89 2372.30 89.99 2339.62 94.812097.43 89.64 1638.32 39.59 1393.19 60.76 1197.13 93.32 1121.90 85.46656.61 65.3 7 606.86 65.33

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3444.34

2958 .69

2869.55

2372.30

2339.62

2097.43

1638.32

1393.19

1197.13

1121.90

656.61

606.86

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/5/2008

Sample -5.pk

SA0150~1.SP 3601 4 000.00 400.00 6.32 99.49 4.00 %T 3 0.50

REF 4000 99.14 2000 90.45 6003762.46 81.13 3443.87 6.32 2959.73 70.00 2870.01 86.87 2373.95 91.142338.41 94.97 2097.45 88.13 1637.32 37.05 1393.57 57.58 1197.33 91.681121.63 82.64 655.39 63.09 606.35 62.47

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3762.46

344 3.87

2959 .73

2870.0 1

237 3.95

2338.41

2097.45

1637.32

1393.57

1197.33

1121.63

655.39

606.35

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/5/2008

Sample -6.pk

SA0950~1.SP 3601 4 000.00 400.00 5.02 99.23 4.00 %T 3 0.50

REF 4000 93.84 2000 85.92 6003444.54 5.02 2963.34 8.87 2880.66 32.87 2734.67 92.98 2618.71 93.102377.31 85.60 2339.15 95.57 2098.49 83.63 1638.05 34.06 1464.50 62.581390.37 45.95 1122.86 76.73 607.1 1 54.83

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

344 4.542963.34

2880.66

2734.6 7

26 18.71

237 7.31

2339.1 5

2098.49

1638.05

1464.50

13 90.37

1122.86

607.11

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/5/2008

Sample -7.pk

SA0160~1.SP 3601 4 000.00 400.00 6.38 98.84 4.00 %T 3 0.50

REF 4000 93.08 2000 86.76 6003764.86 77.62 3443.50 6.38 2963.43 8.28 2881.58 31.36 2736.02 92.112607.90 92.48 2378.82 88.57 2338.53 96.16 2098.42 84.67 1636.90 37.041464.69 61.36 1389.93 47.68 1122.81 76.74 604.99 60.69

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3764.86

3443.50 2963.43

2881.5 8

2736 .02

2607.902378.82

2338.53

2098.42

1636.90

1464.69

13 89.93

1122.81

60 4.99

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Sample-8. sp

Date: 3/7/2008

Sample-8.pk

Sample-8.sp 3601 4000.00 400.00 6.33 97.51 4.00 %T 3 1.00

REF 4000 84.55 2000 80.75 6003918.22 83.54 3772.95 76.26 3439.77 6.33 2966.44 19.88 2881.30 45.022382.58 82.21 2092.97 79.30 1632.89 35.32 1465.86 64.53 1389.67 42.541122.49 64.85 606.53 56.10

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3918.22

3772.95

343 9.77

2966.4 4

2 881.30

2382.58

20 92.97

1 632.89

1465.86

13 89.67

1122.49

606.53

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Sample-9. sp

Date: 3/7/2008

Sample-9.pk

Sample-9.sp 3601 4000.00 400.00 6.31 100.00 4.00 %T 3 0.50

REF 4000 86.60 2000 80.34 6003960.16 84.69 3772.70 76.04 3440.74 6.31 2966.7 7 52.44 2882.23 71.422623.58 86.22 2424.51 84.47 2099.25 78.9 5 1812.30 83.05 1634.40 35.681392.11 44.16 1195.14 76.80 1122.73 64.7 1 605.92 55.45

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3960 .16

3772.70

3440.74

2966.7 7

2882.23

26 23.58

2424 .51

2099.25

181 2.30

1 634.40

1392.11

1195.14

1122.73

605.92

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Sample-10.sp

Date: 3/7/2008

Sample-10.pk

SA1D50~1.SP 3601 4000.00 400.00 6.31 98 .56 4.00 %T 3 1 .00

REF 4000 86.21 2000 81.84 6003960.15 84.79 3774.28 76.92 3441.07 6.31 2968.93 71.85 2382.26 84.072339.42 94.42 2086.71 80.32 1634.48 35.73 1390.22 47.88 1195.75 79.211122.83 68.61 606.54 58.61

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3960.15

3774.28

3441.07

2968.93

2382.26

2339.42

20 86.71

1 634.48

13 90.22

11 95.75

1122.83

606.54

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/7/2008

Sample-11.pk

SA1560~1.SP 3601 4 000.00 400.00 7.17 98.93 4.00 %T 3 1.00

REF 4000 87.45 2000 71.02 6003962.13 84.51 3777.70 72.93 3438.87 11.47 2965.03 7.17 2882.61 25.462409.78 73.71 2085.72 70.14 1763.36 73.25 1628.27 42.24 1465.26 54.421387.28 35.79 1283.78 65.39 1120.95 58.93 608.79 57.38

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3962.13

3777.70

343 8.872965.03

2 882.61

2409.78

20 85.72

1763.36

1628.27

1465.26

1387.28

1283.78

1120.95608.79

Table - 7.8

Observations of FTIR spectrums for Hexane + Heptane mixture:

1(HX)

Cm-1

0.9(HX)

+

0.1(HP)

Cm-1

*0.8(HX)

+

0.2(HP)

Cm-1

0.7(HX)

+

0.3(HP)

Cm-1

0.6(HX)

+

0.4(HP)

Cm-1

0.5(HX)

+

0.5(HP)

Cm-1

0.4(HX)

+

0.6(HP)

Cm-1

0.3(HX)

+

0.7(HP)

Cm-1

0.2(HX)

+

0.8(HP)

Cm-1

0.1(HX)

+

0.9(HP)

Cm-1

1(HP)

Cm-1

3443.192964.612376.182095.631639.14

1394.631237.741196.981120.23656.26

607.16

3915.973764.623443.572959.602929.60

2870.022373.482338.642090.581636.19

1392.731196.691120.98607.50

3762.32

3445.522960.28

2868.43

2372.32

2338.30

2100.58

1636.551393.87

1196.25

1120.44607.48

3444.342958.692869.552372.302339.62

2097.431638.321393.191197.131121.90

656.61606.86

3762.463443.872959.732870.012373.95

2338.412097.451637.321393.571197.33

1121.63655.39606.35

3444.542963.342880.662734.672618.71

2377.312339.152098.491638.051464.50

1390.371122.86607.11

3764.863443.502963.432881.582736.02

2607.902378.822338.532098.421636.90

1464.691389.931122.81604.99

3918.223772.953439.772966.442881.30

2382.582092.971632.891465.861389.67

1122.49606.53

3960.163772.703440.742966.772882.23

2623.582424.512099.251812.301634.40

1392.111195.141122.73605.92

3960.153774.283441.072968.932382.26

2339.422086.711634.481390.221195.75

1122.83606.54

3962.133777.703438.872965.032882.61

2409.782085.721763.361628.271465.26

1387.281283.781120.95608.79


286

Fig-7.8: FTIR spectrums for Benzaldehyde + Hexane mixture:

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Hex+Bz-1.sp

Date: 2/17/2009

Hex+Bz-1.pk

HEA9C6~1.SP 3601 4000.00 400.00 7.90 99.06 4.00 %T 5 2.00

REF 4000 95.76 2000 88.36 6003392.00 42.17 3067.51 40.85 2818.96 37.18 2738.48 43.57 1981.96 86.081912.16 86.53 1826.42 85.60 1702.69 7.90 1596.15 26.12 1454.22 53.831393.10 54.44 1307.67 43.97 1205.49 29.19 1168.30 43.76 1110.98 74.241072.56 74.83 1014.39 75.69 924.0 7 85.56 826.40 44.04 746.58 27.49690.41 39.5 8 650.77 44.09 543.19 87.96 450.71 67.18

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3392.003067.51

2 818.96

273 8.48

1 981.96

1912.16

1826.42

1702 .69

1596.15

1454.22

1393.10

1307.67

1205.49

1168.30

1 110.98

1072.56

101 4.39

924.07

826.40

74 6.58

690.41

650.77

543.19

450.71

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/17/2009

Hex+Bz-2.pk

HEB9CA~1.SP 3601 4000.00 400.00 8.27 9 9.09 4.00 %T 5 1.00

REF 4000 92.26 2000 86.34 6003856.01 90.52 3393.85 46.16 3067.04 49.51 2818.41 44.59 2737.93 50.232235.20 91.22 2139.27 91.10 1982.16 84.60 1911.65 85.07 1826.68 84.361702.22 8.26 1595.80 30.55 1454.26 56.32 1392.47 58.03 1308.16 48.461204.57 31.81 1167.94 47.43 1110.93 73.85 1072.33 73.48 1014.06 73.77924.06 81.9 8 826.41 46.91 746.19 30.22 689.47 42.35 650 .20 46.94540.09 83.5 0 450.64 67.08

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3856.01

33 93.853067.04

2818.41

2737.93

2235.20

2139.27

1982.16

19 11.65

182 6.68

1702 .22

1595.80

1454.2 6

13 92.47

1308.16

1204.57

1167 .94

1110.9 3

1072.33

101 4.06

924.06

826.41

74 6.19

689.47

650.20

540.09

450.64

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/17/2009

Hex+Bz-3.pk

HEB9CE~1.SP 3601 4000.00 400.00 7.80 99.22 4.00 %T 5 1.00

REF 4000 94.76 2000 89.96 6003856.08 93.11 3395.06 44.30 3067.92 44.11 2819.03 43.29 2738.25 50.732236.15 93.76 1981.61 88.27 1912.95 88.41 1825.80 88.41 1702.47 7.801596.17 30.97 1453.88 58.70 1394.21 59.03 1306.83 46.79 1205.68 32.371168.75 49.53 1111.87 76.53 1072.42 78.97 1016.32 80.69 925.83 86.07826.51 50.1 7 746.19 32.07 690.83 43.67 650.57 48.64 542 .80 87.24450.49 73.7 4

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3856.08

33 95.06 3067.92

2 819.03

273 8.25

2236.15

1981.61

1912.95

1825.80

1702 .47

1596.17

1453.8 8

1394.21

1306.83

1205.68

1168.75

1111.87

1072.42

101 6.32

925.83

826.51

74 6.19

690.83

650.57

542.80

450.49

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/17/2009

Hex+Bz-4.pk

HEB9C2~1.SP 3601 4000.00 400.00 10.63 9 9.11 4.00 %T 5 1.00

REF 4000 95.66 2000 92.16 6003391.13 67.02 3066.90 62.88 2818.28 57.05 2737.99 62.32 1982.01 90.901912.00 91.23 1826.43 90.84 1702.27 10.62 1594.93 43.47 1454.06 68.371392.28 70.62 1308.56 60.92 1204.72 41.50 1167.49 59.39 1110.62 84.051071.85 83.55 1014.96 84.23 924.2 1 89.78 826.36 57.54 746.62 38.97689.26 53.7 8 650.17 58.34 542.21 92.08 450.27 78.20

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3391.13

3066.90

2 818.28

2737.99

1982.01

1912.00

1826.43

1702 .27

1594.93

1454.06

1392.28

1308.56

1204.72

1167.49

1110.62

1071.85

1014.96

924.21

826.36

74 6.62

689.26

650.17

542.21

450.27

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/17/2009

Hex+Bz-5.pk

HEB9C6~1.SP 3601 4000.00 400.00 8.40 99 .99 4.00 %T 5 1 .00

REF 4000 99.84 2000 96.16 6003391.42 70.09 3066.35 68.63 2965.51 80.07 2817.92 59.84 2737.62 65.082370.07 96.25 1981.82 94.85 1910.37 95.27 1826.60 94.62 1702.49 8.381594.67 43.21 1454.31 70.14 1391.72 73.93 1308.92 63.85 1204.30 40.131166.99 60.60 1109.59 88.40 1071.69 86.51 1014.44 86.78 923.07 94.67826.37 57.0 9 746.61 35.79 688.62 53.00 650.02 58.28 450 .36 80.03

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3391.42

3066.35

2965.51

2 817.92

27 37.62

2370.07 1981.82

1910.37

1826.60

1702 .49

1594.67

1454.3 1

1391.72

1308.92

1204.30

1166.99

1109.5 9

1 071.69

101 4.44

923.07

826.37

74 6.61

688.62

650.02

450.36

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/17/2009

Hex+Bz-6.pk

HEX_BZ~3.SP 3601 4000.00 400.00 9.86 9 9.23 4.00 %T 5 1.00

REF 4000 98.44 2000 96.33 6003754.69 96.07 3443.70 51.89 3068.66 64.84 2819.24 66.54 2738.18 73.272547.97 89.42 1981.77 95.56 1915.13 95.57 1700.71 9.86 1594.88 46.931453.28 70.88 1395.18 72.06 1288.65 60.49 1204.85 45.69 1168.37 64.081112.88 81.67 1071.53 83.86 1018.48 85.38 929.03 87.61 825.84 63.89745.68 44.7 0 689.51 53.31 649.75 57.20 545.50 84.16 449 .83 80.18

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3754 .69

344 3.70

3068.66

2819.24

2738.18

2 547.97

1981.77

1915.13

1700.71

1594.88

1453.28

1395.18

1288.65

1204.85

1 168.37

1112.88

1071.5 3

1018.48

929.03

825.84

74 5.68

689 .51

649.75

545.50

449.83

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/17/2009

Hex+Bz-7.pk

HEC9CE~1.SP 3601 4000.00 400.00 8.01 9 9.65 4.00 %T 5 1.00

REF 4000 93.35 2000 89.96 6003753.95 90.84 3438.06 53.88 3068.23 65.86 2818.22 59.98 2737.96 64.772407.99 91.88 1983.22 89.05 1910.32 89.43 1702.28 8.00 1594.92 40.221454.70 66.39 1392.24 69.28 1309.49 60.83 1204.30 38.00 1167.12 58.731110.58 82.25 1071.97 80.98 1015.76 81.09 923.97 89.16 826.57 54.58746.32 34.2 5 688.44 49.13 649.44 53.68 450.32 74.01

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3753 .95

343 8.06

3068.23

2 818.22

2737.96

2407.99

1983.2 2

19 10.32

1702 .28

1594.92

1454.7 0

1392.24

1309.49

1204.30

1 167.12

1110.58

1071.97

1 015.76

923.97

826.57

74 6.32

688.44

6 49.44

450.32

FTIR SPECTRUM

ACICSt. Joseph's College ( Autonomous )

Trichy-2

Spectrum Name: HEx+BZ-8. spDate: 3/11/2009

HEx+BZ-8.pk

HE79C2~1.SP 3601 4000.00 400.00 7.90 99.24 4.00 %T 5 1.00

REF 4000 99.04 2000 95.92 6003446.29 16.50 3069.14 55.81 2819.86 59.46 2735.88 70.28 2680.13 76.052556.97 78.16 2356.41 62.48 1981.74 94.70 1913.16 94.10 1826.65 97.631692.51 7.89 1597.28 35.66 1417.63 57.01 1287.45 35.28 1202.57 46.051118.74 72.97 1070.57 74.88 1022.40 80.54 928.86 66.02 822.62 67.07744.29 50.57 699.67 32.91 543.49 68.21 449.71 79.49

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3446.29

3069.14

2819.86

2735.88

2680.13

2556.97

2356.41

1981.74

1913.16

1826.65

1692.51

1597.28

1417.63

1287.45

1202.57

1118.74

1070.57

1022.40

928.86

822.62

744.29

699.67

543.49

449.71

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/17/2009

Hex+Bz-9.pk

HEX_BZ~1.SP 3601 4000.00 400.00 8.31 9 8.25 4.00 %T 5 1.00

REF 4000 90.78 2000 89.01 6003755.10 88.09 3443.57 30.77 3069.09 54.78 2962.26 59.31 2819.11 58.082736.59 66.55 2684.53 74.33 2550.96 76.84 1980.04 88.13 1915.12 87.811698.35 8.31 1595.35 36.75 1452.10 59.56 1413.91 57.65 1287.48 40.011204.80 41.72 1170.12 56.39 1116.42 70.19 1071.24 72.84 1021.16 75.88931.57 70.8 2 825.44 60.24 745.66 44.11 705.14 42.12 651 .38 52.70546.23 72.5 2 451.51 76.03

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3755 .10

344 3.57

3069.09

2962 .26

2 819.11

2736.59

2684.53

2550.96

1980.04

1915.12

1698.35

1595.35

1452.10

141 3.91

1287.48

1204.80

11 70.12

1116.42

1071.2 4

1021.16

931.57

825.44

745.66

705.14

651.38

546.23451.51

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/17/2009

Hex+Bz-10.pk

HEX_BZ~2.SP 3601 4000.00 400.00 7.88 9 9.67 4.00 %T 5 1.00

REF 4000 98.87 2000 87.61 6003754.42 95.11 3440.06 26.34 3069.23 47.77 2933.15 50.32 2820.54 51.752737.52 60.98 2551.46 75.65 1980.10 86.42 1912.43 85.77 1698.70 7.881596.29 27.95 1452.54 49.41 1405.56 47.92 1288.79 34.21 1204.91 33.581115.60 58.28 1071.89 61.92 1021.49 63.09 930.58 63.50 826.12 49.99745.46 35.2 1 703.88 35.16 651.10 43.54 545.52 66.27 452 .01 70.72

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

375 4.42

344 0.06

3069.23

2933.15

2 820.54

27 37.52

2551.46

1980.10

19 12.43

1698.70

1596.29

1 452.54

1405.56

1288.791204.91

1115.60

1 071.89

1021.49930.58

826.12

745.46

703.88

6 51.10

545.52

452.01

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/17/2009

Hex+Bz-11.pk

HEX_BZ~4.SP 3601 4000.00 400.00 6.33 9 8.66 4.00 %T 5 1.00

REF 4000 73.80 2000 56.81 6003838.59 68.32 3750.51 65.74 3443.99 6.33 2928.53 47.34 2727.89 65.852405.48 63.83 1628.07 19.08 1415.62 34.75 1117.52 36.84 1028.23 37.71712.33 39.7 2 615.48 38.51

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3838 .59

3750.51

3443.99

2928 .53

2727.89

240 5.48

1628.07

1415.621117.52

1028.23

7 12.33

615.48

Table - 7.9

Observations of FTIR spectrums for Benzaldehyde + Hexane mixture:

1(BD)

Cm-1

0.9(BD)

+

0.1(HX)

Cm-1

0.8(BD)

+

0.2(HX)

Cm-1

0.7(BD)

+

0.3(HX)

Cm-1

0.6(BD)

+

0.4(HX)

Cm-1

0.5(BD)

+

0.5(HX)

Cm-1

*0.4(BD)

+

0.6(HX)

Cm-1

0.3(BD)

+

0.7(HX)

Cm-1

0.2(BD)

+

0.8(HX)

Cm-1

0.1(BD)

+

0.9(HX)

Cm-1

1(HX)

Cm-1

3872.55

3752.13

3392.003067.512818.962738.481981.96

1912.161826.421702.691596.151454.221393.101307.671205.491168.301110.981072.561014.39924.07826.40746.58690.41650.77543.19450.71

3856.013393.853067.042818.412737.932235.202139.271982.161911.651826.681702.221595.801454.261392.471308.161204.571167.941110.931072.331014.06924.06826.41746.19689.47650.20540.09450.64

3856.083395.063067.922819.032738.252236.151981.611912.951825.801702.471596.171453.881394.211306.831205.681168.751111.871072.421016.32925.83826.51746.19690.83650.57542.80450.49

3391.133066.902818.282737.991982.011912.001826.431702.271594.931454.061392.281308.561204.721167.491110.621071.851014.96924.21826.36746.62689.26650.17542.21450.27

3391.423066.352965.512817.922737.622370.071981.821910.371826.601702.491594.671454.311391.721308.921204.301166.991109.591071.691014.44923.07826.37746.61688.62650.02450.36

3754.693443.703068.662819.242738.182547.971981.771915.131700.711594.881453.281395.181288.651204.851168.371112.881071.531018.48929.03825.84745.68689.51649.75545.50449.83

3753.95

3438.06

3068.232818.22

2737.96

2407.991983.22

1910.32

1702.281594.92

1454.70

1392.241309.49

1204.30

1167.12

1110.58

1071.97

1015.76923.97

826.57746.32

688.44

649.44450.32

3446.293069.142819.862735.882680.132556.972356.411981.741913.161826.651692.511597.281417.631287.451202.571118.741070.571022.40928.86822.62744.29699.67543.49449.71

3755.103443.573069.092962.262819.112736.592684.532550.961980.041915.121698.351595.351452.101413.911287.481204.801170.121116.421071.241021.16931.57825.44745.66705.14651.38546.23451.51

3754.423440.063069.232933.152820.542737.522551.461980.101912.431698.701596.291452.541405.561288.791204.911115.601071.891021.49930.58826.12745.46703.88651.10545.52452.01

3838.593750.513443.992928.532727.892405.481628.071415.621117.521028.23712.33615.48


287

Fig-7.9: FTIR spectrums for Hexane + 2-Butanone mixture:

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: RK H 0-1.sp

Date: 1/24/2009

RK H 0-1.pk

RKH0-1~1.SP 3601 4000.00 4 00.00 6.36 98.75 4.00 %T 5 1.00

REF 4000 93.53 2000 75.30 6003856.29 85.07 3755.04 78.56 3437.82 6.36 2927.98 56.76 2860.10 66.082725.15 76.93 2626.86 79.50 2498.58 78.86 2382.32 75.27 2100.44 74.691790.00 73.57 1626.68 21.69 1407.50 44.85 1113.20 52.09 866.86 83.19623.44 61.6 3 573.84 61.51 442.73 79.42

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3856.29

3755 .04

343 7.82

2927 .98

2860.10

2725.15

2626.86

2498.58

2382.32

2100.44179 0.00

1626.68

1407.50

1 113.20

866.86

623.44

573.84

442.73

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: RK H 0.1-0.9.sp

Date: 1/27/2009

RK H 0.1-0.9 .pk

RKH01-~1.SP 3601 4000.00 4 00.00 6.32 100.00 4.00 %T 5 1.00

REF 4000 99.09 2000 93.09 6003770.76 91.69 3451.21 6.32 2983.14 40.57 2369.2 7 91.86 2112.50 90.251736.88 24.28 1636.90 46.89 1425.35 66.7 5 1365.79 45.92 1172.15 46.791088.58 90.14 943.46 84.94 751.14 74.13 589.29 65.55

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3770.76

3451.21

2983 .14

2369.27

2112.50

1736.88

1 636.90

1425.35

1 365.79

1172 .15

1088.5 8

943.46

751.14

5 89.29

FTIR SPECTRUM

ACIC


Trichy-2


Date: 1/27/2009

RK H 0.2-0.8 .pk

RKH02-~1.SP 3601 4000.00 4 00.00 6.32 100.00 4.00 %T 5 1.00

REF 4000 93.55 2000 90.44 6003442.39 6.32 2363.97 87.57 2078.06 89.30 1636.5 7 41.37 1404.06 84.391110.29 89.82 665.02 69.99

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3442.39

2363.97

20 78.06

1636.57

1404.061110.29

665.02

FTIR SPECTRUM

ACIC


Trichy-2


Date: 1/27/2009

RK H 0.3-0.7 .pk

RKH03-~1.SP 3601 4000.00 4 00.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 91.30 2000 88.85 6003921.91 89.99 3773.79 85.99 3457.44 6.33 2367.6 3 88.22 2087.02 87.881636.89 42.85 1410.72 83.80 1107.70 85.9 0 606.37 72.27

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3921.91

3773.7 9

3457.44

2367.63

20 87.02

1636.89

1410.721107.70

606.37

FTIR SPECTRUM

ACIC


Trichy-2


Date: 1/27/2009

RK H 0.4-0.6 .pk

RKH04-~1.SP 3601 4000.00 4 00.00 6.32 99.99 4.00 %T 5 1.00

REF 4000 99.23 2000 94.43 6003767.49 92.66 3450.96 6.32 2982.89 70.14 2366.47 91.58 2097.85 92.681736.49 56.17 1637.25 43.59 1422.03 85.54 1366.54 75.09 1171.54 76.45941.67 96.6 2 589.32 69.79

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3767.49

3450.96

2982 .89

2366.47

2097.85

1736.49

1637.25

1 422.03

1 366.541171 .54

941.67

5 89.32

FTIR SPECTRUM

ACIC


Trichy-2


Date: 1/27/2009

RK H 0.5-0.5 .pk

RKH05-~1.SP 3601 4000.00 4 00.00 6.32 99.44 4.00 %T 5 1.00

REF 4000 98.33 2000 88.98 6003952.31 96.07 3771.15 84.78 3447.85 6.32 2974.55 65.76 2363.47 76.632104.86 86.82 1735.79 77.32 1633.52 46.02 1368.01 77.12 1170.28 81.141110.60 86.26 600.71 70.39

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3952.3 1

3771.15

344 7.85

2974.55

2363.47

210 4.86

1735.79

1 633.52

1 368.011170 .28

1110.60

600.71

FTIR SPECTRUM

ACIC


Trichy-2


Date: 1/27/2009

RK H 0.6-0.4 .pk

RKH06-~1.SP 3601 4000.00 4 00.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 99.10 2000 93.66 6003907.24 98.01 3769.68 92.18 3451.42 6.33 2965.8 1 44.27 2368.73 91.952098.86 91.94 1737.27 60.36 1636.57 46.8 3 1461.93 83.87 1367.97 75.331171.35 77.58 942.63 97.16 591.28 68.27

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3907.24

3769.68

3451.42

2965.81

2368.73

2098.86

1737.27

1636.57

1461.93

1 367.97

1171 .35

942.63

5 91.28

FTIR SPECTRUM

ACIC


Trichy-2


Date: 1/27/2009

RK H 0.7-0.3 .pk

RKH07-~1.SP 3601 4000.00 4 00.00 6.32 100.00 4.00 %T 5 1.00

REF 4000 99.29 2000 94.17 6003775.65 93.36 3455.17 6.32 2981.15 34.35 2361.6 3 90.81 2115.17 91.161735.24 21.06 1636.45 44.74 1422.14 60.1 4 1365.82 39.63 1259.45 91.231172.40 41.11 1087.65 89.22 943.56 80.00 753.72 74.54 588.95 65.65

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3775.65

345 5.17

2981 .15

2361.63

211 5.17

1735.24

1636.45

1422.14

1 365.82

1259.45

1172 .40

1087.65

943.56

753.72

5 88.95

FTIR SPECTRUM

ACIC


Trichy-2


Date: 1/27/2009

RK H 0.8-0.2 .pk

RKH08-~1.SP 3601 4000.00 4 00.00 7.34 99.99 4.00 %T 5 1.00

REF 4000 98.88 2000 94.62 6003957.00 97.52 3776.61 91.03 3452.92 15.60 2965.63 7.34 2882.80 29.342364.40 91.63 2100.69 93.43 1736.42 68.63 1634.05 59.54 1466.16 65.991376.54 70.47 1170.47 80.05 588.5 5 77.06

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3957 .00

3776.6 1

3452.92

2965.63

2882 .80

2364.40

2100.69

1736.42

1 634.05

1466.16

13 76.54

1170 .47588.55

FTIR SPECTRUM

ACIC


Trichy-2


Date: 1/27/2009

RK H 0.9-0.1 .pk

RKH09-~1.SP 3601 4000.00 4 00.00 6.32 99.99 4.00 %T 5 1.00

REF 4000 98.28 2000 89.89 6003963.75 96.94 3774.89 87.55 3450.00 6.32 2963.80 8.78 2882.43 30.012363.58 88.32 2087.18 88.17 1634.47 45.21 1465.35 65.82 1380.34 73.291167.09 87.27 593.01 64.46

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3963.75

3774.8 9

345 0.00 2963.80

2882.43

2363.58

2087.18

1 634.47

1465.35

1 380.34

1167.09

5 93.01

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: RK H 1-0.sp

Date: 1/27/2009

RK H 1-0.pk

RKH1-0~1.SP 3601 4000.00 4 00.00 6.32 99.99 4.00 %T 5 1.00

REF 4000 92.19 2000 80.27 6003919.93 90.20 3775.59 79.25 3449.68 6.32 2964.12 19.48 2882.41 41.182364.48 76.31 2097.24 78.71 1633.55 44.51 1465.81 70.76 1382.96 72.851115.82 81.05 614.13 65.14

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

391 9.93

3775.59

344 9.68

2964.12

2882.41

2364.48

20 97.24

1 633.55

1465.81

1382.96

1115.82

61 4.13

Table - 7.10

Observations of FTIR spectrums for Hexane + 2-Butanone mixture:

1(HX)

Cm-1

0.9(HX)

+

0.1(2B)

Cm-1

0.8(HX)

+

0.2(2B)

Cm-1

0.7(HX)

+

0.3(2B)

Cm-1

0.6(HX)

+

0.4(2B)

Cm-1

0.5(HX)

+

0.5(2B)

Cm-1

0.4(HX)

+

0.6(2B)

Cm-1

*0.3(HX)

+

0.7(2B)

Cm-1

0.2(HX)

+

0.8(2B)

Cm-1

0.1(HX)

+

0.9(2B)

Cm-1

1(2B)

Cm-1

3856.293755.043437.822927.982860.10

2725.152626.862498.582382.322100.441790.001626.681407.501113.20866.86623.44573.84442.73

3770.763451.212983.142369.272112.501736.881636.901425.351365.791172.151088.58943.46751.14589.29

3442.392363.972078.061636.571404.061110.29665.02

3921.913773.793457.442367.632087.021636.891410.721107.70606.37

3767.493450.962982.892366.472097.851736.491637.251422.031366.541171.54941.67589.32

3952.313771.153447.852974.552363.472104.861735.791633.521368.011170.281110.60600.71

3907.243769.683451.422965.812368.732098.861737.271636.571461.931367.971171.35942.63591.28

3775.65

3455.172981.15

2361.63

2115.171735.24

1636.45

1422.141365.82

1259.45

1172.401087.65

943.56

753.72588.95

3957.003776.613452.922965.632882.802364.402100.691736.421634.051466.161376.541170.47588.55

3963.753774.893450.002963.802882.432363.582087.181634.471465.351380.341167.09593.01

3919.933775.593449.682964.122882.412364.482097.241633.551465.811382.961115.82614.13


288

Fig-7.10: FTIR spectrums for Hexane + Ethyl Acetate mixture:

FTIR SPECTRUM


Trichy-2

Spectrum Name: EA+Hex-1.spDate: 2/18/2009

EA+Hex-1.pk

EA31CE~1.SP 3601 4000.00 400.00 6.32 99.74 4.00 %T 5 1.00

REF 4000 98.67 2000 92.84 6003964.09 97.24 3772.12 85.75 3449.31 6.32 2990.08 60.70 2929.67 61.592365.35 87.76 2091.73 90.07 1762.09 38.27 1629.98 42.76 1378.55 59.411242.99 19.75 1055.03 53.73 930.11 96.52 616.31 66.89

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3964.09

3772.12

3449.31

2990.08

2929.67

2365.352091.73

1762.09

1629.98

1378.55

1242.99

1055.03

930.11

616.31

FTIR SPECTRUM


Trichy-2


EA+Hex-2.pk

EA31C2~1.SP 3601 4000.00 400.00 6.32 100.00 4.00 %T 5 1.00

REF 4000 90.10 2000 82.09 6003917.93 87.95 3772.03 75.37 3449.73 6.32 2928.11 60.34 2859.61 70.812098.42 80.11 1753.54 71.73 1628.57 40.24 1379.58 66.33 1243.52 54.281111.63 69.40 1050.10 65.81 558.53 59.86

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3917.93

3772.03

3449.73

2928.11

2859.61

2098.42

1753.54

1628.57

1379.58

1243.52

1111.63

1050.10

558.53

FTIR SPECTRUM


Trichy-2


EA+Hex-3.pk

EA_HEX~4.SP 3601 4000.00 400.00 6.34 99.37 4.00 %T 5 1.00

REF 4000 93.46 2000 89.84 6003770.59 84.10 3450.82 6.34 2988.62 65.19 2493.14 92.57 2384.79 92.612088.86 87.78 1760.91 43.61 1636.38 42.22 1378.06 64.36 1243.04 26.351054.23 58.75 929.20 92.46 617.11 61.12

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3770.59

3450.82

2988.62

2493.14

2384.79

2088.86

1760.911636.38

1378.06

1243.04

1054.23

929.20

617.11

FTIR SPECTRUM


Trichy-2


EA+Hex-4.pk

EA_HEX~3.SP 3601 4000.00 400.00 6.32 99.58 4.00 %T 5 1.00

REF 4000 93.21 2000 89.78 6003972.80 91.82 3774.67 85.42 3448.93 6.32 2990.04 70.32 2931.38 71.652087.94 87.89 1762.57 53.80 1634.83 42.26 1377.68 67.09 1242.66 37.011055.31 65.42 547.94 64.74

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3972.80

3774.67

3448.93

2990.04

2931.38

2087.94

1762.57

1634.83

1377.68

1242.66

1055.31 547.94

FTIR SPECTRUM


Trichy-2


EA+Hex-5.pk

EA_HEX~2.SP 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 84.37 2000 81.95 6003905.70 82.45 3769.87 73.71 3448.68 6.33 2928.17 62.66 2859.60 72.712379.02 81.84 2092.59 80.92 1634.91 39.67 1381.22 68.07 1242.46 68.751110.54 69.20 1049.25 68.98 557.41 62.66

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3905.70

3769.87

3448.68

2928.17

2859.60

2379.022092.59

1634.91

1381.22

1242.46

1110.54

1049.25 557.41

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: EA+Hex-6.sp

Date: 2/18/2009

EA+Hex-6.pk

EA_HEX~1.SP 3601 4000.00 400.00 6.32 99.36 4.00 %T 5 1.00

REF 4000 98.40 2000 91.37 6003855.32 96.93 3768.40 91.09 3448.96 6.32 2960.84 53.32 2378.76 92.672093.17 89.21 1741.82 27.67 1636.66 37.95 1371.21 44.99 1241.77 24.201049.37 53.91 931.21 96.86 607.99 71.80 533.17 68.16

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3855.32

3768.40

3448.96

2960.84

2378.76

2093.17

1 741.82

1636.66

1371.21

1241.77

1049 .37

931.21

607.99

533.17

FTIR SPECTRUM


Trichy-2


EA+Hex-7.pk

EA41C6~1.SP 3601 4000.00 400.00 7.59 99.33 4.00 %T 5 1.00

REF 4000 98.10 2000 78.25 6003906.07 96.10 3770.91 83.08 3448.84 7.59 2964.89 26.03 2491.89 78.462091.99 75.63 1763.72 21.24 1627.25 39.37 1378.57 42.71 1242.87 8.651056.01 36.36 930.32 79.15 619.94 57.13

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3906.07

3770.91

3448.84

2964.89

2491.89

2091.99

1763.72

1627.251378.57

1242.87

1056.01

930.32

619.94

FTIR S PECTRUM

ACICSt.Joseph' s College ( Autonomous )

Trichy-2

Spectrum Name: EA+Hex-8.sp

Date: 2/18/2009

EA+Hex-8.pk

EA51CA~1.SP 3601 4000. 00 400.00 6.93 100.00 4.00 %T 5 1.00

REF 4000 97.12 2000 48.79 6003964.69 94.69 3773.07 81.25 3446.90 6.93 2932.51 35.60 2405.75 51.642091.46 47.39 1763.23 17.31 1627.46 25.19 1377.93 31.18 1242.94 8.111055.57 28.88 621.67 47.00

40 00.0 3000 20 00 15 00 1 000 4 00.0

0.0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

1 00.0

cm-1

%T

3964.69

3773.07

3446.90

2932.51

2405.752091.46

1763.23

1627.46

1377.93

1242.94

1055.57

621.67

FTIR SPECTRUM


Trichy-2

Spectrum Name:EA+Hex-9.spDate: 2/18/2009

EA+Hex-9.pk

EA51CE~1.SP 3601 4000.00 400.00 6.34 100.00 4.00 %T 5 1.00

REF 4000 84.74 2000 61.21 6003964.05 83.34 3772.43 70.77 3447.13 6.34 2929.40 43.90 2110.78 59.071757.54 65.65 1625.96 32.05 1410.74 56.65 1245.29 58.90 1116.49 59.46609.33 58.59

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3964.05

3772.43

3447.13

2929.40

2110.78

1757.54

1625.96

1410.74

1245.29

1116.49 609.33

FTIR SPECTRUM


Trichy-2


EA+Hex-10.pk

EA0607~1.SP 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 76.42 2000 65.23 6003964.48 74.66 3772.97 63.95 3448.43 6.33 2928.27 47.96 2109.27 63.461627.09 35.23 1410.61 58.11 1115.31 58.29 608.91 53.13

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3964.48

3772.97

3448.43

2928.27

2109.27

1627.09

1410.61 1115.31

608.91

FTIR SPECTRUM


Trichy-2


EA+Hex-11.pk

EA0E07~1.SP 3601 4000.00 400.00 6.35 99.99 4.00 %T 5 1.00

REF 4000 75.79 2000 35.78 6003964.24 73.75 3772.57 57.82 3437.12 6.35 2928.11 25.90 2119.44 34.171619.21 21.51 1408.65 36.29 1117.56 37.55 615.47 44.68

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3964.24

3772.57

3437.12

2928.11

2119.44

1619.21

1408.651117.56

615.47

Table - 7.11

Observations of FTIR spectrums for Hexane + Ethyl Acetate mixture:

1 (EA)

Cm-1

0.9(EA)

+

0.1(HX)

Cm-1

*0.8(EA)

+

0.2(HX)

Cm-1

0.7(EA)

+

0.3(HX)

Cm-1

0.6(EA)

+

0.4(HX)

Cm-1

0.5(EA)

+

0.5(HX)

Cm-1

0.4(EA)

+

0.6(HX)

Cm-1

0.3(EA)

+

0.7(HX)

Cm-1

0.2(EA)

+

0.8(HX)

Cm-1

0.1(EA)

+

0.9(HX)

Cm-1

1(HX)

Cm-1

3964.093772.123449.312990.082929.672365.352091.731762.091629.981378.551242.991055.03930.11616.31

3917.933772.033449.732928.112859.612098.421753.541628.571379.581243.521111.631050.10558.53

3770.593450.82

2988.622493.14

2384.79

2088.861760.91

1636.38

1378.061243.04

1054.23

929.20617.11

3972.803774.673448.932990.042931.382087.941762.571634.831377.681242.661055.31547.94

3905.703769.873448.682928.172859.602379.022092.591634.911381.221242.461110.541049.25557.41

3855.323768.403448.962960.842378.762093.171741.821636.661371.211241.771049.37931.21607.99533.17

3906.073770.913448.842964.892491.892091.991763.721627.251378.571242.871056.01930.32619.94

3964.693773.073446.902932.512405.752091.461763.231627.461377.931242.941055.57621.67

3964.053772.433447.132929.402110.781757.541625.961410.741245.291116.49609.33

3964.483772.973448.432928.272109.271627.091410.611115.31608.91

3964.243772.573437.122928.112119.44


289

Fig-7.11: FTIR spectrums for Heptane + Benzaldehyde mixture:

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-J-1.sp

Date: 04-2-2010

SJC-J-1.pk

SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4.00 %T 5 1.00

REF 4 000 87.15 2000 85.48 6003794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49.43 2722.97 78.961596.87 6.70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

379 4.95

3444.07

2964.92

2879.83

2722.97

1596.87

1467.24

1 362.51

774.31

608.97

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-PH-JO-2. sp

Date: 13-2-2010

SJC-PH-JO-2.pk

SJC-PH~1.SP 3601 4000.00 400.00 7.89 99.69 4.00 %T 5 1.00

REF 4 000 95.81 2000 94.48 6003927.66 92.70 3781.71 88.30 3446.47 14.16 2963.39 7.88 2882.29 27.542738.34 85.29 2542.27 92.66 2031.43 94.02 1696.28 28.71 1459.80 54.911384.69 44.14 1282.06 65.12 1205.65 70.99 1116.35 87.42 1072.46 88.021019.24 88.74 930.62 92 .20 824.80 78.44 708.76 57.49 651.75 65.22549.54 78 .72 454.31 85.15

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3927.66

3781.71

3446.47

296 3.39

2882.2 9

2738.34

2542.27 2031.43

1696.28

1459.80

13 84.69

1282.06

1205.65

1 116.35

1 072.46

1019.2 4

930.62

824.80

708.76

651.75

549.5 4

454.31

FTIR SPECTRUM

ACIC


Trichy-2


Date: 13-2-2010

SJC-PH-JO-3.pk

SJC-PH~4.SP 3601 4000.00 400.00 6.66 99.78 4.00 %T 5 2.00

REF 4 000 98.92 2000 91.26 6003895.66 96.56 3781.88 91.06 3451.06 23.89 3068.53 39.90 2963.39 12.542876.23 27.95 2738.28 45.53 1981.59 88.94 1912.36 90.03 1825.66 91.621701.59 6.65 1596.46 27 .37 1455.72 46.37 1387.56 42.62 1307.72 46.291204.70 29.38 1168.51 44.99 1111.62 77.55 1072.53 77.66 1014.23 78.65923.64 89 .35 826.22 44.29 745.68 25.4 7 689.77 36.06 650.69 40.26541.80 83 .49 450.90 65.50

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

38 95.66

3781.88

3 451.06

3 068.53

296 3.39

2876.2 3

27 38.28

1981.59

1912.36

1 825.66

1701.59

1596.46

1455.72

1387.56

1307.72

1204.70

11 68.51

1111.62

1072.53

101 4.23

923.64

826.22

745.68

68 9.77

650.69

541 .80

450.90

FTIR SPECTRUM

ACIC


Trichy-2


Date: 13-2-2010

SJC-PH-JO-4.pk

SJ66F3~1.SP 3601 4000.00 400.00 5.99 99.99 4.00 %T 5 2.0 0

REF 4 000 98.89 2000 90.36 6003914.34 96.44 3781.23 91.67 3443.35 18.38 3069.26 37.08 2964.49 12.672874.81 27.62 2819.58 35.28 2738.20 42.07 2331.49 91.44 1981.75 87.571911.94 89.04 1825.07 89.52 1701.53 5.98 1596.03 25.01 1455.67 43.911387.49 39.39 1308.11 46.00 1204.69 28.52 1167.87 44.55 1110.91 75.591072.24 75.31 1014.99 76.25 923.73 88.34 825.81 42.13 745 .96 23.78689.26 34 .03 650.63 37.30 543.53 78.9 4 450.87 60.93

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3914.34

3781.23

3443.35

3069.26

296 4.49

2874.8 1

2819.58

2738.20

2331.491981.75

1911.9 4

1825.07

17 01.53

1596.03

1455.67

1387.49

1308.11

1204.69

1167.87

1110.91

1072.24

1014.99

923.73

825.81

745.96

68 9.26

650.63

543 .53

450.87

FTIR SPECTRUM

ACIC


Trichy-2


Date: 13-2-2010

SJC-PH-JO-5.pk

SJ6EF3~1.SP 3601 4000.00 400 .00 7.66 100.00 4.00 %T 5 2.00

REF 4 000 98.97 2000 89.20 6003781.38 93.86 3394.87 3 0.73 3067.63 43.84 2964.19 26.73 2864.03 39.012818.61 35.71 2738.01 4 0.99 2329.95 92.09 2140.56 96.58 1982.09 86.011910.52 87.83 1826.00 8 7.49 1701.59 7.65 1595.69 25.07 1455.19 46.981388.72 44.85 1307.95 4 5.65 1204.08 28.15 1167.30 41.01 1109.11 78.711072.08 73.55 1013.14 7 2.81 922.50 86.91 825.69 38.57 746.33 22.63688.95 33 .75 650.63 37.32 450.65 59.52

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

37 81.38

3394.87

3067.63

296 4.19

2864.03

2818.61

2738.01

23 29.95

2140.56

1982.09

1910.5 2

1826.00

17 01.59

1595.69

1455.19

1388.72

1307.95

1204.08

1167.30

1109.11

1072.08

101 3.14

922.50

825.69

746.33

688.95

650.63

450.65

FTIR SPECTRUM

ACIC


Trichy-2


Date: 13-2-2010

SJC-PH-JO-6.pk

SJ6604~1.SP 3601 4000.00 400.00 6.53 99.91 4.00 %T 5 2.00

REF 4 000 98.75 2000 93.82 6003924.16 96.21 3779.77 90.67 3440.24 33.34 3069.41 60.40 2965.22 47.232818.14 52.16 2737.72 57.94 2333.38 95.41 1982.26 92.30 1909.07 93.651823.92 93.85 1702.19 6.53 1595.40 32.39 1455.10 58.52 1387.80 54.561309.26 57.85 1203.86 33.23 1167.12 53.27 1072.05 81.73 1013.85 81.71922.80 93 .52 826.26 48.04 746.35 27.0 0 688.57 41.50 650.24 46.69450.80 70 .90

