THEBARTON ASSESSMENT AREA - epa.sa.gov.au

Post on 01-Dec-2021

3 Views

Category:

Documents

0 Downloads

Preview:

Click to see full reader

Transcript

THEBARTON ASSESSMENT AREA STAGE 1 ENVIRONMENTAL ASSESSMENT

FINAL REPORT | EPA REF 0524111 ENVIRONMENT PROTECTION AUTHORITY

SOUTH AUSTRALIA

30 OCTOBER 2017 VOLUME 1 REPORT

THEBARTON ASSESSMENT AREA

STAGE 1 ENVIRONMENTAL ASSESSMENT

FINAL REPORT

EPA REF 0524111

PREPARED FOR Environment Protection Authority South Australia

PREPARED BY Fyfe Pty Ltd

ABN 57 008 116 130

ADDRESS L1 124 South Terrace Adelaide SA 5000

CONTACT Mr Marc Andrews Division Manager - Environment

TELEPHONE direct 08 8201 9794 mobile 0408 805 264

FACSIMILE 61 8 8201 9650

EMAIL marcandrewsfyfecomau

DATE 30102017

REFERENCE 80607-1 REV1

copyFyfe Pty Ltd 2017

Proprietary Information Statement

The information contained in this document produced by Fyfe Pty Ltd is solely for the use of the Client identified on the cover sheet for the purpose for which it has been prepared and Fyfe Pty Ltd undertakes no duty to or accepts any responsibility to any third party who may rely upon this document

All rights reserved No section or element of this document may be removed from this document reproduced electronically stored or transmitted in any form without the written permission of Fyfe Pty Ltd

Document Information

Report prepared by Dr Ruth Keogh Principal Environmental Scientist Fyfe Pty Ltd Date 27 October 2017

Report reviewed and approved by Division Manager - Environment Fyfe Pty Ltd Date 30 October 2017 Marc Andrews

Client receipt by Shannon Thompson Advisor Site Contamination SA EPA Date 30 October 2017

Revision History

Revision Revision Status Date of Issue Prepared Reviewed Approved

REV 0 Draft 6 October 2017 RK MJA MJA

REV 1 Final 30 October 2017 RK MJA MJA

Please note that when viewed electronically this document may contain pages that have been intentionally left blank These blank pages may occur because in consideration of the environment and for your convenience this document has been set up so that it can be printed correctly in double-sided format

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

CONTENTS

Page

VOLUME 1 REPORT

LIST OF ACRONYMS V

EXECUTIVE SUMMARY VIII

1 INTRODUCTION 1

11 Purpose 1

12 General background information 1

13 Definition of the assessment area 2

14 Identification of contaminants of potential concern 2

15 Objectives 3

2 CHARACTERISATION OF THE ASSESSMENT AREA 5

21 Site identification 5

22 Regional geology and hydrogeology 5

23 Data quality objectives 7

3 SCOPE OF WORK 11

31 Preliminary work 12

32 Field investigation and laboratory analysis program 12

33 Data interpretation 14

4 METHODOLOGY 15

41 Field methodologies 15

42 Laboratory analysis 19

5 QUALITY ASSURANCE AND QUALITY CONTROL 21

51 Field QAQC 21

52 Laboratory QAQC 24

53 QAQC summary 26

80607-1 REV1 30102017 PAGE I

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

6 ASSESSMENT CRITERIA 27

61 Groundwater 27

62 Soil vapour 29

7 RESULTS 31

71 Surface and sub surface soil conditions 31

72 Waterloo Membrane Samplerstrade 32

73 Groundwater 34

74 Soil vapour bores 40

8 GROUNDWATER FATE AND TRANSPORT MODELLING 43

81 Groundwater flow modelling 43

82 Solute transport modelling 43

9 VAPOUR INTRUSION RISK ASSESSMENT 47

91 Objective 47

92 Areas of interest 47

93 Risk assessment approach 47

94 Tier 1 assessment 48

95 Tier 2 assessment 49

96 Conclusions 59

10 CONCEPTUAL SITE MODEL 61

11 CONCLUSIONS 67

12 DATA GAPS 71

13 REFERENCES 73

14 STATEMENT OF LIMITATIONS 77

PAGE II 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

LIST OF TABLES

Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area 7

Table 22 Data Quality Objectives 8 Table 31 Scope of field investigation program ndash May to August 2017 12 Table 32 Scope of laboratory testing program 13 Table 41 Summary of field methodologies 15 Table 51 Field QAQC procedures ndash Groundwater 22 Table 52 Field QAQC procedures ndash Soil vapour 23 Table 53 Laboratory QAQC procedures 25 Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area 28 Table 62 Sources of adopted groundwater assessment criteria 29 Table 71 Detectable Waterloo Membrane Samplertrade CHC results 32 Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units 33 Table 73 Hydraulic conductivities (rising and falling head tests) 35 Table 74 Detectable groundwater CHC results 37 Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area 41 Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores 42 Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs 49 Table 92 Tier 2 vapour intrusion modelling ndash building input parameters 51 Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters 52 Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air 52 Table 95 Summary of chemical parameters adopted for vapour intrusion modelling 52 Table 96 Comparison of predicted residential indoor air concentrations with SA EPA

response levels 54 Table 97 Summary of model input parameters subjected to sensitivity analysis 55 Table 98 Exposure parameters ndash Commercialindustrial workers 58 Table 99 Adopted inhalation toxicity reference values 58 Table 910 Summary of properties with predicted indoor air concentrations

(residential crawl space) above adopted EPA response levels 59 Table 101 Summary of existing information for the Thebarton EPA Assessment Area 61

LIST OF FIGURES (in text)

Figure 71 Piper diagram 39 Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green)

relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple) 46

Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels 50

80607-1 REV1 30102017 PAGE III

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

FIGURES follow page 79

Figure 1 Site Location and Assessment Area Figure 2 Assessment Point Locations Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan Figure 4 Groundwater Elevation Contour Plan Figure 5 Groundwater Concentration Plan Figure 6 Soil Vapour Concentration Plan (10 m) Figure 7 Soil Vapour Concentration Plan (30 m)

VOLUME 2 APPENDICES

APPENDICES

Appendix A Historical Report Summary Appendix B Historical Information Supplied by the EPA Appendix C DEWNR Registered Groundwater Database Search Results Appendix D Groundwater Well Permits Appendix E Field Sampling Sheets ndash Groundwater Appendix F Survey Data Appendix G Certified Laboratory Certificates and Chain of Custody Documentation Appendix H Groundwater Well Log Reports Appendix I WMStrade Borehole Log Reports Appendix J Soil Vapour Borehole Log Reports Appendix K Waste Transport Certificates Appendix L Tabulated Results ndash Soil Vapour Geotechnical and Groundwater Appendix M Equipment Calibration Records Appendix N Drill Core Photographs Appendix O Arcadis Groundwater Fate and Transport Modelling Report Appendix P Arcadis Vapour Intrusion Risk Assessment Report

PAGE IV 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

LIST OF ACRONYMS

AER Air Exchange Rate

AF Attenuation Factor

AHD Australian Height Datum

ANZECC Australian and New Zealand Environment and Conservation Council

ARMCANZ Agriculture and Resource Management Council of Australia and New Zealand

ASC Assessment of Site Contamination

ASTM American Standard Testing Material

AT Averaging Time

ATSDR Agency for Toxic Substances and Disease Registry

AWQC Australian Water Quality Centre

BGL Below Ground Level

BTEX Benzene Toluene Ethylbenzene Xylenes

BTOC Below Top of Casing

BUA Beneficial Use Assessment

CBD Central Business District

CHC Chlorinated Hydrocarbon Compound

COC Chain of Custody

COPC Contaminants of Potential Concern

CRC CARE Cooperative Research Centre for Contamination Assessment and Remediation of the Environment

CSM Conceptual Site Model

11-DCA 11-dichloroethane

11-DCE 11-dichloroethene

12-DCE 12-dichloroethene

DCE Dichloroethene

DEC Department of Environment and Conservation

DEWNR Department of Environment Water and Natural Resources

DNAPL Dense Non-Aqueous Phase Liquid

DO Dissolved Oxygen

DQI Data Quality Indicator

DQO Data Quality Objective

EC Electrical Conductivity

ED Exposure Duration

80607-1 REV1 30102017 PAGE V

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

EF Exposure Frequency

EMP Environmental Management Plan

EPA Environment Protection Authority

EPC Exposure Point Concentration

EPP Environment Protection Policy

ET Exposure Time

GPA Groundwater Prohibition Area

GPR Ground Penetrating Radar

GPS Global Positioning System

HHRA Human Health Risk Assessment

HIL Health Investigation Level

HSP Health and safety Plan

IPA Isopropyl Alcohol (isopropanol or 2-propanol)

IRIS Integrated Risk Information System

ITRC Interstate Technology and Regulatory Council

JampE Johnson and Ettinger

JHA Job Hazard Analysis

LNAPL Light Non-Aqueous Phase Liquid

LOR Limit of Reporting

MGA Map Grid of Australia

MQO Measuring Quality Objectives

MTC Mass Transfer Co-efficient

NA Not Applicable

NAPL Non-Aqueous Phase Liquid

NATA National Association of Testing Authorities

ND Non Detect

NEPM National Environment Protection Measure

NHMRC National Health and Medical Research Council

NJDEP New Jersey Department of Environmental Protection

NRMMC National Resource Management Ministerial Council

PAH Polycyclic Aromatic Hydrocarbons

PCE Tetrachloroethene (perchloroethylene)

PID Photoionisation Detector

PQL Practical Quantification Limit

PSD Particle Size Distribution

QA Quality Assurance

80607-1 REV1 30102017 PAGE VI

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

QC Quality Control

RAIS Risk Assessment Information System

RFQ Request for Quote

REM Resource and Environmental Management

RPD Relative Percentage Difference

RSL Regional Screening Level

SA EPA South Australian Environment Protection Authority

SAQP Sampling and Analysis Quality Plan

SOP Standard Operating Procedure

SVOC Semi-Volatile Organic Compound

SWL Standing Water Level

SWMS Safe Work Method Statement

111-TCA 111-trichloroethane

TCE Trichloroethene

TDS Total Dissolved Solids

TRH Total Recoverable Hydrocarbons1

TRV Toxicity Reference Value

US EPA United Stated Environment Protection Agency

USGS United States Geological Survey

VC Vinyl Chloride

VIRA Vapour Intrusion Risk Assessment

VOC Volatile Organic Compound

VOCC Volatile Organic Chlorinated Compound

WHO World Health Organisation

WMStrade Waterloo Membrane Samplertrade

TRH = measurable amount of petroleum-based hydrocarbon (ie complex mixture of crude oil and natural gas (gt 250 compounds) including aromatics aliphatics paraffins unsaturated alkanes and naphthalenes) plus various other compounds including fatty acids esters humic acids phthalates and sterols

80607-1 REV1 30102017 PAGE VII

1

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

EXECUTIVE SUMMARY

Background information

An approximate 27 hectare mixed use area of Thebarton has been designated by the South Australian Environment Protection Authority (EPA) as the Thebarton EPA Assessment Area

The former Austral sheet metal works (Austral) property located over multiple allotments between George and Maria Streets from the 1920s until the 1960s-1970s has been identified as a possible source of dissolved phase groundwater chlorinated hydrocarbon (CHC) contamination Groundwater CHC impacts within the uppermost (Quaternary ndash Q1) aquifer were identified as extending in a general north-westerly direction (consistent with regional groundwater flow direction) from the south-eastern portion of the Thebarton EPA Assessment Area and having resulted in the generation of soil vapour containing elevated concentrations of CHC

The boundaries of the Thebarton EPA Assessment Area were established on the basis of the following

the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street (part of the former Austral property) and 39 Smith Street (hydraulically down-gradient of the former Austral property) in Thebarton

the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

Key objectives

The results of the recent investigations undertaken by Fyfe have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties within the Thebarton EPA Assessment Area

The key objectives detailed by the EPA were to

further delineate the chlorinated hydrocarbon contamination in groundwater

further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

80607-1 REV1 30102017 PAGE VIII

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

With respect to the VIRA the EPA requested that there be specific consideration of

residential properties (slab on grade)

residential properties (crawl space)

residential properties (with basement) and

trenchmaintenanceutility workers that may be working in the vicinity of the contamination

Site conditions

Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were identified within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m below ground level (BGL) during the drilling of groundwater well MW17 the latter consistent with the depth of groundwater within the Q1 aquifer

Soil

Groundwater within the Q1 aquifer is located at a depth of approximately 123 to Groundwater 159 m BGL and flows in a general north-westerly direction The closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred and the groundwater gradient is relatively flat (ie 000062 to 00012)

Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified (based on factors such a groundwater salinity registered bore use and the locations of potential sensitive receptors) as including domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux) and possibly also potable

Contaminants of Potential Concern (COPC)

The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans-) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

80607-1 REV1 30102017 PAGE IX

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Scope of work

A groundwater and soil vapour monitoring program was undertaken by Fyfe across the Thebarton EPA Assessment Area between May and August 2017 It involved the following scope of work

installation of a total of 41 WMStrade units to 1 m BGL in an approximate grid-pattern across the entire assessment area (Round 1) and at specific targeted locations (Round 2) followed by laboratory analysis of retrieved sample units for specific CHC

drilling and installation of 25 groundwater wells to depths of between 15 and 19 m BGL including a background well to the east of the southern portion of the assessment area

testing of 30 selected groundwater well drill core samples for geotechnical parameters

gauging and sampling of the 25 newly installed groundwater wells as well as an existing well located in Admella Street followed by laboratory analysis of all samples for specific CHC and 10 selected samples for major cationsanions natural attenuation parameters and additional nutrients

aquifer permeability (rising and falling head ldquoslugrdquo) testing of 10 groundwater wells

drilling and installation of 13 soil vapour bores including 11 nested bores (ie to 1 and 3 m BGL) and two bores to 1 m BGL and

sampling of all soil vapour bores followed by laboratory analysis of samples for specific CHC and general gases

The soil vapour data were used to undertake a VIRA aimed at predicting indoor air concentrations of TCE under various land use and building construction scenarios In order to validate the results of the modelling which includes a number of conservative assumptions and is therefore expected to over-estimate potential risk the EPA has commissioned indoor air monitoring in a number of residential properties within the Thebarton EPA Assessment Area ndash the indoor air monitoring results will be reported under separate cover

Groundwater fate and transport modelling was undertaken to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton EPA Assessment Area The provision of this information is aimed at supporting the definition (extent and geometry) of a potential future Groundwater Prohibition Area (GPA) to be designated by the EPA in accordance with the provisions of Section S103S of the Environment Protection Act 1993

80607-1 REV1 30102017 PAGE X

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Identified impacts

Contaminants identified in the Q1 aquifer beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down

Groundwater

(ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested

The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected (Austral) source site in accordance with the predominant flow direction associated with the Q1 aquifer The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) ndash whereas its north-western extent has not yet been determined the groundwater CHC plume has been delineated in all other directions

Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion

Soil vapour

The soil vapour samples with the maximum TCE concentrations also had the highest PCE and 11-DCE concentrations (or elevated laboratory limits of reporting (LOR)) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-)

Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE exceeded the adopted health investigation levels (HILs) for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE degradation has not yet resulted in its production

Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

80607-1 REV1 30102017 PAGE XI

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Assessment of risk

Measured concentrations of TCE exceeded the adopted assessment criteria for potable use andor primary contact recreation in wells located on Admella Maria George Albert Chapel and Dew Streets as well as Light Terrace ndash with the highest concentrations corresponding to the ldquocorerdquo area of the plume One well on Albert Street also contained a concentration of carbon tetrachloride that exceeded the respective potable criterion

Groundwater risks

Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous

Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

The groundwater modelling undertaken by Arcadis involved the development of an Groundwater fate and transport initial groundwater flow model using MODFLOW followed by the development of a modelling site-specific (three-dimensional) solute transport model using the MT3DMS transport

code

The results of this modelling were interpreted to indicate the following

although scattered detectable concentrations of 12-DCE have been measured in groundwater across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE daughter products indicate that substantial dechlorination is not occurring and

the dissolved phase groundwater TCE plume is predicted to extend by another 500 m (ie beyond the boundaries of the current Thebarton EPA Assessment Area) over the next 100 years whereas no significant lateral plume expansion is expected

The VIRA undertaken by Arcadis involved a two-tier assessment approach Whereas Vapour intrusion the Tier 1 screening risk assessment compared the measured soil vapour CHC concentrations to (modified) guideline values the Tier 2 risk assessment involved the application of the Johnson and Ettinger vapour intrusion model to predict indoor air CHC concentrations for residential (slab on grade crawl space and basement construction) and commercialindustrial (slab on grade construction) properties across the assessment area Site-specific geotechnical parameters and soil vapour data collected from 1 and 3 m BGL throughout the Thebarton EPA Assessment Area were used in the modelling It should be noted that overall the vapour modelling

risks

80607-1 REV1 30102017 PAGE XII

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

The results of the VIRA with respect to the predicted indoor air concentrations of TCE within residential properties (assuming crawl space construction) versus adopted EPA response levels indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air that require further action as follows

10 properties within the investigation range (2 to lt20 microgm3)

eight properties within the intervention range (20 to lt200 microgm3) and

three properties within accelerated intervention range (ge200 microgm3)

All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises

Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which is expected to be overly-conservative) ndash these results will be documented in a subsequent report

Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie as determined for the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

A qualitative assessment of potential risks to subsurface trenchmaintenanceutility workers indicated that exposure management may be required in areas where TCE concentrations at 1 m BGL are above 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific health and safety plan (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a photoionisation detector (PID) unit providing increased ventilation and using appropriate personal protective equipment (eg gas masks) as required

80607-1 REV1 30102017 PAGE XIII

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Data gaps

Based on the results obtained during the recent Fyfe investigations as well as available historical information the following data gaps have been identified for the Thebarton EPA Assessment Area

property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

Notes ie the interim soil vapour HILs adopted from the National Environment (Assessment of Site Contamination) Measure 1999 (as revised in 2013 ndash ie the ASC NEPM (1999)) but assuming a sub-slab to indoor air attenuation factor of 003 as compared to the value of 01 adopted by the ASC NEPM (1999)

80607-1 REV1 30102017 PAGE XIV

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

1 INTRODUCTION

11 Purpose

Fyfe Pty Ltd (Fyfe) was commissioned by the South Australian Environment Protection Authority (SA EPA referred to herein as the EPA) to undertake Stage 1 groundwater and soil vapour investigation works groundwater fate and transport modelling and a human health vapour intrusion risk assessment (VIRA) within an EPA designated assessment area located within Thebarton South Australia (herein referred to as the Thebarton EPA Assessment Area) The location and extent of the Thebarton EPA Assessment Area referenced within this document is identified on Figure 1

12 General background information

Previous environmental assessment work undertaken since 1994 (as summarised in Appendix A) combined with historical information provided by the EPA (as included in Appendix B) indicates that the Thebarton EPA Assessment Area has been used for mixed residential and commercialindustrial purposes over time

Groundwater impacts2 identified within the uppermost (Quaternary ndash Q1) aquifer in the vicinity of the former Austral sheet metal works (Austral) on George Street included both petroleum hydrocarbons (ie diesel fuel) as well as chlorinated hydrocarbon compounds (CHC) such as trichloroethene (TCE) and were first notified to the EPA in 2006

Available historical information for the Austral property (ie the suspected source site) indicates that it operated from the 1920s until the 1960s-1970s and occupied an extensive area of Thebarton including

part of the southern side of George Street extending from about half way between East Terrace3 and Admella Street (ie 11-25 George Street) to the west of Admella Street (ie 31-35 George Street)

the entire northern side of Maria Street from East Terrace to the west of Admella Street

part of the southern side of Maria Street (ie from 21 Maria Street) to Admella Street and

25-27 East Terrace

2 Note that the term ldquoimpactrdquo has been used by Fyfe to indicate identified concentrations of compounds (specifically chlorinated hydrocarbons) that are not naturally occurring (ie concentrations above background that have resulted from anthropogenic activities) The use of this term does not denote that the presence of these compounds represents a risk to either human health or the environment and the term ldquoimpactrdquo is therefore not directly interchangeable with the term ldquoSite Contaminationrdquo the latter defined under the Environment Protection Act 1993 to include actual or potential harm to human health andor the environment

3 now James Congdon Drive

80607-1 REV1 30102017 PAGE 1

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Historical newspaper articles described the Austral property as hosting a factory that extended over more than three acres and included an electroplating facility In 1938 it was described as the largest aluminium utensil manufacturing company in the southern hemisphere

Other potential sources of groundwater contamination4 identified within the Thebarton EPA Assessment Area include a former gas works (ie located to the south and south-east of the Austral property and including the current Ice Arena property) a mechanicrsquos workshop another sheet metal working facility and a farm machinery manufacturer

The Stage 1 assessment work described herein was commissioned by the EPA to determine whether historical contamination in the vicinity of George Street was presenting a risk to human health or the environment

13 Definition of the assessment area

As detailed on Figure 1 the current EPA Assessment Area covers an area of approximately 27 ha within the suburb of Thebarton located approximately 2 km north-west of the Adelaide central business district (CBD)

The boundaries of the Thebarton EPA Assessment Area were established by the EPA on the basis of the following

the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street and 39 Smith Street in Thebarton (refer to Appendix A)

the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

14 Identification of contaminants of potential concern

The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

Site Contamination is defined by the Environment Protection Act 1993 as existing if chemical substances are present on or below the surface of a site in concentrations above background the contaminants are there as a result of activity at the site or elsewhere and their presence has resulted in actual or potential harm (that is not trivial) to the health and safety of human beings taking into account current and proposed land uses or water or the environment

PAGE 2 80607-1 REV1 30102017

4

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

15 Objectives

As defined by the EPA the key objectives of the recent Stage 1 environmental assessment program undertaken within the Thebarton EPA Assessment Area (refer to Figure 1) were to

further delineate the chlorinated hydrocarbon contamination in groundwater

further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

With respect to the VIRA the EPA requested that there be specific consideration of

residential properties (slab on grade)

residential properties (crawl space)

residential properties (with basement) and

trenchmaintenanceutility workers that may be working in the vicinity of the contamination

80607-1 REV1 30102017 PAGE 3

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

2 CHARACTERISATION OF THE ASSESSMENT AREA

21 Site identification

For the purpose of this investigation program the Thebarton EPA Assessment Area (as delineated in Figure 1) has been defined by the following roadways

North northern verge of Smith Street

South Maria Street (between Dew Street and Albert Street) portion of Parker Street (between Maria Street and Goodenough Street) and Goodenough Street (between Parker Street and James Congdon Drive)

East western verge of Port Road and James Congdon Drive and

West western verge of Dew Street

22 Regional geology and hydrogeology

221 Geology

The Thebarton area is located within the Adelaide Plains approximately 8 km to the east of Gulf St Vincent and to the west of the Para Fault It lies within the Golden Grove ndash Adelaide Embayment area of the St Vincent Basin which consists of a succession of Tertiary and Quaternary age sediments (with thicknesses of up to 600 m) overlying basement rocks

The 1250000 Adelaide geological map (SA Department of Mines and Energy 1969) indicates that the near-surface geology of the area consists primarily of Quaternary aged soils and sediments including the Pooraka and Hindmarsh Clay formations The Pleistocene aged Pooraka Formation generally comprises a thickness of approximately 10 m and is of alluvial origin comprising sandy clays and clayey to sandy silts interbedded with layers of clay sand andor gravel The underlying Pleistocene aged Hindmarsh Clay Formation represents the basal unit of the Adelaide Plains and has a maximum general thickness of more than 100 m It generally comprises a basal gravel layer a middle layer of mottled medium to high plasticity (red-brown yellow brown greygreen to orange) often stiff to hard clays and an upper layer of fluvial and alluvial red-brown silty sand Gerges (1999) describes Hindmarsh Clay as comprising a mottled brown to pale olive grey predominantly clay formation that becomes green grey towards the basal section (approximately 16 to 20 m below ground level (BGL)) and is characterised by an increasing gravel content with depth

Underlying the Hindmarsh Clay are sands and limestone of Tertiary age which are in turn underlain by metamorphosed basement rock of the Proterozoic Umberatana Group

80607-1 REV1 30102017 PAGE 5

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

222 Hydrogeology

According to Gerges (2006) the aquifers identified within the Quaternary aged sediments of the Adelaide Plains are typically found within the coarser interbedded silt sand and gravel layers of the Hindmarsh Clay Formation and vary greatly in thickness (typically from 1 to 18 m) lithology and hydraulic conductivity Confining beds between the Quaternary aquifers consist of clay and silt layers and range in thickness from 1 to 20 m These confining beds vary in terms of the amount of coarser grained material they contain their bulk hydraulic conductivity andor the presence and density of fractures In addition their absence in some areas allows direct hydraulic connection between the aquifers

The Thebarton area is located within Hydrogeological Zone 3 (Subzone 3E) of Gerges (2006) This zone contains five to six Quaternary aquifers and three to four almost flat-lying Tertiary aquifers The first Tertiary aquifer estimated by Gerges (2006) to be intersected at a depth of approximately 130 m BGL near the Para Fault is most frequently accessed for industrial and recreational groundwater use

The Q1 aquifer assessed as part of the current investigations is typically located at depths of between 3 and 10 m BGL beneath the Adelaide Plains with an average thickness of 2 m The Q1 aquifer contains water of variable salinity with Subzone 3E including a range of 500 to 3500 mgL total dissolved solids (TDS) The gradient of the Q1 aquifer is generally flat (particularly to the west of the Para Fault) and flow direction is typically towards the north-west

A search of the registered bore database maintained by the Department of Environment Water and Natural Resources (DEWNR (2017) WaterConnect database) identified 59 bores within the general Thebarton area of which 18 are located in the Thebarton EPA Assessment Area Although eight bores were installed for monitoring purposes on or immediately adjacent to the property located at 31-37 George Street (ie part of the former Austral facility) it is understood that only one bore (6628-21951 ndash located within the Admella Street roadway intersecting the Q1 aquifer and identified as MW01 in Appendix A but MW02 by Fyfe5) remains in situ

In addition to numerous monitoringinvestigationobservation bores the Q1 aquifer within the general (ie broader) Thebarton area is recorded in the DEWNR (2017) database as being accessed for drainage domestic and industrial purposes

DEWNR (2017) information for registered bores located within the general Thebarton area is included in Appendix C whereas information for bores located within the Thebarton EPA Assessment Area (excluding those associated with the property at 31-37 George Street and installed solely for monitoring purposes6) is summarised in Table 21

5 This existing groundwater well was identified as MW02 by Fyfe in accordance with the markings on the gatic cover and the DEWNR (2017) WaterConnect bore identification details although it was originally installed as MW01 by REM (refer to discussion of previous reports in Appendix A)

6 ie 6628-21951 6628-21952 6628-22229 to 6628-22233 and 6628-22236

PAGE 6 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area

Bore ID Location Purpose Status Maximu SWL Salinity Yield Aquifer m well (m (mgL (Lsec

Tertiary (T1)

depth BGL) TDS) ) (m BGL)

125 6628-516 Coca Cola plant Rehabilitated 138 1963 794

6628-1435 Coca Cola plant Backfilled 184 212 921 392 Tertiary (T1)

6628-4576 Corner of Admella amp Chapel Streets

125 1454 445 Tertiary (T1)

6628-7724 Coca Cola plant Observation 155 2017 1272 1516 Tertiary (T1)

6628-7725 Coca Cola plant Observation 127 3016 1100 1005 Tertiary (T1)

6628-12516 Coca Cola plant Industrial Backfilled 210 212 1300 1875 Tertiary (T1)

6628-20663 39 Smith Street Irrigation 121 1105 50 Tertiary (T1)

6628-20969 39 Smith Street Industrial 30 14 1535 25 Quaternary (Q1)

6628shy21951

Admella Street 20 Quaternary (Q1)

6628-22395 21 James Congdon Drive

20 157 1541 05 Quaternary

6628-23525 41 Maria Street 206 273 1078 10 Tertiary (T1)

Notes Shading indicates that information was not recorded in the database as interpreted from information provided in the database ndash approximate only in some instances

ie MW02 as included in the groundwater monitoring program of Fyfe ndash refer to Table 31 Abbreviations BGL = below ground level SWL = standing water level TDS = total dissolved solids

23 Data quality objectives

The Data Quality Objective (DQO) process as described in Australian Standard AS44821-2005 and the National Environment Protection (Assessment of Site Contamination) Measure (ASC NEPM 1999)7

Schedule B2 Guideline on Data Collection Sample Design and Reporting and more fully documented in the NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme involves a seven-step iterative approach that was initially developed by the United States Environment Protection Agency (US EPA) to facilitate the systematic planning and verification of contaminated sites assessment projects

As stated in Schedule B2 of the ASC NEPM (1999) the first six steps of the DQO process comprise the development of qualitative and quantitative statements that define the objectives of the site assessment program and the quantity and quality of data needed to inform risk-based decisions These steps enable the

All references to the ASC NEPM (1999) refer to the version amended on 16 May 2013

80607-1 REV1 30102017 PAGE 7

7

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

project team to communicate the goals decisions constraints (eg time budget) and uncertainties associated with the project and detail how they are to be addressed The seventh step comprises the development of a Sampling and Analysis Quality Plan (SAQP) to generate the data required to adequately characterise site contamination issues and assess their associated potential environmental and human health risks under the proposed land use scenario

The DQOs defined for the Thebarton EPA Assessment Area are summarised in Table 22

Table 22 Data Quality Objectives

Objective Comment

Step 1 ndash Statement of the Problem According to information provided to Fyfe by the EPA (as summarised in Appendix A) a property located at 31-37 George Street (immediately west of Admella Street) in Thebarton and historically occupied by part of the Austral facility had been found to be underlain by groundwater CHC (primarily TCE) impacts More recent reporting to the EPA for a property at 39 Smith Street located approximately 350 m north-west (and hydraulically down-gradient) of the George Street property indicated that detectable CHC (predominantly TCE) were also present within groundwater Since this area of Thebarton is occupied by a mixture of commercialindustrial and residential properties and the source and extent of the CHC impacts within the Q1 aquifer had not yet been determined potential risks to human health andor the environment had yet to be assessed

Step 2 ndash The Decision that Needs The assessment works commissioned by the EPA were necessitated to to Result from the Investigation investigate the source extent and magnitude of the groundwater CHC

contamination beneath a designated area of Thebarton (ie that included both the George Street and Smith Street properties) and to understand the possible risk to public health from potential vapour generation Fyfe have therefore undertaken vapour modelling and intrusion risk assessment works aimed at evaluating whether concentrations of identified groundwater andor soil vapour contaminants pose an unacceptable risk to human health In addition groundwater fate and transport modelling has been undertaken to predict the extent of the plume This will assist the EPA to determine a potential future Groundwater Prohibition Area (GPA) in accordance with the provisions of Section 103S of the Environment Protection Act 1993

Step 3 ndash Inputs to the Decision The information that was required to resolve the decision statement included the collection of physical and chemical data from across the Thebarton EPA Assessment Area The collected data as well as physical observations regarding the geology of the area and possible preferential contaminant pathways was used to determine potential risks to human health via groundwater fate and transport and vapour intrusion modelling

Step 4 ndash Boundaries of the Investigation

The lateral boundaries of the Thebarton EPA Assessment Area are as defined in Sections 13 and 21 as depicted on Figure 1 Vertically the investigations extended as far as the maximum drilled depth (19 m BGL)

Step 5 ndash Decision Rules The decision rule will be based upon the identification of predicted indoor air concentrations of CHC compounds associated with groundwater andor soil vapour impacts which exceed adopted response levels

PAGE 8 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Objective Comment

Step 6 ndash Decision Error Tolerances The purpose of establishing decision error tolerance is to control the acceptable degree of uncertainty upon which decisions are made in order to avoid the making of an incorrect decision and to enable identification of additional investigation monitoring or remediation activities required on the basis of accurate data for the protection of human health and the environment The Measuring Quality Objectives (MQO) include the quality assurance (QA) activities that were conducted during the assessment the quality control (QC) acceptance criteria applicable to the assessment and the adopted Data Quality Indicators (DQIs) as follows (and further discussed in Section 5) completeness ndash a measure of the amount of useable data from a data

collection activity comparability ndash the confidence (expressed qualitatively) that data may be

considered to be equivalent for each sampling and analytical event representativeness ndash the confidence (expressed qualitatively) that data

are representative of each media present on the site precision ndash a quantitative measure of the variability (or reproducibility) of

data and accuracy (bias) ndash a quantitative measure of the closeness of reported data

to the true value

Step 7 ndash Optimisation of the Data collection was undertaken in general accordance with the Sample Collection Design methodologies outlined in the relevant documentsguidelines referenced

throughout this report As determined by the EPA the data collection design included targeted sampling to investigate and delineate areas of potential groundwater and soil vapour contamination and to assess potential associated human health risks

80607-1 REV1 30102017 PAGE 9

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

3 SCOPE OF WORK

The scope of work undertaken by Fyfe was generally consistent with that requested within the original EPA request for quote (RFQ) dated 27 March 2017 Some modifications to the original workscope occurred based on site findings and additional site information was collected where required and as agreed with the EPA in order to achieve the EPArsquos project objectives outlined in Section 15

As identified in the RFQ the scope of work was designed to

provide an initial delineation of CHC impacts in soil vapour through the deployment of Waterloo Membrane Samplers (WMStrade) as a screening tool

further delineate the previously identified CHC impacts in groundwater

decide based on the results of the WMStrade and groundwater results the need for the number of and the locations of permanent soil vapour monitoring bores

identify the nature extent and potential source area(s) of the identified CHC impacts in groundwater andor soil vapour

determine the likely fate and transport of the groundwater CHC plume to support the establishment of a potential future GPA

determine the potential human health (including vapour intrusion) risk(s) on the basis of the data collected and

ascertain whether or not a public health risk exists within the Thebarton EPA Assessment Area

The scope of work is further detailed in Section 32 Variations from the scope of work originally requested in the EPA RFQ were agreed with the EPA during the course of the project and included the following

deployment of an additional four WMStrade units ndash ie 41 in total as compared to the original allowance of 37

installation (and sampling) of an additional six nested soil vapour bores (to depths of 1 and 3 m BGL) ndash ie 11 in total as compared to the original allowance of five

installation (and sampling) two individually located (ie as opposed to the nested locations) soil vapour bores to a depth of 1 m BGL ndash ie as compared to the original allowance of 10

installation (and sampling) of 25 groundwater monitoring wells ndash ie as compared to the original allowance of 20 and

sampling of an existing well in Admella Street (MW02) ndash ie not included in the original EPA scope

80607-1 REV1 30102017 PAGE 11

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

31 Preliminary work

Preliminary work involved the following

review and summation of all available historical reports (as supplied by the EPA) ndash refer to Appendix A

development of a preliminary (working) conceptual site model (CSM) based on a review of the historical data

preparation of a detailed health and safety plan covering all aspects and stages of the work and

detailed planning with key stakeholders prior to the execution of the field investigation program

32 Field investigation and laboratory analysis program

The scope of the field investigation program undertaken by Fyfe between 31 May and 28 August 2017 is summarised in Table 31 whereas the scope of the laboratory testing program is summarised in Table 32

A plan showing the various assessment point locations is included as Figure 2

Table 31 Scope of field investigation program ndash May to August 2017

Scope Item Description of works Date of works

Passive soil vapour sampling ndash Round 1

Thirty-seven WMStrade units identified as WMS 1 to WMS 37 were installed within the soil profile to 1 m BGL at scattered (approximately grid-like) locations across the Thebarton EPA Assessment Area

31 May and 1 to 2 June

The WMStrade units were extracted and forwarded to the analytical laboratory 7 June

Soil bores were located using a hand-held global positioning system (GPS) unit before being backfilled with (drillerrsquos) sand

7 August

Monitoring well drilling and installation

Individual groundwater well permits were obtained from DEWNR prior to well installation ndash copies of the well permits are included in Appendix D Groundwater monitoring wells (MW1 MW3 and MW5 to MW26) were installed to depths of between 15 and 19 m BGL at 24 locations across the Thebarton EPA Assessment Area Background well MW4 was installed to 19 m BGL within a public recreational area located across James Congdon Drive to the east (ie near the south-eastern corner of the Thebarton EPA Assessment Area) All 25 newly installed wells were developed following installation

28 to 30 June 3 to 7 July and 10 to 14 July

Geotechnical soil testing

Intact soil cores collected during the drilling of 10 groundwater wells (MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25) were forwarded to the analytical laboratory for geotechnical testing

Groundwater gauging

All 25 newly installed monitoring wells (MW1 and MW3 to MW26) as well as the existing Admella Street well (MW02) were gauged to assess total well depth standing water level (SWL) and the presenceabsence of non aqueous phase liquid (NAPL) This was undertaken as a discrete event prior to the commencement of groundwater sampling

18 July

PAGE 12 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Scope Item Description of works Date of works

Groundwater sampling

All 26 existing and newly installed wells were sampled using a combination of low flow (micropurge) and HydraSleevetrade sampling techniques (as recorded on the field sampling sheets in Appendix E) ndash samples were forwarded to the analytical laboratories

18 to 21 and 24 to 25 July

Aquifer testing Aquifer permeability (slug) testing was undertaken on 10 wells (MW02 MW3 MW7 MW14 MW17 MW20 MW21 MW23 MW25 and MW26) Data was subsequently evaluated by Arcadis Pty Ltd (Arcadis) to estimate the hydraulic conductivity of the aquifer beneath the Thebarton EPA Assessment Area (refer to Section 732)

28 July

Soil vapour bore drilling and installation

Following the receipt of the groundwater data 11 nested soil vapour bores (SV1 to SV10 and SV12) were installed to a depth of 1 and 3 m BGL at selected locations within the Thebarton EPA Assessment Area Two additional soil vapour bores (SV11 and SV13) were installed to a depth of 1 m BGL

18 21 and 22 August

Active soil vapour sampling

Sampling of soil vapour bores was undertaken using summa canister (TO-15) sample collection methods Vapour (canister) and general gas (Tedlar bag) samples were extracted from all 13 locations (ie SV1 to SV13) including the 11 nested bores

24 August

Passive soil vapour sampling ndash Round 2

Following the receipt of the groundwater data and for the purposes of comparison with the soil vapour bore data an additional four WMStrade units (WMS 38 to WMS 41) were installed within the soil profile to 1 m BGL at targeted locations across the Thebarton EPA Assessment Area (ie within approximately 1 m of soil vapour bores SV2 SV4 SV5 and SV7) Soil bores were located using a hand-held GPS unit

18 August

The WMStrade units were extracted and forwarded to the analytical laboratory and the soil bores were backfilled with (drillerrsquos) sand

24 August

Surveying The locations of all soil vapour bores and groundwater wells were surveyed by a licensed surveyor relative to the Map Grid of Australia (MGA) 1994 and the top of each bore was surveyed relative to Australian Height Datum (AHD) The survey data are included in Appendix F

22 July and 28 August

Notes as determined by the EPA

Table 32 Scope of laboratory testing program

Scope Item Description of works

Soil geotechnical testing

Soil samples from each of three depths within core samples collected during the drilling of groundwater wells MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25 were analysed for particle size distribution (PSD) moisture content including degree of saturation bulk density dry density and specific gravity void ratio and porosity

80607-1 REV1 30102017 PAGE 13

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Scope Item Description of works

Groundwater testing Groundwater samples from all 26 wells were analysed for the COPC detailed in Section 14 As requested by the EPA groundwater samples from selected wells (MW02 MW5 MW8 MW9 MW12 MW17 MW21 MW22 MW23 and MW26) were also analysed for the following major cations and anions (calcium magnesium sodium potassium chloride and alkalinity)

and natural attenuation parameters (carbon dioxide (CO2) sulfate iron manganese nitrate) Additional components reported by the analytical laboratory included nitrite and nitrate + nitrite

Soil vapour testing The WMStrade units deployed during each of Rounds 1 and 2 were analysed for the COPC detailed in Section 14 The soil vapour (summa canister) samples were analysed for the COPC detailed in Section 14 as well as 2-propanol and general gases (helium hydrogen oxygen nitrogen methane carbon dioxide ethane propane butane iso-butane pentane iso-pentane hexane argon carbon monoxide and ethylene)

Notes Specific sample depths are detailed in the relevant laboratory reports in Appendix G also known as isopropyl alcohol isopropanol or IPA

33 Data interpretation

Following the receipt and collation of the field and laboratory data hydrogeological (fate and transport) and VIRA modelling (refer to Sections 8 and 9 respectively) were undertaken to enable an assessment of risk and to refine the CSM (Section 10)

PAGE 14 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

4 METHODOLOGY

41 Field methodologies

Prior to the commencement of the field investigations a site specific Health and Safety Plan (HSP) including Safe Work Method Statements (SWMS) and a Job Hazard Analysis (JHA) was prepared ndash all personnel working at the site were required to read understand sign and conform to the HSP

Each proposed drilling location was cleared of underground services by a professional service location company (Pipeline Technologies) using conventional (electronic) service detection methods as well as ground penetrating radar (GPR) Where underground or overhead services were present andor deemed to be a potential safety risk during drilling activities the drill location was moved to an area considered by the Fyfe representative and service locator to be safe All changes to drilling locations were notified to EPA and recorded on a site plan for future reference

Given that works were undertaken within suburban streets Fyfe employed the services of a qualified traffic management company (Altus Traffic) during drilling activities in order to ensure safety for pedestrians and road users minimal disruption to traffic flow and the provision of a safe working environment

Field methodologies as detailed in Table 41 were undertaken in accordance with Fyfersquos standard operating procedures (SOPs) Relevant field sampling sheets are included in Appendices F (groundwater) and G (soil vapour ndash combined field sampling sheets and chain of custody (COC) documents) and borehole log reports are presented in Appendices H (groundwater) I (WMStrade) and J (soil vapour)

Table 41 Summary of field methodologies

Activity Details

Passive soil bore sampling The soil bores used to deploy the WMStrade units were hand augered by personnel from Fyfe and Aussie Probe to a depth of 1 m BGL SGS Australia (SGS) personnel suspended each WMStrade unit into its respective borehole from a string The hole was then sealed with an expandable foam plug inside a polyethylene sleeve and the string suspending the sampler was connected to a temporary plastic cap at the ground surface The Round 1 WMStrade units were deployed for periods of between six and seven days whereas the Round 2 WMStrade units were all deployed for six days Following retrieval by SGS each WMStrade unit was placed into a sealed glass vial and a labelled foil bag The WMStrade units did not require chilling during transport to the analytical laboratory Borehole log reports are included in Appendix I whereas combined field sampling sheets and COC documents are presented in Appendix G

80607-1 REV1 30102017 PAGE 15

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Activity Details

Groundwater well Groundwater wells were drilled by WB Drilling using a combination of hand augering installation mechanical pushtube and solid auger techniques

Following the completion of drilling each borehole was fitted with 50 mm class 18 uPVC casing with a basal 6 m long section of slotted well screen A filter pack comprising clean graded sands of suitable size to provide sufficient inflow of groundwater was installed within the annular space between the borehole and the well casing and extended from the base of the screened interval to approximately 1 m above the termination of the slotted casing A 1 m long bentonite collar comprising pelleted or granulated bentonite was placed above the filter pack to prevent water seepage downward along the well casing or borehole from ground surface Each well was grouted up to surface level and fitted with a (lockable) steel gatic cover the latter flush mounted to prevent tripping andor other hazards Groundwater well log reports are included in Appendix H

Soil logging and Soil logging was undertaken in general accordance with the ASC NEPM (1999) which geotechnical sampling endorses AS1726-1993 In addition to the requirements of AS1726-1993 particular

attention was paid during logging to any lithological variations such as sandgravel lenses or secondary porosity (such as clay fracturing) which may act as potential preferential pathways for contaminant vapourgroundwater migration through the sub-surface as well as the presence of fill material andor any olfactory or visual evidence of contamination Soil descriptions have been included on the logs in Appendices H to J Cores for geotechnical analysis were collected using push tube sampling methodologies to obtain undisturbed samples Section(s) of core to be tested were retained (intact) within the pushtube liners and capped at each end for storage and transport to the analytical laboratory

Field screening of soils Field screening of individual soil layers was undertaken at the majority of the drilling locations and involved the use of a photoionisation (PID) unit fitted with an 117 eV lamp (ie as considered suitable for the detection of CHC) The PID unit was calibrated by the hire company prior to delivery and was checked on a daily basis against an isobutylene calibration gas of known concentration Field screen samples were collected with care to ensure that each sample was representative of the soil stratum from which it was collected and experienced minimal loss of volatile compounds The soil material was placed immediately into a zip lock bag and sealed ensuring the bag was half filled (ie such that the volume ratio of soil to air was equal) Soil clumps within the bag were manually broken up and the bag was left to rest for a minimum of five minutes but no longer than 20 minutes Prior to testing the bag was shaken vigorously to release any vapours within the soil To test the tip of the PID probe was inserted into the bag and the maximum volatile organic compound (VOC) reading recorded after a nominal 10 second period or when the reading had peaked Results were recorded on the appropriate bore log sheets presented in Appendices H to J

Groundwater well Following installation the wells were developed by purging a minimum of four well development volumes (ie until stable parameters were obtained andor until the well purged dry) from

the casing with a steel bailer andor twister pump to ensure hydraulic connectivity with the aquifer formation

Groundwater gauging Groundwater levels in the newly installed and existing monitoring wells located across the Thebarton EPA Assessment Area were gauged using an interface probe prior to the commencement of the groundwater sampling program All monitoring wells were gauged for SWL the potential presence of NAPL and the total well depth Groundwater field gauging results are presented in Appendix E

PAGE 16 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Activity Details

Groundwater sampling The majority of the wells were sampled using low flow (micropurge) techniques Where recovery was particularly low (ie MW4 MW8 MW15 MW18 MW19 and MW24) and unsuitable for low flow (micropurge) sampling the original sampling technique was abandoned and a HydraSleeveTM (no purge) methodology was used instead Groundwater samples were collected in laboratory-supplied screw top bottles containing appropriate preservative (if required) with no headspace allowed Samples were chilled during storage and transport to the analytical laboratory Disposable nitrile gloves worn by field personnel were changed prior to the collection of each sample Samples for metals (ie iron manganese) analysis were filtered in the field using 045 microm filters Groundwater field sampling sheets are presented in Appendix E

Low Flow Methodology The low flow sampling technique involved the following the pump was placed close to the bottom of the screened interval the flow rate (up to 05 Lmin) was regulated to maintain an acceptable level of

drawdown with minimal fluctuation of the dynamic water level during pumping and sampling

groundwater drawdown was monitored constantly during purging and sampling using an interface probe

water quality parameters were considered to have stabilised when the following ranges were recorded over three consecutive readings ndash electrical conductivity plusmn 5 ndash pH plusmn 01 ndash temperature plusmn 02degC ndash dissolved oxygen plusmn 10 ndash redox potential plusmn 10 mV

the stabilisation parameters were recorded on field logging sheets after every one litre of groundwater purged using a calibrated water quality meter and a flow cell suspended in a bucket with litre intervals marked and

samples were collected once three consecutive stabilisation parameters were recorded and a volume of between 28 and 6 litres was purged prior to sampling

HydraSleeveTM Methodology The HydraSleeveTM sampling technique involved attaching a stainless steel weight to the bottom and a wire tether clip to the throat of the HydraSleeveTM before lowering it into the water column to the desired depth and allowing it to fill with groundwater After a minimum period of 24 hours the HydraSleeveTM was quickly and smoothly withdrawn from the well and the contents were transferred into the sample containers Water quality parameters were measured after samples were decanted ndash either within the water remaining in the HydraSleeveTM or within a grab sample collected using a disposable bailer

Hydraulic testing Rising and falling head permeability (ldquoslugrdquo) tests were undertaken to estimate the hydraulic conductivity (K) of the aquifer within various parts of the Thebarton EPA Assessment Area The falling-head tests were initiated by quickly inserting a 1285 m long and 36 mm diameter solid PVC cylinder (slug) into the water column at each well to produce a sufficient sudden rise in the water level The subsequent ldquofallrdquo back to the static water level (recovery) was measured and recorded automatically and in real-time using a

80607-1 REV1 30102017 PAGE 17

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Activity Details

pressure transducerdata logger programmed to record water levels at a one second interval After static water level conditions returned in the well the rising-head test was initiated by quickly removing the slug from the well to create a sudden drop in the water column height As with the falling-head test the rise of the water level back to a static condition (recovery) was automatically recorded

Soil vapour bore Soil vapour bores were drilled by Aussie Probe using a combination of hand augering and installation mechanical pushtube techniques

Within each 3 m deep soil vapour bore teflon tubing attached to a soil vapour probe was inserted to the base of the hole which had been prefilled with approximately 005 m of clean filter pack sand An additional 045 m of sand (ie approximately 05 m in total) was then added to the hole and topped by a bentonite plug seal of approximately 05 m thickness A second soil vapour probe was installed at a depth of about 1 m within a 05 m sand pack which was overlain by bentonite to a depth of about 02 to 03 m BGL The two 1 m deep soil vapour bores were installed in a similar manner with a sand pack extending from the base to about 05 to 06 m BGL overlain by a bentonite plug to 03 m BGL Each installation was completed with grout to surface and topped with a standard flush-mounted gatic cover Soil vapour bore log reports are included in Appendix J

Soil vapour sampling All soil vapour sampling works were undertaken by SGS using suitably trained and experienced personnel ndash SGS holds National Association of Testing Authorities (NATA) accreditation for all soil vapour sampling and laboratory analytical works Combined field sampling sheets and COC documents are presented in Appendix G Soil vapour samples were collected using summa canisters and analysed using the US EPA (1999) TO-15 method Sampling involved the connection of a passivated 1 L stainless steel canister to the teflon tubing extending from the soil vapour probe and the use of a soil gas sampling train to restrict flow to a maximum rate of 200 mLmin Canister vacuum pressure was monitored during sampling to enable calculation of the volume of sample drawn into the canister ndash the small amount of vacuum left in the canister at the end of the sampling procedure was measured in the laboratory to check if any leaks occurred during transit (refer to further discussion in Table 52) A shroud was set up around the sampling point and tracer chemicals were introduced at high concentrations by flooding the shroud with helium and placing a cloth soaked with IPA into the shroud Each canister was cleaned and certified by SGS prior to use (refer to Appendix G) and backshyup coconut shell carbon sorbent tube samples were also collected (but not analysed) Summa canisters did not require chilling during transport to the analytical laboratory

Waste disposal Waste water and surplus soil corescuttings were stored together within 205 litre drums in the rear car park of a commercialindustrial property at 19-21 James Congdon Drive (as organised by the EPA) prior to removaldisposal by a licensed waste removal company (Cleanaway) Analytical results pertaining to the soils were forwarded to the licensed receiving facility and all of the soil was classified as lsquoWaste Fillrsquo in accordance with the Environment Protection Regulations 2009 The waste transport certificates are included in Appendix K

PAGE 18 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

42 Laboratory analysis

The following laboratories were used for the analysis of the environmental samples

complete soil cores for geotechnical sample analysis were forwarded to SMS Geotechnical

primary groundwater samples collected by Fyfe were analysed at the SGS laboratory whereas secondary groundwater samples were forwarded to EurofinsMGT and

soil vapour (including WMStrade) samples collected by SGS were analysed at their laboratory

80607-1 REV1 30102017 PAGE 19

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

5 QUALITY ASSURANCE AND QUALITY CONTROL

Data quality is typically discussed in terms of the DQIs presented in Table 22 ndash ie completeness comparability representativeness precision and accuracy In order to assess the quality of the data collected during the Fyfe investigation program against these DQIs specific QAQC procedures were implemented during both the field sampling and laboratory analysis programs as detailed in the following sections

51 Field QAQC

Field QA procedures undertaken during the recent investigations included the collection of the following QC samples aimed at assessing possible errors associated with cross contamination as well as inconsistencies in sampling andor laboratory analytical techniques

intra-laboratory duplicate (duplicate) samples submitted to the same (primary laboratory) to assess variation in analyte concentrations between samples collected from the same sampling point andor the repeatability (precision) of the analytical procedures

inter-laboratory duplicate (split or triplicate) samples submitted to a second laboratory to check on the analytical proficiency (accuracy) of the results produced by the primary laboratory

equipment rinsate blank samples collected during groundwater sampling only and used to assess cross-contamination that may have occurred from sampling equipment during sampling and

trip blank samples used to assess whether cross-contamination may have occurred between samples during transport

Whereas analyte concentrations within the rinsate and trip blank samples should be below the laboratory limit of reporting (LOR) the inter- and intra-laboratory duplicate sample results are assessed via the calculation of a relative percentage difference (RPD) as follows

(Concentration 1 minus Concentration 2) x 100RPD = (Concentration 1 + Concentration 2) 2

Maximum RPDs of 30 (inorganics) and 50 (organics) are generally considered acceptable with higher RPD values often recorded where concentrations of an analyte approach the laboratory LOR

All field QC sample results are included in the summary data tables in Appendix L

511 Groundwater

Table 51 presents conformance to field QAQC procedures undertaken as part of the groundwater investigations

80607-1 REV1 30102017 PAGE 21

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Table 51 Field QAQC procedures ndash Groundwater

QAQC Item Detail

Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) AustralianNew Zealand standards ASNZS 566711998 and ASNZS 5667111998 SA EPA (2007) and Fyfe SOPs Details are provided in Table 41

Calibration of field equipment

Documentation regarding the calibration of field equipment is included in Appendix M

Decontamination of All disposable equipment (tubing pump bladders plastic bailers bailer cord and equipment HydraSleeveTM units) were replaced between wells Re-usable equipment (micropurge pump

interface probe and HydraSleeveTM weights) was decontaminated between sampling locations using potable water and Decon 90trade phosphate free detergent

Sample preservation and storage

Samples were kept in laboratory supplied containers in a portable chilled insulated box (esky) prior to and during transport to the laboratory

Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

Duplicate samples Two intra-laboratory and two inter-laboratory duplicate samples were analysed for CHC with respect to 26 primary groundwater samples ndash thereby constituting an overall ratio of approximately one duplicate per 65 primary samples (or 15) compared to a generally acceptable ratio of 110 samples (or 10) One intra-laboratory and one inter-laboratory duplicate sample were analysed for the remaining parameters with respect to 10 primary groundwater samples ndash thereby constituting an overall ratio of one duplicate per five primary samples (or 20) compared to a generally acceptable ratio of 110 samples (or 10) Intra- and inter-laboratory duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within the acceptable range with the exception of the following intra-laboratory duplicate sample pair MW9QW1 TCE (67) nitrate (147) and inter-laboratory duplicate sample pair MW9QW2 total CO2 (59) iron (190)

manganese (183) potassium (64) nitrate (194) The elevated RPD for TCE in the intra-laboratory duplicate sample pair is considered to be related to the low concentration detected and does not alter the interpretation of the data The other RPD exceedances are not considered significant (ie in terms of overall data interpretation) as they were not obtained for identified COPC (as defined in Section 14)

Rinsate blank samples Six equipment rinsate blank samples (one for each day of sampling) were collected from either the pump housing or a new HydraSleevetrade (final day of sampling only) and analysed for CHC to confirm the effectiveness of the decontamination procedures and the cleanliness of disposable equipment The analytical results obtained for the rinsate blank samples were all below the laboratory LOR thereby indicating that decontamination practices during the groundwater sampling program were acceptable and that no contamination was introduced by the use of the HydraSleevestrade

Trip blank samples Six trip blank samples were included within containers (eskies) of sample bottles provided by the analytical laboratory and returned to the analytical laboratory All of the trip blank samples were analysed for CHC With the exception of TB187 which contained 1 microgL TCE the analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was limited impact on sample quality during storage or transport of the samples to the analytical laboratory

PAGE 22 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Notes No duplicate QC samples were collected during the use of the HydraSleeveTM sampling technique as detailed in ANZECCARMCANZ (2000a) at least 5 (ie 120) duplicate samples should be analysed ndash the generally accepted industry standard however is 10 (110) including 5 intra-laboratory and 5 inter-laboratory duplicates

512 Soil vapour

Tables 52 presents conformance to field QAQC procedures undertaken as part of the soil vapour (passive and active) investigations

Table 52 Field QAQC procedures ndash Soil vapour

QAQC Item Detail

Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) as well as ASTM (2001 2006) ITRC (2007) CRC CARE (2013) guidance and Fyfe SOPs Details are included in Table 41 and Appendix G (ie SGS sampling methodology sheet) During the use of summa canisters to sample the soil vapour bores leak testing was undertaken (as described in Table 41) Although small leaks or ambient drawdown appear to have occurred with respect to samples SV11_10m (003 helium) SV13_10m (003 helium) and SV1_10m (360 microgm3 IPA) ITRC (2007) and NJDEP (2013) state that ge 5 helium andor gt10 mgm3 IPA are required to be indicative of a significant leak or substantial ambient drawdown Given that the leaks were relatively small (ie 06 (helium) and 36 (IPA) of the levels considered indicative of a significant leak) the data from these bores were still considered to be valid ndash refer to SGS correspondence in Appendix G As detailed in Table 41 a small amount of vacuum was generally left in each summa canister at the end of the sampling procedure and was measured in the laboratory to check if any leaks had occurred during transit However samples SV11_10m SV12_30m as well as the helium blank were recorded as having zero vacuum upon receipt at the analytical laboratory A query lodged with SGS regarding this issue indicated that whereas the helium blank comprised a grab sample collected into a Tedlar bag directly from the helium cylinder (ie without the use of a gauge) the canisters used for samples SV11_10m and SV12_30 were filled during sampling so that there was no remaining vacuum ndash refer to field sampling documentation in Appendix G SGS stated that although it is good practice to have a small amount of vacuum remaining in a canister at the completion of sampling appropriate additional QC measures were employed and the absence of other common background VOCs (eg petroleum hydrocarbons) upon sample testing indicated that leakage had not occurred during transit In addition all canisters are fitted with quick connect one-way valves that are closed upon removal from the sampling train and canistersfittings are leak checked prior to leaving the laboratory and again in the field to ensure that they are leak free Refer to SGS correspondence in Appendix G The presence of detectable IPA (120 microgm3) and TCE (48 microgm3) in the helium blank was also queried with SGS who stated that this (ie variability in the quality of the high purity helium gas used) is not an uncommon occurrence The reason for collecting a helium blank sample is to identify any impurities present in the helium gas so that if a leak does occur during sampling it is possible to determine whether any target compounds could be introduced into the sample train Although a target compound (ie TCE) was detected in the blank the concentration is minor and even if a leak had occurred during sampling (of which there was no evidence) it would not have affected the overall results and data interpretation The presence of IPA in the helium blank is

80607-1 REV1 30102017 PAGE 23

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

QAQC Item Detail

suspected by SGS of having resulted from a handling issue in the field ndash ie sub-sampling from the helium cylinder (ie into a summa canister via a flex foil bag) in the vicinity of the high concentrations of IPA being used for leak detection Refer to SGS correspondence in Appendix G

Sample preservation and storage

Following collection the WMStrade units were placed into individual glass vials which were sealed and placed into foil bags for transport to the analytical laboratory at ambient temperature Summa canisters were stored in specially constructed cases during transport to the analytical laboratory at ambient temperature

Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

QC samples ndash WMStrade sampling

During the first round of passive soil vapour sampling three additional WMStrade units were deployed in soil bores drilled adjacent to WMS 22 WMS 25 and WMS 28 to act as duplicate QC samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 8) Two trip blank samples were also included with samples transported from and to the analytical laboratory All of the QC samples were analysed by the primary laboratory Intra-duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within an acceptable range (ie lt30) The analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was negligible impact on sample quality during storage or transport of the samples to the analytical laboratory

QC samples ndash soil vapour bore sampling

Two intra-laboratory duplicate QC samples were analysed for CHC and general gases with respect to 24 primary soil vapour samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 83) compared to an acceptable ratio of 110 samples (or 10) Intra-laboratory duplicate RPDs were calculated where both samples had a reported concentration above the laboratory LOR All calculated RPDs for CHC and general gases were within an acceptable range (ie lt30) The analytical results obtained for the helium shroud (Tedlar bags) helium blank and IPA shroud (carbon tube) samples were all considered to be satisfactory

Notes The American Society for Testing and Materials (ASTM) is an internationally recognised source of testing methods Although Appendix J of CRC CARE (2013) stipulates a 110 duplicate sampling ratio for active vapour sampling a specific ratio is not stipulated for passive vapour sampling

52 Laboratory QAQC

Laboratory QA procedures generally include the performance of a number of internal checks of data precision and accuracy that are aimed at assessing possible errors associated with sample preparation and analytical techniques Specific types of QC samples analysed by laboratories and the relevant acceptance criteria are as follows

PAGE 24 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

internal laboratory replicate samples maximum RPD values of 20 to 50 although this varies depending on laboratory LOR

spike recoveries results between 70 and 130 and

laboratory controlmethod blanks results below the laboratory LOR

Table 53 presents conformance to laboratory QAQC procedures undertaken as part of the overall investigation program

Table 53 Laboratory QAQC procedures

QAQC Item Detail

Samples analysed and Samples were generally analysed within specified holding times ndash with the exception extracted within relevant of the following groundwater samples holding times SGS report no ME303457 nitrate was analysed two days late in some samples

(MW5 MW17 MW26) SGS report no ME303475 nitrate was analysed one day late in all samples and EurofinsMGT report no 555810-W total CO2 was analysed five days late None of these holding time exceedances are considered to be significant with respect to the interpretation of the CHC data the determination of potential human healthenvironmental risks andor the determination of natural attenuation

Laboratories used and The laboratories used (SGS Eurofins MGT and SMS Geotechnical) were NATA NATA accreditation accredited for the majority of the analyses undertaken

The exception was SMS Geotechnical which was not NATA accredited for the calculations undertaken to derive some of the data ndash this is the case however for all geotechnical laboratories

Appropriate analytical methodologies used

Refer to the laboratory reports in Appendix G

Laboratory limit of The laboratory LOR is the minimum concentration of an analyte (substance) that can reporting (LOR) be measured with a high degree of confidence that the analyte is present at or above

that concentration The LOR are presented in the laboratory certificates of analysis (Appendix G) and are considered to be generally appropriate (ie below the adopted assessment criteria ndash refer to Section 62) ndash the following exceptions in soil vapour (ie considered to be due to interference associated with elevated concentrations of other compounds ndash refer to SGS correspondence in Appendix G) are discussed further in Table 101 VC in all of the WMStrade samples relative to the ASC NEPM (1999) interim soil

vapour health investigation level (HIL) for residential land use cis-12-DCE and VC in two soil vapour bore samples (SV2_30m and SV3_30m)

relative to the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land use and

VC in two soil vapour bore samples (SV3_10m and SV7_30m) relative to the ASC NEPM (1999) interim soil vapour HIL for residential land use

In addition to the above although ultra-trace analysis was requested the laboratory LOR for VC in groundwater (ie 1 microgL) is above the adopted NHMRCMRMMC (2011) potable guideline (ie 03 microgL) ndash refer to Section 612

80607-1 REV1 30102017 PAGE 25

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

QAQC Item Detail

Laboratory internal QC analyses

Results obtained for the laboratory internal QC samples were generally within the acceptable limits of repeatability chemical extraction and detection with the exception of the following SGS report ME303457 matrix spike results for iron were outside normal tolerances

due to the high concentrations of iron in the spiked sample ndash matrix spike results for iron could therefore not be calculated This is not considered to be a significant issue

Full details regarding laboratory QAQC procedures and results are presented in the certified laboratory certificates contained in Appendix G

Notes Since holding times were not specified in the SGS groundwater reports Fyfersquos assessment of holding times has been based on those adopted by EurofinsMGT (ie the secondary laboratory used for groundwater analysis) ie in accordance with Schedule B3 of the ASC NEPM (1999) also referred to as practical quantification limits (PQL)

53 QAQC summary

In summary it is considered that

the field QAQC programs were generally undertaken with regard to relevant legislation standards andor guidelines and were sufficient for obtaining samples that are representative of site conditions and

the overall laboratory QAQC procedures and results were adequate such that the laboratory analytical results obtained are of acceptable quality for addressing the key objectives outlined in Section 15

PAGE 26 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

6 ASSESSMENT CRITERIA

61 Groundwater

611 Beneficial Use Assessment

In accordance with Schedule B6 of the ASC NEPM (1999) and SA EPA (2009) a Beneficial Use Assessment (BUA) was undertaken to assess both the current and realistic future uses of groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area

This was aimed at determining what groundwater uses need to be protected and assessing the risk(s) that groundwater may pose to human health and the environment (refer also to the VIRA in Section 9)

As summarised in Table 61 the potential beneficial uses for groundwater within the Q1 aquifer that have been considered are as follows ndash taking into account the salinity of the groundwater the Environment Protection (Water Quality) Policy 2015 (Water Quality EPP 2015) the DEWNR (2017) WaterConnect database information presented in Section 222 and possible sensitive receptors located within andor within the vicinity of the Thebarton EPA Assessment Area

The salinity of groundwater has been calculated to approximate 1230 to 3620 mgL TDS (refer to Section 7312) According to the Water Quality EPP 2015 the applicable environmental values for groundwater with salinity above 1200 mgL TDS but less than 3000 mgL TDS are irrigation livestock and aquaculture whereas the salinity is considered to be too high for potable use ndash although domestic irrigation is considered to be a potentially realistic use for this area (see below) livestock watering is considered unlikely to be undertaken in such an urban setting and no local water bodies (ie surface or groundwater) have been identified as being used for commercial aquaculture purposes

The DEWNR (2017) WaterConnect database indicates that groundwater within the Q1 aquifer in the Thebarton area is accessed for drainage domestic and industrial purposes ndash domestic groundwater use could include garden irrigation plumbing water andor the filling of swimming pools (ie primary contact recreation) Although domestic groundwater extraction is considered unlikely to include potable use (ie due to its salinity and the availability of a reticulated mains water supply) potential mixing with rain watermains water could render it suitable (ie from a salinity perspective) for drinking

As the closest freshwater surface water body the River Torrens is located approximately 03 km to the east and 07 km to the north and north-west of the northern portion of this area groundwater discharge from the Thebarton EPA Assessment Area into a freshwater aquatic ecosystem is considered possible However as the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area the potential for impact on a freshwater aquatic environment has not been confirmed

80607-1 REV1 30102017 PAGE 27

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Since the closest marine surface water body Gulf St Vincent is located approximately 8 km to the west groundwater discharge from the Thebarton EPA Assessment Area into a marine aquatic ecosystem is not considered to be realistic

Since volatile contaminants have been detected within the Q1 aquifer (refer to Section 7331) a potential vapour flux risk to future site users must be considered

Given the measured depth of the Q1 aquifer beneath the site (ie approximately 1232 to 1585 m BGL ndash refer to Section 7311) it is considered unlikely that direct contact could occur between groundwater and building footingsunderground services

Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area

Environmental Values Beneficial Uses

Water Quality EPP 2015

environmental value

SA EPA (2009) Potential

Beneficial Uses

Beneficial Use Assessment

Considered Applicable

Aquatic Ecosystem

Marine Yes No

Fresh Yes Possibly

Potable - Yes Possibly

Agriculture Irrigation - Yes Yes

Livestock - Yes No

Aquaculture - Yes No

Recreation amp Aesthetics

Primary contact Yes Possibly

Aesthetics Yes Possibly

Industrial - Yes Yes

Human health in non-use scenarios

Vapour flux -

Yes Yes

Buildings and structures

Contact - Yes No

Notes ie for underground waters with a background TDS level of between 1200 and 3000 mgL ndash note that although they are not listed as environmental values of groundwater in Schedule 1(3) of the Water Quality EPP 2015 aquatic ecosystems as well as recreation amp aesthetics are included as environmental values for waters in general in Part 1(6) of the document ie domestic irrigation only

612 Groundwater beneficial use criteria

The health and ecological criteria used for the assessment of the COPC (refer to Section 14) in groundwater have been based on the results of the BUA (Section 611) A summary of the references used to source the groundwater assessment criteria is provided in Table 62

PAGE 28 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Table 62 Sources of adopted groundwater assessment criteria

Beneficial Use Reference

Freshwater Ecosystems No criteria available for COPC

Potable NHMRCNRMMC (2011) Australian Drinking Water Guidelines

WHO (2017) Guidelines for Drinking-water Quality ndash TCE only

Irrigation No criteria available for COPC

Primary contact recreation (including aesthetics)

NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines but (with the exception of aesthetic guidelines) multiplied by a factor of 10 to take account of accidental ingestion rates as opposed to deliberate ingestion

ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality ndash recreational values (TCE only)

Human health in non-use scenarios ndash vapour flux Refer to the VIRA in Section 9

Notes As there are no specific guidelines for industrial water these values are considered likely to be protective of this additional beneficial use The NHMRC (2008) guidelines are based on drinking water levels and assume a consumption factor of 2 L per day Therefore as recommended in the NHMRC (2008) document potable criteria (ie with the exception of aesthetic criteria) need to be adjusted by a factor of 10 to account for an accidental consumption rate of 100 to 200 ml per day As noted in ANZECCARMCANZ (2000b) although recreational guidelines are protective of ingestion recreational waters should also not contain any chemicals that can cause skin irritation likewise although not specifically addressed by recreational water criteria inhalation may also represent a source of exposure with respect to some (ie volatile) contaminants In the absence of a NHMRCNRMMC (2011) drinking water guideline for TCE the ANZECCARMCANZ (2000b) recreational criterion (30 microgL) has been adopted However if the NHMRC (2008) rule of multiplying potable (healthshybased) guidelines by 10 is applied to the WHO (2017) drinking water guideline of 20 microgL a recreational guideline of 200 microgL would be more applicable

62 Soil vapour

The ASC NEPM (1999) interim soil vapour health investigation levels (HILs) for volatile organic chlorinated compounds (VOCCs) have been adopted (ie in the first instance ndash refer to Section 7331) as Tier 1 soil vapour assessment criteria ndash relevant land use scenarios within the Thebarton EPA Assessment Area include residential (HIL AB) and commercialindustrial (HIL D)

These criteria have been further adjustedappended for the purposes of the VIRA Tier 1 assessment ndash refer to Section 94

80607-1 REV1 30102017 PAGE 29

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

7 RESULTS

71 Surface and sub surface soil conditions

711 Field observations

Groundwater well and soil vapour borehole log reports are included in Appendices H to J and provide details of the soil profile encountered at each sampling location

Where encountered fill materials extended to depths of between 01 and 09 m BGL and included a range of different soil types (sand gravelcrushed rock silt) with only minimal waste inclusions (ie asphalt glass andor metal fragments) identified at some locations

The underlying natural soil profile (encountered to the maximum drill depth of 19 m BGL) was dominated by low to medium plasticity brown to red-brown silty clays and sand claysclayey sands some of which contained sub-angular to rounded gravels that included river pebbles andor comprised fine distinct lenses in places Groundwater well MW17 also included a 15 m thick layer of gravel at depth (ie 12 to 135 m BGL) ndash ie consistent with the depth of groundwater within the Q1 aquifer

During the course of the drilling works no odours or visual indicators of contamination were detected and measured PID readings ranged up to 6 ppm but were generally lt3 ppm

712 Soil geotechnical testing

A table of geotechnical testing results is presented in Appendix L (Table 1) and a copy of the certified laboratory report is included in Appendix G Photographs of soil cores are included in Appendix N

The results were interpreted to indicate the following

The soil core samples submitted for PSD analysis were dominated by clay with lesser amounts of fine to medium gravel andor fine to coarse-grained sand ndash all samples analysed were classified as either CLAY or Sandy CLAY with one sample classified as Clayey SAND The classifications obtained from the laboratory were deemed to be generally consistent with the descriptions on the groundwater well log reports (Appendix H) although the PSD results did not specify silt as a significant secondary component

The moisture content of the analysed soil core samples ranged from 65 to 231 Moisture content with respect to soil type depth and location has been considered in more detail for the purposes of the VIRA (Section 9) The degree of saturation for the analysed soil cores samples ranged from 218 to 964

Measured bulk density ranged from 160 to 212 tm3 specimen dry density from 141 to 184 tm3 and specific gravity from 255 to 281 tm3

The measured void ratio ranged from 043 to 088 whereas porosity ranged from 032 to 047

80607-1 REV1 30102017 PAGE 31

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

72 Waterloo Membrane Samplerstrade A table of WMStrade analytical results (ie from both rounds of sampling) is presented in Appendix L (Table 2) and copies of certified laboratory reports are included in Appendix G8

Of the 41 WMStrade units deployed across the Thebarton EPA Assessment Area during the two sampling rounds 20 returned measurable concentrations of CHC including TCE PCE cis-12-DCE trans-12-DCE andor 11-DCE Although no VC was detected the laboratory LOR in all samples (ie 35 to 50 microgm3) was above the ASC NEPM (1999) soil vapour interim HIL for residential land use (30 microgm3) ndash refer also to Table 53

Detectable COPC concentrations are summarised in Table 71 relative to the ASC NEPM (1999) soil vapour interim HILs along with the closest soil vapour bore andor groundwater monitoring well locations Measured TCE concentrations are detailed on Figure 3

A comparison of the Round 1 and 2 WMStrade results (ie for closely located units9) is presented in Table 72 ndash the results indicate a general order of magnitude correlation of the results for most COPC with the exception of PCE for which lower concentrations were obtained during Round 2 As the Round 1 and 2 WMStrade units were located within different soil bores and deployed at different times some variability in the results is to be expected In addition and as discussed in Section 74 the WMStrade units have been used during this assessment as a (semi-quantitative) screening tool (ie to assist with the siting of the permanent soil vapour bores) with the results obtained from the soil vapour bores considered more representative of actual subsurface conditions

Table 71 Detectable Waterloo Membrane Samplertrade CHC results

Sample ID

Location Closest land uses

CHC concentration (microgm3) Closest soil vapour bore

andor groundwater

well

TCE PCE cis-12shyDCE

trans-12shyDCE

11shyDCE

VC

WMS 1 Goodenough Street CI 35 -

WMS 6 Maria Street CI 32 -

WMS 7 Maria Street CI and R 1900 45 SV2 MW5

WMS 8 Maria Street CI and R 12000 37 SV4

WMS 11 Admella Street CI 71000 260 19 20 36 SV5 MW02

WMS 14 George Street CI 46000 45 SV6 MW11

WMS 18 Admella Street CI 4200 34 MW14

WMS 19 Albert Street CI 11000 42 SV10MW15

WMS 21 Chapel Street CI 10 -

WMS 22 Admella Street CI 38 SV9

WMS 24 Chapel Street CI 230 62 10 11 48 MW17

8 Note that the original laboratory report for the Round 1 WMStrade samples was found to be incorrect (ie following receipt of the soil vapour bore and Round 2 WMStrade sample results) and was subsequently re-issued by SGS

9 only two of which were sufficiently co-located for comparative purposes ndash Round 2 locations WMS 39 and WMS 41 were not within the immediate vicinity of Round 1 WMStrade bores (ie the closest Round 1 bores were approximately 30 m away)

PAGE 32 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Sample ID

Location Closest land uses

CHC concentration (microgm3) Closest soil vapour bore

andor groundwater

well

TCE PCE cis-12shyDCE

trans-12shyDCE

11shyDCE

VC

WMS 25 Albert Street CI and R 1400 20 MW17

WMS 27 Light Terrace CI 64 62 SV11 MW19

WMS 32 Holland Street R 16 -

WMS 34 James Street R 11 -

WMS 37 Dew Street R 44 -

WMS 38 Maria Street CI and R 13000 56 SV2 MW5

WMS 39 Maria Street CI and R 1300 SV4

WMS 40 Admella Street CI 110000 97 SV5 MW02

WMS 41 George Street CI 18000 10 SV7 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform (up to 530 microgm3) was also detected in WMS 8 WMS 11 WMS 14 WMS 16 WMS 18 WMS 19 WM 25 WMS 33 WMS 40 and WMS 41 interim soil vapour health investigation level (HIL)

Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units

Bore ID

Depth (m)

Location CHC concentration (microgm3)

TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

WMS 8 10 Maria Street 12000 37 lt95 lt99 lt22 lt36

WMS 38 13000 56 lt11 lt11 lt25 lt41

Relative percentage difference 8 147 - - - -

WMS 11 10 Admella Street 71000 260 19 20 36 lt37

WMS 40 110000 97 lt11 lt11 lt25 lt41

Relative percentage difference 43 91 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

80607-1 REV1 30102017 PAGE 33

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

73 Groundwater

731 Field measurements

A table of groundwater field parameters is presented in Appendix L (Table 3) and groundwater field sampling sheets are included in Appendix E

7311 Groundwater elevation and flow direction

The depth to water within the Q1 aquifer beneath the Thebarton EPA Assessment Area on 18 July 2017 ranged from 12323 to 15854 m below top of casing (BTOC)10 and 4469 to 5070 m AHD

Groundwater elevation contours constructed from the July 2017 gauging data indicated that the overall groundwater flow direction within the Q1 aquifer was north-westerly consistent with expected regional groundwater flow The groundwater contours and inferred flow direction are shown on Figure 4

7312 Field parameters

As detailed in Table 51 field measurements were recorded during low flow purging (ie prior to micropurge sampling) of monitoring wells and immediately following the collection of HydraSleeveTM samples

The field parameter readings recorded for the monitoring wells immediately prior to (low flow micropurge) and after (HydraSleeveTM) sampling indicated the following (as summarised in Table 3 Appendix L)

groundwater pH ranged from 6 8 to 79 thereby indicating neutral conditions

electrical conductivity (EC) measurements ranged from 189 to 556 mScm and were found to be reasonably consistent across the area thereby indicating that it is underlain by moderately saline water (ie approximating 1230 to 3620 mgL TDS11)

redox concentrations ranged from -20 to 624 mV thereby indicating slightly reducing to strongly oxygenating conditions

measured dissolved oxygen (DO) concentrations ranged from 04 to 78 ppm indicating slightly to highly oxygenated water and

temperature ranged from 173 to 224oC

Observations recorded during sampling indicated that the groundwater was clear to brown and only slightly to moderately turbid at most locations ndash the higher turbidity at MW18 and MW19 (combined with poor recharge) contributed towards the decision to use a HydraSleeveTM sampling method No odours or sheen were observed in any of the wells during gauging or sampling

10 ie approximating m BGL 11 ie calculated by multiplying the field EC data by 065

PAGE 34 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

732 Hydraulic conductivity

Rising and falling head aquifer permeability (ldquoslugrdquo) tests were conducted on 10 groundwater wells (refer to Table 31 and Figure 2) to assess the hydraulic conductivity (K) of the Q1 aquifer

To obtain estimates of near-well horizontal hydraulic conductivity for each well tested the slug test data were analysed by Arcadis using AQTESOLV for Windowstrade (Duffield 2007) following the guidelines presented in Butler (1998) ndash normalised displacement data collected from each test are plotted against time in Appendix A of the Arcadis report (refer to Appendix O) Since only one set of tests were performed at each well the reproducibility of the results as well as the dependence of the results on the initial displacement could not be verified or demonstrated As such multiple relevant and applicable solutions were applied to each test to account for that uncertainty (ie to ensure consistency of normalised response at each well regardless of initial displacement)

Table 73 presents a summary of the range and average estimated hydraulic conductivity values (and corresponding analytical solutions used) for each well tested The results indicate that hydraulic conductivities ranged from approximately 0073 to 37 mday with an overall average of approximately 1 mday

Table 73 Hydraulic conductivities (rising and falling head tests)

Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

(mday) Hydraulic Conductivity

(mday)

MW02 Falling head 011 to 014 DA CBP HV

012 Rising head 0073 to 015 BR DA

MW3 Falling head 034 to 062 BR DA

047 Rising head 030 to 062 BR DA

MW7 Falling head 075 to 25 BR DA

139 Rising head 055 to 175 BR DA

MW14 Falling head 011 to 021 BR DA

014 Rising head 009 to 015 BR DA

MW17 Falling head 21 to 22 DA KGS

220 Rising head 225 to 244 DA KGS

MW20 Falling head 22 to 37 BR DA HV

256 Rising head 06 to 32 BR DA

MW21 Falling head 073 to 123 BR DA

084 Rising head 054 to 084 BR DA

MW23 Falling head 088 to 162 BR DA

101 Rising head 031 to 122 BR DA

80607-1 REV1 30102017 PAGE 35

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

(mday) Hydraulic Conductivity

(mday)

MW25 Falling head 10 to 18 BR DA CBP HV

132 Rising head 049 to 17 BR DA

MW26 Falling head 019 to 036 BR DA

023 Rising head 010 to 029 BR DA

Overall average K (mday) 1028 Notes References BR = Bouwer and Rice (1976) CBP = Cooper et al (1967) DA = Dagan (1978) HV = Hvorslev (1951) KGS = Hyder et al (1994)

The monitoring wells that exhibited lower permeabilities (ie MW02 MW3 MW14 and MW26) were noted to be generally located in the up-gradient (south-eastern) portion of the Thebarton EPA Assessment Area whereas monitoring wells showing relatively higher permeabilities (ie MW7 MW17 MW20 MW21 MW23 and MW25) are generally located in the down-gradient (north-western) portion These results were considered by Arcadis to suggest a possible hydrogeologic transition from the south-east to the north-west AQTESOLV solution plots for each analysis are provided as Appendix A of the Arcadis report (Appendix O)

As slug test results can be influenced by a number of factors which are difficult to avoid when performing and analysing slug test results hydraulic conductivity estimates derived from slug tests should be considered to be the lower bound of the hydraulic conductivity of the formation in the vicinity of the well (Butler 1998) However Arcadis also noted that the results obtained for the Thebarton EPA Assessment Area were similar to those reported for other areas of Adelaide with average values of 1 and 27 mday (refer to Appendix O)

The slug test results were used by Arcadis in their groundwater fate and transport model (refer to Section 8)

733 Analytical results

Tables of groundwater analytical results are presented in Appendix L (Tables 4 and 5) and copies of certified laboratory reports are included in Appendix G

7331 Chlorinated hydrocarbon compounds

A table of CHC results is included in Appendix L (Table 4) and a plan showing their distribution in groundwater beneath the Thebarton EPA Assessment Area is included as Figure 5 Detectable CHC concentrations are summarised in Table 74 relative to the adopted potable and primary contact recreation criteria ndash the closest soil vapour bore locations are also detailed

PAGE 36 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Table 74 Detectable groundwater CHC results

Sample ID

Location CHC concentration (microgL) Closest soil vapour bore

TCE PCE cis-12shyDCE

trans-12-DCE

11-DCE VC Carbon tetrachloride

MW02 Admella Street 20000 38 7 15 SV5

MW3 Admella Street 69 SV1

MW5 Maria Street 29000 3 21 2 6 SV2 SV3

MW6 Maria Street 29 SV4

MW9 Albert Street 2 -

MW11 George Street 4900 3 4 1 7 SV6 SV7

MW12 George Street 700 SV8

MW14 Admella Street 1000 4 2 SV9

MW15 Albert Street 180 SV10

MW17 Chapel Street 24 -

MW18 Dew Street 5 -

MW20 Light Terrace 70 SV12

MW21 Light Terrace 23 SV13

MW23 Dew Street 21 -

MW25 Smith Street 2 5 -

MW26 Kintore Street 2 -

Potable 20 50 60 30 03 3

Primary contact recreation

30 500 600 300 30 30

Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Chloroform was also detected in a number of wells (MW02 MW3 MW5 MW8 MW11 MW12 and MW19 to MW25) ndash refer to Table 4 in Appendix L Although no VC was detected the laboratory LOR (1 microgL) exceeded the adopted potable criterion NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from WHO (2017) Guidelines for Drinking-water Quality NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

The results indicate that the highest TCE concentrations (20000 to 29000 microgL) were measured in wells MW02 and MW5 located in the immediate vicinity of the former Austral property and that the TCE plume extends in a general north-westerly direction (ie consistent with the inferred groundwater flow direction

80607-1 REV1 30102017 PAGE 37

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

within the Q1 aquifer) Although lesser concentrations of PCE 12-DCE (cis- andor trans) andor 11-DCE were present in some wells no VC was detected and the main COPC was identified as TCE

A number of wells within the Thebarton EPA Assessment Area contained TCE concentrations that exceeded the adopted potable andor primary contact recreation criteria Although the extent of the TCE plume was not delineated to the north-west (but was delineated in all other directions) with detectable TCE concentrations (ie up to 21 microgL) identified beneath both Smith Street and Dew Street these concentrations were below the adopted primary contact recreation criterion (but not necessarily the adopted potable value ndash ie MW23)

The background well (MW4) located across James Congdon Drive (to the east of the southern portion of the Thebarton EPA Assessment Area) did not contain any measurable CHC concentrations

7332 Other measured groundwater parameters

Major cations and anions

The laboratory results obtained for the remaining groundwater analytes are summarised in Appendix L (Table 5)

The groundwater ionic data obtained from selected wells across the Thebarton EPA Assessment Area are graphically represented on a Piper diagram in Figure 71 The results indicate a relatively consistent groundwater composition across the area thereby indicating that the groundwater sampled from these wells is derived from a single aquifer Ionic charge balance ranged from 32 to 22 with the highest value (22) calculated for MW12 indicating that additional anions (ie not measured as part of this study) could be present

PAGE 38 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Figure 71 Piper diagram

Natural attenuation parameters

With respect to the measured natural attenuation parameters (ie DO nitrate iron sulfate CO2 and manganese) the following wells were selected based on their locations relative to the inferred extent of the CHC plume

MW26 located on Kintore Street to the south (and hydraulically up-gradient) of the former Austral property (ie the suspected source site)

MW02 and MW5 located within the immediate vicinity of the former Austral property and the area of maximum CHC contamination

MW9 MW12 and MW17 located on Albert Street George Street and Chapel Street respectively to the north-west (and hydraulically down-gradient) of the former Austral property

80607-1 REV1 30102017 PAGE 39

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

MW21 and MW22 located on Light Terrace and Cawthorne Street respectively to the northshywestnorth-north-west (and further hydraulically down-gradient) of the former Austral property and

MW8 and MW23 located on Smith Street and Dew Street respectively representing the furthest wells to the northnorth-west of the former Austral property

According to Wiedemeier et al (1998) the most important process in the degradation of CHC is the process of reductive dechlorination Although daughter products of TCE (ie 12-DCE) are present in groundwater (and soil vapour) at scattered locations within the Thebarton EPA Assessment Area they are not considered indicative of substantial breakdown of TCE ndash refer also to the Arcadis report in Appendix O as summarised in Section 8 In addition the analysis of the natural attenuation parameters data constituting physical and chemical indicators of biodegradation processes has not provided a definitive secondary line of evidence

74 Soil vapour bores A table of soil vapour bore analytical results is presented in Appendix L (Table 6) and a copy of the certified laboratory report is included in Appendix G

Of the soil vapour bores installed to 10 andor 30 m BGL within the Thebarton EPA Assessment Area the majority (ie with the exception of the 10 m deep bores installed as SV11 and SV13 and located on Light Terrace) returned measurable concentrations of CHC dominated by TCE and to a lesser extent (and only at some locations) PCE Detectable soil vapour CHC concentrations are summarised in Table 75 whereas CHC concentrations and inferred soil vapour TCE concentration contours are detailed on Figures 6 (1 m BGL) and 7 (3 m BGL)

The TCE results which have been used to predict indoor air concentrations as part of the VIRA (refer to Section 9) suggest the following

the highest concentration (1000000 microgL) was detected at 3 m BGL in soil vapour bore SV3 located in the vicinity of residential and commercialindustrial properties (including the former Austral property) on Maria Street

where nested wells were tested soil vapour CHC concentrations were higher at depth consistent with a groundwater source

TCE PCE and 11-DCE are all assumed to represent primary contaminants with 12-DCE representing a break-down product of TCE andor PCE

although no VC was detected the laboratory LOR in some samples (ie up to 490 microgm3 in samples with the highest measured TCE concentrations) was above the ASC NEPM (1999) interim soil vapour HIL for residential land use (30 microgm3) ndash refer to Table 53 and

although the extent of the soil vapour plume has apparently not been delineated (ie in any direction) by the existing soil vapour bores it extends in a north-westerly direction (and hydraulically down-

PAGE 40 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

gradient) from the suspected source site (ie the former Austral property) and corresponds well with the groundwater TCE plume (refer to Figure 5)

A comparison of the results obtained for the WMStrade units (WMS 38 to WMS 41) deployed during the second round of sampling and the closest soil vapour bore data (10 m BGL) is provided in Table 76 Although the results indicate good correlation for TCE and PCE in SV5WMS 40 as well as TCE in SV7WMS 41 the remaining results were more variable ndash this supports the use of the WMStrade units as an initial (semishyquantitative) screening tool with follow-up soil vapour bore data considered to provide more quantitative results

Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area

Bore ID

Depth (m)

Location Closest land

uses

CHC concentration (microgm3)

TCE PCE cis-12shyDCE

trans-12-DCE

11-DCE VC

SV1 10 Admella Street CI and R 6300 78

30 21000 21

SV2 10 Maria Street CI and R 51000 39 21 39

30 940000

SV3 10 Maria Street CI and R 210000 6500 5900

30 1000000 15000 14000

SV4 10 Maria Street CI and R 17000 31

30 43000 90 30

SV5 10 Admella Street CI 100000 84

30 160000 310 20 33

SV6 10 George Street CI 22000 12

30 150000 56

SV7 10 George Street CI 22000 19

30 110000

SV8 10 George Street CI 2300 62

30 14000 19

SV9 10 Chapel Street CI 170

30 260

SV10 10 Albert Street CI 93

30 51

SV12 10 Light Terrace CI 16

30 55 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

Notes Shaded cells indicate concentrations were below the laboratory LOR

80607-1 REV1 30102017 PAGE 41

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Where (field andor laboratory) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform was also detected in a number of samplesinterim soil vapour health investigation level (HIL)

Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores

Bore ID

Depth (m)

Location CHC concentration (microgm3)

TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

SV2 10 Maria Street 51000 39 21 lt13 39 lt89

WMS 38 13000 56 lt11 lt11 lt25 lt41

Relative percentage difference 119 150 - - - -

SV4 10 Maria Street 17000 31 lt18 lt14 lt14 lt92

WMS 39 1300 lt52 lt11 lt11 lt25 lt41

Relative percentage difference 172 - - - - -

SV5 10 Admella Street 100000 84 lt44 lt33 lt33 lt22

WMS 40 110000 97 lt11 lt11 lt25 lt41

Relative percentage difference 95 14 - - - -

SV7 10 George Street 22000 19 lt37 lt27 lt27 lt18

WMS 41 18000 10 lt11 lt11 lt25 lt41

Relative percentage difference 20 62 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

PAGE 42 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

8 GROUNDWATER FATE AND TRANSPORT MODELLING

Arcadis were commissioned by Fyfe to undertake preliminary fate and transport modelling of the groundwater CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained groundwater data The Arcadis report is included as Appendix O

The aim of the modelling was to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton area in order that potential future groundwater restrictions could be applied by the EPA (ie via the potential future definition of a GPA) to protect human health

81 Groundwater flow modelling

The MODFLOW code a publicly-available groundwater flow simulation program developed by the United States Geological Survey (USGS) as described by McDonald and Harbaugh (1988) was used to construct a groundwater flow model It was developed for a horizontal area of approximately 25 km2 (ie to minimise possible boundary effects within the assessment area itself12) and was rotated 45deg counter-clockwise to align with the prevailing (north-westerly) groundwater flow direction The model extended approximately 23 km in a south-east to north-west direction and approximately 11 km in a south-west to north-east direction (ie perpendicular to groundwater flow) Whereas a 4 m grid spacing was used within the area of the plume and its migration pathway (ie to enhance model accuracy and precision) a broader 15 m grid was adopted outside the specific area of interest Vertically the model adopted a single 20 m thick layer as representative of the hydrostratigraphy of the Q1 aquifer sediments beneath the area but it was noted that only the bottom portion (ie few metres) of this model layer are actually saturated and therefore active in the model

An informal sensitivity analysis performed as part of the model calibration process indicated that the model was most sensitive to changes in hydraulic conductivity and recharge ndash this was not unexpected given the relatively flat hydraulic gradient and relatively narrow range of estimated values for both model parameters (ie based on reasonably low uncertainty) The final calibrated value for aquifer recharge adopted in the model was 295 mmyear consistent with results reported for nearby sites as well as regional estimates Likewise the final calibrated hydraulic conductivity values for the up-gradient (06 mday) and down-gradient (2 mday) zones were consistent with both the site-specific slug test data and results obtained for other nearby EPA assessment areas The final calibrated down-gradient constant head elevation was 15 m AHD It was concluded by Arcadis that the groundwater flow model was well calibrated and could therefore serve as an appropriate basis for the development of a site-specific solute transport model

82 Solute transport modelling

A site-specific (three-dimensional) solute transport model using the MT3DMS transport code of Zheng (1990) was developed by Arcadis to predict the fate and transport of groundwater contaminants (specifically

12 Further information regarding boundary effects is provided in the Arcadis report (Appendix O)

80607-1 REV1 30102017 PAGE 43

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

CHC) under current conditions over a period of 100 years This dual-domain mass transport model was used in conjunction with the groundwater flow model developed through the use of MODFLOW (as detailed above) assuming the following

The primary COPC is TCE ndash the initial concentration distribution of TCE in groundwater was based on the recent (July 2017) monitoring data

The age of the groundwater TCE plume was assumed to be up to about 90 years ndash ie based on the history of industrial land use (specifically the former Austral facility) in the area

Although lesser amounts of other CHC are present in groundwater the lack of significant daughter products of TCE has been interpreted to indicate that substantial biodegradation is not occurring (ie as a conservative approach)

Although a CHC source was not explicitly incorporated into the solute transport model the MT3DMS transport code indirectly accounts for on-going contaminant mass contribution to the dissolved-phase plume

The fate and transport of TCE within the area of interest involves the processes of advection adsorption dilution and diffusion ndash however given that recharge via the infiltration of precipitation was considered to be insignificant dilution effects were assumed to be minimal

Two porosity values (ie dual domain) are relevant to the movement of contaminants in the subshysurface with adopted values based on site-specific geology and Payne et al (2008) ndash whereby the two domains are in equilibrium

― mobile porosity that portion of the formation with the highest permeability where advective transport dominates ndash assumed to be 5 (high) 10 (intermediate) or 15 (low) for different mobility transport conditions and

― immobile porosity lower permeability portions of the formation where diffusion is dominant ndash assumed to be 15

As discussed in Section 732 hydraulic conductivity values of 06 mday (south-eastern approximate quarter of the modelling area) and 2 mday (northern approximate three-quarters of the modelling area) were adopted to reflect the hydrogeologic transition (ie from the south-east to the north-west) interpreted from the slug test data

The adopted TCE retardation factor of 147 for intermediate mobility transport conditions was based on the following

― an assumed organic carbon fraction of 01 (US EPA 1996 amp 2009) ndash this was varied to 005 and 2 to assess alternate (ie high versus low) mobility transport conditions

― an assumed organic carbon adsorption co-efficient of 61 Lkg (US EPA 2017a)

PAGE 44 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

― a calculated partition co-efficient of 0061 Lkg ndash this was varied to 129 and 178 Lkg to assess alternate (ie high versus low) mobility transport conditions and

― an average soil bulk density of 192 gcm3 (based on measured geochemical data ndash refer to Table 1 Appendix L)

An optimum mass transfer co-efficient (MTC) was based on simulated flux distribution in the groundwater flow model whereby

― the calculated MTC in the model ranged from approximately 38E-08day-1 to 37E-05 day-1 and

― the average MTC was 185E-05day-1

The site-specific solute transport model was used in predictive mode to assess the long-term (eg 100 year) potential migration of the groundwater TCE plume and to support the EPA in the potential future definition of an appropriate GPA The model was calibrated against the current extent (ie concentrations of TCE above 1 microgL have migrated approximately 500 m from the suspected source site13) and expected age (ie up to about 90 years) of the plume The results indicate that the leading edge of the TCE (ie the 1 microgL contour) is estimated to migrate between approximately 400 and 620 m over a period of 100 years under low to high mobility transport conditions14 with intermediate transport conditions resulting in an estimated migration of 500 m By comparison no significant lateral plume expansion would be expected to occur Figures 5 to 17 of the Arcadis report (Appendix O) show the predicted extent of the TCE plume at 5 10 50 and 100 years under low to high mobility transport conditions

Figure 81 shows the predicted extent of the 1 microgL TCE boundary in 100 years under intermediate transport conditions ndash it is recommended that this information be used to support the EPA in establishing a potential future GPA

The Arcadis report notes that given the available site information (site history potential source area(s) and uncertainty associated with the current plume extent) and degree of model calibration (flow model parameter values are consistent with site-specific data as well as regionalnearby studies while transport parameter values are consistent with literatureindustry standards) the model-predicted migration of approximately 500 m over 100 years is considered to be a reasonable representation of future conditions

Key uncertainties associated with the modelling were identified as including the following

current plume extents (ie down-gradient delineation)

site-specific fraction organic values (or site-specific partition coefficient estimates) and

site-specific porosity estimates

13 although it was noted that there is uncertainty with respect to the current extent of the TCE plume since all three down-gradient monitoring wells (MW18 MW23 and MW25) have TCE concentrations above 1 μgL

14 ie assuming different values for mobileimmobile porosity the TCE distribution (sorption) coefficient and the TCE retardation factor

80607-1 REV1 30102017 PAGE 45

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Lesser uncertainties were considered to include site-specific bulk hydraulic conductivity estimates and determination of the presence or absence of naturally-occurring TCE degradation

Additional site investigation and data collection (eg multi-well pumping tests for bulk hydraulic conductivity estimates site-specific fraction organic carbon andor distribution (sorption) coefficient additional down-gradient plume delineation) would help to further refine the model and increase confidence in the predictive results

Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green) relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple)

PAGE 46 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

9 VAPOUR INTRUSION RISK ASSESSMENT

Arcadis were commissioned by Fyfe to undertake a Vapour Intrusion Risk Assessment (VIRA) of the soil vapour CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained (ie August 2017) permanent soil vapour bore data The Arcadis report is included as Appendix P

91 Objective

The main objective of the VIRA was to evaluate the potential risk to human health from vapour intrusion related to the concentrations of CHC identified in soil vapour within the Thebarton EPA Assessment Area

92 Areas of interest

The following areas of specific interest (ie located within the Thebarton EPA Assessment Area) were identified for the purpose of this VIRA

commercialindustrial properties (assumed slab on grade construction) including the former Austral property (ie the suspected source site) and

residential properties (slab on grade crawl space and basement constructions)

Potential exposure by trenchmaintenanceutility workers has also been considered (qualitatively)

93 Risk assessment approach

The VIRA was conducted in accordance with the ASC NEPM (1999) enHealth (2012a) and other relevant Australian guidance documents as well as guidance documents issued by the US EPA and other international regulatory agencies (where applicable)

The conduct of the risk assessment was based on a multiple lines of evidence approach using the available site-specific information collected as part of the scope of works detailed in Section 32

The following information was used as a basis for the VIRA

CHC including TCE PCE and DCE (11- cis-12- and trans-12-) have been identified within soil vapour andor groundwater within the Thebarton EPA Assessment Area ndash the analytical data indicate that TCE constitutes between about 95 and 100 of the CHC identified in groundwater and soil vapour

TCE has been considered as the risk driver for the VIRA (ie based on its toxicity and concentrations in soil vapour and groundwater) ndash although TCE PCE 12-DCE 11-DCE and VC have all been included as COPC for the Tier 1 screening assessment (Section 94) the Tier 2 assessment (Section 95) has

80607-1 REV1 30102017 PAGE 47

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

concentrated on TCE PCE and 11-DCE (ie due to their presence at concentrations that exceeded the adopted Tier 1 screening criteria)

The CHC identified within the Thebarton EPA Assessment Area are volatile chemicals and could potentially pose a risk to human health via the vapour intrusion pathway Although the source area has yet to be confirmed the CHC concentrations observed in groundwater and soil vapour are considered likely to have originated from the former Austral property (as discussed in Section 12)

The natural soils underlying the fill material (where present) in the Thebarton EPA Assessment Area are typified by the Quaternary age soils and sediments of the Adelaide Plains with the Pooraka Formation and Hindmarsh Clay units considered to dominate the upper soil profile

The soil geotechnical data and soil vapour results collected by Fyfe (as discussed in Sections 712 and 74 respectively) have been used for the VIRA

A two-tier approach was adopted for the VIRA The first tier (herein referred to as the Tier 1 assessment) was conducted by comparing the measured soil vapour TCE concentrations to published guideline values adjusted (conservatively) to account for attenuation from sub-slab soil into indoor air The second tier (herein referred to as the Tier 2 assessment) involved the comparison of predicted indoor air TCE concentrations to adopted indoor air criteria or response levels

94 Tier 1 assessment

As detailed in Section 74 the initial Tier 1 (screening risk) assessment involved comparing measured soil vapour COPC concentrations with the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land uses (refer to Table 74) Given that the development of the interim soil vapour HILs was based on very conservative assumptions the initial Tier 1 assessment provided only a first-pass screening assessment of the data to determine if further risk assessment would be required

The interim soil vapour HILs are applicable for the assessment of soil vapour at 0 to 1 m beneath the floor of a building They were based on adopted toxicity reference values (TRV) and relevant exposure parameters (ie adjusted for different land uses) as well as an assumed soil vapour to indoor air attenuation factor of 01

The soil vapour to indoor air attenuation factor (01) was based on the US EPA (2002) recommended default attenuation factors for the generic screening step of a tiered vapour intrusion assessment process As discussed in the US EPA (2002) document the default attenuation factor of 01 for sub-slab soil vapour was based on a US EPA database of empirical attenuation factors calculated using measurements of indoor air and soil vapours from different sites In 2012 the US EPA provided an updated database which was accompanied by an evaluation and statistical analysis of attenuation factors for volatile CHC in residential buildings US EPA (2012) found the sub-slab to indoor air attenuation factor of 003 to be the 95th percentile In 2015 the revised sub-slab attenuation factor (003) was adopted by the US EPA

PAGE 48 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

The revised sub-slab to indoor air attenuation factor of 003 was adopted to derive modified residential and commercialindustrial soil vapour HILs for the Tier 1 assessment The modified residential soil vapour HILs are presented in Table 91 relative to the maximum CHC concentrations obtained for soil vapour within the Thebarton EPA Assessment Area

The Tier 1 assessment based on a comparison of the COPC concentrations measured in soil vapour at various locations within the Thebarton EPA Assessment Area with the modified residential soil vapour HILs detailed in Table 91 indicated the following

TCE concentrations exceeded the adopted criterion in SV1 to SV9 whereas

the concentrations of PCE and 11-DCE exceeded the adopted criteria in SV3 only

These locations were identified as requiring further assessment (ie Tier 2 VIRA ndash refer to Section 95)15

Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs

Compound ASC NEPM (1999) HIL

(microgm3)

Modified Tier 1 HIL (microgm3)

(AF = 003)

Maximum measured soil vapour concentration (microgm3)

Acceptable

Location 1 m BGL Location 3 m BGL

11-DCE 7000 SV3 5900 SV3 14000 No ndash Tier 2 required

cis-12-DCE 80 265 SV2 21 SV4 30 Yes

trans-12-DCE 80 265 - ND SV5 20 Yes

PCE 2000 6650 SV3 6500 SV3 15000 No ndash Tier 2 required

TCE 20 65 SV3 210000 SV3 100000 0

No ndash Tier 2 required

VC 30 100 - ND - ND Yes Notes Values in bold exceed the modified residential soil vapour HILs cis-12-DCE HIL adopted as surrogate screening criterion based on US EPA (2017b) regional screening level for residential air elevated laboratory LOR (ie above modified Tier 1 HIL) also reported Abbreviations AF = attenuation factor HIL = health investigation level ND = non detect

95 Tier 2 assessment

951 Tier 2 assessment criteria

The Tier 2 VIRA criteria for the residential zone comprise HIL-based residential indoor air criteria for the COPC (refer to Section 94) along with the residential indoor air level response ranges for TCE that were

15 Note that all locations were subjected to the Tier 2 VIRA in this assessment

80607-1 REV1 30102017 PAGE 49

EPA REF 0524111 FINAL REPORT

STAGE 1 ENVIRONMENTAL ASSESSMENT

THEBARTON ASSESSMENT AREA

initially developed by the EPA and SA Health for the EPA Assessment Area at Clovelly Park and Mitchell

Park These screening criteria and indoor air response ranges as detailed in SA EPA (2014) and

reproduced in Figure 91 are now widely adopted in South Australia for the assessment of TCE relating

to indoor air exposure

Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels

Note The no action response level is applicable where a soil vapour concentration is below the laboratory LOR (ie ND or ldquonon-

detectrdquo assumed to be lt01 microgm3)

PAGE 50 80607-1 REV1 | 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

952 Vapour intrusion modelling

For this VIRA exposure point concentrations (EPCs) of COPC in the indoor air of buildings with a slab on grade crawl space or basement construction were estimated using conservative screening assumptions and the Johnson and Ettinger (1991) vapour transport and mixing model (ie the JampE model)

The algorithms applied in the JampE (1991) model are detailed in Appendix A of the Arcadis report whereas the modelling spreadsheets for each scenario are provided in Appendix B ndash the Arcadis report is attached to this report as Appendix P

9521 Input parameters

The input parameters adopted for the vapour intrusion modelling relate to the following

the construction type and details of existing or proposed buildings ndash refer to Table 92 for adopted building input parameters

the nature of the soil profile ndash refer to Table 93 for adopted soil input parameters (0 to 1 m BGL) and

the contaminant source concentrations ndash refer to Table 6 in Appendix L

Table 92 Tier 2 vapour intrusion modelling ndash building input parameters

Parameter Units Adopted value Reference

Residential Commercial industrial

Width of Building cm 1000 2000 Friebel and Nadebaum (2011)

Length of Building cm 1500 2000

Height of Room cm 240 300

Height of crawl space cm 30 - Assumption for crawl space

Attenuation from basement to ground floor air

- 01 01 Friebel and Nadebaum (2011)

Air Exchange Rate (AER)

Indoor per hour 06 083 Friebel and Nadebaum (2011)

Crawl space per hour 06 - Friebel and Nadebaum (2011)

Basement per hour 06 - As per residential (indoor)

Fraction of Cracks in Walls and foundation

- 0001 0001 Friebel and Nadebaum (2011)

Qsoil cm 3s 300 277 Calculated from QsoilQbuilding ratio of 0005 (residential) and 0001 (commercial)

80607-1 REV1 30102017 PAGE 51

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters

Parameter Units Adopted value Reference

Depth cm 100 Depth of shallow soil vapour data

Total porosity - 047 Site specific geotechnical data ndash ie averaged from MW3 and MW11 shallow samples (refer to Table 1 in Appendix L) Air filled porosity - 030

Water filled porosity - 017 Notes ie representing a conservative approach whereby data for the shallow samples with the highest total porosity and lowest degree of saturation (and therefore the highest air filled porosity) have been adopted

The site specific attenuation factors calculated within the vapour intrusion models (Appendix B of the Arcadis report) are summarised in Table 94 These are chemical and depth specific values applicable to each building construction scenario These attenuation factors have been applied to the soil vapour data measured across the Thebarton EPA Assessment Area to calculate indoor air concentrations (residential properties only) in proximity to each soil vapour location ndash for commercialindustrial properties (slab on grade) indoor air concentrations have only been calculated with respect to the soil vapour data obtained for SV3 (ie the soil vapour bore with the highest measured TCE concentrations)

Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air

Scenario Attenuation factor

Residential ndash slab on grade 706 x 10-4

Residential ndash crawl space 209 x 10-3

Residential ndash basement 113 x 10-1

Commercial ndash slab on grade 408 x 10-4

Notes ie soil vapour intrusion to indoor air of residential living spaces refer to Section 953 for a discussion of potential vapour intrusion risks associated with commercialindustrial properties

The chemical parameters of the COPC adopted in the JampE model were updated with data from the chemical database in the Risk Assessment Information System (RAIS 2016) as detailed in Table 95

Table 95 Summary of chemical parameters adopted for vapour intrusion modelling

Chemical Diffusivity in Air Diffusivity in Water Solubility Henryrsquos Law Molecular weight (Dair) Water (Dwater) (S) Constant 25oC (gmol)

(cm2s) (cm2s) (mgL) (unitless)

11-DCE 00863 0000011 2420 107 969

PCE 00505 000000946 206 0724 166

TCE 00687 00000102 1280 0403 131

PAGE 52 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

9522 Predicted indoor air concentrations

Residential The predicted indoor air concentrations for each soil vapour data point as calculated by Arcadis for the three residential building scenarios (ie slab on grade crawl space and basement) are presented in Appendix C of the Arcadis report (included in this report as Appendix P)

Table 96 provides a comparison of predicted indoor air concentrations against the EPA response levels detailed in Section 951 (Figure 91) ndash ie using the 1 m soil vapour data space for slab on grade and crawl space scenarios versus the 3 m soil vapour data for basements

It should be noted that if residential properties within the Thebarton EPA Assessment Area have basements however the vapour intrusion risks will increase whereas slab on grade construction will carry a lesser vapour intrusion risk (as detailed in Table 96)

Commercialindustrial The predicted indoor air concentrations as calculated by Arcadis for a commercialindustrial (ie slab on grade) land use scenario with respect to the soil vapour data obtained for SV3 (ie maximum measured soil vapour concentrations) are as follows

11-DCE 3 microgm3

PCE 19 microgm3 and

TCE 86 microgm3

As these values are not directly comparable to the EPA response levels developed for residential land use further discussion of potential vapour intrusion risks to human health under a commercialindustrial land use

scenario is included in Section 953

As discussed for residential properties the vapour intrusion risks may increase if basements are present

80607-1 REV1 30102017 PAGE 53

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Table 96 Comparison of predicted residential indoor air concentrations with SA EPA response levels

Indoor Air Concentration Ranges (microgmsup3) SA EPA response levels

non-detect No action

gt non-detect to lt2 Validation

2 to lt20 Investigation

20 to lt200 Intervention

ge200 Accelerated Intervention

Soil vapour bore

Sample depth

(m)

Soil vapour TCE concentration

(microgmsup3)

Predicted indoor air concentration (microgmsup3)

Residential scenario

Slab on grade Crawl space Basement

Attenuation factor

7 x 10-4 2 x 10-3 1 x 10-1

SV1 10 5700 4 11

SV1 30 21000 2100

SV2 10 51000 36 102

SV2 30 890000 89000

SV2 (FD) 30 940000 94000

SV3 10 210000 147 420

SV3 30 1000000 100000

SV4 10 17000 12 34

SV4 30 43000 4300

SV5 10 100000 70 200

SV5 30 160000 16000

SV6 10 22000 15 44

SV6 (FD) 10 22000 15 44

SV6 30 150000 15000

SV6 (FD) 30 140000 14000

SV7 10 22000 15 44

SV7 30 110000 11000

SV8 10 2300 2 5

SV8 30 14000 1400

SV9 10 170 012 030

SV9 30 260 26

SV10 10 9 0007 0019

SV10 30 51 51

SV11 10 lt18 - -

SV12 10 16 0011 0032

SV12 30 55 55

SV13 10 lt21 - -

PAGE 54 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Notes With respect to the predicted indoor air CHC concentrations in the Arcadis VIRA report (refer to Appendix P) the results in Table 5 were calculated for SV3 using the unrounded attenuation factors presented in Appendix B (and Table 94 of this report) whereas the TCE indoor air concentrations in Appendix C (as summarised in Table 96) were calculated using rounded attenuation factors ndash this does not change the overall interpretation of the results Abbreviations FD = field duplicate

9523 Sensitivity analysis

Table 97 presents a qualitative sensitivity analysis for some of the input variables used in the modelling ndash it includes the range of practical values for each variable the value used in the risk assessment the relative model sensitivity and the uncertainty associated with the variable

Although Arcadis note that a number of parameters used within the risk assessment have a moderate degree of uncertainty associated with them thereby suggesting that the modelling may be sensitive to changes in these parameters values used to define these parameters were selected to be conservative This is considered to have resulted in an assessment which is expected to be conservative and to over-estimate actual risk

Table 97 Summary of model input parameters subjected to sensitivity analysis

Input Range of values Value adopted Sensitivity of calculated input parameters variable

Soil physical parameters

Total porosity

Varies by soil type generally 03 to 05

047 Site-specific

Indoor air concentrations will decrease with increasing total porosity Moderate sensitivity parameter decreasing by 50 will increase predicted concentration by a factor of 4

Air filled porosity

Varies by soil type generally 015 to 03

03 Site-specific

Indoor air concentrations will increase with increasing air filled porosity Moderate to high sensitivity parameter reduction by 50 decreases concentration by a factor of 10

Water filled porosity

Varies by soil type from 005 (fill or

sand) to 03 (clay)

017 Site-specific

Negligible impact on predicted indoor air concentrations although may decrease with increasing moisture content Very low sensitivity parameter

Building parameters

Air exchange rate (AER)

Varies from 05 hr-1

in smaller buildings to gt2 hr-1

06 hr-1 for residential structures

083 hr-1 for commercial

Indoor air concentrations will decrease with increasing air exchange Moderate sensitivity parameter has linear relationship with predicted concentrations conservative assumptions used

80607-1 REV1 30102017 PAGE 55

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Input Range of values Value adopted Sensitivity of calculated input parameters variable

Advective flow rates

Varies depending on building size and

AER

300 cm3sec Calculated from building AER and

ratio of 0005

Indoor air concentrations will increase with increasing advective flow Low sensitivity parameter particularly within normal range of potential values The assumption that advective flow is occurring into a building at all times is generally conservative for Australian settings Advection is unlikely to occur under a crawl space home and diffusive transport is the dominant transport mechanism

Building size Variable Variable consistent with

Friebel and Nadebaum (2011)

Indoor air concentrations decrease with increasing building volume

Very low sensitivity parameter

9524 Uncertainties

The following uncertainties were identified in the Arcadis report (Appendix P)

Vapour transport modelling

The use of a model to predict the migration of vapour from a sub-surface source to indoor air requires the simplification of many complex processes in the sub-surface as well as the potential for entry and dispersion within a building or outdoor air To address this simplification the vapour models available (and adopted in this assessment) are considered to be conservative such that uncertainties are addressed through the overshyestimation of likely concentrations

It should be noted that the vapour model used is designed to be a first tier screening tool and is considered likely to over-estimate air concentrations due to the incorporation of a number of conservative assumptions including the following

chemical concentrations in soil vapour were assumed to remain constant over the duration of exposure (ie it was assumed that the source was non-depleting and not subject to natural biodegradation processes)

the maximum reported soil vapour concentrations were assumed to be present beneath nearby dwellings and

the occurrence of steady well-mixed vapour dispersion within the enclosed or ambient mixing space

Overall the vapour modelling undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

PAGE 56 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Toxicological Data

In general the available scientific information involves the extrapolation of toxicity information from studies involving experimental laboratory animals with some validation of observable health effects obtained through epidemiological studies

This may introduce two types of uncertainties into the risk assessment as follows

those related to extrapolating from one species to another and

those related to extrapolating from the high exposure doses usually used in experimental animal studies to the lower doses usually estimated for human exposure situations

In order to adjust for these uncertainties toxicity values commonly incorporate safety factors that may vary from 10 to 10000

Overall the toxicological data presented in this assessment are considered to be current and adequate for the assessment of risks to human health associated with potential exposure to the COPC identified The uncertainties inherent in the toxicological values adopted are considered likely to result in an over-estimation of actual risk

953 Potential vapour intrusion risks associated with commercialindustrial properties

An assessment of potential vapour intrusion risks to workers at commercialindustrial properties (slab on grade construction) within the Thebarton EPA Assessment Area was undertaken by Arcadis using the methodology published by US EPA (2009) and incorporated into the ASC NEPM (1999) This approach recommends adjustment of the measured or estimated contaminant concentrations in air to account for site specific exposures by the relevant receptors as follows

Ca ET EF EDECinh = days hours AT 365 24 year day

Where

ECinh = Exposure Adjusted Air Concentration (mgm3) Ca = Chemical Concentration in Air (mgm3) ET = Exposure Time (hoursday) EF = Exposure Frequency (daysyear) ED = Exposure Duration (years) AT = Averaging Time (years)

= 70 years for non-threshold carcinogens = ED for chemicals assessed based on threshold effects

80607-1 REV1 30102017 PAGE 57

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Exposure parameters were selected from Australian sources (enHealth 2012b ASC NEPM 1999) for the receptor groups evaluated or were based on site specific factors Table 98 presents an overview of the parameters used whereas adopted inhalation TRVs are presented in Table 99

Risk was characterised for threshold and non-threshold effects for the COPC ndash spreadsheets presenting the risk calculations are provided in Appendix B of the Arcadis report (as included in Appendix P) For commercialindustrial properties the non-threshold risk level was calculated to be 3 x 10-5 (compared to a target risk level of 1 x 10-5) whereas the threshold risk level was calculated to be 10 (compared to a target risk level of 1) ndash these results indicated a potentially unacceptable vapour intrusion risk to commercialindustrial workers in the vicinity of the maximum soil vapour CHC concentrations (ie at SV3 ndash worst-case scenario based on maximum soil vapour concentrations)

Table 98 Exposure parameters ndash Commercialindustrial workers

Exposure parameter Units Value Reference

Exposure frequency days year 365 ASC NEPM (1999)

Exposure duration years 30 ASC NEPM (1999)

Exposure time indoors hoursday 8 ASC NEPM (1999)

Averaging time

Non-threshold

threshold

Years

years

70

30 ASC NEPM (1999)

Table 99 Adopted inhalation toxicity reference values

COPC Toxicity reference values

Non-threshold (microgm3)

Reference Threshold (microgm3)

Reference

11-DCE NA - 80 ATSDR (1994)

PCE NA - 200 WHO (2006)

TCE 41 US EPA (2011) IRIS 2 US EPA (2011) IRIS Notes Abbreviations NA = not applicable

954 Potential risks to trenchmaintenanceutility workers

Although trenchmaintenanceutility workers may be exposed to soil vapour concentrations as measured at 1 m BGL due to the short-term nature of such works their total intakes of TCE and other CHC will be low Assuming that a trenchmaintenanceutility worker may be exposed to TCE for a limited number of working days throughout the year (eg 20 days of 8 hours duration within an excavation) their intake will be approximately one fiftieth of the intake of a resident (who is assumed to be exposed 21 hours a day for 365 days a year)

PAGE 58 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Therefore the management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air)

96 Conclusions

On the basis of the available data and the assessment presented in the Arcadis VIRA report (Appendix P) the following conclusions were provided

Health risks for residents due to the intrusion of CHC in soil vapour into residential buildings with a slab on grade crawl space or basement construction were calculated to be above the adopted EPA response levels and risks to residents may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

Health risks for commercial workers due to the intrusion of CHC in soil vapour into buildings with a slab on grade construction were calculated to be above the adopted target risk levels and risks to workers may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

In the absence of specific information regarding building construction within the Thebarton EPA Assessment Area the predicted indoor air concentrations calculated from the 1 m BGL soil vapour data for a residential crawl space scenario are summarised in Table 910

Table 910 Summary of properties with predicted indoor air concentrations (residential crawl space) above adopted EPA response levels

EPA response level No of residential properties affected Indoor air concentration (microgm3) Response

non-detect to lt2 Validation 9

2 to lt20 Investigation 10

20 to lt200 Intervention 8

ge200 Accelerated intervention 3 Notes According to information provided by the EPA there are approximately 130 residential properties located in the Thebarton EPA Assessment Area calculated on the basis of cadastral boundaries ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial facility ndash these data would therefore need to be confirmed via a property survey

80607-1 REV1 30102017 PAGE 59

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

10 CONCEPTUAL SITE MODEL

As detailed in Table 101 a CSM has been developed for the Thebarton EPA Assessment Area on the basis of historical information (as summarised in Section 12 as well as Appendices A and B) and the data obtained during the recent Fyfe investigation program

Table 101 Summary of existing information for the Thebarton EPA Assessment Area

Topic Summarised Information

Site Characterisation

Identification of Assessment Area

An approximately 27 ha Assessment Area located within the suburb of Thebarton has been defined by the EPA The boundaries of this area are detailed in Section 21 and illustrated on Figure 1

History of land use Properties located within the Thebarton EPA Assessment Area have been used for a mixture of commercialindustrial and low density residential land uses over time Current commercialindustrial properties include a beverage factory in the north-eastern portion of the assessment area a refrigeration equipment facility a car dealership two hotels (at least one of which has a cellarbasement) automotive and other workshops and the Ice Arena Former commercialindustrial activities have been identified as including a gas works a mechanicrsquos workshop sheet metal working facilities and a farm machinery manufacturer

Historical investigations

Reports provided to Fyfe by the EPA that pertain to previous investigations undertaken within the Thebarton EPA Assessment Area have been reviewed and summarised in Appendix A Additional historical information is included in Appendix B

Local geology Natural soils encountered from the surfacenear surface to the maximum drill depth of 19 m BGL across the Thebarton EPA Assessment Area were considered to be indicative of the Quaternary Pooraka and Hindmarsh Clay formations Whereas fill materials (ie sand gravelcrushed rock andor silt) were encountered to depths of up to 09 m BGL at a number of sampling locations underlying natural soils comprised mainly low to medium plasticity silty or sandy clays with variable gravel contents Geotechnical testing of subsurface soil samples collected from 10 drill cores indicated that the PSD comprised predominantly claysilt with lesser components of sand andor gravel ndash these soil samples were mostly classified as Clay although some were classified as Sandy Clay or Clayey Sand According to Stapledon (1971) the Hindmarsh Clay unit typically contains many structural features and defects which greatly influence its permeability thereby resulting in potential preferential pathways for the vertical and lateral movement of soil vapour and groundwater Such features were not specifically observed during the recent drilling and soil logging work although some gravel lenseslayers were identified

Hydrogeology In accordance with Gerges (2006) and his classification of the Adelaide metropolitan area into a number of zones based on their individual hydrogeological characteristics the Thebarton EPA Assessment Area is located within Zone 3 (subzone 3E) to the west of the Para Fault It contains five to six Quaternary aquifers and three or four Tertiary aquifers Based on the most recent investigations the depth to water within the Q1 aquifer in the Thebarton EPA Assessment Area ranges from approximately 123 to 159 m BGL and groundwater flows in a general north-westerly direction with a relatively flat hydraulic gradient (000062 to 00012) Salinity levels (based on field EC readings) range from approximately 1230 to 3620 mgL TDS and a groundwater flow velocity range of approximately 44 to 23 myear has

80607-1 REV1 30102017 PAGE 61

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Topic Summarised Information

been inferred As detailed in Section 222 a search of the DEWNR (2017) WaterConnect database identified 59 bores within the general Thebarton area of which 18 are located within the Thebarton EPA Assessment Area Although (where recorded) bores were listed as having been installed primarily for monitoring investigation or observation purpose other purposes (for presumed Quaternary aquifer bores) included drainage domestic and industrial A BUA has identified realistic groundwater uses as potentially including potable residential irrigation and primary contact recreationaesthetics Based on proximity to the River Torrens freshwater ecosystem protection has also been considered ndash however since the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area this may not be a realistic beneficial use Since volatile contaminants have been detected within the Q1 aquifer a potential vapour flux risk to future site users has also been considered

Hydrology No surface water bodies have been identified within the Thebarton EPA Assessment Area The closest surface water body is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west Current stormwater run-off within the Thebarton EPA Assessment Area is expected to be collected by localised (and engineered) drainage systems

Fyfe Investigation Results

Groundwater impacts Contaminants identified in groundwater beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected source site (ie the former Austral sheet metal works) in accordance with the predominant flow direction associated with the Q1 aquifer (refer to Figures 4 and 5) The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) but its north-western extent has not yet been determined (whereas its extent has been defined in all other directions)

Soil vapour impacts Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction (refer to Figures 6 and 7) and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion The soil vapour samples with the maximum TCE concentrations (ie SV3_10m and SV3_30m) also had the highest PCE and 11-DCE concentrations (or elevated LOR) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-) Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE (ie SV2_30m SV3_10m SV3_30m and SV7_30m) exceeded the adopted HILs for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE

PAGE 62 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Topic Summarised Information

degradation has not yet resulted in its production (ie at measureable levels) Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

Potential Exposure Pathways

Contaminants of Based on the results of historical investigations the EPA identified a number of CHC as being of Potential Concern concern for the Thebarton EPA Assessment Area The main COPC was identified as TCE with

additional COPC including PCE 12-DCE (cis- and trans-) VC and 11-DCE Further detail is provided in Section 14 These COPC were confirmed by the Fyfe investigations with TCE identified as both the main contaminant in groundwater and soil vapour and the main driver in terms of potential human health risks associated with vapour intrusion into buildings within the Thebarton EPA Assessment Area (refer to Section 9)

Suspected source and The suspected source of the identified CHC groundwater (and soil vapour) impacts within the affected media Thebarton EPA Assessment Area is the former Austral sheet metal works located over multiple

allotments between George and Maria Streets from the 1920s until the 1960s-1970s Previous investigations (Appendix A) had identified groundwater CHC impacts on part of this suspected source site The Fyfe investigations have concentrated on impacts within groundwater and soil vapour across the Thebarton EPA Assessment Area both of which generally correlate with the inferred north-westerly groundwater flow direction and are considered to be related to the previously identified dissolved phase groundwater CHC impacts

Sensitive receptors The following sensitive receptors have been identified as potentially relevant to the Thebarton EPA Assessment Area Ecological groundwater ecosystems within the assessment area extending to at least Dew and Smith

Streets (ie as the north-western extent of the groundwater CHC plume has not yet been determined) and

the freshwater ecosystem of the River Torrens located at a distance of approximately 07 km in a hydraulically down-gradient (ie north-westerly) direction but not necessarily representing a groundwater receiving environment

Human current and future occupants of and visitors to residential properties current and future workers on the source site and other commercialindustrial properties

within the area current and future underground trenchmaintenanceutility workers and down-gradient groundwater bore users

Contaminant Possible contaminant transport mechanisms associated with the CHC-impacted groundwater transport identified within the Q1 aquifer beneath the Thebarton EPA Assessment Area include mechanisms flow through the aquifer to a hydraulically down-gradient surface water body andor down-

gradient groundwater bores vapour generation andor flow via subsurface preferential pathways (eg service trenches

more permeable soils) and downward movement into underlying aquifers (eg dense non-aqueous phase liquid

(DNAPL))

80607-1 REV1 30102017 PAGE 63

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Topic Summarised Information

Exposure Possible exposure mechanisms associated with impacted groundwater within the Thebarton mechanisms EPA Assessment Area include

direct contact (eg during extractionuse of groundwater) incidental ingestion (eg during extractionuse of groundwater) and inhalation of vapours (eg during extractionuse of groundwater andor as a result of

vapour intrusion into buildings)

Assessment of Risk

Groundwater risks The recent groundwater analytical results have indicated that the Q1 aquifer beneath the Thebarton EPA Assessment Area contains measurable concentrations of CHC (mainly TCE but also including PCE 12-DCE andor 11-DCE at some locations) Measured concentrations of TCE exceeded the adopted assessment criteria for potable andor primary contact recreation in wells MW02 MW3 MW5 MW6 MW11 MW12 MW14 MW15 MW17 MW20 MW21 and MW23 located on Admella Maria George Albert and Dew Streets as well as Light Terrace with maximum concentrations corresponding to the ldquocorerdquo area of the plume One well (MW25) contained a concentration of carbon tetrachloride that exceeded the adopted potable criterion Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

Groundwater fate Although scattered detectable concentrations of 12-DCE have been measured in groundwater and transport across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE modelling daughter products has been interpreted to indicate that substantial dechlorination is not

occurring Groundwater fate and transport modelling (refer to Section 8 and Appendix O) has predicted that the likely extent of the dissolved phase groundwater TCE plume over the next 100 years will extend by another 500 m beyond the boundaries of the current Thebarton EPA Assessment Area However no significant lateral plume expansion is expected

Vapour intrusion risks A VIRA (refer to Section 9 and Appendix P) was undertaken to assess potential risks to human health from the intrusion of CHC vapours (primarily TCE) into indoor air from soil vapour The predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction in the absence of specific structural information) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and therefore require further action as follows 10 properties within the investigation range (2 to lt20 microgm3) eight properties within the intervention range (20 to lt200 microgm3) and three properties within accelerated intervention range (ge200 microgm3) All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3

(assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as

PAGE 64 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Topic Summarised Information

selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which are expected to be overly-conservative) ndash these results will be documented in a subsequent report Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed Management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air)

Complete Exposure Pathways

Identified pathways and areas of potential risk

Based on the results of the recent Fyfe investigations (including the VIRA) and taking into account available historical information (Appendices A and B) and DEWNR (2017) WaterConnect bore information the following complete exposure pathways and associated risks are considered possible for the Thebarton EPA Assessment Area exposure (direct contact incidental ingestion andor inhalation of vapours) during use of

groundwater for domestic (eg drinking water plumbing garden irrigation) andor recreational (eg filling of swimming poolsspas) purposes

vapour intrusion into indoor air within 30 residential propertieslocated within the vicinity of soil vapour bores SV1 to SV9 (assuming crawl space construction) ndash although 19 of these properties are predicted to be in the validationinvestigation action level range 11 are predicted to be in the intervention action level range (with actual indoor air monitoring results for properties within the intervention action level range pending)

vapour intrusion into residential cellarsbasements (if present) in the vicinity of soil vapour bores SV1 to SV10 and SV12 and

vapour intrusion into the indoor air of commercialindustrial properties ndash although actual risks to site workers would require further specific considerationassessment

In addition although only assessed in a qualitative manner to date trenchmaintenanceutility workers may also be at risk where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

Notes calculated on the basis of cadastral boundaries and assuming crawl space construction ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial premises a property survey would be required to confirm building construction details and the number of individual residences affected

80607-1 REV1 30102017 PAGE 65

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

11 CONCLUSIONS

Between May and August 2017 Fyfe undertook an investigation of groundwater and soil vapour CHC impacts within an EPA-designated Assessment Area located in Thebarton South Australia The results of the investigation have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties A CSM has been developed from the field analytical and modelling results as presented in Section 10

The following conclusions have been reached

Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were present within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m in groundwater well MW17

Groundwater within the Q1 aquifer is located at a depth of approximately 123 to 159 m BGL and flows in a general north-westerly direction (refer to Figure 4) ndash the closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred16 and the groundwater gradient beneath the Thebarton EPA Assessment area is relatively flat (ie 000062 to 00012)

Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified to include domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux as assessed by the VIRA) and possibly also potable Although freshwater ecosystem protection was also considered the River Torrens is thought to comprise either a recharge boundary (ie discharging to local groundwater) or to not actually be hydraulically connected to the Q1 aquifer in this area

Groundwater beneath parts of the Thebarton EPA Assessment Area contains detectable concentrations of various CHC and includes TCE and carbon tetrachloride (one location only) levels that exceed the adopted assessment criteria for potable use andor primary contact recreation ndash thereby indicating that groundwater would be unsuitable for drinking or the filling of swimming poolsspas In addition vapour flux could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the groundwater could be odorous

16 ie as calculated by Fyfe based on available data

80607-1 REV1 30102017 PAGE 67

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

The groundwater and soil vapour CHC impacts identified beneath parts of the Thebarton EPA Assessment Area are considered likely to have emanated from the former Austral sheet metal works located over multiple allotments between George and Maria Streets from the 1920s until the 1960sshy1970s The possible presence of on-going (primary andor secondary) source(s) at this property has not yet been investigated

As depicted on Figures 6 and 7 the current extent of the soil vapour CHC (ie dominated by TCE) impacts has been determined to correspond to the mapped distribution of the groundwater TCE impacts (Figure 5) and is considered to be directly related to groundwater (rather than soil) CHC impacts Although no soil vapour impacts were detected at 1 m BGL in SV11 and SV1317 located near the eastern and western ends of Light Terrace respectively the north-western extents of the groundwater and soil vapour CHC impacts have not yet been determined In addition although the extent of the groundwater TCE plume has been delineated in all other directions the soil vapour TCE plume has not been delineated in any direction

TCE is considered to be a primary contaminant as well as the dominant (ie in terms of concentration and extent) CHC in both groundwater and soil vapour ndash the presence of PCE and 11-DCE suggests however that more than one primary contaminant is present Although the detectable concentrations of 12-DCE (cis- and trans) are considered to have resulted from the breakdown of TCEPCE no VC has been detected in either groundwater or soil vapour ndash the scattered distribution and relatively low concentrations of 12-DCE as well as the absence of measurable VC have been interpreted to indicate that significant dechlorination of the primary contaminants has not occurred (despite the likely age of the plume ndash ie possibly up to about 90 years old)

Although the COPC adopted for the soil vapour assessment program included various CHC (ie with TCE identified as the dominant contaminant in groundwater and soil vapour) the Tier 1 VIRA confirmed that TCE PCE and 11-DCE all exceeded the adopted vapour intrusion HILs Based primarily on its greater toxicity however the risk driver for the Thebarton EPA Assessment Area is considered to be TCE

The VIRA (Tier 2) results for predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and that require further action as follows

― 10 properties within the investigation range (2 to lt20 microgm3)

― eight properties within the intervention range (20 to lt200 microgm3) and

― three properties within accelerated intervention range (ge200 microgm3)

All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming

17 noting that the laboratory LOR for TCE was elevated as compared to the other soil vapour samples

PAGE 68 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises ndash refer to Table 96

Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentration obtained for soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

Although only assessed in a qualitative manner trenchmaintenanceutility workers may be at risk in areas where TCE concentrations at 1 m BGL are greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) ndash in this case appropriate management measures would be required to be adopted This should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

80607-1 REV1 30102017 PAGE 69

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

12 DATA GAPS

Based on the results obtained during the recent Fyfe investigations as well as available historical information (Appendices A and B) the following data gaps have been identified for the Thebarton EPA Assessment Area

property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

80607-1 REV1 30102017 PAGE 71

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

13 REFERENCES

ANZECCARMCANZ (2000a) Australian Guidelines for Water Quality Monitoring and Reporting

ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

ASTM (2001) Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations ASTM Guide D7663-12

ASTM (2006) Standard Guide for Soil Gas Monitoring in the Vadose Zone ASTM Guide D5314-92

ATSDR (1994) Toxicological profile ndash 11-Dichloroethene httpswwwatsdrcdcgovToxProfilestpaspid=722amptid=130

AustralianNew Zealand Standard (1998) Water Quality Sampling Part 1 Guidance on the Design of Sampling Programs Sampling Techniques and the Preservation and Handling of Samples ASNZS 566711998

AustralianNew Zealand Standard (1998) Water Quality Sampling Part 11 Guidance on Sampling of Groundwaters ASNZS 5667111998

Bouwer H and Rice RC (1976) A Slug Test Method for Determining Hydraulic Conductivity of Unconfined Aquifers with Completely or Partially Penetrating Wells Water Resources Research vol 12 no 3 pp 423-428

Butler JJ Jr (1998) The Design Performance and Analysis of Slug Tests

Cooper HH Bredehoeft JD and Papadopulos SS (1967) Response of a Finite-Diameter Well to an Instantaneous Charge of Water Water Resources Research vol 3 no 1 pp 263-269

CRC CARE (2013) Petroleum Hydrocarbon Vapour Intrusion Assessment ndash Australian Guidance CRC CARE Technical Report No 23 July 2013

Dagan G (1978) A Note on Packer Slug and Recovery Tests in Unconfined Aquifers Water Resources Research vol 14 no 5 pp 929-934

Department of Environment Water and Natural Resources (DEWNR 2017) Water Connect Master Register of All Bores Primary Industries and Resources South Australia

Duffield G (2007) AQTESOLVreg Professional Version 45 Hydrosolve Inc

enHealth (2012a) Environmental Health Risk Assessment - Guidelines for assessing human health risks from environmental hazards enHealth Council

enHealth (2012b) Australian Exposure Factor Guidance Handbook enHealth Council

Environment Protection Act 1993

80607-1 REV1 30102017 PAGE 73

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

Environment Protection Regulations 2009

Friebel E and Nadebaum P (2011) Health Screening Levels for Petroleum Hydrocarbons in Soil and Groundwater CRC CARE Technical Report No 10

Gerges NZ (1999) The Geology and Hydrogeology of the Adelaide Metropolitan Area Flinders University (South Australia) PhD thesis (unpublished)

Gerges NZ (2006) Overview of the Hydrogeology of the Adelaide Metropolitan Area DWLBC Report 200610

Golder Associates (1994) Contamination Assessment George Street Thebarton SA Report to United Land dated 9 December 1994

Hvorslev MJ (1951) Time Lag and Soil Permeability in Ground-Water Observations Bulletin no 36 Waterways Exper Sta Corps of Engrs US Army Vicksburg Mississippi pp 1-50

Hyder Z Butler JJ Jr McElwee CD and Liu W (1994) Slug Tests in Partially Penetrating Wells Water Resources Research vol 30 no 11 pp 2945-2957

ITRC (2007) Vapor Intrusion Pathway - A Practical Guidance

Johnson PC and Ettinger RA (1991) Heuristic Model for Predicting the Intrusion Rate of Contaminant Vapors

into Buildings Environ Sci Technology 251445-1452

McDonald M G and Harbaugh A W (1988) A Modular Three-Dimensional Finite-Difference Ground-Water Flow Model Techniques of Water-Resources Investigations Book 6 Chapter A1 U S Geological Survey

NEPM (1999) National Environment Protection (Assessment of Site Contamination) Measure Schedules B1 to

B9 National Environment Protection Council Australia

NHMRC (2008) Guidelines for Managing Risks in Recreational Water

NHMRCNRMMC (2011) Australian Drinking Water Guidelines (as revised in 2016)

NJDEP (2013) Site Remediation Program Vapor Intrusion Technical Guidance (Version 31)

NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme (2nd edition)

Payne FC Quinnan JA and Potter ST (2008) Remediation Hydraulics CRC Press Boca Raton FL

RAIS (2016) Chemical Specific Parameters for Trichloroethylene Risk Assessment Information System Office of Environmental Management US Department of Energy

REM (2005a) George St Thebarton Site ndash Stage 2 Investigations Report to Luca Group dated 26 August 2005

REM (2005b) Stage 3 Environmental Site Assessment George St Thebarton SA Report to Luca Group dated 23 November 2005

SA Department of Mines and Energy (1969) 1250000 Adelaide Geological Map Sheet Sheet S1 54-9

PAGE 74 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

SA EPA (2007) Regulatory Monitoring and Testing Groundwater Sampling

SA EPA (2009) Guidelines for the Assessment and Remediation of Groundwater Contamination

SA EPA (2014) Clovelly Park Mitchell Park Project Management Team Assessment Program Flip Book November 2014

SA EPA (2015) Environment Protection (Water Quality) Policy

Standards Australia (1993) Geotechnical Site Investigations AS1726-1993

Standards Australia (2005) Guide to the Sampling and Investigation of Potentially Contaminated Soil Part 1 Non-Volatile and Semi-Volatile Compounds AS44821-2005

Stapledon DH (1971) Changes and Structural Defects Developed in some South Australian Clays and their Engineering Consequences Proceedings of Symposium on Soils and Earth Structures in Arid Climates Adelaide 1970

US EPA (1996) Soil Screening Guidance Technical Background Document Office of Emergency and Remedial Response Washington DC EPA540R95128

US EPA (1999) Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air Second Edition Compendium Method TO-15 Determination Of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed By Gas Chromatography Mass Spectrometry (GCMS) EPA625R-96010b

US EPA (2002) OSWER Draft Guidance for Evaluating the Vapour Intrusion to Indoor Air Pathway from Groundwater and Soils (Subsurface Vapour Intrusion Guidance) EPA530-D-02-004

US EPA (2009) EPArsquos Risk-Screening Environmental Indicators (RSEI) Methodology Office of Pollution Prevention and Toxics Washington DC

US EPA (2011) IRIS (Integrated Risk Information System) Trichloroethylene Chemical Assessment Summary httpscfpubepagovnceairisiris_documentsdocumentssubst0199_summarypdf

US EPA (2012) EPArsquos Vapor Intrusion Database Evaluation and Characterization of Attenuation Factors for Chlorinated Volatile Organic Compounds and Residential Buildings

US EPA (2015) OSWER Technical Guide for Assessing and Mitigating the Vapour Intrusion Pathway from Subsurface Vapour Sources to Indoor Air

US EPA (2017a) Regional Screening Levels (RSLs) - Generic Tables (June 2017) httpswwwepagovriskregional-screening-levels-rsls-generic-tables-june-2017

US EPA (2017b) Regional Screening Levels for Chemical Contaminants at Superfund Sites httpwwwepagovreg3hwmdriskhumanrb-concentration_tableGeneric_Tablesindexhtm

80607-1 REV1 30102017 PAGE 75

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

WHO (2006) Air Quality Guidelines for Europe Second Edition WHO Regional Publications European Series No 91

WHO (2017) Guidelines for Drinking-water Quality Fourth edition (incorporating the first addendum)

Wiedemeier T Swanson M Moutoux D Gordon E Wilson J Wilson B Kampbell D Haas P Miller R Hansen J and Chapelle F (1998) Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water National Risk Management Research Laboratory Office of Research and Development US EPA

Zheng C (1990) MT3D A Modular Three-Dimensional Transport Model for Simulation of Advection Dispersion and Chemical Reactions of Contaminants in Groundwater Systems Prepared for US EPA by Robert S Kerr Environmental Research Laboratory Ada Oklahoma developed by SS Papadopulos amp Associates Inc Rockville Maryland

PAGE 76 80607-1 REV1 30102017

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

14 STATEMENT OF LIMITATIONS

The opinions and conclusions presented in this report are specific to the conditions of the Thebarton EPA Assessment Area and the state of legislation currently enacted as at the date of this report Fyfe does not make any representation or warranty that the opinions and conclusions in this report will be applicable in the future as there may be changes in the condition of the Thebarton EPA Assessment Area applicable legislation or other factors that would affect the opinions and conclusions contained in this report

Fyfe has used the degree of skill and care ordinarily exercised by reputable members of our profession practising in the same or similar locality This report has been prepared for the South Australian Environment Protection Authority for the specific purpose identified in the report Fyfe accepts no liability or responsibility to any third party for the accuracy of any information contained in the report or any opinion or conclusion expressed in the report Neither the whole of the report nor any part or reference thereto may be in any way used relied upon or reproduced by any third party without Fyfersquos prior written approval This report must be read in its entirety including all tables and attachments

80607-1 REV1 30102017 PAGE 77

EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

FIGURES

Figure 1 Site Location and Assessment Area

Figure 2 Assessment Point Locations

Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan

Figure 4 Groundwater Elevation Contour Plan

Figure 5 Groundwater Concentration Plan

Figure 6 Soil Vapour Concentration Plan (10m)

Figure 7 Soil Vapour Concentration Plan (30m)

80607-1 REV1 30102017 PAGE 79

JAM

ES CO

NG

DO

N D

RIV

E

JAM

ES CO

NG

DO

N D

RIV

E

DEW

STREET

DEW

STREET

CHAPEL STREETCHAPEL STREET

PAR

KER

STREET

PAR

KER

STREET

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

LIGHT TERRACELIGHT TERRACE

DEW

STREET

DEW

STREET

WA

LSH ST

WA

LSH ST

AD

MELLA

STREET

AD

MELLA

STREET

ALB

ERT STR

EETA

LBER

T STREET

HO

LLAN

D ST

REET

HO

LLAN

D ST

REET

RANDOLPH STREET

RANDOLPH STREET

JAM

ES STREET

JAM

ES STREET

DOVE STREET

DOVE STREET

SMITH STREETSMITH STREET

MARIA STREETMARIA STREET

GEORGE STREETGEORGE STREET

KINTORE STREET

KINTORE STREET

PORT ROAD

PORT ROAD

PORT ROAD

PORT ROAD

CAW

THO

RN

E STR

EETC

AWTH

OR

NE ST

REET

DEVON STREETDEVON STREET

KINTORE STREETKINTORE STREET

GOODENOUGH STREETGOODENOUGH STREET

LIVESTR

ON

G PATH

WAY

LIVESTR

ON

G PATH

WAY

CCAAWW

TTHHOO

RRNN

EE SSTTRR

EEEETT

HHOO

LLLLAANN

DD SSTT

RREEEETT

DE

DEW

SW

STREET

TREET

JJAM

EA

MES S

S STREET

TREET

DDOOVVEE SSTTRREEEETT

LLIIVVEESSTTRR

OONN

GG PPAATTHH

WWAAYY

LIGHT TERRLIGHT TERRAACECE

AD

MELLA

SA

DM

ELLA STR

EETTR

EET

CHAPEL SCHAPEL STREETTREET

AALLBB

EERRTT SSTTRR

EEEETT

GEGEORORGE SGE STREETTREET

PPOORRTT RROOAADD

PPOORRTT RROOAADD

DDEEWW

SSTTRREEEETT

MMAARRIIAA SSTTRREEEETT

JJAAMM

EESS CCOO

NNGG

DDOO

NN DD

RRIIVV

EE

WWAA

LLSSHH SSTT

SSMMIITTHH SSTTRREEEETT

RRANDOLPH S

ANDOLPH STREETTREET

PPOORR

TT RROO

AADD

PPOORR

TT RROO

AADD

KKIINNTTOORREE SSTTRREEEETT

KKIINNTTOORREE SSTTRREEEETT

PPAARR

KKEERR

SSTTRREEEETT

GGOOOODDEENNOOUUGGHH SSTTRREEEETT

DDEEVVOONN SSTTRREEEETT

ASSESSMENT AREA

CBD

750m

LEGEND

EPA ASSESSMENT AREA

CADASTRE

12500 A3

0 25 50 m

CLIENT

SA EPA

PROJECT

FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

EPA THEBARTON ASSESSMENT AREA - STAGE 1

TITLE

FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

PROJECT NO DATE CREATED

80607-1 290917

80607_Fig 1 - Site Location and Assessment Areaai REV 1 gt 290917

LE

VE

L 1

12

4 S

OU

TH

TE

RR

AC

E

AD

EL

AID

E S

A 5

00

0

P

H

(08

) 8

23

2 9

08

8

F

AX

(0

8)

82

32

90

99

EM

AIL

in

fo

fyfe

co

ma

u

W

EB

fy

fec

om

au

AB

N

57

00

8 1

16 1

30

JAM

ES CO

NG

DO

N D

RIV

E

JAM

ES CO

NG

DO

N D

RIV

E

DEW

STREET

DEW

STREET

CHAPEL STREETCHAPEL STREET

PAR

KER

STREET

PAR

KER

STREET

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

LIGHT TERRACELIGHT TERRACE

DEW

STREET

DEW

STREET

WA

LSH ST

WA

LSH ST

AD

MELLA

STREET

AD

MELLA

STREET

ALB

ERT STR

EETA

LBER

T STREET

HO

LLAN

D ST

REET

HO

LLAN

D ST

REET

RANDOLPH STREET

RANDOLPH STREET

JAM

ES STREET

JAM

ES STREET

DOVE STREET

DOVE STREET

SMITH STREETSMITH STREET

MARIA STREETMARIA STREET

GEORGE STREETGEORGE STREET

KINTORE STREET

KINTORE STREET

PORT ROAD

PORT ROAD

PORT ROAD

PORT ROAD

CAW

THO

RN

E STR

EETC

AWTH

OR

NE ST

REET

DEVON STREETDEVON STREET

KINTORE STREETKINTORE STREET

GOODENOUGH STREETGOODENOUGH STREET

LIVESTR

ON

G PATH

WAY

LIVESTR

ON

G PATH

WAY

SV1SV1

SV2SV2

SV3SV3SV4SV4

SV5SV5

SV6SV6

SV7SV7SV8SV8

SV9SV9

SV10SV10

SV11SV11SV12SV12

SV13SV13

MW1MW1

MW02MW02

MW3MW3

MW4MW4MW5MW5MW6MW6

MW7MW7

MW8MW8

MW9MW9

MW10MW10MW11MW11

MW12MW12MW13MW13

MW14MW14MW15MW15

MW16MW16

MW17MW17

MW18MW18

MW19MW19

MW20MW20

MW21MW21

MW22MW22

MW23MW23

MW24MW24

MW25MW25

MW26MW26

WMS2WMS2WMS1WMS1

WMS3WMS3WMS4WMS4WMS5WMS5

WMS6WMS6

WMS7WMS7WMS8WMS8

WMS9WMS9WMS10WMS10

WMS11WMS11

WMS12WMS12

WMS13WMS13WMS14WMS14

WMS15WMS15

WMS41WMS41

WMS40WMS40

WMS39WMS39WMS38WMS38

WMS16WMS16

WMS17WMS17

WMS18WMS18WMS19WMS19

WMS20WMS20

WMS21WMS21WMS22WMS22

WMS23WMS23WMS24WMS24

WMS25WMS25

WMS26WMS26

WMS27WMS27WMS28WMS28WMS29WMS29

WMS30WMS30

WMS31WMS31

WMS32WMS32

WMS33WMS33

WMS34WMS34

WMS35WMS35

WMS36WMS36

WMS37WMS37

WWAA

LLSSHHSSTT

SSMMIITTHH SSTTRREEEETT

RRANDOLPH S

ANDOLPH STREETTREET

PPOORR

TT RROO

AADD

PPOORR

TT RROO

AADD

CCAAWW

TTHHOO

RRNN

EE SSTTRR

EEEETT

JJAM

EA

MES S

S STREET

TREET

HHOO

LLLLAANN

DDSSTT

RREEEETT

DE

DEW

SW

STREET

TREET

DDOOVVEE SSTTRREEEETT

LLIIVVEESSTTRR

OONN

GGPPAATTHH

WWAAYY

LIGHT TERRLIGHT TERRAACECE

CHAPEL SCHAPEL STREETTREET

AALLBB

EERRTT SSTTRR

EEEETT

AD

MELLA

SA

DM

ELLA STR

EETTR

EET

GEGEORORGE SGE STREETTREET

PPOORRTT RROOAADD PPOORRTT RROOAADD

DDEEWW

SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

JJAAMM

EESS CCOO

NNGG

DDOO

NN DD

RRIIVV

EE

KKIINNTTOORREE SSTTRREEEETT

KKIINNTTOORREE SSTTRREEEETT

PPAARR

KKEERR

SSTTRREEEETT

GGOOOODDEENNOOUUGGHH SSTTRREEEETT

DDEEVVOONN SSTTRREEEETT

FIGURE 2 ASSESSMENT POINT LOCATIONS

MMWW88

MW2MW244 WMS3WMS355

MW2MW255

WMS3WMS366

WMS3WMS377

WMS3WMS311

MW2MW222WMS34WMS34

MW2MW233 WMS3WMS322

WMS3WMS333

WMS2WMS277WMS2WMS299 WMS2WMS288

SSV12V12 SSVV1111 MW19MW19

MW18MW18 SSVV1133 MW2MW200 WMS3WMS300

MW2MW211 WMS2WMS255

WMS2WMS266

MW17MW17 WMS2WMS244

WMS2WMS233

WMS2WMS222 WMS2WMS211

SSVV99

SSV10V10WMS2WMS200 MW14MW14MW15MW15 WMS18WMS18

WMS19WMS19 MW16MW16

WMS13WMS13MW10MW10 WMS14WMS14MMWW1111SVSV77WMS15WMS15SSVV88WMS16WMS16

SVSV66WMS4WMS411MW13MW13 LEGENDMW12MW12

WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS17WMS17 WMS40WMS40 SSVV55 MW0MW022MW9MW9 GROUNDWATER MONITORING WELL

WMS11WMS11 WMS6WMS6 SOIL VAPOUR BORE

WATERLOO MEMBRANE SAMPLERTM - ROUND 2

SVSV22WMS8WMS8SVSVWMS12WMS12 44 WMS7WMS7 MW4MW4MMWW SVSV66 33 MW5MW5WMS3WMS388

WMS3WMS399 MW7MW7 EPA ASSESSMENT AREAWMS10WMS10 WMS9WMS9

SVSV11 CADASTRE

MW3MW3

MW1MW1 WMS3WMS3WMS4WMS4MW2MW266 WMS5WMS5 12500 A3

0 25 50 m

CLIENT

SA EPAWMS1WMS1

WMS2WMS2 PROJECT

EPA THEBARTON ASSESSMENT AREA - STAGE 1

TITLE

FIGURE 2 ASSESSMENT POINT LOCATIONS

PROJECT NO DATE CREATED

80607-1 280917

80607_Fig 2 - Assessment Point Locationsai REV 1 gt 280917

LE

VE

L 1

12

4 S

OU

TH

TE

RR

AC

E

AD

EL

AID

E S

A 5

00

0

PH

(0

8)

82

32

90

88

F

AX

(0

8)

82

32

90

99

E

MA

IL

info

fy

fec

om

au

W

EB

fy

fec

om

au

A

BN

5

7 0

08

116

13

0

JAM

ES CO

NG

DO

N D

RIV

E

JAM

ES CO

NG

DO

N D

RIV

E

DEW

STREET

DEW

STREET

CHAPEL STREETCHAPEL STREET

PAR

KER

STREET

PAR

KER

STREET

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

LIGHT TERRACELIGHT TERRACE

DEW

STREET

DEW

STREET

WA

LSH ST

WA

LSH ST

AD

MELLA

STREET

AD

MELLA

STREET

ALB

ERT STR

EETA

LBER

T STREET

HO

LLAN

D ST

REET

HO

LLAN

D ST

REET

RANDOLPH STREET

RANDOLPH STREET

JAM

ES STREET

JAM

ES STREET

DOVE STREET

DOVE STREET

SMITH STREETSMITH STREET

MARIA STREETMARIA STREET

GEORGE STREETGEORGE STREET

KINTORE STREET

KINTORE STREET

PORT ROAD

PORT ROAD

PORT ROAD

PORT ROAD

CAW

THO

RN

E STR

EETC

AWTH

OR

NE ST

REET

DEVON STREETDEVON STREET

KINTORE STREETKINTORE STREET

GOODENOUGH STREETGOODENOUGH STREET

LIVESTR

ON

G PATH

WAY

LIVESTR

ON

G PATH

WAY

WMS2WMS2WMS1WMS1

WMS3WMS3WMS4WMS4

WMS5WMS5

WMS6WMS6

WMS7WMS7WMS8WMS8

WMS9WMS9

WMS10WMS10

WMS11WMS11

WMS12WMS12

WMS13WMS13WMS14WMS14

WMS15WMS15 WMS41WMS41

WMS40WMS40

WMS39WMS39WMS38WMS38

WMS16WMS16

WMS17WMS17

WMS18WMS18WMS19WMS19WMS20WMS20

WMS21WMS21WMS22WMS22

WMS23WMS23WMS24WMS24

WMS25WMS25

WMS26WMS26

WMS27WMS27WMS28WMS28WMS29WMS29

WMS30WMS30

WMS31WMS31

WMS32WMS32WMS33WMS33

WMS34WMS34

WMS35WMS35

WMS36WMS36

WMS37WMS37

WWAA

LLSSHHSSTT

SSMMIITTHH SSTTRREEEETT

RRANDOLPH S

ANDOLPH STREETTREET

PPOORR

TT RROO

AADD

PPOORR

TT RROO

AADD

CCAAWW

TTHHOO

RRNN

EE SSTTRR

EEEETT

JJAM

EA

MES S

S STREET

TREET

HHOO

LLLLAANN

DDSSTT

RREEEETT

DE

DEW

SW

STREET

TREET

DDOOVVEE SSTTRREEEETT

LLIIVVEESSTTRR

OONN

GGPPAATTHH

WWAAYY

LIGHT TERRLIGHT TERRAACECE

AD

MELLA

SA

DM

ELLA STR

EETTR

EET

AALLBB

EERRTT SSTTRR

EEEETT

CHAPEL SCHAPEL STREETTREET

GEGEORORGE SGE STREETTREET

PPOORRTT RROOAADD PPOORRTT RROOAADD

DDEEWW

SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

JJAAMM

EESS CCOO

NNGG

DDOO

NN DD

RRIIVV

EE

KKIINNTTOORREE SSTTRREEEETT

KKIINNTTOORREE SSTTRREEEETT

PPAARR

KKEERR

SSTTRREEEETT

GGOOOODDEENNOOUUGGHH SSTTRREEEETT

DDEEVVOONN SSTTRREEEETT

FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

TCE CONCENTRATION PLAN

WMS3WMS355 TCE lt78

WMS3WMS366 TCE lt77WMS3WMS377

TCE 44

WMS3WMS311 TCE lt78

WMS34WMS34 TCE 11

WMS3WMS322WMS3WMS333 TCE lt78TCE lt79

WMS2WMS277WMS2WMS299 WMS2WMS288 TCE 64 TCE lt77 TCE lt8

WMS3WMS300 TCE lt8

WMS2WMS255

WMS2WMS266 TCE 1400(D)

WMS2WMS222 TCE 38 WMS2WMS211

TCE lt79

TCE lt78

WMS2WMS233 WMS2WMS244 TCE lt77

TCE 230

WMS2WMS200 WMS19WMS19TCE lt78 WMS18WMS18 TCE 11000

TCE 4200

WMS13WMS13 WMS14WMS14 TCE lt79

WMS4WMS411WMS15WMS15 TCE 46000WMS16WMS16 TCE 18000 LEGENDTCE lt8

TCE lt78WMS17WMS17 WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS40WMS40TCE lt79

TCE 110000 WATERLOO MEMBRANE SAMPLERTM - ROUND 2WMS11WMS11

TCE 71000WMS12WMS12 EPA ASSESSMENT AREA

CADASTRE

WMS6WMS6 TCE lt58 WMS8WMS8 WMS3WMS388 TCE 32WMS7WMS7WMS3WMS399

TCE 12000 TCE 13000 TCE 1900TCE 1300WMS9WMS9 TCE lt58 NotesWMS10WMS10

All concentrations are in μgm3 TCE lt58

D = Duplicate result

WMS3WMS3WMS4WMS4 12500 A3

LE

VE

L 1

12

4 S

OU

TH

TE

RR

AC

E

AD

EL

AID

E S

A 5

00

0

PH

(0

8)

82

32

90

88

F

AX

(0

8)

82

32

90

99

E

MA

IL

info

fy

fec

om

au

W

EB

fy

fec

om

au

A

BN

5

7 0

08

116

13

0

TCE lt57WMS5WMS5 TCE lt57 TCE lt58 0 25 50

m

CLIENT

SA EPA

WMS2WMS2 TCE lt56

WMS1WMS1 TCE lt56

PROJECT

EPA THEBARTON ASSESSMENT AREA - STAGE 1

TITLE

FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

TCE CONCENTRATION PLAN

PROJECT NO DATE CREATED

80607-1 241017

80607_Fig 3 - WMS TCE Concentration Planai REV 1 gt 241017

JAM

ES CO

NG

DO

N D

RIV

E

JAM

ES CO

NG

DO

N D

RIV

E

DEW

STREET

DEW

STREET

CHAPEL STREETCHAPEL STREET

PAR

KER

STREET

PAR

KER

STREET

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

LIGHT TERRACELIGHT TERRACE

DEW

STREET

DEW

STREET

WA

LSH ST

WA

LSH ST

AD

MELLA

STREET

AD

MELLA

STREET

ALB

ERT STR

EETA

LBER

T STREET

HO

LLAN

D ST

REET

HO

LLAN

D ST

REET

RANDOLPH STREET

RANDOLPH STREET

JAM

ES STREET

JAM

ES STREET

DOVE STREET

DOVE STREET

SMITH STREETSMITH STREET

MARIA STREETMARIA STREET

GEORGE STREETGEORGE STREET

KINTORE STREET

KINTORE STREET

PORT ROAD

PORT ROAD

PORT ROAD

PORT ROAD

CAW

THO

RN

E STR

EETC

AWTH

OR

NE ST

REET

DEVON STREETDEVON STREET

KINTORE STREETKINTORE STREET

GOODENOUGH STREETGOODENOUGH STREET

LIVESTR

ON

G PATH

WAY

LIVESTR

ON

G PATH

WAY

MW1MW1

MW02MW02

MW3MW3

MW4MW4MW5MW5

MW6MW6

MW7MW7

MW8MW8

MW9MW9

MW10MW10MW11MW11

MW12MW12

MW13MW13

MW14MW14

MW15MW15

MW16MW16

MW17MW17

MW18MW18

MW19MW19MW20MW20

MW21MW21

MW22MW22

MW23MW23

MW24MW24

MW25MW25

MW26MW26

WWAA

LLSSHHSSTT

SSMMIITTHH SSTTRREEEETT

4

466

PPOORR

TT RROO

AADD

PPOORR

TT RROO

AADD

RRANDOLPH S

ANDOLPH STREETTREET 4455

DE

DEW

SW

STREET

TREET

JJAM

EA

MES S

S STREET

TREET

HHOO

LLLLAANN

DD SSTT

RREEEETT

CCAAWW

TTHHOO

RRNN

EE SSTTRR

EEEETT 4477

DDOOVVEE SSTTRREEEETT

4455

4488

LLIIVVEESSTTRR

OONN

GGPPAATTHH

WWAAYY

4455

LIGHT TERRLIGHT TERRAACECE

AD

MELLA

SA

DM

ELLA STR

EETTR

EET

4466

CHAPEL SCHAPEL STREETTREET

4477 AA

LLBBEERR

TT SSTTRREEEETT

4499

GR4466 OUND

FLOW DIREW

GEGEORORGE SGE STREETTREET ATER C

4488 TION

PPOORRTT RROOAADD PPOORRTT RROOAADD 55

00 DD

EEWW SSTTRR

EEEETT 4499

MMAARRIIAA SSTTRREEEETT

4477

5500

JJAAMM

EESS CCOO

NNGG

DDOO

NN DD

RRIIVV

EE

88 44

KKIINNTTOORREE SSTTRREEEETT

KKIINNTTOORREE SSTTRREEEETT

PPAARR

KKEERR

SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

5500

4499

DDEEVVOONN SSTTRREEEETT

FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

Groundwater SWL MMWW88 Monitoring Well (m AHD)

MW1 5011 MW2MW244

MW02 4786

MW3 484

MW2MW255 MW4 507

MW5 4833

MW6 4794

MW7 4703

MW8 4581

MW9 4728

MW10 4871

MW11 4785 MW2MW222

MW12 4689

MW13 4662

MW2MW233 MW14 4723

MW15 464

MW16 4577

MW17 4619

MW18 4538

MW19 4735

MW20 457

MW21 4531

MW22 4501

MW23 4497

MW24 4537

MW25 4469

MW26 4918

MW19MW19 MW2MW200

MW2MW211MW18MW18

MW17MW17

MW14MW14

MW15MW15

MW16MW16

MW10MW10 LEGEND MMWW1111

GROUNDWATER MONITORING WELLMW12MW12

50 INFERRED GROUNDWATER ELEVATION CONTOUR

MW13MW13

MW0MW022 INFERRED GROUNDWATER FLOW DIRECTION

EPA ASSESSMENT AREA

MW9MW9

MW5MW5 CADASTREMMWW66 MW4MW4

MW7MW7 Note This is one interpretation only Other interpretations possibleMW3MW3

12500 A3

0 25 50 m

CLIENT

SA EPA

PROJECT

EPA THEBARTON ASSESSMENT AREA - STAGE 1

TITLE

FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

PROJECT NO DATE CREATED

80607-1 290917

MW1MW1 MW2MW266

80607_Fig 4 - Groundwater Elevation Contour Planai REV 1 gt 290917

LE

VE

L 1

12

4 S

OU

TH

TE

RR

AC

E

AD

EL

AID

E S

A 5

00

0

PH

(0

8)

82

32

90

88

F

AX

(0

8)

82

32

90

99

E

MA

IL

info

fy

fec

om

au

W

EB

fy

fec

om

au

A

BN

5

7 0

08

116

13

0

JAM

ES CO

NG

DO

N D

RIV

E

JAM

ES CO

NG

DO

N D

RIV

E

DEW

STREET

DEW

STREET

CHAPEL STREETCHAPEL STREET

PAR

KER

STREET

PAR

KER

STREET

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

LIGHT TERRACELIGHT TERRACE

DEW

STREET

DEW

STREET

WA

LSH ST

WA

LSH ST

AD

MELLA

STREET

AD

MELLA

STREET

ALB

ERT STR

EETA

LBER

T STREET

HO

LLAN

D ST

REET

HO

LLAN

D ST

REET

RANDOLPH STREET

RANDOLPH STREET

JAM

ES STREET

JAM

ES STREET

DOVE STREET

DOVE STREET

SMITH STREETSMITH STREET

MARIA STREETMARIA STREET

GEORGE STREETGEORGE STREET

KINTORE STREET

KINTORE STREET

PORT ROAD

PORT ROAD

PORT ROAD

PORT ROAD

CAW

THO

RN

E STR

EETC

AWTH

OR

NE ST

REET

DEVON STREETDEVON STREET

KINTORE STREETKINTORE STREET

GOODENOUGH STREETGOODENOUGH STREET

LIVESTR

ON

G PATH

WAY

LIVESTR

ON

G PATH

WAY

MW1MW1

MW02MW02

MW3MW3

MW4MW4

MW5MW5

MW6MW6

MW7MW7

MW8MW8

MW9MW9

MW10MW10MW11MW11

MW12MW12

MW13MW13

MW14MW14

MW15MW15

MW16MW16

MW17MW17

MW18MW18

MW19MW19MW20MW20

MW21MW21

MW22MW22

MW23MW23

MW24MW24

MW25MW25

MW26MW26

WWAA

LLSSHHSSTT

SSMMIITTHH SSTTRREEEETT

ndnd

RRANDOLPH S

ANDOLPH STREETTREET

PPOORR

TTRR

OOAA

DD

PPOORR

TTRR

OOAA

DD

JJAM

EA

MES S

S STREET

TREET

HHOO

LLLLAANN

DDSSTT

RREEEETT

CCAAWW

TTHHOO

RRNN

EESSTT

RREEEETT

DE

DEW

SW

STREET

TREET

DDOOVVEE SSTTRREEEETT

LLIIVVEESSTTRR

OONN

GGPPAATTHH

WWAAYY

LIGHT TERRLIGHT TERRAACECE

AD

MELLA

SA

DM

ELLA STR

EETTR

EET

AALLBB

EERRTT SSTTRR

EEEETT

CHAPEL SCHAPEL STREETTREET

ndnd ndnd

100100

11000000

GEGEORORGE SGE STREETTREET

1010000000

PPOORRTT RROOAADD PPOORRTT RROOAADD

DDEEWW

SSTTRREEEETT

1010000000 11000000 MMAARRIIAA SSTTRREEEETT

100100

JJAAMM

EESSCC

OONN

GGDD

OONN

DDRR

IIVVEE

KKIINNTTOORREE SSTTRREEEETT ndnd

KKIINNTTOORREE SSTTRREEEETT

PPAARR

KKEERR

SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

DDEEVVOONN SSTTRREEEETT

FIGURE 5 GROUNDWATER CONCENTRATION PLAN

MW2MW244

MMWW88 TCE lt1

PCE lt1

11-DCE lt1TCE lt1

12-DCE lt1PCE lt1

11-DCE lt1MW2MW255 12-DCE lt1

TCE 2

PCE lt1

11-DCE lt1

12-DCE lt1

MW2MW222 TCE lt1

PCE lt1

11-DCE lt1MW2MW233 12-DCE lt1

TCE 21

PCE lt1

11-DCE lt1

12-DCE lt1

MW19MW19 TCE lt1

MW2MW200 TCE 70 PCE lt1MW2MW211 PCE lt1MW18MW18 11-DCE lt1

TCE 23 11-DCE lt1TCE 5 12-DCE lt1 PCE lt1 12-DCE lt1PCE lt1 11-DCE lt1

11-DCE lt1 12-DCE lt1

12-DCE lt1

MW17MW17 LEGENDTCE 24 MW14MW14

PCE lt1 TCE 1100 lt1 MW15MW15 GROUNDWATER MONITORING WELL11-DCE PCE lt1

12-DCE lt1 TCE 180 11-DCE 2MW16MW16 100 INFERRED TCE GROUNDWATERPCE lt1 12-DCE 4 CONCENTRATION CONTOURSTCE lt1 11-DCE lt1 PCE lt1 12-DCE lt1 11-DCE lt1

12-DCE lt1 MMWW1111

EPA ASSESSMENT AREAMW10MW10

TCE lt1 CADASTREMW12MW12 TCE lt14900 PCE

lt1 11-DCE lt1TCE 700 PCEMW13MW13 12-DCE lt1 TCE CONCENTRATIONS (μgL)lt1 11-DCE 7PCE

TCE lt1 lt1 12-DCE 511-DCE gtnd to lt100 100 to lt1000 1000 to lt10000

MW0MW022PCE lt1 12-DCE lt1 2100011-DCE lt1 MW9MW9 TCE

PCE lt112-DCE lt1 TCE 2(D) 11-DCE 15PCE lt1 MW5MW5

10000 to 29000

nd = non-detect (lt1)12-DCE 4511-DCE lt1 MMWW66 TCE 29000 MW4MW4 12-DCE lt1

PCE 3 TCE lt1 NotesTCE 29 11-DCE 6MW7MW7 PCE lt1PCE lt1 This is one interpretation only Other interpretations possible12-DCE 23TCE lt1 11-DCE lt111-DCE lt1 All concentrations are in μgL

