1 The Chemistry of Acids and Bases Chemistry I – Chapter 19 Chemistry I HD – Chapter 16 ICP – Chapter 23 SAVE PAPER AND INK!!! When you print out the notes.

11The Chemistry The Chemistry of Acids and of Acids and BasesBases

The Chemistry The Chemistry of Acids and of Acids and BasesBases

Chemistry I – Chapter 19Chemistry I – Chapter 19

Chemistry I HD – Chapter 16Chemistry I HD – Chapter 16

ICP – Chapter 23ICP – Chapter 23

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22

Acid and BasesAcid and Bases

33


44


55Acids

Have a sour taste. Vinegar is a solution of acetic acid. Citrusfruits contain citric acid.

React with certain metals to produce hydrogen gas.

React with carbonates and bicarbonates to produce carbon dioxide gas

Have a bitter taste.

Feel slippery. Many soaps contain bases.

Bases

66

Some Properties of Acids

Produce H+ (as H3O+) ions in water (the hydronium ion is a

hydrogen ion attached to a water molecule)

Taste sour

Corrode metals

Electrolytes

React with bases to form a salt and water

pH is less than 7

Turns blue litmus paper to red “Blue to Red A-CID”

77

Anion Ending Acid Name

-ide hydro-(stem)-ic acid

-ate (stem)-ic acid

-ite (stem)-ous acid

Acid Nomenclature Review

Binary Binary

Ternary Ternary

An easy way to remember which goes with which…An easy way to remember which goes with which…

““In the cafeteria, you In the cafeteria, you ATEATE something something ICICky”ky”

88Acid Nomenclature Flowchart

h yd ro - p re fix-ic en d in g

2 e lem en ts

-a te en d in gb ecom es-ic en d in g

-ite en d in gb ecom es

-o u s en d in g

n o h yd ro - p re fix

3 e lem en ts

AC ID Ss ta rt w ith 'H '

99

• HBr HBr (aq)(aq)

• HH22COCO33

• HH22SOSO33

hydrohydrobromicbromic acidacid

carboncarbonicic acidacid

sulfursulfurousous acidacid

Acid Nomenclature Review

1010

Name ‘Em!

• HI HI (aq)(aq)

• HCl HCl (aq)(aq)

• HH22SOSO33

• HNOHNO33

• HIOHIO44

1111

Some Properties of Bases

Produce OH- ions in water

Taste bitter, chalky

Are electrolytes

Feel soapy, slippery

React with acids to form salts and water

pH greater than 7

Turns red litmus paper to blue “Basic Blue”

1212

Some Common Bases

NaOH sodium hydroxide lye

KOH potassium hydroxide liquid soap

Ba(OH)2 barium hydroxide stabilizer for plastics

Mg(OH)2 magnesium hydroxide “MOM” Milk of magnesia

Al(OH)3 aluminum hydroxide Maalox (antacid)

1313

Acid/Base definitions

• Definition #1: Arrhenius (traditional)

Acids – produce H+ ions (or hydronium ions H3O+)

Bases – produce OH- ions

(problem: some bases don’t have hydroxide ions!)

1414Arrhenius acid is a substance that produces H+ (H3O+) in water

Arrhenius base is a substance that produces OH- in water

1515

Acid/Base Definitions

• Definition #2: Brønsted – Lowry

Acids – proton donor

Bases – proton acceptor

A “proton” is really just a hydrogen atom that has lost it’s electron!

