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SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006
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SDS # : 087920 AVGAS 100LL
Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF
THECOMPANY/UNDERTAKING
1.1. Product identifier
Product name AVGAS 100LLSubstance/mixture Mixture
1.2. Relevant identified uses of the substance or mixture and
uses advised against
Identified uses Fuel for aircraft piston engines.
1.3. Details of the supplier of the safety data sheet
Supplier TOTAL EUROPEAN TRADINGTour Coupole2 place Jean
Millier92400 COURBEVOIEFRANCETél: +33 (0)1 47 44 45 46
For further information, please contact:
Contact Point Technical/ HSEQE-mail Address [email protected]
1.4. Emergency telephone number
For English and European languages: +44 1235 239 670For Arabic:
+44 1235 239 671For Asia Pacific in English, Mandarin, or local
languages (Philippines, India, Sri Lanka, Malaysia, Indonesia,
Thailand, Vietnam,Korea, Japan): +65 3158 1074P.R. China: +86 532
8388 9090US & Canada in English, French, Spanish : +1 215 207
0061
Section 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
REGULATION (EC) No 1272/2008For the full text of the
H-Statements mentioned in this Section, see Section 2.2.
Date of the previous version: not applicable Revision Date:
2018-12-13 Version 1
Version EU
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ClassificationFlammable liquids - Category 1 - H224Aspiration
toxicity - Category 1 - H304Acute oral toxicity - Category 4 -
H302Acute dermal toxicity - Category 4 - H312Acute inhalation
toxicity - vapor - Category 4 - H332Skin corrosion/irritation -
Category 2 - H315Reproductive toxicity - Category 2 - H361dSpecific
target organ toxicity (single exposure) - Category 3 - H336Specific
target organ toxicity (repeated exposure) - Category 2 -
H373Chronic aquatic toxicity - Category 2 - H411
2.2. Label elements
Labelled according to REGULATION (EC) No 1272/2008
Contains Gasoline, Tetraethyllead
Signal wordDANGER
Hazard StatementsH224 - Extremely flammable liquid and vaporH332
- Harmful if inhaledH312 - Harmful in contact with skinH302 -
Harmful if swallowedH336 - May cause drowsiness or dizzinessH373 -
May cause damage to organs through prolonged or repeated
exposureH304 - May be fatal if swallowed and enters airwaysH315 -
Causes skin irritationH361d - Suspected of damaging the unborn
childH411 - Toxic to aquatic life with long lasting effects
Precautionary StatementsP210 - Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No
smokingP261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP280 -
Wear protective gloves and eye/face protectionP302 + P352 - IF ON
SKIN: Wash with plenty of soap and waterP301 + P310 - IF SWALLOWED:
Immediately call a POISON CENTER or doctor/physicianP331 - Do NOT
induce vomitingP362 - Take off contaminated clothing and wash
before reuseP403 + P233 - Store in a well-ventilated place. Keep
container tightly closedP243 - Take precautionary measures against
static dischargeP240 - Ground/bond container and receiving
equipmentP241 - Use explosion-proof electrical/ ventilating/
lighting/ equipment
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P242 - Use only non-sparking toolsP273 - Avoid release to the
environmentP501 - Dispose of contents/ container to an approved
waste disposal plant
2.3. Other hazards
Physical-Chemical Properties Extremely flammable. Highly
volatile. The vapours are heavier than air and may carry alongthe
ground giving a high risk of explosion . In case of pump , Friction
generated by product discharge can create static charges
ofsufficient magnitude to cause SPARKS WHICH MAY LEAD TO FIRE OR
EXPLOSION.
Properties Affecting Health May cause central nervous system
depression with nausea, headache, dizziness, vomiting,and
incoordination.Vapors or mists are irritating for mucous membranes,
notably in the eyes.If swallowed accidentally, the product may
enter the lungs due to its low viscosity and leadto the rapid
development of very serious pulmonary lesions (medical survey
during 48hours).
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixture
Chemical nature A complex and variable combination of
paraffinic, cyclic and aromatic hydrocarbons havinga carbon number
range predominantly of C4 to C12 and boiling in the range
ofapproximately 30°C to 170°C.
Hazardous ingredientsChemical Name EC-No REACH registration
NoCAS-No Weight % Classification (Reg. 1272/2008)
Gasoline 289-220-8 01-2119471335-39 86290-81-5 >99 Flam. Liq.
1 (H224)Repr. 2 (H361d)
Asp. Tox. 1 (H304)Skin Irrit. 2 (H315)STOT SE 3 (H336)
Aquatic Chronic 2 (H411)Tetraethyllead 201-075-4 no data
available 78-00-2
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For the full text of the H-Statements mentioned in this Section,
see Section 16.
Section 4: FIRST AID MEASURES
4.1. Description of first-aid measures
General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL
A DOCTOR OREMERGENCY MEDICAL CARE. Before attempting to rescue
casualties, isolate area from all potential sources of
ignitionincluding disconnecting electrical supply. Ensure adequate
ventilation and check that a safe, breathable atmosphere is
present
Chemical Name EC-No CAS-No Weight % Classification
(Reg.1272/2008)
2-methylbutane 201-142-8 78-78-4
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before entry into confined spaces. Drench contaminated clothing
with water before removing to avoid risk of sparks from
staticelectricity.
Eye contact Rinse thoroughly with plenty of water, also under
the eyelids. Check for and remove any contact lenses. Rinse eyes.If
eye irritation persists, consult a specialist.
Skin contact Remove contaminated clothing and shoes. Wash skin
with soap and water.High pressure injection of the products under
the skin may have very serious consequenceseven though no symptom
or injury may be apparent.In this case, the casualty should be sent
immediately to hospital.Wash off with soap and water.
Inhalation In case of exposure to intense concentrations of
vapours, fumes or spray, transport theperson away from the
contaminated zone, keep warm and allow to rest. Immediately begin
artificial respiration if breathing has ceased. Call a
physicianimmediately.
Ingestion Give nothing to drink.Do NOT induce vomiting, as there
is high risk of aspiration. The fluid can enter the lungsand cause
damage (chemical pneumonitis, potentially fatal).Take victim
immediately to hospital.Do not wait for symptoms to develop.
Protection of First-aiders CAUTION! First aid personnel must be
aware of personal risk during rescue!.Use personal protective
equipment. See Section 8 for more detail.
4.2. Most important symptoms and effects, both acute and
delayed
Eye contact Burning feeling and temporary redness.
Skin contact Irritating to skin.
Inhalation Inhalation of vapours may cause headache, nausea,
vomiting and an altered state ofconsciousness.
Ingestion Ingestion may cause gastrointestinal irritation,
nausea, vomiting and diarrhea. May causecentral nervous system
depression.Harmful: If swallowed accidentally, the product may
enter the lungs due to its low viscosityand lead to the rapid
development of very serious inhalation pulmonary lesions
(medicalsurvey during 48 hours).
4.3. Indication of any immediate medical attention and special
treatment needed
Notes to physician Harmful: If swallowed accidentally, the
product may enter the lungs due to its low viscosityand lead to the
rapid development of very serious inhalation pulmonary lesions
(medicalsurvey during 48 hours). Treat symptomatically.
Section 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing media
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Suitable Extinguishing Media Extinguishing media - small fires.
Carbon dioxide (CO 2). Dry powder. Sand or earth.Extinguishing
media - large fires. Foam. Foams on base of general-purpose
emulsifier.Water spray. Water fog (trained personnel only).
Unsuitable Extinguishing Media Do not use a solid water stream
as it may scatter and spread fire.Simultaneous use of foam and
water on the same surface is to be avoided as waterdestroys the
foam.
5.2. Special hazards arising from the substance or mixture
Special Hazard In case of fire hazardous decomposition products
may be produced such as:. Sulfur oxides.Incomplete combustion and
thermolysis may produce gases of varying toxicity such ascarbon
monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot.
These maybe highly dangerous if inhaled in confined spaces or at
high concentration.Vapors may form explosive mixtures with air.
5.3. Advice for fire-fighters
Special protective equipment forfire-fighters
In case of a large fire or in confined or poorly ventilated
spaces, wear full fire resistantprotective clothing and
self-contained breathing apparatus (SCBA) with a full
face-pieceoperated in positive pressure mode.
Other information Cool down any tanks and surfaces exposed to
fire by spraying abundantly with water. Usewater to cool tanks and
parts exposed to the thermal flux not caught up in the flames.Do
not allow run-off from fire fighting to enter drains or water
courses. Fire residues andcontaminated fire extinguishing water
must be disposed of in accordance with localregulations.
Section 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency
procedures
General Information Except in case of small spillages. The
feasibility of any actions should always be assessedand advised, if
possible, by a trained, competent person in charge of managing
theemergency. If required, notify relevant authorities according to
all applicable regulations.Avoid contact with skin, eyes and
inhalation of vapors. Evacuate non-essential personnel.For personal
protection see section 8. Stop or contain leak at the source, if
safe to do so. Cut off the electric power supply if thisoperation
causes no sparks in the area containing vapors from the product.