12-DCE includes cis and trans PCE lt1 MW3MW3 12-DCE lt112-DCE lt1 11-DCE lt1

TCE 69 D = Duplicate result12-DCE lt1 PCE lt1

11-DCE lt1

12-DCE lt1 MW1MW1

12500 A3MW2MW266 TCE lt1

TCE 2 PCE lt1

PCE lt1 11-DCE lt1

11-DCE lt1 12-DCE lt1

12-DCE lt1

LE

VE

L 1

12

4 S

OU

TH

TE

RR

AC

E

AD

EL

AID

E S

A 5

00

0

PH

(0

8)

82

32

90

88

F

AX

(0

8)

82

32

90

99

E

MA

IL

info

fy

fec

om

au

W

EB

fy

fec

om

au

A

BN

5

7 0

08

116

13

0

0 25 50 m

CLIENT

SA EPA

PROJECT

EPA THEBARTON ASSESSMENT AREA - STAGE 1

TITLE

FIGURE 5 GROUNDWATER CONCENTRATION PLAN

PROJECT NO DATE CREATED

80607-1 280917

80607_Fig 5 - Groundwater TCE Concentration Plan r2ai REV 2 gt 280917

JAM

ES CO

NG

DO

N D

RIV

E

JAM

ES CO

NG

DO

N D

RIV

E

DEW

STREET

DEW

STREET

CHAPEL STREETCHAPEL STREET

PAR

KER

STREET

PAR

KER

STREET

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

LIGHT TERRACELIGHT TERRACE

DEW

STREET

DEW

STREET

WA

LSH ST

WA

LSH ST

AD

MELLA

STREET

AD

MELLA

STREET

ALB

ERT STR

EETA

LBER

T STREET

HO

LLAN

D ST

REET

HO

LLAN

D ST

REET

RANDOLPH STREET

RANDOLPH STREET

JAM

ES STREET

JAM

ES STREET

DOVE STREET

DOVE STREET

SMITH STREETSMITH STREET

MARIA STREETMARIA STREET

GEORGE STREETGEORGE STREET

KINTORE STREET

KINTORE STREET

PORT ROAD

PORT ROAD

PORT ROAD

PORT ROAD

CAW

THO

RN

E STR

EETC

AWTH

OR

NE ST

REET

DEVON STREETDEVON STREET

KINTORE STREETKINTORE STREET

GOODENOUGH STREETGOODENOUGH STREET

LIVESTR

ON

G PATH

WAY

LIVESTR

ON

G PATH

WAY

SV1SV1

SV2SV2SV3SV3SV4SV4

SV5SV5

SV7SV7SV8SV8

SV9SV9

SV10SV10

SV11SV11SV12SV12

SV13SV13

SV6SV6

WWAA

LLSSHHSSTT

SSMMIITTHH SSTTRREEEETT

RRANDOLPH S

ANDOLPH STREETTREET

PPOORR

TTRR

OOAA

DD

PPOORR

TTRR

OOAA

DD

CCAAWW

TTHHOO

RRNN

EESSTT

RREEEETT

HHOO

LLLLAANN

DDSSTT

RREEEETT

JJAM

EA

MES S

S STREET

TREET

DE

DEW

SW

STREET

TREET

DDOOVVEE SSTTRREEEETT

00

LLIIVVEESSTTRR

OONN

GGPPAATTHH

WWAAYY

LIGHT TERRLIGHT TERRAACECE

AD

MELLA

SA

DM

ELLA STR

EETTR

EET

CHAPEL SCHAPEL STREETTREET

00

AALLBB

EERRTT SSTTRR

EEEETT

1010

GEGEORORGE SGE STREETTREET

000000

PPOORRTT RROOAADD

100100000

000

1010

PPOORRTT RROOAADD

000000

DDEEWW

SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

JJAAMM

EESSCC

OONN

GGDD

OONN

DDRR

IIVVEE

KKIINNTTOORREE SSTTRREEEETT 00

KKIINNTTOORREE SSTTRREEEETT

PPAARR

KKEERR

SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

DDEEVVOONN SSTTRREEEETT

FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

SSVV1111 SSV12V12 TCE lt18

SSVV1133 TCE 16

PCE lt54 TCE lt21

11-DCE lt29 PCE lt25

12-DCE lt39 11-DCE lt14

12-DCE lt18

PCE lt22

11-DCE lt12

12-DCE lt16

TCE 170

PCE lt54

11-DCE lt3

12-DCE lt39 LEGEND SSVV99

SSV10V10 SOIL VAPOUR BORE

TCE lt21 0 INFERRED TCE SOIL VAPOUR CONTOUR PCE lt25

TCE 2200011-DCE lt14 EPA ASSESSMENT AREA

PCE 1912-DCE lt18

11-DCE lt27 CADASTRE

12-DCE lt37 SVSV66SVSV77

SSVV88 TCE 22000

TCE 2300 PCE 12 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)TCE 100000 PCE 62 11-DCE lt29PCE 84 0 to lt10000SSVV55lt2711-DCE 12-DCE lt2911-DCE lt33 10000 to lt100000

100000 to 210000 12-DCE lt36 12-DCE lt44

TCE 17000 SVSV44 SVSV22SVSV33 NotePCE 31 TCE 51000TCE 210000 This is one interpretation only Other interpretations possible11-DCE lt14 PCE 39PCE 650012-DCE lt18 39 Estimated extent of plume has utilised groundwater11-DCE11-DCE 5900 12-DCE 21 concentration data12-DCE lt71

SVSV11 All concentrations are in (μgmsup3)

TCE 6300(LD) 12-DCE includes cis and trans PCE 78 LD = Laboratory duplicate result 11-DCE lt29

12-DCE lt38

12500 A3

0 25 50 m

CLIENT

SA EPA

PROJECT

EPA THEBARTON ASSESSMENT AREA - STAGE 1

TITLE

FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

PROJECT NO DATE CREATED

80607-1 290917

80607_Fig 6 - Soil Vapour TCE Concentration Plan - 1mai REV 2 gt 290917

LE

VE

L 1

12

4 S

OU

TH

TE

RR

AC

E

AD

EL

AID

E S

A 5

00

0

PH

(0

8)

82

32

90

88

F

AX

(0

8)

82

32

90

99

E

MA

IL

info

fy

fec

om

au

W

EB

fy

fec

om

au

A

BN

5

7 0

08

116

13

0

JAM

ES CO

NG

DO

N D

RIV

E

JAM

ES CO

NG

DO

N D

RIV

E

DEW

STREET

DEW

STREET

CHAPEL STREETCHAPEL STREET

PAR

KER

STREET

PAR

KER

STREET

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

POR

T RO

AD

LIGHT TERRACELIGHT TERRACE

DEW

STREET

DEW

STREET

WA

LSH ST

WA

LSH ST

AD

MELLA

STREET

AD

MELLA

STREET

ALB

ERT STR

EETA

LBER

T STREET

HO

LLAN

D ST

REET

HO

LLAN

D ST

REET

RANDOLPH STREET

RANDOLPH STREET

JAM

ES STREET

JAM

ES STREET

DOVE STREET

DOVE STREET

SMITH STREETSMITH STREET

MARIA STREETMARIA STREET

GEORGE STREETGEORGE STREET

KINTORE STREET

KINTORE STREET

PORT ROAD

PORT ROAD

PORT ROAD

PORT ROAD

CAW

THO

RN

E STR

EETC

AWTH

OR

NE ST

REET

DEVON STREETDEVON STREET

KINTORE STREETKINTORE STREET

GOODENOUGH STREETGOODENOUGH STREET

LIVESTR

ON

G PATH

WAY

LIVESTR

ON

G PATH

WAY

SV1SV1

SV2SV2SV3SV3SV4SV4

SV5SV5

SV7SV7SV8SV8

SV9SV9

SV10SV10

SV12SV12

SV6SV6

WWAA

LLSSHHSSTT

SSMMIITTHH SSTTRREEEETT

RRANDOLPH S

ANDOLPH STREETTREET

PPOORR

TTRR

OOAA

DD

PPOORR

TTRR

OOAA

DD

CCAAWW

TTHHOO

RRNN

EESSTT

RREEEETT

HHOO

LLLLAANN

DDSSTT

RREEEETT

DE

DEW

SW

STREET

TREET

JJAM

EA

MES S

S STREET

TREET

DDOOVVEE SSTTRREEEETT

00

LIGHT TERRLIGHT TERRAACECE

LLIIVVEESSTTRR

OONN

GGPPAATTHH

WWAAYY

AD

MELLA

SA

DM

ELLA STR

EETTR

EET

CHAPEL SCHAPEL STREETTREET

00

1010000000

AALLBB

EERRTT SSTTRR

EEEETT

100100 000

000 GEGEORORGE SGE STREETTREET

PPOORRTT RROOAADD 11000000000

000 PPOORRTT RROOAADD

DDEEWW

SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

100100000000

JJAAMM

EESSCC

OONN

GGDD

OONN

DDRR

IIVVEE

1010000000

KKIINNTTOORREE SSTTRREEEETT

00

KKIINNTTOORREE SSTTRREEEETT

PPAARR

KKEERR

SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

DDEEVVOONN SSTTRREEEETT

FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

SSV12V12 TCE 55

PCE lt45

11-DCE lt24

12-DCE lt32

TCE 260

PCE lt51

11-DCE lt28

12-DCE

SSVV99

lt37 LEGEND

SSV10V10 SOIL VAPOUR BORE

TCE 51 0 INFERRED TCE SOIL VAPOUR CONTOURPCE lt53

TCE 11000011-DCE lt29

EPA ASSESSMENT AREAPCE lt13012-DCE lt39

11-DCE lt69

CADASTRE12-DCE lt92 SVSV66SVSV77

SSVV88 TCE 150000

TCE 14000 56 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)PCETCE 160000 PCE 19 11-DCE lt30PCE 310 0 to lt10000SSVV5511-DCE lt26 12-DCE lt3911-DCE 33 10000 to lt100000

100000 to lt1000000 1000000

12-DCE lt35 12-DCE 20

TCE 43000 SVSV44 SVSV22SVSV33 NotePCE 90 TCE 940000(FD)TCE 1000000 This is one interpretation only Other interpretations possible11-DCE lt15 PCE 15000PCE 1500012-DCE 30 14000 Estimated extent of plume has utilised groundwater11-DCE11-DCE 14000 12-DCE lt930 concentration data12-DCE lt930

All concentrations are in (μgmsup3) 12-DCE includes cis and trans

SVSV11 TCE 21000

FD = Field Duplicate resultPCE 21

11-DCE lt57

12-DCE lt76

12500 A3

0 25 50 m

CLIENT

SA EPA

PROJECT

EPA THEBARTON ASSESSMENT AREA - STAGE 1

TITLE

FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

PROJECT NO DATE CREATED

80607-1 290917

80607_Fig 7 - Soil Vapour TCE Concentration Plan - 3m r2ai REV 2 gt 290917

LE

VE

L 1

12

4 S

OU

TH

TE

RR

AC

E

AD

EL

AID

E S

A 5

00

0

PH

(0

8)

82

32

90

88

F

AX

(0

8)

82

32

90

99

E

MA

IL

info

fy

fec

om

au

W

EB

fy

fec

om

au

A

BN

5

7 0

08

116

13

0

  • THEBARTON ASSESSMENT AREA STAGE 1 ENVIRONMENTAL ASSESSMENT FINAL REPORT | EPA REF 0524111 30 OCTOBER 2017 VOLUME 1 REPORT13
  • This report is formatted to print Double Sided
  • TITLE PAGE13
  • CONTENTS13
  • LIST OF ACRONYMS13
  • EXECUTIVE SUMMARY13
  • 1 INTRODUCTION
    • 11 Purpose
    • 12 General background information
    • 13 Definition of the assessment area
    • 14 Identification of contaminants of potential concern
    • 15 Objectives
      • 2 CHARACTERISATION OF THE ASSESSMENT AREA
        • 21 Site identification
        • 22 Regional geology and hydrogeology
        • 23 Data quality objectives
          • 3 SCOPE OF WORK
            • 31 Preliminary work
            • 32 Field investigation and laboratory analysis program
            • 33 Data interpretation
              • 4 METHODOLOGY
                • 41 Field methodologies
                • 42 Laboratory analysis
                  • 5 QUALITY ASSURANCE AND QUALITY CONTROL
                    • 51 Field QAQC
                    • 52 Laboratory QAQC
                    • 53 QAQC summary
                      • 6 ASSESSMENT CRITERIA
                        • 61 Groundwater
                        • 62 Soil vapour
                          • 7 RESULTS
                            • 71 Surface and sub surface soil conditions
                            • 72 Waterloo Membrane Samplerstrade
                            • 73 Groundwater
                            • 74 Soil vapour bores
                              • 8 GROUNDWATER FATE AND TRANSPORT MODELLING
                                • 81 Groundwater flow modelling
                                • 82 Solute transport modelling
                                  • 9 VAPOUR INTRUSION RISK ASSESSMENT
                                    • 91 Objective
                                    • 92 Areas of interest
                                    • 93 Risk assessment approach
                                    • 94 Tier 1 assessment
                                    • 95 Tier 2 assessment
                                    • 96 Conclusions
                                      • 10 CONCEPTUAL SITE MODEL
                                      • 11 CONCLUSIONS
                                      • 12 DATA GAPS
                                      • 13 REFERENCES
                                      • 14 STATEMENT OF LIMITATIONS
                                      • FIGURES13
                                      • FIGURE 1 SITE LOCATION AND ASSESSMENT AREA
                                      • FIGURE 2 ASSESSMENT POINT LOCATIONS
                                      • FIGURE 3 WATERLOO MEMBRANE SAMPLERTM TCE CONCENTRATION PLAN13
                                      • FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN
                                      • FIGURE 5 GROUNDWATER CONCENTRATION PLAN
                                      • FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)
                                      • FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

    THEBARTON ASSESSMENT AREA

    STAGE 1 ENVIRONMENTAL ASSESSMENT

    FINAL REPORT

    EPA REF 0524111

    PREPARED FOR Environment Protection Authority South Australia

    PREPARED BY Fyfe Pty Ltd

    ABN 57 008 116 130

    ADDRESS L1 124 South Terrace Adelaide SA 5000

    CONTACT Mr Marc Andrews Division Manager - Environment

    TELEPHONE direct 08 8201 9794 mobile 0408 805 264

    FACSIMILE 61 8 8201 9650

    EMAIL marcandrewsfyfecomau

    DATE 30102017

    REFERENCE 80607-1 REV1

    copyFyfe Pty Ltd 2017

    Proprietary Information Statement

    The information contained in this document produced by Fyfe Pty Ltd is solely for the use of the Client identified on the cover sheet for the purpose for which it has been prepared and Fyfe Pty Ltd undertakes no duty to or accepts any responsibility to any third party who may rely upon this document

    All rights reserved No section or element of this document may be removed from this document reproduced electronically stored or transmitted in any form without the written permission of Fyfe Pty Ltd

    Document Information

    Report prepared by Dr Ruth Keogh Principal Environmental Scientist Fyfe Pty Ltd Date 27 October 2017

    Report reviewed and approved by Division Manager - Environment Fyfe Pty Ltd Date 30 October 2017 Marc Andrews

    Client receipt by Shannon Thompson Advisor Site Contamination SA EPA Date 30 October 2017

    Revision History

    Revision Revision Status Date of Issue Prepared Reviewed Approved

    REV 0 Draft 6 October 2017 RK MJA MJA

    REV 1 Final 30 October 2017 RK MJA MJA

    Please note that when viewed electronically this document may contain pages that have been intentionally left blank These blank pages may occur because in consideration of the environment and for your convenience this document has been set up so that it can be printed correctly in double-sided format

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    CONTENTS

    Page

    VOLUME 1 REPORT

    LIST OF ACRONYMS V

    EXECUTIVE SUMMARY VIII

    1 INTRODUCTION 1

    11 Purpose 1

    12 General background information 1

    13 Definition of the assessment area 2

    14 Identification of contaminants of potential concern 2

    15 Objectives 3

    2 CHARACTERISATION OF THE ASSESSMENT AREA 5

    21 Site identification 5

    22 Regional geology and hydrogeology 5

    23 Data quality objectives 7

    3 SCOPE OF WORK 11

    31 Preliminary work 12

    32 Field investigation and laboratory analysis program 12

    33 Data interpretation 14

    4 METHODOLOGY 15

    41 Field methodologies 15

    42 Laboratory analysis 19

    5 QUALITY ASSURANCE AND QUALITY CONTROL 21

    51 Field QAQC 21

    52 Laboratory QAQC 24

    53 QAQC summary 26

    80607-1 REV1 30102017 PAGE I

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    6 ASSESSMENT CRITERIA 27

    61 Groundwater 27

    62 Soil vapour 29

    7 RESULTS 31

    71 Surface and sub surface soil conditions 31

    72 Waterloo Membrane Samplerstrade 32

    73 Groundwater 34

    74 Soil vapour bores 40

    8 GROUNDWATER FATE AND TRANSPORT MODELLING 43

    81 Groundwater flow modelling 43

    82 Solute transport modelling 43

    9 VAPOUR INTRUSION RISK ASSESSMENT 47

    91 Objective 47

    92 Areas of interest 47

    93 Risk assessment approach 47

    94 Tier 1 assessment 48

    95 Tier 2 assessment 49

    96 Conclusions 59

    10 CONCEPTUAL SITE MODEL 61

    11 CONCLUSIONS 67

    12 DATA GAPS 71

    13 REFERENCES 73

    14 STATEMENT OF LIMITATIONS 77

    PAGE II 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    LIST OF TABLES

    Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area 7

    Table 22 Data Quality Objectives 8 Table 31 Scope of field investigation program ndash May to August 2017 12 Table 32 Scope of laboratory testing program 13 Table 41 Summary of field methodologies 15 Table 51 Field QAQC procedures ndash Groundwater 22 Table 52 Field QAQC procedures ndash Soil vapour 23 Table 53 Laboratory QAQC procedures 25 Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area 28 Table 62 Sources of adopted groundwater assessment criteria 29 Table 71 Detectable Waterloo Membrane Samplertrade CHC results 32 Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units 33 Table 73 Hydraulic conductivities (rising and falling head tests) 35 Table 74 Detectable groundwater CHC results 37 Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area 41 Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores 42 Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs 49 Table 92 Tier 2 vapour intrusion modelling ndash building input parameters 51 Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters 52 Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air 52 Table 95 Summary of chemical parameters adopted for vapour intrusion modelling 52 Table 96 Comparison of predicted residential indoor air concentrations with SA EPA

    response levels 54 Table 97 Summary of model input parameters subjected to sensitivity analysis 55 Table 98 Exposure parameters ndash Commercialindustrial workers 58 Table 99 Adopted inhalation toxicity reference values 58 Table 910 Summary of properties with predicted indoor air concentrations

    (residential crawl space) above adopted EPA response levels 59 Table 101 Summary of existing information for the Thebarton EPA Assessment Area 61

    LIST OF FIGURES (in text)

    Figure 71 Piper diagram 39 Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green)

    relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple) 46

    Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels 50

    80607-1 REV1 30102017 PAGE III

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    FIGURES follow page 79

    Figure 1 Site Location and Assessment Area Figure 2 Assessment Point Locations Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan Figure 4 Groundwater Elevation Contour Plan Figure 5 Groundwater Concentration Plan Figure 6 Soil Vapour Concentration Plan (10 m) Figure 7 Soil Vapour Concentration Plan (30 m)

    VOLUME 2 APPENDICES

    APPENDICES

    Appendix A Historical Report Summary Appendix B Historical Information Supplied by the EPA Appendix C DEWNR Registered Groundwater Database Search Results Appendix D Groundwater Well Permits Appendix E Field Sampling Sheets ndash Groundwater Appendix F Survey Data Appendix G Certified Laboratory Certificates and Chain of Custody Documentation Appendix H Groundwater Well Log Reports Appendix I WMStrade Borehole Log Reports Appendix J Soil Vapour Borehole Log Reports Appendix K Waste Transport Certificates Appendix L Tabulated Results ndash Soil Vapour Geotechnical and Groundwater Appendix M Equipment Calibration Records Appendix N Drill Core Photographs Appendix O Arcadis Groundwater Fate and Transport Modelling Report Appendix P Arcadis Vapour Intrusion Risk Assessment Report

    PAGE IV 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    LIST OF ACRONYMS

    AER Air Exchange Rate

    AF Attenuation Factor

    AHD Australian Height Datum

    ANZECC Australian and New Zealand Environment and Conservation Council

    ARMCANZ Agriculture and Resource Management Council of Australia and New Zealand

    ASC Assessment of Site Contamination

    ASTM American Standard Testing Material

    AT Averaging Time

    ATSDR Agency for Toxic Substances and Disease Registry

    AWQC Australian Water Quality Centre

    BGL Below Ground Level

    BTEX Benzene Toluene Ethylbenzene Xylenes

    BTOC Below Top of Casing

    BUA Beneficial Use Assessment

    CBD Central Business District

    CHC Chlorinated Hydrocarbon Compound

    COC Chain of Custody

    COPC Contaminants of Potential Concern

    CRC CARE Cooperative Research Centre for Contamination Assessment and Remediation of the Environment

    CSM Conceptual Site Model

    11-DCA 11-dichloroethane

    11-DCE 11-dichloroethene

    12-DCE 12-dichloroethene

    DCE Dichloroethene

    DEC Department of Environment and Conservation

    DEWNR Department of Environment Water and Natural Resources

    DNAPL Dense Non-Aqueous Phase Liquid

    DO Dissolved Oxygen

    DQI Data Quality Indicator

    DQO Data Quality Objective

    EC Electrical Conductivity

    ED Exposure Duration

    80607-1 REV1 30102017 PAGE V

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    EF Exposure Frequency

    EMP Environmental Management Plan

    EPA Environment Protection Authority

    EPC Exposure Point Concentration

    EPP Environment Protection Policy

    ET Exposure Time

    GPA Groundwater Prohibition Area

    GPR Ground Penetrating Radar

    GPS Global Positioning System

    HHRA Human Health Risk Assessment

    HIL Health Investigation Level

    HSP Health and safety Plan

    IPA Isopropyl Alcohol (isopropanol or 2-propanol)

    IRIS Integrated Risk Information System

    ITRC Interstate Technology and Regulatory Council

    JampE Johnson and Ettinger

    JHA Job Hazard Analysis

    LNAPL Light Non-Aqueous Phase Liquid

    LOR Limit of Reporting

    MGA Map Grid of Australia

    MQO Measuring Quality Objectives

    MTC Mass Transfer Co-efficient

    NA Not Applicable

    NAPL Non-Aqueous Phase Liquid

    NATA National Association of Testing Authorities

    ND Non Detect

    NEPM National Environment Protection Measure

    NHMRC National Health and Medical Research Council

    NJDEP New Jersey Department of Environmental Protection

    NRMMC National Resource Management Ministerial Council

    PAH Polycyclic Aromatic Hydrocarbons

    PCE Tetrachloroethene (perchloroethylene)

    PID Photoionisation Detector

    PQL Practical Quantification Limit

    PSD Particle Size Distribution

    QA Quality Assurance

    80607-1 REV1 30102017 PAGE VI

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    QC Quality Control

    RAIS Risk Assessment Information System

    RFQ Request for Quote

    REM Resource and Environmental Management

    RPD Relative Percentage Difference

    RSL Regional Screening Level

    SA EPA South Australian Environment Protection Authority

    SAQP Sampling and Analysis Quality Plan

    SOP Standard Operating Procedure

    SVOC Semi-Volatile Organic Compound

    SWL Standing Water Level

    SWMS Safe Work Method Statement

    111-TCA 111-trichloroethane

    TCE Trichloroethene

    TDS Total Dissolved Solids

    TRH Total Recoverable Hydrocarbons1

    TRV Toxicity Reference Value

    US EPA United Stated Environment Protection Agency

    USGS United States Geological Survey

    VC Vinyl Chloride

    VIRA Vapour Intrusion Risk Assessment

    VOC Volatile Organic Compound

    VOCC Volatile Organic Chlorinated Compound

    WHO World Health Organisation

    WMStrade Waterloo Membrane Samplertrade

    TRH = measurable amount of petroleum-based hydrocarbon (ie complex mixture of crude oil and natural gas (gt 250 compounds) including aromatics aliphatics paraffins unsaturated alkanes and naphthalenes) plus various other compounds including fatty acids esters humic acids phthalates and sterols

    80607-1 REV1 30102017 PAGE VII

    1

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    EXECUTIVE SUMMARY

    Background information

    An approximate 27 hectare mixed use area of Thebarton has been designated by the South Australian Environment Protection Authority (EPA) as the Thebarton EPA Assessment Area

    The former Austral sheet metal works (Austral) property located over multiple allotments between George and Maria Streets from the 1920s until the 1960s-1970s has been identified as a possible source of dissolved phase groundwater chlorinated hydrocarbon (CHC) contamination Groundwater CHC impacts within the uppermost (Quaternary ndash Q1) aquifer were identified as extending in a general north-westerly direction (consistent with regional groundwater flow direction) from the south-eastern portion of the Thebarton EPA Assessment Area and having resulted in the generation of soil vapour containing elevated concentrations of CHC

    The boundaries of the Thebarton EPA Assessment Area were established on the basis of the following

    the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street (part of the former Austral property) and 39 Smith Street (hydraulically down-gradient of the former Austral property) in Thebarton

    the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

    the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

    Key objectives

    The results of the recent investigations undertaken by Fyfe have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties within the Thebarton EPA Assessment Area

    The key objectives detailed by the EPA were to

    further delineate the chlorinated hydrocarbon contamination in groundwater

    further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

    undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

    80607-1 REV1 30102017 PAGE VIII

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    With respect to the VIRA the EPA requested that there be specific consideration of

    residential properties (slab on grade)

    residential properties (crawl space)

    residential properties (with basement) and

    trenchmaintenanceutility workers that may be working in the vicinity of the contamination

    Site conditions

    Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were identified within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m below ground level (BGL) during the drilling of groundwater well MW17 the latter consistent with the depth of groundwater within the Q1 aquifer

    Soil

    Groundwater within the Q1 aquifer is located at a depth of approximately 123 to Groundwater 159 m BGL and flows in a general north-westerly direction The closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred and the groundwater gradient is relatively flat (ie 000062 to 00012)

    Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified (based on factors such a groundwater salinity registered bore use and the locations of potential sensitive receptors) as including domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux) and possibly also potable

    Contaminants of Potential Concern (COPC)

    The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans-) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

    80607-1 REV1 30102017 PAGE IX

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Scope of work

    A groundwater and soil vapour monitoring program was undertaken by Fyfe across the Thebarton EPA Assessment Area between May and August 2017 It involved the following scope of work

    installation of a total of 41 WMStrade units to 1 m BGL in an approximate grid-pattern across the entire assessment area (Round 1) and at specific targeted locations (Round 2) followed by laboratory analysis of retrieved sample units for specific CHC

    drilling and installation of 25 groundwater wells to depths of between 15 and 19 m BGL including a background well to the east of the southern portion of the assessment area

    testing of 30 selected groundwater well drill core samples for geotechnical parameters

    gauging and sampling of the 25 newly installed groundwater wells as well as an existing well located in Admella Street followed by laboratory analysis of all samples for specific CHC and 10 selected samples for major cationsanions natural attenuation parameters and additional nutrients

    aquifer permeability (rising and falling head ldquoslugrdquo) testing of 10 groundwater wells

    drilling and installation of 13 soil vapour bores including 11 nested bores (ie to 1 and 3 m BGL) and two bores to 1 m BGL and

    sampling of all soil vapour bores followed by laboratory analysis of samples for specific CHC and general gases

    The soil vapour data were used to undertake a VIRA aimed at predicting indoor air concentrations of TCE under various land use and building construction scenarios In order to validate the results of the modelling which includes a number of conservative assumptions and is therefore expected to over-estimate potential risk the EPA has commissioned indoor air monitoring in a number of residential properties within the Thebarton EPA Assessment Area ndash the indoor air monitoring results will be reported under separate cover

    Groundwater fate and transport modelling was undertaken to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton EPA Assessment Area The provision of this information is aimed at supporting the definition (extent and geometry) of a potential future Groundwater Prohibition Area (GPA) to be designated by the EPA in accordance with the provisions of Section S103S of the Environment Protection Act 1993

    80607-1 REV1 30102017 PAGE X

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Identified impacts

    Contaminants identified in the Q1 aquifer beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down

    Groundwater

    (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested

    The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected (Austral) source site in accordance with the predominant flow direction associated with the Q1 aquifer The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) ndash whereas its north-western extent has not yet been determined the groundwater CHC plume has been delineated in all other directions

    Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion

    Soil vapour

    The soil vapour samples with the maximum TCE concentrations also had the highest PCE and 11-DCE concentrations (or elevated laboratory limits of reporting (LOR)) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-)

    Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE exceeded the adopted health investigation levels (HILs) for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE degradation has not yet resulted in its production

    Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

    80607-1 REV1 30102017 PAGE XI

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Assessment of risk

    Measured concentrations of TCE exceeded the adopted assessment criteria for potable use andor primary contact recreation in wells located on Admella Maria George Albert Chapel and Dew Streets as well as Light Terrace ndash with the highest concentrations corresponding to the ldquocorerdquo area of the plume One well on Albert Street also contained a concentration of carbon tetrachloride that exceeded the respective potable criterion

    Groundwater risks

    Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous

    Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

    The groundwater modelling undertaken by Arcadis involved the development of an Groundwater fate and transport initial groundwater flow model using MODFLOW followed by the development of a modelling site-specific (three-dimensional) solute transport model using the MT3DMS transport

    code

    The results of this modelling were interpreted to indicate the following

    although scattered detectable concentrations of 12-DCE have been measured in groundwater across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE daughter products indicate that substantial dechlorination is not occurring and

    the dissolved phase groundwater TCE plume is predicted to extend by another 500 m (ie beyond the boundaries of the current Thebarton EPA Assessment Area) over the next 100 years whereas no significant lateral plume expansion is expected

    The VIRA undertaken by Arcadis involved a two-tier assessment approach Whereas Vapour intrusion the Tier 1 screening risk assessment compared the measured soil vapour CHC concentrations to (modified) guideline values the Tier 2 risk assessment involved the application of the Johnson and Ettinger vapour intrusion model to predict indoor air CHC concentrations for residential (slab on grade crawl space and basement construction) and commercialindustrial (slab on grade construction) properties across the assessment area Site-specific geotechnical parameters and soil vapour data collected from 1 and 3 m BGL throughout the Thebarton EPA Assessment Area were used in the modelling It should be noted that overall the vapour modelling

    risks

    80607-1 REV1 30102017 PAGE XII

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

    The results of the VIRA with respect to the predicted indoor air concentrations of TCE within residential properties (assuming crawl space construction) versus adopted EPA response levels indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air that require further action as follows

    10 properties within the investigation range (2 to lt20 microgm3)

    eight properties within the intervention range (20 to lt200 microgm3) and

    three properties within accelerated intervention range (ge200 microgm3)

    All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises

    Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which is expected to be overly-conservative) ndash these results will be documented in a subsequent report

    Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie as determined for the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

    A qualitative assessment of potential risks to subsurface trenchmaintenanceutility workers indicated that exposure management may be required in areas where TCE concentrations at 1 m BGL are above 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific health and safety plan (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a photoionisation detector (PID) unit providing increased ventilation and using appropriate personal protective equipment (eg gas masks) as required

    80607-1 REV1 30102017 PAGE XIII

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Data gaps

    Based on the results obtained during the recent Fyfe investigations as well as available historical information the following data gaps have been identified for the Thebarton EPA Assessment Area

    property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

    groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

    the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

    the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

    Notes ie the interim soil vapour HILs adopted from the National Environment (Assessment of Site Contamination) Measure 1999 (as revised in 2013 ndash ie the ASC NEPM (1999)) but assuming a sub-slab to indoor air attenuation factor of 003 as compared to the value of 01 adopted by the ASC NEPM (1999)

    80607-1 REV1 30102017 PAGE XIV

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    1 INTRODUCTION

    11 Purpose

    Fyfe Pty Ltd (Fyfe) was commissioned by the South Australian Environment Protection Authority (SA EPA referred to herein as the EPA) to undertake Stage 1 groundwater and soil vapour investigation works groundwater fate and transport modelling and a human health vapour intrusion risk assessment (VIRA) within an EPA designated assessment area located within Thebarton South Australia (herein referred to as the Thebarton EPA Assessment Area) The location and extent of the Thebarton EPA Assessment Area referenced within this document is identified on Figure 1

    12 General background information

    Previous environmental assessment work undertaken since 1994 (as summarised in Appendix A) combined with historical information provided by the EPA (as included in Appendix B) indicates that the Thebarton EPA Assessment Area has been used for mixed residential and commercialindustrial purposes over time

    Groundwater impacts2 identified within the uppermost (Quaternary ndash Q1) aquifer in the vicinity of the former Austral sheet metal works (Austral) on George Street included both petroleum hydrocarbons (ie diesel fuel) as well as chlorinated hydrocarbon compounds (CHC) such as trichloroethene (TCE) and were first notified to the EPA in 2006

    Available historical information for the Austral property (ie the suspected source site) indicates that it operated from the 1920s until the 1960s-1970s and occupied an extensive area of Thebarton including

    part of the southern side of George Street extending from about half way between East Terrace3 and Admella Street (ie 11-25 George Street) to the west of Admella Street (ie 31-35 George Street)

    the entire northern side of Maria Street from East Terrace to the west of Admella Street

    part of the southern side of Maria Street (ie from 21 Maria Street) to Admella Street and

    25-27 East Terrace

    2 Note that the term ldquoimpactrdquo has been used by Fyfe to indicate identified concentrations of compounds (specifically chlorinated hydrocarbons) that are not naturally occurring (ie concentrations above background that have resulted from anthropogenic activities) The use of this term does not denote that the presence of these compounds represents a risk to either human health or the environment and the term ldquoimpactrdquo is therefore not directly interchangeable with the term ldquoSite Contaminationrdquo the latter defined under the Environment Protection Act 1993 to include actual or potential harm to human health andor the environment

    3 now James Congdon Drive

    80607-1 REV1 30102017 PAGE 1

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Historical newspaper articles described the Austral property as hosting a factory that extended over more than three acres and included an electroplating facility In 1938 it was described as the largest aluminium utensil manufacturing company in the southern hemisphere

    Other potential sources of groundwater contamination4 identified within the Thebarton EPA Assessment Area include a former gas works (ie located to the south and south-east of the Austral property and including the current Ice Arena property) a mechanicrsquos workshop another sheet metal working facility and a farm machinery manufacturer

    The Stage 1 assessment work described herein was commissioned by the EPA to determine whether historical contamination in the vicinity of George Street was presenting a risk to human health or the environment

    13 Definition of the assessment area

    As detailed on Figure 1 the current EPA Assessment Area covers an area of approximately 27 ha within the suburb of Thebarton located approximately 2 km north-west of the Adelaide central business district (CBD)

    The boundaries of the Thebarton EPA Assessment Area were established by the EPA on the basis of the following

    the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street and 39 Smith Street in Thebarton (refer to Appendix A)

    the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

    the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

    14 Identification of contaminants of potential concern

    The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

    Site Contamination is defined by the Environment Protection Act 1993 as existing if chemical substances are present on or below the surface of a site in concentrations above background the contaminants are there as a result of activity at the site or elsewhere and their presence has resulted in actual or potential harm (that is not trivial) to the health and safety of human beings taking into account current and proposed land uses or water or the environment

    PAGE 2 80607-1 REV1 30102017

    4

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    15 Objectives

    As defined by the EPA the key objectives of the recent Stage 1 environmental assessment program undertaken within the Thebarton EPA Assessment Area (refer to Figure 1) were to

    further delineate the chlorinated hydrocarbon contamination in groundwater

    further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

    undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

    With respect to the VIRA the EPA requested that there be specific consideration of

    residential properties (slab on grade)

    residential properties (crawl space)

    residential properties (with basement) and

    trenchmaintenanceutility workers that may be working in the vicinity of the contamination

    80607-1 REV1 30102017 PAGE 3

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    2 CHARACTERISATION OF THE ASSESSMENT AREA

    21 Site identification

    For the purpose of this investigation program the Thebarton EPA Assessment Area (as delineated in Figure 1) has been defined by the following roadways

    North northern verge of Smith Street

    South Maria Street (between Dew Street and Albert Street) portion of Parker Street (between Maria Street and Goodenough Street) and Goodenough Street (between Parker Street and James Congdon Drive)

    East western verge of Port Road and James Congdon Drive and

    West western verge of Dew Street

    22 Regional geology and hydrogeology

    221 Geology

    The Thebarton area is located within the Adelaide Plains approximately 8 km to the east of Gulf St Vincent and to the west of the Para Fault It lies within the Golden Grove ndash Adelaide Embayment area of the St Vincent Basin which consists of a succession of Tertiary and Quaternary age sediments (with thicknesses of up to 600 m) overlying basement rocks

    The 1250000 Adelaide geological map (SA Department of Mines and Energy 1969) indicates that the near-surface geology of the area consists primarily of Quaternary aged soils and sediments including the Pooraka and Hindmarsh Clay formations The Pleistocene aged Pooraka Formation generally comprises a thickness of approximately 10 m and is of alluvial origin comprising sandy clays and clayey to sandy silts interbedded with layers of clay sand andor gravel The underlying Pleistocene aged Hindmarsh Clay Formation represents the basal unit of the Adelaide Plains and has a maximum general thickness of more than 100 m It generally comprises a basal gravel layer a middle layer of mottled medium to high plasticity (red-brown yellow brown greygreen to orange) often stiff to hard clays and an upper layer of fluvial and alluvial red-brown silty sand Gerges (1999) describes Hindmarsh Clay as comprising a mottled brown to pale olive grey predominantly clay formation that becomes green grey towards the basal section (approximately 16 to 20 m below ground level (BGL)) and is characterised by an increasing gravel content with depth

    Underlying the Hindmarsh Clay are sands and limestone of Tertiary age which are in turn underlain by metamorphosed basement rock of the Proterozoic Umberatana Group

    80607-1 REV1 30102017 PAGE 5

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    222 Hydrogeology

    According to Gerges (2006) the aquifers identified within the Quaternary aged sediments of the Adelaide Plains are typically found within the coarser interbedded silt sand and gravel layers of the Hindmarsh Clay Formation and vary greatly in thickness (typically from 1 to 18 m) lithology and hydraulic conductivity Confining beds between the Quaternary aquifers consist of clay and silt layers and range in thickness from 1 to 20 m These confining beds vary in terms of the amount of coarser grained material they contain their bulk hydraulic conductivity andor the presence and density of fractures In addition their absence in some areas allows direct hydraulic connection between the aquifers

    The Thebarton area is located within Hydrogeological Zone 3 (Subzone 3E) of Gerges (2006) This zone contains five to six Quaternary aquifers and three to four almost flat-lying Tertiary aquifers The first Tertiary aquifer estimated by Gerges (2006) to be intersected at a depth of approximately 130 m BGL near the Para Fault is most frequently accessed for industrial and recreational groundwater use

    The Q1 aquifer assessed as part of the current investigations is typically located at depths of between 3 and 10 m BGL beneath the Adelaide Plains with an average thickness of 2 m The Q1 aquifer contains water of variable salinity with Subzone 3E including a range of 500 to 3500 mgL total dissolved solids (TDS) The gradient of the Q1 aquifer is generally flat (particularly to the west of the Para Fault) and flow direction is typically towards the north-west

    A search of the registered bore database maintained by the Department of Environment Water and Natural Resources (DEWNR (2017) WaterConnect database) identified 59 bores within the general Thebarton area of which 18 are located in the Thebarton EPA Assessment Area Although eight bores were installed for monitoring purposes on or immediately adjacent to the property located at 31-37 George Street (ie part of the former Austral facility) it is understood that only one bore (6628-21951 ndash located within the Admella Street roadway intersecting the Q1 aquifer and identified as MW01 in Appendix A but MW02 by Fyfe5) remains in situ

    In addition to numerous monitoringinvestigationobservation bores the Q1 aquifer within the general (ie broader) Thebarton area is recorded in the DEWNR (2017) database as being accessed for drainage domestic and industrial purposes

    DEWNR (2017) information for registered bores located within the general Thebarton area is included in Appendix C whereas information for bores located within the Thebarton EPA Assessment Area (excluding those associated with the property at 31-37 George Street and installed solely for monitoring purposes6) is summarised in Table 21

    5 This existing groundwater well was identified as MW02 by Fyfe in accordance with the markings on the gatic cover and the DEWNR (2017) WaterConnect bore identification details although it was originally installed as MW01 by REM (refer to discussion of previous reports in Appendix A)

    6 ie 6628-21951 6628-21952 6628-22229 to 6628-22233 and 6628-22236

    PAGE 6 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area

    Bore ID Location Purpose Status Maximu SWL Salinity Yield Aquifer m well (m (mgL (Lsec

    Tertiary (T1)

    depth BGL) TDS) ) (m BGL)

    125 6628-516 Coca Cola plant Rehabilitated 138 1963 794

    6628-1435 Coca Cola plant Backfilled 184 212 921 392 Tertiary (T1)

    6628-4576 Corner of Admella amp Chapel Streets

    125 1454 445 Tertiary (T1)

    6628-7724 Coca Cola plant Observation 155 2017 1272 1516 Tertiary (T1)

    6628-7725 Coca Cola plant Observation 127 3016 1100 1005 Tertiary (T1)

    6628-12516 Coca Cola plant Industrial Backfilled 210 212 1300 1875 Tertiary (T1)

    6628-20663 39 Smith Street Irrigation 121 1105 50 Tertiary (T1)

    6628-20969 39 Smith Street Industrial 30 14 1535 25 Quaternary (Q1)

    6628shy21951

    Admella Street 20 Quaternary (Q1)

    6628-22395 21 James Congdon Drive

    20 157 1541 05 Quaternary

    6628-23525 41 Maria Street 206 273 1078 10 Tertiary (T1)

    Notes Shading indicates that information was not recorded in the database as interpreted from information provided in the database ndash approximate only in some instances

    ie MW02 as included in the groundwater monitoring program of Fyfe ndash refer to Table 31 Abbreviations BGL = below ground level SWL = standing water level TDS = total dissolved solids

    23 Data quality objectives

    The Data Quality Objective (DQO) process as described in Australian Standard AS44821-2005 and the National Environment Protection (Assessment of Site Contamination) Measure (ASC NEPM 1999)7

    Schedule B2 Guideline on Data Collection Sample Design and Reporting and more fully documented in the NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme involves a seven-step iterative approach that was initially developed by the United States Environment Protection Agency (US EPA) to facilitate the systematic planning and verification of contaminated sites assessment projects

    As stated in Schedule B2 of the ASC NEPM (1999) the first six steps of the DQO process comprise the development of qualitative and quantitative statements that define the objectives of the site assessment program and the quantity and quality of data needed to inform risk-based decisions These steps enable the

    All references to the ASC NEPM (1999) refer to the version amended on 16 May 2013

    80607-1 REV1 30102017 PAGE 7

    7

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    project team to communicate the goals decisions constraints (eg time budget) and uncertainties associated with the project and detail how they are to be addressed The seventh step comprises the development of a Sampling and Analysis Quality Plan (SAQP) to generate the data required to adequately characterise site contamination issues and assess their associated potential environmental and human health risks under the proposed land use scenario

    The DQOs defined for the Thebarton EPA Assessment Area are summarised in Table 22

    Table 22 Data Quality Objectives

    Objective Comment

    Step 1 ndash Statement of the Problem According to information provided to Fyfe by the EPA (as summarised in Appendix A) a property located at 31-37 George Street (immediately west of Admella Street) in Thebarton and historically occupied by part of the Austral facility had been found to be underlain by groundwater CHC (primarily TCE) impacts More recent reporting to the EPA for a property at 39 Smith Street located approximately 350 m north-west (and hydraulically down-gradient) of the George Street property indicated that detectable CHC (predominantly TCE) were also present within groundwater Since this area of Thebarton is occupied by a mixture of commercialindustrial and residential properties and the source and extent of the CHC impacts within the Q1 aquifer had not yet been determined potential risks to human health andor the environment had yet to be assessed

    Step 2 ndash The Decision that Needs The assessment works commissioned by the EPA were necessitated to to Result from the Investigation investigate the source extent and magnitude of the groundwater CHC

    contamination beneath a designated area of Thebarton (ie that included both the George Street and Smith Street properties) and to understand the possible risk to public health from potential vapour generation Fyfe have therefore undertaken vapour modelling and intrusion risk assessment works aimed at evaluating whether concentrations of identified groundwater andor soil vapour contaminants pose an unacceptable risk to human health In addition groundwater fate and transport modelling has been undertaken to predict the extent of the plume This will assist the EPA to determine a potential future Groundwater Prohibition Area (GPA) in accordance with the provisions of Section 103S of the Environment Protection Act 1993

    Step 3 ndash Inputs to the Decision The information that was required to resolve the decision statement included the collection of physical and chemical data from across the Thebarton EPA Assessment Area The collected data as well as physical observations regarding the geology of the area and possible preferential contaminant pathways was used to determine potential risks to human health via groundwater fate and transport and vapour intrusion modelling

    Step 4 ndash Boundaries of the Investigation

    The lateral boundaries of the Thebarton EPA Assessment Area are as defined in Sections 13 and 21 as depicted on Figure 1 Vertically the investigations extended as far as the maximum drilled depth (19 m BGL)

    Step 5 ndash Decision Rules The decision rule will be based upon the identification of predicted indoor air concentrations of CHC compounds associated with groundwater andor soil vapour impacts which exceed adopted response levels

    PAGE 8 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Objective Comment

    Step 6 ndash Decision Error Tolerances The purpose of establishing decision error tolerance is to control the acceptable degree of uncertainty upon which decisions are made in order to avoid the making of an incorrect decision and to enable identification of additional investigation monitoring or remediation activities required on the basis of accurate data for the protection of human health and the environment The Measuring Quality Objectives (MQO) include the quality assurance (QA) activities that were conducted during the assessment the quality control (QC) acceptance criteria applicable to the assessment and the adopted Data Quality Indicators (DQIs) as follows (and further discussed in Section 5) completeness ndash a measure of the amount of useable data from a data

    collection activity comparability ndash the confidence (expressed qualitatively) that data may be

    considered to be equivalent for each sampling and analytical event representativeness ndash the confidence (expressed qualitatively) that data

    are representative of each media present on the site precision ndash a quantitative measure of the variability (or reproducibility) of

    data and accuracy (bias) ndash a quantitative measure of the closeness of reported data

    to the true value

    Step 7 ndash Optimisation of the Data collection was undertaken in general accordance with the Sample Collection Design methodologies outlined in the relevant documentsguidelines referenced

    throughout this report As determined by the EPA the data collection design included targeted sampling to investigate and delineate areas of potential groundwater and soil vapour contamination and to assess potential associated human health risks

    80607-1 REV1 30102017 PAGE 9

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    3 SCOPE OF WORK

    The scope of work undertaken by Fyfe was generally consistent with that requested within the original EPA request for quote (RFQ) dated 27 March 2017 Some modifications to the original workscope occurred based on site findings and additional site information was collected where required and as agreed with the EPA in order to achieve the EPArsquos project objectives outlined in Section 15

    As identified in the RFQ the scope of work was designed to

    provide an initial delineation of CHC impacts in soil vapour through the deployment of Waterloo Membrane Samplers (WMStrade) as a screening tool

    further delineate the previously identified CHC impacts in groundwater

    decide based on the results of the WMStrade and groundwater results the need for the number of and the locations of permanent soil vapour monitoring bores

    identify the nature extent and potential source area(s) of the identified CHC impacts in groundwater andor soil vapour

    determine the likely fate and transport of the groundwater CHC plume to support the establishment of a potential future GPA

    determine the potential human health (including vapour intrusion) risk(s) on the basis of the data collected and

    ascertain whether or not a public health risk exists within the Thebarton EPA Assessment Area

    The scope of work is further detailed in Section 32 Variations from the scope of work originally requested in the EPA RFQ were agreed with the EPA during the course of the project and included the following

    deployment of an additional four WMStrade units ndash ie 41 in total as compared to the original allowance of 37

    installation (and sampling) of an additional six nested soil vapour bores (to depths of 1 and 3 m BGL) ndash ie 11 in total as compared to the original allowance of five

    installation (and sampling) two individually located (ie as opposed to the nested locations) soil vapour bores to a depth of 1 m BGL ndash ie as compared to the original allowance of 10

    installation (and sampling) of 25 groundwater monitoring wells ndash ie as compared to the original allowance of 20 and

    sampling of an existing well in Admella Street (MW02) ndash ie not included in the original EPA scope

    80607-1 REV1 30102017 PAGE 11

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    31 Preliminary work

    Preliminary work involved the following

    review and summation of all available historical reports (as supplied by the EPA) ndash refer to Appendix A

    development of a preliminary (working) conceptual site model (CSM) based on a review of the historical data

    preparation of a detailed health and safety plan covering all aspects and stages of the work and

    detailed planning with key stakeholders prior to the execution of the field investigation program

    32 Field investigation and laboratory analysis program

    The scope of the field investigation program undertaken by Fyfe between 31 May and 28 August 2017 is summarised in Table 31 whereas the scope of the laboratory testing program is summarised in Table 32

    A plan showing the various assessment point locations is included as Figure 2

    Table 31 Scope of field investigation program ndash May to August 2017

    Scope Item Description of works Date of works

    Passive soil vapour sampling ndash Round 1

    Thirty-seven WMStrade units identified as WMS 1 to WMS 37 were installed within the soil profile to 1 m BGL at scattered (approximately grid-like) locations across the Thebarton EPA Assessment Area

    31 May and 1 to 2 June

    The WMStrade units were extracted and forwarded to the analytical laboratory 7 June

    Soil bores were located using a hand-held global positioning system (GPS) unit before being backfilled with (drillerrsquos) sand

    7 August

    Monitoring well drilling and installation

    Individual groundwater well permits were obtained from DEWNR prior to well installation ndash copies of the well permits are included in Appendix D Groundwater monitoring wells (MW1 MW3 and MW5 to MW26) were installed to depths of between 15 and 19 m BGL at 24 locations across the Thebarton EPA Assessment Area Background well MW4 was installed to 19 m BGL within a public recreational area located across James Congdon Drive to the east (ie near the south-eastern corner of the Thebarton EPA Assessment Area) All 25 newly installed wells were developed following installation

    28 to 30 June 3 to 7 July and 10 to 14 July

    Geotechnical soil testing

    Intact soil cores collected during the drilling of 10 groundwater wells (MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25) were forwarded to the analytical laboratory for geotechnical testing

    Groundwater gauging

    All 25 newly installed monitoring wells (MW1 and MW3 to MW26) as well as the existing Admella Street well (MW02) were gauged to assess total well depth standing water level (SWL) and the presenceabsence of non aqueous phase liquid (NAPL) This was undertaken as a discrete event prior to the commencement of groundwater sampling

    18 July

    PAGE 12 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Scope Item Description of works Date of works

    Groundwater sampling

    All 26 existing and newly installed wells were sampled using a combination of low flow (micropurge) and HydraSleevetrade sampling techniques (as recorded on the field sampling sheets in Appendix E) ndash samples were forwarded to the analytical laboratories

    18 to 21 and 24 to 25 July

    Aquifer testing Aquifer permeability (slug) testing was undertaken on 10 wells (MW02 MW3 MW7 MW14 MW17 MW20 MW21 MW23 MW25 and MW26) Data was subsequently evaluated by Arcadis Pty Ltd (Arcadis) to estimate the hydraulic conductivity of the aquifer beneath the Thebarton EPA Assessment Area (refer to Section 732)

    28 July

    Soil vapour bore drilling and installation

    Following the receipt of the groundwater data 11 nested soil vapour bores (SV1 to SV10 and SV12) were installed to a depth of 1 and 3 m BGL at selected locations within the Thebarton EPA Assessment Area Two additional soil vapour bores (SV11 and SV13) were installed to a depth of 1 m BGL

    18 21 and 22 August

    Active soil vapour sampling

    Sampling of soil vapour bores was undertaken using summa canister (TO-15) sample collection methods Vapour (canister) and general gas (Tedlar bag) samples were extracted from all 13 locations (ie SV1 to SV13) including the 11 nested bores

    24 August

    Passive soil vapour sampling ndash Round 2

    Following the receipt of the groundwater data and for the purposes of comparison with the soil vapour bore data an additional four WMStrade units (WMS 38 to WMS 41) were installed within the soil profile to 1 m BGL at targeted locations across the Thebarton EPA Assessment Area (ie within approximately 1 m of soil vapour bores SV2 SV4 SV5 and SV7) Soil bores were located using a hand-held GPS unit

    18 August

    The WMStrade units were extracted and forwarded to the analytical laboratory and the soil bores were backfilled with (drillerrsquos) sand

    24 August

    Surveying The locations of all soil vapour bores and groundwater wells were surveyed by a licensed surveyor relative to the Map Grid of Australia (MGA) 1994 and the top of each bore was surveyed relative to Australian Height Datum (AHD) The survey data are included in Appendix F

    22 July and 28 August

    Notes as determined by the EPA

    Table 32 Scope of laboratory testing program

    Scope Item Description of works

    Soil geotechnical testing

    Soil samples from each of three depths within core samples collected during the drilling of groundwater wells MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25 were analysed for particle size distribution (PSD) moisture content including degree of saturation bulk density dry density and specific gravity void ratio and porosity

    80607-1 REV1 30102017 PAGE 13

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Scope Item Description of works

    Groundwater testing Groundwater samples from all 26 wells were analysed for the COPC detailed in Section 14 As requested by the EPA groundwater samples from selected wells (MW02 MW5 MW8 MW9 MW12 MW17 MW21 MW22 MW23 and MW26) were also analysed for the following major cations and anions (calcium magnesium sodium potassium chloride and alkalinity)

    and natural attenuation parameters (carbon dioxide (CO2) sulfate iron manganese nitrate) Additional components reported by the analytical laboratory included nitrite and nitrate + nitrite

    Soil vapour testing The WMStrade units deployed during each of Rounds 1 and 2 were analysed for the COPC detailed in Section 14 The soil vapour (summa canister) samples were analysed for the COPC detailed in Section 14 as well as 2-propanol and general gases (helium hydrogen oxygen nitrogen methane carbon dioxide ethane propane butane iso-butane pentane iso-pentane hexane argon carbon monoxide and ethylene)

    Notes Specific sample depths are detailed in the relevant laboratory reports in Appendix G also known as isopropyl alcohol isopropanol or IPA

    33 Data interpretation

    Following the receipt and collation of the field and laboratory data hydrogeological (fate and transport) and VIRA modelling (refer to Sections 8 and 9 respectively) were undertaken to enable an assessment of risk and to refine the CSM (Section 10)

    PAGE 14 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    4 METHODOLOGY

    41 Field methodologies

    Prior to the commencement of the field investigations a site specific Health and Safety Plan (HSP) including Safe Work Method Statements (SWMS) and a Job Hazard Analysis (JHA) was prepared ndash all personnel working at the site were required to read understand sign and conform to the HSP

    Each proposed drilling location was cleared of underground services by a professional service location company (Pipeline Technologies) using conventional (electronic) service detection methods as well as ground penetrating radar (GPR) Where underground or overhead services were present andor deemed to be a potential safety risk during drilling activities the drill location was moved to an area considered by the Fyfe representative and service locator to be safe All changes to drilling locations were notified to EPA and recorded on a site plan for future reference

    Given that works were undertaken within suburban streets Fyfe employed the services of a qualified traffic management company (Altus Traffic) during drilling activities in order to ensure safety for pedestrians and road users minimal disruption to traffic flow and the provision of a safe working environment

    Field methodologies as detailed in Table 41 were undertaken in accordance with Fyfersquos standard operating procedures (SOPs) Relevant field sampling sheets are included in Appendices F (groundwater) and G (soil vapour ndash combined field sampling sheets and chain of custody (COC) documents) and borehole log reports are presented in Appendices H (groundwater) I (WMStrade) and J (soil vapour)

    Table 41 Summary of field methodologies

    Activity Details

    Passive soil bore sampling The soil bores used to deploy the WMStrade units were hand augered by personnel from Fyfe and Aussie Probe to a depth of 1 m BGL SGS Australia (SGS) personnel suspended each WMStrade unit into its respective borehole from a string The hole was then sealed with an expandable foam plug inside a polyethylene sleeve and the string suspending the sampler was connected to a temporary plastic cap at the ground surface The Round 1 WMStrade units were deployed for periods of between six and seven days whereas the Round 2 WMStrade units were all deployed for six days Following retrieval by SGS each WMStrade unit was placed into a sealed glass vial and a labelled foil bag The WMStrade units did not require chilling during transport to the analytical laboratory Borehole log reports are included in Appendix I whereas combined field sampling sheets and COC documents are presented in Appendix G

    80607-1 REV1 30102017 PAGE 15

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Activity Details

    Groundwater well Groundwater wells were drilled by WB Drilling using a combination of hand augering installation mechanical pushtube and solid auger techniques

    Following the completion of drilling each borehole was fitted with 50 mm class 18 uPVC casing with a basal 6 m long section of slotted well screen A filter pack comprising clean graded sands of suitable size to provide sufficient inflow of groundwater was installed within the annular space between the borehole and the well casing and extended from the base of the screened interval to approximately 1 m above the termination of the slotted casing A 1 m long bentonite collar comprising pelleted or granulated bentonite was placed above the filter pack to prevent water seepage downward along the well casing or borehole from ground surface Each well was grouted up to surface level and fitted with a (lockable) steel gatic cover the latter flush mounted to prevent tripping andor other hazards Groundwater well log reports are included in Appendix H

    Soil logging and Soil logging was undertaken in general accordance with the ASC NEPM (1999) which geotechnical sampling endorses AS1726-1993 In addition to the requirements of AS1726-1993 particular

    attention was paid during logging to any lithological variations such as sandgravel lenses or secondary porosity (such as clay fracturing) which may act as potential preferential pathways for contaminant vapourgroundwater migration through the sub-surface as well as the presence of fill material andor any olfactory or visual evidence of contamination Soil descriptions have been included on the logs in Appendices H to J Cores for geotechnical analysis were collected using push tube sampling methodologies to obtain undisturbed samples Section(s) of core to be tested were retained (intact) within the pushtube liners and capped at each end for storage and transport to the analytical laboratory

    Field screening of soils Field screening of individual soil layers was undertaken at the majority of the drilling locations and involved the use of a photoionisation (PID) unit fitted with an 117 eV lamp (ie as considered suitable for the detection of CHC) The PID unit was calibrated by the hire company prior to delivery and was checked on a daily basis against an isobutylene calibration gas of known concentration Field screen samples were collected with care to ensure that each sample was representative of the soil stratum from which it was collected and experienced minimal loss of volatile compounds The soil material was placed immediately into a zip lock bag and sealed ensuring the bag was half filled (ie such that the volume ratio of soil to air was equal) Soil clumps within the bag were manually broken up and the bag was left to rest for a minimum of five minutes but no longer than 20 minutes Prior to testing the bag was shaken vigorously to release any vapours within the soil To test the tip of the PID probe was inserted into the bag and the maximum volatile organic compound (VOC) reading recorded after a nominal 10 second period or when the reading had peaked Results were recorded on the appropriate bore log sheets presented in Appendices H to J

    Groundwater well Following installation the wells were developed by purging a minimum of four well development volumes (ie until stable parameters were obtained andor until the well purged dry) from

    the casing with a steel bailer andor twister pump to ensure hydraulic connectivity with the aquifer formation

    Groundwater gauging Groundwater levels in the newly installed and existing monitoring wells located across the Thebarton EPA Assessment Area were gauged using an interface probe prior to the commencement of the groundwater sampling program All monitoring wells were gauged for SWL the potential presence of NAPL and the total well depth Groundwater field gauging results are presented in Appendix E

    PAGE 16 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Activity Details

    Groundwater sampling The majority of the wells were sampled using low flow (micropurge) techniques Where recovery was particularly low (ie MW4 MW8 MW15 MW18 MW19 and MW24) and unsuitable for low flow (micropurge) sampling the original sampling technique was abandoned and a HydraSleeveTM (no purge) methodology was used instead Groundwater samples were collected in laboratory-supplied screw top bottles containing appropriate preservative (if required) with no headspace allowed Samples were chilled during storage and transport to the analytical laboratory Disposable nitrile gloves worn by field personnel were changed prior to the collection of each sample Samples for metals (ie iron manganese) analysis were filtered in the field using 045 microm filters Groundwater field sampling sheets are presented in Appendix E

    Low Flow Methodology The low flow sampling technique involved the following the pump was placed close to the bottom of the screened interval the flow rate (up to 05 Lmin) was regulated to maintain an acceptable level of

    drawdown with minimal fluctuation of the dynamic water level during pumping and sampling

    groundwater drawdown was monitored constantly during purging and sampling using an interface probe

    water quality parameters were considered to have stabilised when the following ranges were recorded over three consecutive readings ndash electrical conductivity plusmn 5 ndash pH plusmn 01 ndash temperature plusmn 02degC ndash dissolved oxygen plusmn 10 ndash redox potential plusmn 10 mV

    the stabilisation parameters were recorded on field logging sheets after every one litre of groundwater purged using a calibrated water quality meter and a flow cell suspended in a bucket with litre intervals marked and

    samples were collected once three consecutive stabilisation parameters were recorded and a volume of between 28 and 6 litres was purged prior to sampling

    HydraSleeveTM Methodology The HydraSleeveTM sampling technique involved attaching a stainless steel weight to the bottom and a wire tether clip to the throat of the HydraSleeveTM before lowering it into the water column to the desired depth and allowing it to fill with groundwater After a minimum period of 24 hours the HydraSleeveTM was quickly and smoothly withdrawn from the well and the contents were transferred into the sample containers Water quality parameters were measured after samples were decanted ndash either within the water remaining in the HydraSleeveTM or within a grab sample collected using a disposable bailer

    Hydraulic testing Rising and falling head permeability (ldquoslugrdquo) tests were undertaken to estimate the hydraulic conductivity (K) of the aquifer within various parts of the Thebarton EPA Assessment Area The falling-head tests were initiated by quickly inserting a 1285 m long and 36 mm diameter solid PVC cylinder (slug) into the water column at each well to produce a sufficient sudden rise in the water level The subsequent ldquofallrdquo back to the static water level (recovery) was measured and recorded automatically and in real-time using a

    80607-1 REV1 30102017 PAGE 17

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Activity Details

    pressure transducerdata logger programmed to record water levels at a one second interval After static water level conditions returned in the well the rising-head test was initiated by quickly removing the slug from the well to create a sudden drop in the water column height As with the falling-head test the rise of the water level back to a static condition (recovery) was automatically recorded

    Soil vapour bore Soil vapour bores were drilled by Aussie Probe using a combination of hand augering and installation mechanical pushtube techniques

    Within each 3 m deep soil vapour bore teflon tubing attached to a soil vapour probe was inserted to the base of the hole which had been prefilled with approximately 005 m of clean filter pack sand An additional 045 m of sand (ie approximately 05 m in total) was then added to the hole and topped by a bentonite plug seal of approximately 05 m thickness A second soil vapour probe was installed at a depth of about 1 m within a 05 m sand pack which was overlain by bentonite to a depth of about 02 to 03 m BGL The two 1 m deep soil vapour bores were installed in a similar manner with a sand pack extending from the base to about 05 to 06 m BGL overlain by a bentonite plug to 03 m BGL Each installation was completed with grout to surface and topped with a standard flush-mounted gatic cover Soil vapour bore log reports are included in Appendix J

    Soil vapour sampling All soil vapour sampling works were undertaken by SGS using suitably trained and experienced personnel ndash SGS holds National Association of Testing Authorities (NATA) accreditation for all soil vapour sampling and laboratory analytical works Combined field sampling sheets and COC documents are presented in Appendix G Soil vapour samples were collected using summa canisters and analysed using the US EPA (1999) TO-15 method Sampling involved the connection of a passivated 1 L stainless steel canister to the teflon tubing extending from the soil vapour probe and the use of a soil gas sampling train to restrict flow to a maximum rate of 200 mLmin Canister vacuum pressure was monitored during sampling to enable calculation of the volume of sample drawn into the canister ndash the small amount of vacuum left in the canister at the end of the sampling procedure was measured in the laboratory to check if any leaks occurred during transit (refer to further discussion in Table 52) A shroud was set up around the sampling point and tracer chemicals were introduced at high concentrations by flooding the shroud with helium and placing a cloth soaked with IPA into the shroud Each canister was cleaned and certified by SGS prior to use (refer to Appendix G) and backshyup coconut shell carbon sorbent tube samples were also collected (but not analysed) Summa canisters did not require chilling during transport to the analytical laboratory

    Waste disposal Waste water and surplus soil corescuttings were stored together within 205 litre drums in the rear car park of a commercialindustrial property at 19-21 James Congdon Drive (as organised by the EPA) prior to removaldisposal by a licensed waste removal company (Cleanaway) Analytical results pertaining to the soils were forwarded to the licensed receiving facility and all of the soil was classified as lsquoWaste Fillrsquo in accordance with the Environment Protection Regulations 2009 The waste transport certificates are included in Appendix K

    PAGE 18 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    42 Laboratory analysis

    The following laboratories were used for the analysis of the environmental samples

    complete soil cores for geotechnical sample analysis were forwarded to SMS Geotechnical

    primary groundwater samples collected by Fyfe were analysed at the SGS laboratory whereas secondary groundwater samples were forwarded to EurofinsMGT and

    soil vapour (including WMStrade) samples collected by SGS were analysed at their laboratory

    80607-1 REV1 30102017 PAGE 19

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    5 QUALITY ASSURANCE AND QUALITY CONTROL

    Data quality is typically discussed in terms of the DQIs presented in Table 22 ndash ie completeness comparability representativeness precision and accuracy In order to assess the quality of the data collected during the Fyfe investigation program against these DQIs specific QAQC procedures were implemented during both the field sampling and laboratory analysis programs as detailed in the following sections

    51 Field QAQC

    Field QA procedures undertaken during the recent investigations included the collection of the following QC samples aimed at assessing possible errors associated with cross contamination as well as inconsistencies in sampling andor laboratory analytical techniques

    intra-laboratory duplicate (duplicate) samples submitted to the same (primary laboratory) to assess variation in analyte concentrations between samples collected from the same sampling point andor the repeatability (precision) of the analytical procedures

    inter-laboratory duplicate (split or triplicate) samples submitted to a second laboratory to check on the analytical proficiency (accuracy) of the results produced by the primary laboratory

    equipment rinsate blank samples collected during groundwater sampling only and used to assess cross-contamination that may have occurred from sampling equipment during sampling and

    trip blank samples used to assess whether cross-contamination may have occurred between samples during transport

    Whereas analyte concentrations within the rinsate and trip blank samples should be below the laboratory limit of reporting (LOR) the inter- and intra-laboratory duplicate sample results are assessed via the calculation of a relative percentage difference (RPD) as follows

    (Concentration 1 minus Concentration 2) x 100RPD = (Concentration 1 + Concentration 2) 2

    Maximum RPDs of 30 (inorganics) and 50 (organics) are generally considered acceptable with higher RPD values often recorded where concentrations of an analyte approach the laboratory LOR

    All field QC sample results are included in the summary data tables in Appendix L

    511 Groundwater

    Table 51 presents conformance to field QAQC procedures undertaken as part of the groundwater investigations

    80607-1 REV1 30102017 PAGE 21

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Table 51 Field QAQC procedures ndash Groundwater

    QAQC Item Detail

    Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) AustralianNew Zealand standards ASNZS 566711998 and ASNZS 5667111998 SA EPA (2007) and Fyfe SOPs Details are provided in Table 41

    Calibration of field equipment

    Documentation regarding the calibration of field equipment is included in Appendix M

    Decontamination of All disposable equipment (tubing pump bladders plastic bailers bailer cord and equipment HydraSleeveTM units) were replaced between wells Re-usable equipment (micropurge pump

    interface probe and HydraSleeveTM weights) was decontaminated between sampling locations using potable water and Decon 90trade phosphate free detergent

    Sample preservation and storage

    Samples were kept in laboratory supplied containers in a portable chilled insulated box (esky) prior to and during transport to the laboratory

    Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

    Duplicate samples Two intra-laboratory and two inter-laboratory duplicate samples were analysed for CHC with respect to 26 primary groundwater samples ndash thereby constituting an overall ratio of approximately one duplicate per 65 primary samples (or 15) compared to a generally acceptable ratio of 110 samples (or 10) One intra-laboratory and one inter-laboratory duplicate sample were analysed for the remaining parameters with respect to 10 primary groundwater samples ndash thereby constituting an overall ratio of one duplicate per five primary samples (or 20) compared to a generally acceptable ratio of 110 samples (or 10) Intra- and inter-laboratory duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within the acceptable range with the exception of the following intra-laboratory duplicate sample pair MW9QW1 TCE (67) nitrate (147) and inter-laboratory duplicate sample pair MW9QW2 total CO2 (59) iron (190)

    manganese (183) potassium (64) nitrate (194) The elevated RPD for TCE in the intra-laboratory duplicate sample pair is considered to be related to the low concentration detected and does not alter the interpretation of the data The other RPD exceedances are not considered significant (ie in terms of overall data interpretation) as they were not obtained for identified COPC (as defined in Section 14)

    Rinsate blank samples Six equipment rinsate blank samples (one for each day of sampling) were collected from either the pump housing or a new HydraSleevetrade (final day of sampling only) and analysed for CHC to confirm the effectiveness of the decontamination procedures and the cleanliness of disposable equipment The analytical results obtained for the rinsate blank samples were all below the laboratory LOR thereby indicating that decontamination practices during the groundwater sampling program were acceptable and that no contamination was introduced by the use of the HydraSleevestrade

    Trip blank samples Six trip blank samples were included within containers (eskies) of sample bottles provided by the analytical laboratory and returned to the analytical laboratory All of the trip blank samples were analysed for CHC With the exception of TB187 which contained 1 microgL TCE the analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was limited impact on sample quality during storage or transport of the samples to the analytical laboratory

    PAGE 22 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Notes No duplicate QC samples were collected during the use of the HydraSleeveTM sampling technique as detailed in ANZECCARMCANZ (2000a) at least 5 (ie 120) duplicate samples should be analysed ndash the generally accepted industry standard however is 10 (110) including 5 intra-laboratory and 5 inter-laboratory duplicates

    512 Soil vapour

    Tables 52 presents conformance to field QAQC procedures undertaken as part of the soil vapour (passive and active) investigations

    Table 52 Field QAQC procedures ndash Soil vapour

    QAQC Item Detail

    Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) as well as ASTM (2001 2006) ITRC (2007) CRC CARE (2013) guidance and Fyfe SOPs Details are included in Table 41 and Appendix G (ie SGS sampling methodology sheet) During the use of summa canisters to sample the soil vapour bores leak testing was undertaken (as described in Table 41) Although small leaks or ambient drawdown appear to have occurred with respect to samples SV11_10m (003 helium) SV13_10m (003 helium) and SV1_10m (360 microgm3 IPA) ITRC (2007) and NJDEP (2013) state that ge 5 helium andor gt10 mgm3 IPA are required to be indicative of a significant leak or substantial ambient drawdown Given that the leaks were relatively small (ie 06 (helium) and 36 (IPA) of the levels considered indicative of a significant leak) the data from these bores were still considered to be valid ndash refer to SGS correspondence in Appendix G As detailed in Table 41 a small amount of vacuum was generally left in each summa canister at the end of the sampling procedure and was measured in the laboratory to check if any leaks had occurred during transit However samples SV11_10m SV12_30m as well as the helium blank were recorded as having zero vacuum upon receipt at the analytical laboratory A query lodged with SGS regarding this issue indicated that whereas the helium blank comprised a grab sample collected into a Tedlar bag directly from the helium cylinder (ie without the use of a gauge) the canisters used for samples SV11_10m and SV12_30 were filled during sampling so that there was no remaining vacuum ndash refer to field sampling documentation in Appendix G SGS stated that although it is good practice to have a small amount of vacuum remaining in a canister at the completion of sampling appropriate additional QC measures were employed and the absence of other common background VOCs (eg petroleum hydrocarbons) upon sample testing indicated that leakage had not occurred during transit In addition all canisters are fitted with quick connect one-way valves that are closed upon removal from the sampling train and canistersfittings are leak checked prior to leaving the laboratory and again in the field to ensure that they are leak free Refer to SGS correspondence in Appendix G The presence of detectable IPA (120 microgm3) and TCE (48 microgm3) in the helium blank was also queried with SGS who stated that this (ie variability in the quality of the high purity helium gas used) is not an uncommon occurrence The reason for collecting a helium blank sample is to identify any impurities present in the helium gas so that if a leak does occur during sampling it is possible to determine whether any target compounds could be introduced into the sample train Although a target compound (ie TCE) was detected in the blank the concentration is minor and even if a leak had occurred during sampling (of which there was no evidence) it would not have affected the overall results and data interpretation The presence of IPA in the helium blank is

    80607-1 REV1 30102017 PAGE 23

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    QAQC Item Detail

    suspected by SGS of having resulted from a handling issue in the field ndash ie sub-sampling from the helium cylinder (ie into a summa canister via a flex foil bag) in the vicinity of the high concentrations of IPA being used for leak detection Refer to SGS correspondence in Appendix G

    Sample preservation and storage

    Following collection the WMStrade units were placed into individual glass vials which were sealed and placed into foil bags for transport to the analytical laboratory at ambient temperature Summa canisters were stored in specially constructed cases during transport to the analytical laboratory at ambient temperature

    Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

    QC samples ndash WMStrade sampling

    During the first round of passive soil vapour sampling three additional WMStrade units were deployed in soil bores drilled adjacent to WMS 22 WMS 25 and WMS 28 to act as duplicate QC samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 8) Two trip blank samples were also included with samples transported from and to the analytical laboratory All of the QC samples were analysed by the primary laboratory Intra-duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within an acceptable range (ie lt30) The analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was negligible impact on sample quality during storage or transport of the samples to the analytical laboratory

    QC samples ndash soil vapour bore sampling

    Two intra-laboratory duplicate QC samples were analysed for CHC and general gases with respect to 24 primary soil vapour samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 83) compared to an acceptable ratio of 110 samples (or 10) Intra-laboratory duplicate RPDs were calculated where both samples had a reported concentration above the laboratory LOR All calculated RPDs for CHC and general gases were within an acceptable range (ie lt30) The analytical results obtained for the helium shroud (Tedlar bags) helium blank and IPA shroud (carbon tube) samples were all considered to be satisfactory

    Notes The American Society for Testing and Materials (ASTM) is an internationally recognised source of testing methods Although Appendix J of CRC CARE (2013) stipulates a 110 duplicate sampling ratio for active vapour sampling a specific ratio is not stipulated for passive vapour sampling

    52 Laboratory QAQC

    Laboratory QA procedures generally include the performance of a number of internal checks of data precision and accuracy that are aimed at assessing possible errors associated with sample preparation and analytical techniques Specific types of QC samples analysed by laboratories and the relevant acceptance criteria are as follows

    PAGE 24 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    internal laboratory replicate samples maximum RPD values of 20 to 50 although this varies depending on laboratory LOR

    spike recoveries results between 70 and 130 and

    laboratory controlmethod blanks results below the laboratory LOR

    Table 53 presents conformance to laboratory QAQC procedures undertaken as part of the overall investigation program

    Table 53 Laboratory QAQC procedures

    QAQC Item Detail

    Samples analysed and Samples were generally analysed within specified holding times ndash with the exception extracted within relevant of the following groundwater samples holding times SGS report no ME303457 nitrate was analysed two days late in some samples

    (MW5 MW17 MW26) SGS report no ME303475 nitrate was analysed one day late in all samples and EurofinsMGT report no 555810-W total CO2 was analysed five days late None of these holding time exceedances are considered to be significant with respect to the interpretation of the CHC data the determination of potential human healthenvironmental risks andor the determination of natural attenuation

    Laboratories used and The laboratories used (SGS Eurofins MGT and SMS Geotechnical) were NATA NATA accreditation accredited for the majority of the analyses undertaken

    The exception was SMS Geotechnical which was not NATA accredited for the calculations undertaken to derive some of the data ndash this is the case however for all geotechnical laboratories

    Appropriate analytical methodologies used

    Refer to the laboratory reports in Appendix G

    Laboratory limit of The laboratory LOR is the minimum concentration of an analyte (substance) that can reporting (LOR) be measured with a high degree of confidence that the analyte is present at or above

    that concentration The LOR are presented in the laboratory certificates of analysis (Appendix G) and are considered to be generally appropriate (ie below the adopted assessment criteria ndash refer to Section 62) ndash the following exceptions in soil vapour (ie considered to be due to interference associated with elevated concentrations of other compounds ndash refer to SGS correspondence in Appendix G) are discussed further in Table 101 VC in all of the WMStrade samples relative to the ASC NEPM (1999) interim soil

    vapour health investigation level (HIL) for residential land use cis-12-DCE and VC in two soil vapour bore samples (SV2_30m and SV3_30m)

    relative to the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land use and

    VC in two soil vapour bore samples (SV3_10m and SV7_30m) relative to the ASC NEPM (1999) interim soil vapour HIL for residential land use

    In addition to the above although ultra-trace analysis was requested the laboratory LOR for VC in groundwater (ie 1 microgL) is above the adopted NHMRCMRMMC (2011) potable guideline (ie 03 microgL) ndash refer to Section 612

    80607-1 REV1 30102017 PAGE 25

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    QAQC Item Detail

    Laboratory internal QC analyses

    Results obtained for the laboratory internal QC samples were generally within the acceptable limits of repeatability chemical extraction and detection with the exception of the following SGS report ME303457 matrix spike results for iron were outside normal tolerances

    due to the high concentrations of iron in the spiked sample ndash matrix spike results for iron could therefore not be calculated This is not considered to be a significant issue

    Full details regarding laboratory QAQC procedures and results are presented in the certified laboratory certificates contained in Appendix G

    Notes Since holding times were not specified in the SGS groundwater reports Fyfersquos assessment of holding times has been based on those adopted by EurofinsMGT (ie the secondary laboratory used for groundwater analysis) ie in accordance with Schedule B3 of the ASC NEPM (1999) also referred to as practical quantification limits (PQL)

    53 QAQC summary

    In summary it is considered that

    the field QAQC programs were generally undertaken with regard to relevant legislation standards andor guidelines and were sufficient for obtaining samples that are representative of site conditions and

    the overall laboratory QAQC procedures and results were adequate such that the laboratory analytical results obtained are of acceptable quality for addressing the key objectives outlined in Section 15

    PAGE 26 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    6 ASSESSMENT CRITERIA

    61 Groundwater

    611 Beneficial Use Assessment

    In accordance with Schedule B6 of the ASC NEPM (1999) and SA EPA (2009) a Beneficial Use Assessment (BUA) was undertaken to assess both the current and realistic future uses of groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area

    This was aimed at determining what groundwater uses need to be protected and assessing the risk(s) that groundwater may pose to human health and the environment (refer also to the VIRA in Section 9)

    As summarised in Table 61 the potential beneficial uses for groundwater within the Q1 aquifer that have been considered are as follows ndash taking into account the salinity of the groundwater the Environment Protection (Water Quality) Policy 2015 (Water Quality EPP 2015) the DEWNR (2017) WaterConnect database information presented in Section 222 and possible sensitive receptors located within andor within the vicinity of the Thebarton EPA Assessment Area

    The salinity of groundwater has been calculated to approximate 1230 to 3620 mgL TDS (refer to Section 7312) According to the Water Quality EPP 2015 the applicable environmental values for groundwater with salinity above 1200 mgL TDS but less than 3000 mgL TDS are irrigation livestock and aquaculture whereas the salinity is considered to be too high for potable use ndash although domestic irrigation is considered to be a potentially realistic use for this area (see below) livestock watering is considered unlikely to be undertaken in such an urban setting and no local water bodies (ie surface or groundwater) have been identified as being used for commercial aquaculture purposes

    The DEWNR (2017) WaterConnect database indicates that groundwater within the Q1 aquifer in the Thebarton area is accessed for drainage domestic and industrial purposes ndash domestic groundwater use could include garden irrigation plumbing water andor the filling of swimming pools (ie primary contact recreation) Although domestic groundwater extraction is considered unlikely to include potable use (ie due to its salinity and the availability of a reticulated mains water supply) potential mixing with rain watermains water could render it suitable (ie from a salinity perspective) for drinking

    As the closest freshwater surface water body the River Torrens is located approximately 03 km to the east and 07 km to the north and north-west of the northern portion of this area groundwater discharge from the Thebarton EPA Assessment Area into a freshwater aquatic ecosystem is considered possible However as the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area the potential for impact on a freshwater aquatic environment has not been confirmed

    80607-1 REV1 30102017 PAGE 27

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Since the closest marine surface water body Gulf St Vincent is located approximately 8 km to the west groundwater discharge from the Thebarton EPA Assessment Area into a marine aquatic ecosystem is not considered to be realistic

    Since volatile contaminants have been detected within the Q1 aquifer (refer to Section 7331) a potential vapour flux risk to future site users must be considered

    Given the measured depth of the Q1 aquifer beneath the site (ie approximately 1232 to 1585 m BGL ndash refer to Section 7311) it is considered unlikely that direct contact could occur between groundwater and building footingsunderground services

    Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area

    Environmental Values Beneficial Uses

    Water Quality EPP 2015

    environmental value

    SA EPA (2009) Potential

    Beneficial Uses

    Beneficial Use Assessment

    Considered Applicable

    Aquatic Ecosystem

    Marine Yes No

    Fresh Yes Possibly

    Potable - Yes Possibly

    Agriculture Irrigation - Yes Yes

    Livestock - Yes No

    Aquaculture - Yes No

    Recreation amp Aesthetics

    Primary contact Yes Possibly

    Aesthetics Yes Possibly

    Industrial - Yes Yes

    Human health in non-use scenarios

    Vapour flux -

    Yes Yes

    Buildings and structures

    Contact - Yes No

    Notes ie for underground waters with a background TDS level of between 1200 and 3000 mgL ndash note that although they are not listed as environmental values of groundwater in Schedule 1(3) of the Water Quality EPP 2015 aquatic ecosystems as well as recreation amp aesthetics are included as environmental values for waters in general in Part 1(6) of the document ie domestic irrigation only

    612 Groundwater beneficial use criteria

    The health and ecological criteria used for the assessment of the COPC (refer to Section 14) in groundwater have been based on the results of the BUA (Section 611) A summary of the references used to source the groundwater assessment criteria is provided in Table 62

    PAGE 28 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Table 62 Sources of adopted groundwater assessment criteria

    Beneficial Use Reference

    Freshwater Ecosystems No criteria available for COPC

    Potable NHMRCNRMMC (2011) Australian Drinking Water Guidelines

    WHO (2017) Guidelines for Drinking-water Quality ndash TCE only

    Irrigation No criteria available for COPC

    Primary contact recreation (including aesthetics)

    NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines but (with the exception of aesthetic guidelines) multiplied by a factor of 10 to take account of accidental ingestion rates as opposed to deliberate ingestion

    ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality ndash recreational values (TCE only)

    Human health in non-use scenarios ndash vapour flux Refer to the VIRA in Section 9

    Notes As there are no specific guidelines for industrial water these values are considered likely to be protective of this additional beneficial use The NHMRC (2008) guidelines are based on drinking water levels and assume a consumption factor of 2 L per day Therefore as recommended in the NHMRC (2008) document potable criteria (ie with the exception of aesthetic criteria) need to be adjusted by a factor of 10 to account for an accidental consumption rate of 100 to 200 ml per day As noted in ANZECCARMCANZ (2000b) although recreational guidelines are protective of ingestion recreational waters should also not contain any chemicals that can cause skin irritation likewise although not specifically addressed by recreational water criteria inhalation may also represent a source of exposure with respect to some (ie volatile) contaminants In the absence of a NHMRCNRMMC (2011) drinking water guideline for TCE the ANZECCARMCANZ (2000b) recreational criterion (30 microgL) has been adopted However if the NHMRC (2008) rule of multiplying potable (healthshybased) guidelines by 10 is applied to the WHO (2017) drinking water guideline of 20 microgL a recreational guideline of 200 microgL would be more applicable

    62 Soil vapour

    The ASC NEPM (1999) interim soil vapour health investigation levels (HILs) for volatile organic chlorinated compounds (VOCCs) have been adopted (ie in the first instance ndash refer to Section 7331) as Tier 1 soil vapour assessment criteria ndash relevant land use scenarios within the Thebarton EPA Assessment Area include residential (HIL AB) and commercialindustrial (HIL D)

    These criteria have been further adjustedappended for the purposes of the VIRA Tier 1 assessment ndash refer to Section 94

    80607-1 REV1 30102017 PAGE 29

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    7 RESULTS

    71 Surface and sub surface soil conditions

    711 Field observations

    Groundwater well and soil vapour borehole log reports are included in Appendices H to J and provide details of the soil profile encountered at each sampling location

    Where encountered fill materials extended to depths of between 01 and 09 m BGL and included a range of different soil types (sand gravelcrushed rock silt) with only minimal waste inclusions (ie asphalt glass andor metal fragments) identified at some locations

    The underlying natural soil profile (encountered to the maximum drill depth of 19 m BGL) was dominated by low to medium plasticity brown to red-brown silty clays and sand claysclayey sands some of which contained sub-angular to rounded gravels that included river pebbles andor comprised fine distinct lenses in places Groundwater well MW17 also included a 15 m thick layer of gravel at depth (ie 12 to 135 m BGL) ndash ie consistent with the depth of groundwater within the Q1 aquifer

    During the course of the drilling works no odours or visual indicators of contamination were detected and measured PID readings ranged up to 6 ppm but were generally lt3 ppm

    712 Soil geotechnical testing

    A table of geotechnical testing results is presented in Appendix L (Table 1) and a copy of the certified laboratory report is included in Appendix G Photographs of soil cores are included in Appendix N

    The results were interpreted to indicate the following

    The soil core samples submitted for PSD analysis were dominated by clay with lesser amounts of fine to medium gravel andor fine to coarse-grained sand ndash all samples analysed were classified as either CLAY or Sandy CLAY with one sample classified as Clayey SAND The classifications obtained from the laboratory were deemed to be generally consistent with the descriptions on the groundwater well log reports (Appendix H) although the PSD results did not specify silt as a significant secondary component

    The moisture content of the analysed soil core samples ranged from 65 to 231 Moisture content with respect to soil type depth and location has been considered in more detail for the purposes of the VIRA (Section 9) The degree of saturation for the analysed soil cores samples ranged from 218 to 964

    Measured bulk density ranged from 160 to 212 tm3 specimen dry density from 141 to 184 tm3 and specific gravity from 255 to 281 tm3

    The measured void ratio ranged from 043 to 088 whereas porosity ranged from 032 to 047

    80607-1 REV1 30102017 PAGE 31

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    72 Waterloo Membrane Samplerstrade A table of WMStrade analytical results (ie from both rounds of sampling) is presented in Appendix L (Table 2) and copies of certified laboratory reports are included in Appendix G8

    Of the 41 WMStrade units deployed across the Thebarton EPA Assessment Area during the two sampling rounds 20 returned measurable concentrations of CHC including TCE PCE cis-12-DCE trans-12-DCE andor 11-DCE Although no VC was detected the laboratory LOR in all samples (ie 35 to 50 microgm3) was above the ASC NEPM (1999) soil vapour interim HIL for residential land use (30 microgm3) ndash refer also to Table 53

    Detectable COPC concentrations are summarised in Table 71 relative to the ASC NEPM (1999) soil vapour interim HILs along with the closest soil vapour bore andor groundwater monitoring well locations Measured TCE concentrations are detailed on Figure 3

    A comparison of the Round 1 and 2 WMStrade results (ie for closely located units9) is presented in Table 72 ndash the results indicate a general order of magnitude correlation of the results for most COPC with the exception of PCE for which lower concentrations were obtained during Round 2 As the Round 1 and 2 WMStrade units were located within different soil bores and deployed at different times some variability in the results is to be expected In addition and as discussed in Section 74 the WMStrade units have been used during this assessment as a (semi-quantitative) screening tool (ie to assist with the siting of the permanent soil vapour bores) with the results obtained from the soil vapour bores considered more representative of actual subsurface conditions

    Table 71 Detectable Waterloo Membrane Samplertrade CHC results

    Sample ID

    Location Closest land uses

    CHC concentration (microgm3) Closest soil vapour bore

    andor groundwater

    well

    TCE PCE cis-12shyDCE

    trans-12shyDCE

    11shyDCE

    VC

    WMS 1 Goodenough Street CI 35 -

    WMS 6 Maria Street CI 32 -

    WMS 7 Maria Street CI and R 1900 45 SV2 MW5

    WMS 8 Maria Street CI and R 12000 37 SV4

    WMS 11 Admella Street CI 71000 260 19 20 36 SV5 MW02

    WMS 14 George Street CI 46000 45 SV6 MW11

    WMS 18 Admella Street CI 4200 34 MW14

    WMS 19 Albert Street CI 11000 42 SV10MW15

    WMS 21 Chapel Street CI 10 -

    WMS 22 Admella Street CI 38 SV9

    WMS 24 Chapel Street CI 230 62 10 11 48 MW17

    8 Note that the original laboratory report for the Round 1 WMStrade samples was found to be incorrect (ie following receipt of the soil vapour bore and Round 2 WMStrade sample results) and was subsequently re-issued by SGS

    9 only two of which were sufficiently co-located for comparative purposes ndash Round 2 locations WMS 39 and WMS 41 were not within the immediate vicinity of Round 1 WMStrade bores (ie the closest Round 1 bores were approximately 30 m away)

    PAGE 32 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Sample ID

    Location Closest land uses

    CHC concentration (microgm3) Closest soil vapour bore

    andor groundwater

    well

    TCE PCE cis-12shyDCE

    trans-12shyDCE

    11shyDCE

    VC

    WMS 25 Albert Street CI and R 1400 20 MW17

    WMS 27 Light Terrace CI 64 62 SV11 MW19

    WMS 32 Holland Street R 16 -

    WMS 34 James Street R 11 -

    WMS 37 Dew Street R 44 -

    WMS 38 Maria Street CI and R 13000 56 SV2 MW5

    WMS 39 Maria Street CI and R 1300 SV4

    WMS 40 Admella Street CI 110000 97 SV5 MW02

    WMS 41 George Street CI 18000 10 SV7 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

    Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform (up to 530 microgm3) was also detected in WMS 8 WMS 11 WMS 14 WMS 16 WMS 18 WMS 19 WM 25 WMS 33 WMS 40 and WMS 41 interim soil vapour health investigation level (HIL)

    Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units

    Bore ID

    Depth (m)

    Location CHC concentration (microgm3)

    TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

    WMS 8 10 Maria Street 12000 37 lt95 lt99 lt22 lt36

    WMS 38 13000 56 lt11 lt11 lt25 lt41

    Relative percentage difference 8 147 - - - -

    WMS 11 10 Admella Street 71000 260 19 20 36 lt37

    WMS 40 110000 97 lt11 lt11 lt25 lt41

    Relative percentage difference 43 91 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

    80607-1 REV1 30102017 PAGE 33

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    73 Groundwater

    731 Field measurements

    A table of groundwater field parameters is presented in Appendix L (Table 3) and groundwater field sampling sheets are included in Appendix E

    7311 Groundwater elevation and flow direction

    The depth to water within the Q1 aquifer beneath the Thebarton EPA Assessment Area on 18 July 2017 ranged from 12323 to 15854 m below top of casing (BTOC)10 and 4469 to 5070 m AHD

    Groundwater elevation contours constructed from the July 2017 gauging data indicated that the overall groundwater flow direction within the Q1 aquifer was north-westerly consistent with expected regional groundwater flow The groundwater contours and inferred flow direction are shown on Figure 4

    7312 Field parameters

    As detailed in Table 51 field measurements were recorded during low flow purging (ie prior to micropurge sampling) of monitoring wells and immediately following the collection of HydraSleeveTM samples

    The field parameter readings recorded for the monitoring wells immediately prior to (low flow micropurge) and after (HydraSleeveTM) sampling indicated the following (as summarised in Table 3 Appendix L)

    groundwater pH ranged from 6 8 to 79 thereby indicating neutral conditions

    electrical conductivity (EC) measurements ranged from 189 to 556 mScm and were found to be reasonably consistent across the area thereby indicating that it is underlain by moderately saline water (ie approximating 1230 to 3620 mgL TDS11)

    redox concentrations ranged from -20 to 624 mV thereby indicating slightly reducing to strongly oxygenating conditions

    measured dissolved oxygen (DO) concentrations ranged from 04 to 78 ppm indicating slightly to highly oxygenated water and

    temperature ranged from 173 to 224oC

    Observations recorded during sampling indicated that the groundwater was clear to brown and only slightly to moderately turbid at most locations ndash the higher turbidity at MW18 and MW19 (combined with poor recharge) contributed towards the decision to use a HydraSleeveTM sampling method No odours or sheen were observed in any of the wells during gauging or sampling

    10 ie approximating m BGL 11 ie calculated by multiplying the field EC data by 065

    PAGE 34 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    732 Hydraulic conductivity

    Rising and falling head aquifer permeability (ldquoslugrdquo) tests were conducted on 10 groundwater wells (refer to Table 31 and Figure 2) to assess the hydraulic conductivity (K) of the Q1 aquifer

    To obtain estimates of near-well horizontal hydraulic conductivity for each well tested the slug test data were analysed by Arcadis using AQTESOLV for Windowstrade (Duffield 2007) following the guidelines presented in Butler (1998) ndash normalised displacement data collected from each test are plotted against time in Appendix A of the Arcadis report (refer to Appendix O) Since only one set of tests were performed at each well the reproducibility of the results as well as the dependence of the results on the initial displacement could not be verified or demonstrated As such multiple relevant and applicable solutions were applied to each test to account for that uncertainty (ie to ensure consistency of normalised response at each well regardless of initial displacement)

    Table 73 presents a summary of the range and average estimated hydraulic conductivity values (and corresponding analytical solutions used) for each well tested The results indicate that hydraulic conductivities ranged from approximately 0073 to 37 mday with an overall average of approximately 1 mday

    Table 73 Hydraulic conductivities (rising and falling head tests)

    Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

    (mday) Hydraulic Conductivity

    (mday)

    MW02 Falling head 011 to 014 DA CBP HV

    012 Rising head 0073 to 015 BR DA

    MW3 Falling head 034 to 062 BR DA

    047 Rising head 030 to 062 BR DA

    MW7 Falling head 075 to 25 BR DA

    139 Rising head 055 to 175 BR DA

    MW14 Falling head 011 to 021 BR DA

    014 Rising head 009 to 015 BR DA

    MW17 Falling head 21 to 22 DA KGS

    220 Rising head 225 to 244 DA KGS

    MW20 Falling head 22 to 37 BR DA HV

    256 Rising head 06 to 32 BR DA

    MW21 Falling head 073 to 123 BR DA

    084 Rising head 054 to 084 BR DA

    MW23 Falling head 088 to 162 BR DA

    101 Rising head 031 to 122 BR DA

    80607-1 REV1 30102017 PAGE 35

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

    (mday) Hydraulic Conductivity

    (mday)

    MW25 Falling head 10 to 18 BR DA CBP HV

    132 Rising head 049 to 17 BR DA

    MW26 Falling head 019 to 036 BR DA

    023 Rising head 010 to 029 BR DA

    Overall average K (mday) 1028 Notes References BR = Bouwer and Rice (1976) CBP = Cooper et al (1967) DA = Dagan (1978) HV = Hvorslev (1951) KGS = Hyder et al (1994)

    The monitoring wells that exhibited lower permeabilities (ie MW02 MW3 MW14 and MW26) were noted to be generally located in the up-gradient (south-eastern) portion of the Thebarton EPA Assessment Area whereas monitoring wells showing relatively higher permeabilities (ie MW7 MW17 MW20 MW21 MW23 and MW25) are generally located in the down-gradient (north-western) portion These results were considered by Arcadis to suggest a possible hydrogeologic transition from the south-east to the north-west AQTESOLV solution plots for each analysis are provided as Appendix A of the Arcadis report (Appendix O)

    As slug test results can be influenced by a number of factors which are difficult to avoid when performing and analysing slug test results hydraulic conductivity estimates derived from slug tests should be considered to be the lower bound of the hydraulic conductivity of the formation in the vicinity of the well (Butler 1998) However Arcadis also noted that the results obtained for the Thebarton EPA Assessment Area were similar to those reported for other areas of Adelaide with average values of 1 and 27 mday (refer to Appendix O)

    The slug test results were used by Arcadis in their groundwater fate and transport model (refer to Section 8)

    733 Analytical results

    Tables of groundwater analytical results are presented in Appendix L (Tables 4 and 5) and copies of certified laboratory reports are included in Appendix G

    7331 Chlorinated hydrocarbon compounds

    A table of CHC results is included in Appendix L (Table 4) and a plan showing their distribution in groundwater beneath the Thebarton EPA Assessment Area is included as Figure 5 Detectable CHC concentrations are summarised in Table 74 relative to the adopted potable and primary contact recreation criteria ndash the closest soil vapour bore locations are also detailed

    PAGE 36 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Table 74 Detectable groundwater CHC results

    Sample ID

    Location CHC concentration (microgL) Closest soil vapour bore

    TCE PCE cis-12shyDCE

    trans-12-DCE

    11-DCE VC Carbon tetrachloride

    MW02 Admella Street 20000 38 7 15 SV5

    MW3 Admella Street 69 SV1

    MW5 Maria Street 29000 3 21 2 6 SV2 SV3

    MW6 Maria Street 29 SV4

    MW9 Albert Street 2 -

    MW11 George Street 4900 3 4 1 7 SV6 SV7

    MW12 George Street 700 SV8

    MW14 Admella Street 1000 4 2 SV9

    MW15 Albert Street 180 SV10

    MW17 Chapel Street 24 -

    MW18 Dew Street 5 -

    MW20 Light Terrace 70 SV12

    MW21 Light Terrace 23 SV13

    MW23 Dew Street 21 -

    MW25 Smith Street 2 5 -

    MW26 Kintore Street 2 -

    Potable 20 50 60 30 03 3

    Primary contact recreation

    30 500 600 300 30 30

    Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Chloroform was also detected in a number of wells (MW02 MW3 MW5 MW8 MW11 MW12 and MW19 to MW25) ndash refer to Table 4 in Appendix L Although no VC was detected the laboratory LOR (1 microgL) exceeded the adopted potable criterion NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from WHO (2017) Guidelines for Drinking-water Quality NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

    The results indicate that the highest TCE concentrations (20000 to 29000 microgL) were measured in wells MW02 and MW5 located in the immediate vicinity of the former Austral property and that the TCE plume extends in a general north-westerly direction (ie consistent with the inferred groundwater flow direction

    80607-1 REV1 30102017 PAGE 37

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    within the Q1 aquifer) Although lesser concentrations of PCE 12-DCE (cis- andor trans) andor 11-DCE were present in some wells no VC was detected and the main COPC was identified as TCE

    A number of wells within the Thebarton EPA Assessment Area contained TCE concentrations that exceeded the adopted potable andor primary contact recreation criteria Although the extent of the TCE plume was not delineated to the north-west (but was delineated in all other directions) with detectable TCE concentrations (ie up to 21 microgL) identified beneath both Smith Street and Dew Street these concentrations were below the adopted primary contact recreation criterion (but not necessarily the adopted potable value ndash ie MW23)

    The background well (MW4) located across James Congdon Drive (to the east of the southern portion of the Thebarton EPA Assessment Area) did not contain any measurable CHC concentrations

    7332 Other measured groundwater parameters

    Major cations and anions

    The laboratory results obtained for the remaining groundwater analytes are summarised in Appendix L (Table 5)

    The groundwater ionic data obtained from selected wells across the Thebarton EPA Assessment Area are graphically represented on a Piper diagram in Figure 71 The results indicate a relatively consistent groundwater composition across the area thereby indicating that the groundwater sampled from these wells is derived from a single aquifer Ionic charge balance ranged from 32 to 22 with the highest value (22) calculated for MW12 indicating that additional anions (ie not measured as part of this study) could be present

    PAGE 38 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Figure 71 Piper diagram

    Natural attenuation parameters

    With respect to the measured natural attenuation parameters (ie DO nitrate iron sulfate CO2 and manganese) the following wells were selected based on their locations relative to the inferred extent of the CHC plume

    MW26 located on Kintore Street to the south (and hydraulically up-gradient) of the former Austral property (ie the suspected source site)

    MW02 and MW5 located within the immediate vicinity of the former Austral property and the area of maximum CHC contamination

    MW9 MW12 and MW17 located on Albert Street George Street and Chapel Street respectively to the north-west (and hydraulically down-gradient) of the former Austral property

    80607-1 REV1 30102017 PAGE 39

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    MW21 and MW22 located on Light Terrace and Cawthorne Street respectively to the northshywestnorth-north-west (and further hydraulically down-gradient) of the former Austral property and

    MW8 and MW23 located on Smith Street and Dew Street respectively representing the furthest wells to the northnorth-west of the former Austral property

    According to Wiedemeier et al (1998) the most important process in the degradation of CHC is the process of reductive dechlorination Although daughter products of TCE (ie 12-DCE) are present in groundwater (and soil vapour) at scattered locations within the Thebarton EPA Assessment Area they are not considered indicative of substantial breakdown of TCE ndash refer also to the Arcadis report in Appendix O as summarised in Section 8 In addition the analysis of the natural attenuation parameters data constituting physical and chemical indicators of biodegradation processes has not provided a definitive secondary line of evidence

    74 Soil vapour bores A table of soil vapour bore analytical results is presented in Appendix L (Table 6) and a copy of the certified laboratory report is included in Appendix G

    Of the soil vapour bores installed to 10 andor 30 m BGL within the Thebarton EPA Assessment Area the majority (ie with the exception of the 10 m deep bores installed as SV11 and SV13 and located on Light Terrace) returned measurable concentrations of CHC dominated by TCE and to a lesser extent (and only at some locations) PCE Detectable soil vapour CHC concentrations are summarised in Table 75 whereas CHC concentrations and inferred soil vapour TCE concentration contours are detailed on Figures 6 (1 m BGL) and 7 (3 m BGL)

    The TCE results which have been used to predict indoor air concentrations as part of the VIRA (refer to Section 9) suggest the following

    the highest concentration (1000000 microgL) was detected at 3 m BGL in soil vapour bore SV3 located in the vicinity of residential and commercialindustrial properties (including the former Austral property) on Maria Street

    where nested wells were tested soil vapour CHC concentrations were higher at depth consistent with a groundwater source

    TCE PCE and 11-DCE are all assumed to represent primary contaminants with 12-DCE representing a break-down product of TCE andor PCE

    although no VC was detected the laboratory LOR in some samples (ie up to 490 microgm3 in samples with the highest measured TCE concentrations) was above the ASC NEPM (1999) interim soil vapour HIL for residential land use (30 microgm3) ndash refer to Table 53 and

    although the extent of the soil vapour plume has apparently not been delineated (ie in any direction) by the existing soil vapour bores it extends in a north-westerly direction (and hydraulically down-

    PAGE 40 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    gradient) from the suspected source site (ie the former Austral property) and corresponds well with the groundwater TCE plume (refer to Figure 5)

    A comparison of the results obtained for the WMStrade units (WMS 38 to WMS 41) deployed during the second round of sampling and the closest soil vapour bore data (10 m BGL) is provided in Table 76 Although the results indicate good correlation for TCE and PCE in SV5WMS 40 as well as TCE in SV7WMS 41 the remaining results were more variable ndash this supports the use of the WMStrade units as an initial (semishyquantitative) screening tool with follow-up soil vapour bore data considered to provide more quantitative results

    Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area

    Bore ID

    Depth (m)

    Location Closest land

    uses

    CHC concentration (microgm3)

    TCE PCE cis-12shyDCE

    trans-12-DCE

    11-DCE VC

    SV1 10 Admella Street CI and R 6300 78

    30 21000 21

    SV2 10 Maria Street CI and R 51000 39 21 39

    30 940000

    SV3 10 Maria Street CI and R 210000 6500 5900

    30 1000000 15000 14000

    SV4 10 Maria Street CI and R 17000 31

    30 43000 90 30

    SV5 10 Admella Street CI 100000 84

    30 160000 310 20 33

    SV6 10 George Street CI 22000 12

    30 150000 56

    SV7 10 George Street CI 22000 19

    30 110000

    SV8 10 George Street CI 2300 62

    30 14000 19

    SV9 10 Chapel Street CI 170

    30 260

    SV10 10 Albert Street CI 93

    30 51

    SV12 10 Light Terrace CI 16

    30 55 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

    Notes Shaded cells indicate concentrations were below the laboratory LOR

    80607-1 REV1 30102017 PAGE 41

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Where (field andor laboratory) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform was also detected in a number of samplesinterim soil vapour health investigation level (HIL)

    Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores

    Bore ID

    Depth (m)

    Location CHC concentration (microgm3)

    TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

    SV2 10 Maria Street 51000 39 21 lt13 39 lt89

    WMS 38 13000 56 lt11 lt11 lt25 lt41

    Relative percentage difference 119 150 - - - -

    SV4 10 Maria Street 17000 31 lt18 lt14 lt14 lt92

    WMS 39 1300 lt52 lt11 lt11 lt25 lt41

    Relative percentage difference 172 - - - - -

    SV5 10 Admella Street 100000 84 lt44 lt33 lt33 lt22

    WMS 40 110000 97 lt11 lt11 lt25 lt41

    Relative percentage difference 95 14 - - - -

    SV7 10 George Street 22000 19 lt37 lt27 lt27 lt18

    WMS 41 18000 10 lt11 lt11 lt25 lt41

    Relative percentage difference 20 62 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

    PAGE 42 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    8 GROUNDWATER FATE AND TRANSPORT MODELLING

    Arcadis were commissioned by Fyfe to undertake preliminary fate and transport modelling of the groundwater CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained groundwater data The Arcadis report is included as Appendix O

    The aim of the modelling was to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton area in order that potential future groundwater restrictions could be applied by the EPA (ie via the potential future definition of a GPA) to protect human health

    81 Groundwater flow modelling

    The MODFLOW code a publicly-available groundwater flow simulation program developed by the United States Geological Survey (USGS) as described by McDonald and Harbaugh (1988) was used to construct a groundwater flow model It was developed for a horizontal area of approximately 25 km2 (ie to minimise possible boundary effects within the assessment area itself12) and was rotated 45deg counter-clockwise to align with the prevailing (north-westerly) groundwater flow direction The model extended approximately 23 km in a south-east to north-west direction and approximately 11 km in a south-west to north-east direction (ie perpendicular to groundwater flow) Whereas a 4 m grid spacing was used within the area of the plume and its migration pathway (ie to enhance model accuracy and precision) a broader 15 m grid was adopted outside the specific area of interest Vertically the model adopted a single 20 m thick layer as representative of the hydrostratigraphy of the Q1 aquifer sediments beneath the area but it was noted that only the bottom portion (ie few metres) of this model layer are actually saturated and therefore active in the model

    An informal sensitivity analysis performed as part of the model calibration process indicated that the model was most sensitive to changes in hydraulic conductivity and recharge ndash this was not unexpected given the relatively flat hydraulic gradient and relatively narrow range of estimated values for both model parameters (ie based on reasonably low uncertainty) The final calibrated value for aquifer recharge adopted in the model was 295 mmyear consistent with results reported for nearby sites as well as regional estimates Likewise the final calibrated hydraulic conductivity values for the up-gradient (06 mday) and down-gradient (2 mday) zones were consistent with both the site-specific slug test data and results obtained for other nearby EPA assessment areas The final calibrated down-gradient constant head elevation was 15 m AHD It was concluded by Arcadis that the groundwater flow model was well calibrated and could therefore serve as an appropriate basis for the development of a site-specific solute transport model

    82 Solute transport modelling

    A site-specific (three-dimensional) solute transport model using the MT3DMS transport code of Zheng (1990) was developed by Arcadis to predict the fate and transport of groundwater contaminants (specifically

    12 Further information regarding boundary effects is provided in the Arcadis report (Appendix O)

    80607-1 REV1 30102017 PAGE 43

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    CHC) under current conditions over a period of 100 years This dual-domain mass transport model was used in conjunction with the groundwater flow model developed through the use of MODFLOW (as detailed above) assuming the following

    The primary COPC is TCE ndash the initial concentration distribution of TCE in groundwater was based on the recent (July 2017) monitoring data

    The age of the groundwater TCE plume was assumed to be up to about 90 years ndash ie based on the history of industrial land use (specifically the former Austral facility) in the area

    Although lesser amounts of other CHC are present in groundwater the lack of significant daughter products of TCE has been interpreted to indicate that substantial biodegradation is not occurring (ie as a conservative approach)

    Although a CHC source was not explicitly incorporated into the solute transport model the MT3DMS transport code indirectly accounts for on-going contaminant mass contribution to the dissolved-phase plume

    The fate and transport of TCE within the area of interest involves the processes of advection adsorption dilution and diffusion ndash however given that recharge via the infiltration of precipitation was considered to be insignificant dilution effects were assumed to be minimal

    Two porosity values (ie dual domain) are relevant to the movement of contaminants in the subshysurface with adopted values based on site-specific geology and Payne et al (2008) ndash whereby the two domains are in equilibrium

    ― mobile porosity that portion of the formation with the highest permeability where advective transport dominates ndash assumed to be 5 (high) 10 (intermediate) or 15 (low) for different mobility transport conditions and

    ― immobile porosity lower permeability portions of the formation where diffusion is dominant ndash assumed to be 15

    As discussed in Section 732 hydraulic conductivity values of 06 mday (south-eastern approximate quarter of the modelling area) and 2 mday (northern approximate three-quarters of the modelling area) were adopted to reflect the hydrogeologic transition (ie from the south-east to the north-west) interpreted from the slug test data

    The adopted TCE retardation factor of 147 for intermediate mobility transport conditions was based on the following

    ― an assumed organic carbon fraction of 01 (US EPA 1996 amp 2009) ndash this was varied to 005 and 2 to assess alternate (ie high versus low) mobility transport conditions

    ― an assumed organic carbon adsorption co-efficient of 61 Lkg (US EPA 2017a)

    PAGE 44 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    ― a calculated partition co-efficient of 0061 Lkg ndash this was varied to 129 and 178 Lkg to assess alternate (ie high versus low) mobility transport conditions and

    ― an average soil bulk density of 192 gcm3 (based on measured geochemical data ndash refer to Table 1 Appendix L)

    An optimum mass transfer co-efficient (MTC) was based on simulated flux distribution in the groundwater flow model whereby

    ― the calculated MTC in the model ranged from approximately 38E-08day-1 to 37E-05 day-1 and

    ― the average MTC was 185E-05day-1

    The site-specific solute transport model was used in predictive mode to assess the long-term (eg 100 year) potential migration of the groundwater TCE plume and to support the EPA in the potential future definition of an appropriate GPA The model was calibrated against the current extent (ie concentrations of TCE above 1 microgL have migrated approximately 500 m from the suspected source site13) and expected age (ie up to about 90 years) of the plume The results indicate that the leading edge of the TCE (ie the 1 microgL contour) is estimated to migrate between approximately 400 and 620 m over a period of 100 years under low to high mobility transport conditions14 with intermediate transport conditions resulting in an estimated migration of 500 m By comparison no significant lateral plume expansion would be expected to occur Figures 5 to 17 of the Arcadis report (Appendix O) show the predicted extent of the TCE plume at 5 10 50 and 100 years under low to high mobility transport conditions

    Figure 81 shows the predicted extent of the 1 microgL TCE boundary in 100 years under intermediate transport conditions ndash it is recommended that this information be used to support the EPA in establishing a potential future GPA

    The Arcadis report notes that given the available site information (site history potential source area(s) and uncertainty associated with the current plume extent) and degree of model calibration (flow model parameter values are consistent with site-specific data as well as regionalnearby studies while transport parameter values are consistent with literatureindustry standards) the model-predicted migration of approximately 500 m over 100 years is considered to be a reasonable representation of future conditions

    Key uncertainties associated with the modelling were identified as including the following

    current plume extents (ie down-gradient delineation)

    site-specific fraction organic values (or site-specific partition coefficient estimates) and

    site-specific porosity estimates

    13 although it was noted that there is uncertainty with respect to the current extent of the TCE plume since all three down-gradient monitoring wells (MW18 MW23 and MW25) have TCE concentrations above 1 μgL

    14 ie assuming different values for mobileimmobile porosity the TCE distribution (sorption) coefficient and the TCE retardation factor

    80607-1 REV1 30102017 PAGE 45

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Lesser uncertainties were considered to include site-specific bulk hydraulic conductivity estimates and determination of the presence or absence of naturally-occurring TCE degradation

    Additional site investigation and data collection (eg multi-well pumping tests for bulk hydraulic conductivity estimates site-specific fraction organic carbon andor distribution (sorption) coefficient additional down-gradient plume delineation) would help to further refine the model and increase confidence in the predictive results

    Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green) relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple)

    PAGE 46 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    9 VAPOUR INTRUSION RISK ASSESSMENT

    Arcadis were commissioned by Fyfe to undertake a Vapour Intrusion Risk Assessment (VIRA) of the soil vapour CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained (ie August 2017) permanent soil vapour bore data The Arcadis report is included as Appendix P

    91 Objective

    The main objective of the VIRA was to evaluate the potential risk to human health from vapour intrusion related to the concentrations of CHC identified in soil vapour within the Thebarton EPA Assessment Area

    92 Areas of interest

    The following areas of specific interest (ie located within the Thebarton EPA Assessment Area) were identified for the purpose of this VIRA

    commercialindustrial properties (assumed slab on grade construction) including the former Austral property (ie the suspected source site) and

    residential properties (slab on grade crawl space and basement constructions)

    Potential exposure by trenchmaintenanceutility workers has also been considered (qualitatively)

    93 Risk assessment approach

    The VIRA was conducted in accordance with the ASC NEPM (1999) enHealth (2012a) and other relevant Australian guidance documents as well as guidance documents issued by the US EPA and other international regulatory agencies (where applicable)

    The conduct of the risk assessment was based on a multiple lines of evidence approach using the available site-specific information collected as part of the scope of works detailed in Section 32

    The following information was used as a basis for the VIRA

    CHC including TCE PCE and DCE (11- cis-12- and trans-12-) have been identified within soil vapour andor groundwater within the Thebarton EPA Assessment Area ndash the analytical data indicate that TCE constitutes between about 95 and 100 of the CHC identified in groundwater and soil vapour

    TCE has been considered as the risk driver for the VIRA (ie based on its toxicity and concentrations in soil vapour and groundwater) ndash although TCE PCE 12-DCE 11-DCE and VC have all been included as COPC for the Tier 1 screening assessment (Section 94) the Tier 2 assessment (Section 95) has

    80607-1 REV1 30102017 PAGE 47

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    concentrated on TCE PCE and 11-DCE (ie due to their presence at concentrations that exceeded the adopted Tier 1 screening criteria)

    The CHC identified within the Thebarton EPA Assessment Area are volatile chemicals and could potentially pose a risk to human health via the vapour intrusion pathway Although the source area has yet to be confirmed the CHC concentrations observed in groundwater and soil vapour are considered likely to have originated from the former Austral property (as discussed in Section 12)

    The natural soils underlying the fill material (where present) in the Thebarton EPA Assessment Area are typified by the Quaternary age soils and sediments of the Adelaide Plains with the Pooraka Formation and Hindmarsh Clay units considered to dominate the upper soil profile

    The soil geotechnical data and soil vapour results collected by Fyfe (as discussed in Sections 712 and 74 respectively) have been used for the VIRA

    A two-tier approach was adopted for the VIRA The first tier (herein referred to as the Tier 1 assessment) was conducted by comparing the measured soil vapour TCE concentrations to published guideline values adjusted (conservatively) to account for attenuation from sub-slab soil into indoor air The second tier (herein referred to as the Tier 2 assessment) involved the comparison of predicted indoor air TCE concentrations to adopted indoor air criteria or response levels

    94 Tier 1 assessment

    As detailed in Section 74 the initial Tier 1 (screening risk) assessment involved comparing measured soil vapour COPC concentrations with the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land uses (refer to Table 74) Given that the development of the interim soil vapour HILs was based on very conservative assumptions the initial Tier 1 assessment provided only a first-pass screening assessment of the data to determine if further risk assessment would be required

    The interim soil vapour HILs are applicable for the assessment of soil vapour at 0 to 1 m beneath the floor of a building They were based on adopted toxicity reference values (TRV) and relevant exposure parameters (ie adjusted for different land uses) as well as an assumed soil vapour to indoor air attenuation factor of 01

    The soil vapour to indoor air attenuation factor (01) was based on the US EPA (2002) recommended default attenuation factors for the generic screening step of a tiered vapour intrusion assessment process As discussed in the US EPA (2002) document the default attenuation factor of 01 for sub-slab soil vapour was based on a US EPA database of empirical attenuation factors calculated using measurements of indoor air and soil vapours from different sites In 2012 the US EPA provided an updated database which was accompanied by an evaluation and statistical analysis of attenuation factors for volatile CHC in residential buildings US EPA (2012) found the sub-slab to indoor air attenuation factor of 003 to be the 95th percentile In 2015 the revised sub-slab attenuation factor (003) was adopted by the US EPA

    PAGE 48 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    The revised sub-slab to indoor air attenuation factor of 003 was adopted to derive modified residential and commercialindustrial soil vapour HILs for the Tier 1 assessment The modified residential soil vapour HILs are presented in Table 91 relative to the maximum CHC concentrations obtained for soil vapour within the Thebarton EPA Assessment Area

    The Tier 1 assessment based on a comparison of the COPC concentrations measured in soil vapour at various locations within the Thebarton EPA Assessment Area with the modified residential soil vapour HILs detailed in Table 91 indicated the following

    TCE concentrations exceeded the adopted criterion in SV1 to SV9 whereas

    the concentrations of PCE and 11-DCE exceeded the adopted criteria in SV3 only

    These locations were identified as requiring further assessment (ie Tier 2 VIRA ndash refer to Section 95)15

    Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs

    Compound ASC NEPM (1999) HIL

    (microgm3)

    Modified Tier 1 HIL (microgm3)

    (AF = 003)

    Maximum measured soil vapour concentration (microgm3)

    Acceptable

    Location 1 m BGL Location 3 m BGL

    11-DCE 7000 SV3 5900 SV3 14000 No ndash Tier 2 required

    cis-12-DCE 80 265 SV2 21 SV4 30 Yes

    trans-12-DCE 80 265 - ND SV5 20 Yes

    PCE 2000 6650 SV3 6500 SV3 15000 No ndash Tier 2 required

    TCE 20 65 SV3 210000 SV3 100000 0

    No ndash Tier 2 required

    VC 30 100 - ND - ND Yes Notes Values in bold exceed the modified residential soil vapour HILs cis-12-DCE HIL adopted as surrogate screening criterion based on US EPA (2017b) regional screening level for residential air elevated laboratory LOR (ie above modified Tier 1 HIL) also reported Abbreviations AF = attenuation factor HIL = health investigation level ND = non detect

    95 Tier 2 assessment

    951 Tier 2 assessment criteria

    The Tier 2 VIRA criteria for the residential zone comprise HIL-based residential indoor air criteria for the COPC (refer to Section 94) along with the residential indoor air level response ranges for TCE that were

    15 Note that all locations were subjected to the Tier 2 VIRA in this assessment

    80607-1 REV1 30102017 PAGE 49

    EPA REF 0524111 FINAL REPORT

    STAGE 1 ENVIRONMENTAL ASSESSMENT

    THEBARTON ASSESSMENT AREA

    initially developed by the EPA and SA Health for the EPA Assessment Area at Clovelly Park and Mitchell

    Park These screening criteria and indoor air response ranges as detailed in SA EPA (2014) and

    reproduced in Figure 91 are now widely adopted in South Australia for the assessment of TCE relating

    to indoor air exposure

    Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels

    Note The no action response level is applicable where a soil vapour concentration is below the laboratory LOR (ie ND or ldquonon-

    detectrdquo assumed to be lt01 microgm3)

    PAGE 50 80607-1 REV1 | 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    952 Vapour intrusion modelling

    For this VIRA exposure point concentrations (EPCs) of COPC in the indoor air of buildings with a slab on grade crawl space or basement construction were estimated using conservative screening assumptions and the Johnson and Ettinger (1991) vapour transport and mixing model (ie the JampE model)

    The algorithms applied in the JampE (1991) model are detailed in Appendix A of the Arcadis report whereas the modelling spreadsheets for each scenario are provided in Appendix B ndash the Arcadis report is attached to this report as Appendix P

    9521 Input parameters

    The input parameters adopted for the vapour intrusion modelling relate to the following

    the construction type and details of existing or proposed buildings ndash refer to Table 92 for adopted building input parameters

    the nature of the soil profile ndash refer to Table 93 for adopted soil input parameters (0 to 1 m BGL) and

    the contaminant source concentrations ndash refer to Table 6 in Appendix L

    Table 92 Tier 2 vapour intrusion modelling ndash building input parameters

    Parameter Units Adopted value Reference

    Residential Commercial industrial

    Width of Building cm 1000 2000 Friebel and Nadebaum (2011)

    Length of Building cm 1500 2000

    Height of Room cm 240 300

    Height of crawl space cm 30 - Assumption for crawl space

    Attenuation from basement to ground floor air

    - 01 01 Friebel and Nadebaum (2011)

    Air Exchange Rate (AER)

    Indoor per hour 06 083 Friebel and Nadebaum (2011)

    Crawl space per hour 06 - Friebel and Nadebaum (2011)

    Basement per hour 06 - As per residential (indoor)

    Fraction of Cracks in Walls and foundation

    - 0001 0001 Friebel and Nadebaum (2011)

    Qsoil cm 3s 300 277 Calculated from QsoilQbuilding ratio of 0005 (residential) and 0001 (commercial)

    80607-1 REV1 30102017 PAGE 51

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters

    Parameter Units Adopted value Reference

    Depth cm 100 Depth of shallow soil vapour data

    Total porosity - 047 Site specific geotechnical data ndash ie averaged from MW3 and MW11 shallow samples (refer to Table 1 in Appendix L) Air filled porosity - 030

    Water filled porosity - 017 Notes ie representing a conservative approach whereby data for the shallow samples with the highest total porosity and lowest degree of saturation (and therefore the highest air filled porosity) have been adopted

    The site specific attenuation factors calculated within the vapour intrusion models (Appendix B of the Arcadis report) are summarised in Table 94 These are chemical and depth specific values applicable to each building construction scenario These attenuation factors have been applied to the soil vapour data measured across the Thebarton EPA Assessment Area to calculate indoor air concentrations (residential properties only) in proximity to each soil vapour location ndash for commercialindustrial properties (slab on grade) indoor air concentrations have only been calculated with respect to the soil vapour data obtained for SV3 (ie the soil vapour bore with the highest measured TCE concentrations)

    Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air

    Scenario Attenuation factor

    Residential ndash slab on grade 706 x 10-4

    Residential ndash crawl space 209 x 10-3

    Residential ndash basement 113 x 10-1

    Commercial ndash slab on grade 408 x 10-4

    Notes ie soil vapour intrusion to indoor air of residential living spaces refer to Section 953 for a discussion of potential vapour intrusion risks associated with commercialindustrial properties

    The chemical parameters of the COPC adopted in the JampE model were updated with data from the chemical database in the Risk Assessment Information System (RAIS 2016) as detailed in Table 95

    Table 95 Summary of chemical parameters adopted for vapour intrusion modelling

    Chemical Diffusivity in Air Diffusivity in Water Solubility Henryrsquos Law Molecular weight (Dair) Water (Dwater) (S) Constant 25oC (gmol)

    (cm2s) (cm2s) (mgL) (unitless)

    11-DCE 00863 0000011 2420 107 969

    PCE 00505 000000946 206 0724 166

    TCE 00687 00000102 1280 0403 131

    PAGE 52 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    9522 Predicted indoor air concentrations

    Residential The predicted indoor air concentrations for each soil vapour data point as calculated by Arcadis for the three residential building scenarios (ie slab on grade crawl space and basement) are presented in Appendix C of the Arcadis report (included in this report as Appendix P)

    Table 96 provides a comparison of predicted indoor air concentrations against the EPA response levels detailed in Section 951 (Figure 91) ndash ie using the 1 m soil vapour data space for slab on grade and crawl space scenarios versus the 3 m soil vapour data for basements

    It should be noted that if residential properties within the Thebarton EPA Assessment Area have basements however the vapour intrusion risks will increase whereas slab on grade construction will carry a lesser vapour intrusion risk (as detailed in Table 96)

    Commercialindustrial The predicted indoor air concentrations as calculated by Arcadis for a commercialindustrial (ie slab on grade) land use scenario with respect to the soil vapour data obtained for SV3 (ie maximum measured soil vapour concentrations) are as follows

    11-DCE 3 microgm3

    PCE 19 microgm3 and

    TCE 86 microgm3

    As these values are not directly comparable to the EPA response levels developed for residential land use further discussion of potential vapour intrusion risks to human health under a commercialindustrial land use

    scenario is included in Section 953

    As discussed for residential properties the vapour intrusion risks may increase if basements are present

    80607-1 REV1 30102017 PAGE 53

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Table 96 Comparison of predicted residential indoor air concentrations with SA EPA response levels

    Indoor Air Concentration Ranges (microgmsup3) SA EPA response levels

    non-detect No action

    gt non-detect to lt2 Validation

    2 to lt20 Investigation

    20 to lt200 Intervention

    ge200 Accelerated Intervention

    Soil vapour bore

    Sample depth

    (m)

    Soil vapour TCE concentration

    (microgmsup3)

    Predicted indoor air concentration (microgmsup3)

    Residential scenario

    Slab on grade Crawl space Basement

    Attenuation factor

    7 x 10-4 2 x 10-3 1 x 10-1

    SV1 10 5700 4 11

    SV1 30 21000 2100

    SV2 10 51000 36 102

    SV2 30 890000 89000

    SV2 (FD) 30 940000 94000

    SV3 10 210000 147 420

    SV3 30 1000000 100000

    SV4 10 17000 12 34

    SV4 30 43000 4300

    SV5 10 100000 70 200

    SV5 30 160000 16000

    SV6 10 22000 15 44

    SV6 (FD) 10 22000 15 44

    SV6 30 150000 15000

    SV6 (FD) 30 140000 14000

    SV7 10 22000 15 44

    SV7 30 110000 11000

    SV8 10 2300 2 5

    SV8 30 14000 1400

    SV9 10 170 012 030

    SV9 30 260 26

    SV10 10 9 0007 0019

    SV10 30 51 51

    SV11 10 lt18 - -

    SV12 10 16 0011 0032

    SV12 30 55 55

    SV13 10 lt21 - -

    PAGE 54 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Notes With respect to the predicted indoor air CHC concentrations in the Arcadis VIRA report (refer to Appendix P) the results in Table 5 were calculated for SV3 using the unrounded attenuation factors presented in Appendix B (and Table 94 of this report) whereas the TCE indoor air concentrations in Appendix C (as summarised in Table 96) were calculated using rounded attenuation factors ndash this does not change the overall interpretation of the results Abbreviations FD = field duplicate

    9523 Sensitivity analysis

    Table 97 presents a qualitative sensitivity analysis for some of the input variables used in the modelling ndash it includes the range of practical values for each variable the value used in the risk assessment the relative model sensitivity and the uncertainty associated with the variable

    Although Arcadis note that a number of parameters used within the risk assessment have a moderate degree of uncertainty associated with them thereby suggesting that the modelling may be sensitive to changes in these parameters values used to define these parameters were selected to be conservative This is considered to have resulted in an assessment which is expected to be conservative and to over-estimate actual risk

    Table 97 Summary of model input parameters subjected to sensitivity analysis

    Input Range of values Value adopted Sensitivity of calculated input parameters variable

    Soil physical parameters

    Total porosity

    Varies by soil type generally 03 to 05

    047 Site-specific

    Indoor air concentrations will decrease with increasing total porosity Moderate sensitivity parameter decreasing by 50 will increase predicted concentration by a factor of 4

    Air filled porosity

    Varies by soil type generally 015 to 03

    03 Site-specific

    Indoor air concentrations will increase with increasing air filled porosity Moderate to high sensitivity parameter reduction by 50 decreases concentration by a factor of 10

    Water filled porosity

    Varies by soil type from 005 (fill or

    sand) to 03 (clay)

    017 Site-specific

    Negligible impact on predicted indoor air concentrations although may decrease with increasing moisture content Very low sensitivity parameter

    Building parameters

    Air exchange rate (AER)

    Varies from 05 hr-1

    in smaller buildings to gt2 hr-1

    06 hr-1 for residential structures

    083 hr-1 for commercial

    Indoor air concentrations will decrease with increasing air exchange Moderate sensitivity parameter has linear relationship with predicted concentrations conservative assumptions used

    80607-1 REV1 30102017 PAGE 55

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Input Range of values Value adopted Sensitivity of calculated input parameters variable

    Advective flow rates

    Varies depending on building size and

    AER

    300 cm3sec Calculated from building AER and

    ratio of 0005

    Indoor air concentrations will increase with increasing advective flow Low sensitivity parameter particularly within normal range of potential values The assumption that advective flow is occurring into a building at all times is generally conservative for Australian settings Advection is unlikely to occur under a crawl space home and diffusive transport is the dominant transport mechanism

    Building size Variable Variable consistent with

    Friebel and Nadebaum (2011)

    Indoor air concentrations decrease with increasing building volume

    Very low sensitivity parameter

    9524 Uncertainties

    The following uncertainties were identified in the Arcadis report (Appendix P)

    Vapour transport modelling

    The use of a model to predict the migration of vapour from a sub-surface source to indoor air requires the simplification of many complex processes in the sub-surface as well as the potential for entry and dispersion within a building or outdoor air To address this simplification the vapour models available (and adopted in this assessment) are considered to be conservative such that uncertainties are addressed through the overshyestimation of likely concentrations

    It should be noted that the vapour model used is designed to be a first tier screening tool and is considered likely to over-estimate air concentrations due to the incorporation of a number of conservative assumptions including the following

    chemical concentrations in soil vapour were assumed to remain constant over the duration of exposure (ie it was assumed that the source was non-depleting and not subject to natural biodegradation processes)

    the maximum reported soil vapour concentrations were assumed to be present beneath nearby dwellings and

    the occurrence of steady well-mixed vapour dispersion within the enclosed or ambient mixing space

    Overall the vapour modelling undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

    PAGE 56 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Toxicological Data

    In general the available scientific information involves the extrapolation of toxicity information from studies involving experimental laboratory animals with some validation of observable health effects obtained through epidemiological studies

    This may introduce two types of uncertainties into the risk assessment as follows

    those related to extrapolating from one species to another and

    those related to extrapolating from the high exposure doses usually used in experimental animal studies to the lower doses usually estimated for human exposure situations

    In order to adjust for these uncertainties toxicity values commonly incorporate safety factors that may vary from 10 to 10000

    Overall the toxicological data presented in this assessment are considered to be current and adequate for the assessment of risks to human health associated with potential exposure to the COPC identified The uncertainties inherent in the toxicological values adopted are considered likely to result in an over-estimation of actual risk

    953 Potential vapour intrusion risks associated with commercialindustrial properties

    An assessment of potential vapour intrusion risks to workers at commercialindustrial properties (slab on grade construction) within the Thebarton EPA Assessment Area was undertaken by Arcadis using the methodology published by US EPA (2009) and incorporated into the ASC NEPM (1999) This approach recommends adjustment of the measured or estimated contaminant concentrations in air to account for site specific exposures by the relevant receptors as follows

    Ca ET EF EDECinh = days hours AT 365 24 year day

    Where

    ECinh = Exposure Adjusted Air Concentration (mgm3) Ca = Chemical Concentration in Air (mgm3) ET = Exposure Time (hoursday) EF = Exposure Frequency (daysyear) ED = Exposure Duration (years) AT = Averaging Time (years)

    = 70 years for non-threshold carcinogens = ED for chemicals assessed based on threshold effects

    80607-1 REV1 30102017 PAGE 57

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Exposure parameters were selected from Australian sources (enHealth 2012b ASC NEPM 1999) for the receptor groups evaluated or were based on site specific factors Table 98 presents an overview of the parameters used whereas adopted inhalation TRVs are presented in Table 99

    Risk was characterised for threshold and non-threshold effects for the COPC ndash spreadsheets presenting the risk calculations are provided in Appendix B of the Arcadis report (as included in Appendix P) For commercialindustrial properties the non-threshold risk level was calculated to be 3 x 10-5 (compared to a target risk level of 1 x 10-5) whereas the threshold risk level was calculated to be 10 (compared to a target risk level of 1) ndash these results indicated a potentially unacceptable vapour intrusion risk to commercialindustrial workers in the vicinity of the maximum soil vapour CHC concentrations (ie at SV3 ndash worst-case scenario based on maximum soil vapour concentrations)

    Table 98 Exposure parameters ndash Commercialindustrial workers

    Exposure parameter Units Value Reference

    Exposure frequency days year 365 ASC NEPM (1999)

    Exposure duration years 30 ASC NEPM (1999)

    Exposure time indoors hoursday 8 ASC NEPM (1999)

    Averaging time

    Non-threshold

    threshold

    Years

    years

    70

    30 ASC NEPM (1999)

    Table 99 Adopted inhalation toxicity reference values

    COPC Toxicity reference values

    Non-threshold (microgm3)

    Reference Threshold (microgm3)

    Reference

    11-DCE NA - 80 ATSDR (1994)

    PCE NA - 200 WHO (2006)

    TCE 41 US EPA (2011) IRIS 2 US EPA (2011) IRIS Notes Abbreviations NA = not applicable

    954 Potential risks to trenchmaintenanceutility workers

    Although trenchmaintenanceutility workers may be exposed to soil vapour concentrations as measured at 1 m BGL due to the short-term nature of such works their total intakes of TCE and other CHC will be low Assuming that a trenchmaintenanceutility worker may be exposed to TCE for a limited number of working days throughout the year (eg 20 days of 8 hours duration within an excavation) their intake will be approximately one fiftieth of the intake of a resident (who is assumed to be exposed 21 hours a day for 365 days a year)

    PAGE 58 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Therefore the management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air)

    96 Conclusions

    On the basis of the available data and the assessment presented in the Arcadis VIRA report (Appendix P) the following conclusions were provided

    Health risks for residents due to the intrusion of CHC in soil vapour into residential buildings with a slab on grade crawl space or basement construction were calculated to be above the adopted EPA response levels and risks to residents may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

    Health risks for commercial workers due to the intrusion of CHC in soil vapour into buildings with a slab on grade construction were calculated to be above the adopted target risk levels and risks to workers may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

    In the absence of specific information regarding building construction within the Thebarton EPA Assessment Area the predicted indoor air concentrations calculated from the 1 m BGL soil vapour data for a residential crawl space scenario are summarised in Table 910

    Table 910 Summary of properties with predicted indoor air concentrations (residential crawl space) above adopted EPA response levels

    EPA response level No of residential properties affected Indoor air concentration (microgm3) Response

    non-detect to lt2 Validation 9

    2 to lt20 Investigation 10

    20 to lt200 Intervention 8

    ge200 Accelerated intervention 3 Notes According to information provided by the EPA there are approximately 130 residential properties located in the Thebarton EPA Assessment Area calculated on the basis of cadastral boundaries ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial facility ndash these data would therefore need to be confirmed via a property survey

    80607-1 REV1 30102017 PAGE 59

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    10 CONCEPTUAL SITE MODEL

    As detailed in Table 101 a CSM has been developed for the Thebarton EPA Assessment Area on the basis of historical information (as summarised in Section 12 as well as Appendices A and B) and the data obtained during the recent Fyfe investigation program

    Table 101 Summary of existing information for the Thebarton EPA Assessment Area

    Topic Summarised Information

    Site Characterisation

    Identification of Assessment Area

    An approximately 27 ha Assessment Area located within the suburb of Thebarton has been defined by the EPA The boundaries of this area are detailed in Section 21 and illustrated on Figure 1

    History of land use Properties located within the Thebarton EPA Assessment Area have been used for a mixture of commercialindustrial and low density residential land uses over time Current commercialindustrial properties include a beverage factory in the north-eastern portion of the assessment area a refrigeration equipment facility a car dealership two hotels (at least one of which has a cellarbasement) automotive and other workshops and the Ice Arena Former commercialindustrial activities have been identified as including a gas works a mechanicrsquos workshop sheet metal working facilities and a farm machinery manufacturer

    Historical investigations

    Reports provided to Fyfe by the EPA that pertain to previous investigations undertaken within the Thebarton EPA Assessment Area have been reviewed and summarised in Appendix A Additional historical information is included in Appendix B

    Local geology Natural soils encountered from the surfacenear surface to the maximum drill depth of 19 m BGL across the Thebarton EPA Assessment Area were considered to be indicative of the Quaternary Pooraka and Hindmarsh Clay formations Whereas fill materials (ie sand gravelcrushed rock andor silt) were encountered to depths of up to 09 m BGL at a number of sampling locations underlying natural soils comprised mainly low to medium plasticity silty or sandy clays with variable gravel contents Geotechnical testing of subsurface soil samples collected from 10 drill cores indicated that the PSD comprised predominantly claysilt with lesser components of sand andor gravel ndash these soil samples were mostly classified as Clay although some were classified as Sandy Clay or Clayey Sand According to Stapledon (1971) the Hindmarsh Clay unit typically contains many structural features and defects which greatly influence its permeability thereby resulting in potential preferential pathways for the vertical and lateral movement of soil vapour and groundwater Such features were not specifically observed during the recent drilling and soil logging work although some gravel lenseslayers were identified

    Hydrogeology In accordance with Gerges (2006) and his classification of the Adelaide metropolitan area into a number of zones based on their individual hydrogeological characteristics the Thebarton EPA Assessment Area is located within Zone 3 (subzone 3E) to the west of the Para Fault It contains five to six Quaternary aquifers and three or four Tertiary aquifers Based on the most recent investigations the depth to water within the Q1 aquifer in the Thebarton EPA Assessment Area ranges from approximately 123 to 159 m BGL and groundwater flows in a general north-westerly direction with a relatively flat hydraulic gradient (000062 to 00012) Salinity levels (based on field EC readings) range from approximately 1230 to 3620 mgL TDS and a groundwater flow velocity range of approximately 44 to 23 myear has

    80607-1 REV1 30102017 PAGE 61

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Topic Summarised Information

    been inferred As detailed in Section 222 a search of the DEWNR (2017) WaterConnect database identified 59 bores within the general Thebarton area of which 18 are located within the Thebarton EPA Assessment Area Although (where recorded) bores were listed as having been installed primarily for monitoring investigation or observation purpose other purposes (for presumed Quaternary aquifer bores) included drainage domestic and industrial A BUA has identified realistic groundwater uses as potentially including potable residential irrigation and primary contact recreationaesthetics Based on proximity to the River Torrens freshwater ecosystem protection has also been considered ndash however since the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area this may not be a realistic beneficial use Since volatile contaminants have been detected within the Q1 aquifer a potential vapour flux risk to future site users has also been considered

    Hydrology No surface water bodies have been identified within the Thebarton EPA Assessment Area The closest surface water body is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west Current stormwater run-off within the Thebarton EPA Assessment Area is expected to be collected by localised (and engineered) drainage systems

    Fyfe Investigation Results

    Groundwater impacts Contaminants identified in groundwater beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected source site (ie the former Austral sheet metal works) in accordance with the predominant flow direction associated with the Q1 aquifer (refer to Figures 4 and 5) The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) but its north-western extent has not yet been determined (whereas its extent has been defined in all other directions)

    Soil vapour impacts Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction (refer to Figures 6 and 7) and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion The soil vapour samples with the maximum TCE concentrations (ie SV3_10m and SV3_30m) also had the highest PCE and 11-DCE concentrations (or elevated LOR) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-) Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE (ie SV2_30m SV3_10m SV3_30m and SV7_30m) exceeded the adopted HILs for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE

    PAGE 62 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Topic Summarised Information

    degradation has not yet resulted in its production (ie at measureable levels) Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

    Potential Exposure Pathways

    Contaminants of Based on the results of historical investigations the EPA identified a number of CHC as being of Potential Concern concern for the Thebarton EPA Assessment Area The main COPC was identified as TCE with

    additional COPC including PCE 12-DCE (cis- and trans-) VC and 11-DCE Further detail is provided in Section 14 These COPC were confirmed by the Fyfe investigations with TCE identified as both the main contaminant in groundwater and soil vapour and the main driver in terms of potential human health risks associated with vapour intrusion into buildings within the Thebarton EPA Assessment Area (refer to Section 9)

    Suspected source and The suspected source of the identified CHC groundwater (and soil vapour) impacts within the affected media Thebarton EPA Assessment Area is the former Austral sheet metal works located over multiple

    allotments between George and Maria Streets from the 1920s until the 1960s-1970s Previous investigations (Appendix A) had identified groundwater CHC impacts on part of this suspected source site The Fyfe investigations have concentrated on impacts within groundwater and soil vapour across the Thebarton EPA Assessment Area both of which generally correlate with the inferred north-westerly groundwater flow direction and are considered to be related to the previously identified dissolved phase groundwater CHC impacts

    Sensitive receptors The following sensitive receptors have been identified as potentially relevant to the Thebarton EPA Assessment Area Ecological groundwater ecosystems within the assessment area extending to at least Dew and Smith

    Streets (ie as the north-western extent of the groundwater CHC plume has not yet been determined) and

    the freshwater ecosystem of the River Torrens located at a distance of approximately 07 km in a hydraulically down-gradient (ie north-westerly) direction but not necessarily representing a groundwater receiving environment

    Human current and future occupants of and visitors to residential properties current and future workers on the source site and other commercialindustrial properties

    within the area current and future underground trenchmaintenanceutility workers and down-gradient groundwater bore users

    Contaminant Possible contaminant transport mechanisms associated with the CHC-impacted groundwater transport identified within the Q1 aquifer beneath the Thebarton EPA Assessment Area include mechanisms flow through the aquifer to a hydraulically down-gradient surface water body andor down-

    gradient groundwater bores vapour generation andor flow via subsurface preferential pathways (eg service trenches

    more permeable soils) and downward movement into underlying aquifers (eg dense non-aqueous phase liquid

    (DNAPL))

    80607-1 REV1 30102017 PAGE 63

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Topic Summarised Information

    Exposure Possible exposure mechanisms associated with impacted groundwater within the Thebarton mechanisms EPA Assessment Area include

    direct contact (eg during extractionuse of groundwater) incidental ingestion (eg during extractionuse of groundwater) and inhalation of vapours (eg during extractionuse of groundwater andor as a result of

    vapour intrusion into buildings)

    Assessment of Risk

    Groundwater risks The recent groundwater analytical results have indicated that the Q1 aquifer beneath the Thebarton EPA Assessment Area contains measurable concentrations of CHC (mainly TCE but also including PCE 12-DCE andor 11-DCE at some locations) Measured concentrations of TCE exceeded the adopted assessment criteria for potable andor primary contact recreation in wells MW02 MW3 MW5 MW6 MW11 MW12 MW14 MW15 MW17 MW20 MW21 and MW23 located on Admella Maria George Albert and Dew Streets as well as Light Terrace with maximum concentrations corresponding to the ldquocorerdquo area of the plume One well (MW25) contained a concentration of carbon tetrachloride that exceeded the adopted potable criterion Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

    Groundwater fate Although scattered detectable concentrations of 12-DCE have been measured in groundwater and transport across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE modelling daughter products has been interpreted to indicate that substantial dechlorination is not

    occurring Groundwater fate and transport modelling (refer to Section 8 and Appendix O) has predicted that the likely extent of the dissolved phase groundwater TCE plume over the next 100 years will extend by another 500 m beyond the boundaries of the current Thebarton EPA Assessment Area However no significant lateral plume expansion is expected

    Vapour intrusion risks A VIRA (refer to Section 9 and Appendix P) was undertaken to assess potential risks to human health from the intrusion of CHC vapours (primarily TCE) into indoor air from soil vapour The predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction in the absence of specific structural information) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and therefore require further action as follows 10 properties within the investigation range (2 to lt20 microgm3) eight properties within the intervention range (20 to lt200 microgm3) and three properties within accelerated intervention range (ge200 microgm3) All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3

    (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as

    PAGE 64 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Topic Summarised Information

    selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which are expected to be overly-conservative) ndash these results will be documented in a subsequent report Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed Management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air)

    Complete Exposure Pathways

    Identified pathways and areas of potential risk

    Based on the results of the recent Fyfe investigations (including the VIRA) and taking into account available historical information (Appendices A and B) and DEWNR (2017) WaterConnect bore information the following complete exposure pathways and associated risks are considered possible for the Thebarton EPA Assessment Area exposure (direct contact incidental ingestion andor inhalation of vapours) during use of

    groundwater for domestic (eg drinking water plumbing garden irrigation) andor recreational (eg filling of swimming poolsspas) purposes

    vapour intrusion into indoor air within 30 residential propertieslocated within the vicinity of soil vapour bores SV1 to SV9 (assuming crawl space construction) ndash although 19 of these properties are predicted to be in the validationinvestigation action level range 11 are predicted to be in the intervention action level range (with actual indoor air monitoring results for properties within the intervention action level range pending)

    vapour intrusion into residential cellarsbasements (if present) in the vicinity of soil vapour bores SV1 to SV10 and SV12 and

    vapour intrusion into the indoor air of commercialindustrial properties ndash although actual risks to site workers would require further specific considerationassessment

    In addition although only assessed in a qualitative manner to date trenchmaintenanceutility workers may also be at risk where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

    Notes calculated on the basis of cadastral boundaries and assuming crawl space construction ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial premises a property survey would be required to confirm building construction details and the number of individual residences affected

    80607-1 REV1 30102017 PAGE 65

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    11 CONCLUSIONS

    Between May and August 2017 Fyfe undertook an investigation of groundwater and soil vapour CHC impacts within an EPA-designated Assessment Area located in Thebarton South Australia The results of the investigation have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties A CSM has been developed from the field analytical and modelling results as presented in Section 10

    The following conclusions have been reached

    Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were present within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m in groundwater well MW17

    Groundwater within the Q1 aquifer is located at a depth of approximately 123 to 159 m BGL and flows in a general north-westerly direction (refer to Figure 4) ndash the closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred16 and the groundwater gradient beneath the Thebarton EPA Assessment area is relatively flat (ie 000062 to 00012)

    Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified to include domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux as assessed by the VIRA) and possibly also potable Although freshwater ecosystem protection was also considered the River Torrens is thought to comprise either a recharge boundary (ie discharging to local groundwater) or to not actually be hydraulically connected to the Q1 aquifer in this area

    Groundwater beneath parts of the Thebarton EPA Assessment Area contains detectable concentrations of various CHC and includes TCE and carbon tetrachloride (one location only) levels that exceed the adopted assessment criteria for potable use andor primary contact recreation ndash thereby indicating that groundwater would be unsuitable for drinking or the filling of swimming poolsspas In addition vapour flux could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the groundwater could be odorous

    16 ie as calculated by Fyfe based on available data

    80607-1 REV1 30102017 PAGE 67

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    The groundwater and soil vapour CHC impacts identified beneath parts of the Thebarton EPA Assessment Area are considered likely to have emanated from the former Austral sheet metal works located over multiple allotments between George and Maria Streets from the 1920s until the 1960sshy1970s The possible presence of on-going (primary andor secondary) source(s) at this property has not yet been investigated

    As depicted on Figures 6 and 7 the current extent of the soil vapour CHC (ie dominated by TCE) impacts has been determined to correspond to the mapped distribution of the groundwater TCE impacts (Figure 5) and is considered to be directly related to groundwater (rather than soil) CHC impacts Although no soil vapour impacts were detected at 1 m BGL in SV11 and SV1317 located near the eastern and western ends of Light Terrace respectively the north-western extents of the groundwater and soil vapour CHC impacts have not yet been determined In addition although the extent of the groundwater TCE plume has been delineated in all other directions the soil vapour TCE plume has not been delineated in any direction

    TCE is considered to be a primary contaminant as well as the dominant (ie in terms of concentration and extent) CHC in both groundwater and soil vapour ndash the presence of PCE and 11-DCE suggests however that more than one primary contaminant is present Although the detectable concentrations of 12-DCE (cis- and trans) are considered to have resulted from the breakdown of TCEPCE no VC has been detected in either groundwater or soil vapour ndash the scattered distribution and relatively low concentrations of 12-DCE as well as the absence of measurable VC have been interpreted to indicate that significant dechlorination of the primary contaminants has not occurred (despite the likely age of the plume ndash ie possibly up to about 90 years old)

    Although the COPC adopted for the soil vapour assessment program included various CHC (ie with TCE identified as the dominant contaminant in groundwater and soil vapour) the Tier 1 VIRA confirmed that TCE PCE and 11-DCE all exceeded the adopted vapour intrusion HILs Based primarily on its greater toxicity however the risk driver for the Thebarton EPA Assessment Area is considered to be TCE

    The VIRA (Tier 2) results for predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and that require further action as follows

    ― 10 properties within the investigation range (2 to lt20 microgm3)

    ― eight properties within the intervention range (20 to lt200 microgm3) and

    ― three properties within accelerated intervention range (ge200 microgm3)

    All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming

    17 noting that the laboratory LOR for TCE was elevated as compared to the other soil vapour samples

    PAGE 68 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises ndash refer to Table 96

    Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentration obtained for soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

    Although only assessed in a qualitative manner trenchmaintenanceutility workers may be at risk in areas where TCE concentrations at 1 m BGL are greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) ndash in this case appropriate management measures would be required to be adopted This should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

    80607-1 REV1 30102017 PAGE 69

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    12 DATA GAPS

    Based on the results obtained during the recent Fyfe investigations as well as available historical information (Appendices A and B) the following data gaps have been identified for the Thebarton EPA Assessment Area

    property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

    groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

    the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

    the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

    80607-1 REV1 30102017 PAGE 71

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    13 REFERENCES

    ANZECCARMCANZ (2000a) Australian Guidelines for Water Quality Monitoring and Reporting

    ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

    ASTM (2001) Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations ASTM Guide D7663-12

    ASTM (2006) Standard Guide for Soil Gas Monitoring in the Vadose Zone ASTM Guide D5314-92

    ATSDR (1994) Toxicological profile ndash 11-Dichloroethene httpswwwatsdrcdcgovToxProfilestpaspid=722amptid=130

    AustralianNew Zealand Standard (1998) Water Quality Sampling Part 1 Guidance on the Design of Sampling Programs Sampling Techniques and the Preservation and Handling of Samples ASNZS 566711998

    AustralianNew Zealand Standard (1998) Water Quality Sampling Part 11 Guidance on Sampling of Groundwaters ASNZS 5667111998

    Bouwer H and Rice RC (1976) A Slug Test Method for Determining Hydraulic Conductivity of Unconfined Aquifers with Completely or Partially Penetrating Wells Water Resources Research vol 12 no 3 pp 423-428

    Butler JJ Jr (1998) The Design Performance and Analysis of Slug Tests

    Cooper HH Bredehoeft JD and Papadopulos SS (1967) Response of a Finite-Diameter Well to an Instantaneous Charge of Water Water Resources Research vol 3 no 1 pp 263-269

    CRC CARE (2013) Petroleum Hydrocarbon Vapour Intrusion Assessment ndash Australian Guidance CRC CARE Technical Report No 23 July 2013

    Dagan G (1978) A Note on Packer Slug and Recovery Tests in Unconfined Aquifers Water Resources Research vol 14 no 5 pp 929-934

    Department of Environment Water and Natural Resources (DEWNR 2017) Water Connect Master Register of All Bores Primary Industries and Resources South Australia

    Duffield G (2007) AQTESOLVreg Professional Version 45 Hydrosolve Inc

    enHealth (2012a) Environmental Health Risk Assessment - Guidelines for assessing human health risks from environmental hazards enHealth Council

    enHealth (2012b) Australian Exposure Factor Guidance Handbook enHealth Council

    Environment Protection Act 1993

    80607-1 REV1 30102017 PAGE 73

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    Environment Protection Regulations 2009

    Friebel E and Nadebaum P (2011) Health Screening Levels for Petroleum Hydrocarbons in Soil and Groundwater CRC CARE Technical Report No 10

    Gerges NZ (1999) The Geology and Hydrogeology of the Adelaide Metropolitan Area Flinders University (South Australia) PhD thesis (unpublished)

    Gerges NZ (2006) Overview of the Hydrogeology of the Adelaide Metropolitan Area DWLBC Report 200610

    Golder Associates (1994) Contamination Assessment George Street Thebarton SA Report to United Land dated 9 December 1994

    Hvorslev MJ (1951) Time Lag and Soil Permeability in Ground-Water Observations Bulletin no 36 Waterways Exper Sta Corps of Engrs US Army Vicksburg Mississippi pp 1-50

    Hyder Z Butler JJ Jr McElwee CD and Liu W (1994) Slug Tests in Partially Penetrating Wells Water Resources Research vol 30 no 11 pp 2945-2957

    ITRC (2007) Vapor Intrusion Pathway - A Practical Guidance

    Johnson PC and Ettinger RA (1991) Heuristic Model for Predicting the Intrusion Rate of Contaminant Vapors

    into Buildings Environ Sci Technology 251445-1452

    McDonald M G and Harbaugh A W (1988) A Modular Three-Dimensional Finite-Difference Ground-Water Flow Model Techniques of Water-Resources Investigations Book 6 Chapter A1 U S Geological Survey

    NEPM (1999) National Environment Protection (Assessment of Site Contamination) Measure Schedules B1 to

    B9 National Environment Protection Council Australia

    NHMRC (2008) Guidelines for Managing Risks in Recreational Water

    NHMRCNRMMC (2011) Australian Drinking Water Guidelines (as revised in 2016)

    NJDEP (2013) Site Remediation Program Vapor Intrusion Technical Guidance (Version 31)

    NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme (2nd edition)

    Payne FC Quinnan JA and Potter ST (2008) Remediation Hydraulics CRC Press Boca Raton FL

    RAIS (2016) Chemical Specific Parameters for Trichloroethylene Risk Assessment Information System Office of Environmental Management US Department of Energy

    REM (2005a) George St Thebarton Site ndash Stage 2 Investigations Report to Luca Group dated 26 August 2005

    REM (2005b) Stage 3 Environmental Site Assessment George St Thebarton SA Report to Luca Group dated 23 November 2005

    SA Department of Mines and Energy (1969) 1250000 Adelaide Geological Map Sheet Sheet S1 54-9

    PAGE 74 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    SA EPA (2007) Regulatory Monitoring and Testing Groundwater Sampling

    SA EPA (2009) Guidelines for the Assessment and Remediation of Groundwater Contamination

    SA EPA (2014) Clovelly Park Mitchell Park Project Management Team Assessment Program Flip Book November 2014

    SA EPA (2015) Environment Protection (Water Quality) Policy

    Standards Australia (1993) Geotechnical Site Investigations AS1726-1993

    Standards Australia (2005) Guide to the Sampling and Investigation of Potentially Contaminated Soil Part 1 Non-Volatile and Semi-Volatile Compounds AS44821-2005

    Stapledon DH (1971) Changes and Structural Defects Developed in some South Australian Clays and their Engineering Consequences Proceedings of Symposium on Soils and Earth Structures in Arid Climates Adelaide 1970

    US EPA (1996) Soil Screening Guidance Technical Background Document Office of Emergency and Remedial Response Washington DC EPA540R95128

    US EPA (1999) Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air Second Edition Compendium Method TO-15 Determination Of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed By Gas Chromatography Mass Spectrometry (GCMS) EPA625R-96010b

    US EPA (2002) OSWER Draft Guidance for Evaluating the Vapour Intrusion to Indoor Air Pathway from Groundwater and Soils (Subsurface Vapour Intrusion Guidance) EPA530-D-02-004

    US EPA (2009) EPArsquos Risk-Screening Environmental Indicators (RSEI) Methodology Office of Pollution Prevention and Toxics Washington DC

    US EPA (2011) IRIS (Integrated Risk Information System) Trichloroethylene Chemical Assessment Summary httpscfpubepagovnceairisiris_documentsdocumentssubst0199_summarypdf

    US EPA (2012) EPArsquos Vapor Intrusion Database Evaluation and Characterization of Attenuation Factors for Chlorinated Volatile Organic Compounds and Residential Buildings

    US EPA (2015) OSWER Technical Guide for Assessing and Mitigating the Vapour Intrusion Pathway from Subsurface Vapour Sources to Indoor Air

    US EPA (2017a) Regional Screening Levels (RSLs) - Generic Tables (June 2017) httpswwwepagovriskregional-screening-levels-rsls-generic-tables-june-2017

    US EPA (2017b) Regional Screening Levels for Chemical Contaminants at Superfund Sites httpwwwepagovreg3hwmdriskhumanrb-concentration_tableGeneric_Tablesindexhtm

    80607-1 REV1 30102017 PAGE 75

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    WHO (2006) Air Quality Guidelines for Europe Second Edition WHO Regional Publications European Series No 91

    WHO (2017) Guidelines for Drinking-water Quality Fourth edition (incorporating the first addendum)

    Wiedemeier T Swanson M Moutoux D Gordon E Wilson J Wilson B Kampbell D Haas P Miller R Hansen J and Chapelle F (1998) Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water National Risk Management Research Laboratory Office of Research and Development US EPA

    Zheng C (1990) MT3D A Modular Three-Dimensional Transport Model for Simulation of Advection Dispersion and Chemical Reactions of Contaminants in Groundwater Systems Prepared for US EPA by Robert S Kerr Environmental Research Laboratory Ada Oklahoma developed by SS Papadopulos amp Associates Inc Rockville Maryland

    PAGE 76 80607-1 REV1 30102017

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    14 STATEMENT OF LIMITATIONS

    The opinions and conclusions presented in this report are specific to the conditions of the Thebarton EPA Assessment Area and the state of legislation currently enacted as at the date of this report Fyfe does not make any representation or warranty that the opinions and conclusions in this report will be applicable in the future as there may be changes in the condition of the Thebarton EPA Assessment Area applicable legislation or other factors that would affect the opinions and conclusions contained in this report

    Fyfe has used the degree of skill and care ordinarily exercised by reputable members of our profession practising in the same or similar locality This report has been prepared for the South Australian Environment Protection Authority for the specific purpose identified in the report Fyfe accepts no liability or responsibility to any third party for the accuracy of any information contained in the report or any opinion or conclusion expressed in the report Neither the whole of the report nor any part or reference thereto may be in any way used relied upon or reproduced by any third party without Fyfersquos prior written approval This report must be read in its entirety including all tables and attachments

    80607-1 REV1 30102017 PAGE 77

    EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

    FIGURES

    Figure 1 Site Location and Assessment Area

    Figure 2 Assessment Point Locations

    Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan

    Figure 4 Groundwater Elevation Contour Plan

    Figure 5 Groundwater Concentration Plan

    Figure 6 Soil Vapour Concentration Plan (10m)

    Figure 7 Soil Vapour Concentration Plan (30m)

    80607-1 REV1 30102017 PAGE 79

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    DEW

    STREET

    DEW

    STREET

    CHAPEL STREETCHAPEL STREET

    PAR

    KER

    STREET

    PAR

    KER

    STREET

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    LIGHT TERRACELIGHT TERRACE

    DEW

    STREET

    DEW

    STREET

    WA

    LSH ST

    WA

    LSH ST

    AD

    MELLA

    STREET

    AD

    MELLA

    STREET

    ALB

    ERT STR

    EETA

    LBER

    T STREET

    HO

    LLAN

    D ST

    REET

    HO

    LLAN

    D ST

    REET

    RANDOLPH STREET

    RANDOLPH STREET

    JAM

    ES STREET

    JAM

    ES STREET

    DOVE STREET

    DOVE STREET

    SMITH STREETSMITH STREET

    MARIA STREETMARIA STREET

    GEORGE STREETGEORGE STREET

    KINTORE STREET

    KINTORE STREET

    PORT ROAD

    PORT ROAD

    PORT ROAD

    PORT ROAD

    CAW

    THO

    RN

    E STR

    EETC

    AWTH

    OR

    NE ST

    REET

    DEVON STREETDEVON STREET

    KINTORE STREETKINTORE STREET

    GOODENOUGH STREETGOODENOUGH STREET

    LIVESTR

    ON

    G PATH

    WAY

    LIVESTR

    ON

    G PATH

    WAY

    CCAAWW

    TTHHOO

    RRNN

    EE SSTTRR

    EEEETT

    HHOO

    LLLLAANN

    DD SSTT

    RREEEETT

    DE

    DEW

    SW

    STREET

    TREET

    JJAM

    EA

    MES S

    S STREET

    TREET

    DDOOVVEE SSTTRREEEETT

    LLIIVVEESSTTRR

    OONN

    GG PPAATTHH

    WWAAYY

    LIGHT TERRLIGHT TERRAACECE

    AD

    MELLA

    SA

    DM

    ELLA STR

    EETTR

    EET

    CHAPEL SCHAPEL STREETTREET

    AALLBB

    EERRTT SSTTRR

    EEEETT

    GEGEORORGE SGE STREETTREET

    PPOORRTT RROOAADD

    PPOORRTT RROOAADD

    DDEEWW

    SSTTRREEEETT

    MMAARRIIAA SSTTRREEEETT

    JJAAMM

    EESS CCOO

    NNGG

    DDOO

    NN DD

    RRIIVV

    EE

    WWAA

    LLSSHH SSTT

    SSMMIITTHH SSTTRREEEETT

    RRANDOLPH S

    ANDOLPH STREETTREET

    PPOORR

    TT RROO

    AADD

    PPOORR

    TT RROO

    AADD

    KKIINNTTOORREE SSTTRREEEETT

    KKIINNTTOORREE SSTTRREEEETT

    PPAARR

    KKEERR

    SSTTRREEEETT

    GGOOOODDEENNOOUUGGHH SSTTRREEEETT

    DDEEVVOONN SSTTRREEEETT

    ASSESSMENT AREA

    CBD

    750m

    LEGEND

    EPA ASSESSMENT AREA

    CADASTRE

    12500 A3

    0 25 50 m

    CLIENT

    SA EPA

    PROJECT

    FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

    EPA THEBARTON ASSESSMENT AREA - STAGE 1

    TITLE

    FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

    PROJECT NO DATE CREATED

    80607-1 290917

    80607_Fig 1 - Site Location and Assessment Areaai REV 1 gt 290917

    LE

    VE

    L 1

    12

    4 S

    OU

    TH

    TE

    RR

    AC

    E

    AD

    EL

    AID

    E S

    A 5

    00

    0

    P

    H

    (08

    ) 8

    23

    2 9

    08

    8

    F

    AX

    (0

    8)

    82

    32

    90

    99

    EM

    AIL

    in

    fo

    fyfe

    co

    ma

    u

    W

    EB

    fy

    fec

    om

    au

    AB

    N

    57

    00

    8 1

    16 1

    30

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    DEW

    STREET

    DEW

    STREET

    CHAPEL STREETCHAPEL STREET

    PAR

    KER

    STREET

    PAR

    KER

    STREET

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    LIGHT TERRACELIGHT TERRACE

    DEW

    STREET

    DEW

    STREET

    WA

    LSH ST

    WA

    LSH ST

    AD

    MELLA

    STREET

    AD

    MELLA

    STREET

    ALB

    ERT STR

    EETA

    LBER

    T STREET

    HO

    LLAN

    D ST

    REET

    HO

    LLAN

    D ST

    REET

    RANDOLPH STREET

    RANDOLPH STREET

    JAM

    ES STREET

    JAM

    ES STREET

    DOVE STREET

    DOVE STREET

    SMITH STREETSMITH STREET

    MARIA STREETMARIA STREET

    GEORGE STREETGEORGE STREET

    KINTORE STREET

    KINTORE STREET

    PORT ROAD

    PORT ROAD

    PORT ROAD

    PORT ROAD

    CAW

    THO

    RN

    E STR

    EETC

    AWTH

    OR

    NE ST

    REET

    DEVON STREETDEVON STREET

    KINTORE STREETKINTORE STREET

    GOODENOUGH STREETGOODENOUGH STREET

    LIVESTR

    ON

    G PATH

    WAY

    LIVESTR

    ON

    G PATH

    WAY

    SV1SV1

    SV2SV2

    SV3SV3SV4SV4

    SV5SV5

    SV6SV6

    SV7SV7SV8SV8

    SV9SV9

    SV10SV10

    SV11SV11SV12SV12

    SV13SV13

    MW1MW1

    MW02MW02

    MW3MW3

    MW4MW4MW5MW5MW6MW6

    MW7MW7

    MW8MW8

    MW9MW9

    MW10MW10MW11MW11

    MW12MW12MW13MW13

    MW14MW14MW15MW15

    MW16MW16

    MW17MW17

    MW18MW18

    MW19MW19

    MW20MW20

    MW21MW21

    MW22MW22

    MW23MW23

    MW24MW24

    MW25MW25

    MW26MW26

    WMS2WMS2WMS1WMS1

    WMS3WMS3WMS4WMS4WMS5WMS5

    WMS6WMS6

    WMS7WMS7WMS8WMS8

    WMS9WMS9WMS10WMS10

    WMS11WMS11

    WMS12WMS12

    WMS13WMS13WMS14WMS14

    WMS15WMS15

    WMS41WMS41

    WMS40WMS40

    WMS39WMS39WMS38WMS38

    WMS16WMS16

    WMS17WMS17

    WMS18WMS18WMS19WMS19

    WMS20WMS20

    WMS21WMS21WMS22WMS22

    WMS23WMS23WMS24WMS24

    WMS25WMS25

    WMS26WMS26

    WMS27WMS27WMS28WMS28WMS29WMS29

    WMS30WMS30

    WMS31WMS31

    WMS32WMS32

    WMS33WMS33

    WMS34WMS34

    WMS35WMS35

    WMS36WMS36

    WMS37WMS37

    WWAA

    LLSSHHSSTT

    SSMMIITTHH SSTTRREEEETT

    RRANDOLPH S

    ANDOLPH STREETTREET

    PPOORR

    TT RROO

    AADD

    PPOORR

    TT RROO

    AADD

    CCAAWW

    TTHHOO

    RRNN

    EE SSTTRR

    EEEETT

    JJAM

    EA

    MES S

    S STREET

    TREET

    HHOO

    LLLLAANN

    DDSSTT

    RREEEETT

    DE

    DEW

    SW

    STREET

    TREET

    DDOOVVEE SSTTRREEEETT

    LLIIVVEESSTTRR

    OONN

    GGPPAATTHH

    WWAAYY

    LIGHT TERRLIGHT TERRAACECE

    CHAPEL SCHAPEL STREETTREET

    AALLBB

    EERRTT SSTTRR

    EEEETT

    AD

    MELLA

    SA

    DM

    ELLA STR

    EETTR

    EET

    GEGEORORGE SGE STREETTREET

    PPOORRTT RROOAADD PPOORRTT RROOAADD

    DDEEWW

    SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

    JJAAMM

    EESS CCOO

    NNGG

    DDOO

    NN DD

    RRIIVV

    EE

    KKIINNTTOORREE SSTTRREEEETT

    KKIINNTTOORREE SSTTRREEEETT

    PPAARR

    KKEERR

    SSTTRREEEETT

    GGOOOODDEENNOOUUGGHH SSTTRREEEETT

    DDEEVVOONN SSTTRREEEETT

    FIGURE 2 ASSESSMENT POINT LOCATIONS

    MMWW88

    MW2MW244 WMS3WMS355

    MW2MW255

    WMS3WMS366

    WMS3WMS377

    WMS3WMS311

    MW2MW222WMS34WMS34

    MW2MW233 WMS3WMS322

    WMS3WMS333

    WMS2WMS277WMS2WMS299 WMS2WMS288

    SSV12V12 SSVV1111 MW19MW19

    MW18MW18 SSVV1133 MW2MW200 WMS3WMS300

    MW2MW211 WMS2WMS255

    WMS2WMS266

    MW17MW17 WMS2WMS244

    WMS2WMS233

    WMS2WMS222 WMS2WMS211

    SSVV99

    SSV10V10WMS2WMS200 MW14MW14MW15MW15 WMS18WMS18

    WMS19WMS19 MW16MW16

    WMS13WMS13MW10MW10 WMS14WMS14MMWW1111SVSV77WMS15WMS15SSVV88WMS16WMS16

    SVSV66WMS4WMS411MW13MW13 LEGENDMW12MW12

    WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS17WMS17 WMS40WMS40 SSVV55 MW0MW022MW9MW9 GROUNDWATER MONITORING WELL

