ISSN 2518-718Х (Print) ISSN 2663-4872 (Online) Индексі 74617 Индекс 74617 ҚАРАҒАНДЫ УНИВЕРСИТЕТ I Н I Ң ÕÀÁÀÐØÛÑÛ ÂÅÑÒÍÈÊ КАРАГАНДИНСКОГО УНИВЕРСИТЕТА BULLETIN OF THE KARAGANDA UNIVERSITY ХИМИЯ сериясы Серия ХИМИЯ CHEMISTRY Series № 2(98)/2020 Сәуір–мамыр–маусым 30 маусым 2020 ж. Апрель–май–июнь 30 июня 2020 г. April–May–June June 30 th , 2020 1996 жылдан бастап шығады Издается с 1996 года Founded in 1996 Жылына 4 рет шығады Выходит 4 раза в год Published 4 times a year Қарағанды, 2020 Караганда, 2020 Karaganda, 2020
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ISSN 2518-718Х (Print) ISSN 2663-4872 (Online) Индексі 74617 Индекс 74617
ҚАРАҒАНДЫ УНИВЕРСИТЕТ IН IҢ
ÕÀÁÀÐØÛÑÛ ÂÅÑÒÍÈÊ
КАРАГАНДИНСКОГО УНИВЕРСИТЕТА
BULLETIN OF THE KARAGANDA
UNIVERSITY
ХИМИЯ сериясы
Серия ХИМИЯ
CHEMISTRY Series
№ 2(98)/2020
Сәуір–мамыр–маусым 30 маусым 2020 ж. Апрель–май–июнь
30 июня 2020 г. April–May–June June 30th, 2020
1996 жылдан бастап шығады
Издается с 1996 года Founded in 1996
Жылына 4 рет шығады Выходит 4 раза в год
Published 4 times a year
Қарағанды, 2020 Караганда, 2020 Karaganda, 2020
Серия «Химия». № 2(98)/2020 5
МАЗМҰНЫ — СОДЕРЖАНИЕ — CONTENTS ОРГАНИКАЛЫҚ ХИМИЯ ОРГАНИЧЕСКАЯ ХИМИЯ
ORGANIC CHEMISTRY Abduletip D.T., Urkimbayeva P.I., Mun G.A., Kenessova Z.A., Khavilhairat B. Application of com-
posite materials based on polyvinyl alcohol in phytoremediation soil ......................................................... 7 Arinova A.E., Nurkenov O.A., Fazylov S.D., Seilkhanov T.M., Ibraev M.K., Kabieva S.K., Oma-
rov T.S. N-methyl-2-(4-styrylphenyl)-3,4-fulleropyrrolidine synthesis and structure ................................. 15 Fazylov S.D., Nurkenov O.A., Mukasheva A.Zh., Seilkhanov T.M., Shulgau Z.T., Zhanzhuman A.M.
Supramolecular inclusion complexes of functionally substituted N-benzylidene and allylidene isonico-tinohydrazides with oligosaccharides and their properties ........................................................................... 22
ФИЗИКАЛЫҚ ЖӘНЕ АНАЛИТИКАЛЫҚ ХИМИЯ ФИЗИЧЕСКАЯ И АНАЛИТИЧЕСКАЯ ХИМИЯ
of intermolecular proton exchange of 3,6-di-tert-butyl-2-oxyphenoxyl with N-phenylanthranilic acid by ESR spectroscopy method ............................................................................................................................ 35
Vissurkhanova Ya.A., Soboleva E.A., Ivanova N.M., Muldakhmetov Z.M. Thermal and electrochem-ical reduction of nickel (II) ferrite under the influence of polymer stabilizers ............................................. 42
Burkeev M.Zh., Zhumanazarova G.M., Kudaibergen G.K., Tazhbayev E.M., Turlybek G.A., Zhakupbekova E.Zh. Research of the influence of external factors on copolymers based on unsaturated polyester resins ............................................................................................................................................. 51
БЕЙОРГАНИКАЛЫҚ ХИМИЯ НЕОРГАНИЧЕСКАЯ ХИМИЯ
INORGANIC CHEMISTRY Jumadilov T.K., Kondaurov R.G., Imangazy A.M. Features of sorption of rare-earth metals of ceri-
um group by intergel systems based on polyacrylic acid, polymethacrylic acid and poly-4-vinylpyridine hydrogels ...................................................................................................................................................... 58
Kazhikenova A.Sh., Alibiyev D.B., Seitimbetova A.B., Smailova A.S. Application of cluster-associative model for calculation of kinematic viscosity of metal melts ..................................................... 68
nologies for purification of industrial wastes, using pulse water treatment ................................................. 83 Raiymbekov Y.B., Besterekov U., Abdurazova P.A. Review of methods for enrichment of phosphate
raw materials in the world ............................................................................................................................ 92 Tazhbayev Ye.M., Zhumagalieva T.S., Zhaparova L.Zh., Agdarbek A.A., Zhakupbekova E.Zh.,
Burkeeva G.K., Karimova B.N., Zhautikova S.B. Synthesis and investigation of PLGA-based nanoparti-cles as a modern tool for the drug delivery .................................................................................................. 97
It is seen in the above photographs, that the membranes, which have been tested, using EWTD, practically
have no deposits thereon, and those, tested without using EWTD, have a noticeable contamination on their
surface. Hence it follows, that the use of EWTD in the process of the reverse osmosis desalination can signif-
icantly increase the service life of the membranes, and maintain their selectivity.