Stay upwind.In case of large spillages, alert occupants in downwind
areas. ELIMINATE all ignitionsources (no smoking, flares, sparks or
flames in immediate area). In case of importantspillages: risk of
fire or explosion . Cover discharges with foam in order to reduce
the risksof ignition. Vapours are heavier than air and may spread
near ground level to sources ofignition .
Advice for non-emergencypersonnel
Do not touch or walk through spilled material. For personal
protection see section 8.ELIMINATE all ignition sources (no
smoking, flares, sparks or flames in immediate area).
Advice for emergency responders Take all appropriate steps to
avoid fire, explosion and inhalation hazards to the
rescuersincluding the use of breathing apparatus. In case of: Small
spillages: normal antistatic working clothes are usually adequate.
Large spillages: full body suit of chemically resistant and
antistatic material. Work gloves
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(preferably gauntlets) providing adequate chemical resistance.
Remarks:. Gloves made ofPVA are not water-resistant, and are not
suitable for emergency use. Work helmet.Antistatic non-skid safety
shoes or boots. Goggles and/or face shield, if splashes or
contactwith eyes is possible or anticipated.Respiratory protection.
In the case of vapor formation use a respirator with an
approvedfilter. A Self-Contained Breathing Apparatus (SCBA) can be
used according to the extent ofspill and predictable amount of
exposure. If the situation cannot be completely assessed,or if an
oxygen deficiency is possible, only SCBA’s should be used.
6.2. Environmental precautions
General Information The product should not be allowed to enter
drains, water courses or the soil. Do not allowmaterial to
contaminate ground water system. In case of spill in river, suspend
the use of the water downstream to the spillpoint. Ifnecessary,
Consult an expert. Local authorities should be advised if
significant spillagescannot be contained.
6.3. Methods and material for containment and cleaning up
Methods for containment Contain and collect spillage with
non-combustible absorbent material, (e.g. sand, earth,diatomaceous
earth, vermiculite) and place in container for disposal according
to local /national regulations (see Section 13). Large spillages
may be cautiously covered withfoam, if available, to limit fire
risk. In case of spillage in the water: Let the product spreadon
the surface of the water. In case of no obstacle (barrage, bank or
shore). Spillages ofliquid product in the water will likely result
in a quick and complete vaporization of theproduct. In case of
small spillages in closed waters , when the quantities to be
recoveredare small (some tens of liters), contain product with
floating barriers or other equipment.
Methods for cleaning up Never use dispersing agents. Transfer
recovered product and other materials to suitable tanks or
containers andstore/dispose according to relevant regulations.Do
not flush into surface water or sanitary sewer system. Prevent
product from enteringdrains.
6.4. Reference to other sections
Personal Protective Equipment See Section 8 for more detail.
Waste treatment See section 13.
Other information Recommended measures are based on the most
likely spillage scenarios for this material.However, local
conditions (wind, air temperature, wave/current direction and
speed) maysignificantly influence the choice of appropriate
actions. For this reason, local experts should be consulted when
necessary. Local regulations may also prescribe or limit actions to
be taken.
Section 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Advice on safe handling Ensure that all relevant regulations
regarding explosive atmospheres, handling and storagefacilities of
flammable products, are followed. Take precautionary measures
against staticelectricity.
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The inspection, cleaning and maintenance of storage containers
require the application ofstrict procedures and must be entrusted
to qualified personnel (internal or external).Ensure adequate
ventilation. Vapors may form explosive mixtures with air. Do not
smoke.Avoid breathing vapors or mists. Avoid contact with skin,
eyes and clothing.NEVER ATTEMPT TO PRIME THE CONTAINER SIPHON BY
SUCKING WITH THEMOUTH. Prevent the formation of vapors, mists and
aerosols. Do not use compressed air for filling, discharging, or
handling operations. Never pierce,drill, grind, cut, saw or weld
any empty container.For personal protection see section 8.
Technical measures Ensure adequate ventilation.WHILE MOVING THE
PRODUCT:. To avoid ignition of vapors by static
electricitydischarge, all metal parts of the equipment must be
grounded.Take all necessary precautions to prevent water from
entering the containers, tanks,transfer lines etc...
Prevention of fire and explosion Handle away from any source of
ignition (open flame and sparks) and heat (hot manifoldsor
casings). Take precautionary measures against static discharges.
Ground/bondcontainers, tanks and transfer/receiving equipment.
Friction generated by product dischargecan create static charges of
sufficient magnitude to cause SPARKS WHICH MAY LEAD TOFIRE OR
EXPLOSION. Do not allow splash loading and ensure that the product
is pouredslowly, particularly at the beginning of the
operation.Empty containers may contain flammable or explosive
vapors. Never weld any container orempty pipe that has not been
degassed.OPERATE ONLY ON COLD AND DEGASSED TANKS IN VENTILATED
PREMISES (TOAVOID RISK OF EXPLOSION).Design installations
(machinery and equipment) to prevent burning product from
spreading(tanks, retention systems, interceptors (traps) in
drainage systems).
Hygiene measures When using, do not eat, drink or smoke. Avoid
contact with skin, eyes and clothing. Avoidbreathing vapors, mist
or gas. Wash hands before breaks and immediately after handlingthe
product. IF ON SKIN: Wash skin with soap and water. Remove
contaminated clothingand shoes. Gloves must be periodically
inspected and changed in case of wear, perforations
orcontaminations.Provide regular cleaning of equipment, work area
and clothing. Keep away from food, drinkand animal feeding stuffs.
Ensure the application of strict rules of hygiene by the
personnelexposed to the risk of contact with the product. Use
personal protective equipment asrequired.
7.2. Conditions for safe storage, including any
incompatibilities
Technical measures/Storageconditions
Storage area layout, tank design, equipment and operating
procedures must comply withthe relevant European, national or local
legislation.. All the electric installations, including the
lighting of rooms that may contain this product,must be adapted to
the risk area, in compliance with the European ATEX directives.
Takeprecautionary measures against static discharges.. Ensure all
equipment is electrically grounded before beginning transfer
operations.Storage installations should be designed with adequate
bunds so as to prevent ground orwater pollution in case of leaks or
spills. Do not remove the hazard labels of the containers(even if
they are empty).. Store the packed products (drums, samples, cans
...) in properly ventilated rooms, awayfrom damp, heat and any
potential source of ignition.. Keep preferably in the original
container. Otherwise reproduce all indication of the
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regulation label on the new container. Keep containers tightly
closed and properly labelled.Store separately from oxidising
agents.
Materials to Avoid Dangerous reaction with oxidizing agents
(chlorates, nitrates, and permanganates...).
Packaging material Use only hydrocarbon-resistant containers,
seals, pipes, etc.
7.3. Specific end uses
Specific use(s) See exposure scenarios.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Exposure limits Ingredients with workplace control
parameters
Other constituents required for disclosure
Chemical Name European Union2-methylbutane
78-78-4TWA 1000 ppm
TWA 3000 mg/m3
Xylene (mixed isomers o, m, p) 1330-20-7
TWA 50 ppmTWA 221 mg/m3
STEL 100 ppmSTEL 442 mg/m3
S*n-Hexane 110-54-3
TWA 20 ppmTWA 72 mg/m3
1,2,4-Trimethylbenzene 95-63-6
TWA 20 ppmTWA 100 mg/m3
Ethylbenzene 100-41-4
TWA 100 ppmTWA 442 mg/m3
STEL 200 ppmSTEL 884 mg/m3
S*toluene
108-88-3TWA 50 ppm
TWA 192 mg/m3
STEL 100 ppmSTEL 384 mg/m3
S*Benzene 71-43-2
S*TWA 1 ppm
TWA 3.25 mg/m3
Legend See section 16
Biological standards
Other constituents required for disclosure
DNEL Worker (Industrial/Professional)Chemical Name Short term,
systemic
effectsShort term, local effects Long term, systemic
effectsLong term, local effects
Gasoline 1300 mg/m3/15min 1100 mg/m3/15min 840 mg/m3/8h
(inhalation)
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86290-81-5 (inhalation) (inhalation)DNEL Consumer
Chemical Name Short term, systemiceffects
Short term, local effects Long term, systemiceffects
Long term, local effects
Gasoline 86290-81-5
1200 mg/m3/15min(inhalation)
640 mg/m3/15min(inhalation)
180 mg/m3/24h(inhalation)
8.2. Exposure controls
Occupational Exposure Controls
Engineering Measures Ensure adequate ventilation. Apply
technical measures to comply with the occupationalexposure
limits.When working in confined spaces (tanks, containers, etc.),
ensure that there is a supply ofair suitable for breathing and wear
the recommended equipment. Do not enter emptystorage tanks until
measurements of available oxygen have been carried out.
Personal Protective Equipment
General Information Protective engineering solutions should be
implemented and in use before personalprotective equipment is
considered.
Respiratory protection In case of insufficient ventilation, wear
suitable respiratory equipment. To enter tankers,tanks, reservoirs
where the oxygen content is too low, wear insulating
respiratoryapparatus.. In an emergency or for exceptional
short-lasting jobs in an atmosphere polluted by theproduct, it is
necessary to wear protective respiratory equipment. When using a
mask orhalf mask :. Full face piece respirator with organic
vapor/acid gas cartridge or canister. TypeA. The use of breathing
apparatus must comply strictly with the manufacturer's
instructionsand the regulations governing their choices and
uses.