    WMS11WMS11 WMS6WMS6 SOIL VAPOUR BORE

    WATERLOO MEMBRANE SAMPLERTM - ROUND 2

    SVSV22WMS8WMS8SVSVWMS12WMS12 44 WMS7WMS7 MW4MW4MMWW SVSV66 33 MW5MW5WMS3WMS388

    WMS3WMS399 MW7MW7 EPA ASSESSMENT AREAWMS10WMS10 WMS9WMS9

    SVSV11 CADASTRE

    MW3MW3

    MW1MW1 WMS3WMS3WMS4WMS4MW2MW266 WMS5WMS5 12500 A3

    0 25 50 m

    CLIENT

    SA EPAWMS1WMS1

    WMS2WMS2 PROJECT

    EPA THEBARTON ASSESSMENT AREA - STAGE 1

    TITLE

    FIGURE 2 ASSESSMENT POINT LOCATIONS

    PROJECT NO DATE CREATED

    80607-1 280917

    80607_Fig 2 - Assessment Point Locationsai REV 1 gt 280917

    LE

    VE

    L 1

    12

    4 S

    OU

    TH

    TE

    RR

    AC

    E

    AD

    EL

    AID

    E S

    A 5

    00

    0

    PH

    (0

    8)

    82

    32

    90

    88

    F

    AX

    (0

    8)

    82

    32

    90

    99

    E

    MA

    IL

    info

    fy

    fec

    om

    au

    W

    EB

    fy

    fec

    om

    au

    A

    BN

    5

    7 0

    08

    116

    13

    0

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    DEW

    STREET

    DEW

    STREET

    CHAPEL STREETCHAPEL STREET

    PAR

    KER

    STREET

    PAR

    KER

    STREET

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    LIGHT TERRACELIGHT TERRACE

    DEW

    STREET

    DEW

    STREET

    WA

    LSH ST

    WA

    LSH ST

    AD

    MELLA

    STREET

    AD

    MELLA

    STREET

    ALB

    ERT STR

    EETA

    LBER

    T STREET

    HO

    LLAN

    D ST

    REET

    HO

    LLAN

    D ST

    REET

    RANDOLPH STREET

    RANDOLPH STREET

    JAM

    ES STREET

    JAM

    ES STREET

    DOVE STREET

    DOVE STREET

    SMITH STREETSMITH STREET

    MARIA STREETMARIA STREET

    GEORGE STREETGEORGE STREET

    KINTORE STREET

    KINTORE STREET

    PORT ROAD

    PORT ROAD

    PORT ROAD

    PORT ROAD

    CAW

    THO

    RN

    E STR

    EETC

    AWTH

    OR

    NE ST

    REET

    DEVON STREETDEVON STREET

    KINTORE STREETKINTORE STREET

    GOODENOUGH STREETGOODENOUGH STREET

    LIVESTR

    ON

    G PATH

    WAY

    LIVESTR

    ON

    G PATH

    WAY

    WMS2WMS2WMS1WMS1

    WMS3WMS3WMS4WMS4

    WMS5WMS5

    WMS6WMS6

    WMS7WMS7WMS8WMS8

    WMS9WMS9

    WMS10WMS10

    WMS11WMS11

    WMS12WMS12

    WMS13WMS13WMS14WMS14

    WMS15WMS15 WMS41WMS41

    WMS40WMS40

    WMS39WMS39WMS38WMS38

    WMS16WMS16

    WMS17WMS17

    WMS18WMS18WMS19WMS19WMS20WMS20

    WMS21WMS21WMS22WMS22

    WMS23WMS23WMS24WMS24

    WMS25WMS25

    WMS26WMS26

    WMS27WMS27WMS28WMS28WMS29WMS29

    WMS30WMS30

    WMS31WMS31

    WMS32WMS32WMS33WMS33

    WMS34WMS34

    WMS35WMS35

    WMS36WMS36

    WMS37WMS37

    WWAA

    LLSSHHSSTT

    SSMMIITTHH SSTTRREEEETT

    RRANDOLPH S

    ANDOLPH STREETTREET

    PPOORR

    TT RROO

    AADD

    PPOORR

    TT RROO

    AADD

    CCAAWW

    TTHHOO

    RRNN

    EE SSTTRR

    EEEETT

    JJAM

    EA

    MES S

    S STREET

    TREET

    HHOO

    LLLLAANN

    DDSSTT

    RREEEETT

    DE

    DEW

    SW

    STREET

    TREET

    DDOOVVEE SSTTRREEEETT

    LLIIVVEESSTTRR

    OONN

    GGPPAATTHH

    WWAAYY

    LIGHT TERRLIGHT TERRAACECE

    AD

    MELLA

    SA

    DM

    ELLA STR

    EETTR

    EET

    AALLBB

    EERRTT SSTTRR

    EEEETT

    CHAPEL SCHAPEL STREETTREET

    GEGEORORGE SGE STREETTREET

    PPOORRTT RROOAADD PPOORRTT RROOAADD

    DDEEWW

    SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

    JJAAMM

    EESS CCOO

    NNGG

    DDOO

    NN DD

    RRIIVV

    EE

    KKIINNTTOORREE SSTTRREEEETT

    KKIINNTTOORREE SSTTRREEEETT

    PPAARR

    KKEERR

    SSTTRREEEETT

    GGOOOODDEENNOOUUGGHH SSTTRREEEETT

    DDEEVVOONN SSTTRREEEETT

    FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

    TCE CONCENTRATION PLAN

    WMS3WMS355 TCE lt78

    WMS3WMS366 TCE lt77WMS3WMS377

    TCE 44

    WMS3WMS311 TCE lt78

    WMS34WMS34 TCE 11

    WMS3WMS322WMS3WMS333 TCE lt78TCE lt79

    WMS2WMS277WMS2WMS299 WMS2WMS288 TCE 64 TCE lt77 TCE lt8

    WMS3WMS300 TCE lt8

    WMS2WMS255

    WMS2WMS266 TCE 1400(D)

    WMS2WMS222 TCE 38 WMS2WMS211

    TCE lt79

    TCE lt78

    WMS2WMS233 WMS2WMS244 TCE lt77

    TCE 230

    WMS2WMS200 WMS19WMS19TCE lt78 WMS18WMS18 TCE 11000

    TCE 4200

    WMS13WMS13 WMS14WMS14 TCE lt79

    WMS4WMS411WMS15WMS15 TCE 46000WMS16WMS16 TCE 18000 LEGENDTCE lt8

    TCE lt78WMS17WMS17 WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS40WMS40TCE lt79

    TCE 110000 WATERLOO MEMBRANE SAMPLERTM - ROUND 2WMS11WMS11

    TCE 71000WMS12WMS12 EPA ASSESSMENT AREA

    CADASTRE

    WMS6WMS6 TCE lt58 WMS8WMS8 WMS3WMS388 TCE 32WMS7WMS7WMS3WMS399

    TCE 12000 TCE 13000 TCE 1900TCE 1300WMS9WMS9 TCE lt58 NotesWMS10WMS10

    All concentrations are in μgm3 TCE lt58

    D = Duplicate result

    WMS3WMS3WMS4WMS4 12500 A3

    LE

    VE

    L 1

    12

    4 S

    OU

    TH

    TE

    RR

    AC

    E

    AD

    EL

    AID

    E S

    A 5

    00

    0

    PH

    (0

    8)

    82

    32

    90

    88

    F

    AX

    (0

    8)

    82

    32

    90

    99

    E

    MA

    IL

    info

    fy

    fec

    om

    au

    W

    EB

    fy

    fec

    om

    au

    A

    BN

    5

    7 0

    08

    116

    13

    0

    TCE lt57WMS5WMS5 TCE lt57 TCE lt58 0 25 50

    m

    CLIENT

    SA EPA

    WMS2WMS2 TCE lt56

    WMS1WMS1 TCE lt56

    PROJECT

    EPA THEBARTON ASSESSMENT AREA - STAGE 1

    TITLE

    FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

    TCE CONCENTRATION PLAN

    PROJECT NO DATE CREATED

    80607-1 241017

    80607_Fig 3 - WMS TCE Concentration Planai REV 1 gt 241017

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    DEW

    STREET

    DEW

    STREET

    CHAPEL STREETCHAPEL STREET

    PAR

    KER

    STREET

    PAR

    KER

    STREET

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    LIGHT TERRACELIGHT TERRACE

    DEW

    STREET

    DEW

    STREET

    WA

    LSH ST

    WA

    LSH ST

    AD

    MELLA

    STREET

    AD

    MELLA

    STREET

    ALB

    ERT STR

    EETA

    LBER

    T STREET

    HO

    LLAN

    D ST

    REET

    HO

    LLAN

    D ST

    REET

    RANDOLPH STREET

    RANDOLPH STREET

    JAM

    ES STREET

    JAM

    ES STREET

    DOVE STREET

    DOVE STREET

    SMITH STREETSMITH STREET

    MARIA STREETMARIA STREET

    GEORGE STREETGEORGE STREET

    KINTORE STREET

    KINTORE STREET

    PORT ROAD

    PORT ROAD

    PORT ROAD

    PORT ROAD

    CAW

    THO

    RN

    E STR

    EETC

    AWTH

    OR

    NE ST

    REET

    DEVON STREETDEVON STREET

    KINTORE STREETKINTORE STREET

    GOODENOUGH STREETGOODENOUGH STREET

    LIVESTR

    ON

    G PATH

    WAY

    LIVESTR

    ON

    G PATH

    WAY

    MW1MW1

    MW02MW02

    MW3MW3

    MW4MW4MW5MW5

    MW6MW6

    MW7MW7

    MW8MW8

    MW9MW9

    MW10MW10MW11MW11

    MW12MW12

    MW13MW13

    MW14MW14

    MW15MW15

    MW16MW16

    MW17MW17

    MW18MW18

    MW19MW19MW20MW20

    MW21MW21

    MW22MW22

    MW23MW23

    MW24MW24

    MW25MW25

    MW26MW26

    WWAA

    LLSSHHSSTT

    SSMMIITTHH SSTTRREEEETT

    4

    466

    PPOORR

    TT RROO

    AADD

    PPOORR

    TT RROO

    AADD

    RRANDOLPH S

    ANDOLPH STREETTREET 4455

    DE

    DEW

    SW

    STREET

    TREET

    JJAM

    EA

    MES S

    S STREET

    TREET

    HHOO

    LLLLAANN

    DD SSTT

    RREEEETT

    CCAAWW

    TTHHOO

    RRNN

    EE SSTTRR

    EEEETT 4477

    DDOOVVEE SSTTRREEEETT

    4455

    4488

    LLIIVVEESSTTRR

    OONN

    GGPPAATTHH

    WWAAYY

    4455

    LIGHT TERRLIGHT TERRAACECE

    AD

    MELLA

    SA

    DM

    ELLA STR

    EETTR

    EET

    4466

    CHAPEL SCHAPEL STREETTREET

    4477 AA

    LLBBEERR

    TT SSTTRREEEETT

    4499

    GR4466 OUND

    FLOW DIREW

    GEGEORORGE SGE STREETTREET ATER C

    4488 TION

    PPOORRTT RROOAADD PPOORRTT RROOAADD 55

    00 DD

    EEWW SSTTRR

    EEEETT 4499

    MMAARRIIAA SSTTRREEEETT

    4477

    5500

    JJAAMM

    EESS CCOO

    NNGG

    DDOO

    NN DD

    RRIIVV

    EE

    88 44

    KKIINNTTOORREE SSTTRREEEETT

    KKIINNTTOORREE SSTTRREEEETT

    PPAARR

    KKEERR

    SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

    5500

    4499

    DDEEVVOONN SSTTRREEEETT

    FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

    Groundwater SWL MMWW88 Monitoring Well (m AHD)

    MW1 5011 MW2MW244

    MW02 4786

    MW3 484

    MW2MW255 MW4 507

    MW5 4833

    MW6 4794

    MW7 4703

    MW8 4581

    MW9 4728

    MW10 4871

    MW11 4785 MW2MW222

    MW12 4689

    MW13 4662

    MW2MW233 MW14 4723

    MW15 464

    MW16 4577

    MW17 4619

    MW18 4538

    MW19 4735

    MW20 457

    MW21 4531

    MW22 4501

    MW23 4497

    MW24 4537

    MW25 4469

    MW26 4918

    MW19MW19 MW2MW200

    MW2MW211MW18MW18

    MW17MW17

    MW14MW14

    MW15MW15

    MW16MW16

    MW10MW10 LEGEND MMWW1111

    GROUNDWATER MONITORING WELLMW12MW12

    50 INFERRED GROUNDWATER ELEVATION CONTOUR

    MW13MW13

    MW0MW022 INFERRED GROUNDWATER FLOW DIRECTION

    EPA ASSESSMENT AREA

    MW9MW9

    MW5MW5 CADASTREMMWW66 MW4MW4

    MW7MW7 Note This is one interpretation only Other interpretations possibleMW3MW3

    12500 A3

    0 25 50 m

    CLIENT

    SA EPA

    PROJECT

    EPA THEBARTON ASSESSMENT AREA - STAGE 1

    TITLE

    FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

    PROJECT NO DATE CREATED

    80607-1 290917

    MW1MW1 MW2MW266

    80607_Fig 4 - Groundwater Elevation Contour Planai REV 1 gt 290917

    LE

    VE

    L 1

    12

    4 S

    OU

    TH

    TE

    RR

    AC

    E

    AD

    EL

    AID

    E S

    A 5

    00

    0

    PH

    (0

    8)

    82

    32

    90

    88

    F

    AX

    (0

    8)

    82

    32

    90

    99

    E

    MA

    IL

    info

    fy

    fec

    om

    au

    W

    EB

    fy

    fec

    om

    au

    A

    BN

    5

    7 0

    08

    116

    13

    0

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    DEW

    STREET

    DEW

    STREET

    CHAPEL STREETCHAPEL STREET

    PAR

    KER

    STREET

    PAR

    KER

    STREET

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    LIGHT TERRACELIGHT TERRACE

    DEW

    STREET

    DEW

    STREET

    WA

    LSH ST

    WA

    LSH ST

    AD

    MELLA

    STREET

    AD

    MELLA

    STREET

    ALB

    ERT STR

    EETA

    LBER

    T STREET

    HO

    LLAN

    D ST

    REET

    HO

    LLAN

    D ST

    REET

    RANDOLPH STREET

    RANDOLPH STREET

    JAM

    ES STREET

    JAM

    ES STREET

    DOVE STREET

    DOVE STREET

    SMITH STREETSMITH STREET

    MARIA STREETMARIA STREET

    GEORGE STREETGEORGE STREET

    KINTORE STREET

    KINTORE STREET

    PORT ROAD

    PORT ROAD

    PORT ROAD

    PORT ROAD

    CAW

    THO

    RN

    E STR

    EETC

    AWTH

    OR

    NE ST

    REET

    DEVON STREETDEVON STREET

    KINTORE STREETKINTORE STREET

    GOODENOUGH STREETGOODENOUGH STREET

    LIVESTR

    ON

    G PATH

    WAY

    LIVESTR

    ON

    G PATH

    WAY

    MW1MW1

    MW02MW02

    MW3MW3

    MW4MW4

    MW5MW5

    MW6MW6

    MW7MW7

    MW8MW8

    MW9MW9

    MW10MW10MW11MW11

    MW12MW12

    MW13MW13

    MW14MW14

    MW15MW15

    MW16MW16

    MW17MW17

    MW18MW18

    MW19MW19MW20MW20

    MW21MW21

    MW22MW22

    MW23MW23

    MW24MW24

    MW25MW25

    MW26MW26

    WWAA

    LLSSHHSSTT

    SSMMIITTHH SSTTRREEEETT

    ndnd

    RRANDOLPH S

    ANDOLPH STREETTREET

    PPOORR

    TTRR

    OOAA

    DD

    PPOORR

    TTRR

    OOAA

    DD

    JJAM

    EA

    MES S

    S STREET

    TREET

    HHOO

    LLLLAANN

    DDSSTT

    RREEEETT

    CCAAWW

    TTHHOO

    RRNN

    EESSTT

    RREEEETT

    DE

    DEW

    SW

    STREET

    TREET

    DDOOVVEE SSTTRREEEETT

    LLIIVVEESSTTRR

    OONN

    GGPPAATTHH

    WWAAYY

    LIGHT TERRLIGHT TERRAACECE

    AD

    MELLA

    SA

    DM

    ELLA STR

    EETTR

    EET

    AALLBB

    EERRTT SSTTRR

    EEEETT

    CHAPEL SCHAPEL STREETTREET

    ndnd ndnd

    100100

    11000000

    GEGEORORGE SGE STREETTREET

    1010000000

    PPOORRTT RROOAADD PPOORRTT RROOAADD

    DDEEWW

    SSTTRREEEETT

    1010000000 11000000 MMAARRIIAA SSTTRREEEETT

    100100

    JJAAMM

    EESSCC

    OONN

    GGDD

    OONN

    DDRR

    IIVVEE

    KKIINNTTOORREE SSTTRREEEETT ndnd

    KKIINNTTOORREE SSTTRREEEETT

    PPAARR

    KKEERR

    SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

    DDEEVVOONN SSTTRREEEETT

    FIGURE 5 GROUNDWATER CONCENTRATION PLAN

    MW2MW244

    MMWW88 TCE lt1

    PCE lt1

    11-DCE lt1TCE lt1

    12-DCE lt1PCE lt1

    11-DCE lt1MW2MW255 12-DCE lt1

    TCE 2

    PCE lt1

    11-DCE lt1

    12-DCE lt1

    MW2MW222 TCE lt1

    PCE lt1

    11-DCE lt1MW2MW233 12-DCE lt1

    TCE 21

    PCE lt1

    11-DCE lt1

    12-DCE lt1

    MW19MW19 TCE lt1

    MW2MW200 TCE 70 PCE lt1MW2MW211 PCE lt1MW18MW18 11-DCE lt1

    TCE 23 11-DCE lt1TCE 5 12-DCE lt1 PCE lt1 12-DCE lt1PCE lt1 11-DCE lt1

    11-DCE lt1 12-DCE lt1

    12-DCE lt1

    MW17MW17 LEGENDTCE 24 MW14MW14

    PCE lt1 TCE 1100 lt1 MW15MW15 GROUNDWATER MONITORING WELL11-DCE PCE lt1

    12-DCE lt1 TCE 180 11-DCE 2MW16MW16 100 INFERRED TCE GROUNDWATERPCE lt1 12-DCE 4 CONCENTRATION CONTOURSTCE lt1 11-DCE lt1 PCE lt1 12-DCE lt1 11-DCE lt1

    12-DCE lt1 MMWW1111

    EPA ASSESSMENT AREAMW10MW10

    TCE lt1 CADASTREMW12MW12 TCE lt14900 PCE

    lt1 11-DCE lt1TCE 700 PCEMW13MW13 12-DCE lt1 TCE CONCENTRATIONS (μgL)lt1 11-DCE 7PCE

    TCE lt1 lt1 12-DCE 511-DCE gtnd to lt100 100 to lt1000 1000 to lt10000

    MW0MW022PCE lt1 12-DCE lt1 2100011-DCE lt1 MW9MW9 TCE

    PCE lt112-DCE lt1 TCE 2(D) 11-DCE 15PCE lt1 MW5MW5

    10000 to 29000

    nd = non-detect (lt1)12-DCE 4511-DCE lt1 MMWW66 TCE 29000 MW4MW4 12-DCE lt1

    PCE 3 TCE lt1 NotesTCE 29 11-DCE 6MW7MW7 PCE lt1PCE lt1 This is one interpretation only Other interpretations possible12-DCE 23TCE lt1 11-DCE lt111-DCE lt1 All concentrations are in μgL

    12-DCE includes cis and trans PCE lt1 MW3MW3 12-DCE lt112-DCE lt1 11-DCE lt1

    TCE 69 D = Duplicate result12-DCE lt1 PCE lt1

    11-DCE lt1

    12-DCE lt1 MW1MW1

    12500 A3MW2MW266 TCE lt1

    TCE 2 PCE lt1

    PCE lt1 11-DCE lt1

    11-DCE lt1 12-DCE lt1

    12-DCE lt1

    LE

    VE

    L 1

    12

    4 S

    OU

    TH

    TE

    RR

    AC

    E

    AD

    EL

    AID

    E S

    A 5

    00

    0

    PH

    (0

    8)

    82

    32

    90

    88

    F

    AX

    (0

    8)

    82

    32

    90

    99

    E

    MA

    IL

    info

    fy

    fec

    om

    au

    W

    EB

    fy

    fec

    om

    au

    A

    BN

    5

    7 0

    08

    116

    13

    0

    0 25 50 m

    CLIENT

    SA EPA

    PROJECT

    EPA THEBARTON ASSESSMENT AREA - STAGE 1

    TITLE

    FIGURE 5 GROUNDWATER CONCENTRATION PLAN

    PROJECT NO DATE CREATED

    80607-1 280917

    80607_Fig 5 - Groundwater TCE Concentration Plan r2ai REV 2 gt 280917

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    DEW

    STREET

    DEW

    STREET

    CHAPEL STREETCHAPEL STREET

    PAR

    KER

    STREET

    PAR

    KER

    STREET

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    LIGHT TERRACELIGHT TERRACE

    DEW

    STREET

    DEW

    STREET

    WA

    LSH ST

    WA

    LSH ST

    AD

    MELLA

    STREET

    AD

    MELLA

    STREET

    ALB

    ERT STR

    EETA

    LBER

    T STREET

    HO

    LLAN

    D ST

    REET

    HO

    LLAN

    D ST

    REET

    RANDOLPH STREET

    RANDOLPH STREET

    JAM

    ES STREET

    JAM

    ES STREET

    DOVE STREET

    DOVE STREET

    SMITH STREETSMITH STREET

    MARIA STREETMARIA STREET

    GEORGE STREETGEORGE STREET

    KINTORE STREET

    KINTORE STREET

    PORT ROAD

    PORT ROAD

    PORT ROAD

    PORT ROAD

    CAW

    THO

    RN

    E STR

    EETC

    AWTH

    OR

    NE ST

    REET

    DEVON STREETDEVON STREET

    KINTORE STREETKINTORE STREET

    GOODENOUGH STREETGOODENOUGH STREET

    LIVESTR

    ON

    G PATH

    WAY

    LIVESTR

    ON

    G PATH

    WAY

    SV1SV1

    SV2SV2SV3SV3SV4SV4

    SV5SV5

    SV7SV7SV8SV8

    SV9SV9

    SV10SV10

    SV11SV11SV12SV12

    SV13SV13

    SV6SV6

    WWAA

    LLSSHHSSTT

    SSMMIITTHH SSTTRREEEETT

    RRANDOLPH S

    ANDOLPH STREETTREET

    PPOORR

    TTRR

    OOAA

    DD

    PPOORR

    TTRR

    OOAA

    DD

    CCAAWW

    TTHHOO

    RRNN

    EESSTT

    RREEEETT

    HHOO

    LLLLAANN

    DDSSTT

    RREEEETT

    JJAM

    EA

    MES S

    S STREET

    TREET

    DE

    DEW

    SW

    STREET

    TREET

    DDOOVVEE SSTTRREEEETT

    00

    LLIIVVEESSTTRR

    OONN

    GGPPAATTHH

    WWAAYY

    LIGHT TERRLIGHT TERRAACECE

    AD

    MELLA

    SA

    DM

    ELLA STR

    EETTR

    EET

    CHAPEL SCHAPEL STREETTREET

    00

    AALLBB

    EERRTT SSTTRR

    EEEETT

    1010

    GEGEORORGE SGE STREETTREET

    000000

    PPOORRTT RROOAADD

    100100000

    000

    1010

    PPOORRTT RROOAADD

    000000

    DDEEWW

    SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

    JJAAMM

    EESSCC

    OONN

    GGDD

    OONN

    DDRR

    IIVVEE

    KKIINNTTOORREE SSTTRREEEETT 00

    KKIINNTTOORREE SSTTRREEEETT

    PPAARR

    KKEERR

    SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

    DDEEVVOONN SSTTRREEEETT

    FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

    SSVV1111 SSV12V12 TCE lt18

    SSVV1133 TCE 16

    PCE lt54 TCE lt21

    11-DCE lt29 PCE lt25

    12-DCE lt39 11-DCE lt14

    12-DCE lt18

    PCE lt22

    11-DCE lt12

    12-DCE lt16

    TCE 170

    PCE lt54

    11-DCE lt3

    12-DCE lt39 LEGEND SSVV99

    SSV10V10 SOIL VAPOUR BORE

    TCE lt21 0 INFERRED TCE SOIL VAPOUR CONTOUR PCE lt25

    TCE 2200011-DCE lt14 EPA ASSESSMENT AREA

    PCE 1912-DCE lt18

    11-DCE lt27 CADASTRE

    12-DCE lt37 SVSV66SVSV77

    SSVV88 TCE 22000

    TCE 2300 PCE 12 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)TCE 100000 PCE 62 11-DCE lt29PCE 84 0 to lt10000SSVV55lt2711-DCE 12-DCE lt2911-DCE lt33 10000 to lt100000

    100000 to 210000 12-DCE lt36 12-DCE lt44

    TCE 17000 SVSV44 SVSV22SVSV33 NotePCE 31 TCE 51000TCE 210000 This is one interpretation only Other interpretations possible11-DCE lt14 PCE 39PCE 650012-DCE lt18 39 Estimated extent of plume has utilised groundwater11-DCE11-DCE 5900 12-DCE 21 concentration data12-DCE lt71

    SVSV11 All concentrations are in (μgmsup3)

    TCE 6300(LD) 12-DCE includes cis and trans PCE 78 LD = Laboratory duplicate result 11-DCE lt29

    12-DCE lt38

    12500 A3

    0 25 50 m

    CLIENT

    SA EPA

    PROJECT

    EPA THEBARTON ASSESSMENT AREA - STAGE 1

    TITLE

    FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

    PROJECT NO DATE CREATED

    80607-1 290917

    80607_Fig 6 - Soil Vapour TCE Concentration Plan - 1mai REV 2 gt 290917

    LE

    VE

    L 1

    12

    4 S

    OU

    TH

    TE

    RR

    AC

    E

    AD

    EL

    AID

    E S

    A 5

    00

    0

    PH

    (0

    8)

    82

    32

    90

    88

    F

    AX

    (0

    8)

    82

    32

    90

    99

    E

    MA

    IL

    info

    fy

    fec

    om

    au

    W

    EB

    fy

    fec

    om

    au

    A

    BN

    5

    7 0

    08

    116

    13

    0

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    JAM

    ES CO

    NG

    DO

    N D

    RIV

    E

    DEW

    STREET

    DEW

    STREET

    CHAPEL STREETCHAPEL STREET

    PAR

    KER

    STREET

    PAR

    KER

    STREET

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    POR

    T RO

    AD

    LIGHT TERRACELIGHT TERRACE

    DEW

    STREET

    DEW

    STREET

    WA

    LSH ST

    WA

    LSH ST

    AD

    MELLA

    STREET

    AD

    MELLA

    STREET

    ALB

    ERT STR

    EETA

    LBER

    T STREET

    HO

    LLAN

    D ST

    REET

    HO

    LLAN

    D ST

    REET

    RANDOLPH STREET

    RANDOLPH STREET

    JAM

    ES STREET

    JAM

    ES STREET

    DOVE STREET

    DOVE STREET

    SMITH STREETSMITH STREET

    MARIA STREETMARIA STREET

    GEORGE STREETGEORGE STREET

    KINTORE STREET

    KINTORE STREET

    PORT ROAD

    PORT ROAD

    PORT ROAD

    PORT ROAD

    CAW

    THO

    RN

    E STR

    EETC

    AWTH

    OR

    NE ST

    REET

    DEVON STREETDEVON STREET

    KINTORE STREETKINTORE STREET

    GOODENOUGH STREETGOODENOUGH STREET

    LIVESTR

    ON

    G PATH

    WAY

    LIVESTR

    ON

    G PATH

    WAY

    SV1SV1

    SV2SV2SV3SV3SV4SV4

    SV5SV5

    SV7SV7SV8SV8

    SV9SV9

    SV10SV10

    SV12SV12

    SV6SV6

    WWAA

    LLSSHHSSTT

    SSMMIITTHH SSTTRREEEETT

    RRANDOLPH S

    ANDOLPH STREETTREET

    PPOORR

    TTRR

    OOAA

    DD

    PPOORR

    TTRR

    OOAA

    DD

    CCAAWW

    TTHHOO

    RRNN

    EESSTT

    RREEEETT

    HHOO

    LLLLAANN

    DDSSTT

    RREEEETT

    DE

    DEW

    SW

    STREET

    TREET

    JJAM

    EA

    MES S

    S STREET

    TREET

    DDOOVVEE SSTTRREEEETT

    00

    LIGHT TERRLIGHT TERRAACECE

    LLIIVVEESSTTRR

    OONN

    GGPPAATTHH

    WWAAYY

    AD

    MELLA

    SA

    DM

    ELLA STR

    EETTR

    EET

    CHAPEL SCHAPEL STREETTREET

    00

    1010000000

    AALLBB

    EERRTT SSTTRR

    EEEETT

    100100 000

    000 GEGEORORGE SGE STREETTREET

    PPOORRTT RROOAADD 11000000000

    000 PPOORRTT RROOAADD

    DDEEWW

    SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

    100100000000

    JJAAMM

    EESSCC

    OONN

    GGDD

    OONN

    DDRR

    IIVVEE

    1010000000

    KKIINNTTOORREE SSTTRREEEETT

    00

    KKIINNTTOORREE SSTTRREEEETT

    PPAARR

    KKEERR

    SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

    DDEEVVOONN SSTTRREEEETT

    FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

    SSV12V12 TCE 55

    PCE lt45

    11-DCE lt24

    12-DCE lt32

    TCE 260

    PCE lt51

    11-DCE lt28

    12-DCE

    SSVV99

    lt37 LEGEND

    SSV10V10 SOIL VAPOUR BORE

    TCE 51 0 INFERRED TCE SOIL VAPOUR CONTOURPCE lt53

    TCE 11000011-DCE lt29

    EPA ASSESSMENT AREAPCE lt13012-DCE lt39

    11-DCE lt69

    CADASTRE12-DCE lt92 SVSV66SVSV77

    SSVV88 TCE 150000

    TCE 14000 56 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)PCETCE 160000 PCE 19 11-DCE lt30PCE 310 0 to lt10000SSVV5511-DCE lt26 12-DCE lt3911-DCE 33 10000 to lt100000

    100000 to lt1000000 1000000

    12-DCE lt35 12-DCE 20

    TCE 43000 SVSV44 SVSV22SVSV33 NotePCE 90 TCE 940000(FD)TCE 1000000 This is one interpretation only Other interpretations possible11-DCE lt15 PCE 15000PCE 1500012-DCE 30 14000 Estimated extent of plume has utilised groundwater11-DCE11-DCE 14000 12-DCE lt930 concentration data12-DCE lt930

    All concentrations are in (μgmsup3) 12-DCE includes cis and trans

    SVSV11 TCE 21000

    FD = Field Duplicate resultPCE 21

    11-DCE lt57

    12-DCE lt76

    12500 A3

    0 25 50 m

    CLIENT

    SA EPA

    PROJECT

    EPA THEBARTON ASSESSMENT AREA - STAGE 1

    TITLE

    FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

    PROJECT NO DATE CREATED

    80607-1 290917

    80607_Fig 7 - Soil Vapour TCE Concentration Plan - 3m r2ai REV 2 gt 290917

    LE

    VE

    L 1

    12

    4 S

    OU

    TH

    TE

    RR

    AC

    E

    AD

    EL

    AID

    E S

    A 5

    00

    0

    PH

    (0

    8)

    82

    32

    90

    88

    F

    AX

    (0

    8)

    82

    32

    90

    99

    E

    MA

    IL

    info

    fy

    fec

    om

    au

    W

    EB

    fy

    fec

    om

    au

    A

    BN

    5

    7 0

    08

    116

    13

    0

    • THEBARTON ASSESSMENT AREA STAGE 1 ENVIRONMENTAL ASSESSMENT FINAL REPORT | EPA REF 0524111 30 OCTOBER 2017 VOLUME 1 REPORT13
    • This report is formatted to print Double Sided
    • TITLE PAGE13
    • CONTENTS13
    • LIST OF ACRONYMS13
    • EXECUTIVE SUMMARY13
    • 1 INTRODUCTION
      • 11 Purpose
      • 12 General background information
      • 13 Definition of the assessment area
      • 14 Identification of contaminants of potential concern
      • 15 Objectives
        • 2 CHARACTERISATION OF THE ASSESSMENT AREA
          • 21 Site identification
          • 22 Regional geology and hydrogeology
          • 23 Data quality objectives
            • 3 SCOPE OF WORK
              • 31 Preliminary work
              • 32 Field investigation and laboratory analysis program
              • 33 Data interpretation
                • 4 METHODOLOGY
                  • 41 Field methodologies
                  • 42 Laboratory analysis
                    • 5 QUALITY ASSURANCE AND QUALITY CONTROL
                      • 51 Field QAQC
                      • 52 Laboratory QAQC
                      • 53 QAQC summary
                        • 6 ASSESSMENT CRITERIA
                          • 61 Groundwater
                          • 62 Soil vapour
                            • 7 RESULTS
                              • 71 Surface and sub surface soil conditions
                              • 72 Waterloo Membrane Samplerstrade
                              • 73 Groundwater
                              • 74 Soil vapour bores
                                • 8 GROUNDWATER FATE AND TRANSPORT MODELLING
                                  • 81 Groundwater flow modelling
                                  • 82 Solute transport modelling
                                    • 9 VAPOUR INTRUSION RISK ASSESSMENT
                                      • 91 Objective
                                      • 92 Areas of interest
                                      • 93 Risk assessment approach
                                      • 94 Tier 1 assessment
                                      • 95 Tier 2 assessment
                                      • 96 Conclusions
                                        • 10 CONCEPTUAL SITE MODEL
                                        • 11 CONCLUSIONS
                                        • 12 DATA GAPS
                                        • 13 REFERENCES
                                        • 14 STATEMENT OF LIMITATIONS
                                        • FIGURES13
                                        • FIGURE 1 SITE LOCATION AND ASSESSMENT AREA
                                        • FIGURE 2 ASSESSMENT POINT LOCATIONS
                                        • FIGURE 3 WATERLOO MEMBRANE SAMPLERTM TCE CONCENTRATION PLAN13
                                        • FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN
                                        • FIGURE 5 GROUNDWATER CONCENTRATION PLAN
                                        • FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)
                                        • FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

      copyFyfe Pty Ltd 2017

      Proprietary Information Statement

      The information contained in this document produced by Fyfe Pty Ltd is solely for the use of the Client identified on the cover sheet for the purpose for which it has been prepared and Fyfe Pty Ltd undertakes no duty to or accepts any responsibility to any third party who may rely upon this document

      All rights reserved No section or element of this document may be removed from this document reproduced electronically stored or transmitted in any form without the written permission of Fyfe Pty Ltd

      Document Information

      Report prepared by Dr Ruth Keogh Principal Environmental Scientist Fyfe Pty Ltd Date 27 October 2017

      Report reviewed and approved by Division Manager - Environment Fyfe Pty Ltd Date 30 October 2017 Marc Andrews

      Client receipt by Shannon Thompson Advisor Site Contamination SA EPA Date 30 October 2017

      Revision History

      Revision Revision Status Date of Issue Prepared Reviewed Approved

      REV 0 Draft 6 October 2017 RK MJA MJA

      REV 1 Final 30 October 2017 RK MJA MJA

      Please note that when viewed electronically this document may contain pages that have been intentionally left blank These blank pages may occur because in consideration of the environment and for your convenience this document has been set up so that it can be printed correctly in double-sided format

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      CONTENTS

      Page

      VOLUME 1 REPORT

      LIST OF ACRONYMS V

      EXECUTIVE SUMMARY VIII

      1 INTRODUCTION 1

      11 Purpose 1

      12 General background information 1

      13 Definition of the assessment area 2

      14 Identification of contaminants of potential concern 2

      15 Objectives 3

      2 CHARACTERISATION OF THE ASSESSMENT AREA 5

      21 Site identification 5

      22 Regional geology and hydrogeology 5

      23 Data quality objectives 7

      3 SCOPE OF WORK 11

      31 Preliminary work 12

      32 Field investigation and laboratory analysis program 12

      33 Data interpretation 14

      4 METHODOLOGY 15

      41 Field methodologies 15

      42 Laboratory analysis 19

      5 QUALITY ASSURANCE AND QUALITY CONTROL 21

      51 Field QAQC 21

      52 Laboratory QAQC 24

      53 QAQC summary 26

      80607-1 REV1 30102017 PAGE I

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      6 ASSESSMENT CRITERIA 27

      61 Groundwater 27

      62 Soil vapour 29

      7 RESULTS 31

      71 Surface and sub surface soil conditions 31

      72 Waterloo Membrane Samplerstrade 32

      73 Groundwater 34

      74 Soil vapour bores 40

      8 GROUNDWATER FATE AND TRANSPORT MODELLING 43

      81 Groundwater flow modelling 43

      82 Solute transport modelling 43

      9 VAPOUR INTRUSION RISK ASSESSMENT 47

      91 Objective 47

      92 Areas of interest 47

      93 Risk assessment approach 47

      94 Tier 1 assessment 48

      95 Tier 2 assessment 49

      96 Conclusions 59

      10 CONCEPTUAL SITE MODEL 61

      11 CONCLUSIONS 67

      12 DATA GAPS 71

      13 REFERENCES 73

      14 STATEMENT OF LIMITATIONS 77

      PAGE II 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      LIST OF TABLES

      Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area 7

      Table 22 Data Quality Objectives 8 Table 31 Scope of field investigation program ndash May to August 2017 12 Table 32 Scope of laboratory testing program 13 Table 41 Summary of field methodologies 15 Table 51 Field QAQC procedures ndash Groundwater 22 Table 52 Field QAQC procedures ndash Soil vapour 23 Table 53 Laboratory QAQC procedures 25 Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area 28 Table 62 Sources of adopted groundwater assessment criteria 29 Table 71 Detectable Waterloo Membrane Samplertrade CHC results 32 Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units 33 Table 73 Hydraulic conductivities (rising and falling head tests) 35 Table 74 Detectable groundwater CHC results 37 Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area 41 Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores 42 Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs 49 Table 92 Tier 2 vapour intrusion modelling ndash building input parameters 51 Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters 52 Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air 52 Table 95 Summary of chemical parameters adopted for vapour intrusion modelling 52 Table 96 Comparison of predicted residential indoor air concentrations with SA EPA

      response levels 54 Table 97 Summary of model input parameters subjected to sensitivity analysis 55 Table 98 Exposure parameters ndash Commercialindustrial workers 58 Table 99 Adopted inhalation toxicity reference values 58 Table 910 Summary of properties with predicted indoor air concentrations

      (residential crawl space) above adopted EPA response levels 59 Table 101 Summary of existing information for the Thebarton EPA Assessment Area 61

      LIST OF FIGURES (in text)

      Figure 71 Piper diagram 39 Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green)

      relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple) 46

      Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels 50

      80607-1 REV1 30102017 PAGE III

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      FIGURES follow page 79

      Figure 1 Site Location and Assessment Area Figure 2 Assessment Point Locations Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan Figure 4 Groundwater Elevation Contour Plan Figure 5 Groundwater Concentration Plan Figure 6 Soil Vapour Concentration Plan (10 m) Figure 7 Soil Vapour Concentration Plan (30 m)

      VOLUME 2 APPENDICES

      APPENDICES

      Appendix A Historical Report Summary Appendix B Historical Information Supplied by the EPA Appendix C DEWNR Registered Groundwater Database Search Results Appendix D Groundwater Well Permits Appendix E Field Sampling Sheets ndash Groundwater Appendix F Survey Data Appendix G Certified Laboratory Certificates and Chain of Custody Documentation Appendix H Groundwater Well Log Reports Appendix I WMStrade Borehole Log Reports Appendix J Soil Vapour Borehole Log Reports Appendix K Waste Transport Certificates Appendix L Tabulated Results ndash Soil Vapour Geotechnical and Groundwater Appendix M Equipment Calibration Records Appendix N Drill Core Photographs Appendix O Arcadis Groundwater Fate and Transport Modelling Report Appendix P Arcadis Vapour Intrusion Risk Assessment Report

      PAGE IV 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      LIST OF ACRONYMS

      AER Air Exchange Rate

      AF Attenuation Factor

      AHD Australian Height Datum

      ANZECC Australian and New Zealand Environment and Conservation Council

      ARMCANZ Agriculture and Resource Management Council of Australia and New Zealand

      ASC Assessment of Site Contamination

      ASTM American Standard Testing Material

      AT Averaging Time

      ATSDR Agency for Toxic Substances and Disease Registry

      AWQC Australian Water Quality Centre

      BGL Below Ground Level

      BTEX Benzene Toluene Ethylbenzene Xylenes

      BTOC Below Top of Casing

      BUA Beneficial Use Assessment

      CBD Central Business District

      CHC Chlorinated Hydrocarbon Compound

      COC Chain of Custody

      COPC Contaminants of Potential Concern

      CRC CARE Cooperative Research Centre for Contamination Assessment and Remediation of the Environment

      CSM Conceptual Site Model

      11-DCA 11-dichloroethane

      11-DCE 11-dichloroethene

      12-DCE 12-dichloroethene

      DCE Dichloroethene

      DEC Department of Environment and Conservation

      DEWNR Department of Environment Water and Natural Resources

      DNAPL Dense Non-Aqueous Phase Liquid

      DO Dissolved Oxygen

      DQI Data Quality Indicator

      DQO Data Quality Objective

      EC Electrical Conductivity

      ED Exposure Duration

      80607-1 REV1 30102017 PAGE V

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      EF Exposure Frequency

      EMP Environmental Management Plan

      EPA Environment Protection Authority

      EPC Exposure Point Concentration

      EPP Environment Protection Policy

      ET Exposure Time

      GPA Groundwater Prohibition Area

      GPR Ground Penetrating Radar

      GPS Global Positioning System

      HHRA Human Health Risk Assessment

      HIL Health Investigation Level

      HSP Health and safety Plan

      IPA Isopropyl Alcohol (isopropanol or 2-propanol)

      IRIS Integrated Risk Information System

      ITRC Interstate Technology and Regulatory Council

      JampE Johnson and Ettinger

      JHA Job Hazard Analysis

      LNAPL Light Non-Aqueous Phase Liquid

      LOR Limit of Reporting

      MGA Map Grid of Australia

      MQO Measuring Quality Objectives

      MTC Mass Transfer Co-efficient

      NA Not Applicable

      NAPL Non-Aqueous Phase Liquid

      NATA National Association of Testing Authorities

      ND Non Detect

      NEPM National Environment Protection Measure

      NHMRC National Health and Medical Research Council

      NJDEP New Jersey Department of Environmental Protection

      NRMMC National Resource Management Ministerial Council

      PAH Polycyclic Aromatic Hydrocarbons

      PCE Tetrachloroethene (perchloroethylene)

      PID Photoionisation Detector

      PQL Practical Quantification Limit

      PSD Particle Size Distribution

      QA Quality Assurance

      80607-1 REV1 30102017 PAGE VI

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      QC Quality Control

      RAIS Risk Assessment Information System

      RFQ Request for Quote

      REM Resource and Environmental Management

      RPD Relative Percentage Difference

      RSL Regional Screening Level

      SA EPA South Australian Environment Protection Authority

      SAQP Sampling and Analysis Quality Plan

      SOP Standard Operating Procedure

      SVOC Semi-Volatile Organic Compound

      SWL Standing Water Level

      SWMS Safe Work Method Statement

      111-TCA 111-trichloroethane

      TCE Trichloroethene

      TDS Total Dissolved Solids

      TRH Total Recoverable Hydrocarbons1

      TRV Toxicity Reference Value

      US EPA United Stated Environment Protection Agency

      USGS United States Geological Survey

      VC Vinyl Chloride

      VIRA Vapour Intrusion Risk Assessment

      VOC Volatile Organic Compound

      VOCC Volatile Organic Chlorinated Compound

      WHO World Health Organisation

      WMStrade Waterloo Membrane Samplertrade

      TRH = measurable amount of petroleum-based hydrocarbon (ie complex mixture of crude oil and natural gas (gt 250 compounds) including aromatics aliphatics paraffins unsaturated alkanes and naphthalenes) plus various other compounds including fatty acids esters humic acids phthalates and sterols

      80607-1 REV1 30102017 PAGE VII

      1

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      EXECUTIVE SUMMARY

      Background information

      An approximate 27 hectare mixed use area of Thebarton has been designated by the South Australian Environment Protection Authority (EPA) as the Thebarton EPA Assessment Area

      The former Austral sheet metal works (Austral) property located over multiple allotments between George and Maria Streets from the 1920s until the 1960s-1970s has been identified as a possible source of dissolved phase groundwater chlorinated hydrocarbon (CHC) contamination Groundwater CHC impacts within the uppermost (Quaternary ndash Q1) aquifer were identified as extending in a general north-westerly direction (consistent with regional groundwater flow direction) from the south-eastern portion of the Thebarton EPA Assessment Area and having resulted in the generation of soil vapour containing elevated concentrations of CHC

      The boundaries of the Thebarton EPA Assessment Area were established on the basis of the following

      the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street (part of the former Austral property) and 39 Smith Street (hydraulically down-gradient of the former Austral property) in Thebarton

      the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

      the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

      Key objectives

      The results of the recent investigations undertaken by Fyfe have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties within the Thebarton EPA Assessment Area

      The key objectives detailed by the EPA were to

      further delineate the chlorinated hydrocarbon contamination in groundwater

      further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

      undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

      80607-1 REV1 30102017 PAGE VIII

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      With respect to the VIRA the EPA requested that there be specific consideration of

      residential properties (slab on grade)

      residential properties (crawl space)

      residential properties (with basement) and

      trenchmaintenanceutility workers that may be working in the vicinity of the contamination

      Site conditions

      Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were identified within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m below ground level (BGL) during the drilling of groundwater well MW17 the latter consistent with the depth of groundwater within the Q1 aquifer

      Soil

      Groundwater within the Q1 aquifer is located at a depth of approximately 123 to Groundwater 159 m BGL and flows in a general north-westerly direction The closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred and the groundwater gradient is relatively flat (ie 000062 to 00012)

      Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified (based on factors such a groundwater salinity registered bore use and the locations of potential sensitive receptors) as including domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux) and possibly also potable

      Contaminants of Potential Concern (COPC)

      The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans-) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

      80607-1 REV1 30102017 PAGE IX

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Scope of work

      A groundwater and soil vapour monitoring program was undertaken by Fyfe across the Thebarton EPA Assessment Area between May and August 2017 It involved the following scope of work

      installation of a total of 41 WMStrade units to 1 m BGL in an approximate grid-pattern across the entire assessment area (Round 1) and at specific targeted locations (Round 2) followed by laboratory analysis of retrieved sample units for specific CHC

      drilling and installation of 25 groundwater wells to depths of between 15 and 19 m BGL including a background well to the east of the southern portion of the assessment area

      testing of 30 selected groundwater well drill core samples for geotechnical parameters

      gauging and sampling of the 25 newly installed groundwater wells as well as an existing well located in Admella Street followed by laboratory analysis of all samples for specific CHC and 10 selected samples for major cationsanions natural attenuation parameters and additional nutrients

      aquifer permeability (rising and falling head ldquoslugrdquo) testing of 10 groundwater wells

      drilling and installation of 13 soil vapour bores including 11 nested bores (ie to 1 and 3 m BGL) and two bores to 1 m BGL and

      sampling of all soil vapour bores followed by laboratory analysis of samples for specific CHC and general gases

      The soil vapour data were used to undertake a VIRA aimed at predicting indoor air concentrations of TCE under various land use and building construction scenarios In order to validate the results of the modelling which includes a number of conservative assumptions and is therefore expected to over-estimate potential risk the EPA has commissioned indoor air monitoring in a number of residential properties within the Thebarton EPA Assessment Area ndash the indoor air monitoring results will be reported under separate cover

      Groundwater fate and transport modelling was undertaken to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton EPA Assessment Area The provision of this information is aimed at supporting the definition (extent and geometry) of a potential future Groundwater Prohibition Area (GPA) to be designated by the EPA in accordance with the provisions of Section S103S of the Environment Protection Act 1993

      80607-1 REV1 30102017 PAGE X

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Identified impacts

      Contaminants identified in the Q1 aquifer beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down

      Groundwater

      (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested

      The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected (Austral) source site in accordance with the predominant flow direction associated with the Q1 aquifer The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) ndash whereas its north-western extent has not yet been determined the groundwater CHC plume has been delineated in all other directions

      Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion

      Soil vapour

      The soil vapour samples with the maximum TCE concentrations also had the highest PCE and 11-DCE concentrations (or elevated laboratory limits of reporting (LOR)) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-)

      Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE exceeded the adopted health investigation levels (HILs) for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE degradation has not yet resulted in its production

      Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

      80607-1 REV1 30102017 PAGE XI

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Assessment of risk

      Measured concentrations of TCE exceeded the adopted assessment criteria for potable use andor primary contact recreation in wells located on Admella Maria George Albert Chapel and Dew Streets as well as Light Terrace ndash with the highest concentrations corresponding to the ldquocorerdquo area of the plume One well on Albert Street also contained a concentration of carbon tetrachloride that exceeded the respective potable criterion

      Groundwater risks

      Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous

      Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

      The groundwater modelling undertaken by Arcadis involved the development of an Groundwater fate and transport initial groundwater flow model using MODFLOW followed by the development of a modelling site-specific (three-dimensional) solute transport model using the MT3DMS transport

      code

      The results of this modelling were interpreted to indicate the following

      although scattered detectable concentrations of 12-DCE have been measured in groundwater across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE daughter products indicate that substantial dechlorination is not occurring and

      the dissolved phase groundwater TCE plume is predicted to extend by another 500 m (ie beyond the boundaries of the current Thebarton EPA Assessment Area) over the next 100 years whereas no significant lateral plume expansion is expected

      The VIRA undertaken by Arcadis involved a two-tier assessment approach Whereas Vapour intrusion the Tier 1 screening risk assessment compared the measured soil vapour CHC concentrations to (modified) guideline values the Tier 2 risk assessment involved the application of the Johnson and Ettinger vapour intrusion model to predict indoor air CHC concentrations for residential (slab on grade crawl space and basement construction) and commercialindustrial (slab on grade construction) properties across the assessment area Site-specific geotechnical parameters and soil vapour data collected from 1 and 3 m BGL throughout the Thebarton EPA Assessment Area were used in the modelling It should be noted that overall the vapour modelling

      risks

      80607-1 REV1 30102017 PAGE XII

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

      The results of the VIRA with respect to the predicted indoor air concentrations of TCE within residential properties (assuming crawl space construction) versus adopted EPA response levels indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air that require further action as follows

      10 properties within the investigation range (2 to lt20 microgm3)

      eight properties within the intervention range (20 to lt200 microgm3) and

      three properties within accelerated intervention range (ge200 microgm3)

      All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises

      Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which is expected to be overly-conservative) ndash these results will be documented in a subsequent report

      Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie as determined for the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

      A qualitative assessment of potential risks to subsurface trenchmaintenanceutility workers indicated that exposure management may be required in areas where TCE concentrations at 1 m BGL are above 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific health and safety plan (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a photoionisation detector (PID) unit providing increased ventilation and using appropriate personal protective equipment (eg gas masks) as required

      80607-1 REV1 30102017 PAGE XIII

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Data gaps

      Based on the results obtained during the recent Fyfe investigations as well as available historical information the following data gaps have been identified for the Thebarton EPA Assessment Area

      property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

      groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

      the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

      the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

      Notes ie the interim soil vapour HILs adopted from the National Environment (Assessment of Site Contamination) Measure 1999 (as revised in 2013 ndash ie the ASC NEPM (1999)) but assuming a sub-slab to indoor air attenuation factor of 003 as compared to the value of 01 adopted by the ASC NEPM (1999)

      80607-1 REV1 30102017 PAGE XIV

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      1 INTRODUCTION

      11 Purpose

      Fyfe Pty Ltd (Fyfe) was commissioned by the South Australian Environment Protection Authority (SA EPA referred to herein as the EPA) to undertake Stage 1 groundwater and soil vapour investigation works groundwater fate and transport modelling and a human health vapour intrusion risk assessment (VIRA) within an EPA designated assessment area located within Thebarton South Australia (herein referred to as the Thebarton EPA Assessment Area) The location and extent of the Thebarton EPA Assessment Area referenced within this document is identified on Figure 1

      12 General background information

      Previous environmental assessment work undertaken since 1994 (as summarised in Appendix A) combined with historical information provided by the EPA (as included in Appendix B) indicates that the Thebarton EPA Assessment Area has been used for mixed residential and commercialindustrial purposes over time

      Groundwater impacts2 identified within the uppermost (Quaternary ndash Q1) aquifer in the vicinity of the former Austral sheet metal works (Austral) on George Street included both petroleum hydrocarbons (ie diesel fuel) as well as chlorinated hydrocarbon compounds (CHC) such as trichloroethene (TCE) and were first notified to the EPA in 2006

      Available historical information for the Austral property (ie the suspected source site) indicates that it operated from the 1920s until the 1960s-1970s and occupied an extensive area of Thebarton including

      part of the southern side of George Street extending from about half way between East Terrace3 and Admella Street (ie 11-25 George Street) to the west of Admella Street (ie 31-35 George Street)

      the entire northern side of Maria Street from East Terrace to the west of Admella Street

      part of the southern side of Maria Street (ie from 21 Maria Street) to Admella Street and

      25-27 East Terrace

      2 Note that the term ldquoimpactrdquo has been used by Fyfe to indicate identified concentrations of compounds (specifically chlorinated hydrocarbons) that are not naturally occurring (ie concentrations above background that have resulted from anthropogenic activities) The use of this term does not denote that the presence of these compounds represents a risk to either human health or the environment and the term ldquoimpactrdquo is therefore not directly interchangeable with the term ldquoSite Contaminationrdquo the latter defined under the Environment Protection Act 1993 to include actual or potential harm to human health andor the environment

      3 now James Congdon Drive

      80607-1 REV1 30102017 PAGE 1

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Historical newspaper articles described the Austral property as hosting a factory that extended over more than three acres and included an electroplating facility In 1938 it was described as the largest aluminium utensil manufacturing company in the southern hemisphere

      Other potential sources of groundwater contamination4 identified within the Thebarton EPA Assessment Area include a former gas works (ie located to the south and south-east of the Austral property and including the current Ice Arena property) a mechanicrsquos workshop another sheet metal working facility and a farm machinery manufacturer

      The Stage 1 assessment work described herein was commissioned by the EPA to determine whether historical contamination in the vicinity of George Street was presenting a risk to human health or the environment

      13 Definition of the assessment area

      As detailed on Figure 1 the current EPA Assessment Area covers an area of approximately 27 ha within the suburb of Thebarton located approximately 2 km north-west of the Adelaide central business district (CBD)

      The boundaries of the Thebarton EPA Assessment Area were established by the EPA on the basis of the following

      the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street and 39 Smith Street in Thebarton (refer to Appendix A)

      the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

      the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

      14 Identification of contaminants of potential concern

      The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

      Site Contamination is defined by the Environment Protection Act 1993 as existing if chemical substances are present on or below the surface of a site in concentrations above background the contaminants are there as a result of activity at the site or elsewhere and their presence has resulted in actual or potential harm (that is not trivial) to the health and safety of human beings taking into account current and proposed land uses or water or the environment

      PAGE 2 80607-1 REV1 30102017

      4

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      15 Objectives

      As defined by the EPA the key objectives of the recent Stage 1 environmental assessment program undertaken within the Thebarton EPA Assessment Area (refer to Figure 1) were to

      further delineate the chlorinated hydrocarbon contamination in groundwater

      further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

      undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

      With respect to the VIRA the EPA requested that there be specific consideration of

      residential properties (slab on grade)

      residential properties (crawl space)

      residential properties (with basement) and

      trenchmaintenanceutility workers that may be working in the vicinity of the contamination

      80607-1 REV1 30102017 PAGE 3

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      2 CHARACTERISATION OF THE ASSESSMENT AREA

      21 Site identification

      For the purpose of this investigation program the Thebarton EPA Assessment Area (as delineated in Figure 1) has been defined by the following roadways

      North northern verge of Smith Street

      South Maria Street (between Dew Street and Albert Street) portion of Parker Street (between Maria Street and Goodenough Street) and Goodenough Street (between Parker Street and James Congdon Drive)

      East western verge of Port Road and James Congdon Drive and

      West western verge of Dew Street

      22 Regional geology and hydrogeology

      221 Geology

      The Thebarton area is located within the Adelaide Plains approximately 8 km to the east of Gulf St Vincent and to the west of the Para Fault It lies within the Golden Grove ndash Adelaide Embayment area of the St Vincent Basin which consists of a succession of Tertiary and Quaternary age sediments (with thicknesses of up to 600 m) overlying basement rocks

      The 1250000 Adelaide geological map (SA Department of Mines and Energy 1969) indicates that the near-surface geology of the area consists primarily of Quaternary aged soils and sediments including the Pooraka and Hindmarsh Clay formations The Pleistocene aged Pooraka Formation generally comprises a thickness of approximately 10 m and is of alluvial origin comprising sandy clays and clayey to sandy silts interbedded with layers of clay sand andor gravel The underlying Pleistocene aged Hindmarsh Clay Formation represents the basal unit of the Adelaide Plains and has a maximum general thickness of more than 100 m It generally comprises a basal gravel layer a middle layer of mottled medium to high plasticity (red-brown yellow brown greygreen to orange) often stiff to hard clays and an upper layer of fluvial and alluvial red-brown silty sand Gerges (1999) describes Hindmarsh Clay as comprising a mottled brown to pale olive grey predominantly clay formation that becomes green grey towards the basal section (approximately 16 to 20 m below ground level (BGL)) and is characterised by an increasing gravel content with depth

      Underlying the Hindmarsh Clay are sands and limestone of Tertiary age which are in turn underlain by metamorphosed basement rock of the Proterozoic Umberatana Group

      80607-1 REV1 30102017 PAGE 5

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      222 Hydrogeology

      According to Gerges (2006) the aquifers identified within the Quaternary aged sediments of the Adelaide Plains are typically found within the coarser interbedded silt sand and gravel layers of the Hindmarsh Clay Formation and vary greatly in thickness (typically from 1 to 18 m) lithology and hydraulic conductivity Confining beds between the Quaternary aquifers consist of clay and silt layers and range in thickness from 1 to 20 m These confining beds vary in terms of the amount of coarser grained material they contain their bulk hydraulic conductivity andor the presence and density of fractures In addition their absence in some areas allows direct hydraulic connection between the aquifers

      The Thebarton area is located within Hydrogeological Zone 3 (Subzone 3E) of Gerges (2006) This zone contains five to six Quaternary aquifers and three to four almost flat-lying Tertiary aquifers The first Tertiary aquifer estimated by Gerges (2006) to be intersected at a depth of approximately 130 m BGL near the Para Fault is most frequently accessed for industrial and recreational groundwater use

      The Q1 aquifer assessed as part of the current investigations is typically located at depths of between 3 and 10 m BGL beneath the Adelaide Plains with an average thickness of 2 m The Q1 aquifer contains water of variable salinity with Subzone 3E including a range of 500 to 3500 mgL total dissolved solids (TDS) The gradient of the Q1 aquifer is generally flat (particularly to the west of the Para Fault) and flow direction is typically towards the north-west

      A search of the registered bore database maintained by the Department of Environment Water and Natural Resources (DEWNR (2017) WaterConnect database) identified 59 bores within the general Thebarton area of which 18 are located in the Thebarton EPA Assessment Area Although eight bores were installed for monitoring purposes on or immediately adjacent to the property located at 31-37 George Street (ie part of the former Austral facility) it is understood that only one bore (6628-21951 ndash located within the Admella Street roadway intersecting the Q1 aquifer and identified as MW01 in Appendix A but MW02 by Fyfe5) remains in situ

      In addition to numerous monitoringinvestigationobservation bores the Q1 aquifer within the general (ie broader) Thebarton area is recorded in the DEWNR (2017) database as being accessed for drainage domestic and industrial purposes

      DEWNR (2017) information for registered bores located within the general Thebarton area is included in Appendix C whereas information for bores located within the Thebarton EPA Assessment Area (excluding those associated with the property at 31-37 George Street and installed solely for monitoring purposes6) is summarised in Table 21

      5 This existing groundwater well was identified as MW02 by Fyfe in accordance with the markings on the gatic cover and the DEWNR (2017) WaterConnect bore identification details although it was originally installed as MW01 by REM (refer to discussion of previous reports in Appendix A)

      6 ie 6628-21951 6628-21952 6628-22229 to 6628-22233 and 6628-22236

      PAGE 6 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area

      Bore ID Location Purpose Status Maximu SWL Salinity Yield Aquifer m well (m (mgL (Lsec

      Tertiary (T1)

      depth BGL) TDS) ) (m BGL)

      125 6628-516 Coca Cola plant Rehabilitated 138 1963 794

      6628-1435 Coca Cola plant Backfilled 184 212 921 392 Tertiary (T1)

      6628-4576 Corner of Admella amp Chapel Streets

      125 1454 445 Tertiary (T1)

      6628-7724 Coca Cola plant Observation 155 2017 1272 1516 Tertiary (T1)

      6628-7725 Coca Cola plant Observation 127 3016 1100 1005 Tertiary (T1)

      6628-12516 Coca Cola plant Industrial Backfilled 210 212 1300 1875 Tertiary (T1)

      6628-20663 39 Smith Street Irrigation 121 1105 50 Tertiary (T1)

      6628-20969 39 Smith Street Industrial 30 14 1535 25 Quaternary (Q1)

      6628shy21951

      Admella Street 20 Quaternary (Q1)

      6628-22395 21 James Congdon Drive

      20 157 1541 05 Quaternary

      6628-23525 41 Maria Street 206 273 1078 10 Tertiary (T1)

      Notes Shading indicates that information was not recorded in the database as interpreted from information provided in the database ndash approximate only in some instances

      ie MW02 as included in the groundwater monitoring program of Fyfe ndash refer to Table 31 Abbreviations BGL = below ground level SWL = standing water level TDS = total dissolved solids

      23 Data quality objectives

      The Data Quality Objective (DQO) process as described in Australian Standard AS44821-2005 and the National Environment Protection (Assessment of Site Contamination) Measure (ASC NEPM 1999)7

      Schedule B2 Guideline on Data Collection Sample Design and Reporting and more fully documented in the NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme involves a seven-step iterative approach that was initially developed by the United States Environment Protection Agency (US EPA) to facilitate the systematic planning and verification of contaminated sites assessment projects

      As stated in Schedule B2 of the ASC NEPM (1999) the first six steps of the DQO process comprise the development of qualitative and quantitative statements that define the objectives of the site assessment program and the quantity and quality of data needed to inform risk-based decisions These steps enable the

      All references to the ASC NEPM (1999) refer to the version amended on 16 May 2013

      80607-1 REV1 30102017 PAGE 7

      7

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      project team to communicate the goals decisions constraints (eg time budget) and uncertainties associated with the project and detail how they are to be addressed The seventh step comprises the development of a Sampling and Analysis Quality Plan (SAQP) to generate the data required to adequately characterise site contamination issues and assess their associated potential environmental and human health risks under the proposed land use scenario

      The DQOs defined for the Thebarton EPA Assessment Area are summarised in Table 22

      Table 22 Data Quality Objectives

      Objective Comment

      Step 1 ndash Statement of the Problem According to information provided to Fyfe by the EPA (as summarised in Appendix A) a property located at 31-37 George Street (immediately west of Admella Street) in Thebarton and historically occupied by part of the Austral facility had been found to be underlain by groundwater CHC (primarily TCE) impacts More recent reporting to the EPA for a property at 39 Smith Street located approximately 350 m north-west (and hydraulically down-gradient) of the George Street property indicated that detectable CHC (predominantly TCE) were also present within groundwater Since this area of Thebarton is occupied by a mixture of commercialindustrial and residential properties and the source and extent of the CHC impacts within the Q1 aquifer had not yet been determined potential risks to human health andor the environment had yet to be assessed

      Step 2 ndash The Decision that Needs The assessment works commissioned by the EPA were necessitated to to Result from the Investigation investigate the source extent and magnitude of the groundwater CHC

      contamination beneath a designated area of Thebarton (ie that included both the George Street and Smith Street properties) and to understand the possible risk to public health from potential vapour generation Fyfe have therefore undertaken vapour modelling and intrusion risk assessment works aimed at evaluating whether concentrations of identified groundwater andor soil vapour contaminants pose an unacceptable risk to human health In addition groundwater fate and transport modelling has been undertaken to predict the extent of the plume This will assist the EPA to determine a potential future Groundwater Prohibition Area (GPA) in accordance with the provisions of Section 103S of the Environment Protection Act 1993

      Step 3 ndash Inputs to the Decision The information that was required to resolve the decision statement included the collection of physical and chemical data from across the Thebarton EPA Assessment Area The collected data as well as physical observations regarding the geology of the area and possible preferential contaminant pathways was used to determine potential risks to human health via groundwater fate and transport and vapour intrusion modelling

      Step 4 ndash Boundaries of the Investigation

      The lateral boundaries of the Thebarton EPA Assessment Area are as defined in Sections 13 and 21 as depicted on Figure 1 Vertically the investigations extended as far as the maximum drilled depth (19 m BGL)

      Step 5 ndash Decision Rules The decision rule will be based upon the identification of predicted indoor air concentrations of CHC compounds associated with groundwater andor soil vapour impacts which exceed adopted response levels

      PAGE 8 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Objective Comment

      Step 6 ndash Decision Error Tolerances The purpose of establishing decision error tolerance is to control the acceptable degree of uncertainty upon which decisions are made in order to avoid the making of an incorrect decision and to enable identification of additional investigation monitoring or remediation activities required on the basis of accurate data for the protection of human health and the environment The Measuring Quality Objectives (MQO) include the quality assurance (QA) activities that were conducted during the assessment the quality control (QC) acceptance criteria applicable to the assessment and the adopted Data Quality Indicators (DQIs) as follows (and further discussed in Section 5) completeness ndash a measure of the amount of useable data from a data

      collection activity comparability ndash the confidence (expressed qualitatively) that data may be

      considered to be equivalent for each sampling and analytical event representativeness ndash the confidence (expressed qualitatively) that data

      are representative of each media present on the site precision ndash a quantitative measure of the variability (or reproducibility) of

      data and accuracy (bias) ndash a quantitative measure of the closeness of reported data

      to the true value

      Step 7 ndash Optimisation of the Data collection was undertaken in general accordance with the Sample Collection Design methodologies outlined in the relevant documentsguidelines referenced

      throughout this report As determined by the EPA the data collection design included targeted sampling to investigate and delineate areas of potential groundwater and soil vapour contamination and to assess potential associated human health risks

      80607-1 REV1 30102017 PAGE 9

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      3 SCOPE OF WORK

      The scope of work undertaken by Fyfe was generally consistent with that requested within the original EPA request for quote (RFQ) dated 27 March 2017 Some modifications to the original workscope occurred based on site findings and additional site information was collected where required and as agreed with the EPA in order to achieve the EPArsquos project objectives outlined in Section 15

      As identified in the RFQ the scope of work was designed to

      provide an initial delineation of CHC impacts in soil vapour through the deployment of Waterloo Membrane Samplers (WMStrade) as a screening tool

      further delineate the previously identified CHC impacts in groundwater

      decide based on the results of the WMStrade and groundwater results the need for the number of and the locations of permanent soil vapour monitoring bores

      identify the nature extent and potential source area(s) of the identified CHC impacts in groundwater andor soil vapour

      determine the likely fate and transport of the groundwater CHC plume to support the establishment of a potential future GPA

      determine the potential human health (including vapour intrusion) risk(s) on the basis of the data collected and

      ascertain whether or not a public health risk exists within the Thebarton EPA Assessment Area

      The scope of work is further detailed in Section 32 Variations from the scope of work originally requested in the EPA RFQ were agreed with the EPA during the course of the project and included the following

      deployment of an additional four WMStrade units ndash ie 41 in total as compared to the original allowance of 37

      installation (and sampling) of an additional six nested soil vapour bores (to depths of 1 and 3 m BGL) ndash ie 11 in total as compared to the original allowance of five

      installation (and sampling) two individually located (ie as opposed to the nested locations) soil vapour bores to a depth of 1 m BGL ndash ie as compared to the original allowance of 10

      installation (and sampling) of 25 groundwater monitoring wells ndash ie as compared to the original allowance of 20 and

      sampling of an existing well in Admella Street (MW02) ndash ie not included in the original EPA scope

      80607-1 REV1 30102017 PAGE 11

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      31 Preliminary work

      Preliminary work involved the following

      review and summation of all available historical reports (as supplied by the EPA) ndash refer to Appendix A

      development of a preliminary (working) conceptual site model (CSM) based on a review of the historical data

      preparation of a detailed health and safety plan covering all aspects and stages of the work and

      detailed planning with key stakeholders prior to the execution of the field investigation program

      32 Field investigation and laboratory analysis program

      The scope of the field investigation program undertaken by Fyfe between 31 May and 28 August 2017 is summarised in Table 31 whereas the scope of the laboratory testing program is summarised in Table 32

      A plan showing the various assessment point locations is included as Figure 2

      Table 31 Scope of field investigation program ndash May to August 2017

      Scope Item Description of works Date of works

      Passive soil vapour sampling ndash Round 1

      Thirty-seven WMStrade units identified as WMS 1 to WMS 37 were installed within the soil profile to 1 m BGL at scattered (approximately grid-like) locations across the Thebarton EPA Assessment Area

      31 May and 1 to 2 June

      The WMStrade units were extracted and forwarded to the analytical laboratory 7 June

      Soil bores were located using a hand-held global positioning system (GPS) unit before being backfilled with (drillerrsquos) sand

      7 August

      Monitoring well drilling and installation

      Individual groundwater well permits were obtained from DEWNR prior to well installation ndash copies of the well permits are included in Appendix D Groundwater monitoring wells (MW1 MW3 and MW5 to MW26) were installed to depths of between 15 and 19 m BGL at 24 locations across the Thebarton EPA Assessment Area Background well MW4 was installed to 19 m BGL within a public recreational area located across James Congdon Drive to the east (ie near the south-eastern corner of the Thebarton EPA Assessment Area) All 25 newly installed wells were developed following installation

      28 to 30 June 3 to 7 July and 10 to 14 July

      Geotechnical soil testing

      Intact soil cores collected during the drilling of 10 groundwater wells (MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25) were forwarded to the analytical laboratory for geotechnical testing

      Groundwater gauging

      All 25 newly installed monitoring wells (MW1 and MW3 to MW26) as well as the existing Admella Street well (MW02) were gauged to assess total well depth standing water level (SWL) and the presenceabsence of non aqueous phase liquid (NAPL) This was undertaken as a discrete event prior to the commencement of groundwater sampling

      18 July

      PAGE 12 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Scope Item Description of works Date of works

      Groundwater sampling

      All 26 existing and newly installed wells were sampled using a combination of low flow (micropurge) and HydraSleevetrade sampling techniques (as recorded on the field sampling sheets in Appendix E) ndash samples were forwarded to the analytical laboratories

      18 to 21 and 24 to 25 July

      Aquifer testing Aquifer permeability (slug) testing was undertaken on 10 wells (MW02 MW3 MW7 MW14 MW17 MW20 MW21 MW23 MW25 and MW26) Data was subsequently evaluated by Arcadis Pty Ltd (Arcadis) to estimate the hydraulic conductivity of the aquifer beneath the Thebarton EPA Assessment Area (refer to Section 732)

      28 July

      Soil vapour bore drilling and installation

      Following the receipt of the groundwater data 11 nested soil vapour bores (SV1 to SV10 and SV12) were installed to a depth of 1 and 3 m BGL at selected locations within the Thebarton EPA Assessment Area Two additional soil vapour bores (SV11 and SV13) were installed to a depth of 1 m BGL

      18 21 and 22 August

      Active soil vapour sampling

      Sampling of soil vapour bores was undertaken using summa canister (TO-15) sample collection methods Vapour (canister) and general gas (Tedlar bag) samples were extracted from all 13 locations (ie SV1 to SV13) including the 11 nested bores

      24 August

      Passive soil vapour sampling ndash Round 2

      Following the receipt of the groundwater data and for the purposes of comparison with the soil vapour bore data an additional four WMStrade units (WMS 38 to WMS 41) were installed within the soil profile to 1 m BGL at targeted locations across the Thebarton EPA Assessment Area (ie within approximately 1 m of soil vapour bores SV2 SV4 SV5 and SV7) Soil bores were located using a hand-held GPS unit

      18 August

      The WMStrade units were extracted and forwarded to the analytical laboratory and the soil bores were backfilled with (drillerrsquos) sand

      24 August

      Surveying The locations of all soil vapour bores and groundwater wells were surveyed by a licensed surveyor relative to the Map Grid of Australia (MGA) 1994 and the top of each bore was surveyed relative to Australian Height Datum (AHD) The survey data are included in Appendix F

      22 July and 28 August

      Notes as determined by the EPA

      Table 32 Scope of laboratory testing program

      Scope Item Description of works

      Soil geotechnical testing

      Soil samples from each of three depths within core samples collected during the drilling of groundwater wells MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25 were analysed for particle size distribution (PSD) moisture content including degree of saturation bulk density dry density and specific gravity void ratio and porosity

      80607-1 REV1 30102017 PAGE 13

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Scope Item Description of works

      Groundwater testing Groundwater samples from all 26 wells were analysed for the COPC detailed in Section 14 As requested by the EPA groundwater samples from selected wells (MW02 MW5 MW8 MW9 MW12 MW17 MW21 MW22 MW23 and MW26) were also analysed for the following major cations and anions (calcium magnesium sodium potassium chloride and alkalinity)

      and natural attenuation parameters (carbon dioxide (CO2) sulfate iron manganese nitrate) Additional components reported by the analytical laboratory included nitrite and nitrate + nitrite

      Soil vapour testing The WMStrade units deployed during each of Rounds 1 and 2 were analysed for the COPC detailed in Section 14 The soil vapour (summa canister) samples were analysed for the COPC detailed in Section 14 as well as 2-propanol and general gases (helium hydrogen oxygen nitrogen methane carbon dioxide ethane propane butane iso-butane pentane iso-pentane hexane argon carbon monoxide and ethylene)

      Notes Specific sample depths are detailed in the relevant laboratory reports in Appendix G also known as isopropyl alcohol isopropanol or IPA

      33 Data interpretation

      Following the receipt and collation of the field and laboratory data hydrogeological (fate and transport) and VIRA modelling (refer to Sections 8 and 9 respectively) were undertaken to enable an assessment of risk and to refine the CSM (Section 10)

      PAGE 14 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      4 METHODOLOGY

      41 Field methodologies

      Prior to the commencement of the field investigations a site specific Health and Safety Plan (HSP) including Safe Work Method Statements (SWMS) and a Job Hazard Analysis (JHA) was prepared ndash all personnel working at the site were required to read understand sign and conform to the HSP

      Each proposed drilling location was cleared of underground services by a professional service location company (Pipeline Technologies) using conventional (electronic) service detection methods as well as ground penetrating radar (GPR) Where underground or overhead services were present andor deemed to be a potential safety risk during drilling activities the drill location was moved to an area considered by the Fyfe representative and service locator to be safe All changes to drilling locations were notified to EPA and recorded on a site plan for future reference

      Given that works were undertaken within suburban streets Fyfe employed the services of a qualified traffic management company (Altus Traffic) during drilling activities in order to ensure safety for pedestrians and road users minimal disruption to traffic flow and the provision of a safe working environment

      Field methodologies as detailed in Table 41 were undertaken in accordance with Fyfersquos standard operating procedures (SOPs) Relevant field sampling sheets are included in Appendices F (groundwater) and G (soil vapour ndash combined field sampling sheets and chain of custody (COC) documents) and borehole log reports are presented in Appendices H (groundwater) I (WMStrade) and J (soil vapour)

      Table 41 Summary of field methodologies

      Activity Details

      Passive soil bore sampling The soil bores used to deploy the WMStrade units were hand augered by personnel from Fyfe and Aussie Probe to a depth of 1 m BGL SGS Australia (SGS) personnel suspended each WMStrade unit into its respective borehole from a string The hole was then sealed with an expandable foam plug inside a polyethylene sleeve and the string suspending the sampler was connected to a temporary plastic cap at the ground surface The Round 1 WMStrade units were deployed for periods of between six and seven days whereas the Round 2 WMStrade units were all deployed for six days Following retrieval by SGS each WMStrade unit was placed into a sealed glass vial and a labelled foil bag The WMStrade units did not require chilling during transport to the analytical laboratory Borehole log reports are included in Appendix I whereas combined field sampling sheets and COC documents are presented in Appendix G

      80607-1 REV1 30102017 PAGE 15

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Activity Details

      Groundwater well Groundwater wells were drilled by WB Drilling using a combination of hand augering installation mechanical pushtube and solid auger techniques

      Following the completion of drilling each borehole was fitted with 50 mm class 18 uPVC casing with a basal 6 m long section of slotted well screen A filter pack comprising clean graded sands of suitable size to provide sufficient inflow of groundwater was installed within the annular space between the borehole and the well casing and extended from the base of the screened interval to approximately 1 m above the termination of the slotted casing A 1 m long bentonite collar comprising pelleted or granulated bentonite was placed above the filter pack to prevent water seepage downward along the well casing or borehole from ground surface Each well was grouted up to surface level and fitted with a (lockable) steel gatic cover the latter flush mounted to prevent tripping andor other hazards Groundwater well log reports are included in Appendix H

      Soil logging and Soil logging was undertaken in general accordance with the ASC NEPM (1999) which geotechnical sampling endorses AS1726-1993 In addition to the requirements of AS1726-1993 particular

      attention was paid during logging to any lithological variations such as sandgravel lenses or secondary porosity (such as clay fracturing) which may act as potential preferential pathways for contaminant vapourgroundwater migration through the sub-surface as well as the presence of fill material andor any olfactory or visual evidence of contamination Soil descriptions have been included on the logs in Appendices H to J Cores for geotechnical analysis were collected using push tube sampling methodologies to obtain undisturbed samples Section(s) of core to be tested were retained (intact) within the pushtube liners and capped at each end for storage and transport to the analytical laboratory

      Field screening of soils Field screening of individual soil layers was undertaken at the majority of the drilling locations and involved the use of a photoionisation (PID) unit fitted with an 117 eV lamp (ie as considered suitable for the detection of CHC) The PID unit was calibrated by the hire company prior to delivery and was checked on a daily basis against an isobutylene calibration gas of known concentration Field screen samples were collected with care to ensure that each sample was representative of the soil stratum from which it was collected and experienced minimal loss of volatile compounds The soil material was placed immediately into a zip lock bag and sealed ensuring the bag was half filled (ie such that the volume ratio of soil to air was equal) Soil clumps within the bag were manually broken up and the bag was left to rest for a minimum of five minutes but no longer than 20 minutes Prior to testing the bag was shaken vigorously to release any vapours within the soil To test the tip of the PID probe was inserted into the bag and the maximum volatile organic compound (VOC) reading recorded after a nominal 10 second period or when the reading had peaked Results were recorded on the appropriate bore log sheets presented in Appendices H to J

      Groundwater well Following installation the wells were developed by purging a minimum of four well development volumes (ie until stable parameters were obtained andor until the well purged dry) from

      the casing with a steel bailer andor twister pump to ensure hydraulic connectivity with the aquifer formation

      Groundwater gauging Groundwater levels in the newly installed and existing monitoring wells located across the Thebarton EPA Assessment Area were gauged using an interface probe prior to the commencement of the groundwater sampling program All monitoring wells were gauged for SWL the potential presence of NAPL and the total well depth Groundwater field gauging results are presented in Appendix E

      PAGE 16 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Activity Details

      Groundwater sampling The majority of the wells were sampled using low flow (micropurge) techniques Where recovery was particularly low (ie MW4 MW8 MW15 MW18 MW19 and MW24) and unsuitable for low flow (micropurge) sampling the original sampling technique was abandoned and a HydraSleeveTM (no purge) methodology was used instead Groundwater samples were collected in laboratory-supplied screw top bottles containing appropriate preservative (if required) with no headspace allowed Samples were chilled during storage and transport to the analytical laboratory Disposable nitrile gloves worn by field personnel were changed prior to the collection of each sample Samples for metals (ie iron manganese) analysis were filtered in the field using 045 microm filters Groundwater field sampling sheets are presented in Appendix E

      Low Flow Methodology The low flow sampling technique involved the following the pump was placed close to the bottom of the screened interval the flow rate (up to 05 Lmin) was regulated to maintain an acceptable level of

      drawdown with minimal fluctuation of the dynamic water level during pumping and sampling

      groundwater drawdown was monitored constantly during purging and sampling using an interface probe

      water quality parameters were considered to have stabilised when the following ranges were recorded over three consecutive readings ndash electrical conductivity plusmn 5 ndash pH plusmn 01 ndash temperature plusmn 02degC ndash dissolved oxygen plusmn 10 ndash redox potential plusmn 10 mV

      the stabilisation parameters were recorded on field logging sheets after every one litre of groundwater purged using a calibrated water quality meter and a flow cell suspended in a bucket with litre intervals marked and

      samples were collected once three consecutive stabilisation parameters were recorded and a volume of between 28 and 6 litres was purged prior to sampling

      HydraSleeveTM Methodology The HydraSleeveTM sampling technique involved attaching a stainless steel weight to the bottom and a wire tether clip to the throat of the HydraSleeveTM before lowering it into the water column to the desired depth and allowing it to fill with groundwater After a minimum period of 24 hours the HydraSleeveTM was quickly and smoothly withdrawn from the well and the contents were transferred into the sample containers Water quality parameters were measured after samples were decanted ndash either within the water remaining in the HydraSleeveTM or within a grab sample collected using a disposable bailer

      Hydraulic testing Rising and falling head permeability (ldquoslugrdquo) tests were undertaken to estimate the hydraulic conductivity (K) of the aquifer within various parts of the Thebarton EPA Assessment Area The falling-head tests were initiated by quickly inserting a 1285 m long and 36 mm diameter solid PVC cylinder (slug) into the water column at each well to produce a sufficient sudden rise in the water level The subsequent ldquofallrdquo back to the static water level (recovery) was measured and recorded automatically and in real-time using a

      80607-1 REV1 30102017 PAGE 17

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Activity Details

      pressure transducerdata logger programmed to record water levels at a one second interval After static water level conditions returned in the well the rising-head test was initiated by quickly removing the slug from the well to create a sudden drop in the water column height As with the falling-head test the rise of the water level back to a static condition (recovery) was automatically recorded

      Soil vapour bore Soil vapour bores were drilled by Aussie Probe using a combination of hand augering and installation mechanical pushtube techniques

      Within each 3 m deep soil vapour bore teflon tubing attached to a soil vapour probe was inserted to the base of the hole which had been prefilled with approximately 005 m of clean filter pack sand An additional 045 m of sand (ie approximately 05 m in total) was then added to the hole and topped by a bentonite plug seal of approximately 05 m thickness A second soil vapour probe was installed at a depth of about 1 m within a 05 m sand pack which was overlain by bentonite to a depth of about 02 to 03 m BGL The two 1 m deep soil vapour bores were installed in a similar manner with a sand pack extending from the base to about 05 to 06 m BGL overlain by a bentonite plug to 03 m BGL Each installation was completed with grout to surface and topped with a standard flush-mounted gatic cover Soil vapour bore log reports are included in Appendix J

      Soil vapour sampling All soil vapour sampling works were undertaken by SGS using suitably trained and experienced personnel ndash SGS holds National Association of Testing Authorities (NATA) accreditation for all soil vapour sampling and laboratory analytical works Combined field sampling sheets and COC documents are presented in Appendix G Soil vapour samples were collected using summa canisters and analysed using the US EPA (1999) TO-15 method Sampling involved the connection of a passivated 1 L stainless steel canister to the teflon tubing extending from the soil vapour probe and the use of a soil gas sampling train to restrict flow to a maximum rate of 200 mLmin Canister vacuum pressure was monitored during sampling to enable calculation of the volume of sample drawn into the canister ndash the small amount of vacuum left in the canister at the end of the sampling procedure was measured in the laboratory to check if any leaks occurred during transit (refer to further discussion in Table 52) A shroud was set up around the sampling point and tracer chemicals were introduced at high concentrations by flooding the shroud with helium and placing a cloth soaked with IPA into the shroud Each canister was cleaned and certified by SGS prior to use (refer to Appendix G) and backshyup coconut shell carbon sorbent tube samples were also collected (but not analysed) Summa canisters did not require chilling during transport to the analytical laboratory

      Waste disposal Waste water and surplus soil corescuttings were stored together within 205 litre drums in the rear car park of a commercialindustrial property at 19-21 James Congdon Drive (as organised by the EPA) prior to removaldisposal by a licensed waste removal company (Cleanaway) Analytical results pertaining to the soils were forwarded to the licensed receiving facility and all of the soil was classified as lsquoWaste Fillrsquo in accordance with the Environment Protection Regulations 2009 The waste transport certificates are included in Appendix K

      PAGE 18 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      42 Laboratory analysis

      The following laboratories were used for the analysis of the environmental samples

      complete soil cores for geotechnical sample analysis were forwarded to SMS Geotechnical

      primary groundwater samples collected by Fyfe were analysed at the SGS laboratory whereas secondary groundwater samples were forwarded to EurofinsMGT and

      soil vapour (including WMStrade) samples collected by SGS were analysed at their laboratory

      80607-1 REV1 30102017 PAGE 19

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      5 QUALITY ASSURANCE AND QUALITY CONTROL

      Data quality is typically discussed in terms of the DQIs presented in Table 22 ndash ie completeness comparability representativeness precision and accuracy In order to assess the quality of the data collected during the Fyfe investigation program against these DQIs specific QAQC procedures were implemented during both the field sampling and laboratory analysis programs as detailed in the following sections

      51 Field QAQC

      Field QA procedures undertaken during the recent investigations included the collection of the following QC samples aimed at assessing possible errors associated with cross contamination as well as inconsistencies in sampling andor laboratory analytical techniques

      intra-laboratory duplicate (duplicate) samples submitted to the same (primary laboratory) to assess variation in analyte concentrations between samples collected from the same sampling point andor the repeatability (precision) of the analytical procedures

      inter-laboratory duplicate (split or triplicate) samples submitted to a second laboratory to check on the analytical proficiency (accuracy) of the results produced by the primary laboratory

      equipment rinsate blank samples collected during groundwater sampling only and used to assess cross-contamination that may have occurred from sampling equipment during sampling and

      trip blank samples used to assess whether cross-contamination may have occurred between samples during transport

      Whereas analyte concentrations within the rinsate and trip blank samples should be below the laboratory limit of reporting (LOR) the inter- and intra-laboratory duplicate sample results are assessed via the calculation of a relative percentage difference (RPD) as follows

      (Concentration 1 minus Concentration 2) x 100RPD = (Concentration 1 + Concentration 2) 2

      Maximum RPDs of 30 (inorganics) and 50 (organics) are generally considered acceptable with higher RPD values often recorded where concentrations of an analyte approach the laboratory LOR

      All field QC sample results are included in the summary data tables in Appendix L

      511 Groundwater

      Table 51 presents conformance to field QAQC procedures undertaken as part of the groundwater investigations

      80607-1 REV1 30102017 PAGE 21

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Table 51 Field QAQC procedures ndash Groundwater

      QAQC Item Detail

      Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) AustralianNew Zealand standards ASNZS 566711998 and ASNZS 5667111998 SA EPA (2007) and Fyfe SOPs Details are provided in Table 41

      Calibration of field equipment

      Documentation regarding the calibration of field equipment is included in Appendix M

      Decontamination of All disposable equipment (tubing pump bladders plastic bailers bailer cord and equipment HydraSleeveTM units) were replaced between wells Re-usable equipment (micropurge pump

      interface probe and HydraSleeveTM weights) was decontaminated between sampling locations using potable water and Decon 90trade phosphate free detergent

      Sample preservation and storage

      Samples were kept in laboratory supplied containers in a portable chilled insulated box (esky) prior to and during transport to the laboratory

      Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

      Duplicate samples Two intra-laboratory and two inter-laboratory duplicate samples were analysed for CHC with respect to 26 primary groundwater samples ndash thereby constituting an overall ratio of approximately one duplicate per 65 primary samples (or 15) compared to a generally acceptable ratio of 110 samples (or 10) One intra-laboratory and one inter-laboratory duplicate sample were analysed for the remaining parameters with respect to 10 primary groundwater samples ndash thereby constituting an overall ratio of one duplicate per five primary samples (or 20) compared to a generally acceptable ratio of 110 samples (or 10) Intra- and inter-laboratory duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within the acceptable range with the exception of the following intra-laboratory duplicate sample pair MW9QW1 TCE (67) nitrate (147) and inter-laboratory duplicate sample pair MW9QW2 total CO2 (59) iron (190)

      manganese (183) potassium (64) nitrate (194) The elevated RPD for TCE in the intra-laboratory duplicate sample pair is considered to be related to the low concentration detected and does not alter the interpretation of the data The other RPD exceedances are not considered significant (ie in terms of overall data interpretation) as they were not obtained for identified COPC (as defined in Section 14)

      Rinsate blank samples Six equipment rinsate blank samples (one for each day of sampling) were collected from either the pump housing or a new HydraSleevetrade (final day of sampling only) and analysed for CHC to confirm the effectiveness of the decontamination procedures and the cleanliness of disposable equipment The analytical results obtained for the rinsate blank samples were all below the laboratory LOR thereby indicating that decontamination practices during the groundwater sampling program were acceptable and that no contamination was introduced by the use of the HydraSleevestrade

      Trip blank samples Six trip blank samples were included within containers (eskies) of sample bottles provided by the analytical laboratory and returned to the analytical laboratory All of the trip blank samples were analysed for CHC With the exception of TB187 which contained 1 microgL TCE the analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was limited impact on sample quality during storage or transport of the samples to the analytical laboratory

      PAGE 22 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Notes No duplicate QC samples were collected during the use of the HydraSleeveTM sampling technique as detailed in ANZECCARMCANZ (2000a) at least 5 (ie 120) duplicate samples should be analysed ndash the generally accepted industry standard however is 10 (110) including 5 intra-laboratory and 5 inter-laboratory duplicates

      512 Soil vapour

      Tables 52 presents conformance to field QAQC procedures undertaken as part of the soil vapour (passive and active) investigations

      Table 52 Field QAQC procedures ndash Soil vapour

      QAQC Item Detail

      Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) as well as ASTM (2001 2006) ITRC (2007) CRC CARE (2013) guidance and Fyfe SOPs Details are included in Table 41 and Appendix G (ie SGS sampling methodology sheet) During the use of summa canisters to sample the soil vapour bores leak testing was undertaken (as described in Table 41) Although small leaks or ambient drawdown appear to have occurred with respect to samples SV11_10m (003 helium) SV13_10m (003 helium) and SV1_10m (360 microgm3 IPA) ITRC (2007) and NJDEP (2013) state that ge 5 helium andor gt10 mgm3 IPA are required to be indicative of a significant leak or substantial ambient drawdown Given that the leaks were relatively small (ie 06 (helium) and 36 (IPA) of the levels considered indicative of a significant leak) the data from these bores were still considered to be valid ndash refer to SGS correspondence in Appendix G As detailed in Table 41 a small amount of vacuum was generally left in each summa canister at the end of the sampling procedure and was measured in the laboratory to check if any leaks had occurred during transit However samples SV11_10m SV12_30m as well as the helium blank were recorded as having zero vacuum upon receipt at the analytical laboratory A query lodged with SGS regarding this issue indicated that whereas the helium blank comprised a grab sample collected into a Tedlar bag directly from the helium cylinder (ie without the use of a gauge) the canisters used for samples SV11_10m and SV12_30 were filled during sampling so that there was no remaining vacuum ndash refer to field sampling documentation in Appendix G SGS stated that although it is good practice to have a small amount of vacuum remaining in a canister at the completion of sampling appropriate additional QC measures were employed and the absence of other common background VOCs (eg petroleum hydrocarbons) upon sample testing indicated that leakage had not occurred during transit In addition all canisters are fitted with quick connect one-way valves that are closed upon removal from the sampling train and canistersfittings are leak checked prior to leaving the laboratory and again in the field to ensure that they are leak free Refer to SGS correspondence in Appendix G The presence of detectable IPA (120 microgm3) and TCE (48 microgm3) in the helium blank was also queried with SGS who stated that this (ie variability in the quality of the high purity helium gas used) is not an uncommon occurrence The reason for collecting a helium blank sample is to identify any impurities present in the helium gas so that if a leak does occur during sampling it is possible to determine whether any target compounds could be introduced into the sample train Although a target compound (ie TCE) was detected in the blank the concentration is minor and even if a leak had occurred during sampling (of which there was no evidence) it would not have affected the overall results and data interpretation The presence of IPA in the helium blank is

      80607-1 REV1 30102017 PAGE 23

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      QAQC Item Detail

      suspected by SGS of having resulted from a handling issue in the field ndash ie sub-sampling from the helium cylinder (ie into a summa canister via a flex foil bag) in the vicinity of the high concentrations of IPA being used for leak detection Refer to SGS correspondence in Appendix G

      Sample preservation and storage

      Following collection the WMStrade units were placed into individual glass vials which were sealed and placed into foil bags for transport to the analytical laboratory at ambient temperature Summa canisters were stored in specially constructed cases during transport to the analytical laboratory at ambient temperature

      Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

      QC samples ndash WMStrade sampling

      During the first round of passive soil vapour sampling three additional WMStrade units were deployed in soil bores drilled adjacent to WMS 22 WMS 25 and WMS 28 to act as duplicate QC samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 8) Two trip blank samples were also included with samples transported from and to the analytical laboratory All of the QC samples were analysed by the primary laboratory Intra-duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within an acceptable range (ie lt30) The analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was negligible impact on sample quality during storage or transport of the samples to the analytical laboratory

      QC samples ndash soil vapour bore sampling

      Two intra-laboratory duplicate QC samples were analysed for CHC and general gases with respect to 24 primary soil vapour samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 83) compared to an acceptable ratio of 110 samples (or 10) Intra-laboratory duplicate RPDs were calculated where both samples had a reported concentration above the laboratory LOR All calculated RPDs for CHC and general gases were within an acceptable range (ie lt30) The analytical results obtained for the helium shroud (Tedlar bags) helium blank and IPA shroud (carbon tube) samples were all considered to be satisfactory

      Notes The American Society for Testing and Materials (ASTM) is an internationally recognised source of testing methods Although Appendix J of CRC CARE (2013) stipulates a 110 duplicate sampling ratio for active vapour sampling a specific ratio is not stipulated for passive vapour sampling

      52 Laboratory QAQC

      Laboratory QA procedures generally include the performance of a number of internal checks of data precision and accuracy that are aimed at assessing possible errors associated with sample preparation and analytical techniques Specific types of QC samples analysed by laboratories and the relevant acceptance criteria are as follows

      PAGE 24 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      internal laboratory replicate samples maximum RPD values of 20 to 50 although this varies depending on laboratory LOR

      spike recoveries results between 70 and 130 and

      laboratory controlmethod blanks results below the laboratory LOR

      Table 53 presents conformance to laboratory QAQC procedures undertaken as part of the overall investigation program

      Table 53 Laboratory QAQC procedures

      QAQC Item Detail

      Samples analysed and Samples were generally analysed within specified holding times ndash with the exception extracted within relevant of the following groundwater samples holding times SGS report no ME303457 nitrate was analysed two days late in some samples

      (MW5 MW17 MW26) SGS report no ME303475 nitrate was analysed one day late in all samples and EurofinsMGT report no 555810-W total CO2 was analysed five days late None of these holding time exceedances are considered to be significant with respect to the interpretation of the CHC data the determination of potential human healthenvironmental risks andor the determination of natural attenuation

      Laboratories used and The laboratories used (SGS Eurofins MGT and SMS Geotechnical) were NATA NATA accreditation accredited for the majority of the analyses undertaken

      The exception was SMS Geotechnical which was not NATA accredited for the calculations undertaken to derive some of the data ndash this is the case however for all geotechnical laboratories

      Appropriate analytical methodologies used

      Refer to the laboratory reports in Appendix G

      Laboratory limit of The laboratory LOR is the minimum concentration of an analyte (substance) that can reporting (LOR) be measured with a high degree of confidence that the analyte is present at or above

      that concentration The LOR are presented in the laboratory certificates of analysis (Appendix G) and are considered to be generally appropriate (ie below the adopted assessment criteria ndash refer to Section 62) ndash the following exceptions in soil vapour (ie considered to be due to interference associated with elevated concentrations of other compounds ndash refer to SGS correspondence in Appendix G) are discussed further in Table 101 VC in all of the WMStrade samples relative to the ASC NEPM (1999) interim soil

      vapour health investigation level (HIL) for residential land use cis-12-DCE and VC in two soil vapour bore samples (SV2_30m and SV3_30m)

      relative to the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land use and

      VC in two soil vapour bore samples (SV3_10m and SV7_30m) relative to the ASC NEPM (1999) interim soil vapour HIL for residential land use

      In addition to the above although ultra-trace analysis was requested the laboratory LOR for VC in groundwater (ie 1 microgL) is above the adopted NHMRCMRMMC (2011) potable guideline (ie 03 microgL) ndash refer to Section 612

      80607-1 REV1 30102017 PAGE 25

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      QAQC Item Detail

      Laboratory internal QC analyses

      Results obtained for the laboratory internal QC samples were generally within the acceptable limits of repeatability chemical extraction and detection with the exception of the following SGS report ME303457 matrix spike results for iron were outside normal tolerances

      due to the high concentrations of iron in the spiked sample ndash matrix spike results for iron could therefore not be calculated This is not considered to be a significant issue

      Full details regarding laboratory QAQC procedures and results are presented in the certified laboratory certificates contained in Appendix G

      Notes Since holding times were not specified in the SGS groundwater reports Fyfersquos assessment of holding times has been based on those adopted by EurofinsMGT (ie the secondary laboratory used for groundwater analysis) ie in accordance with Schedule B3 of the ASC NEPM (1999) also referred to as practical quantification limits (PQL)

      53 QAQC summary

      In summary it is considered that

      the field QAQC programs were generally undertaken with regard to relevant legislation standards andor guidelines and were sufficient for obtaining samples that are representative of site conditions and

      the overall laboratory QAQC procedures and results were adequate such that the laboratory analytical results obtained are of acceptable quality for addressing the key objectives outlined in Section 15

      PAGE 26 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      6 ASSESSMENT CRITERIA

      61 Groundwater

      611 Beneficial Use Assessment

      In accordance with Schedule B6 of the ASC NEPM (1999) and SA EPA (2009) a Beneficial Use Assessment (BUA) was undertaken to assess both the current and realistic future uses of groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area

      This was aimed at determining what groundwater uses need to be protected and assessing the risk(s) that groundwater may pose to human health and the environment (refer also to the VIRA in Section 9)

      As summarised in Table 61 the potential beneficial uses for groundwater within the Q1 aquifer that have been considered are as follows ndash taking into account the salinity of the groundwater the Environment Protection (Water Quality) Policy 2015 (Water Quality EPP 2015) the DEWNR (2017) WaterConnect database information presented in Section 222 and possible sensitive receptors located within andor within the vicinity of the Thebarton EPA Assessment Area

      The salinity of groundwater has been calculated to approximate 1230 to 3620 mgL TDS (refer to Section 7312) According to the Water Quality EPP 2015 the applicable environmental values for groundwater with salinity above 1200 mgL TDS but less than 3000 mgL TDS are irrigation livestock and aquaculture whereas the salinity is considered to be too high for potable use ndash although domestic irrigation is considered to be a potentially realistic use for this area (see below) livestock watering is considered unlikely to be undertaken in such an urban setting and no local water bodies (ie surface or groundwater) have been identified as being used for commercial aquaculture purposes

      The DEWNR (2017) WaterConnect database indicates that groundwater within the Q1 aquifer in the Thebarton area is accessed for drainage domestic and industrial purposes ndash domestic groundwater use could include garden irrigation plumbing water andor the filling of swimming pools (ie primary contact recreation) Although domestic groundwater extraction is considered unlikely to include potable use (ie due to its salinity and the availability of a reticulated mains water supply) potential mixing with rain watermains water could render it suitable (ie from a salinity perspective) for drinking

      As the closest freshwater surface water body the River Torrens is located approximately 03 km to the east and 07 km to the north and north-west of the northern portion of this area groundwater discharge from the Thebarton EPA Assessment Area into a freshwater aquatic ecosystem is considered possible However as the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area the potential for impact on a freshwater aquatic environment has not been confirmed

      80607-1 REV1 30102017 PAGE 27

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Since the closest marine surface water body Gulf St Vincent is located approximately 8 km to the west groundwater discharge from the Thebarton EPA Assessment Area into a marine aquatic ecosystem is not considered to be realistic

      Since volatile contaminants have been detected within the Q1 aquifer (refer to Section 7331) a potential vapour flux risk to future site users must be considered

      Given the measured depth of the Q1 aquifer beneath the site (ie approximately 1232 to 1585 m BGL ndash refer to Section 7311) it is considered unlikely that direct contact could occur between groundwater and building footingsunderground services

      Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area

      Environmental Values Beneficial Uses

      Water Quality EPP 2015

      environmental value

      SA EPA (2009) Potential

      Beneficial Uses

      Beneficial Use Assessment

      Considered Applicable

      Aquatic Ecosystem

      Marine Yes No

      Fresh Yes Possibly

      Potable - Yes Possibly

      Agriculture Irrigation - Yes Yes

      Livestock - Yes No

      Aquaculture - Yes No

      Recreation amp Aesthetics

      Primary contact Yes Possibly

      Aesthetics Yes Possibly

      Industrial - Yes Yes

      Human health in non-use scenarios

      Vapour flux -

      Yes Yes

      Buildings and structures

      Contact - Yes No

      Notes ie for underground waters with a background TDS level of between 1200 and 3000 mgL ndash note that although they are not listed as environmental values of groundwater in Schedule 1(3) of the Water Quality EPP 2015 aquatic ecosystems as well as recreation amp aesthetics are included as environmental values for waters in general in Part 1(6) of the document ie domestic irrigation only

      612 Groundwater beneficial use criteria

      The health and ecological criteria used for the assessment of the COPC (refer to Section 14) in groundwater have been based on the results of the BUA (Section 611) A summary of the references used to source the groundwater assessment criteria is provided in Table 62

      PAGE 28 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Table 62 Sources of adopted groundwater assessment criteria

      Beneficial Use Reference

      Freshwater Ecosystems No criteria available for COPC

      Potable NHMRCNRMMC (2011) Australian Drinking Water Guidelines

      WHO (2017) Guidelines for Drinking-water Quality ndash TCE only

      Irrigation No criteria available for COPC

      Primary contact recreation (including aesthetics)

      NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines but (with the exception of aesthetic guidelines) multiplied by a factor of 10 to take account of accidental ingestion rates as opposed to deliberate ingestion

      ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality ndash recreational values (TCE only)

      Human health in non-use scenarios ndash vapour flux Refer to the VIRA in Section 9

      Notes As there are no specific guidelines for industrial water these values are considered likely to be protective of this additional beneficial use The NHMRC (2008) guidelines are based on drinking water levels and assume a consumption factor of 2 L per day Therefore as recommended in the NHMRC (2008) document potable criteria (ie with the exception of aesthetic criteria) need to be adjusted by a factor of 10 to account for an accidental consumption rate of 100 to 200 ml per day As noted in ANZECCARMCANZ (2000b) although recreational guidelines are protective of ingestion recreational waters should also not contain any chemicals that can cause skin irritation likewise although not specifically addressed by recreational water criteria inhalation may also represent a source of exposure with respect to some (ie volatile) contaminants In the absence of a NHMRCNRMMC (2011) drinking water guideline for TCE the ANZECCARMCANZ (2000b) recreational criterion (30 microgL) has been adopted However if the NHMRC (2008) rule of multiplying potable (healthshybased) guidelines by 10 is applied to the WHO (2017) drinking water guideline of 20 microgL a recreational guideline of 200 microgL would be more applicable

      62 Soil vapour

      The ASC NEPM (1999) interim soil vapour health investigation levels (HILs) for volatile organic chlorinated compounds (VOCCs) have been adopted (ie in the first instance ndash refer to Section 7331) as Tier 1 soil vapour assessment criteria ndash relevant land use scenarios within the Thebarton EPA Assessment Area include residential (HIL AB) and commercialindustrial (HIL D)

      These criteria have been further adjustedappended for the purposes of the VIRA Tier 1 assessment ndash refer to Section 94

      80607-1 REV1 30102017 PAGE 29

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      7 RESULTS

      71 Surface and sub surface soil conditions

      711 Field observations

      Groundwater well and soil vapour borehole log reports are included in Appendices H to J and provide details of the soil profile encountered at each sampling location

      Where encountered fill materials extended to depths of between 01 and 09 m BGL and included a range of different soil types (sand gravelcrushed rock silt) with only minimal waste inclusions (ie asphalt glass andor metal fragments) identified at some locations

      The underlying natural soil profile (encountered to the maximum drill depth of 19 m BGL) was dominated by low to medium plasticity brown to red-brown silty clays and sand claysclayey sands some of which contained sub-angular to rounded gravels that included river pebbles andor comprised fine distinct lenses in places Groundwater well MW17 also included a 15 m thick layer of gravel at depth (ie 12 to 135 m BGL) ndash ie consistent with the depth of groundwater within the Q1 aquifer

      During the course of the drilling works no odours or visual indicators of contamination were detected and measured PID readings ranged up to 6 ppm but were generally lt3 ppm

      712 Soil geotechnical testing

      A table of geotechnical testing results is presented in Appendix L (Table 1) and a copy of the certified laboratory report is included in Appendix G Photographs of soil cores are included in Appendix N

      The results were interpreted to indicate the following

      The soil core samples submitted for PSD analysis were dominated by clay with lesser amounts of fine to medium gravel andor fine to coarse-grained sand ndash all samples analysed were classified as either CLAY or Sandy CLAY with one sample classified as Clayey SAND The classifications obtained from the laboratory were deemed to be generally consistent with the descriptions on the groundwater well log reports (Appendix H) although the PSD results did not specify silt as a significant secondary component

      The moisture content of the analysed soil core samples ranged from 65 to 231 Moisture content with respect to soil type depth and location has been considered in more detail for the purposes of the VIRA (Section 9) The degree of saturation for the analysed soil cores samples ranged from 218 to 964

      Measured bulk density ranged from 160 to 212 tm3 specimen dry density from 141 to 184 tm3 and specific gravity from 255 to 281 tm3

      The measured void ratio ranged from 043 to 088 whereas porosity ranged from 032 to 047

      80607-1 REV1 30102017 PAGE 31

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      72 Waterloo Membrane Samplerstrade A table of WMStrade analytical results (ie from both rounds of sampling) is presented in Appendix L (Table 2) and copies of certified laboratory reports are included in Appendix G8

      Of the 41 WMStrade units deployed across the Thebarton EPA Assessment Area during the two sampling rounds 20 returned measurable concentrations of CHC including TCE PCE cis-12-DCE trans-12-DCE andor 11-DCE Although no VC was detected the laboratory LOR in all samples (ie 35 to 50 microgm3) was above the ASC NEPM (1999) soil vapour interim HIL for residential land use (30 microgm3) ndash refer also to Table 53

      Detectable COPC concentrations are summarised in Table 71 relative to the ASC NEPM (1999) soil vapour interim HILs along with the closest soil vapour bore andor groundwater monitoring well locations Measured TCE concentrations are detailed on Figure 3

      A comparison of the Round 1 and 2 WMStrade results (ie for closely located units9) is presented in Table 72 ndash the results indicate a general order of magnitude correlation of the results for most COPC with the exception of PCE for which lower concentrations were obtained during Round 2 As the Round 1 and 2 WMStrade units were located within different soil bores and deployed at different times some variability in the results is to be expected In addition and as discussed in Section 74 the WMStrade units have been used during this assessment as a (semi-quantitative) screening tool (ie to assist with the siting of the permanent soil vapour bores) with the results obtained from the soil vapour bores considered more representative of actual subsurface conditions

      Table 71 Detectable Waterloo Membrane Samplertrade CHC results

      Sample ID

      Location Closest land uses

      CHC concentration (microgm3) Closest soil vapour bore

      andor groundwater

      well

      TCE PCE cis-12shyDCE

      trans-12shyDCE

      11shyDCE

      VC

      WMS 1 Goodenough Street CI 35 -

      WMS 6 Maria Street CI 32 -

      WMS 7 Maria Street CI and R 1900 45 SV2 MW5

      WMS 8 Maria Street CI and R 12000 37 SV4

      WMS 11 Admella Street CI 71000 260 19 20 36 SV5 MW02

      WMS 14 George Street CI 46000 45 SV6 MW11

      WMS 18 Admella Street CI 4200 34 MW14

      WMS 19 Albert Street CI 11000 42 SV10MW15

      WMS 21 Chapel Street CI 10 -

      WMS 22 Admella Street CI 38 SV9

      WMS 24 Chapel Street CI 230 62 10 11 48 MW17

      8 Note that the original laboratory report for the Round 1 WMStrade samples was found to be incorrect (ie following receipt of the soil vapour bore and Round 2 WMStrade sample results) and was subsequently re-issued by SGS

      9 only two of which were sufficiently co-located for comparative purposes ndash Round 2 locations WMS 39 and WMS 41 were not within the immediate vicinity of Round 1 WMStrade bores (ie the closest Round 1 bores were approximately 30 m away)

      PAGE 32 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Sample ID

      Location Closest land uses

      CHC concentration (microgm3) Closest soil vapour bore

      andor groundwater

      well

      TCE PCE cis-12shyDCE

      trans-12shyDCE

      11shyDCE

      VC

      WMS 25 Albert Street CI and R 1400 20 MW17

      WMS 27 Light Terrace CI 64 62 SV11 MW19

      WMS 32 Holland Street R 16 -

      WMS 34 James Street R 11 -

      WMS 37 Dew Street R 44 -

      WMS 38 Maria Street CI and R 13000 56 SV2 MW5

      WMS 39 Maria Street CI and R 1300 SV4

      WMS 40 Admella Street CI 110000 97 SV5 MW02

      WMS 41 George Street CI 18000 10 SV7 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

      Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform (up to 530 microgm3) was also detected in WMS 8 WMS 11 WMS 14 WMS 16 WMS 18 WMS 19 WM 25 WMS 33 WMS 40 and WMS 41 interim soil vapour health investigation level (HIL)

      Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units

      Bore ID

      Depth (m)

      Location CHC concentration (microgm3)

      TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

      WMS 8 10 Maria Street 12000 37 lt95 lt99 lt22 lt36

      WMS 38 13000 56 lt11 lt11 lt25 lt41

      Relative percentage difference 8 147 - - - -

      WMS 11 10 Admella Street 71000 260 19 20 36 lt37

      WMS 40 110000 97 lt11 lt11 lt25 lt41

      Relative percentage difference 43 91 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

      80607-1 REV1 30102017 PAGE 33

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      73 Groundwater

      731 Field measurements

      A table of groundwater field parameters is presented in Appendix L (Table 3) and groundwater field sampling sheets are included in Appendix E

      7311 Groundwater elevation and flow direction

      The depth to water within the Q1 aquifer beneath the Thebarton EPA Assessment Area on 18 July 2017 ranged from 12323 to 15854 m below top of casing (BTOC)10 and 4469 to 5070 m AHD

      Groundwater elevation contours constructed from the July 2017 gauging data indicated that the overall groundwater flow direction within the Q1 aquifer was north-westerly consistent with expected regional groundwater flow The groundwater contours and inferred flow direction are shown on Figure 4

      7312 Field parameters

      As detailed in Table 51 field measurements were recorded during low flow purging (ie prior to micropurge sampling) of monitoring wells and immediately following the collection of HydraSleeveTM samples

      The field parameter readings recorded for the monitoring wells immediately prior to (low flow micropurge) and after (HydraSleeveTM) sampling indicated the following (as summarised in Table 3 Appendix L)

      groundwater pH ranged from 6 8 to 79 thereby indicating neutral conditions

      electrical conductivity (EC) measurements ranged from 189 to 556 mScm and were found to be reasonably consistent across the area thereby indicating that it is underlain by moderately saline water (ie approximating 1230 to 3620 mgL TDS11)

      redox concentrations ranged from -20 to 624 mV thereby indicating slightly reducing to strongly oxygenating conditions

      measured dissolved oxygen (DO) concentrations ranged from 04 to 78 ppm indicating slightly to highly oxygenated water and

      temperature ranged from 173 to 224oC

      Observations recorded during sampling indicated that the groundwater was clear to brown and only slightly to moderately turbid at most locations ndash the higher turbidity at MW18 and MW19 (combined with poor recharge) contributed towards the decision to use a HydraSleeveTM sampling method No odours or sheen were observed in any of the wells during gauging or sampling

      10 ie approximating m BGL 11 ie calculated by multiplying the field EC data by 065

      PAGE 34 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      732 Hydraulic conductivity

      Rising and falling head aquifer permeability (ldquoslugrdquo) tests were conducted on 10 groundwater wells (refer to Table 31 and Figure 2) to assess the hydraulic conductivity (K) of the Q1 aquifer

      To obtain estimates of near-well horizontal hydraulic conductivity for each well tested the slug test data were analysed by Arcadis using AQTESOLV for Windowstrade (Duffield 2007) following the guidelines presented in Butler (1998) ndash normalised displacement data collected from each test are plotted against time in Appendix A of the Arcadis report (refer to Appendix O) Since only one set of tests were performed at each well the reproducibility of the results as well as the dependence of the results on the initial displacement could not be verified or demonstrated As such multiple relevant and applicable solutions were applied to each test to account for that uncertainty (ie to ensure consistency of normalised response at each well regardless of initial displacement)

      Table 73 presents a summary of the range and average estimated hydraulic conductivity values (and corresponding analytical solutions used) for each well tested The results indicate that hydraulic conductivities ranged from approximately 0073 to 37 mday with an overall average of approximately 1 mday

      Table 73 Hydraulic conductivities (rising and falling head tests)

      Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

      (mday) Hydraulic Conductivity

      (mday)

      MW02 Falling head 011 to 014 DA CBP HV

      012 Rising head 0073 to 015 BR DA

      MW3 Falling head 034 to 062 BR DA

      047 Rising head 030 to 062 BR DA

      MW7 Falling head 075 to 25 BR DA

      139 Rising head 055 to 175 BR DA

      MW14 Falling head 011 to 021 BR DA

      014 Rising head 009 to 015 BR DA

      MW17 Falling head 21 to 22 DA KGS

      220 Rising head 225 to 244 DA KGS

      MW20 Falling head 22 to 37 BR DA HV

      256 Rising head 06 to 32 BR DA

      MW21 Falling head 073 to 123 BR DA

      084 Rising head 054 to 084 BR DA

      MW23 Falling head 088 to 162 BR DA

      101 Rising head 031 to 122 BR DA

      80607-1 REV1 30102017 PAGE 35

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

      (mday) Hydraulic Conductivity

      (mday)

      MW25 Falling head 10 to 18 BR DA CBP HV

      132 Rising head 049 to 17 BR DA

      MW26 Falling head 019 to 036 BR DA

      023 Rising head 010 to 029 BR DA

      Overall average K (mday) 1028 Notes References BR = Bouwer and Rice (1976) CBP = Cooper et al (1967) DA = Dagan (1978) HV = Hvorslev (1951) KGS = Hyder et al (1994)

      The monitoring wells that exhibited lower permeabilities (ie MW02 MW3 MW14 and MW26) were noted to be generally located in the up-gradient (south-eastern) portion of the Thebarton EPA Assessment Area whereas monitoring wells showing relatively higher permeabilities (ie MW7 MW17 MW20 MW21 MW23 and MW25) are generally located in the down-gradient (north-western) portion These results were considered by Arcadis to suggest a possible hydrogeologic transition from the south-east to the north-west AQTESOLV solution plots for each analysis are provided as Appendix A of the Arcadis report (Appendix O)

      As slug test results can be influenced by a number of factors which are difficult to avoid when performing and analysing slug test results hydraulic conductivity estimates derived from slug tests should be considered to be the lower bound of the hydraulic conductivity of the formation in the vicinity of the well (Butler 1998) However Arcadis also noted that the results obtained for the Thebarton EPA Assessment Area were similar to those reported for other areas of Adelaide with average values of 1 and 27 mday (refer to Appendix O)

      The slug test results were used by Arcadis in their groundwater fate and transport model (refer to Section 8)

      733 Analytical results

      Tables of groundwater analytical results are presented in Appendix L (Tables 4 and 5) and copies of certified laboratory reports are included in Appendix G

      7331 Chlorinated hydrocarbon compounds

      A table of CHC results is included in Appendix L (Table 4) and a plan showing their distribution in groundwater beneath the Thebarton EPA Assessment Area is included as Figure 5 Detectable CHC concentrations are summarised in Table 74 relative to the adopted potable and primary contact recreation criteria ndash the closest soil vapour bore locations are also detailed

      PAGE 36 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Table 74 Detectable groundwater CHC results

      Sample ID

      Location CHC concentration (microgL) Closest soil vapour bore

      TCE PCE cis-12shyDCE

      trans-12-DCE

      11-DCE VC Carbon tetrachloride

      MW02 Admella Street 20000 38 7 15 SV5

      MW3 Admella Street 69 SV1

      MW5 Maria Street 29000 3 21 2 6 SV2 SV3

      MW6 Maria Street 29 SV4

      MW9 Albert Street 2 -

      MW11 George Street 4900 3 4 1 7 SV6 SV7

      MW12 George Street 700 SV8

      MW14 Admella Street 1000 4 2 SV9

      MW15 Albert Street 180 SV10

      MW17 Chapel Street 24 -

      MW18 Dew Street 5 -

      MW20 Light Terrace 70 SV12

      MW21 Light Terrace 23 SV13

      MW23 Dew Street 21 -

      MW25 Smith Street 2 5 -

      MW26 Kintore Street 2 -

      Potable 20 50 60 30 03 3

      Primary contact recreation

      30 500 600 300 30 30

      Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Chloroform was also detected in a number of wells (MW02 MW3 MW5 MW8 MW11 MW12 and MW19 to MW25) ndash refer to Table 4 in Appendix L Although no VC was detected the laboratory LOR (1 microgL) exceeded the adopted potable criterion NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from WHO (2017) Guidelines for Drinking-water Quality NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

      The results indicate that the highest TCE concentrations (20000 to 29000 microgL) were measured in wells MW02 and MW5 located in the immediate vicinity of the former Austral property and that the TCE plume extends in a general north-westerly direction (ie consistent with the inferred groundwater flow direction

      80607-1 REV1 30102017 PAGE 37

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      within the Q1 aquifer) Although lesser concentrations of PCE 12-DCE (cis- andor trans) andor 11-DCE were present in some wells no VC was detected and the main COPC was identified as TCE

      A number of wells within the Thebarton EPA Assessment Area contained TCE concentrations that exceeded the adopted potable andor primary contact recreation criteria Although the extent of the TCE plume was not delineated to the north-west (but was delineated in all other directions) with detectable TCE concentrations (ie up to 21 microgL) identified beneath both Smith Street and Dew Street these concentrations were below the adopted primary contact recreation criterion (but not necessarily the adopted potable value ndash ie MW23)

      The background well (MW4) located across James Congdon Drive (to the east of the southern portion of the Thebarton EPA Assessment Area) did not contain any measurable CHC concentrations

      7332 Other measured groundwater parameters

      Major cations and anions

      The laboratory results obtained for the remaining groundwater analytes are summarised in Appendix L (Table 5)

      The groundwater ionic data obtained from selected wells across the Thebarton EPA Assessment Area are graphically represented on a Piper diagram in Figure 71 The results indicate a relatively consistent groundwater composition across the area thereby indicating that the groundwater sampled from these wells is derived from a single aquifer Ionic charge balance ranged from 32 to 22 with the highest value (22) calculated for MW12 indicating that additional anions (ie not measured as part of this study) could be present

      PAGE 38 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Figure 71 Piper diagram

      Natural attenuation parameters

      With respect to the measured natural attenuation parameters (ie DO nitrate iron sulfate CO2 and manganese) the following wells were selected based on their locations relative to the inferred extent of the CHC plume

      MW26 located on Kintore Street to the south (and hydraulically up-gradient) of the former Austral property (ie the suspected source site)

      MW02 and MW5 located within the immediate vicinity of the former Austral property and the area of maximum CHC contamination

      MW9 MW12 and MW17 located on Albert Street George Street and Chapel Street respectively to the north-west (and hydraulically down-gradient) of the former Austral property

      80607-1 REV1 30102017 PAGE 39

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      MW21 and MW22 located on Light Terrace and Cawthorne Street respectively to the northshywestnorth-north-west (and further hydraulically down-gradient) of the former Austral property and

      MW8 and MW23 located on Smith Street and Dew Street respectively representing the furthest wells to the northnorth-west of the former Austral property

      According to Wiedemeier et al (1998) the most important process in the degradation of CHC is the process of reductive dechlorination Although daughter products of TCE (ie 12-DCE) are present in groundwater (and soil vapour) at scattered locations within the Thebarton EPA Assessment Area they are not considered indicative of substantial breakdown of TCE ndash refer also to the Arcadis report in Appendix O as summarised in Section 8 In addition the analysis of the natural attenuation parameters data constituting physical and chemical indicators of biodegradation processes has not provided a definitive secondary line of evidence

      74 Soil vapour bores A table of soil vapour bore analytical results is presented in Appendix L (Table 6) and a copy of the certified laboratory report is included in Appendix G

      Of the soil vapour bores installed to 10 andor 30 m BGL within the Thebarton EPA Assessment Area the majority (ie with the exception of the 10 m deep bores installed as SV11 and SV13 and located on Light Terrace) returned measurable concentrations of CHC dominated by TCE and to a lesser extent (and only at some locations) PCE Detectable soil vapour CHC concentrations are summarised in Table 75 whereas CHC concentrations and inferred soil vapour TCE concentration contours are detailed on Figures 6 (1 m BGL) and 7 (3 m BGL)

      The TCE results which have been used to predict indoor air concentrations as part of the VIRA (refer to Section 9) suggest the following

      the highest concentration (1000000 microgL) was detected at 3 m BGL in soil vapour bore SV3 located in the vicinity of residential and commercialindustrial properties (including the former Austral property) on Maria Street

      where nested wells were tested soil vapour CHC concentrations were higher at depth consistent with a groundwater source

      TCE PCE and 11-DCE are all assumed to represent primary contaminants with 12-DCE representing a break-down product of TCE andor PCE

      although no VC was detected the laboratory LOR in some samples (ie up to 490 microgm3 in samples with the highest measured TCE concentrations) was above the ASC NEPM (1999) interim soil vapour HIL for residential land use (30 microgm3) ndash refer to Table 53 and

      although the extent of the soil vapour plume has apparently not been delineated (ie in any direction) by the existing soil vapour bores it extends in a north-westerly direction (and hydraulically down-

      PAGE 40 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      gradient) from the suspected source site (ie the former Austral property) and corresponds well with the groundwater TCE plume (refer to Figure 5)

      A comparison of the results obtained for the WMStrade units (WMS 38 to WMS 41) deployed during the second round of sampling and the closest soil vapour bore data (10 m BGL) is provided in Table 76 Although the results indicate good correlation for TCE and PCE in SV5WMS 40 as well as TCE in SV7WMS 41 the remaining results were more variable ndash this supports the use of the WMStrade units as an initial (semishyquantitative) screening tool with follow-up soil vapour bore data considered to provide more quantitative results

      Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area

      Bore ID

      Depth (m)

      Location Closest land

      uses

      CHC concentration (microgm3)

      TCE PCE cis-12shyDCE

      trans-12-DCE

      11-DCE VC

      SV1 10 Admella Street CI and R 6300 78

      30 21000 21

      SV2 10 Maria Street CI and R 51000 39 21 39

      30 940000

      SV3 10 Maria Street CI and R 210000 6500 5900

      30 1000000 15000 14000

      SV4 10 Maria Street CI and R 17000 31

      30 43000 90 30

      SV5 10 Admella Street CI 100000 84

      30 160000 310 20 33

      SV6 10 George Street CI 22000 12

      30 150000 56

      SV7 10 George Street CI 22000 19

      30 110000

      SV8 10 George Street CI 2300 62

      30 14000 19

      SV9 10 Chapel Street CI 170

      30 260

      SV10 10 Albert Street CI 93

      30 51

      SV12 10 Light Terrace CI 16

      30 55 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

      Notes Shaded cells indicate concentrations were below the laboratory LOR

      80607-1 REV1 30102017 PAGE 41

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Where (field andor laboratory) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform was also detected in a number of samplesinterim soil vapour health investigation level (HIL)

      Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores

      Bore ID

      Depth (m)

      Location CHC concentration (microgm3)

      TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

      SV2 10 Maria Street 51000 39 21 lt13 39 lt89

      WMS 38 13000 56 lt11 lt11 lt25 lt41

      Relative percentage difference 119 150 - - - -

      SV4 10 Maria Street 17000 31 lt18 lt14 lt14 lt92

      WMS 39 1300 lt52 lt11 lt11 lt25 lt41

      Relative percentage difference 172 - - - - -

      SV5 10 Admella Street 100000 84 lt44 lt33 lt33 lt22

      WMS 40 110000 97 lt11 lt11 lt25 lt41

      Relative percentage difference 95 14 - - - -

      SV7 10 George Street 22000 19 lt37 lt27 lt27 lt18

      WMS 41 18000 10 lt11 lt11 lt25 lt41

      Relative percentage difference 20 62 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

      PAGE 42 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      8 GROUNDWATER FATE AND TRANSPORT MODELLING

      Arcadis were commissioned by Fyfe to undertake preliminary fate and transport modelling of the groundwater CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained groundwater data The Arcadis report is included as Appendix O

      The aim of the modelling was to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton area in order that potential future groundwater restrictions could be applied by the EPA (ie via the potential future definition of a GPA) to protect human health

      81 Groundwater flow modelling

      The MODFLOW code a publicly-available groundwater flow simulation program developed by the United States Geological Survey (USGS) as described by McDonald and Harbaugh (1988) was used to construct a groundwater flow model It was developed for a horizontal area of approximately 25 km2 (ie to minimise possible boundary effects within the assessment area itself12) and was rotated 45deg counter-clockwise to align with the prevailing (north-westerly) groundwater flow direction The model extended approximately 23 km in a south-east to north-west direction and approximately 11 km in a south-west to north-east direction (ie perpendicular to groundwater flow) Whereas a 4 m grid spacing was used within the area of the plume and its migration pathway (ie to enhance model accuracy and precision) a broader 15 m grid was adopted outside the specific area of interest Vertically the model adopted a single 20 m thick layer as representative of the hydrostratigraphy of the Q1 aquifer sediments beneath the area but it was noted that only the bottom portion (ie few metres) of this model layer are actually saturated and therefore active in the model

      An informal sensitivity analysis performed as part of the model calibration process indicated that the model was most sensitive to changes in hydraulic conductivity and recharge ndash this was not unexpected given the relatively flat hydraulic gradient and relatively narrow range of estimated values for both model parameters (ie based on reasonably low uncertainty) The final calibrated value for aquifer recharge adopted in the model was 295 mmyear consistent with results reported for nearby sites as well as regional estimates Likewise the final calibrated hydraulic conductivity values for the up-gradient (06 mday) and down-gradient (2 mday) zones were consistent with both the site-specific slug test data and results obtained for other nearby EPA assessment areas The final calibrated down-gradient constant head elevation was 15 m AHD It was concluded by Arcadis that the groundwater flow model was well calibrated and could therefore serve as an appropriate basis for the development of a site-specific solute transport model

      82 Solute transport modelling

      A site-specific (three-dimensional) solute transport model using the MT3DMS transport code of Zheng (1990) was developed by Arcadis to predict the fate and transport of groundwater contaminants (specifically

      12 Further information regarding boundary effects is provided in the Arcadis report (Appendix O)

      80607-1 REV1 30102017 PAGE 43

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      CHC) under current conditions over a period of 100 years This dual-domain mass transport model was used in conjunction with the groundwater flow model developed through the use of MODFLOW (as detailed above) assuming the following

      The primary COPC is TCE ndash the initial concentration distribution of TCE in groundwater was based on the recent (July 2017) monitoring data

      The age of the groundwater TCE plume was assumed to be up to about 90 years ndash ie based on the history of industrial land use (specifically the former Austral facility) in the area

      Although lesser amounts of other CHC are present in groundwater the lack of significant daughter products of TCE has been interpreted to indicate that substantial biodegradation is not occurring (ie as a conservative approach)

      Although a CHC source was not explicitly incorporated into the solute transport model the MT3DMS transport code indirectly accounts for on-going contaminant mass contribution to the dissolved-phase plume

      The fate and transport of TCE within the area of interest involves the processes of advection adsorption dilution and diffusion ndash however given that recharge via the infiltration of precipitation was considered to be insignificant dilution effects were assumed to be minimal

      Two porosity values (ie dual domain) are relevant to the movement of contaminants in the subshysurface with adopted values based on site-specific geology and Payne et al (2008) ndash whereby the two domains are in equilibrium

      ― mobile porosity that portion of the formation with the highest permeability where advective transport dominates ndash assumed to be 5 (high) 10 (intermediate) or 15 (low) for different mobility transport conditions and

      ― immobile porosity lower permeability portions of the formation where diffusion is dominant ndash assumed to be 15

      As discussed in Section 732 hydraulic conductivity values of 06 mday (south-eastern approximate quarter of the modelling area) and 2 mday (northern approximate three-quarters of the modelling area) were adopted to reflect the hydrogeologic transition (ie from the south-east to the north-west) interpreted from the slug test data

      The adopted TCE retardation factor of 147 for intermediate mobility transport conditions was based on the following

      ― an assumed organic carbon fraction of 01 (US EPA 1996 amp 2009) ndash this was varied to 005 and 2 to assess alternate (ie high versus low) mobility transport conditions

      ― an assumed organic carbon adsorption co-efficient of 61 Lkg (US EPA 2017a)

      PAGE 44 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      ― a calculated partition co-efficient of 0061 Lkg ndash this was varied to 129 and 178 Lkg to assess alternate (ie high versus low) mobility transport conditions and

      ― an average soil bulk density of 192 gcm3 (based on measured geochemical data ndash refer to Table 1 Appendix L)

      An optimum mass transfer co-efficient (MTC) was based on simulated flux distribution in the groundwater flow model whereby

      ― the calculated MTC in the model ranged from approximately 38E-08day-1 to 37E-05 day-1 and

      ― the average MTC was 185E-05day-1

      The site-specific solute transport model was used in predictive mode to assess the long-term (eg 100 year) potential migration of the groundwater TCE plume and to support the EPA in the potential future definition of an appropriate GPA The model was calibrated against the current extent (ie concentrations of TCE above 1 microgL have migrated approximately 500 m from the suspected source site13) and expected age (ie up to about 90 years) of the plume The results indicate that the leading edge of the TCE (ie the 1 microgL contour) is estimated to migrate between approximately 400 and 620 m over a period of 100 years under low to high mobility transport conditions14 with intermediate transport conditions resulting in an estimated migration of 500 m By comparison no significant lateral plume expansion would be expected to occur Figures 5 to 17 of the Arcadis report (Appendix O) show the predicted extent of the TCE plume at 5 10 50 and 100 years under low to high mobility transport conditions

      Figure 81 shows the predicted extent of the 1 microgL TCE boundary in 100 years under intermediate transport conditions ndash it is recommended that this information be used to support the EPA in establishing a potential future GPA

      The Arcadis report notes that given the available site information (site history potential source area(s) and uncertainty associated with the current plume extent) and degree of model calibration (flow model parameter values are consistent with site-specific data as well as regionalnearby studies while transport parameter values are consistent with literatureindustry standards) the model-predicted migration of approximately 500 m over 100 years is considered to be a reasonable representation of future conditions

      Key uncertainties associated with the modelling were identified as including the following

      current plume extents (ie down-gradient delineation)

      site-specific fraction organic values (or site-specific partition coefficient estimates) and

      site-specific porosity estimates

      13 although it was noted that there is uncertainty with respect to the current extent of the TCE plume since all three down-gradient monitoring wells (MW18 MW23 and MW25) have TCE concentrations above 1 μgL

      14 ie assuming different values for mobileimmobile porosity the TCE distribution (sorption) coefficient and the TCE retardation factor

      80607-1 REV1 30102017 PAGE 45

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Lesser uncertainties were considered to include site-specific bulk hydraulic conductivity estimates and determination of the presence or absence of naturally-occurring TCE degradation

      Additional site investigation and data collection (eg multi-well pumping tests for bulk hydraulic conductivity estimates site-specific fraction organic carbon andor distribution (sorption) coefficient additional down-gradient plume delineation) would help to further refine the model and increase confidence in the predictive results

      Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green) relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple)

      PAGE 46 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      9 VAPOUR INTRUSION RISK ASSESSMENT

      Arcadis were commissioned by Fyfe to undertake a Vapour Intrusion Risk Assessment (VIRA) of the soil vapour CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained (ie August 2017) permanent soil vapour bore data The Arcadis report is included as Appendix P

      91 Objective

      The main objective of the VIRA was to evaluate the potential risk to human health from vapour intrusion related to the concentrations of CHC identified in soil vapour within the Thebarton EPA Assessment Area

      92 Areas of interest

      The following areas of specific interest (ie located within the Thebarton EPA Assessment Area) were identified for the purpose of this VIRA

      commercialindustrial properties (assumed slab on grade construction) including the former Austral property (ie the suspected source site) and

      residential properties (slab on grade crawl space and basement constructions)

      Potential exposure by trenchmaintenanceutility workers has also been considered (qualitatively)

      93 Risk assessment approach

      The VIRA was conducted in accordance with the ASC NEPM (1999) enHealth (2012a) and other relevant Australian guidance documents as well as guidance documents issued by the US EPA and other international regulatory agencies (where applicable)

      The conduct of the risk assessment was based on a multiple lines of evidence approach using the available site-specific information collected as part of the scope of works detailed in Section 32

      The following information was used as a basis for the VIRA

      CHC including TCE PCE and DCE (11- cis-12- and trans-12-) have been identified within soil vapour andor groundwater within the Thebarton EPA Assessment Area ndash the analytical data indicate that TCE constitutes between about 95 and 100 of the CHC identified in groundwater and soil vapour

      TCE has been considered as the risk driver for the VIRA (ie based on its toxicity and concentrations in soil vapour and groundwater) ndash although TCE PCE 12-DCE 11-DCE and VC have all been included as COPC for the Tier 1 screening assessment (Section 94) the Tier 2 assessment (Section 95) has

      80607-1 REV1 30102017 PAGE 47

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      concentrated on TCE PCE and 11-DCE (ie due to their presence at concentrations that exceeded the adopted Tier 1 screening criteria)

      The CHC identified within the Thebarton EPA Assessment Area are volatile chemicals and could potentially pose a risk to human health via the vapour intrusion pathway Although the source area has yet to be confirmed the CHC concentrations observed in groundwater and soil vapour are considered likely to have originated from the former Austral property (as discussed in Section 12)

      The natural soils underlying the fill material (where present) in the Thebarton EPA Assessment Area are typified by the Quaternary age soils and sediments of the Adelaide Plains with the Pooraka Formation and Hindmarsh Clay units considered to dominate the upper soil profile

      The soil geotechnical data and soil vapour results collected by Fyfe (as discussed in Sections 712 and 74 respectively) have been used for the VIRA

      A two-tier approach was adopted for the VIRA The first tier (herein referred to as the Tier 1 assessment) was conducted by comparing the measured soil vapour TCE concentrations to published guideline values adjusted (conservatively) to account for attenuation from sub-slab soil into indoor air The second tier (herein referred to as the Tier 2 assessment) involved the comparison of predicted indoor air TCE concentrations to adopted indoor air criteria or response levels

      94 Tier 1 assessment

      As detailed in Section 74 the initial Tier 1 (screening risk) assessment involved comparing measured soil vapour COPC concentrations with the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land uses (refer to Table 74) Given that the development of the interim soil vapour HILs was based on very conservative assumptions the initial Tier 1 assessment provided only a first-pass screening assessment of the data to determine if further risk assessment would be required

      The interim soil vapour HILs are applicable for the assessment of soil vapour at 0 to 1 m beneath the floor of a building They were based on adopted toxicity reference values (TRV) and relevant exposure parameters (ie adjusted for different land uses) as well as an assumed soil vapour to indoor air attenuation factor of 01

      The soil vapour to indoor air attenuation factor (01) was based on the US EPA (2002) recommended default attenuation factors for the generic screening step of a tiered vapour intrusion assessment process As discussed in the US EPA (2002) document the default attenuation factor of 01 for sub-slab soil vapour was based on a US EPA database of empirical attenuation factors calculated using measurements of indoor air and soil vapours from different sites In 2012 the US EPA provided an updated database which was accompanied by an evaluation and statistical analysis of attenuation factors for volatile CHC in residential buildings US EPA (2012) found the sub-slab to indoor air attenuation factor of 003 to be the 95th percentile In 2015 the revised sub-slab attenuation factor (003) was adopted by the US EPA

      PAGE 48 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      The revised sub-slab to indoor air attenuation factor of 003 was adopted to derive modified residential and commercialindustrial soil vapour HILs for the Tier 1 assessment The modified residential soil vapour HILs are presented in Table 91 relative to the maximum CHC concentrations obtained for soil vapour within the Thebarton EPA Assessment Area

      The Tier 1 assessment based on a comparison of the COPC concentrations measured in soil vapour at various locations within the Thebarton EPA Assessment Area with the modified residential soil vapour HILs detailed in Table 91 indicated the following

      TCE concentrations exceeded the adopted criterion in SV1 to SV9 whereas

      the concentrations of PCE and 11-DCE exceeded the adopted criteria in SV3 only

      These locations were identified as requiring further assessment (ie Tier 2 VIRA ndash refer to Section 95)15

      Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs

      Compound ASC NEPM (1999) HIL

      (microgm3)

      Modified Tier 1 HIL (microgm3)

      (AF = 003)

      Maximum measured soil vapour concentration (microgm3)

      Acceptable

      Location 1 m BGL Location 3 m BGL

      11-DCE 7000 SV3 5900 SV3 14000 No ndash Tier 2 required

      cis-12-DCE 80 265 SV2 21 SV4 30 Yes

      trans-12-DCE 80 265 - ND SV5 20 Yes

      PCE 2000 6650 SV3 6500 SV3 15000 No ndash Tier 2 required

      TCE 20 65 SV3 210000 SV3 100000 0

      No ndash Tier 2 required

      VC 30 100 - ND - ND Yes Notes Values in bold exceed the modified residential soil vapour HILs cis-12-DCE HIL adopted as surrogate screening criterion based on US EPA (2017b) regional screening level for residential air elevated laboratory LOR (ie above modified Tier 1 HIL) also reported Abbreviations AF = attenuation factor HIL = health investigation level ND = non detect

      95 Tier 2 assessment

      951 Tier 2 assessment criteria

      The Tier 2 VIRA criteria for the residential zone comprise HIL-based residential indoor air criteria for the COPC (refer to Section 94) along with the residential indoor air level response ranges for TCE that were

      15 Note that all locations were subjected to the Tier 2 VIRA in this assessment

      80607-1 REV1 30102017 PAGE 49

      EPA REF 0524111 FINAL REPORT

      STAGE 1 ENVIRONMENTAL ASSESSMENT

      THEBARTON ASSESSMENT AREA

      initially developed by the EPA and SA Health for the EPA Assessment Area at Clovelly Park and Mitchell

      Park These screening criteria and indoor air response ranges as detailed in SA EPA (2014) and

      reproduced in Figure 91 are now widely adopted in South Australia for the assessment of TCE relating

      to indoor air exposure

      Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels

      Note The no action response level is applicable where a soil vapour concentration is below the laboratory LOR (ie ND or ldquonon-

      detectrdquo assumed to be lt01 microgm3)

      PAGE 50 80607-1 REV1 | 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      952 Vapour intrusion modelling

      For this VIRA exposure point concentrations (EPCs) of COPC in the indoor air of buildings with a slab on grade crawl space or basement construction were estimated using conservative screening assumptions and the Johnson and Ettinger (1991) vapour transport and mixing model (ie the JampE model)

      The algorithms applied in the JampE (1991) model are detailed in Appendix A of the Arcadis report whereas the modelling spreadsheets for each scenario are provided in Appendix B ndash the Arcadis report is attached to this report as Appendix P

      9521 Input parameters

      The input parameters adopted for the vapour intrusion modelling relate to the following

      the construction type and details of existing or proposed buildings ndash refer to Table 92 for adopted building input parameters

      the nature of the soil profile ndash refer to Table 93 for adopted soil input parameters (0 to 1 m BGL) and

      the contaminant source concentrations ndash refer to Table 6 in Appendix L

      Table 92 Tier 2 vapour intrusion modelling ndash building input parameters

      Parameter Units Adopted value Reference

      Residential Commercial industrial

      Width of Building cm 1000 2000 Friebel and Nadebaum (2011)

      Length of Building cm 1500 2000

      Height of Room cm 240 300

      Height of crawl space cm 30 - Assumption for crawl space

      Attenuation from basement to ground floor air

      - 01 01 Friebel and Nadebaum (2011)

      Air Exchange Rate (AER)

      Indoor per hour 06 083 Friebel and Nadebaum (2011)

      Crawl space per hour 06 - Friebel and Nadebaum (2011)

      Basement per hour 06 - As per residential (indoor)

      Fraction of Cracks in Walls and foundation

      - 0001 0001 Friebel and Nadebaum (2011)

      Qsoil cm 3s 300 277 Calculated from QsoilQbuilding ratio of 0005 (residential) and 0001 (commercial)

      80607-1 REV1 30102017 PAGE 51

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters

      Parameter Units Adopted value Reference

      Depth cm 100 Depth of shallow soil vapour data

      Total porosity - 047 Site specific geotechnical data ndash ie averaged from MW3 and MW11 shallow samples (refer to Table 1 in Appendix L) Air filled porosity - 030

      Water filled porosity - 017 Notes ie representing a conservative approach whereby data for the shallow samples with the highest total porosity and lowest degree of saturation (and therefore the highest air filled porosity) have been adopted

      The site specific attenuation factors calculated within the vapour intrusion models (Appendix B of the Arcadis report) are summarised in Table 94 These are chemical and depth specific values applicable to each building construction scenario These attenuation factors have been applied to the soil vapour data measured across the Thebarton EPA Assessment Area to calculate indoor air concentrations (residential properties only) in proximity to each soil vapour location ndash for commercialindustrial properties (slab on grade) indoor air concentrations have only been calculated with respect to the soil vapour data obtained for SV3 (ie the soil vapour bore with the highest measured TCE concentrations)

      Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air

      Scenario Attenuation factor

      Residential ndash slab on grade 706 x 10-4

      Residential ndash crawl space 209 x 10-3

      Residential ndash basement 113 x 10-1

      Commercial ndash slab on grade 408 x 10-4

      Notes ie soil vapour intrusion to indoor air of residential living spaces refer to Section 953 for a discussion of potential vapour intrusion risks associated with commercialindustrial properties

      The chemical parameters of the COPC adopted in the JampE model were updated with data from the chemical database in the Risk Assessment Information System (RAIS 2016) as detailed in Table 95

      Table 95 Summary of chemical parameters adopted for vapour intrusion modelling

      Chemical Diffusivity in Air Diffusivity in Water Solubility Henryrsquos Law Molecular weight (Dair) Water (Dwater) (S) Constant 25oC (gmol)

      (cm2s) (cm2s) (mgL) (unitless)

      11-DCE 00863 0000011 2420 107 969

      PCE 00505 000000946 206 0724 166

      TCE 00687 00000102 1280 0403 131

      PAGE 52 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      9522 Predicted indoor air concentrations

      Residential The predicted indoor air concentrations for each soil vapour data point as calculated by Arcadis for the three residential building scenarios (ie slab on grade crawl space and basement) are presented in Appendix C of the Arcadis report (included in this report as Appendix P)

      Table 96 provides a comparison of predicted indoor air concentrations against the EPA response levels detailed in Section 951 (Figure 91) ndash ie using the 1 m soil vapour data space for slab on grade and crawl space scenarios versus the 3 m soil vapour data for basements

      It should be noted that if residential properties within the Thebarton EPA Assessment Area have basements however the vapour intrusion risks will increase whereas slab on grade construction will carry a lesser vapour intrusion risk (as detailed in Table 96)

      Commercialindustrial The predicted indoor air concentrations as calculated by Arcadis for a commercialindustrial (ie slab on grade) land use scenario with respect to the soil vapour data obtained for SV3 (ie maximum measured soil vapour concentrations) are as follows

      11-DCE 3 microgm3

      PCE 19 microgm3 and

      TCE 86 microgm3

      As these values are not directly comparable to the EPA response levels developed for residential land use further discussion of potential vapour intrusion risks to human health under a commercialindustrial land use

      scenario is included in Section 953

      As discussed for residential properties the vapour intrusion risks may increase if basements are present

      80607-1 REV1 30102017 PAGE 53

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Table 96 Comparison of predicted residential indoor air concentrations with SA EPA response levels

      Indoor Air Concentration Ranges (microgmsup3) SA EPA response levels

      non-detect No action

      gt non-detect to lt2 Validation

      2 to lt20 Investigation

      20 to lt200 Intervention

      ge200 Accelerated Intervention

      Soil vapour bore

      Sample depth

      (m)

      Soil vapour TCE concentration

      (microgmsup3)

      Predicted indoor air concentration (microgmsup3)

      Residential scenario

      Slab on grade Crawl space Basement

      Attenuation factor

      7 x 10-4 2 x 10-3 1 x 10-1

      SV1 10 5700 4 11

      SV1 30 21000 2100

      SV2 10 51000 36 102

      SV2 30 890000 89000

      SV2 (FD) 30 940000 94000

      SV3 10 210000 147 420

      SV3 30 1000000 100000

      SV4 10 17000 12 34

      SV4 30 43000 4300

      SV5 10 100000 70 200

      SV5 30 160000 16000

      SV6 10 22000 15 44

      SV6 (FD) 10 22000 15 44

      SV6 30 150000 15000

      SV6 (FD) 30 140000 14000

      SV7 10 22000 15 44

      SV7 30 110000 11000

      SV8 10 2300 2 5

      SV8 30 14000 1400

      SV9 10 170 012 030

      SV9 30 260 26

      SV10 10 9 0007 0019

      SV10 30 51 51

      SV11 10 lt18 - -

      SV12 10 16 0011 0032

      SV12 30 55 55

      SV13 10 lt21 - -

      PAGE 54 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Notes With respect to the predicted indoor air CHC concentrations in the Arcadis VIRA report (refer to Appendix P) the results in Table 5 were calculated for SV3 using the unrounded attenuation factors presented in Appendix B (and Table 94 of this report) whereas the TCE indoor air concentrations in Appendix C (as summarised in Table 96) were calculated using rounded attenuation factors ndash this does not change the overall interpretation of the results Abbreviations FD = field duplicate

      9523 Sensitivity analysis

      Table 97 presents a qualitative sensitivity analysis for some of the input variables used in the modelling ndash it includes the range of practical values for each variable the value used in the risk assessment the relative model sensitivity and the uncertainty associated with the variable

      Although Arcadis note that a number of parameters used within the risk assessment have a moderate degree of uncertainty associated with them thereby suggesting that the modelling may be sensitive to changes in these parameters values used to define these parameters were selected to be conservative This is considered to have resulted in an assessment which is expected to be conservative and to over-estimate actual risk

      Table 97 Summary of model input parameters subjected to sensitivity analysis

      Input Range of values Value adopted Sensitivity of calculated input parameters variable

      Soil physical parameters

      Total porosity

      Varies by soil type generally 03 to 05

      047 Site-specific

      Indoor air concentrations will decrease with increasing total porosity Moderate sensitivity parameter decreasing by 50 will increase predicted concentration by a factor of 4

      Air filled porosity

      Varies by soil type generally 015 to 03

      03 Site-specific

      Indoor air concentrations will increase with increasing air filled porosity Moderate to high sensitivity parameter reduction by 50 decreases concentration by a factor of 10

      Water filled porosity

      Varies by soil type from 005 (fill or

      sand) to 03 (clay)

      017 Site-specific

      Negligible impact on predicted indoor air concentrations although may decrease with increasing moisture content Very low sensitivity parameter

      Building parameters

      Air exchange rate (AER)

      Varies from 05 hr-1

      in smaller buildings to gt2 hr-1

      06 hr-1 for residential structures

      083 hr-1 for commercial

      Indoor air concentrations will decrease with increasing air exchange Moderate sensitivity parameter has linear relationship with predicted concentrations conservative assumptions used

      80607-1 REV1 30102017 PAGE 55

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Input Range of values Value adopted Sensitivity of calculated input parameters variable

      Advective flow rates

      Varies depending on building size and

      AER

      300 cm3sec Calculated from building AER and

      ratio of 0005

      Indoor air concentrations will increase with increasing advective flow Low sensitivity parameter particularly within normal range of potential values The assumption that advective flow is occurring into a building at all times is generally conservative for Australian settings Advection is unlikely to occur under a crawl space home and diffusive transport is the dominant transport mechanism

      Building size Variable Variable consistent with

      Friebel and Nadebaum (2011)

      Indoor air concentrations decrease with increasing building volume

      Very low sensitivity parameter

      9524 Uncertainties

      The following uncertainties were identified in the Arcadis report (Appendix P)

      Vapour transport modelling

      The use of a model to predict the migration of vapour from a sub-surface source to indoor air requires the simplification of many complex processes in the sub-surface as well as the potential for entry and dispersion within a building or outdoor air To address this simplification the vapour models available (and adopted in this assessment) are considered to be conservative such that uncertainties are addressed through the overshyestimation of likely concentrations

      It should be noted that the vapour model used is designed to be a first tier screening tool and is considered likely to over-estimate air concentrations due to the incorporation of a number of conservative assumptions including the following

      chemical concentrations in soil vapour were assumed to remain constant over the duration of exposure (ie it was assumed that the source was non-depleting and not subject to natural biodegradation processes)

      the maximum reported soil vapour concentrations were assumed to be present beneath nearby dwellings and

      the occurrence of steady well-mixed vapour dispersion within the enclosed or ambient mixing space

      Overall the vapour modelling undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

      PAGE 56 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Toxicological Data

      In general the available scientific information involves the extrapolation of toxicity information from studies involving experimental laboratory animals with some validation of observable health effects obtained through epidemiological studies

      This may introduce two types of uncertainties into the risk assessment as follows

      those related to extrapolating from one species to another and

      those related to extrapolating from the high exposure doses usually used in experimental animal studies to the lower doses usually estimated for human exposure situations

      In order to adjust for these uncertainties toxicity values commonly incorporate safety factors that may vary from 10 to 10000

      Overall the toxicological data presented in this assessment are considered to be current and adequate for the assessment of risks to human health associated with potential exposure to the COPC identified The uncertainties inherent in the toxicological values adopted are considered likely to result in an over-estimation of actual risk

      953 Potential vapour intrusion risks associated with commercialindustrial properties

      An assessment of potential vapour intrusion risks to workers at commercialindustrial properties (slab on grade construction) within the Thebarton EPA Assessment Area was undertaken by Arcadis using the methodology published by US EPA (2009) and incorporated into the ASC NEPM (1999) This approach recommends adjustment of the measured or estimated contaminant concentrations in air to account for site specific exposures by the relevant receptors as follows

      Ca ET EF EDECinh = days hours AT 365 24 year day

      Where

      ECinh = Exposure Adjusted Air Concentration (mgm3) Ca = Chemical Concentration in Air (mgm3) ET = Exposure Time (hoursday) EF = Exposure Frequency (daysyear) ED = Exposure Duration (years) AT = Averaging Time (years)

      = 70 years for non-threshold carcinogens = ED for chemicals assessed based on threshold effects

      80607-1 REV1 30102017 PAGE 57

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Exposure parameters were selected from Australian sources (enHealth 2012b ASC NEPM 1999) for the receptor groups evaluated or were based on site specific factors Table 98 presents an overview of the parameters used whereas adopted inhalation TRVs are presented in Table 99

      Risk was characterised for threshold and non-threshold effects for the COPC ndash spreadsheets presenting the risk calculations are provided in Appendix B of the Arcadis report (as included in Appendix P) For commercialindustrial properties the non-threshold risk level was calculated to be 3 x 10-5 (compared to a target risk level of 1 x 10-5) whereas the threshold risk level was calculated to be 10 (compared to a target risk level of 1) ndash these results indicated a potentially unacceptable vapour intrusion risk to commercialindustrial workers in the vicinity of the maximum soil vapour CHC concentrations (ie at SV3 ndash worst-case scenario based on maximum soil vapour concentrations)

      Table 98 Exposure parameters ndash Commercialindustrial workers

      Exposure parameter Units Value Reference

      Exposure frequency days year 365 ASC NEPM (1999)

      Exposure duration years 30 ASC NEPM (1999)

      Exposure time indoors hoursday 8 ASC NEPM (1999)

      Averaging time

      Non-threshold

      threshold

      Years

      years

      70

      30 ASC NEPM (1999)

      Table 99 Adopted inhalation toxicity reference values

      COPC Toxicity reference values

      Non-threshold (microgm3)

      Reference Threshold (microgm3)

      Reference

      11-DCE NA - 80 ATSDR (1994)

      PCE NA - 200 WHO (2006)

      TCE 41 US EPA (2011) IRIS 2 US EPA (2011) IRIS Notes Abbreviations NA = not applicable

      954 Potential risks to trenchmaintenanceutility workers

      Although trenchmaintenanceutility workers may be exposed to soil vapour concentrations as measured at 1 m BGL due to the short-term nature of such works their total intakes of TCE and other CHC will be low Assuming that a trenchmaintenanceutility worker may be exposed to TCE for a limited number of working days throughout the year (eg 20 days of 8 hours duration within an excavation) their intake will be approximately one fiftieth of the intake of a resident (who is assumed to be exposed 21 hours a day for 365 days a year)

      PAGE 58 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Therefore the management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air)

      96 Conclusions

      On the basis of the available data and the assessment presented in the Arcadis VIRA report (Appendix P) the following conclusions were provided

      Health risks for residents due to the intrusion of CHC in soil vapour into residential buildings with a slab on grade crawl space or basement construction were calculated to be above the adopted EPA response levels and risks to residents may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

      Health risks for commercial workers due to the intrusion of CHC in soil vapour into buildings with a slab on grade construction were calculated to be above the adopted target risk levels and risks to workers may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

      In the absence of specific information regarding building construction within the Thebarton EPA Assessment Area the predicted indoor air concentrations calculated from the 1 m BGL soil vapour data for a residential crawl space scenario are summarised in Table 910

      Table 910 Summary of properties with predicted indoor air concentrations (residential crawl space) above adopted EPA response levels

      EPA response level No of residential properties affected Indoor air concentration (microgm3) Response

      non-detect to lt2 Validation 9

      2 to lt20 Investigation 10

      20 to lt200 Intervention 8

      ge200 Accelerated intervention 3 Notes According to information provided by the EPA there are approximately 130 residential properties located in the Thebarton EPA Assessment Area calculated on the basis of cadastral boundaries ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial facility ndash these data would therefore need to be confirmed via a property survey

      80607-1 REV1 30102017 PAGE 59

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      10 CONCEPTUAL SITE MODEL

      As detailed in Table 101 a CSM has been developed for the Thebarton EPA Assessment Area on the basis of historical information (as summarised in Section 12 as well as Appendices A and B) and the data obtained during the recent Fyfe investigation program

      Table 101 Summary of existing information for the Thebarton EPA Assessment Area

      Topic Summarised Information

      Site Characterisation

      Identification of Assessment Area

      An approximately 27 ha Assessment Area located within the suburb of Thebarton has been defined by the EPA The boundaries of this area are detailed in Section 21 and illustrated on Figure 1

      History of land use Properties located within the Thebarton EPA Assessment Area have been used for a mixture of commercialindustrial and low density residential land uses over time Current commercialindustrial properties include a beverage factory in the north-eastern portion of the assessment area a refrigeration equipment facility a car dealership two hotels (at least one of which has a cellarbasement) automotive and other workshops and the Ice Arena Former commercialindustrial activities have been identified as including a gas works a mechanicrsquos workshop sheet metal working facilities and a farm machinery manufacturer

      Historical investigations

      Reports provided to Fyfe by the EPA that pertain to previous investigations undertaken within the Thebarton EPA Assessment Area have been reviewed and summarised in Appendix A Additional historical information is included in Appendix B

      Local geology Natural soils encountered from the surfacenear surface to the maximum drill depth of 19 m BGL across the Thebarton EPA Assessment Area were considered to be indicative of the Quaternary Pooraka and Hindmarsh Clay formations Whereas fill materials (ie sand gravelcrushed rock andor silt) were encountered to depths of up to 09 m BGL at a number of sampling locations underlying natural soils comprised mainly low to medium plasticity silty or sandy clays with variable gravel contents Geotechnical testing of subsurface soil samples collected from 10 drill cores indicated that the PSD comprised predominantly claysilt with lesser components of sand andor gravel ndash these soil samples were mostly classified as Clay although some were classified as Sandy Clay or Clayey Sand According to Stapledon (1971) the Hindmarsh Clay unit typically contains many structural features and defects which greatly influence its permeability thereby resulting in potential preferential pathways for the vertical and lateral movement of soil vapour and groundwater Such features were not specifically observed during the recent drilling and soil logging work although some gravel lenseslayers were identified

      Hydrogeology In accordance with Gerges (2006) and his classification of the Adelaide metropolitan area into a number of zones based on their individual hydrogeological characteristics the Thebarton EPA Assessment Area is located within Zone 3 (subzone 3E) to the west of the Para Fault It contains five to six Quaternary aquifers and three or four Tertiary aquifers Based on the most recent investigations the depth to water within the Q1 aquifer in the Thebarton EPA Assessment Area ranges from approximately 123 to 159 m BGL and groundwater flows in a general north-westerly direction with a relatively flat hydraulic gradient (000062 to 00012) Salinity levels (based on field EC readings) range from approximately 1230 to 3620 mgL TDS and a groundwater flow velocity range of approximately 44 to 23 myear has

      80607-1 REV1 30102017 PAGE 61

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Topic Summarised Information

      been inferred As detailed in Section 222 a search of the DEWNR (2017) WaterConnect database identified 59 bores within the general Thebarton area of which 18 are located within the Thebarton EPA Assessment Area Although (where recorded) bores were listed as having been installed primarily for monitoring investigation or observation purpose other purposes (for presumed Quaternary aquifer bores) included drainage domestic and industrial A BUA has identified realistic groundwater uses as potentially including potable residential irrigation and primary contact recreationaesthetics Based on proximity to the River Torrens freshwater ecosystem protection has also been considered ndash however since the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area this may not be a realistic beneficial use Since volatile contaminants have been detected within the Q1 aquifer a potential vapour flux risk to future site users has also been considered

      Hydrology No surface water bodies have been identified within the Thebarton EPA Assessment Area The closest surface water body is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west Current stormwater run-off within the Thebarton EPA Assessment Area is expected to be collected by localised (and engineered) drainage systems

      Fyfe Investigation Results

      Groundwater impacts Contaminants identified in groundwater beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected source site (ie the former Austral sheet metal works) in accordance with the predominant flow direction associated with the Q1 aquifer (refer to Figures 4 and 5) The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) but its north-western extent has not yet been determined (whereas its extent has been defined in all other directions)

      Soil vapour impacts Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction (refer to Figures 6 and 7) and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion The soil vapour samples with the maximum TCE concentrations (ie SV3_10m and SV3_30m) also had the highest PCE and 11-DCE concentrations (or elevated LOR) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-) Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE (ie SV2_30m SV3_10m SV3_30m and SV7_30m) exceeded the adopted HILs for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE

      PAGE 62 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Topic Summarised Information

      degradation has not yet resulted in its production (ie at measureable levels) Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

      Potential Exposure Pathways

      Contaminants of Based on the results of historical investigations the EPA identified a number of CHC as being of Potential Concern concern for the Thebarton EPA Assessment Area The main COPC was identified as TCE with

      additional COPC including PCE 12-DCE (cis- and trans-) VC and 11-DCE Further detail is provided in Section 14 These COPC were confirmed by the Fyfe investigations with TCE identified as both the main contaminant in groundwater and soil vapour and the main driver in terms of potential human health risks associated with vapour intrusion into buildings within the Thebarton EPA Assessment Area (refer to Section 9)

      Suspected source and The suspected source of the identified CHC groundwater (and soil vapour) impacts within the affected media Thebarton EPA Assessment Area is the former Austral sheet metal works located over multiple

      allotments between George and Maria Streets from the 1920s until the 1960s-1970s Previous investigations (Appendix A) had identified groundwater CHC impacts on part of this suspected source site The Fyfe investigations have concentrated on impacts within groundwater and soil vapour across the Thebarton EPA Assessment Area both of which generally correlate with the inferred north-westerly groundwater flow direction and are considered to be related to the previously identified dissolved phase groundwater CHC impacts

      Sensitive receptors The following sensitive receptors have been identified as potentially relevant to the Thebarton EPA Assessment Area Ecological groundwater ecosystems within the assessment area extending to at least Dew and Smith

      Streets (ie as the north-western extent of the groundwater CHC plume has not yet been determined) and

      the freshwater ecosystem of the River Torrens located at a distance of approximately 07 km in a hydraulically down-gradient (ie north-westerly) direction but not necessarily representing a groundwater receiving environment

      Human current and future occupants of and visitors to residential properties current and future workers on the source site and other commercialindustrial properties

      within the area current and future underground trenchmaintenanceutility workers and down-gradient groundwater bore users

      Contaminant Possible contaminant transport mechanisms associated with the CHC-impacted groundwater transport identified within the Q1 aquifer beneath the Thebarton EPA Assessment Area include mechanisms flow through the aquifer to a hydraulically down-gradient surface water body andor down-

      gradient groundwater bores vapour generation andor flow via subsurface preferential pathways (eg service trenches

      more permeable soils) and downward movement into underlying aquifers (eg dense non-aqueous phase liquid

      (DNAPL))

      80607-1 REV1 30102017 PAGE 63

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Topic Summarised Information

      Exposure Possible exposure mechanisms associated with impacted groundwater within the Thebarton mechanisms EPA Assessment Area include

      direct contact (eg during extractionuse of groundwater) incidental ingestion (eg during extractionuse of groundwater) and inhalation of vapours (eg during extractionuse of groundwater andor as a result of

      vapour intrusion into buildings)

      Assessment of Risk

      Groundwater risks The recent groundwater analytical results have indicated that the Q1 aquifer beneath the Thebarton EPA Assessment Area contains measurable concentrations of CHC (mainly TCE but also including PCE 12-DCE andor 11-DCE at some locations) Measured concentrations of TCE exceeded the adopted assessment criteria for potable andor primary contact recreation in wells MW02 MW3 MW5 MW6 MW11 MW12 MW14 MW15 MW17 MW20 MW21 and MW23 located on Admella Maria George Albert and Dew Streets as well as Light Terrace with maximum concentrations corresponding to the ldquocorerdquo area of the plume One well (MW25) contained a concentration of carbon tetrachloride that exceeded the adopted potable criterion Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

      Groundwater fate Although scattered detectable concentrations of 12-DCE have been measured in groundwater and transport across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE modelling daughter products has been interpreted to indicate that substantial dechlorination is not

      occurring Groundwater fate and transport modelling (refer to Section 8 and Appendix O) has predicted that the likely extent of the dissolved phase groundwater TCE plume over the next 100 years will extend by another 500 m beyond the boundaries of the current Thebarton EPA Assessment Area However no significant lateral plume expansion is expected

      Vapour intrusion risks A VIRA (refer to Section 9 and Appendix P) was undertaken to assess potential risks to human health from the intrusion of CHC vapours (primarily TCE) into indoor air from soil vapour The predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction in the absence of specific structural information) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and therefore require further action as follows 10 properties within the investigation range (2 to lt20 microgm3) eight properties within the intervention range (20 to lt200 microgm3) and three properties within accelerated intervention range (ge200 microgm3) All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3

      (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as

      PAGE 64 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Topic Summarised Information

      selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which are expected to be overly-conservative) ndash these results will be documented in a subsequent report Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed Management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air)

      Complete Exposure Pathways

      Identified pathways and areas of potential risk

      Based on the results of the recent Fyfe investigations (including the VIRA) and taking into account available historical information (Appendices A and B) and DEWNR (2017) WaterConnect bore information the following complete exposure pathways and associated risks are considered possible for the Thebarton EPA Assessment Area exposure (direct contact incidental ingestion andor inhalation of vapours) during use of

      groundwater for domestic (eg drinking water plumbing garden irrigation) andor recreational (eg filling of swimming poolsspas) purposes

      vapour intrusion into indoor air within 30 residential propertieslocated within the vicinity of soil vapour bores SV1 to SV9 (assuming crawl space construction) ndash although 19 of these properties are predicted to be in the validationinvestigation action level range 11 are predicted to be in the intervention action level range (with actual indoor air monitoring results for properties within the intervention action level range pending)

      vapour intrusion into residential cellarsbasements (if present) in the vicinity of soil vapour bores SV1 to SV10 and SV12 and

      vapour intrusion into the indoor air of commercialindustrial properties ndash although actual risks to site workers would require further specific considerationassessment

      In addition although only assessed in a qualitative manner to date trenchmaintenanceutility workers may also be at risk where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

      Notes calculated on the basis of cadastral boundaries and assuming crawl space construction ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial premises a property survey would be required to confirm building construction details and the number of individual residences affected

      80607-1 REV1 30102017 PAGE 65

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      11 CONCLUSIONS

      Between May and August 2017 Fyfe undertook an investigation of groundwater and soil vapour CHC impacts within an EPA-designated Assessment Area located in Thebarton South Australia The results of the investigation have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties A CSM has been developed from the field analytical and modelling results as presented in Section 10

      The following conclusions have been reached

      Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were present within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m in groundwater well MW17

      Groundwater within the Q1 aquifer is located at a depth of approximately 123 to 159 m BGL and flows in a general north-westerly direction (refer to Figure 4) ndash the closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred16 and the groundwater gradient beneath the Thebarton EPA Assessment area is relatively flat (ie 000062 to 00012)

      Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified to include domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux as assessed by the VIRA) and possibly also potable Although freshwater ecosystem protection was also considered the River Torrens is thought to comprise either a recharge boundary (ie discharging to local groundwater) or to not actually be hydraulically connected to the Q1 aquifer in this area

      Groundwater beneath parts of the Thebarton EPA Assessment Area contains detectable concentrations of various CHC and includes TCE and carbon tetrachloride (one location only) levels that exceed the adopted assessment criteria for potable use andor primary contact recreation ndash thereby indicating that groundwater would be unsuitable for drinking or the filling of swimming poolsspas In addition vapour flux could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the groundwater could be odorous

      16 ie as calculated by Fyfe based on available data

      80607-1 REV1 30102017 PAGE 67

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      The groundwater and soil vapour CHC impacts identified beneath parts of the Thebarton EPA Assessment Area are considered likely to have emanated from the former Austral sheet metal works located over multiple allotments between George and Maria Streets from the 1920s until the 1960sshy1970s The possible presence of on-going (primary andor secondary) source(s) at this property has not yet been investigated

      As depicted on Figures 6 and 7 the current extent of the soil vapour CHC (ie dominated by TCE) impacts has been determined to correspond to the mapped distribution of the groundwater TCE impacts (Figure 5) and is considered to be directly related to groundwater (rather than soil) CHC impacts Although no soil vapour impacts were detected at 1 m BGL in SV11 and SV1317 located near the eastern and western ends of Light Terrace respectively the north-western extents of the groundwater and soil vapour CHC impacts have not yet been determined In addition although the extent of the groundwater TCE plume has been delineated in all other directions the soil vapour TCE plume has not been delineated in any direction

      TCE is considered to be a primary contaminant as well as the dominant (ie in terms of concentration and extent) CHC in both groundwater and soil vapour ndash the presence of PCE and 11-DCE suggests however that more than one primary contaminant is present Although the detectable concentrations of 12-DCE (cis- and trans) are considered to have resulted from the breakdown of TCEPCE no VC has been detected in either groundwater or soil vapour ndash the scattered distribution and relatively low concentrations of 12-DCE as well as the absence of measurable VC have been interpreted to indicate that significant dechlorination of the primary contaminants has not occurred (despite the likely age of the plume ndash ie possibly up to about 90 years old)

      Although the COPC adopted for the soil vapour assessment program included various CHC (ie with TCE identified as the dominant contaminant in groundwater and soil vapour) the Tier 1 VIRA confirmed that TCE PCE and 11-DCE all exceeded the adopted vapour intrusion HILs Based primarily on its greater toxicity however the risk driver for the Thebarton EPA Assessment Area is considered to be TCE

      The VIRA (Tier 2) results for predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and that require further action as follows

      ― 10 properties within the investigation range (2 to lt20 microgm3)

      ― eight properties within the intervention range (20 to lt200 microgm3) and

      ― three properties within accelerated intervention range (ge200 microgm3)

      All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming

      17 noting that the laboratory LOR for TCE was elevated as compared to the other soil vapour samples

      PAGE 68 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises ndash refer to Table 96

      Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentration obtained for soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

