Molecular studies on Azadirachta indica Department of Biotechnology, Gulbarga University, Kalaburagi. 1 1. INTRODUCTION India is one of the fastest developing countries with a stable economic growth, which multiplies the demand for transportation in many folds. Fossil fuel consumption is directly proportionate to this demand. India depends mainly on imported fuels due to lack of fossil fuel reservoirs and it has a great impact on the economy. Fast depletion of fossil fuels demands an immediate and urgent need for extensive research so that some viable alternative is obtained and sustainable energy demand with less environmental impact is met. The major environmental concern, as expressed in an IPCC report is most of the observed increase in globally averaged temperatures since the mid 20th century is due to the observed increase in anthropogenic greenhouse gas concentrations (IPCC, 2009). The major percentages of energy used in the world today are being generated from fossil fuel sources. These fossil fuels are non-renewable resources that take millions of years to form and their reserves are being depleted faster than they are being regenerated. They are the major contributors and sources of greenhouse gases, air pollution and global warming. Some of the emissions generated from these fossil fuels are CO, CO 2 , NOx, SOx, unburnt or partially burnt hydrocarbon and particulate (Ndana et al., 2011). Non-renewable fossil fuels are a limited resource that supplies nearly 90% of the world‟s energy demand. Sustained economic growth in India desires for similar trends, especially the increase in global energy consumption (Fig.1). Although it is much debated as to whether substantial oil reserves lie undiscovered, inaccessible or environmentally hazardous to recover. It is widely accepted that the rate of consumption will continue to increase.
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Molecular studies on Azadirachta indica
Department of Biotechnology, Gulbarga University, Kalaburagi.
1
1. INTRODUCTION
India is one of the fastest developing countries with a stable economic growth,
which multiplies the demand for transportation in many folds. Fossil fuel
consumption is directly proportionate to this demand. India depends mainly on
imported fuels due to lack of fossil fuel reservoirs and it has a great impact on the
economy. Fast depletion of fossil fuels demands an immediate and urgent need for
extensive research so that some viable alternative is obtained and sustainable energy
demand with less environmental impact is met. The major environmental concern, as
expressed in an IPCC report is most of the observed increase in globally averaged
temperatures since the mid 20th century is due to the observed increase in
anthropogenic greenhouse gas concentrations (IPCC, 2009).
The major percentages of energy used in the world today are being generated
from fossil fuel sources. These fossil fuels are non-renewable resources that take
millions of years to form and their reserves are being depleted faster than they are
being regenerated. They are the major contributors and sources of greenhouse gases,
air pollution and global warming. Some of the emissions generated from these fossil
fuels are CO, CO2, NOx, SOx, unburnt or partially burnt hydrocarbon and particulate
(Ndana et al., 2011). Non-renewable fossil fuels are a limited resource that supplies
nearly 90% of the world‟s energy demand. Sustained economic growth in India
desires for similar trends, especially the increase in global energy consumption
(Fig.1). Although it is much debated as to whether substantial oil reserves lie
undiscovered, inaccessible or environmentally hazardous to recover. It is widely
accepted that the rate of consumption will continue to increase.
Molecular studies on Azadirachta indica
Department of Biotechnology, Gulbarga University, Kalaburagi.
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Fig 1: World marketed energy consumption 1980-2030
(Adapted from www.eia.doe.gov/iea)
Another concern is advocated by the peak oil theory which predicts a rising
cost of fossil fuels caused by a severe shortage of petroleum reserves underground
during an era of growing energy consumption. According to the peak oil theory, the
demand for oil will exceed the supply, and the gap between the demand and supply
will continue to grow. This could cause a growing energy crisis starting between 2010
and 2020. However, the crisis has not yet come and it may be delayed further. The
reason is that the peak oil theory did not take into consideration the growing
technological developments in the energy sector (Fusco, 2013). Since the majority of
the known petroleum reserves are located in the Middle East, Asia, there is a general
concern that the fuel shortage worldwide could intensify the unrest in this region. This
rate of depletion and environmental issue is seriously calling for an alternative.
An alternative fuel also known as a non-conventional fuel, is any material or
substance that can be used as a fuel other than conventional fuels. Conventional fuels
include fossil fuels (petroleum oil, coal, propane and natural gas) and also nuclear
Molecular studies on Azadirachta indica
Department of Biotechnology, Gulbarga University, Kalaburagi.
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fuels such as uranium in some instances. A host of alternative fuels has already been
identified, and these include biodiesel, bio-alcohol (methanol, ethanol and butanol),
hydrogen, non-fossil methane, non-fossil natural gas, vegetable oils and other fuels
derived from biomass sources. Among all those alternative fuels, biodiesel is the most
promising, popular in the transport sector and other CI engine applications.