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3924.16

377 9.77

3440.24

3 069.41

296 5.22

2818.14

2737.72

233 3.381982.26

1909.07

1823.92

17 02.19

1595.40

1455.10

13 87.80

1309.26

1203.86

11 67.12

1 072.05

1013.85

922.80

826.26

746.35

68 8.57

650.24

450.80

FTIR SPECTRUM

ACIC


Trichy-2


Date: 13-2-2010

SJC-PH-JO-7.pk

SJC-PH~2.SP 3601 4000.00 400.00 7.40 99.79 4.00 %T 5 2.00

REF 4 000 98.91 2000 89.96 6003782.72 96.20 3395.10 34.31 3067.16 48.96 2965.78 64.04 2818.27 37.382738.03 43.12 2329.14 94.09 2140.52 96.60 1982.75 87.51 1911.07 89.411827.05 88.97 1702.23 7.40 1596.21 26.49 1454.70 55.08 1389.65 54.171308.39 49.90 1203.75 30.14 1167.62 44.37 1072.24 77.99 1011.34 75.98922.10 89 .47 826.17 40.94 746.69 23.8 1 688.84 37.20 650.87 42.32450.91 66 .32

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3782.72

3395.10

3067.16

2965.78

2818.27

2 738.03

2329.14

2140.52

1982.75

1911.07

1827.05

17 02.23

1596.21

1454.70

1389.65

1308.39

1203.75

116 7.62

1 072.241011.34

922.10

826.17

746.69

688.84

650.87

450.91

FTIR SPECTRUM

ACIC


Trichy-2


Date: 13-2-2010

SJC-PH-JO-8.pk

SJC-PH~3.SP 3601 4000.00 400.00 8.57 99.83 4.00 %T 5 2.00

REF 4 000 99.35 2000 91.49 6003783.77 96.21 3393.20 45.93 3067.20 55.39 2964.71 59.91 2818.09 42.612737.97 47.49 2328.98 94.71 2140.49 97.19 1982.50 88.97 1910.16 90.651826.64 89.75 1702.05 8.57 1595.47 29.97 1454.75 56.91 1389.89 57.761308.31 53.17 1203.73 32.80 1166.93 46.95 1071.87 78.74 1012.36 77.12922.12 89 .92 825.89 43.20 746.81 25.7 7 688.77 40.01 650.66 44.75450.64 66 .89

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3783.77

3393.20

3067.20

2964.71

2818.09

2737.97

2328.98

2140.49

1982.50

1910.16

1826.64

1702.05

1595.47

1454.75

1389.89

1308.31

1203.73

1166.93

1071.87

1012.36

922.12

825.89

746.81

68 8.77

650.66

450.64

FTIR SPECTRUM

ACIC


Trichy-2


Date: 13-2-2010

SJC-PH-JO-9.pk

SJ6E1 4~1.SP 3601 4000.00 400.00 11.02 99.89 4.00 %T 5 2.00

REF 4 000 99.22 2000 94.14 6003779.85 96.02 3456.88 43.95 3067.58 67.71 2965.54 73.41 2817.82 54.512737.69 59.18 2329.54 96.63 1982.44 92.49 1909.34 93.70 1826.49 93.501702.07 11.02 1595.35 36.89 1454.62 65.15 1388.71 63.22 1308.78 62.551203.47 40.03 1166.70 56.47 1071.86 84.36 1012.18 83.31 922.12 93.44826.01 51 .01 746.67 31.13 688.53 46.4 9 650.36 51.60 450.84 73.67

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3779.85

3456.88

3067.58

2965.54

2817.82

2737.69

2329.541982.44

1909.34

1826.49

17 02.07

1595.35

1454.62

13 88.71

1308.78

1203.47

116 6.70

1 071.86

1012.18

922.12

826.01

746.67

68 8.53

650.36

4 50.84

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-PH-JO-10.sp

Date: 13-2-2010

SJC-PH-JO-10.pk

SJ57CE~1.SP 3601 4000.00 400.00 6.48 99.82 4.00 %T 5 2.00

REF 4 000 99.01 2000 92.28 6003780.86 91.73 3449.62 18.83 3068.39 56.63 2817.83 44.06 2737.63 50.032332.01 93.90 1982.62 90.54 1910.05 92.43 1825.75 92.39 1702.37 6.481596.45 24.92 1454.62 57.80 1388.46 53.80 1309.18 53.78 1203.54 30.541167.33 47.93 1072.25 81.04 1011.51 79.80 921.71 92.45 826.32 41.01746.63 21 .38 688.51 34.45 650.56 39.6 1 451.05 65.18

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

37 80.86

3 449.62

3068.39

2817.83

2737.63

2332.01

1982.62

1910.0 5

1 825.75

1702.37

1596.45

1454.6 2

13 88.46

1309.18

1203.54

1167.33

1 072.25

1011.51

921.71

826.32

746.63

688.51

650.56

451.05

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-PH-JO-11.sp

Date: 13-2-2010

SJC-PH-JO-11.pk

SJ57C2~1.SP 3601 4000.00 400 .00 9.19 100.00 4.00 %T 5 2.00

REF 4 000 99.17 2000 91.90 6003779.18 91.96 3393.17 4 9.55 3067.61 56.55 2818.16 47.88 2738.01 53.252332.65 92.39 1981.60 8 9.76 1910.63 90.99 1825.07 90.53 1703.08 9.191595.88 32.13 1454.22 6 0.71 1389.83 58.76 1308.82 52.85 1204.23 32.121167.84 49.04 1072.35 7 8.97 1011.85 78.28 921.88 88.49 826.54 44.82746.72 26 .61 688.99 40.38 650.78 45.75 4 50.67 68.49

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3779.18

3393.17

3067.61

2818.16

2738.01

2332.651981.60

1910.63

1825.07

1703.08

1595.88

1454.22

1389.83

1308.82

1204.23

1167.84

1 072.35

101 1.85

921.88

826.54

746.72

688.99

650.78

450.67

Table - 7.12

Observations of FTIR spectrums for Heptane + Benzaldehyde mixture:

1 (HP)

Cm-1

0.9(HP)

+

0.1(BD)

Cm-1

0.8(HP)

+

0.2(BD)

Cm-1

0.7(HP)

+

0.3(BD)

Cm-1

*0.6(HP)

+

0.4(BD)

Cm-1

0.5(HP)

+

0.5(BD)

Cm-1

0.4(HP)

+

0.6(BD)

Cm-1

0.3(HP)

+

0.7(BD)

Cm-1

0.2(HP)

+

0.8(BD)

Cm-1

0.1(HP)

+

0.9(BD)

Cm-1

1(BD)

Cm-1

3794.953444.072964.922879.832722.971596.871467.241362.51774.31608.97

3927.663781.713446.472963.392882.292738.342542.272031.431696.281459.801384.691282.061205.651116.351072.461019.24930.62824.80708.76651.75549.54454.31

3895.663781.883451.063068.532963.392876.232738.281981.591912.361825.661701.591596.461455.721387.561307.721204.701168.511111.621072.531014.23923.64826.22745.68689.77650.69541.80450.90

3914.343781.233443.353069.262964.492874.812819.582738.202331.491981.751911.941825.071701.531596.031455.671387.491308.111204.691167.871110.911072.241014.99923.73825.81745.96689.26650.63543.53450.87

3781.38

3394.873067.63

2964.19

2864.032818.61

2738.01

2329.952140.56

1982.09

1910.521826.00

1701.59

1595.691455.19

1388.721307.95

1204.08

1167.301109.11

1072.08

1013.14922.50

825.69

746.33688.95

650.63

450.65

3924.163779.773440.243069.412965.222818.142737.722333.381982.261909.071823.921702.191595.401455.101387.801309.261203.861167.121072.051013.85922.80826.26746.35688.57650.24450.80

3782.723395.103067.162965.782818.272738.032329.142140.521982.751911.071827.051702.231596.211454.701389.651308.391203.751167.621072.241011.34922.10826.17746.69688.84650.87450.91

3783.773393.203067.202964.712818.092737.972328.982140.491982.501910.161826.641702.051595.471454.751389.891308.311203.731166.931071.871012.36922.12825.89746.81688.77650.66450.64

3779.853456.883067.582965.542817.822737.692329.541982.441909.341826.491702.071595.351454.621388.711308.781203.471166.701071.861012.18922.12826.01746.67688.53650.36450.84

3780.863449.623068.392817.832737.632332.011982.621910.051825.751702.371596.451454.621388.461309.181203.541167.331072.251011.51921.71826.32746.63688.51650.56451.05

3779.183393.173067.612818.162738.012332.651981.601910.631825.071703.081595.881454.221389.831308.821204.231167.841072.351011.85921.88826.54746.72688.99650.78450.67


290

Fig-7.12: FTIR spectrums for Heptane + Benzyl Chloride mixture:

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-1.pk

SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4.00 %T 5 1.00

REF 4 000 87.15 2000 85.48 6003794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49.43 2722.97 78.961596.87 6.70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

379 4.95

3444.07

2964.92

2879.83

2722.97

1596.87

1467.24

1 362.51

774.31

608.97

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: T1-2--0.1+0.9 .asc

Date: 18-6-2010

T1-2--0.1+0.9.pk

T1-2--~1.ASC 3601 4000.00 400.00 8.12 99.32 4.00 %T 3 1.00

REF 4 000 98.96 2000 93.72 6003941.78 89.03 3832.74 92.98 3421.26 8.12 2773.89 97.31 2673.51 97.202158.92 89.12 1637.70 29.86 1396.87 59.09 1267.20 81.71 1119.09 83.70696.89 31 .11

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3941.78

3832.74

3421.26

2773.8 9

2673.51

2158.9 2

1637.70

13 96.87

1267.20

111 9.09

696 .89

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: T1-0.2+0.8.sp

Date: 18-6-2010

T1-0.2+0.8 .pk

T1-02_~1.SP 3601 4000.00 400.00 7.03 99.41 4.00 %T 3 1.00

REF 4 000 98.85 2000 72.44 6003916.55 82.46 3821.81 72.74 3428.44 7.03 3058.42 34.05 1962.21 70.761641.16 37.88 1450.86 54.41 1267.15 51.52 1075.12 83.25 926.22 95.66693.65 9.49 560.22 58.4 8 469.60 76.88

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3916.55

3821.81

3428.44

3058.42

1962.21

1641.16

1450.86

1267.15

1 075.12

926.22

693.65

560.2 2

469.60

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T1-0.3+0.7 .pk

T1-03_~1.SP 3601 4000.00 400.00 7.43 99.83 4.00 %T 3 1.00

REF 4 000 99.21 2000 98.58 6003928.10 93.30 3425.62 14.46 3049.12 44.13 2956.52 48.84 2329.91 96.671959.22 92.20 1888.85 95.69 1636.74 49.47 1445.90 54.79 1269.43 50.281080.95 83.96 923.13 93 .04 691.00 7.43 564.45 56.61 472.96 73.33

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3928.10

3425.62

3049.1 2

2956.52

2329.91

1959.22

1888.85

1636.74

1445.90

1269.43

1080.95

923.13

691.00

564.45

472.96

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T1-0.4+0.6 .pk

T1-04_~1.SP 3601 4000.00 400.00 6.36 99.99 4.00 %T 3 1.00

REF 4 000 99.76 2000 95.31 6003943.95 92.18 3435.30 6.36 2962.30 67.61 2336.30 93.53 2085.56 92.391962.22 93.83 1640.94 35.45 1449.54 64.66 1266.95 65.24 1075.12 88.92693.78 13 .07 560.93 54.40

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3943.95

3435.30

2962.30

233 6.30

2085.56

1962.22

1640.94

1449.54 1266.95

1 075.12

693.78

560.9 3

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T1-0.5+0.5 .pk

T1-05_~1.SP 3601 4000.00 400.00 9.26 99.47 4.00 %T 3 1.00

REF 4 000 97.29 2000 95.11 6003939.48 92.27 3433.62 12.01 3057.23 56.94 2961.07 64.74 2148.79 92.831958.64 91.87 1886.71 94.80 1639.96 40.21 1449.91 58.61 1266.90 55.241074.47 84.91 923.81 93 .18 693.87 9.26 560.54 56.01 472.08 76.32

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3939.4 8

3433.62

3057.23

2961.07

2148.79

1958.64

1886.71

1639.96

1449.911266.90

1 074.47

9 23.81

693.87

560.5 4

472.08

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T1-0.6+0.4 .pk

T1-06_~1.SP 3601 4000.00 400.00 8.43 99.98 4.00 %T 3 1.00

REF 4 000 99.90 2000 98.05 6003937.09 97.08 3423.02 42.74 3040.77 42.44 2957.59 35.57 2335.39 94.551956.20 86.05 1888.10 90.42 1804.23 89.13 1611.02 63.35 1451.90 44.551267.39 38.53 1208.92 72.63 1074.56 76.41 925.06 88.87 692.73 8.43559.84 55 .18 465.92 71.56

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3937.09

3423.02

3040.77

2957.59

233 5.39

1956.20

1888.10

1804.23

1611.02

1451.90

1267.39

1208.92

1 074.56

925.06

692.73

559.84

465.92

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T1-0.7+0.3 .pk

T1-07_~1.SP 3601 4000.00 400.00 7.41 99.99 4.00 %T 3 1.00

REF 4 000 99.71 2000 98.83 6003927.46 94.33 3431.07 16.25 3042.60 46.09 2957.85 41.34 2335.70 95.151956.83 90.91 1887.34 94.72 1637.31 47.82 1451.49 50.04 1267.13 45.201208.74 80.78 1074.40 80.61 924.41 92.22 692.85 7.41 560.16 52.83467.87 71 .17

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3927.4 6

3 431.07

3042.6 0

2957.85

233 5.70

1956.83

1887.34

1637.311451.49

1267.13

1208.74

1 074.40

924.41

692.85

560.1 6

467.87

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T1-0.8+0.2 .pk

T1-08_~1.SP 3601 4000.00 400.00 8.00 99.80 4.00 %T 3 1.00

REF 4 000 98.26 2000 95.21 6003947.94 86.85 3427.62 8.00 3077.27 57.94 2959.79 32.72 2411.56 96.782154.27 91.90 1960.17 92.33 1887.23 95.77 1640.16 33.61 1449.82 55.261394.17 65.88 1267.22 60.17 1206.80 90.25 1076.88 85.22 1026.35 89.49922.15 93 .69 692.73 11.15 561.66 49.3 7

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3947.94

3 427.62

30 77.27

2959.79

2411.56

2154.27

1960.17

1887.23

1640.16

1449.82

1394.17

1267.22

1206.80

1076.88

1026.35

922.15

692.73

561.6 6

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T1-0.9+0.1 .pk

T1-09_~1.SP 3601 4000.00 400.00 6.33 99.81 4.00 %T 3 1.00

REF 4 000 97.38 2000 93.68 6003938.15 88.50 3430.86 6.33 2959.53 48.48 2410.89 95.61 2149.02 89.851640.46 30.25 1445.88 66.07 1397.04 65.96 1266.80 75.76 1119.70 88.79692.66 21 .44 563.68 54.16

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

393 8.15

3430.86

2959.53

2410.89

2149.02

1640.46

1445.88

1397.0 4

1266.80

111 9.70

692.66

563.68

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-11.pk

EA9C82~1.SP 3601 4000.00 400.00 7.08 99.91 4.00 %T 5 2.00

REF 4 000 98.47 2000 59.62 6003906.50 94.80 3772.29 83.63 3435.57 39.14 3034.41 25.24 2960.75 35.212868.60 51.22 2708.50 60.11 2336.46 56.86 1956.03 48.63 1890.06 51.791811.47 53.04 1600.22 42.75 1493.17 41.14 1451.17 26.63 1266.87 19.471207.69 41.07 1074.43 41.36 1027.31 49.25 927.39 55.87 810.55 38.57759.02 31 .11 694.99 7.08 559.37 42.03 465.12 60.85

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 06.50

3772.29

3435.57

3034.41

2960.75

2868.60

270 8.50

2336.46

1956.03

189 0.06

1811.47

1600.2 2

1493.17

1451.17

1266.87

1207.69

1 074.43

1027.31

9 27.39

810 .55

7 59.02

694.99

559.3 7

465.12

Table - 7.13

Observations of FTIR spectrums for Heptane + Benzyl Chloride mixture:

1(HP)

Cm-1

0.9(HP)

+

0.1(BC)

Cm-1

0.8(HP)

+

0.2(BC)

Cm-1

0.7(HP)

+

0.3(BC)

Cm-1

0.6(HP)

+

0.4(BC)

Cm-1

0.5(HP)

+

0.5(BC)

Cm-1

*0.4(HP)

+

0.6(BC)

Cm-1

0.3(HP)

+

0.7(BC)

Cm-1

0.2(HP)

+

0.8(BC)

Cm-1

0.1(HP)

+

0.9(BC)

Cm-1

1(BC)

Cm-1

3794.953444.072964.922879.832722.971596.871467.241362.51774.31608.97

3941.783832.743421.22773.892673.512158.921637.701396.871267.201119.09696.89

3916.553821.813428.443058.421962.211641.161450.861267.151075.12926.22693.65560.22469.60

3928.103425.623049.122956.522329.911959.221888.851636.741445.901269.431080.95923.13691.00564.45472.96

3943.953435.302962.302336.302085.561962.221640.941449.541266.951075.12693.78560.93

3939.483433.623057.232961.072148.791958.641886.711639.961449.911266.901074.47923.81693.87560.54472.08

3937.09

3423.023040.77

2957.59

2335.391956.20

1888.10

1804.231611.02

1451.90

1267.391208.92

1074.56

925.06692.73

559.84465.92

3927.463431.073042.602957.852335.701956.831887.341637.311451.491267.131208.741074.40924.41692.85560.16467.87

3947.943427.623077.272959.792411.562154.271960.171887.231640.161449.821394.171267.221206.801076.881026.35922.15692.73561.66

3938.153430.862959.532410.892149.021640.461445.881397.041266.801119.70692.66563.68

3906.503772.293435.573034.412960.752868.602708.502336.461956.031890.061811.471600.221493.171451.171266.871207.691074.431027.31927.39810.55759.02694.99559.37465.12


291

Fig-7.13: FTIR spectrums for Heptane + 2-Butanone mixture:

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-1.pk

SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4.00 %T 5 1.00

REF 4 000 87.15 2000 85.48 6003794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49.43 2722.97 78.961596.87 6.70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

379 4.95

3444.07

2964.92

2879.83

2722.97

1596.87

1467.24

1 362.51

774.31

608.97

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-2.pk

SJC-J-2.sp 3601 4000.00 400.00 5.34 98.50 4.00 %T 5 1.00

REF 4 000 81.24 2000 79.36 6003924.74 79.66 3796.71 77.77 3437.58 19.83 2966.33 18.58 2880.55 40.032723.06 72.86 1597.43 5.34 1466.31 54.01 1362.14 19.05 1165.83 77.23774.50 52 .68 607.14 61.13

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3924.74

379 6.71

3437.58 296 6.33

2880.55

2723.06

1597.43

1466.31

1 362.14

1165.83

774.50

607.14

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-3.pk

SJC-J-3.sp 3601 4000.00 400.00 6.68 99.29 4.00 %T 5 1.00

REF 4 000 94.92 2000 92.95 6003925.74 92.51 3438.36 10.85 2966.74 28.56 2881.08 52.92 2724.40 84.552152.75 91.02 1594.90 6.68 1467.00 66.21 1360.44 27.18 773.90 59.77611.49 64 .44

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 925.74

3438.36

2966.74

2881.0 8

2724.40

2152.75

1594.90

1467.00

1360.44

773.90

611.49

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-4.pk

SJC-J-4.sp 3601 4000.00 400.00 6.99 98.71 4.00 %T 5 1.00

REF 4 000 88.56 2000 85.88 6003793.09 86.71 3447.26 33.86 2964.96 35.79 2879.53 57.08 2833.22 56.602720.21 80.32 1599.26 6.99 1466.09 63.33 1362.68 19.16 1168.73 82.94773.91 61 .72 604.10 75.15

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

37 93.09

3447.26296 4.96

2879.53

28 33.22

2720.21

1599.26

1466.0 9

1 362.68

1168.73

773.91

604.10

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-5.pk

SJC-J-5.sp 3601 4000.00 400.00 6.48 99.27 4.00 %T 5 1.00

REF 4 000 83.27 2000 82.94 6003919.84 82.16 3441.28 21.00 2967.45 21.89 2882.12 44.66 2834.84 55.282722.39 74.85 2133.98 81.68 1735.65 49.12 1596.16 6.48 1465.64 56.001361.93 19.58 1171.14 69.44 1021.01 81.52 937.60 82.09 774.24 55.71590.12 63 .23

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3919.84

3441.28 2967.45

2882.12

2834.84

2722.39

2133.9 8

1735.65

1596.16

1465.6 4

1 361.93

1171.14

1021.01937.60

774.24

590.12

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-6.pk

SJC-J-6.sp 3601 4000.00 400.00 6.72 99.69 4.00 %T 5 1.00

REF 4 000 95.97 2000 95.87 6003924.97 94.42 3445.25 20.72 2967.38 29.99 2833.78 63.93 2722.63 86.662127.72 94.15 1736.29 41.79 1596.73 6.72 1463.67 64.95 1362.50 19.781171.32 71.15 939.52 92 .66 773.93 63.48 588.48 70.02

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3924.97

3445.25

2967.38

2833.7 8

27 22.63

2127.72

1736.29

1596.73

1463.6 7

1 362.50

1171.32

9 39.52

773.93

588.48

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-7.pk

SJC-J-7.sp 3601 4000.00 400.00 6.46 99.24 4.00 %T 5 1.00

REF 4 000 82.55 2000 82.12 6003441.96 12.97 2968.63 27.75 2832.85 59.07 2726.68 74.50 2124.88 79.881736.61 31.12 1595.85 6.46 1462.48 55.47 1359.86 20.07 1171.65 55.99940.87 78 .64 772.60 54.04 589.83 56.5 1

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3441.96

2968.63

2832.85

272 6.68

2124.88

1736.61

1595.85

1462.4 8

1359.86

1171.65

9 40.87

7 72.60589.83

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-8.pk

SJC-J-8.sp 3601 4000.00 400.00 6.48 99.56 4.00 %T 5 1.00

REF 4 000 92.98 2000 91.83 6003438.91 17.36 2831.35 68.26 2723.43 84.71 2134.62 90.16 1596.53 6.481359.60 28.00 1120.91 87.96 773.73 59.63 594.09 63.59

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3438.91

2831.35

2723.43

2134.6 2

1596.53

1359.60

112 0.91

773.73

594.09

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-9.pk

SJC-J-9.sp 3601 4000.00 400.00 6.32 99.38 4.00 %T 5 1.00

REF 4 000 87.32 2000 85.60 6003438.28 6.32 2988.35 54 .28 2830.07 70.35 2729.15 81.21 2120.11 82.931736.42 49.70 1592.41 12.55 1461.68 68.81 1357.24 36.54 1171.97 70.24940.23 85 .60 770.78 60.36 590.76 58.5 5

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3438.28

2988.35

2830.0 7

27 29.15

2120.11

1736.42

1592.41

1461.6 8

1357.24

1171.97

9 40.23

7 70.78 590.76

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-10.pk

SJC-J-10.sp 3601 4000.00 400.00 6.48 99.84 4.00 %T 5 1.00

REF 4 000 85.01 2000 84.80 6003925.39 83.44 3438.81 15.62 2986.89 53.90 2832.18 59.94 2723.22 77.052124.20 83.21 1736.34 44.75 1596.16 6.48 1361.50 21.09 1171.40 68.10940.16 83 .14 772.42 58.51 590.67 63.4 7

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3925.39

3438.81

2986.89

2832.1 8

2723.22

2124.20

1736.34

1596.16

1 361.50

1171.40

9 40.16

7 72.42

590.67

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-11.pk

SJC-J-11.sp 3601 4000.00 400.00 7.03 99.99 4.00 %T 5 1.00

REF 4 000 99.04 2000 98.74 6003926.98 96.87 3799.99 95.07 3445.81 12.13 2987.82 40.47 2832.12 69.242726.13 89.36 2121.16 95.77 1737.56 19.80 1595.49 7.03 1362.59 17.871171.83 49.73 941.51 89 .22 770.71 65.15 588.52 63.33

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3926.98

3799.99

3445.81

2987.82

2832.12

2726.13

2121.16

1737.56

1595.49

1 362.59

1171.83

941.51

7 70.71 588.52

Table - 7.14

Observations of FTIR spectrums for Heptane + 2-Butanone mixture:

1(HP)

Cm-1

0.9(HP)

+

0.1(2B)

Cm-1

0.8(HP)

+

0.2(2B)

Cm-1

0.7(HP)

+

0.3(2B)

Cm-1

*0.6(HP)

+ 0.4(2B)

Cm-1

0.5(HP)

+

0.5(2B)

Cm-1

0.4(HP)

+

0.6(2B)

Cm-1

0.3(HP)

+

0.7(2B)

Cm-1

0.2(HP)

+

0.8(2B)

Cm-1

0.1(HP)

+

0.9(2B)

Cm-1

1(2B)

Cm-1

3794.953444.072964.922879.832722.971596.871467.241362.51774.31608.97

3924.743796.713437.582966.332880.552723.061597.431466.311362.141165.83774.50607.14

3925.743438.362966.742881.082724.402152.751594.901467.001360.44773.90611.49

3793.093447.262964.962879.532833.222720.211599.261466.091362.681168.73773.91604.10

3919.84

3441.282967.45

2882.12

2834.842722.39

2133.98

1735.651596.16

1465.64

1361.931171.14

1021.01937.60

774.24

590.12

3924.973445.252967.382833.782722.632127.721736.291596.731463.671362.501171.32939.52773.93588.48

3441.962968.632832.852726.682124.881736.611595.851462.481359.861171.65940.87772.60589.83

3438.912831.352723.432134.621596.531359.601120.91773.73594.09

3438.282988.352830.072729.152120.111736.421592.411461.681357.241171.97940.23770.78590.76

3925.393438.812986.892832.182723.222124.201736.341596.161361.501171.40940.16772.42590.67

3926.983799.993445.812987.822832.122726.132121.161737.561595.491362.591171.83941.51770.71588.52


292

Fig-7.14: FTIR spectrums for Heptane + Ethyl Acetate mixture:

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-1.pk

SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4.00 %T 5 1.00

REF 4 000 87.15 2000 85.48 6003794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49.43 2722.97 78.961596.87 6.70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

379 4.95

3444.07

2964.92

2879.83

2722.97

1596.87

1467.24

1 362.51

774.31

608.97

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T2-0.1+0.9 .pk

T2-01_~1.SP 3601 4000.00 400.00 7.99 99.74 4.00 %T 3 1.00

REF 4 000 99.37 2000 95.61 6003944.42 97.72 3440.75 7.99 2985.63 68.54 2092.63 91.01 1762.43 35.791642.62 38.32 1385.70 58.71 1242.99 24.28 1058.39 60.42 633.00 61.40

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3944.42

3440.75

2985.63

2092.63

1762.431642.62

13 85.70

12 42.99

1058.39 633.00

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T2-0.2+0.8 .pk

T2-02_~1.SP 3601 4000.00 400.00 6.40 100.00 4.00 %T 3 1 .00

REF 4 000 99.54 2000 95.78 6003937.42 93.52 3432.96 6 .40 2977.21 65.61 2091.63 91.40 1762.28 39.261641.77 36.66 1384.35 5 9.71 1242.98 27.08 1057.12 63.32 630.89 57.49

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3937.42

3432.96

2977.21

2091.63

1762.28

1641.77

13 84.35

12 42.98

1057.12

630.89

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T2-0.3+0.7 .pk

T2-03_~1.SP 3601 4000.00 400.00 6.34 99.90 4.00 %T 3 1.00

REF 4 000 99.84 2000 95.76 6003926.24 89.73 3444.00 6.34 2969.03 57.57 2341.82 94.54 2089.68 91.201761.82 38.81 1641.73 34.08 1384.93 57.71 1243.00 27.85 1056.86 62.63633.59 57 .56

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3926.2 4

3444.00

2969.03

2341.82

2089.68

1761.821641.73

13 84.93

12 43.00

1056.86

633.59

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T2-0.4+0.6 .pk

T2-04_~1.SP 3601 4000.00 400.00 8.02 99.97 4.00 %T 3 1.00

REF 4 000 99.85 2000 96.00 6003933.76 90.71 3781.90 75.14 3420.70 8.02 2964.89 61.04 2087.64 92.441760.48 70.22 1641.33 34.60 1390.89 68.26 1242.86 64.48 1056.26 84.99640.28 60 .49

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3933.76

378 1.90

3420.70

2964.89

2087.64

1760.48

1641.33

1390.89

12 42.86

1056.26

6 40.28

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T2-0.5+0.5 .pk

T2-05_~1.SP 3601 4000.00 400.00 6.39 100.00 4.00 %T 3 1 .00

REF 4 000 99.52 2000 95.82 6003435.67 6.39 2961.06 44.06 2341.88 94.46 2089.59 91.67 1761.14 56.231641.59 34.28 1386.94 6 1.59 1242.98 47.57 1057.10 76.47 638.77 58.31

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3435.67

296 1.06

2341.88

208 9.59

1761.14

1641.59

13 86.94

12 42.98

1057.10

6 38.77

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T2-0.6+0.4 .pk

T2-06_~1.SP 3601 4000.00 400.00 7.97 99.99 4.00 %T 3 1.00

REF 4 000 99.63 2000 95.68 6003954.90 97.26 3437.23 7.97 2962.58 51.23 2088.75 92.18 1762.00 57.811641.34 41.22 1385.53 66.49 1243.01 46.85 1057.23 76.92 633.82 62.32

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 54.90

3437.23

2962.58

2088.75

1762.00

1641.34

13 85.53

12 43.01

1057.23

633.82

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T2-0.7+0.3 .pk

T2-07_~1.SP 3601 4000.00 400.00 6.34 99.99 4.00 %T 3 1.00

REF 4 000 99.57 2000 95.58 6003437.11 6.34 2957.17 25 .06 2095.36 91.88 1760.17 72.99 1640.58 35.981388.10 63.96 1243.15 67.11 1056.29 83.60 636.95 58.13

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3437.11

2957.17

2095.36

1760.17

1640.58

13 88.1012 43.15

1056.29

6 36.95

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T2-0.8+0.2 .pk

T2-08_~1.SP 3601 4000.00 400.00 7.97 100.00 4.00 %T 3 1 .00

REF 4 000 99.86 2000 95.70 6003946.31 94.12 3441.69 7 .97 2958.68 37.05 2084.93 92.67 1641.21 39.331462.72 79.27 1390.99 7 2.83 1249.22 96.70 1115.43 92.09 656.34 64.27

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3946.3 1

3441.69

2958.68

2084.93

1641.21

1462.72

1390.99

1249.221115.43

656.34

FTIR SPECTRUM

ACIC


Trichy-2


Date: 18-6-2010

T2-0.9+0.1 .pk

T2-09_~1.SP 3601 4000.00 400.00 7.95 99.99 4.00 %T 3 1.00

REF 4 000 99.28 2000 95.68 6003940.85 95.93 3443.85 7.95 2960.80 63.70 2087.25 92.87 1640.75 41.141394.47 77.50 1114.81 93.56 657.87 64.42

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.85

3443.85

2 960.80

2087.25

1640.75

13 94.47

1114.81

657.87

FTIR SPECTRUM


Trichy-2

Spectrum Name: Cl-AN-1.spDate: 3/11/2009

Cl-AN-1.pk

Cl-AN-1.s p 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 99.39 2000 97.58 6003449.55 6.33 2991.58 69.36 2489.19 98.54 2362.08 89.00 2088.87 95.421763.76 32.63 1637.15 43.78 1378.64 67.05 1242.81 18.73 1056.51 55. 12928.00 97.75 622.08 69.86

4000. 0 3000 2000 1500 1000 400.0

0. 0

10

20

30

40

50

60

70

80

90

100. 0

cm-1

%T

3449.55

2991.58

2489.19

2362.08

2088.87

1763.76

1637.15

1378.64

1242.81

1056.51

928.00

622.08

Table - 7.15

Observations of FTIR spectrums for Heptane + Ethyl Acetate mixture:

1(HP)

Cm-1

0.9(HP)

+

0.1(EA)

Cm-1

0.8(HP)

+

0.2(EA)

Cm-1

*0.7(HP)

+ 0.3(EA)

Cm-1

0.6(HP)

+

0.4(EA)

Cm-1

0.5(HP)

+

0.5(EA)

Cm-1

0.4(HP)

+

0.6(EA)

Cm-1

0.3(HP)

+

0.7(EA)

Cm-1

0.2(HP) +

0.8(EA)

Cm-1

0.1(HP)

+

0.9(EA)

Cm-1

1(EA)

Cm-1

3933.913435.812954.982665.982348.122135.821640.001459.351392.351225.901120.63657.99

3944.423440.752985.632092.631762.431642.621385.701242.991058.39633.00

3937.423432.962977.212091.631762.281641.771384.351242.981057.12630.89

3926.24

3444.002969.03

2341.82

2089.681761.82

1641.73

1384.931243.00

1056.86

633.59

3933.763781.903420.702964.892087.641760.481641.331390.891242.861056.26640.28

3435.672961.062341.882089.591761.141641.591386.941242.981057.10638.7757.56

3954.903437.232962.582088.751762.001641.341385.531243.011057.23633.82

3437.112957.172095.361760.171640.581388.101243.151056.29636.95

3946.313441.692958.682084.931641.211462.721390.991249.221115.43656.34

3940.853443.852960.802087.251640.751394.471114.81657.87

3449.552991.582489.192362.082088.87

1763.761637.151378.641242.811056.51928.00622.08


293

Fig-7.15: FTIR spectrums for Benzaldehyde + Benzyl Chloride mixture:

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Sam =0+19.67. sp

Date: 2/15/2008

Sam =0+19.67.pk

SAM_0_~1.SP 3601 4000.00 400.00 8.19 1 00.00 4.00 %T 3 2.00

REF 4000 99.61 2000 99.02 6003444.32 31.42 3065.58 52.84 3033.08 49.6 3 2960.77 67.54 2866.83 88.382361.42 79.78 1954.65 88.69 1887.33 92.5 0 1807.15 90.79 1699.23 68.221637.89 63.83 1495.29 64.98 1452.48 48.8 1 1394.35 74.16 1266.53 41.051207.06 75.43 1160.38 83.44 1073.70 76.1 4 1027.37 86.66 925.88 91.32810.75 61.0 7 760.56 50.09 696.69 8.19 559.46 56.01 464.81 74.80

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

344 4.32

3065.58

303 3.08

2960.77

2866.83

2361.42

1954 .65

1887.33

1807.15

1699.23

1637.89

149 5.29

1452.48

1 394.35

126 6.53

1207.06

1160 .38

1073.70

1027.37

925.88

8 10.75

760.56

696.69

559.46

464.81

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Sam =2.41+17.70.sp

Date: 2/15/2008

Sam =2.41+17.70.pk

SAM_24~2.SP 3601 4000.00 400.00 9.09 9 9.99 4.00 %T 3 2.00

REF 4000 99.73 2000 97.37 6003447.49 15.67 3070.48 53.89 3034.51 54.06 2962.70 74.19 2817.92 87.662736.78 92.46 2540.68 96.74 2358.99 85.24 1958.06 93.14 1699.03 26.021648.19 48.37 1495.12 74.20 1452.03 55.76 1398.17 68.40 1268.72 46.301204.97 67.30 1167.05 80.32 1074.60 83.18 1025.73 91.89 926.73 92.71813.02 62.7 8 695.77 9.09 5 59.03 60.03 462.79 78.76

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

344 7.49

3070.48

3034.51

2 962.70

2 817.92

2736.78

2540.68

2358.99

1958 .06

1699.03

1648.19

1495.1 2

1452.03

1398.17

126 8.72

1204.97

1167.05

1074.60

1025.73

926.73

813.02

695.77

559.03

462.79

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/15/2008

Sam =4.82+15.73.pk

SAM_48~1.SP 3601 4000.00 400.00 7.05 9 9.84 4.00 %T 3 2.00

REF 4000 99.51 2000 96.55 6003443.18 13.70 3073.15 41.73 2819.75 72.10 2737.67 80.92 2545.69 90.362359.20 75.50 1960.10 91.90 1698.89 10.57 1495.36 71.10 1452.09 48.981400.26 54.69 1271.31 38.58 1204.83 52.91 1168.03 68.46 1074.55 79.231024.51 89.32 928.75 88.11 815.57 57.97 747.40 38.25 695.95 7.05557.54 55.9 8 458.71 76.87

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

344 3.18

3073.15

2 819.75

2737.67

2545.69

2359.20

1960.10

1698.89

1495.36

1452.09

1400.26

127 1.31

1204.8 3

1168.03

1074.55

1024.51

928.75

815.57

747.40

695.95

557.54

458.71

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/15/2008

Sam =7.24+13.76.pk

SAM_72~1.SP 3601 4000.00 400.00 10.80 100.00 4.00 %T 3 2.00

REF 4000 99.69 2000 97.42 6003439.42 35.10 3067.86 54.14 2963.51 74.4 0 2817.20 70.15 2736.97 75.712359.43 82.44 1962.60 93.52 1701.42 11.7 4 1597.63 47.02 1494.80 75.981452.57 54.02 1393.77 66.01 1268.98 48.7 6 1204.22 47.37 1166.43 67.521074.02 81.80 1022.76 89.54 925.20 92.24 821.29 57.31 747.14 35.39694.86 10.8 0 559.14 68.49 456.26 78.41

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

343 9.42

3067.86

2963.51

2817.20

2736.97

2359.43

1962.6 0

1701.42

1597.63

1494.80

1452.57

1393.77

1268.98

1204.22

1166.43

1074.02

1022.76

925.20

821.29

747.14

694.86

559.14

456.26

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/15/2008

Sam =9.65+11.80.pk

SAM_96~1.SP 3601 4000.00 400.00 9.03 9 9.53 4.00 %T 3 2.00

REF 4000 99.49 2000 97.40 6003439.86 38.48 3066.36 53.18 3033.97 54.15 2817.73 64.78 2737.26 70.802361.84 84.33 1965.84 94.10 1701.17 9.03 1596.78 45.36 1495.51 77.771453.28 53.72 1393.06 65.17 1310.13 61.95 1269.20 49.82 1204.36 42.211166.79 63.53 1072.78 81.35 1023.51 88.83 925.94 90.76 824.59 56.31746.84 34.2 8 696.19 13.99 559.12 71.66 453.69 79.39

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

343 9.86

3 066.36

3033.97

2 817.73

2737.26

2361.84

1965.8 4

1701.17

1596.78

1495.51

1453.2 8

1393.06

1310.13

126 9.20

1204.36

11 66.79

1072.78

1023.51

925.94

824.59

746.84

696.19

559.12

453.69

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/15/2008

Sam =12.07+9.835.pk

SAM_12~1.SP 3601 4000.00 400.00 10.98 99.92 4.00 %T 3 2.00

REF 4000 99.76 2000 97.59 6003437.67 41.99 3069.79 55.88 2818.57 66.69 2737.87 73.89 2362.73 92.481970.64 95.50 1700.91 10.98 1597.14 50.47 1495.11 85.31 1452.75 64.321397.50 68.22 1277.16 55.15 1205.39 49.42 1168.03 68.01 1073.45 86.321020.97 91.54 927.05 91.33 823.92 62.41 746.94 41.79 696.10 23.64557.83 79.5 8 453.48 83.27

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

343 7.67

3069.79

2 818.57

2737.87

2362.731970.64

1700.91

1597.14

14 95.11

1452.75

1397.50

127 7.16

1205.39

1168.03

1073.45

1020.97

927.05

823.92

746.94

696.10

557.83

453.48

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/15/2008

Sam =14.48+7.86.pk

SAM_14~1.SP 3601 4000.00 400.00 7.75 1 00.00 4.00 %T 3 2.00

REF 4000 99.55 2000 95.47 6003390.66 50.09 3068.18 41.88 2818.64 45.5 2 2737.89 53.38 2550.12 77.802361.64 89.14 1976.28 92.30 1911.15 92.3 8 1821.69 92.83 1700.47 7.741595.83 35.79 1494.04 84.79 1451.93 56.2 4 1397.26 56.41 1281.88 40.721205.43 34.78 1168.71 49.49 1112.48 76.0 8 1072.39 76.63 1018.08 81.55927.95 74.7 8 824.10 48.14 746.52 31.25 695.80 22.89 553.80 74.39451.58 72.7 8

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T3390.66

3068.18

2 818.64

2737.89

2550.12

2361.64

1 976.28

19 11.15

1821.6 9

1700.47

1595.83

1494 .04

1451.93

139 7.26

128 1.88

1205.43

1 168.71

1112.48

1072.39

10 18.08

927.95

824.10

746 .52

695.80

553.80451.58

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/15/2008

Sam =16.89+5.90.pk

SAM_16~1.SP 3601 4000.00 400.00 7.53 9 9.99 4.00 %T 3 2.00

REF 4000 99.34 2000 94.39 6003390.58 45.03 3066.47 33.83 2818.69 38.42 2737.93 45.81 2549.23 73.482363.98 85.77 1973.32 89.72 1908.74 89.98 1820.52 89.71 1700.74 7.531596.05 29.28 1494.75 76.42 1452.81 45.15 1394.61 50.67 1281.16 34.041205.18 27.26 1167.95 41.83 1111.33 71.55 1072.00 68.93 1022.32 75.99927.04 71.2 7 825.21 40.05 746.76 24.05 695.33 16.20 556 .59 66.92452.04 66.6 8

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3390.58

3066.47

2 818.69

27 37.93

2549.23

2363.98

1973.32

1908.74

1820.52

1700.74

1596.0 5

1494.75

1452.81

1394.61

128 1.16

1205.18

1167.95

11 11.33

1072.00

10 22.32

927.04

825.21

746 .76

695.33

556.59

452.04

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/15/2008

Sam =19.32+3.93.pk

SAM_19~1.SP 3601 4000.00 400.00 10.42 99.85 4.00 %T 3 1.00

REF 4000 99.56 2000 95.70 6003392.16 56.03 3069.01 55.70 2818.59 57.23 2738.17 63.97 1978.74 93.871910.83 94.16 1822.87 93.44 1701.95 10.42 1595.96 44.54 1453.08 67.521394.45 66.72 1306.81 58.70 1205.67 43.04 1167.92 59.89 1110.72 84.701072.84 85.51 1016.10 88.45 925.4 8 89.27 825.54 56.98 746.88 37.69693.96 38.1 6 652.64 53.20 555.32 86.77 451.12 79.20

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T33 92.16

3069.01

2 818.59

2738.17

1978.74

1910.83

1822 .87

1701.95

1595.96

1453.08

1394.45

1306.81

1205.67

11 67.92

1110.72

1072.84

10 16.10

925.48

825.54

74 6.88

693.96

652 .64

555.32

451.12

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/15/2008

Sam =21.72+1.967.pk

SAM_21~1.SP 3601 4000.00 400.00 7.14 9 9.99 4.00 %T 3 1.00

REF 4000 99.23 2000 90.91 6003390.83 28.65 3071.24 29.60 2819.15 32.65 2738.60 39.18 2550.16 68.322365.30 84.93 2140.47 98.07 2027.14 91.35 1980.33 86.94 1913.14 86.831823.61 87.25 1700.22 7.14 1596.65 25.06 1492.91 85.87 1452.23 49.481396.15 41.91 1285.60 34.66 1205.95 26.63 1169.01 38.12 1112.44 65.441072.61 70.52 1015.51 74.79 926.8 8 67.28 824.81 37.12 746.45 23.20694.76 24.2 1 652.82 31.36 548.34 68.70 450.72 60.11