      Although only assessed in a qualitative manner trenchmaintenanceutility workers may be at risk in areas where TCE concentrations at 1 m BGL are greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) ndash in this case appropriate management measures would be required to be adopted This should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

      80607-1 REV1 30102017 PAGE 69

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      12 DATA GAPS

      Based on the results obtained during the recent Fyfe investigations as well as available historical information (Appendices A and B) the following data gaps have been identified for the Thebarton EPA Assessment Area

      property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

      groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

      the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

      the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

      80607-1 REV1 30102017 PAGE 71

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      13 REFERENCES

      ANZECCARMCANZ (2000a) Australian Guidelines for Water Quality Monitoring and Reporting

      ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

      ASTM (2001) Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations ASTM Guide D7663-12

      ASTM (2006) Standard Guide for Soil Gas Monitoring in the Vadose Zone ASTM Guide D5314-92

      ATSDR (1994) Toxicological profile ndash 11-Dichloroethene httpswwwatsdrcdcgovToxProfilestpaspid=722amptid=130

      AustralianNew Zealand Standard (1998) Water Quality Sampling Part 1 Guidance on the Design of Sampling Programs Sampling Techniques and the Preservation and Handling of Samples ASNZS 566711998

      AustralianNew Zealand Standard (1998) Water Quality Sampling Part 11 Guidance on Sampling of Groundwaters ASNZS 5667111998

      Bouwer H and Rice RC (1976) A Slug Test Method for Determining Hydraulic Conductivity of Unconfined Aquifers with Completely or Partially Penetrating Wells Water Resources Research vol 12 no 3 pp 423-428

      Butler JJ Jr (1998) The Design Performance and Analysis of Slug Tests

      Cooper HH Bredehoeft JD and Papadopulos SS (1967) Response of a Finite-Diameter Well to an Instantaneous Charge of Water Water Resources Research vol 3 no 1 pp 263-269

      CRC CARE (2013) Petroleum Hydrocarbon Vapour Intrusion Assessment ndash Australian Guidance CRC CARE Technical Report No 23 July 2013

      Dagan G (1978) A Note on Packer Slug and Recovery Tests in Unconfined Aquifers Water Resources Research vol 14 no 5 pp 929-934

      Department of Environment Water and Natural Resources (DEWNR 2017) Water Connect Master Register of All Bores Primary Industries and Resources South Australia

      Duffield G (2007) AQTESOLVreg Professional Version 45 Hydrosolve Inc

      enHealth (2012a) Environmental Health Risk Assessment - Guidelines for assessing human health risks from environmental hazards enHealth Council

      enHealth (2012b) Australian Exposure Factor Guidance Handbook enHealth Council

      Environment Protection Act 1993

      80607-1 REV1 30102017 PAGE 73

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      Environment Protection Regulations 2009

      Friebel E and Nadebaum P (2011) Health Screening Levels for Petroleum Hydrocarbons in Soil and Groundwater CRC CARE Technical Report No 10

      Gerges NZ (1999) The Geology and Hydrogeology of the Adelaide Metropolitan Area Flinders University (South Australia) PhD thesis (unpublished)

      Gerges NZ (2006) Overview of the Hydrogeology of the Adelaide Metropolitan Area DWLBC Report 200610

      Golder Associates (1994) Contamination Assessment George Street Thebarton SA Report to United Land dated 9 December 1994

      Hvorslev MJ (1951) Time Lag and Soil Permeability in Ground-Water Observations Bulletin no 36 Waterways Exper Sta Corps of Engrs US Army Vicksburg Mississippi pp 1-50

      Hyder Z Butler JJ Jr McElwee CD and Liu W (1994) Slug Tests in Partially Penetrating Wells Water Resources Research vol 30 no 11 pp 2945-2957

      ITRC (2007) Vapor Intrusion Pathway - A Practical Guidance

      Johnson PC and Ettinger RA (1991) Heuristic Model for Predicting the Intrusion Rate of Contaminant Vapors

      into Buildings Environ Sci Technology 251445-1452

      McDonald M G and Harbaugh A W (1988) A Modular Three-Dimensional Finite-Difference Ground-Water Flow Model Techniques of Water-Resources Investigations Book 6 Chapter A1 U S Geological Survey

      NEPM (1999) National Environment Protection (Assessment of Site Contamination) Measure Schedules B1 to

      B9 National Environment Protection Council Australia

      NHMRC (2008) Guidelines for Managing Risks in Recreational Water

      NHMRCNRMMC (2011) Australian Drinking Water Guidelines (as revised in 2016)

      NJDEP (2013) Site Remediation Program Vapor Intrusion Technical Guidance (Version 31)

      NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme (2nd edition)

      Payne FC Quinnan JA and Potter ST (2008) Remediation Hydraulics CRC Press Boca Raton FL

      RAIS (2016) Chemical Specific Parameters for Trichloroethylene Risk Assessment Information System Office of Environmental Management US Department of Energy

      REM (2005a) George St Thebarton Site ndash Stage 2 Investigations Report to Luca Group dated 26 August 2005

      REM (2005b) Stage 3 Environmental Site Assessment George St Thebarton SA Report to Luca Group dated 23 November 2005

      SA Department of Mines and Energy (1969) 1250000 Adelaide Geological Map Sheet Sheet S1 54-9

      PAGE 74 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      SA EPA (2007) Regulatory Monitoring and Testing Groundwater Sampling

      SA EPA (2009) Guidelines for the Assessment and Remediation of Groundwater Contamination

      SA EPA (2014) Clovelly Park Mitchell Park Project Management Team Assessment Program Flip Book November 2014

      SA EPA (2015) Environment Protection (Water Quality) Policy

      Standards Australia (1993) Geotechnical Site Investigations AS1726-1993

      Standards Australia (2005) Guide to the Sampling and Investigation of Potentially Contaminated Soil Part 1 Non-Volatile and Semi-Volatile Compounds AS44821-2005

      Stapledon DH (1971) Changes and Structural Defects Developed in some South Australian Clays and their Engineering Consequences Proceedings of Symposium on Soils and Earth Structures in Arid Climates Adelaide 1970

      US EPA (1996) Soil Screening Guidance Technical Background Document Office of Emergency and Remedial Response Washington DC EPA540R95128

      US EPA (1999) Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air Second Edition Compendium Method TO-15 Determination Of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed By Gas Chromatography Mass Spectrometry (GCMS) EPA625R-96010b

      US EPA (2002) OSWER Draft Guidance for Evaluating the Vapour Intrusion to Indoor Air Pathway from Groundwater and Soils (Subsurface Vapour Intrusion Guidance) EPA530-D-02-004

      US EPA (2009) EPArsquos Risk-Screening Environmental Indicators (RSEI) Methodology Office of Pollution Prevention and Toxics Washington DC

      US EPA (2011) IRIS (Integrated Risk Information System) Trichloroethylene Chemical Assessment Summary httpscfpubepagovnceairisiris_documentsdocumentssubst0199_summarypdf

      US EPA (2012) EPArsquos Vapor Intrusion Database Evaluation and Characterization of Attenuation Factors for Chlorinated Volatile Organic Compounds and Residential Buildings

      US EPA (2015) OSWER Technical Guide for Assessing and Mitigating the Vapour Intrusion Pathway from Subsurface Vapour Sources to Indoor Air

      US EPA (2017a) Regional Screening Levels (RSLs) - Generic Tables (June 2017) httpswwwepagovriskregional-screening-levels-rsls-generic-tables-june-2017

      US EPA (2017b) Regional Screening Levels for Chemical Contaminants at Superfund Sites httpwwwepagovreg3hwmdriskhumanrb-concentration_tableGeneric_Tablesindexhtm

      80607-1 REV1 30102017 PAGE 75

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      WHO (2006) Air Quality Guidelines for Europe Second Edition WHO Regional Publications European Series No 91

      WHO (2017) Guidelines for Drinking-water Quality Fourth edition (incorporating the first addendum)

      Wiedemeier T Swanson M Moutoux D Gordon E Wilson J Wilson B Kampbell D Haas P Miller R Hansen J and Chapelle F (1998) Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water National Risk Management Research Laboratory Office of Research and Development US EPA

      Zheng C (1990) MT3D A Modular Three-Dimensional Transport Model for Simulation of Advection Dispersion and Chemical Reactions of Contaminants in Groundwater Systems Prepared for US EPA by Robert S Kerr Environmental Research Laboratory Ada Oklahoma developed by SS Papadopulos amp Associates Inc Rockville Maryland

      PAGE 76 80607-1 REV1 30102017

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      14 STATEMENT OF LIMITATIONS

      The opinions and conclusions presented in this report are specific to the conditions of the Thebarton EPA Assessment Area and the state of legislation currently enacted as at the date of this report Fyfe does not make any representation or warranty that the opinions and conclusions in this report will be applicable in the future as there may be changes in the condition of the Thebarton EPA Assessment Area applicable legislation or other factors that would affect the opinions and conclusions contained in this report

      Fyfe has used the degree of skill and care ordinarily exercised by reputable members of our profession practising in the same or similar locality This report has been prepared for the South Australian Environment Protection Authority for the specific purpose identified in the report Fyfe accepts no liability or responsibility to any third party for the accuracy of any information contained in the report or any opinion or conclusion expressed in the report Neither the whole of the report nor any part or reference thereto may be in any way used relied upon or reproduced by any third party without Fyfersquos prior written approval This report must be read in its entirety including all tables and attachments

      80607-1 REV1 30102017 PAGE 77

      EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

      FIGURES

      Figure 1 Site Location and Assessment Area

      Figure 2 Assessment Point Locations

      Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan

      Figure 4 Groundwater Elevation Contour Plan

      Figure 5 Groundwater Concentration Plan

      Figure 6 Soil Vapour Concentration Plan (10m)

      Figure 7 Soil Vapour Concentration Plan (30m)

      80607-1 REV1 30102017 PAGE 79

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      DEW

      STREET

      DEW

      STREET

      CHAPEL STREETCHAPEL STREET

      PAR

      KER

      STREET

      PAR

      KER

      STREET

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      LIGHT TERRACELIGHT TERRACE

      DEW

      STREET

      DEW

      STREET

      WA

      LSH ST

      WA

      LSH ST

      AD

      MELLA

      STREET

      AD

      MELLA

      STREET

      ALB

      ERT STR

      EETA

      LBER

      T STREET

      HO

      LLAN

      D ST

      REET

      HO

      LLAN

      D ST

      REET

      RANDOLPH STREET

      RANDOLPH STREET

      JAM

      ES STREET

      JAM

      ES STREET

      DOVE STREET

      DOVE STREET

      SMITH STREETSMITH STREET

      MARIA STREETMARIA STREET

      GEORGE STREETGEORGE STREET

      KINTORE STREET

      KINTORE STREET

      PORT ROAD

      PORT ROAD

      PORT ROAD

      PORT ROAD

      CAW

      THO

      RN

      E STR

      EETC

      AWTH

      OR

      NE ST

      REET

      DEVON STREETDEVON STREET

      KINTORE STREETKINTORE STREET

      GOODENOUGH STREETGOODENOUGH STREET

      LIVESTR

      ON

      G PATH

      WAY

      LIVESTR

      ON

      G PATH

      WAY

      CCAAWW

      TTHHOO

      RRNN

      EE SSTTRR

      EEEETT

      HHOO

      LLLLAANN

      DD SSTT

      RREEEETT

      DE

      DEW

      SW

      STREET

      TREET

      JJAM

      EA

      MES S

      S STREET

      TREET

      DDOOVVEE SSTTRREEEETT

      LLIIVVEESSTTRR

      OONN

      GG PPAATTHH

      WWAAYY

      LIGHT TERRLIGHT TERRAACECE

      AD

      MELLA

      SA

      DM

      ELLA STR

      EETTR

      EET

      CHAPEL SCHAPEL STREETTREET

      AALLBB

      EERRTT SSTTRR

      EEEETT

      GEGEORORGE SGE STREETTREET

      PPOORRTT RROOAADD

      PPOORRTT RROOAADD

      DDEEWW

      SSTTRREEEETT

      MMAARRIIAA SSTTRREEEETT

      JJAAMM

      EESS CCOO

      NNGG

      DDOO

      NN DD

      RRIIVV

      EE

      WWAA

      LLSSHH SSTT

      SSMMIITTHH SSTTRREEEETT

      RRANDOLPH S

      ANDOLPH STREETTREET

      PPOORR

      TT RROO

      AADD

      PPOORR

      TT RROO

      AADD

      KKIINNTTOORREE SSTTRREEEETT

      KKIINNTTOORREE SSTTRREEEETT

      PPAARR

      KKEERR

      SSTTRREEEETT

      GGOOOODDEENNOOUUGGHH SSTTRREEEETT

      DDEEVVOONN SSTTRREEEETT

      ASSESSMENT AREA

      CBD

      750m

      LEGEND

      EPA ASSESSMENT AREA

      CADASTRE

      12500 A3

      0 25 50 m

      CLIENT

      SA EPA

      PROJECT

      FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

      EPA THEBARTON ASSESSMENT AREA - STAGE 1

      TITLE

      FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

      PROJECT NO DATE CREATED

      80607-1 290917

      80607_Fig 1 - Site Location and Assessment Areaai REV 1 gt 290917

      LE

      VE

      L 1

      12

      4 S

      OU

      TH

      TE

      RR

      AC

      E

      AD

      EL

      AID

      E S

      A 5

      00

      0

      P

      H

      (08

      ) 8

      23

      2 9

      08

      8

      F

      AX

      (0

      8)

      82

      32

      90

      99

      EM

      AIL

      in

      fo

      fyfe

      co

      ma

      u

      W

      EB

      fy

      fec

      om

      au

      AB

      N

      57

      00

      8 1

      16 1

      30

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      DEW

      STREET

      DEW

      STREET

      CHAPEL STREETCHAPEL STREET

      PAR

      KER

      STREET

      PAR

      KER

      STREET

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      LIGHT TERRACELIGHT TERRACE

      DEW

      STREET

      DEW

      STREET

      WA

      LSH ST

      WA

      LSH ST

      AD

      MELLA

      STREET

      AD

      MELLA

      STREET

      ALB

      ERT STR

      EETA

      LBER

      T STREET

      HO

      LLAN

      D ST

      REET

      HO

      LLAN

      D ST

      REET

      RANDOLPH STREET

      RANDOLPH STREET

      JAM

      ES STREET

      JAM

      ES STREET

      DOVE STREET

      DOVE STREET

      SMITH STREETSMITH STREET

      MARIA STREETMARIA STREET

      GEORGE STREETGEORGE STREET

      KINTORE STREET

      KINTORE STREET

      PORT ROAD

      PORT ROAD

      PORT ROAD

      PORT ROAD

      CAW

      THO

      RN

      E STR

      EETC

      AWTH

      OR

      NE ST

      REET

      DEVON STREETDEVON STREET

      KINTORE STREETKINTORE STREET

      GOODENOUGH STREETGOODENOUGH STREET

      LIVESTR

      ON

      G PATH

      WAY

      LIVESTR

      ON

      G PATH

      WAY

      SV1SV1

      SV2SV2

      SV3SV3SV4SV4

      SV5SV5

      SV6SV6

      SV7SV7SV8SV8

      SV9SV9

      SV10SV10

      SV11SV11SV12SV12

      SV13SV13

      MW1MW1

      MW02MW02

      MW3MW3

      MW4MW4MW5MW5MW6MW6

      MW7MW7

      MW8MW8

      MW9MW9

      MW10MW10MW11MW11

      MW12MW12MW13MW13

      MW14MW14MW15MW15

      MW16MW16

      MW17MW17

      MW18MW18

      MW19MW19

      MW20MW20

      MW21MW21

      MW22MW22

      MW23MW23

      MW24MW24

      MW25MW25

      MW26MW26

      WMS2WMS2WMS1WMS1

      WMS3WMS3WMS4WMS4WMS5WMS5

      WMS6WMS6

      WMS7WMS7WMS8WMS8

      WMS9WMS9WMS10WMS10

      WMS11WMS11

      WMS12WMS12

      WMS13WMS13WMS14WMS14

      WMS15WMS15

      WMS41WMS41

      WMS40WMS40

      WMS39WMS39WMS38WMS38

      WMS16WMS16

      WMS17WMS17

      WMS18WMS18WMS19WMS19

      WMS20WMS20

      WMS21WMS21WMS22WMS22

      WMS23WMS23WMS24WMS24

      WMS25WMS25

      WMS26WMS26

      WMS27WMS27WMS28WMS28WMS29WMS29

      WMS30WMS30

      WMS31WMS31

      WMS32WMS32

      WMS33WMS33

      WMS34WMS34

      WMS35WMS35

      WMS36WMS36

      WMS37WMS37

      WWAA

      LLSSHHSSTT

      SSMMIITTHH SSTTRREEEETT

      RRANDOLPH S

      ANDOLPH STREETTREET

      PPOORR

      TT RROO

      AADD

      PPOORR

      TT RROO

      AADD

      CCAAWW

      TTHHOO

      RRNN

      EE SSTTRR

      EEEETT

      JJAM

      EA

      MES S

      S STREET

      TREET

      HHOO

      LLLLAANN

      DDSSTT

      RREEEETT

      DE

      DEW

      SW

      STREET

      TREET

      DDOOVVEE SSTTRREEEETT

      LLIIVVEESSTTRR

      OONN

      GGPPAATTHH

      WWAAYY

      LIGHT TERRLIGHT TERRAACECE

      CHAPEL SCHAPEL STREETTREET

      AALLBB

      EERRTT SSTTRR

      EEEETT

      AD

      MELLA

      SA

      DM

      ELLA STR

      EETTR

      EET

      GEGEORORGE SGE STREETTREET

      PPOORRTT RROOAADD PPOORRTT RROOAADD

      DDEEWW

      SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

      JJAAMM

      EESS CCOO

      NNGG

      DDOO

      NN DD

      RRIIVV

      EE

      KKIINNTTOORREE SSTTRREEEETT

      KKIINNTTOORREE SSTTRREEEETT

      PPAARR

      KKEERR

      SSTTRREEEETT

      GGOOOODDEENNOOUUGGHH SSTTRREEEETT

      DDEEVVOONN SSTTRREEEETT

      FIGURE 2 ASSESSMENT POINT LOCATIONS

      MMWW88

      MW2MW244 WMS3WMS355

      MW2MW255

      WMS3WMS366

      WMS3WMS377

      WMS3WMS311

      MW2MW222WMS34WMS34

      MW2MW233 WMS3WMS322

      WMS3WMS333

      WMS2WMS277WMS2WMS299 WMS2WMS288

      SSV12V12 SSVV1111 MW19MW19

      MW18MW18 SSVV1133 MW2MW200 WMS3WMS300

      MW2MW211 WMS2WMS255

      WMS2WMS266

      MW17MW17 WMS2WMS244

      WMS2WMS233

      WMS2WMS222 WMS2WMS211

      SSVV99

      SSV10V10WMS2WMS200 MW14MW14MW15MW15 WMS18WMS18

      WMS19WMS19 MW16MW16

      WMS13WMS13MW10MW10 WMS14WMS14MMWW1111SVSV77WMS15WMS15SSVV88WMS16WMS16

      SVSV66WMS4WMS411MW13MW13 LEGENDMW12MW12

      WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS17WMS17 WMS40WMS40 SSVV55 MW0MW022MW9MW9 GROUNDWATER MONITORING WELL

      WMS11WMS11 WMS6WMS6 SOIL VAPOUR BORE

      WATERLOO MEMBRANE SAMPLERTM - ROUND 2

      SVSV22WMS8WMS8SVSVWMS12WMS12 44 WMS7WMS7 MW4MW4MMWW SVSV66 33 MW5MW5WMS3WMS388

      WMS3WMS399 MW7MW7 EPA ASSESSMENT AREAWMS10WMS10 WMS9WMS9

      SVSV11 CADASTRE

      MW3MW3

      MW1MW1 WMS3WMS3WMS4WMS4MW2MW266 WMS5WMS5 12500 A3

      0 25 50 m

      CLIENT

      SA EPAWMS1WMS1

      WMS2WMS2 PROJECT

      EPA THEBARTON ASSESSMENT AREA - STAGE 1

      TITLE

      FIGURE 2 ASSESSMENT POINT LOCATIONS

      PROJECT NO DATE CREATED

      80607-1 280917

      80607_Fig 2 - Assessment Point Locationsai REV 1 gt 280917

      LE

      VE

      L 1

      12

      4 S

      OU

      TH

      TE

      RR

      AC

      E

      AD

      EL

      AID

      E S

      A 5

      00

      0

      PH

      (0

      8)

      82

      32

      90

      88

      F

      AX

      (0

      8)

      82

      32

      90

      99

      E

      MA

      IL

      info

      fy

      fec

      om

      au

      W

      EB

      fy

      fec

      om

      au

      A

      BN

      5

      7 0

      08

      116

      13

      0

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      DEW

      STREET

      DEW

      STREET

      CHAPEL STREETCHAPEL STREET

      PAR

      KER

      STREET

      PAR

      KER

      STREET

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      LIGHT TERRACELIGHT TERRACE

      DEW

      STREET

      DEW

      STREET

      WA

      LSH ST

      WA

      LSH ST

      AD

      MELLA

      STREET

      AD

      MELLA

      STREET

      ALB

      ERT STR

      EETA

      LBER

      T STREET

      HO

      LLAN

      D ST

      REET

      HO

      LLAN

      D ST

      REET

      RANDOLPH STREET

      RANDOLPH STREET

      JAM

      ES STREET

      JAM

      ES STREET

      DOVE STREET

      DOVE STREET

      SMITH STREETSMITH STREET

      MARIA STREETMARIA STREET

      GEORGE STREETGEORGE STREET

      KINTORE STREET

      KINTORE STREET

      PORT ROAD

      PORT ROAD

      PORT ROAD

      PORT ROAD

      CAW

      THO

      RN

      E STR

      EETC

      AWTH

      OR

      NE ST

      REET

      DEVON STREETDEVON STREET

      KINTORE STREETKINTORE STREET

      GOODENOUGH STREETGOODENOUGH STREET

      LIVESTR

      ON

      G PATH

      WAY

      LIVESTR

      ON

      G PATH

      WAY

      WMS2WMS2WMS1WMS1

      WMS3WMS3WMS4WMS4

      WMS5WMS5

      WMS6WMS6

      WMS7WMS7WMS8WMS8

      WMS9WMS9

      WMS10WMS10

      WMS11WMS11

      WMS12WMS12

      WMS13WMS13WMS14WMS14

      WMS15WMS15 WMS41WMS41

      WMS40WMS40

      WMS39WMS39WMS38WMS38

      WMS16WMS16

      WMS17WMS17

      WMS18WMS18WMS19WMS19WMS20WMS20

      WMS21WMS21WMS22WMS22

      WMS23WMS23WMS24WMS24

      WMS25WMS25

      WMS26WMS26

      WMS27WMS27WMS28WMS28WMS29WMS29

      WMS30WMS30

      WMS31WMS31

      WMS32WMS32WMS33WMS33

      WMS34WMS34

      WMS35WMS35

      WMS36WMS36

      WMS37WMS37

      WWAA

      LLSSHHSSTT

      SSMMIITTHH SSTTRREEEETT

      RRANDOLPH S

      ANDOLPH STREETTREET

      PPOORR

      TT RROO

      AADD

      PPOORR

      TT RROO

      AADD

      CCAAWW

      TTHHOO

      RRNN

      EE SSTTRR

      EEEETT

      JJAM

      EA

      MES S

      S STREET

      TREET

      HHOO

      LLLLAANN

      DDSSTT

      RREEEETT

      DE

      DEW

      SW

      STREET

      TREET

      DDOOVVEE SSTTRREEEETT

      LLIIVVEESSTTRR

      OONN

      GGPPAATTHH

      WWAAYY

      LIGHT TERRLIGHT TERRAACECE

      AD

      MELLA

      SA

      DM

      ELLA STR

      EETTR

      EET

      AALLBB

      EERRTT SSTTRR

      EEEETT

      CHAPEL SCHAPEL STREETTREET

      GEGEORORGE SGE STREETTREET

      PPOORRTT RROOAADD PPOORRTT RROOAADD

      DDEEWW

      SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

      JJAAMM

      EESS CCOO

      NNGG

      DDOO

      NN DD

      RRIIVV

      EE

      KKIINNTTOORREE SSTTRREEEETT

      KKIINNTTOORREE SSTTRREEEETT

      PPAARR

      KKEERR

      SSTTRREEEETT

      GGOOOODDEENNOOUUGGHH SSTTRREEEETT

      DDEEVVOONN SSTTRREEEETT

      FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

      TCE CONCENTRATION PLAN

      WMS3WMS355 TCE lt78

      WMS3WMS366 TCE lt77WMS3WMS377

      TCE 44

      WMS3WMS311 TCE lt78

      WMS34WMS34 TCE 11

      WMS3WMS322WMS3WMS333 TCE lt78TCE lt79

      WMS2WMS277WMS2WMS299 WMS2WMS288 TCE 64 TCE lt77 TCE lt8

      WMS3WMS300 TCE lt8

      WMS2WMS255

      WMS2WMS266 TCE 1400(D)

      WMS2WMS222 TCE 38 WMS2WMS211

      TCE lt79

      TCE lt78

      WMS2WMS233 WMS2WMS244 TCE lt77

      TCE 230

      WMS2WMS200 WMS19WMS19TCE lt78 WMS18WMS18 TCE 11000

      TCE 4200

      WMS13WMS13 WMS14WMS14 TCE lt79

      WMS4WMS411WMS15WMS15 TCE 46000WMS16WMS16 TCE 18000 LEGENDTCE lt8

      TCE lt78WMS17WMS17 WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS40WMS40TCE lt79

      TCE 110000 WATERLOO MEMBRANE SAMPLERTM - ROUND 2WMS11WMS11

      TCE 71000WMS12WMS12 EPA ASSESSMENT AREA

      CADASTRE

      WMS6WMS6 TCE lt58 WMS8WMS8 WMS3WMS388 TCE 32WMS7WMS7WMS3WMS399

      TCE 12000 TCE 13000 TCE 1900TCE 1300WMS9WMS9 TCE lt58 NotesWMS10WMS10

      All concentrations are in μgm3 TCE lt58

      D = Duplicate result

      WMS3WMS3WMS4WMS4 12500 A3

      LE

      VE

      L 1

      12

      4 S

      OU

      TH

      TE

      RR

      AC

      E

      AD

      EL

      AID

      E S

      A 5

      00

      0

      PH

      (0

      8)

      82

      32

      90

      88

      F

      AX

      (0

      8)

      82

      32

      90

      99

      E

      MA

      IL

      info

      fy

      fec

      om

      au

      W

      EB

      fy

      fec

      om

      au

      A

      BN

      5

      7 0

      08

      116

      13

      0

      TCE lt57WMS5WMS5 TCE lt57 TCE lt58 0 25 50

      m

      CLIENT

      SA EPA

      WMS2WMS2 TCE lt56

      WMS1WMS1 TCE lt56

      PROJECT

      EPA THEBARTON ASSESSMENT AREA - STAGE 1

      TITLE

      FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

      TCE CONCENTRATION PLAN

      PROJECT NO DATE CREATED

      80607-1 241017

      80607_Fig 3 - WMS TCE Concentration Planai REV 1 gt 241017

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      DEW

      STREET

      DEW

      STREET

      CHAPEL STREETCHAPEL STREET

      PAR

      KER

      STREET

      PAR

      KER

      STREET

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      LIGHT TERRACELIGHT TERRACE

      DEW

      STREET

      DEW

      STREET

      WA

      LSH ST

      WA

      LSH ST

      AD

      MELLA

      STREET

      AD

      MELLA

      STREET

      ALB

      ERT STR

      EETA

      LBER

      T STREET

      HO

      LLAN

      D ST

      REET

      HO

      LLAN

      D ST

      REET

      RANDOLPH STREET

      RANDOLPH STREET

      JAM

      ES STREET

      JAM

      ES STREET

      DOVE STREET

      DOVE STREET

      SMITH STREETSMITH STREET

      MARIA STREETMARIA STREET

      GEORGE STREETGEORGE STREET

      KINTORE STREET

      KINTORE STREET

      PORT ROAD

      PORT ROAD

      PORT ROAD

      PORT ROAD

      CAW

      THO

      RN

      E STR

      EETC

      AWTH

      OR

      NE ST

      REET

      DEVON STREETDEVON STREET

      KINTORE STREETKINTORE STREET

      GOODENOUGH STREETGOODENOUGH STREET

      LIVESTR

      ON

      G PATH

      WAY

      LIVESTR

      ON

      G PATH

      WAY

      MW1MW1

      MW02MW02

      MW3MW3

      MW4MW4MW5MW5

      MW6MW6

      MW7MW7

      MW8MW8

      MW9MW9

      MW10MW10MW11MW11

      MW12MW12

      MW13MW13

      MW14MW14

      MW15MW15

      MW16MW16

      MW17MW17

      MW18MW18

      MW19MW19MW20MW20

      MW21MW21

      MW22MW22

      MW23MW23

      MW24MW24

      MW25MW25

      MW26MW26

      WWAA

      LLSSHHSSTT

      SSMMIITTHH SSTTRREEEETT

      4

      466

      PPOORR

      TT RROO

      AADD

      PPOORR

      TT RROO

      AADD

      RRANDOLPH S

      ANDOLPH STREETTREET 4455

      DE

      DEW

      SW

      STREET

      TREET

      JJAM

      EA

      MES S

      S STREET

      TREET

      HHOO

      LLLLAANN

      DD SSTT

      RREEEETT

      CCAAWW

      TTHHOO

      RRNN

      EE SSTTRR

      EEEETT 4477

      DDOOVVEE SSTTRREEEETT

      4455

      4488

      LLIIVVEESSTTRR

      OONN

      GGPPAATTHH

      WWAAYY

      4455

      LIGHT TERRLIGHT TERRAACECE

      AD

      MELLA

      SA

      DM

      ELLA STR

      EETTR

      EET

      4466

      CHAPEL SCHAPEL STREETTREET

      4477 AA

      LLBBEERR

      TT SSTTRREEEETT

      4499

      GR4466 OUND

      FLOW DIREW

      GEGEORORGE SGE STREETTREET ATER C

      4488 TION

      PPOORRTT RROOAADD PPOORRTT RROOAADD 55

      00 DD

      EEWW SSTTRR

      EEEETT 4499

      MMAARRIIAA SSTTRREEEETT

      4477

      5500

      JJAAMM

      EESS CCOO

      NNGG

      DDOO

      NN DD

      RRIIVV

      EE

      88 44

      KKIINNTTOORREE SSTTRREEEETT

      KKIINNTTOORREE SSTTRREEEETT

      PPAARR

      KKEERR

      SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

      5500

      4499

      DDEEVVOONN SSTTRREEEETT

      FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

      Groundwater SWL MMWW88 Monitoring Well (m AHD)

      MW1 5011 MW2MW244

      MW02 4786

      MW3 484

      MW2MW255 MW4 507

      MW5 4833

      MW6 4794

      MW7 4703

      MW8 4581

      MW9 4728

      MW10 4871

      MW11 4785 MW2MW222

      MW12 4689

      MW13 4662

      MW2MW233 MW14 4723

      MW15 464

      MW16 4577

      MW17 4619

      MW18 4538

      MW19 4735

      MW20 457

      MW21 4531

      MW22 4501

      MW23 4497

      MW24 4537

      MW25 4469

      MW26 4918

      MW19MW19 MW2MW200

      MW2MW211MW18MW18

      MW17MW17

      MW14MW14

      MW15MW15

      MW16MW16

      MW10MW10 LEGEND MMWW1111

      GROUNDWATER MONITORING WELLMW12MW12

      50 INFERRED GROUNDWATER ELEVATION CONTOUR

      MW13MW13

      MW0MW022 INFERRED GROUNDWATER FLOW DIRECTION

      EPA ASSESSMENT AREA

      MW9MW9

      MW5MW5 CADASTREMMWW66 MW4MW4

      MW7MW7 Note This is one interpretation only Other interpretations possibleMW3MW3

      12500 A3

      0 25 50 m

      CLIENT

      SA EPA

      PROJECT

      EPA THEBARTON ASSESSMENT AREA - STAGE 1

      TITLE

      FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

      PROJECT NO DATE CREATED

      80607-1 290917

      MW1MW1 MW2MW266

      80607_Fig 4 - Groundwater Elevation Contour Planai REV 1 gt 290917

      LE

      VE

      L 1

      12

      4 S

      OU

      TH

      TE

      RR

      AC

      E

      AD

      EL

      AID

      E S

      A 5

      00

      0

      PH

      (0

      8)

      82

      32

      90

      88

      F

      AX

      (0

      8)

      82

      32

      90

      99

      E

      MA

      IL

      info

      fy

      fec

      om

      au

      W

      EB

      fy

      fec

      om

      au

      A

      BN

      5

      7 0

      08

      116

      13

      0

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      DEW

      STREET

      DEW

      STREET

      CHAPEL STREETCHAPEL STREET

      PAR

      KER

      STREET

      PAR

      KER

      STREET

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      LIGHT TERRACELIGHT TERRACE

      DEW

      STREET

      DEW

      STREET

      WA

      LSH ST

      WA

      LSH ST

      AD

      MELLA

      STREET

      AD

      MELLA

      STREET

      ALB

      ERT STR

      EETA

      LBER

      T STREET

      HO

      LLAN

      D ST

      REET

      HO

      LLAN

      D ST

      REET

      RANDOLPH STREET

      RANDOLPH STREET

      JAM

      ES STREET

      JAM

      ES STREET

      DOVE STREET

      DOVE STREET

      SMITH STREETSMITH STREET

      MARIA STREETMARIA STREET

      GEORGE STREETGEORGE STREET

      KINTORE STREET

      KINTORE STREET

      PORT ROAD

      PORT ROAD

      PORT ROAD

      PORT ROAD

      CAW

      THO

      RN

      E STR

      EETC

      AWTH

      OR

      NE ST

      REET

      DEVON STREETDEVON STREET

      KINTORE STREETKINTORE STREET

      GOODENOUGH STREETGOODENOUGH STREET

      LIVESTR

      ON

      G PATH

      WAY

      LIVESTR

      ON

      G PATH

      WAY

      MW1MW1

      MW02MW02

      MW3MW3

      MW4MW4

      MW5MW5

      MW6MW6

      MW7MW7

      MW8MW8

      MW9MW9

      MW10MW10MW11MW11

      MW12MW12

      MW13MW13

      MW14MW14

      MW15MW15

      MW16MW16

      MW17MW17

      MW18MW18

      MW19MW19MW20MW20

      MW21MW21

      MW22MW22

      MW23MW23

      MW24MW24

      MW25MW25

      MW26MW26

      WWAA

      LLSSHHSSTT

      SSMMIITTHH SSTTRREEEETT

      ndnd

      RRANDOLPH S

      ANDOLPH STREETTREET

      PPOORR

      TTRR

      OOAA

      DD

      PPOORR

      TTRR

      OOAA

      DD

      JJAM

      EA

      MES S

      S STREET

      TREET

      HHOO

      LLLLAANN

      DDSSTT

      RREEEETT

      CCAAWW

      TTHHOO

      RRNN

      EESSTT

      RREEEETT

      DE

      DEW

      SW

      STREET

      TREET

      DDOOVVEE SSTTRREEEETT

      LLIIVVEESSTTRR

      OONN

      GGPPAATTHH

      WWAAYY

      LIGHT TERRLIGHT TERRAACECE

      AD

      MELLA

      SA

      DM

      ELLA STR

      EETTR

      EET

      AALLBB

      EERRTT SSTTRR

      EEEETT

      CHAPEL SCHAPEL STREETTREET

      ndnd ndnd

      100100

      11000000

      GEGEORORGE SGE STREETTREET

      1010000000

      PPOORRTT RROOAADD PPOORRTT RROOAADD

      DDEEWW

      SSTTRREEEETT

      1010000000 11000000 MMAARRIIAA SSTTRREEEETT

      100100

      JJAAMM

      EESSCC

      OONN

      GGDD

      OONN

      DDRR

      IIVVEE

      KKIINNTTOORREE SSTTRREEEETT ndnd

      KKIINNTTOORREE SSTTRREEEETT

      PPAARR

      KKEERR

      SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

      DDEEVVOONN SSTTRREEEETT

      FIGURE 5 GROUNDWATER CONCENTRATION PLAN

      MW2MW244

      MMWW88 TCE lt1

      PCE lt1

      11-DCE lt1TCE lt1

      12-DCE lt1PCE lt1

      11-DCE lt1MW2MW255 12-DCE lt1

      TCE 2

      PCE lt1

      11-DCE lt1

      12-DCE lt1

      MW2MW222 TCE lt1

      PCE lt1

      11-DCE lt1MW2MW233 12-DCE lt1

      TCE 21

      PCE lt1

      11-DCE lt1

      12-DCE lt1

      MW19MW19 TCE lt1

      MW2MW200 TCE 70 PCE lt1MW2MW211 PCE lt1MW18MW18 11-DCE lt1

      TCE 23 11-DCE lt1TCE 5 12-DCE lt1 PCE lt1 12-DCE lt1PCE lt1 11-DCE lt1

      11-DCE lt1 12-DCE lt1

      12-DCE lt1

      MW17MW17 LEGENDTCE 24 MW14MW14

      PCE lt1 TCE 1100 lt1 MW15MW15 GROUNDWATER MONITORING WELL11-DCE PCE lt1

      12-DCE lt1 TCE 180 11-DCE 2MW16MW16 100 INFERRED TCE GROUNDWATERPCE lt1 12-DCE 4 CONCENTRATION CONTOURSTCE lt1 11-DCE lt1 PCE lt1 12-DCE lt1 11-DCE lt1

      12-DCE lt1 MMWW1111

      EPA ASSESSMENT AREAMW10MW10

      TCE lt1 CADASTREMW12MW12 TCE lt14900 PCE

      lt1 11-DCE lt1TCE 700 PCEMW13MW13 12-DCE lt1 TCE CONCENTRATIONS (μgL)lt1 11-DCE 7PCE

      TCE lt1 lt1 12-DCE 511-DCE gtnd to lt100 100 to lt1000 1000 to lt10000

      MW0MW022PCE lt1 12-DCE lt1 2100011-DCE lt1 MW9MW9 TCE

      PCE lt112-DCE lt1 TCE 2(D) 11-DCE 15PCE lt1 MW5MW5

      10000 to 29000

      nd = non-detect (lt1)12-DCE 4511-DCE lt1 MMWW66 TCE 29000 MW4MW4 12-DCE lt1

      PCE 3 TCE lt1 NotesTCE 29 11-DCE 6MW7MW7 PCE lt1PCE lt1 This is one interpretation only Other interpretations possible12-DCE 23TCE lt1 11-DCE lt111-DCE lt1 All concentrations are in μgL

      12-DCE includes cis and trans PCE lt1 MW3MW3 12-DCE lt112-DCE lt1 11-DCE lt1

      TCE 69 D = Duplicate result12-DCE lt1 PCE lt1

      11-DCE lt1

      12-DCE lt1 MW1MW1

      12500 A3MW2MW266 TCE lt1

      TCE 2 PCE lt1

      PCE lt1 11-DCE lt1

      11-DCE lt1 12-DCE lt1

      12-DCE lt1

      LE

      VE

      L 1

      12

      4 S

      OU

      TH

      TE

      RR

      AC

      E

      AD

      EL

      AID

      E S

      A 5

      00

      0

      PH

      (0

      8)

      82

      32

      90

      88

      F

      AX

      (0

      8)

      82

      32

      90

      99

      E

      MA

      IL

      info

      fy

      fec

      om

      au

      W

      EB

      fy

      fec

      om

      au

      A

      BN

      5

      7 0

      08

      116

      13

      0

      0 25 50 m

      CLIENT

      SA EPA

      PROJECT

      EPA THEBARTON ASSESSMENT AREA - STAGE 1

      TITLE

      FIGURE 5 GROUNDWATER CONCENTRATION PLAN

      PROJECT NO DATE CREATED

      80607-1 280917

      80607_Fig 5 - Groundwater TCE Concentration Plan r2ai REV 2 gt 280917

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      DEW

      STREET

      DEW

      STREET

      CHAPEL STREETCHAPEL STREET

      PAR

      KER

      STREET

      PAR

      KER

      STREET

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      LIGHT TERRACELIGHT TERRACE

      DEW

      STREET

      DEW

      STREET

      WA

      LSH ST

      WA

      LSH ST

      AD

      MELLA

      STREET

      AD

      MELLA

      STREET

      ALB

      ERT STR

      EETA

      LBER

      T STREET

      HO

      LLAN

      D ST

      REET

      HO

      LLAN

      D ST

      REET

      RANDOLPH STREET

      RANDOLPH STREET

      JAM

      ES STREET

      JAM

      ES STREET

      DOVE STREET

      DOVE STREET

      SMITH STREETSMITH STREET

      MARIA STREETMARIA STREET

      GEORGE STREETGEORGE STREET

      KINTORE STREET

      KINTORE STREET

      PORT ROAD

      PORT ROAD

      PORT ROAD

      PORT ROAD

      CAW

      THO

      RN

      E STR

      EETC

      AWTH

      OR

      NE ST

      REET

      DEVON STREETDEVON STREET

      KINTORE STREETKINTORE STREET

      GOODENOUGH STREETGOODENOUGH STREET

      LIVESTR

      ON

      G PATH

      WAY

      LIVESTR

      ON

      G PATH

      WAY

      SV1SV1

      SV2SV2SV3SV3SV4SV4

      SV5SV5

      SV7SV7SV8SV8

      SV9SV9

      SV10SV10

      SV11SV11SV12SV12

      SV13SV13

      SV6SV6

      WWAA

      LLSSHHSSTT

      SSMMIITTHH SSTTRREEEETT

      RRANDOLPH S

      ANDOLPH STREETTREET

      PPOORR

      TTRR

      OOAA

      DD

      PPOORR

      TTRR

      OOAA

      DD

      CCAAWW

      TTHHOO

      RRNN

      EESSTT

      RREEEETT

      HHOO

      LLLLAANN

      DDSSTT

      RREEEETT

      JJAM

      EA

      MES S

      S STREET

      TREET

      DE

      DEW

      SW

      STREET

      TREET

      DDOOVVEE SSTTRREEEETT

      00

      LLIIVVEESSTTRR

      OONN

      GGPPAATTHH

      WWAAYY

      LIGHT TERRLIGHT TERRAACECE

      AD

      MELLA

      SA

      DM

      ELLA STR

      EETTR

      EET

      CHAPEL SCHAPEL STREETTREET

      00

      AALLBB

      EERRTT SSTTRR

      EEEETT

      1010

      GEGEORORGE SGE STREETTREET

      000000

      PPOORRTT RROOAADD

      100100000

      000

      1010

      PPOORRTT RROOAADD

      000000

      DDEEWW

      SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

      JJAAMM

      EESSCC

      OONN

      GGDD

      OONN

      DDRR

      IIVVEE

      KKIINNTTOORREE SSTTRREEEETT 00

      KKIINNTTOORREE SSTTRREEEETT

      PPAARR

      KKEERR

      SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

      DDEEVVOONN SSTTRREEEETT

      FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

      SSVV1111 SSV12V12 TCE lt18

      SSVV1133 TCE 16

      PCE lt54 TCE lt21

      11-DCE lt29 PCE lt25

      12-DCE lt39 11-DCE lt14

      12-DCE lt18

      PCE lt22

      11-DCE lt12

      12-DCE lt16

      TCE 170

      PCE lt54

      11-DCE lt3

      12-DCE lt39 LEGEND SSVV99

      SSV10V10 SOIL VAPOUR BORE

      TCE lt21 0 INFERRED TCE SOIL VAPOUR CONTOUR PCE lt25

      TCE 2200011-DCE lt14 EPA ASSESSMENT AREA

      PCE 1912-DCE lt18

      11-DCE lt27 CADASTRE

      12-DCE lt37 SVSV66SVSV77

      SSVV88 TCE 22000

      TCE 2300 PCE 12 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)TCE 100000 PCE 62 11-DCE lt29PCE 84 0 to lt10000SSVV55lt2711-DCE 12-DCE lt2911-DCE lt33 10000 to lt100000

      100000 to 210000 12-DCE lt36 12-DCE lt44

      TCE 17000 SVSV44 SVSV22SVSV33 NotePCE 31 TCE 51000TCE 210000 This is one interpretation only Other interpretations possible11-DCE lt14 PCE 39PCE 650012-DCE lt18 39 Estimated extent of plume has utilised groundwater11-DCE11-DCE 5900 12-DCE 21 concentration data12-DCE lt71

      SVSV11 All concentrations are in (μgmsup3)

      TCE 6300(LD) 12-DCE includes cis and trans PCE 78 LD = Laboratory duplicate result 11-DCE lt29

      12-DCE lt38

      12500 A3

      0 25 50 m

      CLIENT

      SA EPA

      PROJECT

      EPA THEBARTON ASSESSMENT AREA - STAGE 1

      TITLE

      FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

      PROJECT NO DATE CREATED

      80607-1 290917

      80607_Fig 6 - Soil Vapour TCE Concentration Plan - 1mai REV 2 gt 290917

      LE

      VE

      L 1

      12

      4 S

      OU

      TH

      TE

      RR

      AC

      E

      AD

      EL

      AID

      E S

      A 5

      00

      0

      PH

      (0

      8)

      82

      32

      90

      88

      F

      AX

      (0

      8)

      82

      32

      90

      99

      E

      MA

      IL

      info

      fy

      fec

      om

      au

      W

      EB

      fy

      fec

      om

      au

      A

      BN

      5

      7 0

      08

      116

      13

      0

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      JAM

      ES CO

      NG

      DO

      N D

      RIV

      E

      DEW

      STREET

      DEW

      STREET

      CHAPEL STREETCHAPEL STREET

      PAR

      KER

      STREET

      PAR

      KER

      STREET

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      POR

      T RO

      AD

      LIGHT TERRACELIGHT TERRACE

      DEW

      STREET

      DEW

      STREET

      WA

      LSH ST

      WA

      LSH ST

      AD

      MELLA

      STREET

      AD

      MELLA

      STREET

      ALB

      ERT STR

      EETA

      LBER

      T STREET

      HO

      LLAN

      D ST

      REET

      HO

      LLAN

      D ST

      REET

      RANDOLPH STREET

      RANDOLPH STREET

      JAM

      ES STREET

      JAM

      ES STREET

      DOVE STREET

      DOVE STREET

      SMITH STREETSMITH STREET

      MARIA STREETMARIA STREET

      GEORGE STREETGEORGE STREET

      KINTORE STREET

      KINTORE STREET

      PORT ROAD

      PORT ROAD

      PORT ROAD

      PORT ROAD

      CAW

      THO

      RN

      E STR

      EETC

      AWTH

      OR

      NE ST

      REET

      DEVON STREETDEVON STREET

      KINTORE STREETKINTORE STREET

      GOODENOUGH STREETGOODENOUGH STREET

      LIVESTR

      ON

      G PATH

      WAY

      LIVESTR

      ON

      G PATH

      WAY

      SV1SV1

      SV2SV2SV3SV3SV4SV4

      SV5SV5

      SV7SV7SV8SV8

      SV9SV9

      SV10SV10

      SV12SV12

      SV6SV6

      WWAA

      LLSSHHSSTT

      SSMMIITTHH SSTTRREEEETT

      RRANDOLPH S

      ANDOLPH STREETTREET

      PPOORR

      TTRR

      OOAA

      DD

      PPOORR

      TTRR

      OOAA

      DD

      CCAAWW

      TTHHOO

      RRNN

      EESSTT

      RREEEETT

      HHOO

      LLLLAANN

      DDSSTT

      RREEEETT

      DE

      DEW

      SW

      STREET

      TREET

      JJAM

      EA

      MES S

      S STREET

      TREET

      DDOOVVEE SSTTRREEEETT

      00

      LIGHT TERRLIGHT TERRAACECE

      LLIIVVEESSTTRR

      OONN

      GGPPAATTHH

      WWAAYY

      AD

      MELLA

      SA

      DM

      ELLA STR

      EETTR

      EET

      CHAPEL SCHAPEL STREETTREET

      00

      1010000000

      AALLBB

      EERRTT SSTTRR

      EEEETT

      100100 000

      000 GEGEORORGE SGE STREETTREET

      PPOORRTT RROOAADD 11000000000

      000 PPOORRTT RROOAADD

      DDEEWW

      SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

      100100000000

      JJAAMM

      EESSCC

      OONN

      GGDD

      OONN

      DDRR

      IIVVEE

      1010000000

      KKIINNTTOORREE SSTTRREEEETT

      00

      KKIINNTTOORREE SSTTRREEEETT

      PPAARR

      KKEERR

      SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

      DDEEVVOONN SSTTRREEEETT

      FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

      SSV12V12 TCE 55

      PCE lt45

      11-DCE lt24

      12-DCE lt32

      TCE 260

      PCE lt51

      11-DCE lt28

      12-DCE

      SSVV99

      lt37 LEGEND

      SSV10V10 SOIL VAPOUR BORE

      TCE 51 0 INFERRED TCE SOIL VAPOUR CONTOURPCE lt53

      TCE 11000011-DCE lt29

      EPA ASSESSMENT AREAPCE lt13012-DCE lt39

      11-DCE lt69

      CADASTRE12-DCE lt92 SVSV66SVSV77

      SSVV88 TCE 150000

      TCE 14000 56 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)PCETCE 160000 PCE 19 11-DCE lt30PCE 310 0 to lt10000SSVV5511-DCE lt26 12-DCE lt3911-DCE 33 10000 to lt100000

      100000 to lt1000000 1000000

      12-DCE lt35 12-DCE 20

      TCE 43000 SVSV44 SVSV22SVSV33 NotePCE 90 TCE 940000(FD)TCE 1000000 This is one interpretation only Other interpretations possible11-DCE lt15 PCE 15000PCE 1500012-DCE 30 14000 Estimated extent of plume has utilised groundwater11-DCE11-DCE 14000 12-DCE lt930 concentration data12-DCE lt930

      All concentrations are in (μgmsup3) 12-DCE includes cis and trans

      SVSV11 TCE 21000

      FD = Field Duplicate resultPCE 21

      11-DCE lt57

      12-DCE lt76

      12500 A3

      0 25 50 m

      CLIENT

      SA EPA

      PROJECT

      EPA THEBARTON ASSESSMENT AREA - STAGE 1

      TITLE

      FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

      PROJECT NO DATE CREATED

      80607-1 290917

      80607_Fig 7 - Soil Vapour TCE Concentration Plan - 3m r2ai REV 2 gt 290917

      LE

      VE

      L 1

      12

      4 S

      OU

      TH

      TE

      RR

      AC

      E

      AD

      EL

      AID

      E S

      A 5

      00

      0

      PH

      (0

      8)

      82

      32

      90

      88

      F

      AX

      (0

      8)

      82

      32

      90

      99

      E

      MA

      IL

      info

      fy

      fec

      om

      au

      W

      EB

      fy

      fec

      om

      au

      A

      BN

      5

      7 0

      08

      116

      13

      0

      • THEBARTON ASSESSMENT AREA STAGE 1 ENVIRONMENTAL ASSESSMENT FINAL REPORT | EPA REF 0524111 30 OCTOBER 2017 VOLUME 1 REPORT13
      • This report is formatted to print Double Sided
      • TITLE PAGE13
      • CONTENTS13
      • LIST OF ACRONYMS13
      • EXECUTIVE SUMMARY13
      • 1 INTRODUCTION
        • 11 Purpose
        • 12 General background information
        • 13 Definition of the assessment area
        • 14 Identification of contaminants of potential concern
        • 15 Objectives
          • 2 CHARACTERISATION OF THE ASSESSMENT AREA
            • 21 Site identification
            • 22 Regional geology and hydrogeology
            • 23 Data quality objectives
              • 3 SCOPE OF WORK
                • 31 Preliminary work
                • 32 Field investigation and laboratory analysis program
                • 33 Data interpretation
                  • 4 METHODOLOGY
                    • 41 Field methodologies
                    • 42 Laboratory analysis
                      • 5 QUALITY ASSURANCE AND QUALITY CONTROL
                        • 51 Field QAQC
                        • 52 Laboratory QAQC
                        • 53 QAQC summary
                          • 6 ASSESSMENT CRITERIA
                            • 61 Groundwater
                            • 62 Soil vapour
                              • 7 RESULTS
                                • 71 Surface and sub surface soil conditions
                                • 72 Waterloo Membrane Samplerstrade
                                • 73 Groundwater
                                • 74 Soil vapour bores
                                  • 8 GROUNDWATER FATE AND TRANSPORT MODELLING
                                    • 81 Groundwater flow modelling
                                    • 82 Solute transport modelling
                                      • 9 VAPOUR INTRUSION RISK ASSESSMENT
                                        • 91 Objective
                                        • 92 Areas of interest
                                        • 93 Risk assessment approach
                                        • 94 Tier 1 assessment
                                        • 95 Tier 2 assessment
                                        • 96 Conclusions
                                          • 10 CONCEPTUAL SITE MODEL
                                          • 11 CONCLUSIONS
                                          • 12 DATA GAPS
                                          • 13 REFERENCES
                                          • 14 STATEMENT OF LIMITATIONS
                                          • FIGURES13
                                          • FIGURE 1 SITE LOCATION AND ASSESSMENT AREA
                                          • FIGURE 2 ASSESSMENT POINT LOCATIONS
                                          • FIGURE 3 WATERLOO MEMBRANE SAMPLERTM TCE CONCENTRATION PLAN13
                                          • FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN
                                          • FIGURE 5 GROUNDWATER CONCENTRATION PLAN
                                          • FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)
                                          • FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        CONTENTS

        Page

        VOLUME 1 REPORT

        LIST OF ACRONYMS V

        EXECUTIVE SUMMARY VIII

        1 INTRODUCTION 1

        11 Purpose 1

        12 General background information 1

        13 Definition of the assessment area 2

        14 Identification of contaminants of potential concern 2

        15 Objectives 3

        2 CHARACTERISATION OF THE ASSESSMENT AREA 5

        21 Site identification 5

        22 Regional geology and hydrogeology 5

        23 Data quality objectives 7

        3 SCOPE OF WORK 11

        31 Preliminary work 12

        32 Field investigation and laboratory analysis program 12

        33 Data interpretation 14

        4 METHODOLOGY 15

        41 Field methodologies 15

        42 Laboratory analysis 19

        5 QUALITY ASSURANCE AND QUALITY CONTROL 21

        51 Field QAQC 21

        52 Laboratory QAQC 24

        53 QAQC summary 26

        80607-1 REV1 30102017 PAGE I

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        6 ASSESSMENT CRITERIA 27

        61 Groundwater 27

        62 Soil vapour 29

        7 RESULTS 31

        71 Surface and sub surface soil conditions 31

        72 Waterloo Membrane Samplerstrade 32

        73 Groundwater 34

        74 Soil vapour bores 40

        8 GROUNDWATER FATE AND TRANSPORT MODELLING 43

        81 Groundwater flow modelling 43

        82 Solute transport modelling 43

        9 VAPOUR INTRUSION RISK ASSESSMENT 47

        91 Objective 47

        92 Areas of interest 47

        93 Risk assessment approach 47

        94 Tier 1 assessment 48

        95 Tier 2 assessment 49

        96 Conclusions 59

        10 CONCEPTUAL SITE MODEL 61

        11 CONCLUSIONS 67

        12 DATA GAPS 71

        13 REFERENCES 73

        14 STATEMENT OF LIMITATIONS 77

        PAGE II 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        LIST OF TABLES

        Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area 7

        Table 22 Data Quality Objectives 8 Table 31 Scope of field investigation program ndash May to August 2017 12 Table 32 Scope of laboratory testing program 13 Table 41 Summary of field methodologies 15 Table 51 Field QAQC procedures ndash Groundwater 22 Table 52 Field QAQC procedures ndash Soil vapour 23 Table 53 Laboratory QAQC procedures 25 Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area 28 Table 62 Sources of adopted groundwater assessment criteria 29 Table 71 Detectable Waterloo Membrane Samplertrade CHC results 32 Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units 33 Table 73 Hydraulic conductivities (rising and falling head tests) 35 Table 74 Detectable groundwater CHC results 37 Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area 41 Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores 42 Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs 49 Table 92 Tier 2 vapour intrusion modelling ndash building input parameters 51 Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters 52 Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air 52 Table 95 Summary of chemical parameters adopted for vapour intrusion modelling 52 Table 96 Comparison of predicted residential indoor air concentrations with SA EPA

        response levels 54 Table 97 Summary of model input parameters subjected to sensitivity analysis 55 Table 98 Exposure parameters ndash Commercialindustrial workers 58 Table 99 Adopted inhalation toxicity reference values 58 Table 910 Summary of properties with predicted indoor air concentrations

        (residential crawl space) above adopted EPA response levels 59 Table 101 Summary of existing information for the Thebarton EPA Assessment Area 61

        LIST OF FIGURES (in text)

        Figure 71 Piper diagram 39 Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green)

        relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple) 46

        Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels 50

        80607-1 REV1 30102017 PAGE III

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        FIGURES follow page 79

        Figure 1 Site Location and Assessment Area Figure 2 Assessment Point Locations Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan Figure 4 Groundwater Elevation Contour Plan Figure 5 Groundwater Concentration Plan Figure 6 Soil Vapour Concentration Plan (10 m) Figure 7 Soil Vapour Concentration Plan (30 m)

        VOLUME 2 APPENDICES

        APPENDICES

        Appendix A Historical Report Summary Appendix B Historical Information Supplied by the EPA Appendix C DEWNR Registered Groundwater Database Search Results Appendix D Groundwater Well Permits Appendix E Field Sampling Sheets ndash Groundwater Appendix F Survey Data Appendix G Certified Laboratory Certificates and Chain of Custody Documentation Appendix H Groundwater Well Log Reports Appendix I WMStrade Borehole Log Reports Appendix J Soil Vapour Borehole Log Reports Appendix K Waste Transport Certificates Appendix L Tabulated Results ndash Soil Vapour Geotechnical and Groundwater Appendix M Equipment Calibration Records Appendix N Drill Core Photographs Appendix O Arcadis Groundwater Fate and Transport Modelling Report Appendix P Arcadis Vapour Intrusion Risk Assessment Report

        PAGE IV 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        LIST OF ACRONYMS

        AER Air Exchange Rate

        AF Attenuation Factor

        AHD Australian Height Datum

        ANZECC Australian and New Zealand Environment and Conservation Council

        ARMCANZ Agriculture and Resource Management Council of Australia and New Zealand

        ASC Assessment of Site Contamination

        ASTM American Standard Testing Material

        AT Averaging Time

        ATSDR Agency for Toxic Substances and Disease Registry

        AWQC Australian Water Quality Centre

        BGL Below Ground Level

        BTEX Benzene Toluene Ethylbenzene Xylenes

        BTOC Below Top of Casing

        BUA Beneficial Use Assessment

        CBD Central Business District

        CHC Chlorinated Hydrocarbon Compound

        COC Chain of Custody

        COPC Contaminants of Potential Concern

        CRC CARE Cooperative Research Centre for Contamination Assessment and Remediation of the Environment

        CSM Conceptual Site Model

        11-DCA 11-dichloroethane

        11-DCE 11-dichloroethene

        12-DCE 12-dichloroethene

        DCE Dichloroethene

        DEC Department of Environment and Conservation

        DEWNR Department of Environment Water and Natural Resources

        DNAPL Dense Non-Aqueous Phase Liquid

        DO Dissolved Oxygen

        DQI Data Quality Indicator

        DQO Data Quality Objective

        EC Electrical Conductivity

        ED Exposure Duration

        80607-1 REV1 30102017 PAGE V

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        EF Exposure Frequency

        EMP Environmental Management Plan

        EPA Environment Protection Authority

        EPC Exposure Point Concentration

        EPP Environment Protection Policy

        ET Exposure Time

        GPA Groundwater Prohibition Area

        GPR Ground Penetrating Radar

        GPS Global Positioning System

        HHRA Human Health Risk Assessment

        HIL Health Investigation Level

        HSP Health and safety Plan

        IPA Isopropyl Alcohol (isopropanol or 2-propanol)

        IRIS Integrated Risk Information System

        ITRC Interstate Technology and Regulatory Council

        JampE Johnson and Ettinger

        JHA Job Hazard Analysis

        LNAPL Light Non-Aqueous Phase Liquid

        LOR Limit of Reporting

        MGA Map Grid of Australia

        MQO Measuring Quality Objectives

        MTC Mass Transfer Co-efficient

        NA Not Applicable

        NAPL Non-Aqueous Phase Liquid

        NATA National Association of Testing Authorities

        ND Non Detect

        NEPM National Environment Protection Measure

        NHMRC National Health and Medical Research Council

        NJDEP New Jersey Department of Environmental Protection

        NRMMC National Resource Management Ministerial Council

        PAH Polycyclic Aromatic Hydrocarbons

        PCE Tetrachloroethene (perchloroethylene)

        PID Photoionisation Detector

        PQL Practical Quantification Limit

        PSD Particle Size Distribution

        QA Quality Assurance

        80607-1 REV1 30102017 PAGE VI

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        QC Quality Control

        RAIS Risk Assessment Information System

        RFQ Request for Quote

        REM Resource and Environmental Management

        RPD Relative Percentage Difference

        RSL Regional Screening Level

        SA EPA South Australian Environment Protection Authority

        SAQP Sampling and Analysis Quality Plan

        SOP Standard Operating Procedure

        SVOC Semi-Volatile Organic Compound

        SWL Standing Water Level

        SWMS Safe Work Method Statement

        111-TCA 111-trichloroethane

        TCE Trichloroethene

        TDS Total Dissolved Solids

        TRH Total Recoverable Hydrocarbons1

        TRV Toxicity Reference Value

        US EPA United Stated Environment Protection Agency

        USGS United States Geological Survey

        VC Vinyl Chloride

        VIRA Vapour Intrusion Risk Assessment

        VOC Volatile Organic Compound

        VOCC Volatile Organic Chlorinated Compound

        WHO World Health Organisation

        WMStrade Waterloo Membrane Samplertrade

        TRH = measurable amount of petroleum-based hydrocarbon (ie complex mixture of crude oil and natural gas (gt 250 compounds) including aromatics aliphatics paraffins unsaturated alkanes and naphthalenes) plus various other compounds including fatty acids esters humic acids phthalates and sterols

        80607-1 REV1 30102017 PAGE VII

        1

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        EXECUTIVE SUMMARY

        Background information

        An approximate 27 hectare mixed use area of Thebarton has been designated by the South Australian Environment Protection Authority (EPA) as the Thebarton EPA Assessment Area

        The former Austral sheet metal works (Austral) property located over multiple allotments between George and Maria Streets from the 1920s until the 1960s-1970s has been identified as a possible source of dissolved phase groundwater chlorinated hydrocarbon (CHC) contamination Groundwater CHC impacts within the uppermost (Quaternary ndash Q1) aquifer were identified as extending in a general north-westerly direction (consistent with regional groundwater flow direction) from the south-eastern portion of the Thebarton EPA Assessment Area and having resulted in the generation of soil vapour containing elevated concentrations of CHC

        The boundaries of the Thebarton EPA Assessment Area were established on the basis of the following

        the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street (part of the former Austral property) and 39 Smith Street (hydraulically down-gradient of the former Austral property) in Thebarton

        the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

        the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

        Key objectives

        The results of the recent investigations undertaken by Fyfe have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties within the Thebarton EPA Assessment Area

        The key objectives detailed by the EPA were to

        further delineate the chlorinated hydrocarbon contamination in groundwater

        further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

        undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

        80607-1 REV1 30102017 PAGE VIII

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        With respect to the VIRA the EPA requested that there be specific consideration of

        residential properties (slab on grade)

        residential properties (crawl space)

        residential properties (with basement) and

        trenchmaintenanceutility workers that may be working in the vicinity of the contamination

        Site conditions

        Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were identified within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m below ground level (BGL) during the drilling of groundwater well MW17 the latter consistent with the depth of groundwater within the Q1 aquifer

        Soil

        Groundwater within the Q1 aquifer is located at a depth of approximately 123 to Groundwater 159 m BGL and flows in a general north-westerly direction The closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred and the groundwater gradient is relatively flat (ie 000062 to 00012)

        Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified (based on factors such a groundwater salinity registered bore use and the locations of potential sensitive receptors) as including domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux) and possibly also potable

        Contaminants of Potential Concern (COPC)

        The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans-) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

        80607-1 REV1 30102017 PAGE IX

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Scope of work

        A groundwater and soil vapour monitoring program was undertaken by Fyfe across the Thebarton EPA Assessment Area between May and August 2017 It involved the following scope of work

        installation of a total of 41 WMStrade units to 1 m BGL in an approximate grid-pattern across the entire assessment area (Round 1) and at specific targeted locations (Round 2) followed by laboratory analysis of retrieved sample units for specific CHC

        drilling and installation of 25 groundwater wells to depths of between 15 and 19 m BGL including a background well to the east of the southern portion of the assessment area

        testing of 30 selected groundwater well drill core samples for geotechnical parameters

        gauging and sampling of the 25 newly installed groundwater wells as well as an existing well located in Admella Street followed by laboratory analysis of all samples for specific CHC and 10 selected samples for major cationsanions natural attenuation parameters and additional nutrients

        aquifer permeability (rising and falling head ldquoslugrdquo) testing of 10 groundwater wells

        drilling and installation of 13 soil vapour bores including 11 nested bores (ie to 1 and 3 m BGL) and two bores to 1 m BGL and

        sampling of all soil vapour bores followed by laboratory analysis of samples for specific CHC and general gases

        The soil vapour data were used to undertake a VIRA aimed at predicting indoor air concentrations of TCE under various land use and building construction scenarios In order to validate the results of the modelling which includes a number of conservative assumptions and is therefore expected to over-estimate potential risk the EPA has commissioned indoor air monitoring in a number of residential properties within the Thebarton EPA Assessment Area ndash the indoor air monitoring results will be reported under separate cover

        Groundwater fate and transport modelling was undertaken to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton EPA Assessment Area The provision of this information is aimed at supporting the definition (extent and geometry) of a potential future Groundwater Prohibition Area (GPA) to be designated by the EPA in accordance with the provisions of Section S103S of the Environment Protection Act 1993

        80607-1 REV1 30102017 PAGE X

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Identified impacts

        Contaminants identified in the Q1 aquifer beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down

        Groundwater

        (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested

        The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected (Austral) source site in accordance with the predominant flow direction associated with the Q1 aquifer The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) ndash whereas its north-western extent has not yet been determined the groundwater CHC plume has been delineated in all other directions

        Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion

        Soil vapour

        The soil vapour samples with the maximum TCE concentrations also had the highest PCE and 11-DCE concentrations (or elevated laboratory limits of reporting (LOR)) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-)

        Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE exceeded the adopted health investigation levels (HILs) for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE degradation has not yet resulted in its production

        Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

        80607-1 REV1 30102017 PAGE XI

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Assessment of risk

        Measured concentrations of TCE exceeded the adopted assessment criteria for potable use andor primary contact recreation in wells located on Admella Maria George Albert Chapel and Dew Streets as well as Light Terrace ndash with the highest concentrations corresponding to the ldquocorerdquo area of the plume One well on Albert Street also contained a concentration of carbon tetrachloride that exceeded the respective potable criterion

        Groundwater risks

        Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous

        Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

        The groundwater modelling undertaken by Arcadis involved the development of an Groundwater fate and transport initial groundwater flow model using MODFLOW followed by the development of a modelling site-specific (three-dimensional) solute transport model using the MT3DMS transport

        code

        The results of this modelling were interpreted to indicate the following

        although scattered detectable concentrations of 12-DCE have been measured in groundwater across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE daughter products indicate that substantial dechlorination is not occurring and

        the dissolved phase groundwater TCE plume is predicted to extend by another 500 m (ie beyond the boundaries of the current Thebarton EPA Assessment Area) over the next 100 years whereas no significant lateral plume expansion is expected

        The VIRA undertaken by Arcadis involved a two-tier assessment approach Whereas Vapour intrusion the Tier 1 screening risk assessment compared the measured soil vapour CHC concentrations to (modified) guideline values the Tier 2 risk assessment involved the application of the Johnson and Ettinger vapour intrusion model to predict indoor air CHC concentrations for residential (slab on grade crawl space and basement construction) and commercialindustrial (slab on grade construction) properties across the assessment area Site-specific geotechnical parameters and soil vapour data collected from 1 and 3 m BGL throughout the Thebarton EPA Assessment Area were used in the modelling It should be noted that overall the vapour modelling

        risks

        80607-1 REV1 30102017 PAGE XII

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

        The results of the VIRA with respect to the predicted indoor air concentrations of TCE within residential properties (assuming crawl space construction) versus adopted EPA response levels indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air that require further action as follows

        10 properties within the investigation range (2 to lt20 microgm3)

        eight properties within the intervention range (20 to lt200 microgm3) and

        three properties within accelerated intervention range (ge200 microgm3)

        All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises

        Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which is expected to be overly-conservative) ndash these results will be documented in a subsequent report

        Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie as determined for the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

        A qualitative assessment of potential risks to subsurface trenchmaintenanceutility workers indicated that exposure management may be required in areas where TCE concentrations at 1 m BGL are above 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific health and safety plan (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a photoionisation detector (PID) unit providing increased ventilation and using appropriate personal protective equipment (eg gas masks) as required

        80607-1 REV1 30102017 PAGE XIII

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Data gaps

        Based on the results obtained during the recent Fyfe investigations as well as available historical information the following data gaps have been identified for the Thebarton EPA Assessment Area

        property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

        groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

        the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

        the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

        Notes ie the interim soil vapour HILs adopted from the National Environment (Assessment of Site Contamination) Measure 1999 (as revised in 2013 ndash ie the ASC NEPM (1999)) but assuming a sub-slab to indoor air attenuation factor of 003 as compared to the value of 01 adopted by the ASC NEPM (1999)

        80607-1 REV1 30102017 PAGE XIV

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        1 INTRODUCTION

        11 Purpose

        Fyfe Pty Ltd (Fyfe) was commissioned by the South Australian Environment Protection Authority (SA EPA referred to herein as the EPA) to undertake Stage 1 groundwater and soil vapour investigation works groundwater fate and transport modelling and a human health vapour intrusion risk assessment (VIRA) within an EPA designated assessment area located within Thebarton South Australia (herein referred to as the Thebarton EPA Assessment Area) The location and extent of the Thebarton EPA Assessment Area referenced within this document is identified on Figure 1

        12 General background information

        Previous environmental assessment work undertaken since 1994 (as summarised in Appendix A) combined with historical information provided by the EPA (as included in Appendix B) indicates that the Thebarton EPA Assessment Area has been used for mixed residential and commercialindustrial purposes over time

        Groundwater impacts2 identified within the uppermost (Quaternary ndash Q1) aquifer in the vicinity of the former Austral sheet metal works (Austral) on George Street included both petroleum hydrocarbons (ie diesel fuel) as well as chlorinated hydrocarbon compounds (CHC) such as trichloroethene (TCE) and were first notified to the EPA in 2006

        Available historical information for the Austral property (ie the suspected source site) indicates that it operated from the 1920s until the 1960s-1970s and occupied an extensive area of Thebarton including

        part of the southern side of George Street extending from about half way between East Terrace3 and Admella Street (ie 11-25 George Street) to the west of Admella Street (ie 31-35 George Street)

        the entire northern side of Maria Street from East Terrace to the west of Admella Street

        part of the southern side of Maria Street (ie from 21 Maria Street) to Admella Street and

        25-27 East Terrace

        2 Note that the term ldquoimpactrdquo has been used by Fyfe to indicate identified concentrations of compounds (specifically chlorinated hydrocarbons) that are not naturally occurring (ie concentrations above background that have resulted from anthropogenic activities) The use of this term does not denote that the presence of these compounds represents a risk to either human health or the environment and the term ldquoimpactrdquo is therefore not directly interchangeable with the term ldquoSite Contaminationrdquo the latter defined under the Environment Protection Act 1993 to include actual or potential harm to human health andor the environment

        3 now James Congdon Drive

        80607-1 REV1 30102017 PAGE 1

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Historical newspaper articles described the Austral property as hosting a factory that extended over more than three acres and included an electroplating facility In 1938 it was described as the largest aluminium utensil manufacturing company in the southern hemisphere

        Other potential sources of groundwater contamination4 identified within the Thebarton EPA Assessment Area include a former gas works (ie located to the south and south-east of the Austral property and including the current Ice Arena property) a mechanicrsquos workshop another sheet metal working facility and a farm machinery manufacturer

        The Stage 1 assessment work described herein was commissioned by the EPA to determine whether historical contamination in the vicinity of George Street was presenting a risk to human health or the environment

        13 Definition of the assessment area

        As detailed on Figure 1 the current EPA Assessment Area covers an area of approximately 27 ha within the suburb of Thebarton located approximately 2 km north-west of the Adelaide central business district (CBD)

        The boundaries of the Thebarton EPA Assessment Area were established by the EPA on the basis of the following

        the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street and 39 Smith Street in Thebarton (refer to Appendix A)

        the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

        the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

        14 Identification of contaminants of potential concern

        The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

        Site Contamination is defined by the Environment Protection Act 1993 as existing if chemical substances are present on or below the surface of a site in concentrations above background the contaminants are there as a result of activity at the site or elsewhere and their presence has resulted in actual or potential harm (that is not trivial) to the health and safety of human beings taking into account current and proposed land uses or water or the environment

        PAGE 2 80607-1 REV1 30102017

        4

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        15 Objectives

        As defined by the EPA the key objectives of the recent Stage 1 environmental assessment program undertaken within the Thebarton EPA Assessment Area (refer to Figure 1) were to

        further delineate the chlorinated hydrocarbon contamination in groundwater

        further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

        undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

        With respect to the VIRA the EPA requested that there be specific consideration of

        residential properties (slab on grade)

        residential properties (crawl space)

        residential properties (with basement) and

        trenchmaintenanceutility workers that may be working in the vicinity of the contamination

        80607-1 REV1 30102017 PAGE 3

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        2 CHARACTERISATION OF THE ASSESSMENT AREA

        21 Site identification

        For the purpose of this investigation program the Thebarton EPA Assessment Area (as delineated in Figure 1) has been defined by the following roadways

        North northern verge of Smith Street

        South Maria Street (between Dew Street and Albert Street) portion of Parker Street (between Maria Street and Goodenough Street) and Goodenough Street (between Parker Street and James Congdon Drive)

        East western verge of Port Road and James Congdon Drive and

        West western verge of Dew Street

        22 Regional geology and hydrogeology

        221 Geology

        The Thebarton area is located within the Adelaide Plains approximately 8 km to the east of Gulf St Vincent and to the west of the Para Fault It lies within the Golden Grove ndash Adelaide Embayment area of the St Vincent Basin which consists of a succession of Tertiary and Quaternary age sediments (with thicknesses of up to 600 m) overlying basement rocks

        The 1250000 Adelaide geological map (SA Department of Mines and Energy 1969) indicates that the near-surface geology of the area consists primarily of Quaternary aged soils and sediments including the Pooraka and Hindmarsh Clay formations The Pleistocene aged Pooraka Formation generally comprises a thickness of approximately 10 m and is of alluvial origin comprising sandy clays and clayey to sandy silts interbedded with layers of clay sand andor gravel The underlying Pleistocene aged Hindmarsh Clay Formation represents the basal unit of the Adelaide Plains and has a maximum general thickness of more than 100 m It generally comprises a basal gravel layer a middle layer of mottled medium to high plasticity (red-brown yellow brown greygreen to orange) often stiff to hard clays and an upper layer of fluvial and alluvial red-brown silty sand Gerges (1999) describes Hindmarsh Clay as comprising a mottled brown to pale olive grey predominantly clay formation that becomes green grey towards the basal section (approximately 16 to 20 m below ground level (BGL)) and is characterised by an increasing gravel content with depth

        Underlying the Hindmarsh Clay are sands and limestone of Tertiary age which are in turn underlain by metamorphosed basement rock of the Proterozoic Umberatana Group

        80607-1 REV1 30102017 PAGE 5

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        222 Hydrogeology

        According to Gerges (2006) the aquifers identified within the Quaternary aged sediments of the Adelaide Plains are typically found within the coarser interbedded silt sand and gravel layers of the Hindmarsh Clay Formation and vary greatly in thickness (typically from 1 to 18 m) lithology and hydraulic conductivity Confining beds between the Quaternary aquifers consist of clay and silt layers and range in thickness from 1 to 20 m These confining beds vary in terms of the amount of coarser grained material they contain their bulk hydraulic conductivity andor the presence and density of fractures In addition their absence in some areas allows direct hydraulic connection between the aquifers

        The Thebarton area is located within Hydrogeological Zone 3 (Subzone 3E) of Gerges (2006) This zone contains five to six Quaternary aquifers and three to four almost flat-lying Tertiary aquifers The first Tertiary aquifer estimated by Gerges (2006) to be intersected at a depth of approximately 130 m BGL near the Para Fault is most frequently accessed for industrial and recreational groundwater use

        The Q1 aquifer assessed as part of the current investigations is typically located at depths of between 3 and 10 m BGL beneath the Adelaide Plains with an average thickness of 2 m The Q1 aquifer contains water of variable salinity with Subzone 3E including a range of 500 to 3500 mgL total dissolved solids (TDS) The gradient of the Q1 aquifer is generally flat (particularly to the west of the Para Fault) and flow direction is typically towards the north-west

        A search of the registered bore database maintained by the Department of Environment Water and Natural Resources (DEWNR (2017) WaterConnect database) identified 59 bores within the general Thebarton area of which 18 are located in the Thebarton EPA Assessment Area Although eight bores were installed for monitoring purposes on or immediately adjacent to the property located at 31-37 George Street (ie part of the former Austral facility) it is understood that only one bore (6628-21951 ndash located within the Admella Street roadway intersecting the Q1 aquifer and identified as MW01 in Appendix A but MW02 by Fyfe5) remains in situ

        In addition to numerous monitoringinvestigationobservation bores the Q1 aquifer within the general (ie broader) Thebarton area is recorded in the DEWNR (2017) database as being accessed for drainage domestic and industrial purposes

        DEWNR (2017) information for registered bores located within the general Thebarton area is included in Appendix C whereas information for bores located within the Thebarton EPA Assessment Area (excluding those associated with the property at 31-37 George Street and installed solely for monitoring purposes6) is summarised in Table 21

        5 This existing groundwater well was identified as MW02 by Fyfe in accordance with the markings on the gatic cover and the DEWNR (2017) WaterConnect bore identification details although it was originally installed as MW01 by REM (refer to discussion of previous reports in Appendix A)

        6 ie 6628-21951 6628-21952 6628-22229 to 6628-22233 and 6628-22236

        PAGE 6 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area

        Bore ID Location Purpose Status Maximu SWL Salinity Yield Aquifer m well (m (mgL (Lsec

        Tertiary (T1)

        depth BGL) TDS) ) (m BGL)

        125 6628-516 Coca Cola plant Rehabilitated 138 1963 794

        6628-1435 Coca Cola plant Backfilled 184 212 921 392 Tertiary (T1)

        6628-4576 Corner of Admella amp Chapel Streets

        125 1454 445 Tertiary (T1)

        6628-7724 Coca Cola plant Observation 155 2017 1272 1516 Tertiary (T1)

        6628-7725 Coca Cola plant Observation 127 3016 1100 1005 Tertiary (T1)

        6628-12516 Coca Cola plant Industrial Backfilled 210 212 1300 1875 Tertiary (T1)

        6628-20663 39 Smith Street Irrigation 121 1105 50 Tertiary (T1)

        6628-20969 39 Smith Street Industrial 30 14 1535 25 Quaternary (Q1)

        6628shy21951

        Admella Street 20 Quaternary (Q1)

        6628-22395 21 James Congdon Drive

        20 157 1541 05 Quaternary

        6628-23525 41 Maria Street 206 273 1078 10 Tertiary (T1)

        Notes Shading indicates that information was not recorded in the database as interpreted from information provided in the database ndash approximate only in some instances

        ie MW02 as included in the groundwater monitoring program of Fyfe ndash refer to Table 31 Abbreviations BGL = below ground level SWL = standing water level TDS = total dissolved solids

        23 Data quality objectives

        The Data Quality Objective (DQO) process as described in Australian Standard AS44821-2005 and the National Environment Protection (Assessment of Site Contamination) Measure (ASC NEPM 1999)7

        Schedule B2 Guideline on Data Collection Sample Design and Reporting and more fully documented in the NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme involves a seven-step iterative approach that was initially developed by the United States Environment Protection Agency (US EPA) to facilitate the systematic planning and verification of contaminated sites assessment projects

        As stated in Schedule B2 of the ASC NEPM (1999) the first six steps of the DQO process comprise the development of qualitative and quantitative statements that define the objectives of the site assessment program and the quantity and quality of data needed to inform risk-based decisions These steps enable the

        All references to the ASC NEPM (1999) refer to the version amended on 16 May 2013

        80607-1 REV1 30102017 PAGE 7

        7

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        project team to communicate the goals decisions constraints (eg time budget) and uncertainties associated with the project and detail how they are to be addressed The seventh step comprises the development of a Sampling and Analysis Quality Plan (SAQP) to generate the data required to adequately characterise site contamination issues and assess their associated potential environmental and human health risks under the proposed land use scenario

        The DQOs defined for the Thebarton EPA Assessment Area are summarised in Table 22

        Table 22 Data Quality Objectives

        Objective Comment

        Step 1 ndash Statement of the Problem According to information provided to Fyfe by the EPA (as summarised in Appendix A) a property located at 31-37 George Street (immediately west of Admella Street) in Thebarton and historically occupied by part of the Austral facility had been found to be underlain by groundwater CHC (primarily TCE) impacts More recent reporting to the EPA for a property at 39 Smith Street located approximately 350 m north-west (and hydraulically down-gradient) of the George Street property indicated that detectable CHC (predominantly TCE) were also present within groundwater Since this area of Thebarton is occupied by a mixture of commercialindustrial and residential properties and the source and extent of the CHC impacts within the Q1 aquifer had not yet been determined potential risks to human health andor the environment had yet to be assessed

        Step 2 ndash The Decision that Needs The assessment works commissioned by the EPA were necessitated to to Result from the Investigation investigate the source extent and magnitude of the groundwater CHC

        contamination beneath a designated area of Thebarton (ie that included both the George Street and Smith Street properties) and to understand the possible risk to public health from potential vapour generation Fyfe have therefore undertaken vapour modelling and intrusion risk assessment works aimed at evaluating whether concentrations of identified groundwater andor soil vapour contaminants pose an unacceptable risk to human health In addition groundwater fate and transport modelling has been undertaken to predict the extent of the plume This will assist the EPA to determine a potential future Groundwater Prohibition Area (GPA) in accordance with the provisions of Section 103S of the Environment Protection Act 1993

        Step 3 ndash Inputs to the Decision The information that was required to resolve the decision statement included the collection of physical and chemical data from across the Thebarton EPA Assessment Area The collected data as well as physical observations regarding the geology of the area and possible preferential contaminant pathways was used to determine potential risks to human health via groundwater fate and transport and vapour intrusion modelling

        Step 4 ndash Boundaries of the Investigation

        The lateral boundaries of the Thebarton EPA Assessment Area are as defined in Sections 13 and 21 as depicted on Figure 1 Vertically the investigations extended as far as the maximum drilled depth (19 m BGL)

        Step 5 ndash Decision Rules The decision rule will be based upon the identification of predicted indoor air concentrations of CHC compounds associated with groundwater andor soil vapour impacts which exceed adopted response levels

        PAGE 8 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Objective Comment

        Step 6 ndash Decision Error Tolerances The purpose of establishing decision error tolerance is to control the acceptable degree of uncertainty upon which decisions are made in order to avoid the making of an incorrect decision and to enable identification of additional investigation monitoring or remediation activities required on the basis of accurate data for the protection of human health and the environment The Measuring Quality Objectives (MQO) include the quality assurance (QA) activities that were conducted during the assessment the quality control (QC) acceptance criteria applicable to the assessment and the adopted Data Quality Indicators (DQIs) as follows (and further discussed in Section 5) completeness ndash a measure of the amount of useable data from a data

        collection activity comparability ndash the confidence (expressed qualitatively) that data may be

        considered to be equivalent for each sampling and analytical event representativeness ndash the confidence (expressed qualitatively) that data

        are representative of each media present on the site precision ndash a quantitative measure of the variability (or reproducibility) of

        data and accuracy (bias) ndash a quantitative measure of the closeness of reported data

        to the true value

        Step 7 ndash Optimisation of the Data collection was undertaken in general accordance with the Sample Collection Design methodologies outlined in the relevant documentsguidelines referenced

        throughout this report As determined by the EPA the data collection design included targeted sampling to investigate and delineate areas of potential groundwater and soil vapour contamination and to assess potential associated human health risks

        80607-1 REV1 30102017 PAGE 9

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        3 SCOPE OF WORK

        The scope of work undertaken by Fyfe was generally consistent with that requested within the original EPA request for quote (RFQ) dated 27 March 2017 Some modifications to the original workscope occurred based on site findings and additional site information was collected where required and as agreed with the EPA in order to achieve the EPArsquos project objectives outlined in Section 15

        As identified in the RFQ the scope of work was designed to

        provide an initial delineation of CHC impacts in soil vapour through the deployment of Waterloo Membrane Samplers (WMStrade) as a screening tool

        further delineate the previously identified CHC impacts in groundwater

        decide based on the results of the WMStrade and groundwater results the need for the number of and the locations of permanent soil vapour monitoring bores

        identify the nature extent and potential source area(s) of the identified CHC impacts in groundwater andor soil vapour

        determine the likely fate and transport of the groundwater CHC plume to support the establishment of a potential future GPA

        determine the potential human health (including vapour intrusion) risk(s) on the basis of the data collected and

        ascertain whether or not a public health risk exists within the Thebarton EPA Assessment Area

        The scope of work is further detailed in Section 32 Variations from the scope of work originally requested in the EPA RFQ were agreed with the EPA during the course of the project and included the following

        deployment of an additional four WMStrade units ndash ie 41 in total as compared to the original allowance of 37

        installation (and sampling) of an additional six nested soil vapour bores (to depths of 1 and 3 m BGL) ndash ie 11 in total as compared to the original allowance of five

        installation (and sampling) two individually located (ie as opposed to the nested locations) soil vapour bores to a depth of 1 m BGL ndash ie as compared to the original allowance of 10

        installation (and sampling) of 25 groundwater monitoring wells ndash ie as compared to the original allowance of 20 and

        sampling of an existing well in Admella Street (MW02) ndash ie not included in the original EPA scope

        80607-1 REV1 30102017 PAGE 11

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        31 Preliminary work

        Preliminary work involved the following

        review and summation of all available historical reports (as supplied by the EPA) ndash refer to Appendix A

        development of a preliminary (working) conceptual site model (CSM) based on a review of the historical data

        preparation of a detailed health and safety plan covering all aspects and stages of the work and

        detailed planning with key stakeholders prior to the execution of the field investigation program

        32 Field investigation and laboratory analysis program

        The scope of the field investigation program undertaken by Fyfe between 31 May and 28 August 2017 is summarised in Table 31 whereas the scope of the laboratory testing program is summarised in Table 32

        A plan showing the various assessment point locations is included as Figure 2

        Table 31 Scope of field investigation program ndash May to August 2017

        Scope Item Description of works Date of works

        Passive soil vapour sampling ndash Round 1

        Thirty-seven WMStrade units identified as WMS 1 to WMS 37 were installed within the soil profile to 1 m BGL at scattered (approximately grid-like) locations across the Thebarton EPA Assessment Area

        31 May and 1 to 2 June

        The WMStrade units were extracted and forwarded to the analytical laboratory 7 June

        Soil bores were located using a hand-held global positioning system (GPS) unit before being backfilled with (drillerrsquos) sand

        7 August

        Monitoring well drilling and installation

        Individual groundwater well permits were obtained from DEWNR prior to well installation ndash copies of the well permits are included in Appendix D Groundwater monitoring wells (MW1 MW3 and MW5 to MW26) were installed to depths of between 15 and 19 m BGL at 24 locations across the Thebarton EPA Assessment Area Background well MW4 was installed to 19 m BGL within a public recreational area located across James Congdon Drive to the east (ie near the south-eastern corner of the Thebarton EPA Assessment Area) All 25 newly installed wells were developed following installation

        28 to 30 June 3 to 7 July and 10 to 14 July

        Geotechnical soil testing

        Intact soil cores collected during the drilling of 10 groundwater wells (MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25) were forwarded to the analytical laboratory for geotechnical testing

        Groundwater gauging

        All 25 newly installed monitoring wells (MW1 and MW3 to MW26) as well as the existing Admella Street well (MW02) were gauged to assess total well depth standing water level (SWL) and the presenceabsence of non aqueous phase liquid (NAPL) This was undertaken as a discrete event prior to the commencement of groundwater sampling

        18 July

        PAGE 12 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Scope Item Description of works Date of works

        Groundwater sampling

        All 26 existing and newly installed wells were sampled using a combination of low flow (micropurge) and HydraSleevetrade sampling techniques (as recorded on the field sampling sheets in Appendix E) ndash samples were forwarded to the analytical laboratories

        18 to 21 and 24 to 25 July

        Aquifer testing Aquifer permeability (slug) testing was undertaken on 10 wells (MW02 MW3 MW7 MW14 MW17 MW20 MW21 MW23 MW25 and MW26) Data was subsequently evaluated by Arcadis Pty Ltd (Arcadis) to estimate the hydraulic conductivity of the aquifer beneath the Thebarton EPA Assessment Area (refer to Section 732)

        28 July

        Soil vapour bore drilling and installation

        Following the receipt of the groundwater data 11 nested soil vapour bores (SV1 to SV10 and SV12) were installed to a depth of 1 and 3 m BGL at selected locations within the Thebarton EPA Assessment Area Two additional soil vapour bores (SV11 and SV13) were installed to a depth of 1 m BGL

        18 21 and 22 August

        Active soil vapour sampling

        Sampling of soil vapour bores was undertaken using summa canister (TO-15) sample collection methods Vapour (canister) and general gas (Tedlar bag) samples were extracted from all 13 locations (ie SV1 to SV13) including the 11 nested bores

        24 August

        Passive soil vapour sampling ndash Round 2

        Following the receipt of the groundwater data and for the purposes of comparison with the soil vapour bore data an additional four WMStrade units (WMS 38 to WMS 41) were installed within the soil profile to 1 m BGL at targeted locations across the Thebarton EPA Assessment Area (ie within approximately 1 m of soil vapour bores SV2 SV4 SV5 and SV7) Soil bores were located using a hand-held GPS unit

        18 August

        The WMStrade units were extracted and forwarded to the analytical laboratory and the soil bores were backfilled with (drillerrsquos) sand

        24 August

        Surveying The locations of all soil vapour bores and groundwater wells were surveyed by a licensed surveyor relative to the Map Grid of Australia (MGA) 1994 and the top of each bore was surveyed relative to Australian Height Datum (AHD) The survey data are included in Appendix F

        22 July and 28 August

        Notes as determined by the EPA

        Table 32 Scope of laboratory testing program

        Scope Item Description of works

        Soil geotechnical testing

        Soil samples from each of three depths within core samples collected during the drilling of groundwater wells MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25 were analysed for particle size distribution (PSD) moisture content including degree of saturation bulk density dry density and specific gravity void ratio and porosity

        80607-1 REV1 30102017 PAGE 13

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Scope Item Description of works

        Groundwater testing Groundwater samples from all 26 wells were analysed for the COPC detailed in Section 14 As requested by the EPA groundwater samples from selected wells (MW02 MW5 MW8 MW9 MW12 MW17 MW21 MW22 MW23 and MW26) were also analysed for the following major cations and anions (calcium magnesium sodium potassium chloride and alkalinity)

        and natural attenuation parameters (carbon dioxide (CO2) sulfate iron manganese nitrate) Additional components reported by the analytical laboratory included nitrite and nitrate + nitrite

        Soil vapour testing The WMStrade units deployed during each of Rounds 1 and 2 were analysed for the COPC detailed in Section 14 The soil vapour (summa canister) samples were analysed for the COPC detailed in Section 14 as well as 2-propanol and general gases (helium hydrogen oxygen nitrogen methane carbon dioxide ethane propane butane iso-butane pentane iso-pentane hexane argon carbon monoxide and ethylene)

        Notes Specific sample depths are detailed in the relevant laboratory reports in Appendix G also known as isopropyl alcohol isopropanol or IPA

        33 Data interpretation

        Following the receipt and collation of the field and laboratory data hydrogeological (fate and transport) and VIRA modelling (refer to Sections 8 and 9 respectively) were undertaken to enable an assessment of risk and to refine the CSM (Section 10)

        PAGE 14 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        4 METHODOLOGY

        41 Field methodologies

        Prior to the commencement of the field investigations a site specific Health and Safety Plan (HSP) including Safe Work Method Statements (SWMS) and a Job Hazard Analysis (JHA) was prepared ndash all personnel working at the site were required to read understand sign and conform to the HSP

        Each proposed drilling location was cleared of underground services by a professional service location company (Pipeline Technologies) using conventional (electronic) service detection methods as well as ground penetrating radar (GPR) Where underground or overhead services were present andor deemed to be a potential safety risk during drilling activities the drill location was moved to an area considered by the Fyfe representative and service locator to be safe All changes to drilling locations were notified to EPA and recorded on a site plan for future reference

        Given that works were undertaken within suburban streets Fyfe employed the services of a qualified traffic management company (Altus Traffic) during drilling activities in order to ensure safety for pedestrians and road users minimal disruption to traffic flow and the provision of a safe working environment

        Field methodologies as detailed in Table 41 were undertaken in accordance with Fyfersquos standard operating procedures (SOPs) Relevant field sampling sheets are included in Appendices F (groundwater) and G (soil vapour ndash combined field sampling sheets and chain of custody (COC) documents) and borehole log reports are presented in Appendices H (groundwater) I (WMStrade) and J (soil vapour)

        Table 41 Summary of field methodologies

        Activity Details

        Passive soil bore sampling The soil bores used to deploy the WMStrade units were hand augered by personnel from Fyfe and Aussie Probe to a depth of 1 m BGL SGS Australia (SGS) personnel suspended each WMStrade unit into its respective borehole from a string The hole was then sealed with an expandable foam plug inside a polyethylene sleeve and the string suspending the sampler was connected to a temporary plastic cap at the ground surface The Round 1 WMStrade units were deployed for periods of between six and seven days whereas the Round 2 WMStrade units were all deployed for six days Following retrieval by SGS each WMStrade unit was placed into a sealed glass vial and a labelled foil bag The WMStrade units did not require chilling during transport to the analytical laboratory Borehole log reports are included in Appendix I whereas combined field sampling sheets and COC documents are presented in Appendix G

        80607-1 REV1 30102017 PAGE 15

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Activity Details

        Groundwater well Groundwater wells were drilled by WB Drilling using a combination of hand augering installation mechanical pushtube and solid auger techniques

        Following the completion of drilling each borehole was fitted with 50 mm class 18 uPVC casing with a basal 6 m long section of slotted well screen A filter pack comprising clean graded sands of suitable size to provide sufficient inflow of groundwater was installed within the annular space between the borehole and the well casing and extended from the base of the screened interval to approximately 1 m above the termination of the slotted casing A 1 m long bentonite collar comprising pelleted or granulated bentonite was placed above the filter pack to prevent water seepage downward along the well casing or borehole from ground surface Each well was grouted up to surface level and fitted with a (lockable) steel gatic cover the latter flush mounted to prevent tripping andor other hazards Groundwater well log reports are included in Appendix H

        Soil logging and Soil logging was undertaken in general accordance with the ASC NEPM (1999) which geotechnical sampling endorses AS1726-1993 In addition to the requirements of AS1726-1993 particular

        attention was paid during logging to any lithological variations such as sandgravel lenses or secondary porosity (such as clay fracturing) which may act as potential preferential pathways for contaminant vapourgroundwater migration through the sub-surface as well as the presence of fill material andor any olfactory or visual evidence of contamination Soil descriptions have been included on the logs in Appendices H to J Cores for geotechnical analysis were collected using push tube sampling methodologies to obtain undisturbed samples Section(s) of core to be tested were retained (intact) within the pushtube liners and capped at each end for storage and transport to the analytical laboratory

        Field screening of soils Field screening of individual soil layers was undertaken at the majority of the drilling locations and involved the use of a photoionisation (PID) unit fitted with an 117 eV lamp (ie as considered suitable for the detection of CHC) The PID unit was calibrated by the hire company prior to delivery and was checked on a daily basis against an isobutylene calibration gas of known concentration Field screen samples were collected with care to ensure that each sample was representative of the soil stratum from which it was collected and experienced minimal loss of volatile compounds The soil material was placed immediately into a zip lock bag and sealed ensuring the bag was half filled (ie such that the volume ratio of soil to air was equal) Soil clumps within the bag were manually broken up and the bag was left to rest for a minimum of five minutes but no longer than 20 minutes Prior to testing the bag was shaken vigorously to release any vapours within the soil To test the tip of the PID probe was inserted into the bag and the maximum volatile organic compound (VOC) reading recorded after a nominal 10 second period or when the reading had peaked Results were recorded on the appropriate bore log sheets presented in Appendices H to J

        Groundwater well Following installation the wells were developed by purging a minimum of four well development volumes (ie until stable parameters were obtained andor until the well purged dry) from

        the casing with a steel bailer andor twister pump to ensure hydraulic connectivity with the aquifer formation

        Groundwater gauging Groundwater levels in the newly installed and existing monitoring wells located across the Thebarton EPA Assessment Area were gauged using an interface probe prior to the commencement of the groundwater sampling program All monitoring wells were gauged for SWL the potential presence of NAPL and the total well depth Groundwater field gauging results are presented in Appendix E

        PAGE 16 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Activity Details

        Groundwater sampling The majority of the wells were sampled using low flow (micropurge) techniques Where recovery was particularly low (ie MW4 MW8 MW15 MW18 MW19 and MW24) and unsuitable for low flow (micropurge) sampling the original sampling technique was abandoned and a HydraSleeveTM (no purge) methodology was used instead Groundwater samples were collected in laboratory-supplied screw top bottles containing appropriate preservative (if required) with no headspace allowed Samples were chilled during storage and transport to the analytical laboratory Disposable nitrile gloves worn by field personnel were changed prior to the collection of each sample Samples for metals (ie iron manganese) analysis were filtered in the field using 045 microm filters Groundwater field sampling sheets are presented in Appendix E

        Low Flow Methodology The low flow sampling technique involved the following the pump was placed close to the bottom of the screened interval the flow rate (up to 05 Lmin) was regulated to maintain an acceptable level of

        drawdown with minimal fluctuation of the dynamic water level during pumping and sampling

        groundwater drawdown was monitored constantly during purging and sampling using an interface probe

        water quality parameters were considered to have stabilised when the following ranges were recorded over three consecutive readings ndash electrical conductivity plusmn 5 ndash pH plusmn 01 ndash temperature plusmn 02degC ndash dissolved oxygen plusmn 10 ndash redox potential plusmn 10 mV

        the stabilisation parameters were recorded on field logging sheets after every one litre of groundwater purged using a calibrated water quality meter and a flow cell suspended in a bucket with litre intervals marked and

        samples were collected once three consecutive stabilisation parameters were recorded and a volume of between 28 and 6 litres was purged prior to sampling

        HydraSleeveTM Methodology The HydraSleeveTM sampling technique involved attaching a stainless steel weight to the bottom and a wire tether clip to the throat of the HydraSleeveTM before lowering it into the water column to the desired depth and allowing it to fill with groundwater After a minimum period of 24 hours the HydraSleeveTM was quickly and smoothly withdrawn from the well and the contents were transferred into the sample containers Water quality parameters were measured after samples were decanted ndash either within the water remaining in the HydraSleeveTM or within a grab sample collected using a disposable bailer

        Hydraulic testing Rising and falling head permeability (ldquoslugrdquo) tests were undertaken to estimate the hydraulic conductivity (K) of the aquifer within various parts of the Thebarton EPA Assessment Area The falling-head tests were initiated by quickly inserting a 1285 m long and 36 mm diameter solid PVC cylinder (slug) into the water column at each well to produce a sufficient sudden rise in the water level The subsequent ldquofallrdquo back to the static water level (recovery) was measured and recorded automatically and in real-time using a

        80607-1 REV1 30102017 PAGE 17

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Activity Details

        pressure transducerdata logger programmed to record water levels at a one second interval After static water level conditions returned in the well the rising-head test was initiated by quickly removing the slug from the well to create a sudden drop in the water column height As with the falling-head test the rise of the water level back to a static condition (recovery) was automatically recorded

        Soil vapour bore Soil vapour bores were drilled by Aussie Probe using a combination of hand augering and installation mechanical pushtube techniques

        Within each 3 m deep soil vapour bore teflon tubing attached to a soil vapour probe was inserted to the base of the hole which had been prefilled with approximately 005 m of clean filter pack sand An additional 045 m of sand (ie approximately 05 m in total) was then added to the hole and topped by a bentonite plug seal of approximately 05 m thickness A second soil vapour probe was installed at a depth of about 1 m within a 05 m sand pack which was overlain by bentonite to a depth of about 02 to 03 m BGL The two 1 m deep soil vapour bores were installed in a similar manner with a sand pack extending from the base to about 05 to 06 m BGL overlain by a bentonite plug to 03 m BGL Each installation was completed with grout to surface and topped with a standard flush-mounted gatic cover Soil vapour bore log reports are included in Appendix J

        Soil vapour sampling All soil vapour sampling works were undertaken by SGS using suitably trained and experienced personnel ndash SGS holds National Association of Testing Authorities (NATA) accreditation for all soil vapour sampling and laboratory analytical works Combined field sampling sheets and COC documents are presented in Appendix G Soil vapour samples were collected using summa canisters and analysed using the US EPA (1999) TO-15 method Sampling involved the connection of a passivated 1 L stainless steel canister to the teflon tubing extending from the soil vapour probe and the use of a soil gas sampling train to restrict flow to a maximum rate of 200 mLmin Canister vacuum pressure was monitored during sampling to enable calculation of the volume of sample drawn into the canister ndash the small amount of vacuum left in the canister at the end of the sampling procedure was measured in the laboratory to check if any leaks occurred during transit (refer to further discussion in Table 52) A shroud was set up around the sampling point and tracer chemicals were introduced at high concentrations by flooding the shroud with helium and placing a cloth soaked with IPA into the shroud Each canister was cleaned and certified by SGS prior to use (refer to Appendix G) and backshyup coconut shell carbon sorbent tube samples were also collected (but not analysed) Summa canisters did not require chilling during transport to the analytical laboratory

        Waste disposal Waste water and surplus soil corescuttings were stored together within 205 litre drums in the rear car park of a commercialindustrial property at 19-21 James Congdon Drive (as organised by the EPA) prior to removaldisposal by a licensed waste removal company (Cleanaway) Analytical results pertaining to the soils were forwarded to the licensed receiving facility and all of the soil was classified as lsquoWaste Fillrsquo in accordance with the Environment Protection Regulations 2009 The waste transport certificates are included in Appendix K

        PAGE 18 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        42 Laboratory analysis

        The following laboratories were used for the analysis of the environmental samples

        complete soil cores for geotechnical sample analysis were forwarded to SMS Geotechnical

        primary groundwater samples collected by Fyfe were analysed at the SGS laboratory whereas secondary groundwater samples were forwarded to EurofinsMGT and

        soil vapour (including WMStrade) samples collected by SGS were analysed at their laboratory

        80607-1 REV1 30102017 PAGE 19

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        5 QUALITY ASSURANCE AND QUALITY CONTROL

        Data quality is typically discussed in terms of the DQIs presented in Table 22 ndash ie completeness comparability representativeness precision and accuracy In order to assess the quality of the data collected during the Fyfe investigation program against these DQIs specific QAQC procedures were implemented during both the field sampling and laboratory analysis programs as detailed in the following sections

        51 Field QAQC

        Field QA procedures undertaken during the recent investigations included the collection of the following QC samples aimed at assessing possible errors associated with cross contamination as well as inconsistencies in sampling andor laboratory analytical techniques

        intra-laboratory duplicate (duplicate) samples submitted to the same (primary laboratory) to assess variation in analyte concentrations between samples collected from the same sampling point andor the repeatability (precision) of the analytical procedures

        inter-laboratory duplicate (split or triplicate) samples submitted to a second laboratory to check on the analytical proficiency (accuracy) of the results produced by the primary laboratory

        equipment rinsate blank samples collected during groundwater sampling only and used to assess cross-contamination that may have occurred from sampling equipment during sampling and

        trip blank samples used to assess whether cross-contamination may have occurred between samples during transport

        Whereas analyte concentrations within the rinsate and trip blank samples should be below the laboratory limit of reporting (LOR) the inter- and intra-laboratory duplicate sample results are assessed via the calculation of a relative percentage difference (RPD) as follows

        (Concentration 1 minus Concentration 2) x 100RPD = (Concentration 1 + Concentration 2) 2

        Maximum RPDs of 30 (inorganics) and 50 (organics) are generally considered acceptable with higher RPD values often recorded where concentrations of an analyte approach the laboratory LOR

        All field QC sample results are included in the summary data tables in Appendix L

        511 Groundwater

        Table 51 presents conformance to field QAQC procedures undertaken as part of the groundwater investigations

        80607-1 REV1 30102017 PAGE 21

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Table 51 Field QAQC procedures ndash Groundwater

        QAQC Item Detail

        Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) AustralianNew Zealand standards ASNZS 566711998 and ASNZS 5667111998 SA EPA (2007) and Fyfe SOPs Details are provided in Table 41

        Calibration of field equipment

        Documentation regarding the calibration of field equipment is included in Appendix M

        Decontamination of All disposable equipment (tubing pump bladders plastic bailers bailer cord and equipment HydraSleeveTM units) were replaced between wells Re-usable equipment (micropurge pump

        interface probe and HydraSleeveTM weights) was decontaminated between sampling locations using potable water and Decon 90trade phosphate free detergent

        Sample preservation and storage

        Samples were kept in laboratory supplied containers in a portable chilled insulated box (esky) prior to and during transport to the laboratory

        Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

        Duplicate samples Two intra-laboratory and two inter-laboratory duplicate samples were analysed for CHC with respect to 26 primary groundwater samples ndash thereby constituting an overall ratio of approximately one duplicate per 65 primary samples (or 15) compared to a generally acceptable ratio of 110 samples (or 10) One intra-laboratory and one inter-laboratory duplicate sample were analysed for the remaining parameters with respect to 10 primary groundwater samples ndash thereby constituting an overall ratio of one duplicate per five primary samples (or 20) compared to a generally acceptable ratio of 110 samples (or 10) Intra- and inter-laboratory duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within the acceptable range with the exception of the following intra-laboratory duplicate sample pair MW9QW1 TCE (67) nitrate (147) and inter-laboratory duplicate sample pair MW9QW2 total CO2 (59) iron (190)

        manganese (183) potassium (64) nitrate (194) The elevated RPD for TCE in the intra-laboratory duplicate sample pair is considered to be related to the low concentration detected and does not alter the interpretation of the data The other RPD exceedances are not considered significant (ie in terms of overall data interpretation) as they were not obtained for identified COPC (as defined in Section 14)

        Rinsate blank samples Six equipment rinsate blank samples (one for each day of sampling) were collected from either the pump housing or a new HydraSleevetrade (final day of sampling only) and analysed for CHC to confirm the effectiveness of the decontamination procedures and the cleanliness of disposable equipment The analytical results obtained for the rinsate blank samples were all below the laboratory LOR thereby indicating that decontamination practices during the groundwater sampling program were acceptable and that no contamination was introduced by the use of the HydraSleevestrade

        Trip blank samples Six trip blank samples were included within containers (eskies) of sample bottles provided by the analytical laboratory and returned to the analytical laboratory All of the trip blank samples were analysed for CHC With the exception of TB187 which contained 1 microgL TCE the analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was limited impact on sample quality during storage or transport of the samples to the analytical laboratory

        PAGE 22 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Notes No duplicate QC samples were collected during the use of the HydraSleeveTM sampling technique as detailed in ANZECCARMCANZ (2000a) at least 5 (ie 120) duplicate samples should be analysed ndash the generally accepted industry standard however is 10 (110) including 5 intra-laboratory and 5 inter-laboratory duplicates

        512 Soil vapour

        Tables 52 presents conformance to field QAQC procedures undertaken as part of the soil vapour (passive and active) investigations

        Table 52 Field QAQC procedures ndash Soil vapour

        QAQC Item Detail

        Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) as well as ASTM (2001 2006) ITRC (2007) CRC CARE (2013) guidance and Fyfe SOPs Details are included in Table 41 and Appendix G (ie SGS sampling methodology sheet) During the use of summa canisters to sample the soil vapour bores leak testing was undertaken (as described in Table 41) Although small leaks or ambient drawdown appear to have occurred with respect to samples SV11_10m (003 helium) SV13_10m (003 helium) and SV1_10m (360 microgm3 IPA) ITRC (2007) and NJDEP (2013) state that ge 5 helium andor gt10 mgm3 IPA are required to be indicative of a significant leak or substantial ambient drawdown Given that the leaks were relatively small (ie 06 (helium) and 36 (IPA) of the levels considered indicative of a significant leak) the data from these bores were still considered to be valid ndash refer to SGS correspondence in Appendix G As detailed in Table 41 a small amount of vacuum was generally left in each summa canister at the end of the sampling procedure and was measured in the laboratory to check if any leaks had occurred during transit However samples SV11_10m SV12_30m as well as the helium blank were recorded as having zero vacuum upon receipt at the analytical laboratory A query lodged with SGS regarding this issue indicated that whereas the helium blank comprised a grab sample collected into a Tedlar bag directly from the helium cylinder (ie without the use of a gauge) the canisters used for samples SV11_10m and SV12_30 were filled during sampling so that there was no remaining vacuum ndash refer to field sampling documentation in Appendix G SGS stated that although it is good practice to have a small amount of vacuum remaining in a canister at the completion of sampling appropriate additional QC measures were employed and the absence of other common background VOCs (eg petroleum hydrocarbons) upon sample testing indicated that leakage had not occurred during transit In addition all canisters are fitted with quick connect one-way valves that are closed upon removal from the sampling train and canistersfittings are leak checked prior to leaving the laboratory and again in the field to ensure that they are leak free Refer to SGS correspondence in Appendix G The presence of detectable IPA (120 microgm3) and TCE (48 microgm3) in the helium blank was also queried with SGS who stated that this (ie variability in the quality of the high purity helium gas used) is not an uncommon occurrence The reason for collecting a helium blank sample is to identify any impurities present in the helium gas so that if a leak does occur during sampling it is possible to determine whether any target compounds could be introduced into the sample train Although a target compound (ie TCE) was detected in the blank the concentration is minor and even if a leak had occurred during sampling (of which there was no evidence) it would not have affected the overall results and data interpretation The presence of IPA in the helium blank is

        80607-1 REV1 30102017 PAGE 23

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        QAQC Item Detail

        suspected by SGS of having resulted from a handling issue in the field ndash ie sub-sampling from the helium cylinder (ie into a summa canister via a flex foil bag) in the vicinity of the high concentrations of IPA being used for leak detection Refer to SGS correspondence in Appendix G

        Sample preservation and storage

        Following collection the WMStrade units were placed into individual glass vials which were sealed and placed into foil bags for transport to the analytical laboratory at ambient temperature Summa canisters were stored in specially constructed cases during transport to the analytical laboratory at ambient temperature

        Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

        QC samples ndash WMStrade sampling

        During the first round of passive soil vapour sampling three additional WMStrade units were deployed in soil bores drilled adjacent to WMS 22 WMS 25 and WMS 28 to act as duplicate QC samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 8) Two trip blank samples were also included with samples transported from and to the analytical laboratory All of the QC samples were analysed by the primary laboratory Intra-duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within an acceptable range (ie lt30) The analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was negligible impact on sample quality during storage or transport of the samples to the analytical laboratory

        QC samples ndash soil vapour bore sampling

        Two intra-laboratory duplicate QC samples were analysed for CHC and general gases with respect to 24 primary soil vapour samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 83) compared to an acceptable ratio of 110 samples (or 10) Intra-laboratory duplicate RPDs were calculated where both samples had a reported concentration above the laboratory LOR All calculated RPDs for CHC and general gases were within an acceptable range (ie lt30) The analytical results obtained for the helium shroud (Tedlar bags) helium blank and IPA shroud (carbon tube) samples were all considered to be satisfactory

        Notes The American Society for Testing and Materials (ASTM) is an internationally recognised source of testing methods Although Appendix J of CRC CARE (2013) stipulates a 110 duplicate sampling ratio for active vapour sampling a specific ratio is not stipulated for passive vapour sampling

        52 Laboratory QAQC

        Laboratory QA procedures generally include the performance of a number of internal checks of data precision and accuracy that are aimed at assessing possible errors associated with sample preparation and analytical techniques Specific types of QC samples analysed by laboratories and the relevant acceptance criteria are as follows

        PAGE 24 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        internal laboratory replicate samples maximum RPD values of 20 to 50 although this varies depending on laboratory LOR

        spike recoveries results between 70 and 130 and

        laboratory controlmethod blanks results below the laboratory LOR

        Table 53 presents conformance to laboratory QAQC procedures undertaken as part of the overall investigation program

        Table 53 Laboratory QAQC procedures

        QAQC Item Detail

        Samples analysed and Samples were generally analysed within specified holding times ndash with the exception extracted within relevant of the following groundwater samples holding times SGS report no ME303457 nitrate was analysed two days late in some samples

        (MW5 MW17 MW26) SGS report no ME303475 nitrate was analysed one day late in all samples and EurofinsMGT report no 555810-W total CO2 was analysed five days late None of these holding time exceedances are considered to be significant with respect to the interpretation of the CHC data the determination of potential human healthenvironmental risks andor the determination of natural attenuation

        Laboratories used and The laboratories used (SGS Eurofins MGT and SMS Geotechnical) were NATA NATA accreditation accredited for the majority of the analyses undertaken

        The exception was SMS Geotechnical which was not NATA accredited for the calculations undertaken to derive some of the data ndash this is the case however for all geotechnical laboratories

        Appropriate analytical methodologies used

        Refer to the laboratory reports in Appendix G

        Laboratory limit of The laboratory LOR is the minimum concentration of an analyte (substance) that can reporting (LOR) be measured with a high degree of confidence that the analyte is present at or above

        that concentration The LOR are presented in the laboratory certificates of analysis (Appendix G) and are considered to be generally appropriate (ie below the adopted assessment criteria ndash refer to Section 62) ndash the following exceptions in soil vapour (ie considered to be due to interference associated with elevated concentrations of other compounds ndash refer to SGS correspondence in Appendix G) are discussed further in Table 101 VC in all of the WMStrade samples relative to the ASC NEPM (1999) interim soil

        vapour health investigation level (HIL) for residential land use cis-12-DCE and VC in two soil vapour bore samples (SV2_30m and SV3_30m)

        relative to the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land use and

        VC in two soil vapour bore samples (SV3_10m and SV7_30m) relative to the ASC NEPM (1999) interim soil vapour HIL for residential land use

        In addition to the above although ultra-trace analysis was requested the laboratory LOR for VC in groundwater (ie 1 microgL) is above the adopted NHMRCMRMMC (2011) potable guideline (ie 03 microgL) ndash refer to Section 612

        80607-1 REV1 30102017 PAGE 25

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        QAQC Item Detail

        Laboratory internal QC analyses

        Results obtained for the laboratory internal QC samples were generally within the acceptable limits of repeatability chemical extraction and detection with the exception of the following SGS report ME303457 matrix spike results for iron were outside normal tolerances

        due to the high concentrations of iron in the spiked sample ndash matrix spike results for iron could therefore not be calculated This is not considered to be a significant issue

        Full details regarding laboratory QAQC procedures and results are presented in the certified laboratory certificates contained in Appendix G

        Notes Since holding times were not specified in the SGS groundwater reports Fyfersquos assessment of holding times has been based on those adopted by EurofinsMGT (ie the secondary laboratory used for groundwater analysis) ie in accordance with Schedule B3 of the ASC NEPM (1999) also referred to as practical quantification limits (PQL)

        53 QAQC summary

        In summary it is considered that

        the field QAQC programs were generally undertaken with regard to relevant legislation standards andor guidelines and were sufficient for obtaining samples that are representative of site conditions and

        the overall laboratory QAQC procedures and results were adequate such that the laboratory analytical results obtained are of acceptable quality for addressing the key objectives outlined in Section 15

        PAGE 26 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        6 ASSESSMENT CRITERIA

        61 Groundwater

        611 Beneficial Use Assessment

        In accordance with Schedule B6 of the ASC NEPM (1999) and SA EPA (2009) a Beneficial Use Assessment (BUA) was undertaken to assess both the current and realistic future uses of groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area

        This was aimed at determining what groundwater uses need to be protected and assessing the risk(s) that groundwater may pose to human health and the environment (refer also to the VIRA in Section 9)

        As summarised in Table 61 the potential beneficial uses for groundwater within the Q1 aquifer that have been considered are as follows ndash taking into account the salinity of the groundwater the Environment Protection (Water Quality) Policy 2015 (Water Quality EPP 2015) the DEWNR (2017) WaterConnect database information presented in Section 222 and possible sensitive receptors located within andor within the vicinity of the Thebarton EPA Assessment Area

        The salinity of groundwater has been calculated to approximate 1230 to 3620 mgL TDS (refer to Section 7312) According to the Water Quality EPP 2015 the applicable environmental values for groundwater with salinity above 1200 mgL TDS but less than 3000 mgL TDS are irrigation livestock and aquaculture whereas the salinity is considered to be too high for potable use ndash although domestic irrigation is considered to be a potentially realistic use for this area (see below) livestock watering is considered unlikely to be undertaken in such an urban setting and no local water bodies (ie surface or groundwater) have been identified as being used for commercial aquaculture purposes

        The DEWNR (2017) WaterConnect database indicates that groundwater within the Q1 aquifer in the Thebarton area is accessed for drainage domestic and industrial purposes ndash domestic groundwater use could include garden irrigation plumbing water andor the filling of swimming pools (ie primary contact recreation) Although domestic groundwater extraction is considered unlikely to include potable use (ie due to its salinity and the availability of a reticulated mains water supply) potential mixing with rain watermains water could render it suitable (ie from a salinity perspective) for drinking

        As the closest freshwater surface water body the River Torrens is located approximately 03 km to the east and 07 km to the north and north-west of the northern portion of this area groundwater discharge from the Thebarton EPA Assessment Area into a freshwater aquatic ecosystem is considered possible However as the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area the potential for impact on a freshwater aquatic environment has not been confirmed

        80607-1 REV1 30102017 PAGE 27

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Since the closest marine surface water body Gulf St Vincent is located approximately 8 km to the west groundwater discharge from the Thebarton EPA Assessment Area into a marine aquatic ecosystem is not considered to be realistic

        Since volatile contaminants have been detected within the Q1 aquifer (refer to Section 7331) a potential vapour flux risk to future site users must be considered

        Given the measured depth of the Q1 aquifer beneath the site (ie approximately 1232 to 1585 m BGL ndash refer to Section 7311) it is considered unlikely that direct contact could occur between groundwater and building footingsunderground services

        Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area

        Environmental Values Beneficial Uses

        Water Quality EPP 2015

        environmental value

        SA EPA (2009) Potential

        Beneficial Uses

        Beneficial Use Assessment

        Considered Applicable

        Aquatic Ecosystem

        Marine Yes No

        Fresh Yes Possibly

        Potable - Yes Possibly

        Agriculture Irrigation - Yes Yes

        Livestock - Yes No

        Aquaculture - Yes No

        Recreation amp Aesthetics

        Primary contact Yes Possibly

        Aesthetics Yes Possibly

        Industrial - Yes Yes

        Human health in non-use scenarios

        Vapour flux -

        Yes Yes

        Buildings and structures

        Contact - Yes No

        Notes ie for underground waters with a background TDS level of between 1200 and 3000 mgL ndash note that although they are not listed as environmental values of groundwater in Schedule 1(3) of the Water Quality EPP 2015 aquatic ecosystems as well as recreation amp aesthetics are included as environmental values for waters in general in Part 1(6) of the document ie domestic irrigation only

        612 Groundwater beneficial use criteria

        The health and ecological criteria used for the assessment of the COPC (refer to Section 14) in groundwater have been based on the results of the BUA (Section 611) A summary of the references used to source the groundwater assessment criteria is provided in Table 62

        PAGE 28 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Table 62 Sources of adopted groundwater assessment criteria

        Beneficial Use Reference

        Freshwater Ecosystems No criteria available for COPC

        Potable NHMRCNRMMC (2011) Australian Drinking Water Guidelines

        WHO (2017) Guidelines for Drinking-water Quality ndash TCE only

        Irrigation No criteria available for COPC

        Primary contact recreation (including aesthetics)

        NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines but (with the exception of aesthetic guidelines) multiplied by a factor of 10 to take account of accidental ingestion rates as opposed to deliberate ingestion

        ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality ndash recreational values (TCE only)

        Human health in non-use scenarios ndash vapour flux Refer to the VIRA in Section 9

        Notes As there are no specific guidelines for industrial water these values are considered likely to be protective of this additional beneficial use The NHMRC (2008) guidelines are based on drinking water levels and assume a consumption factor of 2 L per day Therefore as recommended in the NHMRC (2008) document potable criteria (ie with the exception of aesthetic criteria) need to be adjusted by a factor of 10 to account for an accidental consumption rate of 100 to 200 ml per day As noted in ANZECCARMCANZ (2000b) although recreational guidelines are protective of ingestion recreational waters should also not contain any chemicals that can cause skin irritation likewise although not specifically addressed by recreational water criteria inhalation may also represent a source of exposure with respect to some (ie volatile) contaminants In the absence of a NHMRCNRMMC (2011) drinking water guideline for TCE the ANZECCARMCANZ (2000b) recreational criterion (30 microgL) has been adopted However if the NHMRC (2008) rule of multiplying potable (healthshybased) guidelines by 10 is applied to the WHO (2017) drinking water guideline of 20 microgL a recreational guideline of 200 microgL would be more applicable

        62 Soil vapour

        The ASC NEPM (1999) interim soil vapour health investigation levels (HILs) for volatile organic chlorinated compounds (VOCCs) have been adopted (ie in the first instance ndash refer to Section 7331) as Tier 1 soil vapour assessment criteria ndash relevant land use scenarios within the Thebarton EPA Assessment Area include residential (HIL AB) and commercialindustrial (HIL D)

        These criteria have been further adjustedappended for the purposes of the VIRA Tier 1 assessment ndash refer to Section 94

        80607-1 REV1 30102017 PAGE 29

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        7 RESULTS

        71 Surface and sub surface soil conditions

        711 Field observations

        Groundwater well and soil vapour borehole log reports are included in Appendices H to J and provide details of the soil profile encountered at each sampling location

        Where encountered fill materials extended to depths of between 01 and 09 m BGL and included a range of different soil types (sand gravelcrushed rock silt) with only minimal waste inclusions (ie asphalt glass andor metal fragments) identified at some locations

        The underlying natural soil profile (encountered to the maximum drill depth of 19 m BGL) was dominated by low to medium plasticity brown to red-brown silty clays and sand claysclayey sands some of which contained sub-angular to rounded gravels that included river pebbles andor comprised fine distinct lenses in places Groundwater well MW17 also included a 15 m thick layer of gravel at depth (ie 12 to 135 m BGL) ndash ie consistent with the depth of groundwater within the Q1 aquifer

        During the course of the drilling works no odours or visual indicators of contamination were detected and measured PID readings ranged up to 6 ppm but were generally lt3 ppm

        712 Soil geotechnical testing

        A table of geotechnical testing results is presented in Appendix L (Table 1) and a copy of the certified laboratory report is included in Appendix G Photographs of soil cores are included in Appendix N

        The results were interpreted to indicate the following

        The soil core samples submitted for PSD analysis were dominated by clay with lesser amounts of fine to medium gravel andor fine to coarse-grained sand ndash all samples analysed were classified as either CLAY or Sandy CLAY with one sample classified as Clayey SAND The classifications obtained from the laboratory were deemed to be generally consistent with the descriptions on the groundwater well log reports (Appendix H) although the PSD results did not specify silt as a significant secondary component

        The moisture content of the analysed soil core samples ranged from 65 to 231 Moisture content with respect to soil type depth and location has been considered in more detail for the purposes of the VIRA (Section 9) The degree of saturation for the analysed soil cores samples ranged from 218 to 964

        Measured bulk density ranged from 160 to 212 tm3 specimen dry density from 141 to 184 tm3 and specific gravity from 255 to 281 tm3

        The measured void ratio ranged from 043 to 088 whereas porosity ranged from 032 to 047

        80607-1 REV1 30102017 PAGE 31

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        72 Waterloo Membrane Samplerstrade A table of WMStrade analytical results (ie from both rounds of sampling) is presented in Appendix L (Table 2) and copies of certified laboratory reports are included in Appendix G8

        Of the 41 WMStrade units deployed across the Thebarton EPA Assessment Area during the two sampling rounds 20 returned measurable concentrations of CHC including TCE PCE cis-12-DCE trans-12-DCE andor 11-DCE Although no VC was detected the laboratory LOR in all samples (ie 35 to 50 microgm3) was above the ASC NEPM (1999) soil vapour interim HIL for residential land use (30 microgm3) ndash refer also to Table 53

        Detectable COPC concentrations are summarised in Table 71 relative to the ASC NEPM (1999) soil vapour interim HILs along with the closest soil vapour bore andor groundwater monitoring well locations Measured TCE concentrations are detailed on Figure 3

        A comparison of the Round 1 and 2 WMStrade results (ie for closely located units9) is presented in Table 72 ndash the results indicate a general order of magnitude correlation of the results for most COPC with the exception of PCE for which lower concentrations were obtained during Round 2 As the Round 1 and 2 WMStrade units were located within different soil bores and deployed at different times some variability in the results is to be expected In addition and as discussed in Section 74 the WMStrade units have been used during this assessment as a (semi-quantitative) screening tool (ie to assist with the siting of the permanent soil vapour bores) with the results obtained from the soil vapour bores considered more representative of actual subsurface conditions

        Table 71 Detectable Waterloo Membrane Samplertrade CHC results

        Sample ID

        Location Closest land uses

        CHC concentration (microgm3) Closest soil vapour bore

        andor groundwater

        well

        TCE PCE cis-12shyDCE

        trans-12shyDCE

        11shyDCE

        VC

        WMS 1 Goodenough Street CI 35 -

        WMS 6 Maria Street CI 32 -

        WMS 7 Maria Street CI and R 1900 45 SV2 MW5

        WMS 8 Maria Street CI and R 12000 37 SV4

        WMS 11 Admella Street CI 71000 260 19 20 36 SV5 MW02

        WMS 14 George Street CI 46000 45 SV6 MW11

        WMS 18 Admella Street CI 4200 34 MW14

        WMS 19 Albert Street CI 11000 42 SV10MW15

        WMS 21 Chapel Street CI 10 -

        WMS 22 Admella Street CI 38 SV9

        WMS 24 Chapel Street CI 230 62 10 11 48 MW17

        8 Note that the original laboratory report for the Round 1 WMStrade samples was found to be incorrect (ie following receipt of the soil vapour bore and Round 2 WMStrade sample results) and was subsequently re-issued by SGS

        9 only two of which were sufficiently co-located for comparative purposes ndash Round 2 locations WMS 39 and WMS 41 were not within the immediate vicinity of Round 1 WMStrade bores (ie the closest Round 1 bores were approximately 30 m away)

        PAGE 32 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Sample ID

        Location Closest land uses

        CHC concentration (microgm3) Closest soil vapour bore

        andor groundwater

        well

        TCE PCE cis-12shyDCE

        trans-12shyDCE

        11shyDCE

        VC

        WMS 25 Albert Street CI and R 1400 20 MW17

        WMS 27 Light Terrace CI 64 62 SV11 MW19

        WMS 32 Holland Street R 16 -

        WMS 34 James Street R 11 -

        WMS 37 Dew Street R 44 -

        WMS 38 Maria Street CI and R 13000 56 SV2 MW5

        WMS 39 Maria Street CI and R 1300 SV4

        WMS 40 Admella Street CI 110000 97 SV5 MW02

        WMS 41 George Street CI 18000 10 SV7 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

        Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform (up to 530 microgm3) was also detected in WMS 8 WMS 11 WMS 14 WMS 16 WMS 18 WMS 19 WM 25 WMS 33 WMS 40 and WMS 41 interim soil vapour health investigation level (HIL)

        Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units

        Bore ID

        Depth (m)

        Location CHC concentration (microgm3)

        TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

        WMS 8 10 Maria Street 12000 37 lt95 lt99 lt22 lt36

        WMS 38 13000 56 lt11 lt11 lt25 lt41

        Relative percentage difference 8 147 - - - -

        WMS 11 10 Admella Street 71000 260 19 20 36 lt37

        WMS 40 110000 97 lt11 lt11 lt25 lt41

        Relative percentage difference 43 91 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

        80607-1 REV1 30102017 PAGE 33

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        73 Groundwater

        731 Field measurements

        A table of groundwater field parameters is presented in Appendix L (Table 3) and groundwater field sampling sheets are included in Appendix E

        7311 Groundwater elevation and flow direction

        The depth to water within the Q1 aquifer beneath the Thebarton EPA Assessment Area on 18 July 2017 ranged from 12323 to 15854 m below top of casing (BTOC)10 and 4469 to 5070 m AHD

        Groundwater elevation contours constructed from the July 2017 gauging data indicated that the overall groundwater flow direction within the Q1 aquifer was north-westerly consistent with expected regional groundwater flow The groundwater contours and inferred flow direction are shown on Figure 4

        7312 Field parameters

        As detailed in Table 51 field measurements were recorded during low flow purging (ie prior to micropurge sampling) of monitoring wells and immediately following the collection of HydraSleeveTM samples

        The field parameter readings recorded for the monitoring wells immediately prior to (low flow micropurge) and after (HydraSleeveTM) sampling indicated the following (as summarised in Table 3 Appendix L)

        groundwater pH ranged from 6 8 to 79 thereby indicating neutral conditions

        electrical conductivity (EC) measurements ranged from 189 to 556 mScm and were found to be reasonably consistent across the area thereby indicating that it is underlain by moderately saline water (ie approximating 1230 to 3620 mgL TDS11)

        redox concentrations ranged from -20 to 624 mV thereby indicating slightly reducing to strongly oxygenating conditions

        measured dissolved oxygen (DO) concentrations ranged from 04 to 78 ppm indicating slightly to highly oxygenated water and

        temperature ranged from 173 to 224oC

        Observations recorded during sampling indicated that the groundwater was clear to brown and only slightly to moderately turbid at most locations ndash the higher turbidity at MW18 and MW19 (combined with poor recharge) contributed towards the decision to use a HydraSleeveTM sampling method No odours or sheen were observed in any of the wells during gauging or sampling

        10 ie approximating m BGL 11 ie calculated by multiplying the field EC data by 065

        PAGE 34 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        732 Hydraulic conductivity

        Rising and falling head aquifer permeability (ldquoslugrdquo) tests were conducted on 10 groundwater wells (refer to Table 31 and Figure 2) to assess the hydraulic conductivity (K) of the Q1 aquifer

        To obtain estimates of near-well horizontal hydraulic conductivity for each well tested the slug test data were analysed by Arcadis using AQTESOLV for Windowstrade (Duffield 2007) following the guidelines presented in Butler (1998) ndash normalised displacement data collected from each test are plotted against time in Appendix A of the Arcadis report (refer to Appendix O) Since only one set of tests were performed at each well the reproducibility of the results as well as the dependence of the results on the initial displacement could not be verified or demonstrated As such multiple relevant and applicable solutions were applied to each test to account for that uncertainty (ie to ensure consistency of normalised response at each well regardless of initial displacement)

        Table 73 presents a summary of the range and average estimated hydraulic conductivity values (and corresponding analytical solutions used) for each well tested The results indicate that hydraulic conductivities ranged from approximately 0073 to 37 mday with an overall average of approximately 1 mday

        Table 73 Hydraulic conductivities (rising and falling head tests)

        Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

        (mday) Hydraulic Conductivity

        (mday)

        MW02 Falling head 011 to 014 DA CBP HV

        012 Rising head 0073 to 015 BR DA

        MW3 Falling head 034 to 062 BR DA

        047 Rising head 030 to 062 BR DA

        MW7 Falling head 075 to 25 BR DA

        139 Rising head 055 to 175 BR DA

        MW14 Falling head 011 to 021 BR DA

        014 Rising head 009 to 015 BR DA

        MW17 Falling head 21 to 22 DA KGS

        220 Rising head 225 to 244 DA KGS

        MW20 Falling head 22 to 37 BR DA HV

        256 Rising head 06 to 32 BR DA

        MW21 Falling head 073 to 123 BR DA

        084 Rising head 054 to 084 BR DA

        MW23 Falling head 088 to 162 BR DA

        101 Rising head 031 to 122 BR DA

        80607-1 REV1 30102017 PAGE 35

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

        (mday) Hydraulic Conductivity

        (mday)

        MW25 Falling head 10 to 18 BR DA CBP HV

        132 Rising head 049 to 17 BR DA

        MW26 Falling head 019 to 036 BR DA

        023 Rising head 010 to 029 BR DA

        Overall average K (mday) 1028 Notes References BR = Bouwer and Rice (1976) CBP = Cooper et al (1967) DA = Dagan (1978) HV = Hvorslev (1951) KGS = Hyder et al (1994)

        The monitoring wells that exhibited lower permeabilities (ie MW02 MW3 MW14 and MW26) were noted to be generally located in the up-gradient (south-eastern) portion of the Thebarton EPA Assessment Area whereas monitoring wells showing relatively higher permeabilities (ie MW7 MW17 MW20 MW21 MW23 and MW25) are generally located in the down-gradient (north-western) portion These results were considered by Arcadis to suggest a possible hydrogeologic transition from the south-east to the north-west AQTESOLV solution plots for each analysis are provided as Appendix A of the Arcadis report (Appendix O)

        As slug test results can be influenced by a number of factors which are difficult to avoid when performing and analysing slug test results hydraulic conductivity estimates derived from slug tests should be considered to be the lower bound of the hydraulic conductivity of the formation in the vicinity of the well (Butler 1998) However Arcadis also noted that the results obtained for the Thebarton EPA Assessment Area were similar to those reported for other areas of Adelaide with average values of 1 and 27 mday (refer to Appendix O)

        The slug test results were used by Arcadis in their groundwater fate and transport model (refer to Section 8)

        733 Analytical results

        Tables of groundwater analytical results are presented in Appendix L (Tables 4 and 5) and copies of certified laboratory reports are included in Appendix G

        7331 Chlorinated hydrocarbon compounds

        A table of CHC results is included in Appendix L (Table 4) and a plan showing their distribution in groundwater beneath the Thebarton EPA Assessment Area is included as Figure 5 Detectable CHC concentrations are summarised in Table 74 relative to the adopted potable and primary contact recreation criteria ndash the closest soil vapour bore locations are also detailed

        PAGE 36 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Table 74 Detectable groundwater CHC results

        Sample ID

        Location CHC concentration (microgL) Closest soil vapour bore

        TCE PCE cis-12shyDCE

        trans-12-DCE

        11-DCE VC Carbon tetrachloride

        MW02 Admella Street 20000 38 7 15 SV5

        MW3 Admella Street 69 SV1

        MW5 Maria Street 29000 3 21 2 6 SV2 SV3

        MW6 Maria Street 29 SV4

        MW9 Albert Street 2 -

        MW11 George Street 4900 3 4 1 7 SV6 SV7

        MW12 George Street 700 SV8

        MW14 Admella Street 1000 4 2 SV9

        MW15 Albert Street 180 SV10

        MW17 Chapel Street 24 -

        MW18 Dew Street 5 -

        MW20 Light Terrace 70 SV12

        MW21 Light Terrace 23 SV13

        MW23 Dew Street 21 -

        MW25 Smith Street 2 5 -

        MW26 Kintore Street 2 -

        Potable 20 50 60 30 03 3

        Primary contact recreation

        30 500 600 300 30 30

        Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Chloroform was also detected in a number of wells (MW02 MW3 MW5 MW8 MW11 MW12 and MW19 to MW25) ndash refer to Table 4 in Appendix L Although no VC was detected the laboratory LOR (1 microgL) exceeded the adopted potable criterion NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from WHO (2017) Guidelines for Drinking-water Quality NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

        The results indicate that the highest TCE concentrations (20000 to 29000 microgL) were measured in wells MW02 and MW5 located in the immediate vicinity of the former Austral property and that the TCE plume extends in a general north-westerly direction (ie consistent with the inferred groundwater flow direction

        80607-1 REV1 30102017 PAGE 37

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        within the Q1 aquifer) Although lesser concentrations of PCE 12-DCE (cis- andor trans) andor 11-DCE were present in some wells no VC was detected and the main COPC was identified as TCE

        A number of wells within the Thebarton EPA Assessment Area contained TCE concentrations that exceeded the adopted potable andor primary contact recreation criteria Although the extent of the TCE plume was not delineated to the north-west (but was delineated in all other directions) with detectable TCE concentrations (ie up to 21 microgL) identified beneath both Smith Street and Dew Street these concentrations were below the adopted primary contact recreation criterion (but not necessarily the adopted potable value ndash ie MW23)

        The background well (MW4) located across James Congdon Drive (to the east of the southern portion of the Thebarton EPA Assessment Area) did not contain any measurable CHC concentrations

        7332 Other measured groundwater parameters

        Major cations and anions

        The laboratory results obtained for the remaining groundwater analytes are summarised in Appendix L (Table 5)

        The groundwater ionic data obtained from selected wells across the Thebarton EPA Assessment Area are graphically represented on a Piper diagram in Figure 71 The results indicate a relatively consistent groundwater composition across the area thereby indicating that the groundwater sampled from these wells is derived from a single aquifer Ionic charge balance ranged from 32 to 22 with the highest value (22) calculated for MW12 indicating that additional anions (ie not measured as part of this study) could be present

        PAGE 38 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Figure 71 Piper diagram

        Natural attenuation parameters

        With respect to the measured natural attenuation parameters (ie DO nitrate iron sulfate CO2 and manganese) the following wells were selected based on their locations relative to the inferred extent of the CHC plume

        MW26 located on Kintore Street to the south (and hydraulically up-gradient) of the former Austral property (ie the suspected source site)

        MW02 and MW5 located within the immediate vicinity of the former Austral property and the area of maximum CHC contamination

        MW9 MW12 and MW17 located on Albert Street George Street and Chapel Street respectively to the north-west (and hydraulically down-gradient) of the former Austral property

        80607-1 REV1 30102017 PAGE 39

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        MW21 and MW22 located on Light Terrace and Cawthorne Street respectively to the northshywestnorth-north-west (and further hydraulically down-gradient) of the former Austral property and

        MW8 and MW23 located on Smith Street and Dew Street respectively representing the furthest wells to the northnorth-west of the former Austral property

        According to Wiedemeier et al (1998) the most important process in the degradation of CHC is the process of reductive dechlorination Although daughter products of TCE (ie 12-DCE) are present in groundwater (and soil vapour) at scattered locations within the Thebarton EPA Assessment Area they are not considered indicative of substantial breakdown of TCE ndash refer also to the Arcadis report in Appendix O as summarised in Section 8 In addition the analysis of the natural attenuation parameters data constituting physical and chemical indicators of biodegradation processes has not provided a definitive secondary line of evidence

        74 Soil vapour bores A table of soil vapour bore analytical results is presented in Appendix L (Table 6) and a copy of the certified laboratory report is included in Appendix G

        Of the soil vapour bores installed to 10 andor 30 m BGL within the Thebarton EPA Assessment Area the majority (ie with the exception of the 10 m deep bores installed as SV11 and SV13 and located on Light Terrace) returned measurable concentrations of CHC dominated by TCE and to a lesser extent (and only at some locations) PCE Detectable soil vapour CHC concentrations are summarised in Table 75 whereas CHC concentrations and inferred soil vapour TCE concentration contours are detailed on Figures 6 (1 m BGL) and 7 (3 m BGL)

        The TCE results which have been used to predict indoor air concentrations as part of the VIRA (refer to Section 9) suggest the following

        the highest concentration (1000000 microgL) was detected at 3 m BGL in soil vapour bore SV3 located in the vicinity of residential and commercialindustrial properties (including the former Austral property) on Maria Street

        where nested wells were tested soil vapour CHC concentrations were higher at depth consistent with a groundwater source

        TCE PCE and 11-DCE are all assumed to represent primary contaminants with 12-DCE representing a break-down product of TCE andor PCE

        although no VC was detected the laboratory LOR in some samples (ie up to 490 microgm3 in samples with the highest measured TCE concentrations) was above the ASC NEPM (1999) interim soil vapour HIL for residential land use (30 microgm3) ndash refer to Table 53 and

        although the extent of the soil vapour plume has apparently not been delineated (ie in any direction) by the existing soil vapour bores it extends in a north-westerly direction (and hydraulically down-

        PAGE 40 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        gradient) from the suspected source site (ie the former Austral property) and corresponds well with the groundwater TCE plume (refer to Figure 5)

        A comparison of the results obtained for the WMStrade units (WMS 38 to WMS 41) deployed during the second round of sampling and the closest soil vapour bore data (10 m BGL) is provided in Table 76 Although the results indicate good correlation for TCE and PCE in SV5WMS 40 as well as TCE in SV7WMS 41 the remaining results were more variable ndash this supports the use of the WMStrade units as an initial (semishyquantitative) screening tool with follow-up soil vapour bore data considered to provide more quantitative results

        Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area

        Bore ID

        Depth (m)

        Location Closest land

        uses

        CHC concentration (microgm3)

        TCE PCE cis-12shyDCE

        trans-12-DCE

        11-DCE VC

        SV1 10 Admella Street CI and R 6300 78

        30 21000 21

        SV2 10 Maria Street CI and R 51000 39 21 39

        30 940000

        SV3 10 Maria Street CI and R 210000 6500 5900

        30 1000000 15000 14000

        SV4 10 Maria Street CI and R 17000 31

        30 43000 90 30

        SV5 10 Admella Street CI 100000 84

        30 160000 310 20 33

        SV6 10 George Street CI 22000 12

        30 150000 56

        SV7 10 George Street CI 22000 19

        30 110000

        SV8 10 George Street CI 2300 62

        30 14000 19

        SV9 10 Chapel Street CI 170

        30 260

        SV10 10 Albert Street CI 93

        30 51

        SV12 10 Light Terrace CI 16

        30 55 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

        Notes Shaded cells indicate concentrations were below the laboratory LOR

        80607-1 REV1 30102017 PAGE 41

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Where (field andor laboratory) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform was also detected in a number of samplesinterim soil vapour health investigation level (HIL)

        Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores

        Bore ID

        Depth (m)

        Location CHC concentration (microgm3)

        TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

        SV2 10 Maria Street 51000 39 21 lt13 39 lt89

        WMS 38 13000 56 lt11 lt11 lt25 lt41

        Relative percentage difference 119 150 - - - -

        SV4 10 Maria Street 17000 31 lt18 lt14 lt14 lt92

        WMS 39 1300 lt52 lt11 lt11 lt25 lt41

        Relative percentage difference 172 - - - - -

        SV5 10 Admella Street 100000 84 lt44 lt33 lt33 lt22

        WMS 40 110000 97 lt11 lt11 lt25 lt41

        Relative percentage difference 95 14 - - - -

        SV7 10 George Street 22000 19 lt37 lt27 lt27 lt18

        WMS 41 18000 10 lt11 lt11 lt25 lt41

        Relative percentage difference 20 62 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

        PAGE 42 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        8 GROUNDWATER FATE AND TRANSPORT MODELLING

        Arcadis were commissioned by Fyfe to undertake preliminary fate and transport modelling of the groundwater CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained groundwater data The Arcadis report is included as Appendix O

        The aim of the modelling was to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton area in order that potential future groundwater restrictions could be applied by the EPA (ie via the potential future definition of a GPA) to protect human health

        81 Groundwater flow modelling

        The MODFLOW code a publicly-available groundwater flow simulation program developed by the United States Geological Survey (USGS) as described by McDonald and Harbaugh (1988) was used to construct a groundwater flow model It was developed for a horizontal area of approximately 25 km2 (ie to minimise possible boundary effects within the assessment area itself12) and was rotated 45deg counter-clockwise to align with the prevailing (north-westerly) groundwater flow direction The model extended approximately 23 km in a south-east to north-west direction and approximately 11 km in a south-west to north-east direction (ie perpendicular to groundwater flow) Whereas a 4 m grid spacing was used within the area of the plume and its migration pathway (ie to enhance model accuracy and precision) a broader 15 m grid was adopted outside the specific area of interest Vertically the model adopted a single 20 m thick layer as representative of the hydrostratigraphy of the Q1 aquifer sediments beneath the area but it was noted that only the bottom portion (ie few metres) of this model layer are actually saturated and therefore active in the model

        An informal sensitivity analysis performed as part of the model calibration process indicated that the model was most sensitive to changes in hydraulic conductivity and recharge ndash this was not unexpected given the relatively flat hydraulic gradient and relatively narrow range of estimated values for both model parameters (ie based on reasonably low uncertainty) The final calibrated value for aquifer recharge adopted in the model was 295 mmyear consistent with results reported for nearby sites as well as regional estimates Likewise the final calibrated hydraulic conductivity values for the up-gradient (06 mday) and down-gradient (2 mday) zones were consistent with both the site-specific slug test data and results obtained for other nearby EPA assessment areas The final calibrated down-gradient constant head elevation was 15 m AHD It was concluded by Arcadis that the groundwater flow model was well calibrated and could therefore serve as an appropriate basis for the development of a site-specific solute transport model

        82 Solute transport modelling

        A site-specific (three-dimensional) solute transport model using the MT3DMS transport code of Zheng (1990) was developed by Arcadis to predict the fate and transport of groundwater contaminants (specifically

        12 Further information regarding boundary effects is provided in the Arcadis report (Appendix O)

        80607-1 REV1 30102017 PAGE 43

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        CHC) under current conditions over a period of 100 years This dual-domain mass transport model was used in conjunction with the groundwater flow model developed through the use of MODFLOW (as detailed above) assuming the following

        The primary COPC is TCE ndash the initial concentration distribution of TCE in groundwater was based on the recent (July 2017) monitoring data

        The age of the groundwater TCE plume was assumed to be up to about 90 years ndash ie based on the history of industrial land use (specifically the former Austral facility) in the area

        Although lesser amounts of other CHC are present in groundwater the lack of significant daughter products of TCE has been interpreted to indicate that substantial biodegradation is not occurring (ie as a conservative approach)

        Although a CHC source was not explicitly incorporated into the solute transport model the MT3DMS transport code indirectly accounts for on-going contaminant mass contribution to the dissolved-phase plume

        The fate and transport of TCE within the area of interest involves the processes of advection adsorption dilution and diffusion ndash however given that recharge via the infiltration of precipitation was considered to be insignificant dilution effects were assumed to be minimal

        Two porosity values (ie dual domain) are relevant to the movement of contaminants in the subshysurface with adopted values based on site-specific geology and Payne et al (2008) ndash whereby the two domains are in equilibrium

        ― mobile porosity that portion of the formation with the highest permeability where advective transport dominates ndash assumed to be 5 (high) 10 (intermediate) or 15 (low) for different mobility transport conditions and

        ― immobile porosity lower permeability portions of the formation where diffusion is dominant ndash assumed to be 15

        As discussed in Section 732 hydraulic conductivity values of 06 mday (south-eastern approximate quarter of the modelling area) and 2 mday (northern approximate three-quarters of the modelling area) were adopted to reflect the hydrogeologic transition (ie from the south-east to the north-west) interpreted from the slug test data

        The adopted TCE retardation factor of 147 for intermediate mobility transport conditions was based on the following

        ― an assumed organic carbon fraction of 01 (US EPA 1996 amp 2009) ndash this was varied to 005 and 2 to assess alternate (ie high versus low) mobility transport conditions

        ― an assumed organic carbon adsorption co-efficient of 61 Lkg (US EPA 2017a)

        PAGE 44 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        ― a calculated partition co-efficient of 0061 Lkg ndash this was varied to 129 and 178 Lkg to assess alternate (ie high versus low) mobility transport conditions and

        ― an average soil bulk density of 192 gcm3 (based on measured geochemical data ndash refer to Table 1 Appendix L)

        An optimum mass transfer co-efficient (MTC) was based on simulated flux distribution in the groundwater flow model whereby

        ― the calculated MTC in the model ranged from approximately 38E-08day-1 to 37E-05 day-1 and

        ― the average MTC was 185E-05day-1

        The site-specific solute transport model was used in predictive mode to assess the long-term (eg 100 year) potential migration of the groundwater TCE plume and to support the EPA in the potential future definition of an appropriate GPA The model was calibrated against the current extent (ie concentrations of TCE above 1 microgL have migrated approximately 500 m from the suspected source site13) and expected age (ie up to about 90 years) of the plume The results indicate that the leading edge of the TCE (ie the 1 microgL contour) is estimated to migrate between approximately 400 and 620 m over a period of 100 years under low to high mobility transport conditions14 with intermediate transport conditions resulting in an estimated migration of 500 m By comparison no significant lateral plume expansion would be expected to occur Figures 5 to 17 of the Arcadis report (Appendix O) show the predicted extent of the TCE plume at 5 10 50 and 100 years under low to high mobility transport conditions

        Figure 81 shows the predicted extent of the 1 microgL TCE boundary in 100 years under intermediate transport conditions ndash it is recommended that this information be used to support the EPA in establishing a potential future GPA

        The Arcadis report notes that given the available site information (site history potential source area(s) and uncertainty associated with the current plume extent) and degree of model calibration (flow model parameter values are consistent with site-specific data as well as regionalnearby studies while transport parameter values are consistent with literatureindustry standards) the model-predicted migration of approximately 500 m over 100 years is considered to be a reasonable representation of future conditions

        Key uncertainties associated with the modelling were identified as including the following

        current plume extents (ie down-gradient delineation)

        site-specific fraction organic values (or site-specific partition coefficient estimates) and

        site-specific porosity estimates

        13 although it was noted that there is uncertainty with respect to the current extent of the TCE plume since all three down-gradient monitoring wells (MW18 MW23 and MW25) have TCE concentrations above 1 μgL

        14 ie assuming different values for mobileimmobile porosity the TCE distribution (sorption) coefficient and the TCE retardation factor

        80607-1 REV1 30102017 PAGE 45

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Lesser uncertainties were considered to include site-specific bulk hydraulic conductivity estimates and determination of the presence or absence of naturally-occurring TCE degradation

        Additional site investigation and data collection (eg multi-well pumping tests for bulk hydraulic conductivity estimates site-specific fraction organic carbon andor distribution (sorption) coefficient additional down-gradient plume delineation) would help to further refine the model and increase confidence in the predictive results

        Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green) relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple)

        PAGE 46 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        9 VAPOUR INTRUSION RISK ASSESSMENT

        Arcadis were commissioned by Fyfe to undertake a Vapour Intrusion Risk Assessment (VIRA) of the soil vapour CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained (ie August 2017) permanent soil vapour bore data The Arcadis report is included as Appendix P

        91 Objective

        The main objective of the VIRA was to evaluate the potential risk to human health from vapour intrusion related to the concentrations of CHC identified in soil vapour within the Thebarton EPA Assessment Area

        92 Areas of interest

        The following areas of specific interest (ie located within the Thebarton EPA Assessment Area) were identified for the purpose of this VIRA

        commercialindustrial properties (assumed slab on grade construction) including the former Austral property (ie the suspected source site) and

        residential properties (slab on grade crawl space and basement constructions)

        Potential exposure by trenchmaintenanceutility workers has also been considered (qualitatively)

        93 Risk assessment approach

        The VIRA was conducted in accordance with the ASC NEPM (1999) enHealth (2012a) and other relevant Australian guidance documents as well as guidance documents issued by the US EPA and other international regulatory agencies (where applicable)

        The conduct of the risk assessment was based on a multiple lines of evidence approach using the available site-specific information collected as part of the scope of works detailed in Section 32

        The following information was used as a basis for the VIRA

        CHC including TCE PCE and DCE (11- cis-12- and trans-12-) have been identified within soil vapour andor groundwater within the Thebarton EPA Assessment Area ndash the analytical data indicate that TCE constitutes between about 95 and 100 of the CHC identified in groundwater and soil vapour

        TCE has been considered as the risk driver for the VIRA (ie based on its toxicity and concentrations in soil vapour and groundwater) ndash although TCE PCE 12-DCE 11-DCE and VC have all been included as COPC for the Tier 1 screening assessment (Section 94) the Tier 2 assessment (Section 95) has

        80607-1 REV1 30102017 PAGE 47

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        concentrated on TCE PCE and 11-DCE (ie due to their presence at concentrations that exceeded the adopted Tier 1 screening criteria)

        The CHC identified within the Thebarton EPA Assessment Area are volatile chemicals and could potentially pose a risk to human health via the vapour intrusion pathway Although the source area has yet to be confirmed the CHC concentrations observed in groundwater and soil vapour are considered likely to have originated from the former Austral property (as discussed in Section 12)

        The natural soils underlying the fill material (where present) in the Thebarton EPA Assessment Area are typified by the Quaternary age soils and sediments of the Adelaide Plains with the Pooraka Formation and Hindmarsh Clay units considered to dominate the upper soil profile

        The soil geotechnical data and soil vapour results collected by Fyfe (as discussed in Sections 712 and 74 respectively) have been used for the VIRA

        A two-tier approach was adopted for the VIRA The first tier (herein referred to as the Tier 1 assessment) was conducted by comparing the measured soil vapour TCE concentrations to published guideline values adjusted (conservatively) to account for attenuation from sub-slab soil into indoor air The second tier (herein referred to as the Tier 2 assessment) involved the comparison of predicted indoor air TCE concentrations to adopted indoor air criteria or response levels

        94 Tier 1 assessment

        As detailed in Section 74 the initial Tier 1 (screening risk) assessment involved comparing measured soil vapour COPC concentrations with the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land uses (refer to Table 74) Given that the development of the interim soil vapour HILs was based on very conservative assumptions the initial Tier 1 assessment provided only a first-pass screening assessment of the data to determine if further risk assessment would be required

        The interim soil vapour HILs are applicable for the assessment of soil vapour at 0 to 1 m beneath the floor of a building They were based on adopted toxicity reference values (TRV) and relevant exposure parameters (ie adjusted for different land uses) as well as an assumed soil vapour to indoor air attenuation factor of 01

        The soil vapour to indoor air attenuation factor (01) was based on the US EPA (2002) recommended default attenuation factors for the generic screening step of a tiered vapour intrusion assessment process As discussed in the US EPA (2002) document the default attenuation factor of 01 for sub-slab soil vapour was based on a US EPA database of empirical attenuation factors calculated using measurements of indoor air and soil vapours from different sites In 2012 the US EPA provided an updated database which was accompanied by an evaluation and statistical analysis of attenuation factors for volatile CHC in residential buildings US EPA (2012) found the sub-slab to indoor air attenuation factor of 003 to be the 95th percentile In 2015 the revised sub-slab attenuation factor (003) was adopted by the US EPA

        PAGE 48 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        The revised sub-slab to indoor air attenuation factor of 003 was adopted to derive modified residential and commercialindustrial soil vapour HILs for the Tier 1 assessment The modified residential soil vapour HILs are presented in Table 91 relative to the maximum CHC concentrations obtained for soil vapour within the Thebarton EPA Assessment Area

        The Tier 1 assessment based on a comparison of the COPC concentrations measured in soil vapour at various locations within the Thebarton EPA Assessment Area with the modified residential soil vapour HILs detailed in Table 91 indicated the following

        TCE concentrations exceeded the adopted criterion in SV1 to SV9 whereas

        the concentrations of PCE and 11-DCE exceeded the adopted criteria in SV3 only

        These locations were identified as requiring further assessment (ie Tier 2 VIRA ndash refer to Section 95)15

        Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs

        Compound ASC NEPM (1999) HIL

        (microgm3)

        Modified Tier 1 HIL (microgm3)

        (AF = 003)

        Maximum measured soil vapour concentration (microgm3)

        Acceptable

        Location 1 m BGL Location 3 m BGL

        11-DCE 7000 SV3 5900 SV3 14000 No ndash Tier 2 required

        cis-12-DCE 80 265 SV2 21 SV4 30 Yes

        trans-12-DCE 80 265 - ND SV5 20 Yes

        PCE 2000 6650 SV3 6500 SV3 15000 No ndash Tier 2 required

        TCE 20 65 SV3 210000 SV3 100000 0

        No ndash Tier 2 required

        VC 30 100 - ND - ND Yes Notes Values in bold exceed the modified residential soil vapour HILs cis-12-DCE HIL adopted as surrogate screening criterion based on US EPA (2017b) regional screening level for residential air elevated laboratory LOR (ie above modified Tier 1 HIL) also reported Abbreviations AF = attenuation factor HIL = health investigation level ND = non detect

        95 Tier 2 assessment

        951 Tier 2 assessment criteria

        The Tier 2 VIRA criteria for the residential zone comprise HIL-based residential indoor air criteria for the COPC (refer to Section 94) along with the residential indoor air level response ranges for TCE that were

        15 Note that all locations were subjected to the Tier 2 VIRA in this assessment

        80607-1 REV1 30102017 PAGE 49

        EPA REF 0524111 FINAL REPORT

        STAGE 1 ENVIRONMENTAL ASSESSMENT

        THEBARTON ASSESSMENT AREA

        initially developed by the EPA and SA Health for the EPA Assessment Area at Clovelly Park and Mitchell

        Park These screening criteria and indoor air response ranges as detailed in SA EPA (2014) and

        reproduced in Figure 91 are now widely adopted in South Australia for the assessment of TCE relating

        to indoor air exposure

        Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels

        Note The no action response level is applicable where a soil vapour concentration is below the laboratory LOR (ie ND or ldquonon-

        detectrdquo assumed to be lt01 microgm3)

        PAGE 50 80607-1 REV1 | 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        952 Vapour intrusion modelling

        For this VIRA exposure point concentrations (EPCs) of COPC in the indoor air of buildings with a slab on grade crawl space or basement construction were estimated using conservative screening assumptions and the Johnson and Ettinger (1991) vapour transport and mixing model (ie the JampE model)

        The algorithms applied in the JampE (1991) model are detailed in Appendix A of the Arcadis report whereas the modelling spreadsheets for each scenario are provided in Appendix B ndash the Arcadis report is attached to this report as Appendix P

        9521 Input parameters

        The input parameters adopted for the vapour intrusion modelling relate to the following

        the construction type and details of existing or proposed buildings ndash refer to Table 92 for adopted building input parameters

        the nature of the soil profile ndash refer to Table 93 for adopted soil input parameters (0 to 1 m BGL) and

        the contaminant source concentrations ndash refer to Table 6 in Appendix L

        Table 92 Tier 2 vapour intrusion modelling ndash building input parameters

        Parameter Units Adopted value Reference

        Residential Commercial industrial

        Width of Building cm 1000 2000 Friebel and Nadebaum (2011)

        Length of Building cm 1500 2000

        Height of Room cm 240 300

        Height of crawl space cm 30 - Assumption for crawl space

        Attenuation from basement to ground floor air

        - 01 01 Friebel and Nadebaum (2011)

        Air Exchange Rate (AER)

        Indoor per hour 06 083 Friebel and Nadebaum (2011)

        Crawl space per hour 06 - Friebel and Nadebaum (2011)

        Basement per hour 06 - As per residential (indoor)

        Fraction of Cracks in Walls and foundation

        - 0001 0001 Friebel and Nadebaum (2011)

        Qsoil cm 3s 300 277 Calculated from QsoilQbuilding ratio of 0005 (residential) and 0001 (commercial)

        80607-1 REV1 30102017 PAGE 51

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters

        Parameter Units Adopted value Reference

        Depth cm 100 Depth of shallow soil vapour data

        Total porosity - 047 Site specific geotechnical data ndash ie averaged from MW3 and MW11 shallow samples (refer to Table 1 in Appendix L) Air filled porosity - 030

        Water filled porosity - 017 Notes ie representing a conservative approach whereby data for the shallow samples with the highest total porosity and lowest degree of saturation (and therefore the highest air filled porosity) have been adopted

        The site specific attenuation factors calculated within the vapour intrusion models (Appendix B of the Arcadis report) are summarised in Table 94 These are chemical and depth specific values applicable to each building construction scenario These attenuation factors have been applied to the soil vapour data measured across the Thebarton EPA Assessment Area to calculate indoor air concentrations (residential properties only) in proximity to each soil vapour location ndash for commercialindustrial properties (slab on grade) indoor air concentrations have only been calculated with respect to the soil vapour data obtained for SV3 (ie the soil vapour bore with the highest measured TCE concentrations)

        Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air

        Scenario Attenuation factor

        Residential ndash slab on grade 706 x 10-4

        Residential ndash crawl space 209 x 10-3

        Residential ndash basement 113 x 10-1

        Commercial ndash slab on grade 408 x 10-4

        Notes ie soil vapour intrusion to indoor air of residential living spaces refer to Section 953 for a discussion of potential vapour intrusion risks associated with commercialindustrial properties

        The chemical parameters of the COPC adopted in the JampE model were updated with data from the chemical database in the Risk Assessment Information System (RAIS 2016) as detailed in Table 95

        Table 95 Summary of chemical parameters adopted for vapour intrusion modelling

        Chemical Diffusivity in Air Diffusivity in Water Solubility Henryrsquos Law Molecular weight (Dair) Water (Dwater) (S) Constant 25oC (gmol)

        (cm2s) (cm2s) (mgL) (unitless)

        11-DCE 00863 0000011 2420 107 969

        PCE 00505 000000946 206 0724 166

        TCE 00687 00000102 1280 0403 131

        PAGE 52 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        9522 Predicted indoor air concentrations

        Residential The predicted indoor air concentrations for each soil vapour data point as calculated by Arcadis for the three residential building scenarios (ie slab on grade crawl space and basement) are presented in Appendix C of the Arcadis report (included in this report as Appendix P)

        Table 96 provides a comparison of predicted indoor air concentrations against the EPA response levels detailed in Section 951 (Figure 91) ndash ie using the 1 m soil vapour data space for slab on grade and crawl space scenarios versus the 3 m soil vapour data for basements

        It should be noted that if residential properties within the Thebarton EPA Assessment Area have basements however the vapour intrusion risks will increase whereas slab on grade construction will carry a lesser vapour intrusion risk (as detailed in Table 96)

        Commercialindustrial The predicted indoor air concentrations as calculated by Arcadis for a commercialindustrial (ie slab on grade) land use scenario with respect to the soil vapour data obtained for SV3 (ie maximum measured soil vapour concentrations) are as follows

        11-DCE 3 microgm3

        PCE 19 microgm3 and

        TCE 86 microgm3

        As these values are not directly comparable to the EPA response levels developed for residential land use further discussion of potential vapour intrusion risks to human health under a commercialindustrial land use

        scenario is included in Section 953

        As discussed for residential properties the vapour intrusion risks may increase if basements are present

        80607-1 REV1 30102017 PAGE 53

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Table 96 Comparison of predicted residential indoor air concentrations with SA EPA response levels

        Indoor Air Concentration Ranges (microgmsup3) SA EPA response levels

        non-detect No action

        gt non-detect to lt2 Validation

        2 to lt20 Investigation

        20 to lt200 Intervention

        ge200 Accelerated Intervention

        Soil vapour bore

        Sample depth

        (m)

        Soil vapour TCE concentration

        (microgmsup3)

        Predicted indoor air concentration (microgmsup3)

        Residential scenario

        Slab on grade Crawl space Basement

        Attenuation factor

        7 x 10-4 2 x 10-3 1 x 10-1

        SV1 10 5700 4 11

        SV1 30 21000 2100

        SV2 10 51000 36 102

        SV2 30 890000 89000

        SV2 (FD) 30 940000 94000

        SV3 10 210000 147 420

        SV3 30 1000000 100000

        SV4 10 17000 12 34

        SV4 30 43000 4300

        SV5 10 100000 70 200

        SV5 30 160000 16000

        SV6 10 22000 15 44

        SV6 (FD) 10 22000 15 44

        SV6 30 150000 15000

        SV6 (FD) 30 140000 14000

        SV7 10 22000 15 44

        SV7 30 110000 11000

        SV8 10 2300 2 5

        SV8 30 14000 1400

        SV9 10 170 012 030

        SV9 30 260 26

        SV10 10 9 0007 0019

        SV10 30 51 51

        SV11 10 lt18 - -

        SV12 10 16 0011 0032

        SV12 30 55 55

        SV13 10 lt21 - -

        PAGE 54 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Notes With respect to the predicted indoor air CHC concentrations in the Arcadis VIRA report (refer to Appendix P) the results in Table 5 were calculated for SV3 using the unrounded attenuation factors presented in Appendix B (and Table 94 of this report) whereas the TCE indoor air concentrations in Appendix C (as summarised in Table 96) were calculated using rounded attenuation factors ndash this does not change the overall interpretation of the results Abbreviations FD = field duplicate

        9523 Sensitivity analysis

        Table 97 presents a qualitative sensitivity analysis for some of the input variables used in the modelling ndash it includes the range of practical values for each variable the value used in the risk assessment the relative model sensitivity and the uncertainty associated with the variable

        Although Arcadis note that a number of parameters used within the risk assessment have a moderate degree of uncertainty associated with them thereby suggesting that the modelling may be sensitive to changes in these parameters values used to define these parameters were selected to be conservative This is considered to have resulted in an assessment which is expected to be conservative and to over-estimate actual risk

        Table 97 Summary of model input parameters subjected to sensitivity analysis

        Input Range of values Value adopted Sensitivity of calculated input parameters variable

        Soil physical parameters

        Total porosity

        Varies by soil type generally 03 to 05

        047 Site-specific

        Indoor air concentrations will decrease with increasing total porosity Moderate sensitivity parameter decreasing by 50 will increase predicted concentration by a factor of 4

        Air filled porosity

        Varies by soil type generally 015 to 03

        03 Site-specific

        Indoor air concentrations will increase with increasing air filled porosity Moderate to high sensitivity parameter reduction by 50 decreases concentration by a factor of 10

        Water filled porosity

        Varies by soil type from 005 (fill or

        sand) to 03 (clay)

        017 Site-specific

        Negligible impact on predicted indoor air concentrations although may decrease with increasing moisture content Very low sensitivity parameter

        Building parameters

        Air exchange rate (AER)

        Varies from 05 hr-1

        in smaller buildings to gt2 hr-1

        06 hr-1 for residential structures

        083 hr-1 for commercial

        Indoor air concentrations will decrease with increasing air exchange Moderate sensitivity parameter has linear relationship with predicted concentrations conservative assumptions used

        80607-1 REV1 30102017 PAGE 55

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Input Range of values Value adopted Sensitivity of calculated input parameters variable

        Advective flow rates

        Varies depending on building size and

        AER

        300 cm3sec Calculated from building AER and

        ratio of 0005

        Indoor air concentrations will increase with increasing advective flow Low sensitivity parameter particularly within normal range of potential values The assumption that advective flow is occurring into a building at all times is generally conservative for Australian settings Advection is unlikely to occur under a crawl space home and diffusive transport is the dominant transport mechanism

        Building size Variable Variable consistent with

        Friebel and Nadebaum (2011)

        Indoor air concentrations decrease with increasing building volume

        Very low sensitivity parameter

        9524 Uncertainties

        The following uncertainties were identified in the Arcadis report (Appendix P)

        Vapour transport modelling

        The use of a model to predict the migration of vapour from a sub-surface source to indoor air requires the simplification of many complex processes in the sub-surface as well as the potential for entry and dispersion within a building or outdoor air To address this simplification the vapour models available (and adopted in this assessment) are considered to be conservative such that uncertainties are addressed through the overshyestimation of likely concentrations

        It should be noted that the vapour model used is designed to be a first tier screening tool and is considered likely to over-estimate air concentrations due to the incorporation of a number of conservative assumptions including the following

        chemical concentrations in soil vapour were assumed to remain constant over the duration of exposure (ie it was assumed that the source was non-depleting and not subject to natural biodegradation processes)

        the maximum reported soil vapour concentrations were assumed to be present beneath nearby dwellings and

        the occurrence of steady well-mixed vapour dispersion within the enclosed or ambient mixing space

        Overall the vapour modelling undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

        PAGE 56 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Toxicological Data

        In general the available scientific information involves the extrapolation of toxicity information from studies involving experimental laboratory animals with some validation of observable health effects obtained through epidemiological studies

        This may introduce two types of uncertainties into the risk assessment as follows

        those related to extrapolating from one species to another and

        those related to extrapolating from the high exposure doses usually used in experimental animal studies to the lower doses usually estimated for human exposure situations

        In order to adjust for these uncertainties toxicity values commonly incorporate safety factors that may vary from 10 to 10000

        Overall the toxicological data presented in this assessment are considered to be current and adequate for the assessment of risks to human health associated with potential exposure to the COPC identified The uncertainties inherent in the toxicological values adopted are considered likely to result in an over-estimation of actual risk