1.1 Demand of crude oil in India
Currently India is the third largest oil consumer in the world behind the US,
China and Japan. The US will continue to be the world‟s biggest oil consumer but
with almost no demand growth. The US consumed 18.21 million bpd of oil in 2012,
projected to rise 19.23 million bpd in 2020 before falling to 18.97 million bpd in 2025
and to 18.42 million bpd in 2040. China oil consumption is projected to rise from
10.36 million bpd in 2012 to 15.70 million bpd in 2025 and 20.48 million bpd in
2040, posting a compounded annual growth rate of 2.5%.
India‟s oil consumption growth rate from 2012 to 2040 will be highest in the
world with a 3% compounded annual growth rate. Its oil consumption, according to
EIA, will reach 6.11 million bpd in 2030 and 8.33 million bpd in 2040. As much as
80% of India‟s oil need is met through imports. China‟s gross domestic product
(GDP) is roughly 4.5 times more than that of India and the US gross domestic product
almost nine times that of India. India had in 2013 overtaken. Japan is the world‟s
third-biggest crude oil importer. It imported 3.86 million bpd of crude oil, nearly 6%
higher than Japan‟s customs-cleared imports of 36,48,372 bpd. The International
Energy Agency estimates that India will become the world‟s largest oil importer by
2020 (Fig. 2).
Molecular studies on Azadirachta indica
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Fig 2: Oil demand
The rapid increasing demand for crude oil coupled with the increase in fuel
demand has forced the countries to look for an alternative to conventional fuels. The
biodiesel production from a non edible seed plant like neem, pongamia, mahua, etc.
are being considered as an indigenous source of oil for biodiesel production. Once the
oil resources starts to available in the country, the availability of biodiesel as
substitute to the diesel fuel will increase and dependency on oil import would reduce
thereby making the country self sufficient in fuel supplies.
1.2 Biofuel policy in Karnataka
Karnataka is the India‟s eighth largest state in geographical area covering 1.92
lakh Sq.Km and accounting for 6.3% of the geographical area of the country.
Agriculture is the major occupation for a majority of the rural population in
Karnataka. The agricultural sector of Karnataka is characterized by vast steppes of
drought prone region and sporadic patches of irrigated area. Thus, a large portion of
agricultural land in the state is exposed to the vagaries of monsoon with severe agro-
climatic and resource constraints. Agriculture employs more than 60% of Karnataka‟s
workforce.
Molecular studies on Azadirachta indica
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Karnataka has over 13.5 lakh hectares of such lands and the same can be
utilized for growing biofuel species (Table 1). Village tank fore shore and bunds,
degraded forest lands other government marginal lands, institutional lands left
unproductive, village common lands, bunds of the farmers land can be utilized for
raising biofuel species. The implementation of all programs will be with the total
involvement of farmers, landless labourers, NGOs, VFCs and TUGs. Entire program
will be implemented without affecting the food security of the state.
Karnataka took the lead in constituting the Biofuel Task Force on 12th
September, 2008 for effective planning and implementation of the biofuel programs.
The task force was entrusted with the responsibility of advising the Government and
to create an enabling atmosphere in the state. The Karnataka state has already adopted
the Karnataka Biofuel Policy from 1st March, 2009.
In order to take forward the biofuel activities, the state government has
constituted a permanent body by converting the Biofuel task Force into Karnataka
State biofuel Development Board as a society registered under Registrar of Society
and fully funded by Government of Karnataka. Karnataka state biofuel development
board (KSBDB) constituted under the rural development and panchayat raj
department is taking forward the biofuel policy objectives of the state with effect from
6th
decemeber 2010 in Karnataka state.
1.2.1 Biofuel objectives of KSBDB
Help government design and adopt biofuel programs.
Implementation of such programs in tune with the policy.
Identification of suitable land for raising biofuel crops.
Selection of suitable mix of plant species for different geo-climatic
conditions.
Molecular studies on Azadirachta indica
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Raising of quality seedlings through self help groups (SHGs) village,
forest, committees (VFCs)
To ensure total participation of the committees.
To create awareness among the farmers to adopt biofuel activities for their
additional income.
To provide right impetus to ethanol production and usage.
Promotion of crops such as sugar cane, beet sugar, sweet sorghum, cassava
etc as feedstock for ethanol production.
Setting up of information and demonstration centres for biodiesel
production.
Establishment of seed collection networks.
Programs for value addition and usage of value added products in rural
areas.
Establishment of clonal orchards in different regions across the state.
Encouraging various research activities in the entire biofuel value chain
involving Universities and research organizations.