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3390.833071.24

2 819.15

2738.60

2550.16

2365.30

2140.47

202 7.14

1980.3 3

19 13.14

1823 .61

1700.22

1596.65

1492 .91

1452.23

1396.15

1285.60

1205.95

1169.01

1112.44

10 72.61

101 5.51

926.88

824.81

74 6.45

694.76

652.82

548.34

450.72

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Sam =24.14+0.sp

Date: 2/15/2008

Sam =24.14+0.pk

SAM_24~1.SP 3601 4000.00 400.00 7.78 9 9.80 4.00 %T 3 2.00

REF 4000 98.63 2000 89.64 6003392.11 38.45 3068.94 49.16 2818.39 41.61 2738.32 47.07 2332.07 92.722139.72 96.16 1982.52 87.01 1910.62 88.53 1826.09 87.47 1702.46 7.771596.07 28.46 1454.14 58.66 1392.52 56.44 1308.46 50.72 1204.67 31.121167.04 45.91 1108.93 82.45 1072.68 79.76 1012.18 79.42 922.30 88.15826.10 41.8 9 747.24 23.95 689.23 38.08 650.77 42.43 450 .84 67.18

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3392.11

3068.94

2 818.39

2738.32

2332.07

2139.72

1982.52

1910.62

1826.09

1702 .46

1596.07

1454.14

1392.52

1308.46

1204.67

1167.04

1108 .93

1072.68

101 2.18

922.30

826.10

74 7.24

689.23

65 0.77

450.84

Table - 7.16

Observations of FTIR spectrums for Benzaldehyde + Benzyl Chloride mixture:

1 (BD)

Cm-1

0.9(BD)

+

0.1(BC)

Cm-1

0.8(BD)

+

0.2(BC)

Cm-1

0.7(BD)

+

0.3(BC)

Cm-1

*0.6(BD)

+

0.4(BC)

Cm-1

0.5(BD)

+

0.5(BC)

Cm-1

0.4(BD)

+

0.6(BC)

Cm-1

0.3(BD)

+

0.7(BC)

Cm-1

0.2(BD)

+

0.8(BC)

Cm-1

0.1(BD)

+

0.9(BC)

Cm-1

1(BC)

Cm-1

3392.11

3068.94

2818.39

2738.32

2332.07

2139.72

1982.52

1910.62

1826.09

1702.46

1596.07

1454.14

1392.52

1308.46

1204.67

1167.04

1108.93

1072.68

1012.18

922.30

826.10

747.24

689.23

650.77

450.84

3390.83

3071.24

2819.15

2738.60

2550.16

2365.30

2140.47

2027.14

1980.33

1913.14

1823.61

1700.22

1596.65

1492.91

1454.23

1396.15

1285.60

1205.95

1169.01

1112.44

1072.61

1015.51

926.88

824.81

746.45

694.76

3392.16

3069.01

2818.59

2738.17

1978.74

1910.83

1822.87

1701.95

1595.96

1453.08

1394.45

130681

1205.67

1167.92

1110.72

1072.84

1016.10

925.48

825.54

746.88

693.96

65264

555.32

451.12

3390.58

3066.47

2818.69

2737.93

2549.23

2363.98

1973.32

1908.74

1820.52

1700.74

1596.05

1492.75

1452.81

1394.61

1281.16

1205.18

1167.95

1111.33

1072.00

1022.32

927.04

825.21

746.76

695.33

556.59

452.04

3390.66

3068.18

2818.64

2737.89

2550.12

2361.64

1976.28

1911.15

1821.69

1700.47

1595.83

1494.04

1451.93

1397.26

1281.88

1205.43

1168.71

1112.48

1072.39

1018.08

927.95

824.10

746.52

695.80

553.80

451.58

3437.67

3069.79

2818.57

2737.87

2362.73

1970.64

1700.91

1597.14

1495.11

1452.75

1397.50

1277.16

1205.39

1168.03

1073.45

1020.97

927.05

823.92

746.94

696.10

557.83

453.48

3439.86

3066.36

3033.97

2817.73

2737.26

2361.84

1965.84

1701.17

1596.78

1495.51

1453.28

1393.06

1310.13

1269.20

1204.36

1166.79

1072.78

1023.51

925.94

824.59

746.84

696.19

559.12

453.69

3439.42

3067.86

2963.51

2817.20

2736.97

2359.43

1962.60

1701.42

1597.63

1494.80

1452.57

1393.77

1268.98

1204.22

1166.43

1074.02

1022.76

925.20

821.29

747.14

694.86

559.14

456.26

3443.18

3073.15

2819.75

2737.67

2545.69

2359.20

1960.10

1698.89

1495.36

1452.09

1400.26

1271.31

1204.83

1168.03

1074.55

1024.51

928075

815.57

747.40

695.95

557.54

458.71

3447.49

3073.48

2962.70

2817.92

2736.78

2540.68

2358.99

1958.06

1699.03

1648.19

1495.12

1452.03

1398.17

1268.72

1204.97

1167.05

1074.60

1025.73

926.73

813.02

695.77

559.03

462.79

3444.32

3065.58

3033.08

2960.77

2866.83

2361.42

1954.65

1887.33

1807.15

1699.23

1637.89

1495.29

1452.48

1394.35

1266.53

1207.06

1160.38

1073.70

1027.37

925.88

810.75

760.56

696.69

559.46

464.81


294

Fig-7.16: FTIR spectrums for Benzaldehyde + 2-Butanone mixture:

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Sam =0+19.67. sp

Date: 2/15/2008

Sam =0+19.67.pk

SAM_0_~1.SP 3601 4000.00 400.00 8.19 1 00.00 4.00 %T 3 2.00

REF 4000 99.61 2000 99.02 6003444.32 31.42 3065.58 52.84 3033.08 49.6 3 2960.77 67.54 2866.83 88.382361.42 79.78 1954.65 88.69 1887.33 92.5 0 1807.15 90.79 1699.23 68.221637.89 63.83 1495.29 64.98 1452.48 48.8 1 1394.35 74.16 1266.53 41.051207.06 75.43 1160.38 83.44 1073.70 76.1 4 1027.37 86.66 925.88 91.32810.75 61.0 7 760.56 50.09 696.69 8.19 559.46 56.01 464.81 74.80

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

344 4.32

3065.58

303 3.08

2960.77

2866.83

2361.42

1954 .65

1887.33

1807.15

1699.23

1637.89

149 5.29

1452.48

1 394.35

126 6.53

1207.06

1160 .38

1073.70

1027.37

925.88

8 10.75

760.56

696.69

559.46

464.81

FTIR SPECTRUM

ACIC


Trichy-2


Date: 29-6-2010

T3-0.1+0.9 .pk

T3-01_~1.SP 3601 4000.00 400.00 7.88 99.99 4.00 %T 5 1.00

REF 4 000 99.54 2000 90.39 6003431.30 12.40 2984.73 74.96 2819.42 86.55 2737.35 88.66 2033.45 89.501707.96 7.88 1376.29 47 .35 1189.37 49.02 1014.68 94.68 938.97 93.55822.24 65 .70 745.92 40.94 692.77 47.8 5 460.27 78.59

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 431.30

2984.73

2819.42

2737.352033.45

17 07.96

1376.29 1189.37

1014.68

938.97

822 .24

745.92

69 2.77

460.27

FTIR SPECTRUM

ACIC


Trichy-2


Date: 29-6-2010

T3-0.2+0.8 .pk

T3-02_~1.SP 3601 4000.00 400.00 6.36 99.92 4.00 %T 5 1.00

REF 4 000 99.92 2000 95.70 6003942.73 95.56 3451.99 6.36 2991.86 90.02 2815.56 87.29 2736.34 88.632130.63 94.26 1701.44 15.76 1649.46 31.63 1450.89 74.48 1386.52 64.681310.27 80.27 1202.77 61.59 1168.90 70.44 1017.84 94.39 930.50 96.86824.59 66 .51 745.04 43.68 689.05 48.4 5 650.09 51.20 454.91 80.57

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3942.73

3 451.99

2991.86

2815.56

2736.34

2130.63

17 01.44

1649.4 6

1450.89

13 86.52

1310.27

1202.77

1168.90

1017.84

930.50

824.59

745.04689.05

650.09

454.91

FTIR SPECTRUM

ACIC


Trichy-2


Date: 29-6-2010

T3-0.3+0.7 .pk

T3-03_~1.SP 3601 4000.00 400.00 10.53 100.00 4.00 %T 5 1.00

REF 4 000 99.66 2000 94.32 6003956.28 96.54 3426.16 1 3.62 2989.41 77.28 2819.78 79.49 2736.48 83.482027.76 93.89 1704.63 1 0.53 1385.07 55.15 1311.05 70.83 1193.13 48.061013.78 93.69 932.87 94.88 823.73 61 .84 744.12 37.63 688.57 44.28456.26 76 .40

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3956.28

3 426.16

2989.41

2819.78

2736.48

2027.76

1704.63

13 85.07

1311.05

1193.13

1013.78

932.87

823.73

744.12

688.57

456.26

FTIR SPECTRUM

ACIC


Trichy-2


Date: 29-6-2010

T3-0.4+0.6 .pk

T3-04_~1.SP 3601 4000.00 400.00 10.79 99.99 4.00 %T 5 1 .00

REF 4 000 99.38 2000 94.17 6003433.85 10.79 2820.53 82.08 2734.92 86.05 2333.28 97.87 2022.06 93.941700.15 10.96 1393.13 59.38 1303.20 68.69 1197.28 50.47 1016.00 92.70819.82 60 .62 741.06 36.28 682.82 40.5 2

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3433.85

2820.53

2734.92

2333.28

202 2.06

17 00.15

1393.13

1303.20

1197.28

1016.00

81 9.82

741.06

682.82

FTIR SPECTRUM

ACIC


Trichy-2


Date: 29-6-2010

T3-0.5+0.5 .pk

T3-05_~1.SP 3601 4000.00 400.00 5.12 99.99 4.00 %T 5 1.00

REF 4 000 99.58 2000 92.60 6003941.05 90.22 3424.31 5.12 2818.25 74.51 2737.53 79.41 2332.11 95.862032.44 91.25 1700.34 6.90 1396.80 55.71 1304.85 67.90 1204.58 49.541014.90 90.68 821.96 48 .66 743.76 25.53 691.81 31.26 458.13 66.62

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3941.05

3424.31

2818.25

273 7.53

2332.11

2032.44

17 00.34

13 96.80

1304.85

1204.58

1014.90

821.96

743.76

691.81

458.13

FTIR SPECTRUM

ACIC


Trichy-2


Date: 29-6-2010

T3-0.6+0.4 .pk

T3-06_~1.SP 3601 4000.00 400.00 6.36 100.00 4.00 %T 5 1 .00

REF 4 000 100.00 2000 92.51 6003431.33 6.36 2824.30 64.14 2738.44 71.59 2336.90 95.13 2025.07 92.191701.96 14.14 1389.71 5 3.40 1309.49 69.27 1196.87 50.48 1011.91 90.25928.06 94 .26 822.84 56.75 743.49 34.88 6 88.01 39.51 454.79 71.62

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3431.33

2 824.30

2738.44

233 6.90

2025.07

17 01.96

1389.71

1309.49

1196.87

1011.91

9 28.06

822.84

743.49

6 88.01

454.79

FTIR SPECTRUM

ACIC


Trichy-2


Date: 29-6-2010

T3-0.7+0.3 .pk

T3-07_~1.SP 3601 4000.00 400.00 7.87 99.64 4.00 %T 5 1.00

REF 4 000 98.82 2000 90.97 6003936.33 93.51 3841.76 94.15 3421.01 7.87 3084.59 57.89 2821.00 63.732737.73 70.31 2334.08 96.40 1988.46 90.77 1914.74 93.22 1701.67 8.081391.30 47.90 1308.25 57.53 1200.38 38.82 1012.19 86.53 925.46 91.72823.89 47 .79 743.74 25.97 688.83 31.7 4 453.48 67.80

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3936.33

3841.76

3421.01

3084.59

2821.00

2737.73

233 4.08

1988.46

1914.74

17 01.67

1391.30

1308.25

1200.38

1012.19

925.46

823.89

743.74

688.83

453.48

FTIR SPECTRUM

ACIC


Trichy-2


Date: 29-6-2010

T3-0.8+0.2 .pk

T3-08_~1.SP 3601 4000.00 400.00 8.04 99.49 4.00 %T 5 1.00

REF 4 000 98.56 2000 90.34 6003423.22 8.70 3079.94 53 .85 2821.85 58.55 2736.26 66.54 2338.82 95.681995.68 90.29 1698.41 8.04 1395.57 50.35 1302.34 54.78 1197.95 37.701013.52 85.45 820.61 45 .97 741.93 25.02 682.04 28.94 456.62 66.17

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3423.22

3079.94

2821.85

27 36.26

233 8.82

1995.68

16 98.41

13 95.57

1302.34

1197.95

1013.52

820.61

741.93

682.04

456.62

FTIR SPECTRUM

ACIC


Trichy-2


Date: 29-6-2010

T3-0.9+0.1 .pk

T3-09_~1.SP 3601 4000.00 400.00 6.34 100.00 4.00 %T 5 1 .00

REF 4 000 99.21 2000 91.71 6003946.81 94.63 3421.90 6 .34 2818.47 70.21 2737.84 74.90 2407.88 98.272325.60 97.66 2027.07 9 0.96 1913.87 94.69 1699.95 10.11 1396.30 54.871304.90 64.35 1204.59 4 8.62 1015.20 87.01 822.26 48.87 744.02 27.55691.69 32 .76 456.05 66.00

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3946.81

3 421.90

2818.47

27 37.84

2 407.88

23 25.60

2027.071913.87

16 99.95

13 96.30

1304.90

1204.59

1015.20

822.26

744.02

691.69

456.05

FTIR SPECTRUM

ACIC


Trichy-2


Date: 04-2-2010

SJC-J-11.pk

SJC-J-11.sp 3601 4000.00 400.00 7.03 99.99 4.00 %T 5 1.00

REF 4 000 99.04 2000 98.74 6003926.98 96.87 3799.99 95.07 3445.81 12.13 2987.82 40.47 2832.12 69.242726.13 89.36 2121.16 95.77 1737.56 19.80 1595.49 7.03 1362.59 17.871171.83 49.73 941.51 89 .22 770.71 65.15 588.52 63.33

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3926.98

3799.99

3445.81

2987.82

2832.12

2726.13

2121.16

1737.56

1595.49

1 362.59

1171.83

941.51

7 70.71 588.52

Table - 7.17

Observations of FTIR spectrums for Benzaldehyde + 2-Butanone mixture:

1 (BD)

Cm-1

0.9(BD)

+

0.1(2B)

Cm-1

0.8(BD)

+

0.2(2B)

Cm-1

*0.7(BD)

+

0.3(2B)

Cm-1

0.6(BD)

+

0.4(2B)

Cm-1

0.5(BD)

+

0.5(2B)

Cm-1

0.4(BD)

+

0.6(2B)

Cm-1

0.3(BD)

+

0.7(2B)

Cm-1

0.2(BD)

+

0.8(2B)

Cm-1

0.1(BD)

+

0.9(2B)

Cm-1

1(2B)

Cm-1

3928.233446.842819.602738.802363.701982.171913.801824.001697.381594.541453.801387.261310.061206.731169.331114.111072.351015.97924.10825.54746.17690.95651.10545.73452.91

3946.813421.902818.472737.842407.88

2325.602027.071913.871699.951396.30

1304.901204.591015.20822.26744.02

691.69456.05

3423.223079.942821.852736.262338.82

1995.681698.411395.571302.341197.951013.52820.61741.93682.04456.62

3936.33

3841.763421.01

3084.59

2821.002737.73

2334.08

1988.461914.74

1701.67

1391.301308.25

1200.38

1012.19925.46

823.89743.74

688.83

453.48

3431.332824.302738.442336.902025.071701.961389.711309.491196.871011.91928.06822.84743.49688.01454.79

3941.053424.312818.252737.532332.112032.441700.341396.801304.851204.581014.90821.96743.76691.81458.13

3433.852820.532734.922333.282022.061700.151393.131303.201197.281016.00819.82741.06682.82

3956.283426.162989.412819.782736.482027.761704.631385.071311.051193.131013.78932.87823.73744.12688.57456.26

3942.733451.992991.862815.562736.342130.631701.441649.461450.891386.521310.271202.771168.901017.84930.50824.59745.04689.05650.09454.91

3431.302984.732819.422737.352033.451707.961376.291189.371014.68938.97822.24745.92692.77460.27

3921.993778.253445.422930.862087.471815.011626.891409.751247.001117.881011.07563.25


295

Fig-7.17: FTIR spectrums for Benzaldehyde + Ethyl Acetate mixture:

FTIR S PECTR UM

ACIC


Trichy-2

Spectrum Name: SJC-1BD.sp

Date: 21-12-2009

SJC-1BD.pk

SJC-1BD.sp 3601 4000.00 400.00 6.32 99. 90 4.00 %T 5 1.00

R EF 4000 99.33 2000 94.67 6003928.23 97.09 3446.84 6.32 2819.60 52.37 2738.80 63.28 2363.70 95.081982.17 93.61 1913.80 94. 42 1824.00 94.71 1697.38 18. 33 1594.54 10.431453.80 66.53 1387.26 52. 24 1310.06 55.31 1206.73 48. 10 1169.33 62.451114.11 85.01 1072.35 87. 37 1015.97 88.91 924.10 93.62 825.54 55. 94746.17 35.49 690. 95 41.50 651.10 43.65 545.73 67. 86 452.91 69.90

4000 .0 3000 20 00 1 50 0 1 00 0 40 0.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3928.23

3446.84

2819.60

2738.80

2363.70

1982.17

1913.80

1824.00

1697.38

1594.54

1453.80

1387.26

1310.06

1206.73

1169.33

1114.11

1072.35

1015.97

924.10

825.54

746.17

690.95

651.10

545.73

452.91

FTIR SPECT RUM

ACIC

St.Joseph's College ( Autonomous )Trichy-2

Spectrum Name: T 4-0.9+0.1.sp

Date: 23-6-2010

T4-0.9+0.1.pk

T4-09_~1.SP 3601 4000.00 400.00 9.07 99.84 4.00 %T 5 1.00

REF 4000 98.47 2000 94.83 6003426.97 28.43 3074.62 56.80 2822.34 64.77 2738.81 74.71 2543.76 90.902342.05 95.64 1982.50 94.39 1915.68 94.66 1700.87 9.07 1600.13 35.701397.28 59.71 1289.65 48.64 1207.65 43.35 1022.33 89.37 924.55 89.05824.79 59.18 741.17 36.73 544.04 78.22 452.99 78.43

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3426 .97

3074 .62

2822 .34

2738 .81

2 54 3.76

2342 .051982 .50

1 91 5.68

1700 .87

1 60 0.13

1 39 7.28

1 28 9.65

1207 .65

1 02 2.33

9 24 .5 5

82 4.79

7 41 .1 7

5 44 .0 4

45 2.99

FTIR SPECT RUM

ACIC


Spectrum Name: T 4-0.8+0.2.sp

Date: 23-6-2010

T4-0.8+0.2.pk

T4-08_~1.SP 3601 4000.00 400.00 7.67 100.00 4.00 %T 5 1.00

REF 4000 99.49 2000 93.14 6003946.88 96.74 3402.54 26.54 3069.09 33.63 2825.68 38.79 2739.72 49.441983.45 92.59 1916.65 92.30 1698.37 7.67 1605.97 28.26 1400.35 47.521228.31 30.02 925.01 77.31 819.31 50.75 719.78 28.16 540.81 74.24452.23 73.20

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3946.88

3402 .54

3069 .09

2825 .68

2739 .72

1983 .45

1916.65

1698 .37

1605.97

1400.35

1228.31

925 .01

819 .31

719.78

540 .81

452.23

FTIR SPECTRUM


Trichy-2

SpectrumName: T4-0.7+0.3.sp

Date: 23-6-2010

T4-0.7+0.3.pk

T4-07_~1.SP 3601 4000.00 400.00 8.28 99.84 4.00 %T 5 1.00

REF 4000 99.54 2000 92.98 6003940.27 95.72 3824.49 93.52 3408.17 21.31 3073.65 37.37 2823.61 43.922740.09 52.20 2554.09 67.40 1981.36 91.95 1915.75 91.37 1700.85 8.281601.44 31.42 1397.86 49.12 1234.35 31.64 1069.95 75.17 927.36 74.68822.83 52.79 737.91 32.79 543.34 72.29 451.45 74.20

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.27

3824.49

3408.17

3073.65

2823 .61

2740.09

2554.09

1981.36

1915.75

1700.85

1601.44

1397.86

1234.35

1069 .95

927.36

822.83

737.91

543.34

451.45

FTIR SPECTRUM

ACIC

St. Joseph's College ( Autonomous )Trichy-2


Date: 23 -6-2010

T4-0.6+0.4.pk

T4-06_~1.SP 3 601 4000.00 400 .0 0 9 .0 0 9 9.80 4.00 %T 5 1.00

REF 4000 98 .6 0 2000 92.52 6003404.26 25.71 30 69.00 52.52 2821.75 51.64 2738.30 60.23 2338.90 94.091986.61 92.20 19 12.24 93.37 1704.01 9.00 1600.11 31.32 1451.57 61.631389.34 51.76 12 34.43 26.85 1053.37 65.10 921.84 89.99 825.35 51.00744.45 31.91 689.00 40.61 45 2.32 7 3.64

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3404.26

3069.00

2821.75

2738.30

2338.90 1986.61

1912.24

1704.01

1600.11

1451 .57

1389.34

1234.43

1053.37

921.84

825.35

744.45

689.00

452.32

FTIR SPECTRUM


Trichy-2


T4-0.5+0.5.pk

T4-05_~1.SP 3601 4000.00 400.00 5.11 99.54 4.00 %T 5 1.00

REF 4000 98.93 2000 95.20 6003937.36 90.52 3824.09 86.52 3427.15 5.11 2996.89 48.88 2824.44 62.892738.24 73.70 2670.77 73.47 2557.58 73.29 2353.71 88.24 2087.20 94.541982.95 94.39 1914.00 92.78 1686.42 6.82 1402.21 36.22 1246.93 14.711056.49 54.95 927.51 56.11 811.14 49.50 690.96 21.84 544.62 48.94

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

393 7.36

3824.09

3427.15

299 6.89

2824.44

2738.24

2670.77

2557.58

2353.71

2087.20

1982.95

1914.00

1686.42

140 2.21

1246 .93

1056 .4992 7.51

811.14

690.96

544 .62

FTIR SPECTRUM


Trichy-2


T4-0.4+0.6.pk

T4-04_~1.SP 3601 4000.00 400 .00 5.75 99.86 4.00 %T 5 1.00

REF 4000 99.20 2000 94.56 6003928.98 90.25 3442.32 5.75 2997.04 36.93 2826.21 48.37 2739.54 60.282669.71 59.20 2558.07 59.58 2355.10 82.30 2089.29 92.87 1983.47 93.671914.54 90.96 1686.44 6.12 1405.99 33.11 1248.62 12.39 1119.87 65.481056.82 54.72 928.09 45.31 811.86 45.36 692.06 17.95 543.85 44.55454.80 67.65

4000. 0 3000 2000 1500 1000 400.0

0. 0

10

20

30

40

50

60

70

80

90

100. 0

cm-1

%T

3928.98

3442.32

2997.04

2826.21

2739.54

2669.71

2558.07

2355.10

2089.29

1983.47

1914.54

1686.44

1405.99

1248.62

1119.87

1056.82

928.09

811.86

692.06

543.85

454.80

FTIR SPECTRUM


Trichy-2


T4-0.3+0.7.pk

T4-03_~1.SP 3601 4000.00 400 .00 7.89 99.82 4.00 %T 5 1.00

REF 4000 99.42 2000 95.74 6003425.57 24.94 3067.72 44.25 2999.42 44.20 2828.90 48.65 2740.53 61.462669.85 58.80 2556.93 59.51 1915.24 93.73 1690.47 7.89 1599.10 42.031416.36 50.30 1286.37 27.15 1119.47 80.61 1062.06 75.59 931.36 55.80816.01 68.31 701.69 36.35 545.98 69.45 452.08 85.58

4000. 0 3000 2000 1500 1000 400.0

0. 0

10

20

30

40

50

60

70

80

90

100. 0

cm-1

%T

3425.57

3067.72

2999.42

2828.90

2740.53

2669.85

2556.93

1915.24

1690.47

1599.10

1416.36

1286.37

1119.47

1062.06

931.36

816.01

701.69

545.98

452.08

FTIR SPECTRUM

ACIC



T4-0.2+0.8.pk

T4-02_~1.SP 3601 4000.00 400.00 6.38 99.99 4.00 %T 5 1.00

REF 4000 99.26 2000 88.24 6003940.58 92.24 3814.90 88.53 3430.96 6.38 2992.63 51 .91 2661.10 69.152552.21 66.66 2352.41 74.98 1916.25 88.91 1685.89 10.13 1403.64 31.611248.47 16.32 1119.52 55.26 1056.78 49.95 926 .22 40 .29 805.02 50.50690.23 20.43 543.80 37.44

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.58

3814.90

3430.96

2992.63

2661.10

2552.21

2352.41

1916.25

1685.89

1403.64

1248.47

1119.52

1056.78

926.22

805.02

690.23

543.80

FTIR SPECTRUM

ACIC



T4-0.1+0.9.pk

T4-01_~1.SP 3601 4000.00 400.00 7.67 100.00 4.00 %T 5 1.00

REF 4000 99.63 2000 96.95 6003944.19 96.64 3434.47 9.28 2996.97 51.18 2833 .61 64.69 2663.95 74.612556.94 74.70 2089.94 95.37 1914.06 96.49 1698.70 7.67 1394.82 39.571260.52 19.75 1052.99 65.44 930.37 69.32 808.71 67.28 703.05 35.76544.56 62.42

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3944.19

3434.47

2996.97

2833.61

2663.95

2556.94

2089.94

1914.06

1698.70

1394.82

1260.52

1052.99

930.37

808.71

703.05

544.56

FTIR SPECTRUM


Trichy-2


Cl-AN-1.pk

Cl-AN-1.s p 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 99.39 2000 97.58 6003449.55 6.33 2991.58 69.36 2489.19 98.54 2362.08 89.00 2088.87 95.421763.76 32.63 1637.15 43.78 1378.64 67.05 1242.81 18.73 1056.51 55. 12928.00 97.75 622.08 69.86

4000. 0 3000 2000 1500 1000 400.0

0. 0

10

20

30

40

50

60

70

80

90

100. 0

cm-1

%T

3449.55

2991.58

2489.19

2362.08

2088.87

1763.76

1637.15

1378.64

1242.81

1056.51

928.00

622.08

Table - 7.18

Observations of FTIR spectrums for Benzaldehyde + Ethyl Acetate mixture:

1 (BD)

Cm-1

0.9(BD)

+

0.1(EA)

Cm-1

0.8(BD)

+

0.2(EA)

Cm-1

0.7(BD)

+

0.3(EA)

Cm-1

*0.6(BD)

+

0.4(EA)

Cm-1

0.5(BD)

+

0.5(EA)

Cm-1

0.4(BD)

+

0.6(EA)

Cm-1

0.3(BD)

+

0.7(EA)

Cm-1

0.2(BD)

+

0.8(EA)

Cm-1

0.1(BD)

+

0.9(EA)

Cm-1

1(EA)

Cm-1

3928.233446.842819.602738.802363.701982.171913.801824.001697.381594.541453.801387.261310.061206.731169.331114.111072.351015.97924.10825.54746.17690.95651.10545.73452.91

3944.193434.472996.972833.612663.952556.942089.941914.061698.701394.821260.521052.99930.37808.71703.05544.56

3940.583814.903430.962992.632661.102552.212352.411916.251685.891403.641248.471119.521056.78926.22805.02690.23543.80

3425.573067.722999.422828.902740.532669.852556.931915.241690.471599.101416.361286.371119.471062.06931.36816.01701.69545.98452.08

3928.98

3442.322997.04

2826.21

2739.542669.71

2558.07

2355.102089.29

1983.471914.54

1686.44

1405.991248.62

1119.87

1056.82928.09

811.86

692.06543.85

454.80

3937.363824.093427.152996.892824.442738.242670.772557.582353.712087.201982.951914.001686.421402.211246.931056.49927.51811.14690.96544.62

3404.263069.002821.752738.302338.901986.611912.241704.011600.111451.571389.341234.431053.37921.84825.35744.45689.00452.32

3940.273824.493408.173073.652823.612740.092554.091981.361915.751700.851601.441397.861234.351069.95927.36822.83737.91543.34451.45

3946.883402.543069.092825.682739.721983.451916.651698.371605.971400.351228.31925.01819.31719.78540.81452.23

3426.973074.622822.342738.812543.762342.051982.501915.681700.871600.131397.281289.651207.651022.33924.55824.79741.17544.04452.99

3449.552991.582489.192362.082088.87

1763.761637.151378.641242.811056.51928.00622.08


296

Fig-7.18: FTIR spectrums for Benzyl Chloride + 2-Butanone mixture:

FTIR SPECT RUM

ACIC


Trichy-2

Spectrum Name: Sam =1.sp

Date: 2/23/2008

Sam =1.pk

SAM_1~1.SP 3601 4000.00 400.00 8.04 99.86 4.00 %T 3 1.00

REF 4000 99.14 2000 89.33 6003394.11 31.28 3072.11 51.40 2818.42 48.88 2738.34 53.57 2372.89 93.942330.26 93.64 2235.79 97.53 2139.83 96.21 2026.52 89.18 1982.86 86.851911.14 88.44 1826.50 87.25 1701.69 8.03 1596.72 33.01 1454.12 61.661392.85 56.13 1308.72 56.19 1204.25 35.78 1166.91 52.28 1109.92 80.911073.38 80.67 1012.73 81.15 922.40 89.82 826.07 47.98 746.86 29.08688.87 42.31 650.60 46.50 450.67 70.58

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3394 .11

3072 .1 12818 .42

2738 .34

2 37 2.89

2 33 0.2 6

22 35.79 213 9.83

2026 .52

19 82.86

1911 .14

1 82 6.50

1701 .69

1596 .72

1454 .12

1 39 2.85

1308 .72

1204 .25

116 6.91

1109 .92

107 3.38

1 01 2.7 3

9 22 .4 0

82 6.07

74 6.86

688 .8 7

65 0.60

45 0.67

FTIR SPECT RUM

ACIC


Trichy-2

Spectrum Name: Sam = 2.sp

Date: 2/23/2008

Sam = 2.pk

SAM_2~1.SP 3601 4000.00 400.00 9.18 99.98 4.00 %T 3 1.00

REF 4000 99.84 2000 93.13 6003392.13 50.39 3067.40 62.67 2818.44 55.53 2738.20 59.65 2367.01 92.642332.27 92.66 2236.38 98.68 2139.34 97.78 2027.08 92.62 1983.03 91.021910.17 92.08 1826.27 90.69 1702.00 9.18 1655.24 45.74 1595.90 39.271454.70 65.13 1392.10 63.91 1310.13 60.34 1204.12 38.07 1166.83 55.091108.54 86.82 1072.28 83.86 1012.18 85.07 923.43 91.83 826.70 50.84747.06 31.09 688.70 46.57 650.23 51.30 450.89 74.49

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T3392 .13

3 067 .4 0

2 818 .4 4

2 73 8.2 0

2367 .01

23 32.27

22 36.38

213 9.34

2027 .08

19 83.03

1910 .17

1 82 6.27

1702 .00

16 55.24

1595 .90

1 45 4.70

1 39 2.10

1310 .13

12 04.12

11 66.83

1 10 8.5 4

1 072 .2 81 01 2.1 8

9 23 .4 3

82 6.70

74 7.06

6 88.70

6 50.23

450 .8 9

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/23/2008

Sam =3.pk

SAM_3~2.SP 3601 4000.00 400.00 9.36 99.92 4.00 %T 3 1.00

REF 4000 99.12 2000 92.30 6003396.11 35.96 3070.63 61.26 2818.50 59.99 2738.21 64.26 2373.11 95.852330.79 96.13 2235.76 98.05 2139.03 96.82 2027.29 91.74 1983.09 90.431911.42 91.70 1825.70 90.59 1701.38 9.35 1654.81 41.64 1596.48 40.791454.41 67.49 1392.53 62.65 1310.26 62.41 1204.34 41.37 1166.82 58.691109.80 84.41 1072.43 84.63 1012.95 86.94 923.24 91.48 826.64 53.85746.91 33.76 688.63 47.68 650.17 51.53 450.96 74.90

40 00.0 3 000 2000 1500 1000 400.0

0 .0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0.0

cm-1

%T

3396 .11

3070 .632818.50

2738.21

2373 .11

2330.79

2235 .76

2139.03

2027.29

1983 .09

1911 .42

1825 .70

1701.38

1654 .81

1596.48

1454.41

1392 .531310 .26

1204 .34

1166.82

1109.80

1072 .43

1012 .95

923 .24

826 .64

746 .91

688 .63

650.17

450.96

FT IR SPECT RUM

ACIC

St.Joseph 's C ollege ( Autonomous )

T richy-2


Date: 2/23/2008

Sam =4. pk

SAM_4~1.S P 3601 4000.00 400.00 8.99 99.87 4.00 % T 3 1.00

REF 4000 99.34 2000 92.99 6003396.05 39.35 3069.41 54.06 2818. 69 48. 05 2738.46 54.69 2329.91 96.262138.94 97.57 1983.09 91.35 1911. 55 92. 50 1826.24 91.44 1703.53 8.981597.13 34.18 1453.99 62.74 1391. 81 57. 85 1308.28 56.99 1204.32 38.161168.77 48.45 1109.33 84.90 1073. 80 83. 60 1011.83 84.65 925.28 91.77825.98 50.45 747. 33 31.29 690.05 46.11 651.03 50.52 451.19 73.87

4000 .0 3000 2000 1500 1000 400 .0

0 .0

10

20

30

40

50

60

70

80

90

100 .0

cm -1

%T

3396.05

3069.41

2818.69

2738.46

2329.91

2138.94

1983.09

1911.55

1826.24

1703.53

1597.13

1453.99

1391.81

1308.28

1204.32

1168.77

1109.33

1073.80

1011.83

925.28

825.98

747.33

690.05

651.03

451.19

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/23/2008

Sam =5.pk

SAM_5~2.SP 3601 4000.00 400.00 8.95 99.98 4.00 %T 3 1.00

REF 4000 99.81 2000 96.51 6003393.76 58.42 3067.49 63.29 2818.81 62.12 2738.32 68.14 2331.93 97.791982.81 95.37 1912.98 95.82 1825.18 95.14 1703.44 8.94 1595.99 47.211454.20 67.73 1391.37 65.94 1310.66 63.92 1204.91 43.62 1168.61 55.981109.98 86.79 1072.58 87.48 1015.10 90.79 930.45 92.50 826.77 60.21747.39 38.72 689.11 55.98 650.24 59.36 451.16 82.34

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3393 .76

3 067 .492818.81

2738.32

2 331 .931982 .81

1912 .98

1825 .18

1703.44

1595.99

1454 .20

1391.37

1310 .66

1204 .91

1168.61

1109.98

1072 .58

1015.10

930 .45

826 .77

747 .39

689 .11

650.24

451.16

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/21/2008

Sam = 6.pk

SAM_6~1.SP 3601 4000.00 400.00 7.36 99.92 4.00 %T 3 2.00

REF 4000 99.20 2000 90.29 6003393.99 32.63 3066.72 49.01 2981.95 58.79 2818.73 40.37 2738.47 45.182405.59 95.68 2329.51 94.80 2138.99 96.05 2027.34 89.59 1984.22 87.571911.03 89.28 1826.92 87.47 1703.87 7.35 1596.18 27.64 1454.61 48.791391.15 47.10 1310.20 49.05 1203.83 28.43 1168.19 36.29 1106.93 83.071073.17 76.76 1011.61 79.05 928.64 87.21 826.38 40.72 747.78 22.49689.19 37.55 650.30 41.85 451.17 66.64

4000 .0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

10 0.0

cm-1

%T

3393 .99

3066.72

2981 .95

2818.73

2738.47

2405.59

2329.51

2138 .99

2027 .341984.22

1911 .03

1826 .92

1703 .87

1596.18

1454 .61

1391.15

1310 .20

1203.83

1168 .19

1106 .93

107 3.171011.61

9 28.64

826.38

747 .78

689 .19

650.30

451 .17

FTIR SPECTRUM

ACIC


Spectrum Name: Sam = 7.spDate: 2/21/2008

Sam = 7.pk

SAM_7~1.SP 3601 4000.00 400.00 9.19 99.85 4 .00 %T 3 2.00

REF 4000 99.75 2000 96.32 6003399.05 57.33 3069.09 63.15 2983.47 64.86 2819.42 62.71 2738.97 69.661983.33 95.46 1705.87 9.19 1596.94 49.46 1453.55 66 .53 1387.82 62.111309.35 64.96 1204.37 45.42 1170.93 52.92 1109.88 86.60 1012.35 90.83935.87 90.76 826.54 64.55 747 .69 44 .24 691.22 60.37 650.64 64.96451.50 86.71

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3399.05

3069.09

2983.47

2819.42

2738.97

1983.33

1705.87

1596.94

1453.55

1387.82

1309.35

1204.37

1170.93

1109.88

1012.35

935.87

826.54

747.69

691.22

650.64

451.50

FTIR SPECTRUM

ACIC



Sam = 8.pk

SAM_8~1.SP 3601 4000.00 400.00 8.38 99.85 4 .00 %T 3 2.00

REF 4000 99.10 2000 95.75 6003446.56 36.47 2984.11 68.93 2819.21 67.88 2738.64 73.35 1984.33 94.861703.56 8.37 1596.96 48.66 1454.30 65.93 1391.35 61 .11 1311.01 65.221204.29 44.16 1169.24 54.53 1110.76 84.92 1073.33 86.65 1016.45 91.12933.56 91.56 826.81 61.89 747 .32 41 .10 689.04 54.92 650.21 58.33451.46 83.18

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3446.56

2984.11

2819.21

2738.64

1984.33

1703.56

1596.96

1454.30

1391.351311.01

1204.29

1169.24

1110.76

1073.33

1016.45

933.56

826.81

747.32

689.04

650.21

451.46

FTIR SPECTRUM

ACIC



Sam = 9.pk

SAM_9~1.SP 3601 4000.00 400.00 6.87 99.57 4 .00 %T 3 2.00

REF 4000 99.46 2000 90.97 6003446.41 23.54 3069.90 45.63 2984.67 40.80 2823.30 51.11 2736.41 61.182670.86 59.71 2558.19 59.51 1917.31 89.76 1698.20 6.87 1597.56 43.171451.42 54.01 1418.90 40.44 1288.32 28.23 1174.81 42.16 1124.97 74.461072.21 80.23 1024.29 90.34 933.60 51.24 821.56 67.89 746 .48 51.87706.48 31.65 654.22 52.72 547 .54 68 .63 450.85 87.84

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3446.41

3069.90

2984.67

2823.30

2736.41

2670.86

2558.19

1917.31

1698.20

1597.56

1451.42

1418.90

1288.32

1174.81

1124.97

1072.21

1024.29

933.60

821.56

746.48

706.48

654.22

547.54

450.85

FTIR SPECTRUM

ACIC



Sam = 10.pk

SAM_10~1.SP 3601 4000.00 400.00 6.95 99.68 4.00 %T 3 2.00

REF 4000 99.53 2000 95.68 6003450.46 19.61 2985.42 39.89 2668.13 69.66 2558.32 67.90 1916.64 94.531690.02 6.95 1419.42 38.35 1324.68 46.40 1289.26 27 .86 1176.11 42.531126.20 77.73 1073.49 84.46 1025.96 94.37 934 .40 50 .29 805.24 77.29750.45 79.91 707.39 30.60 594 .50 76 .48 547.41 69.65

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3450.46

2985.42

2668.13

2558.32

1916.64

1690.02

1419.42

1324.68

1289.26

1176.11

1126.20

1073.49

1025.96

934.40

805.24

750.45

707.39

594.50

547.41

FTIR SPECTRUM

ACIC



Sam = 11.pk

SAM_11~1.SP 3601 4000.00 400.00 6.34 99.25 4.00 %T 3 1.00

REF 4000 99.25 2000 84.80 6003449.47 6.34 2987.29 35.70 2552.77 91.18 2370.90 75 .22 2339.69 84.292098.22 82.03 1724.52 7.85 1453.62 48.10 1374.94 24 .73 1289.16 60.261172.99 28.20 1024.90 96.34 938.37 70.56 752.00 64.59 708 .66 45.53593.27 58.47 548.46 67.08

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3449.47

2987.29

2552.77

2370.90

2339.69

2098.22

1724.52

1453.62

1374.94

1289.16

1172.99

1024.90

938.37

752.00

708.66

593.27

548.46

Table - 7.19

Observations of FTIR spectrums for 2-Butanone + Ethyl Acetate

1 (BC)

Cm-1

0.9(BC)

+

0.1(2B)

Cm-1

0.8(BC)

+

0.2(2B)

Cm-1

0.7(BC)

+

0.3(2B)

Cm-1

0.6(BC)

+

0.4(2B)

Cm-1

*0.5(BC)

+

0.5(2B)

Cm-1

0.4(BC)

+

0.6(2B)

Cm-1

0.3(BC)

+

0.7(2B)

Cm-1

0.2(BC)

+

0.8(2B)

Cm-1

0.1(BC)

+

0.9(2B)

Cm-1

1(2B)

Cm-1

3394.113072.112818.422738.342372.89

2330.262235.792139.832026.521982.86

1911.141826.501701.691596.721454.12

1392.851308.721204.251166.911109.92

1073.381012.73922.40746.86

688.87650.60450.67

3392.133067.402818.442738.202367.01

2332.272236.382139.342027.081983.03

1910.171826.271702.001655.241595.90

1454.701392.101310.131204.121166.83

1108.541072.281012.18923.43

747.06688.70450.89

3396.113070.632818.502738.212373.11

2330.792235.762139.032027.291983.09

1911.421825.701701.381654.811596.48

1454.411392.531310.261204.341166.821109.801072.431012.95923.24746.91688.63450.96

3396.053069.412818.692738.462329.91

2138.941983.091911.551826.241703.53

1597.131453.991391.811308.281204.32

1168.771109.331073.801011.83925.28

825.98747.33690.05651.03451.19

3393.763067.492818.812738.322331.93

1982.811912.981825.181703.441595.99

1454.201391.371310.661204.911168.61

1109.981072.581015.10930.45826.77

747.39689.11650.24451.16

3393.993066.72

2981.95

2818.732738.47

2405.59

2329.512138.99

2027.34

1984.221911.03

1826.92

1703.871596.18

1454.61

1391.151310.20

1203.83

1168.191106.93

1073.17

1011.61928.64

747.78

689.19650.30

451.17

3399.053069.092983.472819.422738.971983.331705.871596.941453.551387.821309.351204.371170.931109.881012.35935.87826.54747.69691.22650.64451.50

3446.562984.112819.212738.641984.331703.561596.961454.301391.351311.011204.291169.241110.761073.331016.45933.56826.81747.32689.04650.21451.46

3446.413069.902984.672823.302736.412670.862558.191917.311698.201597.561451.421418.901288.321174.811124.971072.211024.29933.60821.56746.48706.48654.22547.54450.85

3450.462985.422668.132558.321916.641690.021419.421324.681289.261176.111126.201073.491025.96934.40805.24750.45707.39594.50547.41

3449.472987.292552.772370.902339.692098.221724.521453.621374.941289.161172.991024.90938.37752.00708.66593.27548.46


297

Fig-7.19: FTIR spectrums for Ethyl Acetate + Benzyl Chloride mixture:

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-1.pk

EA_BC-~4.SP 3601 4000.00 4 00.00 6.33 99.84 4.00 %T 5 1.00

REF 4000 75.33 2000 41.99 6003957.87 72.68 3776.13 59.06 3443.70 6.33 2990.70 33.10 2375.94 39.212106.73 40.14 1766.66 38.80 1607.16 27.22 1389.69 38.26 1243.16 26.831114.03 32.93 620.59 45.10

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3957.8 7

3776.13

344 3.70

2990.70237 5.94

210 6.731766.66

1607.16

13 89.69

1243.16

1 114.03

620.59

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-2.pk

EA_BC-~1.SP 3601 4000.00 4 00.00 6.35 99.94 4.00 %T 5 1.00

REF 4000 98.26 2000 61.61 6003964.11 93.33 3776.47 67.73 3437.83 6.35 2928.87 40.87 2115.59 58.761817.37 68.83 1723.04 57.79 1610.33 34.28 1379.47 44.37 1242.98 36.731118.19 31.32 697.37 35.99 620.03 43.80 559.44 49.88