        953 Potential vapour intrusion risks associated with commercialindustrial properties

        An assessment of potential vapour intrusion risks to workers at commercialindustrial properties (slab on grade construction) within the Thebarton EPA Assessment Area was undertaken by Arcadis using the methodology published by US EPA (2009) and incorporated into the ASC NEPM (1999) This approach recommends adjustment of the measured or estimated contaminant concentrations in air to account for site specific exposures by the relevant receptors as follows

        Ca ET EF EDECinh = days hours AT 365 24 year day

        Where

        ECinh = Exposure Adjusted Air Concentration (mgm3) Ca = Chemical Concentration in Air (mgm3) ET = Exposure Time (hoursday) EF = Exposure Frequency (daysyear) ED = Exposure Duration (years) AT = Averaging Time (years)

        = 70 years for non-threshold carcinogens = ED for chemicals assessed based on threshold effects

        80607-1 REV1 30102017 PAGE 57

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Exposure parameters were selected from Australian sources (enHealth 2012b ASC NEPM 1999) for the receptor groups evaluated or were based on site specific factors Table 98 presents an overview of the parameters used whereas adopted inhalation TRVs are presented in Table 99

        Risk was characterised for threshold and non-threshold effects for the COPC ndash spreadsheets presenting the risk calculations are provided in Appendix B of the Arcadis report (as included in Appendix P) For commercialindustrial properties the non-threshold risk level was calculated to be 3 x 10-5 (compared to a target risk level of 1 x 10-5) whereas the threshold risk level was calculated to be 10 (compared to a target risk level of 1) ndash these results indicated a potentially unacceptable vapour intrusion risk to commercialindustrial workers in the vicinity of the maximum soil vapour CHC concentrations (ie at SV3 ndash worst-case scenario based on maximum soil vapour concentrations)

        Table 98 Exposure parameters ndash Commercialindustrial workers

        Exposure parameter Units Value Reference

        Exposure frequency days year 365 ASC NEPM (1999)

        Exposure duration years 30 ASC NEPM (1999)

        Exposure time indoors hoursday 8 ASC NEPM (1999)

        Averaging time

        Non-threshold

        threshold

        Years

        years

        70

        30 ASC NEPM (1999)

        Table 99 Adopted inhalation toxicity reference values

        COPC Toxicity reference values

        Non-threshold (microgm3)

        Reference Threshold (microgm3)

        Reference

        11-DCE NA - 80 ATSDR (1994)

        PCE NA - 200 WHO (2006)

        TCE 41 US EPA (2011) IRIS 2 US EPA (2011) IRIS Notes Abbreviations NA = not applicable

        954 Potential risks to trenchmaintenanceutility workers

        Although trenchmaintenanceutility workers may be exposed to soil vapour concentrations as measured at 1 m BGL due to the short-term nature of such works their total intakes of TCE and other CHC will be low Assuming that a trenchmaintenanceutility worker may be exposed to TCE for a limited number of working days throughout the year (eg 20 days of 8 hours duration within an excavation) their intake will be approximately one fiftieth of the intake of a resident (who is assumed to be exposed 21 hours a day for 365 days a year)

        PAGE 58 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Therefore the management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air)

        96 Conclusions

        On the basis of the available data and the assessment presented in the Arcadis VIRA report (Appendix P) the following conclusions were provided

        Health risks for residents due to the intrusion of CHC in soil vapour into residential buildings with a slab on grade crawl space or basement construction were calculated to be above the adopted EPA response levels and risks to residents may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

        Health risks for commercial workers due to the intrusion of CHC in soil vapour into buildings with a slab on grade construction were calculated to be above the adopted target risk levels and risks to workers may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

        In the absence of specific information regarding building construction within the Thebarton EPA Assessment Area the predicted indoor air concentrations calculated from the 1 m BGL soil vapour data for a residential crawl space scenario are summarised in Table 910

        Table 910 Summary of properties with predicted indoor air concentrations (residential crawl space) above adopted EPA response levels

        EPA response level No of residential properties affected Indoor air concentration (microgm3) Response

        non-detect to lt2 Validation 9

        2 to lt20 Investigation 10

        20 to lt200 Intervention 8

        ge200 Accelerated intervention 3 Notes According to information provided by the EPA there are approximately 130 residential properties located in the Thebarton EPA Assessment Area calculated on the basis of cadastral boundaries ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial facility ndash these data would therefore need to be confirmed via a property survey

        80607-1 REV1 30102017 PAGE 59

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        10 CONCEPTUAL SITE MODEL

        As detailed in Table 101 a CSM has been developed for the Thebarton EPA Assessment Area on the basis of historical information (as summarised in Section 12 as well as Appendices A and B) and the data obtained during the recent Fyfe investigation program

        Table 101 Summary of existing information for the Thebarton EPA Assessment Area

        Topic Summarised Information

        Site Characterisation

        Identification of Assessment Area

        An approximately 27 ha Assessment Area located within the suburb of Thebarton has been defined by the EPA The boundaries of this area are detailed in Section 21 and illustrated on Figure 1

        History of land use Properties located within the Thebarton EPA Assessment Area have been used for a mixture of commercialindustrial and low density residential land uses over time Current commercialindustrial properties include a beverage factory in the north-eastern portion of the assessment area a refrigeration equipment facility a car dealership two hotels (at least one of which has a cellarbasement) automotive and other workshops and the Ice Arena Former commercialindustrial activities have been identified as including a gas works a mechanicrsquos workshop sheet metal working facilities and a farm machinery manufacturer

        Historical investigations

        Reports provided to Fyfe by the EPA that pertain to previous investigations undertaken within the Thebarton EPA Assessment Area have been reviewed and summarised in Appendix A Additional historical information is included in Appendix B

        Local geology Natural soils encountered from the surfacenear surface to the maximum drill depth of 19 m BGL across the Thebarton EPA Assessment Area were considered to be indicative of the Quaternary Pooraka and Hindmarsh Clay formations Whereas fill materials (ie sand gravelcrushed rock andor silt) were encountered to depths of up to 09 m BGL at a number of sampling locations underlying natural soils comprised mainly low to medium plasticity silty or sandy clays with variable gravel contents Geotechnical testing of subsurface soil samples collected from 10 drill cores indicated that the PSD comprised predominantly claysilt with lesser components of sand andor gravel ndash these soil samples were mostly classified as Clay although some were classified as Sandy Clay or Clayey Sand According to Stapledon (1971) the Hindmarsh Clay unit typically contains many structural features and defects which greatly influence its permeability thereby resulting in potential preferential pathways for the vertical and lateral movement of soil vapour and groundwater Such features were not specifically observed during the recent drilling and soil logging work although some gravel lenseslayers were identified

        Hydrogeology In accordance with Gerges (2006) and his classification of the Adelaide metropolitan area into a number of zones based on their individual hydrogeological characteristics the Thebarton EPA Assessment Area is located within Zone 3 (subzone 3E) to the west of the Para Fault It contains five to six Quaternary aquifers and three or four Tertiary aquifers Based on the most recent investigations the depth to water within the Q1 aquifer in the Thebarton EPA Assessment Area ranges from approximately 123 to 159 m BGL and groundwater flows in a general north-westerly direction with a relatively flat hydraulic gradient (000062 to 00012) Salinity levels (based on field EC readings) range from approximately 1230 to 3620 mgL TDS and a groundwater flow velocity range of approximately 44 to 23 myear has

        80607-1 REV1 30102017 PAGE 61

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Topic Summarised Information

        been inferred As detailed in Section 222 a search of the DEWNR (2017) WaterConnect database identified 59 bores within the general Thebarton area of which 18 are located within the Thebarton EPA Assessment Area Although (where recorded) bores were listed as having been installed primarily for monitoring investigation or observation purpose other purposes (for presumed Quaternary aquifer bores) included drainage domestic and industrial A BUA has identified realistic groundwater uses as potentially including potable residential irrigation and primary contact recreationaesthetics Based on proximity to the River Torrens freshwater ecosystem protection has also been considered ndash however since the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area this may not be a realistic beneficial use Since volatile contaminants have been detected within the Q1 aquifer a potential vapour flux risk to future site users has also been considered

        Hydrology No surface water bodies have been identified within the Thebarton EPA Assessment Area The closest surface water body is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west Current stormwater run-off within the Thebarton EPA Assessment Area is expected to be collected by localised (and engineered) drainage systems

        Fyfe Investigation Results

        Groundwater impacts Contaminants identified in groundwater beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected source site (ie the former Austral sheet metal works) in accordance with the predominant flow direction associated with the Q1 aquifer (refer to Figures 4 and 5) The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) but its north-western extent has not yet been determined (whereas its extent has been defined in all other directions)

        Soil vapour impacts Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction (refer to Figures 6 and 7) and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion The soil vapour samples with the maximum TCE concentrations (ie SV3_10m and SV3_30m) also had the highest PCE and 11-DCE concentrations (or elevated LOR) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-) Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE (ie SV2_30m SV3_10m SV3_30m and SV7_30m) exceeded the adopted HILs for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE

        PAGE 62 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Topic Summarised Information

        degradation has not yet resulted in its production (ie at measureable levels) Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

        Potential Exposure Pathways

        Contaminants of Based on the results of historical investigations the EPA identified a number of CHC as being of Potential Concern concern for the Thebarton EPA Assessment Area The main COPC was identified as TCE with

        additional COPC including PCE 12-DCE (cis- and trans-) VC and 11-DCE Further detail is provided in Section 14 These COPC were confirmed by the Fyfe investigations with TCE identified as both the main contaminant in groundwater and soil vapour and the main driver in terms of potential human health risks associated with vapour intrusion into buildings within the Thebarton EPA Assessment Area (refer to Section 9)

        Suspected source and The suspected source of the identified CHC groundwater (and soil vapour) impacts within the affected media Thebarton EPA Assessment Area is the former Austral sheet metal works located over multiple

        allotments between George and Maria Streets from the 1920s until the 1960s-1970s Previous investigations (Appendix A) had identified groundwater CHC impacts on part of this suspected source site The Fyfe investigations have concentrated on impacts within groundwater and soil vapour across the Thebarton EPA Assessment Area both of which generally correlate with the inferred north-westerly groundwater flow direction and are considered to be related to the previously identified dissolved phase groundwater CHC impacts

        Sensitive receptors The following sensitive receptors have been identified as potentially relevant to the Thebarton EPA Assessment Area Ecological groundwater ecosystems within the assessment area extending to at least Dew and Smith

        Streets (ie as the north-western extent of the groundwater CHC plume has not yet been determined) and

        the freshwater ecosystem of the River Torrens located at a distance of approximately 07 km in a hydraulically down-gradient (ie north-westerly) direction but not necessarily representing a groundwater receiving environment

        Human current and future occupants of and visitors to residential properties current and future workers on the source site and other commercialindustrial properties

        within the area current and future underground trenchmaintenanceutility workers and down-gradient groundwater bore users

        Contaminant Possible contaminant transport mechanisms associated with the CHC-impacted groundwater transport identified within the Q1 aquifer beneath the Thebarton EPA Assessment Area include mechanisms flow through the aquifer to a hydraulically down-gradient surface water body andor down-

        gradient groundwater bores vapour generation andor flow via subsurface preferential pathways (eg service trenches

        more permeable soils) and downward movement into underlying aquifers (eg dense non-aqueous phase liquid

        (DNAPL))

        80607-1 REV1 30102017 PAGE 63

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Topic Summarised Information

        Exposure Possible exposure mechanisms associated with impacted groundwater within the Thebarton mechanisms EPA Assessment Area include

        direct contact (eg during extractionuse of groundwater) incidental ingestion (eg during extractionuse of groundwater) and inhalation of vapours (eg during extractionuse of groundwater andor as a result of

        vapour intrusion into buildings)

        Assessment of Risk

        Groundwater risks The recent groundwater analytical results have indicated that the Q1 aquifer beneath the Thebarton EPA Assessment Area contains measurable concentrations of CHC (mainly TCE but also including PCE 12-DCE andor 11-DCE at some locations) Measured concentrations of TCE exceeded the adopted assessment criteria for potable andor primary contact recreation in wells MW02 MW3 MW5 MW6 MW11 MW12 MW14 MW15 MW17 MW20 MW21 and MW23 located on Admella Maria George Albert and Dew Streets as well as Light Terrace with maximum concentrations corresponding to the ldquocorerdquo area of the plume One well (MW25) contained a concentration of carbon tetrachloride that exceeded the adopted potable criterion Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

        Groundwater fate Although scattered detectable concentrations of 12-DCE have been measured in groundwater and transport across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE modelling daughter products has been interpreted to indicate that substantial dechlorination is not

        occurring Groundwater fate and transport modelling (refer to Section 8 and Appendix O) has predicted that the likely extent of the dissolved phase groundwater TCE plume over the next 100 years will extend by another 500 m beyond the boundaries of the current Thebarton EPA Assessment Area However no significant lateral plume expansion is expected

        Vapour intrusion risks A VIRA (refer to Section 9 and Appendix P) was undertaken to assess potential risks to human health from the intrusion of CHC vapours (primarily TCE) into indoor air from soil vapour The predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction in the absence of specific structural information) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and therefore require further action as follows 10 properties within the investigation range (2 to lt20 microgm3) eight properties within the intervention range (20 to lt200 microgm3) and three properties within accelerated intervention range (ge200 microgm3) All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3

        (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as

        PAGE 64 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Topic Summarised Information

        selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which are expected to be overly-conservative) ndash these results will be documented in a subsequent report Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed Management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air)

        Complete Exposure Pathways

        Identified pathways and areas of potential risk

        Based on the results of the recent Fyfe investigations (including the VIRA) and taking into account available historical information (Appendices A and B) and DEWNR (2017) WaterConnect bore information the following complete exposure pathways and associated risks are considered possible for the Thebarton EPA Assessment Area exposure (direct contact incidental ingestion andor inhalation of vapours) during use of

        groundwater for domestic (eg drinking water plumbing garden irrigation) andor recreational (eg filling of swimming poolsspas) purposes

        vapour intrusion into indoor air within 30 residential propertieslocated within the vicinity of soil vapour bores SV1 to SV9 (assuming crawl space construction) ndash although 19 of these properties are predicted to be in the validationinvestigation action level range 11 are predicted to be in the intervention action level range (with actual indoor air monitoring results for properties within the intervention action level range pending)

        vapour intrusion into residential cellarsbasements (if present) in the vicinity of soil vapour bores SV1 to SV10 and SV12 and

        vapour intrusion into the indoor air of commercialindustrial properties ndash although actual risks to site workers would require further specific considerationassessment

        In addition although only assessed in a qualitative manner to date trenchmaintenanceutility workers may also be at risk where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

        Notes calculated on the basis of cadastral boundaries and assuming crawl space construction ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial premises a property survey would be required to confirm building construction details and the number of individual residences affected

        80607-1 REV1 30102017 PAGE 65

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        11 CONCLUSIONS

        Between May and August 2017 Fyfe undertook an investigation of groundwater and soil vapour CHC impacts within an EPA-designated Assessment Area located in Thebarton South Australia The results of the investigation have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties A CSM has been developed from the field analytical and modelling results as presented in Section 10

        The following conclusions have been reached

        Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were present within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m in groundwater well MW17

        Groundwater within the Q1 aquifer is located at a depth of approximately 123 to 159 m BGL and flows in a general north-westerly direction (refer to Figure 4) ndash the closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred16 and the groundwater gradient beneath the Thebarton EPA Assessment area is relatively flat (ie 000062 to 00012)

        Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified to include domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux as assessed by the VIRA) and possibly also potable Although freshwater ecosystem protection was also considered the River Torrens is thought to comprise either a recharge boundary (ie discharging to local groundwater) or to not actually be hydraulically connected to the Q1 aquifer in this area

        Groundwater beneath parts of the Thebarton EPA Assessment Area contains detectable concentrations of various CHC and includes TCE and carbon tetrachloride (one location only) levels that exceed the adopted assessment criteria for potable use andor primary contact recreation ndash thereby indicating that groundwater would be unsuitable for drinking or the filling of swimming poolsspas In addition vapour flux could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the groundwater could be odorous

        16 ie as calculated by Fyfe based on available data

        80607-1 REV1 30102017 PAGE 67

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        The groundwater and soil vapour CHC impacts identified beneath parts of the Thebarton EPA Assessment Area are considered likely to have emanated from the former Austral sheet metal works located over multiple allotments between George and Maria Streets from the 1920s until the 1960sshy1970s The possible presence of on-going (primary andor secondary) source(s) at this property has not yet been investigated

        As depicted on Figures 6 and 7 the current extent of the soil vapour CHC (ie dominated by TCE) impacts has been determined to correspond to the mapped distribution of the groundwater TCE impacts (Figure 5) and is considered to be directly related to groundwater (rather than soil) CHC impacts Although no soil vapour impacts were detected at 1 m BGL in SV11 and SV1317 located near the eastern and western ends of Light Terrace respectively the north-western extents of the groundwater and soil vapour CHC impacts have not yet been determined In addition although the extent of the groundwater TCE plume has been delineated in all other directions the soil vapour TCE plume has not been delineated in any direction

        TCE is considered to be a primary contaminant as well as the dominant (ie in terms of concentration and extent) CHC in both groundwater and soil vapour ndash the presence of PCE and 11-DCE suggests however that more than one primary contaminant is present Although the detectable concentrations of 12-DCE (cis- and trans) are considered to have resulted from the breakdown of TCEPCE no VC has been detected in either groundwater or soil vapour ndash the scattered distribution and relatively low concentrations of 12-DCE as well as the absence of measurable VC have been interpreted to indicate that significant dechlorination of the primary contaminants has not occurred (despite the likely age of the plume ndash ie possibly up to about 90 years old)

        Although the COPC adopted for the soil vapour assessment program included various CHC (ie with TCE identified as the dominant contaminant in groundwater and soil vapour) the Tier 1 VIRA confirmed that TCE PCE and 11-DCE all exceeded the adopted vapour intrusion HILs Based primarily on its greater toxicity however the risk driver for the Thebarton EPA Assessment Area is considered to be TCE

        The VIRA (Tier 2) results for predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and that require further action as follows

        ― 10 properties within the investigation range (2 to lt20 microgm3)

        ― eight properties within the intervention range (20 to lt200 microgm3) and

        ― three properties within accelerated intervention range (ge200 microgm3)

        All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming

        17 noting that the laboratory LOR for TCE was elevated as compared to the other soil vapour samples

        PAGE 68 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises ndash refer to Table 96

        Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentration obtained for soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

        Although only assessed in a qualitative manner trenchmaintenanceutility workers may be at risk in areas where TCE concentrations at 1 m BGL are greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) ndash in this case appropriate management measures would be required to be adopted This should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

        80607-1 REV1 30102017 PAGE 69

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        12 DATA GAPS

        Based on the results obtained during the recent Fyfe investigations as well as available historical information (Appendices A and B) the following data gaps have been identified for the Thebarton EPA Assessment Area

        property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

        groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

        the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

        the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

        80607-1 REV1 30102017 PAGE 71

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        13 REFERENCES

        ANZECCARMCANZ (2000a) Australian Guidelines for Water Quality Monitoring and Reporting

        ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

        ASTM (2001) Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations ASTM Guide D7663-12

        ASTM (2006) Standard Guide for Soil Gas Monitoring in the Vadose Zone ASTM Guide D5314-92

        ATSDR (1994) Toxicological profile ndash 11-Dichloroethene httpswwwatsdrcdcgovToxProfilestpaspid=722amptid=130

        AustralianNew Zealand Standard (1998) Water Quality Sampling Part 1 Guidance on the Design of Sampling Programs Sampling Techniques and the Preservation and Handling of Samples ASNZS 566711998

        AustralianNew Zealand Standard (1998) Water Quality Sampling Part 11 Guidance on Sampling of Groundwaters ASNZS 5667111998

        Bouwer H and Rice RC (1976) A Slug Test Method for Determining Hydraulic Conductivity of Unconfined Aquifers with Completely or Partially Penetrating Wells Water Resources Research vol 12 no 3 pp 423-428

        Butler JJ Jr (1998) The Design Performance and Analysis of Slug Tests

        Cooper HH Bredehoeft JD and Papadopulos SS (1967) Response of a Finite-Diameter Well to an Instantaneous Charge of Water Water Resources Research vol 3 no 1 pp 263-269

        CRC CARE (2013) Petroleum Hydrocarbon Vapour Intrusion Assessment ndash Australian Guidance CRC CARE Technical Report No 23 July 2013

        Dagan G (1978) A Note on Packer Slug and Recovery Tests in Unconfined Aquifers Water Resources Research vol 14 no 5 pp 929-934

        Department of Environment Water and Natural Resources (DEWNR 2017) Water Connect Master Register of All Bores Primary Industries and Resources South Australia

        Duffield G (2007) AQTESOLVreg Professional Version 45 Hydrosolve Inc

        enHealth (2012a) Environmental Health Risk Assessment - Guidelines for assessing human health risks from environmental hazards enHealth Council

        enHealth (2012b) Australian Exposure Factor Guidance Handbook enHealth Council

        Environment Protection Act 1993

        80607-1 REV1 30102017 PAGE 73

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        Environment Protection Regulations 2009

        Friebel E and Nadebaum P (2011) Health Screening Levels for Petroleum Hydrocarbons in Soil and Groundwater CRC CARE Technical Report No 10

        Gerges NZ (1999) The Geology and Hydrogeology of the Adelaide Metropolitan Area Flinders University (South Australia) PhD thesis (unpublished)

        Gerges NZ (2006) Overview of the Hydrogeology of the Adelaide Metropolitan Area DWLBC Report 200610

        Golder Associates (1994) Contamination Assessment George Street Thebarton SA Report to United Land dated 9 December 1994

        Hvorslev MJ (1951) Time Lag and Soil Permeability in Ground-Water Observations Bulletin no 36 Waterways Exper Sta Corps of Engrs US Army Vicksburg Mississippi pp 1-50

        Hyder Z Butler JJ Jr McElwee CD and Liu W (1994) Slug Tests in Partially Penetrating Wells Water Resources Research vol 30 no 11 pp 2945-2957

        ITRC (2007) Vapor Intrusion Pathway - A Practical Guidance

        Johnson PC and Ettinger RA (1991) Heuristic Model for Predicting the Intrusion Rate of Contaminant Vapors

        into Buildings Environ Sci Technology 251445-1452

        McDonald M G and Harbaugh A W (1988) A Modular Three-Dimensional Finite-Difference Ground-Water Flow Model Techniques of Water-Resources Investigations Book 6 Chapter A1 U S Geological Survey

        NEPM (1999) National Environment Protection (Assessment of Site Contamination) Measure Schedules B1 to

        B9 National Environment Protection Council Australia

        NHMRC (2008) Guidelines for Managing Risks in Recreational Water

        NHMRCNRMMC (2011) Australian Drinking Water Guidelines (as revised in 2016)

        NJDEP (2013) Site Remediation Program Vapor Intrusion Technical Guidance (Version 31)

        NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme (2nd edition)

        Payne FC Quinnan JA and Potter ST (2008) Remediation Hydraulics CRC Press Boca Raton FL

        RAIS (2016) Chemical Specific Parameters for Trichloroethylene Risk Assessment Information System Office of Environmental Management US Department of Energy

        REM (2005a) George St Thebarton Site ndash Stage 2 Investigations Report to Luca Group dated 26 August 2005

        REM (2005b) Stage 3 Environmental Site Assessment George St Thebarton SA Report to Luca Group dated 23 November 2005

        SA Department of Mines and Energy (1969) 1250000 Adelaide Geological Map Sheet Sheet S1 54-9

        PAGE 74 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        SA EPA (2007) Regulatory Monitoring and Testing Groundwater Sampling

        SA EPA (2009) Guidelines for the Assessment and Remediation of Groundwater Contamination

        SA EPA (2014) Clovelly Park Mitchell Park Project Management Team Assessment Program Flip Book November 2014

        SA EPA (2015) Environment Protection (Water Quality) Policy

        Standards Australia (1993) Geotechnical Site Investigations AS1726-1993

        Standards Australia (2005) Guide to the Sampling and Investigation of Potentially Contaminated Soil Part 1 Non-Volatile and Semi-Volatile Compounds AS44821-2005

        Stapledon DH (1971) Changes and Structural Defects Developed in some South Australian Clays and their Engineering Consequences Proceedings of Symposium on Soils and Earth Structures in Arid Climates Adelaide 1970

        US EPA (1996) Soil Screening Guidance Technical Background Document Office of Emergency and Remedial Response Washington DC EPA540R95128

        US EPA (1999) Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air Second Edition Compendium Method TO-15 Determination Of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed By Gas Chromatography Mass Spectrometry (GCMS) EPA625R-96010b

        US EPA (2002) OSWER Draft Guidance for Evaluating the Vapour Intrusion to Indoor Air Pathway from Groundwater and Soils (Subsurface Vapour Intrusion Guidance) EPA530-D-02-004

        US EPA (2009) EPArsquos Risk-Screening Environmental Indicators (RSEI) Methodology Office of Pollution Prevention and Toxics Washington DC

        US EPA (2011) IRIS (Integrated Risk Information System) Trichloroethylene Chemical Assessment Summary httpscfpubepagovnceairisiris_documentsdocumentssubst0199_summarypdf

        US EPA (2012) EPArsquos Vapor Intrusion Database Evaluation and Characterization of Attenuation Factors for Chlorinated Volatile Organic Compounds and Residential Buildings

        US EPA (2015) OSWER Technical Guide for Assessing and Mitigating the Vapour Intrusion Pathway from Subsurface Vapour Sources to Indoor Air

        US EPA (2017a) Regional Screening Levels (RSLs) - Generic Tables (June 2017) httpswwwepagovriskregional-screening-levels-rsls-generic-tables-june-2017

        US EPA (2017b) Regional Screening Levels for Chemical Contaminants at Superfund Sites httpwwwepagovreg3hwmdriskhumanrb-concentration_tableGeneric_Tablesindexhtm

        80607-1 REV1 30102017 PAGE 75

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        WHO (2006) Air Quality Guidelines for Europe Second Edition WHO Regional Publications European Series No 91

        WHO (2017) Guidelines for Drinking-water Quality Fourth edition (incorporating the first addendum)

        Wiedemeier T Swanson M Moutoux D Gordon E Wilson J Wilson B Kampbell D Haas P Miller R Hansen J and Chapelle F (1998) Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water National Risk Management Research Laboratory Office of Research and Development US EPA

        Zheng C (1990) MT3D A Modular Three-Dimensional Transport Model for Simulation of Advection Dispersion and Chemical Reactions of Contaminants in Groundwater Systems Prepared for US EPA by Robert S Kerr Environmental Research Laboratory Ada Oklahoma developed by SS Papadopulos amp Associates Inc Rockville Maryland

        PAGE 76 80607-1 REV1 30102017

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        14 STATEMENT OF LIMITATIONS

        The opinions and conclusions presented in this report are specific to the conditions of the Thebarton EPA Assessment Area and the state of legislation currently enacted as at the date of this report Fyfe does not make any representation or warranty that the opinions and conclusions in this report will be applicable in the future as there may be changes in the condition of the Thebarton EPA Assessment Area applicable legislation or other factors that would affect the opinions and conclusions contained in this report

        Fyfe has used the degree of skill and care ordinarily exercised by reputable members of our profession practising in the same or similar locality This report has been prepared for the South Australian Environment Protection Authority for the specific purpose identified in the report Fyfe accepts no liability or responsibility to any third party for the accuracy of any information contained in the report or any opinion or conclusion expressed in the report Neither the whole of the report nor any part or reference thereto may be in any way used relied upon or reproduced by any third party without Fyfersquos prior written approval This report must be read in its entirety including all tables and attachments

        80607-1 REV1 30102017 PAGE 77

        EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

        FIGURES

        Figure 1 Site Location and Assessment Area

        Figure 2 Assessment Point Locations

        Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan

        Figure 4 Groundwater Elevation Contour Plan

        Figure 5 Groundwater Concentration Plan

        Figure 6 Soil Vapour Concentration Plan (10m)

        Figure 7 Soil Vapour Concentration Plan (30m)

        80607-1 REV1 30102017 PAGE 79

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        DEW

        STREET

        DEW

        STREET

        CHAPEL STREETCHAPEL STREET

        PAR

        KER

        STREET

        PAR

        KER

        STREET

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        LIGHT TERRACELIGHT TERRACE

        DEW

        STREET

        DEW

        STREET

        WA

        LSH ST

        WA

        LSH ST

        AD

        MELLA

        STREET

        AD

        MELLA

        STREET

        ALB

        ERT STR

        EETA

        LBER

        T STREET

        HO

        LLAN

        D ST

        REET

        HO

        LLAN

        D ST

        REET

        RANDOLPH STREET

        RANDOLPH STREET

        JAM

        ES STREET

        JAM

        ES STREET

        DOVE STREET

        DOVE STREET

        SMITH STREETSMITH STREET

        MARIA STREETMARIA STREET

        GEORGE STREETGEORGE STREET

        KINTORE STREET

        KINTORE STREET

        PORT ROAD

        PORT ROAD

        PORT ROAD

        PORT ROAD

        CAW

        THO

        RN

        E STR

        EETC

        AWTH

        OR

        NE ST

        REET

        DEVON STREETDEVON STREET

        KINTORE STREETKINTORE STREET

        GOODENOUGH STREETGOODENOUGH STREET

        LIVESTR

        ON

        G PATH

        WAY

        LIVESTR

        ON

        G PATH

        WAY

        CCAAWW

        TTHHOO

        RRNN

        EE SSTTRR

        EEEETT

        HHOO

        LLLLAANN

        DD SSTT

        RREEEETT

        DE

        DEW

        SW

        STREET

        TREET

        JJAM

        EA

        MES S

        S STREET

        TREET

        DDOOVVEE SSTTRREEEETT

        LLIIVVEESSTTRR

        OONN

        GG PPAATTHH

        WWAAYY

        LIGHT TERRLIGHT TERRAACECE

        AD

        MELLA

        SA

        DM

        ELLA STR

        EETTR

        EET

        CHAPEL SCHAPEL STREETTREET

        AALLBB

        EERRTT SSTTRR

        EEEETT

        GEGEORORGE SGE STREETTREET

        PPOORRTT RROOAADD

        PPOORRTT RROOAADD

        DDEEWW

        SSTTRREEEETT

        MMAARRIIAA SSTTRREEEETT

        JJAAMM

        EESS CCOO

        NNGG

        DDOO

        NN DD

        RRIIVV

        EE

        WWAA

        LLSSHH SSTT

        SSMMIITTHH SSTTRREEEETT

        RRANDOLPH S

        ANDOLPH STREETTREET

        PPOORR

        TT RROO

        AADD

        PPOORR

        TT RROO

        AADD

        KKIINNTTOORREE SSTTRREEEETT

        KKIINNTTOORREE SSTTRREEEETT

        PPAARR

        KKEERR

        SSTTRREEEETT

        GGOOOODDEENNOOUUGGHH SSTTRREEEETT

        DDEEVVOONN SSTTRREEEETT

        ASSESSMENT AREA

        CBD

        750m

        LEGEND

        EPA ASSESSMENT AREA

        CADASTRE

        12500 A3

        0 25 50 m

        CLIENT

        SA EPA

        PROJECT

        FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

        EPA THEBARTON ASSESSMENT AREA - STAGE 1

        TITLE

        FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

        PROJECT NO DATE CREATED

        80607-1 290917

        80607_Fig 1 - Site Location and Assessment Areaai REV 1 gt 290917

        LE

        VE

        L 1

        12

        4 S

        OU

        TH

        TE

        RR

        AC

        E

        AD

        EL

        AID

        E S

        A 5

        00

        0

        P

        H

        (08

        ) 8

        23

        2 9

        08

        8

        F

        AX

        (0

        8)

        82

        32

        90

        99

        EM

        AIL

        in

        fo

        fyfe

        co

        ma

        u

        W

        EB

        fy

        fec

        om

        au

        AB

        N

        57

        00

        8 1

        16 1

        30

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        DEW

        STREET

        DEW

        STREET

        CHAPEL STREETCHAPEL STREET

        PAR

        KER

        STREET

        PAR

        KER

        STREET

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        LIGHT TERRACELIGHT TERRACE

        DEW

        STREET

        DEW

        STREET

        WA

        LSH ST

        WA

        LSH ST

        AD

        MELLA

        STREET

        AD

        MELLA

        STREET

        ALB

        ERT STR

        EETA

        LBER

        T STREET

        HO

        LLAN

        D ST

        REET

        HO

        LLAN

        D ST

        REET

        RANDOLPH STREET

        RANDOLPH STREET

        JAM

        ES STREET

        JAM

        ES STREET

        DOVE STREET

        DOVE STREET

        SMITH STREETSMITH STREET

        MARIA STREETMARIA STREET

        GEORGE STREETGEORGE STREET

        KINTORE STREET

        KINTORE STREET

        PORT ROAD

        PORT ROAD

        PORT ROAD

        PORT ROAD

        CAW

        THO

        RN

        E STR

        EETC

        AWTH

        OR

        NE ST

        REET

        DEVON STREETDEVON STREET

        KINTORE STREETKINTORE STREET

        GOODENOUGH STREETGOODENOUGH STREET

        LIVESTR

        ON

        G PATH

        WAY

        LIVESTR

        ON

        G PATH

        WAY

        SV1SV1

        SV2SV2

        SV3SV3SV4SV4

        SV5SV5

        SV6SV6

        SV7SV7SV8SV8

        SV9SV9

        SV10SV10

        SV11SV11SV12SV12

        SV13SV13

        MW1MW1

        MW02MW02

        MW3MW3

        MW4MW4MW5MW5MW6MW6

        MW7MW7

        MW8MW8

        MW9MW9

        MW10MW10MW11MW11

        MW12MW12MW13MW13

        MW14MW14MW15MW15

        MW16MW16

        MW17MW17

        MW18MW18

        MW19MW19

        MW20MW20

        MW21MW21

        MW22MW22

        MW23MW23

        MW24MW24

        MW25MW25

        MW26MW26

        WMS2WMS2WMS1WMS1

        WMS3WMS3WMS4WMS4WMS5WMS5

        WMS6WMS6

        WMS7WMS7WMS8WMS8

        WMS9WMS9WMS10WMS10

        WMS11WMS11

        WMS12WMS12

        WMS13WMS13WMS14WMS14

        WMS15WMS15

        WMS41WMS41

        WMS40WMS40

        WMS39WMS39WMS38WMS38

        WMS16WMS16

        WMS17WMS17

        WMS18WMS18WMS19WMS19

        WMS20WMS20

        WMS21WMS21WMS22WMS22

        WMS23WMS23WMS24WMS24

        WMS25WMS25

        WMS26WMS26

        WMS27WMS27WMS28WMS28WMS29WMS29

        WMS30WMS30

        WMS31WMS31

        WMS32WMS32

        WMS33WMS33

        WMS34WMS34

        WMS35WMS35

        WMS36WMS36

        WMS37WMS37

        WWAA

        LLSSHHSSTT

        SSMMIITTHH SSTTRREEEETT

        RRANDOLPH S

        ANDOLPH STREETTREET

        PPOORR

        TT RROO

        AADD

        PPOORR

        TT RROO

        AADD

        CCAAWW

        TTHHOO

        RRNN

        EE SSTTRR

        EEEETT

        JJAM

        EA

        MES S

        S STREET

        TREET

        HHOO

        LLLLAANN

        DDSSTT

        RREEEETT

        DE

        DEW

        SW

        STREET

        TREET

        DDOOVVEE SSTTRREEEETT

        LLIIVVEESSTTRR

        OONN

        GGPPAATTHH

        WWAAYY

        LIGHT TERRLIGHT TERRAACECE

        CHAPEL SCHAPEL STREETTREET

        AALLBB

        EERRTT SSTTRR

        EEEETT

        AD

        MELLA

        SA

        DM

        ELLA STR

        EETTR

        EET

        GEGEORORGE SGE STREETTREET

        PPOORRTT RROOAADD PPOORRTT RROOAADD

        DDEEWW

        SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

        JJAAMM

        EESS CCOO

        NNGG

        DDOO

        NN DD

        RRIIVV

        EE

        KKIINNTTOORREE SSTTRREEEETT

        KKIINNTTOORREE SSTTRREEEETT

        PPAARR

        KKEERR

        SSTTRREEEETT

        GGOOOODDEENNOOUUGGHH SSTTRREEEETT

        DDEEVVOONN SSTTRREEEETT

        FIGURE 2 ASSESSMENT POINT LOCATIONS

        MMWW88

        MW2MW244 WMS3WMS355

        MW2MW255

        WMS3WMS366

        WMS3WMS377

        WMS3WMS311

        MW2MW222WMS34WMS34

        MW2MW233 WMS3WMS322

        WMS3WMS333

        WMS2WMS277WMS2WMS299 WMS2WMS288

        SSV12V12 SSVV1111 MW19MW19

        MW18MW18 SSVV1133 MW2MW200 WMS3WMS300

        MW2MW211 WMS2WMS255

        WMS2WMS266

        MW17MW17 WMS2WMS244

        WMS2WMS233

        WMS2WMS222 WMS2WMS211

        SSVV99

        SSV10V10WMS2WMS200 MW14MW14MW15MW15 WMS18WMS18

        WMS19WMS19 MW16MW16

        WMS13WMS13MW10MW10 WMS14WMS14MMWW1111SVSV77WMS15WMS15SSVV88WMS16WMS16

        SVSV66WMS4WMS411MW13MW13 LEGENDMW12MW12

        WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS17WMS17 WMS40WMS40 SSVV55 MW0MW022MW9MW9 GROUNDWATER MONITORING WELL

        WMS11WMS11 WMS6WMS6 SOIL VAPOUR BORE

        WATERLOO MEMBRANE SAMPLERTM - ROUND 2

        SVSV22WMS8WMS8SVSVWMS12WMS12 44 WMS7WMS7 MW4MW4MMWW SVSV66 33 MW5MW5WMS3WMS388

        WMS3WMS399 MW7MW7 EPA ASSESSMENT AREAWMS10WMS10 WMS9WMS9

        SVSV11 CADASTRE

        MW3MW3

        MW1MW1 WMS3WMS3WMS4WMS4MW2MW266 WMS5WMS5 12500 A3

        0 25 50 m

        CLIENT

        SA EPAWMS1WMS1

        WMS2WMS2 PROJECT

        EPA THEBARTON ASSESSMENT AREA - STAGE 1

        TITLE

        FIGURE 2 ASSESSMENT POINT LOCATIONS

        PROJECT NO DATE CREATED

        80607-1 280917

        80607_Fig 2 - Assessment Point Locationsai REV 1 gt 280917

        LE

        VE

        L 1

        12

        4 S

        OU

        TH

        TE

        RR

        AC

        E

        AD

        EL

        AID

        E S

        A 5

        00

        0

        PH

        (0

        8)

        82

        32

        90

        88

        F

        AX

        (0

        8)

        82

        32

        90

        99

        E

        MA

        IL

        info

        fy

        fec

        om

        au

        W

        EB

        fy

        fec

        om

        au

        A

        BN

        5

        7 0

        08

        116

        13

        0

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        DEW

        STREET

        DEW

        STREET

        CHAPEL STREETCHAPEL STREET

        PAR

        KER

        STREET

        PAR

        KER

        STREET

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        LIGHT TERRACELIGHT TERRACE

        DEW

        STREET

        DEW

        STREET

        WA

        LSH ST

        WA

        LSH ST

        AD

        MELLA

        STREET

        AD

        MELLA

        STREET

        ALB

        ERT STR

        EETA

        LBER

        T STREET

        HO

        LLAN

        D ST

        REET

        HO

        LLAN

        D ST

        REET

        RANDOLPH STREET

        RANDOLPH STREET

        JAM

        ES STREET

        JAM

        ES STREET

        DOVE STREET

        DOVE STREET

        SMITH STREETSMITH STREET

        MARIA STREETMARIA STREET

        GEORGE STREETGEORGE STREET

        KINTORE STREET

        KINTORE STREET

        PORT ROAD

        PORT ROAD

        PORT ROAD

        PORT ROAD

        CAW

        THO

        RN

        E STR

        EETC

        AWTH

        OR

        NE ST

        REET

        DEVON STREETDEVON STREET

        KINTORE STREETKINTORE STREET

        GOODENOUGH STREETGOODENOUGH STREET

        LIVESTR

        ON

        G PATH

        WAY

        LIVESTR

        ON

        G PATH

        WAY

        WMS2WMS2WMS1WMS1

        WMS3WMS3WMS4WMS4

        WMS5WMS5

        WMS6WMS6

        WMS7WMS7WMS8WMS8

        WMS9WMS9

        WMS10WMS10

        WMS11WMS11

        WMS12WMS12

        WMS13WMS13WMS14WMS14

        WMS15WMS15 WMS41WMS41

        WMS40WMS40

        WMS39WMS39WMS38WMS38

        WMS16WMS16

        WMS17WMS17

        WMS18WMS18WMS19WMS19WMS20WMS20

        WMS21WMS21WMS22WMS22

        WMS23WMS23WMS24WMS24

        WMS25WMS25

        WMS26WMS26

        WMS27WMS27WMS28WMS28WMS29WMS29

        WMS30WMS30

        WMS31WMS31

        WMS32WMS32WMS33WMS33

        WMS34WMS34

        WMS35WMS35

        WMS36WMS36

        WMS37WMS37

        WWAA

        LLSSHHSSTT

        SSMMIITTHH SSTTRREEEETT

        RRANDOLPH S

        ANDOLPH STREETTREET

        PPOORR

        TT RROO

        AADD

        PPOORR

        TT RROO

        AADD

        CCAAWW

        TTHHOO

        RRNN

        EE SSTTRR

        EEEETT

        JJAM

        EA

        MES S

        S STREET

        TREET

        HHOO

        LLLLAANN

        DDSSTT

        RREEEETT

        DE

        DEW

        SW

        STREET

        TREET

        DDOOVVEE SSTTRREEEETT

        LLIIVVEESSTTRR

        OONN

        GGPPAATTHH

        WWAAYY

        LIGHT TERRLIGHT TERRAACECE

        AD

        MELLA

        SA

        DM

        ELLA STR

        EETTR

        EET

        AALLBB

        EERRTT SSTTRR

        EEEETT

        CHAPEL SCHAPEL STREETTREET

        GEGEORORGE SGE STREETTREET

        PPOORRTT RROOAADD PPOORRTT RROOAADD

        DDEEWW

        SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

        JJAAMM

        EESS CCOO

        NNGG

        DDOO

        NN DD

        RRIIVV

        EE

        KKIINNTTOORREE SSTTRREEEETT

        KKIINNTTOORREE SSTTRREEEETT

        PPAARR

        KKEERR

        SSTTRREEEETT

        GGOOOODDEENNOOUUGGHH SSTTRREEEETT

        DDEEVVOONN SSTTRREEEETT

        FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

        TCE CONCENTRATION PLAN

        WMS3WMS355 TCE lt78

        WMS3WMS366 TCE lt77WMS3WMS377

        TCE 44

        WMS3WMS311 TCE lt78

        WMS34WMS34 TCE 11

        WMS3WMS322WMS3WMS333 TCE lt78TCE lt79

        WMS2WMS277WMS2WMS299 WMS2WMS288 TCE 64 TCE lt77 TCE lt8

        WMS3WMS300 TCE lt8

        WMS2WMS255

        WMS2WMS266 TCE 1400(D)

        WMS2WMS222 TCE 38 WMS2WMS211

        TCE lt79

        TCE lt78

        WMS2WMS233 WMS2WMS244 TCE lt77

        TCE 230

        WMS2WMS200 WMS19WMS19TCE lt78 WMS18WMS18 TCE 11000

        TCE 4200

        WMS13WMS13 WMS14WMS14 TCE lt79

        WMS4WMS411WMS15WMS15 TCE 46000WMS16WMS16 TCE 18000 LEGENDTCE lt8

        TCE lt78WMS17WMS17 WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS40WMS40TCE lt79

        TCE 110000 WATERLOO MEMBRANE SAMPLERTM - ROUND 2WMS11WMS11

        TCE 71000WMS12WMS12 EPA ASSESSMENT AREA

        CADASTRE

        WMS6WMS6 TCE lt58 WMS8WMS8 WMS3WMS388 TCE 32WMS7WMS7WMS3WMS399

        TCE 12000 TCE 13000 TCE 1900TCE 1300WMS9WMS9 TCE lt58 NotesWMS10WMS10

        All concentrations are in μgm3 TCE lt58

        D = Duplicate result

        WMS3WMS3WMS4WMS4 12500 A3

        LE

        VE

        L 1

        12

        4 S

        OU

        TH

        TE

        RR

        AC

        E

        AD

        EL

        AID

        E S

        A 5

        00

        0

        PH

        (0

        8)

        82

        32

        90

        88

        F

        AX

        (0

        8)

        82

        32

        90

        99

        E

        MA

        IL

        info

        fy

        fec

        om

        au

        W

        EB

        fy

        fec

        om

        au

        A

        BN

        5

        7 0

        08

        116

        13

        0

        TCE lt57WMS5WMS5 TCE lt57 TCE lt58 0 25 50

        m

        CLIENT

        SA EPA

        WMS2WMS2 TCE lt56

        WMS1WMS1 TCE lt56

        PROJECT

        EPA THEBARTON ASSESSMENT AREA - STAGE 1

        TITLE

        FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

        TCE CONCENTRATION PLAN

        PROJECT NO DATE CREATED

        80607-1 241017

        80607_Fig 3 - WMS TCE Concentration Planai REV 1 gt 241017

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        DEW

        STREET

        DEW

        STREET

        CHAPEL STREETCHAPEL STREET

        PAR

        KER

        STREET

        PAR

        KER

        STREET

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        LIGHT TERRACELIGHT TERRACE

        DEW

        STREET

        DEW

        STREET

        WA

        LSH ST

        WA

        LSH ST

        AD

        MELLA

        STREET

        AD

        MELLA

        STREET

        ALB

        ERT STR

        EETA

        LBER

        T STREET

        HO

        LLAN

        D ST

        REET

        HO

        LLAN

        D ST

        REET

        RANDOLPH STREET

        RANDOLPH STREET

        JAM

        ES STREET

        JAM

        ES STREET

        DOVE STREET

        DOVE STREET

        SMITH STREETSMITH STREET

        MARIA STREETMARIA STREET

        GEORGE STREETGEORGE STREET

        KINTORE STREET

        KINTORE STREET

        PORT ROAD

        PORT ROAD

        PORT ROAD

        PORT ROAD

        CAW

        THO

        RN

        E STR

        EETC

        AWTH

        OR

        NE ST

        REET

        DEVON STREETDEVON STREET

        KINTORE STREETKINTORE STREET

        GOODENOUGH STREETGOODENOUGH STREET

        LIVESTR

        ON

        G PATH

        WAY

        LIVESTR

        ON

        G PATH

        WAY

        MW1MW1

        MW02MW02

        MW3MW3

        MW4MW4MW5MW5

        MW6MW6

        MW7MW7

        MW8MW8

        MW9MW9

        MW10MW10MW11MW11

        MW12MW12

        MW13MW13

        MW14MW14

        MW15MW15

        MW16MW16

        MW17MW17

        MW18MW18

        MW19MW19MW20MW20

        MW21MW21

        MW22MW22

        MW23MW23

        MW24MW24

        MW25MW25

        MW26MW26

        WWAA

        LLSSHHSSTT

        SSMMIITTHH SSTTRREEEETT

        4

        466

        PPOORR

        TT RROO

        AADD

        PPOORR

        TT RROO

        AADD

        RRANDOLPH S

        ANDOLPH STREETTREET 4455

        DE

        DEW

        SW

        STREET

        TREET

        JJAM

        EA

        MES S

        S STREET

        TREET

        HHOO

        LLLLAANN

        DD SSTT

        RREEEETT

        CCAAWW

        TTHHOO

        RRNN

        EE SSTTRR

        EEEETT 4477

        DDOOVVEE SSTTRREEEETT

        4455

        4488

        LLIIVVEESSTTRR

        OONN

        GGPPAATTHH

        WWAAYY

        4455

        LIGHT TERRLIGHT TERRAACECE

        AD

        MELLA

        SA

        DM

        ELLA STR

        EETTR

        EET

        4466

        CHAPEL SCHAPEL STREETTREET

        4477 AA

        LLBBEERR

        TT SSTTRREEEETT

        4499

        GR4466 OUND

        FLOW DIREW

        GEGEORORGE SGE STREETTREET ATER C

        4488 TION

        PPOORRTT RROOAADD PPOORRTT RROOAADD 55

        00 DD

        EEWW SSTTRR

        EEEETT 4499

        MMAARRIIAA SSTTRREEEETT

        4477

        5500

        JJAAMM

        EESS CCOO

        NNGG

        DDOO

        NN DD

        RRIIVV

        EE

        88 44

        KKIINNTTOORREE SSTTRREEEETT

        KKIINNTTOORREE SSTTRREEEETT

        PPAARR

        KKEERR

        SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

        5500

        4499

        DDEEVVOONN SSTTRREEEETT

        FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

        Groundwater SWL MMWW88 Monitoring Well (m AHD)

        MW1 5011 MW2MW244

        MW02 4786

        MW3 484

        MW2MW255 MW4 507

        MW5 4833

        MW6 4794

        MW7 4703

        MW8 4581

        MW9 4728

        MW10 4871

        MW11 4785 MW2MW222

        MW12 4689

        MW13 4662

        MW2MW233 MW14 4723

        MW15 464

        MW16 4577

        MW17 4619

        MW18 4538

        MW19 4735

        MW20 457

        MW21 4531

        MW22 4501

        MW23 4497

        MW24 4537

        MW25 4469

        MW26 4918

        MW19MW19 MW2MW200

        MW2MW211MW18MW18

        MW17MW17

        MW14MW14

        MW15MW15

        MW16MW16

        MW10MW10 LEGEND MMWW1111

        GROUNDWATER MONITORING WELLMW12MW12

        50 INFERRED GROUNDWATER ELEVATION CONTOUR

        MW13MW13

        MW0MW022 INFERRED GROUNDWATER FLOW DIRECTION

        EPA ASSESSMENT AREA

        MW9MW9

        MW5MW5 CADASTREMMWW66 MW4MW4

        MW7MW7 Note This is one interpretation only Other interpretations possibleMW3MW3

        12500 A3

        0 25 50 m

        CLIENT

        SA EPA

        PROJECT

        EPA THEBARTON ASSESSMENT AREA - STAGE 1

        TITLE

        FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

        PROJECT NO DATE CREATED

        80607-1 290917

        MW1MW1 MW2MW266

        80607_Fig 4 - Groundwater Elevation Contour Planai REV 1 gt 290917

        LE

        VE

        L 1

        12

        4 S

        OU

        TH

        TE

        RR

        AC

        E

        AD

        EL

        AID

        E S

        A 5

        00

        0

        PH

        (0

        8)

        82

        32

        90

        88

        F

        AX

        (0

        8)

        82

        32

        90

        99

        E

        MA

        IL

        info

        fy

        fec

        om

        au

        W

        EB

        fy

        fec

        om

        au

        A

        BN

        5

        7 0

        08

        116

        13

        0

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        DEW

        STREET

        DEW

        STREET

        CHAPEL STREETCHAPEL STREET

        PAR

        KER

        STREET

        PAR

        KER

        STREET

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        LIGHT TERRACELIGHT TERRACE

        DEW

        STREET

        DEW

        STREET

        WA

        LSH ST

        WA

        LSH ST

        AD

        MELLA

        STREET

        AD

        MELLA

        STREET

        ALB

        ERT STR

        EETA

        LBER

        T STREET

        HO

        LLAN

        D ST

        REET

        HO

        LLAN

        D ST

        REET

        RANDOLPH STREET

        RANDOLPH STREET

        JAM

        ES STREET

        JAM

        ES STREET

        DOVE STREET

        DOVE STREET

        SMITH STREETSMITH STREET

        MARIA STREETMARIA STREET

        GEORGE STREETGEORGE STREET

        KINTORE STREET

        KINTORE STREET

        PORT ROAD

        PORT ROAD

        PORT ROAD

        PORT ROAD

        CAW

        THO

        RN

        E STR

        EETC

        AWTH

        OR

        NE ST

        REET

        DEVON STREETDEVON STREET

        KINTORE STREETKINTORE STREET

        GOODENOUGH STREETGOODENOUGH STREET

        LIVESTR

        ON

        G PATH

        WAY

        LIVESTR

        ON

        G PATH

        WAY

        MW1MW1

        MW02MW02

        MW3MW3

        MW4MW4

        MW5MW5

        MW6MW6

        MW7MW7

        MW8MW8

        MW9MW9

        MW10MW10MW11MW11

        MW12MW12

        MW13MW13

        MW14MW14

        MW15MW15

        MW16MW16

        MW17MW17

        MW18MW18

        MW19MW19MW20MW20

        MW21MW21

        MW22MW22

        MW23MW23

        MW24MW24

        MW25MW25

        MW26MW26

        WWAA

        LLSSHHSSTT

        SSMMIITTHH SSTTRREEEETT

        ndnd

        RRANDOLPH S

        ANDOLPH STREETTREET

        PPOORR

        TTRR

        OOAA

        DD

        PPOORR

        TTRR

        OOAA

        DD

        JJAM

        EA

        MES S

        S STREET

        TREET

        HHOO

        LLLLAANN

        DDSSTT

        RREEEETT

        CCAAWW

        TTHHOO

        RRNN

        EESSTT

        RREEEETT

        DE

        DEW

        SW

        STREET

        TREET

        DDOOVVEE SSTTRREEEETT

        LLIIVVEESSTTRR

        OONN

        GGPPAATTHH

        WWAAYY

        LIGHT TERRLIGHT TERRAACECE

        AD

        MELLA

        SA

        DM

        ELLA STR

        EETTR

        EET

        AALLBB

        EERRTT SSTTRR

        EEEETT

        CHAPEL SCHAPEL STREETTREET

        ndnd ndnd

        100100

        11000000

        GEGEORORGE SGE STREETTREET

        1010000000

        PPOORRTT RROOAADD PPOORRTT RROOAADD

        DDEEWW

        SSTTRREEEETT

        1010000000 11000000 MMAARRIIAA SSTTRREEEETT

        100100

        JJAAMM

        EESSCC

        OONN

        GGDD

        OONN

        DDRR

        IIVVEE

        KKIINNTTOORREE SSTTRREEEETT ndnd

        KKIINNTTOORREE SSTTRREEEETT

        PPAARR

        KKEERR

        SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

        DDEEVVOONN SSTTRREEEETT

        FIGURE 5 GROUNDWATER CONCENTRATION PLAN

        MW2MW244

        MMWW88 TCE lt1

        PCE lt1

        11-DCE lt1TCE lt1

        12-DCE lt1PCE lt1

        11-DCE lt1MW2MW255 12-DCE lt1

        TCE 2

        PCE lt1

        11-DCE lt1

        12-DCE lt1

        MW2MW222 TCE lt1

        PCE lt1

        11-DCE lt1MW2MW233 12-DCE lt1

        TCE 21

        PCE lt1

        11-DCE lt1

        12-DCE lt1

        MW19MW19 TCE lt1

        MW2MW200 TCE 70 PCE lt1MW2MW211 PCE lt1MW18MW18 11-DCE lt1

        TCE 23 11-DCE lt1TCE 5 12-DCE lt1 PCE lt1 12-DCE lt1PCE lt1 11-DCE lt1

        11-DCE lt1 12-DCE lt1

        12-DCE lt1

        MW17MW17 LEGENDTCE 24 MW14MW14

        PCE lt1 TCE 1100 lt1 MW15MW15 GROUNDWATER MONITORING WELL11-DCE PCE lt1

        12-DCE lt1 TCE 180 11-DCE 2MW16MW16 100 INFERRED TCE GROUNDWATERPCE lt1 12-DCE 4 CONCENTRATION CONTOURSTCE lt1 11-DCE lt1 PCE lt1 12-DCE lt1 11-DCE lt1

        12-DCE lt1 MMWW1111

        EPA ASSESSMENT AREAMW10MW10

        TCE lt1 CADASTREMW12MW12 TCE lt14900 PCE

        lt1 11-DCE lt1TCE 700 PCEMW13MW13 12-DCE lt1 TCE CONCENTRATIONS (μgL)lt1 11-DCE 7PCE

        TCE lt1 lt1 12-DCE 511-DCE gtnd to lt100 100 to lt1000 1000 to lt10000

        MW0MW022PCE lt1 12-DCE lt1 2100011-DCE lt1 MW9MW9 TCE

        PCE lt112-DCE lt1 TCE 2(D) 11-DCE 15PCE lt1 MW5MW5

        10000 to 29000

        nd = non-detect (lt1)12-DCE 4511-DCE lt1 MMWW66 TCE 29000 MW4MW4 12-DCE lt1

        PCE 3 TCE lt1 NotesTCE 29 11-DCE 6MW7MW7 PCE lt1PCE lt1 This is one interpretation only Other interpretations possible12-DCE 23TCE lt1 11-DCE lt111-DCE lt1 All concentrations are in μgL

        12-DCE includes cis and trans PCE lt1 MW3MW3 12-DCE lt112-DCE lt1 11-DCE lt1

        TCE 69 D = Duplicate result12-DCE lt1 PCE lt1

        11-DCE lt1

        12-DCE lt1 MW1MW1

        12500 A3MW2MW266 TCE lt1

        TCE 2 PCE lt1

        PCE lt1 11-DCE lt1

        11-DCE lt1 12-DCE lt1

        12-DCE lt1

        LE

        VE

        L 1

        12

        4 S

        OU

        TH

        TE

        RR

        AC

        E

        AD

        EL

        AID

        E S

        A 5

        00

        0

        PH

        (0

        8)

        82

        32

        90

        88

        F

        AX

        (0

        8)

        82

        32

        90

        99

        E

        MA

        IL

        info

        fy

        fec

        om

        au

        W

        EB

        fy

        fec

        om

        au

        A

        BN

        5

        7 0

        08

        116

        13

        0

        0 25 50 m

        CLIENT

        SA EPA

        PROJECT

        EPA THEBARTON ASSESSMENT AREA - STAGE 1

        TITLE

        FIGURE 5 GROUNDWATER CONCENTRATION PLAN

        PROJECT NO DATE CREATED

        80607-1 280917

        80607_Fig 5 - Groundwater TCE Concentration Plan r2ai REV 2 gt 280917

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        DEW

        STREET

        DEW

        STREET

        CHAPEL STREETCHAPEL STREET

        PAR

        KER

        STREET

        PAR

        KER

        STREET

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        LIGHT TERRACELIGHT TERRACE

        DEW

        STREET

        DEW

        STREET

        WA

        LSH ST

        WA

        LSH ST

        AD

        MELLA

        STREET

        AD

        MELLA

        STREET

        ALB

        ERT STR

        EETA

        LBER

        T STREET

        HO

        LLAN

        D ST

        REET

        HO

        LLAN

        D ST

        REET

        RANDOLPH STREET

        RANDOLPH STREET

        JAM

        ES STREET

        JAM

        ES STREET

        DOVE STREET

        DOVE STREET

        SMITH STREETSMITH STREET

        MARIA STREETMARIA STREET

        GEORGE STREETGEORGE STREET

        KINTORE STREET

        KINTORE STREET

        PORT ROAD

        PORT ROAD

        PORT ROAD

        PORT ROAD

        CAW

        THO

        RN

        E STR

        EETC

        AWTH

        OR

        NE ST

        REET

        DEVON STREETDEVON STREET

        KINTORE STREETKINTORE STREET

        GOODENOUGH STREETGOODENOUGH STREET

        LIVESTR

        ON

        G PATH

        WAY

        LIVESTR

        ON

        G PATH

        WAY

        SV1SV1

        SV2SV2SV3SV3SV4SV4

        SV5SV5

        SV7SV7SV8SV8

        SV9SV9

        SV10SV10

        SV11SV11SV12SV12

        SV13SV13

        SV6SV6

        WWAA

        LLSSHHSSTT

        SSMMIITTHH SSTTRREEEETT

        RRANDOLPH S

        ANDOLPH STREETTREET

        PPOORR

        TTRR

        OOAA

        DD

        PPOORR

        TTRR

        OOAA

        DD

        CCAAWW

        TTHHOO

        RRNN

        EESSTT

        RREEEETT

        HHOO

        LLLLAANN

        DDSSTT

        RREEEETT

        JJAM

        EA

        MES S

        S STREET

        TREET

        DE

        DEW

        SW

        STREET

        TREET

        DDOOVVEE SSTTRREEEETT

        00

        LLIIVVEESSTTRR

        OONN

        GGPPAATTHH

        WWAAYY

        LIGHT TERRLIGHT TERRAACECE

        AD

        MELLA

        SA

        DM

        ELLA STR

        EETTR

        EET

        CHAPEL SCHAPEL STREETTREET

        00

        AALLBB

        EERRTT SSTTRR

        EEEETT

        1010

        GEGEORORGE SGE STREETTREET

        000000

        PPOORRTT RROOAADD

        100100000

        000

        1010

        PPOORRTT RROOAADD

        000000

        DDEEWW

        SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

        JJAAMM

        EESSCC

        OONN

        GGDD

        OONN

        DDRR

        IIVVEE

        KKIINNTTOORREE SSTTRREEEETT 00

        KKIINNTTOORREE SSTTRREEEETT

        PPAARR

        KKEERR

        SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

        DDEEVVOONN SSTTRREEEETT

        FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

        SSVV1111 SSV12V12 TCE lt18

        SSVV1133 TCE 16

        PCE lt54 TCE lt21

        11-DCE lt29 PCE lt25

        12-DCE lt39 11-DCE lt14

        12-DCE lt18

        PCE lt22

        11-DCE lt12

        12-DCE lt16

        TCE 170

        PCE lt54

        11-DCE lt3

        12-DCE lt39 LEGEND SSVV99

        SSV10V10 SOIL VAPOUR BORE

        TCE lt21 0 INFERRED TCE SOIL VAPOUR CONTOUR PCE lt25

        TCE 2200011-DCE lt14 EPA ASSESSMENT AREA

        PCE 1912-DCE lt18

        11-DCE lt27 CADASTRE

        12-DCE lt37 SVSV66SVSV77

        SSVV88 TCE 22000

        TCE 2300 PCE 12 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)TCE 100000 PCE 62 11-DCE lt29PCE 84 0 to lt10000SSVV55lt2711-DCE 12-DCE lt2911-DCE lt33 10000 to lt100000

        100000 to 210000 12-DCE lt36 12-DCE lt44

        TCE 17000 SVSV44 SVSV22SVSV33 NotePCE 31 TCE 51000TCE 210000 This is one interpretation only Other interpretations possible11-DCE lt14 PCE 39PCE 650012-DCE lt18 39 Estimated extent of plume has utilised groundwater11-DCE11-DCE 5900 12-DCE 21 concentration data12-DCE lt71

        SVSV11 All concentrations are in (μgmsup3)

        TCE 6300(LD) 12-DCE includes cis and trans PCE 78 LD = Laboratory duplicate result 11-DCE lt29

        12-DCE lt38

        12500 A3

        0 25 50 m

        CLIENT

        SA EPA

        PROJECT

        EPA THEBARTON ASSESSMENT AREA - STAGE 1

        TITLE

        FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

        PROJECT NO DATE CREATED

        80607-1 290917

        80607_Fig 6 - Soil Vapour TCE Concentration Plan - 1mai REV 2 gt 290917

        LE

        VE

        L 1

        12

        4 S

        OU

        TH

        TE

        RR

        AC

        E

        AD

        EL

        AID

        E S

        A 5

        00

        0

        PH

        (0

        8)

        82

        32

        90

        88

        F

        AX

        (0

        8)

        82

        32

        90

        99

        E

        MA

        IL

        info

        fy

        fec

        om

        au

        W

        EB

        fy

        fec

        om

        au

        A

        BN

        5

        7 0

        08

        116

        13

        0

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        JAM

        ES CO

        NG

        DO

        N D

        RIV

        E

        DEW

        STREET

        DEW

        STREET

        CHAPEL STREETCHAPEL STREET

        PAR

        KER

        STREET

        PAR

        KER

        STREET

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        POR

        T RO

        AD

        LIGHT TERRACELIGHT TERRACE

        DEW

        STREET

        DEW

        STREET

        WA

        LSH ST

        WA

        LSH ST

        AD

        MELLA

        STREET

        AD

        MELLA

        STREET

        ALB

        ERT STR

        EETA

        LBER

        T STREET

        HO

        LLAN

        D ST

        REET

        HO

        LLAN

        D ST

        REET

        RANDOLPH STREET

        RANDOLPH STREET

        JAM

        ES STREET

        JAM

        ES STREET

        DOVE STREET

        DOVE STREET

        SMITH STREETSMITH STREET

        MARIA STREETMARIA STREET

        GEORGE STREETGEORGE STREET

        KINTORE STREET

        KINTORE STREET

        PORT ROAD

        PORT ROAD

        PORT ROAD

        PORT ROAD

        CAW

        THO

        RN

        E STR

        EETC

        AWTH

        OR

        NE ST

        REET

        DEVON STREETDEVON STREET

        KINTORE STREETKINTORE STREET

        GOODENOUGH STREETGOODENOUGH STREET

        LIVESTR

        ON

        G PATH

        WAY

        LIVESTR

        ON

        G PATH

        WAY

        SV1SV1

        SV2SV2SV3SV3SV4SV4

        SV5SV5

        SV7SV7SV8SV8

        SV9SV9

        SV10SV10

        SV12SV12

        SV6SV6

        WWAA

        LLSSHHSSTT

        SSMMIITTHH SSTTRREEEETT

        RRANDOLPH S

        ANDOLPH STREETTREET

        PPOORR

        TTRR

        OOAA

        DD

        PPOORR

        TTRR

        OOAA

        DD

        CCAAWW

        TTHHOO

        RRNN

        EESSTT

        RREEEETT

        HHOO

        LLLLAANN

        DDSSTT

        RREEEETT

        DE

        DEW

        SW

        STREET

        TREET

        JJAM

        EA

        MES S

        S STREET

        TREET

        DDOOVVEE SSTTRREEEETT

        00

        LIGHT TERRLIGHT TERRAACECE

        LLIIVVEESSTTRR

        OONN

        GGPPAATTHH

        WWAAYY

        AD

        MELLA

        SA

        DM

        ELLA STR

        EETTR

        EET

        CHAPEL SCHAPEL STREETTREET

        00

        1010000000

        AALLBB

        EERRTT SSTTRR

        EEEETT

        100100 000

        000 GEGEORORGE SGE STREETTREET

        PPOORRTT RROOAADD 11000000000

        000 PPOORRTT RROOAADD

        DDEEWW

        SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

        100100000000

        JJAAMM

        EESSCC

        OONN

        GGDD

        OONN

        DDRR

        IIVVEE

        1010000000

        KKIINNTTOORREE SSTTRREEEETT

        00

        KKIINNTTOORREE SSTTRREEEETT

        PPAARR

        KKEERR

        SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

        DDEEVVOONN SSTTRREEEETT

        FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

        SSV12V12 TCE 55

        PCE lt45

        11-DCE lt24

        12-DCE lt32

        TCE 260

        PCE lt51

        11-DCE lt28

        12-DCE

        SSVV99

        lt37 LEGEND

        SSV10V10 SOIL VAPOUR BORE

        TCE 51 0 INFERRED TCE SOIL VAPOUR CONTOURPCE lt53

        TCE 11000011-DCE lt29

        EPA ASSESSMENT AREAPCE lt13012-DCE lt39

        11-DCE lt69

        CADASTRE12-DCE lt92 SVSV66SVSV77

        SSVV88 TCE 150000

        TCE 14000 56 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)PCETCE 160000 PCE 19 11-DCE lt30PCE 310 0 to lt10000SSVV5511-DCE lt26 12-DCE lt3911-DCE 33 10000 to lt100000

        100000 to lt1000000 1000000

        12-DCE lt35 12-DCE 20

        TCE 43000 SVSV44 SVSV22SVSV33 NotePCE 90 TCE 940000(FD)TCE 1000000 This is one interpretation only Other interpretations possible11-DCE lt15 PCE 15000PCE 1500012-DCE 30 14000 Estimated extent of plume has utilised groundwater11-DCE11-DCE 14000 12-DCE lt930 concentration data12-DCE lt930

        All concentrations are in (μgmsup3) 12-DCE includes cis and trans

        SVSV11 TCE 21000

        FD = Field Duplicate resultPCE 21

        11-DCE lt57

        12-DCE lt76

        12500 A3

        0 25 50 m

        CLIENT

        SA EPA

        PROJECT

        EPA THEBARTON ASSESSMENT AREA - STAGE 1

        TITLE

        FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

        PROJECT NO DATE CREATED

        80607-1 290917

        80607_Fig 7 - Soil Vapour TCE Concentration Plan - 3m r2ai REV 2 gt 290917

        LE

        VE

        L 1

        12

        4 S

        OU

        TH

        TE

        RR

        AC

        E

        AD

        EL

        AID

        E S

        A 5

        00

        0

        PH

        (0

        8)

        82

        32

        90

        88

        F

        AX

        (0

        8)

        82

        32

        90

        99

        E

        MA

        IL

        info

        fy

        fec

        om

        au

        W

        EB

        fy

        fec

        om

        au

        A

        BN

        5

        7 0

        08

        116

        13

        0

        • THEBARTON ASSESSMENT AREA STAGE 1 ENVIRONMENTAL ASSESSMENT FINAL REPORT | EPA REF 0524111 30 OCTOBER 2017 VOLUME 1 REPORT13
        • This report is formatted to print Double Sided
        • TITLE PAGE13
        • CONTENTS13
        • LIST OF ACRONYMS13
        • EXECUTIVE SUMMARY13
        • 1 INTRODUCTION
          • 11 Purpose
          • 12 General background information
          • 13 Definition of the assessment area
          • 14 Identification of contaminants of potential concern
          • 15 Objectives
            • 2 CHARACTERISATION OF THE ASSESSMENT AREA
              • 21 Site identification
              • 22 Regional geology and hydrogeology
              • 23 Data quality objectives
                • 3 SCOPE OF WORK
                  • 31 Preliminary work
                  • 32 Field investigation and laboratory analysis program
                  • 33 Data interpretation
                    • 4 METHODOLOGY
                      • 41 Field methodologies
                      • 42 Laboratory analysis
                        • 5 QUALITY ASSURANCE AND QUALITY CONTROL
                          • 51 Field QAQC
                          • 52 Laboratory QAQC
                          • 53 QAQC summary
                            • 6 ASSESSMENT CRITERIA
                              • 61 Groundwater
                              • 62 Soil vapour
                                • 7 RESULTS
                                  • 71 Surface and sub surface soil conditions
                                  • 72 Waterloo Membrane Samplerstrade
                                  • 73 Groundwater
                                  • 74 Soil vapour bores
                                    • 8 GROUNDWATER FATE AND TRANSPORT MODELLING
                                      • 81 Groundwater flow modelling
                                      • 82 Solute transport modelling
                                        • 9 VAPOUR INTRUSION RISK ASSESSMENT
                                          • 91 Objective
                                          • 92 Areas of interest
                                          • 93 Risk assessment approach
                                          • 94 Tier 1 assessment
                                          • 95 Tier 2 assessment
                                          • 96 Conclusions
                                            • 10 CONCEPTUAL SITE MODEL
                                            • 11 CONCLUSIONS
                                            • 12 DATA GAPS
                                            • 13 REFERENCES
                                            • 14 STATEMENT OF LIMITATIONS
                                            • FIGURES13
                                            • FIGURE 1 SITE LOCATION AND ASSESSMENT AREA
                                            • FIGURE 2 ASSESSMENT POINT LOCATIONS
                                            • FIGURE 3 WATERLOO MEMBRANE SAMPLERTM TCE CONCENTRATION PLAN13
                                            • FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN
                                            • FIGURE 5 GROUNDWATER CONCENTRATION PLAN
                                            • FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)
                                            • FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          6 ASSESSMENT CRITERIA 27

          61 Groundwater 27

          62 Soil vapour 29

          7 RESULTS 31

          71 Surface and sub surface soil conditions 31

          72 Waterloo Membrane Samplerstrade 32

          73 Groundwater 34

          74 Soil vapour bores 40

          8 GROUNDWATER FATE AND TRANSPORT MODELLING 43

          81 Groundwater flow modelling 43

          82 Solute transport modelling 43

          9 VAPOUR INTRUSION RISK ASSESSMENT 47

          91 Objective 47

          92 Areas of interest 47

          93 Risk assessment approach 47

          94 Tier 1 assessment 48

          95 Tier 2 assessment 49

          96 Conclusions 59

          10 CONCEPTUAL SITE MODEL 61

          11 CONCLUSIONS 67

          12 DATA GAPS 71

          13 REFERENCES 73

          14 STATEMENT OF LIMITATIONS 77

          PAGE II 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          LIST OF TABLES

          Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area 7

          Table 22 Data Quality Objectives 8 Table 31 Scope of field investigation program ndash May to August 2017 12 Table 32 Scope of laboratory testing program 13 Table 41 Summary of field methodologies 15 Table 51 Field QAQC procedures ndash Groundwater 22 Table 52 Field QAQC procedures ndash Soil vapour 23 Table 53 Laboratory QAQC procedures 25 Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area 28 Table 62 Sources of adopted groundwater assessment criteria 29 Table 71 Detectable Waterloo Membrane Samplertrade CHC results 32 Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units 33 Table 73 Hydraulic conductivities (rising and falling head tests) 35 Table 74 Detectable groundwater CHC results 37 Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area 41 Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores 42 Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs 49 Table 92 Tier 2 vapour intrusion modelling ndash building input parameters 51 Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters 52 Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air 52 Table 95 Summary of chemical parameters adopted for vapour intrusion modelling 52 Table 96 Comparison of predicted residential indoor air concentrations with SA EPA

          response levels 54 Table 97 Summary of model input parameters subjected to sensitivity analysis 55 Table 98 Exposure parameters ndash Commercialindustrial workers 58 Table 99 Adopted inhalation toxicity reference values 58 Table 910 Summary of properties with predicted indoor air concentrations

          (residential crawl space) above adopted EPA response levels 59 Table 101 Summary of existing information for the Thebarton EPA Assessment Area 61

          LIST OF FIGURES (in text)

          Figure 71 Piper diagram 39 Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green)

          relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple) 46

          Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels 50

          80607-1 REV1 30102017 PAGE III

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          FIGURES follow page 79

          Figure 1 Site Location and Assessment Area Figure 2 Assessment Point Locations Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan Figure 4 Groundwater Elevation Contour Plan Figure 5 Groundwater Concentration Plan Figure 6 Soil Vapour Concentration Plan (10 m) Figure 7 Soil Vapour Concentration Plan (30 m)

          VOLUME 2 APPENDICES

          APPENDICES

          Appendix A Historical Report Summary Appendix B Historical Information Supplied by the EPA Appendix C DEWNR Registered Groundwater Database Search Results Appendix D Groundwater Well Permits Appendix E Field Sampling Sheets ndash Groundwater Appendix F Survey Data Appendix G Certified Laboratory Certificates and Chain of Custody Documentation Appendix H Groundwater Well Log Reports Appendix I WMStrade Borehole Log Reports Appendix J Soil Vapour Borehole Log Reports Appendix K Waste Transport Certificates Appendix L Tabulated Results ndash Soil Vapour Geotechnical and Groundwater Appendix M Equipment Calibration Records Appendix N Drill Core Photographs Appendix O Arcadis Groundwater Fate and Transport Modelling Report Appendix P Arcadis Vapour Intrusion Risk Assessment Report

          PAGE IV 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          LIST OF ACRONYMS

          AER Air Exchange Rate

          AF Attenuation Factor

          AHD Australian Height Datum

          ANZECC Australian and New Zealand Environment and Conservation Council

          ARMCANZ Agriculture and Resource Management Council of Australia and New Zealand

          ASC Assessment of Site Contamination

          ASTM American Standard Testing Material

          AT Averaging Time

          ATSDR Agency for Toxic Substances and Disease Registry

          AWQC Australian Water Quality Centre

          BGL Below Ground Level

          BTEX Benzene Toluene Ethylbenzene Xylenes

          BTOC Below Top of Casing

          BUA Beneficial Use Assessment

          CBD Central Business District

          CHC Chlorinated Hydrocarbon Compound

          COC Chain of Custody

          COPC Contaminants of Potential Concern

          CRC CARE Cooperative Research Centre for Contamination Assessment and Remediation of the Environment

          CSM Conceptual Site Model

          11-DCA 11-dichloroethane

          11-DCE 11-dichloroethene

          12-DCE 12-dichloroethene

          DCE Dichloroethene

          DEC Department of Environment and Conservation

          DEWNR Department of Environment Water and Natural Resources

          DNAPL Dense Non-Aqueous Phase Liquid

          DO Dissolved Oxygen

          DQI Data Quality Indicator

          DQO Data Quality Objective

          EC Electrical Conductivity

          ED Exposure Duration

          80607-1 REV1 30102017 PAGE V

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          EF Exposure Frequency

          EMP Environmental Management Plan

          EPA Environment Protection Authority

          EPC Exposure Point Concentration

          EPP Environment Protection Policy

          ET Exposure Time

          GPA Groundwater Prohibition Area

          GPR Ground Penetrating Radar

          GPS Global Positioning System

          HHRA Human Health Risk Assessment

          HIL Health Investigation Level

          HSP Health and safety Plan

          IPA Isopropyl Alcohol (isopropanol or 2-propanol)

          IRIS Integrated Risk Information System

          ITRC Interstate Technology and Regulatory Council

          JampE Johnson and Ettinger

          JHA Job Hazard Analysis

          LNAPL Light Non-Aqueous Phase Liquid

          LOR Limit of Reporting

          MGA Map Grid of Australia

          MQO Measuring Quality Objectives

          MTC Mass Transfer Co-efficient

          NA Not Applicable

          NAPL Non-Aqueous Phase Liquid

          NATA National Association of Testing Authorities

          ND Non Detect

          NEPM National Environment Protection Measure

          NHMRC National Health and Medical Research Council

          NJDEP New Jersey Department of Environmental Protection

          NRMMC National Resource Management Ministerial Council

          PAH Polycyclic Aromatic Hydrocarbons

          PCE Tetrachloroethene (perchloroethylene)

          PID Photoionisation Detector

          PQL Practical Quantification Limit

          PSD Particle Size Distribution

          QA Quality Assurance

          80607-1 REV1 30102017 PAGE VI

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          QC Quality Control

          RAIS Risk Assessment Information System

          RFQ Request for Quote

          REM Resource and Environmental Management

          RPD Relative Percentage Difference

          RSL Regional Screening Level

          SA EPA South Australian Environment Protection Authority

          SAQP Sampling and Analysis Quality Plan

          SOP Standard Operating Procedure

          SVOC Semi-Volatile Organic Compound

          SWL Standing Water Level

          SWMS Safe Work Method Statement

          111-TCA 111-trichloroethane

          TCE Trichloroethene

          TDS Total Dissolved Solids

          TRH Total Recoverable Hydrocarbons1

          TRV Toxicity Reference Value

          US EPA United Stated Environment Protection Agency

          USGS United States Geological Survey

          VC Vinyl Chloride

          VIRA Vapour Intrusion Risk Assessment

          VOC Volatile Organic Compound

          VOCC Volatile Organic Chlorinated Compound

          WHO World Health Organisation

          WMStrade Waterloo Membrane Samplertrade

          TRH = measurable amount of petroleum-based hydrocarbon (ie complex mixture of crude oil and natural gas (gt 250 compounds) including aromatics aliphatics paraffins unsaturated alkanes and naphthalenes) plus various other compounds including fatty acids esters humic acids phthalates and sterols

          80607-1 REV1 30102017 PAGE VII

          1

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          EXECUTIVE SUMMARY

          Background information

          An approximate 27 hectare mixed use area of Thebarton has been designated by the South Australian Environment Protection Authority (EPA) as the Thebarton EPA Assessment Area

          The former Austral sheet metal works (Austral) property located over multiple allotments between George and Maria Streets from the 1920s until the 1960s-1970s has been identified as a possible source of dissolved phase groundwater chlorinated hydrocarbon (CHC) contamination Groundwater CHC impacts within the uppermost (Quaternary ndash Q1) aquifer were identified as extending in a general north-westerly direction (consistent with regional groundwater flow direction) from the south-eastern portion of the Thebarton EPA Assessment Area and having resulted in the generation of soil vapour containing elevated concentrations of CHC

          The boundaries of the Thebarton EPA Assessment Area were established on the basis of the following

          the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street (part of the former Austral property) and 39 Smith Street (hydraulically down-gradient of the former Austral property) in Thebarton

          the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

          the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

          Key objectives

          The results of the recent investigations undertaken by Fyfe have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties within the Thebarton EPA Assessment Area

          The key objectives detailed by the EPA were to

          further delineate the chlorinated hydrocarbon contamination in groundwater

          further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

          undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

          80607-1 REV1 30102017 PAGE VIII

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          With respect to the VIRA the EPA requested that there be specific consideration of

          residential properties (slab on grade)

          residential properties (crawl space)

          residential properties (with basement) and

          trenchmaintenanceutility workers that may be working in the vicinity of the contamination

          Site conditions

          Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were identified within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m below ground level (BGL) during the drilling of groundwater well MW17 the latter consistent with the depth of groundwater within the Q1 aquifer

          Soil

          Groundwater within the Q1 aquifer is located at a depth of approximately 123 to Groundwater 159 m BGL and flows in a general north-westerly direction The closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred and the groundwater gradient is relatively flat (ie 000062 to 00012)

          Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified (based on factors such a groundwater salinity registered bore use and the locations of potential sensitive receptors) as including domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux) and possibly also potable

          Contaminants of Potential Concern (COPC)

          The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans-) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

          80607-1 REV1 30102017 PAGE IX

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Scope of work

          A groundwater and soil vapour monitoring program was undertaken by Fyfe across the Thebarton EPA Assessment Area between May and August 2017 It involved the following scope of work

          installation of a total of 41 WMStrade units to 1 m BGL in an approximate grid-pattern across the entire assessment area (Round 1) and at specific targeted locations (Round 2) followed by laboratory analysis of retrieved sample units for specific CHC

          drilling and installation of 25 groundwater wells to depths of between 15 and 19 m BGL including a background well to the east of the southern portion of the assessment area

          testing of 30 selected groundwater well drill core samples for geotechnical parameters

          gauging and sampling of the 25 newly installed groundwater wells as well as an existing well located in Admella Street followed by laboratory analysis of all samples for specific CHC and 10 selected samples for major cationsanions natural attenuation parameters and additional nutrients

          aquifer permeability (rising and falling head ldquoslugrdquo) testing of 10 groundwater wells

          drilling and installation of 13 soil vapour bores including 11 nested bores (ie to 1 and 3 m BGL) and two bores to 1 m BGL and

          sampling of all soil vapour bores followed by laboratory analysis of samples for specific CHC and general gases

          The soil vapour data were used to undertake a VIRA aimed at predicting indoor air concentrations of TCE under various land use and building construction scenarios In order to validate the results of the modelling which includes a number of conservative assumptions and is therefore expected to over-estimate potential risk the EPA has commissioned indoor air monitoring in a number of residential properties within the Thebarton EPA Assessment Area ndash the indoor air monitoring results will be reported under separate cover

          Groundwater fate and transport modelling was undertaken to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton EPA Assessment Area The provision of this information is aimed at supporting the definition (extent and geometry) of a potential future Groundwater Prohibition Area (GPA) to be designated by the EPA in accordance with the provisions of Section S103S of the Environment Protection Act 1993

          80607-1 REV1 30102017 PAGE X

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Identified impacts

          Contaminants identified in the Q1 aquifer beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down

          Groundwater

          (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested

          The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected (Austral) source site in accordance with the predominant flow direction associated with the Q1 aquifer The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) ndash whereas its north-western extent has not yet been determined the groundwater CHC plume has been delineated in all other directions

          Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion

          Soil vapour

          The soil vapour samples with the maximum TCE concentrations also had the highest PCE and 11-DCE concentrations (or elevated laboratory limits of reporting (LOR)) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-)

          Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE exceeded the adopted health investigation levels (HILs) for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE degradation has not yet resulted in its production

          Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

          80607-1 REV1 30102017 PAGE XI

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Assessment of risk

          Measured concentrations of TCE exceeded the adopted assessment criteria for potable use andor primary contact recreation in wells located on Admella Maria George Albert Chapel and Dew Streets as well as Light Terrace ndash with the highest concentrations corresponding to the ldquocorerdquo area of the plume One well on Albert Street also contained a concentration of carbon tetrachloride that exceeded the respective potable criterion

          Groundwater risks

          Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous

          Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

          The groundwater modelling undertaken by Arcadis involved the development of an Groundwater fate and transport initial groundwater flow model using MODFLOW followed by the development of a modelling site-specific (three-dimensional) solute transport model using the MT3DMS transport

          code

          The results of this modelling were interpreted to indicate the following

          although scattered detectable concentrations of 12-DCE have been measured in groundwater across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE daughter products indicate that substantial dechlorination is not occurring and

          the dissolved phase groundwater TCE plume is predicted to extend by another 500 m (ie beyond the boundaries of the current Thebarton EPA Assessment Area) over the next 100 years whereas no significant lateral plume expansion is expected

          The VIRA undertaken by Arcadis involved a two-tier assessment approach Whereas Vapour intrusion the Tier 1 screening risk assessment compared the measured soil vapour CHC concentrations to (modified) guideline values the Tier 2 risk assessment involved the application of the Johnson and Ettinger vapour intrusion model to predict indoor air CHC concentrations for residential (slab on grade crawl space and basement construction) and commercialindustrial (slab on grade construction) properties across the assessment area Site-specific geotechnical parameters and soil vapour data collected from 1 and 3 m BGL throughout the Thebarton EPA Assessment Area were used in the modelling It should be noted that overall the vapour modelling

          risks

          80607-1 REV1 30102017 PAGE XII

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

          The results of the VIRA with respect to the predicted indoor air concentrations of TCE within residential properties (assuming crawl space construction) versus adopted EPA response levels indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air that require further action as follows

          10 properties within the investigation range (2 to lt20 microgm3)

          eight properties within the intervention range (20 to lt200 microgm3) and

          three properties within accelerated intervention range (ge200 microgm3)

          All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises

          Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which is expected to be overly-conservative) ndash these results will be documented in a subsequent report

          Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie as determined for the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

          A qualitative assessment of potential risks to subsurface trenchmaintenanceutility workers indicated that exposure management may be required in areas where TCE concentrations at 1 m BGL are above 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific health and safety plan (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a photoionisation detector (PID) unit providing increased ventilation and using appropriate personal protective equipment (eg gas masks) as required

          80607-1 REV1 30102017 PAGE XIII

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Data gaps

          Based on the results obtained during the recent Fyfe investigations as well as available historical information the following data gaps have been identified for the Thebarton EPA Assessment Area

          property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

          groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

          the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

          the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

          Notes ie the interim soil vapour HILs adopted from the National Environment (Assessment of Site Contamination) Measure 1999 (as revised in 2013 ndash ie the ASC NEPM (1999)) but assuming a sub-slab to indoor air attenuation factor of 003 as compared to the value of 01 adopted by the ASC NEPM (1999)

          80607-1 REV1 30102017 PAGE XIV

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          1 INTRODUCTION

          11 Purpose

          Fyfe Pty Ltd (Fyfe) was commissioned by the South Australian Environment Protection Authority (SA EPA referred to herein as the EPA) to undertake Stage 1 groundwater and soil vapour investigation works groundwater fate and transport modelling and a human health vapour intrusion risk assessment (VIRA) within an EPA designated assessment area located within Thebarton South Australia (herein referred to as the Thebarton EPA Assessment Area) The location and extent of the Thebarton EPA Assessment Area referenced within this document is identified on Figure 1

          12 General background information

          Previous environmental assessment work undertaken since 1994 (as summarised in Appendix A) combined with historical information provided by the EPA (as included in Appendix B) indicates that the Thebarton EPA Assessment Area has been used for mixed residential and commercialindustrial purposes over time

          Groundwater impacts2 identified within the uppermost (Quaternary ndash Q1) aquifer in the vicinity of the former Austral sheet metal works (Austral) on George Street included both petroleum hydrocarbons (ie diesel fuel) as well as chlorinated hydrocarbon compounds (CHC) such as trichloroethene (TCE) and were first notified to the EPA in 2006

          Available historical information for the Austral property (ie the suspected source site) indicates that it operated from the 1920s until the 1960s-1970s and occupied an extensive area of Thebarton including

          part of the southern side of George Street extending from about half way between East Terrace3 and Admella Street (ie 11-25 George Street) to the west of Admella Street (ie 31-35 George Street)

          the entire northern side of Maria Street from East Terrace to the west of Admella Street

          part of the southern side of Maria Street (ie from 21 Maria Street) to Admella Street and

          25-27 East Terrace

          2 Note that the term ldquoimpactrdquo has been used by Fyfe to indicate identified concentrations of compounds (specifically chlorinated hydrocarbons) that are not naturally occurring (ie concentrations above background that have resulted from anthropogenic activities) The use of this term does not denote that the presence of these compounds represents a risk to either human health or the environment and the term ldquoimpactrdquo is therefore not directly interchangeable with the term ldquoSite Contaminationrdquo the latter defined under the Environment Protection Act 1993 to include actual or potential harm to human health andor the environment

          3 now James Congdon Drive

          80607-1 REV1 30102017 PAGE 1

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Historical newspaper articles described the Austral property as hosting a factory that extended over more than three acres and included an electroplating facility In 1938 it was described as the largest aluminium utensil manufacturing company in the southern hemisphere

          Other potential sources of groundwater contamination4 identified within the Thebarton EPA Assessment Area include a former gas works (ie located to the south and south-east of the Austral property and including the current Ice Arena property) a mechanicrsquos workshop another sheet metal working facility and a farm machinery manufacturer

          The Stage 1 assessment work described herein was commissioned by the EPA to determine whether historical contamination in the vicinity of George Street was presenting a risk to human health or the environment

          13 Definition of the assessment area

          As detailed on Figure 1 the current EPA Assessment Area covers an area of approximately 27 ha within the suburb of Thebarton located approximately 2 km north-west of the Adelaide central business district (CBD)

          The boundaries of the Thebarton EPA Assessment Area were established by the EPA on the basis of the following

          the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street and 39 Smith Street in Thebarton (refer to Appendix A)

          the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

          the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

          14 Identification of contaminants of potential concern

          The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

          Site Contamination is defined by the Environment Protection Act 1993 as existing if chemical substances are present on or below the surface of a site in concentrations above background the contaminants are there as a result of activity at the site or elsewhere and their presence has resulted in actual or potential harm (that is not trivial) to the health and safety of human beings taking into account current and proposed land uses or water or the environment

          PAGE 2 80607-1 REV1 30102017

          4

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          15 Objectives

          As defined by the EPA the key objectives of the recent Stage 1 environmental assessment program undertaken within the Thebarton EPA Assessment Area (refer to Figure 1) were to

          further delineate the chlorinated hydrocarbon contamination in groundwater

          further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

          undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

          With respect to the VIRA the EPA requested that there be specific consideration of

          residential properties (slab on grade)

          residential properties (crawl space)

          residential properties (with basement) and

          trenchmaintenanceutility workers that may be working in the vicinity of the contamination

          80607-1 REV1 30102017 PAGE 3

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          2 CHARACTERISATION OF THE ASSESSMENT AREA

          21 Site identification

          For the purpose of this investigation program the Thebarton EPA Assessment Area (as delineated in Figure 1) has been defined by the following roadways

          North northern verge of Smith Street

          South Maria Street (between Dew Street and Albert Street) portion of Parker Street (between Maria Street and Goodenough Street) and Goodenough Street (between Parker Street and James Congdon Drive)

          East western verge of Port Road and James Congdon Drive and

          West western verge of Dew Street

          22 Regional geology and hydrogeology

          221 Geology

          The Thebarton area is located within the Adelaide Plains approximately 8 km to the east of Gulf St Vincent and to the west of the Para Fault It lies within the Golden Grove ndash Adelaide Embayment area of the St Vincent Basin which consists of a succession of Tertiary and Quaternary age sediments (with thicknesses of up to 600 m) overlying basement rocks

          The 1250000 Adelaide geological map (SA Department of Mines and Energy 1969) indicates that the near-surface geology of the area consists primarily of Quaternary aged soils and sediments including the Pooraka and Hindmarsh Clay formations The Pleistocene aged Pooraka Formation generally comprises a thickness of approximately 10 m and is of alluvial origin comprising sandy clays and clayey to sandy silts interbedded with layers of clay sand andor gravel The underlying Pleistocene aged Hindmarsh Clay Formation represents the basal unit of the Adelaide Plains and has a maximum general thickness of more than 100 m It generally comprises a basal gravel layer a middle layer of mottled medium to high plasticity (red-brown yellow brown greygreen to orange) often stiff to hard clays and an upper layer of fluvial and alluvial red-brown silty sand Gerges (1999) describes Hindmarsh Clay as comprising a mottled brown to pale olive grey predominantly clay formation that becomes green grey towards the basal section (approximately 16 to 20 m below ground level (BGL)) and is characterised by an increasing gravel content with depth

          Underlying the Hindmarsh Clay are sands and limestone of Tertiary age which are in turn underlain by metamorphosed basement rock of the Proterozoic Umberatana Group

          80607-1 REV1 30102017 PAGE 5

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          222 Hydrogeology

          According to Gerges (2006) the aquifers identified within the Quaternary aged sediments of the Adelaide Plains are typically found within the coarser interbedded silt sand and gravel layers of the Hindmarsh Clay Formation and vary greatly in thickness (typically from 1 to 18 m) lithology and hydraulic conductivity Confining beds between the Quaternary aquifers consist of clay and silt layers and range in thickness from 1 to 20 m These confining beds vary in terms of the amount of coarser grained material they contain their bulk hydraulic conductivity andor the presence and density of fractures In addition their absence in some areas allows direct hydraulic connection between the aquifers

          The Thebarton area is located within Hydrogeological Zone 3 (Subzone 3E) of Gerges (2006) This zone contains five to six Quaternary aquifers and three to four almost flat-lying Tertiary aquifers The first Tertiary aquifer estimated by Gerges (2006) to be intersected at a depth of approximately 130 m BGL near the Para Fault is most frequently accessed for industrial and recreational groundwater use

          The Q1 aquifer assessed as part of the current investigations is typically located at depths of between 3 and 10 m BGL beneath the Adelaide Plains with an average thickness of 2 m The Q1 aquifer contains water of variable salinity with Subzone 3E including a range of 500 to 3500 mgL total dissolved solids (TDS) The gradient of the Q1 aquifer is generally flat (particularly to the west of the Para Fault) and flow direction is typically towards the north-west

          A search of the registered bore database maintained by the Department of Environment Water and Natural Resources (DEWNR (2017) WaterConnect database) identified 59 bores within the general Thebarton area of which 18 are located in the Thebarton EPA Assessment Area Although eight bores were installed for monitoring purposes on or immediately adjacent to the property located at 31-37 George Street (ie part of the former Austral facility) it is understood that only one bore (6628-21951 ndash located within the Admella Street roadway intersecting the Q1 aquifer and identified as MW01 in Appendix A but MW02 by Fyfe5) remains in situ

          In addition to numerous monitoringinvestigationobservation bores the Q1 aquifer within the general (ie broader) Thebarton area is recorded in the DEWNR (2017) database as being accessed for drainage domestic and industrial purposes

          DEWNR (2017) information for registered bores located within the general Thebarton area is included in Appendix C whereas information for bores located within the Thebarton EPA Assessment Area (excluding those associated with the property at 31-37 George Street and installed solely for monitoring purposes6) is summarised in Table 21

          5 This existing groundwater well was identified as MW02 by Fyfe in accordance with the markings on the gatic cover and the DEWNR (2017) WaterConnect bore identification details although it was originally installed as MW01 by REM (refer to discussion of previous reports in Appendix A)

          6 ie 6628-21951 6628-21952 6628-22229 to 6628-22233 and 6628-22236

          PAGE 6 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area

          Bore ID Location Purpose Status Maximu SWL Salinity Yield Aquifer m well (m (mgL (Lsec

          Tertiary (T1)

          depth BGL) TDS) ) (m BGL)

          125 6628-516 Coca Cola plant Rehabilitated 138 1963 794

          6628-1435 Coca Cola plant Backfilled 184 212 921 392 Tertiary (T1)

          6628-4576 Corner of Admella amp Chapel Streets

          125 1454 445 Tertiary (T1)

          6628-7724 Coca Cola plant Observation 155 2017 1272 1516 Tertiary (T1)

          6628-7725 Coca Cola plant Observation 127 3016 1100 1005 Tertiary (T1)

          6628-12516 Coca Cola plant Industrial Backfilled 210 212 1300 1875 Tertiary (T1)

          6628-20663 39 Smith Street Irrigation 121 1105 50 Tertiary (T1)

          6628-20969 39 Smith Street Industrial 30 14 1535 25 Quaternary (Q1)

          6628shy21951

          Admella Street 20 Quaternary (Q1)

          6628-22395 21 James Congdon Drive

          20 157 1541 05 Quaternary

          6628-23525 41 Maria Street 206 273 1078 10 Tertiary (T1)

          Notes Shading indicates that information was not recorded in the database as interpreted from information provided in the database ndash approximate only in some instances

          ie MW02 as included in the groundwater monitoring program of Fyfe ndash refer to Table 31 Abbreviations BGL = below ground level SWL = standing water level TDS = total dissolved solids

          23 Data quality objectives

          The Data Quality Objective (DQO) process as described in Australian Standard AS44821-2005 and the National Environment Protection (Assessment of Site Contamination) Measure (ASC NEPM 1999)7

          Schedule B2 Guideline on Data Collection Sample Design and Reporting and more fully documented in the NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme involves a seven-step iterative approach that was initially developed by the United States Environment Protection Agency (US EPA) to facilitate the systematic planning and verification of contaminated sites assessment projects

          As stated in Schedule B2 of the ASC NEPM (1999) the first six steps of the DQO process comprise the development of qualitative and quantitative statements that define the objectives of the site assessment program and the quantity and quality of data needed to inform risk-based decisions These steps enable the

          All references to the ASC NEPM (1999) refer to the version amended on 16 May 2013

          80607-1 REV1 30102017 PAGE 7

          7

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          project team to communicate the goals decisions constraints (eg time budget) and uncertainties associated with the project and detail how they are to be addressed The seventh step comprises the development of a Sampling and Analysis Quality Plan (SAQP) to generate the data required to adequately characterise site contamination issues and assess their associated potential environmental and human health risks under the proposed land use scenario

          The DQOs defined for the Thebarton EPA Assessment Area are summarised in Table 22

          Table 22 Data Quality Objectives

          Objective Comment

          Step 1 ndash Statement of the Problem According to information provided to Fyfe by the EPA (as summarised in Appendix A) a property located at 31-37 George Street (immediately west of Admella Street) in Thebarton and historically occupied by part of the Austral facility had been found to be underlain by groundwater CHC (primarily TCE) impacts More recent reporting to the EPA for a property at 39 Smith Street located approximately 350 m north-west (and hydraulically down-gradient) of the George Street property indicated that detectable CHC (predominantly TCE) were also present within groundwater Since this area of Thebarton is occupied by a mixture of commercialindustrial and residential properties and the source and extent of the CHC impacts within the Q1 aquifer had not yet been determined potential risks to human health andor the environment had yet to be assessed

          Step 2 ndash The Decision that Needs The assessment works commissioned by the EPA were necessitated to to Result from the Investigation investigate the source extent and magnitude of the groundwater CHC

          contamination beneath a designated area of Thebarton (ie that included both the George Street and Smith Street properties) and to understand the possible risk to public health from potential vapour generation Fyfe have therefore undertaken vapour modelling and intrusion risk assessment works aimed at evaluating whether concentrations of identified groundwater andor soil vapour contaminants pose an unacceptable risk to human health In addition groundwater fate and transport modelling has been undertaken to predict the extent of the plume This will assist the EPA to determine a potential future Groundwater Prohibition Area (GPA) in accordance with the provisions of Section 103S of the Environment Protection Act 1993

          Step 3 ndash Inputs to the Decision The information that was required to resolve the decision statement included the collection of physical and chemical data from across the Thebarton EPA Assessment Area The collected data as well as physical observations regarding the geology of the area and possible preferential contaminant pathways was used to determine potential risks to human health via groundwater fate and transport and vapour intrusion modelling

          Step 4 ndash Boundaries of the Investigation

          The lateral boundaries of the Thebarton EPA Assessment Area are as defined in Sections 13 and 21 as depicted on Figure 1 Vertically the investigations extended as far as the maximum drilled depth (19 m BGL)

          Step 5 ndash Decision Rules The decision rule will be based upon the identification of predicted indoor air concentrations of CHC compounds associated with groundwater andor soil vapour impacts which exceed adopted response levels

          PAGE 8 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Objective Comment

          Step 6 ndash Decision Error Tolerances The purpose of establishing decision error tolerance is to control the acceptable degree of uncertainty upon which decisions are made in order to avoid the making of an incorrect decision and to enable identification of additional investigation monitoring or remediation activities required on the basis of accurate data for the protection of human health and the environment The Measuring Quality Objectives (MQO) include the quality assurance (QA) activities that were conducted during the assessment the quality control (QC) acceptance criteria applicable to the assessment and the adopted Data Quality Indicators (DQIs) as follows (and further discussed in Section 5) completeness ndash a measure of the amount of useable data from a data

          collection activity comparability ndash the confidence (expressed qualitatively) that data may be

          considered to be equivalent for each sampling and analytical event representativeness ndash the confidence (expressed qualitatively) that data

          are representative of each media present on the site precision ndash a quantitative measure of the variability (or reproducibility) of

          data and accuracy (bias) ndash a quantitative measure of the closeness of reported data

          to the true value

          Step 7 ndash Optimisation of the Data collection was undertaken in general accordance with the Sample Collection Design methodologies outlined in the relevant documentsguidelines referenced

          throughout this report As determined by the EPA the data collection design included targeted sampling to investigate and delineate areas of potential groundwater and soil vapour contamination and to assess potential associated human health risks

          80607-1 REV1 30102017 PAGE 9

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          3 SCOPE OF WORK

          The scope of work undertaken by Fyfe was generally consistent with that requested within the original EPA request for quote (RFQ) dated 27 March 2017 Some modifications to the original workscope occurred based on site findings and additional site information was collected where required and as agreed with the EPA in order to achieve the EPArsquos project objectives outlined in Section 15

          As identified in the RFQ the scope of work was designed to

          provide an initial delineation of CHC impacts in soil vapour through the deployment of Waterloo Membrane Samplers (WMStrade) as a screening tool

          further delineate the previously identified CHC impacts in groundwater

          decide based on the results of the WMStrade and groundwater results the need for the number of and the locations of permanent soil vapour monitoring bores

          identify the nature extent and potential source area(s) of the identified CHC impacts in groundwater andor soil vapour

          determine the likely fate and transport of the groundwater CHC plume to support the establishment of a potential future GPA

          determine the potential human health (including vapour intrusion) risk(s) on the basis of the data collected and

          ascertain whether or not a public health risk exists within the Thebarton EPA Assessment Area

          The scope of work is further detailed in Section 32 Variations from the scope of work originally requested in the EPA RFQ were agreed with the EPA during the course of the project and included the following

          deployment of an additional four WMStrade units ndash ie 41 in total as compared to the original allowance of 37

          installation (and sampling) of an additional six nested soil vapour bores (to depths of 1 and 3 m BGL) ndash ie 11 in total as compared to the original allowance of five

          installation (and sampling) two individually located (ie as opposed to the nested locations) soil vapour bores to a depth of 1 m BGL ndash ie as compared to the original allowance of 10

          installation (and sampling) of 25 groundwater monitoring wells ndash ie as compared to the original allowance of 20 and

          sampling of an existing well in Admella Street (MW02) ndash ie not included in the original EPA scope

          80607-1 REV1 30102017 PAGE 11

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          31 Preliminary work

          Preliminary work involved the following

          review and summation of all available historical reports (as supplied by the EPA) ndash refer to Appendix A

          development of a preliminary (working) conceptual site model (CSM) based on a review of the historical data

          preparation of a detailed health and safety plan covering all aspects and stages of the work and

          detailed planning with key stakeholders prior to the execution of the field investigation program

          32 Field investigation and laboratory analysis program

          The scope of the field investigation program undertaken by Fyfe between 31 May and 28 August 2017 is summarised in Table 31 whereas the scope of the laboratory testing program is summarised in Table 32

          A plan showing the various assessment point locations is included as Figure 2

          Table 31 Scope of field investigation program ndash May to August 2017

          Scope Item Description of works Date of works

          Passive soil vapour sampling ndash Round 1

          Thirty-seven WMStrade units identified as WMS 1 to WMS 37 were installed within the soil profile to 1 m BGL at scattered (approximately grid-like) locations across the Thebarton EPA Assessment Area

          31 May and 1 to 2 June

          The WMStrade units were extracted and forwarded to the analytical laboratory 7 June

          Soil bores were located using a hand-held global positioning system (GPS) unit before being backfilled with (drillerrsquos) sand

          7 August

          Monitoring well drilling and installation

          Individual groundwater well permits were obtained from DEWNR prior to well installation ndash copies of the well permits are included in Appendix D Groundwater monitoring wells (MW1 MW3 and MW5 to MW26) were installed to depths of between 15 and 19 m BGL at 24 locations across the Thebarton EPA Assessment Area Background well MW4 was installed to 19 m BGL within a public recreational area located across James Congdon Drive to the east (ie near the south-eastern corner of the Thebarton EPA Assessment Area) All 25 newly installed wells were developed following installation

          28 to 30 June 3 to 7 July and 10 to 14 July

          Geotechnical soil testing

          Intact soil cores collected during the drilling of 10 groundwater wells (MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25) were forwarded to the analytical laboratory for geotechnical testing

          Groundwater gauging

          All 25 newly installed monitoring wells (MW1 and MW3 to MW26) as well as the existing Admella Street well (MW02) were gauged to assess total well depth standing water level (SWL) and the presenceabsence of non aqueous phase liquid (NAPL) This was undertaken as a discrete event prior to the commencement of groundwater sampling

          18 July

          PAGE 12 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Scope Item Description of works Date of works

          Groundwater sampling

          All 26 existing and newly installed wells were sampled using a combination of low flow (micropurge) and HydraSleevetrade sampling techniques (as recorded on the field sampling sheets in Appendix E) ndash samples were forwarded to the analytical laboratories

          18 to 21 and 24 to 25 July

          Aquifer testing Aquifer permeability (slug) testing was undertaken on 10 wells (MW02 MW3 MW7 MW14 MW17 MW20 MW21 MW23 MW25 and MW26) Data was subsequently evaluated by Arcadis Pty Ltd (Arcadis) to estimate the hydraulic conductivity of the aquifer beneath the Thebarton EPA Assessment Area (refer to Section 732)

          28 July

          Soil vapour bore drilling and installation

          Following the receipt of the groundwater data 11 nested soil vapour bores (SV1 to SV10 and SV12) were installed to a depth of 1 and 3 m BGL at selected locations within the Thebarton EPA Assessment Area Two additional soil vapour bores (SV11 and SV13) were installed to a depth of 1 m BGL

          18 21 and 22 August

          Active soil vapour sampling

          Sampling of soil vapour bores was undertaken using summa canister (TO-15) sample collection methods Vapour (canister) and general gas (Tedlar bag) samples were extracted from all 13 locations (ie SV1 to SV13) including the 11 nested bores

          24 August

          Passive soil vapour sampling ndash Round 2

          Following the receipt of the groundwater data and for the purposes of comparison with the soil vapour bore data an additional four WMStrade units (WMS 38 to WMS 41) were installed within the soil profile to 1 m BGL at targeted locations across the Thebarton EPA Assessment Area (ie within approximately 1 m of soil vapour bores SV2 SV4 SV5 and SV7) Soil bores were located using a hand-held GPS unit

          18 August

          The WMStrade units were extracted and forwarded to the analytical laboratory and the soil bores were backfilled with (drillerrsquos) sand

          24 August

          Surveying The locations of all soil vapour bores and groundwater wells were surveyed by a licensed surveyor relative to the Map Grid of Australia (MGA) 1994 and the top of each bore was surveyed relative to Australian Height Datum (AHD) The survey data are included in Appendix F

          22 July and 28 August

          Notes as determined by the EPA

          Table 32 Scope of laboratory testing program

          Scope Item Description of works

          Soil geotechnical testing

          Soil samples from each of three depths within core samples collected during the drilling of groundwater wells MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25 were analysed for particle size distribution (PSD) moisture content including degree of saturation bulk density dry density and specific gravity void ratio and porosity

          80607-1 REV1 30102017 PAGE 13

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Scope Item Description of works

          Groundwater testing Groundwater samples from all 26 wells were analysed for the COPC detailed in Section 14 As requested by the EPA groundwater samples from selected wells (MW02 MW5 MW8 MW9 MW12 MW17 MW21 MW22 MW23 and MW26) were also analysed for the following major cations and anions (calcium magnesium sodium potassium chloride and alkalinity)

          and natural attenuation parameters (carbon dioxide (CO2) sulfate iron manganese nitrate) Additional components reported by the analytical laboratory included nitrite and nitrate + nitrite

          Soil vapour testing The WMStrade units deployed during each of Rounds 1 and 2 were analysed for the COPC detailed in Section 14 The soil vapour (summa canister) samples were analysed for the COPC detailed in Section 14 as well as 2-propanol and general gases (helium hydrogen oxygen nitrogen methane carbon dioxide ethane propane butane iso-butane pentane iso-pentane hexane argon carbon monoxide and ethylene)

          Notes Specific sample depths are detailed in the relevant laboratory reports in Appendix G also known as isopropyl alcohol isopropanol or IPA

          33 Data interpretation

          Following the receipt and collation of the field and laboratory data hydrogeological (fate and transport) and VIRA modelling (refer to Sections 8 and 9 respectively) were undertaken to enable an assessment of risk and to refine the CSM (Section 10)

          PAGE 14 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          4 METHODOLOGY

          41 Field methodologies

          Prior to the commencement of the field investigations a site specific Health and Safety Plan (HSP) including Safe Work Method Statements (SWMS) and a Job Hazard Analysis (JHA) was prepared ndash all personnel working at the site were required to read understand sign and conform to the HSP

          Each proposed drilling location was cleared of underground services by a professional service location company (Pipeline Technologies) using conventional (electronic) service detection methods as well as ground penetrating radar (GPR) Where underground or overhead services were present andor deemed to be a potential safety risk during drilling activities the drill location was moved to an area considered by the Fyfe representative and service locator to be safe All changes to drilling locations were notified to EPA and recorded on a site plan for future reference

          Given that works were undertaken within suburban streets Fyfe employed the services of a qualified traffic management company (Altus Traffic) during drilling activities in order to ensure safety for pedestrians and road users minimal disruption to traffic flow and the provision of a safe working environment

          Field methodologies as detailed in Table 41 were undertaken in accordance with Fyfersquos standard operating procedures (SOPs) Relevant field sampling sheets are included in Appendices F (groundwater) and G (soil vapour ndash combined field sampling sheets and chain of custody (COC) documents) and borehole log reports are presented in Appendices H (groundwater) I (WMStrade) and J (soil vapour)

          Table 41 Summary of field methodologies

          Activity Details

          Passive soil bore sampling The soil bores used to deploy the WMStrade units were hand augered by personnel from Fyfe and Aussie Probe to a depth of 1 m BGL SGS Australia (SGS) personnel suspended each WMStrade unit into its respective borehole from a string The hole was then sealed with an expandable foam plug inside a polyethylene sleeve and the string suspending the sampler was connected to a temporary plastic cap at the ground surface The Round 1 WMStrade units were deployed for periods of between six and seven days whereas the Round 2 WMStrade units were all deployed for six days Following retrieval by SGS each WMStrade unit was placed into a sealed glass vial and a labelled foil bag The WMStrade units did not require chilling during transport to the analytical laboratory Borehole log reports are included in Appendix I whereas combined field sampling sheets and COC documents are presented in Appendix G

          80607-1 REV1 30102017 PAGE 15

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Activity Details

          Groundwater well Groundwater wells were drilled by WB Drilling using a combination of hand augering installation mechanical pushtube and solid auger techniques

          Following the completion of drilling each borehole was fitted with 50 mm class 18 uPVC casing with a basal 6 m long section of slotted well screen A filter pack comprising clean graded sands of suitable size to provide sufficient inflow of groundwater was installed within the annular space between the borehole and the well casing and extended from the base of the screened interval to approximately 1 m above the termination of the slotted casing A 1 m long bentonite collar comprising pelleted or granulated bentonite was placed above the filter pack to prevent water seepage downward along the well casing or borehole from ground surface Each well was grouted up to surface level and fitted with a (lockable) steel gatic cover the latter flush mounted to prevent tripping andor other hazards Groundwater well log reports are included in Appendix H

          Soil logging and Soil logging was undertaken in general accordance with the ASC NEPM (1999) which geotechnical sampling endorses AS1726-1993 In addition to the requirements of AS1726-1993 particular

          attention was paid during logging to any lithological variations such as sandgravel lenses or secondary porosity (such as clay fracturing) which may act as potential preferential pathways for contaminant vapourgroundwater migration through the sub-surface as well as the presence of fill material andor any olfactory or visual evidence of contamination Soil descriptions have been included on the logs in Appendices H to J Cores for geotechnical analysis were collected using push tube sampling methodologies to obtain undisturbed samples Section(s) of core to be tested were retained (intact) within the pushtube liners and capped at each end for storage and transport to the analytical laboratory

          Field screening of soils Field screening of individual soil layers was undertaken at the majority of the drilling locations and involved the use of a photoionisation (PID) unit fitted with an 117 eV lamp (ie as considered suitable for the detection of CHC) The PID unit was calibrated by the hire company prior to delivery and was checked on a daily basis against an isobutylene calibration gas of known concentration Field screen samples were collected with care to ensure that each sample was representative of the soil stratum from which it was collected and experienced minimal loss of volatile compounds The soil material was placed immediately into a zip lock bag and sealed ensuring the bag was half filled (ie such that the volume ratio of soil to air was equal) Soil clumps within the bag were manually broken up and the bag was left to rest for a minimum of five minutes but no longer than 20 minutes Prior to testing the bag was shaken vigorously to release any vapours within the soil To test the tip of the PID probe was inserted into the bag and the maximum volatile organic compound (VOC) reading recorded after a nominal 10 second period or when the reading had peaked Results were recorded on the appropriate bore log sheets presented in Appendices H to J

          Groundwater well Following installation the wells were developed by purging a minimum of four well development volumes (ie until stable parameters were obtained andor until the well purged dry) from

          the casing with a steel bailer andor twister pump to ensure hydraulic connectivity with the aquifer formation

          Groundwater gauging Groundwater levels in the newly installed and existing monitoring wells located across the Thebarton EPA Assessment Area were gauged using an interface probe prior to the commencement of the groundwater sampling program All monitoring wells were gauged for SWL the potential presence of NAPL and the total well depth Groundwater field gauging results are presented in Appendix E

          PAGE 16 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Activity Details

          Groundwater sampling The majority of the wells were sampled using low flow (micropurge) techniques Where recovery was particularly low (ie MW4 MW8 MW15 MW18 MW19 and MW24) and unsuitable for low flow (micropurge) sampling the original sampling technique was abandoned and a HydraSleeveTM (no purge) methodology was used instead Groundwater samples were collected in laboratory-supplied screw top bottles containing appropriate preservative (if required) with no headspace allowed Samples were chilled during storage and transport to the analytical laboratory Disposable nitrile gloves worn by field personnel were changed prior to the collection of each sample Samples for metals (ie iron manganese) analysis were filtered in the field using 045 microm filters Groundwater field sampling sheets are presented in Appendix E

          Low Flow Methodology The low flow sampling technique involved the following the pump was placed close to the bottom of the screened interval the flow rate (up to 05 Lmin) was regulated to maintain an acceptable level of

          drawdown with minimal fluctuation of the dynamic water level during pumping and sampling

          groundwater drawdown was monitored constantly during purging and sampling using an interface probe

          water quality parameters were considered to have stabilised when the following ranges were recorded over three consecutive readings ndash electrical conductivity plusmn 5 ndash pH plusmn 01 ndash temperature plusmn 02degC ndash dissolved oxygen plusmn 10 ndash redox potential plusmn 10 mV

          the stabilisation parameters were recorded on field logging sheets after every one litre of groundwater purged using a calibrated water quality meter and a flow cell suspended in a bucket with litre intervals marked and

          samples were collected once three consecutive stabilisation parameters were recorded and a volume of between 28 and 6 litres was purged prior to sampling

          HydraSleeveTM Methodology The HydraSleeveTM sampling technique involved attaching a stainless steel weight to the bottom and a wire tether clip to the throat of the HydraSleeveTM before lowering it into the water column to the desired depth and allowing it to fill with groundwater After a minimum period of 24 hours the HydraSleeveTM was quickly and smoothly withdrawn from the well and the contents were transferred into the sample containers Water quality parameters were measured after samples were decanted ndash either within the water remaining in the HydraSleeveTM or within a grab sample collected using a disposable bailer

          Hydraulic testing Rising and falling head permeability (ldquoslugrdquo) tests were undertaken to estimate the hydraulic conductivity (K) of the aquifer within various parts of the Thebarton EPA Assessment Area The falling-head tests were initiated by quickly inserting a 1285 m long and 36 mm diameter solid PVC cylinder (slug) into the water column at each well to produce a sufficient sudden rise in the water level The subsequent ldquofallrdquo back to the static water level (recovery) was measured and recorded automatically and in real-time using a

          80607-1 REV1 30102017 PAGE 17

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Activity Details

          pressure transducerdata logger programmed to record water levels at a one second interval After static water level conditions returned in the well the rising-head test was initiated by quickly removing the slug from the well to create a sudden drop in the water column height As with the falling-head test the rise of the water level back to a static condition (recovery) was automatically recorded

          Soil vapour bore Soil vapour bores were drilled by Aussie Probe using a combination of hand augering and installation mechanical pushtube techniques

          Within each 3 m deep soil vapour bore teflon tubing attached to a soil vapour probe was inserted to the base of the hole which had been prefilled with approximately 005 m of clean filter pack sand An additional 045 m of sand (ie approximately 05 m in total) was then added to the hole and topped by a bentonite plug seal of approximately 05 m thickness A second soil vapour probe was installed at a depth of about 1 m within a 05 m sand pack which was overlain by bentonite to a depth of about 02 to 03 m BGL The two 1 m deep soil vapour bores were installed in a similar manner with a sand pack extending from the base to about 05 to 06 m BGL overlain by a bentonite plug to 03 m BGL Each installation was completed with grout to surface and topped with a standard flush-mounted gatic cover Soil vapour bore log reports are included in Appendix J

          Soil vapour sampling All soil vapour sampling works were undertaken by SGS using suitably trained and experienced personnel ndash SGS holds National Association of Testing Authorities (NATA) accreditation for all soil vapour sampling and laboratory analytical works Combined field sampling sheets and COC documents are presented in Appendix G Soil vapour samples were collected using summa canisters and analysed using the US EPA (1999) TO-15 method Sampling involved the connection of a passivated 1 L stainless steel canister to the teflon tubing extending from the soil vapour probe and the use of a soil gas sampling train to restrict flow to a maximum rate of 200 mLmin Canister vacuum pressure was monitored during sampling to enable calculation of the volume of sample drawn into the canister ndash the small amount of vacuum left in the canister at the end of the sampling procedure was measured in the laboratory to check if any leaks occurred during transit (refer to further discussion in Table 52) A shroud was set up around the sampling point and tracer chemicals were introduced at high concentrations by flooding the shroud with helium and placing a cloth soaked with IPA into the shroud Each canister was cleaned and certified by SGS prior to use (refer to Appendix G) and backshyup coconut shell carbon sorbent tube samples were also collected (but not analysed) Summa canisters did not require chilling during transport to the analytical laboratory

          Waste disposal Waste water and surplus soil corescuttings were stored together within 205 litre drums in the rear car park of a commercialindustrial property at 19-21 James Congdon Drive (as organised by the EPA) prior to removaldisposal by a licensed waste removal company (Cleanaway) Analytical results pertaining to the soils were forwarded to the licensed receiving facility and all of the soil was classified as lsquoWaste Fillrsquo in accordance with the Environment Protection Regulations 2009 The waste transport certificates are included in Appendix K

          PAGE 18 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          42 Laboratory analysis

          The following laboratories were used for the analysis of the environmental samples

          complete soil cores for geotechnical sample analysis were forwarded to SMS Geotechnical

          primary groundwater samples collected by Fyfe were analysed at the SGS laboratory whereas secondary groundwater samples were forwarded to EurofinsMGT and

          soil vapour (including WMStrade) samples collected by SGS were analysed at their laboratory

          80607-1 REV1 30102017 PAGE 19

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          5 QUALITY ASSURANCE AND QUALITY CONTROL

          Data quality is typically discussed in terms of the DQIs presented in Table 22 ndash ie completeness comparability representativeness precision and accuracy In order to assess the quality of the data collected during the Fyfe investigation program against these DQIs specific QAQC procedures were implemented during both the field sampling and laboratory analysis programs as detailed in the following sections

          51 Field QAQC

          Field QA procedures undertaken during the recent investigations included the collection of the following QC samples aimed at assessing possible errors associated with cross contamination as well as inconsistencies in sampling andor laboratory analytical techniques

          intra-laboratory duplicate (duplicate) samples submitted to the same (primary laboratory) to assess variation in analyte concentrations between samples collected from the same sampling point andor the repeatability (precision) of the analytical procedures

          inter-laboratory duplicate (split or triplicate) samples submitted to a second laboratory to check on the analytical proficiency (accuracy) of the results produced by the primary laboratory

          equipment rinsate blank samples collected during groundwater sampling only and used to assess cross-contamination that may have occurred from sampling equipment during sampling and

          trip blank samples used to assess whether cross-contamination may have occurred between samples during transport

          Whereas analyte concentrations within the rinsate and trip blank samples should be below the laboratory limit of reporting (LOR) the inter- and intra-laboratory duplicate sample results are assessed via the calculation of a relative percentage difference (RPD) as follows

          (Concentration 1 minus Concentration 2) x 100RPD = (Concentration 1 + Concentration 2) 2

          Maximum RPDs of 30 (inorganics) and 50 (organics) are generally considered acceptable with higher RPD values often recorded where concentrations of an analyte approach the laboratory LOR

          All field QC sample results are included in the summary data tables in Appendix L

          511 Groundwater

          Table 51 presents conformance to field QAQC procedures undertaken as part of the groundwater investigations

          80607-1 REV1 30102017 PAGE 21

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Table 51 Field QAQC procedures ndash Groundwater

          QAQC Item Detail

          Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) AustralianNew Zealand standards ASNZS 566711998 and ASNZS 5667111998 SA EPA (2007) and Fyfe SOPs Details are provided in Table 41

          Calibration of field equipment

          Documentation regarding the calibration of field equipment is included in Appendix M

          Decontamination of All disposable equipment (tubing pump bladders plastic bailers bailer cord and equipment HydraSleeveTM units) were replaced between wells Re-usable equipment (micropurge pump

          interface probe and HydraSleeveTM weights) was decontaminated between sampling locations using potable water and Decon 90trade phosphate free detergent

          Sample preservation and storage

          Samples were kept in laboratory supplied containers in a portable chilled insulated box (esky) prior to and during transport to the laboratory

          Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

          Duplicate samples Two intra-laboratory and two inter-laboratory duplicate samples were analysed for CHC with respect to 26 primary groundwater samples ndash thereby constituting an overall ratio of approximately one duplicate per 65 primary samples (or 15) compared to a generally acceptable ratio of 110 samples (or 10) One intra-laboratory and one inter-laboratory duplicate sample were analysed for the remaining parameters with respect to 10 primary groundwater samples ndash thereby constituting an overall ratio of one duplicate per five primary samples (or 20) compared to a generally acceptable ratio of 110 samples (or 10) Intra- and inter-laboratory duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within the acceptable range with the exception of the following intra-laboratory duplicate sample pair MW9QW1 TCE (67) nitrate (147) and inter-laboratory duplicate sample pair MW9QW2 total CO2 (59) iron (190)

          manganese (183) potassium (64) nitrate (194) The elevated RPD for TCE in the intra-laboratory duplicate sample pair is considered to be related to the low concentration detected and does not alter the interpretation of the data The other RPD exceedances are not considered significant (ie in terms of overall data interpretation) as they were not obtained for identified COPC (as defined in Section 14)

          Rinsate blank samples Six equipment rinsate blank samples (one for each day of sampling) were collected from either the pump housing or a new HydraSleevetrade (final day of sampling only) and analysed for CHC to confirm the effectiveness of the decontamination procedures and the cleanliness of disposable equipment The analytical results obtained for the rinsate blank samples were all below the laboratory LOR thereby indicating that decontamination practices during the groundwater sampling program were acceptable and that no contamination was introduced by the use of the HydraSleevestrade

          Trip blank samples Six trip blank samples were included within containers (eskies) of sample bottles provided by the analytical laboratory and returned to the analytical laboratory All of the trip blank samples were analysed for CHC With the exception of TB187 which contained 1 microgL TCE the analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was limited impact on sample quality during storage or transport of the samples to the analytical laboratory

          PAGE 22 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Notes No duplicate QC samples were collected during the use of the HydraSleeveTM sampling technique as detailed in ANZECCARMCANZ (2000a) at least 5 (ie 120) duplicate samples should be analysed ndash the generally accepted industry standard however is 10 (110) including 5 intra-laboratory and 5 inter-laboratory duplicates

          512 Soil vapour

          Tables 52 presents conformance to field QAQC procedures undertaken as part of the soil vapour (passive and active) investigations

          Table 52 Field QAQC procedures ndash Soil vapour

          QAQC Item Detail

          Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) as well as ASTM (2001 2006) ITRC (2007) CRC CARE (2013) guidance and Fyfe SOPs Details are included in Table 41 and Appendix G (ie SGS sampling methodology sheet) During the use of summa canisters to sample the soil vapour bores leak testing was undertaken (as described in Table 41) Although small leaks or ambient drawdown appear to have occurred with respect to samples SV11_10m (003 helium) SV13_10m (003 helium) and SV1_10m (360 microgm3 IPA) ITRC (2007) and NJDEP (2013) state that ge 5 helium andor gt10 mgm3 IPA are required to be indicative of a significant leak or substantial ambient drawdown Given that the leaks were relatively small (ie 06 (helium) and 36 (IPA) of the levels considered indicative of a significant leak) the data from these bores were still considered to be valid ndash refer to SGS correspondence in Appendix G As detailed in Table 41 a small amount of vacuum was generally left in each summa canister at the end of the sampling procedure and was measured in the laboratory to check if any leaks had occurred during transit However samples SV11_10m SV12_30m as well as the helium blank were recorded as having zero vacuum upon receipt at the analytical laboratory A query lodged with SGS regarding this issue indicated that whereas the helium blank comprised a grab sample collected into a Tedlar bag directly from the helium cylinder (ie without the use of a gauge) the canisters used for samples SV11_10m and SV12_30 were filled during sampling so that there was no remaining vacuum ndash refer to field sampling documentation in Appendix G SGS stated that although it is good practice to have a small amount of vacuum remaining in a canister at the completion of sampling appropriate additional QC measures were employed and the absence of other common background VOCs (eg petroleum hydrocarbons) upon sample testing indicated that leakage had not occurred during transit In addition all canisters are fitted with quick connect one-way valves that are closed upon removal from the sampling train and canistersfittings are leak checked prior to leaving the laboratory and again in the field to ensure that they are leak free Refer to SGS correspondence in Appendix G The presence of detectable IPA (120 microgm3) and TCE (48 microgm3) in the helium blank was also queried with SGS who stated that this (ie variability in the quality of the high purity helium gas used) is not an uncommon occurrence The reason for collecting a helium blank sample is to identify any impurities present in the helium gas so that if a leak does occur during sampling it is possible to determine whether any target compounds could be introduced into the sample train Although a target compound (ie TCE) was detected in the blank the concentration is minor and even if a leak had occurred during sampling (of which there was no evidence) it would not have affected the overall results and data interpretation The presence of IPA in the helium blank is

          80607-1 REV1 30102017 PAGE 23

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          QAQC Item Detail

          suspected by SGS of having resulted from a handling issue in the field ndash ie sub-sampling from the helium cylinder (ie into a summa canister via a flex foil bag) in the vicinity of the high concentrations of IPA being used for leak detection Refer to SGS correspondence in Appendix G

          Sample preservation and storage

          Following collection the WMStrade units were placed into individual glass vials which were sealed and placed into foil bags for transport to the analytical laboratory at ambient temperature Summa canisters were stored in specially constructed cases during transport to the analytical laboratory at ambient temperature

          Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

          QC samples ndash WMStrade sampling

          During the first round of passive soil vapour sampling three additional WMStrade units were deployed in soil bores drilled adjacent to WMS 22 WMS 25 and WMS 28 to act as duplicate QC samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 8) Two trip blank samples were also included with samples transported from and to the analytical laboratory All of the QC samples were analysed by the primary laboratory Intra-duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within an acceptable range (ie lt30) The analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was negligible impact on sample quality during storage or transport of the samples to the analytical laboratory

          QC samples ndash soil vapour bore sampling

          Two intra-laboratory duplicate QC samples were analysed for CHC and general gases with respect to 24 primary soil vapour samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 83) compared to an acceptable ratio of 110 samples (or 10) Intra-laboratory duplicate RPDs were calculated where both samples had a reported concentration above the laboratory LOR All calculated RPDs for CHC and general gases were within an acceptable range (ie lt30) The analytical results obtained for the helium shroud (Tedlar bags) helium blank and IPA shroud (carbon tube) samples were all considered to be satisfactory

          Notes The American Society for Testing and Materials (ASTM) is an internationally recognised source of testing methods Although Appendix J of CRC CARE (2013) stipulates a 110 duplicate sampling ratio for active vapour sampling a specific ratio is not stipulated for passive vapour sampling

          52 Laboratory QAQC

          Laboratory QA procedures generally include the performance of a number of internal checks of data precision and accuracy that are aimed at assessing possible errors associated with sample preparation and analytical techniques Specific types of QC samples analysed by laboratories and the relevant acceptance criteria are as follows

          PAGE 24 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          internal laboratory replicate samples maximum RPD values of 20 to 50 although this varies depending on laboratory LOR

          spike recoveries results between 70 and 130 and

          laboratory controlmethod blanks results below the laboratory LOR

          Table 53 presents conformance to laboratory QAQC procedures undertaken as part of the overall investigation program

          Table 53 Laboratory QAQC procedures

          QAQC Item Detail

          Samples analysed and Samples were generally analysed within specified holding times ndash with the exception extracted within relevant of the following groundwater samples holding times SGS report no ME303457 nitrate was analysed two days late in some samples

          (MW5 MW17 MW26) SGS report no ME303475 nitrate was analysed one day late in all samples and EurofinsMGT report no 555810-W total CO2 was analysed five days late None of these holding time exceedances are considered to be significant with respect to the interpretation of the CHC data the determination of potential human healthenvironmental risks andor the determination of natural attenuation

          Laboratories used and The laboratories used (SGS Eurofins MGT and SMS Geotechnical) were NATA NATA accreditation accredited for the majority of the analyses undertaken

          The exception was SMS Geotechnical which was not NATA accredited for the calculations undertaken to derive some of the data ndash this is the case however for all geotechnical laboratories

          Appropriate analytical methodologies used

          Refer to the laboratory reports in Appendix G

          Laboratory limit of The laboratory LOR is the minimum concentration of an analyte (substance) that can reporting (LOR) be measured with a high degree of confidence that the analyte is present at or above

          that concentration The LOR are presented in the laboratory certificates of analysis (Appendix G) and are considered to be generally appropriate (ie below the adopted assessment criteria ndash refer to Section 62) ndash the following exceptions in soil vapour (ie considered to be due to interference associated with elevated concentrations of other compounds ndash refer to SGS correspondence in Appendix G) are discussed further in Table 101 VC in all of the WMStrade samples relative to the ASC NEPM (1999) interim soil

          vapour health investigation level (HIL) for residential land use cis-12-DCE and VC in two soil vapour bore samples (SV2_30m and SV3_30m)

          relative to the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land use and

          VC in two soil vapour bore samples (SV3_10m and SV7_30m) relative to the ASC NEPM (1999) interim soil vapour HIL for residential land use

          In addition to the above although ultra-trace analysis was requested the laboratory LOR for VC in groundwater (ie 1 microgL) is above the adopted NHMRCMRMMC (2011) potable guideline (ie 03 microgL) ndash refer to Section 612

          80607-1 REV1 30102017 PAGE 25

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          QAQC Item Detail

          Laboratory internal QC analyses

          Results obtained for the laboratory internal QC samples were generally within the acceptable limits of repeatability chemical extraction and detection with the exception of the following SGS report ME303457 matrix spike results for iron were outside normal tolerances

          due to the high concentrations of iron in the spiked sample ndash matrix spike results for iron could therefore not be calculated This is not considered to be a significant issue

          Full details regarding laboratory QAQC procedures and results are presented in the certified laboratory certificates contained in Appendix G

          Notes Since holding times were not specified in the SGS groundwater reports Fyfersquos assessment of holding times has been based on those adopted by EurofinsMGT (ie the secondary laboratory used for groundwater analysis) ie in accordance with Schedule B3 of the ASC NEPM (1999) also referred to as practical quantification limits (PQL)

          53 QAQC summary

          In summary it is considered that

          the field QAQC programs were generally undertaken with regard to relevant legislation standards andor guidelines and were sufficient for obtaining samples that are representative of site conditions and

          the overall laboratory QAQC procedures and results were adequate such that the laboratory analytical results obtained are of acceptable quality for addressing the key objectives outlined in Section 15

          PAGE 26 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          6 ASSESSMENT CRITERIA

          61 Groundwater

          611 Beneficial Use Assessment

          In accordance with Schedule B6 of the ASC NEPM (1999) and SA EPA (2009) a Beneficial Use Assessment (BUA) was undertaken to assess both the current and realistic future uses of groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area

          This was aimed at determining what groundwater uses need to be protected and assessing the risk(s) that groundwater may pose to human health and the environment (refer also to the VIRA in Section 9)

          As summarised in Table 61 the potential beneficial uses for groundwater within the Q1 aquifer that have been considered are as follows ndash taking into account the salinity of the groundwater the Environment Protection (Water Quality) Policy 2015 (Water Quality EPP 2015) the DEWNR (2017) WaterConnect database information presented in Section 222 and possible sensitive receptors located within andor within the vicinity of the Thebarton EPA Assessment Area

          The salinity of groundwater has been calculated to approximate 1230 to 3620 mgL TDS (refer to Section 7312) According to the Water Quality EPP 2015 the applicable environmental values for groundwater with salinity above 1200 mgL TDS but less than 3000 mgL TDS are irrigation livestock and aquaculture whereas the salinity is considered to be too high for potable use ndash although domestic irrigation is considered to be a potentially realistic use for this area (see below) livestock watering is considered unlikely to be undertaken in such an urban setting and no local water bodies (ie surface or groundwater) have been identified as being used for commercial aquaculture purposes

          The DEWNR (2017) WaterConnect database indicates that groundwater within the Q1 aquifer in the Thebarton area is accessed for drainage domestic and industrial purposes ndash domestic groundwater use could include garden irrigation plumbing water andor the filling of swimming pools (ie primary contact recreation) Although domestic groundwater extraction is considered unlikely to include potable use (ie due to its salinity and the availability of a reticulated mains water supply) potential mixing with rain watermains water could render it suitable (ie from a salinity perspective) for drinking

          As the closest freshwater surface water body the River Torrens is located approximately 03 km to the east and 07 km to the north and north-west of the northern portion of this area groundwater discharge from the Thebarton EPA Assessment Area into a freshwater aquatic ecosystem is considered possible However as the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area the potential for impact on a freshwater aquatic environment has not been confirmed

          80607-1 REV1 30102017 PAGE 27

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Since the closest marine surface water body Gulf St Vincent is located approximately 8 km to the west groundwater discharge from the Thebarton EPA Assessment Area into a marine aquatic ecosystem is not considered to be realistic

          Since volatile contaminants have been detected within the Q1 aquifer (refer to Section 7331) a potential vapour flux risk to future site users must be considered

          Given the measured depth of the Q1 aquifer beneath the site (ie approximately 1232 to 1585 m BGL ndash refer to Section 7311) it is considered unlikely that direct contact could occur between groundwater and building footingsunderground services

          Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area

          Environmental Values Beneficial Uses

          Water Quality EPP 2015

          environmental value

          SA EPA (2009) Potential

          Beneficial Uses

          Beneficial Use Assessment

          Considered Applicable

          Aquatic Ecosystem

          Marine Yes No

          Fresh Yes Possibly

          Potable - Yes Possibly

          Agriculture Irrigation - Yes Yes

          Livestock - Yes No

          Aquaculture - Yes No

          Recreation amp Aesthetics

          Primary contact Yes Possibly

          Aesthetics Yes Possibly

          Industrial - Yes Yes

          Human health in non-use scenarios

          Vapour flux -

          Yes Yes

          Buildings and structures

          Contact - Yes No

          Notes ie for underground waters with a background TDS level of between 1200 and 3000 mgL ndash note that although they are not listed as environmental values of groundwater in Schedule 1(3) of the Water Quality EPP 2015 aquatic ecosystems as well as recreation amp aesthetics are included as environmental values for waters in general in Part 1(6) of the document ie domestic irrigation only

          612 Groundwater beneficial use criteria

          The health and ecological criteria used for the assessment of the COPC (refer to Section 14) in groundwater have been based on the results of the BUA (Section 611) A summary of the references used to source the groundwater assessment criteria is provided in Table 62

          PAGE 28 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Table 62 Sources of adopted groundwater assessment criteria

          Beneficial Use Reference

          Freshwater Ecosystems No criteria available for COPC

          Potable NHMRCNRMMC (2011) Australian Drinking Water Guidelines

          WHO (2017) Guidelines for Drinking-water Quality ndash TCE only

          Irrigation No criteria available for COPC

          Primary contact recreation (including aesthetics)

          NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines but (with the exception of aesthetic guidelines) multiplied by a factor of 10 to take account of accidental ingestion rates as opposed to deliberate ingestion

          ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality ndash recreational values (TCE only)

          Human health in non-use scenarios ndash vapour flux Refer to the VIRA in Section 9

          Notes As there are no specific guidelines for industrial water these values are considered likely to be protective of this additional beneficial use The NHMRC (2008) guidelines are based on drinking water levels and assume a consumption factor of 2 L per day Therefore as recommended in the NHMRC (2008) document potable criteria (ie with the exception of aesthetic criteria) need to be adjusted by a factor of 10 to account for an accidental consumption rate of 100 to 200 ml per day As noted in ANZECCARMCANZ (2000b) although recreational guidelines are protective of ingestion recreational waters should also not contain any chemicals that can cause skin irritation likewise although not specifically addressed by recreational water criteria inhalation may also represent a source of exposure with respect to some (ie volatile) contaminants In the absence of a NHMRCNRMMC (2011) drinking water guideline for TCE the ANZECCARMCANZ (2000b) recreational criterion (30 microgL) has been adopted However if the NHMRC (2008) rule of multiplying potable (healthshybased) guidelines by 10 is applied to the WHO (2017) drinking water guideline of 20 microgL a recreational guideline of 200 microgL would be more applicable

          62 Soil vapour

          The ASC NEPM (1999) interim soil vapour health investigation levels (HILs) for volatile organic chlorinated compounds (VOCCs) have been adopted (ie in the first instance ndash refer to Section 7331) as Tier 1 soil vapour assessment criteria ndash relevant land use scenarios within the Thebarton EPA Assessment Area include residential (HIL AB) and commercialindustrial (HIL D)

          These criteria have been further adjustedappended for the purposes of the VIRA Tier 1 assessment ndash refer to Section 94

          80607-1 REV1 30102017 PAGE 29

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          7 RESULTS

          71 Surface and sub surface soil conditions

          711 Field observations

          Groundwater well and soil vapour borehole log reports are included in Appendices H to J and provide details of the soil profile encountered at each sampling location

          Where encountered fill materials extended to depths of between 01 and 09 m BGL and included a range of different soil types (sand gravelcrushed rock silt) with only minimal waste inclusions (ie asphalt glass andor metal fragments) identified at some locations

          The underlying natural soil profile (encountered to the maximum drill depth of 19 m BGL) was dominated by low to medium plasticity brown to red-brown silty clays and sand claysclayey sands some of which contained sub-angular to rounded gravels that included river pebbles andor comprised fine distinct lenses in places Groundwater well MW17 also included a 15 m thick layer of gravel at depth (ie 12 to 135 m BGL) ndash ie consistent with the depth of groundwater within the Q1 aquifer

          During the course of the drilling works no odours or visual indicators of contamination were detected and measured PID readings ranged up to 6 ppm but were generally lt3 ppm

          712 Soil geotechnical testing

          A table of geotechnical testing results is presented in Appendix L (Table 1) and a copy of the certified laboratory report is included in Appendix G Photographs of soil cores are included in Appendix N

          The results were interpreted to indicate the following

          The soil core samples submitted for PSD analysis were dominated by clay with lesser amounts of fine to medium gravel andor fine to coarse-grained sand ndash all samples analysed were classified as either CLAY or Sandy CLAY with one sample classified as Clayey SAND The classifications obtained from the laboratory were deemed to be generally consistent with the descriptions on the groundwater well log reports (Appendix H) although the PSD results did not specify silt as a significant secondary component

          The moisture content of the analysed soil core samples ranged from 65 to 231 Moisture content with respect to soil type depth and location has been considered in more detail for the purposes of the VIRA (Section 9) The degree of saturation for the analysed soil cores samples ranged from 218 to 964

          Measured bulk density ranged from 160 to 212 tm3 specimen dry density from 141 to 184 tm3 and specific gravity from 255 to 281 tm3

          The measured void ratio ranged from 043 to 088 whereas porosity ranged from 032 to 047

          80607-1 REV1 30102017 PAGE 31

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          72 Waterloo Membrane Samplerstrade A table of WMStrade analytical results (ie from both rounds of sampling) is presented in Appendix L (Table 2) and copies of certified laboratory reports are included in Appendix G8

          Of the 41 WMStrade units deployed across the Thebarton EPA Assessment Area during the two sampling rounds 20 returned measurable concentrations of CHC including TCE PCE cis-12-DCE trans-12-DCE andor 11-DCE Although no VC was detected the laboratory LOR in all samples (ie 35 to 50 microgm3) was above the ASC NEPM (1999) soil vapour interim HIL for residential land use (30 microgm3) ndash refer also to Table 53

          Detectable COPC concentrations are summarised in Table 71 relative to the ASC NEPM (1999) soil vapour interim HILs along with the closest soil vapour bore andor groundwater monitoring well locations Measured TCE concentrations are detailed on Figure 3

          A comparison of the Round 1 and 2 WMStrade results (ie for closely located units9) is presented in Table 72 ndash the results indicate a general order of magnitude correlation of the results for most COPC with the exception of PCE for which lower concentrations were obtained during Round 2 As the Round 1 and 2 WMStrade units were located within different soil bores and deployed at different times some variability in the results is to be expected In addition and as discussed in Section 74 the WMStrade units have been used during this assessment as a (semi-quantitative) screening tool (ie to assist with the siting of the permanent soil vapour bores) with the results obtained from the soil vapour bores considered more representative of actual subsurface conditions

          Table 71 Detectable Waterloo Membrane Samplertrade CHC results

          Sample ID

          Location Closest land uses

          CHC concentration (microgm3) Closest soil vapour bore

          andor groundwater

          well

          TCE PCE cis-12shyDCE

          trans-12shyDCE

          11shyDCE

          VC

          WMS 1 Goodenough Street CI 35 -

          WMS 6 Maria Street CI 32 -

          WMS 7 Maria Street CI and R 1900 45 SV2 MW5

          WMS 8 Maria Street CI and R 12000 37 SV4

          WMS 11 Admella Street CI 71000 260 19 20 36 SV5 MW02

          WMS 14 George Street CI 46000 45 SV6 MW11

          WMS 18 Admella Street CI 4200 34 MW14

          WMS 19 Albert Street CI 11000 42 SV10MW15

          WMS 21 Chapel Street CI 10 -

          WMS 22 Admella Street CI 38 SV9

          WMS 24 Chapel Street CI 230 62 10 11 48 MW17

          8 Note that the original laboratory report for the Round 1 WMStrade samples was found to be incorrect (ie following receipt of the soil vapour bore and Round 2 WMStrade sample results) and was subsequently re-issued by SGS

          9 only two of which were sufficiently co-located for comparative purposes ndash Round 2 locations WMS 39 and WMS 41 were not within the immediate vicinity of Round 1 WMStrade bores (ie the closest Round 1 bores were approximately 30 m away)

          PAGE 32 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Sample ID

          Location Closest land uses

          CHC concentration (microgm3) Closest soil vapour bore

          andor groundwater

          well

          TCE PCE cis-12shyDCE

          trans-12shyDCE

          11shyDCE

          VC

          WMS 25 Albert Street CI and R 1400 20 MW17

          WMS 27 Light Terrace CI 64 62 SV11 MW19

          WMS 32 Holland Street R 16 -

          WMS 34 James Street R 11 -

          WMS 37 Dew Street R 44 -

          WMS 38 Maria Street CI and R 13000 56 SV2 MW5

          WMS 39 Maria Street CI and R 1300 SV4

          WMS 40 Admella Street CI 110000 97 SV5 MW02

          WMS 41 George Street CI 18000 10 SV7 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

          Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform (up to 530 microgm3) was also detected in WMS 8 WMS 11 WMS 14 WMS 16 WMS 18 WMS 19 WM 25 WMS 33 WMS 40 and WMS 41 interim soil vapour health investigation level (HIL)

          Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units

          Bore ID

          Depth (m)

          Location CHC concentration (microgm3)

          TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

          WMS 8 10 Maria Street 12000 37 lt95 lt99 lt22 lt36

          WMS 38 13000 56 lt11 lt11 lt25 lt41

          Relative percentage difference 8 147 - - - -

          WMS 11 10 Admella Street 71000 260 19 20 36 lt37

          WMS 40 110000 97 lt11 lt11 lt25 lt41

          Relative percentage difference 43 91 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

          80607-1 REV1 30102017 PAGE 33

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          73 Groundwater

          731 Field measurements

          A table of groundwater field parameters is presented in Appendix L (Table 3) and groundwater field sampling sheets are included in Appendix E

          7311 Groundwater elevation and flow direction

          The depth to water within the Q1 aquifer beneath the Thebarton EPA Assessment Area on 18 July 2017 ranged from 12323 to 15854 m below top of casing (BTOC)10 and 4469 to 5070 m AHD

          Groundwater elevation contours constructed from the July 2017 gauging data indicated that the overall groundwater flow direction within the Q1 aquifer was north-westerly consistent with expected regional groundwater flow The groundwater contours and inferred flow direction are shown on Figure 4

          7312 Field parameters

          As detailed in Table 51 field measurements were recorded during low flow purging (ie prior to micropurge sampling) of monitoring wells and immediately following the collection of HydraSleeveTM samples

          The field parameter readings recorded for the monitoring wells immediately prior to (low flow micropurge) and after (HydraSleeveTM) sampling indicated the following (as summarised in Table 3 Appendix L)

          groundwater pH ranged from 6 8 to 79 thereby indicating neutral conditions

          electrical conductivity (EC) measurements ranged from 189 to 556 mScm and were found to be reasonably consistent across the area thereby indicating that it is underlain by moderately saline water (ie approximating 1230 to 3620 mgL TDS11)

          redox concentrations ranged from -20 to 624 mV thereby indicating slightly reducing to strongly oxygenating conditions

          measured dissolved oxygen (DO) concentrations ranged from 04 to 78 ppm indicating slightly to highly oxygenated water and

          temperature ranged from 173 to 224oC

          Observations recorded during sampling indicated that the groundwater was clear to brown and only slightly to moderately turbid at most locations ndash the higher turbidity at MW18 and MW19 (combined with poor recharge) contributed towards the decision to use a HydraSleeveTM sampling method No odours or sheen were observed in any of the wells during gauging or sampling

          10 ie approximating m BGL 11 ie calculated by multiplying the field EC data by 065

          PAGE 34 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          732 Hydraulic conductivity

          Rising and falling head aquifer permeability (ldquoslugrdquo) tests were conducted on 10 groundwater wells (refer to Table 31 and Figure 2) to assess the hydraulic conductivity (K) of the Q1 aquifer

          To obtain estimates of near-well horizontal hydraulic conductivity for each well tested the slug test data were analysed by Arcadis using AQTESOLV for Windowstrade (Duffield 2007) following the guidelines presented in Butler (1998) ndash normalised displacement data collected from each test are plotted against time in Appendix A of the Arcadis report (refer to Appendix O) Since only one set of tests were performed at each well the reproducibility of the results as well as the dependence of the results on the initial displacement could not be verified or demonstrated As such multiple relevant and applicable solutions were applied to each test to account for that uncertainty (ie to ensure consistency of normalised response at each well regardless of initial displacement)

          Table 73 presents a summary of the range and average estimated hydraulic conductivity values (and corresponding analytical solutions used) for each well tested The results indicate that hydraulic conductivities ranged from approximately 0073 to 37 mday with an overall average of approximately 1 mday

          Table 73 Hydraulic conductivities (rising and falling head tests)

          Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

          (mday) Hydraulic Conductivity

          (mday)

          MW02 Falling head 011 to 014 DA CBP HV

          012 Rising head 0073 to 015 BR DA

          MW3 Falling head 034 to 062 BR DA

          047 Rising head 030 to 062 BR DA

          MW7 Falling head 075 to 25 BR DA

          139 Rising head 055 to 175 BR DA

          MW14 Falling head 011 to 021 BR DA

          014 Rising head 009 to 015 BR DA

          MW17 Falling head 21 to 22 DA KGS

          220 Rising head 225 to 244 DA KGS

          MW20 Falling head 22 to 37 BR DA HV

          256 Rising head 06 to 32 BR DA

          MW21 Falling head 073 to 123 BR DA

          084 Rising head 054 to 084 BR DA

          MW23 Falling head 088 to 162 BR DA

          101 Rising head 031 to 122 BR DA

          80607-1 REV1 30102017 PAGE 35

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

          (mday) Hydraulic Conductivity

          (mday)

          MW25 Falling head 10 to 18 BR DA CBP HV

          132 Rising head 049 to 17 BR DA

          MW26 Falling head 019 to 036 BR DA

          023 Rising head 010 to 029 BR DA

          Overall average K (mday) 1028 Notes References BR = Bouwer and Rice (1976) CBP = Cooper et al (1967) DA = Dagan (1978) HV = Hvorslev (1951) KGS = Hyder et al (1994)

          The monitoring wells that exhibited lower permeabilities (ie MW02 MW3 MW14 and MW26) were noted to be generally located in the up-gradient (south-eastern) portion of the Thebarton EPA Assessment Area whereas monitoring wells showing relatively higher permeabilities (ie MW7 MW17 MW20 MW21 MW23 and MW25) are generally located in the down-gradient (north-western) portion These results were considered by Arcadis to suggest a possible hydrogeologic transition from the south-east to the north-west AQTESOLV solution plots for each analysis are provided as Appendix A of the Arcadis report (Appendix O)

          As slug test results can be influenced by a number of factors which are difficult to avoid when performing and analysing slug test results hydraulic conductivity estimates derived from slug tests should be considered to be the lower bound of the hydraulic conductivity of the formation in the vicinity of the well (Butler 1998) However Arcadis also noted that the results obtained for the Thebarton EPA Assessment Area were similar to those reported for other areas of Adelaide with average values of 1 and 27 mday (refer to Appendix O)

          The slug test results were used by Arcadis in their groundwater fate and transport model (refer to Section 8)

          733 Analytical results

          Tables of groundwater analytical results are presented in Appendix L (Tables 4 and 5) and copies of certified laboratory reports are included in Appendix G

          7331 Chlorinated hydrocarbon compounds

          A table of CHC results is included in Appendix L (Table 4) and a plan showing their distribution in groundwater beneath the Thebarton EPA Assessment Area is included as Figure 5 Detectable CHC concentrations are summarised in Table 74 relative to the adopted potable and primary contact recreation criteria ndash the closest soil vapour bore locations are also detailed

          PAGE 36 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Table 74 Detectable groundwater CHC results

          Sample ID

          Location CHC concentration (microgL) Closest soil vapour bore

          TCE PCE cis-12shyDCE

          trans-12-DCE

          11-DCE VC Carbon tetrachloride

          MW02 Admella Street 20000 38 7 15 SV5

          MW3 Admella Street 69 SV1

          MW5 Maria Street 29000 3 21 2 6 SV2 SV3

          MW6 Maria Street 29 SV4

          MW9 Albert Street 2 -

          MW11 George Street 4900 3 4 1 7 SV6 SV7

          MW12 George Street 700 SV8

          MW14 Admella Street 1000 4 2 SV9

          MW15 Albert Street 180 SV10

          MW17 Chapel Street 24 -

          MW18 Dew Street 5 -

          MW20 Light Terrace 70 SV12

          MW21 Light Terrace 23 SV13

          MW23 Dew Street 21 -

          MW25 Smith Street 2 5 -

          MW26 Kintore Street 2 -

          Potable 20 50 60 30 03 3

          Primary contact recreation

          30 500 600 300 30 30

          Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Chloroform was also detected in a number of wells (MW02 MW3 MW5 MW8 MW11 MW12 and MW19 to MW25) ndash refer to Table 4 in Appendix L Although no VC was detected the laboratory LOR (1 microgL) exceeded the adopted potable criterion NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from WHO (2017) Guidelines for Drinking-water Quality NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

          The results indicate that the highest TCE concentrations (20000 to 29000 microgL) were measured in wells MW02 and MW5 located in the immediate vicinity of the former Austral property and that the TCE plume extends in a general north-westerly direction (ie consistent with the inferred groundwater flow direction

          80607-1 REV1 30102017 PAGE 37

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          within the Q1 aquifer) Although lesser concentrations of PCE 12-DCE (cis- andor trans) andor 11-DCE were present in some wells no VC was detected and the main COPC was identified as TCE

          A number of wells within the Thebarton EPA Assessment Area contained TCE concentrations that exceeded the adopted potable andor primary contact recreation criteria Although the extent of the TCE plume was not delineated to the north-west (but was delineated in all other directions) with detectable TCE concentrations (ie up to 21 microgL) identified beneath both Smith Street and Dew Street these concentrations were below the adopted primary contact recreation criterion (but not necessarily the adopted potable value ndash ie MW23)

          The background well (MW4) located across James Congdon Drive (to the east of the southern portion of the Thebarton EPA Assessment Area) did not contain any measurable CHC concentrations

          7332 Other measured groundwater parameters

          Major cations and anions

          The laboratory results obtained for the remaining groundwater analytes are summarised in Appendix L (Table 5)

          The groundwater ionic data obtained from selected wells across the Thebarton EPA Assessment Area are graphically represented on a Piper diagram in Figure 71 The results indicate a relatively consistent groundwater composition across the area thereby indicating that the groundwater sampled from these wells is derived from a single aquifer Ionic charge balance ranged from 32 to 22 with the highest value (22) calculated for MW12 indicating that additional anions (ie not measured as part of this study) could be present

          PAGE 38 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Figure 71 Piper diagram

          Natural attenuation parameters

          With respect to the measured natural attenuation parameters (ie DO nitrate iron sulfate CO2 and manganese) the following wells were selected based on their locations relative to the inferred extent of the CHC plume

          MW26 located on Kintore Street to the south (and hydraulically up-gradient) of the former Austral property (ie the suspected source site)

          MW02 and MW5 located within the immediate vicinity of the former Austral property and the area of maximum CHC contamination

          MW9 MW12 and MW17 located on Albert Street George Street and Chapel Street respectively to the north-west (and hydraulically down-gradient) of the former Austral property

          80607-1 REV1 30102017 PAGE 39

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          MW21 and MW22 located on Light Terrace and Cawthorne Street respectively to the northshywestnorth-north-west (and further hydraulically down-gradient) of the former Austral property and

          MW8 and MW23 located on Smith Street and Dew Street respectively representing the furthest wells to the northnorth-west of the former Austral property

          According to Wiedemeier et al (1998) the most important process in the degradation of CHC is the process of reductive dechlorination Although daughter products of TCE (ie 12-DCE) are present in groundwater (and soil vapour) at scattered locations within the Thebarton EPA Assessment Area they are not considered indicative of substantial breakdown of TCE ndash refer also to the Arcadis report in Appendix O as summarised in Section 8 In addition the analysis of the natural attenuation parameters data constituting physical and chemical indicators of biodegradation processes has not provided a definitive secondary line of evidence

          74 Soil vapour bores A table of soil vapour bore analytical results is presented in Appendix L (Table 6) and a copy of the certified laboratory report is included in Appendix G

          Of the soil vapour bores installed to 10 andor 30 m BGL within the Thebarton EPA Assessment Area the majority (ie with the exception of the 10 m deep bores installed as SV11 and SV13 and located on Light Terrace) returned measurable concentrations of CHC dominated by TCE and to a lesser extent (and only at some locations) PCE Detectable soil vapour CHC concentrations are summarised in Table 75 whereas CHC concentrations and inferred soil vapour TCE concentration contours are detailed on Figures 6 (1 m BGL) and 7 (3 m BGL)

          The TCE results which have been used to predict indoor air concentrations as part of the VIRA (refer to Section 9) suggest the following

          the highest concentration (1000000 microgL) was detected at 3 m BGL in soil vapour bore SV3 located in the vicinity of residential and commercialindustrial properties (including the former Austral property) on Maria Street

          where nested wells were tested soil vapour CHC concentrations were higher at depth consistent with a groundwater source

          TCE PCE and 11-DCE are all assumed to represent primary contaminants with 12-DCE representing a break-down product of TCE andor PCE

          although no VC was detected the laboratory LOR in some samples (ie up to 490 microgm3 in samples with the highest measured TCE concentrations) was above the ASC NEPM (1999) interim soil vapour HIL for residential land use (30 microgm3) ndash refer to Table 53 and

          although the extent of the soil vapour plume has apparently not been delineated (ie in any direction) by the existing soil vapour bores it extends in a north-westerly direction (and hydraulically down-

          PAGE 40 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          gradient) from the suspected source site (ie the former Austral property) and corresponds well with the groundwater TCE plume (refer to Figure 5)

          A comparison of the results obtained for the WMStrade units (WMS 38 to WMS 41) deployed during the second round of sampling and the closest soil vapour bore data (10 m BGL) is provided in Table 76 Although the results indicate good correlation for TCE and PCE in SV5WMS 40 as well as TCE in SV7WMS 41 the remaining results were more variable ndash this supports the use of the WMStrade units as an initial (semishyquantitative) screening tool with follow-up soil vapour bore data considered to provide more quantitative results

          Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area

          Bore ID

          Depth (m)

          Location Closest land

          uses

          CHC concentration (microgm3)

          TCE PCE cis-12shyDCE

          trans-12-DCE

          11-DCE VC

          SV1 10 Admella Street CI and R 6300 78

          30 21000 21

          SV2 10 Maria Street CI and R 51000 39 21 39

          30 940000

          SV3 10 Maria Street CI and R 210000 6500 5900

          30 1000000 15000 14000

          SV4 10 Maria Street CI and R 17000 31

          30 43000 90 30

          SV5 10 Admella Street CI 100000 84

          30 160000 310 20 33

          SV6 10 George Street CI 22000 12

          30 150000 56

          SV7 10 George Street CI 22000 19

          30 110000

          SV8 10 George Street CI 2300 62

          30 14000 19

          SV9 10 Chapel Street CI 170

          30 260

          SV10 10 Albert Street CI 93

          30 51

          SV12 10 Light Terrace CI 16

          30 55 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

          Notes Shaded cells indicate concentrations were below the laboratory LOR

          80607-1 REV1 30102017 PAGE 41

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Where (field andor laboratory) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform was also detected in a number of samplesinterim soil vapour health investigation level (HIL)

          Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores

          Bore ID

          Depth (m)

          Location CHC concentration (microgm3)

          TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

          SV2 10 Maria Street 51000 39 21 lt13 39 lt89

          WMS 38 13000 56 lt11 lt11 lt25 lt41

          Relative percentage difference 119 150 - - - -

          SV4 10 Maria Street 17000 31 lt18 lt14 lt14 lt92

          WMS 39 1300 lt52 lt11 lt11 lt25 lt41

          Relative percentage difference 172 - - - - -

          SV5 10 Admella Street 100000 84 lt44 lt33 lt33 lt22

          WMS 40 110000 97 lt11 lt11 lt25 lt41

          Relative percentage difference 95 14 - - - -

          SV7 10 George Street 22000 19 lt37 lt27 lt27 lt18

          WMS 41 18000 10 lt11 lt11 lt25 lt41

          Relative percentage difference 20 62 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

          PAGE 42 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          8 GROUNDWATER FATE AND TRANSPORT MODELLING

          Arcadis were commissioned by Fyfe to undertake preliminary fate and transport modelling of the groundwater CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained groundwater data The Arcadis report is included as Appendix O

          The aim of the modelling was to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton area in order that potential future groundwater restrictions could be applied by the EPA (ie via the potential future definition of a GPA) to protect human health

          81 Groundwater flow modelling

          The MODFLOW code a publicly-available groundwater flow simulation program developed by the United States Geological Survey (USGS) as described by McDonald and Harbaugh (1988) was used to construct a groundwater flow model It was developed for a horizontal area of approximately 25 km2 (ie to minimise possible boundary effects within the assessment area itself12) and was rotated 45deg counter-clockwise to align with the prevailing (north-westerly) groundwater flow direction The model extended approximately 23 km in a south-east to north-west direction and approximately 11 km in a south-west to north-east direction (ie perpendicular to groundwater flow) Whereas a 4 m grid spacing was used within the area of the plume and its migration pathway (ie to enhance model accuracy and precision) a broader 15 m grid was adopted outside the specific area of interest Vertically the model adopted a single 20 m thick layer as representative of the hydrostratigraphy of the Q1 aquifer sediments beneath the area but it was noted that only the bottom portion (ie few metres) of this model layer are actually saturated and therefore active in the model

          An informal sensitivity analysis performed as part of the model calibration process indicated that the model was most sensitive to changes in hydraulic conductivity and recharge ndash this was not unexpected given the relatively flat hydraulic gradient and relatively narrow range of estimated values for both model parameters (ie based on reasonably low uncertainty) The final calibrated value for aquifer recharge adopted in the model was 295 mmyear consistent with results reported for nearby sites as well as regional estimates Likewise the final calibrated hydraulic conductivity values for the up-gradient (06 mday) and down-gradient (2 mday) zones were consistent with both the site-specific slug test data and results obtained for other nearby EPA assessment areas The final calibrated down-gradient constant head elevation was 15 m AHD It was concluded by Arcadis that the groundwater flow model was well calibrated and could therefore serve as an appropriate basis for the development of a site-specific solute transport model

          82 Solute transport modelling

          A site-specific (three-dimensional) solute transport model using the MT3DMS transport code of Zheng (1990) was developed by Arcadis to predict the fate and transport of groundwater contaminants (specifically

          12 Further information regarding boundary effects is provided in the Arcadis report (Appendix O)

          80607-1 REV1 30102017 PAGE 43

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          CHC) under current conditions over a period of 100 years This dual-domain mass transport model was used in conjunction with the groundwater flow model developed through the use of MODFLOW (as detailed above) assuming the following

          The primary COPC is TCE ndash the initial concentration distribution of TCE in groundwater was based on the recent (July 2017) monitoring data

          The age of the groundwater TCE plume was assumed to be up to about 90 years ndash ie based on the history of industrial land use (specifically the former Austral facility) in the area

          Although lesser amounts of other CHC are present in groundwater the lack of significant daughter products of TCE has been interpreted to indicate that substantial biodegradation is not occurring (ie as a conservative approach)

          Although a CHC source was not explicitly incorporated into the solute transport model the MT3DMS transport code indirectly accounts for on-going contaminant mass contribution to the dissolved-phase plume

          The fate and transport of TCE within the area of interest involves the processes of advection adsorption dilution and diffusion ndash however given that recharge via the infiltration of precipitation was considered to be insignificant dilution effects were assumed to be minimal

          Two porosity values (ie dual domain) are relevant to the movement of contaminants in the subshysurface with adopted values based on site-specific geology and Payne et al (2008) ndash whereby the two domains are in equilibrium

          ― mobile porosity that portion of the formation with the highest permeability where advective transport dominates ndash assumed to be 5 (high) 10 (intermediate) or 15 (low) for different mobility transport conditions and

          ― immobile porosity lower permeability portions of the formation where diffusion is dominant ndash assumed to be 15

          As discussed in Section 732 hydraulic conductivity values of 06 mday (south-eastern approximate quarter of the modelling area) and 2 mday (northern approximate three-quarters of the modelling area) were adopted to reflect the hydrogeologic transition (ie from the south-east to the north-west) interpreted from the slug test data

          The adopted TCE retardation factor of 147 for intermediate mobility transport conditions was based on the following

          ― an assumed organic carbon fraction of 01 (US EPA 1996 amp 2009) ndash this was varied to 005 and 2 to assess alternate (ie high versus low) mobility transport conditions

          ― an assumed organic carbon adsorption co-efficient of 61 Lkg (US EPA 2017a)

          PAGE 44 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          ― a calculated partition co-efficient of 0061 Lkg ndash this was varied to 129 and 178 Lkg to assess alternate (ie high versus low) mobility transport conditions and

          ― an average soil bulk density of 192 gcm3 (based on measured geochemical data ndash refer to Table 1 Appendix L)

          An optimum mass transfer co-efficient (MTC) was based on simulated flux distribution in the groundwater flow model whereby

          ― the calculated MTC in the model ranged from approximately 38E-08day-1 to 37E-05 day-1 and

          ― the average MTC was 185E-05day-1

          The site-specific solute transport model was used in predictive mode to assess the long-term (eg 100 year) potential migration of the groundwater TCE plume and to support the EPA in the potential future definition of an appropriate GPA The model was calibrated against the current extent (ie concentrations of TCE above 1 microgL have migrated approximately 500 m from the suspected source site13) and expected age (ie up to about 90 years) of the plume The results indicate that the leading edge of the TCE (ie the 1 microgL contour) is estimated to migrate between approximately 400 and 620 m over a period of 100 years under low to high mobility transport conditions14 with intermediate transport conditions resulting in an estimated migration of 500 m By comparison no significant lateral plume expansion would be expected to occur Figures 5 to 17 of the Arcadis report (Appendix O) show the predicted extent of the TCE plume at 5 10 50 and 100 years under low to high mobility transport conditions

          Figure 81 shows the predicted extent of the 1 microgL TCE boundary in 100 years under intermediate transport conditions ndash it is recommended that this information be used to support the EPA in establishing a potential future GPA

          The Arcadis report notes that given the available site information (site history potential source area(s) and uncertainty associated with the current plume extent) and degree of model calibration (flow model parameter values are consistent with site-specific data as well as regionalnearby studies while transport parameter values are consistent with literatureindustry standards) the model-predicted migration of approximately 500 m over 100 years is considered to be a reasonable representation of future conditions

          Key uncertainties associated with the modelling were identified as including the following

          current plume extents (ie down-gradient delineation)

          site-specific fraction organic values (or site-specific partition coefficient estimates) and

          site-specific porosity estimates

          13 although it was noted that there is uncertainty with respect to the current extent of the TCE plume since all three down-gradient monitoring wells (MW18 MW23 and MW25) have TCE concentrations above 1 μgL

          14 ie assuming different values for mobileimmobile porosity the TCE distribution (sorption) coefficient and the TCE retardation factor

          80607-1 REV1 30102017 PAGE 45

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Lesser uncertainties were considered to include site-specific bulk hydraulic conductivity estimates and determination of the presence or absence of naturally-occurring TCE degradation

          Additional site investigation and data collection (eg multi-well pumping tests for bulk hydraulic conductivity estimates site-specific fraction organic carbon andor distribution (sorption) coefficient additional down-gradient plume delineation) would help to further refine the model and increase confidence in the predictive results

          Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green) relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple)

          PAGE 46 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          9 VAPOUR INTRUSION RISK ASSESSMENT

          Arcadis were commissioned by Fyfe to undertake a Vapour Intrusion Risk Assessment (VIRA) of the soil vapour CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained (ie August 2017) permanent soil vapour bore data The Arcadis report is included as Appendix P

          91 Objective

          The main objective of the VIRA was to evaluate the potential risk to human health from vapour intrusion related to the concentrations of CHC identified in soil vapour within the Thebarton EPA Assessment Area

          92 Areas of interest

          The following areas of specific interest (ie located within the Thebarton EPA Assessment Area) were identified for the purpose of this VIRA

          commercialindustrial properties (assumed slab on grade construction) including the former Austral property (ie the suspected source site) and

          residential properties (slab on grade crawl space and basement constructions)