Eye Protection If splashes are likely to occur, wear:. Safety
glasses with side-shields. or. Face-shield.
Skin and body protection Wear suitable protective clothing.
hydrocarbon-proof clothing. Protective shoes or boots.
Hand Protection Hydrocarbon-proof gloves for aromatic
hydrocarbons. Please observe the instructionsregarding permeability
and breakthrough time which are provided by the supplier of
thegloves. Also take into consideration the specific local
conditions under which the product isused, such as the danger of
cuts, abrasion, and the contact time.. Note. Gloves made of PVA are
not water-resistant, and are not suitable for emergencyuse.
Repeated or prolonged exposureGlove material Glove thickness
Break through time Remarks
PVA (*) > 480 min EN 374 (*) any thicknessFluorinated rubber
(*) > 480 min EN 374 (*) any thickness
Nitrile rubber > 0.5 mm > 480 min EN 374
In case of contact through splashing:Glove material Glove
thickness Break through time RemarksNitrile rubber > 0.3 mm >
60 min EN 374
Environmental exposure controls
General Information The product should not be allowed to enter
drains, water courses or the soil.
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Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance limpidColor bluePhysical State @20°C liquidOdor
CharacteristicOdor Threshold No information available
9.2. Other information
Section 10: STABILITY AND REACTIVITY
10.1. Reactivity
General Information No information available.
Property Values Remarks Method pH Not applicableMelting
point/range No information available
Boiling point/boiling range 30 - 170 °C ASTM D 86 86 - 338 °F
ASTM D 86
Flash point < -40 °C ASTM D 93< -40 °F ASTM D 93
Evaporation rate Not applicableFlammability Limits in Air
upper 8.7 %Lower 1.4 %
Vapor Pressure 70 kPa @ 50 °C approximately EN 13016-1Vapor
density > 3Relative density No information availableDensity 700
- 740 kg/m3 @ 15 °CWater solubility 0.025 Practically insoluble To
slightly
solubleSolubility in other solvents Soluble in many common
organic solventslogPow Not applicableAutoignition temperature
> 300 °C ASTM E659-78
> 572 °F ASTM E659-78Decomposition temperature No information
availableViscosity, kinematic < 1 mm2/s @ 20 °C ISO
3104Explosive properties Not explosiveOxidizing Properties This
product is not considered oxidising based on chemical structure
considerationsPossibility of hazardous reactions None under normal
processing
Freezing Point No information available
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10.2. Chemical stability
Stability Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous Reactions None under normal processing.
10.4. Conditions to avoid
Conditions to avoid Take precautionary measures against static
discharges. Heat, flames and sparks.
10.5. Incompatible materials
Materials to Avoid Dangerous reaction with oxidizing agents
(chlorates, nitrates, and permanganates...).
10.6. Hazardous Decomposition Products
Hazardous Decomposition Products None under normal use.
Section 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity Local effects Product Information
General Information The acute toxicity has been adequately
characterised in a large number of GLP-compliantguideline
investigations following oral, dermal or inhalation exposure.
Skin contact . Irritating to skin.
Eye contact This product does not meet the EU criteria for
classification. Burning feeling and temporary redness.
Inhalation . Inhalation of vapours may cause headache, nausea,
vomiting and an altered state ofconsciousness.
Ingestion . Ingestion may cause gastrointestinal irritation,
nausea, vomiting and diarrhea. May causecentral nervous system
depression.Harmful: If swallowed accidentally, the product may
enter the lungs due to its low viscosityand lead to the rapid
development of very serious inhalation pulmonary lesions
(medicalsurvey during 48 hours).
Acute toxicity - Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 InhalationGasoline LD50
> 5000 mg/kg bw (rat -
OECD TG 401)LD50 > 2000 mg/kg bw (rabbit -OECD TG 402 - under
occlusive
conditions)
LC50 (4h) > 5610 mg/m3 air(vapor) (rat - OECD 403)
Tetraethyllead = 12.3 mg/kg ( Rat ) = 850 mg/m3 ( Rat ) 1 h
Sensitization
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Sensitization This product does not meet the EU criteria for
classification.
Specific effects
Carcinogenicity This product does not meet the EU criteria for
classification.Other constituents required for disclosure
Chemical Name European UnionBenzene 71-43-2
Carc. 1A (H350)
Mutagenicity . This product does not meet the EU criteria for
classification.Other constituents required for disclosure
Chemical Name European UnionBenzene 71-43-2
Muta. 1B (H340)
Reproductive toxicity Suspected of damaging the unborn
child.
Chemical Name European UnionGasoline
86290-81-5Repr. 2 (H361d)
Tetraethyllead 78-00-2
Repr. 1A (H360Df)
Other constituents required for disclosureChemical Name European
Union
n-Hexane 110-54-3
Repr. 2 (H361f)
toluene 108-88-3
Repr. 2 (H361d)
Repeated dose toxicity
Target Organ Effects (STOT)
Specific target organ systemictoxicity (single exposure)
Acute exposure studies show no evidence of systemic toxicity,
other than a potential tocause narcosis / CNS depression at higher
exposure concentrations.
Specific target organ systemictoxicity (repeated exposure)
The repeat dose toxicity of the substance has been studied
following dermal and inhalationexposure for periods between 10 days
and up to 2 years. In dermal studies, no systemictoxicity has been
seen. The only effect observed was moderate to severe dermal
irritation.Repeated inhalation exposure causes : light hydrocarbon
nephropathy.
Aspiration toxicity The fluid can enter the lungs and cause
damage (chemical pneumonitis, potentially fatal).
Other information
Other information No information available.
Section 12: ECOLOGICAL INFORMATION
12.1. Toxicity
Toxic to aquatic life with long lasting effects.
Acute aquatic toxicity - Product Information
No information available.
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Acute aquatic toxicity - Component Information
Chemical Name Toxicity to algae Toxicity to daphnia andother
aquatic invertebrates
Toxicity to fish Toxicity tomicroorganisms
Gasoline 86290-81-5
EL50 (72 h) > 3.1 mg/l(Selenastrum
capricornutum/Pseudokirchnerella subcapitata - OECD
201)
EL50 (48 h) > 4.5 mg/l(Daphnia magna - OECD
202)
LL50 (96 h) > 8.2 mg/l(Pimephales promelas -
OECD 203)
Tetraethyllead 78-00-2
EC50 (48h) = 0.1 mg/LDunaliella tertiolecta
EC50 (48h) = 0.085 mg/LArtemia salina
LC50 (96h) = 19.3 mg/LPimephales promelas ()LC50 (96h) = 84
mg/L
Lepomis macrochirus ()
Chronic aquatic toxicity - Product Information No information
available.
Chronic aquatic toxicity - Component Information .
Chemical Name Toxicity to algae Toxicity to daphnia andother
aquatic invertebrates
Toxicity to fish Toxicity tomicroorganisms
Gasoline 86290-81-5
NOEL (21d) > 2.6 mg/l(Daphnia magna - OECD
211)
NOEL (14/28d) > 2.6 mg/l(Read across from Daphnia
magna)
Effects on terrestrial organisms No information available.
12.2. Persistence and degradability
General InformationNo product level data available.
12.3. Bioaccumulative potential
Product Information No information available.
logPow Not applicableComponent Information .
Chemical Name log PowTetraethyllead - 78-00-2 4.32
12.4. Mobility in soil
Soil Given its physical and chemical characteristics, the
product is generally mobile in theground. It may contaminate ground
water.
Air The product evaporates in the air and dissipates more or
less depending on localconditions. However, it may stagnate in
pools in low-lying areas, in an undisturbed orconfined
atmosphere.
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SDS # : 087920 AVGAS 100LLRevision Date: 2018-12-13 Version
1
Water The product spreads on the surface of the water. May
exhibit slight solubility in water.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment This product contains no substance
considered as PBT and/or vPvB according to REACHregulation annex
XIII criteria.
12.6. Other adverse effects
General Information No information available.
Section 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste from Residues / UnusedProducts
Dispose of in accordance with the European Directives on waste
and hazardous waste.
Contaminated packaging Empty containers may contain flammable or
explosive vapors. Do not cut, weld, bore, burnor incinerate emptied
containers, unless they have been cleaned and declared safe.
Emptycontainers should be taken to an approved waste handling site
for recycling or disposal.
EWC Waste Disposal No. According to the European Waste
Catalogue, Waste Codes are not product specific, butapplication
specific. Waste codes should be assigned by the user based on the
applicationfor which the product was used.