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 964.11

3776.47

3437.83

2928 .87

2115.59

1817.37

1723.04

1610.33

13 79.47

1242.98

1118.19697.37

620.03

559.44

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-3.pk

EA_BC-~2.SP 3601 4000.00 4 00.00 8.83 100.00 4.00 %T 5 1.00

REF 4000 98.23 2000 95.06 6003918.91 96.12 3775.26 84.22 3451.07 10.0 9 3067.61 48.72 3034.19 45.502965.86 58.33 2340.59 92.81 2084.37 94.0 0 1957.48 89.45 1889.30 92.011763.12 55.78 1625.53 52.11 1492.95 67.4 8 1451.41 45.74 1381.27 62.421253.88 23.09 1107.37 60.80 1067.81 55.7 3 927.99 89.85 809.62 64.19760.92 51.5 2 695.67 8.82 559.29 50.52 467.04 68.36

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3918.91

3775.26

3451.07

3067.61

3034.19

2965.86

2340.59

2084.37

1957 .48

1 889.30

1763.12

1625.53

1492.95

1451.41

1381.27

1253.88

1107.37

1067.8 1

927.99

8 09.62

760.92

695.67

559.29

467.04

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-4.pk

EAE083~1.SP 3601 4000.00 4 00.00 7.15 100.00 4.00 %T 5 2.00

REF 4000 97.79 2000 53.46 6003921.12 94.46 3774.33 75.22 3436.06 23.0 1 3033.29 24.66 1956.79 47.841891.42 50.22 1761.67 27.52 1599.84 37.4 7 1450.39 27.33 1377.21 36.991249.46 8.69 1061.68 28.92 928.36 51.66 810.08 38.59 759.95 31.90695.28 7.15 559.59 40.30 466.15 57.44

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3921.12

3774.33

3436.06

3033.29

1956 .79

1891.42

1761.67

1599.84

1450.39

1377.21

1249.46

1061.68

928.36

8 10.08

759.95

695.28

559.59

466.15

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-5.pk

EAE883~1.SP 3601 4000.00 4 00.00 6.95 100.00 4.00 %T 5 2.00

REF 4000 98.98 2000 73.22 6003775.53 88.58 3433.62 55.25 3033.16 39.2 5 2961.40 51.44 1955.96 67.241889.21 69.55 1764.05 65.42 1598.56 60.0 1 1493.24 56.73 1451.21 38.771381.19 66.13 1264.45 25.83 1071.85 55.6 1 927.66 71.26 810.37 53.78761.09 45.5 0 694.94 6.95 559.24 54.20 465.43 72.70

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3775.5 3

3433.62

3033.16

2961.40

1955 .96

1889.21

17 64.05

1598.56

1493.24

1451.21

1381.19

1264.45

1071.85

927.66

810.37

761.09

694.94

559.24

465.43

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-6.pk

EAE093~1.SP 3601 4000.00 4 00.00 8.67 99.99 4.00 %T 5 2.00

REF 4000 98.18 2000 71.48 6003916.71 95.98 3776.62 84.25 3435.76 43.35 3033.47 37.84 2961.25 48.641956.21 65.29 1889.50 67.83 1811.99 69.25 1765.78 67.67 1598.42 55.261492.95 56.29 1451.06 39.15 1265.27 27.62 1072.82 53.03 1031.02 59.53927.48 67.8 8 810.22 50.27 760.92 42.27 695.62 8.67 559.42 51.00465.89 68.1 8

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3916 .71

3776.62

3435.76

3033.47

29 61.25

1956 .211 889.50

181 1.99

17 65.78

1598.42

1492.95

1451.06

1265.27

1072.82

1031.02

927.48

810.22

760.92

695.62

559.42

465.89

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-7.pk

EAE893~1.SP 3601 4000.00 4 00.00 7.45 99.99 4.00 %T 5 2.00

REF 4000 98.09 2000 60.09 6003774.70 84.76 3435.13 41.14 3034.24 36.80 2961.08 46.92 1956.43 55.841891.62 57.84 1814.22 59.48 1600.19 48.94 1493.15 50.68 1451.65 35.851266.03 26.31 1073.74 48.88 928.4 7 60.94 811.07 48.01 760.48 41.33694.87 7.45 558.97 47.51 4 66.13 65.92

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3774.7 0

3435.13

3034.24

2961 .08

1956.4 3

1891.62

181 4.22

1600.19

1493 .15

1451.65

126 6.03

1073.74

928.47

811.07

760.48

694.87

558.97

466.13

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-8.pk

EA_BC-~3.SP 3601 4000.00 4 00.00 7.32 99.99 4.00 %T 5 1.00

REF 4000 98.72 2000 81.52 6003908.14 96.36 3773.20 87.62 3446.99 35.66 3034.34 33.30 2961.58 45.872869.48 66.48 2709.24 78.12 2524.74 80.31 2338.23 75.23 1956.02 69.471889.76 73.30 1810.23 74.35 1761.76 74.92 1601.62 56.57 1493.38 55.111451.38 36.25 1265.76 25.95 1209.60 54.50 1161.44 58.88 1073.99 51.881029.68 60.99 927.24 70.66 809.95 48.15 758.79 38.23 695.21 7.31559.57 47.3 1 465.40 64.47

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3908.14

3773.20

344 6.993034.34

2961.58

2869.48

2709.24

2524.74

2 338.23

1956 .02

1889.76

1810.23

1761.76

1601.621493.38

1451.38

126 5.76

1209.60

1161.44

1073.9 9

1029.68

927.24

8 09.95

758.79

695.21

559.57

465.40

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-9.pk

EAE8A3~1.SP 3601 4000.00 400.00 7.31 10 0.00 4.00 %T 5 2.00

REF 4000 98.97 2000 71.06 6003773.85 87.59 3435.20 49.88 3033.88 34.3 2 2960.87 47.62 2868.79 63.952336.49 69.32 1956.00 63.59 1890.40 66.4 6 1811.93 67.89 1600.27 57.821493.61 53.47 1451.51 36.27 1266.47 26.2 2 1208.69 55.80 1073.76 54.701028.04 62.74 927.51 69.32 810.70 49.54 759.61 40.26 694.82 7.31559.42 51.0 3 465.61 70.35

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3773.85

3435.20

3033.88

2960.87

2868.79

2336.49

1956 .00

1 890.40

181 1.93 1600.27

149 3.61

1451.51

126 6.47

1208.69

1073.76

1028.04

927.51

810.70

759.61

694.82

559.42

465.61

FTIR SPECTRUM


Trichy-2

Spectrum Name: EA+BC-10.spDate: 2/14/2009

EA+BC-10.pk

EA9C8E~1.SP 3601 4000.00 400.00 7.68 100.00 4.00 %T 5 2.00

REF 4000 99.10 2000 73.01 6003773.89 89.40 3432.65 57.28 3033.50 43.83 2960.91 56.07 1955.94 68.061890.82 70.10 1812.72 71.44 1599.21 61.13 1493.40 59.52 1451.82 42.891265.93 31.38 1073.25 59.33 927.60 71.78 810.96 56.08 760.18 47.55695.01 7.68 559.62 58.26 466.26 75.75

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3773.89

3432.65

3033.50

2960.91

1955.94

1890.82

1812.72

1599.21

1493.40

1451.82

1265.93

1073.25

927.60

810.96

760.18

695.01

559.62

466.26

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/14/2009

EA+BC-11.pk

EA9C82~1.SP 3601 4000.00 400.00 7.08 99.91 4.00 %T 5 2.00

REF 4000 98.47 2000 59.62 6003906.50 94.80 3772.29 83.63 3435.57 39.14 3034.41 25.24 2960.75 35.212868.60 51.22 2708.50 60.11 2336.46 56.86 1956.03 48.63 1890.06 51.791811.47 53.04 1600.22 42.75 1493.17 41.14 1451.17 26.63 1266.87 19.471207.69 41.07 1074.43 41.36 1027.31 49.25 927.39 55.87 810.55 38.57759.02 31.1 1 694.99 7.08 5 59.37 42.03 465.12 60.85

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3906.50

3772.2 9

3435.57

3034.41

2960.75

2868.60

2708.50

2336.46

1956.03

1890.06

181 1.47

1 600.22

1493 .17

1451.17

126 6.87

1207 .69

1074.43

1027.31

927.39

810.55

759.02

694.99

559.37

465.12

Table - 7.20

Observations of FTIR spectrums for Ethyl Acetate + Benzyl Chloride mixture:

1 (EA)

Cm-1

0.9(EA)

+

0.1(BC)

Cm-1

0.8(EA)

+

0.2(BC)

Cm-1

0.7(EA)

+

0.3(BC)

Cm-1

0.6(EA)

+

0.4(BC)

Cm-1

0.5(EA)

+

0.5(BC)

Cm-1

0.4(EA)

+

0.6(BC)

Cm-1

*0.3(EA)

+

0.7(BC)

Cm-1

0.2(EA)

+

0.8(BC)

Cm-1

0.1(EA)

+

0.9(BC)

Cm-1

1(BC)

Cm-1

3957.873776.133443.702990.702375.94

2106.731766.661607.161389.691243.161114.03620.59

3964.113776.473437.832928.872115.591817.371723.041610.331379.471242.981118.19697.37620.03559.44

3918.913775.263451.073067.613034.192965.862340.592084.371957.481889.30

1763.121625.531492.951451.411381.271253.881107.371067.81927.99809.62760.92695.67559.29467.04

3921.123774.333436.063033.291956.791891.421761.671599.841450.391377.211249.461061.68928.36810.08759.95695.28559.59466.15

3775.533433.623033.162961.401955.961889.211764.051598.561493.241451.211381.191264.451071.85927.66810.37761.09694.94559.24465.43

3916.713776.623435.763033.472961.251956.211889.501811.991765.781598.421492.951451.061265.271072.821031.02927.48810.22760.92695.62559.42465.89

3774.703435.133034.242961.081956.431891.621814.221600.191493.151451.651266.031073.74928.47811.07760.48694.87558.97466.13

3908.14

3773.203446.99

3034.34

2961.582869.48

2709.24

2524.742338.23

1956.02

1889.761810.23

1761.76

1601.621493.38

1451.381265.76

1209.60

1161.441073.99

1029.68

927.24809.95

758.79

695.21559.57

465.40

3773.853435.203033.882960.872868.792336.491956.001890.401811.931600.271493.611451.511266.471208.691073.761028.04927.51810.70759.61694.82559.42465.61

3773.893432.653033.502960.911955.941890.821812.721599.211493.401451.821265.931073.25927.60810.96760.18695.01559.62466.26

3906.503772.293435.573034.412960.752868.602708.502336.461956.031890.061811.471600.221493.171451.171266.871207.691074.431027.31927.39810.55759.02694.99559.37465.12


298

Fig-7.20: FTIR spectrums for Ethyl Acetate + 2-Butanone mixture:

FTIR SPECTRUM


Trichy-2


Cl-AN-1.pk

Cl-AN-1.sp 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 99.39 2000 97.58 6003449.55 6.33 2991.58 69.36 2489.19 98.54 2362.08 89.00 2088.87 95.421763.76 32.63 1637.15 43.78 1378.64 67.05 1242.81 18.73 1056.51 55.12928.00 97.75 622.08 69.86

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3449.55

2991.58

2489.19

2362.08

2088.87

1763.76

1637.15

1378.64

1242.81

1056.51

928.00

622.08

FTIR SPECTRUM


Trichy-2


Cl-AN-2.pk

Cl-AN-2.sp 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 98.71 2000 96.65 6003449.85 6.33 2369.39 92.94 2089.05 94.90 1739.40 79.26 1637.90 39.821409.82 86.69 1244.60 78.23 1110.28 81.86 1049.78 78.70 574.78 61.81

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3449.85

2369.39

2089.05

1739.40

1637.90

1409.82

1244.60

1110.28

1049.78

574.78

FTIR SPECTRUM


Trichy-2


Cl-AN-3.pk

Cl-AN-3.sp 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 98.69 2000 96.73 6003450.45 6.33 2990.51 56.61 2488.21 97.59 2365.16 92.03 2089.01 94.121762.32 21.07 1637.33 43.39 1376.73 53.59 1242.82 11.07 1164.40 84.671056.35 45.12 931.02 94.74 623.89 63.96

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3450.45

2990.51

2488.21

2365.162089.01

1762.32

1637.33

1376.73

1242.82

1164.40

1056.35

931.02

623.89

FTIR SPECTRUM


Trichy-2


Cl-AN-4.pk

Cl-AN-4.sp 3601 4000.00 400.00 6.34 99.75 4.00 %T 5 1.00

REF 4000 97.57 2000 95.86 6003755.77 94.19 3450.69 6.34 2990.49 54.27 2489.94 96.40 2375.18 94.862090.50 93.31 1761.48 19.31 1637.41 42.15 1375.96 51.98 1242.79 10.201165.69 79.36 1056.63 45.21 932.09 93.90 622.77 66.13

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3755.77

3450.69

2990.49

2489.94

2375.18

2090.50

1761.48

1637.41

1375.96

1242.79

1165.69

1056.63

932.09

622.77

FTIR SPECTRUM


Trichy-2


Cl-AN-5.pk

Cl-AN-5.sp 3601 4000.00 400.00 6.34 99.61 4.00 %T 5 1.00

REF 4000 95.93 2000 94.61 6003778.13 93.82 3447.05 6.34 2928.83 84.16 2376.34 93.57 2093.87 93.591636.17 39.47 1418.32 81.88 1245.49 93.11 1113.89 76.66 1021.27 78.67577.76 63.78

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3778.13

3447.05

2928.832376.34

2093.87

1636.17

1418.32

1245.49

1113.89

1021.27

577.76

FTIR SPECTRUM


Trichy-2


Cl-AN-6.pk

Cl-AN-6.sp 3601 4000.00 400.00 6.34 99.58 4.00 %T 5 1.00

REF 4000 95.44 2000 93.34 6003768.93 89.15 3450.23 6.34 2990.28 63.10 2378.86 93.82 2091.95 91.681757.15 41.96 1637.35 45.43 1373.67 65.02 1242.87 35.39 1168.70 78.441056.34 65.29 935.24 93.23 595.26 64.81

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3768.93

3450.23

2990.28

2378.86

2091.95

1757.15

1637.35

1373.67

1242.87

1168.70

1056.34

935.24

595.26

FTIR SPECTRUM


Trichy-2


Cl-AN-7.pk

Cl-AN-7.sp 3601 4000.00 400.00 6.32 99.45 4.00 %T 5 1.00

REF 4000 97.51 2000 95.13 6003775.07 92.31 3448.38 6.32 2989.86 58.27 2370.49 92.46 2092.69 93.041757.83 34.82 1635.10 45.07 1373.15 58.91 1242.82 26.44 1164.26 68.311109.66 66.78 1056.57 56.70 1005.30 75.18 938.26 92.74 594.26 65.12

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3775.07

3448.38

2989.86

2370.49

2092.69

1757.83

1635.10

1373.15

1242.82

1164.26

1109.66

1056.57

1005.30

938.26

594.26

FTIR SPECTRUM


Trichy-2


Cl-AN-8.pk

Cl-AN-8.sp 3601 4000.00 400.00 6.34 100.00 4.00 %T 5 1.00

REF 4000 80.85 2000 77.99 6003765.76 75.87 3448.32 6.34 2988.64 56.76 2368.72 74.98 2094.28 76.581746.98 48.38 1635.26 38.45 1370.94 57.05 1242.92 49.25 1114.23 57.80595.48 52.73

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3765.76

3448.32

2988.64

2368.722094.28

1746.98

1635.26

1370.94

1242.92

1114.23

595.48

FTIR SPECTRUM


Trichy-2


Cl-AN-9.pk

Cl-AN-9.sp 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 71.37 2000 68.30 6003906.73 69.57 3769.93 61.87 3449.06 6.33 2375.62 65.34 2089.51 67.561636.11 34.39 1405.90 57.02 1243.50 56.03 1116.30 44.72 1008.25 47.96670.17 42.17

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3906.73

3769.93

3449.06

2375.62

2089.51

1636.11

1405.90

1243.50

1116.30

1008.25

670.17

FTIR SPECTRUM


Trichy-2


Cl-AN-10.pk

Cl-AN-10.sp 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

REF 4000 84.49 2000 80.62 6003920.45 83.10 3772.35 71.56 3449.47 6.33 2988.97 43.60 2380.41 82.932104.31 79.26 1740.66 29.75 1628.07 38.07 1367.68 44.01 1243.00 53.091167.31 42.59 1008.88 58.20 586.32 53.29

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3920.45

3772.35

3449.47

2988.97

2380.41

2104.31

1740.66

1628.071367.68

1243.00

1167.31

1008.88

586.32

FTIR SPECTRUM


Trichy-2


Cl-AN-11.pk

Cl-AN-11.sp 3601 4000.00 400.00 6.34 99.17 4.00 %T 5 1.00

REF 4000 88.37 2000 83.26 6003921.99 87.11 3778.25 73.94 3445.42 6.34 2930.86 71.20 2087.47 82.531815.01 86.05 1626.89 35.54 1409.75 68.12 1247.00 74.30 1117.88 55.351011.07 61.13 563.25 53.03

4 00 0 .0 3 0 00 20 00 1 50 0 1 0 00 4 00 .0

0. 0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0. 0

c m -1

% T

3921.99

3778.25

3445.42

2930.86

2087.471815.01

1626.89

1409.75

1247.00

1117.88

1011.07

563.25

Table - 7.21

Observations of FTIR spectrums for Ethyl Acetate + 2-Butanone mixture:

1 (EA)

Cm-1

0.9(EA)

+

0.1(2B)

Cm-1

0.8(EA)

+

0.2(2B)

Cm-1

*0.7(EA)

+

0.3(2B)

Cm-1

0.6(EA)

+

0.4(2B)

Cm-1

0.5(EA)

+

0.5(2B)

Cm-1

0.4(EA)

+

0.6(2B)

Cm-1

0.3(EA)

+

0.7(2B)

Cm-1

0.2(EA)

+

0.8(2B)

Cm-1

0.1(EA)

+

0.9(2B)

Cm-1

1(2B)

Cm-1

3449.552991.582489.192362.082088.871763.761637.151378.641242.811056.51928.00622.08

3449.852369.392089.051739.401637.901409.821244.601110.281049.78574.78

3450.452990.512488.212365.162089.011762.321637.331376.731242.821164.401056.35931.02623.89

3755.77

3450.69

2990.492489.94

2375.182090.50

1761.48

1637.411375.96

1242.79

1165.691056.63

932.09

622.77

3778.133447.052928.832376.342093.871636.171418.321245.491113.891021.27577.76

3768.933450.232990.282378.862091.951757.151637.351373.671242.871168.701056.34935.24595.26

3775.073448.382989.862370.492092.691757.831635.101373.151242.821164.261109.661056.571005.30938.26594.26

3765.763448.322988.642368.722094.281746.981635.261370.941242.921114.23595.48

3906.733769.933449.062375.622089.511636.111405.901243.501116.301008.25670.17

3920.453772.353449.472988.972380.412104.311740.661628.071367.681243.001167.311008.88586.32

3921.993778.253445.422930.862087.471815.011626.891409.751247.001117.881011.07563.25


299

For Ternary mixtures:

Fig-7.21: FTIR spectrums for Cyclohexanone + Hexane + Heptane mixture:

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/22/2008

Sample-4.pk

Sample-4.sp 3601 4000.00 400.00 8.43 99.99 4.00 %T 3 1.00

REF 4000 97.81 2000 97.05 6003948.52 96.28 3412.01 53.26 2940.39 10.75 2866.33 25.76 2670.59 90.982358.73 89.51 2176.94 95.31 2064.94 95.22 1970.70 96.02 1805.14 87.081712.63 8.42 1444.01 44.13 1314.03 50.51 1223.01 48.26 1119.24 54.461055.45 76.87 1018.64 82.56 904.24 73.85 865.83 83.54 750.64 73.63652.99 85.58 491.29 65.88 413.75 88.37

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3 948.52

341 2.01

2 940 .39

2 866.3 3

267 0.59235 8.73

2 176.94

206 4.94

1970 .70 180 5.14

171 2.63

144 4.01

131 4.03122 3.01

11 19.24

1 055.4 5

101 8.64

904.24

865 .83

7 50.6 4

65 2.99

491 .29

413.75

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/22/2008

Sample-5.pk

Sample-5.sp 3601 4000.00 400.00 7.51 99.99 4.00 %T 3 1.00

REF 4000 89.33 2000 89.05 6003450.59 50.34 2940.26 18.84 2865.14 40.07 2671.90 83.52 2361.71 84.491711.12 7.51 1448.81 57.57 1424.79 58.06 1342.88 65.22 1312.32 59.701223.71 51.56 1120.51 62.07 1055.88 78.51 1019.51 83.30 905.11 78.16864.80 81.87 750.96 77.67 653.03 81.80 492.28 73.35 415.92 88.32

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

34 50.5 9

2 940 .26

286 5.14

267 1.90

236 1.71

171 1.12

1 448.8114 24.7 9

1 342.88

1 312 .32

122 3.71

11 20.51

1 055.8 8

1019 .51

905.11

864 .80

7 50.9 6

65 3.03

492 .28

415.92

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/22/2008

Sample-6.pk

Sample-6.sp 3601 4000.00 400.00 8.16 100.00 4.00 %T 3 1.00

REF 4000 98.34 2000 97.70 6003442.33 45.68 2940.88 20.63 2865.82 45.24 2671.60 91.76 2361.63 88.892065.75 96.95 1711.15 8.16 1447.85 62.93 1423.73 62.87 1342.76 71.441312.31 65.86 1223.74 56.24 1120.90 68.06 1056.75 85.28 905.36 86.07864.52 89.04 750.64 83.29 653.46 85.64 492.38 78.87 413.67 91.62

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3442 .33

2 940 .88

2865 .82

267 1.60236 1.63

206 5.75

171 1.15

144 7.85

142 3.73

1342 .76

1 312 .31

122 3.74

11 20.90

1056 .75905.36

8 64.5 2

7 50.6 4

65 3.46

492 .38

41 3.67

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/7/2008

Sample-7.pk

Sample-7.sp 3601 4000.00 400.00 6.31 100.00 4.00 %T 3 1.00

REF 4000 98.57 2000 96.09 6003441.89 6.31 2939.73 9.03 2869.57 29.76 2672.73 96.06 2365.72 75.702066.40 93.81 1712.17 11.88 1640.67 34.38 1452.34 52.22 1391.42 45.201343.39 69.50 1312.96 64.65 1222.31 62.45 1119.43 54.53 1054.19 81.731019.48 83.58 904.99 84.68 863.28 85.64 749.44 64.07 653.81 64.34491.58 68.63 415.62 90.49

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

344 1.89 2 939 .73

286 9.57

267 2.73

236 5.72

206 6.40

171 2.17

1640 .67

14 52.3 4

1391 .42

13 43.3 9

1 312 .96122 2.31

11 19.43

10 54.19

1 019.4 8

9 04.9 9

86 3.28

7 49.4 4

6 53.8 1

491 .58

415 .62

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/7/2008

Sample-8.pk

Sample-8.sp 3601 4000.00 400.00 6.33 100.00 4.00 %T 3 1.00

REF 4000 98.44 2000 95.39 6003442.72 6.33 2941.82 18.80 2868.13 47.92 2673.01 97.10 2364.26 90.052090.47 93.00 1712.69 20.22 1641.05 32.36 1451.04 59.40 1392.30 43.591343.77 73.70 1313.47 71.61 1221.45 69.57 1119.64 58.89 1020.47 83.48903.21 88.46 748.07 62.12 653.88 59.49 605.29 60.18 492.92 67.40

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3442 .72

2 941 .82

2868 .13

267 3.01

236 4.26209 0.47

171 2.69

1 641.05

1 451 .04

13 92.30

1343 .77

1313 .47

122 1.45

11 19.64

102 0.47

903.21

7 48.0 7

65 3.88

605.2 9

492 .92

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/7/2008

Sample-9.pk

Sample-9.sp 3601 4000.00 400.00 6.32 99.99 4.00 %T 3 0.75

REF 4000 98.59 2000 90.95 6003863.90 83.44 3747.72 73.42 3442.93 6.32 2939.48 65.43 2868.94 83.442523.97 97.04 2358.57 30.87 2032.01 90.24 1640.01 28.38 1395.51 41.161117.96 63.95 1031.16 80.53 671.08 54.50 434.46 85.53

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3863 .90

374 7.72

3442 .93

293 9.48

286 8.94

2 523.9 7

235 8.57

2032 .01

164 0.01

1395 .51

11 17.96

1 031.1 6

6 71.08

43 4.46

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Sampe-10.sp

Date: 2/23/2008

Sampe-10.pk

Sampe-10.sp 3601 4000.00 400.00 9.14 100.00 4.00 %T 3 1.00

REF 4000 98.76 2000 98.22 6003414.02 55.34 2940.30 18.24 2865.13 41.11 2671.13 95.49 2372.20 96.522064.24 97.11 1804.81 92.90 1712.58 9.13 1448.16 60.75 1340.50 72.241312.45 64.60 1222.36 61.11 1119.03 65.78 1054.35 85.44 1018.20 89.60905.32 84.05 864.51 89.53 750.17 81.53 652.59 89.35 490.57 77.45411.88 94.22

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T 341 4.02

2 940 .30

2865 .13

267 1.13

237 2.20

206 4.24

180 4.81

171 2.58

1 448.16

1 340 .50

1 312 .45

122 2.36

11 19.03

10 54.35

10 18.2 0

905.32

8 64.5 1

7 50.1 7

65 2.59

4 90.57

41 1.88

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/23/2008

Sampe-11.pk

Sampe-11.sp 3601 4000.00 400.00 8.37 100.00 4.00 %T 3 1.00

REF 4000 97.87 2000 97.50 6003948.18 96.47 3504.58 61.49 3410.73 59.93 2940.43 10.32 2866.70 24.622670.73 89.76 2367.36 95.65 2177.18 95.74 2064.69 95.68 1969.33 96.151805.00 86.01 1712.76 8.37 1444.68 42.73 1314.10 49.22 1223.00 47.131119.22 53.82 1055.68 75.35 1018.52 82.15 904.12 72.30 865.95 82.42750.67 73.30 652.49 87.11 491.15 65.74 413.69 88.21

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

394 8.18

3 504.58341 0.73

2 940 .43

286 6.70

267 0.73

23 67.3 6

21 77.1 8

2 064 .69

1969 .33

18 05.0 0

171 2.76

144 4.68

1 314.10

122 3.00

11 19.22

105 5.68

1018 .52

904.12

865.9 5

7 50.6 7

65 2.49

491 .15

41 3.69

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/23/2008

Sampe-12.pk

Sampe-12.sp 3601 4000.00 400.00 9.52 100.00 4.00 %T 3 1.00

REF 4000 98.57 2000 98.17 6003413.01 60.31 2940.32 13.51 2866.06 34.75 2670.70 94.38 2374.29 97.232064.95 97.04 1712.75 9.51 1444.79 54.55 1313.65 60.42 1222.75 57.801119.19 63.29 1055.53 83.40 1018.69 88.13 904.49 81.31 865.64 88.62750.51 80.45 652.53 89.76 490.97 74.44 413.59 92.15

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

341 3.01

2 940 .32

286 6.06

267 0.70

2374 .29 206 4.95

171 2.75

144 4.79

1 313.65

122 2.75

11 19.19

1055 .53

10 18.6 9

904.49

865.6 4

7 50.5 1

65 2.53

490 .97

413.5 9

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/23/2008

Sampe-13.pk

Sampe-13.sp 3601 4000.00 400.00 6.69 100.00 4.00 %T 3 1.00

REF 4000 97.77 2000 97.28 6003948.09 96.54 3412.46 53.01 2941.43 6.69 2868.71 18.07 2670.38 89.882373.36 96.19 2177.26 95.57 2065.52 95.54 1967.86 96.11 1713.21 9.161445.60 37.56 1315.50 47.19 1222.95 45.81 1119.25 52.62 1055.31 75.421018.34 81.83 904.74 72.45 866.04 82.66 750.44 72.47 652.48 86.55491.16 64.59 414.46 89.22

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

394 8.09

341 2.46

294 1.43

286 8.71

2 670.3 8

23 73.36

21 77.2 6

206 5.52

19 67.86

171 3.21

144 5.60

131 5.50

122 2.95

1119 .25

105 5.31

101 8.34

904.74

866.04

7 50.4 4

65 2.48

491 .16

4 14.46

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/23/2008

Sampe-14.pk

Sampe-14.sp 3601 4000.00 400.00 7.36 122.21 4.00 %T 3 1.00

REF 4000 99.77 2000 99.52 6003949.58 98.65 3409.40 64.26 2939.12 11.66 2864.65 25.52 2672.12 92.472372.19 98.36 2176.22 97.75 2063.26 97.62 1973.10 98.24 1871.50 97.621806.01 88.79 1712.02 7.36 1640.05 73.02 1450.02 45.33 1426.32 47.611342.36 56.84 1312.57 47.97 1222.64 44.62 1119.21 50.78 1054.78 77.581018.16 83.48 993.17 91.83 903.80 72.93 865.37 83.49 750.88 73.12652.44 88.31 490.97 65.00 414.93 95.54

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

39 49.58

340 9.40

2 939 .12

2 864 .65

26 72.12

23 72.1 9

2 176.2 2

2 063 .26

19 73.10

187 1.50

18 06.01

17 12.02

16 40.0 5

145 0.02

142 6.32

13 42.36

131 2.57

122 2.64

11 19.21

105 4.78

10 18.1 6

993.17

90 3.80

865.3 7

750 .88

65 2.44

490 .97

4 14.9 3

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/25/2008

Sampe-15.pk

Sampe-15.sp 3601 4000.00 400.00 6.32 98.54 4.00 %T 3 1.00

REF 4000 96.58 2000 93.48 6003446.36 6.32 2944.18 43.11 2869.37 70.48 2374.64 89.18 2339.07 96.152091.08 91.47 1729.51 46.84 1638.31 38.77 1395.95 53.30 1220.65 83.911119.83 72.02 655.54 68.70 607.17 68.84

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3446 .36

294 4.18

2 869.3 7

2374 .64

233 9.07

209 1.08

1729 .51

163 8.31

1395 .95

122 0.65

11 19.83655.54

6 07.17

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/25/2008

Sampe-16.pk

Sampe-16.sp 3601 4000.00 400.00 8.23 99.99 4.00 %T 3 1.00

REF 4000 98.14 2000 96.53 6003446.62 25.03 2940.72 11.02 2866.24 30.81 2671.76 94.24 2370.23 93.792064.97 94.76 1805.50 91.51 1712.77 8.23 1640.21 56.95 1448.99 53.161340.74 67.49 1312.77 59.26 1222.54 56.10 1119.22 59.55 1054.59 83.121018.35 87.30 905.53 80.81 864.51 86.78 750.10 73.72 653.11 80.94491.05 70.52 412.58 91.48

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3446 .62

2 940 .72

286 6.24

26 71.7 6237 0.23

206 4.97

180 5.50

171 2.77

1640 .21

1 448.99

134 0.74

13 12.77

122 2.54

1 119.2 2

1054 .59

10 18.3 5

905.53

864.5 1

7 50.1 0

65 3.11

491 .05

41 2.58

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/25/2008

Sampe-17.pk

Sampe-17.sp 3601 4000.00 400.00 8.36 99.99 4.00 %T 3 1.00

REF 4000 98.05 2000 96.57 6003448.44 30.41 2940.75 11.92 2865.85 30.47 2671.58 93.57 2371.71 94.612064.97 94.70 1805.42 90.22 1712.81 8.36 1640.65 58.52 1448.87 51.861340.61 65.88 1312.81 58.10 1222.55 55.22 1119.23 58.70 1054.60 81.981018.35 86.35 905.39 79.69 864.59 86.16 750.19 73.89 652.84 82.13491.06 70.37 412.47 91.06

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

34 48.4 4

2 940 .75

2865 .85

26 71.5 8

23 71.71

206 4.97

1805 .42

171 2.81

16 40.6 5

1 448.87

134 0.61

131 2.81

122 2.55

1119 .23

1054 .60

101 8.35

905.39

8 64.5 9

7 50.1 9

65 2.84

491 .06

41 2.47

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/25/2008

Sampe-18.pk

Sampe-18.sp 3601 4000.00 400.00 7.09 99.99 4.00 %T 3 1.00

REF 4000 97.14 2000 95.36 6003419.75 19.72 2940.96 7.09 2867.03 19.94 2671.50 91.03 2367.48 92.872175.74 93.52 2064.36 92.94 1872.02 95.53 1805.71 86.63 1712.82 7.601640.37 49.06 1449.22 40.00 1340.61 55.36 1312.93 47.27 1222.64 44.461119.27 48.31 1054.66 75.30 1018.27 81.08 905.36 71.88 864.70 80.70750.24 64.94 652.80 75.90 491.14 60.74 412.60 86.69

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3 419.7 5

29 40.96

2 867.0 3

267 1.50

23 67.4 8

217 5.74

2064 .36

18 72.0 2

18 05.7 1

171 2.82

164 0.37

1 449.22

134 0.61

1 312 .93

122 2.64

11 19.27

10 54.66

1 018.2 7

905.36

864 .70

7 50.2 4

65 2.80

491 .14

41 2.60

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/25/2008

Sampe-19.pk

Sampe-19.sp 3601 4000.00 400.00 6.31 100.00 4.00 %T 3 1.00

REF 4000 99.44 2000 95.37 6003446.24 6.31 2942.83 46.68 2866.55 72.01 2368.87 92.69 2338.38 94.692092.08 93.00 1713.43 41.53 1637.62 39.94 1393.69 62.24 1313.92 87.781221.54 86.97 1119.83 78.32 655.37 66.55 606.71 67.27

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

34 46.2 4

2 942 .83

2866 .55

2368 .87

233 8.38

209 2.08

1 713.4 3

1 637.6 2

13 93.69

131 3.92

122 1.54

11 19.83

655 .37

60 6.71

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: Sample - 20.sp

Date: 2/26/2008

Sample - 20.pk

SAMPLE~1.SP 3601 4000.00 400.00 8.14 100.00 4.00 %T 3 1.00

REF 4000 98.31 2000 97.63 6003413.73 45.12 2941.40 9.61 2866.64 26.54 2671.62 92.71 2366.84 91.322176.60 96.16 2064.13 95.95 1805.04 89.03 1712.84 8.14 1448.98 47.801340.50 62.59 1312.82 54.79 1222.47 51.64 1119.14 55.97 1054.55 79.091018.18 83.77 905.33 77.80 864.84 85.98 750.27 75.45 652.96 85.92490.61 70.35 412.37 91.63

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

341 3.73

2 941 .40

2 866.6 4

267 1.62

236 6.84

217 6.602 064.1 3

180 5.04

171 2.84

1 448.98

1 340 .50

1 312 .82

122 2.47

11 19.14

1 054.5 5

1018 .18

905.33

864.8 4

7 50.2 7

65 2.96

4 90.61

412 .37

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/26/2008

Sample - 21.pk

SAMPLE~2.SP 3601 4000.00 400.00 10.45 100.00 4.00 %T 3 1.00

REF 4000 98.37 2000 97.82 6003415.79 56.60 2941.10 15.37 2866.57 38.37 2671.24 94.81 2365.10 90.642065.56 96.84 1713.15 10.45 1446.46 57.79 1313.60 64.76 1222.53 61.981119.14 65.87 1055.33 84.60 1018.94 88.03 904.65 84.59 865.59 90.60750.22 83.08 653.21 89.81 490.70 78.81 414.08 93.47

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T3 415.7 9

2 941 .10

2866 .57

267 1.24

2 365.1 0

206 5.56

171 3.15

144 6.46

131 3.60

122 2.53

11 19.14

1 055.3 3

1 018.9 4

904.65

865 .59

7 50.2 2

6 53.2 1

4 90.70

41 4.08

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/26/2008

Sample - 22.pk

SAMPLE~3.SP 3601 4000.00 400.00 8.75 99.99 4.00 %T 3 1.00

REF 4000 98.88 2000 97.75 6003440.92 37.68 2941.24 12.54 2867.48 37.03 2672.32 96.11 2364.43 87.692065.06 96.52 1712.94 8.75 1641.75 65.66 1450.06 59.71 1341.00 74.641312.69 67.93 1222.22 64.77 1119.03 66.45 1054.45 86.20 1018.43 88.88905.50 86.73 864.45 91.49 749.74 81.51 653.48 86.39 490.25 78.54412.55 94.72

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3440 .92

2 941 .24

2 867.4 8

267 2.32

236 4.43

206 5.06

171 2.94

164 1.75

1 450.06

134 1.00

1 312 .69

122 2.2211 19.03

1 054.4 5

1018 .43

905.50

8 64.45

7 49.7 4

653.48

4 90.25

4 12.55

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/26/2008

Sample - 23.pk

SAMPLE~4.SP 3601 4000.00 400.00 6.54 99.99 4.00 %T 3 1.00

REF 4000 98.57 2000 97.54 6003417.65 41.11 2942.07 6.54 2868.82 21.84 2670.86 93.30 2361.85 91.552065.34 95.79 1713.40 9.59 1450.30 46.71 1313.77 58.65 1222.69 56.521119.23 61.18 1055.54 81.95 1018.48 86.45 904.44 79.76 865.50 87.34750.10 76.50 652.96 85.87 490.97 72.99 413.74 92.27

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3 417.6 5

29 42.07

286 8.82

267 0.86

236 1.85

206 5.34

1 713 .40

1 450.30

1 313.77

122 2.69

1119 .23

1 055.5 4

10 18.48

904.44

865.50

7 50.1 0

65 2.96

490 .97

413 .74

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/26/2008

Sample - 24.pk

SA811D~1.SP 3601 4000.00 400.00 6.32 99.19 4.00 %T 3 1.00

REF 4000 99.08 2000 95.08 6003445.53 6.32 2957.50 54.14 2872.16 76.64 2363.45 78.10 2098.33 92.541640.38 38.12 1458.96 81.51 1394.13 60.12 1204.44 95.36 1120.39 83.84659.33 66.76

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3445 .53

2 957.50

28 72.16 236 3.45

2098 .33

164 0.38

1 458.9 6

13 94.13

1 204.4 4

11 20.39

659 .33

FTIR SPECTRUM

ACIC


Trichy-2


Date: 2/26/2008

Sample - 25.pk

SA891D~1.SP 3601 4000.00 400.00 6.33 97.92 4.00 %T 3 1.00

REF 4000 97.77 2000 89.50 6003444.36 6.33 2953.79 30.89 2869.35 57.50 2363.45 60.82 2096.38 87.521716.72 41.97 1640.64 30.08 1458.33 62.18 1393.87 44.66 1219.78 85.181120.41 70.91 659.07 63.85

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3444 .36

295 3.79

2869 .35

236 3.45

20 96.3 8

1716 .72

164 0.64

1 458.3 3

13 93.87

121 9.78

11 20.41

659 .07

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/7/2008

Sample-26.pk

SA2D8C~1.SP 3601 4000.00 400.00 6.35 100.00 4.00 %T 3 0.75

REF 4000 99.42 2000 93.97 6003441.76 6.35 2945.05 61.75 2872.26 83.30 2371.91 84.56 2098.52 91.841639.62 31.53 1393.90 44.28 1120.49 70.26 1026.18 86.89 606.22 59.70

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3441 .76

29 45.05

2872 .26

23 71.9 1

2098 .52

163 9.62

13 93.90

11 20.49

1 026.1 8

606 .22

FTIR SPECTRUM

ACIC


Trichy-2


Date: 3/7/2008

Sample-27.pk

SA259C~1.SP 3601 4000.00 400.00 6.34 97.60 4.00 %T 3 0.75

REF 4000 97.44 2000 94.76 6003821.18 80.17 3741.43 68.94 3444.92 6.34 2948.94 7.74 2877.21 33.662677.47 96.56 2522.83 96.67 2371.03 81.33 2095.76 92.35 1733.70 21.411638.29 26.84 1456.34 50.65 1393.11 37.05 1220.73 72.88 1120.06 55.45745.19 70.36 656.97 66.47 603.82 65.82

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

c m-1

%T

3821 .18

37 41.4 3

3444 .92 294 8.94

287 7.21

26 77.47

252 2.83

23 71.0 3

20 95.7 6

173 3.70

163 8.29

145 6.34

13 93.11

122 0.73

11 20.06

745 .19

656 .97

603.8 2

Table - 7.22

Observations of FTIR spectrums for

Cyclohexanone + Hexane + Heptane mixture

S1

(Cm-1

)

S2

(Cm-1

)

S3

(Cm-1

)

S4

(Cm-1

)

S5

(Cm-1

)

S6

(Cm-1

)

S7

(Cm-1

)

*S8

(Cm-1

)

3948.523412.012940.392866.332670.592358.732176.942064.941970.701805.141712.631444.011314.031223.011119.241055.451018.64904.24865.83750.64652.99491.29413.75

3450.592940.262865.142671.902361.711711.121448.811424.791342.881312.321223.711120.511055.881019.51905.11864.80750.96653.03492.28415.92

3442.332940.882865.822671.602361.632065.751711.151447.851423.731342.761312.311223.741120.901056.75905.36864.52750.64653.46492.38413.67

3441.892939.732869.572672.732365.722066.401712.171640.671452.341391.421343.391312.961222.311119.431054.191019.48904.99863.28749.44653.81491.58415.62

3442.722941.822868.132673.012364.262090.471712.691641.051451.041392.301343.771313.471221.451119.641020.47903.21748.07653.88605.29492.92

3863.903747.723442.932939.482868.942523.972358.572032.011640.011395.511117.961031.16671.08434.46

3414.022940.302865.132671.132372.20

2064.241804.811712.581448.161340.50

1312.451222.361119.031054.351018.20905.32864.51750.17652.59490.57411.88

3948.183504.58

3410.73

2940.43

2866.70

2670.73

2367.362177.18

2064.69

1969.33

1805.00

1712.761444.68

1314.10

1223.00

1119.22

1055.68

1018.52904.12

865.95

750.67

652.49

491.15

413.69


300

S9

(Cm-1)

S10

(Cm-1)

*S11

(Cm-1

)

S12

(Cm-1)

S13

(Cm-1)

S14

(Cm-1)

S15

(Cm-1)

S16

(Cm-1)

3413.012940.322866.062670.702374.292064.951712.751444.791313.651222.751119.191055.531018.69904.49865.64750.51652.53490.97413.59

3948.093412.462941.432868.712670.382373.362177.262065.521967.861713.211445.601315.501222.951119.251055.311018.34904.74866.04750.44652.48491.16414.46

3949.58

2939.12

2864.65

2672.12

2372.19

2176.22

2063.26

1973.10

1871.50

1806.01

1712.02

1640.05

1450.02

1426.32

1342.36

1312.57

1119.21

1054.78

1018.16

993.17

903.80

865.37

750.88

652.44

490.97

414.93

3446.362944.182869.372374.642339.072091.081729.511638.311395.951220.651119.83655.54607.17

3446.622940.722866.242671.762370.232064.971805.501712.771640.211448.991340.741312.771222.541119.221054.591018.35905.53864.51750.10653.11491.05412.58

3448.442940.752865.852671.582371.712064.971805.421712.811640.651448.871340.611312.811222.551119.231054.601018.35905.39864.59750.19652.84491.06412.47

3419.752940.962867.032671.502367.482175.742064.361872.021805.711712.821640.371449.221340.611312.931222.641119.271054.661018.27905.36864.70750.24652.80491.14412.60

3446.242942.832866.552368.872338.38

2092.081713.431637.621393.691313.921221.541119.83655.37606.71

S17

(Cm-1)

S18

(Cm-1)

S19

(Cm-1)

S20

(Cm-1)

S21

(Cm-1)

S22

(Cm-1)

S23

(Cm-1)

S24

(Cm-1)

3413.732941.402866.642671.622366.842176.602064.131805.041712.841448.981340.501312.821222.471119.141054.551018.18905.33864.84750.27652.96490.61412.37

3415.792941.102866.572671.242365.102065.561713.151446.461313.601222.531119.141055.331018.94904.65865.59750.22653.21490.70414.08