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Table 1: Biofuel Plants in Karnataka State
Biofuel
plants Neem Pongamia Simarouba Mahua Jatropha
Uses
Biofuel,
Medicine,
Biopesticide,
Oil cake,
Manure,
Agricultural
equipment
Biofuel,
Manufacture
of soap,
Leather
tanning, Oil
cake, Manure,
Medicine,
Biopesticide
Biofuel,
Medicine,
Edible oil,
Biopesticide,
Oil cake,
Manure
Biofuel,
Medicine,
Oil cake,
Manure,
Agricultural
equipment
Biofuel,
Medicine,
Biopesticide
Starts
yielding 5 Years 5-6 Years 5-6 Years 10 Years 3 Years
Yield of
seeds 15-35 Kg 15-40 Kg 10-25 Kg 10-40 Kg 2-4 Kg
Oil
Content 28-35% 30-35% 40-50% 30-35% 30-35%
Seed cost
per Kg 12/- 16/- 11/- 10/- 10/-
Harvesting
period June-August March-May Feb-April June-August Aug-Oct.
1.2.2 Hyderabad Karnataka Region
Hyderabad Karnataka region is situated in the north eastern part of the
Karnataka state and falls within the geographical region of north maiden (Fig. 3). It
spreads between 140 60‟ to 18
0 30‟ Northern latitude and 75
0 60‟ to 77
0 70‟ Eastern
altitude (Brisbhasi, 2001). The region is bound on the north by Sholapur, Nanded and
Usmanabad districts of Maharashtra State and on the east by Nizamabad, Medak,
Mahaboob Nagar, Rangareddy districts of Andhra Pradesh, in the south by Karnool
district of Andhra Pradesh and Chitradurga, Devangere districts of Karnataka state in
the west by Bijapur, Bagalkot, Gadag and Haveri districts of Karnataka state.
The Hyderabad Karnataka region covers the area of 44138 Sq.Km. This is
account for 23.12% of the total geographical area of the Karnataka State. At presently
it is consist of six districts i.e., Bellary, Bidar, Gulbarga, Yadgir, Raichur and Koppal.
The Karnataka State Biofuel Development Board has identified the Hyderabad
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Karnataka region as the best site in the State, with its vast wastelands, for the
cultivation of biofuel plants to increase its production manifold (Table 2).
Fig 3: Administrative Map of Hyderabad Karnataka Region
Table 2: Wastelands of Hyderabad Karnataka region
HK Region Wasteland (Hectares)
Bidar 19,127
Gulbarga 63,155
Yadigir 63,155
Raichur 20,084
Bellary 53,477
Koppal 16,627
Molecular studies on Azadirachta indica
Department of Biotechnology, Gulbarga University, Kalaburagi.
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1.2.2.1 Physiographic of HK Region
Physiographical, the Hyderabad Karnataka region forms the part of two well
defined physiographic region of Karnataka state.
Northern part of Karnataka Plateau
The northern Karnataka plateau comprises the districts of Bidar and Gulbarga.
It is largely composed of Deccan trap. It represents a monotonous treeless extensive
plateau landscape with a general elevation of 300 to 600 mts. From the mean sea level
this region is largely covered with the rich black cotton soil.
Central Karnataka plateau
The central Karnataka plateau comprises of the districts of Raichur, Koppal
and Bellary. The region represents the transisnal surface between the Northern
Karnataka plateaus with relatively higher surface. By and large this region represents
the area of Tungabhadra basin. The general evaluation varies between 450 to700 mts.
from the sea level.
1.2.2.2 Soil
The soil condition in Hyderabad Karnataka region varies from district to
district. Major portion of Gulbarga and Bidar districts consists of deep black soil, few
parts of Bidar district i.e., Humanabad, Basavakalyan, Bidar talukas have laterite soil.
On the other hand the districts of Raichur, Koppal, Yadgir and Bellary districts are
covered by the reddish. Sandy soil, the light green loamy soil and there reddish drown
soil. The soil and climate conditions are very district to district in the H.K. region.
1.2.2.3 Climate
The climate of the H.K. region in general is characterized by dryness for the
major part of the year and a very hot summer. The year may be divided broadly into
four seasons. The hot season begins by the middle of February and extends to the end
Molecular studies on Azadirachta indica
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of May. The south-west monsoon season is from June to the end of September.
October and November are post monsoon and the period from December to the
middle of February is the cold season. The region receives rainfall both from south-
west and North West monsoons. However, the mean rainfall in the region is very
scant at 692 million meter in a year.
1.3 Biodiesel in India
The consumption of diesel fuel in India is approximately six times that of
gasoline fuel, as shown in Table 3 (BPC, 2013). The table predicts a rising cost of oil-
derived fuels caused by severe shortages of oil because of growing energy demand.
Renewable fuels, particularly biodiesel, should get more attention in India.
Researchers are trying to find several ways to make biodiesel from different feedstock
such as edible oil, non-edible oil, waste vegetable oil, algae, animal tallow and fats,
etc.