Section 14: TRANSPORT INFORMATION
ADR/RID UN/ID No UN1203Proper shipping name GASOLINEProper
shipping name GASOLINEHazard class 3Packing Group IIADR/RID-Labels
3Environmental hazard YesClassification Code F1Special Provisions
243, 534, 363Tunnel Restriction Code (D/E)ADR Hazard Id
(KemmlerNumber)
33
Description UN1203, GASOLINE, 3, II, (D/E)Excepted Quantity
E2Limited quantity 1 L
IMDG/IMO UN/ID No UN1203Proper shipping name GasolineHazard
class 3Packing Group IIMarine pollutant Yes
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_____________________________________________________________________________________________
_____________________________________________________________________________________________
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SDS # : 087920 AVGAS 100LLRevision Date: 2018-12-13 Version
1
EmS No. F-E, S-EDescription UN1203, Gasoline, 3, II, (-40°C
c.c.)Special Provisions 243, 363Excepted Quantity E2Limited
quantity 1 L
ICAO/IATA UN/ID No UN1203Proper shipping name GasolineHazard
class 3Packing Group IIERG Code 3HSpecial Provisions
A100Description UN1203, Gasoline, 3, IIExcepted Quantity E2Limited
quantity 1 L
ADN UN/ID No UN1203Proper shipping name GASOLINEProper shipping
name GASOLINEHazard class 3Packing Group IIEnvironmental hazard
YesClassification Code F1Special Provisions 243, 363,
534Description UN1203, GASOLINE, 3, IIExcepted Quantity E2Limited
quantity 1 LVentilation VE01
Section 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation
specific for the substance or mixture
European Union
REACHAll substances contained in this mixture have been
pre-registered, registered or are exempt from registration in
accordance withRegulation (CE) No. 1907/2006 (REACh)
Other regulationsDIRECTIVE 2010/75/EU on industrial emissions.
Take note of Dir 94/33/EC on the protection of young people at
work. Take noteof Dir 92/85/EEC on the safety and health at work of
pregnant workers.
Take note of Directive 98/24/EC on the protection of the health
and safety of workers from the risks related to chemical agents
atwork
International Inventories All the substances contained in this
product are listed or exempted from listing in the
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_____________________________________________________________________________________________
_____________________________________________________________________________________________
Page 17 / 41
SDS # : 087920 AVGAS 100LLRevision Date: 2018-12-13 Version
1
following inventories:Australia (AICS)Canada (DSL/NDSL)Europe
(EINECS/ELINCS/NLP)Korea (KECL)New Zealand (NZIoC)Philippines
(PICCS)
Further information
No information available
15.2. Chemical Safety Assessment
Chemical Safety Assessment See exposure scenarios
Section 16: OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3H224
- Extremely flammable liquid and vaporH225 - Highly flammable
liquid and vaporH226 - Flammable liquid and vaporH300 - Fatal if
swallowedH301 - Toxic if swallowedH302 - Harmful if swallowedH304 -
May be fatal if swallowed and enters airwaysH310 - Fatal in contact
with skinH312 - Harmful in contact with skinH315 - Causes skin
irritationH319 - Causes serious eye irritationH330 - Fatal if
inhaledH332 - Harmful if inhaledH335 - May cause respiratory
irritationH336 - May cause drowsiness or dizzinessH340 - May cause
genetic defectsH350 - May cause cancerH360Df - May damage the
unborn child. Suspected of damaging fertilityH361d - Suspected of
damaging the unborn childH361f - Suspected of damaging
fertilityH372 - Causes damage to organs through prolonged or
repeated exposureH373 - May cause damage to organs through
prolonged or repeated exposureH400 - Very toxic to aquatic lifeH410
- Very toxic to aquatic life with long lasting effectsH411 - Toxic
to aquatic life with long lasting effectsH412 - Harmful to aquatic
life with long lasting effects
Abbreviations, acronymsACGIH = American Conference of
Governmental Industrial Hygienistsbw = body weightbw/day = body
weight/dayEC x = Effect Concentration associated with x%
responseGLP = Good Laboratory Practice
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_____________________________________________________________________________________________
_____________________________________________________________________________________________
Page 18 / 41
SDS # : 087920 AVGAS 100LLRevision Date: 2018-12-13 Version
1
IARC = International Agency for Research of CancerLC50 = 50%
Lethal concentration - Concentration of a chemical in air or a
chemical in water which causes the death of 50% (onehalf) of a
group of test animalsLD50 = 50% Lethal Dose - Chemical amount,
given at once, which causes the death of 50% (one half) of a group
of test animalsLL = Lethal LoadingNIOSH = National Institute of
Occupational Safety and HealthNOAEL = No Observed Adverse Effect
LevelNOEC = No Observed Effect ConcentrationNOEL = No Observed
Effect LevelOECD = Organization for Economic Co-operation and
DevelopmentOSHA = Occupational Safety and Health AdministrationUVCB
= Substance of unknown or Variable composition, Complex reaction
products or Biological materialDNEL = Derived No Effect LevelPNEC =
Predicted No Effect Concentrationdw = dry weightfw = fresh watermw
= marine wateror = occasional release
Legend Section 8
TWA: Time Weight AverageSTEL: Short Time Exposure LimitPEL:
Permissible exposure limitREL: Recommended exposure limitTLV:
Threshold Limit Values
Revision Date: 2018-12-13Revision Note (M)SDS sections updated:
11, 12, 16.
Further information Note P: The classification as a carcinogen
or mutagen need not apply if it can be shownthat the substance
contains less than 0,1 % w/w benzene (EINECS No 200-753-7). Whenthe
substance is not classified as a carcinogen at least the
precautionary statements(P102-)P260-P262-P301 + P310-P331 (Table
3.1) or the S-phrases (2-)23-24-62 (Table3.2) shall apply. This
note applies only to certain complex oil-derived substances in Part
3.
Other uses than these listed under section 1.2 may have been
foreseen for thesubstance(s) contained in the product. Please
contact us if your use is not listed undersection 1.2.
This safety data sheet complies with the requirements of
Regulation (EC) No.
1907/2006_____________________________________________________________________________________________This
safety data sheet serves to complete but not to replace the
technical product sheets. The information containedherein is given
in good faith and is accurate to the best of knowledge at the date
indicated above.It is understood by theuser that any use of the
product for purposes other than those for which it was designed
entails potential risk.Theinformation given herein in no way
dispenses the user from knowing and applying all provisions
regulating hisactivity.The user bears sole liability for the
precautions required when using the product.The regulatory texts
indicatedherein are intended to aid the user to fulfil his
obligations. This list is not to be considered complete and
exhaustive.It isthe user's responsibility to ensure that he is
subject to no other obligations than those mentioned.
+ Sensitizer * Skin designation** Hazard Designation C:
CarcinogenM: Mutagen R: Toxic to reproduction
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_____________________________________________________________________________________________
_____________________________________________________________________________________________
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SDS # : 087920 AVGAS 100LLRevision Date: 2018-12-13 Version
1
End of the Safety Data Sheet
-
Page20 / 41
ES02001Version 1.0Trade name / designation Low Boiling point
Naphta
1. Exposure scenarioManufacture of substances, Industrial.
Use DescriptorSector of useSU3 - Industrial Manufacturing
(all)SU8 - Manufacture of bulk, large scale chemicals (including
petroleum products)SU9 - Manufacture of fine chemicals
Process categoryPROC1 - Use in closed process, no likelihood of
exposurePROC2 - Use in closed, continuous process with occasional
controlled exposurePROC3 - Use in closed batch process (synthesis
or formulation)PROC4 - Use in batch and other process (synthesis)
where opportunity for exposure arisesPROC8a - Transfer of substance
or preparation (charging/discharging) from/to vessels/large
containers at non-dedicated facilitiesPROC8b - Transfer of
substance or preparation (charging/discharging) from/to
vessels/large containers at dedicated facilitiesPROC15 - Use as
laboratory reagent
Environmental Release CategoryERC1 - Manufacture of
substancesERC4 - Industrial use of processing aids in processes and
products, not becoming part of articles
Specific Environmental Release CategoryESVOC SpERC 1.1.v1.
Processes, tasks, activities coveredManufacture of the substance
or use as a process chemical or extraction agent within closed or
contained systems. Includesincidental exposures during recycling/
recovery, material transfers, storage, sampling, associated
laboratory activities, maintenanceand loading (including marine
vessel/barge, road/rail car and bulk container).
2. Operational conditions and risk management measures
2.1. Control of environmental exposure
Product characteristicsSubstance is complex UVCB. Predominantly
hydrophobic.
Amounts used:
Fraction of EU tonnage used in region: 0.1Regional use tonnage
(tonnes/year): 1.87E+7Fraction of Regional tonnage used locally:
0.032Annual site tonnage (tonnes/year): 6.0E+5Maximum daily site
tonnage (kg/day): 2.0E+6
Frequency and duration of use Continuous releaseEmission Days
(days/year): 300
Environment factors not influenced by risk management-
Local freshwater dilution factor: 10Local marine water dilution
factor: 100
Other operational conditions of use affecting environmental
exposure-.