1616

A Brønsted-Lowry acid is a proton donorA Brønsted-Lowry base is a proton acceptor

acidconjugate

basebase conjugate

acid

1717

ACID-BASE THEORIESACID-BASE THEORIESACID-BASE THEORIESACID-BASE THEORIES

The Brønsted definition means NHThe Brønsted definition means NH33 is is aa BASEBASE in water — and water is in water — and water is itself anitself an ACIDACID

BaseAcidAcidBaseNH4

+ + OH-NH3 + H2OBaseAcidAcidBase

NH4+ + OH-NH3 + H2O

1818

Conjugate PairsConjugate Pairs

1919Acids & Base Acids & Base DefinitionsDefinitions

Lewis acid - a Lewis acid - a substance that substance that accepts an electron accepts an electron pairpair

Lewis base - a Lewis base - a substance that substance that donates an electron donates an electron pairpair

Definition #3 – Lewis Definition #3 – Lewis

2020

Formation ofFormation of hydronium ion hydronium ion is also an is also an excellent example.excellent example.

Lewis Acids & BasesLewis Acids & Bases

•Electron pair of the new O-H bond Electron pair of the new O-H bond originates on the Lewis base.originates on the Lewis base.

HH

H

BASE

••••••

O—HO—H

H+

ACID

2121

Lewis Acid/Base ReactionLewis Acid/Base Reaction

2222

Lewis Acid-Base Lewis Acid-Base Interactions in BiologyInteractions in Biology

• The heme group in hemoglobin can interact with O2 and CO.

• The Fe ion in hemoglobin is a Lewis acid

• O2 and CO can act as Lewis bases

Heme group

2323The pH scale is a way of expressing the strength of acids and bases. Instead of using very small numbers, we just use the NEGATIVE power of 10 on the Molarity of the H+ (or OH-) ion.

Under 7 = acid 7 = neutral

Over 7 = base

2424

pH of Common pH of Common SubstancesSubstances

2525Calculating the pH

pH = - log [H+](Remember that the [ ] mean Molarity)

Example: If [H+] = 1 X 10-10

pH = - log 1 X 10-10

pH = - (- 10)

pH = 10

Example: If [H+] = 1.8 X 10-5

pH = - log 1.8 X 10-5

pH = - (- 4.74)

pH = 4.74

2626

Try These!

Find the pH of these:

1) A 0.15 M solution of Hydrochloric acid

2) A 3.00 X 10-7 M solution of Nitric acid

2727pH calculations – Solving for pH calculations – Solving for H+H+pH calculations – Solving for pH calculations – Solving for H+H+

If the pH of Coke is 3.12, [HIf the pH of Coke is 3.12, [H++] = ???] = ???

Because pH = - log [HBecause pH = - log [H++] then] then

- pH = log [H- pH = log [H++]]

Take antilog (10Take antilog (10xx) of both) of both sides and get sides and get

1010-pH -pH == [H[H++]][H[H++] = 10] = 10-3.12-3.12 = 7.6 x 10 = 7.6 x 10-4-4 M M *** to find antilog on your calculator, look for “Shift” or “2*** to find antilog on your calculator, look for “Shift” or “2nd nd

function” and then the log buttonfunction” and then the log button

2828pH calculations – Solving for pH calculations – Solving for H+H+

• A solution has a pH of 8.5. What is the Molarity of hydrogen ions in the solution?

pH = - log [H+]

8.5 = - log [H+]

-8.5 = log [H+]

Antilog -8.5 = antilog (log [H+])

10-8.5 = [H+]

3.16 X 10-9 = [H+]

pH = - log [H+]

8.5 = - log [H+]

-8.5 = log [H+]

Antilog -8.5 = antilog (log [H+])

10-8.5 = [H+]

3.16 X 10-9 = [H+]

2929

More About WaterMore About Water

HH22O can function as both an ACID and a BASE.O can function as both an ACID and a BASE.