Table 3: Demand for gasoline and diesel in India.
Year Gasoline demand (MMT) Diesel demand (MMT)
2001–2002 7.07 39.81
2002–2003 7.62 42.15
2003–2004 8.20 44.51
2004–2005 8.81 46.97
2005–2006 9.42 49.56
2006–2007 10.07 52.33
2011–2012 12.85 66.90
The transesterification process, employed to manufacture biodiesel from raw
feedstock, yields a byproduct glycerol, which has many applications in the
pharmaceutical, cosmetics and food industries. Sharma and Singh in 2010 produced
biodiesel from non-edible feedstock such as Karanja, Mahua and a hybrid mixture
(50:50 v/v) of the two. Saka and Kusdiana in 2011 produced biodiesel from rapeseed
vegetable oil. Venkanna and Reddy in 2009 produced biodiesel from Calophyllum
Molecular studies on Azadirachta indica
Department of Biotechnology, Gulbarga University, Kalaburagi.
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Inophyllum Linn oil. Ghadge and Raheman in 2005-06 produced biodiesel from
Mahua oil.
Biodiesel produced from different sources, may be considered supplementary
fuels to the diesel fuel in CI engine applications. In addition, it also promises
employment to rural people through the opportunities of cultivation of oil bearing
plants, and this may help to improve the domestic economy. Biodiesel is a clean
burning fuel, and it can be produced from 100% renewable resources (Minnesota,
2013). Several experimental studies (Palit et al., 2011; Agarwal and Das, 2000; Shaoo
and Das, 2009; Misra and Murthy, 2011) available in the literature have shown that
biodiesel and biodiesel-diesel blends reduce smoke opacity, emission of particulate
matter, unburnt hydrocarbon and carbon monoxide as well as life-cycle carbon
dioxide emissions. However, the emission of nitrogen oxides increases to some extent
with the use of biodiesel as fuel. However, the NOx emissions can be reduced by the
use of any post-combustion techniques such as exhaust gas recirculation and catalytic
conversion. As biodiesel contains about 11% excess oxygen, the calorific value is
lower than diesel, but it enhances the combustion process. The peak pressure rise after
TDC with biodiesel makes the combustion process safer and more efficient. Another
advantage is the shorter ignition delay of biodiesel, which results in a decrease in
maximum heat release rate.
Biodiesel does not contain petroleum, but it can be mixed with petroleum and
a biodiesel blend thus made it can be used in a number of vehicles. Biodiesel is
biodegradable and nontoxic. It has even been claimed to be less toxic than common
salt. Biodiesel is made from oil through a process called transesterification. This
process involves removing the glycerin from the oil or fat. Biodiesel is free from
some environmentally harmful substances such as sulfur and aromatics that are found
Molecular studies on Azadirachta indica
Department of Biotechnology, Gulbarga University, Kalaburagi.
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Fig 4: Transesterification reaction for biodiesel production
in the traditional diesel fuels. The overall reaction of the transesterification process is
shown in Fig 4.
1.4 Biofuel policy in India
The Government of India (GOI) approved the National Policy on Biofuels on
December 24, 2009. The policy encourages use of renewable energy resources as
alternate fuel to supplement transport fuels and had proposed an indicative target to
replace 20% of petroleum fuel consumption with biofuels (bioethanol and biodiesel)
by end of 12th Five-Year Plan (2017).
Indian Governement has adopted several policies in order to strengthen the
biofuel sector. It starts with the selection of appropriate feedstock having a relatively
higher oil yield and higher availability. The selection of the feedstock should be made
in such a manner so that the cultivation throughout the country with minimum cost is
possible. It also includes the identification of lands and seeds and the task of
motivating farmers for cultivating the biodiesel feedstock, mainly the non-edible plant
like Neem. So there is a long chain of activities that starts with the identification of oil
seeds, extraction of oil from the seed, transesterification of the raw vegetable oil for
the production of biodiesel, transportation of biodiesel to the oil depot, making blends
with mineral diesel, and finally, distribution to retailers. Table 4 (Kumar and Sharma,
2011) and Table 5 (Borugadda and Goud, 2012) estimated the yield of oil seed and
the potential of non-edible oil seed, respectively, in the Indian scenario. It can be seen
Molecular studies on Azadirachta indica
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from Table 4 that the oil yield of neem per hectare of land is highest among the
prospective non-edible oil seeds. It is quite interesting to note from the data in Table 5
that although neem has higher potential, it is found to be very attractive in the sense
that it can grow in adverse agro-climatic conditions throughout India. For the above-
mentioned reasons, neem has been identified as one of the most acceptable another
potential biodiesel-producing feedstock in India.
Table 4: Estimated yield of non-edible oil from different plants