Release fraction to air from process (initial release prior to
RMM): 0.05
-
Page 21 / 41Release fraction to wastewater from process (initial
release prior to RMM): 0.003Release fraction to soil from process
(initial release prior to RMM): 0.0001
Technical conditions and measures at process level to prevent
releaseCommon practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit
discharges, air emissions and releases to soilPrevent discharge of
undissolved substance to or recover from onsite wastewaterRisk from
environmental exposure is driven by humans via indirect exposure
(primarily inhalation)Onsite wastewater treatment required
Treat air emission to provide a typical removal efficiency of
(%): 99.0Treat onsite wastewater (prior to receiving water
discharge) to provide the required removal efficiency of (%): >=
95.2If discharging to domestic sewage treatment plant, provide the
required onsite wastewater removal efficiency of (%): >=
80.4
Organizational measures to prevent/limit release from the siteDo
not apply industrial sludge to natural soils. Sludge should be
incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment
plant:
Estimated substance removal from wastewater via domestic sewage
treatment (%): 95.5Total efficiency of removal from wastewater
after onsite and offsite (domestic treatment plant) RMMs (%):
99.1Maximum allowable site tonnage (MSafe) (kg/d): 2.0E+6Assumed
domestic sewage treatment plant flow (m3/d): 10000Conditions and
measures related to external treatment of waste for disposalDuring
manufacturing no waste of the substance is generated.
Conditions and measures related to external recovery of
wasteDuring manufacturing no waste of the substance is
generated.
RemarksAdditional information on the basis for the allocation of
the identified OCs (operating conditions) and RMMs ( Risk
ManagementMeasures) is contained in Petrorisk file
2.2. Control of exposure - Workers / Consumers
Product characteristicsPhysical StateLiquid, vapor pressure >
10 kPa at STP
Concentration of substance in productCovers percentage substance
in the product up to 100 % (unless stated differently).
Amounts usedAmounts used. Not applicable.Frequency and duration
of useCovers daily exposures up to 8 hours (unless stated
differently)
Human factors not influenced by risk managementnot
applicableOther operational conditions affecting exposureOperation
is carried out at elevated temperature (> 20°C above ambient
temperature). Assumes a good basic standard ofoccupational hygiene
is implemented.
-
Page 22 / 41
3. Exposure estimation and references
Information for contributing exposure scenarioThe ECETOC TRA
tool has been used to estimate consumer exposures unless otherwise
indicated.
Information for contributing exposure scenarioThe Hydrocarbon
Block Method has been used to calculate environmental exposure with
the Petrorisk model.
4. Guidance for Downstream User to check compliance with the
Exposurescenario
HealthPredicted exposures are not expected to exceed the DN(M)EL
when the Risk Management Measures/Operational Conditionsoutlined in
Section 2 are implemented. Where other Risk Management
Measures/Operational Conditions are adopted, then usersshould
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNELfor
dermal irritant effects. Available hazard data do not support the
need for a DNEL to be established for other health effects.
RiskManagement Measures are based on qualitative risk
characterization.
EnvironmentGuidance is based on assumed operating conditions
which may not be applicable to all sites; thus, scaling may be
necessary todefine appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be
achieved using
2.2a. Control of worker exposure
2.2b. Control of consumer exposure
Contributing Scenarios Operational conditions and risk
management measuresGeneral measures (skin irritants) Avoid direct
skin contact with product. Identify potential areas for indirect
skin
contact. Wear gloves (tested to EN374) if hand contact with
substance likely.Clean up contamination/spills as soon as they
occur. Wash off any skincontamination immediately. Provide basic
employee training to prevent /minimise exposures and to report any
skin problems that may develop.
General exposures (closed systems) No other specific measures
identified.
General exposures (closed systems) withsample collection
No other specific measures identified.
General exposures (open systems) Provide extract ventilation to
points where emissions occur.
Mixing operations (closed systems) No other specific measures
identified.
Process sampling No other specific measures identified.
Laboratory activities Handle in a fume cupboard or under extract
ventilation.
Bulk transfers No other specific measures identified.
Drum/batch transfers No other specific measures identified.
Equipment maintenance No other specific measures identified.
Storage No other specific measures identified.
Product Category(ies) Operational conditions and risk management
measuresNot applicable
-
Page 23 / 41onsite/offsite technologies, either alone or in
combination. Required removal efficiency for air can be achieved
using on-sitetechnologies, either alone or in combination. Further
details on scaling and control technologies are provided in SpERC
factsheet(http://cefic.org/en/reach-for-industries-libraries html).
Scaled local assessments for EU refineries have been performed
usingsite-specific data and are attached in PETRORISK file –
“Site-Specific Production” worksheet. If scaling reveals a
condition ofunsafe use (i.e., RCRs > 1), additional RMMs or a
site-specific chemical safety assessment is required. Measured data
have beenused to demonstrate that the PETRORISK predicteds
fence-line concentrations in air are overestimated. These data
support theconclusion that no refineries have RCRs>1 (Petrorisk
file in IUCLID section 13- Site-specific Production & Tier II
worksheets).
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Page24 / 41
ES02009Version 1.0Trade name / designation Low Boiling point
Naphta
1. Exposure scenarioIndustrial, Distribution of substance.
Use DescriptorSector of useSU3 - Industrial Manufacturing
(all)
Process categoryPROC1 - Use in closed process, no likelihood of
exposurePROC2 - Use in closed, continuous process with occasional
controlled exposurePROC3 - Use in closed batch process (synthesis
or formulation)PROC4 - Use in batch and other process (synthesis)
where opportunity for exposure arisesPROC8a - Transfer of substance
or preparation (charging/discharging) from/to vessels/large
containers at non-dedicated facilitiesPROC8b - Transfer of
substance or preparation (charging/discharging) from/to
vessels/large containers at dedicated facilitiesPROC9 - Transfer of
substance or preparation into small containers (dedicated filling
line, including weighing)PROC15 - Use as laboratory reagent
Environmental Release CategoryERC1 - Manufacture of
substancesERC2 - Formulation of preparationsERC3 - Formulation in
materialsERC4 - Industrial use of processing aids in processes and
products, not becoming part of articlesERC5 - Industrial use
resulting in inclusion into or onto a matrixERC6a - Industrial use
resulting in manufacture of another substance (use of
intermediates)ERC6b - Industrial use of reactive processing
aidsERC6c - Industrial use of monomers for manufacture of
thermoplasticsERC6d - Industrial use of process regulators for
polymerization processes in production of resins, rubbers,
polymersERC7 - Industrial use of substances in closed systems
Specific Environmental Release CategoryESVOC SpERC 1.1b. v1.
Processes, tasks, activities coveredLoading (including marine
vessel/barge, rail/road car and IBC loading) and repacking
(including drums and small packs) ofsubstance, including its
sampling, storage, unloading distribution and associated laboratory
activities.
2. Operational conditions and risk management measures
2.1. Control of environmental exposure
Product characteristicsSubstance is complex UVCB. Predominantly
hydrophobic.
Amounts used:
Fraction of EU tonnage used in region: 0.1Regional use tonnage
(tonnes/year): 1.87E+7Fraction of Regional tonnage used locally:
0.002Annual site tonnage (tonnes/year): 3.75E+4Maximum daily site
tonnage (kg/day): 1.2E+5
Frequency and duration of use Continuous releaseEmission Days
(days/year): 300
Environment factors not influenced by risk management-
Local freshwater dilution factor: 10
-
Page 25 / 41Local marine water dilution factor: 100
Release fraction to air from process (initial release prior to
RMM): 1E-3Release fraction to wastewater from process (initial
release prior to RMM): 1E-5Release fraction to soil from process
(initial release prior to RMM): 1E-5
Technical conditions and measures at process level to prevent
releaseCommon practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit
discharges, air emissions and releases to soilRisk from
environmental exposure is driven by humans via indirect exposure
(primarily inhalation)If discharging to domestic sewage treatment
plant, no onsite wastewater treatment required
Treat air emission to provide a typical removal efficiency of
(%): 90Treat onsite wastewater (prior to receiving water discharge)
to provide the required removal efficiency of (%): >=12If
discharging to domestic sewage treatment plant, provide the
required onsite wastewater removal efficiency of (%): >=0
Organizational measures to prevent/limit release from the siteDo
not apply industrial sludge to natural soils. Sludge should be
incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment
plant:
Estimated substance removal from wastewater via domestic sewage
treatment (%): 95.5Total efficiency of removal from wastewater
after onsite and offsite (domestic treatment plant) RMMs (%):
95.5Maximum allowable site tonnage (MSafe) (kg/d): 1.1E+6Assumed
domestic sewage treatment plant flow (m3/d): 2000Conditions and
measures related to external treatment of waste for
disposalExternal treatment and disposal of waste should comply with
applicable local and/or national regulations.
Conditions and measures related to external recovery of
wasteExternal recovery and recycling of waste should comply with
applicable local and/or national regulations.
RemarksAdditional information on the basis for the allocation of
the identified OCs (operating conditions) and RMMs ( Risk
ManagementMeasures) is contained in Petrorisk file
2.2. Control of exposure - Workers / Consumers
Product characteristicsPhysical StateLiquid, vapor pressure >
10 kPa at STP
Concentration of substance in productCovers percentage substance
in the product up to 100 % (unless stated differently).
Amounts usedNot applicable.Frequency and duration of useCovers
daily exposures up to 8 hours (unless stated differently)
Human factors not influenced by risk managementnot
applicableOther operational conditions affecting exposureAssumes
use at not more than 20°C above ambient temperature, unless stated
differently. Assumes a good basic standard ofoccupational hygiene
is implemented.