In pure water there can beIn pure water there can be AUTOIONIZATIONAUTOIONIZATION

Equilibrium constant for water = KEquilibrium constant for water = Kww

KKww = [H = [H33OO++] [OH] [OH--] =] = 1.00 x 101.00 x 10-14-14 at 25 at 25 ooCC

3030

More About WaterMore About Water

KKww = [H = [H33OO++] [OH] [OH--] = 1.00 x 10] = 1.00 x 10-14-14 at 25 at 25 ooCC

In a In a neutralneutral solution [Hsolution [H33OO++] = [OH] = [OH--]]

so Kso Kww = [H = [H33OO++]]22 = [OH = [OH--]]22

and so [Hand so [H33OO++] = [OH] = [OH--] = 1.00 x 10] = 1.00 x 10-7-7 M M

OH-

H3O+

OH-

H3O+

AutoionizationAutoionization

3131pOH

• Since acids and bases are opposites, pH and pOH are opposites!

• pOH does not really exist, but it is useful for changing bases to pH.

• pOH looks at the perspective of a base

pOH = - log [OH-]Since pH and pOH are on opposite

ends,pH + pOH = 14

3232

pHpH [H+][H+] [OH-][OH-] pOHpOH

3333

[H[H33OO++], [OH], [OH--] and pH] and pHWhat is the pH of the What is the pH of the

0.0010 M NaOH solution? 0.0010 M NaOH solution?

[OH-] = 0.0010 (or 1.0 X 10[OH-] = 0.0010 (or 1.0 X 10-3-3 M) M)

pOH = - log 0.0010pOH = - log 0.0010

pOH = 3pOH = 3

pH = 14 – 3 = 11pH = 14 – 3 = 11

OR KOR Kww = [H = [H33OO++] [OH] [OH--]]

[H[H3OO++] = 1.0 x 10] = 1.0 x 10-11-11 M M

pH = - log (1.0 x 10pH = - log (1.0 x 10-11-11) = 11.00) = 11.00

3434The pH of rainwater collected in a certain region of the northeastern United States on a particular day was 4.82. What is the H+ ion concentration of the rainwater?

The OH- ion concentration of a blood sample is 2.5 x 10-7 M. What is the pH of the blood?

3535Calculating [H3O+], pH, [OH-], and pOH

Problem 1: A chemist dilutes concentrated hydrochloric acid to make two solutions: (a)0.30M and (b) 0.0024 M. Calculate the [H3O+], pH, [OH-], and pOH of the two solutions at 25°C.

Problem 2: What is the [H3O+], [OH-], and pOH of a solution with pH = 3.67? Is this an acid, base, or neutral?

Problem 3: Problem #2 with pH = 8.05?

3636pH testing

• There are several ways to test pH

–Blue litmus paper (red = acid)

–Red litmus paper (blue = basic)

–pH paper (multi-colored)

–pH meter (7 is neutral, <7 acid, >7 base)

–Universal indicator (multi-colored)

– Indicators like phenolphthalein

–Natural indicators like red cabbage, radishes

3737Paper testing

• Paper tests like litmus paper and pH paper

– Put a stirring rod into the solution and stir.

– Take the stirring rod out, and place a drop of the solution from the end of the stirring rod onto a piece of the paper

– Read and record the color change. Note what the color indicates.

– You should only use a small portion of the paper. You can use one piece of paper for several tests.

3838pH paperpH paper

3939

pH meter

• Tests the voltage of the electrolyte

• Converts the voltage to pH

• Very cheap, accurate

• Must be calibrated with a buffer solution

4040pH indicators

• Indicators are dyes that can be added that will change color in the presence of an acid or base.

• Some indicators only work in a specific range of pH

• Once the drops are added, the sample is ruined

• Some dyes are natural, like radish skin or red cabbage

4141Strong and Weak Strong and Weak Acids/BasesAcids/Bases

The strength of an acid (or base) is determined by the amount of IONIZATION.

The strength of an acid (or base) is determined by the amount of IONIZATION.

4242

Strong and Weak Strong and Weak Acids/BasesAcids/Bases

• Generally divide acids and bases into STRONG or Generally divide acids and bases into STRONG or WEAK ones.WEAK ones.

STRONG ACID:STRONG ACID: HNOHNO3 3 (aq) + H(aq) + H22O (l) --->O (l) --->

HH33OO+ + (aq) + NO(aq) + NO33- - (aq)(aq)

HNOHNO33 is about 100% dissociated in water. is about 100% dissociated in water.