          Potential exposure by trenchmaintenanceutility workers has also been considered (qualitatively)

          93 Risk assessment approach

          The VIRA was conducted in accordance with the ASC NEPM (1999) enHealth (2012a) and other relevant Australian guidance documents as well as guidance documents issued by the US EPA and other international regulatory agencies (where applicable)

          The conduct of the risk assessment was based on a multiple lines of evidence approach using the available site-specific information collected as part of the scope of works detailed in Section 32

          The following information was used as a basis for the VIRA

          CHC including TCE PCE and DCE (11- cis-12- and trans-12-) have been identified within soil vapour andor groundwater within the Thebarton EPA Assessment Area ndash the analytical data indicate that TCE constitutes between about 95 and 100 of the CHC identified in groundwater and soil vapour

          TCE has been considered as the risk driver for the VIRA (ie based on its toxicity and concentrations in soil vapour and groundwater) ndash although TCE PCE 12-DCE 11-DCE and VC have all been included as COPC for the Tier 1 screening assessment (Section 94) the Tier 2 assessment (Section 95) has

          80607-1 REV1 30102017 PAGE 47

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          concentrated on TCE PCE and 11-DCE (ie due to their presence at concentrations that exceeded the adopted Tier 1 screening criteria)

          The CHC identified within the Thebarton EPA Assessment Area are volatile chemicals and could potentially pose a risk to human health via the vapour intrusion pathway Although the source area has yet to be confirmed the CHC concentrations observed in groundwater and soil vapour are considered likely to have originated from the former Austral property (as discussed in Section 12)

          The natural soils underlying the fill material (where present) in the Thebarton EPA Assessment Area are typified by the Quaternary age soils and sediments of the Adelaide Plains with the Pooraka Formation and Hindmarsh Clay units considered to dominate the upper soil profile

          The soil geotechnical data and soil vapour results collected by Fyfe (as discussed in Sections 712 and 74 respectively) have been used for the VIRA

          A two-tier approach was adopted for the VIRA The first tier (herein referred to as the Tier 1 assessment) was conducted by comparing the measured soil vapour TCE concentrations to published guideline values adjusted (conservatively) to account for attenuation from sub-slab soil into indoor air The second tier (herein referred to as the Tier 2 assessment) involved the comparison of predicted indoor air TCE concentrations to adopted indoor air criteria or response levels

          94 Tier 1 assessment

          As detailed in Section 74 the initial Tier 1 (screening risk) assessment involved comparing measured soil vapour COPC concentrations with the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land uses (refer to Table 74) Given that the development of the interim soil vapour HILs was based on very conservative assumptions the initial Tier 1 assessment provided only a first-pass screening assessment of the data to determine if further risk assessment would be required

          The interim soil vapour HILs are applicable for the assessment of soil vapour at 0 to 1 m beneath the floor of a building They were based on adopted toxicity reference values (TRV) and relevant exposure parameters (ie adjusted for different land uses) as well as an assumed soil vapour to indoor air attenuation factor of 01

          The soil vapour to indoor air attenuation factor (01) was based on the US EPA (2002) recommended default attenuation factors for the generic screening step of a tiered vapour intrusion assessment process As discussed in the US EPA (2002) document the default attenuation factor of 01 for sub-slab soil vapour was based on a US EPA database of empirical attenuation factors calculated using measurements of indoor air and soil vapours from different sites In 2012 the US EPA provided an updated database which was accompanied by an evaluation and statistical analysis of attenuation factors for volatile CHC in residential buildings US EPA (2012) found the sub-slab to indoor air attenuation factor of 003 to be the 95th percentile In 2015 the revised sub-slab attenuation factor (003) was adopted by the US EPA

          PAGE 48 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          The revised sub-slab to indoor air attenuation factor of 003 was adopted to derive modified residential and commercialindustrial soil vapour HILs for the Tier 1 assessment The modified residential soil vapour HILs are presented in Table 91 relative to the maximum CHC concentrations obtained for soil vapour within the Thebarton EPA Assessment Area

          The Tier 1 assessment based on a comparison of the COPC concentrations measured in soil vapour at various locations within the Thebarton EPA Assessment Area with the modified residential soil vapour HILs detailed in Table 91 indicated the following

          TCE concentrations exceeded the adopted criterion in SV1 to SV9 whereas

          the concentrations of PCE and 11-DCE exceeded the adopted criteria in SV3 only

          These locations were identified as requiring further assessment (ie Tier 2 VIRA ndash refer to Section 95)15

          Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs

          Compound ASC NEPM (1999) HIL

          (microgm3)

          Modified Tier 1 HIL (microgm3)

          (AF = 003)

          Maximum measured soil vapour concentration (microgm3)

          Acceptable

          Location 1 m BGL Location 3 m BGL

          11-DCE 7000 SV3 5900 SV3 14000 No ndash Tier 2 required

          cis-12-DCE 80 265 SV2 21 SV4 30 Yes

          trans-12-DCE 80 265 - ND SV5 20 Yes

          PCE 2000 6650 SV3 6500 SV3 15000 No ndash Tier 2 required

          TCE 20 65 SV3 210000 SV3 100000 0

          No ndash Tier 2 required

          VC 30 100 - ND - ND Yes Notes Values in bold exceed the modified residential soil vapour HILs cis-12-DCE HIL adopted as surrogate screening criterion based on US EPA (2017b) regional screening level for residential air elevated laboratory LOR (ie above modified Tier 1 HIL) also reported Abbreviations AF = attenuation factor HIL = health investigation level ND = non detect

          95 Tier 2 assessment

          951 Tier 2 assessment criteria

          The Tier 2 VIRA criteria for the residential zone comprise HIL-based residential indoor air criteria for the COPC (refer to Section 94) along with the residential indoor air level response ranges for TCE that were

          15 Note that all locations were subjected to the Tier 2 VIRA in this assessment

          80607-1 REV1 30102017 PAGE 49

          EPA REF 0524111 FINAL REPORT

          STAGE 1 ENVIRONMENTAL ASSESSMENT

          THEBARTON ASSESSMENT AREA

          initially developed by the EPA and SA Health for the EPA Assessment Area at Clovelly Park and Mitchell

          Park These screening criteria and indoor air response ranges as detailed in SA EPA (2014) and

          reproduced in Figure 91 are now widely adopted in South Australia for the assessment of TCE relating

          to indoor air exposure

          Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels

          Note The no action response level is applicable where a soil vapour concentration is below the laboratory LOR (ie ND or ldquonon-

          detectrdquo assumed to be lt01 microgm3)

          PAGE 50 80607-1 REV1 | 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          952 Vapour intrusion modelling

          For this VIRA exposure point concentrations (EPCs) of COPC in the indoor air of buildings with a slab on grade crawl space or basement construction were estimated using conservative screening assumptions and the Johnson and Ettinger (1991) vapour transport and mixing model (ie the JampE model)

          The algorithms applied in the JampE (1991) model are detailed in Appendix A of the Arcadis report whereas the modelling spreadsheets for each scenario are provided in Appendix B ndash the Arcadis report is attached to this report as Appendix P

          9521 Input parameters

          The input parameters adopted for the vapour intrusion modelling relate to the following

          the construction type and details of existing or proposed buildings ndash refer to Table 92 for adopted building input parameters

          the nature of the soil profile ndash refer to Table 93 for adopted soil input parameters (0 to 1 m BGL) and

          the contaminant source concentrations ndash refer to Table 6 in Appendix L

          Table 92 Tier 2 vapour intrusion modelling ndash building input parameters

          Parameter Units Adopted value Reference

          Residential Commercial industrial

          Width of Building cm 1000 2000 Friebel and Nadebaum (2011)

          Length of Building cm 1500 2000

          Height of Room cm 240 300

          Height of crawl space cm 30 - Assumption for crawl space

          Attenuation from basement to ground floor air

          - 01 01 Friebel and Nadebaum (2011)

          Air Exchange Rate (AER)

          Indoor per hour 06 083 Friebel and Nadebaum (2011)

          Crawl space per hour 06 - Friebel and Nadebaum (2011)

          Basement per hour 06 - As per residential (indoor)

          Fraction of Cracks in Walls and foundation

          - 0001 0001 Friebel and Nadebaum (2011)

          Qsoil cm 3s 300 277 Calculated from QsoilQbuilding ratio of 0005 (residential) and 0001 (commercial)

          80607-1 REV1 30102017 PAGE 51

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters

          Parameter Units Adopted value Reference

          Depth cm 100 Depth of shallow soil vapour data

          Total porosity - 047 Site specific geotechnical data ndash ie averaged from MW3 and MW11 shallow samples (refer to Table 1 in Appendix L) Air filled porosity - 030

          Water filled porosity - 017 Notes ie representing a conservative approach whereby data for the shallow samples with the highest total porosity and lowest degree of saturation (and therefore the highest air filled porosity) have been adopted

          The site specific attenuation factors calculated within the vapour intrusion models (Appendix B of the Arcadis report) are summarised in Table 94 These are chemical and depth specific values applicable to each building construction scenario These attenuation factors have been applied to the soil vapour data measured across the Thebarton EPA Assessment Area to calculate indoor air concentrations (residential properties only) in proximity to each soil vapour location ndash for commercialindustrial properties (slab on grade) indoor air concentrations have only been calculated with respect to the soil vapour data obtained for SV3 (ie the soil vapour bore with the highest measured TCE concentrations)

          Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air

          Scenario Attenuation factor

          Residential ndash slab on grade 706 x 10-4

          Residential ndash crawl space 209 x 10-3

          Residential ndash basement 113 x 10-1

          Commercial ndash slab on grade 408 x 10-4

          Notes ie soil vapour intrusion to indoor air of residential living spaces refer to Section 953 for a discussion of potential vapour intrusion risks associated with commercialindustrial properties

          The chemical parameters of the COPC adopted in the JampE model were updated with data from the chemical database in the Risk Assessment Information System (RAIS 2016) as detailed in Table 95

          Table 95 Summary of chemical parameters adopted for vapour intrusion modelling

          Chemical Diffusivity in Air Diffusivity in Water Solubility Henryrsquos Law Molecular weight (Dair) Water (Dwater) (S) Constant 25oC (gmol)

          (cm2s) (cm2s) (mgL) (unitless)

          11-DCE 00863 0000011 2420 107 969

          PCE 00505 000000946 206 0724 166

          TCE 00687 00000102 1280 0403 131

          PAGE 52 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          9522 Predicted indoor air concentrations

          Residential The predicted indoor air concentrations for each soil vapour data point as calculated by Arcadis for the three residential building scenarios (ie slab on grade crawl space and basement) are presented in Appendix C of the Arcadis report (included in this report as Appendix P)

          Table 96 provides a comparison of predicted indoor air concentrations against the EPA response levels detailed in Section 951 (Figure 91) ndash ie using the 1 m soil vapour data space for slab on grade and crawl space scenarios versus the 3 m soil vapour data for basements

          It should be noted that if residential properties within the Thebarton EPA Assessment Area have basements however the vapour intrusion risks will increase whereas slab on grade construction will carry a lesser vapour intrusion risk (as detailed in Table 96)

          Commercialindustrial The predicted indoor air concentrations as calculated by Arcadis for a commercialindustrial (ie slab on grade) land use scenario with respect to the soil vapour data obtained for SV3 (ie maximum measured soil vapour concentrations) are as follows

          11-DCE 3 microgm3

          PCE 19 microgm3 and

          TCE 86 microgm3

          As these values are not directly comparable to the EPA response levels developed for residential land use further discussion of potential vapour intrusion risks to human health under a commercialindustrial land use

          scenario is included in Section 953

          As discussed for residential properties the vapour intrusion risks may increase if basements are present

          80607-1 REV1 30102017 PAGE 53

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Table 96 Comparison of predicted residential indoor air concentrations with SA EPA response levels

          Indoor Air Concentration Ranges (microgmsup3) SA EPA response levels

          non-detect No action

          gt non-detect to lt2 Validation

          2 to lt20 Investigation

          20 to lt200 Intervention

          ge200 Accelerated Intervention

          Soil vapour bore

          Sample depth

          (m)

          Soil vapour TCE concentration

          (microgmsup3)

          Predicted indoor air concentration (microgmsup3)

          Residential scenario

          Slab on grade Crawl space Basement

          Attenuation factor

          7 x 10-4 2 x 10-3 1 x 10-1

          SV1 10 5700 4 11

          SV1 30 21000 2100

          SV2 10 51000 36 102

          SV2 30 890000 89000

          SV2 (FD) 30 940000 94000

          SV3 10 210000 147 420

          SV3 30 1000000 100000

          SV4 10 17000 12 34

          SV4 30 43000 4300

          SV5 10 100000 70 200

          SV5 30 160000 16000

          SV6 10 22000 15 44

          SV6 (FD) 10 22000 15 44

          SV6 30 150000 15000

          SV6 (FD) 30 140000 14000

          SV7 10 22000 15 44

          SV7 30 110000 11000

          SV8 10 2300 2 5

          SV8 30 14000 1400

          SV9 10 170 012 030

          SV9 30 260 26

          SV10 10 9 0007 0019

          SV10 30 51 51

          SV11 10 lt18 - -

          SV12 10 16 0011 0032

          SV12 30 55 55

          SV13 10 lt21 - -

          PAGE 54 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Notes With respect to the predicted indoor air CHC concentrations in the Arcadis VIRA report (refer to Appendix P) the results in Table 5 were calculated for SV3 using the unrounded attenuation factors presented in Appendix B (and Table 94 of this report) whereas the TCE indoor air concentrations in Appendix C (as summarised in Table 96) were calculated using rounded attenuation factors ndash this does not change the overall interpretation of the results Abbreviations FD = field duplicate

          9523 Sensitivity analysis

          Table 97 presents a qualitative sensitivity analysis for some of the input variables used in the modelling ndash it includes the range of practical values for each variable the value used in the risk assessment the relative model sensitivity and the uncertainty associated with the variable

          Although Arcadis note that a number of parameters used within the risk assessment have a moderate degree of uncertainty associated with them thereby suggesting that the modelling may be sensitive to changes in these parameters values used to define these parameters were selected to be conservative This is considered to have resulted in an assessment which is expected to be conservative and to over-estimate actual risk

          Table 97 Summary of model input parameters subjected to sensitivity analysis

          Input Range of values Value adopted Sensitivity of calculated input parameters variable

          Soil physical parameters

          Total porosity

          Varies by soil type generally 03 to 05

          047 Site-specific

          Indoor air concentrations will decrease with increasing total porosity Moderate sensitivity parameter decreasing by 50 will increase predicted concentration by a factor of 4

          Air filled porosity

          Varies by soil type generally 015 to 03

          03 Site-specific

          Indoor air concentrations will increase with increasing air filled porosity Moderate to high sensitivity parameter reduction by 50 decreases concentration by a factor of 10

          Water filled porosity

          Varies by soil type from 005 (fill or

          sand) to 03 (clay)

          017 Site-specific

          Negligible impact on predicted indoor air concentrations although may decrease with increasing moisture content Very low sensitivity parameter

          Building parameters

          Air exchange rate (AER)

          Varies from 05 hr-1

          in smaller buildings to gt2 hr-1

          06 hr-1 for residential structures

          083 hr-1 for commercial

          Indoor air concentrations will decrease with increasing air exchange Moderate sensitivity parameter has linear relationship with predicted concentrations conservative assumptions used

          80607-1 REV1 30102017 PAGE 55

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Input Range of values Value adopted Sensitivity of calculated input parameters variable

          Advective flow rates

          Varies depending on building size and

          AER

          300 cm3sec Calculated from building AER and

          ratio of 0005

          Indoor air concentrations will increase with increasing advective flow Low sensitivity parameter particularly within normal range of potential values The assumption that advective flow is occurring into a building at all times is generally conservative for Australian settings Advection is unlikely to occur under a crawl space home and diffusive transport is the dominant transport mechanism

          Building size Variable Variable consistent with

          Friebel and Nadebaum (2011)

          Indoor air concentrations decrease with increasing building volume

          Very low sensitivity parameter

          9524 Uncertainties

          The following uncertainties were identified in the Arcadis report (Appendix P)

          Vapour transport modelling

          The use of a model to predict the migration of vapour from a sub-surface source to indoor air requires the simplification of many complex processes in the sub-surface as well as the potential for entry and dispersion within a building or outdoor air To address this simplification the vapour models available (and adopted in this assessment) are considered to be conservative such that uncertainties are addressed through the overshyestimation of likely concentrations

          It should be noted that the vapour model used is designed to be a first tier screening tool and is considered likely to over-estimate air concentrations due to the incorporation of a number of conservative assumptions including the following

          chemical concentrations in soil vapour were assumed to remain constant over the duration of exposure (ie it was assumed that the source was non-depleting and not subject to natural biodegradation processes)

          the maximum reported soil vapour concentrations were assumed to be present beneath nearby dwellings and

          the occurrence of steady well-mixed vapour dispersion within the enclosed or ambient mixing space

          Overall the vapour modelling undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

          PAGE 56 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Toxicological Data

          In general the available scientific information involves the extrapolation of toxicity information from studies involving experimental laboratory animals with some validation of observable health effects obtained through epidemiological studies

          This may introduce two types of uncertainties into the risk assessment as follows

          those related to extrapolating from one species to another and

          those related to extrapolating from the high exposure doses usually used in experimental animal studies to the lower doses usually estimated for human exposure situations

          In order to adjust for these uncertainties toxicity values commonly incorporate safety factors that may vary from 10 to 10000

          Overall the toxicological data presented in this assessment are considered to be current and adequate for the assessment of risks to human health associated with potential exposure to the COPC identified The uncertainties inherent in the toxicological values adopted are considered likely to result in an over-estimation of actual risk

          953 Potential vapour intrusion risks associated with commercialindustrial properties

          An assessment of potential vapour intrusion risks to workers at commercialindustrial properties (slab on grade construction) within the Thebarton EPA Assessment Area was undertaken by Arcadis using the methodology published by US EPA (2009) and incorporated into the ASC NEPM (1999) This approach recommends adjustment of the measured or estimated contaminant concentrations in air to account for site specific exposures by the relevant receptors as follows

          Ca ET EF EDECinh = days hours AT 365 24 year day

          Where

          ECinh = Exposure Adjusted Air Concentration (mgm3) Ca = Chemical Concentration in Air (mgm3) ET = Exposure Time (hoursday) EF = Exposure Frequency (daysyear) ED = Exposure Duration (years) AT = Averaging Time (years)

          = 70 years for non-threshold carcinogens = ED for chemicals assessed based on threshold effects

          80607-1 REV1 30102017 PAGE 57

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Exposure parameters were selected from Australian sources (enHealth 2012b ASC NEPM 1999) for the receptor groups evaluated or were based on site specific factors Table 98 presents an overview of the parameters used whereas adopted inhalation TRVs are presented in Table 99

          Risk was characterised for threshold and non-threshold effects for the COPC ndash spreadsheets presenting the risk calculations are provided in Appendix B of the Arcadis report (as included in Appendix P) For commercialindustrial properties the non-threshold risk level was calculated to be 3 x 10-5 (compared to a target risk level of 1 x 10-5) whereas the threshold risk level was calculated to be 10 (compared to a target risk level of 1) ndash these results indicated a potentially unacceptable vapour intrusion risk to commercialindustrial workers in the vicinity of the maximum soil vapour CHC concentrations (ie at SV3 ndash worst-case scenario based on maximum soil vapour concentrations)

          Table 98 Exposure parameters ndash Commercialindustrial workers

          Exposure parameter Units Value Reference

          Exposure frequency days year 365 ASC NEPM (1999)

          Exposure duration years 30 ASC NEPM (1999)

          Exposure time indoors hoursday 8 ASC NEPM (1999)

          Averaging time

          Non-threshold

          threshold

          Years

          years

          70

          30 ASC NEPM (1999)

          Table 99 Adopted inhalation toxicity reference values

          COPC Toxicity reference values

          Non-threshold (microgm3)

          Reference Threshold (microgm3)

          Reference

          11-DCE NA - 80 ATSDR (1994)

          PCE NA - 200 WHO (2006)

          TCE 41 US EPA (2011) IRIS 2 US EPA (2011) IRIS Notes Abbreviations NA = not applicable

          954 Potential risks to trenchmaintenanceutility workers

          Although trenchmaintenanceutility workers may be exposed to soil vapour concentrations as measured at 1 m BGL due to the short-term nature of such works their total intakes of TCE and other CHC will be low Assuming that a trenchmaintenanceutility worker may be exposed to TCE for a limited number of working days throughout the year (eg 20 days of 8 hours duration within an excavation) their intake will be approximately one fiftieth of the intake of a resident (who is assumed to be exposed 21 hours a day for 365 days a year)

          PAGE 58 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Therefore the management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air)

          96 Conclusions

          On the basis of the available data and the assessment presented in the Arcadis VIRA report (Appendix P) the following conclusions were provided

          Health risks for residents due to the intrusion of CHC in soil vapour into residential buildings with a slab on grade crawl space or basement construction were calculated to be above the adopted EPA response levels and risks to residents may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

          Health risks for commercial workers due to the intrusion of CHC in soil vapour into buildings with a slab on grade construction were calculated to be above the adopted target risk levels and risks to workers may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

          In the absence of specific information regarding building construction within the Thebarton EPA Assessment Area the predicted indoor air concentrations calculated from the 1 m BGL soil vapour data for a residential crawl space scenario are summarised in Table 910

          Table 910 Summary of properties with predicted indoor air concentrations (residential crawl space) above adopted EPA response levels

          EPA response level No of residential properties affected Indoor air concentration (microgm3) Response

          non-detect to lt2 Validation 9

          2 to lt20 Investigation 10

          20 to lt200 Intervention 8

          ge200 Accelerated intervention 3 Notes According to information provided by the EPA there are approximately 130 residential properties located in the Thebarton EPA Assessment Area calculated on the basis of cadastral boundaries ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial facility ndash these data would therefore need to be confirmed via a property survey

          80607-1 REV1 30102017 PAGE 59

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          10 CONCEPTUAL SITE MODEL

          As detailed in Table 101 a CSM has been developed for the Thebarton EPA Assessment Area on the basis of historical information (as summarised in Section 12 as well as Appendices A and B) and the data obtained during the recent Fyfe investigation program

          Table 101 Summary of existing information for the Thebarton EPA Assessment Area

          Topic Summarised Information

          Site Characterisation

          Identification of Assessment Area

          An approximately 27 ha Assessment Area located within the suburb of Thebarton has been defined by the EPA The boundaries of this area are detailed in Section 21 and illustrated on Figure 1

          History of land use Properties located within the Thebarton EPA Assessment Area have been used for a mixture of commercialindustrial and low density residential land uses over time Current commercialindustrial properties include a beverage factory in the north-eastern portion of the assessment area a refrigeration equipment facility a car dealership two hotels (at least one of which has a cellarbasement) automotive and other workshops and the Ice Arena Former commercialindustrial activities have been identified as including a gas works a mechanicrsquos workshop sheet metal working facilities and a farm machinery manufacturer

          Historical investigations

          Reports provided to Fyfe by the EPA that pertain to previous investigations undertaken within the Thebarton EPA Assessment Area have been reviewed and summarised in Appendix A Additional historical information is included in Appendix B

          Local geology Natural soils encountered from the surfacenear surface to the maximum drill depth of 19 m BGL across the Thebarton EPA Assessment Area were considered to be indicative of the Quaternary Pooraka and Hindmarsh Clay formations Whereas fill materials (ie sand gravelcrushed rock andor silt) were encountered to depths of up to 09 m BGL at a number of sampling locations underlying natural soils comprised mainly low to medium plasticity silty or sandy clays with variable gravel contents Geotechnical testing of subsurface soil samples collected from 10 drill cores indicated that the PSD comprised predominantly claysilt with lesser components of sand andor gravel ndash these soil samples were mostly classified as Clay although some were classified as Sandy Clay or Clayey Sand According to Stapledon (1971) the Hindmarsh Clay unit typically contains many structural features and defects which greatly influence its permeability thereby resulting in potential preferential pathways for the vertical and lateral movement of soil vapour and groundwater Such features were not specifically observed during the recent drilling and soil logging work although some gravel lenseslayers were identified

          Hydrogeology In accordance with Gerges (2006) and his classification of the Adelaide metropolitan area into a number of zones based on their individual hydrogeological characteristics the Thebarton EPA Assessment Area is located within Zone 3 (subzone 3E) to the west of the Para Fault It contains five to six Quaternary aquifers and three or four Tertiary aquifers Based on the most recent investigations the depth to water within the Q1 aquifer in the Thebarton EPA Assessment Area ranges from approximately 123 to 159 m BGL and groundwater flows in a general north-westerly direction with a relatively flat hydraulic gradient (000062 to 00012) Salinity levels (based on field EC readings) range from approximately 1230 to 3620 mgL TDS and a groundwater flow velocity range of approximately 44 to 23 myear has

          80607-1 REV1 30102017 PAGE 61

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Topic Summarised Information

          been inferred As detailed in Section 222 a search of the DEWNR (2017) WaterConnect database identified 59 bores within the general Thebarton area of which 18 are located within the Thebarton EPA Assessment Area Although (where recorded) bores were listed as having been installed primarily for monitoring investigation or observation purpose other purposes (for presumed Quaternary aquifer bores) included drainage domestic and industrial A BUA has identified realistic groundwater uses as potentially including potable residential irrigation and primary contact recreationaesthetics Based on proximity to the River Torrens freshwater ecosystem protection has also been considered ndash however since the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area this may not be a realistic beneficial use Since volatile contaminants have been detected within the Q1 aquifer a potential vapour flux risk to future site users has also been considered

          Hydrology No surface water bodies have been identified within the Thebarton EPA Assessment Area The closest surface water body is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west Current stormwater run-off within the Thebarton EPA Assessment Area is expected to be collected by localised (and engineered) drainage systems

          Fyfe Investigation Results

          Groundwater impacts Contaminants identified in groundwater beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected source site (ie the former Austral sheet metal works) in accordance with the predominant flow direction associated with the Q1 aquifer (refer to Figures 4 and 5) The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) but its north-western extent has not yet been determined (whereas its extent has been defined in all other directions)

          Soil vapour impacts Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction (refer to Figures 6 and 7) and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion The soil vapour samples with the maximum TCE concentrations (ie SV3_10m and SV3_30m) also had the highest PCE and 11-DCE concentrations (or elevated LOR) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-) Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE (ie SV2_30m SV3_10m SV3_30m and SV7_30m) exceeded the adopted HILs for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE

          PAGE 62 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Topic Summarised Information

          degradation has not yet resulted in its production (ie at measureable levels) Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

          Potential Exposure Pathways

          Contaminants of Based on the results of historical investigations the EPA identified a number of CHC as being of Potential Concern concern for the Thebarton EPA Assessment Area The main COPC was identified as TCE with

          additional COPC including PCE 12-DCE (cis- and trans-) VC and 11-DCE Further detail is provided in Section 14 These COPC were confirmed by the Fyfe investigations with TCE identified as both the main contaminant in groundwater and soil vapour and the main driver in terms of potential human health risks associated with vapour intrusion into buildings within the Thebarton EPA Assessment Area (refer to Section 9)

          Suspected source and The suspected source of the identified CHC groundwater (and soil vapour) impacts within the affected media Thebarton EPA Assessment Area is the former Austral sheet metal works located over multiple

          allotments between George and Maria Streets from the 1920s until the 1960s-1970s Previous investigations (Appendix A) had identified groundwater CHC impacts on part of this suspected source site The Fyfe investigations have concentrated on impacts within groundwater and soil vapour across the Thebarton EPA Assessment Area both of which generally correlate with the inferred north-westerly groundwater flow direction and are considered to be related to the previously identified dissolved phase groundwater CHC impacts

          Sensitive receptors The following sensitive receptors have been identified as potentially relevant to the Thebarton EPA Assessment Area Ecological groundwater ecosystems within the assessment area extending to at least Dew and Smith

          Streets (ie as the north-western extent of the groundwater CHC plume has not yet been determined) and

          the freshwater ecosystem of the River Torrens located at a distance of approximately 07 km in a hydraulically down-gradient (ie north-westerly) direction but not necessarily representing a groundwater receiving environment

          Human current and future occupants of and visitors to residential properties current and future workers on the source site and other commercialindustrial properties

          within the area current and future underground trenchmaintenanceutility workers and down-gradient groundwater bore users

          Contaminant Possible contaminant transport mechanisms associated with the CHC-impacted groundwater transport identified within the Q1 aquifer beneath the Thebarton EPA Assessment Area include mechanisms flow through the aquifer to a hydraulically down-gradient surface water body andor down-

          gradient groundwater bores vapour generation andor flow via subsurface preferential pathways (eg service trenches

          more permeable soils) and downward movement into underlying aquifers (eg dense non-aqueous phase liquid

          (DNAPL))

          80607-1 REV1 30102017 PAGE 63

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Topic Summarised Information

          Exposure Possible exposure mechanisms associated with impacted groundwater within the Thebarton mechanisms EPA Assessment Area include

          direct contact (eg during extractionuse of groundwater) incidental ingestion (eg during extractionuse of groundwater) and inhalation of vapours (eg during extractionuse of groundwater andor as a result of

          vapour intrusion into buildings)

          Assessment of Risk

          Groundwater risks The recent groundwater analytical results have indicated that the Q1 aquifer beneath the Thebarton EPA Assessment Area contains measurable concentrations of CHC (mainly TCE but also including PCE 12-DCE andor 11-DCE at some locations) Measured concentrations of TCE exceeded the adopted assessment criteria for potable andor primary contact recreation in wells MW02 MW3 MW5 MW6 MW11 MW12 MW14 MW15 MW17 MW20 MW21 and MW23 located on Admella Maria George Albert and Dew Streets as well as Light Terrace with maximum concentrations corresponding to the ldquocorerdquo area of the plume One well (MW25) contained a concentration of carbon tetrachloride that exceeded the adopted potable criterion Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

          Groundwater fate Although scattered detectable concentrations of 12-DCE have been measured in groundwater and transport across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE modelling daughter products has been interpreted to indicate that substantial dechlorination is not

          occurring Groundwater fate and transport modelling (refer to Section 8 and Appendix O) has predicted that the likely extent of the dissolved phase groundwater TCE plume over the next 100 years will extend by another 500 m beyond the boundaries of the current Thebarton EPA Assessment Area However no significant lateral plume expansion is expected

          Vapour intrusion risks A VIRA (refer to Section 9 and Appendix P) was undertaken to assess potential risks to human health from the intrusion of CHC vapours (primarily TCE) into indoor air from soil vapour The predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction in the absence of specific structural information) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and therefore require further action as follows 10 properties within the investigation range (2 to lt20 microgm3) eight properties within the intervention range (20 to lt200 microgm3) and three properties within accelerated intervention range (ge200 microgm3) All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3

          (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as

          PAGE 64 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Topic Summarised Information

          selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which are expected to be overly-conservative) ndash these results will be documented in a subsequent report Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed Management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air)

          Complete Exposure Pathways

          Identified pathways and areas of potential risk

          Based on the results of the recent Fyfe investigations (including the VIRA) and taking into account available historical information (Appendices A and B) and DEWNR (2017) WaterConnect bore information the following complete exposure pathways and associated risks are considered possible for the Thebarton EPA Assessment Area exposure (direct contact incidental ingestion andor inhalation of vapours) during use of

          groundwater for domestic (eg drinking water plumbing garden irrigation) andor recreational (eg filling of swimming poolsspas) purposes

          vapour intrusion into indoor air within 30 residential propertieslocated within the vicinity of soil vapour bores SV1 to SV9 (assuming crawl space construction) ndash although 19 of these properties are predicted to be in the validationinvestigation action level range 11 are predicted to be in the intervention action level range (with actual indoor air monitoring results for properties within the intervention action level range pending)

          vapour intrusion into residential cellarsbasements (if present) in the vicinity of soil vapour bores SV1 to SV10 and SV12 and

          vapour intrusion into the indoor air of commercialindustrial properties ndash although actual risks to site workers would require further specific considerationassessment

          In addition although only assessed in a qualitative manner to date trenchmaintenanceutility workers may also be at risk where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

          Notes calculated on the basis of cadastral boundaries and assuming crawl space construction ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial premises a property survey would be required to confirm building construction details and the number of individual residences affected

          80607-1 REV1 30102017 PAGE 65

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          11 CONCLUSIONS

          Between May and August 2017 Fyfe undertook an investigation of groundwater and soil vapour CHC impacts within an EPA-designated Assessment Area located in Thebarton South Australia The results of the investigation have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties A CSM has been developed from the field analytical and modelling results as presented in Section 10

          The following conclusions have been reached

          Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were present within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m in groundwater well MW17

          Groundwater within the Q1 aquifer is located at a depth of approximately 123 to 159 m BGL and flows in a general north-westerly direction (refer to Figure 4) ndash the closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred16 and the groundwater gradient beneath the Thebarton EPA Assessment area is relatively flat (ie 000062 to 00012)

          Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified to include domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux as assessed by the VIRA) and possibly also potable Although freshwater ecosystem protection was also considered the River Torrens is thought to comprise either a recharge boundary (ie discharging to local groundwater) or to not actually be hydraulically connected to the Q1 aquifer in this area

          Groundwater beneath parts of the Thebarton EPA Assessment Area contains detectable concentrations of various CHC and includes TCE and carbon tetrachloride (one location only) levels that exceed the adopted assessment criteria for potable use andor primary contact recreation ndash thereby indicating that groundwater would be unsuitable for drinking or the filling of swimming poolsspas In addition vapour flux could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the groundwater could be odorous

          16 ie as calculated by Fyfe based on available data

          80607-1 REV1 30102017 PAGE 67

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          The groundwater and soil vapour CHC impacts identified beneath parts of the Thebarton EPA Assessment Area are considered likely to have emanated from the former Austral sheet metal works located over multiple allotments between George and Maria Streets from the 1920s until the 1960sshy1970s The possible presence of on-going (primary andor secondary) source(s) at this property has not yet been investigated

          As depicted on Figures 6 and 7 the current extent of the soil vapour CHC (ie dominated by TCE) impacts has been determined to correspond to the mapped distribution of the groundwater TCE impacts (Figure 5) and is considered to be directly related to groundwater (rather than soil) CHC impacts Although no soil vapour impacts were detected at 1 m BGL in SV11 and SV1317 located near the eastern and western ends of Light Terrace respectively the north-western extents of the groundwater and soil vapour CHC impacts have not yet been determined In addition although the extent of the groundwater TCE plume has been delineated in all other directions the soil vapour TCE plume has not been delineated in any direction

          TCE is considered to be a primary contaminant as well as the dominant (ie in terms of concentration and extent) CHC in both groundwater and soil vapour ndash the presence of PCE and 11-DCE suggests however that more than one primary contaminant is present Although the detectable concentrations of 12-DCE (cis- and trans) are considered to have resulted from the breakdown of TCEPCE no VC has been detected in either groundwater or soil vapour ndash the scattered distribution and relatively low concentrations of 12-DCE as well as the absence of measurable VC have been interpreted to indicate that significant dechlorination of the primary contaminants has not occurred (despite the likely age of the plume ndash ie possibly up to about 90 years old)

          Although the COPC adopted for the soil vapour assessment program included various CHC (ie with TCE identified as the dominant contaminant in groundwater and soil vapour) the Tier 1 VIRA confirmed that TCE PCE and 11-DCE all exceeded the adopted vapour intrusion HILs Based primarily on its greater toxicity however the risk driver for the Thebarton EPA Assessment Area is considered to be TCE

          The VIRA (Tier 2) results for predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and that require further action as follows

          ― 10 properties within the investigation range (2 to lt20 microgm3)

          ― eight properties within the intervention range (20 to lt200 microgm3) and

          ― three properties within accelerated intervention range (ge200 microgm3)

          All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming

          17 noting that the laboratory LOR for TCE was elevated as compared to the other soil vapour samples

          PAGE 68 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises ndash refer to Table 96

          Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentration obtained for soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

          Although only assessed in a qualitative manner trenchmaintenanceutility workers may be at risk in areas where TCE concentrations at 1 m BGL are greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) ndash in this case appropriate management measures would be required to be adopted This should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

          80607-1 REV1 30102017 PAGE 69

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          12 DATA GAPS

          Based on the results obtained during the recent Fyfe investigations as well as available historical information (Appendices A and B) the following data gaps have been identified for the Thebarton EPA Assessment Area

          property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

          groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

          the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

          the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

          80607-1 REV1 30102017 PAGE 71

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          13 REFERENCES

          ANZECCARMCANZ (2000a) Australian Guidelines for Water Quality Monitoring and Reporting

          ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

          ASTM (2001) Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations ASTM Guide D7663-12

          ASTM (2006) Standard Guide for Soil Gas Monitoring in the Vadose Zone ASTM Guide D5314-92

          ATSDR (1994) Toxicological profile ndash 11-Dichloroethene httpswwwatsdrcdcgovToxProfilestpaspid=722amptid=130

          AustralianNew Zealand Standard (1998) Water Quality Sampling Part 1 Guidance on the Design of Sampling Programs Sampling Techniques and the Preservation and Handling of Samples ASNZS 566711998

          AustralianNew Zealand Standard (1998) Water Quality Sampling Part 11 Guidance on Sampling of Groundwaters ASNZS 5667111998

          Bouwer H and Rice RC (1976) A Slug Test Method for Determining Hydraulic Conductivity of Unconfined Aquifers with Completely or Partially Penetrating Wells Water Resources Research vol 12 no 3 pp 423-428

          Butler JJ Jr (1998) The Design Performance and Analysis of Slug Tests

          Cooper HH Bredehoeft JD and Papadopulos SS (1967) Response of a Finite-Diameter Well to an Instantaneous Charge of Water Water Resources Research vol 3 no 1 pp 263-269

          CRC CARE (2013) Petroleum Hydrocarbon Vapour Intrusion Assessment ndash Australian Guidance CRC CARE Technical Report No 23 July 2013

          Dagan G (1978) A Note on Packer Slug and Recovery Tests in Unconfined Aquifers Water Resources Research vol 14 no 5 pp 929-934

          Department of Environment Water and Natural Resources (DEWNR 2017) Water Connect Master Register of All Bores Primary Industries and Resources South Australia

          Duffield G (2007) AQTESOLVreg Professional Version 45 Hydrosolve Inc

          enHealth (2012a) Environmental Health Risk Assessment - Guidelines for assessing human health risks from environmental hazards enHealth Council

          enHealth (2012b) Australian Exposure Factor Guidance Handbook enHealth Council

          Environment Protection Act 1993

          80607-1 REV1 30102017 PAGE 73

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          Environment Protection Regulations 2009

          Friebel E and Nadebaum P (2011) Health Screening Levels for Petroleum Hydrocarbons in Soil and Groundwater CRC CARE Technical Report No 10

          Gerges NZ (1999) The Geology and Hydrogeology of the Adelaide Metropolitan Area Flinders University (South Australia) PhD thesis (unpublished)

          Gerges NZ (2006) Overview of the Hydrogeology of the Adelaide Metropolitan Area DWLBC Report 200610

          Golder Associates (1994) Contamination Assessment George Street Thebarton SA Report to United Land dated 9 December 1994

          Hvorslev MJ (1951) Time Lag and Soil Permeability in Ground-Water Observations Bulletin no 36 Waterways Exper Sta Corps of Engrs US Army Vicksburg Mississippi pp 1-50

          Hyder Z Butler JJ Jr McElwee CD and Liu W (1994) Slug Tests in Partially Penetrating Wells Water Resources Research vol 30 no 11 pp 2945-2957

          ITRC (2007) Vapor Intrusion Pathway - A Practical Guidance

          Johnson PC and Ettinger RA (1991) Heuristic Model for Predicting the Intrusion Rate of Contaminant Vapors

          into Buildings Environ Sci Technology 251445-1452

          McDonald M G and Harbaugh A W (1988) A Modular Three-Dimensional Finite-Difference Ground-Water Flow Model Techniques of Water-Resources Investigations Book 6 Chapter A1 U S Geological Survey

          NEPM (1999) National Environment Protection (Assessment of Site Contamination) Measure Schedules B1 to

          B9 National Environment Protection Council Australia

          NHMRC (2008) Guidelines for Managing Risks in Recreational Water

          NHMRCNRMMC (2011) Australian Drinking Water Guidelines (as revised in 2016)

          NJDEP (2013) Site Remediation Program Vapor Intrusion Technical Guidance (Version 31)

          NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme (2nd edition)

          Payne FC Quinnan JA and Potter ST (2008) Remediation Hydraulics CRC Press Boca Raton FL

          RAIS (2016) Chemical Specific Parameters for Trichloroethylene Risk Assessment Information System Office of Environmental Management US Department of Energy

          REM (2005a) George St Thebarton Site ndash Stage 2 Investigations Report to Luca Group dated 26 August 2005

          REM (2005b) Stage 3 Environmental Site Assessment George St Thebarton SA Report to Luca Group dated 23 November 2005

          SA Department of Mines and Energy (1969) 1250000 Adelaide Geological Map Sheet Sheet S1 54-9

          PAGE 74 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          SA EPA (2007) Regulatory Monitoring and Testing Groundwater Sampling

          SA EPA (2009) Guidelines for the Assessment and Remediation of Groundwater Contamination

          SA EPA (2014) Clovelly Park Mitchell Park Project Management Team Assessment Program Flip Book November 2014

          SA EPA (2015) Environment Protection (Water Quality) Policy

          Standards Australia (1993) Geotechnical Site Investigations AS1726-1993

          Standards Australia (2005) Guide to the Sampling and Investigation of Potentially Contaminated Soil Part 1 Non-Volatile and Semi-Volatile Compounds AS44821-2005

          Stapledon DH (1971) Changes and Structural Defects Developed in some South Australian Clays and their Engineering Consequences Proceedings of Symposium on Soils and Earth Structures in Arid Climates Adelaide 1970

          US EPA (1996) Soil Screening Guidance Technical Background Document Office of Emergency and Remedial Response Washington DC EPA540R95128

          US EPA (1999) Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air Second Edition Compendium Method TO-15 Determination Of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed By Gas Chromatography Mass Spectrometry (GCMS) EPA625R-96010b

          US EPA (2002) OSWER Draft Guidance for Evaluating the Vapour Intrusion to Indoor Air Pathway from Groundwater and Soils (Subsurface Vapour Intrusion Guidance) EPA530-D-02-004

          US EPA (2009) EPArsquos Risk-Screening Environmental Indicators (RSEI) Methodology Office of Pollution Prevention and Toxics Washington DC

          US EPA (2011) IRIS (Integrated Risk Information System) Trichloroethylene Chemical Assessment Summary httpscfpubepagovnceairisiris_documentsdocumentssubst0199_summarypdf

          US EPA (2012) EPArsquos Vapor Intrusion Database Evaluation and Characterization of Attenuation Factors for Chlorinated Volatile Organic Compounds and Residential Buildings

          US EPA (2015) OSWER Technical Guide for Assessing and Mitigating the Vapour Intrusion Pathway from Subsurface Vapour Sources to Indoor Air

          US EPA (2017a) Regional Screening Levels (RSLs) - Generic Tables (June 2017) httpswwwepagovriskregional-screening-levels-rsls-generic-tables-june-2017

          US EPA (2017b) Regional Screening Levels for Chemical Contaminants at Superfund Sites httpwwwepagovreg3hwmdriskhumanrb-concentration_tableGeneric_Tablesindexhtm

          80607-1 REV1 30102017 PAGE 75

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          WHO (2006) Air Quality Guidelines for Europe Second Edition WHO Regional Publications European Series No 91

          WHO (2017) Guidelines for Drinking-water Quality Fourth edition (incorporating the first addendum)

          Wiedemeier T Swanson M Moutoux D Gordon E Wilson J Wilson B Kampbell D Haas P Miller R Hansen J and Chapelle F (1998) Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water National Risk Management Research Laboratory Office of Research and Development US EPA

          Zheng C (1990) MT3D A Modular Three-Dimensional Transport Model for Simulation of Advection Dispersion and Chemical Reactions of Contaminants in Groundwater Systems Prepared for US EPA by Robert S Kerr Environmental Research Laboratory Ada Oklahoma developed by SS Papadopulos amp Associates Inc Rockville Maryland

          PAGE 76 80607-1 REV1 30102017

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          14 STATEMENT OF LIMITATIONS

          The opinions and conclusions presented in this report are specific to the conditions of the Thebarton EPA Assessment Area and the state of legislation currently enacted as at the date of this report Fyfe does not make any representation or warranty that the opinions and conclusions in this report will be applicable in the future as there may be changes in the condition of the Thebarton EPA Assessment Area applicable legislation or other factors that would affect the opinions and conclusions contained in this report

          Fyfe has used the degree of skill and care ordinarily exercised by reputable members of our profession practising in the same or similar locality This report has been prepared for the South Australian Environment Protection Authority for the specific purpose identified in the report Fyfe accepts no liability or responsibility to any third party for the accuracy of any information contained in the report or any opinion or conclusion expressed in the report Neither the whole of the report nor any part or reference thereto may be in any way used relied upon or reproduced by any third party without Fyfersquos prior written approval This report must be read in its entirety including all tables and attachments

          80607-1 REV1 30102017 PAGE 77

          EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

          FIGURES

          Figure 1 Site Location and Assessment Area

          Figure 2 Assessment Point Locations

          Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan

          Figure 4 Groundwater Elevation Contour Plan

          Figure 5 Groundwater Concentration Plan

          Figure 6 Soil Vapour Concentration Plan (10m)

          Figure 7 Soil Vapour Concentration Plan (30m)

          80607-1 REV1 30102017 PAGE 79

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          DEW

          STREET

          DEW

          STREET

          CHAPEL STREETCHAPEL STREET

          PAR

          KER

          STREET

          PAR

          KER

          STREET

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          LIGHT TERRACELIGHT TERRACE

          DEW

          STREET

          DEW

          STREET

          WA

          LSH ST

          WA

          LSH ST

          AD

          MELLA

          STREET

          AD

          MELLA

          STREET

          ALB

          ERT STR

          EETA

          LBER

          T STREET

          HO

          LLAN

          D ST

          REET

          HO

          LLAN

          D ST

          REET

          RANDOLPH STREET

          RANDOLPH STREET

          JAM

          ES STREET

          JAM

          ES STREET

          DOVE STREET

          DOVE STREET

          SMITH STREETSMITH STREET

          MARIA STREETMARIA STREET

          GEORGE STREETGEORGE STREET

          KINTORE STREET

          KINTORE STREET

          PORT ROAD

          PORT ROAD

          PORT ROAD

          PORT ROAD

          CAW

          THO

          RN

          E STR

          EETC

          AWTH

          OR

          NE ST

          REET

          DEVON STREETDEVON STREET

          KINTORE STREETKINTORE STREET

          GOODENOUGH STREETGOODENOUGH STREET

          LIVESTR

          ON

          G PATH

          WAY

          LIVESTR

          ON

          G PATH

          WAY

          CCAAWW

          TTHHOO

          RRNN

          EE SSTTRR

          EEEETT

          HHOO

          LLLLAANN

          DD SSTT

          RREEEETT

          DE

          DEW

          SW

          STREET

          TREET

          JJAM

          EA

          MES S

          S STREET

          TREET

          DDOOVVEE SSTTRREEEETT

          LLIIVVEESSTTRR

          OONN

          GG PPAATTHH

          WWAAYY

          LIGHT TERRLIGHT TERRAACECE

          AD

          MELLA

          SA

          DM

          ELLA STR

          EETTR

          EET

          CHAPEL SCHAPEL STREETTREET

          AALLBB

          EERRTT SSTTRR

          EEEETT

          GEGEORORGE SGE STREETTREET

          PPOORRTT RROOAADD

          PPOORRTT RROOAADD

          DDEEWW

          SSTTRREEEETT

          MMAARRIIAA SSTTRREEEETT

          JJAAMM

          EESS CCOO

          NNGG

          DDOO

          NN DD

          RRIIVV

          EE

          WWAA

          LLSSHH SSTT

          SSMMIITTHH SSTTRREEEETT

          RRANDOLPH S

          ANDOLPH STREETTREET

          PPOORR

          TT RROO

          AADD

          PPOORR

          TT RROO

          AADD

          KKIINNTTOORREE SSTTRREEEETT

          KKIINNTTOORREE SSTTRREEEETT

          PPAARR

          KKEERR

          SSTTRREEEETT

          GGOOOODDEENNOOUUGGHH SSTTRREEEETT

          DDEEVVOONN SSTTRREEEETT

          ASSESSMENT AREA

          CBD

          750m

          LEGEND

          EPA ASSESSMENT AREA

          CADASTRE

          12500 A3

          0 25 50 m

          CLIENT

          SA EPA

          PROJECT

          FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

          EPA THEBARTON ASSESSMENT AREA - STAGE 1

          TITLE

          FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

          PROJECT NO DATE CREATED

          80607-1 290917

          80607_Fig 1 - Site Location and Assessment Areaai REV 1 gt 290917

          LE

          VE

          L 1

          12

          4 S

          OU

          TH

          TE

          RR

          AC

          E

          AD

          EL

          AID

          E S

          A 5

          00

          0

          P

          H

          (08

          ) 8

          23

          2 9

          08

          8

          F

          AX

          (0

          8)

          82

          32

          90

          99

          EM

          AIL

          in

          fo

          fyfe

          co

          ma

          u

          W

          EB

          fy

          fec

          om

          au

          AB

          N

          57

          00

          8 1

          16 1

          30

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          DEW

          STREET

          DEW

          STREET

          CHAPEL STREETCHAPEL STREET

          PAR

          KER

          STREET

          PAR

          KER

          STREET

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          LIGHT TERRACELIGHT TERRACE

          DEW

          STREET

          DEW

          STREET

          WA

          LSH ST

          WA

          LSH ST

          AD

          MELLA

          STREET

          AD

          MELLA

          STREET

          ALB

          ERT STR

          EETA

          LBER

          T STREET

          HO

          LLAN

          D ST

          REET

          HO

          LLAN

          D ST

          REET

          RANDOLPH STREET

          RANDOLPH STREET

          JAM

          ES STREET

          JAM

          ES STREET

          DOVE STREET

          DOVE STREET

          SMITH STREETSMITH STREET

          MARIA STREETMARIA STREET

          GEORGE STREETGEORGE STREET

          KINTORE STREET

          KINTORE STREET

          PORT ROAD

          PORT ROAD

          PORT ROAD

          PORT ROAD

          CAW

          THO

          RN

          E STR

          EETC

          AWTH

          OR

          NE ST

          REET

          DEVON STREETDEVON STREET

          KINTORE STREETKINTORE STREET

          GOODENOUGH STREETGOODENOUGH STREET

          LIVESTR

          ON

          G PATH

          WAY

          LIVESTR

          ON

          G PATH

          WAY

          SV1SV1

          SV2SV2

          SV3SV3SV4SV4

          SV5SV5

          SV6SV6

          SV7SV7SV8SV8

          SV9SV9

          SV10SV10

          SV11SV11SV12SV12

          SV13SV13

          MW1MW1

          MW02MW02

          MW3MW3

          MW4MW4MW5MW5MW6MW6

          MW7MW7

          MW8MW8

          MW9MW9

          MW10MW10MW11MW11

          MW12MW12MW13MW13

          MW14MW14MW15MW15

          MW16MW16

          MW17MW17

          MW18MW18

          MW19MW19

          MW20MW20

          MW21MW21

          MW22MW22

          MW23MW23

          MW24MW24

          MW25MW25

          MW26MW26

          WMS2WMS2WMS1WMS1

          WMS3WMS3WMS4WMS4WMS5WMS5

          WMS6WMS6

          WMS7WMS7WMS8WMS8

          WMS9WMS9WMS10WMS10

          WMS11WMS11

          WMS12WMS12

          WMS13WMS13WMS14WMS14

          WMS15WMS15

          WMS41WMS41

          WMS40WMS40

          WMS39WMS39WMS38WMS38

          WMS16WMS16

          WMS17WMS17

          WMS18WMS18WMS19WMS19

          WMS20WMS20

          WMS21WMS21WMS22WMS22

          WMS23WMS23WMS24WMS24

          WMS25WMS25

          WMS26WMS26

          WMS27WMS27WMS28WMS28WMS29WMS29

          WMS30WMS30

          WMS31WMS31

          WMS32WMS32

          WMS33WMS33

          WMS34WMS34

          WMS35WMS35

          WMS36WMS36

          WMS37WMS37

          WWAA

          LLSSHHSSTT

          SSMMIITTHH SSTTRREEEETT

          RRANDOLPH S

          ANDOLPH STREETTREET

          PPOORR

          TT RROO

          AADD

          PPOORR

          TT RROO

          AADD

          CCAAWW

          TTHHOO

          RRNN

          EE SSTTRR

          EEEETT

          JJAM

          EA

          MES S

          S STREET

          TREET

          HHOO

          LLLLAANN

          DDSSTT

          RREEEETT

          DE

          DEW

          SW

          STREET

          TREET

          DDOOVVEE SSTTRREEEETT

          LLIIVVEESSTTRR

          OONN

          GGPPAATTHH

          WWAAYY

          LIGHT TERRLIGHT TERRAACECE

          CHAPEL SCHAPEL STREETTREET

          AALLBB

          EERRTT SSTTRR

          EEEETT

          AD

          MELLA

          SA

          DM

          ELLA STR

          EETTR

          EET

          GEGEORORGE SGE STREETTREET

          PPOORRTT RROOAADD PPOORRTT RROOAADD

          DDEEWW

          SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

          JJAAMM

          EESS CCOO

          NNGG

          DDOO

          NN DD

          RRIIVV

          EE

          KKIINNTTOORREE SSTTRREEEETT

          KKIINNTTOORREE SSTTRREEEETT

          PPAARR

          KKEERR

          SSTTRREEEETT

          GGOOOODDEENNOOUUGGHH SSTTRREEEETT

          DDEEVVOONN SSTTRREEEETT

          FIGURE 2 ASSESSMENT POINT LOCATIONS

          MMWW88

          MW2MW244 WMS3WMS355

          MW2MW255

          WMS3WMS366

          WMS3WMS377

          WMS3WMS311

          MW2MW222WMS34WMS34

          MW2MW233 WMS3WMS322

          WMS3WMS333

          WMS2WMS277WMS2WMS299 WMS2WMS288

          SSV12V12 SSVV1111 MW19MW19

          MW18MW18 SSVV1133 MW2MW200 WMS3WMS300

          MW2MW211 WMS2WMS255

          WMS2WMS266

          MW17MW17 WMS2WMS244

          WMS2WMS233

          WMS2WMS222 WMS2WMS211

          SSVV99

          SSV10V10WMS2WMS200 MW14MW14MW15MW15 WMS18WMS18

          WMS19WMS19 MW16MW16

          WMS13WMS13MW10MW10 WMS14WMS14MMWW1111SVSV77WMS15WMS15SSVV88WMS16WMS16

          SVSV66WMS4WMS411MW13MW13 LEGENDMW12MW12

          WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS17WMS17 WMS40WMS40 SSVV55 MW0MW022MW9MW9 GROUNDWATER MONITORING WELL

          WMS11WMS11 WMS6WMS6 SOIL VAPOUR BORE

          WATERLOO MEMBRANE SAMPLERTM - ROUND 2

          SVSV22WMS8WMS8SVSVWMS12WMS12 44 WMS7WMS7 MW4MW4MMWW SVSV66 33 MW5MW5WMS3WMS388

          WMS3WMS399 MW7MW7 EPA ASSESSMENT AREAWMS10WMS10 WMS9WMS9

          SVSV11 CADASTRE

          MW3MW3

          MW1MW1 WMS3WMS3WMS4WMS4MW2MW266 WMS5WMS5 12500 A3

          0 25 50 m

          CLIENT

          SA EPAWMS1WMS1

          WMS2WMS2 PROJECT

          EPA THEBARTON ASSESSMENT AREA - STAGE 1

          TITLE

          FIGURE 2 ASSESSMENT POINT LOCATIONS

          PROJECT NO DATE CREATED

          80607-1 280917

          80607_Fig 2 - Assessment Point Locationsai REV 1 gt 280917

          LE

          VE

          L 1

          12

          4 S

          OU

          TH

          TE

          RR

          AC

          E

          AD

          EL

          AID

          E S

          A 5

          00

          0

          PH

          (0

          8)

          82

          32

          90

          88

          F

          AX

          (0

          8)

          82

          32

          90

          99

          E

          MA

          IL

          info

          fy

          fec

          om

          au

          W

          EB

          fy

          fec

          om

          au

          A

          BN

          5

          7 0

          08

          116

          13

          0

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          DEW

          STREET

          DEW

          STREET

          CHAPEL STREETCHAPEL STREET

          PAR

          KER

          STREET

          PAR

          KER

          STREET

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          LIGHT TERRACELIGHT TERRACE

          DEW

          STREET

          DEW

          STREET

          WA

          LSH ST

          WA

          LSH ST

          AD

          MELLA

          STREET

          AD

          MELLA

          STREET

          ALB

          ERT STR

          EETA

          LBER

          T STREET

          HO

          LLAN

          D ST

          REET

          HO

          LLAN

          D ST

          REET

          RANDOLPH STREET

          RANDOLPH STREET

          JAM

          ES STREET

          JAM

          ES STREET

          DOVE STREET

          DOVE STREET

          SMITH STREETSMITH STREET

          MARIA STREETMARIA STREET

          GEORGE STREETGEORGE STREET

          KINTORE STREET

          KINTORE STREET

          PORT ROAD

          PORT ROAD

          PORT ROAD

          PORT ROAD

          CAW

          THO

          RN

          E STR

          EETC

          AWTH

          OR

          NE ST

          REET

          DEVON STREETDEVON STREET

          KINTORE STREETKINTORE STREET

          GOODENOUGH STREETGOODENOUGH STREET

          LIVESTR

          ON

          G PATH

          WAY

          LIVESTR

          ON

          G PATH

          WAY

          WMS2WMS2WMS1WMS1

          WMS3WMS3WMS4WMS4

          WMS5WMS5

          WMS6WMS6

          WMS7WMS7WMS8WMS8

          WMS9WMS9

          WMS10WMS10

          WMS11WMS11

          WMS12WMS12

          WMS13WMS13WMS14WMS14

          WMS15WMS15 WMS41WMS41

          WMS40WMS40

          WMS39WMS39WMS38WMS38

          WMS16WMS16

          WMS17WMS17

          WMS18WMS18WMS19WMS19WMS20WMS20

          WMS21WMS21WMS22WMS22

          WMS23WMS23WMS24WMS24

          WMS25WMS25

          WMS26WMS26

          WMS27WMS27WMS28WMS28WMS29WMS29

          WMS30WMS30

          WMS31WMS31

          WMS32WMS32WMS33WMS33

          WMS34WMS34

          WMS35WMS35

          WMS36WMS36

          WMS37WMS37

          WWAA

          LLSSHHSSTT

          SSMMIITTHH SSTTRREEEETT

          RRANDOLPH S

          ANDOLPH STREETTREET

          PPOORR

          TT RROO

          AADD

          PPOORR

          TT RROO

          AADD

          CCAAWW

          TTHHOO

          RRNN

          EE SSTTRR

          EEEETT

          JJAM

          EA

          MES S

          S STREET

          TREET

          HHOO

          LLLLAANN

          DDSSTT

          RREEEETT

          DE

          DEW

          SW

          STREET

          TREET

          DDOOVVEE SSTTRREEEETT

          LLIIVVEESSTTRR

          OONN

          GGPPAATTHH

          WWAAYY

          LIGHT TERRLIGHT TERRAACECE

          AD

          MELLA

          SA

          DM

          ELLA STR

          EETTR

          EET

          AALLBB

          EERRTT SSTTRR

          EEEETT

          CHAPEL SCHAPEL STREETTREET

          GEGEORORGE SGE STREETTREET

          PPOORRTT RROOAADD PPOORRTT RROOAADD

          DDEEWW

          SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

          JJAAMM

          EESS CCOO

          NNGG

          DDOO

          NN DD

          RRIIVV

          EE

          KKIINNTTOORREE SSTTRREEEETT

          KKIINNTTOORREE SSTTRREEEETT

          PPAARR

          KKEERR

          SSTTRREEEETT

          GGOOOODDEENNOOUUGGHH SSTTRREEEETT

          DDEEVVOONN SSTTRREEEETT

          FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

          TCE CONCENTRATION PLAN

          WMS3WMS355 TCE lt78

          WMS3WMS366 TCE lt77WMS3WMS377

          TCE 44

          WMS3WMS311 TCE lt78

          WMS34WMS34 TCE 11

          WMS3WMS322WMS3WMS333 TCE lt78TCE lt79

          WMS2WMS277WMS2WMS299 WMS2WMS288 TCE 64 TCE lt77 TCE lt8

          WMS3WMS300 TCE lt8

          WMS2WMS255

          WMS2WMS266 TCE 1400(D)

          WMS2WMS222 TCE 38 WMS2WMS211

          TCE lt79

          TCE lt78

          WMS2WMS233 WMS2WMS244 TCE lt77

          TCE 230

          WMS2WMS200 WMS19WMS19TCE lt78 WMS18WMS18 TCE 11000

          TCE 4200

          WMS13WMS13 WMS14WMS14 TCE lt79

          WMS4WMS411WMS15WMS15 TCE 46000WMS16WMS16 TCE 18000 LEGENDTCE lt8

          TCE lt78WMS17WMS17 WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS40WMS40TCE lt79

          TCE 110000 WATERLOO MEMBRANE SAMPLERTM - ROUND 2WMS11WMS11

          TCE 71000WMS12WMS12 EPA ASSESSMENT AREA

          CADASTRE

          WMS6WMS6 TCE lt58 WMS8WMS8 WMS3WMS388 TCE 32WMS7WMS7WMS3WMS399

          TCE 12000 TCE 13000 TCE 1900TCE 1300WMS9WMS9 TCE lt58 NotesWMS10WMS10

          All concentrations are in μgm3 TCE lt58

          D = Duplicate result

          WMS3WMS3WMS4WMS4 12500 A3

          LE

          VE

          L 1

          12

          4 S

          OU

          TH

          TE

          RR

          AC

          E

          AD

          EL

          AID

          E S

          A 5

          00

          0

          PH

          (0

          8)

          82

          32

          90

          88

          F

          AX

          (0

          8)

          82

          32

          90

          99

          E

          MA

          IL

          info

          fy

          fec

          om

          au

          W

          EB

          fy

          fec

          om

          au

          A

          BN

          5

          7 0

          08

          116

          13

          0

          TCE lt57WMS5WMS5 TCE lt57 TCE lt58 0 25 50

          m

          CLIENT

          SA EPA

          WMS2WMS2 TCE lt56

          WMS1WMS1 TCE lt56

          PROJECT

          EPA THEBARTON ASSESSMENT AREA - STAGE 1

          TITLE

          FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

          TCE CONCENTRATION PLAN

          PROJECT NO DATE CREATED

          80607-1 241017

          80607_Fig 3 - WMS TCE Concentration Planai REV 1 gt 241017

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          DEW

          STREET

          DEW

          STREET

          CHAPEL STREETCHAPEL STREET

          PAR

          KER

          STREET

          PAR

          KER

          STREET

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          LIGHT TERRACELIGHT TERRACE

          DEW

          STREET

          DEW

          STREET

          WA

          LSH ST

          WA

          LSH ST

          AD

          MELLA

          STREET

          AD

          MELLA

          STREET

          ALB

          ERT STR

          EETA

          LBER

          T STREET

          HO

          LLAN

          D ST

          REET

          HO

          LLAN

          D ST

          REET

          RANDOLPH STREET

          RANDOLPH STREET

          JAM

          ES STREET

          JAM

          ES STREET

          DOVE STREET

          DOVE STREET

          SMITH STREETSMITH STREET

          MARIA STREETMARIA STREET

          GEORGE STREETGEORGE STREET

          KINTORE STREET

          KINTORE STREET

          PORT ROAD

          PORT ROAD

          PORT ROAD

          PORT ROAD

          CAW

          THO

          RN

          E STR

          EETC

          AWTH

          OR

          NE ST

          REET

          DEVON STREETDEVON STREET

          KINTORE STREETKINTORE STREET

          GOODENOUGH STREETGOODENOUGH STREET

          LIVESTR

          ON

          G PATH

          WAY

          LIVESTR

          ON

          G PATH

          WAY

          MW1MW1

          MW02MW02

          MW3MW3

          MW4MW4MW5MW5

          MW6MW6

          MW7MW7

          MW8MW8

          MW9MW9

          MW10MW10MW11MW11

          MW12MW12

          MW13MW13

          MW14MW14

          MW15MW15

          MW16MW16

          MW17MW17

          MW18MW18

          MW19MW19MW20MW20

          MW21MW21

          MW22MW22

          MW23MW23

          MW24MW24

          MW25MW25

          MW26MW26

          WWAA

          LLSSHHSSTT

          SSMMIITTHH SSTTRREEEETT

          4

          466

          PPOORR

          TT RROO

          AADD

          PPOORR

          TT RROO

          AADD

          RRANDOLPH S

          ANDOLPH STREETTREET 4455

          DE

          DEW

          SW

          STREET

          TREET

          JJAM

          EA

          MES S

          S STREET

          TREET

          HHOO

          LLLLAANN

          DD SSTT

          RREEEETT

          CCAAWW

          TTHHOO

          RRNN

          EE SSTTRR

          EEEETT 4477

          DDOOVVEE SSTTRREEEETT

          4455

          4488

          LLIIVVEESSTTRR

          OONN

          GGPPAATTHH

          WWAAYY

          4455

          LIGHT TERRLIGHT TERRAACECE

          AD

          MELLA

          SA

          DM

          ELLA STR

          EETTR

          EET

          4466

          CHAPEL SCHAPEL STREETTREET

          4477 AA

          LLBBEERR

          TT SSTTRREEEETT

          4499

          GR4466 OUND

          FLOW DIREW

          GEGEORORGE SGE STREETTREET ATER C

          4488 TION

          PPOORRTT RROOAADD PPOORRTT RROOAADD 55

          00 DD

          EEWW SSTTRR

          EEEETT 4499

          MMAARRIIAA SSTTRREEEETT

          4477

          5500

          JJAAMM

          EESS CCOO

          NNGG

          DDOO

          NN DD

          RRIIVV

          EE

          88 44

          KKIINNTTOORREE SSTTRREEEETT

          KKIINNTTOORREE SSTTRREEEETT

          PPAARR

          KKEERR

          SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

          5500

          4499

          DDEEVVOONN SSTTRREEEETT

          FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

          Groundwater SWL MMWW88 Monitoring Well (m AHD)

          MW1 5011 MW2MW244

          MW02 4786

          MW3 484

          MW2MW255 MW4 507

          MW5 4833

          MW6 4794

          MW7 4703

          MW8 4581

          MW9 4728

          MW10 4871

          MW11 4785 MW2MW222

          MW12 4689

          MW13 4662

          MW2MW233 MW14 4723

          MW15 464

          MW16 4577

          MW17 4619

          MW18 4538

          MW19 4735

          MW20 457

          MW21 4531

          MW22 4501

          MW23 4497

          MW24 4537

          MW25 4469

          MW26 4918

          MW19MW19 MW2MW200

          MW2MW211MW18MW18

          MW17MW17

          MW14MW14

          MW15MW15

          MW16MW16

          MW10MW10 LEGEND MMWW1111

          GROUNDWATER MONITORING WELLMW12MW12

          50 INFERRED GROUNDWATER ELEVATION CONTOUR

          MW13MW13

          MW0MW022 INFERRED GROUNDWATER FLOW DIRECTION

          EPA ASSESSMENT AREA

          MW9MW9

          MW5MW5 CADASTREMMWW66 MW4MW4

          MW7MW7 Note This is one interpretation only Other interpretations possibleMW3MW3

          12500 A3

          0 25 50 m

          CLIENT

          SA EPA

          PROJECT

          EPA THEBARTON ASSESSMENT AREA - STAGE 1

          TITLE

          FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

          PROJECT NO DATE CREATED

          80607-1 290917

          MW1MW1 MW2MW266

          80607_Fig 4 - Groundwater Elevation Contour Planai REV 1 gt 290917

          LE

          VE

          L 1

          12

          4 S

          OU

          TH

          TE

          RR

          AC

          E

          AD

          EL

          AID

          E S

          A 5

          00

          0

          PH

          (0

          8)

          82

          32

          90

          88

          F

          AX

          (0

          8)

          82

          32

          90

          99

          E

          MA

          IL

          info

          fy

          fec

          om

          au

          W

          EB

          fy

          fec

          om

          au

          A

          BN

          5

          7 0

          08

          116

          13

          0

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          DEW

          STREET

          DEW

          STREET

          CHAPEL STREETCHAPEL STREET

          PAR

          KER

          STREET

          PAR

          KER

          STREET

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          LIGHT TERRACELIGHT TERRACE

          DEW

          STREET

          DEW

          STREET

          WA

          LSH ST

          WA

          LSH ST

          AD

          MELLA

          STREET

          AD

          MELLA

          STREET

          ALB

          ERT STR

          EETA

          LBER

          T STREET

          HO

          LLAN

          D ST

          REET

          HO

          LLAN

          D ST

          REET

          RANDOLPH STREET

          RANDOLPH STREET

          JAM

          ES STREET

          JAM

          ES STREET

          DOVE STREET

          DOVE STREET

          SMITH STREETSMITH STREET

          MARIA STREETMARIA STREET

          GEORGE STREETGEORGE STREET

          KINTORE STREET

          KINTORE STREET

          PORT ROAD

          PORT ROAD

          PORT ROAD

          PORT ROAD

          CAW

          THO

          RN

          E STR

          EETC

          AWTH

          OR

          NE ST

          REET

          DEVON STREETDEVON STREET

          KINTORE STREETKINTORE STREET

          GOODENOUGH STREETGOODENOUGH STREET

          LIVESTR

          ON

          G PATH

          WAY

          LIVESTR

          ON

          G PATH

          WAY

          MW1MW1

          MW02MW02

          MW3MW3

          MW4MW4

          MW5MW5

          MW6MW6

          MW7MW7

          MW8MW8

          MW9MW9

          MW10MW10MW11MW11

          MW12MW12

          MW13MW13

          MW14MW14

          MW15MW15

          MW16MW16

          MW17MW17

          MW18MW18

          MW19MW19MW20MW20

          MW21MW21

          MW22MW22

          MW23MW23

          MW24MW24

          MW25MW25

          MW26MW26

          WWAA

          LLSSHHSSTT

          SSMMIITTHH SSTTRREEEETT

          ndnd

          RRANDOLPH S

          ANDOLPH STREETTREET

          PPOORR

          TTRR

          OOAA

          DD

          PPOORR

          TTRR

          OOAA

          DD

          JJAM

          EA

          MES S

          S STREET

          TREET

          HHOO

          LLLLAANN

          DDSSTT

          RREEEETT

          CCAAWW

          TTHHOO

          RRNN

          EESSTT

          RREEEETT

          DE

          DEW

          SW

          STREET

          TREET

          DDOOVVEE SSTTRREEEETT

          LLIIVVEESSTTRR

          OONN

          GGPPAATTHH

          WWAAYY

          LIGHT TERRLIGHT TERRAACECE

          AD

          MELLA

          SA

          DM

          ELLA STR

          EETTR

          EET

          AALLBB

          EERRTT SSTTRR

          EEEETT

          CHAPEL SCHAPEL STREETTREET

          ndnd ndnd

          100100

          11000000

          GEGEORORGE SGE STREETTREET

          1010000000

          PPOORRTT RROOAADD PPOORRTT RROOAADD

          DDEEWW

          SSTTRREEEETT

          1010000000 11000000 MMAARRIIAA SSTTRREEEETT

          100100

          JJAAMM

          EESSCC

          OONN

          GGDD

          OONN

          DDRR

          IIVVEE

          KKIINNTTOORREE SSTTRREEEETT ndnd

          KKIINNTTOORREE SSTTRREEEETT

          PPAARR

          KKEERR

          SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

          DDEEVVOONN SSTTRREEEETT

          FIGURE 5 GROUNDWATER CONCENTRATION PLAN

          MW2MW244

          MMWW88 TCE lt1

          PCE lt1

          11-DCE lt1TCE lt1

          12-DCE lt1PCE lt1

          11-DCE lt1MW2MW255 12-DCE lt1

          TCE 2

          PCE lt1

          11-DCE lt1

          12-DCE lt1

          MW2MW222 TCE lt1

          PCE lt1

          11-DCE lt1MW2MW233 12-DCE lt1

          TCE 21

          PCE lt1

          11-DCE lt1

          12-DCE lt1

          MW19MW19 TCE lt1

          MW2MW200 TCE 70 PCE lt1MW2MW211 PCE lt1MW18MW18 11-DCE lt1

          TCE 23 11-DCE lt1TCE 5 12-DCE lt1 PCE lt1 12-DCE lt1PCE lt1 11-DCE lt1

          11-DCE lt1 12-DCE lt1

          12-DCE lt1

          MW17MW17 LEGENDTCE 24 MW14MW14

          PCE lt1 TCE 1100 lt1 MW15MW15 GROUNDWATER MONITORING WELL11-DCE PCE lt1

          12-DCE lt1 TCE 180 11-DCE 2MW16MW16 100 INFERRED TCE GROUNDWATERPCE lt1 12-DCE 4 CONCENTRATION CONTOURSTCE lt1 11-DCE lt1 PCE lt1 12-DCE lt1 11-DCE lt1

          12-DCE lt1 MMWW1111

          EPA ASSESSMENT AREAMW10MW10

          TCE lt1 CADASTREMW12MW12 TCE lt14900 PCE

          lt1 11-DCE lt1TCE 700 PCEMW13MW13 12-DCE lt1 TCE CONCENTRATIONS (μgL)lt1 11-DCE 7PCE

          TCE lt1 lt1 12-DCE 511-DCE gtnd to lt100 100 to lt1000 1000 to lt10000

          MW0MW022PCE lt1 12-DCE lt1 2100011-DCE lt1 MW9MW9 TCE

          PCE lt112-DCE lt1 TCE 2(D) 11-DCE 15PCE lt1 MW5MW5

          10000 to 29000

          nd = non-detect (lt1)12-DCE 4511-DCE lt1 MMWW66 TCE 29000 MW4MW4 12-DCE lt1

          PCE 3 TCE lt1 NotesTCE 29 11-DCE 6MW7MW7 PCE lt1PCE lt1 This is one interpretation only Other interpretations possible12-DCE 23TCE lt1 11-DCE lt111-DCE lt1 All concentrations are in μgL

          12-DCE includes cis and trans PCE lt1 MW3MW3 12-DCE lt112-DCE lt1 11-DCE lt1

          TCE 69 D = Duplicate result12-DCE lt1 PCE lt1

          11-DCE lt1

          12-DCE lt1 MW1MW1

          12500 A3MW2MW266 TCE lt1

          TCE 2 PCE lt1

          PCE lt1 11-DCE lt1

          11-DCE lt1 12-DCE lt1

          12-DCE lt1

          LE

          VE

          L 1

          12

          4 S

          OU

          TH

          TE

          RR

          AC

          E

          AD

          EL

          AID

          E S

          A 5

          00

          0

          PH

          (0

          8)

          82

          32

          90

          88

          F

          AX

          (0

          8)

          82

          32

          90

          99

          E

          MA

          IL

          info

          fy

          fec

          om

          au

          W

          EB

          fy

          fec

          om

          au

          A

          BN

          5

          7 0

          08

          116

          13

          0

          0 25 50 m

          CLIENT

          SA EPA

          PROJECT

          EPA THEBARTON ASSESSMENT AREA - STAGE 1

          TITLE

          FIGURE 5 GROUNDWATER CONCENTRATION PLAN

          PROJECT NO DATE CREATED

          80607-1 280917

          80607_Fig 5 - Groundwater TCE Concentration Plan r2ai REV 2 gt 280917

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          DEW

          STREET

          DEW

          STREET

          CHAPEL STREETCHAPEL STREET

          PAR

          KER

          STREET

          PAR

          KER

          STREET

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          LIGHT TERRACELIGHT TERRACE

          DEW

          STREET

          DEW

          STREET

          WA

          LSH ST

          WA

          LSH ST

          AD

          MELLA

          STREET

          AD

          MELLA

          STREET

          ALB

          ERT STR

          EETA

          LBER

          T STREET

          HO

          LLAN

          D ST

          REET

          HO

          LLAN

          D ST

          REET

          RANDOLPH STREET

          RANDOLPH STREET

          JAM

          ES STREET

          JAM

          ES STREET

          DOVE STREET

          DOVE STREET

          SMITH STREETSMITH STREET

          MARIA STREETMARIA STREET

          GEORGE STREETGEORGE STREET

          KINTORE STREET

          KINTORE STREET

          PORT ROAD

          PORT ROAD

          PORT ROAD

          PORT ROAD

          CAW

          THO

          RN

          E STR

          EETC

          AWTH

          OR

          NE ST

          REET

          DEVON STREETDEVON STREET

          KINTORE STREETKINTORE STREET

          GOODENOUGH STREETGOODENOUGH STREET

          LIVESTR

          ON

          G PATH

          WAY

          LIVESTR

          ON

          G PATH

          WAY

          SV1SV1

          SV2SV2SV3SV3SV4SV4

          SV5SV5

          SV7SV7SV8SV8

          SV9SV9

          SV10SV10

          SV11SV11SV12SV12

          SV13SV13

          SV6SV6

          WWAA

          LLSSHHSSTT

          SSMMIITTHH SSTTRREEEETT

          RRANDOLPH S

          ANDOLPH STREETTREET

          PPOORR

          TTRR

          OOAA

          DD

          PPOORR

          TTRR

          OOAA

          DD

          CCAAWW

          TTHHOO

          RRNN

          EESSTT

          RREEEETT

          HHOO

          LLLLAANN

          DDSSTT

          RREEEETT

          JJAM

          EA

          MES S

          S STREET

          TREET

          DE

          DEW

          SW

          STREET

          TREET

          DDOOVVEE SSTTRREEEETT

          00

          LLIIVVEESSTTRR

          OONN

          GGPPAATTHH

          WWAAYY

          LIGHT TERRLIGHT TERRAACECE

          AD

          MELLA

          SA

          DM

          ELLA STR

          EETTR

          EET

          CHAPEL SCHAPEL STREETTREET

          00

          AALLBB

          EERRTT SSTTRR

          EEEETT

          1010

          GEGEORORGE SGE STREETTREET

          000000

          PPOORRTT RROOAADD

          100100000

          000

          1010

          PPOORRTT RROOAADD

          000000

          DDEEWW

          SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

          JJAAMM

          EESSCC

          OONN

          GGDD

          OONN

          DDRR

          IIVVEE

          KKIINNTTOORREE SSTTRREEEETT 00

          KKIINNTTOORREE SSTTRREEEETT

          PPAARR

          KKEERR

          SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

          DDEEVVOONN SSTTRREEEETT

          FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

          SSVV1111 SSV12V12 TCE lt18

          SSVV1133 TCE 16

          PCE lt54 TCE lt21

          11-DCE lt29 PCE lt25

          12-DCE lt39 11-DCE lt14

          12-DCE lt18

          PCE lt22

          11-DCE lt12

          12-DCE lt16

          TCE 170

          PCE lt54

          11-DCE lt3

          12-DCE lt39 LEGEND SSVV99

          SSV10V10 SOIL VAPOUR BORE

          TCE lt21 0 INFERRED TCE SOIL VAPOUR CONTOUR PCE lt25

          TCE 2200011-DCE lt14 EPA ASSESSMENT AREA

          PCE 1912-DCE lt18

          11-DCE lt27 CADASTRE

          12-DCE lt37 SVSV66SVSV77

          SSVV88 TCE 22000

          TCE 2300 PCE 12 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)TCE 100000 PCE 62 11-DCE lt29PCE 84 0 to lt10000SSVV55lt2711-DCE 12-DCE lt2911-DCE lt33 10000 to lt100000

          100000 to 210000 12-DCE lt36 12-DCE lt44

          TCE 17000 SVSV44 SVSV22SVSV33 NotePCE 31 TCE 51000TCE 210000 This is one interpretation only Other interpretations possible11-DCE lt14 PCE 39PCE 650012-DCE lt18 39 Estimated extent of plume has utilised groundwater11-DCE11-DCE 5900 12-DCE 21 concentration data12-DCE lt71

          SVSV11 All concentrations are in (μgmsup3)

          TCE 6300(LD) 12-DCE includes cis and trans PCE 78 LD = Laboratory duplicate result 11-DCE lt29

          12-DCE lt38

          12500 A3

          0 25 50 m

          CLIENT

          SA EPA

          PROJECT

          EPA THEBARTON ASSESSMENT AREA - STAGE 1

          TITLE

          FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

          PROJECT NO DATE CREATED

          80607-1 290917

          80607_Fig 6 - Soil Vapour TCE Concentration Plan - 1mai REV 2 gt 290917

          LE

          VE

          L 1

          12

          4 S

          OU

          TH

          TE

          RR

          AC

          E

          AD

          EL

          AID

          E S

          A 5

          00

          0

          PH

          (0

          8)

          82

          32

          90

          88

          F

          AX

          (0

          8)

          82

          32

          90

          99

          E

          MA

          IL

          info

          fy

          fec

          om

          au

          W

          EB

          fy

          fec

          om

          au

          A

          BN

          5

          7 0

          08

          116

          13

          0

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          JAM

          ES CO

          NG

          DO

          N D

          RIV

          E

          DEW

          STREET

          DEW

          STREET

          CHAPEL STREETCHAPEL STREET

          PAR

          KER

          STREET

          PAR

          KER

          STREET

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          POR

          T RO

          AD

          LIGHT TERRACELIGHT TERRACE

          DEW

          STREET

          DEW

          STREET

          WA

          LSH ST

          WA

          LSH ST

          AD

          MELLA

          STREET

          AD

          MELLA

          STREET

          ALB

          ERT STR

          EETA

          LBER

          T STREET

          HO

          LLAN

          D ST

          REET

          HO

          LLAN

          D ST

          REET

          RANDOLPH STREET

          RANDOLPH STREET

          JAM

          ES STREET

          JAM

          ES STREET

          DOVE STREET

          DOVE STREET

          SMITH STREETSMITH STREET

          MARIA STREETMARIA STREET

          GEORGE STREETGEORGE STREET

          KINTORE STREET

          KINTORE STREET

          PORT ROAD

          PORT ROAD

          PORT ROAD

          PORT ROAD

          CAW

          THO

          RN

          E STR

          EETC

          AWTH

          OR

          NE ST

          REET

          DEVON STREETDEVON STREET

          KINTORE STREETKINTORE STREET

          GOODENOUGH STREETGOODENOUGH STREET

          LIVESTR

          ON

          G PATH

          WAY

          LIVESTR

          ON

          G PATH

          WAY

          SV1SV1

          SV2SV2SV3SV3SV4SV4

          SV5SV5

          SV7SV7SV8SV8

          SV9SV9

          SV10SV10

          SV12SV12

          SV6SV6

          WWAA

          LLSSHHSSTT

          SSMMIITTHH SSTTRREEEETT

          RRANDOLPH S

          ANDOLPH STREETTREET

          PPOORR

          TTRR

          OOAA

          DD

          PPOORR

          TTRR

          OOAA

          DD

          CCAAWW

          TTHHOO

          RRNN

          EESSTT

          RREEEETT

          HHOO

          LLLLAANN

          DDSSTT

          RREEEETT

          DE

          DEW

          SW

          STREET

          TREET

          JJAM

          EA

          MES S

          S STREET

          TREET

          DDOOVVEE SSTTRREEEETT

          00

          LIGHT TERRLIGHT TERRAACECE

          LLIIVVEESSTTRR

          OONN

          GGPPAATTHH

          WWAAYY

          AD

          MELLA

          SA

          DM

          ELLA STR

          EETTR

          EET

          CHAPEL SCHAPEL STREETTREET

          00

          1010000000

          AALLBB

          EERRTT SSTTRR

          EEEETT

          100100 000

          000 GEGEORORGE SGE STREETTREET

          PPOORRTT RROOAADD 11000000000

          000 PPOORRTT RROOAADD

          DDEEWW

          SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

          100100000000

          JJAAMM

          EESSCC

          OONN

          GGDD

          OONN

          DDRR

          IIVVEE

          1010000000

          KKIINNTTOORREE SSTTRREEEETT

          00

          KKIINNTTOORREE SSTTRREEEETT

          PPAARR

          KKEERR

          SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

          DDEEVVOONN SSTTRREEEETT

          FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

          SSV12V12 TCE 55

          PCE lt45

          11-DCE lt24

          12-DCE lt32

          TCE 260

          PCE lt51

          11-DCE lt28

          12-DCE

          SSVV99

          lt37 LEGEND

          SSV10V10 SOIL VAPOUR BORE

          TCE 51 0 INFERRED TCE SOIL VAPOUR CONTOURPCE lt53

          TCE 11000011-DCE lt29

          EPA ASSESSMENT AREAPCE lt13012-DCE lt39

          11-DCE lt69

          CADASTRE12-DCE lt92 SVSV66SVSV77

          SSVV88 TCE 150000

          TCE 14000 56 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)PCETCE 160000 PCE 19 11-DCE lt30PCE 310 0 to lt10000SSVV5511-DCE lt26 12-DCE lt3911-DCE 33 10000 to lt100000

          100000 to lt1000000 1000000

          12-DCE lt35 12-DCE 20

          TCE 43000 SVSV44 SVSV22SVSV33 NotePCE 90 TCE 940000(FD)TCE 1000000 This is one interpretation only Other interpretations possible11-DCE lt15 PCE 15000PCE 1500012-DCE 30 14000 Estimated extent of plume has utilised groundwater11-DCE11-DCE 14000 12-DCE lt930 concentration data12-DCE lt930

          All concentrations are in (μgmsup3) 12-DCE includes cis and trans

          SVSV11 TCE 21000

          FD = Field Duplicate resultPCE 21

          11-DCE lt57

          12-DCE lt76

          12500 A3

          0 25 50 m

          CLIENT

          SA EPA

          PROJECT

          EPA THEBARTON ASSESSMENT AREA - STAGE 1

          TITLE

          FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

          PROJECT NO DATE CREATED

          80607-1 290917

          80607_Fig 7 - Soil Vapour TCE Concentration Plan - 3m r2ai REV 2 gt 290917

          LE

          VE

          L 1

          12

          4 S

          OU

          TH

          TE

          RR

          AC

          E

          AD

          EL

          AID

          E S

          A 5

          00

          0

          PH

          (0

          8)

          82

          32

          90

          88

          F

          AX

          (0

          8)

          82

          32

          90

          99

          E

          MA

          IL

          info

          fy

          fec

          om

          au

          W

          EB

          fy

          fec

          om

          au

          A

          BN

          5

          7 0

          08

          116

          13

          0

          • THEBARTON ASSESSMENT AREA STAGE 1 ENVIRONMENTAL ASSESSMENT FINAL REPORT | EPA REF 0524111 30 OCTOBER 2017 VOLUME 1 REPORT13
          • This report is formatted to print Double Sided
          • TITLE PAGE13
          • CONTENTS13
          • LIST OF ACRONYMS13
          • EXECUTIVE SUMMARY13
          • 1 INTRODUCTION
            • 11 Purpose
            • 12 General background information
            • 13 Definition of the assessment area
            • 14 Identification of contaminants of potential concern
            • 15 Objectives
              • 2 CHARACTERISATION OF THE ASSESSMENT AREA
                • 21 Site identification
                • 22 Regional geology and hydrogeology
                • 23 Data quality objectives
                  • 3 SCOPE OF WORK
                    • 31 Preliminary work
                    • 32 Field investigation and laboratory analysis program
                    • 33 Data interpretation
                      • 4 METHODOLOGY
                        • 41 Field methodologies
                        • 42 Laboratory analysis
                          • 5 QUALITY ASSURANCE AND QUALITY CONTROL
                            • 51 Field QAQC
                            • 52 Laboratory QAQC
                            • 53 QAQC summary
                              • 6 ASSESSMENT CRITERIA
                                • 61 Groundwater
                                • 62 Soil vapour
                                  • 7 RESULTS
                                    • 71 Surface and sub surface soil conditions
                                    • 72 Waterloo Membrane Samplerstrade
                                    • 73 Groundwater
                                    • 74 Soil vapour bores
                                      • 8 GROUNDWATER FATE AND TRANSPORT MODELLING
                                        • 81 Groundwater flow modelling
                                        • 82 Solute transport modelling
                                          • 9 VAPOUR INTRUSION RISK ASSESSMENT
                                            • 91 Objective
                                            • 92 Areas of interest
                                            • 93 Risk assessment approach
                                            • 94 Tier 1 assessment
                                            • 95 Tier 2 assessment
                                            • 96 Conclusions
                                              • 10 CONCEPTUAL SITE MODEL
                                              • 11 CONCLUSIONS
                                              • 12 DATA GAPS
                                              • 13 REFERENCES
                                              • 14 STATEMENT OF LIMITATIONS
                                              • FIGURES13
                                              • FIGURE 1 SITE LOCATION AND ASSESSMENT AREA
                                              • FIGURE 2 ASSESSMENT POINT LOCATIONS
                                              • FIGURE 3 WATERLOO MEMBRANE SAMPLERTM TCE CONCENTRATION PLAN13
                                              • FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN
                                              • FIGURE 5 GROUNDWATER CONCENTRATION PLAN
                                              • FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)
                                              • FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            LIST OF TABLES

            Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area 7

            Table 22 Data Quality Objectives 8 Table 31 Scope of field investigation program ndash May to August 2017 12 Table 32 Scope of laboratory testing program 13 Table 41 Summary of field methodologies 15 Table 51 Field QAQC procedures ndash Groundwater 22 Table 52 Field QAQC procedures ndash Soil vapour 23 Table 53 Laboratory QAQC procedures 25 Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area 28 Table 62 Sources of adopted groundwater assessment criteria 29 Table 71 Detectable Waterloo Membrane Samplertrade CHC results 32 Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units 33 Table 73 Hydraulic conductivities (rising and falling head tests) 35 Table 74 Detectable groundwater CHC results 37 Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area 41 Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores 42 Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs 49 Table 92 Tier 2 vapour intrusion modelling ndash building input parameters 51 Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters 52 Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air 52 Table 95 Summary of chemical parameters adopted for vapour intrusion modelling 52 Table 96 Comparison of predicted residential indoor air concentrations with SA EPA

            response levels 54 Table 97 Summary of model input parameters subjected to sensitivity analysis 55 Table 98 Exposure parameters ndash Commercialindustrial workers 58 Table 99 Adopted inhalation toxicity reference values 58 Table 910 Summary of properties with predicted indoor air concentrations

            (residential crawl space) above adopted EPA response levels 59 Table 101 Summary of existing information for the Thebarton EPA Assessment Area 61

            LIST OF FIGURES (in text)

            Figure 71 Piper diagram 39 Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green)

            relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple) 46

            Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels 50

            80607-1 REV1 30102017 PAGE III

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            FIGURES follow page 79

            Figure 1 Site Location and Assessment Area Figure 2 Assessment Point Locations Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan Figure 4 Groundwater Elevation Contour Plan Figure 5 Groundwater Concentration Plan Figure 6 Soil Vapour Concentration Plan (10 m) Figure 7 Soil Vapour Concentration Plan (30 m)

            VOLUME 2 APPENDICES

            APPENDICES

            Appendix A Historical Report Summary Appendix B Historical Information Supplied by the EPA Appendix C DEWNR Registered Groundwater Database Search Results Appendix D Groundwater Well Permits Appendix E Field Sampling Sheets ndash Groundwater Appendix F Survey Data Appendix G Certified Laboratory Certificates and Chain of Custody Documentation Appendix H Groundwater Well Log Reports Appendix I WMStrade Borehole Log Reports Appendix J Soil Vapour Borehole Log Reports Appendix K Waste Transport Certificates Appendix L Tabulated Results ndash Soil Vapour Geotechnical and Groundwater Appendix M Equipment Calibration Records Appendix N Drill Core Photographs Appendix O Arcadis Groundwater Fate and Transport Modelling Report Appendix P Arcadis Vapour Intrusion Risk Assessment Report

            PAGE IV 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            LIST OF ACRONYMS

            AER Air Exchange Rate

            AF Attenuation Factor

            AHD Australian Height Datum

            ANZECC Australian and New Zealand Environment and Conservation Council

            ARMCANZ Agriculture and Resource Management Council of Australia and New Zealand

            ASC Assessment of Site Contamination

            ASTM American Standard Testing Material

            AT Averaging Time

            ATSDR Agency for Toxic Substances and Disease Registry

            AWQC Australian Water Quality Centre

            BGL Below Ground Level

            BTEX Benzene Toluene Ethylbenzene Xylenes

            BTOC Below Top of Casing

            BUA Beneficial Use Assessment

            CBD Central Business District

            CHC Chlorinated Hydrocarbon Compound

            COC Chain of Custody

            COPC Contaminants of Potential Concern

            CRC CARE Cooperative Research Centre for Contamination Assessment and Remediation of the Environment

            CSM Conceptual Site Model

            11-DCA 11-dichloroethane

            11-DCE 11-dichloroethene

            12-DCE 12-dichloroethene

            DCE Dichloroethene

            DEC Department of Environment and Conservation

            DEWNR Department of Environment Water and Natural Resources

            DNAPL Dense Non-Aqueous Phase Liquid

            DO Dissolved Oxygen

            DQI Data Quality Indicator

            DQO Data Quality Objective

            EC Electrical Conductivity

            ED Exposure Duration

            80607-1 REV1 30102017 PAGE V

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            EF Exposure Frequency

            EMP Environmental Management Plan

            EPA Environment Protection Authority

            EPC Exposure Point Concentration

            EPP Environment Protection Policy

            ET Exposure Time

            GPA Groundwater Prohibition Area

            GPR Ground Penetrating Radar

            GPS Global Positioning System

            HHRA Human Health Risk Assessment

            HIL Health Investigation Level

            HSP Health and safety Plan

            IPA Isopropyl Alcohol (isopropanol or 2-propanol)

            IRIS Integrated Risk Information System

            ITRC Interstate Technology and Regulatory Council

            JampE Johnson and Ettinger

            JHA Job Hazard Analysis

            LNAPL Light Non-Aqueous Phase Liquid

            LOR Limit of Reporting

            MGA Map Grid of Australia

            MQO Measuring Quality Objectives

            MTC Mass Transfer Co-efficient

            NA Not Applicable

            NAPL Non-Aqueous Phase Liquid

            NATA National Association of Testing Authorities

            ND Non Detect

            NEPM National Environment Protection Measure

            NHMRC National Health and Medical Research Council

            NJDEP New Jersey Department of Environmental Protection

            NRMMC National Resource Management Ministerial Council

            PAH Polycyclic Aromatic Hydrocarbons

            PCE Tetrachloroethene (perchloroethylene)

            PID Photoionisation Detector

            PQL Practical Quantification Limit

            PSD Particle Size Distribution

            QA Quality Assurance

            80607-1 REV1 30102017 PAGE VI

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            QC Quality Control

            RAIS Risk Assessment Information System

            RFQ Request for Quote

            REM Resource and Environmental Management

            RPD Relative Percentage Difference

            RSL Regional Screening Level

            SA EPA South Australian Environment Protection Authority

            SAQP Sampling and Analysis Quality Plan

            SOP Standard Operating Procedure

            SVOC Semi-Volatile Organic Compound

            SWL Standing Water Level

            SWMS Safe Work Method Statement

            111-TCA 111-trichloroethane

            TCE Trichloroethene

            TDS Total Dissolved Solids

            TRH Total Recoverable Hydrocarbons1

            TRV Toxicity Reference Value

            US EPA United Stated Environment Protection Agency

            USGS United States Geological Survey

            VC Vinyl Chloride

            VIRA Vapour Intrusion Risk Assessment

            VOC Volatile Organic Compound

            VOCC Volatile Organic Chlorinated Compound

            WHO World Health Organisation

            WMStrade Waterloo Membrane Samplertrade

            TRH = measurable amount of petroleum-based hydrocarbon (ie complex mixture of crude oil and natural gas (gt 250 compounds) including aromatics aliphatics paraffins unsaturated alkanes and naphthalenes) plus various other compounds including fatty acids esters humic acids phthalates and sterols

            80607-1 REV1 30102017 PAGE VII

            1

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            EXECUTIVE SUMMARY

            Background information

            An approximate 27 hectare mixed use area of Thebarton has been designated by the South Australian Environment Protection Authority (EPA) as the Thebarton EPA Assessment Area

            The former Austral sheet metal works (Austral) property located over multiple allotments between George and Maria Streets from the 1920s until the 1960s-1970s has been identified as a possible source of dissolved phase groundwater chlorinated hydrocarbon (CHC) contamination Groundwater CHC impacts within the uppermost (Quaternary ndash Q1) aquifer were identified as extending in a general north-westerly direction (consistent with regional groundwater flow direction) from the south-eastern portion of the Thebarton EPA Assessment Area and having resulted in the generation of soil vapour containing elevated concentrations of CHC

            The boundaries of the Thebarton EPA Assessment Area were established on the basis of the following

            the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street (part of the former Austral property) and 39 Smith Street (hydraulically down-gradient of the former Austral property) in Thebarton

            the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

            the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

            Key objectives

            The results of the recent investigations undertaken by Fyfe have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties within the Thebarton EPA Assessment Area

            The key objectives detailed by the EPA were to

            further delineate the chlorinated hydrocarbon contamination in groundwater

            further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

            undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

            80607-1 REV1 30102017 PAGE VIII

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            With respect to the VIRA the EPA requested that there be specific consideration of

            residential properties (slab on grade)

            residential properties (crawl space)

            residential properties (with basement) and

            trenchmaintenanceutility workers that may be working in the vicinity of the contamination

            Site conditions

            Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were identified within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m below ground level (BGL) during the drilling of groundwater well MW17 the latter consistent with the depth of groundwater within the Q1 aquifer

            Soil

            Groundwater within the Q1 aquifer is located at a depth of approximately 123 to Groundwater 159 m BGL and flows in a general north-westerly direction The closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred and the groundwater gradient is relatively flat (ie 000062 to 00012)

            Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified (based on factors such a groundwater salinity registered bore use and the locations of potential sensitive receptors) as including domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux) and possibly also potable

            Contaminants of Potential Concern (COPC)

            The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans-) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

            80607-1 REV1 30102017 PAGE IX

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Scope of work

            A groundwater and soil vapour monitoring program was undertaken by Fyfe across the Thebarton EPA Assessment Area between May and August 2017 It involved the following scope of work

            installation of a total of 41 WMStrade units to 1 m BGL in an approximate grid-pattern across the entire assessment area (Round 1) and at specific targeted locations (Round 2) followed by laboratory analysis of retrieved sample units for specific CHC

            drilling and installation of 25 groundwater wells to depths of between 15 and 19 m BGL including a background well to the east of the southern portion of the assessment area

            testing of 30 selected groundwater well drill core samples for geotechnical parameters

            gauging and sampling of the 25 newly installed groundwater wells as well as an existing well located in Admella Street followed by laboratory analysis of all samples for specific CHC and 10 selected samples for major cationsanions natural attenuation parameters and additional nutrients

            aquifer permeability (rising and falling head ldquoslugrdquo) testing of 10 groundwater wells

            drilling and installation of 13 soil vapour bores including 11 nested bores (ie to 1 and 3 m BGL) and two bores to 1 m BGL and

            sampling of all soil vapour bores followed by laboratory analysis of samples for specific CHC and general gases

            The soil vapour data were used to undertake a VIRA aimed at predicting indoor air concentrations of TCE under various land use and building construction scenarios In order to validate the results of the modelling which includes a number of conservative assumptions and is therefore expected to over-estimate potential risk the EPA has commissioned indoor air monitoring in a number of residential properties within the Thebarton EPA Assessment Area ndash the indoor air monitoring results will be reported under separate cover

            Groundwater fate and transport modelling was undertaken to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton EPA Assessment Area The provision of this information is aimed at supporting the definition (extent and geometry) of a potential future Groundwater Prohibition Area (GPA) to be designated by the EPA in accordance with the provisions of Section S103S of the Environment Protection Act 1993

            80607-1 REV1 30102017 PAGE X

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Identified impacts

            Contaminants identified in the Q1 aquifer beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down

            Groundwater

            (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested

            The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected (Austral) source site in accordance with the predominant flow direction associated with the Q1 aquifer The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) ndash whereas its north-western extent has not yet been determined the groundwater CHC plume has been delineated in all other directions

            Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion

            Soil vapour

            The soil vapour samples with the maximum TCE concentrations also had the highest PCE and 11-DCE concentrations (or elevated laboratory limits of reporting (LOR)) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-)

            Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE exceeded the adopted health investigation levels (HILs) for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE degradation has not yet resulted in its production

            Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

            80607-1 REV1 30102017 PAGE XI

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Assessment of risk

            Measured concentrations of TCE exceeded the adopted assessment criteria for potable use andor primary contact recreation in wells located on Admella Maria George Albert Chapel and Dew Streets as well as Light Terrace ndash with the highest concentrations corresponding to the ldquocorerdquo area of the plume One well on Albert Street also contained a concentration of carbon tetrachloride that exceeded the respective potable criterion

            Groundwater risks

            Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous

            Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

            The groundwater modelling undertaken by Arcadis involved the development of an Groundwater fate and transport initial groundwater flow model using MODFLOW followed by the development of a modelling site-specific (three-dimensional) solute transport model using the MT3DMS transport

            code

            The results of this modelling were interpreted to indicate the following

            although scattered detectable concentrations of 12-DCE have been measured in groundwater across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE daughter products indicate that substantial dechlorination is not occurring and

            the dissolved phase groundwater TCE plume is predicted to extend by another 500 m (ie beyond the boundaries of the current Thebarton EPA Assessment Area) over the next 100 years whereas no significant lateral plume expansion is expected

            The VIRA undertaken by Arcadis involved a two-tier assessment approach Whereas Vapour intrusion the Tier 1 screening risk assessment compared the measured soil vapour CHC concentrations to (modified) guideline values the Tier 2 risk assessment involved the application of the Johnson and Ettinger vapour intrusion model to predict indoor air CHC concentrations for residential (slab on grade crawl space and basement construction) and commercialindustrial (slab on grade construction) properties across the assessment area Site-specific geotechnical parameters and soil vapour data collected from 1 and 3 m BGL throughout the Thebarton EPA Assessment Area were used in the modelling It should be noted that overall the vapour modelling

            risks

            80607-1 REV1 30102017 PAGE XII

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

            The results of the VIRA with respect to the predicted indoor air concentrations of TCE within residential properties (assuming crawl space construction) versus adopted EPA response levels indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air that require further action as follows

            10 properties within the investigation range (2 to lt20 microgm3)

            eight properties within the intervention range (20 to lt200 microgm3) and

            three properties within accelerated intervention range (ge200 microgm3)

            All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises

            Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which is expected to be overly-conservative) ndash these results will be documented in a subsequent report

            Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie as determined for the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

            A qualitative assessment of potential risks to subsurface trenchmaintenanceutility workers indicated that exposure management may be required in areas where TCE concentrations at 1 m BGL are above 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific health and safety plan (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a photoionisation detector (PID) unit providing increased ventilation and using appropriate personal protective equipment (eg gas masks) as required

            80607-1 REV1 30102017 PAGE XIII

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Data gaps

            Based on the results obtained during the recent Fyfe investigations as well as available historical information the following data gaps have been identified for the Thebarton EPA Assessment Area

            property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

            groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

            the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

            the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

            Notes ie the interim soil vapour HILs adopted from the National Environment (Assessment of Site Contamination) Measure 1999 (as revised in 2013 ndash ie the ASC NEPM (1999)) but assuming a sub-slab to indoor air attenuation factor of 003 as compared to the value of 01 adopted by the ASC NEPM (1999)

            80607-1 REV1 30102017 PAGE XIV

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            1 INTRODUCTION

            11 Purpose

            Fyfe Pty Ltd (Fyfe) was commissioned by the South Australian Environment Protection Authority (SA EPA referred to herein as the EPA) to undertake Stage 1 groundwater and soil vapour investigation works groundwater fate and transport modelling and a human health vapour intrusion risk assessment (VIRA) within an EPA designated assessment area located within Thebarton South Australia (herein referred to as the Thebarton EPA Assessment Area) The location and extent of the Thebarton EPA Assessment Area referenced within this document is identified on Figure 1

            12 General background information

            Previous environmental assessment work undertaken since 1994 (as summarised in Appendix A) combined with historical information provided by the EPA (as included in Appendix B) indicates that the Thebarton EPA Assessment Area has been used for mixed residential and commercialindustrial purposes over time

            Groundwater impacts2 identified within the uppermost (Quaternary ndash Q1) aquifer in the vicinity of the former Austral sheet metal works (Austral) on George Street included both petroleum hydrocarbons (ie diesel fuel) as well as chlorinated hydrocarbon compounds (CHC) such as trichloroethene (TCE) and were first notified to the EPA in 2006

            Available historical information for the Austral property (ie the suspected source site) indicates that it operated from the 1920s until the 1960s-1970s and occupied an extensive area of Thebarton including

            part of the southern side of George Street extending from about half way between East Terrace3 and Admella Street (ie 11-25 George Street) to the west of Admella Street (ie 31-35 George Street)

            the entire northern side of Maria Street from East Terrace to the west of Admella Street

            part of the southern side of Maria Street (ie from 21 Maria Street) to Admella Street and

            25-27 East Terrace

            2 Note that the term ldquoimpactrdquo has been used by Fyfe to indicate identified concentrations of compounds (specifically chlorinated hydrocarbons) that are not naturally occurring (ie concentrations above background that have resulted from anthropogenic activities) The use of this term does not denote that the presence of these compounds represents a risk to either human health or the environment and the term ldquoimpactrdquo is therefore not directly interchangeable with the term ldquoSite Contaminationrdquo the latter defined under the Environment Protection Act 1993 to include actual or potential harm to human health andor the environment

            3 now James Congdon Drive

            80607-1 REV1 30102017 PAGE 1

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Historical newspaper articles described the Austral property as hosting a factory that extended over more than three acres and included an electroplating facility In 1938 it was described as the largest aluminium utensil manufacturing company in the southern hemisphere

            Other potential sources of groundwater contamination4 identified within the Thebarton EPA Assessment Area include a former gas works (ie located to the south and south-east of the Austral property and including the current Ice Arena property) a mechanicrsquos workshop another sheet metal working facility and a farm machinery manufacturer

            The Stage 1 assessment work described herein was commissioned by the EPA to determine whether historical contamination in the vicinity of George Street was presenting a risk to human health or the environment

            13 Definition of the assessment area

            As detailed on Figure 1 the current EPA Assessment Area covers an area of approximately 27 ha within the suburb of Thebarton located approximately 2 km north-west of the Adelaide central business district (CBD)

            The boundaries of the Thebarton EPA Assessment Area were established by the EPA on the basis of the following

            the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street and 39 Smith Street in Thebarton (refer to Appendix A)

            the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

            the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

            14 Identification of contaminants of potential concern

            The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

            Site Contamination is defined by the Environment Protection Act 1993 as existing if chemical substances are present on or below the surface of a site in concentrations above background the contaminants are there as a result of activity at the site or elsewhere and their presence has resulted in actual or potential harm (that is not trivial) to the health and safety of human beings taking into account current and proposed land uses or water or the environment

            PAGE 2 80607-1 REV1 30102017

            4

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            15 Objectives

            As defined by the EPA the key objectives of the recent Stage 1 environmental assessment program undertaken within the Thebarton EPA Assessment Area (refer to Figure 1) were to

            further delineate the chlorinated hydrocarbon contamination in groundwater

            further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

            undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

            With respect to the VIRA the EPA requested that there be specific consideration of

            residential properties (slab on grade)

            residential properties (crawl space)

            residential properties (with basement) and

            trenchmaintenanceutility workers that may be working in the vicinity of the contamination

            80607-1 REV1 30102017 PAGE 3

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            2 CHARACTERISATION OF THE ASSESSMENT AREA

            21 Site identification

            For the purpose of this investigation program the Thebarton EPA Assessment Area (as delineated in Figure 1) has been defined by the following roadways

            North northern verge of Smith Street

            South Maria Street (between Dew Street and Albert Street) portion of Parker Street (between Maria Street and Goodenough Street) and Goodenough Street (between Parker Street and James Congdon Drive)

            East western verge of Port Road and James Congdon Drive and

            West western verge of Dew Street

            22 Regional geology and hydrogeology

            221 Geology

            The Thebarton area is located within the Adelaide Plains approximately 8 km to the east of Gulf St Vincent and to the west of the Para Fault It lies within the Golden Grove ndash Adelaide Embayment area of the St Vincent Basin which consists of a succession of Tertiary and Quaternary age sediments (with thicknesses of up to 600 m) overlying basement rocks

            The 1250000 Adelaide geological map (SA Department of Mines and Energy 1969) indicates that the near-surface geology of the area consists primarily of Quaternary aged soils and sediments including the Pooraka and Hindmarsh Clay formations The Pleistocene aged Pooraka Formation generally comprises a thickness of approximately 10 m and is of alluvial origin comprising sandy clays and clayey to sandy silts interbedded with layers of clay sand andor gravel The underlying Pleistocene aged Hindmarsh Clay Formation represents the basal unit of the Adelaide Plains and has a maximum general thickness of more than 100 m It generally comprises a basal gravel layer a middle layer of mottled medium to high plasticity (red-brown yellow brown greygreen to orange) often stiff to hard clays and an upper layer of fluvial and alluvial red-brown silty sand Gerges (1999) describes Hindmarsh Clay as comprising a mottled brown to pale olive grey predominantly clay formation that becomes green grey towards the basal section (approximately 16 to 20 m below ground level (BGL)) and is characterised by an increasing gravel content with depth

            Underlying the Hindmarsh Clay are sands and limestone of Tertiary age which are in turn underlain by metamorphosed basement rock of the Proterozoic Umberatana Group

            80607-1 REV1 30102017 PAGE 5

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            222 Hydrogeology

            According to Gerges (2006) the aquifers identified within the Quaternary aged sediments of the Adelaide Plains are typically found within the coarser interbedded silt sand and gravel layers of the Hindmarsh Clay Formation and vary greatly in thickness (typically from 1 to 18 m) lithology and hydraulic conductivity Confining beds between the Quaternary aquifers consist of clay and silt layers and range in thickness from 1 to 20 m These confining beds vary in terms of the amount of coarser grained material they contain their bulk hydraulic conductivity andor the presence and density of fractures In addition their absence in some areas allows direct hydraulic connection between the aquifers

            The Thebarton area is located within Hydrogeological Zone 3 (Subzone 3E) of Gerges (2006) This zone contains five to six Quaternary aquifers and three to four almost flat-lying Tertiary aquifers The first Tertiary aquifer estimated by Gerges (2006) to be intersected at a depth of approximately 130 m BGL near the Para Fault is most frequently accessed for industrial and recreational groundwater use

            The Q1 aquifer assessed as part of the current investigations is typically located at depths of between 3 and 10 m BGL beneath the Adelaide Plains with an average thickness of 2 m The Q1 aquifer contains water of variable salinity with Subzone 3E including a range of 500 to 3500 mgL total dissolved solids (TDS) The gradient of the Q1 aquifer is generally flat (particularly to the west of the Para Fault) and flow direction is typically towards the north-west

            A search of the registered bore database maintained by the Department of Environment Water and Natural Resources (DEWNR (2017) WaterConnect database) identified 59 bores within the general Thebarton area of which 18 are located in the Thebarton EPA Assessment Area Although eight bores were installed for monitoring purposes on or immediately adjacent to the property located at 31-37 George Street (ie part of the former Austral facility) it is understood that only one bore (6628-21951 ndash located within the Admella Street roadway intersecting the Q1 aquifer and identified as MW01 in Appendix A but MW02 by Fyfe5) remains in situ

            In addition to numerous monitoringinvestigationobservation bores the Q1 aquifer within the general (ie broader) Thebarton area is recorded in the DEWNR (2017) database as being accessed for drainage domestic and industrial purposes

            DEWNR (2017) information for registered bores located within the general Thebarton area is included in Appendix C whereas information for bores located within the Thebarton EPA Assessment Area (excluding those associated with the property at 31-37 George Street and installed solely for monitoring purposes6) is summarised in Table 21

            5 This existing groundwater well was identified as MW02 by Fyfe in accordance with the markings on the gatic cover and the DEWNR (2017) WaterConnect bore identification details although it was originally installed as MW01 by REM (refer to discussion of previous reports in Appendix A)

            6 ie 6628-21951 6628-21952 6628-22229 to 6628-22233 and 6628-22236

            PAGE 6 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area

            Bore ID Location Purpose Status Maximu SWL Salinity Yield Aquifer m well (m (mgL (Lsec

            Tertiary (T1)

            depth BGL) TDS) ) (m BGL)

            125 6628-516 Coca Cola plant Rehabilitated 138 1963 794

            6628-1435 Coca Cola plant Backfilled 184 212 921 392 Tertiary (T1)

            6628-4576 Corner of Admella amp Chapel Streets

            125 1454 445 Tertiary (T1)

            6628-7724 Coca Cola plant Observation 155 2017 1272 1516 Tertiary (T1)

            6628-7725 Coca Cola plant Observation 127 3016 1100 1005 Tertiary (T1)

            6628-12516 Coca Cola plant Industrial Backfilled 210 212 1300 1875 Tertiary (T1)

            6628-20663 39 Smith Street Irrigation 121 1105 50 Tertiary (T1)

            6628-20969 39 Smith Street Industrial 30 14 1535 25 Quaternary (Q1)

            6628shy21951

            Admella Street 20 Quaternary (Q1)

            6628-22395 21 James Congdon Drive

            20 157 1541 05 Quaternary

            6628-23525 41 Maria Street 206 273 1078 10 Tertiary (T1)

            Notes Shading indicates that information was not recorded in the database as interpreted from information provided in the database ndash approximate only in some instances

            ie MW02 as included in the groundwater monitoring program of Fyfe ndash refer to Table 31 Abbreviations BGL = below ground level SWL = standing water level TDS = total dissolved solids

            23 Data quality objectives

            The Data Quality Objective (DQO) process as described in Australian Standard AS44821-2005 and the National Environment Protection (Assessment of Site Contamination) Measure (ASC NEPM 1999)7

            Schedule B2 Guideline on Data Collection Sample Design and Reporting and more fully documented in the NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme involves a seven-step iterative approach that was initially developed by the United States Environment Protection Agency (US EPA) to facilitate the systematic planning and verification of contaminated sites assessment projects

            As stated in Schedule B2 of the ASC NEPM (1999) the first six steps of the DQO process comprise the development of qualitative and quantitative statements that define the objectives of the site assessment program and the quantity and quality of data needed to inform risk-based decisions These steps enable the

            All references to the ASC NEPM (1999) refer to the version amended on 16 May 2013

            80607-1 REV1 30102017 PAGE 7

            7

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            project team to communicate the goals decisions constraints (eg time budget) and uncertainties associated with the project and detail how they are to be addressed The seventh step comprises the development of a Sampling and Analysis Quality Plan (SAQP) to generate the data required to adequately characterise site contamination issues and assess their associated potential environmental and human health risks under the proposed land use scenario

            The DQOs defined for the Thebarton EPA Assessment Area are summarised in Table 22

            Table 22 Data Quality Objectives

            Objective Comment

            Step 1 ndash Statement of the Problem According to information provided to Fyfe by the EPA (as summarised in Appendix A) a property located at 31-37 George Street (immediately west of Admella Street) in Thebarton and historically occupied by part of the Austral facility had been found to be underlain by groundwater CHC (primarily TCE) impacts More recent reporting to the EPA for a property at 39 Smith Street located approximately 350 m north-west (and hydraulically down-gradient) of the George Street property indicated that detectable CHC (predominantly TCE) were also present within groundwater Since this area of Thebarton is occupied by a mixture of commercialindustrial and residential properties and the source and extent of the CHC impacts within the Q1 aquifer had not yet been determined potential risks to human health andor the environment had yet to be assessed

            Step 2 ndash The Decision that Needs The assessment works commissioned by the EPA were necessitated to to Result from the Investigation investigate the source extent and magnitude of the groundwater CHC

            contamination beneath a designated area of Thebarton (ie that included both the George Street and Smith Street properties) and to understand the possible risk to public health from potential vapour generation Fyfe have therefore undertaken vapour modelling and intrusion risk assessment works aimed at evaluating whether concentrations of identified groundwater andor soil vapour contaminants pose an unacceptable risk to human health In addition groundwater fate and transport modelling has been undertaken to predict the extent of the plume This will assist the EPA to determine a potential future Groundwater Prohibition Area (GPA) in accordance with the provisions of Section 103S of the Environment Protection Act 1993

            Step 3 ndash Inputs to the Decision The information that was required to resolve the decision statement included the collection of physical and chemical data from across the Thebarton EPA Assessment Area The collected data as well as physical observations regarding the geology of the area and possible preferential contaminant pathways was used to determine potential risks to human health via groundwater fate and transport and vapour intrusion modelling

            Step 4 ndash Boundaries of the Investigation

            The lateral boundaries of the Thebarton EPA Assessment Area are as defined in Sections 13 and 21 as depicted on Figure 1 Vertically the investigations extended as far as the maximum drilled depth (19 m BGL)

            Step 5 ndash Decision Rules The decision rule will be based upon the identification of predicted indoor air concentrations of CHC compounds associated with groundwater andor soil vapour impacts which exceed adopted response levels

            PAGE 8 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Objective Comment

            Step 6 ndash Decision Error Tolerances The purpose of establishing decision error tolerance is to control the acceptable degree of uncertainty upon which decisions are made in order to avoid the making of an incorrect decision and to enable identification of additional investigation monitoring or remediation activities required on the basis of accurate data for the protection of human health and the environment The Measuring Quality Objectives (MQO) include the quality assurance (QA) activities that were conducted during the assessment the quality control (QC) acceptance criteria applicable to the assessment and the adopted Data Quality Indicators (DQIs) as follows (and further discussed in Section 5) completeness ndash a measure of the amount of useable data from a data

            collection activity comparability ndash the confidence (expressed qualitatively) that data may be

            considered to be equivalent for each sampling and analytical event representativeness ndash the confidence (expressed qualitatively) that data

            are representative of each media present on the site precision ndash a quantitative measure of the variability (or reproducibility) of

            data and accuracy (bias) ndash a quantitative measure of the closeness of reported data

            to the true value

            Step 7 ndash Optimisation of the Data collection was undertaken in general accordance with the Sample Collection Design methodologies outlined in the relevant documentsguidelines referenced

            throughout this report As determined by the EPA the data collection design included targeted sampling to investigate and delineate areas of potential groundwater and soil vapour contamination and to assess potential associated human health risks

            80607-1 REV1 30102017 PAGE 9

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            3 SCOPE OF WORK

            The scope of work undertaken by Fyfe was generally consistent with that requested within the original EPA request for quote (RFQ) dated 27 March 2017 Some modifications to the original workscope occurred based on site findings and additional site information was collected where required and as agreed with the EPA in order to achieve the EPArsquos project objectives outlined in Section 15

            As identified in the RFQ the scope of work was designed to

            provide an initial delineation of CHC impacts in soil vapour through the deployment of Waterloo Membrane Samplers (WMStrade) as a screening tool

            further delineate the previously identified CHC impacts in groundwater

            decide based on the results of the WMStrade and groundwater results the need for the number of and the locations of permanent soil vapour monitoring bores

            identify the nature extent and potential source area(s) of the identified CHC impacts in groundwater andor soil vapour

            determine the likely fate and transport of the groundwater CHC plume to support the establishment of a potential future GPA

            determine the potential human health (including vapour intrusion) risk(s) on the basis of the data collected and

            ascertain whether or not a public health risk exists within the Thebarton EPA Assessment Area

            The scope of work is further detailed in Section 32 Variations from the scope of work originally requested in the EPA RFQ were agreed with the EPA during the course of the project and included the following

            deployment of an additional four WMStrade units ndash ie 41 in total as compared to the original allowance of 37

            installation (and sampling) of an additional six nested soil vapour bores (to depths of 1 and 3 m BGL) ndash ie 11 in total as compared to the original allowance of five

            installation (and sampling) two individually located (ie as opposed to the nested locations) soil vapour bores to a depth of 1 m BGL ndash ie as compared to the original allowance of 10

            installation (and sampling) of 25 groundwater monitoring wells ndash ie as compared to the original allowance of 20 and

            sampling of an existing well in Admella Street (MW02) ndash ie not included in the original EPA scope

            80607-1 REV1 30102017 PAGE 11

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            31 Preliminary work

            Preliminary work involved the following

            review and summation of all available historical reports (as supplied by the EPA) ndash refer to Appendix A

            development of a preliminary (working) conceptual site model (CSM) based on a review of the historical data

            preparation of a detailed health and safety plan covering all aspects and stages of the work and

            detailed planning with key stakeholders prior to the execution of the field investigation program

            32 Field investigation and laboratory analysis program

            The scope of the field investigation program undertaken by Fyfe between 31 May and 28 August 2017 is summarised in Table 31 whereas the scope of the laboratory testing program is summarised in Table 32

            A plan showing the various assessment point locations is included as Figure 2

            Table 31 Scope of field investigation program ndash May to August 2017

            Scope Item Description of works Date of works

            Passive soil vapour sampling ndash Round 1

            Thirty-seven WMStrade units identified as WMS 1 to WMS 37 were installed within the soil profile to 1 m BGL at scattered (approximately grid-like) locations across the Thebarton EPA Assessment Area

            31 May and 1 to 2 June

            The WMStrade units were extracted and forwarded to the analytical laboratory 7 June

            Soil bores were located using a hand-held global positioning system (GPS) unit before being backfilled with (drillerrsquos) sand

            7 August

            Monitoring well drilling and installation

            Individual groundwater well permits were obtained from DEWNR prior to well installation ndash copies of the well permits are included in Appendix D Groundwater monitoring wells (MW1 MW3 and MW5 to MW26) were installed to depths of between 15 and 19 m BGL at 24 locations across the Thebarton EPA Assessment Area Background well MW4 was installed to 19 m BGL within a public recreational area located across James Congdon Drive to the east (ie near the south-eastern corner of the Thebarton EPA Assessment Area) All 25 newly installed wells were developed following installation

            28 to 30 June 3 to 7 July and 10 to 14 July

            Geotechnical soil testing

            Intact soil cores collected during the drilling of 10 groundwater wells (MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25) were forwarded to the analytical laboratory for geotechnical testing

            Groundwater gauging

            All 25 newly installed monitoring wells (MW1 and MW3 to MW26) as well as the existing Admella Street well (MW02) were gauged to assess total well depth standing water level (SWL) and the presenceabsence of non aqueous phase liquid (NAPL) This was undertaken as a discrete event prior to the commencement of groundwater sampling

            18 July

            PAGE 12 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Scope Item Description of works Date of works

            Groundwater sampling

            All 26 existing and newly installed wells were sampled using a combination of low flow (micropurge) and HydraSleevetrade sampling techniques (as recorded on the field sampling sheets in Appendix E) ndash samples were forwarded to the analytical laboratories

            18 to 21 and 24 to 25 July

            Aquifer testing Aquifer permeability (slug) testing was undertaken on 10 wells (MW02 MW3 MW7 MW14 MW17 MW20 MW21 MW23 MW25 and MW26) Data was subsequently evaluated by Arcadis Pty Ltd (Arcadis) to estimate the hydraulic conductivity of the aquifer beneath the Thebarton EPA Assessment Area (refer to Section 732)

            28 July

            Soil vapour bore drilling and installation

            Following the receipt of the groundwater data 11 nested soil vapour bores (SV1 to SV10 and SV12) were installed to a depth of 1 and 3 m BGL at selected locations within the Thebarton EPA Assessment Area Two additional soil vapour bores (SV11 and SV13) were installed to a depth of 1 m BGL

            18 21 and 22 August

            Active soil vapour sampling

            Sampling of soil vapour bores was undertaken using summa canister (TO-15) sample collection methods Vapour (canister) and general gas (Tedlar bag) samples were extracted from all 13 locations (ie SV1 to SV13) including the 11 nested bores

            24 August

            Passive soil vapour sampling ndash Round 2

            Following the receipt of the groundwater data and for the purposes of comparison with the soil vapour bore data an additional four WMStrade units (WMS 38 to WMS 41) were installed within the soil profile to 1 m BGL at targeted locations across the Thebarton EPA Assessment Area (ie within approximately 1 m of soil vapour bores SV2 SV4 SV5 and SV7) Soil bores were located using a hand-held GPS unit

            18 August

            The WMStrade units were extracted and forwarded to the analytical laboratory and the soil bores were backfilled with (drillerrsquos) sand

            24 August

            Surveying The locations of all soil vapour bores and groundwater wells were surveyed by a licensed surveyor relative to the Map Grid of Australia (MGA) 1994 and the top of each bore was surveyed relative to Australian Height Datum (AHD) The survey data are included in Appendix F

            22 July and 28 August

            Notes as determined by the EPA

            Table 32 Scope of laboratory testing program

            Scope Item Description of works

            Soil geotechnical testing

            Soil samples from each of three depths within core samples collected during the drilling of groundwater wells MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25 were analysed for particle size distribution (PSD) moisture content including degree of saturation bulk density dry density and specific gravity void ratio and porosity

            80607-1 REV1 30102017 PAGE 13

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Scope Item Description of works

            Groundwater testing Groundwater samples from all 26 wells were analysed for the COPC detailed in Section 14 As requested by the EPA groundwater samples from selected wells (MW02 MW5 MW8 MW9 MW12 MW17 MW21 MW22 MW23 and MW26) were also analysed for the following major cations and anions (calcium magnesium sodium potassium chloride and alkalinity)

            and natural attenuation parameters (carbon dioxide (CO2) sulfate iron manganese nitrate) Additional components reported by the analytical laboratory included nitrite and nitrate + nitrite

            Soil vapour testing The WMStrade units deployed during each of Rounds 1 and 2 were analysed for the COPC detailed in Section 14 The soil vapour (summa canister) samples were analysed for the COPC detailed in Section 14 as well as 2-propanol and general gases (helium hydrogen oxygen nitrogen methane carbon dioxide ethane propane butane iso-butane pentane iso-pentane hexane argon carbon monoxide and ethylene)

            Notes Specific sample depths are detailed in the relevant laboratory reports in Appendix G also known as isopropyl alcohol isopropanol or IPA

            33 Data interpretation

            Following the receipt and collation of the field and laboratory data hydrogeological (fate and transport) and VIRA modelling (refer to Sections 8 and 9 respectively) were undertaken to enable an assessment of risk and to refine the CSM (Section 10)

            PAGE 14 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            4 METHODOLOGY

            41 Field methodologies

            Prior to the commencement of the field investigations a site specific Health and Safety Plan (HSP) including Safe Work Method Statements (SWMS) and a Job Hazard Analysis (JHA) was prepared ndash all personnel working at the site were required to read understand sign and conform to the HSP

            Each proposed drilling location was cleared of underground services by a professional service location company (Pipeline Technologies) using conventional (electronic) service detection methods as well as ground penetrating radar (GPR) Where underground or overhead services were present andor deemed to be a potential safety risk during drilling activities the drill location was moved to an area considered by the Fyfe representative and service locator to be safe All changes to drilling locations were notified to EPA and recorded on a site plan for future reference

            Given that works were undertaken within suburban streets Fyfe employed the services of a qualified traffic management company (Altus Traffic) during drilling activities in order to ensure safety for pedestrians and road users minimal disruption to traffic flow and the provision of a safe working environment

            Field methodologies as detailed in Table 41 were undertaken in accordance with Fyfersquos standard operating procedures (SOPs) Relevant field sampling sheets are included in Appendices F (groundwater) and G (soil vapour ndash combined field sampling sheets and chain of custody (COC) documents) and borehole log reports are presented in Appendices H (groundwater) I (WMStrade) and J (soil vapour)

            Table 41 Summary of field methodologies

            Activity Details

            Passive soil bore sampling The soil bores used to deploy the WMStrade units were hand augered by personnel from Fyfe and Aussie Probe to a depth of 1 m BGL SGS Australia (SGS) personnel suspended each WMStrade unit into its respective borehole from a string The hole was then sealed with an expandable foam plug inside a polyethylene sleeve and the string suspending the sampler was connected to a temporary plastic cap at the ground surface The Round 1 WMStrade units were deployed for periods of between six and seven days whereas the Round 2 WMStrade units were all deployed for six days Following retrieval by SGS each WMStrade unit was placed into a sealed glass vial and a labelled foil bag The WMStrade units did not require chilling during transport to the analytical laboratory Borehole log reports are included in Appendix I whereas combined field sampling sheets and COC documents are presented in Appendix G

            80607-1 REV1 30102017 PAGE 15

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Activity Details

            Groundwater well Groundwater wells were drilled by WB Drilling using a combination of hand augering installation mechanical pushtube and solid auger techniques

            Following the completion of drilling each borehole was fitted with 50 mm class 18 uPVC casing with a basal 6 m long section of slotted well screen A filter pack comprising clean graded sands of suitable size to provide sufficient inflow of groundwater was installed within the annular space between the borehole and the well casing and extended from the base of the screened interval to approximately 1 m above the termination of the slotted casing A 1 m long bentonite collar comprising pelleted or granulated bentonite was placed above the filter pack to prevent water seepage downward along the well casing or borehole from ground surface Each well was grouted up to surface level and fitted with a (lockable) steel gatic cover the latter flush mounted to prevent tripping andor other hazards Groundwater well log reports are included in Appendix H

            Soil logging and Soil logging was undertaken in general accordance with the ASC NEPM (1999) which geotechnical sampling endorses AS1726-1993 In addition to the requirements of AS1726-1993 particular

            attention was paid during logging to any lithological variations such as sandgravel lenses or secondary porosity (such as clay fracturing) which may act as potential preferential pathways for contaminant vapourgroundwater migration through the sub-surface as well as the presence of fill material andor any olfactory or visual evidence of contamination Soil descriptions have been included on the logs in Appendices H to J Cores for geotechnical analysis were collected using push tube sampling methodologies to obtain undisturbed samples Section(s) of core to be tested were retained (intact) within the pushtube liners and capped at each end for storage and transport to the analytical laboratory

            Field screening of soils Field screening of individual soil layers was undertaken at the majority of the drilling locations and involved the use of a photoionisation (PID) unit fitted with an 117 eV lamp (ie as considered suitable for the detection of CHC) The PID unit was calibrated by the hire company prior to delivery and was checked on a daily basis against an isobutylene calibration gas of known concentration Field screen samples were collected with care to ensure that each sample was representative of the soil stratum from which it was collected and experienced minimal loss of volatile compounds The soil material was placed immediately into a zip lock bag and sealed ensuring the bag was half filled (ie such that the volume ratio of soil to air was equal) Soil clumps within the bag were manually broken up and the bag was left to rest for a minimum of five minutes but no longer than 20 minutes Prior to testing the bag was shaken vigorously to release any vapours within the soil To test the tip of the PID probe was inserted into the bag and the maximum volatile organic compound (VOC) reading recorded after a nominal 10 second period or when the reading had peaked Results were recorded on the appropriate bore log sheets presented in Appendices H to J

            Groundwater well Following installation the wells were developed by purging a minimum of four well development volumes (ie until stable parameters were obtained andor until the well purged dry) from

            the casing with a steel bailer andor twister pump to ensure hydraulic connectivity with the aquifer formation

            Groundwater gauging Groundwater levels in the newly installed and existing monitoring wells located across the Thebarton EPA Assessment Area were gauged using an interface probe prior to the commencement of the groundwater sampling program All monitoring wells were gauged for SWL the potential presence of NAPL and the total well depth Groundwater field gauging results are presented in Appendix E

            PAGE 16 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Activity Details

            Groundwater sampling The majority of the wells were sampled using low flow (micropurge) techniques Where recovery was particularly low (ie MW4 MW8 MW15 MW18 MW19 and MW24) and unsuitable for low flow (micropurge) sampling the original sampling technique was abandoned and a HydraSleeveTM (no purge) methodology was used instead Groundwater samples were collected in laboratory-supplied screw top bottles containing appropriate preservative (if required) with no headspace allowed Samples were chilled during storage and transport to the analytical laboratory Disposable nitrile gloves worn by field personnel were changed prior to the collection of each sample Samples for metals (ie iron manganese) analysis were filtered in the field using 045 microm filters Groundwater field sampling sheets are presented in Appendix E

            Low Flow Methodology The low flow sampling technique involved the following the pump was placed close to the bottom of the screened interval the flow rate (up to 05 Lmin) was regulated to maintain an acceptable level of

            drawdown with minimal fluctuation of the dynamic water level during pumping and sampling

            groundwater drawdown was monitored constantly during purging and sampling using an interface probe

            water quality parameters were considered to have stabilised when the following ranges were recorded over three consecutive readings ndash electrical conductivity plusmn 5 ndash pH plusmn 01 ndash temperature plusmn 02degC ndash dissolved oxygen plusmn 10 ndash redox potential plusmn 10 mV

            the stabilisation parameters were recorded on field logging sheets after every one litre of groundwater purged using a calibrated water quality meter and a flow cell suspended in a bucket with litre intervals marked and

            samples were collected once three consecutive stabilisation parameters were recorded and a volume of between 28 and 6 litres was purged prior to sampling

            HydraSleeveTM Methodology The HydraSleeveTM sampling technique involved attaching a stainless steel weight to the bottom and a wire tether clip to the throat of the HydraSleeveTM before lowering it into the water column to the desired depth and allowing it to fill with groundwater After a minimum period of 24 hours the HydraSleeveTM was quickly and smoothly withdrawn from the well and the contents were transferred into the sample containers Water quality parameters were measured after samples were decanted ndash either within the water remaining in the HydraSleeveTM or within a grab sample collected using a disposable bailer

            Hydraulic testing Rising and falling head permeability (ldquoslugrdquo) tests were undertaken to estimate the hydraulic conductivity (K) of the aquifer within various parts of the Thebarton EPA Assessment Area The falling-head tests were initiated by quickly inserting a 1285 m long and 36 mm diameter solid PVC cylinder (slug) into the water column at each well to produce a sufficient sudden rise in the water level The subsequent ldquofallrdquo back to the static water level (recovery) was measured and recorded automatically and in real-time using a

            80607-1 REV1 30102017 PAGE 17

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Activity Details

            pressure transducerdata logger programmed to record water levels at a one second interval After static water level conditions returned in the well the rising-head test was initiated by quickly removing the slug from the well to create a sudden drop in the water column height As with the falling-head test the rise of the water level back to a static condition (recovery) was automatically recorded

            Soil vapour bore Soil vapour bores were drilled by Aussie Probe using a combination of hand augering and installation mechanical pushtube techniques

            Within each 3 m deep soil vapour bore teflon tubing attached to a soil vapour probe was inserted to the base of the hole which had been prefilled with approximately 005 m of clean filter pack sand An additional 045 m of sand (ie approximately 05 m in total) was then added to the hole and topped by a bentonite plug seal of approximately 05 m thickness A second soil vapour probe was installed at a depth of about 1 m within a 05 m sand pack which was overlain by bentonite to a depth of about 02 to 03 m BGL The two 1 m deep soil vapour bores were installed in a similar manner with a sand pack extending from the base to about 05 to 06 m BGL overlain by a bentonite plug to 03 m BGL Each installation was completed with grout to surface and topped with a standard flush-mounted gatic cover Soil vapour bore log reports are included in Appendix J

            Soil vapour sampling All soil vapour sampling works were undertaken by SGS using suitably trained and experienced personnel ndash SGS holds National Association of Testing Authorities (NATA) accreditation for all soil vapour sampling and laboratory analytical works Combined field sampling sheets and COC documents are presented in Appendix G Soil vapour samples were collected using summa canisters and analysed using the US EPA (1999) TO-15 method Sampling involved the connection of a passivated 1 L stainless steel canister to the teflon tubing extending from the soil vapour probe and the use of a soil gas sampling train to restrict flow to a maximum rate of 200 mLmin Canister vacuum pressure was monitored during sampling to enable calculation of the volume of sample drawn into the canister ndash the small amount of vacuum left in the canister at the end of the sampling procedure was measured in the laboratory to check if any leaks occurred during transit (refer to further discussion in Table 52) A shroud was set up around the sampling point and tracer chemicals were introduced at high concentrations by flooding the shroud with helium and placing a cloth soaked with IPA into the shroud Each canister was cleaned and certified by SGS prior to use (refer to Appendix G) and backshyup coconut shell carbon sorbent tube samples were also collected (but not analysed) Summa canisters did not require chilling during transport to the analytical laboratory

            Waste disposal Waste water and surplus soil corescuttings were stored together within 205 litre drums in the rear car park of a commercialindustrial property at 19-21 James Congdon Drive (as organised by the EPA) prior to removaldisposal by a licensed waste removal company (Cleanaway) Analytical results pertaining to the soils were forwarded to the licensed receiving facility and all of the soil was classified as lsquoWaste Fillrsquo in accordance with the Environment Protection Regulations 2009 The waste transport certificates are included in Appendix K

            PAGE 18 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            42 Laboratory analysis

            The following laboratories were used for the analysis of the environmental samples

            complete soil cores for geotechnical sample analysis were forwarded to SMS Geotechnical

            primary groundwater samples collected by Fyfe were analysed at the SGS laboratory whereas secondary groundwater samples were forwarded to EurofinsMGT and

            soil vapour (including WMStrade) samples collected by SGS were analysed at their laboratory

            80607-1 REV1 30102017 PAGE 19

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            5 QUALITY ASSURANCE AND QUALITY CONTROL

            Data quality is typically discussed in terms of the DQIs presented in Table 22 ndash ie completeness comparability representativeness precision and accuracy In order to assess the quality of the data collected during the Fyfe investigation program against these DQIs specific QAQC procedures were implemented during both the field sampling and laboratory analysis programs as detailed in the following sections

            51 Field QAQC

            Field QA procedures undertaken during the recent investigations included the collection of the following QC samples aimed at assessing possible errors associated with cross contamination as well as inconsistencies in sampling andor laboratory analytical techniques

            intra-laboratory duplicate (duplicate) samples submitted to the same (primary laboratory) to assess variation in analyte concentrations between samples collected from the same sampling point andor the repeatability (precision) of the analytical procedures

            inter-laboratory duplicate (split or triplicate) samples submitted to a second laboratory to check on the analytical proficiency (accuracy) of the results produced by the primary laboratory

            equipment rinsate blank samples collected during groundwater sampling only and used to assess cross-contamination that may have occurred from sampling equipment during sampling and

            trip blank samples used to assess whether cross-contamination may have occurred between samples during transport

            Whereas analyte concentrations within the rinsate and trip blank samples should be below the laboratory limit of reporting (LOR) the inter- and intra-laboratory duplicate sample results are assessed via the calculation of a relative percentage difference (RPD) as follows

            (Concentration 1 minus Concentration 2) x 100RPD = (Concentration 1 + Concentration 2) 2

            Maximum RPDs of 30 (inorganics) and 50 (organics) are generally considered acceptable with higher RPD values often recorded where concentrations of an analyte approach the laboratory LOR

            All field QC sample results are included in the summary data tables in Appendix L

            511 Groundwater

            Table 51 presents conformance to field QAQC procedures undertaken as part of the groundwater investigations

            80607-1 REV1 30102017 PAGE 21

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Table 51 Field QAQC procedures ndash Groundwater

            QAQC Item Detail

            Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) AustralianNew Zealand standards ASNZS 566711998 and ASNZS 5667111998 SA EPA (2007) and Fyfe SOPs Details are provided in Table 41

            Calibration of field equipment

            Documentation regarding the calibration of field equipment is included in Appendix M

            Decontamination of All disposable equipment (tubing pump bladders plastic bailers bailer cord and equipment HydraSleeveTM units) were replaced between wells Re-usable equipment (micropurge pump

            interface probe and HydraSleeveTM weights) was decontaminated between sampling locations using potable water and Decon 90trade phosphate free detergent

            Sample preservation and storage

            Samples were kept in laboratory supplied containers in a portable chilled insulated box (esky) prior to and during transport to the laboratory

            Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

            Duplicate samples Two intra-laboratory and two inter-laboratory duplicate samples were analysed for CHC with respect to 26 primary groundwater samples ndash thereby constituting an overall ratio of approximately one duplicate per 65 primary samples (or 15) compared to a generally acceptable ratio of 110 samples (or 10) One intra-laboratory and one inter-laboratory duplicate sample were analysed for the remaining parameters with respect to 10 primary groundwater samples ndash thereby constituting an overall ratio of one duplicate per five primary samples (or 20) compared to a generally acceptable ratio of 110 samples (or 10) Intra- and inter-laboratory duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within the acceptable range with the exception of the following intra-laboratory duplicate sample pair MW9QW1 TCE (67) nitrate (147) and inter-laboratory duplicate sample pair MW9QW2 total CO2 (59) iron (190)

            manganese (183) potassium (64) nitrate (194) The elevated RPD for TCE in the intra-laboratory duplicate sample pair is considered to be related to the low concentration detected and does not alter the interpretation of the data The other RPD exceedances are not considered significant (ie in terms of overall data interpretation) as they were not obtained for identified COPC (as defined in Section 14)

            Rinsate blank samples Six equipment rinsate blank samples (one for each day of sampling) were collected from either the pump housing or a new HydraSleevetrade (final day of sampling only) and analysed for CHC to confirm the effectiveness of the decontamination procedures and the cleanliness of disposable equipment The analytical results obtained for the rinsate blank samples were all below the laboratory LOR thereby indicating that decontamination practices during the groundwater sampling program were acceptable and that no contamination was introduced by the use of the HydraSleevestrade

            Trip blank samples Six trip blank samples were included within containers (eskies) of sample bottles provided by the analytical laboratory and returned to the analytical laboratory All of the trip blank samples were analysed for CHC With the exception of TB187 which contained 1 microgL TCE the analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was limited impact on sample quality during storage or transport of the samples to the analytical laboratory

            PAGE 22 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Notes No duplicate QC samples were collected during the use of the HydraSleeveTM sampling technique as detailed in ANZECCARMCANZ (2000a) at least 5 (ie 120) duplicate samples should be analysed ndash the generally accepted industry standard however is 10 (110) including 5 intra-laboratory and 5 inter-laboratory duplicates

            512 Soil vapour

            Tables 52 presents conformance to field QAQC procedures undertaken as part of the soil vapour (passive and active) investigations

            Table 52 Field QAQC procedures ndash Soil vapour

            QAQC Item Detail

            Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) as well as ASTM (2001 2006) ITRC (2007) CRC CARE (2013) guidance and Fyfe SOPs Details are included in Table 41 and Appendix G (ie SGS sampling methodology sheet) During the use of summa canisters to sample the soil vapour bores leak testing was undertaken (as described in Table 41) Although small leaks or ambient drawdown appear to have occurred with respect to samples SV11_10m (003 helium) SV13_10m (003 helium) and SV1_10m (360 microgm3 IPA) ITRC (2007) and NJDEP (2013) state that ge 5 helium andor gt10 mgm3 IPA are required to be indicative of a significant leak or substantial ambient drawdown Given that the leaks were relatively small (ie 06 (helium) and 36 (IPA) of the levels considered indicative of a significant leak) the data from these bores were still considered to be valid ndash refer to SGS correspondence in Appendix G As detailed in Table 41 a small amount of vacuum was generally left in each summa canister at the end of the sampling procedure and was measured in the laboratory to check if any leaks had occurred during transit However samples SV11_10m SV12_30m as well as the helium blank were recorded as having zero vacuum upon receipt at the analytical laboratory A query lodged with SGS regarding this issue indicated that whereas the helium blank comprised a grab sample collected into a Tedlar bag directly from the helium cylinder (ie without the use of a gauge) the canisters used for samples SV11_10m and SV12_30 were filled during sampling so that there was no remaining vacuum ndash refer to field sampling documentation in Appendix G SGS stated that although it is good practice to have a small amount of vacuum remaining in a canister at the completion of sampling appropriate additional QC measures were employed and the absence of other common background VOCs (eg petroleum hydrocarbons) upon sample testing indicated that leakage had not occurred during transit In addition all canisters are fitted with quick connect one-way valves that are closed upon removal from the sampling train and canistersfittings are leak checked prior to leaving the laboratory and again in the field to ensure that they are leak free Refer to SGS correspondence in Appendix G The presence of detectable IPA (120 microgm3) and TCE (48 microgm3) in the helium blank was also queried with SGS who stated that this (ie variability in the quality of the high purity helium gas used) is not an uncommon occurrence The reason for collecting a helium blank sample is to identify any impurities present in the helium gas so that if a leak does occur during sampling it is possible to determine whether any target compounds could be introduced into the sample train Although a target compound (ie TCE) was detected in the blank the concentration is minor and even if a leak had occurred during sampling (of which there was no evidence) it would not have affected the overall results and data interpretation The presence of IPA in the helium blank is

            80607-1 REV1 30102017 PAGE 23

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            QAQC Item Detail

            suspected by SGS of having resulted from a handling issue in the field ndash ie sub-sampling from the helium cylinder (ie into a summa canister via a flex foil bag) in the vicinity of the high concentrations of IPA being used for leak detection Refer to SGS correspondence in Appendix G

            Sample preservation and storage

            Following collection the WMStrade units were placed into individual glass vials which were sealed and placed into foil bags for transport to the analytical laboratory at ambient temperature Summa canisters were stored in specially constructed cases during transport to the analytical laboratory at ambient temperature

            Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

            QC samples ndash WMStrade sampling

            During the first round of passive soil vapour sampling three additional WMStrade units were deployed in soil bores drilled adjacent to WMS 22 WMS 25 and WMS 28 to act as duplicate QC samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 8) Two trip blank samples were also included with samples transported from and to the analytical laboratory All of the QC samples were analysed by the primary laboratory Intra-duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within an acceptable range (ie lt30) The analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was negligible impact on sample quality during storage or transport of the samples to the analytical laboratory

            QC samples ndash soil vapour bore sampling

            Two intra-laboratory duplicate QC samples were analysed for CHC and general gases with respect to 24 primary soil vapour samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 83) compared to an acceptable ratio of 110 samples (or 10) Intra-laboratory duplicate RPDs were calculated where both samples had a reported concentration above the laboratory LOR All calculated RPDs for CHC and general gases were within an acceptable range (ie lt30) The analytical results obtained for the helium shroud (Tedlar bags) helium blank and IPA shroud (carbon tube) samples were all considered to be satisfactory

            Notes The American Society for Testing and Materials (ASTM) is an internationally recognised source of testing methods Although Appendix J of CRC CARE (2013) stipulates a 110 duplicate sampling ratio for active vapour sampling a specific ratio is not stipulated for passive vapour sampling

            52 Laboratory QAQC

            Laboratory QA procedures generally include the performance of a number of internal checks of data precision and accuracy that are aimed at assessing possible errors associated with sample preparation and analytical techniques Specific types of QC samples analysed by laboratories and the relevant acceptance criteria are as follows

            PAGE 24 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            internal laboratory replicate samples maximum RPD values of 20 to 50 although this varies depending on laboratory LOR

            spike recoveries results between 70 and 130 and

            laboratory controlmethod blanks results below the laboratory LOR

            Table 53 presents conformance to laboratory QAQC procedures undertaken as part of the overall investigation program

            Table 53 Laboratory QAQC procedures

            QAQC Item Detail

            Samples analysed and Samples were generally analysed within specified holding times ndash with the exception extracted within relevant of the following groundwater samples holding times SGS report no ME303457 nitrate was analysed two days late in some samples

            (MW5 MW17 MW26) SGS report no ME303475 nitrate was analysed one day late in all samples and EurofinsMGT report no 555810-W total CO2 was analysed five days late None of these holding time exceedances are considered to be significant with respect to the interpretation of the CHC data the determination of potential human healthenvironmental risks andor the determination of natural attenuation

            Laboratories used and The laboratories used (SGS Eurofins MGT and SMS Geotechnical) were NATA NATA accreditation accredited for the majority of the analyses undertaken

            The exception was SMS Geotechnical which was not NATA accredited for the calculations undertaken to derive some of the data ndash this is the case however for all geotechnical laboratories

            Appropriate analytical methodologies used

            Refer to the laboratory reports in Appendix G

            Laboratory limit of The laboratory LOR is the minimum concentration of an analyte (substance) that can reporting (LOR) be measured with a high degree of confidence that the analyte is present at or above

            that concentration The LOR are presented in the laboratory certificates of analysis (Appendix G) and are considered to be generally appropriate (ie below the adopted assessment criteria ndash refer to Section 62) ndash the following exceptions in soil vapour (ie considered to be due to interference associated with elevated concentrations of other compounds ndash refer to SGS correspondence in Appendix G) are discussed further in Table 101 VC in all of the WMStrade samples relative to the ASC NEPM (1999) interim soil

            vapour health investigation level (HIL) for residential land use cis-12-DCE and VC in two soil vapour bore samples (SV2_30m and SV3_30m)

            relative to the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land use and

            VC in two soil vapour bore samples (SV3_10m and SV7_30m) relative to the ASC NEPM (1999) interim soil vapour HIL for residential land use

            In addition to the above although ultra-trace analysis was requested the laboratory LOR for VC in groundwater (ie 1 microgL) is above the adopted NHMRCMRMMC (2011) potable guideline (ie 03 microgL) ndash refer to Section 612

            80607-1 REV1 30102017 PAGE 25

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            QAQC Item Detail

            Laboratory internal QC analyses

            Results obtained for the laboratory internal QC samples were generally within the acceptable limits of repeatability chemical extraction and detection with the exception of the following SGS report ME303457 matrix spike results for iron were outside normal tolerances

            due to the high concentrations of iron in the spiked sample ndash matrix spike results for iron could therefore not be calculated This is not considered to be a significant issue

            Full details regarding laboratory QAQC procedures and results are presented in the certified laboratory certificates contained in Appendix G

            Notes Since holding times were not specified in the SGS groundwater reports Fyfersquos assessment of holding times has been based on those adopted by EurofinsMGT (ie the secondary laboratory used for groundwater analysis) ie in accordance with Schedule B3 of the ASC NEPM (1999) also referred to as practical quantification limits (PQL)

            53 QAQC summary

            In summary it is considered that

            the field QAQC programs were generally undertaken with regard to relevant legislation standards andor guidelines and were sufficient for obtaining samples that are representative of site conditions and

            the overall laboratory QAQC procedures and results were adequate such that the laboratory analytical results obtained are of acceptable quality for addressing the key objectives outlined in Section 15

            PAGE 26 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            6 ASSESSMENT CRITERIA

            61 Groundwater

            611 Beneficial Use Assessment

            In accordance with Schedule B6 of the ASC NEPM (1999) and SA EPA (2009) a Beneficial Use Assessment (BUA) was undertaken to assess both the current and realistic future uses of groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area

            This was aimed at determining what groundwater uses need to be protected and assessing the risk(s) that groundwater may pose to human health and the environment (refer also to the VIRA in Section 9)

            As summarised in Table 61 the potential beneficial uses for groundwater within the Q1 aquifer that have been considered are as follows ndash taking into account the salinity of the groundwater the Environment Protection (Water Quality) Policy 2015 (Water Quality EPP 2015) the DEWNR (2017) WaterConnect database information presented in Section 222 and possible sensitive receptors located within andor within the vicinity of the Thebarton EPA Assessment Area

            The salinity of groundwater has been calculated to approximate 1230 to 3620 mgL TDS (refer to Section 7312) According to the Water Quality EPP 2015 the applicable environmental values for groundwater with salinity above 1200 mgL TDS but less than 3000 mgL TDS are irrigation livestock and aquaculture whereas the salinity is considered to be too high for potable use ndash although domestic irrigation is considered to be a potentially realistic use for this area (see below) livestock watering is considered unlikely to be undertaken in such an urban setting and no local water bodies (ie surface or groundwater) have been identified as being used for commercial aquaculture purposes

            The DEWNR (2017) WaterConnect database indicates that groundwater within the Q1 aquifer in the Thebarton area is accessed for drainage domestic and industrial purposes ndash domestic groundwater use could include garden irrigation plumbing water andor the filling of swimming pools (ie primary contact recreation) Although domestic groundwater extraction is considered unlikely to include potable use (ie due to its salinity and the availability of a reticulated mains water supply) potential mixing with rain watermains water could render it suitable (ie from a salinity perspective) for drinking

            As the closest freshwater surface water body the River Torrens is located approximately 03 km to the east and 07 km to the north and north-west of the northern portion of this area groundwater discharge from the Thebarton EPA Assessment Area into a freshwater aquatic ecosystem is considered possible However as the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area the potential for impact on a freshwater aquatic environment has not been confirmed

            80607-1 REV1 30102017 PAGE 27

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Since the closest marine surface water body Gulf St Vincent is located approximately 8 km to the west groundwater discharge from the Thebarton EPA Assessment Area into a marine aquatic ecosystem is not considered to be realistic

            Since volatile contaminants have been detected within the Q1 aquifer (refer to Section 7331) a potential vapour flux risk to future site users must be considered

            Given the measured depth of the Q1 aquifer beneath the site (ie approximately 1232 to 1585 m BGL ndash refer to Section 7311) it is considered unlikely that direct contact could occur between groundwater and building footingsunderground services

            Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area

            Environmental Values Beneficial Uses

            Water Quality EPP 2015

            environmental value

            SA EPA (2009) Potential

            Beneficial Uses

            Beneficial Use Assessment

            Considered Applicable

            Aquatic Ecosystem

            Marine Yes No

            Fresh Yes Possibly

            Potable - Yes Possibly

            Agriculture Irrigation - Yes Yes

            Livestock - Yes No

            Aquaculture - Yes No

            Recreation amp Aesthetics

            Primary contact Yes Possibly

            Aesthetics Yes Possibly

            Industrial - Yes Yes

            Human health in non-use scenarios

            Vapour flux -

            Yes Yes

            Buildings and structures

            Contact - Yes No

            Notes ie for underground waters with a background TDS level of between 1200 and 3000 mgL ndash note that although they are not listed as environmental values of groundwater in Schedule 1(3) of the Water Quality EPP 2015 aquatic ecosystems as well as recreation amp aesthetics are included as environmental values for waters in general in Part 1(6) of the document ie domestic irrigation only

            612 Groundwater beneficial use criteria

            The health and ecological criteria used for the assessment of the COPC (refer to Section 14) in groundwater have been based on the results of the BUA (Section 611) A summary of the references used to source the groundwater assessment criteria is provided in Table 62

            PAGE 28 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Table 62 Sources of adopted groundwater assessment criteria

            Beneficial Use Reference

            Freshwater Ecosystems No criteria available for COPC

            Potable NHMRCNRMMC (2011) Australian Drinking Water Guidelines

            WHO (2017) Guidelines for Drinking-water Quality ndash TCE only

            Irrigation No criteria available for COPC

            Primary contact recreation (including aesthetics)

            NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines but (with the exception of aesthetic guidelines) multiplied by a factor of 10 to take account of accidental ingestion rates as opposed to deliberate ingestion

            ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality ndash recreational values (TCE only)

            Human health in non-use scenarios ndash vapour flux Refer to the VIRA in Section 9

            Notes As there are no specific guidelines for industrial water these values are considered likely to be protective of this additional beneficial use The NHMRC (2008) guidelines are based on drinking water levels and assume a consumption factor of 2 L per day Therefore as recommended in the NHMRC (2008) document potable criteria (ie with the exception of aesthetic criteria) need to be adjusted by a factor of 10 to account for an accidental consumption rate of 100 to 200 ml per day As noted in ANZECCARMCANZ (2000b) although recreational guidelines are protective of ingestion recreational waters should also not contain any chemicals that can cause skin irritation likewise although not specifically addressed by recreational water criteria inhalation may also represent a source of exposure with respect to some (ie volatile) contaminants In the absence of a NHMRCNRMMC (2011) drinking water guideline for TCE the ANZECCARMCANZ (2000b) recreational criterion (30 microgL) has been adopted However if the NHMRC (2008) rule of multiplying potable (healthshybased) guidelines by 10 is applied to the WHO (2017) drinking water guideline of 20 microgL a recreational guideline of 200 microgL would be more applicable

            62 Soil vapour

            The ASC NEPM (1999) interim soil vapour health investigation levels (HILs) for volatile organic chlorinated compounds (VOCCs) have been adopted (ie in the first instance ndash refer to Section 7331) as Tier 1 soil vapour assessment criteria ndash relevant land use scenarios within the Thebarton EPA Assessment Area include residential (HIL AB) and commercialindustrial (HIL D)

            These criteria have been further adjustedappended for the purposes of the VIRA Tier 1 assessment ndash refer to Section 94

            80607-1 REV1 30102017 PAGE 29

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            7 RESULTS

            71 Surface and sub surface soil conditions

            711 Field observations

            Groundwater well and soil vapour borehole log reports are included in Appendices H to J and provide details of the soil profile encountered at each sampling location

            Where encountered fill materials extended to depths of between 01 and 09 m BGL and included a range of different soil types (sand gravelcrushed rock silt) with only minimal waste inclusions (ie asphalt glass andor metal fragments) identified at some locations

            The underlying natural soil profile (encountered to the maximum drill depth of 19 m BGL) was dominated by low to medium plasticity brown to red-brown silty clays and sand claysclayey sands some of which contained sub-angular to rounded gravels that included river pebbles andor comprised fine distinct lenses in places Groundwater well MW17 also included a 15 m thick layer of gravel at depth (ie 12 to 135 m BGL) ndash ie consistent with the depth of groundwater within the Q1 aquifer

            During the course of the drilling works no odours or visual indicators of contamination were detected and measured PID readings ranged up to 6 ppm but were generally lt3 ppm

            712 Soil geotechnical testing

            A table of geotechnical testing results is presented in Appendix L (Table 1) and a copy of the certified laboratory report is included in Appendix G Photographs of soil cores are included in Appendix N

            The results were interpreted to indicate the following

            The soil core samples submitted for PSD analysis were dominated by clay with lesser amounts of fine to medium gravel andor fine to coarse-grained sand ndash all samples analysed were classified as either CLAY or Sandy CLAY with one sample classified as Clayey SAND The classifications obtained from the laboratory were deemed to be generally consistent with the descriptions on the groundwater well log reports (Appendix H) although the PSD results did not specify silt as a significant secondary component

            The moisture content of the analysed soil core samples ranged from 65 to 231 Moisture content with respect to soil type depth and location has been considered in more detail for the purposes of the VIRA (Section 9) The degree of saturation for the analysed soil cores samples ranged from 218 to 964

            Measured bulk density ranged from 160 to 212 tm3 specimen dry density from 141 to 184 tm3 and specific gravity from 255 to 281 tm3

            The measured void ratio ranged from 043 to 088 whereas porosity ranged from 032 to 047

            80607-1 REV1 30102017 PAGE 31

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            72 Waterloo Membrane Samplerstrade A table of WMStrade analytical results (ie from both rounds of sampling) is presented in Appendix L (Table 2) and copies of certified laboratory reports are included in Appendix G8

            Of the 41 WMStrade units deployed across the Thebarton EPA Assessment Area during the two sampling rounds 20 returned measurable concentrations of CHC including TCE PCE cis-12-DCE trans-12-DCE andor 11-DCE Although no VC was detected the laboratory LOR in all samples (ie 35 to 50 microgm3) was above the ASC NEPM (1999) soil vapour interim HIL for residential land use (30 microgm3) ndash refer also to Table 53

            Detectable COPC concentrations are summarised in Table 71 relative to the ASC NEPM (1999) soil vapour interim HILs along with the closest soil vapour bore andor groundwater monitoring well locations Measured TCE concentrations are detailed on Figure 3

            A comparison of the Round 1 and 2 WMStrade results (ie for closely located units9) is presented in Table 72 ndash the results indicate a general order of magnitude correlation of the results for most COPC with the exception of PCE for which lower concentrations were obtained during Round 2 As the Round 1 and 2 WMStrade units were located within different soil bores and deployed at different times some variability in the results is to be expected In addition and as discussed in Section 74 the WMStrade units have been used during this assessment as a (semi-quantitative) screening tool (ie to assist with the siting of the permanent soil vapour bores) with the results obtained from the soil vapour bores considered more representative of actual subsurface conditions

            Table 71 Detectable Waterloo Membrane Samplertrade CHC results

            Sample ID

            Location Closest land uses

            CHC concentration (microgm3) Closest soil vapour bore

            andor groundwater

            well

            TCE PCE cis-12shyDCE

            trans-12shyDCE

            11shyDCE

            VC

            WMS 1 Goodenough Street CI 35 -

            WMS 6 Maria Street CI 32 -

            WMS 7 Maria Street CI and R 1900 45 SV2 MW5

            WMS 8 Maria Street CI and R 12000 37 SV4

            WMS 11 Admella Street CI 71000 260 19 20 36 SV5 MW02

            WMS 14 George Street CI 46000 45 SV6 MW11

            WMS 18 Admella Street CI 4200 34 MW14

            WMS 19 Albert Street CI 11000 42 SV10MW15

            WMS 21 Chapel Street CI 10 -

            WMS 22 Admella Street CI 38 SV9

            WMS 24 Chapel Street CI 230 62 10 11 48 MW17

            8 Note that the original laboratory report for the Round 1 WMStrade samples was found to be incorrect (ie following receipt of the soil vapour bore and Round 2 WMStrade sample results) and was subsequently re-issued by SGS

            9 only two of which were sufficiently co-located for comparative purposes ndash Round 2 locations WMS 39 and WMS 41 were not within the immediate vicinity of Round 1 WMStrade bores (ie the closest Round 1 bores were approximately 30 m away)

            PAGE 32 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Sample ID

            Location Closest land uses

            CHC concentration (microgm3) Closest soil vapour bore

            andor groundwater

            well

            TCE PCE cis-12shyDCE

            trans-12shyDCE

            11shyDCE

            VC

            WMS 25 Albert Street CI and R 1400 20 MW17

            WMS 27 Light Terrace CI 64 62 SV11 MW19

            WMS 32 Holland Street R 16 -

            WMS 34 James Street R 11 -

            WMS 37 Dew Street R 44 -

            WMS 38 Maria Street CI and R 13000 56 SV2 MW5

            WMS 39 Maria Street CI and R 1300 SV4

            WMS 40 Admella Street CI 110000 97 SV5 MW02

            WMS 41 George Street CI 18000 10 SV7 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

            Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform (up to 530 microgm3) was also detected in WMS 8 WMS 11 WMS 14 WMS 16 WMS 18 WMS 19 WM 25 WMS 33 WMS 40 and WMS 41 interim soil vapour health investigation level (HIL)

            Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units

            Bore ID

            Depth (m)

            Location CHC concentration (microgm3)

            TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

            WMS 8 10 Maria Street 12000 37 lt95 lt99 lt22 lt36

            WMS 38 13000 56 lt11 lt11 lt25 lt41

            Relative percentage difference 8 147 - - - -

            WMS 11 10 Admella Street 71000 260 19 20 36 lt37

            WMS 40 110000 97 lt11 lt11 lt25 lt41

            Relative percentage difference 43 91 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

            80607-1 REV1 30102017 PAGE 33

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            73 Groundwater

            731 Field measurements

            A table of groundwater field parameters is presented in Appendix L (Table 3) and groundwater field sampling sheets are included in Appendix E

            7311 Groundwater elevation and flow direction

            The depth to water within the Q1 aquifer beneath the Thebarton EPA Assessment Area on 18 July 2017 ranged from 12323 to 15854 m below top of casing (BTOC)10 and 4469 to 5070 m AHD

            Groundwater elevation contours constructed from the July 2017 gauging data indicated that the overall groundwater flow direction within the Q1 aquifer was north-westerly consistent with expected regional groundwater flow The groundwater contours and inferred flow direction are shown on Figure 4

            7312 Field parameters

            As detailed in Table 51 field measurements were recorded during low flow purging (ie prior to micropurge sampling) of monitoring wells and immediately following the collection of HydraSleeveTM samples

            The field parameter readings recorded for the monitoring wells immediately prior to (low flow micropurge) and after (HydraSleeveTM) sampling indicated the following (as summarised in Table 3 Appendix L)

            groundwater pH ranged from 6 8 to 79 thereby indicating neutral conditions

            electrical conductivity (EC) measurements ranged from 189 to 556 mScm and were found to be reasonably consistent across the area thereby indicating that it is underlain by moderately saline water (ie approximating 1230 to 3620 mgL TDS11)

            redox concentrations ranged from -20 to 624 mV thereby indicating slightly reducing to strongly oxygenating conditions

            measured dissolved oxygen (DO) concentrations ranged from 04 to 78 ppm indicating slightly to highly oxygenated water and

            temperature ranged from 173 to 224oC

            Observations recorded during sampling indicated that the groundwater was clear to brown and only slightly to moderately turbid at most locations ndash the higher turbidity at MW18 and MW19 (combined with poor recharge) contributed towards the decision to use a HydraSleeveTM sampling method No odours or sheen were observed in any of the wells during gauging or sampling

            10 ie approximating m BGL 11 ie calculated by multiplying the field EC data by 065

            PAGE 34 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            732 Hydraulic conductivity

            Rising and falling head aquifer permeability (ldquoslugrdquo) tests were conducted on 10 groundwater wells (refer to Table 31 and Figure 2) to assess the hydraulic conductivity (K) of the Q1 aquifer

            To obtain estimates of near-well horizontal hydraulic conductivity for each well tested the slug test data were analysed by Arcadis using AQTESOLV for Windowstrade (Duffield 2007) following the guidelines presented in Butler (1998) ndash normalised displacement data collected from each test are plotted against time in Appendix A of the Arcadis report (refer to Appendix O) Since only one set of tests were performed at each well the reproducibility of the results as well as the dependence of the results on the initial displacement could not be verified or demonstrated As such multiple relevant and applicable solutions were applied to each test to account for that uncertainty (ie to ensure consistency of normalised response at each well regardless of initial displacement)

            Table 73 presents a summary of the range and average estimated hydraulic conductivity values (and corresponding analytical solutions used) for each well tested The results indicate that hydraulic conductivities ranged from approximately 0073 to 37 mday with an overall average of approximately 1 mday

            Table 73 Hydraulic conductivities (rising and falling head tests)

            Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

            (mday) Hydraulic Conductivity

            (mday)

            MW02 Falling head 011 to 014 DA CBP HV

            012 Rising head 0073 to 015 BR DA

            MW3 Falling head 034 to 062 BR DA

            047 Rising head 030 to 062 BR DA

            MW7 Falling head 075 to 25 BR DA

            139 Rising head 055 to 175 BR DA

            MW14 Falling head 011 to 021 BR DA

            014 Rising head 009 to 015 BR DA

            MW17 Falling head 21 to 22 DA KGS

            220 Rising head 225 to 244 DA KGS

            MW20 Falling head 22 to 37 BR DA HV

            256 Rising head 06 to 32 BR DA

            MW21 Falling head 073 to 123 BR DA

            084 Rising head 054 to 084 BR DA

            MW23 Falling head 088 to 162 BR DA

            101 Rising head 031 to 122 BR DA

            80607-1 REV1 30102017 PAGE 35

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

            (mday) Hydraulic Conductivity

            (mday)

            MW25 Falling head 10 to 18 BR DA CBP HV

            132 Rising head 049 to 17 BR DA

            MW26 Falling head 019 to 036 BR DA

            023 Rising head 010 to 029 BR DA

            Overall average K (mday) 1028 Notes References BR = Bouwer and Rice (1976) CBP = Cooper et al (1967) DA = Dagan (1978) HV = Hvorslev (1951) KGS = Hyder et al (1994)

            The monitoring wells that exhibited lower permeabilities (ie MW02 MW3 MW14 and MW26) were noted to be generally located in the up-gradient (south-eastern) portion of the Thebarton EPA Assessment Area whereas monitoring wells showing relatively higher permeabilities (ie MW7 MW17 MW20 MW21 MW23 and MW25) are generally located in the down-gradient (north-western) portion These results were considered by Arcadis to suggest a possible hydrogeologic transition from the south-east to the north-west AQTESOLV solution plots for each analysis are provided as Appendix A of the Arcadis report (Appendix O)

            As slug test results can be influenced by a number of factors which are difficult to avoid when performing and analysing slug test results hydraulic conductivity estimates derived from slug tests should be considered to be the lower bound of the hydraulic conductivity of the formation in the vicinity of the well (Butler 1998) However Arcadis also noted that the results obtained for the Thebarton EPA Assessment Area were similar to those reported for other areas of Adelaide with average values of 1 and 27 mday (refer to Appendix O)

            The slug test results were used by Arcadis in their groundwater fate and transport model (refer to Section 8)

            733 Analytical results

            Tables of groundwater analytical results are presented in Appendix L (Tables 4 and 5) and copies of certified laboratory reports are included in Appendix G

            7331 Chlorinated hydrocarbon compounds

            A table of CHC results is included in Appendix L (Table 4) and a plan showing their distribution in groundwater beneath the Thebarton EPA Assessment Area is included as Figure 5 Detectable CHC concentrations are summarised in Table 74 relative to the adopted potable and primary contact recreation criteria ndash the closest soil vapour bore locations are also detailed

            PAGE 36 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Table 74 Detectable groundwater CHC results