-
Page 26 / 41
3. Exposure estimation and references
HealthThe ECETOC TRA tool has been used to estimate consumer
exposures unless otherwise indicated
EnvironmentThe Hydrocarbon Block Method has been used to
calculate environmental exposure with the Petrorisk model.
4. Guidance for Downstream User to check compliance with the
Exposurescenario
HealthPredicted exposures are not expected to exceed the DN(M)EL
when the Risk Management Measures/Operational Conditionsoutlined in
Section 2 are implemented. Where other Risk Management
Measures/Operational Conditions are adopted, then usersshould
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNELfor
dermal irritant effects. Available hazard data do not support the
need for a DNEL to be established for other health effects.
RiskManagement Measures are based on qualitative risk
characterization.
EnvironmentGuidance is based on assumed operating conditions
which may not be applicable to all sites; thus, scaling may be
necessary todefine appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be
achieved usingonsite/offsite technologies, either alone or in
combination. Required removal efficiency for air can be achieved
using on-sitetechnologies, either alone or in combination. Further
details on scaling and control technologies are provided in SpERC
factsheet(http://cefic.org/en/reach-for-industries-libraries
html).
2.2a. Control of worker exposure
2.2b. Control of consumer exposure
Contributing Scenarios Operational conditions and risk
management measuresGeneral measures (skin irritants) Avoid direct
skin contact with product. Identify potential areas for indirect
skin
contact. Wear gloves (tested to EN374) if hand contact with
substance likely.Clean up contamination/spills as soon as they
occur. Wash off any skincontamination immediately. Provide basic
employee training to prevent /minimise exposures and to report any
skin problems that may develop.
General exposures (closed systems) No other specific measures
identified.
General exposures (closed systems) withsample collection
No other specific measures identified.
General exposures (open systems) Provide extract ventilation to
material transfer points and other openings.
Process sampling No other specific measures identified.
Laboratory activities Handle in a fume cupboard or under extract
ventilation.
Bulk closed loading and unloading No other specific measures
identified.
Drum and small package filling Fill containers/cans at dedicated
fill points supplied with local extractventilation.
Equipment cleaning and maintenance No other specific measures
identified.
Storage No other specific measures identified.
Product Category(ies) Operational conditions and risk management
measuresNot applicable
-
Page 27 / 41
-
Page28 / 41
ES02013Version 1.0Trade name / designation Low Boiling point
Naphta
1. Exposure scenarioFormulation & (re)packing of substances
and mixtures, Industrial.
Use DescriptorSector of useSU3 - Industrial Manufacturing
(all)SU10 - Formulation [mixing] of preparations and/or
re-packaging (excluding alloys)
Process categoryPROC1 - Use in closed process, no likelihood of
exposurePROC2 - Use in closed, continuous process with occasional
controlled exposurePROC3 - Use in closed batch process (synthesis
or formulation)PROC4 - Use in batch and other process (synthesis)
where opportunity for exposure arisesPROC5 - Mixing or blending in
batch processes for formulation of preparations and articles
(multistage and/or significant contact)PROC8a - Transfer of
substance or preparation (charging/discharging) from/to
vessels/large containers at non-dedicated facilitiesPROC8b -
Transfer of substance or preparation (charging/discharging) from/to
vessels/large containers at dedicated facilitiesPROC9 - Transfer of
substance or preparation into small containers (dedicated filling
line, including weighing)PROC14 - Production of preparations or
articles by tabletting, compression, extrusion, pelletisationPROC15
- Use as laboratory reagent
Environmental Release CategoryERC2 - Formulation of
preparations
Specific Environmental Release CategoryESVOC SpERC 2.2.v1.
Processes, tasks, activities coveredFormulation, packing and
re-packing of the substance and its mixtures in batch or continuous
operations, including storage,materials transfers, mixing,
tabletting, compression, pelletisation, extrusion, large and small
scale packing, sampling, maintenanceand associated laboratory
activities.
2. Operational conditions and risk management measures
2.1. Control of environmental exposure
Product characteristicsSubstance is complex UVCB. Predominantly
hydrophobic.
Amounts used:
Fraction of EU tonnage used in region: 0.1Regional use tonnage
(tonnes/year): 1.65E+7Fraction of Regional tonnage used locally:
0.0018Annual site tonnage (tonnes/year): 3.0E+4Maximum daily site
tonnage (kg/day): 1.0E+5
Frequency and duration of use Continuous releaseEmission Days
(days/year): 300
Environment factors not influenced by risk management
Local freshwater dilution factor: 10Local marine water dilution
factor: 100
Release fraction to air from process (initial release prior to
RMM): 0.025Release fraction to wastewater from process (initial
release prior to RMM): 0.002Release fraction to soil from process
(initial release prior to RMM): 0.0001
-
Page 29 / 41
Technical conditions and measures at process level to prevent
releaseCommon practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit
discharges, air emissions and releases to soilPrevent discharge of
undissolved substance to or recover from onsite wastewaterRisk from
environmental exposure is driven by humans via indirect exposure
(primarily inhalation)If discharging to domestic sewage treatment
plant, no onsite wastewater treatment required
Treat air emission to provide a typical removal efficiency of
(%): 56.5Treat onsite wastewater (prior to receiving water
discharge) to provide the required removal efficiency of (%):
>=94.7If discharging to domestic sewage treatment plant, provide
the required onsite wastewater removal efficiency of (%): >=
0
Organizational measures to prevent/limit release from the siteDo
not apply industrial sludge to natural soils. Sludge should be
incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment
plant:
Estimated substance removal from wastewater via domestic sewage
treatment (%): 95.5Total efficiency of removal from wastewater
after onsite and offsite (domestic treatment plant) RMMs (%):
95.5Maximum allowable site tonnage (MSafe) (kg/d): 1.0E+5Assumed
domestic sewage treatment plant flow (m3/d): 2000Conditions and
measures related to external treatment of waste for
disposalExternal treatment and disposal of waste should comply with
applicable local and/or national regulations.
Conditions and measures related to external recovery of
wasteExternal recovery and recycling of waste should comply with
applicable local and/or national regulations.
RemarksAdditional information on the basis for the allocation of
the identified OCs (operating conditions) and RMMs ( Risk
ManagementMeasures) is contained in Petrorisk file
2.2. Control of exposure - Workers / Consumers
Product characteristicsPhysical StateLiquid, vapor pressure >
10 kPa at STP
Concentration of substance in productCovers percentage substance
in the product up to 100 % (unless stated differently).
Amounts usedNot applicable.Frequency and duration of useCovers
daily exposures up to 8 hours (unless stated differently)
Human factors not influenced by risk managementnot
applicableOther operational conditions affecting exposureAssumes
use at not more than 20°C above ambient temperature, unless stated
differently. Assumes a good basic standard ofoccupational hygiene
is implemented.
-
Page 30 / 41
3. Exposure estimation and references
HealthThe ECETOC TRA tool has been used to estimate consumer
exposures unless otherwise indicated
EnvironmentThe Hydrocarbon Block Method has been used to
calculate environmental exposure with the Petrorisk model.
4. Guidance for Downstream User to check compliance with the
Exposurescenario
HealthPredicted exposures are not expected to exceed the DN(M)EL
when the Risk Management Measures/Operational Conditionsoutlined in
Section 2 are implemented. Where other Risk Management
Measures/Operational Conditions are adopted, then usersshould
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNELfor
dermal irritant effects. Available hazard data do not support the
need for a DNEL to be established for other health effects.
Risk
2.2a. Control of worker exposure
2.2b. Control of consumer exposure
Contributing Scenarios Operational conditions and risk
management measuresGeneral measures (skin irritants) Avoid direct
skin contact with product. Identify potential areas for indirect
skin
contact. Wear gloves (tested to EN374) if hand contact with
substance likely.Clean up contamination/spills as soon as they
occur. Wash off any skincontamination immediately. Provide basic
employee training to prevent /minimise exposures and to report any
skin problems that may develop.
General exposures (closed systems) No other specific measures
identified.
General exposures (closed systems) withsample collection
No other specific measures identified.
General exposures (open systems) Provide extract ventilation to
material transfer points and other openings.
Mixing operations (closed systems) Provide extract ventilation
to points where emissions occur.
Process sampling No other specific measures identified.
Laboratory activities Handle in a fume cupboard or under extract
ventilation.
Bulk transfers Ensure material transfers are under containment
or extract ventilation.
Drum/batch transfers Ensure material transfers are under
containment or extract ventilation.
Drum and small package filling Fill containers/cans at dedicated
fill points supplied with local extractventilation.
Equipment cleaning and maintenance No other specific measures
identified.
Storage No other specific measures identified.
Manual Transfer from/pouring from containers Ensure material
transfers are under containment or extract ventilation.
Product Category(ies) Operational conditions and risk management
measuresNot applicable
-
Page 31 / 41Management Measures are based on qualitative risk
characterization.