3440.922941.242867.482672.322364.432065.061712.941641.751450.061341.001312.691222.221119.031054.451018.43905.50864.45749.74653.48490.25412.55

3417.652942.072868.822670.862361.852065.341713.401450.301313.771222.691119.231055.541018.48904.44865.50750.10652.96490.97413.74

3445.532957.502872.162363.452098.331640.381458.961394.131204.441120.39659.33

3444.362953.792869.352363.452096.381716.721640.641458.331393.871219.781120.41659.07

3441.762945.052872.262371.912098.521639.621393.901120.491026.18606.22

3821.183741.433444.922948.942877.212677.472522.832371.032095.761733.701638.291456.341393.111220.731120.06745.19656.97603.82


301

Fig-7.22: FTIR Spectrums for Cyclohexanone+Hexane+Benzaldehyde mixture:

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-PH-R-1.s p

Date: 08-2-2010

SJC-PH-R-1.pk

SJC-PH~1.SP 3601 4000.00 400.00 6.26 99.99 4.00 %T 5 1.00

REF 4 000 98.25 2000 96.06 6003938.94 97.04 3411.73 52.70 2940.35 9.74 2864.51 26.53 2719.87 91.572673.85 92.26 2062.95 95.42 1712.31 6.25 1595.53 21.53 1448.45 43.121356.25 31.74 1313.77 46.95 1222.96 48.18 1119.02 57.28 1055.22 80.451018.31 84.36 905.31 78 .16 864.41 85.62 753.33 74.15 651.39 85.70490.92 70 .17 412.11 91.67

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3938.94

3411.73

294 0.35

2864.51

2719.87

2673.852062.95

1712.31

1595.53

1448.45

1356.25

131 3.77

1222.96

111 9.02

1055.22

1018.31

905.31

864.4 1

753.33

65 1.39

4 90.92

4 12.11

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-R-2.pk

SJC-PH~2.SP 3601 4000.00 400.00 6.50 100.00 4.00 %T 5 1.00

REF 4 000 97.37 2000 95.11 6003941.40 95.43 3447.65 2 5.12 3068.38 36.53 2942.05 8.93 2865.86 18.472677.62 67.45 2177.10 9 5.51 2062.83 94.36 1709.72 6.50 1610.93 14.981449.22 34.37 1355.77 2 1.05 1314.39 34.71 1228.24 27.77 1173.10 52.261118.35 47.06 1061.64 6 6.75 1020.84 78.21 905.35 74.45 863.92 79.36771.73 62 .88 716.00 57.27 650.00 69.13 4 93.86 65.76 412.85 87.29

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

394 1.40

3447.65

3068.38

294 2.05

2865.8 6

26 77.62

2177.10

20 62.83

1709.72

1610.93

1449.22

1355.77

1314.39

1 228.24

1173.10

111 8.35

1061.64

1020.84

905.35

863 .92

771.73

716.0 0

6 50.00

4 93.86

412.8 5

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-R-3.pk

SJC-PH~3.SP 3601 4000.00 400.00 6.49 100.00 4.00 %T 5 1.00

REF 4 000 77.21 2000 72.09 6003942.53 75.80 3415.15 1 7.93 3068.64 16.61 2942.12 6.49 2867.10 11.752652.26 36.82 1919.88 6 8.40 1712.22 7.33 1599.12 18.08 1449.82 23.071420.51 23.96 1351.29 2 1.79 1313.28 20.81 1231.91 15.33 1173.76 26.821117.20 27.85 1066.08 3 9.55 1022.50 47.21 905.78 45.87 863.94 49.16778.24 42 .28 751.20 41.13 715.50 28.18 6 50.71 41.57 496.88 49.73418.93 76 .12

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3942.53

3415.15

3068.64

2942.12

2867.10

265 2.26

1919.88

17 12.22

1599.12

1449.82

1420.51

1351.29

1313.28

1 231.91

1173.76

1 117.20

1066.08

1022.50

905.78

863 .94

7 78.24

751.20

715.5 0

6 50.71

496.88

418.93

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-R-4.pk

SJC-PH~4.SP 3601 4000.00 400.00 6.32 99.99 4.00 %T 5 1.00

REF 4 000 63.78 2000 54.03 6003944.01 62.08 3431.03 6.32 2944.18 6.49 2660.71 11.93 192 0.32 47.181680.71 8.45 1600.92 8.82 1358.41 11.43 1115.74 16.17 106 7.87 20.30908.16 23 .42 712.49 18.25 652.81 23.7 9 502.47 29.97

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 44.01

3431.03

2944.18

2660.71

1920.3 2

1680.71

1600.92

1358.41 1115.74

1067.87

908.16

712.49

652.81

502.47

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-Ph-Ram-5.sp

Date: 15-2-2010

SJC-Ph-Ram-5.pk

SJ0CDA~1.SP 3601 4000.00 400.00 7.94 100.00 4.00 %T 5 1.00

REF 4 000 98.65 2000 96.86 6003780.00 93.97 3443.67 5 2.90 3067.21 71.46 2940.98 34.80 2864.31 56.072737.45 79.95 2333.47 9 7.95 1980.80 96.21 1707.78 7.94 1596.20 55.951450.30 62.85 1389.44 7 1.18 1310.84 62.49 1209.02 48.87 1168.60 68.581116.50 74.37 1065.69 8 3.89 1017.83 86.77 904.98 90.09 826.63 71.00748.17 49 .99 691.79 65.27 650.17 67.50 4 92.81 83.60 452.53 86.34

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3780.00

3443.67

3067.21

294 0.98

2864.3 1

2737.45

233 3.471980.80

17 07.78

1596.20

1450.30

1389.44

1310.8 4

1209.02

1168.60

1116.50

1065.69

1017.83

904.98

826.63

748.17

691.79

650.1 7

492.81

45 2.53

FTIR SPECTRUM

ACIC


Trichy-2


Date: 15-2-2010

SJC-Ph-Ram-6.pk

SJ0CDE~1.SP 3601 4000.00 400.00 6.39 99.99 4.00 %T 5 1.00

REF 4 000 98.20 2000 93.19 6003879.66 96.56 3778.63 90.32 3401.34 43.48 3065.75 54.75 2941.61 20.262864.04 37.16 2737.66 59.25 2332.62 94.93 1981.01 91.57 1911.94 93.231815.10 88.88 1708.08 6.39 1596.62 36.27 1449.79 46.04 1390.87 56.081310.74 46.16 1207.97 32.12 1168.39 52.68 1117.51 62.37 1067.51 73.461016.38 76.52 905.90 82 .22 826.80 53.97 748.09 32.86 690.97 49.34650.41 53 .04 491.84 75.33 452.10 75.5 6

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3879.66

3778.63

3 401.34

3065.75

294 1.61

2864.0 4

2737.66

2332.62

1 981.01

1911.94

1815.10

1708.08

159 6.62

1449.79

1390.87

1310.74

1207.97

116 8.39

1 117.51

1067.51

1016.38

905.90

826.80

748.09

690.97

650.41

491.84

452.10

FTIR SPECTRUM

ACIC


Trichy-2


Date: 15-2-2010

SJC-Ph-Ram-7.pk

SJ0CD2~1.SP 3601 4000.00 400.00 7.07 100.0 0 4.00 %T 5 1 .00

REF 4 000 98.78 2000 95.10 6003879.79 97.45 3778.22 9 2.66 3403.81 48.02 3066.66 58.45 2941.47 30.362863.59 47.86 2737.81 6 5.84 2333.39 96.15 1981.38 93.87 1912.46 95.061816.49 92.48 1707.39 7 .06 1596.55 43.54 1450.10 55.80 1391.08 63.451310.35 54.27 1207.69 3 9.29 1168.65 58.96 1116.70 69.43 1068.29 78.371016.80 81.64 906.21 87.39 826.78 61 .10 747.84 40.07 691.45 55.73650.41 59 .56 492.69 81.92 451.85 80.70

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3879.79

3778.22

3 403.81

3066.66

294 1.47

2863.59

2737.81

233 3.39

1 981.38

1912.46

1816.49

1707.39

1596.55

1450.10

13 91.08

1310.35

1207.69

1168.65

1116.70

1068.29

10 16.80

906.21

826.78

747.84

6 91.45

650.41

492.69

451.85

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-R-8.pk

SJC90F~1.SP 3601 4000.00 400.00 6.72 100.00 4.00 %T 5 1.00

REF 4 000 98.01 2000 96.65 6003938.95 96.66 3415.96 3 8.82 2941.32 8.41 2866.27 21.88 2677.10 81.581712.23 6.72 1616.13 20.97 1446.64 38.43 1354.11 28.73 1315.48 41.591226.45 35.90 1171.42 6 5.07 1118.42 51.90 1059.36 71.62 1020.26 81.56904.32 77 .41 864.13 83.43 759.83 68.24 7 16.42 73.39 650.48 78.37492.90 68 .36 413.92 89.65

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3938.95

3415.96

294 1.32

2866.27

2677.10

17 12.23

1616.13

1446.64

1354.11

1315.48

1226.45

1171.4 2

111 8.42

1059.36

1 020.26

904.32

864.13

759.83

716.42

650.48

4 92.90

4 13.92

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-R-9.pk

SJD9 0B~1.SP 3601 4000.0 0 400.00 6.60 100.00 4.00 %T 5 1.00

REF 4 000 83.43 2000 82.79 6003940.62 82.36 3420.68 2 4.49 3069.74 34.00 2942.12 6.79 2867.97 16.042668.26 61.89 2178.50 8 2.36 1713.05 6.60 1601.98 19.48 1445.59 30.541352.97 25.76 1229.02 2 5.16 1173.34 45.96 1118.31 41.51 1061.04 56.95904.82 64 .57 864.11 68.72 756.09 57.48 7 16.21 53.11 650.23 62.03494.41 56 .07 420.36 81.47

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 940.62

3420.68

3069.74

294 2.12

2867.97

2668.26

2178.50

171 3.05

1601.98

1445.59

1352.97

1229.02

1173.34

1118.31

1061.04

904.82

864.11

756.09

716.2 1

650.23

4 94.41

420 .36

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-PH-R-10.sp

Date: 08-2-2010

SJC-PH-R-10.pk

SJ8E4 3~1.SP 3601 4000.00 400.00 6.60 100.00 4.00 %T 5 1.00

REF 4 000 99.08 2000 96.37 6003401.83 59.27 3064.87 6 0.72 2940.63 23.94 2864.30 43.46 2824.68 58.962737.03 74.58 1975.38 9 5.17 1916.99 94.64 1706.69 6.59 1593.14 32.351452.05 54.68 1424.28 6 5.03 1355.60 53.21 1313.51 52.05 1227.20 49.411208.42 46.25 1169.23 6 5.09 1117.22 67.68 1066.39 82.99 1019.45 85.56903.77 87 .82 859.50 89.47 826.57 71.01 7 48.94 49.22 715.87 63.15690.06 66 .77 649.91 66.40 493.29 84.48 4 51.75 89.78 413.82 95.01

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 401.833064.87

294 0.63

2864.30

2824.68

2737.03

1 975.38

1916.9 9

1706.69

1593.14

1452.05

1424.28

1355.60

1313.51

1 227.20

120 8.42

1169.23

1117.22

1066.39

10 19.45

903.77

859.50

826.57

748.94

715.87

690 .06

649.91

4 93.29

451.75

413.82

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-R-11.pk

SJ8653~1.SP 3601 4000.00 400.00 7.33 100.00 4.00 %T 5 1 .00

REF 4 000 99.34 2000 95.98 6003396.20 61.37 3067.46 5 3.46 2942.14 30.61 2864.67 47.56 2737.74 69.991977.33 94.66 1914.26 9 3.78 1705.98 7.33 1597.23 30.17 1451.19 58.731359.62 53.12 1310.83 5 2.74 1212.54 43.33 1170.05 61.83 1115.66 71.491068.16 82.84 1018.69 8 6.70 906.16 87.88 826.55 68.26 748.74 49.65714.03 59 .23 650.67 65.29 497.40 88.23 4 51.56 88.84

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3396.20

3067.46

294 2.14

2864.67

27 37.74

1 977.33

1914.26

1705.98

1597.23

1451.19

1359.62

1310.83

1212.54

117 0.05

1 115.66

1068.16

1018.69

906.16

826 .55

748.74

714.03

650.67

497.40

451.56

FTIR SPECTRUM

ACIC

St.Joseph'sCollege( Autonomous )

Trichy-2

SpectrumName: SJC-PH-R-12.sp Date: 09-2-2010

SJC-PH-R-13.pk

SJ8663~1.SP 3601 4000.00 400.00 7.19 99.98 4.00 %T 5 1.00

REF400099.41 200097.82 6003435.76 16.46 3075.36 36.79 2943.84 39.15 2821.39 47.32 2738.03 61.491979.60 96.58 1913.50 96.31 1700.99 12.81 1595.99 7.19 1452.44 59.851385.06 44.86 1354.33 43.00 1312.62 51.91 1207.97 45.16 1169.75 62.341115.27 80.03 1070.67 85.60 1018.94 89.20 825.94 59.29 747.88 38.21694.68 46.63 650.77 49.53 542.68 72.65 453.57 76.93

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3435.76

3075.36

2943.84

2821.39

2738.03

1979.60

1913.50

1700.99

1595.99

1452.44

1385.06

1354.33

1312.62

1207.97

1169.75

1115.27

1070.67

1018.94

825.94

747.88

694.68

650.77

542.68

453.57

FTIR SPECTRUM

ACIC


Trichy-2


Date: 15-2-2010

SJC-Ph-Ram-13.pk

SJC833~1.SP 3601 4000.00 400 .00 7.30 99.94 4.00 %T 5 1.00

REF 4 000 98.94 2000 95.23 6003880.00 97.52 3778.62 91.98 3443.99 39.30 3069.37 56.01 2944.94 60.402819.26 57.97 2738.06 65.71 2544.31 90.10 1981.03 94.00 1913.01 94.351821.90 94.34 1702.36 7.30 1596.60 37.53 1453.37 64.88 1390.11 59.981306.91 54.95 1205.51 38.59 1169.05 58.47 1111.47 82.24 1072.42 85.101017.16 87.43 924.23 90 .74 826.54 55.59 746.04 35.00 690.37 45.92650.82 50 .68 544.35 83.49 450.97 74.7 0

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3880.0 0

3 778.62

3443.99

3069.37

2944.94

2819.26

2738.06

2544.311981.03

1913.01

1 821.90

17 02.36

1596.60

1453.37

1390.11

1306.91

1205.51

1169.05

1 111.47

1072.42

1017.16

924.23

826.54

746.04

690.37

650.82

544.35

450.97

FTIR SPECTRUM

ACIC


Trichy-2


Date: 09-2-2010

SJC-PH-R-14.pk

SJ8E6 3~1.SP 3601 4000.00 400.00 6.68 100.00 4.00 %T 5 1.00

REF 4 000 98.27 2000 97.28 6003438.23 22.03 3071.40 3 1.13 2941.98 12.86 2866.56 25.99 2740.59 63.842658.54 69.83 1975.62 9 5.96 1917.73 95.96 1707.38 6.67 1597.06 15.451449.07 43.07 1386.35 4 3.09 1350.22 37.79 1312.33 37.44 1232.20 27.421172.62 50.12 1116.46 5 2.66 1066.51 69.17 1021.40 78.49 904.94 80.66826.33 70 .30 749.53 47.29 713.17 39.72 6 50.43 55.01 498.23 69.56416.91 91 .23

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3438.23

3071.40

294 1.98

2866.56

2 740.59

2658.54

197 5.62

191 7.73

17 07.38

1597.06

1449.07

1386.35

1350.22

1312.33

1232.20

11 72.62

1116.46

1066.51

102 1.40

904.94

826.33

749.53

713.17

650.43

498.23

416.91

FTIR SPECTRUM

ACIC


Trichy-2


Date: 09-2-2010

SJC-PH-R-15.pk

SJ8673~1.SP 3601 4000.00 400.00 6.46 99.99 4.00 %T 5 1.00

REF 4 000 97.69 2000 93.33 6003938.64 96.09 3439.15 17.67 3204.98 20.38 3069.52 19.75 2942.50 8.602867.00 17.05 2654.89 50.10 1972.99 90.61 1920.05 89.66 1705.04 6.461597.63 16.40 1450.68 33.65 1416.62 34.65 1390.10 34.69 1349.30 32.891313.21 27.17 1233.66 19.40 1173.58 37.72 1117.27 40.43 1068.55 55.771023.35 65.10 906.79 66 .72 862.84 69.76 827.56 62.70 749.24 43.31714.23 28 .64 650.83 46.11 499.66 63.6 8 415.38 86.82

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3938.64

3439.1532 04.98

3069.5 2

294 2.50

2867.0 0

2654.89

1972.99

1920.05

1705.04

1597.63

1450.6 8

1416.62

139 0.10

1349.30

1313.21

1233.66

1173.58

1 117.27

1068.55

1023.35

906.79

862.84

827.56

749.24

714.23

650.83

499.66

415.38

FTIR SPECTRUM

ACIC


Trichy-2


Date: 09-2-2010

SJC-PH-R-16.pk

SJ8E7 3~1.SP 3601 4000.00 400.00 6.50 99.99 4.00 %T 5 1.0 0

REF 4 000 98.22 2000 95.44 6003922.57 97.21 3780.75 94.64 3437.50 23.47 3206.39 27.10 3068.47 25.412942.04 11.42 2865.74 23.02 2739.08 52.99 2660.12 63.17 2368.76 89.941975.95 93.32 1917.85 92.81 1704.78 6.50 1596.58 11.01 1451.25 38.781388.27 36.99 1351.48 35.53 1312.84 31.71 1232.55 25.70 1171.23 40.491116.64 49.61 1068.13 63.34 1021.77 70.81 907.07 76.89 827.30 55.57748.64 34 .17 713.73 31.12 650.63 44.1 5 499.13 69.05 452.91 78.41

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3922.57

3 780.75

3437.5032 06.39

3068.4 7

294 2.04

2865.74

2739.08

2660.12

23 68.76

1 975.95

1917.85

1704.78

1596.58

1451.25

13 88.27

1351.48

1312.84

1232.55

11 71.23

1116.64

1068.13

1021.77

907.07

827.30

748.64

713.73

6 50.63

499.13

4 52.91

FTIR SPECTRUM

ACIC


Trichy-2


Date: 09-2-2010

SJC-PH-R-17.pk

SJ8683~1.SP 3601 4000.00 400.00 7.11 100.00 4.00 %T 5 1 .00

REF 4 000 99.39 2000 92.88 6003925.94 97.82 3795.21 9 7.45 3395.62 28.99 3069.60 33.11 2939.93 29.942821.81 35.56 2737.70 4 5.22 2551.07 68.33 2363.84 85.55 2026.94 93.291979.12 89.42 1914.27 8 8.85 1823.31 90.27 1700.04 7.11 1595.24 11.651452.12 50.18 1387.84 4 1.29 1283.71 36.69 1206.19 31.67 1169.43 43.781114.41 66.70 1070.83 7 4.27 1016.43 78.20 927.79 76.94 824.51 48.12745.60 31 .11 690.87 36.23 651.06 39.50 5 42.09 74.76 449.42 69.53

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

392 5.94

3 795.21

3395.623069.60

29 39.93

2821.81

2 737.70

2551.07

236 3.84

2026.94

1979.12

1914.27

1 823.31

17 00.04

1595.24

1452.1 2

13 87.841283.71

1206.19

1169.43

1114.41

1070.83

1016.43

9 27.79

824.51

745.60

690.87

651.06

542 .09

449.42

FTIR SPECTRUM

ACIC


Trichy-2


Date: 09-2-2010

SJC-PH-R-18.pk

SJ8E8 3~1.SP 3601 4000.00 400.00 5.97 99.99 4.00 %T 5 1.0 0

REF 4 000 99.18 2000 91.35 6003914.04 97.96 3792.24 97.20 3393.43 27.17 3068.32 30.72 2939.60 28.942822.60 32.14 2738.07 41.52 2550.33 67.71 2331.96 87.73 2140.59 98.162028.28 91.40 1979.33 87.44 1914.88 86.06 1823.64 85.97 1699.87 5.971595.44 8.81 1494.04 73 .72 1453.58 44.36 1387.96 36.00 1311.21 33.371284.43 32.58 1205.73 26.12 1168.70 38.59 1114.31 65.30 1071.31 70.101019.30 74.33 928.44 71 .32 826.14 39.26 746.54 24.33 713.83 32.95688.77 31 .17 651.09 33.64 543.54 70.9 9 450.78 61.25

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3914.04

3792.24

3393.433068.32

2939.60

2822.60

2738.07

2550.33

23 31.96

2140.59

2028.28

1979.33

1914.88

1823.64

16 99.87

1595.44

1494.04

1453.58

13 87.96

1311.21

1284.43

1205.73

116 8.70

1114.31

1071.31

1019.30

9 28.44

826.14

746.54

713.83

688.77

651.09

543.54

450.78

302

Table - 7.23

Observations of FTIR Spectrums for

Cyclohexanone + Hexane + Benzaldehyde mixture

S1 (Cm-1) S2 (Cm-1) S3 (Cm-1) S4 (Cm-1) *S5(Cm-1) S6 (Cm-1) S7 (Cm-1) S8 (Cm-1) S9 (Cm-1)

3938.943411.732940.352864.512719.872673.852062.951712.311595.531448.451356.251313.771222.961119.021055.221018.31905.31864.41753.33651.39490.92412.11

3941.403447.653068.382942.052865.862677.622177.102062.831709.721610.931449.221355.771314.391228.241173.101118.351061.641020.84905.35863.92771.73716.00650.00493.86412.85

3942.533415.153068.642942.122867.102652.261919.881712.221599.121449.821420.511351.291313.281231.911173.761117.201066.081022.50905.78863.94778.24751.20715.50650.71496.88

3944.013431.032944.182660.711920.321680.711600.921358.411115.741067.87908.16712.49652.81502.47

3780.00

3443.67

3067.212940.98

2864.31

2737.452333.47

1980.801707.78

1596.20

1450.301389.44

1310.84

1209.021168.60

1116.50

1065.691017.83

904.98

826.63748.17

691.79

650.17492.81

452.53

3879.663778.633401.343065.752941.612864.042737.662332.621981.011911.941815.101708.081596.621449.791390.871310.741207.971168.391117.511067.511016.38905.90826.80748.09690.97

3879.793778.223403.813066.662941.472863.592737.812333.391981.381912.461816.491707.391596.551450.101391.081310.351207.691168.651116.701068.291016.80906.21826.78747.84691.45

3938.953415.962941.322866.272677.101712.231616.131446.641354.111315.481226.451171.421118.421059.361020.26904.32864.13759.83716.42650.48492.90413.92

3940.623420.683069.742942.122867.972668.262178.501713.051601.981445.591352.971229.021173.341118.311061.04904.82864.11756.09716.21650.23494.41420.36

S10 (Cm-1) S11 (Cm-1) S12 (Cm-1) S13 (Cm-1) S14 (Cm-1) S15 (Cm-1) *S16 (Cm-1) S17 (Cm-1) S18 (Cm-1)

3401.833064.872940.632864.302824.682737.031975.381916.991706.691593.141452.051424.281355.601313.511227.201208.421169.231117.221066.391019.45903.77859.50826.57748.94715.87690.06649.91493.29451.75413.82

3396.203067.462942.142864.672737.741977.331914.261705.981597.231451.191359.621310.831212.541170.051115.661068.161018.69906.16826.55748.74714.03650.67497.40451.56

3435.763075.362943.842821.392738.031979.601913.501700.991595.991452.441385.061354.331312.621207.971169.751115.271070.671018.94825.94747.88694.68650.77542.68453.57

3880.003778.623443.993069.372944.942819.262738.062544.311981.031913.011821.901702.361596.601453.371390.111306.911205.511169.051111.471072.421017.16924.23826.54746.04690.37650.82544.35450.97

3438.233071.402941.982866.562740.592658.541975.621917.731707.381597.061449.071386.351350.221312.331232.201172.621116.461066.511021.40904.94826.33749.53713.17650.43498.23416.91

3938.643439.153204.983069.522942.502867.002654.891972.991920.051705.041597.631450.681416.621390.101349.301313.211233.661173.581117.271068.551023.35906.79862.84827.56749.24714.23650.83499.66415.38

3922.57

3780.753437.50

3206.39

3068.472942.04

2865.74

2739.082660.12

2368.76

1975.951917.85

1704.78

1596.581451.25

1388.27

1351.481312.84

1232.55

1171.231116.64

1068.13

1021.77907.07

827.30

748.64713.73

650.63

499.13452.91

3925.943795.213395.623069.602939.932821.812737.702551.072363.842026.941979.121914.271823.311700.041595.241452.121387.841283.711206.191169.431114.411070.831016.43927.79824.51745.60690.87651.06542.09449.42

3914.043792.243393.433068.322939.602822.602738.072550.332331.962140.592028.281979.331914.881823.641699.871595.441494.041453.581387.961311.211284.431205.731168.701114.311071.311019.30928.44826.14746.54713.83688.77651.09543.54450.78


303

Fig-7.23: FTIR Spectrums for Cyclohexanone+Hexane+2-Butanone mixture:

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-0.5+0.2+0.3.sp

Date: 11-5-2010

SJC-0.5+0.2+0.3.pk

SJC-05~3.SP 3601 4000.00 400.00 7.01 99.99 4.00 %T 3 1.00

REF 4000 99.14 2000 97.22 6003932.10 95.11 3785.75 88.95 3447.99 11.09 2942.53 7.04 2871.39 22.582670.15 90.51 2177.52 94.13 1716.75 7.01 1564.39 42.74 1433.02 28.341326.19 47.76 1222.90 51.67 1119.49 60.38 1057.20 79.81 902.29 79.69749.00 67.39 651.22 69.55 493.54 58.54 421.74 87.07

4000.0 300 0 2000 15 00 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3932.10

3785 .75

3447.9929 42.53

28 71.39

2670 .15

2 17 7.5 2

171 6.75

1564 .39

1433 .02

1 326 .1 9

1 22 2.9 0

1 11 9.4 9

105 7.20

902.29

74 9.006 51.22

4 93 .54

4 21 .74

FTIR SPECTRUM

ACIC


Trichy-2


Date: 11-5-2010

SJC-0.5+0.4+0.1.pk

SJC-05~1.SP 3601 4000.00 400.00 8.63 100.00 4.00 %T 3 1.00

REF 4000 97.38 2000 95.95 6003927.77 94.92 3785.81 91.13 3446.59 20.08 2941.96 13.16 2866.78 31.312671.11 91.09 2175.90 93.59 1713.47 8.62 1563.37 52.20 1427.09 37.561314.03 53.58 1222.46 51.74 1118.97 58.70 1054.65 78.80 1018.90 82.94904.34 77.78 864.78 85.54 749.80 70.63 652.49 74.55 491.27 61.74414.99 88.90

40 00.0 3 000 2000 1500 1000 400.0

0 .0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0.0

cm-1

%T

3 92 7.77

37 85.81

34 46.59

29 41.96

28 66.78

2 67 1.1 1

21 75.90

171 3.47

1 56 3.3 7

1427 .09

131 4.03

1 22 2.4 6

1 11 8.9 7

10 54.65

1 018 .9 0

90 4.34

86 4.78

7 49 .8 0

652.49

4 91.27

4 14 .9 9

FTIR SPECTRUM

ACIC


Trichy-2


Date: 11-5-2010

SJC-0.5+0.3+0.2.pk

SJC-05~2.SP 3601 4000.00 400.00 9.53 99.99 4.00 %T 3 1.00

REF 4000 98.50 2000 97.10 6003934.64 95.56 3791.13 92.36 3431.32 25.85 2941.39 9.87 2871.00 27.682669.96 91.54 2345.32 95.97 2177.20 95.09 1714.66 9.53 1564.95 61.021435.37 37.28 1323.22 52.57 1223.03 55.18 1119.00 62.60 1055.01 79.88903.03 81.11 749.67 76.41 651.93 81.89 492.23 68.75 419.47 94.89

40 00.0 3 000 2000 1500 1000 400.0

0 .0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0.0

cm-1

%T

3934.64

3791.13

3431.32

2941.39

2871.00

26 69.96

2345.32

2177.20

1714.66

1564.95

1435.37

1323.22

1223.03

1119.00

1055.01

903 .03

749 .67

651.93

492.23

419.47

FTIR SPECTRUM

ACIC


Trichy-2


Date: 11-5-2010

SJC-0.5+0.1+0.4.pk

SJC-05~4.SP 3601 4000.00 400.00 8.40 100.00 4.00 %T 3 1.00

REF 4000 98.21 2000 97.04 6003928.52 95.87 3783.01 90.94 3455.17 29.09 2941.90 9.59 2867.47 27.082670.99 91.04 2342.34 95.38 2177.76 94.99 1714.55 8.39 1565.60 60.851432.95 37.92 1315.28 51.52 1222.66 49.88 1119.10 57.18 1054.47 78.241018.93 82.27 905.07 77.78 865.27 86.14 750.06 73.20 652.59 79.97491.22 66.00 414.23 92.44

40 00.0 3 000 2000 1500 1000 400.0

0 .0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0.0

cm-1

%T

3928.52

3783 .01

3455.17

2941.90

2867 .47

2670.99

2342.34

2177.76

1714.55

1565 .60

1432.95

1315.28

1222 .66

1119.10

1054.47

1018.93

905.07

865.27

750 .06

652.59

491.22

414 .23

FTIR SPECTRUM

ACIC


Trichy-2


Date: 11-5-2010

SJC-0.4+0.5+0.1.pk

SJC-04~1.SP 3601 4000.00 400.00 9.42 100.00 4.00 %T 3 1.00

REF 4000 98.41 2000 97.41 6003928.61 96.81 3792.17 93.24 3451.01 32.96 2941.36 13.64 2867.00 34.312670.57 93.30 2177.81 95.75 1713.50 9.41 1563.29 64.11 1432.69 45.051314.76 58.31 1222.68 56.08 1118.97 63.21 1054.37 82.27 904.99 81.26865.17 87.97 749.85 76.69 652.26 81.48 491.24 69.21 415.32 92.23

40 00.0 3 000 2000 1500 1000 400.0

0 .0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0.0

cm-1

%T

3928.61

3792 .17

3451 .01

2941.36

2867.00

2670 .57

2177 .81

1713.50

1 56 3.29

1432.69

1314.761222.68

1 11 8.97

1054 .37

904.99

865 .17

749 .85652.26

491.24

415 .32

FTIR SPECTRUM

ACIC


Trichy-2


Date: 11-5-2010

SJC-0.4+0.4+0.2.pk

SJC-04~2.SP 3601 4000.00 400.00 7.82 100.00 4.00 %T 3 1.00

REF 4000 99.42 2000 98.11 6003938.94 97.29 3787.12 94.60 3418.79 36.62 2939.87 7.82 2669.71 86.122345.83 95.88 2178.98 95.63 2071.33 95.81 1965.13 96.70 1713.81 12.521436.06 33.84 1324.15 44.97 1223.75 49.71 1119.14 58.98 1051.94 75.25897.71 74.41 750.43 73.95 652.10 85.17 492.19 66.77 421.08 93.59

40 00.0 3 000 2000 1500 1000 400.0

0 .0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

10 0.0

cm-1

%T

3938.94

3787.12

3418 .79

29 39.87

26 69.71

23 45.83

2 178 .9 8

20 71.33

1 96 5.1 3

171 3.81

14 36.06

1324 .15

1 22 3.7 5

1 11 9.1 4

1051 .94

8 97.71

7 50 .4 3

652.10

4 92.19

421.08

FTIR SPECT RUM

ACIC


Trichy-2


Date: 11-5-2010

SJC-0.4+0.3+0.3.pk

SJC-04~3.SP 3601 4000.00 400.00 9.31 99.99 4.00 %T 3 1.00

REF 4000 97.99 2000 96.97 6003879.99 96.44 3780.50 89.78 3453.98 29.07 2941.44 13.17 2867.27 33.972671.61 92.60 2178.12 95.35 1713.96 9.31 1565.53 63.91 1431.86 45.001315.13 59.59 1222.43 57.89 1119.05 64.97 1054.38 83.43 905.19 82.44864.75 88.35 749.87 74.93 652.33 78.69 491.33 67.36 416.80 89.65

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

387 9.9 9

3780 .50

3 453 .9 8

2941 .44

2867 .27

26 71.61

2178 .12

1713 .96

1565 .53

1 431 .8 6

1 31 5.13

1 22 2.43

1 11 9.05

1054 .38

9 05 .1 9

8 64 .75

74 9.876 52 .3 3

49 1.33

4 16 .8 0

FTIR SPECT RUM

ACIC


Trichy-2


Date: 11-5-2010

SJC-0.4+0.2+0.4.pk

SJC-04~4.SP 3601 4000.00 400.00 8.41 100.00 4.00 %T 3 1.00

REF 4000 97.80 2000 96.23 6003915.77 95.10 3781.01 87.36 3456.52 16.57 2941.78 12.31 2868.11 28.832670.37 90.09 2338.02 95.17 2176.60 93.50 1873.58 96.45 1714.49 8.401564.86 54.39 1429.99 33.80 1316.69 51.41 1222.47 50.84 1172.78 76.931119.22 58.60 1055.00 78.43 1018.59 82.67 905.19 77.64 865.16 86.37750.22 68.56 652.51 74.78 586.51 83.06 491.95 61.85 414.48 90.10

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3915.77

3781.01

3456 .52

2941 .78

2868.11

2670 .37

2338 .02

2176.60

1873.58

1714 .49

1564.86

1429 .99

1316.691222 .47

1172 .78

1119.22

1055 .00

1018 .59

905.19

865 .16

750.22

652 .51

586 .51

491.95

414.48

FTIR SPECT RUM

ACIC


Trichy-2


Date: 11-5-2010

SJC-0.4+0.1+0.5.pk

SJ67A7~1.SP 3601 4000.00 400.00 8.30 99.99 4.00 %T 3 1.00

REF 4000 97.44 2000 96.43 6003879.98 95.57 3778.85 87.88 3459.55 23.37 2941.75 9.92 2868.07 25.522670.91 89.55 2338.96 95.84 2177.85 94.44 1874.69 96.28 1715.54 8.291566.09 66.74 1432.57 36.59 1345.44 51.23 1316.80 51.49 1222.26 50.681172.67 72.06 1119.30 59.24 1055.39 80.07 1018.18 84.62 905.48 77.81865.33 86.59 750.41 70.54 652.43 78.85 586.83 85.12 491.72 63.49415.48 87.79

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3879 .98

3778 .85

3459 .55

2941 .75

2868 .07

2670 .91

2338.96

2177.85

1874.69

1715 .54

1566 .09

1432 .57

1345.44

1316.801222 .26

1172 .67

1119.30

1055 .39

1018.18

905.48

865.33

750.41

652 .43

586 .83

491.72

415.48

FTIR SPECT RUM

ACIC


Trichy-2


Date: 14-5-2010

SJC-0.3+0.5+0.2.pk

SJC-03~1.SP 3601 4000.00 400.00 6.34 99.52 4.00 %T 3 1.00

REF 4000 98.62 2000 95.71 6003942.41 87.88 3822.38 88.96 3712.60 81.90 3421.53 6.34 2946.31 14.782876.47 36.88 2669.97 89.12 2452.71 94.26 2168.14 89.76 1727.85 16.711569.41 11.99 1422.18 19.55 1337.28 57.99 1222.52 66.59 1119.34 70.601038.28 77.83 903.90 87.27 746.93 66.93 650.49 56.70 496.64 65.81

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3942.41

3822 .38

3712 .60

3421 .53

2946.31

2876.47

2669 .97

2452 .712168.14

1727 .85

1569 .41

1422.18

1337 .28

1222 .52

1119.34

1038 .28

903.90

746.93

650 .49

496.64

FTIR SPECT RUM

ACIC


Trichy-2


Date: 14-5-2010

SJC-0.3+0.4+0.3.pk

SJC-03~2.SP 3601 4000.00 400.00 8.61 100.00 4.00 %T 3 1.00

REF 4000 97.90 2000 97.40 6003951.27 95.73 3853.71 96.78 3410.86 60.84 2941.40 9.53 2867.29 24.432670.27 89.76 2176.78 95.54 1966.02 96.26 1713.99 8.61 1572.05 77.821436.33 38.17 1315.23 48.03 1222.81 46.34 1119.13 54.51 1054.92 76.651018.35 82.20 904.80 73.84 865.75 83.46 750.48 74.41 652.54 86.76491.12 65.68 414.32 90.21

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3951.27

3853.71

3410.86

2941 .40

2 86 7.2 9

2 67 0.27

2176 .78

1 966 .0 2

1713 .99

1 57 2.05

1 43 6.33

1 31 5.23

1 22 2.8 1

1 11 9.13

1054 .92

1 01 8.35

9 04.80

8 65 .7 5

75 0.48

6 52 .5 4

49 1.12

4 14 .3 2

FTIR SPECT RUM

ACIC


Trichy-2


Date: 14-5-2010

SJC-0.3+0.3+0.4.pk

SJC-03~3.SP 3601 4000.00 400.00 6.44 100.00 4.00 %T 3 1.00

REF 4000 97.75 2000 96.86 6003941.39 94.67 3832.82 96.29 3414.30 43.93 2941.19 6.44 2872.00 19.592669.47 87.60 2346.99 94.64 2178.62 94.45 1964.53 95.83 1715.29 9.951569.51 65.51 1435.96 32.09 1326.07 46.46 1223.00 50.57 1119.50 60.111056.70 78.21 903.19 76.24 750.92 75.18 651.80 84.95 492.53 66.99419.41 92.10

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

394 1.39

3832 .82

341 4.30

2 94 1.1 9

28 72.00

2669 .47

2 34 6.9 9

2 17 8.62

1 96 4.53

1715 .29

1 569 .5 1

1 43 5.96

1326 .07

1223 .00

1 11 9.50

1056 .70

9 03.1975 0.92

6 51 .8 0

49 2.53

4 19.41

FTIR SPECT RUM

ACIC


Trichy-2


Date: 14-5-2010

SJC-0.3+0.2+0.5.pk

SJC-03~4.SP 3601 4000.00 400.00 8.23 100.00 4.00 %T 3 1.00

REF 4000 99.73 2000 98.75 6003948.44 95.86 3833.01 98.35 3417.96 41.79 2941.24 13.01 2873.32 28.042669.94 91.40 2347.17 96.17 2176.88 96.16 1964.66 97.58 1715.34 8.221569.15 61.37 1434.89 29.68 1330.60 44.83 1222.47 49.46 1175.15 67.801119.68 59.71 1057.84 78.62 904.02 77.02 751.18 74.53 651.73 85.37583.55 91.19 493.13 67.20 418.26 93.49

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3948 .44

3833.01

3417 .96

2941 .24

2873.32

2669 .94

2347.17

2176.88

1964.66

1715 .34

1569.15

1434.89

1330.601222 .47

1175.15

1119.68

1057 .84

904.02751.18

651 .73

583 .55

493.13

418.26

FTIR SPECT RUM

ACIC


Trichy-2


Date: 14-5-2010

SJC-0.2+0.5+0.3.pk

SJC-02~3.SP 3601 4000.00 400.00 8.43 99.99 4.00 %T 3 1.00

REF 4000 98.07 2000 96.37 6003950.92 92.90 3830.30 95.48 3776.76 94.24 3419.94 23.91 2942.39 10.922867.80 28.53 2670.93 91.36 2342.10 94.72 2174.27 93.72 1873.57 96.911714.98 8.43 1566.85 51.73 1429.82 35.93 1315.52 53.91 1222.34 52.631119.05 60.25 1054.36 80.66 1018.78 83.99 905.30 79.98 864.85 87.45749.97 72.20 652.57 76.22 491.42 65.36 414.36 91.40

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3950 .92

3830 .30

3776.76

3419 .94

2942 .39

2867.80

2670.93

2342.10

2174 .27

1873.57

1714 .98

1566 .85

1429 .82

1315.52

1222 .34

1119.05

1054 .36

1018.78905.30

864 .85

749.97

652 .57

491.42

414 .36

FTIR SPECT RUM

ACIC


Trichy-2


Date: 14-5-2010

SJC-0.2+0.3+0.5.pk

SJC-02~1.SP 3601 4000.00 400.00 7.36 100.00 4.00 %T 3 1.00

REF 4000 96.78 2000 95.18 6003943.07 92.03 3777.76 94.63 3411.57 38.88 2941.72 7.36 2867.25 18.692670.38 82.41 2455.77 91.88 2176.67 91.37 1967.65 93.91 1871.93 94.731714.15 8.10 1570.65 66.73 1434.11 31.88 1315.24 42.58 1222.75 41.231119.05 48.96 1054.85 71.38 1018.46 77.46 904.66 69.53 865.76 80.08750.25 68.00 652.24 79.36 491.05 58.63 415.06 85.13

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3943 .07

3777.76

3411.57

2941.72

2867 .25

2670 .38

2455 .77

2176.67

1967 .65

1871.93

1714 .15

1570.65

1 43 4.11

1 31 5.241222 .75

1119.05

1054.85

1018 .46

904.66

865.76

750.25

652.24

491.05

415.06

FTIR SPECT RUM

ACIC


Trichy-2


Date: 14-5-2010

SJC-0.2+0.4+0.4.pk

SJC-02~2.SP 3601 4000.00 400.00 8.37 100.00 4.00 %T 3 1.00

REF 4000 97.73 2000 96.70 6003944.73 92.92 3829.39 95.14 3412.78 40.63 2941.69 10.02 2868.98 24.392670.33 85.88 2457.50 94.72 2175.94 93.51 1967.01 95.36 1871.91 95.621715.39 8.36 1568.57 70.95 1433.46 34.43 1346.81 47.11 1317.35 48.481222.18 48.02 1172.68 66.02 1119.34 56.72 1055.80 76.86 1017.82 82.55905.23 73.74 865.88 83.76 750.79 70.37 652.41 83.03 586.41 89.54491.68 64.38 414.29 89.37

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3944.73

3829 .39

3412.78

2941 .69

28 68.98

2 670 .3 3

245 7.50

21 75.94

1 96 7.01

18 71.91

1715 .39

1568 .57

1 433 .4 6

1 34 6.81

1 317 .3 5

1222 .18

1 17 2.68

1 11 9.34

1055 .80

1017 .82

9 05.23

8 65 .8 8

75 0.79

6 52 .4 1

58 6.41

49 1.68

4 14 .2 9

FTIR SPECT RUM

ACIC


Trichy-2


Date: 14-5-2010

SJC-0.1+0.5+0.4.pk

SJC-01~1.SP 3601 4000.00 400.00 7.97 99.99 4.00 %T 3 1.00

REF 4000 97.35 2000 95.87 6003944.45 93.13 3778.36 95.78 3414.11 35.99 2941.78 7.97 2868.76 21.042670.44 85.92 2343.00 92.83 2176.29 92.63 1968.99 94.78 1872.40 95.521715.00 8.14 1567.71 71.39 1434.23 33.44 1316.46 46.64 1222.47 46.051172.86 74.42 1119.25 54.73 1055.47 76.65 1018.14 82.63 904.93 73.67865.57 83.59 750.49 69.36 652.41 81.03 491.45 61.88 414.72 87.52

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

394 4.45

37 78.36

341 4.11

2941 .78

28 68.76

2 670 .4 4

2 34 3.0 0

2176 .29

19 68.99

1 87 2.4 0

1715 .00

1567 .71

1 43 4.23

131 6.461222 .47

1172 .86

1 11 9.25

1055 .47

101 8.14

9 04.93

86 5.57

75 0.49

6 52 .4 1

49 1.45

41 4.72

FTIR SPECT RUM

ACIC


Trichy-2


Date: 14-5-2010

SJC-0.1+0.4+0.5.pk

SJC-01~2.SP 3601 4000.00 400.00 7.99 100.00 4.00 %T 3 1.00

REF 4000 97.46 2000 95.35 6003948.44 88.43 3828.94 93.56 3415.72 29.30 2942.45 12.01 2868.71 27.612670.38 85.39 2458.04 93.31 2343.73 92.34 2175.42 91.36 1968.75 94.071872.91 95.54 1715.29 7.99 1562.00 59.09 1433.32 33.35 1316.09 47.371222.49 46.07 1119.12 53.77 1055.33 73.98 1018.54 80.27 904.46 73.25865.35 82.71 750.12 67.53 652.22 77.64 491.29 60.94 414.20 88.92