4343

• Weak acidsWeak acids are much less than 100% ionized in are much less than 100% ionized in

water.water.

One of the best known is acetic acid = CHOne of the best known is acetic acid = CH33COCO22HH



4444

• Strong Base:Strong Base: 100% dissociated in 100% dissociated in water.water.

NaOH (aq) ---> NaNaOH (aq) ---> Na+ + (aq) + OH(aq) + OH- - (aq)(aq)


Other common strong Other common strong bases include KOH andbases include KOH and Ca(OH)Ca(OH)22..

CaO (lime) + HCaO (lime) + H22O -->O -->

Ca(OH)Ca(OH)22 (slaked lime) (slaked lime)CaOCaO

4545

• Weak base:Weak base: less than 100% ionized less than 100% ionized in waterin water

One of the best known weak bases is One of the best known weak bases is ammoniaammonia

NHNH3 3 (aq) + H(aq) + H22O (l) O (l) NH NH44+ + (aq) + OH(aq) + OH- - (aq)(aq)



4646

Weak BasesWeak Bases

4747

Titration

• Is the controlled addition and measurement of the amount of a solution of known concentration that is required to react completely with a measured amount of a solution of unknown concentration.

4848

Standard Solution

A solution that contains a precisely known concentration of a solute.

In a titration this is called the titrant.

Analyte – another name for the solution of unknown concentration.

4949

Equivalence Point or End Point

• The point in the titration where equivalent (equal) amount of OH- and H3O+ are present.

• How do we know when the endpoint or equivalence point have been reached?

• pH meter shows rapid changes in pH or indicator changes color (more on this)

5050

Primary Standard

• A highly purified compound, when used in solution to check the concentration of the known solution in a titration.

5151

ACID-BASE REACTIONSACID-BASE REACTIONSTitrationsTitrations

ACID-BASE REACTIONSACID-BASE REACTIONSTitrationsTitrations

HH22CC22OO44(aq) + 2 NaOH(aq) --->(aq) + 2 NaOH(aq) --->

acidacid basebase

NaNa22CC22OO44(aq) + 2 H(aq) + 2 H22O(liq)O(liq)

Carry out this reaction using aCarry out this reaction using a TITRATIONTITRATION..

Oxalic acid,Oxalic acid,

HH22CC22OO44

5252Setup for titrating an acid with a baseSetup for titrating an acid with a base

5353

TitrationTitrationTitrationTitration

1. Add solution from the buret.1. Add solution from the buret.2. Reagent (base) reacts with 2. Reagent (base) reacts with

compound (acid) in solution compound (acid) in solution in the flask.in the flask.

3.3. Indicator shows when exact Indicator shows when exact stoichiometric reaction has stoichiometric reaction has occurred. (Acid = Base)occurred. (Acid = Base)

This is called This is called NEUTRALIZATION.NEUTRALIZATION.

5454

5555

35.62 mL of NaOH is 35.62 mL of NaOH is

neutralized with 25.2 mL of neutralized with 25.2 mL of

0.0998 M HCl by titration to 0.0998 M HCl by titration to

an equivalence point. What an equivalence point. What

is the concentration of the is the concentration of the

NaOH?NaOH?

LAB PROBLEM #1: Standardize a LAB PROBLEM #1: Standardize a solution of NaOH — i.e., accurately solution of NaOH — i.e., accurately determine its concentration.determine its concentration.

LAB PROBLEM #1: Standardize a LAB PROBLEM #1: Standardize a solution of NaOH — i.e., accurately solution of NaOH — i.e., accurately determine its concentration.determine its concentration.

565635.62 mL of NaOH is neutralized with 25.2 mL of 35.62 mL of NaOH is neutralized with 25.2 mL of

0.0998 M HCl by titration to an equivalence point. 0.0998 M HCl by titration to an equivalence point.

What is the concentration of the NaOH?What is the concentration of the NaOH?