            Sample ID

            Location CHC concentration (microgL) Closest soil vapour bore

            TCE PCE cis-12shyDCE

            trans-12-DCE

            11-DCE VC Carbon tetrachloride

            MW02 Admella Street 20000 38 7 15 SV5

            MW3 Admella Street 69 SV1

            MW5 Maria Street 29000 3 21 2 6 SV2 SV3

            MW6 Maria Street 29 SV4

            MW9 Albert Street 2 -

            MW11 George Street 4900 3 4 1 7 SV6 SV7

            MW12 George Street 700 SV8

            MW14 Admella Street 1000 4 2 SV9

            MW15 Albert Street 180 SV10

            MW17 Chapel Street 24 -

            MW18 Dew Street 5 -

            MW20 Light Terrace 70 SV12

            MW21 Light Terrace 23 SV13

            MW23 Dew Street 21 -

            MW25 Smith Street 2 5 -

            MW26 Kintore Street 2 -

            Potable 20 50 60 30 03 3

            Primary contact recreation

            30 500 600 300 30 30

            Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Chloroform was also detected in a number of wells (MW02 MW3 MW5 MW8 MW11 MW12 and MW19 to MW25) ndash refer to Table 4 in Appendix L Although no VC was detected the laboratory LOR (1 microgL) exceeded the adopted potable criterion NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from WHO (2017) Guidelines for Drinking-water Quality NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

            The results indicate that the highest TCE concentrations (20000 to 29000 microgL) were measured in wells MW02 and MW5 located in the immediate vicinity of the former Austral property and that the TCE plume extends in a general north-westerly direction (ie consistent with the inferred groundwater flow direction

            80607-1 REV1 30102017 PAGE 37

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            within the Q1 aquifer) Although lesser concentrations of PCE 12-DCE (cis- andor trans) andor 11-DCE were present in some wells no VC was detected and the main COPC was identified as TCE

            A number of wells within the Thebarton EPA Assessment Area contained TCE concentrations that exceeded the adopted potable andor primary contact recreation criteria Although the extent of the TCE plume was not delineated to the north-west (but was delineated in all other directions) with detectable TCE concentrations (ie up to 21 microgL) identified beneath both Smith Street and Dew Street these concentrations were below the adopted primary contact recreation criterion (but not necessarily the adopted potable value ndash ie MW23)

            The background well (MW4) located across James Congdon Drive (to the east of the southern portion of the Thebarton EPA Assessment Area) did not contain any measurable CHC concentrations

            7332 Other measured groundwater parameters

            Major cations and anions

            The laboratory results obtained for the remaining groundwater analytes are summarised in Appendix L (Table 5)

            The groundwater ionic data obtained from selected wells across the Thebarton EPA Assessment Area are graphically represented on a Piper diagram in Figure 71 The results indicate a relatively consistent groundwater composition across the area thereby indicating that the groundwater sampled from these wells is derived from a single aquifer Ionic charge balance ranged from 32 to 22 with the highest value (22) calculated for MW12 indicating that additional anions (ie not measured as part of this study) could be present

            PAGE 38 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Figure 71 Piper diagram

            Natural attenuation parameters

            With respect to the measured natural attenuation parameters (ie DO nitrate iron sulfate CO2 and manganese) the following wells were selected based on their locations relative to the inferred extent of the CHC plume

            MW26 located on Kintore Street to the south (and hydraulically up-gradient) of the former Austral property (ie the suspected source site)

            MW02 and MW5 located within the immediate vicinity of the former Austral property and the area of maximum CHC contamination

            MW9 MW12 and MW17 located on Albert Street George Street and Chapel Street respectively to the north-west (and hydraulically down-gradient) of the former Austral property

            80607-1 REV1 30102017 PAGE 39

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            MW21 and MW22 located on Light Terrace and Cawthorne Street respectively to the northshywestnorth-north-west (and further hydraulically down-gradient) of the former Austral property and

            MW8 and MW23 located on Smith Street and Dew Street respectively representing the furthest wells to the northnorth-west of the former Austral property

            According to Wiedemeier et al (1998) the most important process in the degradation of CHC is the process of reductive dechlorination Although daughter products of TCE (ie 12-DCE) are present in groundwater (and soil vapour) at scattered locations within the Thebarton EPA Assessment Area they are not considered indicative of substantial breakdown of TCE ndash refer also to the Arcadis report in Appendix O as summarised in Section 8 In addition the analysis of the natural attenuation parameters data constituting physical and chemical indicators of biodegradation processes has not provided a definitive secondary line of evidence

            74 Soil vapour bores A table of soil vapour bore analytical results is presented in Appendix L (Table 6) and a copy of the certified laboratory report is included in Appendix G

            Of the soil vapour bores installed to 10 andor 30 m BGL within the Thebarton EPA Assessment Area the majority (ie with the exception of the 10 m deep bores installed as SV11 and SV13 and located on Light Terrace) returned measurable concentrations of CHC dominated by TCE and to a lesser extent (and only at some locations) PCE Detectable soil vapour CHC concentrations are summarised in Table 75 whereas CHC concentrations and inferred soil vapour TCE concentration contours are detailed on Figures 6 (1 m BGL) and 7 (3 m BGL)

            The TCE results which have been used to predict indoor air concentrations as part of the VIRA (refer to Section 9) suggest the following

            the highest concentration (1000000 microgL) was detected at 3 m BGL in soil vapour bore SV3 located in the vicinity of residential and commercialindustrial properties (including the former Austral property) on Maria Street

            where nested wells were tested soil vapour CHC concentrations were higher at depth consistent with a groundwater source

            TCE PCE and 11-DCE are all assumed to represent primary contaminants with 12-DCE representing a break-down product of TCE andor PCE

            although no VC was detected the laboratory LOR in some samples (ie up to 490 microgm3 in samples with the highest measured TCE concentrations) was above the ASC NEPM (1999) interim soil vapour HIL for residential land use (30 microgm3) ndash refer to Table 53 and

            although the extent of the soil vapour plume has apparently not been delineated (ie in any direction) by the existing soil vapour bores it extends in a north-westerly direction (and hydraulically down-

            PAGE 40 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            gradient) from the suspected source site (ie the former Austral property) and corresponds well with the groundwater TCE plume (refer to Figure 5)

            A comparison of the results obtained for the WMStrade units (WMS 38 to WMS 41) deployed during the second round of sampling and the closest soil vapour bore data (10 m BGL) is provided in Table 76 Although the results indicate good correlation for TCE and PCE in SV5WMS 40 as well as TCE in SV7WMS 41 the remaining results were more variable ndash this supports the use of the WMStrade units as an initial (semishyquantitative) screening tool with follow-up soil vapour bore data considered to provide more quantitative results

            Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area

            Bore ID

            Depth (m)

            Location Closest land

            uses

            CHC concentration (microgm3)

            TCE PCE cis-12shyDCE

            trans-12-DCE

            11-DCE VC

            SV1 10 Admella Street CI and R 6300 78

            30 21000 21

            SV2 10 Maria Street CI and R 51000 39 21 39

            30 940000

            SV3 10 Maria Street CI and R 210000 6500 5900

            30 1000000 15000 14000

            SV4 10 Maria Street CI and R 17000 31

            30 43000 90 30

            SV5 10 Admella Street CI 100000 84

            30 160000 310 20 33

            SV6 10 George Street CI 22000 12

            30 150000 56

            SV7 10 George Street CI 22000 19

            30 110000

            SV8 10 George Street CI 2300 62

            30 14000 19

            SV9 10 Chapel Street CI 170

            30 260

            SV10 10 Albert Street CI 93

            30 51

            SV12 10 Light Terrace CI 16

            30 55 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

            Notes Shaded cells indicate concentrations were below the laboratory LOR

            80607-1 REV1 30102017 PAGE 41

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Where (field andor laboratory) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform was also detected in a number of samplesinterim soil vapour health investigation level (HIL)

            Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores

            Bore ID

            Depth (m)

            Location CHC concentration (microgm3)

            TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

            SV2 10 Maria Street 51000 39 21 lt13 39 lt89

            WMS 38 13000 56 lt11 lt11 lt25 lt41

            Relative percentage difference 119 150 - - - -

            SV4 10 Maria Street 17000 31 lt18 lt14 lt14 lt92

            WMS 39 1300 lt52 lt11 lt11 lt25 lt41

            Relative percentage difference 172 - - - - -

            SV5 10 Admella Street 100000 84 lt44 lt33 lt33 lt22

            WMS 40 110000 97 lt11 lt11 lt25 lt41

            Relative percentage difference 95 14 - - - -

            SV7 10 George Street 22000 19 lt37 lt27 lt27 lt18

            WMS 41 18000 10 lt11 lt11 lt25 lt41

            Relative percentage difference 20 62 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

            PAGE 42 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            8 GROUNDWATER FATE AND TRANSPORT MODELLING

            Arcadis were commissioned by Fyfe to undertake preliminary fate and transport modelling of the groundwater CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained groundwater data The Arcadis report is included as Appendix O

            The aim of the modelling was to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton area in order that potential future groundwater restrictions could be applied by the EPA (ie via the potential future definition of a GPA) to protect human health

            81 Groundwater flow modelling

            The MODFLOW code a publicly-available groundwater flow simulation program developed by the United States Geological Survey (USGS) as described by McDonald and Harbaugh (1988) was used to construct a groundwater flow model It was developed for a horizontal area of approximately 25 km2 (ie to minimise possible boundary effects within the assessment area itself12) and was rotated 45deg counter-clockwise to align with the prevailing (north-westerly) groundwater flow direction The model extended approximately 23 km in a south-east to north-west direction and approximately 11 km in a south-west to north-east direction (ie perpendicular to groundwater flow) Whereas a 4 m grid spacing was used within the area of the plume and its migration pathway (ie to enhance model accuracy and precision) a broader 15 m grid was adopted outside the specific area of interest Vertically the model adopted a single 20 m thick layer as representative of the hydrostratigraphy of the Q1 aquifer sediments beneath the area but it was noted that only the bottom portion (ie few metres) of this model layer are actually saturated and therefore active in the model

            An informal sensitivity analysis performed as part of the model calibration process indicated that the model was most sensitive to changes in hydraulic conductivity and recharge ndash this was not unexpected given the relatively flat hydraulic gradient and relatively narrow range of estimated values for both model parameters (ie based on reasonably low uncertainty) The final calibrated value for aquifer recharge adopted in the model was 295 mmyear consistent with results reported for nearby sites as well as regional estimates Likewise the final calibrated hydraulic conductivity values for the up-gradient (06 mday) and down-gradient (2 mday) zones were consistent with both the site-specific slug test data and results obtained for other nearby EPA assessment areas The final calibrated down-gradient constant head elevation was 15 m AHD It was concluded by Arcadis that the groundwater flow model was well calibrated and could therefore serve as an appropriate basis for the development of a site-specific solute transport model

            82 Solute transport modelling

            A site-specific (three-dimensional) solute transport model using the MT3DMS transport code of Zheng (1990) was developed by Arcadis to predict the fate and transport of groundwater contaminants (specifically

            12 Further information regarding boundary effects is provided in the Arcadis report (Appendix O)

            80607-1 REV1 30102017 PAGE 43

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            CHC) under current conditions over a period of 100 years This dual-domain mass transport model was used in conjunction with the groundwater flow model developed through the use of MODFLOW (as detailed above) assuming the following

            The primary COPC is TCE ndash the initial concentration distribution of TCE in groundwater was based on the recent (July 2017) monitoring data

            The age of the groundwater TCE plume was assumed to be up to about 90 years ndash ie based on the history of industrial land use (specifically the former Austral facility) in the area

            Although lesser amounts of other CHC are present in groundwater the lack of significant daughter products of TCE has been interpreted to indicate that substantial biodegradation is not occurring (ie as a conservative approach)

            Although a CHC source was not explicitly incorporated into the solute transport model the MT3DMS transport code indirectly accounts for on-going contaminant mass contribution to the dissolved-phase plume

            The fate and transport of TCE within the area of interest involves the processes of advection adsorption dilution and diffusion ndash however given that recharge via the infiltration of precipitation was considered to be insignificant dilution effects were assumed to be minimal

            Two porosity values (ie dual domain) are relevant to the movement of contaminants in the subshysurface with adopted values based on site-specific geology and Payne et al (2008) ndash whereby the two domains are in equilibrium

            ― mobile porosity that portion of the formation with the highest permeability where advective transport dominates ndash assumed to be 5 (high) 10 (intermediate) or 15 (low) for different mobility transport conditions and

            ― immobile porosity lower permeability portions of the formation where diffusion is dominant ndash assumed to be 15

            As discussed in Section 732 hydraulic conductivity values of 06 mday (south-eastern approximate quarter of the modelling area) and 2 mday (northern approximate three-quarters of the modelling area) were adopted to reflect the hydrogeologic transition (ie from the south-east to the north-west) interpreted from the slug test data

            The adopted TCE retardation factor of 147 for intermediate mobility transport conditions was based on the following

            ― an assumed organic carbon fraction of 01 (US EPA 1996 amp 2009) ndash this was varied to 005 and 2 to assess alternate (ie high versus low) mobility transport conditions

            ― an assumed organic carbon adsorption co-efficient of 61 Lkg (US EPA 2017a)

            PAGE 44 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            ― a calculated partition co-efficient of 0061 Lkg ndash this was varied to 129 and 178 Lkg to assess alternate (ie high versus low) mobility transport conditions and

            ― an average soil bulk density of 192 gcm3 (based on measured geochemical data ndash refer to Table 1 Appendix L)

            An optimum mass transfer co-efficient (MTC) was based on simulated flux distribution in the groundwater flow model whereby

            ― the calculated MTC in the model ranged from approximately 38E-08day-1 to 37E-05 day-1 and

            ― the average MTC was 185E-05day-1

            The site-specific solute transport model was used in predictive mode to assess the long-term (eg 100 year) potential migration of the groundwater TCE plume and to support the EPA in the potential future definition of an appropriate GPA The model was calibrated against the current extent (ie concentrations of TCE above 1 microgL have migrated approximately 500 m from the suspected source site13) and expected age (ie up to about 90 years) of the plume The results indicate that the leading edge of the TCE (ie the 1 microgL contour) is estimated to migrate between approximately 400 and 620 m over a period of 100 years under low to high mobility transport conditions14 with intermediate transport conditions resulting in an estimated migration of 500 m By comparison no significant lateral plume expansion would be expected to occur Figures 5 to 17 of the Arcadis report (Appendix O) show the predicted extent of the TCE plume at 5 10 50 and 100 years under low to high mobility transport conditions

            Figure 81 shows the predicted extent of the 1 microgL TCE boundary in 100 years under intermediate transport conditions ndash it is recommended that this information be used to support the EPA in establishing a potential future GPA

            The Arcadis report notes that given the available site information (site history potential source area(s) and uncertainty associated with the current plume extent) and degree of model calibration (flow model parameter values are consistent with site-specific data as well as regionalnearby studies while transport parameter values are consistent with literatureindustry standards) the model-predicted migration of approximately 500 m over 100 years is considered to be a reasonable representation of future conditions

            Key uncertainties associated with the modelling were identified as including the following

            current plume extents (ie down-gradient delineation)

            site-specific fraction organic values (or site-specific partition coefficient estimates) and

            site-specific porosity estimates

            13 although it was noted that there is uncertainty with respect to the current extent of the TCE plume since all three down-gradient monitoring wells (MW18 MW23 and MW25) have TCE concentrations above 1 μgL

            14 ie assuming different values for mobileimmobile porosity the TCE distribution (sorption) coefficient and the TCE retardation factor

            80607-1 REV1 30102017 PAGE 45

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Lesser uncertainties were considered to include site-specific bulk hydraulic conductivity estimates and determination of the presence or absence of naturally-occurring TCE degradation

            Additional site investigation and data collection (eg multi-well pumping tests for bulk hydraulic conductivity estimates site-specific fraction organic carbon andor distribution (sorption) coefficient additional down-gradient plume delineation) would help to further refine the model and increase confidence in the predictive results

            Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green) relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple)

            PAGE 46 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            9 VAPOUR INTRUSION RISK ASSESSMENT

            Arcadis were commissioned by Fyfe to undertake a Vapour Intrusion Risk Assessment (VIRA) of the soil vapour CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained (ie August 2017) permanent soil vapour bore data The Arcadis report is included as Appendix P

            91 Objective

            The main objective of the VIRA was to evaluate the potential risk to human health from vapour intrusion related to the concentrations of CHC identified in soil vapour within the Thebarton EPA Assessment Area

            92 Areas of interest

            The following areas of specific interest (ie located within the Thebarton EPA Assessment Area) were identified for the purpose of this VIRA

            commercialindustrial properties (assumed slab on grade construction) including the former Austral property (ie the suspected source site) and

            residential properties (slab on grade crawl space and basement constructions)

            Potential exposure by trenchmaintenanceutility workers has also been considered (qualitatively)

            93 Risk assessment approach

            The VIRA was conducted in accordance with the ASC NEPM (1999) enHealth (2012a) and other relevant Australian guidance documents as well as guidance documents issued by the US EPA and other international regulatory agencies (where applicable)

            The conduct of the risk assessment was based on a multiple lines of evidence approach using the available site-specific information collected as part of the scope of works detailed in Section 32

            The following information was used as a basis for the VIRA

            CHC including TCE PCE and DCE (11- cis-12- and trans-12-) have been identified within soil vapour andor groundwater within the Thebarton EPA Assessment Area ndash the analytical data indicate that TCE constitutes between about 95 and 100 of the CHC identified in groundwater and soil vapour

            TCE has been considered as the risk driver for the VIRA (ie based on its toxicity and concentrations in soil vapour and groundwater) ndash although TCE PCE 12-DCE 11-DCE and VC have all been included as COPC for the Tier 1 screening assessment (Section 94) the Tier 2 assessment (Section 95) has

            80607-1 REV1 30102017 PAGE 47

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            concentrated on TCE PCE and 11-DCE (ie due to their presence at concentrations that exceeded the adopted Tier 1 screening criteria)

            The CHC identified within the Thebarton EPA Assessment Area are volatile chemicals and could potentially pose a risk to human health via the vapour intrusion pathway Although the source area has yet to be confirmed the CHC concentrations observed in groundwater and soil vapour are considered likely to have originated from the former Austral property (as discussed in Section 12)

            The natural soils underlying the fill material (where present) in the Thebarton EPA Assessment Area are typified by the Quaternary age soils and sediments of the Adelaide Plains with the Pooraka Formation and Hindmarsh Clay units considered to dominate the upper soil profile

            The soil geotechnical data and soil vapour results collected by Fyfe (as discussed in Sections 712 and 74 respectively) have been used for the VIRA

            A two-tier approach was adopted for the VIRA The first tier (herein referred to as the Tier 1 assessment) was conducted by comparing the measured soil vapour TCE concentrations to published guideline values adjusted (conservatively) to account for attenuation from sub-slab soil into indoor air The second tier (herein referred to as the Tier 2 assessment) involved the comparison of predicted indoor air TCE concentrations to adopted indoor air criteria or response levels

            94 Tier 1 assessment

            As detailed in Section 74 the initial Tier 1 (screening risk) assessment involved comparing measured soil vapour COPC concentrations with the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land uses (refer to Table 74) Given that the development of the interim soil vapour HILs was based on very conservative assumptions the initial Tier 1 assessment provided only a first-pass screening assessment of the data to determine if further risk assessment would be required

            The interim soil vapour HILs are applicable for the assessment of soil vapour at 0 to 1 m beneath the floor of a building They were based on adopted toxicity reference values (TRV) and relevant exposure parameters (ie adjusted for different land uses) as well as an assumed soil vapour to indoor air attenuation factor of 01

            The soil vapour to indoor air attenuation factor (01) was based on the US EPA (2002) recommended default attenuation factors for the generic screening step of a tiered vapour intrusion assessment process As discussed in the US EPA (2002) document the default attenuation factor of 01 for sub-slab soil vapour was based on a US EPA database of empirical attenuation factors calculated using measurements of indoor air and soil vapours from different sites In 2012 the US EPA provided an updated database which was accompanied by an evaluation and statistical analysis of attenuation factors for volatile CHC in residential buildings US EPA (2012) found the sub-slab to indoor air attenuation factor of 003 to be the 95th percentile In 2015 the revised sub-slab attenuation factor (003) was adopted by the US EPA

            PAGE 48 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            The revised sub-slab to indoor air attenuation factor of 003 was adopted to derive modified residential and commercialindustrial soil vapour HILs for the Tier 1 assessment The modified residential soil vapour HILs are presented in Table 91 relative to the maximum CHC concentrations obtained for soil vapour within the Thebarton EPA Assessment Area

            The Tier 1 assessment based on a comparison of the COPC concentrations measured in soil vapour at various locations within the Thebarton EPA Assessment Area with the modified residential soil vapour HILs detailed in Table 91 indicated the following

            TCE concentrations exceeded the adopted criterion in SV1 to SV9 whereas

            the concentrations of PCE and 11-DCE exceeded the adopted criteria in SV3 only

            These locations were identified as requiring further assessment (ie Tier 2 VIRA ndash refer to Section 95)15

            Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs

            Compound ASC NEPM (1999) HIL

            (microgm3)

            Modified Tier 1 HIL (microgm3)

            (AF = 003)

            Maximum measured soil vapour concentration (microgm3)

            Acceptable

            Location 1 m BGL Location 3 m BGL

            11-DCE 7000 SV3 5900 SV3 14000 No ndash Tier 2 required

            cis-12-DCE 80 265 SV2 21 SV4 30 Yes

            trans-12-DCE 80 265 - ND SV5 20 Yes

            PCE 2000 6650 SV3 6500 SV3 15000 No ndash Tier 2 required

            TCE 20 65 SV3 210000 SV3 100000 0

            No ndash Tier 2 required

            VC 30 100 - ND - ND Yes Notes Values in bold exceed the modified residential soil vapour HILs cis-12-DCE HIL adopted as surrogate screening criterion based on US EPA (2017b) regional screening level for residential air elevated laboratory LOR (ie above modified Tier 1 HIL) also reported Abbreviations AF = attenuation factor HIL = health investigation level ND = non detect

            95 Tier 2 assessment

            951 Tier 2 assessment criteria

            The Tier 2 VIRA criteria for the residential zone comprise HIL-based residential indoor air criteria for the COPC (refer to Section 94) along with the residential indoor air level response ranges for TCE that were

            15 Note that all locations were subjected to the Tier 2 VIRA in this assessment

            80607-1 REV1 30102017 PAGE 49

            EPA REF 0524111 FINAL REPORT

            STAGE 1 ENVIRONMENTAL ASSESSMENT

            THEBARTON ASSESSMENT AREA

            initially developed by the EPA and SA Health for the EPA Assessment Area at Clovelly Park and Mitchell

            Park These screening criteria and indoor air response ranges as detailed in SA EPA (2014) and

            reproduced in Figure 91 are now widely adopted in South Australia for the assessment of TCE relating

            to indoor air exposure

            Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels

            Note The no action response level is applicable where a soil vapour concentration is below the laboratory LOR (ie ND or ldquonon-

            detectrdquo assumed to be lt01 microgm3)

            PAGE 50 80607-1 REV1 | 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            952 Vapour intrusion modelling

            For this VIRA exposure point concentrations (EPCs) of COPC in the indoor air of buildings with a slab on grade crawl space or basement construction were estimated using conservative screening assumptions and the Johnson and Ettinger (1991) vapour transport and mixing model (ie the JampE model)

            The algorithms applied in the JampE (1991) model are detailed in Appendix A of the Arcadis report whereas the modelling spreadsheets for each scenario are provided in Appendix B ndash the Arcadis report is attached to this report as Appendix P

            9521 Input parameters

            The input parameters adopted for the vapour intrusion modelling relate to the following

            the construction type and details of existing or proposed buildings ndash refer to Table 92 for adopted building input parameters

            the nature of the soil profile ndash refer to Table 93 for adopted soil input parameters (0 to 1 m BGL) and

            the contaminant source concentrations ndash refer to Table 6 in Appendix L

            Table 92 Tier 2 vapour intrusion modelling ndash building input parameters

            Parameter Units Adopted value Reference

            Residential Commercial industrial

            Width of Building cm 1000 2000 Friebel and Nadebaum (2011)

            Length of Building cm 1500 2000

            Height of Room cm 240 300

            Height of crawl space cm 30 - Assumption for crawl space

            Attenuation from basement to ground floor air

            - 01 01 Friebel and Nadebaum (2011)

            Air Exchange Rate (AER)

            Indoor per hour 06 083 Friebel and Nadebaum (2011)

            Crawl space per hour 06 - Friebel and Nadebaum (2011)

            Basement per hour 06 - As per residential (indoor)

            Fraction of Cracks in Walls and foundation

            - 0001 0001 Friebel and Nadebaum (2011)

            Qsoil cm 3s 300 277 Calculated from QsoilQbuilding ratio of 0005 (residential) and 0001 (commercial)

            80607-1 REV1 30102017 PAGE 51

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters

            Parameter Units Adopted value Reference

            Depth cm 100 Depth of shallow soil vapour data

            Total porosity - 047 Site specific geotechnical data ndash ie averaged from MW3 and MW11 shallow samples (refer to Table 1 in Appendix L) Air filled porosity - 030

            Water filled porosity - 017 Notes ie representing a conservative approach whereby data for the shallow samples with the highest total porosity and lowest degree of saturation (and therefore the highest air filled porosity) have been adopted

            The site specific attenuation factors calculated within the vapour intrusion models (Appendix B of the Arcadis report) are summarised in Table 94 These are chemical and depth specific values applicable to each building construction scenario These attenuation factors have been applied to the soil vapour data measured across the Thebarton EPA Assessment Area to calculate indoor air concentrations (residential properties only) in proximity to each soil vapour location ndash for commercialindustrial properties (slab on grade) indoor air concentrations have only been calculated with respect to the soil vapour data obtained for SV3 (ie the soil vapour bore with the highest measured TCE concentrations)

            Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air

            Scenario Attenuation factor

            Residential ndash slab on grade 706 x 10-4

            Residential ndash crawl space 209 x 10-3

            Residential ndash basement 113 x 10-1

            Commercial ndash slab on grade 408 x 10-4

            Notes ie soil vapour intrusion to indoor air of residential living spaces refer to Section 953 for a discussion of potential vapour intrusion risks associated with commercialindustrial properties

            The chemical parameters of the COPC adopted in the JampE model were updated with data from the chemical database in the Risk Assessment Information System (RAIS 2016) as detailed in Table 95

            Table 95 Summary of chemical parameters adopted for vapour intrusion modelling

            Chemical Diffusivity in Air Diffusivity in Water Solubility Henryrsquos Law Molecular weight (Dair) Water (Dwater) (S) Constant 25oC (gmol)

            (cm2s) (cm2s) (mgL) (unitless)

            11-DCE 00863 0000011 2420 107 969

            PCE 00505 000000946 206 0724 166

            TCE 00687 00000102 1280 0403 131

            PAGE 52 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            9522 Predicted indoor air concentrations

            Residential The predicted indoor air concentrations for each soil vapour data point as calculated by Arcadis for the three residential building scenarios (ie slab on grade crawl space and basement) are presented in Appendix C of the Arcadis report (included in this report as Appendix P)

            Table 96 provides a comparison of predicted indoor air concentrations against the EPA response levels detailed in Section 951 (Figure 91) ndash ie using the 1 m soil vapour data space for slab on grade and crawl space scenarios versus the 3 m soil vapour data for basements

            It should be noted that if residential properties within the Thebarton EPA Assessment Area have basements however the vapour intrusion risks will increase whereas slab on grade construction will carry a lesser vapour intrusion risk (as detailed in Table 96)

            Commercialindustrial The predicted indoor air concentrations as calculated by Arcadis for a commercialindustrial (ie slab on grade) land use scenario with respect to the soil vapour data obtained for SV3 (ie maximum measured soil vapour concentrations) are as follows

            11-DCE 3 microgm3

            PCE 19 microgm3 and

            TCE 86 microgm3

            As these values are not directly comparable to the EPA response levels developed for residential land use further discussion of potential vapour intrusion risks to human health under a commercialindustrial land use

            scenario is included in Section 953

            As discussed for residential properties the vapour intrusion risks may increase if basements are present

            80607-1 REV1 30102017 PAGE 53

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Table 96 Comparison of predicted residential indoor air concentrations with SA EPA response levels

            Indoor Air Concentration Ranges (microgmsup3) SA EPA response levels

            non-detect No action

            gt non-detect to lt2 Validation

            2 to lt20 Investigation

            20 to lt200 Intervention

            ge200 Accelerated Intervention

            Soil vapour bore

            Sample depth

            (m)

            Soil vapour TCE concentration

            (microgmsup3)

            Predicted indoor air concentration (microgmsup3)

            Residential scenario

            Slab on grade Crawl space Basement

            Attenuation factor

            7 x 10-4 2 x 10-3 1 x 10-1

            SV1 10 5700 4 11

            SV1 30 21000 2100

            SV2 10 51000 36 102

            SV2 30 890000 89000

            SV2 (FD) 30 940000 94000

            SV3 10 210000 147 420

            SV3 30 1000000 100000

            SV4 10 17000 12 34

            SV4 30 43000 4300

            SV5 10 100000 70 200

            SV5 30 160000 16000

            SV6 10 22000 15 44

            SV6 (FD) 10 22000 15 44

            SV6 30 150000 15000

            SV6 (FD) 30 140000 14000

            SV7 10 22000 15 44

            SV7 30 110000 11000

            SV8 10 2300 2 5

            SV8 30 14000 1400

            SV9 10 170 012 030

            SV9 30 260 26

            SV10 10 9 0007 0019

            SV10 30 51 51

            SV11 10 lt18 - -

            SV12 10 16 0011 0032

            SV12 30 55 55

            SV13 10 lt21 - -

            PAGE 54 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Notes With respect to the predicted indoor air CHC concentrations in the Arcadis VIRA report (refer to Appendix P) the results in Table 5 were calculated for SV3 using the unrounded attenuation factors presented in Appendix B (and Table 94 of this report) whereas the TCE indoor air concentrations in Appendix C (as summarised in Table 96) were calculated using rounded attenuation factors ndash this does not change the overall interpretation of the results Abbreviations FD = field duplicate

            9523 Sensitivity analysis

            Table 97 presents a qualitative sensitivity analysis for some of the input variables used in the modelling ndash it includes the range of practical values for each variable the value used in the risk assessment the relative model sensitivity and the uncertainty associated with the variable

            Although Arcadis note that a number of parameters used within the risk assessment have a moderate degree of uncertainty associated with them thereby suggesting that the modelling may be sensitive to changes in these parameters values used to define these parameters were selected to be conservative This is considered to have resulted in an assessment which is expected to be conservative and to over-estimate actual risk

            Table 97 Summary of model input parameters subjected to sensitivity analysis

            Input Range of values Value adopted Sensitivity of calculated input parameters variable

            Soil physical parameters

            Total porosity

            Varies by soil type generally 03 to 05

            047 Site-specific

            Indoor air concentrations will decrease with increasing total porosity Moderate sensitivity parameter decreasing by 50 will increase predicted concentration by a factor of 4

            Air filled porosity

            Varies by soil type generally 015 to 03

            03 Site-specific

            Indoor air concentrations will increase with increasing air filled porosity Moderate to high sensitivity parameter reduction by 50 decreases concentration by a factor of 10

            Water filled porosity

            Varies by soil type from 005 (fill or

            sand) to 03 (clay)

            017 Site-specific

            Negligible impact on predicted indoor air concentrations although may decrease with increasing moisture content Very low sensitivity parameter

            Building parameters

            Air exchange rate (AER)

            Varies from 05 hr-1

            in smaller buildings to gt2 hr-1

            06 hr-1 for residential structures

            083 hr-1 for commercial

            Indoor air concentrations will decrease with increasing air exchange Moderate sensitivity parameter has linear relationship with predicted concentrations conservative assumptions used

            80607-1 REV1 30102017 PAGE 55

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Input Range of values Value adopted Sensitivity of calculated input parameters variable

            Advective flow rates

            Varies depending on building size and

            AER

            300 cm3sec Calculated from building AER and

            ratio of 0005

            Indoor air concentrations will increase with increasing advective flow Low sensitivity parameter particularly within normal range of potential values The assumption that advective flow is occurring into a building at all times is generally conservative for Australian settings Advection is unlikely to occur under a crawl space home and diffusive transport is the dominant transport mechanism

            Building size Variable Variable consistent with

            Friebel and Nadebaum (2011)

            Indoor air concentrations decrease with increasing building volume

            Very low sensitivity parameter

            9524 Uncertainties

            The following uncertainties were identified in the Arcadis report (Appendix P)

            Vapour transport modelling

            The use of a model to predict the migration of vapour from a sub-surface source to indoor air requires the simplification of many complex processes in the sub-surface as well as the potential for entry and dispersion within a building or outdoor air To address this simplification the vapour models available (and adopted in this assessment) are considered to be conservative such that uncertainties are addressed through the overshyestimation of likely concentrations

            It should be noted that the vapour model used is designed to be a first tier screening tool and is considered likely to over-estimate air concentrations due to the incorporation of a number of conservative assumptions including the following

            chemical concentrations in soil vapour were assumed to remain constant over the duration of exposure (ie it was assumed that the source was non-depleting and not subject to natural biodegradation processes)

            the maximum reported soil vapour concentrations were assumed to be present beneath nearby dwellings and

            the occurrence of steady well-mixed vapour dispersion within the enclosed or ambient mixing space

            Overall the vapour modelling undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

            PAGE 56 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Toxicological Data

            In general the available scientific information involves the extrapolation of toxicity information from studies involving experimental laboratory animals with some validation of observable health effects obtained through epidemiological studies

            This may introduce two types of uncertainties into the risk assessment as follows

            those related to extrapolating from one species to another and

            those related to extrapolating from the high exposure doses usually used in experimental animal studies to the lower doses usually estimated for human exposure situations

            In order to adjust for these uncertainties toxicity values commonly incorporate safety factors that may vary from 10 to 10000

            Overall the toxicological data presented in this assessment are considered to be current and adequate for the assessment of risks to human health associated with potential exposure to the COPC identified The uncertainties inherent in the toxicological values adopted are considered likely to result in an over-estimation of actual risk

            953 Potential vapour intrusion risks associated with commercialindustrial properties

            An assessment of potential vapour intrusion risks to workers at commercialindustrial properties (slab on grade construction) within the Thebarton EPA Assessment Area was undertaken by Arcadis using the methodology published by US EPA (2009) and incorporated into the ASC NEPM (1999) This approach recommends adjustment of the measured or estimated contaminant concentrations in air to account for site specific exposures by the relevant receptors as follows

            Ca ET EF EDECinh = days hours AT 365 24 year day

            Where

            ECinh = Exposure Adjusted Air Concentration (mgm3) Ca = Chemical Concentration in Air (mgm3) ET = Exposure Time (hoursday) EF = Exposure Frequency (daysyear) ED = Exposure Duration (years) AT = Averaging Time (years)

            = 70 years for non-threshold carcinogens = ED for chemicals assessed based on threshold effects

            80607-1 REV1 30102017 PAGE 57

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Exposure parameters were selected from Australian sources (enHealth 2012b ASC NEPM 1999) for the receptor groups evaluated or were based on site specific factors Table 98 presents an overview of the parameters used whereas adopted inhalation TRVs are presented in Table 99

            Risk was characterised for threshold and non-threshold effects for the COPC ndash spreadsheets presenting the risk calculations are provided in Appendix B of the Arcadis report (as included in Appendix P) For commercialindustrial properties the non-threshold risk level was calculated to be 3 x 10-5 (compared to a target risk level of 1 x 10-5) whereas the threshold risk level was calculated to be 10 (compared to a target risk level of 1) ndash these results indicated a potentially unacceptable vapour intrusion risk to commercialindustrial workers in the vicinity of the maximum soil vapour CHC concentrations (ie at SV3 ndash worst-case scenario based on maximum soil vapour concentrations)

            Table 98 Exposure parameters ndash Commercialindustrial workers

            Exposure parameter Units Value Reference

            Exposure frequency days year 365 ASC NEPM (1999)

            Exposure duration years 30 ASC NEPM (1999)

            Exposure time indoors hoursday 8 ASC NEPM (1999)

            Averaging time

            Non-threshold

            threshold

            Years

            years

            70

            30 ASC NEPM (1999)

            Table 99 Adopted inhalation toxicity reference values

            COPC Toxicity reference values

            Non-threshold (microgm3)

            Reference Threshold (microgm3)

            Reference

            11-DCE NA - 80 ATSDR (1994)

            PCE NA - 200 WHO (2006)

            TCE 41 US EPA (2011) IRIS 2 US EPA (2011) IRIS Notes Abbreviations NA = not applicable

            954 Potential risks to trenchmaintenanceutility workers

            Although trenchmaintenanceutility workers may be exposed to soil vapour concentrations as measured at 1 m BGL due to the short-term nature of such works their total intakes of TCE and other CHC will be low Assuming that a trenchmaintenanceutility worker may be exposed to TCE for a limited number of working days throughout the year (eg 20 days of 8 hours duration within an excavation) their intake will be approximately one fiftieth of the intake of a resident (who is assumed to be exposed 21 hours a day for 365 days a year)

            PAGE 58 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Therefore the management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air)

            96 Conclusions

            On the basis of the available data and the assessment presented in the Arcadis VIRA report (Appendix P) the following conclusions were provided

            Health risks for residents due to the intrusion of CHC in soil vapour into residential buildings with a slab on grade crawl space or basement construction were calculated to be above the adopted EPA response levels and risks to residents may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

            Health risks for commercial workers due to the intrusion of CHC in soil vapour into buildings with a slab on grade construction were calculated to be above the adopted target risk levels and risks to workers may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

            In the absence of specific information regarding building construction within the Thebarton EPA Assessment Area the predicted indoor air concentrations calculated from the 1 m BGL soil vapour data for a residential crawl space scenario are summarised in Table 910

            Table 910 Summary of properties with predicted indoor air concentrations (residential crawl space) above adopted EPA response levels

            EPA response level No of residential properties affected Indoor air concentration (microgm3) Response

            non-detect to lt2 Validation 9

            2 to lt20 Investigation 10

            20 to lt200 Intervention 8

            ge200 Accelerated intervention 3 Notes According to information provided by the EPA there are approximately 130 residential properties located in the Thebarton EPA Assessment Area calculated on the basis of cadastral boundaries ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial facility ndash these data would therefore need to be confirmed via a property survey

            80607-1 REV1 30102017 PAGE 59

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            10 CONCEPTUAL SITE MODEL

            As detailed in Table 101 a CSM has been developed for the Thebarton EPA Assessment Area on the basis of historical information (as summarised in Section 12 as well as Appendices A and B) and the data obtained during the recent Fyfe investigation program

            Table 101 Summary of existing information for the Thebarton EPA Assessment Area

            Topic Summarised Information

            Site Characterisation

            Identification of Assessment Area

            An approximately 27 ha Assessment Area located within the suburb of Thebarton has been defined by the EPA The boundaries of this area are detailed in Section 21 and illustrated on Figure 1

            History of land use Properties located within the Thebarton EPA Assessment Area have been used for a mixture of commercialindustrial and low density residential land uses over time Current commercialindustrial properties include a beverage factory in the north-eastern portion of the assessment area a refrigeration equipment facility a car dealership two hotels (at least one of which has a cellarbasement) automotive and other workshops and the Ice Arena Former commercialindustrial activities have been identified as including a gas works a mechanicrsquos workshop sheet metal working facilities and a farm machinery manufacturer

            Historical investigations

            Reports provided to Fyfe by the EPA that pertain to previous investigations undertaken within the Thebarton EPA Assessment Area have been reviewed and summarised in Appendix A Additional historical information is included in Appendix B

            Local geology Natural soils encountered from the surfacenear surface to the maximum drill depth of 19 m BGL across the Thebarton EPA Assessment Area were considered to be indicative of the Quaternary Pooraka and Hindmarsh Clay formations Whereas fill materials (ie sand gravelcrushed rock andor silt) were encountered to depths of up to 09 m BGL at a number of sampling locations underlying natural soils comprised mainly low to medium plasticity silty or sandy clays with variable gravel contents Geotechnical testing of subsurface soil samples collected from 10 drill cores indicated that the PSD comprised predominantly claysilt with lesser components of sand andor gravel ndash these soil samples were mostly classified as Clay although some were classified as Sandy Clay or Clayey Sand According to Stapledon (1971) the Hindmarsh Clay unit typically contains many structural features and defects which greatly influence its permeability thereby resulting in potential preferential pathways for the vertical and lateral movement of soil vapour and groundwater Such features were not specifically observed during the recent drilling and soil logging work although some gravel lenseslayers were identified

            Hydrogeology In accordance with Gerges (2006) and his classification of the Adelaide metropolitan area into a number of zones based on their individual hydrogeological characteristics the Thebarton EPA Assessment Area is located within Zone 3 (subzone 3E) to the west of the Para Fault It contains five to six Quaternary aquifers and three or four Tertiary aquifers Based on the most recent investigations the depth to water within the Q1 aquifer in the Thebarton EPA Assessment Area ranges from approximately 123 to 159 m BGL and groundwater flows in a general north-westerly direction with a relatively flat hydraulic gradient (000062 to 00012) Salinity levels (based on field EC readings) range from approximately 1230 to 3620 mgL TDS and a groundwater flow velocity range of approximately 44 to 23 myear has

            80607-1 REV1 30102017 PAGE 61

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Topic Summarised Information

            been inferred As detailed in Section 222 a search of the DEWNR (2017) WaterConnect database identified 59 bores within the general Thebarton area of which 18 are located within the Thebarton EPA Assessment Area Although (where recorded) bores were listed as having been installed primarily for monitoring investigation or observation purpose other purposes (for presumed Quaternary aquifer bores) included drainage domestic and industrial A BUA has identified realistic groundwater uses as potentially including potable residential irrigation and primary contact recreationaesthetics Based on proximity to the River Torrens freshwater ecosystem protection has also been considered ndash however since the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area this may not be a realistic beneficial use Since volatile contaminants have been detected within the Q1 aquifer a potential vapour flux risk to future site users has also been considered

            Hydrology No surface water bodies have been identified within the Thebarton EPA Assessment Area The closest surface water body is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west Current stormwater run-off within the Thebarton EPA Assessment Area is expected to be collected by localised (and engineered) drainage systems

            Fyfe Investigation Results

            Groundwater impacts Contaminants identified in groundwater beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected source site (ie the former Austral sheet metal works) in accordance with the predominant flow direction associated with the Q1 aquifer (refer to Figures 4 and 5) The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) but its north-western extent has not yet been determined (whereas its extent has been defined in all other directions)

            Soil vapour impacts Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction (refer to Figures 6 and 7) and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion The soil vapour samples with the maximum TCE concentrations (ie SV3_10m and SV3_30m) also had the highest PCE and 11-DCE concentrations (or elevated LOR) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-) Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE (ie SV2_30m SV3_10m SV3_30m and SV7_30m) exceeded the adopted HILs for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE

            PAGE 62 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Topic Summarised Information

            degradation has not yet resulted in its production (ie at measureable levels) Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

            Potential Exposure Pathways

            Contaminants of Based on the results of historical investigations the EPA identified a number of CHC as being of Potential Concern concern for the Thebarton EPA Assessment Area The main COPC was identified as TCE with

            additional COPC including PCE 12-DCE (cis- and trans-) VC and 11-DCE Further detail is provided in Section 14 These COPC were confirmed by the Fyfe investigations with TCE identified as both the main contaminant in groundwater and soil vapour and the main driver in terms of potential human health risks associated with vapour intrusion into buildings within the Thebarton EPA Assessment Area (refer to Section 9)

            Suspected source and The suspected source of the identified CHC groundwater (and soil vapour) impacts within the affected media Thebarton EPA Assessment Area is the former Austral sheet metal works located over multiple

            allotments between George and Maria Streets from the 1920s until the 1960s-1970s Previous investigations (Appendix A) had identified groundwater CHC impacts on part of this suspected source site The Fyfe investigations have concentrated on impacts within groundwater and soil vapour across the Thebarton EPA Assessment Area both of which generally correlate with the inferred north-westerly groundwater flow direction and are considered to be related to the previously identified dissolved phase groundwater CHC impacts

            Sensitive receptors The following sensitive receptors have been identified as potentially relevant to the Thebarton EPA Assessment Area Ecological groundwater ecosystems within the assessment area extending to at least Dew and Smith

            Streets (ie as the north-western extent of the groundwater CHC plume has not yet been determined) and

            the freshwater ecosystem of the River Torrens located at a distance of approximately 07 km in a hydraulically down-gradient (ie north-westerly) direction but not necessarily representing a groundwater receiving environment

            Human current and future occupants of and visitors to residential properties current and future workers on the source site and other commercialindustrial properties

            within the area current and future underground trenchmaintenanceutility workers and down-gradient groundwater bore users

            Contaminant Possible contaminant transport mechanisms associated with the CHC-impacted groundwater transport identified within the Q1 aquifer beneath the Thebarton EPA Assessment Area include mechanisms flow through the aquifer to a hydraulically down-gradient surface water body andor down-

            gradient groundwater bores vapour generation andor flow via subsurface preferential pathways (eg service trenches

            more permeable soils) and downward movement into underlying aquifers (eg dense non-aqueous phase liquid

            (DNAPL))

            80607-1 REV1 30102017 PAGE 63

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Topic Summarised Information

            Exposure Possible exposure mechanisms associated with impacted groundwater within the Thebarton mechanisms EPA Assessment Area include

            direct contact (eg during extractionuse of groundwater) incidental ingestion (eg during extractionuse of groundwater) and inhalation of vapours (eg during extractionuse of groundwater andor as a result of

            vapour intrusion into buildings)

            Assessment of Risk

            Groundwater risks The recent groundwater analytical results have indicated that the Q1 aquifer beneath the Thebarton EPA Assessment Area contains measurable concentrations of CHC (mainly TCE but also including PCE 12-DCE andor 11-DCE at some locations) Measured concentrations of TCE exceeded the adopted assessment criteria for potable andor primary contact recreation in wells MW02 MW3 MW5 MW6 MW11 MW12 MW14 MW15 MW17 MW20 MW21 and MW23 located on Admella Maria George Albert and Dew Streets as well as Light Terrace with maximum concentrations corresponding to the ldquocorerdquo area of the plume One well (MW25) contained a concentration of carbon tetrachloride that exceeded the adopted potable criterion Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

            Groundwater fate Although scattered detectable concentrations of 12-DCE have been measured in groundwater and transport across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE modelling daughter products has been interpreted to indicate that substantial dechlorination is not

            occurring Groundwater fate and transport modelling (refer to Section 8 and Appendix O) has predicted that the likely extent of the dissolved phase groundwater TCE plume over the next 100 years will extend by another 500 m beyond the boundaries of the current Thebarton EPA Assessment Area However no significant lateral plume expansion is expected

            Vapour intrusion risks A VIRA (refer to Section 9 and Appendix P) was undertaken to assess potential risks to human health from the intrusion of CHC vapours (primarily TCE) into indoor air from soil vapour The predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction in the absence of specific structural information) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and therefore require further action as follows 10 properties within the investigation range (2 to lt20 microgm3) eight properties within the intervention range (20 to lt200 microgm3) and three properties within accelerated intervention range (ge200 microgm3) All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3

            (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as

            PAGE 64 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Topic Summarised Information

            selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which are expected to be overly-conservative) ndash these results will be documented in a subsequent report Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed Management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air)

            Complete Exposure Pathways

            Identified pathways and areas of potential risk

            Based on the results of the recent Fyfe investigations (including the VIRA) and taking into account available historical information (Appendices A and B) and DEWNR (2017) WaterConnect bore information the following complete exposure pathways and associated risks are considered possible for the Thebarton EPA Assessment Area exposure (direct contact incidental ingestion andor inhalation of vapours) during use of

            groundwater for domestic (eg drinking water plumbing garden irrigation) andor recreational (eg filling of swimming poolsspas) purposes

            vapour intrusion into indoor air within 30 residential propertieslocated within the vicinity of soil vapour bores SV1 to SV9 (assuming crawl space construction) ndash although 19 of these properties are predicted to be in the validationinvestigation action level range 11 are predicted to be in the intervention action level range (with actual indoor air monitoring results for properties within the intervention action level range pending)

            vapour intrusion into residential cellarsbasements (if present) in the vicinity of soil vapour bores SV1 to SV10 and SV12 and

            vapour intrusion into the indoor air of commercialindustrial properties ndash although actual risks to site workers would require further specific considerationassessment

            In addition although only assessed in a qualitative manner to date trenchmaintenanceutility workers may also be at risk where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

            Notes calculated on the basis of cadastral boundaries and assuming crawl space construction ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial premises a property survey would be required to confirm building construction details and the number of individual residences affected

            80607-1 REV1 30102017 PAGE 65

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            11 CONCLUSIONS

            Between May and August 2017 Fyfe undertook an investigation of groundwater and soil vapour CHC impacts within an EPA-designated Assessment Area located in Thebarton South Australia The results of the investigation have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties A CSM has been developed from the field analytical and modelling results as presented in Section 10

            The following conclusions have been reached

            Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were present within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m in groundwater well MW17

            Groundwater within the Q1 aquifer is located at a depth of approximately 123 to 159 m BGL and flows in a general north-westerly direction (refer to Figure 4) ndash the closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred16 and the groundwater gradient beneath the Thebarton EPA Assessment area is relatively flat (ie 000062 to 00012)

            Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified to include domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux as assessed by the VIRA) and possibly also potable Although freshwater ecosystem protection was also considered the River Torrens is thought to comprise either a recharge boundary (ie discharging to local groundwater) or to not actually be hydraulically connected to the Q1 aquifer in this area

            Groundwater beneath parts of the Thebarton EPA Assessment Area contains detectable concentrations of various CHC and includes TCE and carbon tetrachloride (one location only) levels that exceed the adopted assessment criteria for potable use andor primary contact recreation ndash thereby indicating that groundwater would be unsuitable for drinking or the filling of swimming poolsspas In addition vapour flux could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the groundwater could be odorous

            16 ie as calculated by Fyfe based on available data

            80607-1 REV1 30102017 PAGE 67

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            The groundwater and soil vapour CHC impacts identified beneath parts of the Thebarton EPA Assessment Area are considered likely to have emanated from the former Austral sheet metal works located over multiple allotments between George and Maria Streets from the 1920s until the 1960sshy1970s The possible presence of on-going (primary andor secondary) source(s) at this property has not yet been investigated

            As depicted on Figures 6 and 7 the current extent of the soil vapour CHC (ie dominated by TCE) impacts has been determined to correspond to the mapped distribution of the groundwater TCE impacts (Figure 5) and is considered to be directly related to groundwater (rather than soil) CHC impacts Although no soil vapour impacts were detected at 1 m BGL in SV11 and SV1317 located near the eastern and western ends of Light Terrace respectively the north-western extents of the groundwater and soil vapour CHC impacts have not yet been determined In addition although the extent of the groundwater TCE plume has been delineated in all other directions the soil vapour TCE plume has not been delineated in any direction

            TCE is considered to be a primary contaminant as well as the dominant (ie in terms of concentration and extent) CHC in both groundwater and soil vapour ndash the presence of PCE and 11-DCE suggests however that more than one primary contaminant is present Although the detectable concentrations of 12-DCE (cis- and trans) are considered to have resulted from the breakdown of TCEPCE no VC has been detected in either groundwater or soil vapour ndash the scattered distribution and relatively low concentrations of 12-DCE as well as the absence of measurable VC have been interpreted to indicate that significant dechlorination of the primary contaminants has not occurred (despite the likely age of the plume ndash ie possibly up to about 90 years old)

            Although the COPC adopted for the soil vapour assessment program included various CHC (ie with TCE identified as the dominant contaminant in groundwater and soil vapour) the Tier 1 VIRA confirmed that TCE PCE and 11-DCE all exceeded the adopted vapour intrusion HILs Based primarily on its greater toxicity however the risk driver for the Thebarton EPA Assessment Area is considered to be TCE

            The VIRA (Tier 2) results for predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and that require further action as follows

            ― 10 properties within the investigation range (2 to lt20 microgm3)

            ― eight properties within the intervention range (20 to lt200 microgm3) and

            ― three properties within accelerated intervention range (ge200 microgm3)

            All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming

            17 noting that the laboratory LOR for TCE was elevated as compared to the other soil vapour samples

            PAGE 68 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises ndash refer to Table 96

            Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentration obtained for soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

            Although only assessed in a qualitative manner trenchmaintenanceutility workers may be at risk in areas where TCE concentrations at 1 m BGL are greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) ndash in this case appropriate management measures would be required to be adopted This should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

            80607-1 REV1 30102017 PAGE 69

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            12 DATA GAPS

            Based on the results obtained during the recent Fyfe investigations as well as available historical information (Appendices A and B) the following data gaps have been identified for the Thebarton EPA Assessment Area

            property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

            groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

            the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

            the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

            80607-1 REV1 30102017 PAGE 71

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            13 REFERENCES

            ANZECCARMCANZ (2000a) Australian Guidelines for Water Quality Monitoring and Reporting

            ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

            ASTM (2001) Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations ASTM Guide D7663-12

            ASTM (2006) Standard Guide for Soil Gas Monitoring in the Vadose Zone ASTM Guide D5314-92

            ATSDR (1994) Toxicological profile ndash 11-Dichloroethene httpswwwatsdrcdcgovToxProfilestpaspid=722amptid=130

            AustralianNew Zealand Standard (1998) Water Quality Sampling Part 1 Guidance on the Design of Sampling Programs Sampling Techniques and the Preservation and Handling of Samples ASNZS 566711998

            AustralianNew Zealand Standard (1998) Water Quality Sampling Part 11 Guidance on Sampling of Groundwaters ASNZS 5667111998

            Bouwer H and Rice RC (1976) A Slug Test Method for Determining Hydraulic Conductivity of Unconfined Aquifers with Completely or Partially Penetrating Wells Water Resources Research vol 12 no 3 pp 423-428

            Butler JJ Jr (1998) The Design Performance and Analysis of Slug Tests

            Cooper HH Bredehoeft JD and Papadopulos SS (1967) Response of a Finite-Diameter Well to an Instantaneous Charge of Water Water Resources Research vol 3 no 1 pp 263-269

            CRC CARE (2013) Petroleum Hydrocarbon Vapour Intrusion Assessment ndash Australian Guidance CRC CARE Technical Report No 23 July 2013

            Dagan G (1978) A Note on Packer Slug and Recovery Tests in Unconfined Aquifers Water Resources Research vol 14 no 5 pp 929-934

            Department of Environment Water and Natural Resources (DEWNR 2017) Water Connect Master Register of All Bores Primary Industries and Resources South Australia

            Duffield G (2007) AQTESOLVreg Professional Version 45 Hydrosolve Inc

            enHealth (2012a) Environmental Health Risk Assessment - Guidelines for assessing human health risks from environmental hazards enHealth Council

            enHealth (2012b) Australian Exposure Factor Guidance Handbook enHealth Council

            Environment Protection Act 1993

            80607-1 REV1 30102017 PAGE 73

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            Environment Protection Regulations 2009

            Friebel E and Nadebaum P (2011) Health Screening Levels for Petroleum Hydrocarbons in Soil and Groundwater CRC CARE Technical Report No 10

            Gerges NZ (1999) The Geology and Hydrogeology of the Adelaide Metropolitan Area Flinders University (South Australia) PhD thesis (unpublished)

            Gerges NZ (2006) Overview of the Hydrogeology of the Adelaide Metropolitan Area DWLBC Report 200610

            Golder Associates (1994) Contamination Assessment George Street Thebarton SA Report to United Land dated 9 December 1994

            Hvorslev MJ (1951) Time Lag and Soil Permeability in Ground-Water Observations Bulletin no 36 Waterways Exper Sta Corps of Engrs US Army Vicksburg Mississippi pp 1-50

            Hyder Z Butler JJ Jr McElwee CD and Liu W (1994) Slug Tests in Partially Penetrating Wells Water Resources Research vol 30 no 11 pp 2945-2957

            ITRC (2007) Vapor Intrusion Pathway - A Practical Guidance

            Johnson PC and Ettinger RA (1991) Heuristic Model for Predicting the Intrusion Rate of Contaminant Vapors

            into Buildings Environ Sci Technology 251445-1452

            McDonald M G and Harbaugh A W (1988) A Modular Three-Dimensional Finite-Difference Ground-Water Flow Model Techniques of Water-Resources Investigations Book 6 Chapter A1 U S Geological Survey

            NEPM (1999) National Environment Protection (Assessment of Site Contamination) Measure Schedules B1 to

            B9 National Environment Protection Council Australia

            NHMRC (2008) Guidelines for Managing Risks in Recreational Water

            NHMRCNRMMC (2011) Australian Drinking Water Guidelines (as revised in 2016)

            NJDEP (2013) Site Remediation Program Vapor Intrusion Technical Guidance (Version 31)

            NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme (2nd edition)

            Payne FC Quinnan JA and Potter ST (2008) Remediation Hydraulics CRC Press Boca Raton FL

            RAIS (2016) Chemical Specific Parameters for Trichloroethylene Risk Assessment Information System Office of Environmental Management US Department of Energy

            REM (2005a) George St Thebarton Site ndash Stage 2 Investigations Report to Luca Group dated 26 August 2005

            REM (2005b) Stage 3 Environmental Site Assessment George St Thebarton SA Report to Luca Group dated 23 November 2005

            SA Department of Mines and Energy (1969) 1250000 Adelaide Geological Map Sheet Sheet S1 54-9

            PAGE 74 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            SA EPA (2007) Regulatory Monitoring and Testing Groundwater Sampling

            SA EPA (2009) Guidelines for the Assessment and Remediation of Groundwater Contamination

            SA EPA (2014) Clovelly Park Mitchell Park Project Management Team Assessment Program Flip Book November 2014

            SA EPA (2015) Environment Protection (Water Quality) Policy

            Standards Australia (1993) Geotechnical Site Investigations AS1726-1993

            Standards Australia (2005) Guide to the Sampling and Investigation of Potentially Contaminated Soil Part 1 Non-Volatile and Semi-Volatile Compounds AS44821-2005

            Stapledon DH (1971) Changes and Structural Defects Developed in some South Australian Clays and their Engineering Consequences Proceedings of Symposium on Soils and Earth Structures in Arid Climates Adelaide 1970

            US EPA (1996) Soil Screening Guidance Technical Background Document Office of Emergency and Remedial Response Washington DC EPA540R95128

            US EPA (1999) Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air Second Edition Compendium Method TO-15 Determination Of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed By Gas Chromatography Mass Spectrometry (GCMS) EPA625R-96010b

            US EPA (2002) OSWER Draft Guidance for Evaluating the Vapour Intrusion to Indoor Air Pathway from Groundwater and Soils (Subsurface Vapour Intrusion Guidance) EPA530-D-02-004

            US EPA (2009) EPArsquos Risk-Screening Environmental Indicators (RSEI) Methodology Office of Pollution Prevention and Toxics Washington DC

            US EPA (2011) IRIS (Integrated Risk Information System) Trichloroethylene Chemical Assessment Summary httpscfpubepagovnceairisiris_documentsdocumentssubst0199_summarypdf

            US EPA (2012) EPArsquos Vapor Intrusion Database Evaluation and Characterization of Attenuation Factors for Chlorinated Volatile Organic Compounds and Residential Buildings

            US EPA (2015) OSWER Technical Guide for Assessing and Mitigating the Vapour Intrusion Pathway from Subsurface Vapour Sources to Indoor Air

            US EPA (2017a) Regional Screening Levels (RSLs) - Generic Tables (June 2017) httpswwwepagovriskregional-screening-levels-rsls-generic-tables-june-2017

            US EPA (2017b) Regional Screening Levels for Chemical Contaminants at Superfund Sites httpwwwepagovreg3hwmdriskhumanrb-concentration_tableGeneric_Tablesindexhtm

            80607-1 REV1 30102017 PAGE 75

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            WHO (2006) Air Quality Guidelines for Europe Second Edition WHO Regional Publications European Series No 91

            WHO (2017) Guidelines for Drinking-water Quality Fourth edition (incorporating the first addendum)

            Wiedemeier T Swanson M Moutoux D Gordon E Wilson J Wilson B Kampbell D Haas P Miller R Hansen J and Chapelle F (1998) Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water National Risk Management Research Laboratory Office of Research and Development US EPA

            Zheng C (1990) MT3D A Modular Three-Dimensional Transport Model for Simulation of Advection Dispersion and Chemical Reactions of Contaminants in Groundwater Systems Prepared for US EPA by Robert S Kerr Environmental Research Laboratory Ada Oklahoma developed by SS Papadopulos amp Associates Inc Rockville Maryland

            PAGE 76 80607-1 REV1 30102017

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            14 STATEMENT OF LIMITATIONS

            The opinions and conclusions presented in this report are specific to the conditions of the Thebarton EPA Assessment Area and the state of legislation currently enacted as at the date of this report Fyfe does not make any representation or warranty that the opinions and conclusions in this report will be applicable in the future as there may be changes in the condition of the Thebarton EPA Assessment Area applicable legislation or other factors that would affect the opinions and conclusions contained in this report

            Fyfe has used the degree of skill and care ordinarily exercised by reputable members of our profession practising in the same or similar locality This report has been prepared for the South Australian Environment Protection Authority for the specific purpose identified in the report Fyfe accepts no liability or responsibility to any third party for the accuracy of any information contained in the report or any opinion or conclusion expressed in the report Neither the whole of the report nor any part or reference thereto may be in any way used relied upon or reproduced by any third party without Fyfersquos prior written approval This report must be read in its entirety including all tables and attachments

            80607-1 REV1 30102017 PAGE 77

            EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

            FIGURES

            Figure 1 Site Location and Assessment Area

            Figure 2 Assessment Point Locations

            Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan

            Figure 4 Groundwater Elevation Contour Plan

            Figure 5 Groundwater Concentration Plan

            Figure 6 Soil Vapour Concentration Plan (10m)

            Figure 7 Soil Vapour Concentration Plan (30m)

            80607-1 REV1 30102017 PAGE 79

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            DEW

            STREET

            DEW

            STREET

            CHAPEL STREETCHAPEL STREET

            PAR

            KER

            STREET

            PAR

            KER

            STREET

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            LIGHT TERRACELIGHT TERRACE

            DEW

            STREET

            DEW

            STREET

            WA

            LSH ST

            WA

            LSH ST

            AD

            MELLA

            STREET

            AD

            MELLA

            STREET

            ALB

            ERT STR

            EETA

            LBER

            T STREET

            HO

            LLAN

            D ST

            REET

            HO

            LLAN

            D ST

            REET

            RANDOLPH STREET

            RANDOLPH STREET

            JAM

            ES STREET

            JAM

            ES STREET

            DOVE STREET

            DOVE STREET

            SMITH STREETSMITH STREET

            MARIA STREETMARIA STREET

            GEORGE STREETGEORGE STREET

            KINTORE STREET

            KINTORE STREET

            PORT ROAD

            PORT ROAD

            PORT ROAD

            PORT ROAD

            CAW

            THO

            RN

            E STR

            EETC

            AWTH

            OR

            NE ST

            REET

            DEVON STREETDEVON STREET

            KINTORE STREETKINTORE STREET

            GOODENOUGH STREETGOODENOUGH STREET

            LIVESTR

            ON

            G PATH

            WAY

            LIVESTR

            ON

            G PATH

            WAY

            CCAAWW

            TTHHOO

            RRNN

            EE SSTTRR

            EEEETT

            HHOO

            LLLLAANN

            DD SSTT

            RREEEETT

            DE

            DEW

            SW

            STREET

            TREET

            JJAM

            EA

            MES S

            S STREET

            TREET

            DDOOVVEE SSTTRREEEETT

            LLIIVVEESSTTRR

            OONN

            GG PPAATTHH

            WWAAYY

            LIGHT TERRLIGHT TERRAACECE

            AD

            MELLA

            SA

            DM

            ELLA STR

            EETTR

            EET

            CHAPEL SCHAPEL STREETTREET

            AALLBB

            EERRTT SSTTRR

            EEEETT

            GEGEORORGE SGE STREETTREET

            PPOORRTT RROOAADD

            PPOORRTT RROOAADD

            DDEEWW

            SSTTRREEEETT

            MMAARRIIAA SSTTRREEEETT

            JJAAMM

            EESS CCOO

            NNGG

            DDOO

            NN DD

            RRIIVV

            EE

            WWAA

            LLSSHH SSTT

            SSMMIITTHH SSTTRREEEETT

            RRANDOLPH S

            ANDOLPH STREETTREET

            PPOORR

            TT RROO

            AADD

            PPOORR

            TT RROO

            AADD

            KKIINNTTOORREE SSTTRREEEETT

            KKIINNTTOORREE SSTTRREEEETT

            PPAARR

            KKEERR

            SSTTRREEEETT

            GGOOOODDEENNOOUUGGHH SSTTRREEEETT

            DDEEVVOONN SSTTRREEEETT

            ASSESSMENT AREA

            CBD

            750m

            LEGEND

            EPA ASSESSMENT AREA

            CADASTRE

            12500 A3

            0 25 50 m

            CLIENT

            SA EPA

            PROJECT

            FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

            EPA THEBARTON ASSESSMENT AREA - STAGE 1

            TITLE

            FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

            PROJECT NO DATE CREATED

            80607-1 290917

            80607_Fig 1 - Site Location and Assessment Areaai REV 1 gt 290917

            LE

            VE

            L 1

            12

            4 S

            OU

            TH

            TE

            RR

            AC

            E

            AD

            EL

            AID

            E S

            A 5

            00

            0

            P

            H

            (08

            ) 8

            23

            2 9

            08

            8

            F

            AX

            (0

            8)

            82

            32

            90

            99

            EM

            AIL

            in

            fo

            fyfe

            co

            ma

            u

            W

            EB

            fy

            fec

            om

            au

            AB

            N

            57

            00

            8 1

            16 1

            30

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            DEW

            STREET

            DEW

            STREET

            CHAPEL STREETCHAPEL STREET

            PAR

            KER

            STREET

            PAR

            KER

            STREET

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            LIGHT TERRACELIGHT TERRACE

            DEW

            STREET

            DEW

            STREET

            WA

            LSH ST

            WA

            LSH ST

            AD

            MELLA

            STREET

            AD

            MELLA

            STREET

            ALB

            ERT STR

            EETA

            LBER

            T STREET

            HO

            LLAN

            D ST

            REET

            HO

            LLAN

            D ST

            REET

            RANDOLPH STREET

            RANDOLPH STREET

            JAM

            ES STREET

            JAM

            ES STREET

            DOVE STREET

            DOVE STREET

            SMITH STREETSMITH STREET

            MARIA STREETMARIA STREET

            GEORGE STREETGEORGE STREET

            KINTORE STREET

            KINTORE STREET

            PORT ROAD

            PORT ROAD

            PORT ROAD

            PORT ROAD

            CAW

            THO

            RN

            E STR

            EETC

            AWTH

            OR

            NE ST

            REET

            DEVON STREETDEVON STREET

            KINTORE STREETKINTORE STREET

            GOODENOUGH STREETGOODENOUGH STREET

            LIVESTR

            ON

            G PATH

            WAY

            LIVESTR

            ON

            G PATH

            WAY

            SV1SV1

            SV2SV2

            SV3SV3SV4SV4

            SV5SV5

            SV6SV6

            SV7SV7SV8SV8

            SV9SV9

            SV10SV10

            SV11SV11SV12SV12

            SV13SV13

            MW1MW1

            MW02MW02

            MW3MW3

            MW4MW4MW5MW5MW6MW6

            MW7MW7

            MW8MW8

            MW9MW9

            MW10MW10MW11MW11

            MW12MW12MW13MW13

            MW14MW14MW15MW15

            MW16MW16

            MW17MW17

            MW18MW18

            MW19MW19

            MW20MW20

            MW21MW21

            MW22MW22

            MW23MW23

            MW24MW24

            MW25MW25

            MW26MW26

            WMS2WMS2WMS1WMS1

            WMS3WMS3WMS4WMS4WMS5WMS5

            WMS6WMS6

            WMS7WMS7WMS8WMS8

            WMS9WMS9WMS10WMS10

            WMS11WMS11

            WMS12WMS12

            WMS13WMS13WMS14WMS14

            WMS15WMS15

            WMS41WMS41

            WMS40WMS40

            WMS39WMS39WMS38WMS38

            WMS16WMS16

            WMS17WMS17

            WMS18WMS18WMS19WMS19

            WMS20WMS20

            WMS21WMS21WMS22WMS22

            WMS23WMS23WMS24WMS24

            WMS25WMS25

            WMS26WMS26

            WMS27WMS27WMS28WMS28WMS29WMS29

            WMS30WMS30

            WMS31WMS31

            WMS32WMS32

            WMS33WMS33

            WMS34WMS34

            WMS35WMS35

            WMS36WMS36

            WMS37WMS37

            WWAA

            LLSSHHSSTT

            SSMMIITTHH SSTTRREEEETT

            RRANDOLPH S

            ANDOLPH STREETTREET

            PPOORR

            TT RROO

            AADD

            PPOORR

            TT RROO

            AADD

            CCAAWW

            TTHHOO

            RRNN

            EE SSTTRR

            EEEETT

            JJAM

            EA

            MES S

            S STREET

            TREET

            HHOO

            LLLLAANN

            DDSSTT

            RREEEETT

            DE

            DEW

            SW

            STREET

            TREET

            DDOOVVEE SSTTRREEEETT

            LLIIVVEESSTTRR

            OONN

            GGPPAATTHH

            WWAAYY

            LIGHT TERRLIGHT TERRAACECE

            CHAPEL SCHAPEL STREETTREET

            AALLBB

            EERRTT SSTTRR

            EEEETT

            AD

            MELLA

            SA

            DM

            ELLA STR

            EETTR

            EET

            GEGEORORGE SGE STREETTREET

            PPOORRTT RROOAADD PPOORRTT RROOAADD

            DDEEWW

            SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

            JJAAMM

            EESS CCOO

            NNGG

            DDOO

            NN DD

            RRIIVV

            EE

            KKIINNTTOORREE SSTTRREEEETT

            KKIINNTTOORREE SSTTRREEEETT

            PPAARR

            KKEERR

            SSTTRREEEETT

            GGOOOODDEENNOOUUGGHH SSTTRREEEETT

            DDEEVVOONN SSTTRREEEETT

            FIGURE 2 ASSESSMENT POINT LOCATIONS

            MMWW88

            MW2MW244 WMS3WMS355

            MW2MW255

            WMS3WMS366

            WMS3WMS377

            WMS3WMS311

            MW2MW222WMS34WMS34

            MW2MW233 WMS3WMS322

            WMS3WMS333

            WMS2WMS277WMS2WMS299 WMS2WMS288

            SSV12V12 SSVV1111 MW19MW19

            MW18MW18 SSVV1133 MW2MW200 WMS3WMS300

            MW2MW211 WMS2WMS255

            WMS2WMS266

            MW17MW17 WMS2WMS244

            WMS2WMS233

            WMS2WMS222 WMS2WMS211

            SSVV99

            SSV10V10WMS2WMS200 MW14MW14MW15MW15 WMS18WMS18

            WMS19WMS19 MW16MW16

            WMS13WMS13MW10MW10 WMS14WMS14MMWW1111SVSV77WMS15WMS15SSVV88WMS16WMS16

            SVSV66WMS4WMS411MW13MW13 LEGENDMW12MW12

            WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS17WMS17 WMS40WMS40 SSVV55 MW0MW022MW9MW9 GROUNDWATER MONITORING WELL

            WMS11WMS11 WMS6WMS6 SOIL VAPOUR BORE

            WATERLOO MEMBRANE SAMPLERTM - ROUND 2

            SVSV22WMS8WMS8SVSVWMS12WMS12 44 WMS7WMS7 MW4MW4MMWW SVSV66 33 MW5MW5WMS3WMS388

            WMS3WMS399 MW7MW7 EPA ASSESSMENT AREAWMS10WMS10 WMS9WMS9

            SVSV11 CADASTRE

            MW3MW3

            MW1MW1 WMS3WMS3WMS4WMS4MW2MW266 WMS5WMS5 12500 A3

            0 25 50 m

            CLIENT

            SA EPAWMS1WMS1

            WMS2WMS2 PROJECT

            EPA THEBARTON ASSESSMENT AREA - STAGE 1

            TITLE

            FIGURE 2 ASSESSMENT POINT LOCATIONS

            PROJECT NO DATE CREATED

            80607-1 280917

            80607_Fig 2 - Assessment Point Locationsai REV 1 gt 280917

            LE

            VE

            L 1

            12

            4 S

            OU

            TH

            TE

            RR

            AC

            E

            AD

            EL

            AID

            E S

            A 5

            00

            0

            PH

            (0

            8)

            82

            32

            90

            88

            F

            AX

            (0

            8)

            82

            32

            90

            99

            E

            MA

            IL

            info

            fy

            fec

            om

            au

            W

            EB

            fy

            fec

            om

            au

            A

            BN

            5

            7 0

            08

            116

            13

            0

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            DEW

            STREET

            DEW

            STREET

            CHAPEL STREETCHAPEL STREET

            PAR

            KER

            STREET

            PAR

            KER

            STREET

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            LIGHT TERRACELIGHT TERRACE

            DEW

            STREET

            DEW

            STREET

            WA

            LSH ST

            WA

            LSH ST

            AD

            MELLA

            STREET

            AD

            MELLA

            STREET

            ALB

            ERT STR

            EETA

            LBER

            T STREET

            HO

            LLAN

            D ST

            REET

            HO

            LLAN

            D ST

            REET

            RANDOLPH STREET

            RANDOLPH STREET

            JAM

            ES STREET

            JAM

            ES STREET

            DOVE STREET

            DOVE STREET

            SMITH STREETSMITH STREET

            MARIA STREETMARIA STREET

            GEORGE STREETGEORGE STREET

            KINTORE STREET

            KINTORE STREET

            PORT ROAD

            PORT ROAD

            PORT ROAD

            PORT ROAD

            CAW

            THO

            RN

            E STR

            EETC

            AWTH

            OR

            NE ST

            REET

            DEVON STREETDEVON STREET

            KINTORE STREETKINTORE STREET

            GOODENOUGH STREETGOODENOUGH STREET

            LIVESTR

            ON

            G PATH

            WAY

            LIVESTR

            ON

            G PATH

            WAY

            WMS2WMS2WMS1WMS1

            WMS3WMS3WMS4WMS4

            WMS5WMS5

            WMS6WMS6

            WMS7WMS7WMS8WMS8

            WMS9WMS9

            WMS10WMS10

            WMS11WMS11

            WMS12WMS12

            WMS13WMS13WMS14WMS14

            WMS15WMS15 WMS41WMS41

            WMS40WMS40

            WMS39WMS39WMS38WMS38

            WMS16WMS16

            WMS17WMS17

            WMS18WMS18WMS19WMS19WMS20WMS20

            WMS21WMS21WMS22WMS22

            WMS23WMS23WMS24WMS24

            WMS25WMS25

            WMS26WMS26

            WMS27WMS27WMS28WMS28WMS29WMS29

            WMS30WMS30

            WMS31WMS31

            WMS32WMS32WMS33WMS33

            WMS34WMS34

            WMS35WMS35

            WMS36WMS36

            WMS37WMS37

            WWAA

            LLSSHHSSTT

            SSMMIITTHH SSTTRREEEETT

            RRANDOLPH S

            ANDOLPH STREETTREET

            PPOORR

            TT RROO

            AADD

            PPOORR

            TT RROO

            AADD

            CCAAWW

            TTHHOO

            RRNN

            EE SSTTRR

            EEEETT

            JJAM

            EA

            MES S

            S STREET

            TREET

            HHOO

            LLLLAANN

            DDSSTT

            RREEEETT

            DE

            DEW

            SW

            STREET

            TREET

            DDOOVVEE SSTTRREEEETT

            LLIIVVEESSTTRR

            OONN

            GGPPAATTHH

            WWAAYY

            LIGHT TERRLIGHT TERRAACECE

            AD

            MELLA

            SA

            DM

            ELLA STR

            EETTR

            EET

            AALLBB

            EERRTT SSTTRR

            EEEETT

            CHAPEL SCHAPEL STREETTREET

            GEGEORORGE SGE STREETTREET

            PPOORRTT RROOAADD PPOORRTT RROOAADD

            DDEEWW

            SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

            JJAAMM

            EESS CCOO

            NNGG

            DDOO

            NN DD

            RRIIVV

            EE

            KKIINNTTOORREE SSTTRREEEETT

            KKIINNTTOORREE SSTTRREEEETT

            PPAARR

            KKEERR

            SSTTRREEEETT

            GGOOOODDEENNOOUUGGHH SSTTRREEEETT

            DDEEVVOONN SSTTRREEEETT

            FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

            TCE CONCENTRATION PLAN

            WMS3WMS355 TCE lt78

            WMS3WMS366 TCE lt77WMS3WMS377

            TCE 44

            WMS3WMS311 TCE lt78

            WMS34WMS34 TCE 11

            WMS3WMS322WMS3WMS333 TCE lt78TCE lt79

            WMS2WMS277WMS2WMS299 WMS2WMS288 TCE 64 TCE lt77 TCE lt8

            WMS3WMS300 TCE lt8

            WMS2WMS255

            WMS2WMS266 TCE 1400(D)

            WMS2WMS222 TCE 38 WMS2WMS211

            TCE lt79

            TCE lt78

            WMS2WMS233 WMS2WMS244 TCE lt77

            TCE 230

            WMS2WMS200 WMS19WMS19TCE lt78 WMS18WMS18 TCE 11000

            TCE 4200

            WMS13WMS13 WMS14WMS14 TCE lt79

            WMS4WMS411WMS15WMS15 TCE 46000WMS16WMS16 TCE 18000 LEGENDTCE lt8

            TCE lt78WMS17WMS17 WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS40WMS40TCE lt79

            TCE 110000 WATERLOO MEMBRANE SAMPLERTM - ROUND 2WMS11WMS11

            TCE 71000WMS12WMS12 EPA ASSESSMENT AREA

            CADASTRE

            WMS6WMS6 TCE lt58 WMS8WMS8 WMS3WMS388 TCE 32WMS7WMS7WMS3WMS399

            TCE 12000 TCE 13000 TCE 1900TCE 1300WMS9WMS9 TCE lt58 NotesWMS10WMS10

            All concentrations are in μgm3 TCE lt58

            D = Duplicate result

            WMS3WMS3WMS4WMS4 12500 A3

            LE

            VE

            L 1

            12

            4 S

            OU

            TH

            TE

            RR

            AC

            E

            AD

            EL

            AID

            E S

            A 5

            00

            0

            PH

            (0

            8)

            82

            32

            90

            88

            F

            AX

            (0

            8)

            82

            32

            90

            99

            E

            MA

            IL

            info

            fy

            fec

            om

            au

            W

            EB

            fy

            fec

            om

            au

            A

            BN

            5

            7 0

            08

            116

            13

            0

            TCE lt57WMS5WMS5 TCE lt57 TCE lt58 0 25 50

            m

            CLIENT

            SA EPA

            WMS2WMS2 TCE lt56

            WMS1WMS1 TCE lt56

            PROJECT

            EPA THEBARTON ASSESSMENT AREA - STAGE 1

            TITLE

            FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

            TCE CONCENTRATION PLAN

            PROJECT NO DATE CREATED

            80607-1 241017

            80607_Fig 3 - WMS TCE Concentration Planai REV 1 gt 241017

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            DEW

            STREET

            DEW

            STREET

            CHAPEL STREETCHAPEL STREET

            PAR

            KER

            STREET

            PAR

            KER

            STREET

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            LIGHT TERRACELIGHT TERRACE

            DEW

            STREET

            DEW

            STREET

            WA

            LSH ST

            WA

            LSH ST

            AD

            MELLA

            STREET

            AD

            MELLA

            STREET

            ALB

            ERT STR

            EETA

            LBER

            T STREET

            HO

            LLAN

            D ST

            REET

            HO

            LLAN

            D ST

            REET

            RANDOLPH STREET

            RANDOLPH STREET

            JAM

            ES STREET

            JAM

            ES STREET

            DOVE STREET

            DOVE STREET

            SMITH STREETSMITH STREET

            MARIA STREETMARIA STREET

            GEORGE STREETGEORGE STREET

            KINTORE STREET

            KINTORE STREET

            PORT ROAD

            PORT ROAD

            PORT ROAD

            PORT ROAD

            CAW

            THO

            RN

            E STR

            EETC

            AWTH

            OR

            NE ST

            REET

            DEVON STREETDEVON STREET

            KINTORE STREETKINTORE STREET

            GOODENOUGH STREETGOODENOUGH STREET

            LIVESTR

            ON

            G PATH

            WAY

            LIVESTR

            ON

            G PATH

            WAY

            MW1MW1

            MW02MW02

            MW3MW3

            MW4MW4MW5MW5

            MW6MW6

            MW7MW7

            MW8MW8

            MW9MW9

            MW10MW10MW11MW11

            MW12MW12

            MW13MW13

            MW14MW14

            MW15MW15

            MW16MW16

            MW17MW17

            MW18MW18

            MW19MW19MW20MW20

            MW21MW21

            MW22MW22

            MW23MW23

            MW24MW24

            MW25MW25

            MW26MW26

            WWAA

            LLSSHHSSTT

            SSMMIITTHH SSTTRREEEETT

            4

            466

            PPOORR

            TT RROO

            AADD

            PPOORR

            TT RROO

            AADD

            RRANDOLPH S

            ANDOLPH STREETTREET 4455

            DE

            DEW

            SW

            STREET

            TREET

            JJAM

            EA

            MES S

            S STREET

            TREET

            HHOO

            LLLLAANN

            DD SSTT

            RREEEETT

            CCAAWW

            TTHHOO

            RRNN

            EE SSTTRR

            EEEETT 4477

            DDOOVVEE SSTTRREEEETT

            4455

            4488

            LLIIVVEESSTTRR

            OONN

            GGPPAATTHH

            WWAAYY

            4455

            LIGHT TERRLIGHT TERRAACECE

            AD

            MELLA

            SA

            DM

            ELLA STR

            EETTR

            EET

            4466

            CHAPEL SCHAPEL STREETTREET

            4477 AA

            LLBBEERR

            TT SSTTRREEEETT

            4499

            GR4466 OUND

            FLOW DIREW

            GEGEORORGE SGE STREETTREET ATER C

            4488 TION

            PPOORRTT RROOAADD PPOORRTT RROOAADD 55

            00 DD

            EEWW SSTTRR

            EEEETT 4499

            MMAARRIIAA SSTTRREEEETT

            4477

            5500

            JJAAMM

            EESS CCOO

            NNGG

            DDOO

            NN DD

            RRIIVV

            EE

            88 44

            KKIINNTTOORREE SSTTRREEEETT

            KKIINNTTOORREE SSTTRREEEETT

            PPAARR

            KKEERR

            SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

            5500

            4499

            DDEEVVOONN SSTTRREEEETT

            FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

            Groundwater SWL MMWW88 Monitoring Well (m AHD)

            MW1 5011 MW2MW244

            MW02 4786

            MW3 484

            MW2MW255 MW4 507

            MW5 4833

            MW6 4794

            MW7 4703

            MW8 4581

            MW9 4728

            MW10 4871

            MW11 4785 MW2MW222

            MW12 4689

            MW13 4662

            MW2MW233 MW14 4723

            MW15 464

            MW16 4577

            MW17 4619

            MW18 4538

            MW19 4735

            MW20 457

            MW21 4531

            MW22 4501

            MW23 4497

            MW24 4537

            MW25 4469

            MW26 4918

            MW19MW19 MW2MW200

            MW2MW211MW18MW18

            MW17MW17

            MW14MW14

            MW15MW15

            MW16MW16

            MW10MW10 LEGEND MMWW1111

            GROUNDWATER MONITORING WELLMW12MW12

            50 INFERRED GROUNDWATER ELEVATION CONTOUR

            MW13MW13

            MW0MW022 INFERRED GROUNDWATER FLOW DIRECTION

            EPA ASSESSMENT AREA

            MW9MW9

            MW5MW5 CADASTREMMWW66 MW4MW4

            MW7MW7 Note This is one interpretation only Other interpretations possibleMW3MW3

            12500 A3

            0 25 50 m

            CLIENT

            SA EPA

            PROJECT

            EPA THEBARTON ASSESSMENT AREA - STAGE 1

            TITLE

            FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

            PROJECT NO DATE CREATED

            80607-1 290917

            MW1MW1 MW2MW266

            80607_Fig 4 - Groundwater Elevation Contour Planai REV 1 gt 290917

            LE

            VE

            L 1

            12

            4 S

            OU

            TH

            TE

            RR

            AC

            E

            AD

            EL

            AID

            E S

            A 5

            00

            0

            PH

            (0

            8)

            82

            32

            90

            88

            F

            AX

            (0

            8)

            82

            32

            90

            99

            E

            MA

            IL

            info

            fy

            fec

            om

            au

            W

            EB

            fy

            fec

            om

            au

            A

            BN

            5

            7 0

            08

            116

            13

            0

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            DEW

            STREET

            DEW

            STREET

            CHAPEL STREETCHAPEL STREET

            PAR

            KER

            STREET

            PAR

            KER

            STREET

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            LIGHT TERRACELIGHT TERRACE

            DEW

            STREET

            DEW

            STREET

            WA

            LSH ST

            WA

            LSH ST

            AD

            MELLA

            STREET

            AD

            MELLA

            STREET

            ALB

            ERT STR

            EETA

            LBER

            T STREET

            HO

            LLAN

            D ST

            REET

            HO

            LLAN

            D ST

            REET

            RANDOLPH STREET

            RANDOLPH STREET

            JAM

            ES STREET

            JAM

            ES STREET

            DOVE STREET

            DOVE STREET

            SMITH STREETSMITH STREET

            MARIA STREETMARIA STREET

            GEORGE STREETGEORGE STREET

            KINTORE STREET

            KINTORE STREET

            PORT ROAD

            PORT ROAD

            PORT ROAD

            PORT ROAD

            CAW

            THO

            RN

            E STR

            EETC

            AWTH

            OR

            NE ST

            REET

            DEVON STREETDEVON STREET

            KINTORE STREETKINTORE STREET

            GOODENOUGH STREETGOODENOUGH STREET

            LIVESTR

            ON

            G PATH

            WAY

            LIVESTR

            ON

            G PATH

            WAY

            MW1MW1

            MW02MW02

            MW3MW3

            MW4MW4

            MW5MW5

            MW6MW6

            MW7MW7

            MW8MW8

            MW9MW9

            MW10MW10MW11MW11

            MW12MW12

            MW13MW13

            MW14MW14

            MW15MW15

            MW16MW16

            MW17MW17

            MW18MW18

            MW19MW19MW20MW20

            MW21MW21

            MW22MW22

            MW23MW23

            MW24MW24

            MW25MW25

            MW26MW26

            WWAA

            LLSSHHSSTT

            SSMMIITTHH SSTTRREEEETT

            ndnd

            RRANDOLPH S

            ANDOLPH STREETTREET

            PPOORR

            TTRR

            OOAA

            DD

            PPOORR

            TTRR

            OOAA

            DD

            JJAM

            EA

            MES S

            S STREET

            TREET

            HHOO

            LLLLAANN

            DDSSTT

            RREEEETT

            CCAAWW

            TTHHOO

            RRNN

            EESSTT

            RREEEETT

            DE

            DEW

            SW

            STREET

            TREET

            DDOOVVEE SSTTRREEEETT

            LLIIVVEESSTTRR

            OONN

            GGPPAATTHH

            WWAAYY

            LIGHT TERRLIGHT TERRAACECE

            AD

            MELLA

            SA

            DM

            ELLA STR

            EETTR

            EET

            AALLBB

            EERRTT SSTTRR

            EEEETT

            CHAPEL SCHAPEL STREETTREET

            ndnd ndnd

            100100

            11000000

            GEGEORORGE SGE STREETTREET

            1010000000

            PPOORRTT RROOAADD PPOORRTT RROOAADD

            DDEEWW

            SSTTRREEEETT

            1010000000 11000000 MMAARRIIAA SSTTRREEEETT

            100100

            JJAAMM

            EESSCC

            OONN

            GGDD

            OONN

            DDRR

            IIVVEE

            KKIINNTTOORREE SSTTRREEEETT ndnd

            KKIINNTTOORREE SSTTRREEEETT

            PPAARR

            KKEERR

            SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

            DDEEVVOONN SSTTRREEEETT

            FIGURE 5 GROUNDWATER CONCENTRATION PLAN

            MW2MW244

            MMWW88 TCE lt1

            PCE lt1

            11-DCE lt1TCE lt1

            12-DCE lt1PCE lt1

            11-DCE lt1MW2MW255 12-DCE lt1

            TCE 2

            PCE lt1

            11-DCE lt1

            12-DCE lt1

            MW2MW222 TCE lt1

            PCE lt1

            11-DCE lt1MW2MW233 12-DCE lt1

            TCE 21

            PCE lt1

            11-DCE lt1

            12-DCE lt1

            MW19MW19 TCE lt1

            MW2MW200 TCE 70 PCE lt1MW2MW211 PCE lt1MW18MW18 11-DCE lt1

            TCE 23 11-DCE lt1TCE 5 12-DCE lt1 PCE lt1 12-DCE lt1PCE lt1 11-DCE lt1

            11-DCE lt1 12-DCE lt1

            12-DCE lt1

            MW17MW17 LEGENDTCE 24 MW14MW14

            PCE lt1 TCE 1100 lt1 MW15MW15 GROUNDWATER MONITORING WELL11-DCE PCE lt1

            12-DCE lt1 TCE 180 11-DCE 2MW16MW16 100 INFERRED TCE GROUNDWATERPCE lt1 12-DCE 4 CONCENTRATION CONTOURSTCE lt1 11-DCE lt1 PCE lt1 12-DCE lt1 11-DCE lt1

            12-DCE lt1 MMWW1111

            EPA ASSESSMENT AREAMW10MW10

            TCE lt1 CADASTREMW12MW12 TCE lt14900 PCE

            lt1 11-DCE lt1TCE 700 PCEMW13MW13 12-DCE lt1 TCE CONCENTRATIONS (μgL)lt1 11-DCE 7PCE

            TCE lt1 lt1 12-DCE 511-DCE gtnd to lt100 100 to lt1000 1000 to lt10000

            MW0MW022PCE lt1 12-DCE lt1 2100011-DCE lt1 MW9MW9 TCE

            PCE lt112-DCE lt1 TCE 2(D) 11-DCE 15PCE lt1 MW5MW5

            10000 to 29000

            nd = non-detect (lt1)12-DCE 4511-DCE lt1 MMWW66 TCE 29000 MW4MW4 12-DCE lt1

            PCE 3 TCE lt1 NotesTCE 29 11-DCE 6MW7MW7 PCE lt1PCE lt1 This is one interpretation only Other interpretations possible12-DCE 23TCE lt1 11-DCE lt111-DCE lt1 All concentrations are in μgL

            12-DCE includes cis and trans PCE lt1 MW3MW3 12-DCE lt112-DCE lt1 11-DCE lt1

            TCE 69 D = Duplicate result12-DCE lt1 PCE lt1

            11-DCE lt1

            12-DCE lt1 MW1MW1

            12500 A3MW2MW266 TCE lt1

            TCE 2 PCE lt1

            PCE lt1 11-DCE lt1

            11-DCE lt1 12-DCE lt1

            12-DCE lt1

            LE

            VE

            L 1

            12

            4 S

            OU

            TH

            TE

            RR

            AC

            E

            AD

            EL

            AID

            E S

            A 5

            00

            0

            PH

            (0

            8)

            82

            32

            90

            88

            F

            AX

            (0

            8)

            82

            32

            90

            99

            E

            MA

            IL

            info

            fy

            fec

            om

            au

            W

            EB

            fy

            fec

            om

            au

            A

            BN

            5

            7 0

            08

            116

            13

            0

            0 25 50 m

            CLIENT

            SA EPA

            PROJECT

            EPA THEBARTON ASSESSMENT AREA - STAGE 1

            TITLE

            FIGURE 5 GROUNDWATER CONCENTRATION PLAN

            PROJECT NO DATE CREATED

            80607-1 280917

            80607_Fig 5 - Groundwater TCE Concentration Plan r2ai REV 2 gt 280917

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            DEW

            STREET

            DEW

            STREET

            CHAPEL STREETCHAPEL STREET

            PAR

            KER

            STREET

            PAR

            KER

            STREET

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            LIGHT TERRACELIGHT TERRACE

            DEW

            STREET

            DEW

            STREET

            WA

            LSH ST

            WA

            LSH ST

            AD

            MELLA

            STREET

            AD

            MELLA

            STREET

            ALB

            ERT STR

            EETA

            LBER

            T STREET

            HO

            LLAN

            D ST

            REET

            HO

            LLAN

            D ST

            REET

            RANDOLPH STREET

            RANDOLPH STREET

            JAM

            ES STREET

            JAM

            ES STREET

            DOVE STREET

            DOVE STREET

            SMITH STREETSMITH STREET

            MARIA STREETMARIA STREET

            GEORGE STREETGEORGE STREET

            KINTORE STREET

            KINTORE STREET

            PORT ROAD

            PORT ROAD

            PORT ROAD

            PORT ROAD

            CAW

            THO

            RN

            E STR

            EETC

            AWTH

            OR

            NE ST

            REET

            DEVON STREETDEVON STREET

            KINTORE STREETKINTORE STREET

            GOODENOUGH STREETGOODENOUGH STREET

            LIVESTR

            ON

            G PATH

            WAY

            LIVESTR

            ON

            G PATH

            WAY

            SV1SV1

            SV2SV2SV3SV3SV4SV4

            SV5SV5

            SV7SV7SV8SV8

            SV9SV9

            SV10SV10

            SV11SV11SV12SV12

            SV13SV13

            SV6SV6

            WWAA

            LLSSHHSSTT

            SSMMIITTHH SSTTRREEEETT

            RRANDOLPH S

            ANDOLPH STREETTREET

            PPOORR

            TTRR

            OOAA

            DD

            PPOORR

            TTRR

            OOAA

            DD

            CCAAWW

            TTHHOO

            RRNN

            EESSTT

            RREEEETT

            HHOO

            LLLLAANN

            DDSSTT

            RREEEETT

            JJAM

            EA

            MES S

            S STREET

            TREET

            DE

            DEW

            SW

            STREET

            TREET

            DDOOVVEE SSTTRREEEETT

            00

            LLIIVVEESSTTRR

            OONN

            GGPPAATTHH

            WWAAYY

            LIGHT TERRLIGHT TERRAACECE

            AD

            MELLA

            SA

            DM

            ELLA STR

            EETTR

            EET

            CHAPEL SCHAPEL STREETTREET

            00

            AALLBB

            EERRTT SSTTRR

            EEEETT

            1010

            GEGEORORGE SGE STREETTREET

            000000

            PPOORRTT RROOAADD

            100100000

            000

            1010

            PPOORRTT RROOAADD

            000000

            DDEEWW

            SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

            JJAAMM

            EESSCC

            OONN

            GGDD

            OONN

            DDRR

            IIVVEE

            KKIINNTTOORREE SSTTRREEEETT 00

            KKIINNTTOORREE SSTTRREEEETT

            PPAARR

            KKEERR

            SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

            DDEEVVOONN SSTTRREEEETT

            FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

            SSVV1111 SSV12V12 TCE lt18

            SSVV1133 TCE 16

            PCE lt54 TCE lt21

            11-DCE lt29 PCE lt25

            12-DCE lt39 11-DCE lt14

            12-DCE lt18

            PCE lt22

            11-DCE lt12

            12-DCE lt16

            TCE 170

            PCE lt54

            11-DCE lt3

            12-DCE lt39 LEGEND SSVV99

            SSV10V10 SOIL VAPOUR BORE

            TCE lt21 0 INFERRED TCE SOIL VAPOUR CONTOUR PCE lt25

            TCE 2200011-DCE lt14 EPA ASSESSMENT AREA

            PCE 1912-DCE lt18

            11-DCE lt27 CADASTRE

            12-DCE lt37 SVSV66SVSV77

            SSVV88 TCE 22000

            TCE 2300 PCE 12 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)TCE 100000 PCE 62 11-DCE lt29PCE 84 0 to lt10000SSVV55lt2711-DCE 12-DCE lt2911-DCE lt33 10000 to lt100000

            100000 to 210000 12-DCE lt36 12-DCE lt44

            TCE 17000 SVSV44 SVSV22SVSV33 NotePCE 31 TCE 51000TCE 210000 This is one interpretation only Other interpretations possible11-DCE lt14 PCE 39PCE 650012-DCE lt18 39 Estimated extent of plume has utilised groundwater11-DCE11-DCE 5900 12-DCE 21 concentration data12-DCE lt71

            SVSV11 All concentrations are in (μgmsup3)

            TCE 6300(LD) 12-DCE includes cis and trans PCE 78 LD = Laboratory duplicate result 11-DCE lt29

            12-DCE lt38

            12500 A3

            0 25 50 m

            CLIENT

            SA EPA

            PROJECT

            EPA THEBARTON ASSESSMENT AREA - STAGE 1

            TITLE

            FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

            PROJECT NO DATE CREATED

            80607-1 290917

            80607_Fig 6 - Soil Vapour TCE Concentration Plan - 1mai REV 2 gt 290917

            LE

            VE

            L 1

            12

            4 S

            OU

            TH

            TE

            RR

            AC

            E

            AD

            EL

            AID

            E S

            A 5

            00

            0

            PH

            (0

            8)

            82

            32

            90

            88

            F

            AX

            (0

            8)

            82

            32

            90

            99

            E

            MA

            IL

            info

            fy

            fec

            om

            au

            W

            EB

            fy

            fec

            om

            au

            A

            BN

            5

            7 0

            08

            116

            13

            0

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            JAM

            ES CO

            NG

            DO

            N D

            RIV

            E

            DEW

            STREET

            DEW

            STREET

            CHAPEL STREETCHAPEL STREET

            PAR

            KER

            STREET

            PAR

            KER

            STREET

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            POR

            T RO

            AD

            LIGHT TERRACELIGHT TERRACE

            DEW

            STREET

            DEW

            STREET

            WA

            LSH ST

            WA

            LSH ST

            AD

            MELLA

            STREET

            AD

            MELLA

            STREET

            ALB

            ERT STR

            EETA

            LBER

            T STREET

            HO

            LLAN

            D ST

            REET

            HO

            LLAN

            D ST

            REET

            RANDOLPH STREET

            RANDOLPH STREET

            JAM

            ES STREET

            JAM

            ES STREET

            DOVE STREET

            DOVE STREET

            SMITH STREETSMITH STREET

            MARIA STREETMARIA STREET

            GEORGE STREETGEORGE STREET

            KINTORE STREET

            KINTORE STREET

            PORT ROAD

            PORT ROAD

            PORT ROAD

            PORT ROAD

            CAW

            THO

            RN

            E STR

            EETC

            AWTH

            OR

            NE ST

            REET

            DEVON STREETDEVON STREET

            KINTORE STREETKINTORE STREET

            GOODENOUGH STREETGOODENOUGH STREET

            LIVESTR

            ON

            G PATH

            WAY

            LIVESTR

            ON

            G PATH

            WAY

            SV1SV1

            SV2SV2SV3SV3SV4SV4

            SV5SV5

            SV7SV7SV8SV8

            SV9SV9

            SV10SV10

            SV12SV12

            SV6SV6

            WWAA

            LLSSHHSSTT

            SSMMIITTHH SSTTRREEEETT

            RRANDOLPH S

            ANDOLPH STREETTREET

            PPOORR

            TTRR

            OOAA

            DD

            PPOORR

            TTRR

            OOAA

            DD

            CCAAWW

            TTHHOO

            RRNN

            EESSTT

            RREEEETT

            HHOO

            LLLLAANN

            DDSSTT

            RREEEETT

            DE

            DEW

            SW

            STREET

            TREET

            JJAM

            EA

            MES S

            S STREET

            TREET

            DDOOVVEE SSTTRREEEETT

            00

            LIGHT TERRLIGHT TERRAACECE

            LLIIVVEESSTTRR

            OONN

            GGPPAATTHH

            WWAAYY

            AD

            MELLA

            SA

            DM

            ELLA STR

            EETTR

            EET

            CHAPEL SCHAPEL STREETTREET

            00

            1010000000

            AALLBB

            EERRTT SSTTRR

            EEEETT

            100100 000

            000 GEGEORORGE SGE STREETTREET

            PPOORRTT RROOAADD 11000000000

            000 PPOORRTT RROOAADD

            DDEEWW

            SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

            100100000000

            JJAAMM

            EESSCC

            OONN

            GGDD

            OONN

            DDRR

            IIVVEE

            1010000000

            KKIINNTTOORREE SSTTRREEEETT

            00

            KKIINNTTOORREE SSTTRREEEETT

            PPAARR

            KKEERR

            SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

            DDEEVVOONN SSTTRREEEETT

            FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

            SSV12V12 TCE 55

            PCE lt45

            11-DCE lt24

            12-DCE lt32

            TCE 260

            PCE lt51

            11-DCE lt28

            12-DCE

            SSVV99

            lt37 LEGEND

            SSV10V10 SOIL VAPOUR BORE

            TCE 51 0 INFERRED TCE SOIL VAPOUR CONTOURPCE lt53

            TCE 11000011-DCE lt29

            EPA ASSESSMENT AREAPCE lt13012-DCE lt39

            11-DCE lt69

            CADASTRE12-DCE lt92 SVSV66SVSV77

            SSVV88 TCE 150000

            TCE 14000 56 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)PCETCE 160000 PCE 19 11-DCE lt30PCE 310 0 to lt10000SSVV5511-DCE lt26 12-DCE lt3911-DCE 33 10000 to lt100000

            100000 to lt1000000 1000000

            12-DCE lt35 12-DCE 20

            TCE 43000 SVSV44 SVSV22SVSV33 NotePCE 90 TCE 940000(FD)TCE 1000000 This is one interpretation only Other interpretations possible11-DCE lt15 PCE 15000PCE 1500012-DCE 30 14000 Estimated extent of plume has utilised groundwater11-DCE11-DCE 14000 12-DCE lt930 concentration data12-DCE lt930

            All concentrations are in (μgmsup3) 12-DCE includes cis and trans

            SVSV11 TCE 21000

            FD = Field Duplicate resultPCE 21

            11-DCE lt57

            12-DCE lt76

            12500 A3

            0 25 50 m

            CLIENT

            SA EPA

            PROJECT

            EPA THEBARTON ASSESSMENT AREA - STAGE 1

            TITLE

            FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

            PROJECT NO DATE CREATED

            80607-1 290917

            80607_Fig 7 - Soil Vapour TCE Concentration Plan - 3m r2ai REV 2 gt 290917

            LE

            VE

            L 1

            12

            4 S

            OU

            TH

            TE

            RR

            AC

            E

            AD

            EL

            AID

            E S

            A 5

            00

            0

            PH

            (0

            8)

            82

            32

            90

            88

            F

            AX

            (0

            8)

            82

            32

            90

            99

            E

            MA

            IL

            info

            fy

            fec

            om

            au

            W

            EB

            fy

            fec

            om

            au

            A

            BN

            5

            7 0

            08

            116

            13

            0

            • THEBARTON ASSESSMENT AREA STAGE 1 ENVIRONMENTAL ASSESSMENT FINAL REPORT | EPA REF 0524111 30 OCTOBER 2017 VOLUME 1 REPORT13
            • This report is formatted to print Double Sided
            • TITLE PAGE13
            • CONTENTS13
            • LIST OF ACRONYMS13
            • EXECUTIVE SUMMARY13
            • 1 INTRODUCTION
              • 11 Purpose
              • 12 General background information
              • 13 Definition of the assessment area
              • 14 Identification of contaminants of potential concern
              • 15 Objectives
                • 2 CHARACTERISATION OF THE ASSESSMENT AREA
                  • 21 Site identification
                  • 22 Regional geology and hydrogeology
                  • 23 Data quality objectives
                    • 3 SCOPE OF WORK
                      • 31 Preliminary work
                      • 32 Field investigation and laboratory analysis program
                      • 33 Data interpretation
                        • 4 METHODOLOGY
                          • 41 Field methodologies
                          • 42 Laboratory analysis
                            • 5 QUALITY ASSURANCE AND QUALITY CONTROL
                              • 51 Field QAQC
                              • 52 Laboratory QAQC
                              • 53 QAQC summary
                                • 6 ASSESSMENT CRITERIA
                                  • 61 Groundwater
                                  • 62 Soil vapour
                                    • 7 RESULTS
                                      • 71 Surface and sub surface soil conditions
                                      • 72 Waterloo Membrane Samplerstrade
                                      • 73 Groundwater
                                      • 74 Soil vapour bores
                                        • 8 GROUNDWATER FATE AND TRANSPORT MODELLING
                                          • 81 Groundwater flow modelling
                                          • 82 Solute transport modelling
                                            • 9 VAPOUR INTRUSION RISK ASSESSMENT
                                              • 91 Objective
                                              • 92 Areas of interest
                                              • 93 Risk assessment approach
                                              • 94 Tier 1 assessment
                                              • 95 Tier 2 assessment
                                              • 96 Conclusions
                                                • 10 CONCEPTUAL SITE MODEL
                                                • 11 CONCLUSIONS
                                                • 12 DATA GAPS
                                                • 13 REFERENCES
                                                • 14 STATEMENT OF LIMITATIONS
                                                • FIGURES13
                                                • FIGURE 1 SITE LOCATION AND ASSESSMENT AREA
                                                • FIGURE 2 ASSESSMENT POINT LOCATIONS
                                                • FIGURE 3 WATERLOO MEMBRANE SAMPLERTM TCE CONCENTRATION PLAN13
                                                • FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN
                                                • FIGURE 5 GROUNDWATER CONCENTRATION PLAN
                                                • FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)
                                                • FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              FIGURES follow page 79

              Figure 1 Site Location and Assessment Area Figure 2 Assessment Point Locations Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan Figure 4 Groundwater Elevation Contour Plan Figure 5 Groundwater Concentration Plan Figure 6 Soil Vapour Concentration Plan (10 m) Figure 7 Soil Vapour Concentration Plan (30 m)

              VOLUME 2 APPENDICES

              APPENDICES

              Appendix A Historical Report Summary Appendix B Historical Information Supplied by the EPA Appendix C DEWNR Registered Groundwater Database Search Results Appendix D Groundwater Well Permits Appendix E Field Sampling Sheets ndash Groundwater Appendix F Survey Data Appendix G Certified Laboratory Certificates and Chain of Custody Documentation Appendix H Groundwater Well Log Reports Appendix I WMStrade Borehole Log Reports Appendix J Soil Vapour Borehole Log Reports Appendix K Waste Transport Certificates Appendix L Tabulated Results ndash Soil Vapour Geotechnical and Groundwater Appendix M Equipment Calibration Records Appendix N Drill Core Photographs Appendix O Arcadis Groundwater Fate and Transport Modelling Report Appendix P Arcadis Vapour Intrusion Risk Assessment Report

              PAGE IV 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              LIST OF ACRONYMS

              AER Air Exchange Rate

              AF Attenuation Factor

              AHD Australian Height Datum

              ANZECC Australian and New Zealand Environment and Conservation Council

              ARMCANZ Agriculture and Resource Management Council of Australia and New Zealand

              ASC Assessment of Site Contamination

              ASTM American Standard Testing Material

              AT Averaging Time

              ATSDR Agency for Toxic Substances and Disease Registry

              AWQC Australian Water Quality Centre

              BGL Below Ground Level

              BTEX Benzene Toluene Ethylbenzene Xylenes

              BTOC Below Top of Casing

              BUA Beneficial Use Assessment

              CBD Central Business District

              CHC Chlorinated Hydrocarbon Compound

              COC Chain of Custody

              COPC Contaminants of Potential Concern

              CRC CARE Cooperative Research Centre for Contamination Assessment and Remediation of the Environment

              CSM Conceptual Site Model

              11-DCA 11-dichloroethane

              11-DCE 11-dichloroethene

              12-DCE 12-dichloroethene

              DCE Dichloroethene

              DEC Department of Environment and Conservation

              DEWNR Department of Environment Water and Natural Resources

              DNAPL Dense Non-Aqueous Phase Liquid

              DO Dissolved Oxygen

              DQI Data Quality Indicator

              DQO Data Quality Objective

              EC Electrical Conductivity

              ED Exposure Duration

              80607-1 REV1 30102017 PAGE V

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              EF Exposure Frequency

              EMP Environmental Management Plan

              EPA Environment Protection Authority

              EPC Exposure Point Concentration

              EPP Environment Protection Policy

              ET Exposure Time

              GPA Groundwater Prohibition Area

              GPR Ground Penetrating Radar

              GPS Global Positioning System

              HHRA Human Health Risk Assessment

              HIL Health Investigation Level

              HSP Health and safety Plan

              IPA Isopropyl Alcohol (isopropanol or 2-propanol)

              IRIS Integrated Risk Information System

              ITRC Interstate Technology and Regulatory Council

              JampE Johnson and Ettinger

              JHA Job Hazard Analysis

              LNAPL Light Non-Aqueous Phase Liquid

              LOR Limit of Reporting

              MGA Map Grid of Australia

              MQO Measuring Quality Objectives

              MTC Mass Transfer Co-efficient

              NA Not Applicable

              NAPL Non-Aqueous Phase Liquid

              NATA National Association of Testing Authorities

              ND Non Detect

              NEPM National Environment Protection Measure

              NHMRC National Health and Medical Research Council

              NJDEP New Jersey Department of Environmental Protection

              NRMMC National Resource Management Ministerial Council

              PAH Polycyclic Aromatic Hydrocarbons

              PCE Tetrachloroethene (perchloroethylene)

              PID Photoionisation Detector

              PQL Practical Quantification Limit

              PSD Particle Size Distribution

              QA Quality Assurance

              80607-1 REV1 30102017 PAGE VI

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              QC Quality Control

              RAIS Risk Assessment Information System

              RFQ Request for Quote

              REM Resource and Environmental Management

              RPD Relative Percentage Difference

              RSL Regional Screening Level

              SA EPA South Australian Environment Protection Authority

              SAQP Sampling and Analysis Quality Plan

              SOP Standard Operating Procedure

              SVOC Semi-Volatile Organic Compound

              SWL Standing Water Level

              SWMS Safe Work Method Statement

              111-TCA 111-trichloroethane

              TCE Trichloroethene

              TDS Total Dissolved Solids

              TRH Total Recoverable Hydrocarbons1

              TRV Toxicity Reference Value

              US EPA United Stated Environment Protection Agency

              USGS United States Geological Survey

              VC Vinyl Chloride

              VIRA Vapour Intrusion Risk Assessment

              VOC Volatile Organic Compound

              VOCC Volatile Organic Chlorinated Compound

              WHO World Health Organisation

              WMStrade Waterloo Membrane Samplertrade

              TRH = measurable amount of petroleum-based hydrocarbon (ie complex mixture of crude oil and natural gas (gt 250 compounds) including aromatics aliphatics paraffins unsaturated alkanes and naphthalenes) plus various other compounds including fatty acids esters humic acids phthalates and sterols

              80607-1 REV1 30102017 PAGE VII

              1

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              EXECUTIVE SUMMARY

              Background information

              An approximate 27 hectare mixed use area of Thebarton has been designated by the South Australian Environment Protection Authority (EPA) as the Thebarton EPA Assessment Area

              The former Austral sheet metal works (Austral) property located over multiple allotments between George and Maria Streets from the 1920s until the 1960s-1970s has been identified as a possible source of dissolved phase groundwater chlorinated hydrocarbon (CHC) contamination Groundwater CHC impacts within the uppermost (Quaternary ndash Q1) aquifer were identified as extending in a general north-westerly direction (consistent with regional groundwater flow direction) from the south-eastern portion of the Thebarton EPA Assessment Area and having resulted in the generation of soil vapour containing elevated concentrations of CHC

              The boundaries of the Thebarton EPA Assessment Area were established on the basis of the following

              the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street (part of the former Austral property) and 39 Smith Street (hydraulically down-gradient of the former Austral property) in Thebarton

              the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

              the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

              Key objectives

              The results of the recent investigations undertaken by Fyfe have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties within the Thebarton EPA Assessment Area

              The key objectives detailed by the EPA were to

              further delineate the chlorinated hydrocarbon contamination in groundwater

              further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

              undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

              80607-1 REV1 30102017 PAGE VIII

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              With respect to the VIRA the EPA requested that there be specific consideration of

              residential properties (slab on grade)

              residential properties (crawl space)

              residential properties (with basement) and

              trenchmaintenanceutility workers that may be working in the vicinity of the contamination

              Site conditions

              Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were identified within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m below ground level (BGL) during the drilling of groundwater well MW17 the latter consistent with the depth of groundwater within the Q1 aquifer

              Soil

              Groundwater within the Q1 aquifer is located at a depth of approximately 123 to Groundwater 159 m BGL and flows in a general north-westerly direction The closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred and the groundwater gradient is relatively flat (ie 000062 to 00012)

              Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified (based on factors such a groundwater salinity registered bore use and the locations of potential sensitive receptors) as including domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux) and possibly also potable

              Contaminants of Potential Concern (COPC)

              The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans-) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

              80607-1 REV1 30102017 PAGE IX

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Scope of work

              A groundwater and soil vapour monitoring program was undertaken by Fyfe across the Thebarton EPA Assessment Area between May and August 2017 It involved the following scope of work

              installation of a total of 41 WMStrade units to 1 m BGL in an approximate grid-pattern across the entire assessment area (Round 1) and at specific targeted locations (Round 2) followed by laboratory analysis of retrieved sample units for specific CHC

              drilling and installation of 25 groundwater wells to depths of between 15 and 19 m BGL including a background well to the east of the southern portion of the assessment area

              testing of 30 selected groundwater well drill core samples for geotechnical parameters

              gauging and sampling of the 25 newly installed groundwater wells as well as an existing well located in Admella Street followed by laboratory analysis of all samples for specific CHC and 10 selected samples for major cationsanions natural attenuation parameters and additional nutrients

              aquifer permeability (rising and falling head ldquoslugrdquo) testing of 10 groundwater wells

              drilling and installation of 13 soil vapour bores including 11 nested bores (ie to 1 and 3 m BGL) and two bores to 1 m BGL and

              sampling of all soil vapour bores followed by laboratory analysis of samples for specific CHC and general gases

              The soil vapour data were used to undertake a VIRA aimed at predicting indoor air concentrations of TCE under various land use and building construction scenarios In order to validate the results of the modelling which includes a number of conservative assumptions and is therefore expected to over-estimate potential risk the EPA has commissioned indoor air monitoring in a number of residential properties within the Thebarton EPA Assessment Area ndash the indoor air monitoring results will be reported under separate cover

              Groundwater fate and transport modelling was undertaken to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton EPA Assessment Area The provision of this information is aimed at supporting the definition (extent and geometry) of a potential future Groundwater Prohibition Area (GPA) to be designated by the EPA in accordance with the provisions of Section S103S of the Environment Protection Act 1993

              80607-1 REV1 30102017 PAGE X

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Identified impacts

              Contaminants identified in the Q1 aquifer beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down

              Groundwater

              (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested

              The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected (Austral) source site in accordance with the predominant flow direction associated with the Q1 aquifer The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) ndash whereas its north-western extent has not yet been determined the groundwater CHC plume has been delineated in all other directions

              Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion

              Soil vapour

              The soil vapour samples with the maximum TCE concentrations also had the highest PCE and 11-DCE concentrations (or elevated laboratory limits of reporting (LOR)) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-)

              Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE exceeded the adopted health investigation levels (HILs) for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE degradation has not yet resulted in its production

              Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

              80607-1 REV1 30102017 PAGE XI

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Assessment of risk

              Measured concentrations of TCE exceeded the adopted assessment criteria for potable use andor primary contact recreation in wells located on Admella Maria George Albert Chapel and Dew Streets as well as Light Terrace ndash with the highest concentrations corresponding to the ldquocorerdquo area of the plume One well on Albert Street also contained a concentration of carbon tetrachloride that exceeded the respective potable criterion

              Groundwater risks

              Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous

              Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

              The groundwater modelling undertaken by Arcadis involved the development of an Groundwater fate and transport initial groundwater flow model using MODFLOW followed by the development of a modelling site-specific (three-dimensional) solute transport model using the MT3DMS transport

              code

              The results of this modelling were interpreted to indicate the following

              although scattered detectable concentrations of 12-DCE have been measured in groundwater across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE daughter products indicate that substantial dechlorination is not occurring and

              the dissolved phase groundwater TCE plume is predicted to extend by another 500 m (ie beyond the boundaries of the current Thebarton EPA Assessment Area) over the next 100 years whereas no significant lateral plume expansion is expected

              The VIRA undertaken by Arcadis involved a two-tier assessment approach Whereas Vapour intrusion the Tier 1 screening risk assessment compared the measured soil vapour CHC concentrations to (modified) guideline values the Tier 2 risk assessment involved the application of the Johnson and Ettinger vapour intrusion model to predict indoor air CHC concentrations for residential (slab on grade crawl space and basement construction) and commercialindustrial (slab on grade construction) properties across the assessment area Site-specific geotechnical parameters and soil vapour data collected from 1 and 3 m BGL throughout the Thebarton EPA Assessment Area were used in the modelling It should be noted that overall the vapour modelling

              risks

              80607-1 REV1 30102017 PAGE XII

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

              The results of the VIRA with respect to the predicted indoor air concentrations of TCE within residential properties (assuming crawl space construction) versus adopted EPA response levels indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air that require further action as follows

              10 properties within the investigation range (2 to lt20 microgm3)

              eight properties within the intervention range (20 to lt200 microgm3) and

              three properties within accelerated intervention range (ge200 microgm3)

              All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises

              Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which is expected to be overly-conservative) ndash these results will be documented in a subsequent report

              Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie as determined for the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

              A qualitative assessment of potential risks to subsurface trenchmaintenanceutility workers indicated that exposure management may be required in areas where TCE concentrations at 1 m BGL are above 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific health and safety plan (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a photoionisation detector (PID) unit providing increased ventilation and using appropriate personal protective equipment (eg gas masks) as required

              80607-1 REV1 30102017 PAGE XIII

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Data gaps

              Based on the results obtained during the recent Fyfe investigations as well as available historical information the following data gaps have been identified for the Thebarton EPA Assessment Area

              property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

              groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

              the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

              the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

              Notes ie the interim soil vapour HILs adopted from the National Environment (Assessment of Site Contamination) Measure 1999 (as revised in 2013 ndash ie the ASC NEPM (1999)) but assuming a sub-slab to indoor air attenuation factor of 003 as compared to the value of 01 adopted by the ASC NEPM (1999)

              80607-1 REV1 30102017 PAGE XIV

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              1 INTRODUCTION

              11 Purpose

              Fyfe Pty Ltd (Fyfe) was commissioned by the South Australian Environment Protection Authority (SA EPA referred to herein as the EPA) to undertake Stage 1 groundwater and soil vapour investigation works groundwater fate and transport modelling and a human health vapour intrusion risk assessment (VIRA) within an EPA designated assessment area located within Thebarton South Australia (herein referred to as the Thebarton EPA Assessment Area) The location and extent of the Thebarton EPA Assessment Area referenced within this document is identified on Figure 1

              12 General background information

              Previous environmental assessment work undertaken since 1994 (as summarised in Appendix A) combined with historical information provided by the EPA (as included in Appendix B) indicates that the Thebarton EPA Assessment Area has been used for mixed residential and commercialindustrial purposes over time

              Groundwater impacts2 identified within the uppermost (Quaternary ndash Q1) aquifer in the vicinity of the former Austral sheet metal works (Austral) on George Street included both petroleum hydrocarbons (ie diesel fuel) as well as chlorinated hydrocarbon compounds (CHC) such as trichloroethene (TCE) and were first notified to the EPA in 2006

              Available historical information for the Austral property (ie the suspected source site) indicates that it operated from the 1920s until the 1960s-1970s and occupied an extensive area of Thebarton including

              part of the southern side of George Street extending from about half way between East Terrace3 and Admella Street (ie 11-25 George Street) to the west of Admella Street (ie 31-35 George Street)

              the entire northern side of Maria Street from East Terrace to the west of Admella Street

              part of the southern side of Maria Street (ie from 21 Maria Street) to Admella Street and

              25-27 East Terrace

              2 Note that the term ldquoimpactrdquo has been used by Fyfe to indicate identified concentrations of compounds (specifically chlorinated hydrocarbons) that are not naturally occurring (ie concentrations above background that have resulted from anthropogenic activities) The use of this term does not denote that the presence of these compounds represents a risk to either human health or the environment and the term ldquoimpactrdquo is therefore not directly interchangeable with the term ldquoSite Contaminationrdquo the latter defined under the Environment Protection Act 1993 to include actual or potential harm to human health andor the environment

              3 now James Congdon Drive

              80607-1 REV1 30102017 PAGE 1

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Historical newspaper articles described the Austral property as hosting a factory that extended over more than three acres and included an electroplating facility In 1938 it was described as the largest aluminium utensil manufacturing company in the southern hemisphere

              Other potential sources of groundwater contamination4 identified within the Thebarton EPA Assessment Area include a former gas works (ie located to the south and south-east of the Austral property and including the current Ice Arena property) a mechanicrsquos workshop another sheet metal working facility and a farm machinery manufacturer

              The Stage 1 assessment work described herein was commissioned by the EPA to determine whether historical contamination in the vicinity of George Street was presenting a risk to human health or the environment

              13 Definition of the assessment area

              As detailed on Figure 1 the current EPA Assessment Area covers an area of approximately 27 ha within the suburb of Thebarton located approximately 2 km north-west of the Adelaide central business district (CBD)

              The boundaries of the Thebarton EPA Assessment Area were established by the EPA on the basis of the following

              the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street and 39 Smith Street in Thebarton (refer to Appendix A)

              the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

              the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

              14 Identification of contaminants of potential concern

              The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

              Site Contamination is defined by the Environment Protection Act 1993 as existing if chemical substances are present on or below the surface of a site in concentrations above background the contaminants are there as a result of activity at the site or elsewhere and their presence has resulted in actual or potential harm (that is not trivial) to the health and safety of human beings taking into account current and proposed land uses or water or the environment

              PAGE 2 80607-1 REV1 30102017

              4

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              15 Objectives

              As defined by the EPA the key objectives of the recent Stage 1 environmental assessment program undertaken within the Thebarton EPA Assessment Area (refer to Figure 1) were to

              further delineate the chlorinated hydrocarbon contamination in groundwater

              further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

              undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

              With respect to the VIRA the EPA requested that there be specific consideration of

              residential properties (slab on grade)

              residential properties (crawl space)

              residential properties (with basement) and

              trenchmaintenanceutility workers that may be working in the vicinity of the contamination

              80607-1 REV1 30102017 PAGE 3

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              2 CHARACTERISATION OF THE ASSESSMENT AREA

              21 Site identification

              For the purpose of this investigation program the Thebarton EPA Assessment Area (as delineated in Figure 1) has been defined by the following roadways

              North northern verge of Smith Street

              South Maria Street (between Dew Street and Albert Street) portion of Parker Street (between Maria Street and Goodenough Street) and Goodenough Street (between Parker Street and James Congdon Drive)

              East western verge of Port Road and James Congdon Drive and

              West western verge of Dew Street

              22 Regional geology and hydrogeology

              221 Geology

              The Thebarton area is located within the Adelaide Plains approximately 8 km to the east of Gulf St Vincent and to the west of the Para Fault It lies within the Golden Grove ndash Adelaide Embayment area of the St Vincent Basin which consists of a succession of Tertiary and Quaternary age sediments (with thicknesses of up to 600 m) overlying basement rocks

              The 1250000 Adelaide geological map (SA Department of Mines and Energy 1969) indicates that the near-surface geology of the area consists primarily of Quaternary aged soils and sediments including the Pooraka and Hindmarsh Clay formations The Pleistocene aged Pooraka Formation generally comprises a thickness of approximately 10 m and is of alluvial origin comprising sandy clays and clayey to sandy silts interbedded with layers of clay sand andor gravel The underlying Pleistocene aged Hindmarsh Clay Formation represents the basal unit of the Adelaide Plains and has a maximum general thickness of more than 100 m It generally comprises a basal gravel layer a middle layer of mottled medium to high plasticity (red-brown yellow brown greygreen to orange) often stiff to hard clays and an upper layer of fluvial and alluvial red-brown silty sand Gerges (1999) describes Hindmarsh Clay as comprising a mottled brown to pale olive grey predominantly clay formation that becomes green grey towards the basal section (approximately 16 to 20 m below ground level (BGL)) and is characterised by an increasing gravel content with depth

              Underlying the Hindmarsh Clay are sands and limestone of Tertiary age which are in turn underlain by metamorphosed basement rock of the Proterozoic Umberatana Group

              80607-1 REV1 30102017 PAGE 5

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              222 Hydrogeology

              According to Gerges (2006) the aquifers identified within the Quaternary aged sediments of the Adelaide Plains are typically found within the coarser interbedded silt sand and gravel layers of the Hindmarsh Clay Formation and vary greatly in thickness (typically from 1 to 18 m) lithology and hydraulic conductivity Confining beds between the Quaternary aquifers consist of clay and silt layers and range in thickness from 1 to 20 m These confining beds vary in terms of the amount of coarser grained material they contain their bulk hydraulic conductivity andor the presence and density of fractures In addition their absence in some areas allows direct hydraulic connection between the aquifers

              The Thebarton area is located within Hydrogeological Zone 3 (Subzone 3E) of Gerges (2006) This zone contains five to six Quaternary aquifers and three to four almost flat-lying Tertiary aquifers The first Tertiary aquifer estimated by Gerges (2006) to be intersected at a depth of approximately 130 m BGL near the Para Fault is most frequently accessed for industrial and recreational groundwater use

              The Q1 aquifer assessed as part of the current investigations is typically located at depths of between 3 and 10 m BGL beneath the Adelaide Plains with an average thickness of 2 m The Q1 aquifer contains water of variable salinity with Subzone 3E including a range of 500 to 3500 mgL total dissolved solids (TDS) The gradient of the Q1 aquifer is generally flat (particularly to the west of the Para Fault) and flow direction is typically towards the north-west

              A search of the registered bore database maintained by the Department of Environment Water and Natural Resources (DEWNR (2017) WaterConnect database) identified 59 bores within the general Thebarton area of which 18 are located in the Thebarton EPA Assessment Area Although eight bores were installed for monitoring purposes on or immediately adjacent to the property located at 31-37 George Street (ie part of the former Austral facility) it is understood that only one bore (6628-21951 ndash located within the Admella Street roadway intersecting the Q1 aquifer and identified as MW01 in Appendix A but MW02 by Fyfe5) remains in situ

              In addition to numerous monitoringinvestigationobservation bores the Q1 aquifer within the general (ie broader) Thebarton area is recorded in the DEWNR (2017) database as being accessed for drainage domestic and industrial purposes

              DEWNR (2017) information for registered bores located within the general Thebarton area is included in Appendix C whereas information for bores located within the Thebarton EPA Assessment Area (excluding those associated with the property at 31-37 George Street and installed solely for monitoring purposes6) is summarised in Table 21

              5 This existing groundwater well was identified as MW02 by Fyfe in accordance with the markings on the gatic cover and the DEWNR (2017) WaterConnect bore identification details although it was originally installed as MW01 by REM (refer to discussion of previous reports in Appendix A)

              6 ie 6628-21951 6628-21952 6628-22229 to 6628-22233 and 6628-22236

              PAGE 6 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area

              Bore ID Location Purpose Status Maximu SWL Salinity Yield Aquifer m well (m (mgL (Lsec

              Tertiary (T1)

              depth BGL) TDS) ) (m BGL)

              125 6628-516 Coca Cola plant Rehabilitated 138 1963 794

              6628-1435 Coca Cola plant Backfilled 184 212 921 392 Tertiary (T1)

              6628-4576 Corner of Admella amp Chapel Streets

              125 1454 445 Tertiary (T1)

              6628-7724 Coca Cola plant Observation 155 2017 1272 1516 Tertiary (T1)

              6628-7725 Coca Cola plant Observation 127 3016 1100 1005 Tertiary (T1)

              6628-12516 Coca Cola plant Industrial Backfilled 210 212 1300 1875 Tertiary (T1)

              6628-20663 39 Smith Street Irrigation 121 1105 50 Tertiary (T1)

              6628-20969 39 Smith Street Industrial 30 14 1535 25 Quaternary (Q1)

              6628shy21951

              Admella Street 20 Quaternary (Q1)

              6628-22395 21 James Congdon Drive

              20 157 1541 05 Quaternary

              6628-23525 41 Maria Street 206 273 1078 10 Tertiary (T1)

              Notes Shading indicates that information was not recorded in the database as interpreted from information provided in the database ndash approximate only in some instances

              ie MW02 as included in the groundwater monitoring program of Fyfe ndash refer to Table 31 Abbreviations BGL = below ground level SWL = standing water level TDS = total dissolved solids

              23 Data quality objectives

              The Data Quality Objective (DQO) process as described in Australian Standard AS44821-2005 and the National Environment Protection (Assessment of Site Contamination) Measure (ASC NEPM 1999)7

              Schedule B2 Guideline on Data Collection Sample Design and Reporting and more fully documented in the NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme involves a seven-step iterative approach that was initially developed by the United States Environment Protection Agency (US EPA) to facilitate the systematic planning and verification of contaminated sites assessment projects

              As stated in Schedule B2 of the ASC NEPM (1999) the first six steps of the DQO process comprise the development of qualitative and quantitative statements that define the objectives of the site assessment program and the quantity and quality of data needed to inform risk-based decisions These steps enable the

              All references to the ASC NEPM (1999) refer to the version amended on 16 May 2013

              80607-1 REV1 30102017 PAGE 7

              7

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              project team to communicate the goals decisions constraints (eg time budget) and uncertainties associated with the project and detail how they are to be addressed The seventh step comprises the development of a Sampling and Analysis Quality Plan (SAQP) to generate the data required to adequately characterise site contamination issues and assess their associated potential environmental and human health risks under the proposed land use scenario

              The DQOs defined for the Thebarton EPA Assessment Area are summarised in Table 22

              Table 22 Data Quality Objectives

              Objective Comment

              Step 1 ndash Statement of the Problem According to information provided to Fyfe by the EPA (as summarised in Appendix A) a property located at 31-37 George Street (immediately west of Admella Street) in Thebarton and historically occupied by part of the Austral facility had been found to be underlain by groundwater CHC (primarily TCE) impacts More recent reporting to the EPA for a property at 39 Smith Street located approximately 350 m north-west (and hydraulically down-gradient) of the George Street property indicated that detectable CHC (predominantly TCE) were also present within groundwater Since this area of Thebarton is occupied by a mixture of commercialindustrial and residential properties and the source and extent of the CHC impacts within the Q1 aquifer had not yet been determined potential risks to human health andor the environment had yet to be assessed

              Step 2 ndash The Decision that Needs The assessment works commissioned by the EPA were necessitated to to Result from the Investigation investigate the source extent and magnitude of the groundwater CHC

              contamination beneath a designated area of Thebarton (ie that included both the George Street and Smith Street properties) and to understand the possible risk to public health from potential vapour generation Fyfe have therefore undertaken vapour modelling and intrusion risk assessment works aimed at evaluating whether concentrations of identified groundwater andor soil vapour contaminants pose an unacceptable risk to human health In addition groundwater fate and transport modelling has been undertaken to predict the extent of the plume This will assist the EPA to determine a potential future Groundwater Prohibition Area (GPA) in accordance with the provisions of Section 103S of the Environment Protection Act 1993

              Step 3 ndash Inputs to the Decision The information that was required to resolve the decision statement included the collection of physical and chemical data from across the Thebarton EPA Assessment Area The collected data as well as physical observations regarding the geology of the area and possible preferential contaminant pathways was used to determine potential risks to human health via groundwater fate and transport and vapour intrusion modelling

              Step 4 ndash Boundaries of the Investigation

              The lateral boundaries of the Thebarton EPA Assessment Area are as defined in Sections 13 and 21 as depicted on Figure 1 Vertically the investigations extended as far as the maximum drilled depth (19 m BGL)

              Step 5 ndash Decision Rules The decision rule will be based upon the identification of predicted indoor air concentrations of CHC compounds associated with groundwater andor soil vapour impacts which exceed adopted response levels

              PAGE 8 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Objective Comment

              Step 6 ndash Decision Error Tolerances The purpose of establishing decision error tolerance is to control the acceptable degree of uncertainty upon which decisions are made in order to avoid the making of an incorrect decision and to enable identification of additional investigation monitoring or remediation activities required on the basis of accurate data for the protection of human health and the environment The Measuring Quality Objectives (MQO) include the quality assurance (QA) activities that were conducted during the assessment the quality control (QC) acceptance criteria applicable to the assessment and the adopted Data Quality Indicators (DQIs) as follows (and further discussed in Section 5) completeness ndash a measure of the amount of useable data from a data

              collection activity comparability ndash the confidence (expressed qualitatively) that data may be

              considered to be equivalent for each sampling and analytical event representativeness ndash the confidence (expressed qualitatively) that data

              are representative of each media present on the site precision ndash a quantitative measure of the variability (or reproducibility) of

              data and accuracy (bias) ndash a quantitative measure of the closeness of reported data

              to the true value

              Step 7 ndash Optimisation of the Data collection was undertaken in general accordance with the Sample Collection Design methodologies outlined in the relevant documentsguidelines referenced

              throughout this report As determined by the EPA the data collection design included targeted sampling to investigate and delineate areas of potential groundwater and soil vapour contamination and to assess potential associated human health risks

              80607-1 REV1 30102017 PAGE 9

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              3 SCOPE OF WORK

              The scope of work undertaken by Fyfe was generally consistent with that requested within the original EPA request for quote (RFQ) dated 27 March 2017 Some modifications to the original workscope occurred based on site findings and additional site information was collected where required and as agreed with the EPA in order to achieve the EPArsquos project objectives outlined in Section 15

              As identified in the RFQ the scope of work was designed to

              provide an initial delineation of CHC impacts in soil vapour through the deployment of Waterloo Membrane Samplers (WMStrade) as a screening tool

              further delineate the previously identified CHC impacts in groundwater

              decide based on the results of the WMStrade and groundwater results the need for the number of and the locations of permanent soil vapour monitoring bores

              identify the nature extent and potential source area(s) of the identified CHC impacts in groundwater andor soil vapour

              determine the likely fate and transport of the groundwater CHC plume to support the establishment of a potential future GPA

              determine the potential human health (including vapour intrusion) risk(s) on the basis of the data collected and

              ascertain whether or not a public health risk exists within the Thebarton EPA Assessment Area

              The scope of work is further detailed in Section 32 Variations from the scope of work originally requested in the EPA RFQ were agreed with the EPA during the course of the project and included the following

              deployment of an additional four WMStrade units ndash ie 41 in total as compared to the original allowance of 37

              installation (and sampling) of an additional six nested soil vapour bores (to depths of 1 and 3 m BGL) ndash ie 11 in total as compared to the original allowance of five

              installation (and sampling) two individually located (ie as opposed to the nested locations) soil vapour bores to a depth of 1 m BGL ndash ie as compared to the original allowance of 10

              installation (and sampling) of 25 groundwater monitoring wells ndash ie as compared to the original allowance of 20 and

              sampling of an existing well in Admella Street (MW02) ndash ie not included in the original EPA scope

              80607-1 REV1 30102017 PAGE 11

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              31 Preliminary work

              Preliminary work involved the following

              review and summation of all available historical reports (as supplied by the EPA) ndash refer to Appendix A

              development of a preliminary (working) conceptual site model (CSM) based on a review of the historical data

              preparation of a detailed health and safety plan covering all aspects and stages of the work and

              detailed planning with key stakeholders prior to the execution of the field investigation program

              32 Field investigation and laboratory analysis program

              The scope of the field investigation program undertaken by Fyfe between 31 May and 28 August 2017 is summarised in Table 31 whereas the scope of the laboratory testing program is summarised in Table 32

              A plan showing the various assessment point locations is included as Figure 2

              Table 31 Scope of field investigation program ndash May to August 2017

              Scope Item Description of works Date of works

              Passive soil vapour sampling ndash Round 1

              Thirty-seven WMStrade units identified as WMS 1 to WMS 37 were installed within the soil profile to 1 m BGL at scattered (approximately grid-like) locations across the Thebarton EPA Assessment Area

              31 May and 1 to 2 June

              The WMStrade units were extracted and forwarded to the analytical laboratory 7 June

              Soil bores were located using a hand-held global positioning system (GPS) unit before being backfilled with (drillerrsquos) sand

              7 August

              Monitoring well drilling and installation

              Individual groundwater well permits were obtained from DEWNR prior to well installation ndash copies of the well permits are included in Appendix D Groundwater monitoring wells (MW1 MW3 and MW5 to MW26) were installed to depths of between 15 and 19 m BGL at 24 locations across the Thebarton EPA Assessment Area Background well MW4 was installed to 19 m BGL within a public recreational area located across James Congdon Drive to the east (ie near the south-eastern corner of the Thebarton EPA Assessment Area) All 25 newly installed wells were developed following installation

              28 to 30 June 3 to 7 July and 10 to 14 July

              Geotechnical soil testing

              Intact soil cores collected during the drilling of 10 groundwater wells (MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25) were forwarded to the analytical laboratory for geotechnical testing

              Groundwater gauging

              All 25 newly installed monitoring wells (MW1 and MW3 to MW26) as well as the existing Admella Street well (MW02) were gauged to assess total well depth standing water level (SWL) and the presenceabsence of non aqueous phase liquid (NAPL) This was undertaken as a discrete event prior to the commencement of groundwater sampling

              18 July

              PAGE 12 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Scope Item Description of works Date of works

              Groundwater sampling

              All 26 existing and newly installed wells were sampled using a combination of low flow (micropurge) and HydraSleevetrade sampling techniques (as recorded on the field sampling sheets in Appendix E) ndash samples were forwarded to the analytical laboratories

              18 to 21 and 24 to 25 July

              Aquifer testing Aquifer permeability (slug) testing was undertaken on 10 wells (MW02 MW3 MW7 MW14 MW17 MW20 MW21 MW23 MW25 and MW26) Data was subsequently evaluated by Arcadis Pty Ltd (Arcadis) to estimate the hydraulic conductivity of the aquifer beneath the Thebarton EPA Assessment Area (refer to Section 732)

              28 July

              Soil vapour bore drilling and installation

              Following the receipt of the groundwater data 11 nested soil vapour bores (SV1 to SV10 and SV12) were installed to a depth of 1 and 3 m BGL at selected locations within the Thebarton EPA Assessment Area Two additional soil vapour bores (SV11 and SV13) were installed to a depth of 1 m BGL

              18 21 and 22 August

              Active soil vapour sampling

              Sampling of soil vapour bores was undertaken using summa canister (TO-15) sample collection methods Vapour (canister) and general gas (Tedlar bag) samples were extracted from all 13 locations (ie SV1 to SV13) including the 11 nested bores

              24 August

              Passive soil vapour sampling ndash Round 2

              Following the receipt of the groundwater data and for the purposes of comparison with the soil vapour bore data an additional four WMStrade units (WMS 38 to WMS 41) were installed within the soil profile to 1 m BGL at targeted locations across the Thebarton EPA Assessment Area (ie within approximately 1 m of soil vapour bores SV2 SV4 SV5 and SV7) Soil bores were located using a hand-held GPS unit

              18 August

              The WMStrade units were extracted and forwarded to the analytical laboratory and the soil bores were backfilled with (drillerrsquos) sand

              24 August

              Surveying The locations of all soil vapour bores and groundwater wells were surveyed by a licensed surveyor relative to the Map Grid of Australia (MGA) 1994 and the top of each bore was surveyed relative to Australian Height Datum (AHD) The survey data are included in Appendix F

              22 July and 28 August

              Notes as determined by the EPA

              Table 32 Scope of laboratory testing program

              Scope Item Description of works

              Soil geotechnical testing

              Soil samples from each of three depths within core samples collected during the drilling of groundwater wells MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25 were analysed for particle size distribution (PSD) moisture content including degree of saturation bulk density dry density and specific gravity void ratio and porosity

              80607-1 REV1 30102017 PAGE 13

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Scope Item Description of works

              Groundwater testing Groundwater samples from all 26 wells were analysed for the COPC detailed in Section 14 As requested by the EPA groundwater samples from selected wells (MW02 MW5 MW8 MW9 MW12 MW17 MW21 MW22 MW23 and MW26) were also analysed for the following major cations and anions (calcium magnesium sodium potassium chloride and alkalinity)

              and natural attenuation parameters (carbon dioxide (CO2) sulfate iron manganese nitrate) Additional components reported by the analytical laboratory included nitrite and nitrate + nitrite

              Soil vapour testing The WMStrade units deployed during each of Rounds 1 and 2 were analysed for the COPC detailed in Section 14 The soil vapour (summa canister) samples were analysed for the COPC detailed in Section 14 as well as 2-propanol and general gases (helium hydrogen oxygen nitrogen methane carbon dioxide ethane propane butane iso-butane pentane iso-pentane hexane argon carbon monoxide and ethylene)

              Notes Specific sample depths are detailed in the relevant laboratory reports in Appendix G also known as isopropyl alcohol isopropanol or IPA

              33 Data interpretation

              Following the receipt and collation of the field and laboratory data hydrogeological (fate and transport) and VIRA modelling (refer to Sections 8 and 9 respectively) were undertaken to enable an assessment of risk and to refine the CSM (Section 10)

              PAGE 14 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              4 METHODOLOGY

              41 Field methodologies

              Prior to the commencement of the field investigations a site specific Health and Safety Plan (HSP) including Safe Work Method Statements (SWMS) and a Job Hazard Analysis (JHA) was prepared ndash all personnel working at the site were required to read understand sign and conform to the HSP

              Each proposed drilling location was cleared of underground services by a professional service location company (Pipeline Technologies) using conventional (electronic) service detection methods as well as ground penetrating radar (GPR) Where underground or overhead services were present andor deemed to be a potential safety risk during drilling activities the drill location was moved to an area considered by the Fyfe representative and service locator to be safe All changes to drilling locations were notified to EPA and recorded on a site plan for future reference

              Given that works were undertaken within suburban streets Fyfe employed the services of a qualified traffic management company (Altus Traffic) during drilling activities in order to ensure safety for pedestrians and road users minimal disruption to traffic flow and the provision of a safe working environment

              Field methodologies as detailed in Table 41 were undertaken in accordance with Fyfersquos standard operating procedures (SOPs) Relevant field sampling sheets are included in Appendices F (groundwater) and G (soil vapour ndash combined field sampling sheets and chain of custody (COC) documents) and borehole log reports are presented in Appendices H (groundwater) I (WMStrade) and J (soil vapour)

              Table 41 Summary of field methodologies

              Activity Details

              Passive soil bore sampling The soil bores used to deploy the WMStrade units were hand augered by personnel from Fyfe and Aussie Probe to a depth of 1 m BGL SGS Australia (SGS) personnel suspended each WMStrade unit into its respective borehole from a string The hole was then sealed with an expandable foam plug inside a polyethylene sleeve and the string suspending the sampler was connected to a temporary plastic cap at the ground surface The Round 1 WMStrade units were deployed for periods of between six and seven days whereas the Round 2 WMStrade units were all deployed for six days Following retrieval by SGS each WMStrade unit was placed into a sealed glass vial and a labelled foil bag The WMStrade units did not require chilling during transport to the analytical laboratory Borehole log reports are included in Appendix I whereas combined field sampling sheets and COC documents are presented in Appendix G

              80607-1 REV1 30102017 PAGE 15

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Activity Details

              Groundwater well Groundwater wells were drilled by WB Drilling using a combination of hand augering installation mechanical pushtube and solid auger techniques

              Following the completion of drilling each borehole was fitted with 50 mm class 18 uPVC casing with a basal 6 m long section of slotted well screen A filter pack comprising clean graded sands of suitable size to provide sufficient inflow of groundwater was installed within the annular space between the borehole and the well casing and extended from the base of the screened interval to approximately 1 m above the termination of the slotted casing A 1 m long bentonite collar comprising pelleted or granulated bentonite was placed above the filter pack to prevent water seepage downward along the well casing or borehole from ground surface Each well was grouted up to surface level and fitted with a (lockable) steel gatic cover the latter flush mounted to prevent tripping andor other hazards Groundwater well log reports are included in Appendix H

              Soil logging and Soil logging was undertaken in general accordance with the ASC NEPM (1999) which geotechnical sampling endorses AS1726-1993 In addition to the requirements of AS1726-1993 particular

              attention was paid during logging to any lithological variations such as sandgravel lenses or secondary porosity (such as clay fracturing) which may act as potential preferential pathways for contaminant vapourgroundwater migration through the sub-surface as well as the presence of fill material andor any olfactory or visual evidence of contamination Soil descriptions have been included on the logs in Appendices H to J Cores for geotechnical analysis were collected using push tube sampling methodologies to obtain undisturbed samples Section(s) of core to be tested were retained (intact) within the pushtube liners and capped at each end for storage and transport to the analytical laboratory

              Field screening of soils Field screening of individual soil layers was undertaken at the majority of the drilling locations and involved the use of a photoionisation (PID) unit fitted with an 117 eV lamp (ie as considered suitable for the detection of CHC) The PID unit was calibrated by the hire company prior to delivery and was checked on a daily basis against an isobutylene calibration gas of known concentration Field screen samples were collected with care to ensure that each sample was representative of the soil stratum from which it was collected and experienced minimal loss of volatile compounds The soil material was placed immediately into a zip lock bag and sealed ensuring the bag was half filled (ie such that the volume ratio of soil to air was equal) Soil clumps within the bag were manually broken up and the bag was left to rest for a minimum of five minutes but no longer than 20 minutes Prior to testing the bag was shaken vigorously to release any vapours within the soil To test the tip of the PID probe was inserted into the bag and the maximum volatile organic compound (VOC) reading recorded after a nominal 10 second period or when the reading had peaked Results were recorded on the appropriate bore log sheets presented in Appendices H to J

              Groundwater well Following installation the wells were developed by purging a minimum of four well development volumes (ie until stable parameters were obtained andor until the well purged dry) from

              the casing with a steel bailer andor twister pump to ensure hydraulic connectivity with the aquifer formation

              Groundwater gauging Groundwater levels in the newly installed and existing monitoring wells located across the Thebarton EPA Assessment Area were gauged using an interface probe prior to the commencement of the groundwater sampling program All monitoring wells were gauged for SWL the potential presence of NAPL and the total well depth Groundwater field gauging results are presented in Appendix E

              PAGE 16 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Activity Details

              Groundwater sampling The majority of the wells were sampled using low flow (micropurge) techniques Where recovery was particularly low (ie MW4 MW8 MW15 MW18 MW19 and MW24) and unsuitable for low flow (micropurge) sampling the original sampling technique was abandoned and a HydraSleeveTM (no purge) methodology was used instead Groundwater samples were collected in laboratory-supplied screw top bottles containing appropriate preservative (if required) with no headspace allowed Samples were chilled during storage and transport to the analytical laboratory Disposable nitrile gloves worn by field personnel were changed prior to the collection of each sample Samples for metals (ie iron manganese) analysis were filtered in the field using 045 microm filters Groundwater field sampling sheets are presented in Appendix E

              Low Flow Methodology The low flow sampling technique involved the following the pump was placed close to the bottom of the screened interval the flow rate (up to 05 Lmin) was regulated to maintain an acceptable level of

              drawdown with minimal fluctuation of the dynamic water level during pumping and sampling

              groundwater drawdown was monitored constantly during purging and sampling using an interface probe

              water quality parameters were considered to have stabilised when the following ranges were recorded over three consecutive readings ndash electrical conductivity plusmn 5 ndash pH plusmn 01 ndash temperature plusmn 02degC ndash dissolved oxygen plusmn 10 ndash redox potential plusmn 10 mV

              the stabilisation parameters were recorded on field logging sheets after every one litre of groundwater purged using a calibrated water quality meter and a flow cell suspended in a bucket with litre intervals marked and

              samples were collected once three consecutive stabilisation parameters were recorded and a volume of between 28 and 6 litres was purged prior to sampling

              HydraSleeveTM Methodology The HydraSleeveTM sampling technique involved attaching a stainless steel weight to the bottom and a wire tether clip to the throat of the HydraSleeveTM before lowering it into the water column to the desired depth and allowing it to fill with groundwater After a minimum period of 24 hours the HydraSleeveTM was quickly and smoothly withdrawn from the well and the contents were transferred into the sample containers Water quality parameters were measured after samples were decanted ndash either within the water remaining in the HydraSleeveTM or within a grab sample collected using a disposable bailer

              Hydraulic testing Rising and falling head permeability (ldquoslugrdquo) tests were undertaken to estimate the hydraulic conductivity (K) of the aquifer within various parts of the Thebarton EPA Assessment Area The falling-head tests were initiated by quickly inserting a 1285 m long and 36 mm diameter solid PVC cylinder (slug) into the water column at each well to produce a sufficient sudden rise in the water level The subsequent ldquofallrdquo back to the static water level (recovery) was measured and recorded automatically and in real-time using a

              80607-1 REV1 30102017 PAGE 17

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Activity Details

              pressure transducerdata logger programmed to record water levels at a one second interval After static water level conditions returned in the well the rising-head test was initiated by quickly removing the slug from the well to create a sudden drop in the water column height As with the falling-head test the rise of the water level back to a static condition (recovery) was automatically recorded

              Soil vapour bore Soil vapour bores were drilled by Aussie Probe using a combination of hand augering and installation mechanical pushtube techniques

              Within each 3 m deep soil vapour bore teflon tubing attached to a soil vapour probe was inserted to the base of the hole which had been prefilled with approximately 005 m of clean filter pack sand An additional 045 m of sand (ie approximately 05 m in total) was then added to the hole and topped by a bentonite plug seal of approximately 05 m thickness A second soil vapour probe was installed at a depth of about 1 m within a 05 m sand pack which was overlain by bentonite to a depth of about 02 to 03 m BGL The two 1 m deep soil vapour bores were installed in a similar manner with a sand pack extending from the base to about 05 to 06 m BGL overlain by a bentonite plug to 03 m BGL Each installation was completed with grout to surface and topped with a standard flush-mounted gatic cover Soil vapour bore log reports are included in Appendix J

              Soil vapour sampling All soil vapour sampling works were undertaken by SGS using suitably trained and experienced personnel ndash SGS holds National Association of Testing Authorities (NATA) accreditation for all soil vapour sampling and laboratory analytical works Combined field sampling sheets and COC documents are presented in Appendix G Soil vapour samples were collected using summa canisters and analysed using the US EPA (1999) TO-15 method Sampling involved the connection of a passivated 1 L stainless steel canister to the teflon tubing extending from the soil vapour probe and the use of a soil gas sampling train to restrict flow to a maximum rate of 200 mLmin Canister vacuum pressure was monitored during sampling to enable calculation of the volume of sample drawn into the canister ndash the small amount of vacuum left in the canister at the end of the sampling procedure was measured in the laboratory to check if any leaks occurred during transit (refer to further discussion in Table 52) A shroud was set up around the sampling point and tracer chemicals were introduced at high concentrations by flooding the shroud with helium and placing a cloth soaked with IPA into the shroud Each canister was cleaned and certified by SGS prior to use (refer to Appendix G) and backshyup coconut shell carbon sorbent tube samples were also collected (but not analysed) Summa canisters did not require chilling during transport to the analytical laboratory

              Waste disposal Waste water and surplus soil corescuttings were stored together within 205 litre drums in the rear car park of a commercialindustrial property at 19-21 James Congdon Drive (as organised by the EPA) prior to removaldisposal by a licensed waste removal company (Cleanaway) Analytical results pertaining to the soils were forwarded to the licensed receiving facility and all of the soil was classified as lsquoWaste Fillrsquo in accordance with the Environment Protection Regulations 2009 The waste transport certificates are included in Appendix K

              PAGE 18 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              42 Laboratory analysis

              The following laboratories were used for the analysis of the environmental samples

              complete soil cores for geotechnical sample analysis were forwarded to SMS Geotechnical

              primary groundwater samples collected by Fyfe were analysed at the SGS laboratory whereas secondary groundwater samples were forwarded to EurofinsMGT and

              soil vapour (including WMStrade) samples collected by SGS were analysed at their laboratory

              80607-1 REV1 30102017 PAGE 19

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              5 QUALITY ASSURANCE AND QUALITY CONTROL

              Data quality is typically discussed in terms of the DQIs presented in Table 22 ndash ie completeness comparability representativeness precision and accuracy In order to assess the quality of the data collected during the Fyfe investigation program against these DQIs specific QAQC procedures were implemented during both the field sampling and laboratory analysis programs as detailed in the following sections

              51 Field QAQC

              Field QA procedures undertaken during the recent investigations included the collection of the following QC samples aimed at assessing possible errors associated with cross contamination as well as inconsistencies in sampling andor laboratory analytical techniques

              intra-laboratory duplicate (duplicate) samples submitted to the same (primary laboratory) to assess variation in analyte concentrations between samples collected from the same sampling point andor the repeatability (precision) of the analytical procedures

              inter-laboratory duplicate (split or triplicate) samples submitted to a second laboratory to check on the analytical proficiency (accuracy) of the results produced by the primary laboratory

              equipment rinsate blank samples collected during groundwater sampling only and used to assess cross-contamination that may have occurred from sampling equipment during sampling and

              trip blank samples used to assess whether cross-contamination may have occurred between samples during transport

              Whereas analyte concentrations within the rinsate and trip blank samples should be below the laboratory limit of reporting (LOR) the inter- and intra-laboratory duplicate sample results are assessed via the calculation of a relative percentage difference (RPD) as follows

              (Concentration 1 minus Concentration 2) x 100RPD = (Concentration 1 + Concentration 2) 2

              Maximum RPDs of 30 (inorganics) and 50 (organics) are generally considered acceptable with higher RPD values often recorded where concentrations of an analyte approach the laboratory LOR

              All field QC sample results are included in the summary data tables in Appendix L

              511 Groundwater

              Table 51 presents conformance to field QAQC procedures undertaken as part of the groundwater investigations

              80607-1 REV1 30102017 PAGE 21

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Table 51 Field QAQC procedures ndash Groundwater

              QAQC Item Detail

              Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) AustralianNew Zealand standards ASNZS 566711998 and ASNZS 5667111998 SA EPA (2007) and Fyfe SOPs Details are provided in Table 41

              Calibration of field equipment

              Documentation regarding the calibration of field equipment is included in Appendix M

              Decontamination of All disposable equipment (tubing pump bladders plastic bailers bailer cord and equipment HydraSleeveTM units) were replaced between wells Re-usable equipment (micropurge pump

              interface probe and HydraSleeveTM weights) was decontaminated between sampling locations using potable water and Decon 90trade phosphate free detergent

              Sample preservation and storage

              Samples were kept in laboratory supplied containers in a portable chilled insulated box (esky) prior to and during transport to the laboratory

              Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

              Duplicate samples Two intra-laboratory and two inter-laboratory duplicate samples were analysed for CHC with respect to 26 primary groundwater samples ndash thereby constituting an overall ratio of approximately one duplicate per 65 primary samples (or 15) compared to a generally acceptable ratio of 110 samples (or 10) One intra-laboratory and one inter-laboratory duplicate sample were analysed for the remaining parameters with respect to 10 primary groundwater samples ndash thereby constituting an overall ratio of one duplicate per five primary samples (or 20) compared to a generally acceptable ratio of 110 samples (or 10) Intra- and inter-laboratory duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within the acceptable range with the exception of the following intra-laboratory duplicate sample pair MW9QW1 TCE (67) nitrate (147) and inter-laboratory duplicate sample pair MW9QW2 total CO2 (59) iron (190)

              manganese (183) potassium (64) nitrate (194) The elevated RPD for TCE in the intra-laboratory duplicate sample pair is considered to be related to the low concentration detected and does not alter the interpretation of the data The other RPD exceedances are not considered significant (ie in terms of overall data interpretation) as they were not obtained for identified COPC (as defined in Section 14)

              Rinsate blank samples Six equipment rinsate blank samples (one for each day of sampling) were collected from either the pump housing or a new HydraSleevetrade (final day of sampling only) and analysed for CHC to confirm the effectiveness of the decontamination procedures and the cleanliness of disposable equipment The analytical results obtained for the rinsate blank samples were all below the laboratory LOR thereby indicating that decontamination practices during the groundwater sampling program were acceptable and that no contamination was introduced by the use of the HydraSleevestrade

              Trip blank samples Six trip blank samples were included within containers (eskies) of sample bottles provided by the analytical laboratory and returned to the analytical laboratory All of the trip blank samples were analysed for CHC With the exception of TB187 which contained 1 microgL TCE the analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was limited impact on sample quality during storage or transport of the samples to the analytical laboratory

              PAGE 22 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Notes No duplicate QC samples were collected during the use of the HydraSleeveTM sampling technique as detailed in ANZECCARMCANZ (2000a) at least 5 (ie 120) duplicate samples should be analysed ndash the generally accepted industry standard however is 10 (110) including 5 intra-laboratory and 5 inter-laboratory duplicates

              512 Soil vapour

              Tables 52 presents conformance to field QAQC procedures undertaken as part of the soil vapour (passive and active) investigations

              Table 52 Field QAQC procedures ndash Soil vapour

              QAQC Item Detail

              Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) as well as ASTM (2001 2006) ITRC (2007) CRC CARE (2013) guidance and Fyfe SOPs Details are included in Table 41 and Appendix G (ie SGS sampling methodology sheet) During the use of summa canisters to sample the soil vapour bores leak testing was undertaken (as described in Table 41) Although small leaks or ambient drawdown appear to have occurred with respect to samples SV11_10m (003 helium) SV13_10m (003 helium) and SV1_10m (360 microgm3 IPA) ITRC (2007) and NJDEP (2013) state that ge 5 helium andor gt10 mgm3 IPA are required to be indicative of a significant leak or substantial ambient drawdown Given that the leaks were relatively small (ie 06 (helium) and 36 (IPA) of the levels considered indicative of a significant leak) the data from these bores were still considered to be valid ndash refer to SGS correspondence in Appendix G As detailed in Table 41 a small amount of vacuum was generally left in each summa canister at the end of the sampling procedure and was measured in the laboratory to check if any leaks had occurred during transit However samples SV11_10m SV12_30m as well as the helium blank were recorded as having zero vacuum upon receipt at the analytical laboratory A query lodged with SGS regarding this issue indicated that whereas the helium blank comprised a grab sample collected into a Tedlar bag directly from the helium cylinder (ie without the use of a gauge) the canisters used for samples SV11_10m and SV12_30 were filled during sampling so that there was no remaining vacuum ndash refer to field sampling documentation in Appendix G SGS stated that although it is good practice to have a small amount of vacuum remaining in a canister at the completion of sampling appropriate additional QC measures were employed and the absence of other common background VOCs (eg petroleum hydrocarbons) upon sample testing indicated that leakage had not occurred during transit In addition all canisters are fitted with quick connect one-way valves that are closed upon removal from the sampling train and canistersfittings are leak checked prior to leaving the laboratory and again in the field to ensure that they are leak free Refer to SGS correspondence in Appendix G The presence of detectable IPA (120 microgm3) and TCE (48 microgm3) in the helium blank was also queried with SGS who stated that this (ie variability in the quality of the high purity helium gas used) is not an uncommon occurrence The reason for collecting a helium blank sample is to identify any impurities present in the helium gas so that if a leak does occur during sampling it is possible to determine whether any target compounds could be introduced into the sample train Although a target compound (ie TCE) was detected in the blank the concentration is minor and even if a leak had occurred during sampling (of which there was no evidence) it would not have affected the overall results and data interpretation The presence of IPA in the helium blank is

              80607-1 REV1 30102017 PAGE 23

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              QAQC Item Detail

              suspected by SGS of having resulted from a handling issue in the field ndash ie sub-sampling from the helium cylinder (ie into a summa canister via a flex foil bag) in the vicinity of the high concentrations of IPA being used for leak detection Refer to SGS correspondence in Appendix G

              Sample preservation and storage

              Following collection the WMStrade units were placed into individual glass vials which were sealed and placed into foil bags for transport to the analytical laboratory at ambient temperature Summa canisters were stored in specially constructed cases during transport to the analytical laboratory at ambient temperature

              Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

              QC samples ndash WMStrade sampling

              During the first round of passive soil vapour sampling three additional WMStrade units were deployed in soil bores drilled adjacent to WMS 22 WMS 25 and WMS 28 to act as duplicate QC samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 8) Two trip blank samples were also included with samples transported from and to the analytical laboratory All of the QC samples were analysed by the primary laboratory Intra-duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within an acceptable range (ie lt30) The analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was negligible impact on sample quality during storage or transport of the samples to the analytical laboratory

              QC samples ndash soil vapour bore sampling

              Two intra-laboratory duplicate QC samples were analysed for CHC and general gases with respect to 24 primary soil vapour samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 83) compared to an acceptable ratio of 110 samples (or 10) Intra-laboratory duplicate RPDs were calculated where both samples had a reported concentration above the laboratory LOR All calculated RPDs for CHC and general gases were within an acceptable range (ie lt30) The analytical results obtained for the helium shroud (Tedlar bags) helium blank and IPA shroud (carbon tube) samples were all considered to be satisfactory

              Notes The American Society for Testing and Materials (ASTM) is an internationally recognised source of testing methods Although Appendix J of CRC CARE (2013) stipulates a 110 duplicate sampling ratio for active vapour sampling a specific ratio is not stipulated for passive vapour sampling

              52 Laboratory QAQC

              Laboratory QA procedures generally include the performance of a number of internal checks of data precision and accuracy that are aimed at assessing possible errors associated with sample preparation and analytical techniques Specific types of QC samples analysed by laboratories and the relevant acceptance criteria are as follows

              PAGE 24 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              internal laboratory replicate samples maximum RPD values of 20 to 50 although this varies depending on laboratory LOR

              spike recoveries results between 70 and 130 and

              laboratory controlmethod blanks results below the laboratory LOR

              Table 53 presents conformance to laboratory QAQC procedures undertaken as part of the overall investigation program

              Table 53 Laboratory QAQC procedures

              QAQC Item Detail

              Samples analysed and Samples were generally analysed within specified holding times ndash with the exception extracted within relevant of the following groundwater samples holding times SGS report no ME303457 nitrate was analysed two days late in some samples

              (MW5 MW17 MW26) SGS report no ME303475 nitrate was analysed one day late in all samples and EurofinsMGT report no 555810-W total CO2 was analysed five days late None of these holding time exceedances are considered to be significant with respect to the interpretation of the CHC data the determination of potential human healthenvironmental risks andor the determination of natural attenuation

              Laboratories used and The laboratories used (SGS Eurofins MGT and SMS Geotechnical) were NATA NATA accreditation accredited for the majority of the analyses undertaken

              The exception was SMS Geotechnical which was not NATA accredited for the calculations undertaken to derive some of the data ndash this is the case however for all geotechnical laboratories

              Appropriate analytical methodologies used

              Refer to the laboratory reports in Appendix G

              Laboratory limit of The laboratory LOR is the minimum concentration of an analyte (substance) that can reporting (LOR) be measured with a high degree of confidence that the analyte is present at or above

              that concentration The LOR are presented in the laboratory certificates of analysis (Appendix G) and are considered to be generally appropriate (ie below the adopted assessment criteria ndash refer to Section 62) ndash the following exceptions in soil vapour (ie considered to be due to interference associated with elevated concentrations of other compounds ndash refer to SGS correspondence in Appendix G) are discussed further in Table 101 VC in all of the WMStrade samples relative to the ASC NEPM (1999) interim soil

              vapour health investigation level (HIL) for residential land use cis-12-DCE and VC in two soil vapour bore samples (SV2_30m and SV3_30m)

              relative to the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land use and

              VC in two soil vapour bore samples (SV3_10m and SV7_30m) relative to the ASC NEPM (1999) interim soil vapour HIL for residential land use

              In addition to the above although ultra-trace analysis was requested the laboratory LOR for VC in groundwater (ie 1 microgL) is above the adopted NHMRCMRMMC (2011) potable guideline (ie 03 microgL) ndash refer to Section 612

              80607-1 REV1 30102017 PAGE 25

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              QAQC Item Detail

              Laboratory internal QC analyses

              Results obtained for the laboratory internal QC samples were generally within the acceptable limits of repeatability chemical extraction and detection with the exception of the following SGS report ME303457 matrix spike results for iron were outside normal tolerances

              due to the high concentrations of iron in the spiked sample ndash matrix spike results for iron could therefore not be calculated This is not considered to be a significant issue

              Full details regarding laboratory QAQC procedures and results are presented in the certified laboratory certificates contained in Appendix G

              Notes Since holding times were not specified in the SGS groundwater reports Fyfersquos assessment of holding times has been based on those adopted by EurofinsMGT (ie the secondary laboratory used for groundwater analysis) ie in accordance with Schedule B3 of the ASC NEPM (1999) also referred to as practical quantification limits (PQL)

              53 QAQC summary

              In summary it is considered that

              the field QAQC programs were generally undertaken with regard to relevant legislation standards andor guidelines and were sufficient for obtaining samples that are representative of site conditions and

              the overall laboratory QAQC procedures and results were adequate such that the laboratory analytical results obtained are of acceptable quality for addressing the key objectives outlined in Section 15

              PAGE 26 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              6 ASSESSMENT CRITERIA

              61 Groundwater

              611 Beneficial Use Assessment

              In accordance with Schedule B6 of the ASC NEPM (1999) and SA EPA (2009) a Beneficial Use Assessment (BUA) was undertaken to assess both the current and realistic future uses of groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area

              This was aimed at determining what groundwater uses need to be protected and assessing the risk(s) that groundwater may pose to human health and the environment (refer also to the VIRA in Section 9)

              As summarised in Table 61 the potential beneficial uses for groundwater within the Q1 aquifer that have been considered are as follows ndash taking into account the salinity of the groundwater the Environment Protection (Water Quality) Policy 2015 (Water Quality EPP 2015) the DEWNR (2017) WaterConnect database information presented in Section 222 and possible sensitive receptors located within andor within the vicinity of the Thebarton EPA Assessment Area

              The salinity of groundwater has been calculated to approximate 1230 to 3620 mgL TDS (refer to Section 7312) According to the Water Quality EPP 2015 the applicable environmental values for groundwater with salinity above 1200 mgL TDS but less than 3000 mgL TDS are irrigation livestock and aquaculture whereas the salinity is considered to be too high for potable use ndash although domestic irrigation is considered to be a potentially realistic use for this area (see below) livestock watering is considered unlikely to be undertaken in such an urban setting and no local water bodies (ie surface or groundwater) have been identified as being used for commercial aquaculture purposes

              The DEWNR (2017) WaterConnect database indicates that groundwater within the Q1 aquifer in the Thebarton area is accessed for drainage domestic and industrial purposes ndash domestic groundwater use could include garden irrigation plumbing water andor the filling of swimming pools (ie primary contact recreation) Although domestic groundwater extraction is considered unlikely to include potable use (ie due to its salinity and the availability of a reticulated mains water supply) potential mixing with rain watermains water could render it suitable (ie from a salinity perspective) for drinking

              As the closest freshwater surface water body the River Torrens is located approximately 03 km to the east and 07 km to the north and north-west of the northern portion of this area groundwater discharge from the Thebarton EPA Assessment Area into a freshwater aquatic ecosystem is considered possible However as the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area the potential for impact on a freshwater aquatic environment has not been confirmed

              80607-1 REV1 30102017 PAGE 27

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Since the closest marine surface water body Gulf St Vincent is located approximately 8 km to the west groundwater discharge from the Thebarton EPA Assessment Area into a marine aquatic ecosystem is not considered to be realistic

              Since volatile contaminants have been detected within the Q1 aquifer (refer to Section 7331) a potential vapour flux risk to future site users must be considered

              Given the measured depth of the Q1 aquifer beneath the site (ie approximately 1232 to 1585 m BGL ndash refer to Section 7311) it is considered unlikely that direct contact could occur between groundwater and building footingsunderground services

              Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area

              Environmental Values Beneficial Uses

              Water Quality EPP 2015

              environmental value

              SA EPA (2009) Potential

              Beneficial Uses

              Beneficial Use Assessment

              Considered Applicable

              Aquatic Ecosystem

              Marine Yes No

              Fresh Yes Possibly

              Potable - Yes Possibly

              Agriculture Irrigation - Yes Yes

              Livestock - Yes No

              Aquaculture - Yes No

              Recreation amp Aesthetics

              Primary contact Yes Possibly

              Aesthetics Yes Possibly

              Industrial - Yes Yes

              Human health in non-use scenarios

              Vapour flux -

              Yes Yes

              Buildings and structures

              Contact - Yes No

              Notes ie for underground waters with a background TDS level of between 1200 and 3000 mgL ndash note that although they are not listed as environmental values of groundwater in Schedule 1(3) of the Water Quality EPP 2015 aquatic ecosystems as well as recreation amp aesthetics are included as environmental values for waters in general in Part 1(6) of the document ie domestic irrigation only