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3948.44

3828 .94

3415 .72

2942 .45

2868.71

2670.38

2458 .04

2343.73

2175.42

1968.75

1872.91

1715 .29

1562.00

1433 .32

1316.091222 .49

1119.12

1055 .33

1018.54

904.46

865.35

750.12

652 .22

491.29

414.20

304

Table - 7.24


Cyclohexanone + Hexane + 2-Butanone mixture

S1 (Cm-1)S2 (Cm-

1)

S3 (Cm-

1)

S4 (Cm-

1)S5 (Cm-1)

S6 (Cm-

1)

S7

(Cm-1)

S8 (Cm-

1)

*S9 (Cm-

1)

3927.773785.813446.592941.962866.782671.112175.901713.471563.371427.091314.031222.461118.971054.651018.90904.34864.78749.80652.49491.27414.99

3934.643791.133431.322941.392871.002669.962345.322177.201714.661564.951435.371323.221223.031119.001055.01903.03749.67651.93492.23419.47

3932.103785.753447.992942.532871.392670.152177.521716.751564.391433.021326.191222.901119.491057.20902.29749.00651.22493.54421.74

3928.523783.013455.172941.902867.472670.992342.342177.761714.551565.601432.951315.281222.661119.101054.471018.93905.07865.27750.06652.59491.22414.23

3928.613792.173451.012941.362867.002670.572177.811713.501563.291432.691314.761222.681118.971054.37904.99865.1787.97749.85652.26491.24415.32

3938.943787.123418.792939.872669.712345.832178.982071.331965.131713.811436.061324.151223.751119.141051.94897.71750.43652.10492.19421.08

3879.993780.503453.982941.442867.272671.612178.121713.961565.531431.861315.131222.431119.051054.38905.19864.75749.87652.33491.33416.80

3915.773781.013456.522941.782868.112670.372338.022176.601873.581714.49

1564.861429.991316.691222.471172.78

1119.221055.001018.59905.19865.16750.22652.51586.51491.95414.48

3879.98

3778.85

3459.552941.75

2868.07

2670.912338.96

2177.85

1874.691715.54

1566.09

1432.571345.44*

1316.80

1222.261172.67

1119.30

1055.391018.18

905.48

865.33750.41

652.43

586.83491.72

415.48

S10 (Cm-1)S11 (Cm-

1)

S12 (Cm-

1)S13 (Cm-1)

S14 (Cm-

1)

*S15 (Cm-

1)

S16 (Cm-

1)

S17 (Cm-

1)

S18 (Cm-

1)

3942.413822.383712.603421.532946.312876.472669.972452.712168.141727.851569.411422.181337.281222.521119.341038.28903.90746.93650.49496.64

3951.273853.713410.862941.402867.292670.272176.781966.021713.991572.051436.331315.231222.811119.131054.921018.35904.80865.75750.48652.54491.12414.32

3941.393832.823414.302941.192872.002669.472346.992178.621964.531715.291569.511435.961326.071223.001119.501056.70903.19750.92651.80492.53419.41

3948.443833.013417.962941.242873.322669.942347.172176.881964.661715.341569.151434.891330.601222.471175.151119.681057.84904.02751.18651.73583.55493.13418.26

3950.923830.303776.763419.942942.392867.802670.932342.102174.271873.571714.981566.851429.821315.521222.341119.051054.361018.78905.30864.85749.97652.57491.42414.36

3944.733829.39

3412.78

2941.692868.98

2670.33

2457.50*2175.94

1967.01*

1871.911715.39

1568.57

1433.461346.81*

1317.35

1222.181172.68*

1119.34

1055.801017.82

905.23

865.88750.79

652.41

586.41491.68

414.29

3943.073777.763411.572941.722867.252670.382455.772176.671967.651871.931714.151570.651434.111315.241222.751119.051054.851018.46904.66865.76750.25652.24491.05415.06

3944.453778.363414.112941.782868.762670.442343.002176.291968.991872.401715.001567.711434.231316.461222.471172.861119.251055.471018.14904.93865.57750.49652.41491.45414.72

3948.443828.943415.722942.452868.712670.382458.042343.732175.421968.751872.911715.291562.001433.321316.091222.491119.121055.331018.54904.46865.35750.12652.22491.29414.20


305

Fig-7.24: FTIR Spectrums for Cyclohexanone+Hexane+Ethyl Acetate mixture:

FTIR SPECT RUM

ACIC


Trichy-2

Spectrum Name: II-0.5+0.4+0.1.sp

Date: 17-6-2010

II-0.5+0.4+0.1.pk

II-05_~1.SP 3601 4000.00 400.00 10.54 100.00 4.00 %T 3 1.00

REF 4000 99.54 2000 97.02 6003892.11 95.99 3441.46 11.77 2940.47 14.06 2872.49 36.90 2669.53 96.352080.52 94.02 1712.60 10.53 1433.34 46.19 1321.92 60.84 1226.98 56.681118.53 67.72 1051.43 81.27 897.00 83.43 748.28 67.32 651.26 69.65493.18 67.58

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3892.11

3441.462940 .47

2872 .49

2669 .53 2 08 0.52

171 2.60

1 433 .3 4

1321 .92

122 6.98

1 11 8.53

1051 .43897.00

74 8.286 51 .2 6

49 3.18

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.5+0.3+0.2.pk

II-05_~2.SP 3601 4000.00 400.00 12.73 100.00 4.00 %T 3 1.00

REF 4000 99.66 2000 98.24 6003429.43 33.01 2940.20 12.74 2873.48 31.79 2669.59 95.07 2074.41 96.461714.02 12.73 1437.33 46.04 1321.25 55.65 1225.20 55.07 1118.72 64.521051.76 79.75 900.30 81.53 749.72 77.47 651.73 85.14 491.83 72.65418.71 96.08

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3429 .43

2940 .20

2 87 3.48

2 669 .5 9

2 074 .4 1

1714 .02

1 43 7.33

132 1.251 22 5.20

1 11 8.72

1051 .76

90 0.30

74 9.72

6 51 .7 3

49 1.83

4 18 .7 1

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.5+0.2+0.3.pk

II-05_~3.SP 3601 4000.00 400.00 11.41 99.99 4.00 %T 3 1.00

REF 4000 99.21 2000 96.75 6003447.47 13.80 2940.97 14.63 2669.75 95.13 2081.80 93.88 1714.55 11.401435.88 45.22 1320.60 56.75 1236.08 34.46 1117.62 64.06 1053.02 67.33898.17 81.84 748.69 68.01 648.84 69.85 492.57 65.37

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3447.47 2940.97

2669.75

2081.80

1714 .55

1435.88

1320.60

1236 .08

1117.62

1053 .02

898.17

748.69

648 .84

492.57

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.5+0.1+0.4.pk

II-05_~4.SP 3601 4000.00 400.00 9.43 100.00 4.00 %T 3 1.00

REF 4000 99.19 2000 97.31 6003903.73 97.71 3779.91 87.12 3458.65 15.67 2941.85 10.19 2870.95 27.162668.63 93.92 2077.36 94.59 1715.62 9.43 1438.50 40.02 1321.54 50.811233.88 30.79 1117.81 57.71 1054.98 64.19 902.72 77.72 749.35 67.98649.36 73.31 492.25 62.35 421.72 88.37

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3903 .73

3779.91

3458 .65

2941 .85

2870 .95

2668 .632077.36

1715 .62

1438.50

1321.54

1233 .88

1117.81

1054.98

902.72

749.35

649 .36

492.25

421.72

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.4+0.5+0.1.pk

II-04_~2.SP 3601 4000.00 400.00 8.48 99.92 4.00 %T 3 1.00

REF 4000 99.82 2000 97.90 6003428.32 22.80 2941.62 8.58 2665.99 94.01 2077.60 95.25 1715.20 8.481437.55 35.96 1325.75 45.68 1232.42 41.60 1116.63 60.07 1057.58 71.24891.07 76.98 747.44 72.60 647.72 79.84 494.14 66.25 425.63 92.22

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3428 .32

2941 .62

2665.99

2077.60

1715 .20

1 43 7.55

1325 .75

1232 .42

1116 .63

1057 .58

891 .07

747.44

647 .72

494.14

425 .63

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.4+0.4+0.2.pk

II-04_~1.SP 3601 4000.00 400.00 9.60 100.00 4.00 %T 3 1.00

REF 4000 99.86 2000 97.10 6003449.97 12.99 2941.29 11.14 2669.57 95.67 2341.08 96.65 2081.34 94.271714.47 9.59 1436.00 45.77 1320.95 57.65 1230.42 47.28 1118.11 64.731052.38 75.20 898.16 82.88 748.53 69.99 651.04 73.87 492.27 70.29

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3449 .972941 .29

2 669 .5 7

2 341 .0 8

2 081 .3 4

1714 .47

1 43 6.00

132 0.95

123 0.42

1 11 8.11

1 05 2.38

898.16

74 8.53

6 51 .0 4

49 2.27

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.4+0.3+0.3.pk

II-04_~3.SP 3601 4000.00 400.00 10.33 99.81 4.00 %T 3 1.00

REF 4000 99.49 2000 97.98 6003782.74 90.20 3445.73 20.44 2940.76 12.12 2873.13 32.93 2668.75 95.942078.29 96.16 1714.49 10.33 1437.02 47.47 1320.55 57.98 1229.04 49.321118.37 65.05 1052.49 76.98 901.76 83.41 749.13 74.82 651.07 79.66492.04 71.98

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

378 2.7 4

34 45.73

2940 .76

2 873 .1 3

2 66 8.75

2 07 8.29

1714 .49

1 43 7.02

132 0.55

122 9.04

1 11 8.37

1 05 2.49

90 1.76

74 9.13

6 51 .0 7

49 2.04

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.4+0.2+0.4.pk

II-04_~4.SP 3601 4000.00 400.00 8.31 99.99 4.00 %T 3 1.00

REF 4000 97.42 2000 96.27 6003928.07 96.14 3776.04 89.59 3413.97 27.54 2941.65 8.31 2866.83 19.502670.44 88.41 2458.34 96.38 2335.07 95.60 2176.51 93.66 2066.83 93.081970.29 94.93 1872.46 94.87 1714.01 8.95 1442.86 34.27 1313.64 41.611233.61 21.46 1118.48 46.22 1053.23 51.64 904.50 67.82 864.45 79.02750.44 66.04 650.92 78.34 491.29 59.01 413.61 86.68

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3928 .07

3776.04

3413.97

2941 .65

2866.83

2670 .44

2458 .34

2335.07

2176 .51

2066.83

1970.29

1872.46

1714 .01

1442 .86

1313.64

1233 .61

1118.48

1053 .23

904.50

864 .45

750.44

650 .92

491.29

413.61

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.4+0.1+0.5.pk

II5C66~1.SP 3601 4000.00 400.00 6.35 99.20 4.00 %T 3 1.00

REF 4000 99.20 2000 93.16 6003962.41 72.69 3880.74 96.45 3825.22 95.65 3415.84 6.35 2942.37 26.622870.58 56.63 2676.72 95.78 2347.41 88.49 2080.88 87.23 1713.37 12.251642.92 17.62 1425.06 44.56 1324.25 68.36 1238.95 30.16 1116.00 66.991055.52 64.88 741.87 49.84 648.99 45.25 499.30 59.20

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3962.41

3880 .74

3825 .22

3415.84

2942 .37

2870.58

2676 .72

2347.412080.88

1713 .37

1642.92

1425.06

1324 .25

1238.95

1116 .00

1055.52

741 .87

648 .99

499 .30

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.3+0.5+0.2.pk

II-03_~1.SP 3601 4000.00 400.00 7.96 99.96 4.00 %T 3 1.00

REF 4000 99.89 2000 96.26 6003440.05 7.96 2941.00 15.90 2877.47 41.24 2668.67 97.07 2080.46 93.041713.35 11.50 1435.70 51.04 1326.22 64.14 1226.94 70.52 1117.57 73.411039.51 87.11 888.30 86.69 740.76 68.35 649.82 68.86 498.79 70.63

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3440.05

2941 .00

2877.47

2668.67 2080.46

1713 .35

1 43 5.70

1326 .22

1226 .94

1117.57

1039 .5 1

888.30

7 40 .76

649.82

498.79

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.3+0.4+0.3.pk

II-03_~2.SP 3601 4000.00 400.00 9.04 100.00 4.00 %T 3 1.00

REF 4000 99.01 2000 96.54 6003933.85 93.10 3783.51 84.94 3433.03 11.69 2940.29 9.27 2669.71 93.222081.34 92.81 1716.20 9.04 1436.71 35.96 1321.64 48.39 1236.86 25.981117.55 58.50 1050.80 59.00 900.94 77.65 749.61 66.42 649.39 71.54492.70 63.10

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3933.85

3783 .51

3433.032940 .29

2 66 9.7 1

20 81.34

1716 .20

1 43 6.71

132 1.64

1236 .86

1 11 7.55

1050 .80

90 0.94

74 9.61

6 49 .3 9

49 2.70

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.3+0.3+0.4.pk

II-03_~3.SP 3601 4000.00 400.00 10.22 100.00 4.00 %T 3 1.00

REF 4000 99.48 2000 97.92 6003937.63 95.10 3423.01 28.17 2940.67 10.22 2669.30 93.58 2342.90 96.752078.83 95.36 1716.22 11.15 1437.60 39.91 1320.89 50.40 1235.76 30.041117.82 59.69 1052.10 63.20 902.76 79.41 749.99 74.40 649.85 80.86491.88 68.84 424.02 93.79

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 37.63

3423 .01

2940 .67

2669 .30

2 342 .9 0

2 07 8.83

1716 .22

1 43 7.60

132 0.89

1235 .76

1 11 7.82

1052 .10

9 02.76

74 9.99

6 49 .8 5

49 1.88

4 24 .02

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.3+0.2+0.5.pk

II-03_~4.SP 3601 4000.00 400.00 7.99 99.95 4.00 %T 3 1.00

REF 4000 99.78 2000 96.45 6003454.28 7.99 2941.51 14.43 2870.49 35.29 2669.34 95.75 2349.90 96.162080.05 92.87 1714.43 11.76 1647.08 37.48 1437.18 47.02 1321.52 59.691234.73 37.89 1117.61 64.96 1055.13 70.62 902.41 83.62 747.80 66.40649.93 68.45 493.82 67.96

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3454 .28

2941 .51

2870.49

26 69 .34

2349.90

2080.05

1714 .43

1647.08

1437.18

1321.52

1234 .73

1117.61

1055.13

902.41

747.80649 .93

493.82

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.2+0.5+0.3.pk

II-02_~3.SP 3601 4000.00 400.00 11.44 100.00 4.00 %T 3 1.00

REF 4000 99.55 2000 96.55 6003927.85 96.56 3436.37 11.44 2940.73 15.92 2873.45 37.07 2670.05 95.792081.78 93.32 1713.78 11.76 1434.67 46.45 1321.15 59.50 1234.06 43.401118.07 66.45 1052.07 73.76 897.12 83.08 748.41 66.72 650.41 68.99493.13 67.13

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3927 .85

3436.37

2940 .73

2873 .45

2670 .05 2081.78

1713 .78

1434.67

1321.15

1234 .06

1118.07

1052 .07

897.12

748.41650 .41

493.13

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.2+0.4+0.4.pk

II-02_~2.SP 3601 4000.00 400.00 6.35 99.99 4.00 %T 3 1.00

REF 4000 99.29 2000 95.23 6003929.90 89.76 3438.33 6.35 2941.91 16.94 2671.22 95.45 2080.63 91.511714.75 13.36 1434.87 48.11 1322.22 61.05 1229.92 52.70 1118.47 66.671052.81 78.27 895.03 82.96 747.25 61.49 650.76 61.51 494.00 61.43

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3929.90

3438 .33

2941 .91

2671.22

2080.63

1714 .75

1 43 4.87

1322 .22

1229.92

1118.47

1052.81

895.03

747.25

650 .76

494.00

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.2+0.3+0.5.pk

II-02_~1.SP 3601 4000.00 400.00 7.51 100.00 4.00 %T 3 1.00

REF 4000 99.01 2000 97.21 6003940.58 96.76 3470.79 18.71 2940.25 7.51 2669.43 91.92 2344.51 95.912076.52 94.43 1716.72 8.73 1438.31 31.69 1321.29 41.67 1235.19 23.711118.02 53.22 1051.50 57.90 902.61 74.18 750.12 69.96 650.03 78.86492.03 62.46 421.94 92.09

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.58

3470.79

2 94 0.2 5

2669 .43

2 34 4.5 12 07 6.52

1716 .72

1 43 8.31

132 1.29

1235 .19

1 11 8.02

1051 .50

9 02.61

75 0.12

6 50 .0 3

49 2.03

42 1.94

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.1+0.5+0.4.pk

II-01_~2.SP 3601 4000.00 400.00 6.33 99.99 4.00 %T 3 1.00

REF 4000 99.19 2000 95.33 6003928.61 94.91 3441.78 6.33 2942.22 27.15 2672.03 97.64 2087.90 91.531713.58 19.06 1644.45 33.74 1430.48 59.26 1323.47 74.31 1234.44 60.721117.82 75.41 1053.42 81.51 742.89 62.74 649.80 59.88 496.62 67.04

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

392 8.6 1

3 441 .7 8

2942 .22

2672 .03

20 87.90

1713 .58

1 644 .4 5

1430 .48

1323 .47

1234 .44

1 11 7.82

1053 .42

742 .8 9

6 49 .8 0

4 96.62

FTIR SPECT RUM

ACIC


Trichy-2


Date: 17-6-2010

II-0.1+0.4+0.5.pk

II-01_~1.SP 3601 4000.00 400.00 7.98 100.00 4.00 %T 3 1.00

REF 4000 100.00 2000 96.38 6003933.26 87.64 3445.13 7.98 2943.01 13.62 2670.74 96.22 2349.26 93.972085.27 92.19 1716.37 13.14 1433.51 49.31 1321.16 64.71 1238.01 32.961117.30 68.09 1054.27 67.52 747.54 65.20 648.78 64.29 494.42 69.10

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3933.26

3445.13

2943 .01

2670 .74

2349.26

2085.27

1716 .37

1433 .51

1321.16

1238.01

1117 .30

1054 .27747.54

648 .78

494.42

306

Table - 7.25


Cyclohexanone + Hexane + Ethyl Acetate mixture

S1

(Cm-1

)

S2

(Cm-1

)

S3

(Cm-1

)

S4

(Cm-1

)

S5

(Cm-1

)

S6

(Cm-1

)

S7

(Cm-1

)

*S8

(Cm-1

)

S9

(Cm-1

)

3892.113441.462940.472872.492669.532080.521712.601433.341321.921226.981118.531051.43897.00748.28651.26493.18

3429.432940.202873.482669.592074.411714.021437.331321.251225.201118.721051.76900.30749.72651.73491.83418.71

3447.472940.972669.752081.801714.551435.881320.601236.081117.621053.02898.17748.69648.84492.57

3903.733779.913458.652941.852870.952668.632077.361715.621438.501321.541233.881117.811054.98902.72749.35649.36492.25421.72

3428.322941.622665.992077.601715.201437.551325.751232.421116.631057.58891.07747.44647.72494.14425.63

3449.9712.99941.292669.572341.082081.341714.471436.001320.951230.421118.111052.38898.16748.53651.04492.27

3782.743445.732940.762873.132668.752078.291714.491437.021320.551229.041118.371052.49901.76749.13651.07492.04

3928.07

3776.043413.97

2941.65

2866.83

2670.44

2458.34*

2335.07*2176.51*

2066.83

1970.29*

1872.46*

1714.01

1442.861313.64

1233.61

1118.48

1053.23

904.50864.45*

750.44

650.92

3962.413880.743825.223415.842942.372870.582676.722347.412080.881713.371642.921425.061324.251238.951116.001055.52741.87648.99499.30

S10

(Cm-1

)

S11

(Cm-1

)

S12

(Cm-1

)

* S13

(Cm-1

)

S14

(Cm-1

)

S15

(Cm-1

)

S16

(Cm-1

)

S17

(Cm-1

)

S18

(Cm-1

)

3440.052941.002877.472668.672080.461713.351435.701326.221226.941117.571039.51888.30740.76649.82498.79

3933.853783.513433.032940.292669.712081.341716.201436.711321.641236.861117.551050.80900.94749.61649.39492.70

3937.633423.012940.672669.302342.902078.831716.221437.601320.891235.761117.821052.10902.76749.99649.85491.88424.02

3454.28

2941.512870.492669.34

2349.902080.05

1714.431647.081437.18

1321.521234.73

1117.611055.13

902.41747.80649.93

493.82

3927.853436.372940.732873.452670.052081.781713.781434.671321.151234.061118.071052.07897.12748.41650.41493.13

3929.903438.332941.912671.222080.631714.751434.871322.221229.921118.471052.81895.03747.25650.76494.00

3940.583470.792940.252669.432344.512076.521716.721438.311321.291235.191118.021051.50902.61750.12650.03492.03421.94

3928.613441.782942.222672.032087.901713.581644.451430.481323.471234.441117.821053.42742.89649.80496.62

3933.263445.132943.012670.742349.262085.271716.371433.511321.161238.011117.301054.27747.54648.78494.42


307

Fig-7.25: FTIR Spectrum for Cyclohexanone + Heptane + 2-Butanone mixture:

FTIR SPECT RUM

ACIC


Trichy-2

Spectrum Name: K-0.5+0.4+0.1.sp

Date: 16-6-2010

K-0.5+0.4+0.1.pk

K-05_0~2.SP 3601 4000.00 400.00 9.82 99.90 4.00 %T 3 1.00

REF 4000 99.17 2000 98.33 6003927.86 97.62 3790.16 93.89 3431.92 25.82 2939.60 9.82 2671.46 93.032177.81 96.75 1713.01 12.78 1574.71 51.30 1432.52 38.27 1324.44 56.651224.49 62.53 1118.41 68.52 1045.71 80.98 896.35 83.59 747.97 77.57649.10 77.48 492.68 66.69

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3927 .86

3790 .16

3431.92

2939 .60

2 67 1.46

2177 .81

171 3.01

1 574 .7 1

1 432 .5 2

1324 .44

1 22 4.49

1 11 8.41

1 04 5.71896.35

74 7.976 49 .1 0

49 2.68

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.5+0.3+0.2.pk

K-05_0~4.SP 3601 4000.00 400.00 10.23 99.76 4.00 %T 3 1.00

REF 4000 97.55 2000 96.74 6003910.00 95.60 3786.93 91.42 3424.99 40.85 2941.19 10.60 2670.37 90.022076.42 95.29 1966.64 95.90 1714.75 10.23 1578.58 69.76 1435.16 37.391323.23 49.60 1223.13 53.11 1119.07 60.85 1050.79 77.48 900.51 77.23750.13 75.49 651.57 83.89 491.53 65.50 425.55 89.97

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 10.00

3 786 .9 3

3424 .99

2941 .19

2 670 .3 7

2 07 6.42

196 6.64

1714 .75

15 78.58

1 43 5.16

1323 .23

1223 .13

1 11 9.07

1 05 0.7 9

90 0.5175 0.13

6 51 .5 7

49 1.53

42 5.55

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.5+0.2+0.3.pk

K-05_0~1.SP 3601 4000.00 400.00 8.75 100.00 4.00 %T 3 1.00

REF 4000 99.23 2000 98.37 6003921.77 96.69 3789.69 91.84 3423.93 32.60 2940.97 8.75 2670.55 89.902179.10 96.60 1715.03 10.38 1572.28 64.52 1434.25 37.82 1324.60 52.741222.75 56.65 1119.21 64.61 1050.66 81.78 903.28 81.96 749.93 78.31651.23 84.13 491.60 68.24 426.96 91.12

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3921.77

3789 .69

3423 .93

2940 .97

2670.55

2179 .10

1715 .03

1572.28

1434.25

1324 .601222 .75

1119.21

1050.66

903.28 749.93

651 .23

491.60

426 .96

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.5+0.1+0.4.pk

K-05_0~3.SP 3601 4000.00 400.00 8.54 99.97 4.00 %T 3 1.00

REF 4000 98.04 2000 97.28 6003908.21 96.15 3785.54 90.33 3429.85 23.73 2941.21 8.54 2669.44 89.092079.95 95.38 1962.54 96.49 1716.16 10.22 1573.60 53.11 1434.92 28.751327.58 44.24 1224.33 53.20 1120.34 61.64 1042.09 77.27 894.64 78.25749.25 74.91 648.82 80.41 494.07 64.16 427.00 89.24

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3908.21

3785 .54

3429 .85

2941 .21

2669 .44

2079 .95

1962.54

1716 .16

1573.60

1434.92

1327 .58

1224.33

1120.34

1042 .09

894.64749.25

648 .82

494.07

427.00

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.4+0.5+0.1.pk

K-04_0~4.SP 3601 4000.00 400.00 7.28 100.00 4.00 %T 3 1.00

REF 4000 99.33 2000 98.32 6003940.31 96.10 3789.34 95.35 3414.34 42.10 2940.68 7.28 2669.87 84.642179.43 95.50 1963.83 96.77 1713.60 12.96 1578.02 66.37 1435.79 28.761324.42 41.48 1224.00 47.47 1119.07 56.32 1051.25 72.17 897.80 71.50750.46 72.61 651.98 85.08 491.83 63.74 419.22 93.12

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.31

3789.34

3414.34

2940.68

2669.87

2179 .431963.83

1713 .60

1578.02

1 43 5.79

1324 .42

1224.00

1119.07

1051.25

897.80 750.46

651 .98

491.83

419 .22

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.4+0.4+0.2.pk

K-04_0~3.SP 3601 4000.00 400.00 8.00 100.00 4.00 %T 3 1.00

REF 4000 99.23 2000 98.31 6003928.28 97.12 3789.41 94.26 3420.18 32.19 2940.99 8.00 2670.15 88.972179.02 96.30 1964.93 97.41 1713.81 10.65 1574.36 61.29 1434.77 32.151324.45 47.04 1223.17 52.20 1119.06 60.14 1050.64 76.91 900.45 77.75750.07 75.44 651.50 83.69 491.72 66.40 423.61 92.14

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3928 .28

3789 .41

3420 .18

2940 .99

2 67 0.15

217 9.02

1 96 4.93

1713 .81

1574 .36

1 43 4.77

1324 .45

1223 .17

1 11 9.06

1 05 0.6 4

90 0.4575 0.07

6 51 .5 0

49 1.72

4 23 .6 1

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.4+0.3+0.3.pk

K-04_0~2.SP 3601 4000.00 400.00 7.64 99.90 4.00 %T 3 1.00

REF 4000 98.11 2000 97.27 6003932.99 97.00 3793.34 93.61 3429.45 23.44 2940.41 7.64 2670.46 90.962178.76 95.19 1714.52 8.80 1573.96 48.63 1432.97 31.01 1327.84 49.241223.41 56.27 1119.31 63.99 1046.46 78.38 897.42 80.35 748.74 75.72649.36 78.36 492.56 64.76

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 32.99

3793 .34

3 429 .4 5

2940 .41

2670 .46

2178 .76

1714 .52

1 57 3.96

1 432 .9 7

1327 .84

1223 .41

1 11 9.31

10 46.46

897.42

74 8.746 49 .3 6

49 2.56

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.4+0.2+0.4.pk

K-3DF8~1.SP 3601 4000.00 400.00 7.49 99.92 4.00 %T 3 1.00

REF 4000 99.78 2000 98.87 6003935.52 97.82 3787.95 95.14 3420.38 44.36 2938.54 7.49 2669.98 87.492182.12 97.01 1965.25 97.69 1714.08 10.56 1436.94 30.32 1326.48 40.341225.12 47.69 1119.13 57.37 1049.50 72.60 896.53 71.96 750.88 75.38651.65 88.20 492.57 65.54

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3935 .52

3787 .95

3420 .38

2938.54

2669.98

2182 .121965.25

1714 .08

1436.94

1326 .48

1225.12

1119.13

1049.50

896.53750.88

651 .65

492.57

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.4+0.1+0.5.pk

K-04_0~1.SP 3601 4000.00 400.00 7.71 100.00 4.00 %T 3 1.00

REF 4000 99.37 2000 98.60 6003939.35 98.30 3782.97 95.53 3422.52 34.32 2940.57 7.71 2669.78 89.422345.21 96.10 2178.23 96.51 1963.79 97.33 1715.76 8.45 1435.12 28.421335.01 40.96 1222.43 47.63 1119.70 57.17 1052.44 75.66 904.43 74.39750.89 72.98 652.15 85.39 492.57 64.82 420.48 93.12

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3939 .35

3782.97

3422 .52

2940 .57

2669.78

2345.21

2178 .23

1963.79

1715 .76

1435.12

1335.01

1222 .43

1119.70

1052 .44

904.43750.89

652 .15

492.57

420.48

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.3+0.5+0.2.pk

K-03_0~1.SP 3601 4000.00 400.00 7.38 100.00 4.00 %T 3 1.00

REF 4000 99.31 2000 98.39 6003940.88 97.51 3417.95 33.69 2941.00 7.38 2669.86 87.62 2345.42 96.992178.74 95.74 1965.21 97.00 1713.52 10.84 1571.88 58.34 1434.72 28.051325.91 43.04 1223.62 48.99 1119.13 57.91 1051.31 74.24 898.85 74.30750.38 73.48 652.02 84.58 491.91 65.77 420.72 93.08

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.88

3417 .95

2941.00

2669.86

2345.42

2178.74

1965.21

1713 .52

1571.88

1 43 4.72

1325 .91

1223 .62

1119.13

1051.31

898.85750.38

652 .02

491.91

420.72

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.3+0.4+0.3.pk

K-03_0~2.SP 3601 4000.00 400.00 7.51 100.00 4.00 %T 3 1.00

REF 4000 99.73 2000 98.89 6003947.72 98.61 3430.93 33.97 2941.02 7.51 2669.64 92.03 2348.64 94.442180.13 97.06 1715.30 10.34 1436.36 33.99 1328.82 48.36 1223.57 55.351119.68 64.00 1048.33 79.43 897.48 79.89 749.82 77.84 651.40 84.62492.57 67.46

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3947.72

3430 .93

29 41.02

2 66 9.64

234 8.64

2 180 .1 3

1715 .30

1 43 6.36

1328 .82

1223 .57

1 11 9.68

1 04 8.33

897.4874 9.82

6 51 .4 0

49 2.57

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.3+0.3+0.4.pk

K-03_0~3.SP 3601 4000.00 400.00 7.65 99.93 4.00 %T 3 1.00

REF 4000 99.83 2000 99.04 6003943.56 98.35 3425.28 37.78 2939.81 7.65 2670.06 89.88 2179.84 97.171964.98 98.03 1714.55 10.79 1435.72 31.90 1331.72 44.84 1223.42 53.481120.29 63.14 1049.65 78.05 897.72 77.50 750.66 77.54 651.06 87.20493.15 69.19

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 43.56

3425 .28

2939 .81

2 67 0.0 6

2179 .84

1 96 4.98

1714 .55

1 43 5.72

1 33 1.72

1223 .42

1 12 0.29

10 49.65

897.72 75 0.66

6 51 .0 6

49 3.15

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.3+0.2+0.5.pk

K-03_0~4.SP 3601 4000.00 400.00 9.73 100.00 4.00 %T 3 1.00

REF 4000 99.35 2000 98.42 6003937.80 97.43 3789.03 93.55 3430.72 31.63 2941.48 9.72 2671.13 92.682178.21 96.79 1715.95 10.37 1572.30 63.99 1433.51 38.82 1333.54 54.931221.97 60.15 1119.54 68.23 1050.87 84.74 904.72 84.64 749.81 78.61651.05 83.22 492.07 69.32

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3937.80

3789.03

3430 .72

2941 .48

2671.13

2178 .21

1715 .95

1572.30

1433 .51

1333.54

1221 .97

1119.54

1050 .87

904.72

749.81

651 .05

492.07

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.2+0.5+0.3.pk

K-02_0~3.SP 3601 4000.00 400.00 7.30 100.00 4.00 %T 3 1.00

REF 4000 98.92 2000 97.87 6003943.92 97.27 3782.24 95.36 3423.57 23.43 2941.77 7.30 2670.35 89.352343.26 96.51 2178.69 95.36 1965.92 96.87 1713.95 12.16 1571.43 48.291433.03 27.28 1328.58 44.75 1223.24 51.41 1119.32 59.60 1050.59 76.06902.02 76.81 749.97 71.82 651.31 77.25 492.18 59.82 428.14 86.56

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3943.92

3782.24

3423 .57

2941 .77

2670.35

2343.26

2178.69

1965.92

1713 .95

1571.43

1433 .03

1328 .58

1223 .24

1119.32

1050 .59902.02

749.97

651 .31

492.18

428.14

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.1+0.5+0.4.pk

K-01_0~1.SP 3601 4000.00 400.00 7.26 99.83 4.00 %T 3 1.00

REF 4000 99.12 2000 97.67 6003786.76 91.53 3445.99 9.56 2944.90 7.26 2671.36 94.64 2104.10 95.201717.82 12.62 1568.48 39.46 1429.48 33.03 1338.72 56.45 1221.64 64.051119.82 70.14 1048.26 84.62 904.89 86.55 748.22 69.83 650.71 67.40493.63 61.30

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3786.76

3445.99 2944.90

2671.36

2104.10

1717 .82

1568 .48

1429 .48

1338 .72

1221 .64

1119.82

1048.26

904.89

748.22650 .71

493.63

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.2+0.4+0.4.pk

K-02_0~1.SP 3601 4000.00 400.00 7.34 99.80 4.00 %T 3 1.00

REF 4000 99.71 2000 98.70 6003944.50 97.61 3794.25 96.99 3427.73 27.70 2941.41 7.34 2670.18 87.972344.69 97.32 2079.93 96.27 1965.12 97.41 1715.21 9.63 1436.37 29.101334.74 41.04 1223.01 50.79 1120.98 60.60 1050.75 76.07 897.51 74.68750.87 73.60 651.62 86.35 493.53 67.62

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3944.50

3794 .25

3427 .73

29 41.41

2 67 0.1 8

2 34 4.6 9

2079 .93

1 96 5.12

1715 .21

1 43 6.37

133 4.74

1223 .01

1 12 0.98

1 05 0.7 5

897.51 75 0.87

6 51 .6 2

49 3.53

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.2+0.3+0.5.pk

K-02_0~2.SP 3601 4000.00 400.00 7.19 99.97 4.00 %T 3 1.00

REF 4000 99.64 2000 98.71 6003783.94 94.21 3437.78 14.35 2941.84 7.19 2670.71 91.00 2097.07 96.081716.78 10.28 1570.26 41.98 1432.44 24.87 1338.93 42.62 1221.12 54.711122.09 64.10 1048.51 80.76 899.21 81.68 749.44 73.14 649.81 76.63494.34 63.76

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

378 3.94

34 37.78

2 94 1.84

2 67 0.71

2097 .07

1716 .78

1 570 .2 6

1 432 .4 4

1338 .93

1221 .12

1 12 2.09

1048 .51

899.21

74 9.44

6 49 .8 1

49 4.34

FTIR SPECT RUM

ACIC


Trichy-2


Date: 16-6-2010

K-0.1+0.4+0.5.pk

K-01_0~2.SP 3601 4000.00 400.00 6.39 99.86 4.00 %T 3 1.00

REF 4000 98.58 2000 96.89 6003975.43 97.27 3886.01 96.99 3781.74 91.07 3444.68 6.39 2945.92 9.082107.05 94.09 1721.48 13.74 1641.72 41.92 1570.05 32.40 1427.04 30.791219.57 67.56 1173.29 68.82 1121.09 71.98 1045.98 84.96 907.65 89.57747.82 68.49 649.51 63.03 495.14 59.83

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3975 .43

3886.01

3781.74

3444.68 2945.92

2107.05

1721 .48

1641 .72

1570 .051427.04

1219 .57

1173.29

1121 .09

1045.98

907.65

747.82

649 .51

495.14

308

Table - 7.26

Observations of FTIR Spectrum for

Cyclohexanone + Heptane + 2-Butanone mixture

S1

(Cm-1

)

*S2

(Cm-1

)

S3

(Cm-1

)

S4

(Cm-1

)

S5

(Cm-1

)

S6

(Cm-1

)

S7

(Cm-1

)

S8

(Cm-1

)

S9

(Cm-1

)

3927.863790.163431.922939.602671.462177.811713.011574.711432.521324.441224.491118.411045.71896.35747.97649.10492.68

3910.00

3786.933424.99

2941.19

2670.37

2076.42*

1966.64*

1714.751578.58

1435.16

1323.23

1223.13

1119.07

1050.79900.51

750.13

651.57

491.53

425.55

3921.773789.693423.932940.972670.552179.101715.031572.281434.251324.601222.751119.211050.66903.28749.93651.23491.60426.96

3908.213785.543429.852941.212669.442079.951962.541716.161573.601434.921327.581224.331120.341042.09894.64749.25648.82494.07427.00

3940.313789.343414.342940.682669.872179.431963.831713.601578.021435.791324.421224.001119.071051.25897.80750.46651.98491.83419.22

3928.283789.413420.182940.992670.152179.021964.931713.811574.361434.771324.451223.171119.061050.64900.45750.07651.50491.72423.61

3932.993793.343429.452940.412670.462178.761714.521573.961432.971327.841223.411119.311046.46897.42748.74649.36492.56

3935.523787.953420.382938.542669.982182.121965.251714.081436.941326.481225.121119.131049.50896.53750.88651.65492.57

3939.353782.973422.522940.572669.782345.212178.231963.791715.761435.121335.011222.431119.701052.44904.43750.89652.15492.57420.48


S10

(Cm-1

)

S11

(Cm-1

)

S12

(Cm-1

)

S13

(Cm-1

)

*S14

(Cm-1

)

S15

(Cm-1

)

S16

(Cm-1

)

S17

(Cm-1

)

S18

(Cm-1

)

3940.883417.952941.002669.862345.422178.741965.211713.521571.881434.721325.911223.621119.131051.31898.85750.38652.02491.91420.72

3947.723430.932941.022669.642348.642180.131715.301436.361328.821223.571119.681048.33897.48749.82651.40492.57

3943.563425.282939.812670.062179.841964.981714.551435.721331.721223.421120.291049.65897.72750.66651.06493.15

3937.803789.033430.722941.482671.132178.211715.951572.301433.511333.541221.971119.541050.87904.72749.81651.05492.07

3943.92

3782.243423.572941.77

2670.352343.26

2178.691965.92

1713.951571.431433.03

1328.581223.24

1119.321050.59902.02

749.97651.31

492.18428.14

3944.503794.253427.732941.412670.18

2344.692079.931965.121715.211436.371334.741223.011120.981050.75897.51750.87651.62493.53

3783.943437.782941.842670.712097.071716.781570.261432.441338.931221.121122.091048.51899.21749.44649.81494.34

3786.763445.992944.902671.362104.101717.821568.481429.481338.721221.641119.821048.26904.89748.22650.71493.63

3975.433886.013781.743444.682945.922107.051721.481641.721570.051427.041219.571173.291121.091045.98907.65747.82649.51495.14


309

Fig-7.26: FTIR Spectrum for Cyclohexanone + Heptane + Ethyl Acetate

mixture:

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.5+0.4+0.1.pk

K-05_0~4.SP 3601 4000.00 400.00 7.72 100.00 4.00 %T 5 1.00

REF 4000 99.01 2000 97.72 6003944.06 95.52 3417.59 31.96 2939.95 7.72 2669.08 91.33 2345.16 95.302176.67 95.39 2071.77 95.23 1713.39 10.73 1437.88 33.99 1323.22 45.301227.06 45.74 1118.72 57.87 1051.08 71.72 897.91 74.03 749.92 71.31651.67 81.65 491.80 64.54 421.36 92.63

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3944.06

3417 .59

2939 .95

2669 .08

2 34 5.1 6

2176 .67

207 1.77

1713 .39

1 43 7.88

1323 .22122 7.06

1 11 8.72

1051 .08897.91

74 9.92

6 51 .6 7

49 1.80

42 1.36

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.5+0.3+0.2.pk

K-05_0~2.SP 3601 4000.00 400.00 5.05 99.67 4.00 %T 5 1.00

REF 4000 98.59 2000 95.34 6003936.07 95.48 3428.39 5.05 2942.61 30.93 2870.92 59.30 2673.75 96.252077.54 91.12 1713.80 15.21 1641.00 23.84 1424.92 45.14 1328.29 70.061225.09 72.97 1118.90 67.80 1052.79 84.31 742.95 57.43 650.23 54.04496.89 63.92

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 36.07

3 42 8.39

2942 .61

287 0.92

2673 .75

2 07 7.54

1713 .80

1641 .00

142 4.92

1 32 8.29

1 22 5.09

1 11 8.90

1 05 2.79

742 .9 5

65 0.23

4 96.89

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.5+0.2+0.3.pk

K-05_0~3.SP 3601 4000.00 400.00 9.59 100.00 4.00 %T 5 1.00

REF 4000 99.32 2000 98.07 6003938.05 96.77 3417.23 29.49 2941.26 12.04 2871.55 26.38 2668.92 92.972343.79 96.42 2074.57 95.36 1715.16 9.59 1437.91 34.75 1322.66 47.311232.44 33.70 1118.22 56.05 1053.78 64.96 902.70 76.07 750.04 70.82650.00 78.91 492.25 65.04 419.06 91.88

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3938 .05

3417 .23

2941 .26

2871.55

2668 .92

2343.79

2074.57

1715 .16

1437.91

1322 .66

1232 .44

1118.22

1053.78

902.70

750.04

650 .00

492.25

419 .06

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.5+0.1+0.4.pk

K-05_0~1.SP 3601 4000.00 400.00 6.34 100.00 4.00 %T 5 1.00

REF 4000 99.11 2000 95.70 6003935.19 94.03 3428.11 6.34 2941.62 13.91 2871.43 31.14 2669.69 94.042340.84 95.23 2078.34 91.31 1713.68 8.16 1435.14 34.49 1322.68 50.151234.32 30.26 1117.70 56.93 1054.45 63.96 901.86 76.88 748.13 56.85649.94 59.34 493.57 58.08

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3935.19

3428 .11

2941 .62

2871.43

2669 .69

2340.84

2078.34

1713 .68

1435.14

1322 .68

1234 .32

1117.70

1054.45

901.86

748.13649 .94 493.57

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.4+0.5+0.1.pk

K-04_0~2.SP 3601 4000.00 400.00 7.79 99.99 4.00 %T 5 1.00

REF 4000 97.58 2000 96.34 6003945.35 92.87 3833.35 94.76 3501.50 45.15 3413.85 43.26 2941.07 7.792872.51 20.19 2669.03 88.55 2348.24 93.11 2177.35 93.90 2070.87 93.921965.04 95.19 1713.82 11.00 1438.81 34.08 1323.41 44.64 1226.25 44.501118.88 55.61 1055.61 71.13 902.15 72.43 750.20 71.84 651.75 82.91491.90 64.24 419.41 91.14

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3945.35

3833.35

3501 .50

3413 .85

2941 .07

2872 .51

2669 .03

2348.24

2177.35

2070 .87

1965.04

1713 .82

1 43 8.81

1323 .41

1226.25

1118 .88

1055.61

902.15 750.20

651 .75

491.90

419.41

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.4+0.4+0.2.pk

K-04_0~4.SP 3601 4000.00 400.00 8.61 100.00 4.00 %T 5 1.00

REF 4000 99.25 2000 97.20 6003940.61 95.40 3419.72 26.55 2942.26 8.61 2669.27 92.07 2345.81 92.902075.38 94.24 1714.31 9.40 1438.09 36.51 1322.80 48.27 1231.33 39.791118.38 57.89 1052.07 67.95 898.59 76.31 749.75 70.11 651.25 77.79492.05 65.16 422.41 93.28

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940 .61

3419 .72

2942 .26

2669 .27

2 34 5.81

2 075 .3 8

1714 .31

1 43 8.09

1322 .80

123 1.33

1 11 8.38

1052 .07

898.59

74 9.75

6 51 .2 5

49 2.05

42 2.41

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.4+0.3+0.3.pk

K-04_0~3.SP 3601 4000.00 400.00 7.82 100.00 4.00 %T 5 1.00

REF 4000 99.37 2000 98.30 6003944.64 96.25 3417.01 40.21 2939.51 7.82 2669.02 92.20 2344.70 96.382074.65 95.96 1715.94 11.30 1438.07 35.30 1322.61 46.61 1233.34 35.751118.15 59.17 1050.34 65.49 900.40 76.71 750.32 75.62 650.61 85.23491.77 68.07 419.26 94.32