Ma Va = Mb Vb

Ma Va

= Mb

Vb

(0.0998 M) (25.2 mL)

= 0.0706 M

(35.62 mL)

5757

PROBLEM: You have 50.0 mL of PROBLEM: You have 50.0 mL of 3.0 M NaOH and you want 0.50 M 3.0 M NaOH and you want 0.50 M NaOH. What do you do?NaOH. What do you do?

PROBLEM: You have 50.0 mL of PROBLEM: You have 50.0 mL of 3.0 M NaOH and you want 0.50 M 3.0 M NaOH and you want 0.50 M NaOH. What do you do?NaOH. What do you do?

Add water to the 3.0 M solution to lower Add water to the 3.0 M solution to lower its concentration to 0.50 M its concentration to 0.50 M

Dilute the solution!Dilute the solution!

5858

PROBLEM: You have 50.0 mL of 3.0 M PROBLEM: You have 50.0 mL of 3.0 M NaOH and you want 0.50 M NaOH. NaOH and you want 0.50 M NaOH. What do you do?What do you do?


3.0 M NaOH 0.50 M NaOH

H2O

Concentrated Dilute

But how much water But how much water do we add?do we add?

5959

PROBLEM: You have 50.0 mL of 3.0 M PROBLEM: You have 50.0 mL of 3.0 M NaOH and you want 0.50 M NaOH. NaOH and you want 0.50 M NaOH. What do you doWhat do you do??

PROBLEM: You have 50.0 mL of 3.0 M PROBLEM: You have 50.0 mL of 3.0 M NaOH and you want 0.50 M NaOH. NaOH and you want 0.50 M NaOH. What do you doWhat do you do??

How much water is added?How much water is added?

The important point is that --->The important point is that --->

moles of NaOH in ORIGINAL solution = moles of NaOH in ORIGINAL solution = moles of NaOH in FINAL solutionmoles of NaOH in FINAL solution

6060

PROBLEM: You have 50.0 mL of 3.0 M NaOH PROBLEM: You have 50.0 mL of 3.0 M NaOH and you want 0.50 M NaOH. What do you do?and you want 0.50 M NaOH. What do you do?PROBLEM: You have 50.0 mL of 3.0 M NaOH PROBLEM: You have 50.0 mL of 3.0 M NaOH and you want 0.50 M NaOH. What do you do?and you want 0.50 M NaOH. What do you do?

Amount of NaOH in original solution = Amount of NaOH in original solution =

M • VM • V = =

(3.0 mol/L)(0.050 L) = 0.15 mol NaOH(3.0 mol/L)(0.050 L) = 0.15 mol NaOH

Amount of NaOH in final solution must also = Amount of NaOH in final solution must also = 0.15 mol NaOH0.15 mol NaOH

Volume of final solution =Volume of final solution =

(0.15 mol NaOH)(1 L/0.50 mol) = 0.30 L(0.15 mol NaOH)(1 L/0.50 mol) = 0.30 L

or or 300 mL300 mL

6161



Conclusion:Conclusion:

add 250 mL add 250 mL of waterof water to to 50.0 mL of 50.0 mL of 3.0 M NaOH 3.0 M NaOH to make 300 to make 300 mL of 0.50 M mL of 0.50 M NaOH.NaOH.

3.0 M NaOH 0.50 M NaOH

H2O

Concentrated Dilute

6262

A shortcutA shortcut

MM11 • V • V11 = M = M22 • V • V22

Preparing Solutions Preparing Solutions by Dilutionby Dilution

Preparing Solutions Preparing Solutions by Dilutionby Dilution

6363You try this dilution problem

• You have a stock bottle of hydrochloric acid, which is 12.1 M. You need 400 mL of 0.10 M HCl. How much of the acid and how much water will you need?

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