EnvironmentGuidance is based on assumed operating conditions
which may not be applicable to all sites; thus, scaling may be
necessary todefine appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be
achieved usingonsite/offsite technologies, either alone or in
combination. Required removal efficiency for air can be achieved
using on-sitetechnologies, either alone or in combination. Further
details on scaling and control technologies are provided in SpERC
factsheet(http://cefic.org/en/reach-for-industries-libraries
html).
-
Page32 / 41
ES02024Version 1.0Trade name / designation Low Boiling point
Naphta
1. Exposure scenarioUse as a fuel, Industrial.
Use DescriptorSector of useSU3 - Industrial Manufacturing
(all)
Process categoryPROC1 - Use in closed process, no likelihood of
exposurePROC2 - Use in closed, continuous process with occasional
controlled exposurePROC3 - Use in closed batch process (synthesis
or formulation)PROC8a - Transfer of substance or preparation
(charging/discharging) from/to vessels/large containers at
non-dedicated facilitiesPROC8b - Transfer of substance or
preparation (charging/discharging) from/to vessels/large containers
at dedicated facilitiesPROC16 - Using material as fuel sources,
limited exposure to unburned product to be expected
Environmental Release CategoryERC7 - Industrial use of
substances in closed systems
Specific Environmental Release CategoryESVOC SpERC 7.12a.v1.
Processes, tasks, activities coveredCovers the use as a fuel (or
fuel additive) and includes activities associated with its
transfer, use, equipment maintenance andhandling of waste.
2. Operational conditions and risk management measures
2.1. Control of environmental exposure
Product characteristicsSubstance is complex UVCB. Predominantly
hydrophobic.
Amounts used:
Fraction of EU tonnage used in region: 0.1Regional use tonnage
(tonnes/year): 1.4E+6Fraction of Regional tonnage used locally:
1Annual site tonnage (tonnes/year): 1.4E+6Maximum daily site
tonnage (kg/day): 4.6E+6
Frequency and duration of use Continuous releaseEmission Days
(days/year): 300
Environment factors not influenced by risk management-
Local freshwater dilution factor: 10Local marine water dilution
factor: 100
Release fraction to air from process (initial release prior to
RMM): 0.0025Release fraction to wastewater from process (initial
release prior to RMM): 0.00001Release fraction to soil from process
(initial release prior to RMM): 0
Technical conditions and measures at process level to prevent
releaseCommon practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit
discharges, air emissions and releases to soilRisk from
environmental exposure is driven by humans via indirect exposure
(primarily inhalation)
-
Page 33 / 41If discharging to domestic sewage treatment plant,
no onsite wastewater treatment required
Treat air emission to provide a typical removal efficiency of
(%): 99.4Treat onsite wastewater (prior to receiving water
discharge) to provide the required removal efficiency of (%): >=
76.9If discharging to domestic sewage treatment plant, provide the
required onsite wastewater removal efficiency of (%): >= 0
Organizational measures to prevent/limit release from the siteDo
not apply industrial sludge to natural soils. Sludge should be
incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment
plant:
Estimated substance removal from wastewater via domestic sewage
treatment (%): 95.5Total efficiency of removal from wastewater
after onsite and offsite (domestic treatment plant) RMMs (%):
95.5Maximum allowable site tonnage (MSafe) (kg/d): 4.6E+6Assumed
domestic sewage treatment plant flow (m3/d): 2000Conditions and
measures related to external treatment of waste for
disposalCombustion emissions limited by required exhaust emission
controls. Combustion emissions considered in regional
exposureassessment.
Conditions and measures related to external recovery of
wasteThis substance is consumed during use and no waste of the
substance is generated.
RemarksAdditional information on the basis for the allocation of
the identified OCs (operating conditions) and RMMs ( Risk
ManagementMeasures) is contained in Petrorisk file
2.2. Control of exposure - Workers / Consumers
Product characteristicsPhysical StateLiquid, vapor pressure >
10 kPa at STP
Concentration of substance in productCovers percentage substance
in the product up to 100 % (unless stated differently).
Amounts usedNot applicable.Frequency and duration of useCovers
daily exposures up to 8 hours (unless stated differently)
Human factors not influenced by risk managementnot
applicableOther operational conditions affecting exposureAssumes
use at not more than 20°C above ambient temperature, unless stated
differently. Assumes a good basic standard ofoccupational hygiene
is implemented.
-
Page 34 / 41
3. Exposure estimation and references
HealthThe ECETOC TRA tool has been used to estimate consumer
exposures unless otherwise indicated
EnvironmentThe Hydrocarbon Block Method has been used to
calculate environmental exposure with the Petrorisk model.
4. Guidance for Downstream User to check compliance with the
Exposurescenario
HealthPredicted exposures are not expected to exceed the DN(M)EL
when the Risk Management Measures/Operational Conditionsoutlined in
Section 2 are implemented. Where other Risk Management
Measures/Operational Conditions are adopted, then usersshould
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNELfor
dermal irritant effects. Available hazard data do not support the
need for a DNEL to be established for other health effects.
RiskManagement Measures are based on qualitative risk
characterization.
EnvironmentGuidance is based on assumed operating conditions
which may not be applicable to all sites; thus, scaling may be
necessary todefine appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be
achieved usingonsite/offsite technologies, either alone or in
combination. Required removal efficiency for air can be achieved
using on-sitetechnologies, either alone or in combination. Further
details on scaling and control technologies are provided in SpERC
factsheet(http://cefic.org/en/reach-for-industries-libraries
html).
2.2a. Control of worker exposure
2.2b. Control of consumer exposure
Contributing Scenarios Operational conditions and risk
management measuresGeneral measures (skin irritants) Avoid direct
skin contact with product. Identify potential areas for indirect
skin
contact. Wear gloves (tested to EN374) if hand contact with
substance likely.Clean up contamination/spills as soon as they
occur. Wash off any skincontamination immediately. Provide basic
employee training to prevent /minimise exposures and to report any
skin problems that may develop.
General exposures (closed systems) No other specific measures
identified.
Bulk closed unloading No other specific measures identified.
Refueling No other specific measures identified.
Refueling aircraft Ensure material transfers are under
containment or extract ventilation.
Use as a fuel (closed systems) No other specific measures
identified.
Bulk transfers No other specific measures identified.
Drum/batch transfers No other specific measures identified.
Equipment maintenance No other specific measures identified.
Storage No other specific measures identified.
Product Category(ies) Operational conditions and risk management
measuresNot applicable
-
Page35 / 41
ES02026Version 1.0Trade name / designation Low Boiling point
Naphta
1. Exposure scenarioUse as a fuel, Professional.
Use DescriptorSector of useSU22 - Professional uses: Public
domain (administration, education, entertainment, services,
craftsmen)
Process categoryPROC1 - Use in closed process, no likelihood of
exposurePROC2 - Use in closed, continuous process with occasional
controlled exposurePROC3 - Use in closed batch process (synthesis
or formulation)PROC8a - Transfer of substance or preparation
(charging/discharging) from/to vessels/large containers at
non-dedicated facilitiesPROC8b - Transfer of substance or
preparation (charging/discharging) from/to vessels/large containers
at dedicated facilitiesPROC16 - Using material as fuel sources,
limited exposure to unburned product to be expected
Environmental Release CategoryERC9a - Wide dispersive indoor use
of substances in closed systemsERC9b - Wide dispersive outdoor use
of substances in closed systems
Specific Environmental Release CategoryESVOC SpERC 9.12.v1.
Processes, tasks, activities coveredCovers the use as a fuel (or
fuel additive) and includes activities associated with its
transfer, use, equipment maintenance andhandling of waste.
2. Operational conditions and risk management measures
2.1. Control of environmental exposure
Product characteristicsSubstance is complex UVCB. Predominantly
hydrophobic.
Amounts used:
Fraction of EU tonnage used in region: 0.1Regional use tonnage
(tonnes/year): 1.19E+6Fraction of Regional tonnage used locally:
0.0005Annual site tonnage (tonnes/year): 5.9E2Maximum daily site
tonnage (kg/day): 1.6E+3
Frequency and duration of use Continuous releaseEmission Days
(days/year): 365
Environment factors not influenced by risk management-
Local freshwater dilution factor: 10Local marine water dilution
factor: 100
Other operational conditions of use affecting environmental
exposure.
Release fraction to air from process (initial release prior to
RMM): 0.01Release fraction to wastewater from process (initial
release prior to RMM): 0.00001Release fraction to soil from process
(initial release prior to RMM): 0.00001
Technical conditions and measures at process level to prevent
release
-
Page 36 / 41Common practices vary across sites thus conservative
process release estimates used.
Technical onsite conditions and measures to reduce or limit
discharges, air emissions and releases to soilRisk from
environmental exposure is driven by humans via indirect exposure
(primarily inhalation)If discharging to domestic sewage treatment
plant, no onsite wastewater treatment required
Treat air emission to provide a typical removal efficiency of
(%): N/ATreat onsite wastewater (prior to receiving water
discharge) to provide the required removal efficiency of (%): >=
3.4If discharging to domestic sewage treatment plant, provide the
required onsite wastewater removal efficiency of (%): >= 0
Organizational measures to prevent/limit release from the siteDo
not apply industrial sludge to natural soils. Sludge should be
incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment
plant:
Estimated substance removal from wastewater via domestic sewage
treatment (%): 95.5Total efficiency of removal from wastewater
after onsite and offsite (domestic treatment plant) RMMs (%):
95.5Maximum allowable site tonnage (MSafe) (kg/d): 1.5E+4Assumed
domestic sewage treatment plant flow (m3/d): 2000Conditions and
measures related to external treatment of waste for
disposalCombustion emissions limited by required exhaust emission
controls. Combustion emissions considered in regional
exposureassessment.