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

394 4.64

3417 .01

2939 .51

2669 .02

2 344 .7 0

207 4.65

1715 .94

1 43 8.07

1322 .61

1233 .34

1 11 8.15

1050 .34

90 0.4075 0.32

6 50 .6 1

49 1.77

41 9.26

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.4+0.2+0.4.pk

K-04_0~1.SP 3601 4000.00 400.00 7.77 100.00 4.00 %T 5 1.00

REF 4000 99.21 2000 96.92 6003943.67 93.28 3420.18 19.86 2940.47 7.77 2669.30 91.57 2345.73 93.852075.56 93.65 1714.42 9.43 1436.17 33.41 1322.71 46.02 1232.34 35.861118.37 56.41 1051.62 65.84 898.42 75.36 749.76 67.25 650.88 74.13492.31 63.19 424.67 92.31

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3943.67

3420 .18

2940 .47

26 69 .30

2345.73

2075 .56

1714 .42

1436.17

1322 .71

1232 .34

1118.37

1051.62

898.42

749.76

650 .88

492.31

424.67

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.4+0.1+0.5.pk

K-3309~1.SP 3601 4000.00 400.00 10.75 100.00 4.00 %T 5 1.00

REF 4000 99.34 2000 97.42 6003946.87 94.31 3424.23 19.82 2941.04 15.40 2670.39 93.77 2346.47 93.222079.66 94.18 1715.56 10.74 1435.57 38.71 1321.67 51.82 1237.15 27.011117.47 59.41 1052.08 59.90 900.92 78.67 749.66 68.52 649.22 72.71492.30 65.32

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3946.87

3424 .23

2941 .04

2670 .39

2346 .47

2079.66

1715 .56

1435.57

1321.67

1237 .15

1117 .47

1052.08

900.92

749.66649 .22

492.30

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.3+0.5+0.2.pk

K-03_0~4.SP 3601 4000.00 400.00 8.03 100.00 4.00 %T 5 1.00

REF 4000 99.56 2000 95.83 6003431.37 8.24 2940.07 8.25 2669.06 94.48 2344.99 91.44 2083.01 91.931712.57 8.03 1435.17 37.18 1325.52 52.74 1226.18 57.63 1118.24 64.301049.38 80.57 891.66 78.32 746.08 60.24 651.75 62.19 495.09 60.19

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3431.37 2940 .07

2669 .06

2344 .99

2083.01

1712.57

1 43 5.17

1325.52

1226.18

1118.24

1049.38

891 .66

746.08651 .75

495.09

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.3+0.4+0.3.pk

K-03_0~2.SP 3601 4000.00 400.00 7.32 100.00 4.00 %T 5 1.00

REF 4000 99.19 2000 95.61 6003932.40 91.73 3428.81 7.32 2942.27 8.60 2669.06 92.32 2345.27 89.072078.20 91.38 1714.23 8.63 1435.39 30.82 1323.24 45.18 1230.51 38.021118.51 54.93 1052.11 68.08 896.81 73.72 748.97 57.31 651.64 61.67493.00 56.67

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3932 .40

3428.81 2942 .27

266 9.06

2 34 5.27

2 07 8.20

1714 .23

1 43 5.39

1323 .24

123 0.51

1 11 8.51

1052 .11

896.81

74 8.97

6 51 .6 4

49 3.00

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.3+0.3+0.4.pk

K-03_0~3.SP 3601 4000.00 400.00 8.96 99.99 4.00 %T 5 1.00

REF 4000 99.24 2000 97.14 6003929.40 92.91 3423.67 19.72 2940.30 8.96 2667.06 90.27 2345.24 92.362079.20 93.85 1715.77 10.62 1437.52 33.55 1325.66 44.16 1235.59 30.931116.43 58.00 1051.10 60.53 895.88 73.70 750.06 71.39 649.22 79.20492.99 66.81

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3929 .40

3423 .67

2940 .30

2 667 .0 6

2 34 5.2 42 079 .2 0

1715 .77

1 43 7.52

1325 .66

1235 .59

1 11 6.43

1051 .10

895.8875 0.06

6 49 .2 2

49 2.99

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.3+0.2+0.5.pk

K-03_0~1.SP 3601 4000.00 400.00 8.95 100.00 4.00 %T 5 1.00

REF 4000 99.50 2000 96.86 6003944.76 93.92 3425.73 14.73 2941.88 10.45 2670.38 93.64 2347.95 86.762080.56 93.37 1714.99 8.95 1434.78 38.33 1322.07 53.22 1235.84 30.071117.82 60.16 1053.25 64.44 898.30 79.35 749.08 66.20 650.67 69.09492.34 64.57

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3944 .76

3425 .732941 .88

2670 .38

2347.95

2080.56

1714 .99

1434.78

1322 .07

1235 .84

1117.82

1053.25

898.30

749.08

650 .67

492.34

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.2+0.5+0.3.pk

K-02_0~3.SP 3601 4000.00 400.00 6.36 100.00 4.00 %T 5 1.00

REF 4000 99.64 2000 95.36 6003433.41 6.36 2940.71 8.57 2669.63 94.75 2345.14 90.42 2085.22 91.141711.52 8.75 1435.85 35.89 1325.99 51.63 1230.55 48.18 1117.67 63.401051.18 75.48 891.42 77.55 745.95 57.59 651.24 58.82 495.53 57.69

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3433.41 2940 .71

2669 .63

2345.14

2085.22

1711.52

1435.85

1325 .99

1230 .55

1117.67

1051.18

891 .42

745.95651 .24

495.53

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.2+0.4+0.4.pk

K-02_0~1.SP 3601 4000.00 400.00 7.77 99.99 4.00 %T 5 1.00

REF 4000 99.78 2000 97.79 6003936.14 92.82 3422.05 19.31 2940.74 7.77 2667.76 90.61 2345.22 93.072078.36 94.23 1715.16 7.91 1437.48 27.77 1325.98 39.34 1235.37 27.071116.82 53.20 1050.83 56.99 895.80 70.96 749.96 67.67 648.68 75.98492.77 61.40

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3936 .14

3422 .05

2940 .74

2667 .76

2345 .22

2078.36

1715 .16

1 43 7.48

1325 .98

1235 .37

1116 .82

1050.83

895.80

749.96

648 .68

492.77

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.2+0.3+0.5.pk

K-02_0~2.SP 3601 4000.00 400.00 6.47 100.00 4.00 %T 5 1.00

REF 4000 99.40 2000 95.31 6003937.80 93.56 3430.31 6.47 2940.52 12.96 2669.13 95.06 2345.12 90.472086.15 91.25 1712.32 13.75 1434.25 44.34 1327.01 59.93 1235.33 44.091116.26 69.62 1052.76 74.12 744.88 61.21 650.36 60.87 496.68 64.50

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3937.80

3430 .31

2940 .52

2669 .13

2 34 5.12

20 86.15

171 2.32

1 43 4.25

1327 .01

1235 .33

1116 .26

1052 .76

744 .8 86 50 .3 6

4 96.68

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.1+0.5+0.4.pk

K-01_0~2.SP 3601 4000.00 400.00 6.37 99.99 4.00 %T 5 1.00

REF 4000 99.64 2000 95.09 6003943.60 92.37 3432.37 6.37 2942.20 15.49 2670.47 96.19 2345.96 89.232087.49 90.63 1711.83 17.53 1432.99 46.53 1330.69 64.45 1234.50 53.871116.82 71.73 1052.89 78.45 742.59 59.47 650.25 57.11 499.30 63.38

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

394 3.60

3432 .37

2942 .20

267 0.47

2 34 5.9 6

20 87.49

171 1.83

1 432 .9 9

1 33 0.69

1234 .50

1116 .82

1052 .89

7 42 .596 50 .2 5

4 99 .3 0

FTIR SPECT RUM

ACIC


Trichy-2


Date: 24-6-2010

K-0.1+0.4+0.5.pk

K-01_0~1.SP 3601 4000.00 400.00 7.60 99.95 4.00 %T 5 1.00

REF 4000 99.58 2000 96.45 6003948.86 95.05 3429.04 8.74 2943.15 7.89 2670.55 94.64 2346.05 90.322083.81 91.98 1716.58 7.60 1436.18 30.09 1328.88 46.11 1237.89 19.221115.47 55.72 1053.57 54.30 894.85 77.04 747.80 60.40 646.77 61.44494.61 59.17

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3948.86

3429 .04 2943 .15

2670 .55

2346 .05

2083.81

1716 .58

1436.18

1328 .88

1237.89

1115 .47

1053.57

894.85

747.80

646 .77

494.61

310

Table - 7.27

Observations of FTIR Spectrum for

Cyclohexanone + Heptane + Ethyl Acetate mixture

S1

(Cm-1

)

S2

(Cm-1

)

S3

(Cm-1

)

S4

(Cm-1

)

*S5

(Cm-1

)

S6

(Cm-1

)

S7

(Cm-1

)

S8

(Cm-1

)

S9

(Cm-1

)

3944.063417.592939.952669.082345.162176.672071.771713.391437.881323.221227.061118.721051.08897.91749.92651.67491.80421.36

3936.073428.392942.612870.922673.752077.541713.801641.001424.921328.291225.091118.901052.79742.95650.23496.89

3938.053417.232941.262871.552668.922343.792074.571715.161437.911322.661232.441118.221053.78902.70750.04650.00492.25419.06

3935.193428.112941.622871.432669.692340.842078.341713.681435.141322.681234.321117.701054.45901.86748.13649.94493.57

3945.35

3833.35*3501.50*

3413.85

2941.07

2872.51

2669.03

2348.242177.35*

2070.87

1965.04

1713.82

1438.81

1323.411226.25

1118.88

1055.61

902.15

750.20651.75

491.90

419.41

3940.613419.722942.262669.272345.812075.381714.311438.091322.801231.331118.381052.07898.59749.75651.25492.05422.41

3944.643417.012939.512669.022344.702074.651715.941438.071322.611233.341118.151050.34900.40750.32650.61491.77419.26

3943.673420.182940.472669.302345.732075.561714.421436.171322.711232.341118.371051.62898.42749.76650.88492.31424.67

3946.873424.232941.042670.392346.472079.661715.561435.571321.671237.151117.471052.08900.92749.66649.22492.30


S10

(Cm-1

)

S11

(Cm-1

)

S12

(Cm-1

)

S13

(Cm-1

)

S14

(Cm-1

)

S15

(Cm-1

)

S16

(Cm-1

)

S17

(Cm-1

)

S18

(Cm-1

)

3431.372940.072669.062344.992083.011712.571435.171325.521226.181118.241049.38891.66746.08651.75495.09

3932.403428.812942.272669.062345.272078.201714.231435.391323.241230.511118.511052.11896.81748.97651.64493.00

3929.403423.672940.302667.062345.242079.201715.771437.521325.661235.591116.431051.10895.88750.06649.22492.99

3944.763425.732941.882670.382347.952080.561714.991434.781322.071235.841117.821053.25898.30749.08650.67492.34

3433.412940.712669.632345.142085.221711.521435.851325.991230.551117.671051.18891.42745.95651.24495.53

3936.143422.052940.742667.762345.222078.361715.161437.481325.981235.371116.821050.83895.80749.96648.68492.77

3937.803430.312940.522669.132345.122086.151712.321434.251327.011235.331116.261052.76744.88650.36496.68

3943.603432.372942.202670.472345.962087.491711.831432.991330.691234.501116.821052.89742.59650.25499.3063.38

3948.863429.042943.152670.552346.052083.811716.581436.181328.881237.891115.471053.57894.85747.80646.77494.61


311

Fig-7.27: FTIR Spectrums for Cyclohexanone+2-Butanone+Benzaldehyde

mixture:

FTIR SPECTRUM

ACIC


Spectrum Name: SJC-Ph-D-1.spDate: 03-12-2009

SJC-Ph-D-1.pk

SJB907~1.SP 3601 4000.00 400.00 7.45 99.05 4 .00 %T 5 1.00

REF 4000 88.78 2000 87.99 6003927.97 85.91 3788.49 84.61 3420.47 16.33 2940.99 11.72 2865.29 26.252673.39 80.60 2176.04 84.99 1804.84 79.55 1712.31 7.45 1595.46 15.291448.22 39.98 1350.61 30.91 1314.28 45.22 1222.68 48.05 1172.66 77.181119.36 54.46 1054.67 75.08 1018.13 79.40 905 .15 71 .81 863.72 76.49751.78 60.58 651.14 69.69 491 .59 56 .71 413.27 80.34

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3927.97

3788.49

3420.47

2940.99

2865.29

2673.39

2176.04

1804.84

1712.31

1595.46

1448.22

1350.61

1314.28

1222.68

1172.66

1119.36

1054.67

1018.13

905.15

863.72

751.78

651.14

491.59

413.27

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-Ph-D-2.sp

Date: 03-12-2009

SJC-Ph-D-2.pk

SJB90 3~1.SP 3601 4000.00 400.00 6.31 99.58 4.00 %T 5 1.0 0

REF 4 000 87.29 2000 85.89 6003931.42 82.79 3784.96 81.45 3439.70 6.31 2941.24 11.45 2865.46 27.102673.92 79.58 2175.84 82.26 1711.17 8.85 1595.42 7.48 144 4.52 40.171351.08 26.73 1223.19 49.72 1119.18 55.77 1055.20 73.03 1018.91 77.60903.33 70 .43 861.50 72.39 753.18 53.4 9 649.71 59.94 559.88 61.46492.38 52 .58

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3931.42

3 784.96

3439.70

294 1.24

2865.46

2673.92

2175.84

17 11.171595.42

1444.52

1351.08

1223.19

111 9.18

1055.20

1018.91

903.33

861.50

753.18

64 9.71

559.8 8

4 92.38

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-3.pk

SJB90 F~1.SP 3601 4000.00 400 .00 7.42 98.98 4.00 %T 5 1.00

REF 4 000 86.78 2000 86.01 6003927.93 83.62 3790.58 81.90 3420.01 13.77 2940.97 9.61 2864.86 23.692672.36 78.90 2175.61 82.90 1712.05 7.42 1595.16 12.54 1448.21 38.641350.34 29.32 1314.07 42.85 1223.85 43.49 1119.18 50.95 1054.15 67.921018.47 74.60 904.99 68 .67 863.56 73.12 751.69 57.26 650.90 65.91491.47 53 .39 413.32 78.61

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3927.93

3790.58

3420.01

294 0.97

2864.86

2672.36

2175.61

17 12.05

1595.16

1448.21

1350.34

1314.07

1223.85

111 9.18

1054.15

1018.47

904.99

863 .56

751.69

650.90

4 91.47

413 .32

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-4.pk

SJC90B~1.SP 3601 4000.00 400.00 7.08 99.87 4.00 %T 5 1.00

REF 4 000 88.63 2000 87.88 6003931.53 85.79 3788.52 83.89 3431.58 11.94 2940.55 11.10 2864.88 27.742673.57 82.37 2175.76 84.89 1711.36 7.08 1595.65 10.34 1444.00 44.441351.62 31.26 1222.89 52.77 1119.36 56.47 1055.56 73.99 1020.15 78.02903.29 73 .90 861.26 78.65 754.07 61.1 6 649.91 68.43 492.04 56.65416.20 81 .52

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3931.53

3788.52

3431.58 294 0.55

2864.88

2 673.57

2175.76

17 11.361595.65

1444.00

1351.62

1222.8 9

1119.36

1055.56

1020.15

903.29

861 .26

754.07

64 9.91

4 92.04

416.20

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-5.pk

SJC907~1.SP 3601 4000.00 400 .00 8.04 99.68 4.00 %T 5 1.00

REF 4 000 89.65 2000 88.80 6003928.10 87.41 3431.36 18.95 2940.81 13.01 2865.60 30.40 2672.60 83.272175.71 86.26 1711.82 8.04 1595.38 20.53 1445.16 44.62 1348.36 39.861225.70 46.88 1119.05 58.07 1054.63 72.76 904.11 73.92 862.80 78.05752.07 64 .08 649.90 71.91 491.94 60.4 2 414.55 83.95

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3928.10

3 431.36

294 0.81

2865.6 0

2672.60

2175.71

17 11.82

1595.38

1445.16

1348.36

1225.70

111 9.05

1054.63

904.11

862.8 0

752.07

6 49.90

4 91.94

414.55

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-6.pk

SJC903~1.SP 3601 4000.00 400 .00 5.30 99.43 4.00 %T 5 1.00

REF 4 000 81.31 2000 80.29 6003927.50 76.71 3793.60 72.92 3436.14 5.61 2942.42 14.95 2866.09 32.342173.53 76.45 1712.65 11.57 1594.99 5.30 1444.42 42.25 1353.25 22.811227.85 48.63 1172.47 71.60 1119.18 59.91 1055.28 69.28 903.20 70.74755.49 49 .41 587.69 54.57 493.59 52.0 1

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

392 7.50

3793.60

3436.14

294 2.42

2866.09

2173.53

17 12.65

1594.99

1444.42

1353.25

1 227.85

1172.47

11 19.18

1055.28

903.20

755.49

587.69

4 93.59

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-7.pk

SJC90F~1.SP 3601 4000.00 400.00 6.74 99.65 4.00 %T 5 1.00

REF 4 000 88.66 2000 86.67 6003940.76 84.43 3461.11 9.68 2941.52 6.87 2866.52 14.79 267 1.50 75.852459.49 86.83 2175.91 82.44 2066.87 82.78 1971.82 85.56 1871.42 85.701712.00 6.74 1594.24 19 .62 1444.61 26.34 1344.49 28.76 1314.96 31.371227.37 26.28 1119.18 39.57 1053.35 54.35 904.08 59.03 863.95 68.44751.20 51 .31 650.73 63.15 492.02 43.9 6 414.83 75.36

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.76

3461.11 2941.52

2866.52

2 671.50

2459.49

2175.91

206 6.87

1971.82

1871.42

1712.00

1594.24

1444.61

1344.49

1314.96

1227.37

111 9.18

1053.35

904.08

863.95

751.20

65 0.73

4 92.02

414.83

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-8.pk

SJD9 0B~1.SP 3601 4000.0 0 400.00 6.88 99.65 4.00 %T 5 1.00

REF 4 000 92.71 2000 91.14 6003936.68 89.41 3441.28 11.71 2940.25 10.45 2864.48 25.11 2672.80 84.752457.61 91.64 2175.21 87.54 1805.01 83.36 1711.36 6.88 1593.12 17.151449.04 42.43 1426.65 44.77 1384.23 56.55 1346.89 36.08 1313.22 45.751222.77 47.09 1119.25 54.07 1054.29 77.26 1017.87 81.61 904.66 71.89863.45 76 .54 751.24 59.09 651.79 67.9 4 491.59 56.32 412.58 85.22

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3936.68

3441.28 294 0.25

2864.48

2672.80

2457.61

2175.211805.01

1711.36

1593.12

1449.04

1426.65

1384.23

1346.8 9

1313.22

1222.77

111 9.25

1054.2 9

1017.87

904.66

863.45

751.24

651.79

4 91.59

412.58

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-9.pk

SJD9 07~1.SP 3601 4000.00 400.00 5.01 100.00 4.00 %T 5 1.00

REF 4 000 97.62 2000 95.06 6003940.98 94.82 3447.81 5 .01 2941.12 7.74 2865.70 18.58 2672.24 87.452175.11 90.96 1803.58 8 4.06 1711.08 6.06 1593.54 14.08 1443.97 32.691346.39 30.30 1315.05 3 8.41 1223.68 39.70 1119.55 48.73 1055.82 74.961018.97 82.81 903.09 69.63 862.48 77 .91 751.76 55.62 651.89 64.69492.68 49 .14 415.26 84.96

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.98

3447.81 294 1.12

2865.7 0

2672.242175.11

1803.58

1711.08

1593.54

1443.97

1346.39

1315.05

1223.68

111 9.55

1055.82

1 018.97

903.09

862.48

751.76

65 1.89

4 92.68

415 .26

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-10.pk

SJ8E4 F~1.SP 3601 4000.00 400 .00 6.32 100.00 4.00 %T 5 1.00

REF 4 000 98.52 2000 95.78 6003940.75 96.28 3446.44 6 .32 2946.53 31.95 2868.75 41.80 2671.94 88.382337.75 95.09 2174.34 9 2.24 2069.77 91.69 1873.36 96.44 1713.95 31.601594.55 22.28 1444.50 4 7.28 1352.19 38.91 1236.96 40.46 1173.62 77.181118.83 64.78 1052.88 6 7.20 904.39 81.12 861.80 86.51 751.67 65.42649.90 70 .63 493.52 62.98 416.46 89.84

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.75

3 446.44

2946.53

2868.75

2671.94

233 7.75

2174.34

2069.77

1873.36

1713.95

1594.55

1444.50

1352.191236.96

1173.62

111 8.83

1052.88

904.39

861.80

751.67

64 9.90

4 93.52

416.46

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-11.pk

SJ865F~1.SP 3601 4000.00 400.00 5.02 100.00 4.00 %T 5 1.00

REF 4 000 98.40 2000 95.00 6003450.91 5.02 2943.19 31.91 2866.13 47.66 2672.91 93.78 2095.64 91.511710.37 30.25 1634.58 2 7.40 1591.09 24.35 1448.37 57.43 1348.45 49.481314.41 62.31 1230.04 5 5.60 1119.06 71.11 1054.03 79.63 904.81 84.57862.20 85 .71 750.76 65.02 651.46 67.44 4 92.78 64.31

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 450.91

294 3.19

2866.1 3

2 672.91

2095.64

17 10.37

1634.58

1591.09

1448.37

1348.45

13 14.41

1 230.04

111 9.06

1054.03

904.81

862.20

750.76

651.46

4 92.78

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-12.pk

SJ8E5 F~1.SP 3601 4000.00 400 .00 6.31 100.00 4.00 %T 5 1.00

REF 4 000 99.52 2000 96.68 6003444.09 6.31 2990.98 70.97 2948.68 70.81 2103.19 93.89 1748.05 70.071590.14 25.54 1354.17 6 2.45 1242.49 67.03 1056.16 89.49 602.01 68.68

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3444.09

2990.98

2948.6 8

2103.19

1748.05

159 0.14

1354.17

12 42.49

1056.16

602.01

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-13.pk

SJ866F~1.SP 3601 4000.00 400.00 6.35 100.00 4.00 %T 5 1.00

REF 4 000 99.50 2000 97.14 6003437.27 6.35 2988.54 66.60 2949.03 66.48 2732.05 93.58 2099.44 94.181753.55 64.20 1591.87 1 8.50 1355.56 51.26 1242.52 58.89 1114.15 93.281055.20 85.21 766.39 71.35 605.78 68 .51

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3437.27

2988.54

2949.03

2732.052099.44

1753.55

1591.87

1355.56

12 42.52

1114.15

1055.20

766.39605.78

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-14.pk

SJ8E6 F~1.SP 3601 4000.00 400 .00 7.03 100.00 4.00 %T 5 1.00

REF 4 000 98.07 2000 96.53 6003941.98 96.46 3457.36 1 1.15 2940.86 12.17 2865.79 27.97 2671.91 88.972175.32 93.29 2069.64 9 3.13 1872.84 95.73 1711.61 7.02 1594.23 23.261444.32 40.53 1348.34 3 8.57 1314.02 46.06 1236.30 22.58 1118.49 55.201052.50 54.96 903.61 75.36 860.41 82 .10 751.92 65.83 649.01 73.55492.49 59 .49 414.96 87.56

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3941.98

3457.36 294 0.86

2865.7 9

2 671.91

2175.32

206 9.64

1872.84

1711.61

1594.23

1444.32

1348.34

1314.02

1236.30

111 8.49

1052.50

903.61

860.41

751.92

64 9.01

4 92.49

414 .96

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-15.pk

SJC-PH~4.SP 3601 4000.00 400.00 5.02 100.00 4.00 %T 5 1.00

REF 4 000 98.24 2000 95.83 6003939.33 95.78 3451.61 5 .01 2941.88 14.53 2866.44 28.76 2671.32 87.172174.91 91.81 2068.05 9 1.54 1871.57 95.36 1711.30 11.36 1594.37 17.351445.54 40.25 1349.24 3 5.70 1234.39 31.53 1118.87 56.63 1053.66 62.64904.03 75 .11 862.19 80.83 751.75 61.66 6 50.42 68.51 492.81 58.47415.97 88 .65

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 39.33

3451.61

294 1.88

2866.4 4

2671.32

2174.91

206 8.05

1871.57

17 11.30

1594.37

1445.54

1349.24

1 234.39

111 8.87

1053.66

904.03

862.19

751.75

65 0.42

4 92.81

415.97

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-16.pk

SJC-PH~3.SP 3601 4000.00 400.00 5.05 99.99 4.00 %T 5 1.00

REF 4 000 98.20 2000 95.47 6003927.75 96.13 3437.20 5.05 2945.90 37.35 2866.69 49.33 2672.75 89.392174.86 91.54 2067.03 91.49 1871.85 96.30 1593.35 15.56 1447.80 56.371350.91 40.01 1236.83 52.68 1119.14 72.14 1053.46 75.80 904.25 82.97861.97 83 .61 751.82 62.22 650.92 64.6 7 493.75 62.42

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3927.75

3437.20

2945.90

2866.69

26 72.75

2174.86

2067.03

1871.85

1593.35

1447.80

1350.91

1236.83

1119.14

1053.46

904.25

861.9 7

751.8265 0.92

4 93.75

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-17.pk

SJC-PH~2.SP 3601 4000.00 400.00 5.02 100.00 4.00 %T 5 0.50

REF 4 000 99.44 2000 96.21 6003917.86 95.35 3437.82 5 .02 2946.69 72.57 2866.79 84.56 2821.88 86.712735.12 95.38 2130.01 9 2.80 1588.95 18.90 1450.41 84.84 1383.31 65.711350.38 56.67 1223.48 9 3.51 1120.17 94.90 1053.58 98.38 1018.19 98.43751.68 67 .32 650.96 63.96

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3917.86

3437.82

2946.69

2866.79

2821.88

2735.122130.01

158 8.95

1450.41

1383.31

1350.38

1223.48

112 0.17

10 53.58

1018.19

751.68

650.96

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-18.pk

SJC-PH~1.SP 3601 4000.00 400.00 6.34 99.99 4.00 %T 5 0.50

REF 4 000 99.87 2000 97.91 6003438.84 6.34 2992.52 63 .22 2827.64 82.12 2730.73 93.41 2104.59 94.911755.07 58.37 1592.46 15.78 1358.98 44.91 1242.90 56.74 1172.18 88.731056.50 85.87 936.37 98 .32 770.19 70.19 596.99 68.39

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 438.84

2 992.52

2827.64

27 30.73

2104.59

1755.07

1592.46

1358.98

12 42.90

1172.18

1056.50

936.37

770.19 596.99

312

Table - 7.28


Cyclohexanone + 2-Butanone + Benzaldehyde

S1

(Cm-1)

S2

(Cm-1)

S3 (Cm-

1)

S4

(Cm-1)

*S5

(Cm-1

)

S6

(Cm-1)

S7

(Cm-1)

S8

(Cm-1)

S9

(Cm-1)

3448.512941.932866.512175.911711.691595.651446.741354.511223.181172.101118.851059.521019.13904.76863.73752.08716.03650.23493.63413.44

3944.673457.732942.352871.122663.621972.831711.361598.161439.931353.821226.741117.941063.44901.77739.67650.62497.50420.09

3447.863069.302942.162866.542642.711974.421708.851596.961449.871420.521352.561313.871231.921173.121117.781065.991021.08905.75863.20826.87750.48715.61650.48497.45

3442.823073.872943.172867.992644.841975.341920.961704.931597.191448.741351.971312.561236.811173.781117.091066.461021.27904.97749.43714.94651.02501.89

3446.96

3069.41

2942.51

2867.15

2742.55

2645.24

1975.55

1919.41

1705.87

1596.64

1449.33

1386.36

1351.77

1311.62

1235.59

1173.04

1117.10

1067.45

1021.03

905.62

826.00

748.84

713.93

651.02

501.47

3442.443069.802942.722865.862739.702649.951975.261918.671703.091595.961494.871450.941354.831313.831234.881172.071117.711068.721022.21906.73827.00748.77713.83650.53503.14

3926.063450.483069.572941.992862.372822.412737.392408.082329.792139.061981.341911.161705.451595.251450.761351.601312.231207.331167.561118.281066.741015.13905.56826.01748.67

3455.332941.262866.192671.912176.281711.421595.731446.341348.651315.111222.861171.711118.751058.441018.73904.55863.84825.63751.01650.44492.78413.29

3451.982941.652865.602671.022064.061710.161595.591449.081348.011313.511224.951170.561118.541059.181018.87905.16863.45826.85750.34716.30650.35493.24413.79


S10 (Cm-

1)

S11

(Cm-1)

S12

(Cm-1)

S13

(Cm-1)

S14

(Cm-1)

*S15

(Cm-1

)

S16

(Cm-1)

S17

(Cm-1)

S18

(Cm-1)

3445.372943.732869.152646.872235.091921.411708.771596.651448.971355.351314.251238.221173.781117.061067.281021.49905.83748.96715.07651.03505.60

3450.003067.152941.912861.952820.022737.462330.721980.711911.341704.461595.941452.141353.161312.091205.811167.901117.601068.661016.37906.76826.78748.60689.61650.23494.02451.80

3443.873069.862943.112821.832737.742332.311981.131910.461702.891595.421452.761359.161311.861206.241168.081116.391070.051015.42910.00826.14748.19689.91650.58451.78

3442.143070.492820.812738.042328.802138.821981.461910.801702.641595.071453.621362.571311.781204.631169.081112.481072.361014.09928.19826.07747.66689.62650.62451.70

3444.083068.002942.192865.912739.882646.161975.451707.491596.271450.501420.821350.681313.251230.721171.851117.811067.221021.42905.97862.67827.38749.38714.07650.24496.48414.26

3445.39

3067.32

2941.79

2865.71

2740.90

2646.23

1974.43

1919.94

1705.31

1596.41

1493.86

1451.15

1419.53

1388.43

1348.91

1313.75

1231.60

1172.15

1117.93

1067.89

1021.76

905.78

862.33

827.51

749.24

714.42

3926.443440.643073.462943.272867.002658.642282.601975.831918.101701.631595.851448.591356.491278.981174.821117.701068.121022.47928.17748.77710.69651.80537.31

3445.863071.962943.132820.872737.691982.041912.451704.021594.931452.711358.081312.341205.191169.061116.581070.561015.70917.22826.11747.67689.74650.24452.51

3924.883443.263073.512821.422738.012330.101980.781912.521701.431594.831453.441361.191312.781204.681169.211114.771072.111015.31928.42825.71747.00689.37650.48451.87

313

Fig-7.28: FTIR Spectrums for Cyclohexanone+Benzaldehyde+Ethyl Acetate

mixture:

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: SJC-PH-D-1. sp

Date: 08-2-2010

SJC-PH-D-1.pk

SJ9907~1.SP 3601 4000.00 400.00 6.67 99.82 4.00 %T 5 1.00

REF 4 000 99.80 2000 94.10 6003927.26 97.78 3437.28 27.46 2989.93 57.65 2832.68 65.93 2721.34 89.471762.14 23.17 1712.80 37.69 1594.61 6.67 1365.19 14.03 1241.76 15.081056.32 56.66 924.76 95 .95 774.86 64.59 627.14 77.93 535.01 80.78

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3927.26

3437.28

2989.93

2832.68

2721.34

1762.14

1712.80

1594.61

1365.1912 41.76

1056.32

924.76

774.86

6 27.14535.01

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-2.pk

SJ9903~1.SP 3601 4000.00 400.00 6.60 99.99 4.00 %T 5 1.00

REF 4000 98.88 2000 94.18 6003447.33 33.58 31 78.88 36.03 3067.20 31.40 2942.63 15.20 2866.34 27.042739.08 56.28 19 75.66 92.30 1913.90 91.01 1706.59 6.59 1600.09 15.791448.92 41.97 13 60.06 31.08 1310.35 34.76 1226.12 24.69 1116.46 53.701067.46 66.03 10 22.88 75.13 906.96 79.37 826.90 61.52 750.21 40.02710.15 40.51 650.80 54.73 501.24 76.6 5 453.53 85.20

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3447.33

3178.88

3067 .20

2942.63

2866.34

2739.08

1975.66

1913.90

1706.59

1600.09

1448.92

1360.06

1310 .35

1226.12

1116.46

1067.46

1022.88

906.96

826.90

750.21

710.15

650.80

501.24

4 53.53

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-3.pk

SJC-PH~4.SP 3601 4000.00 400.00 6.65 99.99 4.00 %T 5 1.00

REF 4000 98.52 2000 94.34 6003935.83 97.39 34 03.71 42.61 3067.26 33.29 2942.14 14.47 2866.06 27.172739.71 60.22 26 66.94 66.34 1974.48 92.45 1915.94 91.14 1706.27 6.651597.31 25.72 14 50.63 39.90 1364.00 38.32 1311.82 34.08 1239.34 17.131171.52 42.12 11 15.60 48.34 1060.10 55.51 907.01 73.9 1 827.76 62.78749.31 44.42 714.05 40.35 650.30 54.9 9 496.78 75.59 453.18 86.01414.64 91.40

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3935.83

3403.71

3067.26

2942.14

2866.06

2739.71

2666.94

1974.48

1915.94

1706.27

1597.31

1450.63

1364.00

1311.82

1239.34

1171.52

1115.60

1060.10

907.01

827.76

749.31

714 .05

650.30

496.78

453.18

414.64

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-4.pk

SJA90B~1.SP 3601 4000.00 400.00 6.72 100.00 4.00 %T 5 1.00

REF 4000 98.33 2000 93.03 6003424.79 26.30 3069.24 22.97 2942.85 10.22 28 68.59 19.53 2651.44 53.191918.05 89.27 1708.55 6.72 1599.84 19.11 1447.53 36.01 1359.49 29.341238.90 16.85 1115.80 44.49 1064.33 54.69 90 6.53 68.52 826.82 64.21750.05 47.31 713.93 37.44 650.85 54.00 501.40 69.71

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3424.79

3069.24

2942.85

2868.59

2651.44

1918.05

1708.55

1599.84

1447.53

1359.49

1238.90

1115.80

1064.33

906.53

826.82

750.05

713 .93

650.85

501.40

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-5.pk

SJA907~1.SP 360 1 4000.00 400.00 5.26 99.99 4.00 %T 5 1.00

REF 4000 97.91 2000 94.89 6003930.26 96.69 34 28.99 17.89 3195.28 19.68 3071.18 19.06 2943.12 7.072867.87 14.53 26 51.32 52.80 1918.54 91.92 1707.32 5.26 1597.79 11.021447.95 29.20 13 58.40 20.99 1238.76 11.17 1173.38 32.94 1115.66 38.701060.59 47.99 90 5.04 67.53 860.86 69.43 826.8 4 67.07 751.09 46.45715.19 32.75 650.50 49.97 498.41 62.7 6 415.07 89.00

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3930.26

3428.993195.28

3071.18

2943.12

2867.87

2651.32

1918.54

1707.32

1597.79

1447.95

1358.40

1238.76

1173.38

1115.66

1060.59

905.04

860.86

826.84

751.09

715.19

650 .50

498.41

415.07

FTIR SPECTRUM

ACIC


Trichy-2


Date: 15-2-2010

SJC-Ph-D-6.pk

SJC-PH~4.SP 3601 4000.00 400.00 8.54 100.00 4.00 %T 5 1.00

REF 4000 98.89 2000 98.30 6003778.90 95.20 3452.45 49.34 3066.93 81.09 29 40.78 23.02 2865.95 48.572738.58 91.14 2340.54 97.27 1711.18 8.54 1599.26 70.56 1446.82 60.331386.63 73.36 1312.17 64.45 1224.50 51.50 11 68.91 79.21 1117.48 71.071057.09 79.78 905.22 88.08 827.42 85 .19 749.22 67.00 694.44 80.11650.12 78.86 492.00 80.79 415.28 94.86

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 778.90

3452.45

3066.93

2940.78

2865.95

2738.58

2340.54

1711.18

1599.26

1446.82

1386.63

1312.17

1224.50

1168.91

1117.48

1057.09

905.22

827.42

749.22

694.44

650.12492.00

415.28

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-7.pk

SJA90F~1.SP 3601 4000.00 400.00 7.01 99.90 4.00 %T 5 1.00

REF 4000 97.12 2000 95.74 6003935.90 94.23 34 16.02 29.31 2940.85 15.27 2864.32 33.49 2724.45 87.952673.49 91.24 21 74.97 94.27 1711.54 7.00 1595.10 11.1 6 1449.91 46.351426.56 49.36 13 59.72 26.89 1313.35 48.99 1233.74 35.74 1167.38 89.221118.57 58.85 10 53.72 65.92 1019.71 83.14 905.36 79.6 5 862.82 84.18773.32 69.53 751.54 66.92 649.91 76.3 7 491.24 69.08 412.03 91.28

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3935.90

3416.02

2940.85

2864.32

2724.45

2673.49 2174.97

1711.54

1595.10

1449.91

1426.56

1359.72

1313.35

1233.74

1167.38

1118.57

1053.72

1019.71

905.36

862.82

773.32

751.54

649.91

491.24

412.03

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-8.pk

SJC-PH~2.SP 3601 4000.00 400.00 6.59 100.00 4.00 %T 5 1.00

REF 4000 98.36 2000 94.68 6003928.06 96.66 3438.02 30.93 3196.65 35.32 30 68.39 33.72 2942.46 13.742865.74 25.26 2738.45 61.86 2670.32 67.27 19 17.02 91.58 1706.97 6.591597.14 14.57 1450.48 37.99 1419.95 42.80 13 58.49 26.98 1313.52 34.241231.99 26.68 1171.87 46.42 1117.11 49.17 10 66.22 63.85 1021.67 73.00905.93 76.08 862.51 78.05 827.65 68.45 750.06 48.08 714.19 41.95650.20 56.70 496.07 72.72 413.66 91.21

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3928.06

3438.02

3196.65

3068.39

2942.46

2865.74

2738.45

2670.32

1917.02

1706.97

1597.14

1450.48

1419.95

1358.49

1313.52

1231.99

1171.87

1117.11

1066.22

1021.67

905.93

862.51

827.65

750.06

714 .19

650.20

496.07

413.66

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-9.pk

SJB907~1.SP 3601 4000.00 400.0 0 6.76 100.00 4.00 %T 5 1.00

REF 4000 98.19 2000 92.90 6003934.40 95.47 3816.59 95.94 3440.62 22.51 31 94.15 25.99 3069.18 24.162942.93 9.12 2867.50 18.52 2662.74 57.47 1974.15 90.54 1916.67 89.551709.41 6.76 1598.55 12.90 1447.83 34.34 1357.28 26.76 1311.56 30.581235.60 22.08 1116.42 45.46 1065.06 57.79 10 23.04 68.32 905.76 73.38827.08 64.26 750.32 43.97 712.21 39.92 650.50 54.94 497.98 68.82416.14 91.22

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3934.40

3816.59

3440.623194.15

3069.18

2942.93

2867.50

2662.74

1974.15

1916.67

1709.41

1598.55

1447.83

1357.28

1311 .56

1235.60

1116.42

1065.06

1023.04

905.76

827.08

750.32

712.21

650.50

497.98

416.14

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-10.pk

SJC-PH~3.SP 3601 4000.00 400.00 6.66 99.99 4.00 %T 5 1.00

REF 4000 98.36 2000 90.92 6003929.21 96.02 34 16.52 16.99 3188.26 16.24 3071.26 14.90 2944.02 8.452868.81 15.67 26 59.07 41.92 1917.72 85.04 1704.70 6.66 1597.80 10.621448.65 31.41 13 67.66 21.59 1241.38 11.52 1115.06 40.96 1062.51 47.02909.11 63.63 826.49 53.34 748.53 37.6 6 712.88 29.87 651.22 44.33507.28 66.86

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3929.21

3416.52

3188.26

3071.26

2944.02

2868 .81

2659.07

1917.72

1704.70

1597.80

1448.65

1367.66

1241.38

1115.06

1062.51

909.11

826.49

748.53

712 .88

651.22

507.28

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-11.pk

SJ665F~1.SP 3601 4000.00 400.0 0 6.72 100.00 4.00 %T 5 1.00

REF 4000 98.68 2000 92.61 6003445.88 33.77 3193.80 35.41 3066.83 31.33 29 43.54 18.84 2864.82 30.562821.56 33.50 2738.25 52.79 1976.88 90.35 19 13.21 88.20 1703.01 6.721599.47 12.08 1451.63 39.01 1367.83 23.47 13 11.74 32.89 1242.13 10.731170.47 43.20 1114.34 52.86 1056.95 48.71 90 9.35 77.79 827.47 54.24749.71 36.27 714.39 40.46 650.27 47.96 498.57 77.55 452.23 77.67

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3445.88

3193.80

3066.83

2943.54

2864.82

2821.56

2738.25

1976.88

1913.21

1703.01

1599.47

1451.63

1367.83

1311.74

1242.13

1170.47

1114.34

1056.95

909.35

827.47

749.71

714.39

650.27

498.57

452.23

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-12.pk

SJC-PH~1.SP 3601 4000.00 400.00 7.00 99.99 4.00 %T 5 1.00

REF 4000 99.05 2000 92.64 6003929.67 97.69 37 97.75 96.16 3442.84 30.86 3069.99 34.54 2948.27 28.712823.57 35.06 27 36.40 54.08 2551.39 64.57 2084.05 95.45 1976.81 89.901913.35 85.36 17 03.36 6.99 1603.28 9.10 1448.37 41.29 1368.51 16.161243.62 9.21 1110.35 54.21 1053.28 38.49 930.41 63.61 825.56 55.92753.42 43.10 708.91 40.20 650.92 48.7 1 541.90 69.78 451.92 76.52

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3929.67

3797.75

3442.84

3069.99

2948.27

2823.57

2736.40

2551 .39

2084.05

1976.81

1913.35

1703.361603.28

1448.37

1368.51

1243.62

1110.35

1053.28

930.41

825.56

753.42

708.91

650.92

541.90

451.92

FTIR SPECTRUM

ACIC


Trichy-2


Date: 15-2-2010

SJC-Ph-D-13.pk

SJ866F~1.SP 3601 4000.00 400.0 0 7.88 99.95 4.00 %T 5 1.00

REF 4000 98.78 2000 93.48 6003884.73 96.71 37 79.20 90.85 3442.43 33.06 3067.11 49.33 2993.21 54.392946.73 54.50 28 18.59 49.34 2737.88 55.46 2331.80 95.04 2027.35 92.991981.84 91.54 19 07.88 92.24 1823.01 91.21 1702.57 7.87 1595.96 32.041453.62 53.56 13 85.51 44.19 1310.02 47.75 1242.56 18.94 1206.48 29.381167.76 50.22 11 09.72 71.68 1060.30 61.42 924.24 87.5 5 826.90 47.35746.76 29.35 688.90 41.27 649.91 43.7 6 544.25 84.22 451.42 68.07

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3884.73

3779.20

3442.43

3067.11

2993.21

2946.73

2818.59

2737.88

2331.80

2027.35

1981.84

1907.88

1823.01

1702.57

1595.96

1453.62

1385.51

1310.02

1242.56

1206.48

1167.76

1109.72

1060.30

924.24

826.90

746.76

688.90

649.91

5 44.25

451.42

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-14.pk

SJ6E6F~1.SP 360 1 4000.00 400.00 5.60 100.00 4.00 %T 5 1.00

REF 4000 95.76 2000 92.11 6003940.45 90.69 3412.50 20.46 2943.33 5.60 2866.44 11.86 2674.13 74.222465.19 92.32 2176.60 90.18 2068.14 89.17 19 69.42 89.19 1713.33 5.891599.22 8.72 1445.87 19.67 1357.96 13.48 1315.23 23.88 1238.76 6.321117.94 33.47 1052.85 30.09 904.77 57.20 862.99 68.86 753.32 48.20649.23 67.08 491.68 50.24 413.97 82.34