Conclusions
Thus, a highly effective technology for purifying the water steam condensate of Pavlodar Petrochemical
Plant LLP has been developed on the basis of the reverse osmosis method, combined with the electromagnetic
water treatment device. During the tests at the pilot units, the optimal mode for desalinating the water steam
concentrate has been selected. It has been established, that the use of this technology, which is based on pulsed
water treatment technique, makes it possible to minimize the volume of the concentrate and contributes to
preventing an intense salt deposition on the reverse osmosis membranes. Herewith, a high efficiency of water
purification and an increase in the concentration coefficient are achieved and therefore service life of these
membranes is increased with preservation of their highly selective properties.
Е.Е. Ergozhin, Т.K. Chalov et al.
90 Вестник Карагандинского университета
This work performed, using the grant of the Committee of Science of the Ministry Education and Science
of Republic of Kazakhstan № AP05131439 on the theme «Synthesis and modification of nano-structured ion-
exchange membranes and the creation on their basis of innovative water treatment systems».
References
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2 Mudakkar R. Energy for economic growth, industrialization, environment and natural resources: living with just enough /R. Mudakkar, K. Zaman, M.M. Khan, M. Ahmad // Renewable and Sustainable Energy Reviews. — 2013. — Vol. 25. — P. 580–595.
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Е.Е. Ерғожин, Т.К. Чалов, Т.В. Ковригина, Е.А. Мельников, Б.Е. Бегенова
Суды импульстік өңдеуде қолдана отырып, өнеркәсіптік ағындарды
тазартудың баромембранды технологиялары
Мақалада «Павлодар мұнай-химия зауыты» ЖШС су бу конденсатын тазарту бойынша деректер келті-
рілген. Жүргізілген зерттеулер барысында алдын-ала тазалау сүзгілеріне арналған полифункционалды
менты, селективность, пилотная обратноосмотическая установка, прибор электромагнитной обработки
воды, проба воды, протокол испытаний, антискалант.
References
1 Kamali, M., Suhas, D.P., Costa, M.E., Capela, I., & Aminabhavi, T.M. (2019). Sustainability considerations in membrane-based technologies for industrial effluents treatment. Chemical Engineering Journal, 368, 474–494.
2 Mudakkar, R., Zaman, K., Khan, M.M., & Ahmad, M. (2013). Energy for economic growth, industrialization, environment and natural resources: living with just enough. Renewable and Sustainable Energy Reviews, 25, 580–595.
3 Timofeev, K.L., Kurdiumov, V., & Maltsev, G. (2019). Sorption and Membrane Technologies for Mine Water Purification. Materials Science Forum, 946, 621–627.
4 Rodrigues, A.E., Madeira, L.M., Wu, Yi-J., & Faria, R. (2018). Sorption Enhanced Reaction Processes. World Scientific Pub-lishing, 361.
5 Ergozhin, E.E., Chalov, T.K., & Khakimbolatova, K.K. (2017). Membrany i membrannye tekhnolohii [Membranes and Mem-brane Technologies]. Almaty: IP «Beketaeva» [in Russian].
6 Ergozhin, E.E., Chalov, T.K., & Kovrigina, T.V. (2018). Sinteticheskie i prirodnye ionity i sorbtsionnye tekhnolohii [Synthetic and natural ion exchangers and sorption technologies]. Almaty: IP «Beketaeva» [in Russian].
7 Tashlykov, E.I., Zabolockii, V.I., Gorbunov, M.V. & Ckhaj, A.A. et al. (2006). Hibridnaia baroelektromembrannaia ustanovka dlia polucheniia sverkhchistoi vody [Hybrid baroelectric membrane installation for ultrapure water]. Proceedings from Ion transport in organic and inorganic membranes: Rossiiskaia konferentsiia-shkola s mezhdunarodnym uchastiem (22–25 maia 2006 hoda) — Russian Conference School with International Participation. (рр. 146–148). Krasnodar; Tuapse: KubHU [in Russian].
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9 Svittsov, A.A. (2010). Membrannye tekhnolohii v Rossii [Membrane technologies in Russia]. The Chemical Journal, 10, 22–26 [in Russian].
10 Reverse Osmosis and Nanofiltration (M46), Second Edition, Softbound. (2007). American Water Works Association, 226 p.
11 Balandina, A.G., Hangildin, R.I., Ibragimov, I.G., & Martyasheva, V.A. (2015). Razvitie membrannykh tekhnolohii i vozmozhnost ikh primeneniia dlia ochistki stochnykh vod predpriiatii khimii i neftekhimii [The development of membrane technolo-gies and the possibility of their application for wastewater treatment in chemical and petrochemical enterprises]. Neftehazovoe delo — Oil and gas business, 5, 336–375 [in Russian].