Conditions and measures related to external recovery of
wasteThis substance is consumed during use and no waste of the
substance is generated.
RemarksAdditional information on the basis for the allocation of
the identified OCs (operating conditions) and RMMs ( Risk
ManagementMeasures) is contained in Petrorisk file
2.2. Control of exposure - Workers / Consumers
Product characteristicsPhysical StateLiquid, vapor pressure >
10 kPa at STP
Concentration of substance in productCovers percentage substance
in the product up to 100 % (unless stated differently).
Amounts usedNot applicable.Frequency and duration of useCovers
daily exposures up to 8 hours (unless stated differently)
Human factors not influenced by risk managementnot
applicableOther operational conditions affecting exposureAssumes
use at not more than 20°C above ambient temperature, unless stated
differently. Assumes a good basic standard ofoccupational hygiene
is implemented.
-
Page 37 / 41
3. Exposure estimation and references
HealthThe ECETOC TRA tool has been used to estimate consumer
exposures unless otherwise indicated
EnvironmentThe Hydrocarbon Block Method has been used to
calculate environmental exposure with the Petrorisk model.
4. Guidance for Downstream User to check compliance with the
Exposurescenario
HealthPredicted exposures are not expected to exceed the DN(M)EL
when the Risk Management Measures/Operational Conditionsoutlined in
Section 2 are implemented. Where other Risk Management
Measures/Operational Conditions are adopted, then usersshould
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNELfor
carcinogenic and dermal irritant effects. Available hazard data do
not support the need for a DNEL to be established for otherhealth
effects. Risk Management Measures are based on qualitative risk
characterization.
EnvironmentGuidance is based on assumed operating conditions
which may not be applicable to all sites; thus, scaling may be
necessary todefine appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be
achieved usingonsite/offsite technologies, either alone or in
combination. Required removal efficiency for air can be achieved
using on-sitetechnologies, either alone or in combination. Further
details on scaling and control technologies are provided in SpERC
factsheet(http://cefic.org/en/reach-for-industries-libraries
html).
2.2a. Control of worker exposure
2.2b. Control of consumer exposure
Contributing Scenarios Operational conditions and risk
management measuresGeneral measures (skin irritants) Avoid direct
skin contact with product. Identify potential areas for indirect
skin
contact. Wear gloves (tested to EN374) if hand contact with
substance likely.Clean up contamination/spills as soon as they
occur. Wash off any skincontamination immediately. Provide basic
employee training to prevent /minimise exposures and to report any
skin problems that may develop.
General exposures (closed systems) No other specific measures
identified.
Bulk closed unloading No other specific measures identified.
Preparation of material for application Mixingoperations (closed
systems)
No other specific measures identified.
Refueling No other specific measures identified.
Use as a fuel (closed systems) No other specific measures
identified.
Drum/batch transfers No other specific measures identified.
Equipment maintenance Drain down system prior to equipment
break-in or maintenance. Wearchemically resistant gloves (tested to
EN374) in combination with intensivemanagement supervision
controls.
Storage No other specific measures identified.
Product Category(ies) Operational conditions and risk management
measuresNot applicable
-
Page38 / 41
ES02028Version 1.0Trade name / designation Low Boiling point
Naphta
1. Exposure scenarioUse as a fuel, Consumer.
Use DescriptorSector of useSU21 - Private households (= general
public = consumers)
Product categoryPC13 - Fuels
Environmental Release CategoryERC9a - Wide dispersive indoor use
of substances in closed systemsERC9b - Wide dispersive outdoor use
of substances in closed systems
Specific Environmental Release CategoryESVOC SpERC 9.12c.v1.
Processes, tasks, activities coveredCovers consumer uses in
liquid fuels.
2. Operational conditions and risk management measures
2.1. Control of environmental exposure
Product characteristicsSubstance is complex UVCB. Predominantly
hydrophobic.
Amounts used:
Fraction of EU tonnage used in region: 0.1Regional use tonnage
(tonnes/year): 1.39E+7Fraction of Regional tonnage used locally:
0.0005Annual site tonnage (tonnes/year): 7.0E+3Maximum daily site
tonnage (kg/day): 1.9E+3
Frequency and duration of use Continuous releaseEmission Days
(days/year): 365
Environment factors not influenced by risk management-
Local freshwater dilution factor: 10Local marine water dilution
factor: 100
Release fraction to air from process (initial release prior to
RMM): 0.01Release fraction to wastewater from process (initial
release prior to RMM): 0.00001Release fraction to soil from process
(initial release prior to RMM): 0.00001
Conditions and measures related to municipal sewage treatment
plantRisk from environmental exposure is driven by humans via
indirect exposure (primarily inhalation) :
Estimated substance removal from wastewater via domestic sewage
treatment (%): 95.5Maximum allowable site tonnage (MSafe) (kg/d):
1.8E+5Assumed domestic sewage treatment plant flow (m3/d):
2000Conditions and measures related to external treatment of waste
for disposalCombustion emissions limited by required exhaust
emission controls. Combustion emissions considered in regional
exposureassessment.
-
Page 39 / 41Conditions and measures related to external recovery
of wasteThis substance is consumed during use and no waste of the
substance is generated.
RemarksAdditional information on the basis for the allocation of
the identified OCs (operating conditions) and RMMs ( Risk
ManagementMeasures) is contained in Petrorisk file
2.2. Control of exposure - Workers / Consumers
Product characteristicsPhysical StateLiquid, vapor pressure >
10 kPa at STP
Concentration of substance in productUnless otherwise stated.
Covers concentrations up to (%):100.
Amounts usedUnless otherwise stated. Covers use amounts up to
(g) : 37500g . Covers skin contact area up to (cm2): 420.Frequency
and duration of useUnless otherwise statedCovers use up to
(times/day of use):0.143Covers exposure up to (hours/event):2
Other operational conditions affecting exposureUnless otherwise
stated. Assumes use at ambient temperature. Assumes use in a 20 m3
room. Assumes use with typicalventilation.
2.2a. Control of worker exposureContributing Scenarios
Operational conditions and risk management measures
Not applicable
-
Page 40 / 41
3. Exposure estimation and references
HealthThe ECETOC TRA tool has been used to estimate consumer
exposures, consistent with the content of ECETOC report #107 andthe
Chapter R15 of the IR&CSA TGD Where exposure determinants
differ to these sources, then they are indicated
EnvironmentThe Hydrocarbon Block Method has been used to
calculate environmental exposure with the Petrorisk model.
4. Guidance for Downstream User to check compliance with the
Exposure
2.2b. Control of consumer exposureProduct Category(ies)
Operational conditions and risk management measures
PC13 - Fuels Liquid: Automotive Refuelling Unless otherwise
statedCovers concentrations up to (%):100Covers use up to
(days/year):52Covers use up to (times/day of use):1Covers skin
contact area up to (cm2): 210.00For each use event, assumes
swallowed amount of (g):37500Covers outdoor useCovers use in room
size of (m3):100For each use eventCovers exposure up to
(hours/event):0.05No specific risk management measure identified
beyond those operationalconditions stated
PC13 - Fuels Liquid Scooter Refuelling Unless otherwise
statedCovers use up to (days/year):100Covers use up to (times/day
of use):52Covers skin contact area up to (cm2): 210.00For each use
event, covers use amounts up to (g):3750Covers outdoor useCovers
use in room size of (m3):100For each use eventCovers exposure up to
(hours/event):0.03No specific risk management measure identified
beyond those operationalconditions stated
PC13 - Fuels Liquid Garden Equipment - Use Unless otherwise
statedCovers concentrations up to (%):100Covers use up to
(days/year):26Covers use up to (times/day of use):1For each use
event, covers use amounts up to (g):750Covers outdoor useCovers use
in room size of (m3):100For each use eventCovers exposure up to
(hours/event):2.00No specific risk management measure identified
beyond those operationalconditions stated
PC13 - Fuels Liquid: Garden Equipment -Refueling
Unless otherwise statedCovers concentrations up to (%):100Covers
use up to (days/year):26Covers use up to (times/day of use):1Covers
skin contact area up to (cm2): 420.00For each use event, covers use
amounts up to (g):750Covers use in a one car garage (34 m3) under
typical ventilationCovers use in room size of (m3):34For each use
eventCovers exposure up to (hours/event):0.03
No specific risk management measure identifiedbeyond those
operational conditions stated
-
Page 41 / 41
scenario
HealthPredicted exposures are not expected to exceed the
applicable consumer reference values when the operational
conditions/riskmanagement measures given in section 2 are
implemented. Where other Risk Management Measures/Operational
Conditions areadopted, then users should ensure that