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.45

3412.50

2943.33

2866.44

2674.13

2465.19

2176.60

2068.14

1969.42

1713.33

1599.22

1445.87

1357.96

1315.23

1238.76

1117.94

1052.85

904.77

862.99

753.32

649.23

491.68

413.97

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-15.pk

SJ667F~1.SP 3601 4000.00 400.0 0 6.84 100.00 4.00 %T 5 1.00

REF 4000 97.48 2000 96.08 6003934.63 95.06 3454.09 30.08 3067.13 47.02 29 42.13 9.45 2866.44 20.942671.87 77.84 2177.01 96.13 2065.90 95.73 17 12.07 6.84 1596.97 20.211446.90 34.19 1353.97 30.71 1313.30 36.38 12 36.66 18.81 1170.70 56.771117.11 47.39 1055.68 52.97 904.70 74.96 861.93 79.83 829.46 80.66751.20 56.67 716.25 64.15 649.77 68.55 493.24 64.63 413.81 89.58

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3934.63

3454.09

3067.13

2942.13

2866 .44

2671.87

2177.01

2065.90

1712.07

1596.97

1446.90

1353.97

1313.30

1236.66

1170.70

1117.11

1055.68

904.70

861.93

829.46

751.20

716.25

649.77

493.24

413.81

FTIR SPECTRUM

ACIC


Trichy-2


Date: 08-2-2010

SJC-PH-D-16.pk

SJ6E7F~1.SP 360 1 4000.00 400.00 6.79 99.99 4.00 %T 5 1.00

REF 4000 99.15 2000 95.92 6003407.23 48.76 31 71.11 47.11 3068.01 42.29 2942.18 20.11 2865.95 36.752738.92 68.40 19 14.63 93.27 1708.06 6.79 1596.54 25.3 8 1449.55 49.251362.89 39.45 12 39.30 25.13 1171.50 50.71 1114.61 60.44 1060.47 65.20905.95 83.06 827.09 70.65 749.24 53.3 4 714.21 50.63 650.45 64.07498.17 82.88 453.42 90.63

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3407.23

3171.11

3068.01

2942.18

2865.95

2738.92

1914.63

1708.06

1596.54

1449.55

1362.89

1239.30

1171.50

1114.61

1060.47

905.95

827.09

749.24

714 .21

650.45

498.17

453.42

FTIR SPECTRUM

ACIC


Trichy-2


Date: 15-2-2010

SJC-Ph-D-17.pk

SJC-PH~1.SP 3601 4000.00 400.00 6.32 99.99 4.00 %T 5 1.00

REF 4000 99.41 2000 96.36 6003778.76 96.94 34 33.10 41.18 3069.44 44.99 2942.94 46.08 2861.08 54.212821.03 53.27 27 38.87 63.96 2545.57 82.67 2362.24 94.43 1980.26 95.181915.23 94.97 17 03.82 6.32 1596.95 40.89 1451.55 62.1 7 1392.64 58.211288.12 46.77 12 08.16 38.14 1170.48 55.69 1112.33 76.61 1070.56 82.821018.88 87.96 92 3.83 90.31 826.71 60.74 746.3 4 40.16 708.49 47.60650.96 54.86 542.49 86.50 450.97 82.1 1

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3778.76

3433.10

3069.44

2942.94

2861.08

2821.03

2738.87

2545.57

2362.241980.26

1915 .23

1703.82

1596.95

1451.55

1392.64

1288.12

1208.16

1170.48

1112.33

1070.56

1018.88

923.83

826.71

746.34

708.49

650.96

542.49

450.97

FTIR SPECTRUM

ACIC


Trichy-2


Date: 15-2-2010

SJC-Ph-D-18.pk

SJC-PH~3.SP 3601 4000.00 400.00 6.30 99.99 4.00 %T 5 1.00

REF 4000 99.71 2000 95.23 6003779.66 96.64 33 91.68 58.61 3197.19 62.05 3068.08 52.44 2819.25 53.082738.71 60.45 25 46.91 86.11 2333.53 94.76 1981.01 93.68 1911.07 93.091704.11 6.30 1595.91 40.01 1452.81 58.55 1383.83 47.6 6 1242.74 21.711169.05 53.97 11 07.96 73.56 1055.76 63.69 927.44 83.9 5 826.73 53.16747.07 35.26 691.66 48.70 650.61 52.0 6 538.82 87.72 451.07 77.09

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3779.66

3391 .68

3197.19

3068.08

2819.25

2738.71

2546.91

2333.531981.01

1911.07

1704.11

1595.91

1452.81

1383.83

1242.74

1169.05

1107.96

1055.76

927.44

826.73

747.07

691.66

650 .61

538.82

451.07

314

Table - 7.29


Cyclohexanone + Benzaldehyde + Ethyl Acetate:

S1

(Cm-1

)

S2

(Cm-1

)

*S3 (Cm-

1)

S4

(Cm-1

)

S5

(Cm-1

)

S6

(Cm-1

)

S7

(Cm-1

)

S8

(Cm-1

)

*S9

(Cm-1

)

3927.263437.282989.932832.682721.341762.141712.801594.611365.191241.761056.32924.76774.86627.14535.01

3447.333178.883067.202942.632866.342739.081975.661913.901706.591600.091448.921360.061310.351226.121116.461067.461022.88906.96826.90750.21710.15650.80501.24453.53

3935.83

3403.713067.26

2942.142866.06

2739.712666.941974.48

1915.941706.27

1597.311450.63

1364.001311.82

1239.341171.52

1115.601060.10907.01

827.76749.31

714.05650.30

496.78453.18

414.64

3424.793069.242942.852868.592651.441918.051708.551599.841447.531359.491238.901115.801064.33906.53826.82750.05713.93650.85501.40

3930.263428.993195.283071.182943.122867.872651.321918.541707.321597.791447.951358.401238.761173.381115.661060.59905.04860.86826.84751.09715.19650.50498.41415.07

3778.903452.453066.932940.782865.952738.582340.541711.181599.261446.821386.631312.171224.501168.911117.481057.09905.22827.42749.22694.44650.12492.00415.28

3935.903416.022940.852864.322724.452673.492174.971711.541595.101449.911426.561359.721313.351233.741167.381118.571053.721019.71905.36862.82773.32751.54649.91491.24412.03

3928.063438.023196.653068.392942.462865.742738.452670.321917.021706.971597.141450.481419.951358.491313.521231.991171.871117.111066.221021.67905.93862.51827.65750.06650.20496.07

3934.40

3816.593440.62

3194.153069.18

2942.932867.502662.74

1974.151916.67

1709.411598.55

1447.831357.28

1311.561235.60

1116.421065.061023.04

905.76827.08

750.32712.21

650.50497.98

416.14


S10 (Cm-1

)S11

(Cm-1

)

S12

(Cm-1

)

*S13

(Cm-1

)

S14

(Cm-1

)

S15

(Cm-1

)

S16

(Cm-1

)

S17

(Cm-1

)

S18

(Cm-1

)

3929.213416.523188.263071.262944.022868.812659.071917.721704.701597.801448.651367.661241.381115.061062.51909.11826.49748.53712.88651.22507.28

3445.883193.803066.832943.542864.822821.562738.251976.881913.211703.011599.471451.631367.831311.741242.131170.471114.341056.95909.35827.47749.71714.39650.27498.57452.23

3929.673797.753442.843069.992948.272823.572736.402551.392084.051976.811913.351703.361603.281448.371368.511243.621110.351053.28930.41825.56753.42708.91650.92541.90451.92

3884.733779.20

3442.433067.112993.21

2946.732818.59

2737.882331.80

2027.351981.84

1907.881823.01

1702.571595.961453.62

1385.511310.02

1242.561206.48

1167.761109.72

1060.30924.24

826.90746.76451.42

3940.453412.502943.332866.442674.132465.192176.602068.141969.421713.331599.221445.871357.961315.231238.761117.941052.85904.77862.99753.32649.23491.68413.97

3934.633454.093067.132942.132866.442671.872177.012065.901712.071596.971446.901353.971313.301236.661170.701117.111055.68904.70861.93829.46751.20716.25649.77493.24413.81

3407.233171.113068.012942.182865.952738.921914.631708.061596.541449.551362.891239.301171.501114.611060.47905.95827.09749.24714.21650.45498.17453.42

3778.763433.103069.442942.942861.082821.032738.872545.572362.241980.261915.231703.821596.951451.551392.641288.121208.161170.481112.331070.561018.88923.83826.71746.34708.49650.96450.97

3779.663391.683197.193068.082819.252738.712546.912333.531981.011911.071704.111595.911452.811383.831242.741169.051107.961055.76927.44826.73747.07691.66650.61538.82451.07


315

Fig-7.29: FTIR spectrums for Cyclhexanone + Ethyl Acetate + 2-Butanone

mixture:

FTIR SPECTRUM

ACIC



Date: 03-12-2009

SJC-Ph-D-1.pk

SJB907~1.SP 3601 4000.00 400.00 7 .45 99.05 4.00 %T 5 1.00

REF 4000 88.78 2000 87.99 6003927.97 85.91 3788.49 84.61 3420.47 16.33 2940.99 11.72 2865.29 26.252673.39 80.60 2176.04 84.99 1804.84 79.55 1712.31 7.45 1595.46 15.291448.22 39.98 1350.61 30.91 1314.28 45.22 1222.68 48.05 1172.66 77.181119.36 54.46 1054.67 75.08 1018.13 79.40 905.15 71.81 863.72 76.49751.78 60.58 651.14 69.69 491.59 56 .71 413.27 80.34

4000. 0 3000 2000 1500 1000 400.0

0. 0

10

20

30

40

50

60

70

80

90

100. 0

cm-1

%T

3927.97

3788.49

3420.47

2940.99

2865.29

2673.39

2176.04

1804.84

1712.31

1595.46

1448.22

1350.61

1314.28

1222.68

1172.66

1119.36

1054.67

1018.13

905.15

863.72

751.78

651.14

491.59

413.27FTIR SPECTRUM

ACIC

St. Joseph's Colleg e ( Autonomous )

Trichy-2


Date: 03-1 2-200 9

SJ C-Ph-D-2.pk

SJ B90 3~1.SP 3601 4000.00 400 .00 6.31 99.58 4 .0 0 % T 5 1.00

REF 4 000 87.29 2000 85.89 60039 31.42 82.79 3784.96 81.45 3439.70 6.31 2941.24 11 .45 2865.46 27.1026 73.92 79.58 2175.84 82.26 1711.17 8.85 1595.42 7.48 1444.52 40.1713 51.08 26.73 1223.19 49.72 1119.18 55.77 105 5.20 73.03 1018.91 77.6090 3.33 70.43 861.50 72.39 753.18 53.49 649.71 59.94 559 .8 8 61.4649 2.38 52.58

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3931.42

3784.96

3439.70

2941.24

2865.46

2673.92

2175 .84

1711.171595.42

1444.52

1351.08

1223.19

1119.18

1055.20

1018.91

90 3.33

861 .50

753 .18649 .71

559.88

492.38

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-3.pk

SJB90 F~1.SP 3601 4000.00 400 .00 7.42 98.98 4.00 %T 5 1.00

REF 4 000 86.78 2000 86.01 6003927.93 83.62 3790.58 81.90 3420.01 13.77 2940.97 9.61 2864.86 23.692672.36 78.90 2175.61 82.90 1712.05 7.42 1595.16 12.54 1448.21 38.641350.34 29.32 1314.07 42.85 1223.85 43.49 1119.18 50.95 1054.15 67.921018.47 74.60 904.99 68 .67 863.56 73.12 751.69 57.26 650.90 65.91491.47 53 .39 413.32 78.61

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3927.93

3790.58

3420.01

294 0.97

2864.86

2672.36

2175.61

17 12.05

1595.16

1448.21

1350.34

1314.07

1223.85

111 9.18

1054.15

1018.47

904.99

863 .56

751.69

650.90

4 91.47

413 .32

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-4.pk

SJC90B~1.SP 3601 4000.00 400.00 7.08 99.87 4.00 %T 5 1.00

REF 4 000 88.63 2000 87.88 6003931.53 85.79 3788.52 83.89 3431.58 11.94 2940.55 11.10 2864.88 27.742673.57 82.37 2175.76 84.89 1711.36 7.08 1595.65 10.34 1444.00 44.441351.62 31.26 1222.89 52.77 1119.36 56.47 1055.56 73.99 1020.15 78.02903.29 73 .90 861.26 78.65 754.07 61.1 6 649.91 68.43 492.04 56.65416.20 81 .52

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3931.53

3788.52

3431.58 294 0.55

2864.88

2 673.57

2175.76

17 11.361595.65

1444.00

1351.62

1222.8 9

1119.36

1055.56

1020.15

903.29

861 .26

754.07

64 9.91

4 92.04

416.20

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-5.pk

SJC907~1.SP 3601 4000.00 400 .00 8.04 99.68 4.00 %T 5 1.00

REF 4 000 89.65 2000 88.80 6003928.10 87.41 3431.36 18.95 2940.81 13.01 2865.60 30.40 2672.60 83.272175.71 86.26 1711.82 8.04 1595.38 20.53 1445.16 44.62 1348.36 39.861225.70 46.88 1119.05 58.07 1054.63 72.76 904.11 73.92 862.80 78.05752.07 64 .08 649.90 71.91 491.94 60.4 2 414.55 83.95

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3928.10

3 431.36

294 0.81

2865.6 0

2672.60

2175.71

17 11.82

1595.38

1445.16

1348.36

1225.70

111 9.05

1054.63

904.11

862.8 0

752.07

6 49.90

4 91.94

414.55

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-6.pk

SJC903~1.SP 3601 4000.00 400 .00 5.30 99.43 4.00 %T 5 1.00

REF 4 000 81.31 2000 80.29 6003927.50 76.71 3793.60 72.92 3436.14 5.61 2942.42 14.95 2866.09 32.342173.53 76.45 1712.65 11.57 1594.99 5.30 1444.42 42.25 1353.25 22.811227.85 48.63 1172.47 71.60 1119.18 59.91 1055.28 69.28 903.20 70.74755.49 49 .41 587.69 54.57 493.59 52.0 1

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

392 7.50

3793.60

3436.14

294 2.42

2866.09

2173.53

17 12.65

1594.99

1444.42

1353.25

1 227.85

1172.47

11 19.18

1055.28

903.20

755.49

587.69

4 93.59

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-12-2009

SJC-Ph-D-7.pk

SJC90F~1.SP 3601 4000.00 400.00 6.74 99.65 4.00 %T 5 1.00

REF 4 000 88.66 2000 86.67 6003940.76 84.43 3461.11 9.68 2941.52 6.87 2866.52 14.79 267 1.50 75.852459.49 86.83 2175.91 82.44 2066.87 82.78 1971.82 85.56 1871.42 85.701712.00 6.74 1594.24 19 .62 1444.61 26.34 1344.49 28.76 1314.96 31.371227.37 26.28 1119.18 39.57 1053.35 54.35 904.08 59.03 863.95 68.44751.20 51 .31 650.73 63.15 492.02 43.9 6 414.83 75.36

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.76

3461.11 2941.52

2866.52

2 671.50

2459.49

2175.91

206 6.87

1971.82

1871.42

1712.00

1594.24

1444.61

1344.49

1314.96

1227.37

111 9.18

1053.35

904.08

863.95

751.20

65 0.73

4 92.02

414.83

FTIR SPECTRUM

ACIC


Trichy-2


Date: 03-1 2-200 9

SJ C-Ph-D-8.pk

SJ D90B~1.SP 3601 4000 .0 0 4 00.00 6.88 99.65 4.00 %T 5 1.00

REF 4 000 92.71 2000 91.14 60039 36.68 89.41 3441.28 11.71 2940.25 10.45 286 4.48 25.11 2672.80 84.7524 57.61 91.64 2175.21 87.54 1805.01 83.36 171 1.36 6.88 1593.12 17.1514 49.04 42.43 1426.65 44.77 1384.23 56.55 134 6.89 36.08 1313.22 45.7512 22.77 47.09 1119.25 54.07 1054.29 77.26 101 7.87 81.61 904.66 71.8986 3.45 76.54 751.24 59.09 651.79 67.94 491.59 56.32 412 .5 8 85.22

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3936.68

3441.28 2940.25

2864.48

2672.80

2457.61

2175.211805.01

1711.36

1593.12

1449.04

1426.65

1384 .23

1346.89

1313.22

1222.77

1119.25

1054.29

1017.87

904.66

863.45

751 .24

651.79

491.59

412 .58

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-1 2-200 9

SJ C-Ph-D-9.pk

SJ D907~1.SP 3601 4000.00 400.00 5.01 100.00 4.00 %T 5 1.00

REF 4 000 97.62 2000 95.06 60039 40.98 94.82 3447 .8 1 5.01 2941.12 7.74 2865.70 18.58 2672.24 87.4521 75.11 90.96 1803 .5 8 84.06 1711.08 6.06 1593.54 1 4.08 1 443.97 32.6913 46.39 30.30 1315 .0 5 38.41 1223.68 39.70 1119.55 48.73 1055.82 74.9610 18.97 82.81 903.09 69.63 862.48 77.91 751.76 55.62 651.89 64.6949 2.68 49.14 415.26 8 4.96

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.98

3447.81 2941.12

2865.70

2672 .242175.11

1803.58

1711.08

1593.54

1443.97

1346.39

1315.05

1223.68

1119.55

1055.82

1018.97

903.09

862 .48

751 .76

651 .89

492.68

415.26

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-1 2-200 9

SJ C-Ph-D-10.pk

SJ 8E4 F~1.SP 3601 40 00.00 400.00 6.32 100.00 4.00 %T 5 1.00

REF 4 000 98.52 2000 95.78 60039 40.75 96.28 3446 .4 4 6.32 2946.53 31.95 2868.75 4 1.80 2 671.94 88.3823 37.75 95.09 2174 .3 4 92.24 2069.77 91.69 1873.36 96.44 1713.95 31.6015 94.55 22.28 1444 .5 0 47.28 1352.19 38.91 1236.96 40.46 1173.62 77.1811 18.83 64.78 1052 .8 8 67.20 904.39 81.12 861.80 86.51 751.67 65.4264 9.90 70.63 493.52 6 2.98 4 16.46 89.84

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3940.75

3446.44

2946.53

2868.75

2671.94

2337.75

2174.34

2069.77

1873.36

1713.95

1594.55

1444.50

1352.191236.96

1173.62

1118.83

1052.88

904.39

861.80

751 .67

649 .90

493.52

416.46

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-1 2-200 9

SJ C-Ph-D-11.pk

SJ 865F~1.SP 3601 4000.00 400 .00 5.02 100.00 4.00 %T 5 1.00

REF 4 000 98.40 2000 95.00 60034 50.91 5.02 2943.19 31.91 2866.13 47.66 2672.91 9 3.78 2 095.64 91.5117 10.37 30.25 1634 .5 8 27.40 1591.09 24.35 1448.37 57.43 1348.45 49.4813 14.41 62.31 1230 .0 4 55.60 1119.06 71.11 1054.03 79.63 904.81 84.5786 2.20 85.71 750.76 6 5.02 6 51.46 67.44 492.78 64.31

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3450.91

2943.19

2866.13

2672.91

2095.64

1710.37

1634.58

1591.09

1448.37

1348.45

1314.41

1230 .04

1119.06

1054.03

904.81

862.20

750.76

651.46

492.78

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-1 2-200 9

SJ C-Ph-D-12.pk

SJ 8E5 F~1.SP 3601 40 00.00 400.00 6.31 100.00 4.00 %T 5 1.00

REF 4 000 99.52 2000 96.68 60034 44.09 6.31 2990.98 70.97 2948.68 70.81 2103.19 9 3.89 1 748.05 70.0715 90.14 25.54 1354 .1 7 62.45 1242.49 67.03 1056.16 89.49 602.01 68.68

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3444 .09

2990.98

2948.68

2103.19

1748.05

1590.14

1354 .17

1242 .49

1056.16

602 .01

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-1 2-200 9

SJ C-Ph-D-13.pk

SJ 866F~1.SP 3601 4000.00 400 .00 6.35 100.00 4.00 %T 5 1.00

REF 4 000 99.50 2000 97.14 60034 37.27 6.35 2988.54 66.60 2949.03 66.48 2732.05 9 3.58 2 099.44 94.1817 53.55 64.20 1591 .8 7 18.50 1355.56 51.26 1242.52 58.89 1114.15 93.2810 55.20 85.21 766.39 71.35 605.78 68.51

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3437.27

2988.54

2949.03

2732.052099.44

1753.55

1591.87

1355.56

1242 .52

1114.15

1055 .20

7 66.39605.78

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-1 2-200 9

SJ C-Ph-D-14.pk

SJ 8E6 F~1.SP 3601 40 00.00 400.00 7.03 100.00 4.00 %T 5 1.00

REF 4 000 98.07 2000 96.53 60039 41.98 96.46 3457 .3 6 11.15 2940.86 12.17 2865.79 27.97 2671.91 88.9721 75.32 93.29 2069 .6 4 93.13 1872.84 95.73 1711.61 7.02 1 594.23 23.2614 44.32 40.53 1348 .3 4 38.57 1314.02 46.06 1236.30 22.58 1118.49 55.2010 52.50 54.96 903.61 75.36 860.41 82.10 751.92 65.83 649.01 73.5549 2.49 59.49 414.96 8 7.56

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3941.98

3457 .36 2940.86

2865.79

2671.91

2175.32

2069.64

1872.84

1711.61

1594.23

1444.32

1348.34

1314.02

1236.30

1118.49

1052.50

90 3.61

860.41

751 .92

649 .01

492.49

4 14.96

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-12-2009

SJC-Ph-D-15.pk

SJC-PH~4.SP 3601 4000.00 400.00 5.02 100.00 4.00 %T 5 1.00

REF 4 000 98.24 2000 95.83 6003939.33 95.78 3451.61 5 .01 2941.88 14.53 2866.44 28.76 2671.32 87.172174.91 91.81 2068.05 9 1.54 1871.57 95.36 1711.30 11.36 1594.37 17.351445.54 40.25 1349.24 3 5.70 1234.39 31.53 1118.87 56.63 1053.66 62.64904.03 75 .11 862.19 80.83 751.75 61.66 6 50.42 68.51 492.81 58.47415.97 88 .65

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

39 39.33

3451.61

294 1.88

2866.4 4

2671.32

2174.91

206 8.05

1871.57

17 11.30

1594.37

1445.54

1349.24

1 234.39

111 8.87

1053.66

904.03

862.19

751.75

65 0.42

4 92.81

415.97

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-1 2-200 9

SJ C-Ph-D-16.pk

SJ C-PH~3.SP 3601 4000.00 400.00 5.05 99.99 4.00 %T 5 1.00

REF 4 000 98.20 2000 95.47 60039 27.75 96.13 3437.20 5.05 2945.90 37.35 2866.69 49 .33 2672.75 89.3921 74.86 91.54 2067.03 91.49 1871.85 96.30 159 3.35 15.56 1447.80 56.3713 50.91 40.01 1236.83 52.68 1119.14 72.14 105 3.46 75.80 904.25 82.9786 1.97 83.61 751.82 62.22 650.92 64.67 493.75 62.42

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3927.75

3437.20

2945.90

2866.69

2672.75

2174.86

2067.03

1871 .85

1593.35

1447.80

1350.91

1236.83

1119 .14

1053 .46

904.25

861.97

751 .82650 .92

493.75

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-1 2-200 9

SJ C-Ph-D-17.pk

SJ C-PH~2.SP 3601 4000.00 400.00 5.02 100.00 4.00 %T 5 0.50

REF 4 000 99.44 2000 96.21 60039 17.86 95.35 3437 .8 2 5.02 2946.69 72.57 2866.79 8 4.56 2 821.88 86.7127 35.12 95.38 2130 .0 1 92.80 1588.95 18.90 1450.41 84.84 1383.31 65.7113 50.38 56.67 1223 .4 8 93.51 1120.17 94.90 1053.58 98.38 1018.19 98.4375 1.68 67.32 650.96 6 3.96

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3917 .86

3437.82

2946.69

2866.79

2821.88

2735.12 2130.01

1588.95

1450.41

1383.31

1350.38

1223.48

1120.17

1053 .58

1018.19

751 .68

650.96

FTIR SPECTRUM

ACIC


Trichy-2


Date: 02-1 2-200 9

SJ C-Ph-D-18.pk

SJ C-PH~1.SP 3601 4000.00 400.00 6.34 99.99 4.00 %T 5 0.50

REF 4 000 99.87 2000 97.91 60034 38.84 6.34 2992.52 63.22 2827.64 82.12 2730.73 93 .41 2104.59 94.9117 55.07 58.37 1592.46 15.78 1358.98 44.91 124 2.90 56.74 1172.18 88.7310 56.50 85.87 936.3 7 98.32 770.19 70.19 596.99 68 .3 9

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3438.84

2992.52

2827.64

2730.73

2104.59

1755.07

1592.46

1358.98

1242 .90

1172.18

1056.50

936.37

770.19 596.99

316

Table - 7.30


Cyclohexanone + Ethyl Acetate + 2-Butanone mixture

S1

(Cm-1

)

S2

(Cm-1

)

S3

(Cm-1

)

S4

(Cm-1

)

S5

(Cm-1

)

S6

(Cm-1

)

S7

(Cm-1

)

S8

(Cm-1

)

S9

(Cm-1

)

3927.973788.493420.472940.992865.292673.392176.041804.841712.311595.461448.221350.611314.281222.681172.661119.361054.671018.13863.72651.14491.59413.27

3931.423784.963439.702941.242865.462673.922175.841711.171595.421444.521351.081223.191119.181055.201018.91861.50649.71559.88492.38

3927.933790.583420.012940.972864.862672.362175.611712.051595.161448.211350.341314.071223.851119.181054.151018.47863.56650.90491.47413.32

3931.533788.523431.582940.552864.882673.572175.761711.361595.651444.001351.621222.891119.361055.561020.15861.26649.91492.04416.20

3928.103431.362940.812865.602672.602175.711711.821595.381445.161348.361225.701119.051054.63862.80649.90491.94414.55

3927.503793.603436.142942.422866.092173.531712.651594.991444.421353.251227.851172.471119.181055.28587.69493.59

3940.763461.112941.522866.522671.502459.492175.912066.871971.821871.421712.001594.241444.611344.491314.961227.371119.181053.35863.95650.73492.02414.83

3936.683441.282940.252864.482672.802457.612175.211805.011711.361593.121449.041426.651384.231346.891313.221222.771119.251054.291017.87863.45651.79491.59412.58

3940.983447.812941.122865.702672.242175.111803.581711.081593.541443.971346.391315.051223.681119.551055.821018.97862.48651.89492.68415.26


*S10

(Cm-1

)

S11

(Cm-1

)

S12

(Cm-1

)

S13

(Cm-1

)

S14

(Cm-1

)

S15

(Cm-1

)

S16

(Cm-1

)

S17

(Cm-1

)

S18

(Cm-1

)

3940.75

3446.44

2946.532868.75

2671.94

2337.75

2174.34

2069.771873.36

1713.95

1594.55

1444.50

1352.19

1236.961173.62

1118.83

1052.88

861.80

649.90

416.46

3450.912943.192866.132672.912095.641710.371634.581591.091448.371348.451314.411230.041119.061054.03862.20651.46492.78

3444.092990.982948.682103.191748.051590.141354.171242.491056.16602.01

3437.272988.542949.032732.052099.441753.551591.871355.561242.521114.151055.20605.78

3941.983457.362940.862865.792671.912175.322069.641872.841711.611594.231444.321348.341314.021236.301118.491052.50860.41649.01492.49414.96

3939.333451.612941.882866.442671.322174.912068.051871.571711.301594.371445.541349.241234.391118.871053.66862.19650.42492.81415.97

3927.753437.202945.902866.692672.752174.862067.031871.851593.351447.801350.911236.831119.141053.46861.97650.92493.75

3917.863437.822946.692866.792821.882735.122130.011588.951450.411383.311350.381223.481120.171053.581018.19650.96

3438.842992.522827.642730.732104.591755.071592.461358.981242.901172.181056.50936.37770.19596.99


317

Fig-7.30: FTIR spectrums for Ethyl Acetate + 2-Butanone + Hexane mixture:

FTIR SPECT RUM

ACIC


Trichy-2

Spectrum Name: H-E-2B-1.sp

Date: 26-6-2009

H-E-2B-1.pk

H-E-2B-1.sp 3601 4000.00 400.00 6.64 99.62 4.00 %T 10 1.00

REF 4000 99.55 2000 95.26 6003925.08 96.42 3445.96 30.18 2966.78 77.08 2832.19 64.45 2720.35 89.142359.43 82.43 1599.65 6.64 1361.93 20.02 1022.04 96.01 774.63 65.20614.51 79.17

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3925.08

3445.96

2966.78

2 83 2.19

2 72 0.35

23 59.43

1599 .65

1 36 1.93

1022 .04

774 .6 3

61 4.51

FTIR SPECTRUM

ACIC

St. Joseph's College ( Autonomo us )

Tr ich y-2

Spectrum Name: H-E-2B-2 .sp

Date: 26-6-2009

H-E-2B-2.pk

H-E-2B-2.s p 3 601 4000.00 400.00 6.38 99.88 4.00 %T 10 1 .0 0

REF 4 000 98 .6 7 2000 96.56 60039 20.42 95.34 3440.28 19.68 2966.24 71.79 2831.80 66.13 272 1.64 87.6715 98.26 6.38 1360.15 22 .8 6 773.57 62.99 610.23 73 .6 1

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3920.42

3440.28

2 966.24

2831.80

2721.64

1598.26

1360.15

773 .57

6 10.23

FTIR SPECTRUM

ACIC


Trichy-2


Date:26-6-2009

H-E-2B-3.pk

H-E-2B-3.sp 3601 4000.00 400.00 5.15 99.79 4.00 %T 10 1.00

REF 4000 99.57 2000 93.81 6003922.32 96.63 3794.87 95.25 3457.13 31.32 2961.99 74.01 2832.02 59.032719.74 86.77 2376.47 97.70 1599.22 5.15 1362.02 14.88 1228.66 87.25774.51 61.60 612.42 79.54

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3922.32

3794 .87

3457.13

2961.99

2832 .02

2719.74

2376.47

1599.22

1362.02

1228.66

774.51

612 .42

FTIR SPECTRUM

ACIC


Trichy-2


Date: 26-6-2009

H-E-2B-4.pk

H-E-2B-4.sp 3601 4000.00 400.00 5.16 99.63 4.00 %T 10 1.00

REF 4000 99.40 2000 88.87 6003459.19 34.84 2963.90 71.25 2832.28 54.17 2719.35 84.52 2375.56 93.291601.38 5.16 1463.43 66.85 1362.84 11.79 1241.47 76 .30 1065.56 91.01774.90 60.53 612.29 82.33

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3459.19

2963.90

2832.28

2719.35

2375.56

1601.38

1463.43

1362.84

1241.47

1065.56

774.90

612.29

FTIR SPECTRUM

ACIC


Trichy-2

Sp ectrum Name: H-E-2B-5 .sp

Date: 26-6-2009

H-E-2B-5 .p k

H-E-2B-5 .s p 3601 4000.00 400.00 6.37 99.82 4.00 %T 10 1.00

REF 4000 99.73 2000 97.06 6003443.38 30.10 29 61.38 78.46 2831.71 62.58 271 8.65 88.80 1599.10 6.371461.09 74.73 13 62.27 16.98 1241.28 86.94 774 .69 59.02 613.93 77.85

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3443.38

2961.38

2831.71

2718.65

1599.10

1461.09

1362.27

1241.28

774.69

613 .93

FTIR SPECTRUM

ACIC

St.Josep h's Colleg e ( Autonomous )

Tr ichy-2


Date: 26-6-2009

H-E-2B-6.pk

H-E-2B-6.s p 3 601 400 0.00 400.00 6.46 99.62 4.00 %T 10 1.00

REF 4000 99.5 0 2000 9 4.66 6003921.92 96.19 34 41.22 29.63 2978.74 74.79 2832.19 63.55 272 0.26 88.642364.66 93.95 15 99.06 6.46 1362.03 18.23 1242.25 75.38 1061.83 91 .1 4774.45 63.15 614.72 78.20

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3921.92

3441.22

2978.74

2832.19

2720 .26

2364.66

1599.06

1362.03

1242.25

1061.83

774.45

614 .72

FTIR SPECTRUM

ACIC

St.Josep h's Colleg e ( Autonomous )

Tr ichy-2


Date: 26-6-2009

H-E-2B-7.pk

H-E-2B-7.s p 3 601 400 0.00 400.00 6.45 99.74 4.00 %T 10 1.00

REF 4000 99.5 7 2000 7 9.94 6003451.66 27.72 29 99.34 60.07 2832.46 56.03 2719.92 77.81 237 3.04 83.101714.61 12.32 15 98.94 6.45 1427.18 51.15 1362.70 8.15 1226.38 36.291094.54 80.43 10 57.11 80.17 905.57 92.15 774.95 61.01 611.99 77.29532.24 68.40

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3451.66

2999.34

2832.46

2719.92

2373 .04

1714.61

1598.94

1427.18

1362.70

1226.38

1094.54

1057.11

905 .57

774.95

61 1.99

532.24

FTIR SPECTRUM

ACIC


Trichy-2


Date: 26-6-2009

H-E-2B-8.pk

H-E-2B-8.sp 3601 4000.00 400.00 7.96 99.90 4.00 %T 10 1.00

REF 4000 99.61 2000 96.21 6003820.17 93.89 3441.43 29.92 2831.80 67.16 2720.98 89.50 2367.12 96.201598.86 7.96 1465.75 75.68 1361.26 22.32 1241.58 87.34 773.45 65.76604.21 79.31

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3 820 .17

34 41.43

2 831 .8 0

2 720 .98

23 67.12

15 98.86

1465.75

13 61.26

1 241 .5 8

773 .4 5

604 .21

FTIR SPECTRUM

ACIC


Trichy-2


Date: 26-6-2009

H-E-2B-9.pk

H-E-2B-9.sp 3601 4000.00 400.00 6.46 100.00 4.00 %T 10 1.00

REF 4000 99.84 2000 86.03 6003922. 83 94.26 3815.17 91.04 3439.58 27.86 2963.05 66.25 2831.80 58.672720. 66 77.55 2369.69 82.16 1598.12 6. 46 1360.81 21.70 1122.61 88.74773. 98 64.45 613.73 76.51

400 0.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

10 0.0

cm-1

%T

3922.83

3815.17

3439.58

2963.05

2831.80

2720.66

2369.69

1598.12

1360.81

1122.61

773.98

613.73

FTIR SPECTRUM

ACIC


Spec trum Name: H-E-2B-10.sp

Date: 27-6-2009

H-E-2B-10.pk

H-E-2B~1.SP 3601 4000.00 400.00 6.62 99.52 4.00 %T 10 1.00

REF 4000 99.31 2000 92.98 6003925.24 95.14 3800.40 92.20 3444.85 24.69 2966.09 73.26 2832.26 64. 452721.11 88.79 1598.52 6.62 1361.11 20.34 1244.51 86.49 774.34 61.06609.92 75.06

4000.0 3000 2000 1500 1000 400.0

0 .0

10

20

30

40

50

60

70

80

90

100 .0

cm-1

%T

3925.24

3800.40

3444.85

2966.09

2832.26

2721.11

1598.52

1361.11

1244.51

774.34

609.92

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: H-E-2B-11.spDate: 27-6 -2009

H-E-2B-11.pk

H-E-2B~2.SP 3601 4000.00 400.00 6.64 99.19 4.00 %T 10 1.00

REF 4000 98.52 2000 95.57 6003919.64 95.75 3439.12 15.68 2832.01 66.97 2722.24 87.11 2375.34 97.371596.57 6.64 1359.28 24.88 1243.14 81.79 1119.90 92.09 773.88 62.18610.79 71.7 5

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3919.64

343 9.12

2832.01

2 722.24

237 5.34

1596.57

1359.28

1243.14

1119.90

773.88

610.79

FTIR SPECTRUM

ACIC


Trichy-2

Spectrum Name: H-E-2B-12.spDate: 27-6-2009

H-E-2B-12.pk

H-E-2B~3.SP 3601 4000.00 400.00 6.46 99.99 4.00 %T 10 1.00

REF 4000 99.67 2000 89.66 6003921.81 94.37 3438.16 19.83 2989.65 62.20 2831.96 63.00 2722.18 81.971759.91 55.75 1597.41 6.45 1463.92 69.83 1360.37 22 .77 1243.11 58.061116.38 88.61 1056.50 82.60 774.04 62.64 609.81 72.17

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3921.81

3438.16

29 89.65

2831.96

2722 .18

1759.91

1597.41

1463 .92

1360.37

1243.11

1116.38

1056.50

774.04

609.81

FTIR SPECTRUM

ACIC


Trichy-2


Date: 27-6-2009

H-E-2B-13.pk

H-E-2B~4.SP 3601 4000.00 400.00 6.65 100.00 4.00 %T 10 1.00

REF 4000 99.63 2000 95.17 6003922.83 95.68 3445.58 24.72 2832.13 63.65 2721.10 87.72 2368.82 97.281598.01 6.65 1361.14 20.95 774.38 62.04 611.94 75.37

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3922.83

3445.58

28 32.13

2 72 1.10

236 8.82

1 59 8.01

1361 .14

77 4.38

6 11 .9 4

FTIR SPECTRUM

ACIC



Date: 27-6-2009

H-E-2B-14.pk

H-FAD3~1.SP 3601 4000.00 400.00 6.65 100.00 4.00 %T 10 1.00

REF 4000 99.65 2000 95.11 6003931.86 96.66 3440.19 19.73 2831.82 69.47 2721.68 89.44 2366.92 96.141596.80 6.65 1359.07 24.96 1121.18 90.89 1026.21 93.74 773.90 61.60607.79 70.82

4000. 0 3000 2000 1500 1000 400.0

0. 0

10

20

30

40

50

60

70

80

90

100. 0

cm-1

%T

3931.86

3440.19

2831.82

2721.68

2366.92

1596.80

1359.07

1121.18

1026.21

773.90

607.79

FTIR SPECTRUM

ACIC


Trichy-2

Sp ectrum Name: H-E-2B-1 5.sp

Date: 27-6-2009

H-E-2B-1 5.pk

H-F2E3~1.SP 360 1 4000.00 400.00 6.66 100.00 4.00 %T 10 1.00

REF 4000 99.53 2000 97.65 6003920.48 95.73 3788.96 90.14 3438.89 14.76 29 91.14 62.36 2832.10 68.262725.86 86.66 2365.04 96.71 2104.88 96.22 17 60.57 60.47 1596.95 6.661464.87 73.16 1359.05 27.91 1243.08 57.73 10 56.19 81.32 773.60 64 .63610.28 69 .65

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3920.48

3788.96

3438.89

2991.14

2832.10

2725.86

2365.04

2104.88

1760.57

1596 .95

1464.87

1359.05

1243.08

1056.19

773.60

610 .28

FTIR SPECTRUM

ACIC


Trichy-2


Date: 27-6 -2009

H-E-2B-16.pk

H-FAE3~1.SP 3601 4000.00 4 00.00 6.58 99.73 4.00 %T 10 1.00

REF 4000 99.45 2000 91.85 6003924.15 96.89 3434.53 21.99 2978.96 65.46 2830.51 65.84 2723.85 83.182365.51 87.53 2163.66 90.23 1596.72 6.58 1464.73 71.07 1358.40 24.161244.05 76.72 1117.08 91.18 1048.04 89.29 773.34 59.27 607.34 65.87

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

392 4.15

3434.53

2978 .96

2830.51

2723.85

2365.5121 63.66

1596.72

1464.73

1358.40

1244.05

1117.08

104 8.04

773 .34

607.34

FTIR SPECTRUM

ACIC


Trichy-2

Sp ectrum Name: H-E-2B-1 7. sp

Date: 27-6-2009

H-E-2B-1 7.pk

H-F2F3~1.SP 360 1 4000.00 400.00 6.91 99.93 4.00 %T 10 1.00

REF 4000 99.38 2000 97.09 6003923.33 97.13 37 87.28 93.60 3451.48 15.57 298 1.69 41.89 2833.58 66.262724.87 87.93 20 93.13 95.18 1760.87 21.42 159 6.84 6.91 1463.96 62.721364.08 17.80 12 42.70 15.11 1172.52 77.26 105 6.50 57.29 933.98 94.64773.09 62 .44 615.80 67.42

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3923.3 3

378 7.28

34 51.48

2 981.69

2833.58

2724 .87

2093 .13

176 0.87

1596.84

1 463.96

1364.0 81242.7 0

1172 .52

1056.50

933.98

773.09

615.80

FTIR SPECTRUM

ACIC


Trichy-2


Date: 27-6-2009

H-E-2B-18.pk

H-FAF3~1.SP 3601 4000.00 400.00 8.06 100.00 4.00 %T 10 1.00

REF 4000 99.58 2000 97.97 6003452.55 20.96 2987.45 40.50 2833.02 69.66 2721.76 90.87 2480.09 98.552090.67 95.86 1759.67 12.88 1597.19 9.71 1461.30 60.62 1366.24 15.681242.78 8.06 1172.34 69.01 1056.45 47.87 934.26 91.78 843.84 86.86774.40 64.13 603.88 70.44

4000.0 3000 2000 1500 1000 400.0

0.0

10

20

30

40

50

60

70

80

90

100.0

cm-1

%T

3452 .55

2987 .45

2833.02

2721.76

2480.09

2090.67

1759 .67

1597.19

1461.30

1366.24

1 242 .78

1172 .34

1 05 6.45

934 .26

843 .84

774.40

60 3.88

318

Table - 7.31


Ethyl Acetate + 2-Butanone + Hexane mixture:

S1

(Cm-1

)

S2

(Cm-1

)

S3

(Cm-1

)

S4

(Cm-1

)

S5

(Cm-1

)

S6

(Cm-1

)

*S7

(Cm-1

)

S8

(Cm-1

)

S9

(Cm-1

)

3925.08

3445.96

2966.78

2832.19

2720.35

2359.43

1599.65

1361.93

1022.04

774.63

614.51

3920.42

3440.28

2966.24

2831.80

2721.64

1598.26

1360.15

773.57

610.23

3922.323794.873457.132961.992832.022719.742376.471599.221362.021228.66774.51612.42

3459.192963.902832.282719.352375.561601.381463.431362.841241.471065.56774.90612.29

3443.382961.382831.712718.651599.10

1461.091362.271241.28774.69613.93

3921.923441.222978.742832.192720.262364.661599.061362.031242.251061.83774.45614.72

3451.66

2999.34

2832.46

2719.92

2373.04

1714.61

1598.94

1427.18

1362.70

1226.38

1094.54

1057.11

905.57

774.95

611.99

532.24

3820.173441.432831.802720.982367.121598.861465.751361.261241.58773.45604.21

3922.833815.173439.582963.052831.802720.662369.691598.121360.811122.61773.98613.73


S10

(Cm-1

)

S11

(Cm-1

)

S12

(Cm-1

)

S13

(Cm-1

)

S14

(Cm-1

)

S15

(Cm-1

)

S16

(Cm-1

)

*S17

(Cm-1

)

S18

(Cm-1

)

3925.243800.403444.852966.092832.262721.111598.521361.111244.51774.34609.92

3919.643439.122832.012722.242375.341596.571359.281243.141119.90773.88610.79

3921.813438.162989.652831.962722.181759.911597.411463.921360.371243.111116.381056.50774.04609.81

3922.833445.582832.132721.102368.821598.011361.14774.38611.94

3931.86

3440.192831.822721.682366.921596.801359.071121.181026.21773.90607.79

3920.483788.963438.892991.142832.102725.862365.042104.881760.571596.95

1464.871359.051243.081056.19773.60610.28

3924.153434.532978.962830.512723.852365.512163.661596.721464.731358.401244.051117.081048.04773.34607.34

3923.33

3787.28

3451.48

2981.69

2833.58

2724.87

2093.13

1760.87

1596.84

1463.96

1364.08

1242.70

1172.52

1056.50

933.98

773.09

615.80

3452.552987.452833.022721.762480.092090.671759.671597.191461.301366.241242.781172.341056.45934.26843.84774.40603.88


16 Chapter 7

Documents

pect rum date

2 18 2009 spec trum

3 11 2009 spec trum

pk sjd9 0b 1

ethyl acetate

2 26 2008 spectrum na

2 25 2008 spectrum na

2 22 2008 spectrum na