              612 Groundwater beneficial use criteria

              The health and ecological criteria used for the assessment of the COPC (refer to Section 14) in groundwater have been based on the results of the BUA (Section 611) A summary of the references used to source the groundwater assessment criteria is provided in Table 62

              PAGE 28 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Table 62 Sources of adopted groundwater assessment criteria

              Beneficial Use Reference

              Freshwater Ecosystems No criteria available for COPC

              Potable NHMRCNRMMC (2011) Australian Drinking Water Guidelines

              WHO (2017) Guidelines for Drinking-water Quality ndash TCE only

              Irrigation No criteria available for COPC

              Primary contact recreation (including aesthetics)

              NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines but (with the exception of aesthetic guidelines) multiplied by a factor of 10 to take account of accidental ingestion rates as opposed to deliberate ingestion

              ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality ndash recreational values (TCE only)

              Human health in non-use scenarios ndash vapour flux Refer to the VIRA in Section 9

              Notes As there are no specific guidelines for industrial water these values are considered likely to be protective of this additional beneficial use The NHMRC (2008) guidelines are based on drinking water levels and assume a consumption factor of 2 L per day Therefore as recommended in the NHMRC (2008) document potable criteria (ie with the exception of aesthetic criteria) need to be adjusted by a factor of 10 to account for an accidental consumption rate of 100 to 200 ml per day As noted in ANZECCARMCANZ (2000b) although recreational guidelines are protective of ingestion recreational waters should also not contain any chemicals that can cause skin irritation likewise although not specifically addressed by recreational water criteria inhalation may also represent a source of exposure with respect to some (ie volatile) contaminants In the absence of a NHMRCNRMMC (2011) drinking water guideline for TCE the ANZECCARMCANZ (2000b) recreational criterion (30 microgL) has been adopted However if the NHMRC (2008) rule of multiplying potable (healthshybased) guidelines by 10 is applied to the WHO (2017) drinking water guideline of 20 microgL a recreational guideline of 200 microgL would be more applicable

              62 Soil vapour

              The ASC NEPM (1999) interim soil vapour health investigation levels (HILs) for volatile organic chlorinated compounds (VOCCs) have been adopted (ie in the first instance ndash refer to Section 7331) as Tier 1 soil vapour assessment criteria ndash relevant land use scenarios within the Thebarton EPA Assessment Area include residential (HIL AB) and commercialindustrial (HIL D)

              These criteria have been further adjustedappended for the purposes of the VIRA Tier 1 assessment ndash refer to Section 94

              80607-1 REV1 30102017 PAGE 29

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              7 RESULTS

              71 Surface and sub surface soil conditions

              711 Field observations

              Groundwater well and soil vapour borehole log reports are included in Appendices H to J and provide details of the soil profile encountered at each sampling location

              Where encountered fill materials extended to depths of between 01 and 09 m BGL and included a range of different soil types (sand gravelcrushed rock silt) with only minimal waste inclusions (ie asphalt glass andor metal fragments) identified at some locations

              The underlying natural soil profile (encountered to the maximum drill depth of 19 m BGL) was dominated by low to medium plasticity brown to red-brown silty clays and sand claysclayey sands some of which contained sub-angular to rounded gravels that included river pebbles andor comprised fine distinct lenses in places Groundwater well MW17 also included a 15 m thick layer of gravel at depth (ie 12 to 135 m BGL) ndash ie consistent with the depth of groundwater within the Q1 aquifer

              During the course of the drilling works no odours or visual indicators of contamination were detected and measured PID readings ranged up to 6 ppm but were generally lt3 ppm

              712 Soil geotechnical testing

              A table of geotechnical testing results is presented in Appendix L (Table 1) and a copy of the certified laboratory report is included in Appendix G Photographs of soil cores are included in Appendix N

              The results were interpreted to indicate the following

              The soil core samples submitted for PSD analysis were dominated by clay with lesser amounts of fine to medium gravel andor fine to coarse-grained sand ndash all samples analysed were classified as either CLAY or Sandy CLAY with one sample classified as Clayey SAND The classifications obtained from the laboratory were deemed to be generally consistent with the descriptions on the groundwater well log reports (Appendix H) although the PSD results did not specify silt as a significant secondary component

              The moisture content of the analysed soil core samples ranged from 65 to 231 Moisture content with respect to soil type depth and location has been considered in more detail for the purposes of the VIRA (Section 9) The degree of saturation for the analysed soil cores samples ranged from 218 to 964

              Measured bulk density ranged from 160 to 212 tm3 specimen dry density from 141 to 184 tm3 and specific gravity from 255 to 281 tm3

              The measured void ratio ranged from 043 to 088 whereas porosity ranged from 032 to 047

              80607-1 REV1 30102017 PAGE 31

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              72 Waterloo Membrane Samplerstrade A table of WMStrade analytical results (ie from both rounds of sampling) is presented in Appendix L (Table 2) and copies of certified laboratory reports are included in Appendix G8

              Of the 41 WMStrade units deployed across the Thebarton EPA Assessment Area during the two sampling rounds 20 returned measurable concentrations of CHC including TCE PCE cis-12-DCE trans-12-DCE andor 11-DCE Although no VC was detected the laboratory LOR in all samples (ie 35 to 50 microgm3) was above the ASC NEPM (1999) soil vapour interim HIL for residential land use (30 microgm3) ndash refer also to Table 53

              Detectable COPC concentrations are summarised in Table 71 relative to the ASC NEPM (1999) soil vapour interim HILs along with the closest soil vapour bore andor groundwater monitoring well locations Measured TCE concentrations are detailed on Figure 3

              A comparison of the Round 1 and 2 WMStrade results (ie for closely located units9) is presented in Table 72 ndash the results indicate a general order of magnitude correlation of the results for most COPC with the exception of PCE for which lower concentrations were obtained during Round 2 As the Round 1 and 2 WMStrade units were located within different soil bores and deployed at different times some variability in the results is to be expected In addition and as discussed in Section 74 the WMStrade units have been used during this assessment as a (semi-quantitative) screening tool (ie to assist with the siting of the permanent soil vapour bores) with the results obtained from the soil vapour bores considered more representative of actual subsurface conditions

              Table 71 Detectable Waterloo Membrane Samplertrade CHC results

              Sample ID

              Location Closest land uses

              CHC concentration (microgm3) Closest soil vapour bore

              andor groundwater

              well

              TCE PCE cis-12shyDCE

              trans-12shyDCE

              11shyDCE

              VC

              WMS 1 Goodenough Street CI 35 -

              WMS 6 Maria Street CI 32 -

              WMS 7 Maria Street CI and R 1900 45 SV2 MW5

              WMS 8 Maria Street CI and R 12000 37 SV4

              WMS 11 Admella Street CI 71000 260 19 20 36 SV5 MW02

              WMS 14 George Street CI 46000 45 SV6 MW11

              WMS 18 Admella Street CI 4200 34 MW14

              WMS 19 Albert Street CI 11000 42 SV10MW15

              WMS 21 Chapel Street CI 10 -

              WMS 22 Admella Street CI 38 SV9

              WMS 24 Chapel Street CI 230 62 10 11 48 MW17

              8 Note that the original laboratory report for the Round 1 WMStrade samples was found to be incorrect (ie following receipt of the soil vapour bore and Round 2 WMStrade sample results) and was subsequently re-issued by SGS

              9 only two of which were sufficiently co-located for comparative purposes ndash Round 2 locations WMS 39 and WMS 41 were not within the immediate vicinity of Round 1 WMStrade bores (ie the closest Round 1 bores were approximately 30 m away)

              PAGE 32 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Sample ID

              Location Closest land uses

              CHC concentration (microgm3) Closest soil vapour bore

              andor groundwater

              well

              TCE PCE cis-12shyDCE

              trans-12shyDCE

              11shyDCE

              VC

              WMS 25 Albert Street CI and R 1400 20 MW17

              WMS 27 Light Terrace CI 64 62 SV11 MW19

              WMS 32 Holland Street R 16 -

              WMS 34 James Street R 11 -

              WMS 37 Dew Street R 44 -

              WMS 38 Maria Street CI and R 13000 56 SV2 MW5

              WMS 39 Maria Street CI and R 1300 SV4

              WMS 40 Admella Street CI 110000 97 SV5 MW02

              WMS 41 George Street CI 18000 10 SV7 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

              Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform (up to 530 microgm3) was also detected in WMS 8 WMS 11 WMS 14 WMS 16 WMS 18 WMS 19 WM 25 WMS 33 WMS 40 and WMS 41 interim soil vapour health investigation level (HIL)

              Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units

              Bore ID

              Depth (m)

              Location CHC concentration (microgm3)

              TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

              WMS 8 10 Maria Street 12000 37 lt95 lt99 lt22 lt36

              WMS 38 13000 56 lt11 lt11 lt25 lt41

              Relative percentage difference 8 147 - - - -

              WMS 11 10 Admella Street 71000 260 19 20 36 lt37

              WMS 40 110000 97 lt11 lt11 lt25 lt41

              Relative percentage difference 43 91 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

              80607-1 REV1 30102017 PAGE 33

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              73 Groundwater

              731 Field measurements

              A table of groundwater field parameters is presented in Appendix L (Table 3) and groundwater field sampling sheets are included in Appendix E

              7311 Groundwater elevation and flow direction

              The depth to water within the Q1 aquifer beneath the Thebarton EPA Assessment Area on 18 July 2017 ranged from 12323 to 15854 m below top of casing (BTOC)10 and 4469 to 5070 m AHD

              Groundwater elevation contours constructed from the July 2017 gauging data indicated that the overall groundwater flow direction within the Q1 aquifer was north-westerly consistent with expected regional groundwater flow The groundwater contours and inferred flow direction are shown on Figure 4

              7312 Field parameters

              As detailed in Table 51 field measurements were recorded during low flow purging (ie prior to micropurge sampling) of monitoring wells and immediately following the collection of HydraSleeveTM samples

              The field parameter readings recorded for the monitoring wells immediately prior to (low flow micropurge) and after (HydraSleeveTM) sampling indicated the following (as summarised in Table 3 Appendix L)

              groundwater pH ranged from 6 8 to 79 thereby indicating neutral conditions

              electrical conductivity (EC) measurements ranged from 189 to 556 mScm and were found to be reasonably consistent across the area thereby indicating that it is underlain by moderately saline water (ie approximating 1230 to 3620 mgL TDS11)

              redox concentrations ranged from -20 to 624 mV thereby indicating slightly reducing to strongly oxygenating conditions

              measured dissolved oxygen (DO) concentrations ranged from 04 to 78 ppm indicating slightly to highly oxygenated water and

              temperature ranged from 173 to 224oC

              Observations recorded during sampling indicated that the groundwater was clear to brown and only slightly to moderately turbid at most locations ndash the higher turbidity at MW18 and MW19 (combined with poor recharge) contributed towards the decision to use a HydraSleeveTM sampling method No odours or sheen were observed in any of the wells during gauging or sampling

              10 ie approximating m BGL 11 ie calculated by multiplying the field EC data by 065

              PAGE 34 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              732 Hydraulic conductivity

              Rising and falling head aquifer permeability (ldquoslugrdquo) tests were conducted on 10 groundwater wells (refer to Table 31 and Figure 2) to assess the hydraulic conductivity (K) of the Q1 aquifer

              To obtain estimates of near-well horizontal hydraulic conductivity for each well tested the slug test data were analysed by Arcadis using AQTESOLV for Windowstrade (Duffield 2007) following the guidelines presented in Butler (1998) ndash normalised displacement data collected from each test are plotted against time in Appendix A of the Arcadis report (refer to Appendix O) Since only one set of tests were performed at each well the reproducibility of the results as well as the dependence of the results on the initial displacement could not be verified or demonstrated As such multiple relevant and applicable solutions were applied to each test to account for that uncertainty (ie to ensure consistency of normalised response at each well regardless of initial displacement)

              Table 73 presents a summary of the range and average estimated hydraulic conductivity values (and corresponding analytical solutions used) for each well tested The results indicate that hydraulic conductivities ranged from approximately 0073 to 37 mday with an overall average of approximately 1 mday

              Table 73 Hydraulic conductivities (rising and falling head tests)

              Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

              (mday) Hydraulic Conductivity

              (mday)

              MW02 Falling head 011 to 014 DA CBP HV

              012 Rising head 0073 to 015 BR DA

              MW3 Falling head 034 to 062 BR DA

              047 Rising head 030 to 062 BR DA

              MW7 Falling head 075 to 25 BR DA

              139 Rising head 055 to 175 BR DA

              MW14 Falling head 011 to 021 BR DA

              014 Rising head 009 to 015 BR DA

              MW17 Falling head 21 to 22 DA KGS

              220 Rising head 225 to 244 DA KGS

              MW20 Falling head 22 to 37 BR DA HV

              256 Rising head 06 to 32 BR DA

              MW21 Falling head 073 to 123 BR DA

              084 Rising head 054 to 084 BR DA

              MW23 Falling head 088 to 162 BR DA

              101 Rising head 031 to 122 BR DA

              80607-1 REV1 30102017 PAGE 35

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

              (mday) Hydraulic Conductivity

              (mday)

              MW25 Falling head 10 to 18 BR DA CBP HV

              132 Rising head 049 to 17 BR DA

              MW26 Falling head 019 to 036 BR DA

              023 Rising head 010 to 029 BR DA

              Overall average K (mday) 1028 Notes References BR = Bouwer and Rice (1976) CBP = Cooper et al (1967) DA = Dagan (1978) HV = Hvorslev (1951) KGS = Hyder et al (1994)

              The monitoring wells that exhibited lower permeabilities (ie MW02 MW3 MW14 and MW26) were noted to be generally located in the up-gradient (south-eastern) portion of the Thebarton EPA Assessment Area whereas monitoring wells showing relatively higher permeabilities (ie MW7 MW17 MW20 MW21 MW23 and MW25) are generally located in the down-gradient (north-western) portion These results were considered by Arcadis to suggest a possible hydrogeologic transition from the south-east to the north-west AQTESOLV solution plots for each analysis are provided as Appendix A of the Arcadis report (Appendix O)

              As slug test results can be influenced by a number of factors which are difficult to avoid when performing and analysing slug test results hydraulic conductivity estimates derived from slug tests should be considered to be the lower bound of the hydraulic conductivity of the formation in the vicinity of the well (Butler 1998) However Arcadis also noted that the results obtained for the Thebarton EPA Assessment Area were similar to those reported for other areas of Adelaide with average values of 1 and 27 mday (refer to Appendix O)

              The slug test results were used by Arcadis in their groundwater fate and transport model (refer to Section 8)

              733 Analytical results

              Tables of groundwater analytical results are presented in Appendix L (Tables 4 and 5) and copies of certified laboratory reports are included in Appendix G

              7331 Chlorinated hydrocarbon compounds

              A table of CHC results is included in Appendix L (Table 4) and a plan showing their distribution in groundwater beneath the Thebarton EPA Assessment Area is included as Figure 5 Detectable CHC concentrations are summarised in Table 74 relative to the adopted potable and primary contact recreation criteria ndash the closest soil vapour bore locations are also detailed

              PAGE 36 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Table 74 Detectable groundwater CHC results

              Sample ID

              Location CHC concentration (microgL) Closest soil vapour bore

              TCE PCE cis-12shyDCE

              trans-12-DCE

              11-DCE VC Carbon tetrachloride

              MW02 Admella Street 20000 38 7 15 SV5

              MW3 Admella Street 69 SV1

              MW5 Maria Street 29000 3 21 2 6 SV2 SV3

              MW6 Maria Street 29 SV4

              MW9 Albert Street 2 -

              MW11 George Street 4900 3 4 1 7 SV6 SV7

              MW12 George Street 700 SV8

              MW14 Admella Street 1000 4 2 SV9

              MW15 Albert Street 180 SV10

              MW17 Chapel Street 24 -

              MW18 Dew Street 5 -

              MW20 Light Terrace 70 SV12

              MW21 Light Terrace 23 SV13

              MW23 Dew Street 21 -

              MW25 Smith Street 2 5 -

              MW26 Kintore Street 2 -

              Potable 20 50 60 30 03 3

              Primary contact recreation

              30 500 600 300 30 30

              Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Chloroform was also detected in a number of wells (MW02 MW3 MW5 MW8 MW11 MW12 and MW19 to MW25) ndash refer to Table 4 in Appendix L Although no VC was detected the laboratory LOR (1 microgL) exceeded the adopted potable criterion NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from WHO (2017) Guidelines for Drinking-water Quality NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

              The results indicate that the highest TCE concentrations (20000 to 29000 microgL) were measured in wells MW02 and MW5 located in the immediate vicinity of the former Austral property and that the TCE plume extends in a general north-westerly direction (ie consistent with the inferred groundwater flow direction

              80607-1 REV1 30102017 PAGE 37

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              within the Q1 aquifer) Although lesser concentrations of PCE 12-DCE (cis- andor trans) andor 11-DCE were present in some wells no VC was detected and the main COPC was identified as TCE

              A number of wells within the Thebarton EPA Assessment Area contained TCE concentrations that exceeded the adopted potable andor primary contact recreation criteria Although the extent of the TCE plume was not delineated to the north-west (but was delineated in all other directions) with detectable TCE concentrations (ie up to 21 microgL) identified beneath both Smith Street and Dew Street these concentrations were below the adopted primary contact recreation criterion (but not necessarily the adopted potable value ndash ie MW23)

              The background well (MW4) located across James Congdon Drive (to the east of the southern portion of the Thebarton EPA Assessment Area) did not contain any measurable CHC concentrations

              7332 Other measured groundwater parameters

              Major cations and anions

              The laboratory results obtained for the remaining groundwater analytes are summarised in Appendix L (Table 5)

              The groundwater ionic data obtained from selected wells across the Thebarton EPA Assessment Area are graphically represented on a Piper diagram in Figure 71 The results indicate a relatively consistent groundwater composition across the area thereby indicating that the groundwater sampled from these wells is derived from a single aquifer Ionic charge balance ranged from 32 to 22 with the highest value (22) calculated for MW12 indicating that additional anions (ie not measured as part of this study) could be present

              PAGE 38 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Figure 71 Piper diagram

              Natural attenuation parameters

              With respect to the measured natural attenuation parameters (ie DO nitrate iron sulfate CO2 and manganese) the following wells were selected based on their locations relative to the inferred extent of the CHC plume

              MW26 located on Kintore Street to the south (and hydraulically up-gradient) of the former Austral property (ie the suspected source site)

              MW02 and MW5 located within the immediate vicinity of the former Austral property and the area of maximum CHC contamination

              MW9 MW12 and MW17 located on Albert Street George Street and Chapel Street respectively to the north-west (and hydraulically down-gradient) of the former Austral property

              80607-1 REV1 30102017 PAGE 39

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              MW21 and MW22 located on Light Terrace and Cawthorne Street respectively to the northshywestnorth-north-west (and further hydraulically down-gradient) of the former Austral property and

              MW8 and MW23 located on Smith Street and Dew Street respectively representing the furthest wells to the northnorth-west of the former Austral property

              According to Wiedemeier et al (1998) the most important process in the degradation of CHC is the process of reductive dechlorination Although daughter products of TCE (ie 12-DCE) are present in groundwater (and soil vapour) at scattered locations within the Thebarton EPA Assessment Area they are not considered indicative of substantial breakdown of TCE ndash refer also to the Arcadis report in Appendix O as summarised in Section 8 In addition the analysis of the natural attenuation parameters data constituting physical and chemical indicators of biodegradation processes has not provided a definitive secondary line of evidence

              74 Soil vapour bores A table of soil vapour bore analytical results is presented in Appendix L (Table 6) and a copy of the certified laboratory report is included in Appendix G

              Of the soil vapour bores installed to 10 andor 30 m BGL within the Thebarton EPA Assessment Area the majority (ie with the exception of the 10 m deep bores installed as SV11 and SV13 and located on Light Terrace) returned measurable concentrations of CHC dominated by TCE and to a lesser extent (and only at some locations) PCE Detectable soil vapour CHC concentrations are summarised in Table 75 whereas CHC concentrations and inferred soil vapour TCE concentration contours are detailed on Figures 6 (1 m BGL) and 7 (3 m BGL)

              The TCE results which have been used to predict indoor air concentrations as part of the VIRA (refer to Section 9) suggest the following

              the highest concentration (1000000 microgL) was detected at 3 m BGL in soil vapour bore SV3 located in the vicinity of residential and commercialindustrial properties (including the former Austral property) on Maria Street

              where nested wells were tested soil vapour CHC concentrations were higher at depth consistent with a groundwater source

              TCE PCE and 11-DCE are all assumed to represent primary contaminants with 12-DCE representing a break-down product of TCE andor PCE

              although no VC was detected the laboratory LOR in some samples (ie up to 490 microgm3 in samples with the highest measured TCE concentrations) was above the ASC NEPM (1999) interim soil vapour HIL for residential land use (30 microgm3) ndash refer to Table 53 and

              although the extent of the soil vapour plume has apparently not been delineated (ie in any direction) by the existing soil vapour bores it extends in a north-westerly direction (and hydraulically down-

              PAGE 40 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              gradient) from the suspected source site (ie the former Austral property) and corresponds well with the groundwater TCE plume (refer to Figure 5)

              A comparison of the results obtained for the WMStrade units (WMS 38 to WMS 41) deployed during the second round of sampling and the closest soil vapour bore data (10 m BGL) is provided in Table 76 Although the results indicate good correlation for TCE and PCE in SV5WMS 40 as well as TCE in SV7WMS 41 the remaining results were more variable ndash this supports the use of the WMStrade units as an initial (semishyquantitative) screening tool with follow-up soil vapour bore data considered to provide more quantitative results

              Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area

              Bore ID

              Depth (m)

              Location Closest land

              uses

              CHC concentration (microgm3)

              TCE PCE cis-12shyDCE

              trans-12-DCE

              11-DCE VC

              SV1 10 Admella Street CI and R 6300 78

              30 21000 21

              SV2 10 Maria Street CI and R 51000 39 21 39

              30 940000

              SV3 10 Maria Street CI and R 210000 6500 5900

              30 1000000 15000 14000

              SV4 10 Maria Street CI and R 17000 31

              30 43000 90 30

              SV5 10 Admella Street CI 100000 84

              30 160000 310 20 33

              SV6 10 George Street CI 22000 12

              30 150000 56

              SV7 10 George Street CI 22000 19

              30 110000

              SV8 10 George Street CI 2300 62

              30 14000 19

              SV9 10 Chapel Street CI 170

              30 260

              SV10 10 Albert Street CI 93

              30 51

              SV12 10 Light Terrace CI 16

              30 55 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

              Notes Shaded cells indicate concentrations were below the laboratory LOR

              80607-1 REV1 30102017 PAGE 41

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Where (field andor laboratory) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform was also detected in a number of samplesinterim soil vapour health investigation level (HIL)

              Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores

              Bore ID

              Depth (m)

              Location CHC concentration (microgm3)

              TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

              SV2 10 Maria Street 51000 39 21 lt13 39 lt89

              WMS 38 13000 56 lt11 lt11 lt25 lt41

              Relative percentage difference 119 150 - - - -

              SV4 10 Maria Street 17000 31 lt18 lt14 lt14 lt92

              WMS 39 1300 lt52 lt11 lt11 lt25 lt41

              Relative percentage difference 172 - - - - -

              SV5 10 Admella Street 100000 84 lt44 lt33 lt33 lt22

              WMS 40 110000 97 lt11 lt11 lt25 lt41

              Relative percentage difference 95 14 - - - -

              SV7 10 George Street 22000 19 lt37 lt27 lt27 lt18

              WMS 41 18000 10 lt11 lt11 lt25 lt41

              Relative percentage difference 20 62 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

              PAGE 42 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              8 GROUNDWATER FATE AND TRANSPORT MODELLING

              Arcadis were commissioned by Fyfe to undertake preliminary fate and transport modelling of the groundwater CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained groundwater data The Arcadis report is included as Appendix O

              The aim of the modelling was to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton area in order that potential future groundwater restrictions could be applied by the EPA (ie via the potential future definition of a GPA) to protect human health

              81 Groundwater flow modelling

              The MODFLOW code a publicly-available groundwater flow simulation program developed by the United States Geological Survey (USGS) as described by McDonald and Harbaugh (1988) was used to construct a groundwater flow model It was developed for a horizontal area of approximately 25 km2 (ie to minimise possible boundary effects within the assessment area itself12) and was rotated 45deg counter-clockwise to align with the prevailing (north-westerly) groundwater flow direction The model extended approximately 23 km in a south-east to north-west direction and approximately 11 km in a south-west to north-east direction (ie perpendicular to groundwater flow) Whereas a 4 m grid spacing was used within the area of the plume and its migration pathway (ie to enhance model accuracy and precision) a broader 15 m grid was adopted outside the specific area of interest Vertically the model adopted a single 20 m thick layer as representative of the hydrostratigraphy of the Q1 aquifer sediments beneath the area but it was noted that only the bottom portion (ie few metres) of this model layer are actually saturated and therefore active in the model

              An informal sensitivity analysis performed as part of the model calibration process indicated that the model was most sensitive to changes in hydraulic conductivity and recharge ndash this was not unexpected given the relatively flat hydraulic gradient and relatively narrow range of estimated values for both model parameters (ie based on reasonably low uncertainty) The final calibrated value for aquifer recharge adopted in the model was 295 mmyear consistent with results reported for nearby sites as well as regional estimates Likewise the final calibrated hydraulic conductivity values for the up-gradient (06 mday) and down-gradient (2 mday) zones were consistent with both the site-specific slug test data and results obtained for other nearby EPA assessment areas The final calibrated down-gradient constant head elevation was 15 m AHD It was concluded by Arcadis that the groundwater flow model was well calibrated and could therefore serve as an appropriate basis for the development of a site-specific solute transport model

              82 Solute transport modelling

              A site-specific (three-dimensional) solute transport model using the MT3DMS transport code of Zheng (1990) was developed by Arcadis to predict the fate and transport of groundwater contaminants (specifically

              12 Further information regarding boundary effects is provided in the Arcadis report (Appendix O)

              80607-1 REV1 30102017 PAGE 43

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              CHC) under current conditions over a period of 100 years This dual-domain mass transport model was used in conjunction with the groundwater flow model developed through the use of MODFLOW (as detailed above) assuming the following

              The primary COPC is TCE ndash the initial concentration distribution of TCE in groundwater was based on the recent (July 2017) monitoring data

              The age of the groundwater TCE plume was assumed to be up to about 90 years ndash ie based on the history of industrial land use (specifically the former Austral facility) in the area

              Although lesser amounts of other CHC are present in groundwater the lack of significant daughter products of TCE has been interpreted to indicate that substantial biodegradation is not occurring (ie as a conservative approach)

              Although a CHC source was not explicitly incorporated into the solute transport model the MT3DMS transport code indirectly accounts for on-going contaminant mass contribution to the dissolved-phase plume

              The fate and transport of TCE within the area of interest involves the processes of advection adsorption dilution and diffusion ndash however given that recharge via the infiltration of precipitation was considered to be insignificant dilution effects were assumed to be minimal

              Two porosity values (ie dual domain) are relevant to the movement of contaminants in the subshysurface with adopted values based on site-specific geology and Payne et al (2008) ndash whereby the two domains are in equilibrium

              ― mobile porosity that portion of the formation with the highest permeability where advective transport dominates ndash assumed to be 5 (high) 10 (intermediate) or 15 (low) for different mobility transport conditions and

              ― immobile porosity lower permeability portions of the formation where diffusion is dominant ndash assumed to be 15

              As discussed in Section 732 hydraulic conductivity values of 06 mday (south-eastern approximate quarter of the modelling area) and 2 mday (northern approximate three-quarters of the modelling area) were adopted to reflect the hydrogeologic transition (ie from the south-east to the north-west) interpreted from the slug test data

              The adopted TCE retardation factor of 147 for intermediate mobility transport conditions was based on the following

              ― an assumed organic carbon fraction of 01 (US EPA 1996 amp 2009) ndash this was varied to 005 and 2 to assess alternate (ie high versus low) mobility transport conditions

              ― an assumed organic carbon adsorption co-efficient of 61 Lkg (US EPA 2017a)

              PAGE 44 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              ― a calculated partition co-efficient of 0061 Lkg ndash this was varied to 129 and 178 Lkg to assess alternate (ie high versus low) mobility transport conditions and

              ― an average soil bulk density of 192 gcm3 (based on measured geochemical data ndash refer to Table 1 Appendix L)

              An optimum mass transfer co-efficient (MTC) was based on simulated flux distribution in the groundwater flow model whereby

              ― the calculated MTC in the model ranged from approximately 38E-08day-1 to 37E-05 day-1 and

              ― the average MTC was 185E-05day-1

              The site-specific solute transport model was used in predictive mode to assess the long-term (eg 100 year) potential migration of the groundwater TCE plume and to support the EPA in the potential future definition of an appropriate GPA The model was calibrated against the current extent (ie concentrations of TCE above 1 microgL have migrated approximately 500 m from the suspected source site13) and expected age (ie up to about 90 years) of the plume The results indicate that the leading edge of the TCE (ie the 1 microgL contour) is estimated to migrate between approximately 400 and 620 m over a period of 100 years under low to high mobility transport conditions14 with intermediate transport conditions resulting in an estimated migration of 500 m By comparison no significant lateral plume expansion would be expected to occur Figures 5 to 17 of the Arcadis report (Appendix O) show the predicted extent of the TCE plume at 5 10 50 and 100 years under low to high mobility transport conditions

              Figure 81 shows the predicted extent of the 1 microgL TCE boundary in 100 years under intermediate transport conditions ndash it is recommended that this information be used to support the EPA in establishing a potential future GPA

              The Arcadis report notes that given the available site information (site history potential source area(s) and uncertainty associated with the current plume extent) and degree of model calibration (flow model parameter values are consistent with site-specific data as well as regionalnearby studies while transport parameter values are consistent with literatureindustry standards) the model-predicted migration of approximately 500 m over 100 years is considered to be a reasonable representation of future conditions

              Key uncertainties associated with the modelling were identified as including the following

              current plume extents (ie down-gradient delineation)

              site-specific fraction organic values (or site-specific partition coefficient estimates) and

              site-specific porosity estimates

              13 although it was noted that there is uncertainty with respect to the current extent of the TCE plume since all three down-gradient monitoring wells (MW18 MW23 and MW25) have TCE concentrations above 1 μgL

              14 ie assuming different values for mobileimmobile porosity the TCE distribution (sorption) coefficient and the TCE retardation factor

              80607-1 REV1 30102017 PAGE 45

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Lesser uncertainties were considered to include site-specific bulk hydraulic conductivity estimates and determination of the presence or absence of naturally-occurring TCE degradation

              Additional site investigation and data collection (eg multi-well pumping tests for bulk hydraulic conductivity estimates site-specific fraction organic carbon andor distribution (sorption) coefficient additional down-gradient plume delineation) would help to further refine the model and increase confidence in the predictive results

              Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green) relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple)

              PAGE 46 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              9 VAPOUR INTRUSION RISK ASSESSMENT

              Arcadis were commissioned by Fyfe to undertake a Vapour Intrusion Risk Assessment (VIRA) of the soil vapour CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained (ie August 2017) permanent soil vapour bore data The Arcadis report is included as Appendix P

              91 Objective

              The main objective of the VIRA was to evaluate the potential risk to human health from vapour intrusion related to the concentrations of CHC identified in soil vapour within the Thebarton EPA Assessment Area

              92 Areas of interest

              The following areas of specific interest (ie located within the Thebarton EPA Assessment Area) were identified for the purpose of this VIRA

              commercialindustrial properties (assumed slab on grade construction) including the former Austral property (ie the suspected source site) and

              residential properties (slab on grade crawl space and basement constructions)

              Potential exposure by trenchmaintenanceutility workers has also been considered (qualitatively)

              93 Risk assessment approach

              The VIRA was conducted in accordance with the ASC NEPM (1999) enHealth (2012a) and other relevant Australian guidance documents as well as guidance documents issued by the US EPA and other international regulatory agencies (where applicable)

              The conduct of the risk assessment was based on a multiple lines of evidence approach using the available site-specific information collected as part of the scope of works detailed in Section 32

              The following information was used as a basis for the VIRA

              CHC including TCE PCE and DCE (11- cis-12- and trans-12-) have been identified within soil vapour andor groundwater within the Thebarton EPA Assessment Area ndash the analytical data indicate that TCE constitutes between about 95 and 100 of the CHC identified in groundwater and soil vapour

              TCE has been considered as the risk driver for the VIRA (ie based on its toxicity and concentrations in soil vapour and groundwater) ndash although TCE PCE 12-DCE 11-DCE and VC have all been included as COPC for the Tier 1 screening assessment (Section 94) the Tier 2 assessment (Section 95) has

              80607-1 REV1 30102017 PAGE 47

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              concentrated on TCE PCE and 11-DCE (ie due to their presence at concentrations that exceeded the adopted Tier 1 screening criteria)

              The CHC identified within the Thebarton EPA Assessment Area are volatile chemicals and could potentially pose a risk to human health via the vapour intrusion pathway Although the source area has yet to be confirmed the CHC concentrations observed in groundwater and soil vapour are considered likely to have originated from the former Austral property (as discussed in Section 12)

              The natural soils underlying the fill material (where present) in the Thebarton EPA Assessment Area are typified by the Quaternary age soils and sediments of the Adelaide Plains with the Pooraka Formation and Hindmarsh Clay units considered to dominate the upper soil profile

              The soil geotechnical data and soil vapour results collected by Fyfe (as discussed in Sections 712 and 74 respectively) have been used for the VIRA

              A two-tier approach was adopted for the VIRA The first tier (herein referred to as the Tier 1 assessment) was conducted by comparing the measured soil vapour TCE concentrations to published guideline values adjusted (conservatively) to account for attenuation from sub-slab soil into indoor air The second tier (herein referred to as the Tier 2 assessment) involved the comparison of predicted indoor air TCE concentrations to adopted indoor air criteria or response levels

              94 Tier 1 assessment

              As detailed in Section 74 the initial Tier 1 (screening risk) assessment involved comparing measured soil vapour COPC concentrations with the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land uses (refer to Table 74) Given that the development of the interim soil vapour HILs was based on very conservative assumptions the initial Tier 1 assessment provided only a first-pass screening assessment of the data to determine if further risk assessment would be required

              The interim soil vapour HILs are applicable for the assessment of soil vapour at 0 to 1 m beneath the floor of a building They were based on adopted toxicity reference values (TRV) and relevant exposure parameters (ie adjusted for different land uses) as well as an assumed soil vapour to indoor air attenuation factor of 01

              The soil vapour to indoor air attenuation factor (01) was based on the US EPA (2002) recommended default attenuation factors for the generic screening step of a tiered vapour intrusion assessment process As discussed in the US EPA (2002) document the default attenuation factor of 01 for sub-slab soil vapour was based on a US EPA database of empirical attenuation factors calculated using measurements of indoor air and soil vapours from different sites In 2012 the US EPA provided an updated database which was accompanied by an evaluation and statistical analysis of attenuation factors for volatile CHC in residential buildings US EPA (2012) found the sub-slab to indoor air attenuation factor of 003 to be the 95th percentile In 2015 the revised sub-slab attenuation factor (003) was adopted by the US EPA

              PAGE 48 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              The revised sub-slab to indoor air attenuation factor of 003 was adopted to derive modified residential and commercialindustrial soil vapour HILs for the Tier 1 assessment The modified residential soil vapour HILs are presented in Table 91 relative to the maximum CHC concentrations obtained for soil vapour within the Thebarton EPA Assessment Area

              The Tier 1 assessment based on a comparison of the COPC concentrations measured in soil vapour at various locations within the Thebarton EPA Assessment Area with the modified residential soil vapour HILs detailed in Table 91 indicated the following

              TCE concentrations exceeded the adopted criterion in SV1 to SV9 whereas

              the concentrations of PCE and 11-DCE exceeded the adopted criteria in SV3 only

              These locations were identified as requiring further assessment (ie Tier 2 VIRA ndash refer to Section 95)15

              Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs

              Compound ASC NEPM (1999) HIL

              (microgm3)

              Modified Tier 1 HIL (microgm3)

              (AF = 003)

              Maximum measured soil vapour concentration (microgm3)

              Acceptable

              Location 1 m BGL Location 3 m BGL

              11-DCE 7000 SV3 5900 SV3 14000 No ndash Tier 2 required

              cis-12-DCE 80 265 SV2 21 SV4 30 Yes

              trans-12-DCE 80 265 - ND SV5 20 Yes

              PCE 2000 6650 SV3 6500 SV3 15000 No ndash Tier 2 required

              TCE 20 65 SV3 210000 SV3 100000 0

              No ndash Tier 2 required

              VC 30 100 - ND - ND Yes Notes Values in bold exceed the modified residential soil vapour HILs cis-12-DCE HIL adopted as surrogate screening criterion based on US EPA (2017b) regional screening level for residential air elevated laboratory LOR (ie above modified Tier 1 HIL) also reported Abbreviations AF = attenuation factor HIL = health investigation level ND = non detect

              95 Tier 2 assessment

              951 Tier 2 assessment criteria

              The Tier 2 VIRA criteria for the residential zone comprise HIL-based residential indoor air criteria for the COPC (refer to Section 94) along with the residential indoor air level response ranges for TCE that were

              15 Note that all locations were subjected to the Tier 2 VIRA in this assessment

              80607-1 REV1 30102017 PAGE 49

              EPA REF 0524111 FINAL REPORT

              STAGE 1 ENVIRONMENTAL ASSESSMENT

              THEBARTON ASSESSMENT AREA

              initially developed by the EPA and SA Health for the EPA Assessment Area at Clovelly Park and Mitchell

              Park These screening criteria and indoor air response ranges as detailed in SA EPA (2014) and

              reproduced in Figure 91 are now widely adopted in South Australia for the assessment of TCE relating

              to indoor air exposure

              Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels

              Note The no action response level is applicable where a soil vapour concentration is below the laboratory LOR (ie ND or ldquonon-

              detectrdquo assumed to be lt01 microgm3)

              PAGE 50 80607-1 REV1 | 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              952 Vapour intrusion modelling

              For this VIRA exposure point concentrations (EPCs) of COPC in the indoor air of buildings with a slab on grade crawl space or basement construction were estimated using conservative screening assumptions and the Johnson and Ettinger (1991) vapour transport and mixing model (ie the JampE model)

              The algorithms applied in the JampE (1991) model are detailed in Appendix A of the Arcadis report whereas the modelling spreadsheets for each scenario are provided in Appendix B ndash the Arcadis report is attached to this report as Appendix P

              9521 Input parameters

              The input parameters adopted for the vapour intrusion modelling relate to the following

              the construction type and details of existing or proposed buildings ndash refer to Table 92 for adopted building input parameters

              the nature of the soil profile ndash refer to Table 93 for adopted soil input parameters (0 to 1 m BGL) and

              the contaminant source concentrations ndash refer to Table 6 in Appendix L

              Table 92 Tier 2 vapour intrusion modelling ndash building input parameters

              Parameter Units Adopted value Reference

              Residential Commercial industrial

              Width of Building cm 1000 2000 Friebel and Nadebaum (2011)

              Length of Building cm 1500 2000

              Height of Room cm 240 300

              Height of crawl space cm 30 - Assumption for crawl space

              Attenuation from basement to ground floor air

              - 01 01 Friebel and Nadebaum (2011)

              Air Exchange Rate (AER)

              Indoor per hour 06 083 Friebel and Nadebaum (2011)

              Crawl space per hour 06 - Friebel and Nadebaum (2011)

              Basement per hour 06 - As per residential (indoor)

              Fraction of Cracks in Walls and foundation

              - 0001 0001 Friebel and Nadebaum (2011)

              Qsoil cm 3s 300 277 Calculated from QsoilQbuilding ratio of 0005 (residential) and 0001 (commercial)

              80607-1 REV1 30102017 PAGE 51

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters

              Parameter Units Adopted value Reference

              Depth cm 100 Depth of shallow soil vapour data

              Total porosity - 047 Site specific geotechnical data ndash ie averaged from MW3 and MW11 shallow samples (refer to Table 1 in Appendix L) Air filled porosity - 030

              Water filled porosity - 017 Notes ie representing a conservative approach whereby data for the shallow samples with the highest total porosity and lowest degree of saturation (and therefore the highest air filled porosity) have been adopted

              The site specific attenuation factors calculated within the vapour intrusion models (Appendix B of the Arcadis report) are summarised in Table 94 These are chemical and depth specific values applicable to each building construction scenario These attenuation factors have been applied to the soil vapour data measured across the Thebarton EPA Assessment Area to calculate indoor air concentrations (residential properties only) in proximity to each soil vapour location ndash for commercialindustrial properties (slab on grade) indoor air concentrations have only been calculated with respect to the soil vapour data obtained for SV3 (ie the soil vapour bore with the highest measured TCE concentrations)

              Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air

              Scenario Attenuation factor

              Residential ndash slab on grade 706 x 10-4

              Residential ndash crawl space 209 x 10-3

              Residential ndash basement 113 x 10-1

              Commercial ndash slab on grade 408 x 10-4

              Notes ie soil vapour intrusion to indoor air of residential living spaces refer to Section 953 for a discussion of potential vapour intrusion risks associated with commercialindustrial properties

              The chemical parameters of the COPC adopted in the JampE model were updated with data from the chemical database in the Risk Assessment Information System (RAIS 2016) as detailed in Table 95

              Table 95 Summary of chemical parameters adopted for vapour intrusion modelling

              Chemical Diffusivity in Air Diffusivity in Water Solubility Henryrsquos Law Molecular weight (Dair) Water (Dwater) (S) Constant 25oC (gmol)

              (cm2s) (cm2s) (mgL) (unitless)

              11-DCE 00863 0000011 2420 107 969

              PCE 00505 000000946 206 0724 166

              TCE 00687 00000102 1280 0403 131

              PAGE 52 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              9522 Predicted indoor air concentrations

              Residential The predicted indoor air concentrations for each soil vapour data point as calculated by Arcadis for the three residential building scenarios (ie slab on grade crawl space and basement) are presented in Appendix C of the Arcadis report (included in this report as Appendix P)

              Table 96 provides a comparison of predicted indoor air concentrations against the EPA response levels detailed in Section 951 (Figure 91) ndash ie using the 1 m soil vapour data space for slab on grade and crawl space scenarios versus the 3 m soil vapour data for basements

              It should be noted that if residential properties within the Thebarton EPA Assessment Area have basements however the vapour intrusion risks will increase whereas slab on grade construction will carry a lesser vapour intrusion risk (as detailed in Table 96)

              Commercialindustrial The predicted indoor air concentrations as calculated by Arcadis for a commercialindustrial (ie slab on grade) land use scenario with respect to the soil vapour data obtained for SV3 (ie maximum measured soil vapour concentrations) are as follows

              11-DCE 3 microgm3

              PCE 19 microgm3 and

              TCE 86 microgm3

              As these values are not directly comparable to the EPA response levels developed for residential land use further discussion of potential vapour intrusion risks to human health under a commercialindustrial land use

              scenario is included in Section 953

              As discussed for residential properties the vapour intrusion risks may increase if basements are present

              80607-1 REV1 30102017 PAGE 53

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Table 96 Comparison of predicted residential indoor air concentrations with SA EPA response levels

              Indoor Air Concentration Ranges (microgmsup3) SA EPA response levels

              non-detect No action

              gt non-detect to lt2 Validation

              2 to lt20 Investigation

              20 to lt200 Intervention

              ge200 Accelerated Intervention

              Soil vapour bore

              Sample depth

              (m)

              Soil vapour TCE concentration

              (microgmsup3)

              Predicted indoor air concentration (microgmsup3)

              Residential scenario

              Slab on grade Crawl space Basement

              Attenuation factor

              7 x 10-4 2 x 10-3 1 x 10-1

              SV1 10 5700 4 11

              SV1 30 21000 2100

              SV2 10 51000 36 102

              SV2 30 890000 89000

              SV2 (FD) 30 940000 94000

              SV3 10 210000 147 420

              SV3 30 1000000 100000

              SV4 10 17000 12 34

              SV4 30 43000 4300

              SV5 10 100000 70 200

              SV5 30 160000 16000

              SV6 10 22000 15 44

              SV6 (FD) 10 22000 15 44

              SV6 30 150000 15000

              SV6 (FD) 30 140000 14000

              SV7 10 22000 15 44

              SV7 30 110000 11000

              SV8 10 2300 2 5

              SV8 30 14000 1400

              SV9 10 170 012 030

              SV9 30 260 26

              SV10 10 9 0007 0019

              SV10 30 51 51

              SV11 10 lt18 - -

              SV12 10 16 0011 0032

              SV12 30 55 55

              SV13 10 lt21 - -

              PAGE 54 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Notes With respect to the predicted indoor air CHC concentrations in the Arcadis VIRA report (refer to Appendix P) the results in Table 5 were calculated for SV3 using the unrounded attenuation factors presented in Appendix B (and Table 94 of this report) whereas the TCE indoor air concentrations in Appendix C (as summarised in Table 96) were calculated using rounded attenuation factors ndash this does not change the overall interpretation of the results Abbreviations FD = field duplicate

              9523 Sensitivity analysis

              Table 97 presents a qualitative sensitivity analysis for some of the input variables used in the modelling ndash it includes the range of practical values for each variable the value used in the risk assessment the relative model sensitivity and the uncertainty associated with the variable

              Although Arcadis note that a number of parameters used within the risk assessment have a moderate degree of uncertainty associated with them thereby suggesting that the modelling may be sensitive to changes in these parameters values used to define these parameters were selected to be conservative This is considered to have resulted in an assessment which is expected to be conservative and to over-estimate actual risk

              Table 97 Summary of model input parameters subjected to sensitivity analysis

              Input Range of values Value adopted Sensitivity of calculated input parameters variable

              Soil physical parameters

              Total porosity

              Varies by soil type generally 03 to 05

              047 Site-specific

              Indoor air concentrations will decrease with increasing total porosity Moderate sensitivity parameter decreasing by 50 will increase predicted concentration by a factor of 4

              Air filled porosity

              Varies by soil type generally 015 to 03

              03 Site-specific

              Indoor air concentrations will increase with increasing air filled porosity Moderate to high sensitivity parameter reduction by 50 decreases concentration by a factor of 10

              Water filled porosity

              Varies by soil type from 005 (fill or

              sand) to 03 (clay)

              017 Site-specific

              Negligible impact on predicted indoor air concentrations although may decrease with increasing moisture content Very low sensitivity parameter

              Building parameters

              Air exchange rate (AER)

              Varies from 05 hr-1

              in smaller buildings to gt2 hr-1

              06 hr-1 for residential structures

              083 hr-1 for commercial

              Indoor air concentrations will decrease with increasing air exchange Moderate sensitivity parameter has linear relationship with predicted concentrations conservative assumptions used

              80607-1 REV1 30102017 PAGE 55

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Input Range of values Value adopted Sensitivity of calculated input parameters variable

              Advective flow rates

              Varies depending on building size and

              AER

              300 cm3sec Calculated from building AER and

              ratio of 0005

              Indoor air concentrations will increase with increasing advective flow Low sensitivity parameter particularly within normal range of potential values The assumption that advective flow is occurring into a building at all times is generally conservative for Australian settings Advection is unlikely to occur under a crawl space home and diffusive transport is the dominant transport mechanism

              Building size Variable Variable consistent with

              Friebel and Nadebaum (2011)

              Indoor air concentrations decrease with increasing building volume

              Very low sensitivity parameter

              9524 Uncertainties

              The following uncertainties were identified in the Arcadis report (Appendix P)

              Vapour transport modelling

              The use of a model to predict the migration of vapour from a sub-surface source to indoor air requires the simplification of many complex processes in the sub-surface as well as the potential for entry and dispersion within a building or outdoor air To address this simplification the vapour models available (and adopted in this assessment) are considered to be conservative such that uncertainties are addressed through the overshyestimation of likely concentrations

              It should be noted that the vapour model used is designed to be a first tier screening tool and is considered likely to over-estimate air concentrations due to the incorporation of a number of conservative assumptions including the following

              chemical concentrations in soil vapour were assumed to remain constant over the duration of exposure (ie it was assumed that the source was non-depleting and not subject to natural biodegradation processes)

              the maximum reported soil vapour concentrations were assumed to be present beneath nearby dwellings and

              the occurrence of steady well-mixed vapour dispersion within the enclosed or ambient mixing space

              Overall the vapour modelling undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

              PAGE 56 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Toxicological Data

              In general the available scientific information involves the extrapolation of toxicity information from studies involving experimental laboratory animals with some validation of observable health effects obtained through epidemiological studies

              This may introduce two types of uncertainties into the risk assessment as follows

              those related to extrapolating from one species to another and

              those related to extrapolating from the high exposure doses usually used in experimental animal studies to the lower doses usually estimated for human exposure situations

              In order to adjust for these uncertainties toxicity values commonly incorporate safety factors that may vary from 10 to 10000

              Overall the toxicological data presented in this assessment are considered to be current and adequate for the assessment of risks to human health associated with potential exposure to the COPC identified The uncertainties inherent in the toxicological values adopted are considered likely to result in an over-estimation of actual risk

              953 Potential vapour intrusion risks associated with commercialindustrial properties

              An assessment of potential vapour intrusion risks to workers at commercialindustrial properties (slab on grade construction) within the Thebarton EPA Assessment Area was undertaken by Arcadis using the methodology published by US EPA (2009) and incorporated into the ASC NEPM (1999) This approach recommends adjustment of the measured or estimated contaminant concentrations in air to account for site specific exposures by the relevant receptors as follows

              Ca ET EF EDECinh = days hours AT 365 24 year day

              Where

              ECinh = Exposure Adjusted Air Concentration (mgm3) Ca = Chemical Concentration in Air (mgm3) ET = Exposure Time (hoursday) EF = Exposure Frequency (daysyear) ED = Exposure Duration (years) AT = Averaging Time (years)

              = 70 years for non-threshold carcinogens = ED for chemicals assessed based on threshold effects

              80607-1 REV1 30102017 PAGE 57

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Exposure parameters were selected from Australian sources (enHealth 2012b ASC NEPM 1999) for the receptor groups evaluated or were based on site specific factors Table 98 presents an overview of the parameters used whereas adopted inhalation TRVs are presented in Table 99

              Risk was characterised for threshold and non-threshold effects for the COPC ndash spreadsheets presenting the risk calculations are provided in Appendix B of the Arcadis report (as included in Appendix P) For commercialindustrial properties the non-threshold risk level was calculated to be 3 x 10-5 (compared to a target risk level of 1 x 10-5) whereas the threshold risk level was calculated to be 10 (compared to a target risk level of 1) ndash these results indicated a potentially unacceptable vapour intrusion risk to commercialindustrial workers in the vicinity of the maximum soil vapour CHC concentrations (ie at SV3 ndash worst-case scenario based on maximum soil vapour concentrations)

              Table 98 Exposure parameters ndash Commercialindustrial workers

              Exposure parameter Units Value Reference

              Exposure frequency days year 365 ASC NEPM (1999)

              Exposure duration years 30 ASC NEPM (1999)

              Exposure time indoors hoursday 8 ASC NEPM (1999)

              Averaging time

              Non-threshold

              threshold

              Years

              years

              70

              30 ASC NEPM (1999)

              Table 99 Adopted inhalation toxicity reference values

              COPC Toxicity reference values

              Non-threshold (microgm3)

              Reference Threshold (microgm3)

              Reference

              11-DCE NA - 80 ATSDR (1994)

              PCE NA - 200 WHO (2006)

              TCE 41 US EPA (2011) IRIS 2 US EPA (2011) IRIS Notes Abbreviations NA = not applicable

              954 Potential risks to trenchmaintenanceutility workers

              Although trenchmaintenanceutility workers may be exposed to soil vapour concentrations as measured at 1 m BGL due to the short-term nature of such works their total intakes of TCE and other CHC will be low Assuming that a trenchmaintenanceutility worker may be exposed to TCE for a limited number of working days throughout the year (eg 20 days of 8 hours duration within an excavation) their intake will be approximately one fiftieth of the intake of a resident (who is assumed to be exposed 21 hours a day for 365 days a year)

              PAGE 58 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Therefore the management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air)

              96 Conclusions

              On the basis of the available data and the assessment presented in the Arcadis VIRA report (Appendix P) the following conclusions were provided

              Health risks for residents due to the intrusion of CHC in soil vapour into residential buildings with a slab on grade crawl space or basement construction were calculated to be above the adopted EPA response levels and risks to residents may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

              Health risks for commercial workers due to the intrusion of CHC in soil vapour into buildings with a slab on grade construction were calculated to be above the adopted target risk levels and risks to workers may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

              In the absence of specific information regarding building construction within the Thebarton EPA Assessment Area the predicted indoor air concentrations calculated from the 1 m BGL soil vapour data for a residential crawl space scenario are summarised in Table 910

              Table 910 Summary of properties with predicted indoor air concentrations (residential crawl space) above adopted EPA response levels

              EPA response level No of residential properties affected Indoor air concentration (microgm3) Response

              non-detect to lt2 Validation 9

              2 to lt20 Investigation 10

              20 to lt200 Intervention 8

              ge200 Accelerated intervention 3 Notes According to information provided by the EPA there are approximately 130 residential properties located in the Thebarton EPA Assessment Area calculated on the basis of cadastral boundaries ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial facility ndash these data would therefore need to be confirmed via a property survey

              80607-1 REV1 30102017 PAGE 59

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              10 CONCEPTUAL SITE MODEL

              As detailed in Table 101 a CSM has been developed for the Thebarton EPA Assessment Area on the basis of historical information (as summarised in Section 12 as well as Appendices A and B) and the data obtained during the recent Fyfe investigation program

              Table 101 Summary of existing information for the Thebarton EPA Assessment Area

              Topic Summarised Information

              Site Characterisation

              Identification of Assessment Area

              An approximately 27 ha Assessment Area located within the suburb of Thebarton has been defined by the EPA The boundaries of this area are detailed in Section 21 and illustrated on Figure 1

              History of land use Properties located within the Thebarton EPA Assessment Area have been used for a mixture of commercialindustrial and low density residential land uses over time Current commercialindustrial properties include a beverage factory in the north-eastern portion of the assessment area a refrigeration equipment facility a car dealership two hotels (at least one of which has a cellarbasement) automotive and other workshops and the Ice Arena Former commercialindustrial activities have been identified as including a gas works a mechanicrsquos workshop sheet metal working facilities and a farm machinery manufacturer

              Historical investigations

              Reports provided to Fyfe by the EPA that pertain to previous investigations undertaken within the Thebarton EPA Assessment Area have been reviewed and summarised in Appendix A Additional historical information is included in Appendix B

              Local geology Natural soils encountered from the surfacenear surface to the maximum drill depth of 19 m BGL across the Thebarton EPA Assessment Area were considered to be indicative of the Quaternary Pooraka and Hindmarsh Clay formations Whereas fill materials (ie sand gravelcrushed rock andor silt) were encountered to depths of up to 09 m BGL at a number of sampling locations underlying natural soils comprised mainly low to medium plasticity silty or sandy clays with variable gravel contents Geotechnical testing of subsurface soil samples collected from 10 drill cores indicated that the PSD comprised predominantly claysilt with lesser components of sand andor gravel ndash these soil samples were mostly classified as Clay although some were classified as Sandy Clay or Clayey Sand According to Stapledon (1971) the Hindmarsh Clay unit typically contains many structural features and defects which greatly influence its permeability thereby resulting in potential preferential pathways for the vertical and lateral movement of soil vapour and groundwater Such features were not specifically observed during the recent drilling and soil logging work although some gravel lenseslayers were identified

              Hydrogeology In accordance with Gerges (2006) and his classification of the Adelaide metropolitan area into a number of zones based on their individual hydrogeological characteristics the Thebarton EPA Assessment Area is located within Zone 3 (subzone 3E) to the west of the Para Fault It contains five to six Quaternary aquifers and three or four Tertiary aquifers Based on the most recent investigations the depth to water within the Q1 aquifer in the Thebarton EPA Assessment Area ranges from approximately 123 to 159 m BGL and groundwater flows in a general north-westerly direction with a relatively flat hydraulic gradient (000062 to 00012) Salinity levels (based on field EC readings) range from approximately 1230 to 3620 mgL TDS and a groundwater flow velocity range of approximately 44 to 23 myear has

              80607-1 REV1 30102017 PAGE 61

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Topic Summarised Information

              been inferred As detailed in Section 222 a search of the DEWNR (2017) WaterConnect database identified 59 bores within the general Thebarton area of which 18 are located within the Thebarton EPA Assessment Area Although (where recorded) bores were listed as having been installed primarily for monitoring investigation or observation purpose other purposes (for presumed Quaternary aquifer bores) included drainage domestic and industrial A BUA has identified realistic groundwater uses as potentially including potable residential irrigation and primary contact recreationaesthetics Based on proximity to the River Torrens freshwater ecosystem protection has also been considered ndash however since the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area this may not be a realistic beneficial use Since volatile contaminants have been detected within the Q1 aquifer a potential vapour flux risk to future site users has also been considered

              Hydrology No surface water bodies have been identified within the Thebarton EPA Assessment Area The closest surface water body is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west Current stormwater run-off within the Thebarton EPA Assessment Area is expected to be collected by localised (and engineered) drainage systems

              Fyfe Investigation Results

              Groundwater impacts Contaminants identified in groundwater beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected source site (ie the former Austral sheet metal works) in accordance with the predominant flow direction associated with the Q1 aquifer (refer to Figures 4 and 5) The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) but its north-western extent has not yet been determined (whereas its extent has been defined in all other directions)

              Soil vapour impacts Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction (refer to Figures 6 and 7) and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion The soil vapour samples with the maximum TCE concentrations (ie SV3_10m and SV3_30m) also had the highest PCE and 11-DCE concentrations (or elevated LOR) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-) Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE (ie SV2_30m SV3_10m SV3_30m and SV7_30m) exceeded the adopted HILs for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE

              PAGE 62 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Topic Summarised Information

              degradation has not yet resulted in its production (ie at measureable levels) Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

              Potential Exposure Pathways

              Contaminants of Based on the results of historical investigations the EPA identified a number of CHC as being of Potential Concern concern for the Thebarton EPA Assessment Area The main COPC was identified as TCE with

              additional COPC including PCE 12-DCE (cis- and trans-) VC and 11-DCE Further detail is provided in Section 14 These COPC were confirmed by the Fyfe investigations with TCE identified as both the main contaminant in groundwater and soil vapour and the main driver in terms of potential human health risks associated with vapour intrusion into buildings within the Thebarton EPA Assessment Area (refer to Section 9)

              Suspected source and The suspected source of the identified CHC groundwater (and soil vapour) impacts within the affected media Thebarton EPA Assessment Area is the former Austral sheet metal works located over multiple

              allotments between George and Maria Streets from the 1920s until the 1960s-1970s Previous investigations (Appendix A) had identified groundwater CHC impacts on part of this suspected source site The Fyfe investigations have concentrated on impacts within groundwater and soil vapour across the Thebarton EPA Assessment Area both of which generally correlate with the inferred north-westerly groundwater flow direction and are considered to be related to the previously identified dissolved phase groundwater CHC impacts

              Sensitive receptors The following sensitive receptors have been identified as potentially relevant to the Thebarton EPA Assessment Area Ecological groundwater ecosystems within the assessment area extending to at least Dew and Smith

              Streets (ie as the north-western extent of the groundwater CHC plume has not yet been determined) and

              the freshwater ecosystem of the River Torrens located at a distance of approximately 07 km in a hydraulically down-gradient (ie north-westerly) direction but not necessarily representing a groundwater receiving environment

              Human current and future occupants of and visitors to residential properties current and future workers on the source site and other commercialindustrial properties

              within the area current and future underground trenchmaintenanceutility workers and down-gradient groundwater bore users

              Contaminant Possible contaminant transport mechanisms associated with the CHC-impacted groundwater transport identified within the Q1 aquifer beneath the Thebarton EPA Assessment Area include mechanisms flow through the aquifer to a hydraulically down-gradient surface water body andor down-

              gradient groundwater bores vapour generation andor flow via subsurface preferential pathways (eg service trenches

              more permeable soils) and downward movement into underlying aquifers (eg dense non-aqueous phase liquid

              (DNAPL))

              80607-1 REV1 30102017 PAGE 63

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Topic Summarised Information

              Exposure Possible exposure mechanisms associated with impacted groundwater within the Thebarton mechanisms EPA Assessment Area include

              direct contact (eg during extractionuse of groundwater) incidental ingestion (eg during extractionuse of groundwater) and inhalation of vapours (eg during extractionuse of groundwater andor as a result of

              vapour intrusion into buildings)

              Assessment of Risk

              Groundwater risks The recent groundwater analytical results have indicated that the Q1 aquifer beneath the Thebarton EPA Assessment Area contains measurable concentrations of CHC (mainly TCE but also including PCE 12-DCE andor 11-DCE at some locations) Measured concentrations of TCE exceeded the adopted assessment criteria for potable andor primary contact recreation in wells MW02 MW3 MW5 MW6 MW11 MW12 MW14 MW15 MW17 MW20 MW21 and MW23 located on Admella Maria George Albert and Dew Streets as well as Light Terrace with maximum concentrations corresponding to the ldquocorerdquo area of the plume One well (MW25) contained a concentration of carbon tetrachloride that exceeded the adopted potable criterion Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

              Groundwater fate Although scattered detectable concentrations of 12-DCE have been measured in groundwater and transport across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE modelling daughter products has been interpreted to indicate that substantial dechlorination is not

              occurring Groundwater fate and transport modelling (refer to Section 8 and Appendix O) has predicted that the likely extent of the dissolved phase groundwater TCE plume over the next 100 years will extend by another 500 m beyond the boundaries of the current Thebarton EPA Assessment Area However no significant lateral plume expansion is expected

              Vapour intrusion risks A VIRA (refer to Section 9 and Appendix P) was undertaken to assess potential risks to human health from the intrusion of CHC vapours (primarily TCE) into indoor air from soil vapour The predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction in the absence of specific structural information) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and therefore require further action as follows 10 properties within the investigation range (2 to lt20 microgm3) eight properties within the intervention range (20 to lt200 microgm3) and three properties within accelerated intervention range (ge200 microgm3) All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3

              (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as

              PAGE 64 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Topic Summarised Information

              selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which are expected to be overly-conservative) ndash these results will be documented in a subsequent report Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed Management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air)

              Complete Exposure Pathways

              Identified pathways and areas of potential risk

              Based on the results of the recent Fyfe investigations (including the VIRA) and taking into account available historical information (Appendices A and B) and DEWNR (2017) WaterConnect bore information the following complete exposure pathways and associated risks are considered possible for the Thebarton EPA Assessment Area exposure (direct contact incidental ingestion andor inhalation of vapours) during use of

              groundwater for domestic (eg drinking water plumbing garden irrigation) andor recreational (eg filling of swimming poolsspas) purposes

              vapour intrusion into indoor air within 30 residential propertieslocated within the vicinity of soil vapour bores SV1 to SV9 (assuming crawl space construction) ndash although 19 of these properties are predicted to be in the validationinvestigation action level range 11 are predicted to be in the intervention action level range (with actual indoor air monitoring results for properties within the intervention action level range pending)

              vapour intrusion into residential cellarsbasements (if present) in the vicinity of soil vapour bores SV1 to SV10 and SV12 and

              vapour intrusion into the indoor air of commercialindustrial properties ndash although actual risks to site workers would require further specific considerationassessment

              In addition although only assessed in a qualitative manner to date trenchmaintenanceutility workers may also be at risk where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

              Notes calculated on the basis of cadastral boundaries and assuming crawl space construction ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial premises a property survey would be required to confirm building construction details and the number of individual residences affected

              80607-1 REV1 30102017 PAGE 65

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              11 CONCLUSIONS

              Between May and August 2017 Fyfe undertook an investigation of groundwater and soil vapour CHC impacts within an EPA-designated Assessment Area located in Thebarton South Australia The results of the investigation have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties A CSM has been developed from the field analytical and modelling results as presented in Section 10

              The following conclusions have been reached

              Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were present within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m in groundwater well MW17

              Groundwater within the Q1 aquifer is located at a depth of approximately 123 to 159 m BGL and flows in a general north-westerly direction (refer to Figure 4) ndash the closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred16 and the groundwater gradient beneath the Thebarton EPA Assessment area is relatively flat (ie 000062 to 00012)

              Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified to include domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux as assessed by the VIRA) and possibly also potable Although freshwater ecosystem protection was also considered the River Torrens is thought to comprise either a recharge boundary (ie discharging to local groundwater) or to not actually be hydraulically connected to the Q1 aquifer in this area

              Groundwater beneath parts of the Thebarton EPA Assessment Area contains detectable concentrations of various CHC and includes TCE and carbon tetrachloride (one location only) levels that exceed the adopted assessment criteria for potable use andor primary contact recreation ndash thereby indicating that groundwater would be unsuitable for drinking or the filling of swimming poolsspas In addition vapour flux could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the groundwater could be odorous

              16 ie as calculated by Fyfe based on available data

              80607-1 REV1 30102017 PAGE 67

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              The groundwater and soil vapour CHC impacts identified beneath parts of the Thebarton EPA Assessment Area are considered likely to have emanated from the former Austral sheet metal works located over multiple allotments between George and Maria Streets from the 1920s until the 1960sshy1970s The possible presence of on-going (primary andor secondary) source(s) at this property has not yet been investigated

              As depicted on Figures 6 and 7 the current extent of the soil vapour CHC (ie dominated by TCE) impacts has been determined to correspond to the mapped distribution of the groundwater TCE impacts (Figure 5) and is considered to be directly related to groundwater (rather than soil) CHC impacts Although no soil vapour impacts were detected at 1 m BGL in SV11 and SV1317 located near the eastern and western ends of Light Terrace respectively the north-western extents of the groundwater and soil vapour CHC impacts have not yet been determined In addition although the extent of the groundwater TCE plume has been delineated in all other directions the soil vapour TCE plume has not been delineated in any direction

              TCE is considered to be a primary contaminant as well as the dominant (ie in terms of concentration and extent) CHC in both groundwater and soil vapour ndash the presence of PCE and 11-DCE suggests however that more than one primary contaminant is present Although the detectable concentrations of 12-DCE (cis- and trans) are considered to have resulted from the breakdown of TCEPCE no VC has been detected in either groundwater or soil vapour ndash the scattered distribution and relatively low concentrations of 12-DCE as well as the absence of measurable VC have been interpreted to indicate that significant dechlorination of the primary contaminants has not occurred (despite the likely age of the plume ndash ie possibly up to about 90 years old)

              Although the COPC adopted for the soil vapour assessment program included various CHC (ie with TCE identified as the dominant contaminant in groundwater and soil vapour) the Tier 1 VIRA confirmed that TCE PCE and 11-DCE all exceeded the adopted vapour intrusion HILs Based primarily on its greater toxicity however the risk driver for the Thebarton EPA Assessment Area is considered to be TCE

              The VIRA (Tier 2) results for predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and that require further action as follows

              ― 10 properties within the investigation range (2 to lt20 microgm3)

              ― eight properties within the intervention range (20 to lt200 microgm3) and

              ― three properties within accelerated intervention range (ge200 microgm3)

              All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming

              17 noting that the laboratory LOR for TCE was elevated as compared to the other soil vapour samples

              PAGE 68 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises ndash refer to Table 96

              Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentration obtained for soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

              Although only assessed in a qualitative manner trenchmaintenanceutility workers may be at risk in areas where TCE concentrations at 1 m BGL are greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) ndash in this case appropriate management measures would be required to be adopted This should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

              80607-1 REV1 30102017 PAGE 69

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              12 DATA GAPS

              Based on the results obtained during the recent Fyfe investigations as well as available historical information (Appendices A and B) the following data gaps have been identified for the Thebarton EPA Assessment Area

              property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

              groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

              the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

              the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

              80607-1 REV1 30102017 PAGE 71

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              13 REFERENCES

              ANZECCARMCANZ (2000a) Australian Guidelines for Water Quality Monitoring and Reporting

              ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

              ASTM (2001) Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations ASTM Guide D7663-12

              ASTM (2006) Standard Guide for Soil Gas Monitoring in the Vadose Zone ASTM Guide D5314-92

              ATSDR (1994) Toxicological profile ndash 11-Dichloroethene httpswwwatsdrcdcgovToxProfilestpaspid=722amptid=130

              AustralianNew Zealand Standard (1998) Water Quality Sampling Part 1 Guidance on the Design of Sampling Programs Sampling Techniques and the Preservation and Handling of Samples ASNZS 566711998

              AustralianNew Zealand Standard (1998) Water Quality Sampling Part 11 Guidance on Sampling of Groundwaters ASNZS 5667111998

              Bouwer H and Rice RC (1976) A Slug Test Method for Determining Hydraulic Conductivity of Unconfined Aquifers with Completely or Partially Penetrating Wells Water Resources Research vol 12 no 3 pp 423-428

              Butler JJ Jr (1998) The Design Performance and Analysis of Slug Tests

              Cooper HH Bredehoeft JD and Papadopulos SS (1967) Response of a Finite-Diameter Well to an Instantaneous Charge of Water Water Resources Research vol 3 no 1 pp 263-269

              CRC CARE (2013) Petroleum Hydrocarbon Vapour Intrusion Assessment ndash Australian Guidance CRC CARE Technical Report No 23 July 2013

              Dagan G (1978) A Note on Packer Slug and Recovery Tests in Unconfined Aquifers Water Resources Research vol 14 no 5 pp 929-934

              Department of Environment Water and Natural Resources (DEWNR 2017) Water Connect Master Register of All Bores Primary Industries and Resources South Australia

              Duffield G (2007) AQTESOLVreg Professional Version 45 Hydrosolve Inc

              enHealth (2012a) Environmental Health Risk Assessment - Guidelines for assessing human health risks from environmental hazards enHealth Council

              enHealth (2012b) Australian Exposure Factor Guidance Handbook enHealth Council

              Environment Protection Act 1993

              80607-1 REV1 30102017 PAGE 73

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              Environment Protection Regulations 2009

              Friebel E and Nadebaum P (2011) Health Screening Levels for Petroleum Hydrocarbons in Soil and Groundwater CRC CARE Technical Report No 10

              Gerges NZ (1999) The Geology and Hydrogeology of the Adelaide Metropolitan Area Flinders University (South Australia) PhD thesis (unpublished)

              Gerges NZ (2006) Overview of the Hydrogeology of the Adelaide Metropolitan Area DWLBC Report 200610

              Golder Associates (1994) Contamination Assessment George Street Thebarton SA Report to United Land dated 9 December 1994

              Hvorslev MJ (1951) Time Lag and Soil Permeability in Ground-Water Observations Bulletin no 36 Waterways Exper Sta Corps of Engrs US Army Vicksburg Mississippi pp 1-50

              Hyder Z Butler JJ Jr McElwee CD and Liu W (1994) Slug Tests in Partially Penetrating Wells Water Resources Research vol 30 no 11 pp 2945-2957

              ITRC (2007) Vapor Intrusion Pathway - A Practical Guidance

              Johnson PC and Ettinger RA (1991) Heuristic Model for Predicting the Intrusion Rate of Contaminant Vapors

              into Buildings Environ Sci Technology 251445-1452

              McDonald M G and Harbaugh A W (1988) A Modular Three-Dimensional Finite-Difference Ground-Water Flow Model Techniques of Water-Resources Investigations Book 6 Chapter A1 U S Geological Survey

              NEPM (1999) National Environment Protection (Assessment of Site Contamination) Measure Schedules B1 to

              B9 National Environment Protection Council Australia

              NHMRC (2008) Guidelines for Managing Risks in Recreational Water

              NHMRCNRMMC (2011) Australian Drinking Water Guidelines (as revised in 2016)

              NJDEP (2013) Site Remediation Program Vapor Intrusion Technical Guidance (Version 31)

              NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme (2nd edition)

              Payne FC Quinnan JA and Potter ST (2008) Remediation Hydraulics CRC Press Boca Raton FL

              RAIS (2016) Chemical Specific Parameters for Trichloroethylene Risk Assessment Information System Office of Environmental Management US Department of Energy

              REM (2005a) George St Thebarton Site ndash Stage 2 Investigations Report to Luca Group dated 26 August 2005

              REM (2005b) Stage 3 Environmental Site Assessment George St Thebarton SA Report to Luca Group dated 23 November 2005

              SA Department of Mines and Energy (1969) 1250000 Adelaide Geological Map Sheet Sheet S1 54-9

              PAGE 74 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              SA EPA (2007) Regulatory Monitoring and Testing Groundwater Sampling

              SA EPA (2009) Guidelines for the Assessment and Remediation of Groundwater Contamination

              SA EPA (2014) Clovelly Park Mitchell Park Project Management Team Assessment Program Flip Book November 2014

              SA EPA (2015) Environment Protection (Water Quality) Policy

              Standards Australia (1993) Geotechnical Site Investigations AS1726-1993

              Standards Australia (2005) Guide to the Sampling and Investigation of Potentially Contaminated Soil Part 1 Non-Volatile and Semi-Volatile Compounds AS44821-2005

              Stapledon DH (1971) Changes and Structural Defects Developed in some South Australian Clays and their Engineering Consequences Proceedings of Symposium on Soils and Earth Structures in Arid Climates Adelaide 1970

              US EPA (1996) Soil Screening Guidance Technical Background Document Office of Emergency and Remedial Response Washington DC EPA540R95128

              US EPA (1999) Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air Second Edition Compendium Method TO-15 Determination Of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed By Gas Chromatography Mass Spectrometry (GCMS) EPA625R-96010b

              US EPA (2002) OSWER Draft Guidance for Evaluating the Vapour Intrusion to Indoor Air Pathway from Groundwater and Soils (Subsurface Vapour Intrusion Guidance) EPA530-D-02-004

              US EPA (2009) EPArsquos Risk-Screening Environmental Indicators (RSEI) Methodology Office of Pollution Prevention and Toxics Washington DC

              US EPA (2011) IRIS (Integrated Risk Information System) Trichloroethylene Chemical Assessment Summary httpscfpubepagovnceairisiris_documentsdocumentssubst0199_summarypdf

              US EPA (2012) EPArsquos Vapor Intrusion Database Evaluation and Characterization of Attenuation Factors for Chlorinated Volatile Organic Compounds and Residential Buildings

              US EPA (2015) OSWER Technical Guide for Assessing and Mitigating the Vapour Intrusion Pathway from Subsurface Vapour Sources to Indoor Air

              US EPA (2017a) Regional Screening Levels (RSLs) - Generic Tables (June 2017) httpswwwepagovriskregional-screening-levels-rsls-generic-tables-june-2017

              US EPA (2017b) Regional Screening Levels for Chemical Contaminants at Superfund Sites httpwwwepagovreg3hwmdriskhumanrb-concentration_tableGeneric_Tablesindexhtm

              80607-1 REV1 30102017 PAGE 75

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              WHO (2006) Air Quality Guidelines for Europe Second Edition WHO Regional Publications European Series No 91

              WHO (2017) Guidelines for Drinking-water Quality Fourth edition (incorporating the first addendum)

              Wiedemeier T Swanson M Moutoux D Gordon E Wilson J Wilson B Kampbell D Haas P Miller R Hansen J and Chapelle F (1998) Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water National Risk Management Research Laboratory Office of Research and Development US EPA

              Zheng C (1990) MT3D A Modular Three-Dimensional Transport Model for Simulation of Advection Dispersion and Chemical Reactions of Contaminants in Groundwater Systems Prepared for US EPA by Robert S Kerr Environmental Research Laboratory Ada Oklahoma developed by SS Papadopulos amp Associates Inc Rockville Maryland

              PAGE 76 80607-1 REV1 30102017

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              14 STATEMENT OF LIMITATIONS

              The opinions and conclusions presented in this report are specific to the conditions of the Thebarton EPA Assessment Area and the state of legislation currently enacted as at the date of this report Fyfe does not make any representation or warranty that the opinions and conclusions in this report will be applicable in the future as there may be changes in the condition of the Thebarton EPA Assessment Area applicable legislation or other factors that would affect the opinions and conclusions contained in this report

              Fyfe has used the degree of skill and care ordinarily exercised by reputable members of our profession practising in the same or similar locality This report has been prepared for the South Australian Environment Protection Authority for the specific purpose identified in the report Fyfe accepts no liability or responsibility to any third party for the accuracy of any information contained in the report or any opinion or conclusion expressed in the report Neither the whole of the report nor any part or reference thereto may be in any way used relied upon or reproduced by any third party without Fyfersquos prior written approval This report must be read in its entirety including all tables and attachments

              80607-1 REV1 30102017 PAGE 77

              EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

              FIGURES

              Figure 1 Site Location and Assessment Area

              Figure 2 Assessment Point Locations

              Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan

              Figure 4 Groundwater Elevation Contour Plan

              Figure 5 Groundwater Concentration Plan

              Figure 6 Soil Vapour Concentration Plan (10m)

              Figure 7 Soil Vapour Concentration Plan (30m)

              80607-1 REV1 30102017 PAGE 79

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              DEW

              STREET

              DEW

              STREET

              CHAPEL STREETCHAPEL STREET

              PAR

              KER

              STREET

              PAR

              KER

              STREET

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              LIGHT TERRACELIGHT TERRACE

              DEW

              STREET

              DEW

              STREET

              WA

              LSH ST

              WA

              LSH ST

              AD

              MELLA

              STREET

              AD

              MELLA

              STREET

              ALB

              ERT STR

              EETA

              LBER

              T STREET

              HO

              LLAN

              D ST

              REET

              HO

              LLAN

              D ST

              REET

              RANDOLPH STREET

              RANDOLPH STREET

              JAM

              ES STREET

              JAM

              ES STREET

              DOVE STREET

              DOVE STREET

              SMITH STREETSMITH STREET

              MARIA STREETMARIA STREET

              GEORGE STREETGEORGE STREET

              KINTORE STREET

              KINTORE STREET

              PORT ROAD

              PORT ROAD

              PORT ROAD

              PORT ROAD

              CAW

              THO

              RN

              E STR

              EETC

              AWTH

              OR

              NE ST

              REET

              DEVON STREETDEVON STREET

              KINTORE STREETKINTORE STREET

              GOODENOUGH STREETGOODENOUGH STREET

              LIVESTR

              ON

              G PATH

              WAY

              LIVESTR

              ON

              G PATH

              WAY

              CCAAWW

              TTHHOO

              RRNN

              EE SSTTRR

              EEEETT

              HHOO

              LLLLAANN

              DD SSTT

              RREEEETT

              DE

              DEW

              SW

              STREET

              TREET

              JJAM

              EA

              MES S

              S STREET

              TREET

              DDOOVVEE SSTTRREEEETT

              LLIIVVEESSTTRR

              OONN

              GG PPAATTHH

              WWAAYY

              LIGHT TERRLIGHT TERRAACECE

              AD

              MELLA

              SA

              DM

              ELLA STR

              EETTR

              EET

              CHAPEL SCHAPEL STREETTREET

              AALLBB

              EERRTT SSTTRR

              EEEETT

              GEGEORORGE SGE STREETTREET

              PPOORRTT RROOAADD

              PPOORRTT RROOAADD

              DDEEWW

              SSTTRREEEETT

              MMAARRIIAA SSTTRREEEETT

              JJAAMM

              EESS CCOO

              NNGG

              DDOO

              NN DD

              RRIIVV

              EE

              WWAA

              LLSSHH SSTT

              SSMMIITTHH SSTTRREEEETT

              RRANDOLPH S

              ANDOLPH STREETTREET

              PPOORR

              TT RROO

              AADD

              PPOORR

              TT RROO

              AADD

              KKIINNTTOORREE SSTTRREEEETT

              KKIINNTTOORREE SSTTRREEEETT

              PPAARR

              KKEERR

              SSTTRREEEETT

              GGOOOODDEENNOOUUGGHH SSTTRREEEETT

              DDEEVVOONN SSTTRREEEETT

              ASSESSMENT AREA

              CBD

              750m

              LEGEND

              EPA ASSESSMENT AREA

              CADASTRE

              12500 A3

              0 25 50 m

              CLIENT

              SA EPA

              PROJECT

              FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

              EPA THEBARTON ASSESSMENT AREA - STAGE 1

              TITLE

              FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

              PROJECT NO DATE CREATED

              80607-1 290917

              80607_Fig 1 - Site Location and Assessment Areaai REV 1 gt 290917

              LE

              VE

              L 1

              12

              4 S

              OU

              TH

              TE

              RR

              AC

              E

              AD

              EL

              AID

              E S

              A 5

              00

              0

              P

              H

              (08

              ) 8

              23

              2 9

              08

              8

              F

              AX

              (0

              8)

              82

              32

              90

              99

              EM

              AIL

              in

              fo

              fyfe

              co

              ma

              u

              W

              EB

              fy

              fec

              om

              au

              AB

              N

              57

              00

              8 1

              16 1

              30

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              DEW

              STREET

              DEW

              STREET

              CHAPEL STREETCHAPEL STREET

              PAR

              KER

              STREET

              PAR

              KER

              STREET

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              LIGHT TERRACELIGHT TERRACE

              DEW

              STREET

              DEW

              STREET

              WA

              LSH ST

              WA

              LSH ST

              AD

              MELLA

              STREET

              AD

              MELLA

              STREET

              ALB

              ERT STR

              EETA

              LBER

              T STREET

              HO

              LLAN

              D ST

              REET

              HO

              LLAN

              D ST

              REET

              RANDOLPH STREET

              RANDOLPH STREET

              JAM

              ES STREET

              JAM

              ES STREET

              DOVE STREET

              DOVE STREET

              SMITH STREETSMITH STREET

              MARIA STREETMARIA STREET

              GEORGE STREETGEORGE STREET

              KINTORE STREET

              KINTORE STREET

              PORT ROAD

              PORT ROAD

              PORT ROAD

              PORT ROAD

              CAW

              THO

              RN

              E STR

              EETC

              AWTH

              OR

              NE ST

              REET

              DEVON STREETDEVON STREET

              KINTORE STREETKINTORE STREET

              GOODENOUGH STREETGOODENOUGH STREET

              LIVESTR

              ON

              G PATH

              WAY

              LIVESTR

              ON

              G PATH

              WAY

              SV1SV1

              SV2SV2

              SV3SV3SV4SV4

              SV5SV5

              SV6SV6

              SV7SV7SV8SV8

              SV9SV9

              SV10SV10

              SV11SV11SV12SV12

              SV13SV13

              MW1MW1

              MW02MW02

              MW3MW3

              MW4MW4MW5MW5MW6MW6

              MW7MW7

              MW8MW8

              MW9MW9

              MW10MW10MW11MW11

              MW12MW12MW13MW13

              MW14MW14MW15MW15

              MW16MW16

              MW17MW17

              MW18MW18

              MW19MW19

              MW20MW20

              MW21MW21

              MW22MW22

              MW23MW23

              MW24MW24

              MW25MW25

              MW26MW26

              WMS2WMS2WMS1WMS1

              WMS3WMS3WMS4WMS4WMS5WMS5

              WMS6WMS6

              WMS7WMS7WMS8WMS8

              WMS9WMS9WMS10WMS10

              WMS11WMS11

              WMS12WMS12

              WMS13WMS13WMS14WMS14

              WMS15WMS15

              WMS41WMS41

              WMS40WMS40

              WMS39WMS39WMS38WMS38

              WMS16WMS16

              WMS17WMS17

              WMS18WMS18WMS19WMS19

              WMS20WMS20

              WMS21WMS21WMS22WMS22

              WMS23WMS23WMS24WMS24

              WMS25WMS25

              WMS26WMS26

              WMS27WMS27WMS28WMS28WMS29WMS29

              WMS30WMS30

              WMS31WMS31

              WMS32WMS32

              WMS33WMS33

              WMS34WMS34

              WMS35WMS35

              WMS36WMS36

              WMS37WMS37

              WWAA

              LLSSHHSSTT

              SSMMIITTHH SSTTRREEEETT

              RRANDOLPH S

              ANDOLPH STREETTREET

              PPOORR

              TT RROO

              AADD

              PPOORR

              TT RROO

              AADD

              CCAAWW

              TTHHOO

              RRNN

              EE SSTTRR

              EEEETT

              JJAM

              EA

              MES S

              S STREET

              TREET

              HHOO

              LLLLAANN

              DDSSTT

              RREEEETT

              DE

              DEW

              SW

              STREET

              TREET

              DDOOVVEE SSTTRREEEETT

              LLIIVVEESSTTRR

              OONN

              GGPPAATTHH

              WWAAYY

              LIGHT TERRLIGHT TERRAACECE

              CHAPEL SCHAPEL STREETTREET

              AALLBB

              EERRTT SSTTRR

              EEEETT

              AD

              MELLA

              SA

              DM

              ELLA STR

              EETTR

              EET

              GEGEORORGE SGE STREETTREET

              PPOORRTT RROOAADD PPOORRTT RROOAADD

              DDEEWW

              SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

              JJAAMM

              EESS CCOO

              NNGG

              DDOO

              NN DD

              RRIIVV

              EE

              KKIINNTTOORREE SSTTRREEEETT

              KKIINNTTOORREE SSTTRREEEETT

              PPAARR

              KKEERR

              SSTTRREEEETT

              GGOOOODDEENNOOUUGGHH SSTTRREEEETT

              DDEEVVOONN SSTTRREEEETT

              FIGURE 2 ASSESSMENT POINT LOCATIONS

              MMWW88

              MW2MW244 WMS3WMS355

              MW2MW255

              WMS3WMS366

              WMS3WMS377

              WMS3WMS311

              MW2MW222WMS34WMS34

              MW2MW233 WMS3WMS322

              WMS3WMS333

              WMS2WMS277WMS2WMS299 WMS2WMS288

              SSV12V12 SSVV1111 MW19MW19

              MW18MW18 SSVV1133 MW2MW200 WMS3WMS300

              MW2MW211 WMS2WMS255

              WMS2WMS266

              MW17MW17 WMS2WMS244

              WMS2WMS233

              WMS2WMS222 WMS2WMS211

              SSVV99

              SSV10V10WMS2WMS200 MW14MW14MW15MW15 WMS18WMS18

              WMS19WMS19 MW16MW16

              WMS13WMS13MW10MW10 WMS14WMS14MMWW1111SVSV77WMS15WMS15SSVV88WMS16WMS16

              SVSV66WMS4WMS411MW13MW13 LEGENDMW12MW12

              WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS17WMS17 WMS40WMS40 SSVV55 MW0MW022MW9MW9 GROUNDWATER MONITORING WELL

              WMS11WMS11 WMS6WMS6 SOIL VAPOUR BORE

              WATERLOO MEMBRANE SAMPLERTM - ROUND 2

              SVSV22WMS8WMS8SVSVWMS12WMS12 44 WMS7WMS7 MW4MW4MMWW SVSV66 33 MW5MW5WMS3WMS388

              WMS3WMS399 MW7MW7 EPA ASSESSMENT AREAWMS10WMS10 WMS9WMS9

              SVSV11 CADASTRE

              MW3MW3

              MW1MW1 WMS3WMS3WMS4WMS4MW2MW266 WMS5WMS5 12500 A3

              0 25 50 m

              CLIENT

              SA EPAWMS1WMS1

              WMS2WMS2 PROJECT

              EPA THEBARTON ASSESSMENT AREA - STAGE 1

              TITLE

              FIGURE 2 ASSESSMENT POINT LOCATIONS

              PROJECT NO DATE CREATED

              80607-1 280917

              80607_Fig 2 - Assessment Point Locationsai REV 1 gt 280917

              LE

              VE

              L 1

              12

              4 S

              OU

              TH

              TE

              RR

              AC

              E

              AD

              EL

              AID

              E S

              A 5

              00

              0

              PH

              (0

              8)

              82

              32

              90

              88

              F

              AX

              (0

              8)

              82

              32

              90

              99

              E

              MA

              IL

              info

              fy

              fec

              om

              au

              W

              EB

              fy

              fec

              om

              au

              A

              BN

              5

              7 0

              08

              116

              13

              0

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              DEW

              STREET

              DEW

              STREET

              CHAPEL STREETCHAPEL STREET

              PAR

              KER

              STREET

              PAR

              KER

              STREET

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              LIGHT TERRACELIGHT TERRACE

              DEW

              STREET

              DEW

              STREET

              WA

              LSH ST

              WA

              LSH ST

              AD

              MELLA

              STREET

              AD

              MELLA

              STREET

              ALB

              ERT STR

              EETA

              LBER

              T STREET

              HO

              LLAN

              D ST

              REET

              HO

              LLAN

              D ST

              REET

              RANDOLPH STREET

              RANDOLPH STREET

              JAM

              ES STREET

              JAM

              ES STREET

              DOVE STREET

              DOVE STREET

              SMITH STREETSMITH STREET

              MARIA STREETMARIA STREET

              GEORGE STREETGEORGE STREET

              KINTORE STREET

              KINTORE STREET

              PORT ROAD

              PORT ROAD

              PORT ROAD

              PORT ROAD

              CAW

              THO

              RN

              E STR

              EETC

              AWTH

              OR

              NE ST

              REET

              DEVON STREETDEVON STREET

              KINTORE STREETKINTORE STREET

              GOODENOUGH STREETGOODENOUGH STREET

              LIVESTR

              ON

              G PATH

              WAY

              LIVESTR

              ON

              G PATH

              WAY

              WMS2WMS2WMS1WMS1

              WMS3WMS3WMS4WMS4

              WMS5WMS5

              WMS6WMS6

              WMS7WMS7WMS8WMS8

              WMS9WMS9

              WMS10WMS10

              WMS11WMS11

              WMS12WMS12

              WMS13WMS13WMS14WMS14

              WMS15WMS15 WMS41WMS41

              WMS40WMS40

              WMS39WMS39WMS38WMS38

              WMS16WMS16

              WMS17WMS17

              WMS18WMS18WMS19WMS19WMS20WMS20

              WMS21WMS21WMS22WMS22

              WMS23WMS23WMS24WMS24

              WMS25WMS25

              WMS26WMS26

              WMS27WMS27WMS28WMS28WMS29WMS29

              WMS30WMS30

              WMS31WMS31

              WMS32WMS32WMS33WMS33

              WMS34WMS34

              WMS35WMS35

              WMS36WMS36

              WMS37WMS37

              WWAA

              LLSSHHSSTT

              SSMMIITTHH SSTTRREEEETT

              RRANDOLPH S

              ANDOLPH STREETTREET

              PPOORR

              TT RROO

              AADD

              PPOORR

              TT RROO

              AADD

              CCAAWW

              TTHHOO

              RRNN

              EE SSTTRR

              EEEETT

              JJAM

              EA

              MES S

              S STREET

              TREET

              HHOO

              LLLLAANN

              DDSSTT

              RREEEETT

              DE

              DEW

              SW

              STREET

              TREET

              DDOOVVEE SSTTRREEEETT

              LLIIVVEESSTTRR

              OONN

              GGPPAATTHH

              WWAAYY

              LIGHT TERRLIGHT TERRAACECE

              AD

              MELLA

              SA

              DM

              ELLA STR

              EETTR

              EET

              AALLBB

              EERRTT SSTTRR

              EEEETT

              CHAPEL SCHAPEL STREETTREET

              GEGEORORGE SGE STREETTREET

              PPOORRTT RROOAADD PPOORRTT RROOAADD

              DDEEWW

              SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

              JJAAMM

              EESS CCOO

              NNGG

              DDOO

              NN DD

              RRIIVV

              EE

              KKIINNTTOORREE SSTTRREEEETT

              KKIINNTTOORREE SSTTRREEEETT

              PPAARR

              KKEERR

              SSTTRREEEETT

              GGOOOODDEENNOOUUGGHH SSTTRREEEETT

              DDEEVVOONN SSTTRREEEETT

              FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

              TCE CONCENTRATION PLAN

              WMS3WMS355 TCE lt78

              WMS3WMS366 TCE lt77WMS3WMS377

              TCE 44

              WMS3WMS311 TCE lt78

              WMS34WMS34 TCE 11

              WMS3WMS322WMS3WMS333 TCE lt78TCE lt79

              WMS2WMS277WMS2WMS299 WMS2WMS288 TCE 64 TCE lt77 TCE lt8

              WMS3WMS300 TCE lt8

              WMS2WMS255

              WMS2WMS266 TCE 1400(D)

              WMS2WMS222 TCE 38 WMS2WMS211

              TCE lt79

              TCE lt78

              WMS2WMS233 WMS2WMS244 TCE lt77

              TCE 230

              WMS2WMS200 WMS19WMS19TCE lt78 WMS18WMS18 TCE 11000

              TCE 4200

              WMS13WMS13 WMS14WMS14 TCE lt79

              WMS4WMS411WMS15WMS15 TCE 46000WMS16WMS16 TCE 18000 LEGENDTCE lt8

              TCE lt78WMS17WMS17 WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS40WMS40TCE lt79

              TCE 110000 WATERLOO MEMBRANE SAMPLERTM - ROUND 2WMS11WMS11

              TCE 71000WMS12WMS12 EPA ASSESSMENT AREA

              CADASTRE

              WMS6WMS6 TCE lt58 WMS8WMS8 WMS3WMS388 TCE 32WMS7WMS7WMS3WMS399

              TCE 12000 TCE 13000 TCE 1900TCE 1300WMS9WMS9 TCE lt58 NotesWMS10WMS10

              All concentrations are in μgm3 TCE lt58

              D = Duplicate result

              WMS3WMS3WMS4WMS4 12500 A3

              LE

              VE

              L 1

              12

              4 S

              OU

              TH

              TE

              RR

              AC

              E

              AD

              EL

              AID

              E S

              A 5

              00

              0

              PH

              (0

              8)

              82

              32

              90

              88

              F

              AX

              (0

              8)

              82

              32

              90

              99

              E

              MA

              IL

              info

              fy

              fec

              om

              au

              W

              EB

              fy

              fec

              om

              au

              A

              BN

              5

              7 0

              08

              116

              13

              0

              TCE lt57WMS5WMS5 TCE lt57 TCE lt58 0 25 50

              m

              CLIENT

              SA EPA

              WMS2WMS2 TCE lt56

              WMS1WMS1 TCE lt56

              PROJECT

              EPA THEBARTON ASSESSMENT AREA - STAGE 1

              TITLE

              FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

              TCE CONCENTRATION PLAN

              PROJECT NO DATE CREATED

              80607-1 241017

              80607_Fig 3 - WMS TCE Concentration Planai REV 1 gt 241017

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              DEW

              STREET

              DEW

              STREET

              CHAPEL STREETCHAPEL STREET

              PAR

              KER

              STREET

              PAR

              KER

              STREET

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              LIGHT TERRACELIGHT TERRACE

              DEW

              STREET

              DEW

              STREET

              WA

              LSH ST

              WA

              LSH ST

              AD

              MELLA

              STREET

              AD

              MELLA

              STREET

              ALB

              ERT STR

              EETA

              LBER

              T STREET

              HO

              LLAN

              D ST

              REET

              HO

              LLAN

              D ST

              REET

              RANDOLPH STREET

              RANDOLPH STREET

              JAM

              ES STREET

              JAM

              ES STREET

              DOVE STREET

              DOVE STREET

              SMITH STREETSMITH STREET

              MARIA STREETMARIA STREET

              GEORGE STREETGEORGE STREET

              KINTORE STREET

              KINTORE STREET

              PORT ROAD

              PORT ROAD

              PORT ROAD

              PORT ROAD

              CAW

              THO

              RN

              E STR

              EETC

              AWTH

              OR

              NE ST

              REET

              DEVON STREETDEVON STREET

              KINTORE STREETKINTORE STREET

              GOODENOUGH STREETGOODENOUGH STREET

              LIVESTR

              ON

              G PATH

              WAY

              LIVESTR

              ON

              G PATH

              WAY

              MW1MW1

              MW02MW02

              MW3MW3

              MW4MW4MW5MW5

              MW6MW6

              MW7MW7

              MW8MW8

              MW9MW9

              MW10MW10MW11MW11

              MW12MW12

              MW13MW13

              MW14MW14

              MW15MW15

              MW16MW16

              MW17MW17

              MW18MW18

              MW19MW19MW20MW20

              MW21MW21

              MW22MW22

              MW23MW23

              MW24MW24

              MW25MW25

              MW26MW26

              WWAA

              LLSSHHSSTT

              SSMMIITTHH SSTTRREEEETT

              4

              466

              PPOORR

              TT RROO

              AADD

              PPOORR

              TT RROO

              AADD

              RRANDOLPH S

              ANDOLPH STREETTREET 4455

              DE

              DEW

              SW

              STREET

              TREET

              JJAM

              EA

              MES S

              S STREET

              TREET

              HHOO

              LLLLAANN

              DD SSTT

              RREEEETT

              CCAAWW

              TTHHOO

              RRNN

              EE SSTTRR

              EEEETT 4477

              DDOOVVEE SSTTRREEEETT

              4455

              4488

              LLIIVVEESSTTRR

              OONN

              GGPPAATTHH

              WWAAYY

              4455

              LIGHT TERRLIGHT TERRAACECE

              AD

              MELLA

              SA

              DM

              ELLA STR

              EETTR

              EET

              4466

              CHAPEL SCHAPEL STREETTREET

              4477 AA

              LLBBEERR

              TT SSTTRREEEETT

              4499

              GR4466 OUND

              FLOW DIREW

              GEGEORORGE SGE STREETTREET ATER C

              4488 TION

              PPOORRTT RROOAADD PPOORRTT RROOAADD 55

              00 DD

              EEWW SSTTRR

              EEEETT 4499

              MMAARRIIAA SSTTRREEEETT

              4477

              5500

              JJAAMM

              EESS CCOO

              NNGG

              DDOO

              NN DD

              RRIIVV

              EE

              88 44

              KKIINNTTOORREE SSTTRREEEETT

              KKIINNTTOORREE SSTTRREEEETT

              PPAARR

              KKEERR

              SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

              5500

              4499

              DDEEVVOONN SSTTRREEEETT

              FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

              Groundwater SWL MMWW88 Monitoring Well (m AHD)

              MW1 5011 MW2MW244

              MW02 4786

              MW3 484

              MW2MW255 MW4 507

              MW5 4833

              MW6 4794

              MW7 4703

              MW8 4581

              MW9 4728

              MW10 4871

              MW11 4785 MW2MW222

              MW12 4689

              MW13 4662

              MW2MW233 MW14 4723

              MW15 464

              MW16 4577

              MW17 4619

              MW18 4538

              MW19 4735

              MW20 457

              MW21 4531

              MW22 4501

              MW23 4497

              MW24 4537

              MW25 4469

              MW26 4918

              MW19MW19 MW2MW200

              MW2MW211MW18MW18

              MW17MW17

              MW14MW14

              MW15MW15

              MW16MW16

              MW10MW10 LEGEND MMWW1111

              GROUNDWATER MONITORING WELLMW12MW12

              50 INFERRED GROUNDWATER ELEVATION CONTOUR

              MW13MW13

              MW0MW022 INFERRED GROUNDWATER FLOW DIRECTION

              EPA ASSESSMENT AREA

              MW9MW9

              MW5MW5 CADASTREMMWW66 MW4MW4

              MW7MW7 Note This is one interpretation only Other interpretations possibleMW3MW3

              12500 A3

              0 25 50 m

              CLIENT

              SA EPA

              PROJECT

              EPA THEBARTON ASSESSMENT AREA - STAGE 1

              TITLE

              FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

              PROJECT NO DATE CREATED

              80607-1 290917

              MW1MW1 MW2MW266

              80607_Fig 4 - Groundwater Elevation Contour Planai REV 1 gt 290917

              LE

              VE

              L 1

              12

              4 S

              OU

              TH

              TE

              RR

              AC

              E

              AD

              EL

              AID

              E S

              A 5

              00

              0

              PH

              (0

              8)

              82

              32

              90

              88

              F

              AX

              (0

              8)

              82

              32

              90

              99

              E

              MA

              IL

              info

              fy

              fec

              om

              au

              W

              EB

              fy

              fec

              om

              au

              A

              BN

              5

              7 0

              08

              116

              13

              0

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              DEW

              STREET

              DEW

              STREET

              CHAPEL STREETCHAPEL STREET

              PAR

              KER

              STREET

              PAR

              KER

              STREET

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              LIGHT TERRACELIGHT TERRACE

              DEW

              STREET

              DEW

              STREET

              WA

              LSH ST

              WA

              LSH ST

              AD

              MELLA

              STREET

              AD

              MELLA

              STREET

              ALB

              ERT STR

              EETA

              LBER

              T STREET

              HO

              LLAN

              D ST

              REET

              HO

              LLAN

              D ST

              REET

              RANDOLPH STREET

              RANDOLPH STREET

              JAM

              ES STREET

              JAM

              ES STREET

              DOVE STREET

              DOVE STREET

              SMITH STREETSMITH STREET

              MARIA STREETMARIA STREET

              GEORGE STREETGEORGE STREET

              KINTORE STREET

              KINTORE STREET

              PORT ROAD

              PORT ROAD

              PORT ROAD

              PORT ROAD

              CAW

              THO

              RN

              E STR

              EETC

              AWTH

              OR

              NE ST

              REET

              DEVON STREETDEVON STREET

              KINTORE STREETKINTORE STREET

              GOODENOUGH STREETGOODENOUGH STREET

              LIVESTR

              ON

              G PATH

              WAY

              LIVESTR

              ON

              G PATH

              WAY

              MW1MW1

              MW02MW02

              MW3MW3

              MW4MW4

              MW5MW5

              MW6MW6

              MW7MW7

              MW8MW8

              MW9MW9

              MW10MW10MW11MW11

              MW12MW12

              MW13MW13

              MW14MW14

              MW15MW15

              MW16MW16

              MW17MW17

              MW18MW18

              MW19MW19MW20MW20

              MW21MW21

              MW22MW22

              MW23MW23

              MW24MW24

              MW25MW25

              MW26MW26

              WWAA

              LLSSHHSSTT

              SSMMIITTHH SSTTRREEEETT

              ndnd

              RRANDOLPH S

              ANDOLPH STREETTREET

              PPOORR

              TTRR

              OOAA

              DD

              PPOORR

              TTRR

              OOAA

              DD

              JJAM

              EA

              MES S

              S STREET

              TREET

              HHOO

              LLLLAANN

              DDSSTT

              RREEEETT

              CCAAWW

              TTHHOO

              RRNN

              EESSTT

              RREEEETT

              DE

              DEW

              SW

              STREET

              TREET

              DDOOVVEE SSTTRREEEETT

              LLIIVVEESSTTRR

              OONN

              GGPPAATTHH

              WWAAYY

              LIGHT TERRLIGHT TERRAACECE

              AD

              MELLA

              SA

              DM

              ELLA STR

              EETTR

              EET

              AALLBB

              EERRTT SSTTRR

              EEEETT

              CHAPEL SCHAPEL STREETTREET

              ndnd ndnd

              100100

              11000000

              GEGEORORGE SGE STREETTREET

              1010000000

              PPOORRTT RROOAADD PPOORRTT RROOAADD

              DDEEWW

              SSTTRREEEETT

              1010000000 11000000 MMAARRIIAA SSTTRREEEETT

              100100

              JJAAMM

              EESSCC

              OONN

              GGDD

              OONN

              DDRR

              IIVVEE

              KKIINNTTOORREE SSTTRREEEETT ndnd

              KKIINNTTOORREE SSTTRREEEETT

              PPAARR

              KKEERR

              SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

              DDEEVVOONN SSTTRREEEETT

              FIGURE 5 GROUNDWATER CONCENTRATION PLAN

              MW2MW244

              MMWW88 TCE lt1

              PCE lt1

              11-DCE lt1TCE lt1

              12-DCE lt1PCE lt1

              11-DCE lt1MW2MW255 12-DCE lt1

              TCE 2

              PCE lt1

              11-DCE lt1

              12-DCE lt1

              MW2MW222 TCE lt1

              PCE lt1

              11-DCE lt1MW2MW233 12-DCE lt1

              TCE 21

              PCE lt1

              11-DCE lt1

              12-DCE lt1

              MW19MW19 TCE lt1

              MW2MW200 TCE 70 PCE lt1MW2MW211 PCE lt1MW18MW18 11-DCE lt1

              TCE 23 11-DCE lt1TCE 5 12-DCE lt1 PCE lt1 12-DCE lt1PCE lt1 11-DCE lt1

              11-DCE lt1 12-DCE lt1

              12-DCE lt1

              MW17MW17 LEGENDTCE 24 MW14MW14

              PCE lt1 TCE 1100 lt1 MW15MW15 GROUNDWATER MONITORING WELL11-DCE PCE lt1

              12-DCE lt1 TCE 180 11-DCE 2MW16MW16 100 INFERRED TCE GROUNDWATERPCE lt1 12-DCE 4 CONCENTRATION CONTOURSTCE lt1 11-DCE lt1 PCE lt1 12-DCE lt1 11-DCE lt1

              12-DCE lt1 MMWW1111

              EPA ASSESSMENT AREAMW10MW10

              TCE lt1 CADASTREMW12MW12 TCE lt14900 PCE

              lt1 11-DCE lt1TCE 700 PCEMW13MW13 12-DCE lt1 TCE CONCENTRATIONS (μgL)lt1 11-DCE 7PCE

              TCE lt1 lt1 12-DCE 511-DCE gtnd to lt100 100 to lt1000 1000 to lt10000

              MW0MW022PCE lt1 12-DCE lt1 2100011-DCE lt1 MW9MW9 TCE

              PCE lt112-DCE lt1 TCE 2(D) 11-DCE 15PCE lt1 MW5MW5

              10000 to 29000

              nd = non-detect (lt1)12-DCE 4511-DCE lt1 MMWW66 TCE 29000 MW4MW4 12-DCE lt1

              PCE 3 TCE lt1 NotesTCE 29 11-DCE 6MW7MW7 PCE lt1PCE lt1 This is one interpretation only Other interpretations possible12-DCE 23TCE lt1 11-DCE lt111-DCE lt1 All concentrations are in μgL

              12-DCE includes cis and trans PCE lt1 MW3MW3 12-DCE lt112-DCE lt1 11-DCE lt1

              TCE 69 D = Duplicate result12-DCE lt1 PCE lt1

              11-DCE lt1

              12-DCE lt1 MW1MW1

              12500 A3MW2MW266 TCE lt1

              TCE 2 PCE lt1

              PCE lt1 11-DCE lt1

              11-DCE lt1 12-DCE lt1

              12-DCE lt1

              LE

              VE

              L 1

              12

              4 S

              OU

              TH

              TE

              RR

              AC

              E

              AD

              EL

              AID

              E S

              A 5

              00

              0

              PH

              (0

              8)

              82

              32

              90

              88

              F

              AX

              (0

              8)

              82

              32

              90

              99

              E

              MA

              IL

              info

              fy

              fec

              om

              au

              W

              EB

              fy

              fec

              om

              au

              A

              BN

              5

              7 0

              08

              116

              13

              0

              0 25 50 m

              CLIENT

              SA EPA

              PROJECT

              EPA THEBARTON ASSESSMENT AREA - STAGE 1

              TITLE

              FIGURE 5 GROUNDWATER CONCENTRATION PLAN

              PROJECT NO DATE CREATED

              80607-1 280917

              80607_Fig 5 - Groundwater TCE Concentration Plan r2ai REV 2 gt 280917

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              DEW

              STREET

              DEW

              STREET

              CHAPEL STREETCHAPEL STREET

              PAR

              KER

              STREET

              PAR

              KER

              STREET

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              LIGHT TERRACELIGHT TERRACE

              DEW

              STREET

              DEW

              STREET

              WA

              LSH ST

              WA

              LSH ST

              AD

              MELLA

              STREET

              AD

              MELLA

              STREET

              ALB

              ERT STR

              EETA

              LBER

              T STREET

              HO

              LLAN

              D ST

              REET

              HO

              LLAN

              D ST

              REET

              RANDOLPH STREET

              RANDOLPH STREET

              JAM

              ES STREET

              JAM

              ES STREET

              DOVE STREET

              DOVE STREET

              SMITH STREETSMITH STREET

              MARIA STREETMARIA STREET

              GEORGE STREETGEORGE STREET

              KINTORE STREET

              KINTORE STREET

              PORT ROAD

              PORT ROAD

              PORT ROAD

              PORT ROAD

              CAW

              THO

              RN

              E STR

              EETC

              AWTH

              OR

              NE ST

              REET

              DEVON STREETDEVON STREET

              KINTORE STREETKINTORE STREET

              GOODENOUGH STREETGOODENOUGH STREET

              LIVESTR

              ON

              G PATH

              WAY

              LIVESTR

              ON

              G PATH

              WAY

              SV1SV1

              SV2SV2SV3SV3SV4SV4

              SV5SV5

              SV7SV7SV8SV8

              SV9SV9

              SV10SV10

              SV11SV11SV12SV12

              SV13SV13

              SV6SV6

              WWAA

              LLSSHHSSTT

              SSMMIITTHH SSTTRREEEETT

              RRANDOLPH S

              ANDOLPH STREETTREET

              PPOORR

              TTRR

              OOAA

              DD

              PPOORR

              TTRR

              OOAA

              DD

              CCAAWW

              TTHHOO

              RRNN

              EESSTT

              RREEEETT

              HHOO

              LLLLAANN

              DDSSTT

              RREEEETT

              JJAM

              EA

              MES S

              S STREET

              TREET

              DE

              DEW

              SW

              STREET

              TREET

              DDOOVVEE SSTTRREEEETT

              00

              LLIIVVEESSTTRR

              OONN

              GGPPAATTHH

              WWAAYY

              LIGHT TERRLIGHT TERRAACECE

              AD

              MELLA

              SA

              DM

              ELLA STR

              EETTR

              EET

              CHAPEL SCHAPEL STREETTREET

              00

              AALLBB

              EERRTT SSTTRR

              EEEETT

              1010

              GEGEORORGE SGE STREETTREET

              000000

              PPOORRTT RROOAADD

              100100000

              000

              1010

              PPOORRTT RROOAADD

              000000

              DDEEWW

              SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

              JJAAMM

              EESSCC

              OONN

              GGDD

              OONN

              DDRR

              IIVVEE

              KKIINNTTOORREE SSTTRREEEETT 00

              KKIINNTTOORREE SSTTRREEEETT

              PPAARR

              KKEERR

              SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

              DDEEVVOONN SSTTRREEEETT

              FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

              SSVV1111 SSV12V12 TCE lt18

              SSVV1133 TCE 16

              PCE lt54 TCE lt21

              11-DCE lt29 PCE lt25

              12-DCE lt39 11-DCE lt14

              12-DCE lt18

              PCE lt22

              11-DCE lt12

              12-DCE lt16

              TCE 170

              PCE lt54

              11-DCE lt3

              12-DCE lt39 LEGEND SSVV99

              SSV10V10 SOIL VAPOUR BORE

              TCE lt21 0 INFERRED TCE SOIL VAPOUR CONTOUR PCE lt25

              TCE 2200011-DCE lt14 EPA ASSESSMENT AREA

              PCE 1912-DCE lt18

              11-DCE lt27 CADASTRE

              12-DCE lt37 SVSV66SVSV77

              SSVV88 TCE 22000

              TCE 2300 PCE 12 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)TCE 100000 PCE 62 11-DCE lt29PCE 84 0 to lt10000SSVV55lt2711-DCE 12-DCE lt2911-DCE lt33 10000 to lt100000

              100000 to 210000 12-DCE lt36 12-DCE lt44

              TCE 17000 SVSV44 SVSV22SVSV33 NotePCE 31 TCE 51000TCE 210000 This is one interpretation only Other interpretations possible11-DCE lt14 PCE 39PCE 650012-DCE lt18 39 Estimated extent of plume has utilised groundwater11-DCE11-DCE 5900 12-DCE 21 concentration data12-DCE lt71

              SVSV11 All concentrations are in (μgmsup3)

              TCE 6300(LD) 12-DCE includes cis and trans PCE 78 LD = Laboratory duplicate result 11-DCE lt29

              12-DCE lt38

              12500 A3

              0 25 50 m

              CLIENT

              SA EPA

              PROJECT

              EPA THEBARTON ASSESSMENT AREA - STAGE 1

              TITLE

              FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

              PROJECT NO DATE CREATED

              80607-1 290917

              80607_Fig 6 - Soil Vapour TCE Concentration Plan - 1mai REV 2 gt 290917

              LE

              VE

              L 1

              12

              4 S

              OU

              TH

              TE

              RR

              AC

              E

              AD

              EL

              AID

              E S

              A 5

              00

              0

              PH

              (0

              8)

              82

              32

              90

              88

              F

              AX

              (0

              8)

              82

              32

              90

              99

              E

              MA

              IL

              info

              fy

              fec

              om

              au

              W

              EB

              fy

              fec

              om

              au

              A

              BN

              5

              7 0

              08

              116

              13

              0

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              JAM

              ES CO

              NG

              DO

              N D

              RIV

              E

              DEW

              STREET

              DEW

              STREET

              CHAPEL STREETCHAPEL STREET

              PAR

              KER

              STREET

              PAR

              KER

              STREET

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              POR

              T RO

              AD

              LIGHT TERRACELIGHT TERRACE

              DEW

              STREET

              DEW

              STREET

              WA

              LSH ST

              WA

              LSH ST

              AD

              MELLA

              STREET

              AD

              MELLA

              STREET

              ALB

              ERT STR

              EETA

              LBER

              T STREET

              HO

              LLAN

              D ST

              REET

              HO

              LLAN

              D ST

              REET

              RANDOLPH STREET

              RANDOLPH STREET

              JAM

              ES STREET

              JAM

              ES STREET

              DOVE STREET

              DOVE STREET

              SMITH STREETSMITH STREET

              MARIA STREETMARIA STREET

              GEORGE STREETGEORGE STREET

              KINTORE STREET

              KINTORE STREET

              PORT ROAD

              PORT ROAD

              PORT ROAD

              PORT ROAD

              CAW

              THO

              RN

              E STR

              EETC

              AWTH

              OR

              NE ST

              REET

              DEVON STREETDEVON STREET

              KINTORE STREETKINTORE STREET

              GOODENOUGH STREETGOODENOUGH STREET

              LIVESTR

              ON

              G PATH

              WAY

              LIVESTR

              ON

              G PATH

              WAY

              SV1SV1

              SV2SV2SV3SV3SV4SV4

              SV5SV5

              SV7SV7SV8SV8

              SV9SV9

              SV10SV10

              SV12SV12

              SV6SV6

              WWAA

              LLSSHHSSTT

              SSMMIITTHH SSTTRREEEETT

              RRANDOLPH S

              ANDOLPH STREETTREET

              PPOORR

              TTRR

              OOAA

              DD

              PPOORR

              TTRR

              OOAA

              DD

              CCAAWW

              TTHHOO

              RRNN

              EESSTT

              RREEEETT

              HHOO

              LLLLAANN

              DDSSTT

              RREEEETT

              DE

              DEW

              SW

              STREET

              TREET

              JJAM

              EA

              MES S

              S STREET

              TREET

              DDOOVVEE SSTTRREEEETT

              00

              LIGHT TERRLIGHT TERRAACECE

              LLIIVVEESSTTRR

              OONN

              GGPPAATTHH

              WWAAYY

              AD

              MELLA

              SA

              DM

              ELLA STR

              EETTR

              EET

              CHAPEL SCHAPEL STREETTREET

              00

              1010000000

              AALLBB

              EERRTT SSTTRR

              EEEETT

              100100 000

              000 GEGEORORGE SGE STREETTREET

              PPOORRTT RROOAADD 11000000000

              000 PPOORRTT RROOAADD

              DDEEWW

              SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

              100100000000

              JJAAMM

              EESSCC

              OONN

              GGDD

              OONN

              DDRR

              IIVVEE

              1010000000

              KKIINNTTOORREE SSTTRREEEETT

              00

              KKIINNTTOORREE SSTTRREEEETT

              PPAARR

              KKEERR

              SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

              DDEEVVOONN SSTTRREEEETT

              FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

              SSV12V12 TCE 55

              PCE lt45

              11-DCE lt24

              12-DCE lt32

              TCE 260

              PCE lt51

              11-DCE lt28

              12-DCE

              SSVV99

              lt37 LEGEND

              SSV10V10 SOIL VAPOUR BORE

              TCE 51 0 INFERRED TCE SOIL VAPOUR CONTOURPCE lt53

              TCE 11000011-DCE lt29

              EPA ASSESSMENT AREAPCE lt13012-DCE lt39

              11-DCE lt69

              CADASTRE12-DCE lt92 SVSV66SVSV77

              SSVV88 TCE 150000

              TCE 14000 56 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)PCETCE 160000 PCE 19 11-DCE lt30PCE 310 0 to lt10000SSVV5511-DCE lt26 12-DCE lt3911-DCE 33 10000 to lt100000

              100000 to lt1000000 1000000

              12-DCE lt35 12-DCE 20

              TCE 43000 SVSV44 SVSV22SVSV33 NotePCE 90 TCE 940000(FD)TCE 1000000 This is one interpretation only Other interpretations possible11-DCE lt15 PCE 15000PCE 1500012-DCE 30 14000 Estimated extent of plume has utilised groundwater11-DCE11-DCE 14000 12-DCE lt930 concentration data12-DCE lt930

              All concentrations are in (μgmsup3) 12-DCE includes cis and trans

              SVSV11 TCE 21000

              FD = Field Duplicate resultPCE 21

              11-DCE lt57

              12-DCE lt76

              12500 A3

              0 25 50 m

              CLIENT

              SA EPA

              PROJECT

              EPA THEBARTON ASSESSMENT AREA - STAGE 1

              TITLE

              FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

              PROJECT NO DATE CREATED

              80607-1 290917

              80607_Fig 7 - Soil Vapour TCE Concentration Plan - 3m r2ai REV 2 gt 290917

              LE

              VE

              L 1

              12

              4 S

              OU

              TH

              TE

              RR

              AC

              E

              AD

              EL

              AID

              E S

              A 5

              00

              0

              PH

              (0

              8)

              82

              32

              90

              88

              F

              AX

              (0

              8)

              82

              32

              90

              99

              E

              MA

              IL

              info

              fy

              fec

              om

              au

              W

              EB

              fy

              fec

              om

              au

              A

              BN

              5

              7 0

              08

              116

              13

              0

              • THEBARTON ASSESSMENT AREA STAGE 1 ENVIRONMENTAL ASSESSMENT FINAL REPORT | EPA REF 0524111 30 OCTOBER 2017 VOLUME 1 REPORT13
              • This report is formatted to print Double Sided
              • TITLE PAGE13
              • CONTENTS13
              • LIST OF ACRONYMS13
              • EXECUTIVE SUMMARY13
              • 1 INTRODUCTION
                • 11 Purpose
                • 12 General background information
                • 13 Definition of the assessment area
                • 14 Identification of contaminants of potential concern
                • 15 Objectives
                  • 2 CHARACTERISATION OF THE ASSESSMENT AREA
                    • 21 Site identification
                    • 22 Regional geology and hydrogeology
                    • 23 Data quality objectives
                      • 3 SCOPE OF WORK
                        • 31 Preliminary work
                        • 32 Field investigation and laboratory analysis program
                        • 33 Data interpretation
                          • 4 METHODOLOGY
                            • 41 Field methodologies
                            • 42 Laboratory analysis
                              • 5 QUALITY ASSURANCE AND QUALITY CONTROL
                                • 51 Field QAQC
                                • 52 Laboratory QAQC
                                • 53 QAQC summary
                                  • 6 ASSESSMENT CRITERIA
                                    • 61 Groundwater
                                    • 62 Soil vapour
                                      • 7 RESULTS
                                        • 71 Surface and sub surface soil conditions
                                        • 72 Waterloo Membrane Samplerstrade
                                        • 73 Groundwater
                                        • 74 Soil vapour bores
                                          • 8 GROUNDWATER FATE AND TRANSPORT MODELLING
                                            • 81 Groundwater flow modelling
                                            • 82 Solute transport modelling
                                              • 9 VAPOUR INTRUSION RISK ASSESSMENT
                                                • 91 Objective
                                                • 92 Areas of interest
                                                • 93 Risk assessment approach
                                                • 94 Tier 1 assessment
                                                • 95 Tier 2 assessment
                                                • 96 Conclusions
                                                  • 10 CONCEPTUAL SITE MODEL
                                                  • 11 CONCLUSIONS
                                                  • 12 DATA GAPS
                                                  • 13 REFERENCES
                                                  • 14 STATEMENT OF LIMITATIONS
                                                  • FIGURES13
                                                  • FIGURE 1 SITE LOCATION AND ASSESSMENT AREA
                                                  • FIGURE 2 ASSESSMENT POINT LOCATIONS
                                                  • FIGURE 3 WATERLOO MEMBRANE SAMPLERTM TCE CONCENTRATION PLAN13
                                                  • FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN
                                                  • FIGURE 5 GROUNDWATER CONCENTRATION PLAN
                                                  • FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)
                                                  • FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                LIST OF ACRONYMS

                AER Air Exchange Rate

                AF Attenuation Factor

                AHD Australian Height Datum

                ANZECC Australian and New Zealand Environment and Conservation Council

                ARMCANZ Agriculture and Resource Management Council of Australia and New Zealand

                ASC Assessment of Site Contamination

                ASTM American Standard Testing Material

                AT Averaging Time

                ATSDR Agency for Toxic Substances and Disease Registry

                AWQC Australian Water Quality Centre

                BGL Below Ground Level

                BTEX Benzene Toluene Ethylbenzene Xylenes

                BTOC Below Top of Casing

                BUA Beneficial Use Assessment

                CBD Central Business District

                CHC Chlorinated Hydrocarbon Compound

                COC Chain of Custody

                COPC Contaminants of Potential Concern

                CRC CARE Cooperative Research Centre for Contamination Assessment and Remediation of the Environment

                CSM Conceptual Site Model

                11-DCA 11-dichloroethane

                11-DCE 11-dichloroethene

                12-DCE 12-dichloroethene

                DCE Dichloroethene

                DEC Department of Environment and Conservation

                DEWNR Department of Environment Water and Natural Resources

                DNAPL Dense Non-Aqueous Phase Liquid

                DO Dissolved Oxygen

                DQI Data Quality Indicator

                DQO Data Quality Objective

                EC Electrical Conductivity

                ED Exposure Duration

                80607-1 REV1 30102017 PAGE V

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                EF Exposure Frequency

                EMP Environmental Management Plan

                EPA Environment Protection Authority

                EPC Exposure Point Concentration

                EPP Environment Protection Policy

                ET Exposure Time

                GPA Groundwater Prohibition Area

                GPR Ground Penetrating Radar

                GPS Global Positioning System

                HHRA Human Health Risk Assessment

                HIL Health Investigation Level

                HSP Health and safety Plan

                IPA Isopropyl Alcohol (isopropanol or 2-propanol)

                IRIS Integrated Risk Information System

                ITRC Interstate Technology and Regulatory Council

                JampE Johnson and Ettinger

                JHA Job Hazard Analysis

                LNAPL Light Non-Aqueous Phase Liquid

                LOR Limit of Reporting

                MGA Map Grid of Australia

                MQO Measuring Quality Objectives

                MTC Mass Transfer Co-efficient

                NA Not Applicable

                NAPL Non-Aqueous Phase Liquid

                NATA National Association of Testing Authorities

                ND Non Detect

                NEPM National Environment Protection Measure

                NHMRC National Health and Medical Research Council

                NJDEP New Jersey Department of Environmental Protection

                NRMMC National Resource Management Ministerial Council

                PAH Polycyclic Aromatic Hydrocarbons

                PCE Tetrachloroethene (perchloroethylene)

                PID Photoionisation Detector

                PQL Practical Quantification Limit

                PSD Particle Size Distribution

                QA Quality Assurance

                80607-1 REV1 30102017 PAGE VI

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                QC Quality Control

                RAIS Risk Assessment Information System

                RFQ Request for Quote

                REM Resource and Environmental Management

                RPD Relative Percentage Difference

                RSL Regional Screening Level

                SA EPA South Australian Environment Protection Authority

                SAQP Sampling and Analysis Quality Plan

                SOP Standard Operating Procedure

                SVOC Semi-Volatile Organic Compound

                SWL Standing Water Level

                SWMS Safe Work Method Statement

                111-TCA 111-trichloroethane

                TCE Trichloroethene

                TDS Total Dissolved Solids

                TRH Total Recoverable Hydrocarbons1

                TRV Toxicity Reference Value

                US EPA United Stated Environment Protection Agency

                USGS United States Geological Survey

                VC Vinyl Chloride

                VIRA Vapour Intrusion Risk Assessment

                VOC Volatile Organic Compound

                VOCC Volatile Organic Chlorinated Compound

                WHO World Health Organisation

                WMStrade Waterloo Membrane Samplertrade

                TRH = measurable amount of petroleum-based hydrocarbon (ie complex mixture of crude oil and natural gas (gt 250 compounds) including aromatics aliphatics paraffins unsaturated alkanes and naphthalenes) plus various other compounds including fatty acids esters humic acids phthalates and sterols

                80607-1 REV1 30102017 PAGE VII

                1

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                EXECUTIVE SUMMARY

                Background information

                An approximate 27 hectare mixed use area of Thebarton has been designated by the South Australian Environment Protection Authority (EPA) as the Thebarton EPA Assessment Area

                The former Austral sheet metal works (Austral) property located over multiple allotments between George and Maria Streets from the 1920s until the 1960s-1970s has been identified as a possible source of dissolved phase groundwater chlorinated hydrocarbon (CHC) contamination Groundwater CHC impacts within the uppermost (Quaternary ndash Q1) aquifer were identified as extending in a general north-westerly direction (consistent with regional groundwater flow direction) from the south-eastern portion of the Thebarton EPA Assessment Area and having resulted in the generation of soil vapour containing elevated concentrations of CHC

                The boundaries of the Thebarton EPA Assessment Area were established on the basis of the following

                the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street (part of the former Austral property) and 39 Smith Street (hydraulically down-gradient of the former Austral property) in Thebarton

                the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

                the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

                Key objectives

                The results of the recent investigations undertaken by Fyfe have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties within the Thebarton EPA Assessment Area

                The key objectives detailed by the EPA were to

                further delineate the chlorinated hydrocarbon contamination in groundwater

                further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

                undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

                80607-1 REV1 30102017 PAGE VIII

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                With respect to the VIRA the EPA requested that there be specific consideration of

                residential properties (slab on grade)

                residential properties (crawl space)

                residential properties (with basement) and

                trenchmaintenanceutility workers that may be working in the vicinity of the contamination

                Site conditions

                Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were identified within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m below ground level (BGL) during the drilling of groundwater well MW17 the latter consistent with the depth of groundwater within the Q1 aquifer

                Soil

                Groundwater within the Q1 aquifer is located at a depth of approximately 123 to Groundwater 159 m BGL and flows in a general north-westerly direction The closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred and the groundwater gradient is relatively flat (ie 000062 to 00012)

                Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified (based on factors such a groundwater salinity registered bore use and the locations of potential sensitive receptors) as including domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux) and possibly also potable

                Contaminants of Potential Concern (COPC)

                The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans-) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

                80607-1 REV1 30102017 PAGE IX

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Scope of work

                A groundwater and soil vapour monitoring program was undertaken by Fyfe across the Thebarton EPA Assessment Area between May and August 2017 It involved the following scope of work

                installation of a total of 41 WMStrade units to 1 m BGL in an approximate grid-pattern across the entire assessment area (Round 1) and at specific targeted locations (Round 2) followed by laboratory analysis of retrieved sample units for specific CHC

                drilling and installation of 25 groundwater wells to depths of between 15 and 19 m BGL including a background well to the east of the southern portion of the assessment area

                testing of 30 selected groundwater well drill core samples for geotechnical parameters

                gauging and sampling of the 25 newly installed groundwater wells as well as an existing well located in Admella Street followed by laboratory analysis of all samples for specific CHC and 10 selected samples for major cationsanions natural attenuation parameters and additional nutrients

                aquifer permeability (rising and falling head ldquoslugrdquo) testing of 10 groundwater wells

                drilling and installation of 13 soil vapour bores including 11 nested bores (ie to 1 and 3 m BGL) and two bores to 1 m BGL and

                sampling of all soil vapour bores followed by laboratory analysis of samples for specific CHC and general gases

                The soil vapour data were used to undertake a VIRA aimed at predicting indoor air concentrations of TCE under various land use and building construction scenarios In order to validate the results of the modelling which includes a number of conservative assumptions and is therefore expected to over-estimate potential risk the EPA has commissioned indoor air monitoring in a number of residential properties within the Thebarton EPA Assessment Area ndash the indoor air monitoring results will be reported under separate cover

                Groundwater fate and transport modelling was undertaken to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton EPA Assessment Area The provision of this information is aimed at supporting the definition (extent and geometry) of a potential future Groundwater Prohibition Area (GPA) to be designated by the EPA in accordance with the provisions of Section S103S of the Environment Protection Act 1993

                80607-1 REV1 30102017 PAGE X

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Identified impacts

                Contaminants identified in the Q1 aquifer beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down

                Groundwater

                (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested

                The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected (Austral) source site in accordance with the predominant flow direction associated with the Q1 aquifer The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) ndash whereas its north-western extent has not yet been determined the groundwater CHC plume has been delineated in all other directions

                Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion

                Soil vapour

                The soil vapour samples with the maximum TCE concentrations also had the highest PCE and 11-DCE concentrations (or elevated laboratory limits of reporting (LOR)) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-)

                Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE exceeded the adopted health investigation levels (HILs) for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE degradation has not yet resulted in its production

                Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

                80607-1 REV1 30102017 PAGE XI

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Assessment of risk

                Measured concentrations of TCE exceeded the adopted assessment criteria for potable use andor primary contact recreation in wells located on Admella Maria George Albert Chapel and Dew Streets as well as Light Terrace ndash with the highest concentrations corresponding to the ldquocorerdquo area of the plume One well on Albert Street also contained a concentration of carbon tetrachloride that exceeded the respective potable criterion

                Groundwater risks

                Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous

                Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

                The groundwater modelling undertaken by Arcadis involved the development of an Groundwater fate and transport initial groundwater flow model using MODFLOW followed by the development of a modelling site-specific (three-dimensional) solute transport model using the MT3DMS transport

                code

                The results of this modelling were interpreted to indicate the following

                although scattered detectable concentrations of 12-DCE have been measured in groundwater across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE daughter products indicate that substantial dechlorination is not occurring and

                the dissolved phase groundwater TCE plume is predicted to extend by another 500 m (ie beyond the boundaries of the current Thebarton EPA Assessment Area) over the next 100 years whereas no significant lateral plume expansion is expected

                The VIRA undertaken by Arcadis involved a two-tier assessment approach Whereas Vapour intrusion the Tier 1 screening risk assessment compared the measured soil vapour CHC concentrations to (modified) guideline values the Tier 2 risk assessment involved the application of the Johnson and Ettinger vapour intrusion model to predict indoor air CHC concentrations for residential (slab on grade crawl space and basement construction) and commercialindustrial (slab on grade construction) properties across the assessment area Site-specific geotechnical parameters and soil vapour data collected from 1 and 3 m BGL throughout the Thebarton EPA Assessment Area were used in the modelling It should be noted that overall the vapour modelling

                risks

                80607-1 REV1 30102017 PAGE XII

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

                The results of the VIRA with respect to the predicted indoor air concentrations of TCE within residential properties (assuming crawl space construction) versus adopted EPA response levels indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air that require further action as follows

                10 properties within the investigation range (2 to lt20 microgm3)

                eight properties within the intervention range (20 to lt200 microgm3) and

                three properties within accelerated intervention range (ge200 microgm3)

                All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises

                Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which is expected to be overly-conservative) ndash these results will be documented in a subsequent report

                Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie as determined for the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

                A qualitative assessment of potential risks to subsurface trenchmaintenanceutility workers indicated that exposure management may be required in areas where TCE concentrations at 1 m BGL are above 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific health and safety plan (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a photoionisation detector (PID) unit providing increased ventilation and using appropriate personal protective equipment (eg gas masks) as required

                80607-1 REV1 30102017 PAGE XIII

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Data gaps

                Based on the results obtained during the recent Fyfe investigations as well as available historical information the following data gaps have been identified for the Thebarton EPA Assessment Area

                property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

                groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

                the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

                the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

                Notes ie the interim soil vapour HILs adopted from the National Environment (Assessment of Site Contamination) Measure 1999 (as revised in 2013 ndash ie the ASC NEPM (1999)) but assuming a sub-slab to indoor air attenuation factor of 003 as compared to the value of 01 adopted by the ASC NEPM (1999)

                80607-1 REV1 30102017 PAGE XIV

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                1 INTRODUCTION

                11 Purpose

                Fyfe Pty Ltd (Fyfe) was commissioned by the South Australian Environment Protection Authority (SA EPA referred to herein as the EPA) to undertake Stage 1 groundwater and soil vapour investigation works groundwater fate and transport modelling and a human health vapour intrusion risk assessment (VIRA) within an EPA designated assessment area located within Thebarton South Australia (herein referred to as the Thebarton EPA Assessment Area) The location and extent of the Thebarton EPA Assessment Area referenced within this document is identified on Figure 1

                12 General background information

                Previous environmental assessment work undertaken since 1994 (as summarised in Appendix A) combined with historical information provided by the EPA (as included in Appendix B) indicates that the Thebarton EPA Assessment Area has been used for mixed residential and commercialindustrial purposes over time

                Groundwater impacts2 identified within the uppermost (Quaternary ndash Q1) aquifer in the vicinity of the former Austral sheet metal works (Austral) on George Street included both petroleum hydrocarbons (ie diesel fuel) as well as chlorinated hydrocarbon compounds (CHC) such as trichloroethene (TCE) and were first notified to the EPA in 2006

                Available historical information for the Austral property (ie the suspected source site) indicates that it operated from the 1920s until the 1960s-1970s and occupied an extensive area of Thebarton including

                part of the southern side of George Street extending from about half way between East Terrace3 and Admella Street (ie 11-25 George Street) to the west of Admella Street (ie 31-35 George Street)

                the entire northern side of Maria Street from East Terrace to the west of Admella Street

                part of the southern side of Maria Street (ie from 21 Maria Street) to Admella Street and

                25-27 East Terrace

                2 Note that the term ldquoimpactrdquo has been used by Fyfe to indicate identified concentrations of compounds (specifically chlorinated hydrocarbons) that are not naturally occurring (ie concentrations above background that have resulted from anthropogenic activities) The use of this term does not denote that the presence of these compounds represents a risk to either human health or the environment and the term ldquoimpactrdquo is therefore not directly interchangeable with the term ldquoSite Contaminationrdquo the latter defined under the Environment Protection Act 1993 to include actual or potential harm to human health andor the environment

                3 now James Congdon Drive

                80607-1 REV1 30102017 PAGE 1

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Historical newspaper articles described the Austral property as hosting a factory that extended over more than three acres and included an electroplating facility In 1938 it was described as the largest aluminium utensil manufacturing company in the southern hemisphere

                Other potential sources of groundwater contamination4 identified within the Thebarton EPA Assessment Area include a former gas works (ie located to the south and south-east of the Austral property and including the current Ice Arena property) a mechanicrsquos workshop another sheet metal working facility and a farm machinery manufacturer

                The Stage 1 assessment work described herein was commissioned by the EPA to determine whether historical contamination in the vicinity of George Street was presenting a risk to human health or the environment

                13 Definition of the assessment area

                As detailed on Figure 1 the current EPA Assessment Area covers an area of approximately 27 ha within the suburb of Thebarton located approximately 2 km north-west of the Adelaide central business district (CBD)

                The boundaries of the Thebarton EPA Assessment Area were established by the EPA on the basis of the following

                the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street and 39 Smith Street in Thebarton (refer to Appendix A)

                the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

                the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

                14 Identification of contaminants of potential concern

                The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

                Site Contamination is defined by the Environment Protection Act 1993 as existing if chemical substances are present on or below the surface of a site in concentrations above background the contaminants are there as a result of activity at the site or elsewhere and their presence has resulted in actual or potential harm (that is not trivial) to the health and safety of human beings taking into account current and proposed land uses or water or the environment

                PAGE 2 80607-1 REV1 30102017

                4

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                15 Objectives

                As defined by the EPA the key objectives of the recent Stage 1 environmental assessment program undertaken within the Thebarton EPA Assessment Area (refer to Figure 1) were to

                further delineate the chlorinated hydrocarbon contamination in groundwater

                further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

                undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

                With respect to the VIRA the EPA requested that there be specific consideration of

                residential properties (slab on grade)

                residential properties (crawl space)

                residential properties (with basement) and

                trenchmaintenanceutility workers that may be working in the vicinity of the contamination

                80607-1 REV1 30102017 PAGE 3

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                2 CHARACTERISATION OF THE ASSESSMENT AREA

                21 Site identification

                For the purpose of this investigation program the Thebarton EPA Assessment Area (as delineated in Figure 1) has been defined by the following roadways

                North northern verge of Smith Street

                South Maria Street (between Dew Street and Albert Street) portion of Parker Street (between Maria Street and Goodenough Street) and Goodenough Street (between Parker Street and James Congdon Drive)

                East western verge of Port Road and James Congdon Drive and

                West western verge of Dew Street

                22 Regional geology and hydrogeology

                221 Geology

                The Thebarton area is located within the Adelaide Plains approximately 8 km to the east of Gulf St Vincent and to the west of the Para Fault It lies within the Golden Grove ndash Adelaide Embayment area of the St Vincent Basin which consists of a succession of Tertiary and Quaternary age sediments (with thicknesses of up to 600 m) overlying basement rocks

                The 1250000 Adelaide geological map (SA Department of Mines and Energy 1969) indicates that the near-surface geology of the area consists primarily of Quaternary aged soils and sediments including the Pooraka and Hindmarsh Clay formations The Pleistocene aged Pooraka Formation generally comprises a thickness of approximately 10 m and is of alluvial origin comprising sandy clays and clayey to sandy silts interbedded with layers of clay sand andor gravel The underlying Pleistocene aged Hindmarsh Clay Formation represents the basal unit of the Adelaide Plains and has a maximum general thickness of more than 100 m It generally comprises a basal gravel layer a middle layer of mottled medium to high plasticity (red-brown yellow brown greygreen to orange) often stiff to hard clays and an upper layer of fluvial and alluvial red-brown silty sand Gerges (1999) describes Hindmarsh Clay as comprising a mottled brown to pale olive grey predominantly clay formation that becomes green grey towards the basal section (approximately 16 to 20 m below ground level (BGL)) and is characterised by an increasing gravel content with depth

                Underlying the Hindmarsh Clay are sands and limestone of Tertiary age which are in turn underlain by metamorphosed basement rock of the Proterozoic Umberatana Group

                80607-1 REV1 30102017 PAGE 5

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                222 Hydrogeology

                According to Gerges (2006) the aquifers identified within the Quaternary aged sediments of the Adelaide Plains are typically found within the coarser interbedded silt sand and gravel layers of the Hindmarsh Clay Formation and vary greatly in thickness (typically from 1 to 18 m) lithology and hydraulic conductivity Confining beds between the Quaternary aquifers consist of clay and silt layers and range in thickness from 1 to 20 m These confining beds vary in terms of the amount of coarser grained material they contain their bulk hydraulic conductivity andor the presence and density of fractures In addition their absence in some areas allows direct hydraulic connection between the aquifers

                The Thebarton area is located within Hydrogeological Zone 3 (Subzone 3E) of Gerges (2006) This zone contains five to six Quaternary aquifers and three to four almost flat-lying Tertiary aquifers The first Tertiary aquifer estimated by Gerges (2006) to be intersected at a depth of approximately 130 m BGL near the Para Fault is most frequently accessed for industrial and recreational groundwater use

                The Q1 aquifer assessed as part of the current investigations is typically located at depths of between 3 and 10 m BGL beneath the Adelaide Plains with an average thickness of 2 m The Q1 aquifer contains water of variable salinity with Subzone 3E including a range of 500 to 3500 mgL total dissolved solids (TDS) The gradient of the Q1 aquifer is generally flat (particularly to the west of the Para Fault) and flow direction is typically towards the north-west

                A search of the registered bore database maintained by the Department of Environment Water and Natural Resources (DEWNR (2017) WaterConnect database) identified 59 bores within the general Thebarton area of which 18 are located in the Thebarton EPA Assessment Area Although eight bores were installed for monitoring purposes on or immediately adjacent to the property located at 31-37 George Street (ie part of the former Austral facility) it is understood that only one bore (6628-21951 ndash located within the Admella Street roadway intersecting the Q1 aquifer and identified as MW01 in Appendix A but MW02 by Fyfe5) remains in situ

                In addition to numerous monitoringinvestigationobservation bores the Q1 aquifer within the general (ie broader) Thebarton area is recorded in the DEWNR (2017) database as being accessed for drainage domestic and industrial purposes

                DEWNR (2017) information for registered bores located within the general Thebarton area is included in Appendix C whereas information for bores located within the Thebarton EPA Assessment Area (excluding those associated with the property at 31-37 George Street and installed solely for monitoring purposes6) is summarised in Table 21

                5 This existing groundwater well was identified as MW02 by Fyfe in accordance with the markings on the gatic cover and the DEWNR (2017) WaterConnect bore identification details although it was originally installed as MW01 by REM (refer to discussion of previous reports in Appendix A)

                6 ie 6628-21951 6628-21952 6628-22229 to 6628-22233 and 6628-22236

                PAGE 6 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area

                Bore ID Location Purpose Status Maximu SWL Salinity Yield Aquifer m well (m (mgL (Lsec

                Tertiary (T1)

                depth BGL) TDS) ) (m BGL)

                125 6628-516 Coca Cola plant Rehabilitated 138 1963 794

                6628-1435 Coca Cola plant Backfilled 184 212 921 392 Tertiary (T1)

                6628-4576 Corner of Admella amp Chapel Streets

                125 1454 445 Tertiary (T1)

                6628-7724 Coca Cola plant Observation 155 2017 1272 1516 Tertiary (T1)

                6628-7725 Coca Cola plant Observation 127 3016 1100 1005 Tertiary (T1)

                6628-12516 Coca Cola plant Industrial Backfilled 210 212 1300 1875 Tertiary (T1)

                6628-20663 39 Smith Street Irrigation 121 1105 50 Tertiary (T1)

                6628-20969 39 Smith Street Industrial 30 14 1535 25 Quaternary (Q1)

                6628shy21951

                Admella Street 20 Quaternary (Q1)

                6628-22395 21 James Congdon Drive

                20 157 1541 05 Quaternary

                6628-23525 41 Maria Street 206 273 1078 10 Tertiary (T1)

                Notes Shading indicates that information was not recorded in the database as interpreted from information provided in the database ndash approximate only in some instances

                ie MW02 as included in the groundwater monitoring program of Fyfe ndash refer to Table 31 Abbreviations BGL = below ground level SWL = standing water level TDS = total dissolved solids

                23 Data quality objectives

                The Data Quality Objective (DQO) process as described in Australian Standard AS44821-2005 and the National Environment Protection (Assessment of Site Contamination) Measure (ASC NEPM 1999)7

                Schedule B2 Guideline on Data Collection Sample Design and Reporting and more fully documented in the NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme involves a seven-step iterative approach that was initially developed by the United States Environment Protection Agency (US EPA) to facilitate the systematic planning and verification of contaminated sites assessment projects

                As stated in Schedule B2 of the ASC NEPM (1999) the first six steps of the DQO process comprise the development of qualitative and quantitative statements that define the objectives of the site assessment program and the quantity and quality of data needed to inform risk-based decisions These steps enable the

                All references to the ASC NEPM (1999) refer to the version amended on 16 May 2013

                80607-1 REV1 30102017 PAGE 7

                7

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                project team to communicate the goals decisions constraints (eg time budget) and uncertainties associated with the project and detail how they are to be addressed The seventh step comprises the development of a Sampling and Analysis Quality Plan (SAQP) to generate the data required to adequately characterise site contamination issues and assess their associated potential environmental and human health risks under the proposed land use scenario

                The DQOs defined for the Thebarton EPA Assessment Area are summarised in Table 22

                Table 22 Data Quality Objectives

                Objective Comment

                Step 1 ndash Statement of the Problem According to information provided to Fyfe by the EPA (as summarised in Appendix A) a property located at 31-37 George Street (immediately west of Admella Street) in Thebarton and historically occupied by part of the Austral facility had been found to be underlain by groundwater CHC (primarily TCE) impacts More recent reporting to the EPA for a property at 39 Smith Street located approximately 350 m north-west (and hydraulically down-gradient) of the George Street property indicated that detectable CHC (predominantly TCE) were also present within groundwater Since this area of Thebarton is occupied by a mixture of commercialindustrial and residential properties and the source and extent of the CHC impacts within the Q1 aquifer had not yet been determined potential risks to human health andor the environment had yet to be assessed

                Step 2 ndash The Decision that Needs The assessment works commissioned by the EPA were necessitated to to Result from the Investigation investigate the source extent and magnitude of the groundwater CHC

                contamination beneath a designated area of Thebarton (ie that included both the George Street and Smith Street properties) and to understand the possible risk to public health from potential vapour generation Fyfe have therefore undertaken vapour modelling and intrusion risk assessment works aimed at evaluating whether concentrations of identified groundwater andor soil vapour contaminants pose an unacceptable risk to human health In addition groundwater fate and transport modelling has been undertaken to predict the extent of the plume This will assist the EPA to determine a potential future Groundwater Prohibition Area (GPA) in accordance with the provisions of Section 103S of the Environment Protection Act 1993

                Step 3 ndash Inputs to the Decision The information that was required to resolve the decision statement included the collection of physical and chemical data from across the Thebarton EPA Assessment Area The collected data as well as physical observations regarding the geology of the area and possible preferential contaminant pathways was used to determine potential risks to human health via groundwater fate and transport and vapour intrusion modelling

                Step 4 ndash Boundaries of the Investigation

                The lateral boundaries of the Thebarton EPA Assessment Area are as defined in Sections 13 and 21 as depicted on Figure 1 Vertically the investigations extended as far as the maximum drilled depth (19 m BGL)

                Step 5 ndash Decision Rules The decision rule will be based upon the identification of predicted indoor air concentrations of CHC compounds associated with groundwater andor soil vapour impacts which exceed adopted response levels

                PAGE 8 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Objective Comment

                Step 6 ndash Decision Error Tolerances The purpose of establishing decision error tolerance is to control the acceptable degree of uncertainty upon which decisions are made in order to avoid the making of an incorrect decision and to enable identification of additional investigation monitoring or remediation activities required on the basis of accurate data for the protection of human health and the environment The Measuring Quality Objectives (MQO) include the quality assurance (QA) activities that were conducted during the assessment the quality control (QC) acceptance criteria applicable to the assessment and the adopted Data Quality Indicators (DQIs) as follows (and further discussed in Section 5) completeness ndash a measure of the amount of useable data from a data

                collection activity comparability ndash the confidence (expressed qualitatively) that data may be

                considered to be equivalent for each sampling and analytical event representativeness ndash the confidence (expressed qualitatively) that data

                are representative of each media present on the site precision ndash a quantitative measure of the variability (or reproducibility) of

                data and accuracy (bias) ndash a quantitative measure of the closeness of reported data

                to the true value

                Step 7 ndash Optimisation of the Data collection was undertaken in general accordance with the Sample Collection Design methodologies outlined in the relevant documentsguidelines referenced

                throughout this report As determined by the EPA the data collection design included targeted sampling to investigate and delineate areas of potential groundwater and soil vapour contamination and to assess potential associated human health risks

                80607-1 REV1 30102017 PAGE 9

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                3 SCOPE OF WORK

                The scope of work undertaken by Fyfe was generally consistent with that requested within the original EPA request for quote (RFQ) dated 27 March 2017 Some modifications to the original workscope occurred based on site findings and additional site information was collected where required and as agreed with the EPA in order to achieve the EPArsquos project objectives outlined in Section 15

                As identified in the RFQ the scope of work was designed to

                provide an initial delineation of CHC impacts in soil vapour through the deployment of Waterloo Membrane Samplers (WMStrade) as a screening tool

                further delineate the previously identified CHC impacts in groundwater

                decide based on the results of the WMStrade and groundwater results the need for the number of and the locations of permanent soil vapour monitoring bores

                identify the nature extent and potential source area(s) of the identified CHC impacts in groundwater andor soil vapour

                determine the likely fate and transport of the groundwater CHC plume to support the establishment of a potential future GPA

                determine the potential human health (including vapour intrusion) risk(s) on the basis of the data collected and

                ascertain whether or not a public health risk exists within the Thebarton EPA Assessment Area

                The scope of work is further detailed in Section 32 Variations from the scope of work originally requested in the EPA RFQ were agreed with the EPA during the course of the project and included the following

                deployment of an additional four WMStrade units ndash ie 41 in total as compared to the original allowance of 37

                installation (and sampling) of an additional six nested soil vapour bores (to depths of 1 and 3 m BGL) ndash ie 11 in total as compared to the original allowance of five

                installation (and sampling) two individually located (ie as opposed to the nested locations) soil vapour bores to a depth of 1 m BGL ndash ie as compared to the original allowance of 10

                installation (and sampling) of 25 groundwater monitoring wells ndash ie as compared to the original allowance of 20 and

                sampling of an existing well in Admella Street (MW02) ndash ie not included in the original EPA scope

                80607-1 REV1 30102017 PAGE 11

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                31 Preliminary work

                Preliminary work involved the following

                review and summation of all available historical reports (as supplied by the EPA) ndash refer to Appendix A

                development of a preliminary (working) conceptual site model (CSM) based on a review of the historical data

                preparation of a detailed health and safety plan covering all aspects and stages of the work and

                detailed planning with key stakeholders prior to the execution of the field investigation program

                32 Field investigation and laboratory analysis program

                The scope of the field investigation program undertaken by Fyfe between 31 May and 28 August 2017 is summarised in Table 31 whereas the scope of the laboratory testing program is summarised in Table 32

                A plan showing the various assessment point locations is included as Figure 2

                Table 31 Scope of field investigation program ndash May to August 2017

                Scope Item Description of works Date of works

                Passive soil vapour sampling ndash Round 1

                Thirty-seven WMStrade units identified as WMS 1 to WMS 37 were installed within the soil profile to 1 m BGL at scattered (approximately grid-like) locations across the Thebarton EPA Assessment Area

                31 May and 1 to 2 June

                The WMStrade units were extracted and forwarded to the analytical laboratory 7 June

                Soil bores were located using a hand-held global positioning system (GPS) unit before being backfilled with (drillerrsquos) sand

                7 August

                Monitoring well drilling and installation

                Individual groundwater well permits were obtained from DEWNR prior to well installation ndash copies of the well permits are included in Appendix D Groundwater monitoring wells (MW1 MW3 and MW5 to MW26) were installed to depths of between 15 and 19 m BGL at 24 locations across the Thebarton EPA Assessment Area Background well MW4 was installed to 19 m BGL within a public recreational area located across James Congdon Drive to the east (ie near the south-eastern corner of the Thebarton EPA Assessment Area) All 25 newly installed wells were developed following installation

                28 to 30 June 3 to 7 July and 10 to 14 July

                Geotechnical soil testing

                Intact soil cores collected during the drilling of 10 groundwater wells (MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25) were forwarded to the analytical laboratory for geotechnical testing

                Groundwater gauging

                All 25 newly installed monitoring wells (MW1 and MW3 to MW26) as well as the existing Admella Street well (MW02) were gauged to assess total well depth standing water level (SWL) and the presenceabsence of non aqueous phase liquid (NAPL) This was undertaken as a discrete event prior to the commencement of groundwater sampling

                18 July

                PAGE 12 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Scope Item Description of works Date of works

                Groundwater sampling

                All 26 existing and newly installed wells were sampled using a combination of low flow (micropurge) and HydraSleevetrade sampling techniques (as recorded on the field sampling sheets in Appendix E) ndash samples were forwarded to the analytical laboratories

                18 to 21 and 24 to 25 July

                Aquifer testing Aquifer permeability (slug) testing was undertaken on 10 wells (MW02 MW3 MW7 MW14 MW17 MW20 MW21 MW23 MW25 and MW26) Data was subsequently evaluated by Arcadis Pty Ltd (Arcadis) to estimate the hydraulic conductivity of the aquifer beneath the Thebarton EPA Assessment Area (refer to Section 732)

                28 July

                Soil vapour bore drilling and installation

                Following the receipt of the groundwater data 11 nested soil vapour bores (SV1 to SV10 and SV12) were installed to a depth of 1 and 3 m BGL at selected locations within the Thebarton EPA Assessment Area Two additional soil vapour bores (SV11 and SV13) were installed to a depth of 1 m BGL

                18 21 and 22 August

                Active soil vapour sampling

                Sampling of soil vapour bores was undertaken using summa canister (TO-15) sample collection methods Vapour (canister) and general gas (Tedlar bag) samples were extracted from all 13 locations (ie SV1 to SV13) including the 11 nested bores

                24 August

                Passive soil vapour sampling ndash Round 2

                Following the receipt of the groundwater data and for the purposes of comparison with the soil vapour bore data an additional four WMStrade units (WMS 38 to WMS 41) were installed within the soil profile to 1 m BGL at targeted locations across the Thebarton EPA Assessment Area (ie within approximately 1 m of soil vapour bores SV2 SV4 SV5 and SV7) Soil bores were located using a hand-held GPS unit

                18 August

                The WMStrade units were extracted and forwarded to the analytical laboratory and the soil bores were backfilled with (drillerrsquos) sand

                24 August

                Surveying The locations of all soil vapour bores and groundwater wells were surveyed by a licensed surveyor relative to the Map Grid of Australia (MGA) 1994 and the top of each bore was surveyed relative to Australian Height Datum (AHD) The survey data are included in Appendix F

                22 July and 28 August

                Notes as determined by the EPA

                Table 32 Scope of laboratory testing program

                Scope Item Description of works

                Soil geotechnical testing

                Soil samples from each of three depths within core samples collected during the drilling of groundwater wells MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25 were analysed for particle size distribution (PSD) moisture content including degree of saturation bulk density dry density and specific gravity void ratio and porosity

                80607-1 REV1 30102017 PAGE 13

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Scope Item Description of works

                Groundwater testing Groundwater samples from all 26 wells were analysed for the COPC detailed in Section 14 As requested by the EPA groundwater samples from selected wells (MW02 MW5 MW8 MW9 MW12 MW17 MW21 MW22 MW23 and MW26) were also analysed for the following major cations and anions (calcium magnesium sodium potassium chloride and alkalinity)

                and natural attenuation parameters (carbon dioxide (CO2) sulfate iron manganese nitrate) Additional components reported by the analytical laboratory included nitrite and nitrate + nitrite

                Soil vapour testing The WMStrade units deployed during each of Rounds 1 and 2 were analysed for the COPC detailed in Section 14 The soil vapour (summa canister) samples were analysed for the COPC detailed in Section 14 as well as 2-propanol and general gases (helium hydrogen oxygen nitrogen methane carbon dioxide ethane propane butane iso-butane pentane iso-pentane hexane argon carbon monoxide and ethylene)

                Notes Specific sample depths are detailed in the relevant laboratory reports in Appendix G also known as isopropyl alcohol isopropanol or IPA

                33 Data interpretation

                Following the receipt and collation of the field and laboratory data hydrogeological (fate and transport) and VIRA modelling (refer to Sections 8 and 9 respectively) were undertaken to enable an assessment of risk and to refine the CSM (Section 10)

                PAGE 14 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                4 METHODOLOGY

                41 Field methodologies

                Prior to the commencement of the field investigations a site specific Health and Safety Plan (HSP) including Safe Work Method Statements (SWMS) and a Job Hazard Analysis (JHA) was prepared ndash all personnel working at the site were required to read understand sign and conform to the HSP

                Each proposed drilling location was cleared of underground services by a professional service location company (Pipeline Technologies) using conventional (electronic) service detection methods as well as ground penetrating radar (GPR) Where underground or overhead services were present andor deemed to be a potential safety risk during drilling activities the drill location was moved to an area considered by the Fyfe representative and service locator to be safe All changes to drilling locations were notified to EPA and recorded on a site plan for future reference

                Given that works were undertaken within suburban streets Fyfe employed the services of a qualified traffic management company (Altus Traffic) during drilling activities in order to ensure safety for pedestrians and road users minimal disruption to traffic flow and the provision of a safe working environment

                Field methodologies as detailed in Table 41 were undertaken in accordance with Fyfersquos standard operating procedures (SOPs) Relevant field sampling sheets are included in Appendices F (groundwater) and G (soil vapour ndash combined field sampling sheets and chain of custody (COC) documents) and borehole log reports are presented in Appendices H (groundwater) I (WMStrade) and J (soil vapour)

                Table 41 Summary of field methodologies

                Activity Details

                Passive soil bore sampling The soil bores used to deploy the WMStrade units were hand augered by personnel from Fyfe and Aussie Probe to a depth of 1 m BGL SGS Australia (SGS) personnel suspended each WMStrade unit into its respective borehole from a string The hole was then sealed with an expandable foam plug inside a polyethylene sleeve and the string suspending the sampler was connected to a temporary plastic cap at the ground surface The Round 1 WMStrade units were deployed for periods of between six and seven days whereas the Round 2 WMStrade units were all deployed for six days Following retrieval by SGS each WMStrade unit was placed into a sealed glass vial and a labelled foil bag The WMStrade units did not require chilling during transport to the analytical laboratory Borehole log reports are included in Appendix I whereas combined field sampling sheets and COC documents are presented in Appendix G

                80607-1 REV1 30102017 PAGE 15

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Activity Details

                Groundwater well Groundwater wells were drilled by WB Drilling using a combination of hand augering installation mechanical pushtube and solid auger techniques

                Following the completion of drilling each borehole was fitted with 50 mm class 18 uPVC casing with a basal 6 m long section of slotted well screen A filter pack comprising clean graded sands of suitable size to provide sufficient inflow of groundwater was installed within the annular space between the borehole and the well casing and extended from the base of the screened interval to approximately 1 m above the termination of the slotted casing A 1 m long bentonite collar comprising pelleted or granulated bentonite was placed above the filter pack to prevent water seepage downward along the well casing or borehole from ground surface Each well was grouted up to surface level and fitted with a (lockable) steel gatic cover the latter flush mounted to prevent tripping andor other hazards Groundwater well log reports are included in Appendix H

                Soil logging and Soil logging was undertaken in general accordance with the ASC NEPM (1999) which geotechnical sampling endorses AS1726-1993 In addition to the requirements of AS1726-1993 particular

                attention was paid during logging to any lithological variations such as sandgravel lenses or secondary porosity (such as clay fracturing) which may act as potential preferential pathways for contaminant vapourgroundwater migration through the sub-surface as well as the presence of fill material andor any olfactory or visual evidence of contamination Soil descriptions have been included on the logs in Appendices H to J Cores for geotechnical analysis were collected using push tube sampling methodologies to obtain undisturbed samples Section(s) of core to be tested were retained (intact) within the pushtube liners and capped at each end for storage and transport to the analytical laboratory

                Field screening of soils Field screening of individual soil layers was undertaken at the majority of the drilling locations and involved the use of a photoionisation (PID) unit fitted with an 117 eV lamp (ie as considered suitable for the detection of CHC) The PID unit was calibrated by the hire company prior to delivery and was checked on a daily basis against an isobutylene calibration gas of known concentration Field screen samples were collected with care to ensure that each sample was representative of the soil stratum from which it was collected and experienced minimal loss of volatile compounds The soil material was placed immediately into a zip lock bag and sealed ensuring the bag was half filled (ie such that the volume ratio of soil to air was equal) Soil clumps within the bag were manually broken up and the bag was left to rest for a minimum of five minutes but no longer than 20 minutes Prior to testing the bag was shaken vigorously to release any vapours within the soil To test the tip of the PID probe was inserted into the bag and the maximum volatile organic compound (VOC) reading recorded after a nominal 10 second period or when the reading had peaked Results were recorded on the appropriate bore log sheets presented in Appendices H to J

                Groundwater well Following installation the wells were developed by purging a minimum of four well development volumes (ie until stable parameters were obtained andor until the well purged dry) from

                the casing with a steel bailer andor twister pump to ensure hydraulic connectivity with the aquifer formation

                Groundwater gauging Groundwater levels in the newly installed and existing monitoring wells located across the Thebarton EPA Assessment Area were gauged using an interface probe prior to the commencement of the groundwater sampling program All monitoring wells were gauged for SWL the potential presence of NAPL and the total well depth Groundwater field gauging results are presented in Appendix E

                PAGE 16 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Activity Details

                Groundwater sampling The majority of the wells were sampled using low flow (micropurge) techniques Where recovery was particularly low (ie MW4 MW8 MW15 MW18 MW19 and MW24) and unsuitable for low flow (micropurge) sampling the original sampling technique was abandoned and a HydraSleeveTM (no purge) methodology was used instead Groundwater samples were collected in laboratory-supplied screw top bottles containing appropriate preservative (if required) with no headspace allowed Samples were chilled during storage and transport to the analytical laboratory Disposable nitrile gloves worn by field personnel were changed prior to the collection of each sample Samples for metals (ie iron manganese) analysis were filtered in the field using 045 microm filters Groundwater field sampling sheets are presented in Appendix E

                Low Flow Methodology The low flow sampling technique involved the following the pump was placed close to the bottom of the screened interval the flow rate (up to 05 Lmin) was regulated to maintain an acceptable level of

                drawdown with minimal fluctuation of the dynamic water level during pumping and sampling

                groundwater drawdown was monitored constantly during purging and sampling using an interface probe

                water quality parameters were considered to have stabilised when the following ranges were recorded over three consecutive readings ndash electrical conductivity plusmn 5 ndash pH plusmn 01 ndash temperature plusmn 02degC ndash dissolved oxygen plusmn 10 ndash redox potential plusmn 10 mV

                the stabilisation parameters were recorded on field logging sheets after every one litre of groundwater purged using a calibrated water quality meter and a flow cell suspended in a bucket with litre intervals marked and

                samples were collected once three consecutive stabilisation parameters were recorded and a volume of between 28 and 6 litres was purged prior to sampling

                HydraSleeveTM Methodology The HydraSleeveTM sampling technique involved attaching a stainless steel weight to the bottom and a wire tether clip to the throat of the HydraSleeveTM before lowering it into the water column to the desired depth and allowing it to fill with groundwater After a minimum period of 24 hours the HydraSleeveTM was quickly and smoothly withdrawn from the well and the contents were transferred into the sample containers Water quality parameters were measured after samples were decanted ndash either within the water remaining in the HydraSleeveTM or within a grab sample collected using a disposable bailer

                Hydraulic testing Rising and falling head permeability (ldquoslugrdquo) tests were undertaken to estimate the hydraulic conductivity (K) of the aquifer within various parts of the Thebarton EPA Assessment Area The falling-head tests were initiated by quickly inserting a 1285 m long and 36 mm diameter solid PVC cylinder (slug) into the water column at each well to produce a sufficient sudden rise in the water level The subsequent ldquofallrdquo back to the static water level (recovery) was measured and recorded automatically and in real-time using a

                80607-1 REV1 30102017 PAGE 17

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Activity Details

                pressure transducerdata logger programmed to record water levels at a one second interval After static water level conditions returned in the well the rising-head test was initiated by quickly removing the slug from the well to create a sudden drop in the water column height As with the falling-head test the rise of the water level back to a static condition (recovery) was automatically recorded

                Soil vapour bore Soil vapour bores were drilled by Aussie Probe using a combination of hand augering and installation mechanical pushtube techniques

                Within each 3 m deep soil vapour bore teflon tubing attached to a soil vapour probe was inserted to the base of the hole which had been prefilled with approximately 005 m of clean filter pack sand An additional 045 m of sand (ie approximately 05 m in total) was then added to the hole and topped by a bentonite plug seal of approximately 05 m thickness A second soil vapour probe was installed at a depth of about 1 m within a 05 m sand pack which was overlain by bentonite to a depth of about 02 to 03 m BGL The two 1 m deep soil vapour bores were installed in a similar manner with a sand pack extending from the base to about 05 to 06 m BGL overlain by a bentonite plug to 03 m BGL Each installation was completed with grout to surface and topped with a standard flush-mounted gatic cover Soil vapour bore log reports are included in Appendix J

                Soil vapour sampling All soil vapour sampling works were undertaken by SGS using suitably trained and experienced personnel ndash SGS holds National Association of Testing Authorities (NATA) accreditation for all soil vapour sampling and laboratory analytical works Combined field sampling sheets and COC documents are presented in Appendix G Soil vapour samples were collected using summa canisters and analysed using the US EPA (1999) TO-15 method Sampling involved the connection of a passivated 1 L stainless steel canister to the teflon tubing extending from the soil vapour probe and the use of a soil gas sampling train to restrict flow to a maximum rate of 200 mLmin Canister vacuum pressure was monitored during sampling to enable calculation of the volume of sample drawn into the canister ndash the small amount of vacuum left in the canister at the end of the sampling procedure was measured in the laboratory to check if any leaks occurred during transit (refer to further discussion in Table 52) A shroud was set up around the sampling point and tracer chemicals were introduced at high concentrations by flooding the shroud with helium and placing a cloth soaked with IPA into the shroud Each canister was cleaned and certified by SGS prior to use (refer to Appendix G) and backshyup coconut shell carbon sorbent tube samples were also collected (but not analysed) Summa canisters did not require chilling during transport to the analytical laboratory

                Waste disposal Waste water and surplus soil corescuttings were stored together within 205 litre drums in the rear car park of a commercialindustrial property at 19-21 James Congdon Drive (as organised by the EPA) prior to removaldisposal by a licensed waste removal company (Cleanaway) Analytical results pertaining to the soils were forwarded to the licensed receiving facility and all of the soil was classified as lsquoWaste Fillrsquo in accordance with the Environment Protection Regulations 2009 The waste transport certificates are included in Appendix K

                PAGE 18 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                42 Laboratory analysis

                The following laboratories were used for the analysis of the environmental samples

                complete soil cores for geotechnical sample analysis were forwarded to SMS Geotechnical

                primary groundwater samples collected by Fyfe were analysed at the SGS laboratory whereas secondary groundwater samples were forwarded to EurofinsMGT and

                soil vapour (including WMStrade) samples collected by SGS were analysed at their laboratory

                80607-1 REV1 30102017 PAGE 19

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                5 QUALITY ASSURANCE AND QUALITY CONTROL

                Data quality is typically discussed in terms of the DQIs presented in Table 22 ndash ie completeness comparability representativeness precision and accuracy In order to assess the quality of the data collected during the Fyfe investigation program against these DQIs specific QAQC procedures were implemented during both the field sampling and laboratory analysis programs as detailed in the following sections

                51 Field QAQC

                Field QA procedures undertaken during the recent investigations included the collection of the following QC samples aimed at assessing possible errors associated with cross contamination as well as inconsistencies in sampling andor laboratory analytical techniques

                intra-laboratory duplicate (duplicate) samples submitted to the same (primary laboratory) to assess variation in analyte concentrations between samples collected from the same sampling point andor the repeatability (precision) of the analytical procedures

                inter-laboratory duplicate (split or triplicate) samples submitted to a second laboratory to check on the analytical proficiency (accuracy) of the results produced by the primary laboratory

                equipment rinsate blank samples collected during groundwater sampling only and used to assess cross-contamination that may have occurred from sampling equipment during sampling and

                trip blank samples used to assess whether cross-contamination may have occurred between samples during transport

                Whereas analyte concentrations within the rinsate and trip blank samples should be below the laboratory limit of reporting (LOR) the inter- and intra-laboratory duplicate sample results are assessed via the calculation of a relative percentage difference (RPD) as follows

                (Concentration 1 minus Concentration 2) x 100RPD = (Concentration 1 + Concentration 2) 2

                Maximum RPDs of 30 (inorganics) and 50 (organics) are generally considered acceptable with higher RPD values often recorded where concentrations of an analyte approach the laboratory LOR

                All field QC sample results are included in the summary data tables in Appendix L

                511 Groundwater

                Table 51 presents conformance to field QAQC procedures undertaken as part of the groundwater investigations

                80607-1 REV1 30102017 PAGE 21

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Table 51 Field QAQC procedures ndash Groundwater

                QAQC Item Detail

                Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) AustralianNew Zealand standards ASNZS 566711998 and ASNZS 5667111998 SA EPA (2007) and Fyfe SOPs Details are provided in Table 41

                Calibration of field equipment

                Documentation regarding the calibration of field equipment is included in Appendix M

                Decontamination of All disposable equipment (tubing pump bladders plastic bailers bailer cord and equipment HydraSleeveTM units) were replaced between wells Re-usable equipment (micropurge pump

                interface probe and HydraSleeveTM weights) was decontaminated between sampling locations using potable water and Decon 90trade phosphate free detergent

                Sample preservation and storage

                Samples were kept in laboratory supplied containers in a portable chilled insulated box (esky) prior to and during transport to the laboratory

                Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

                Duplicate samples Two intra-laboratory and two inter-laboratory duplicate samples were analysed for CHC with respect to 26 primary groundwater samples ndash thereby constituting an overall ratio of approximately one duplicate per 65 primary samples (or 15) compared to a generally acceptable ratio of 110 samples (or 10) One intra-laboratory and one inter-laboratory duplicate sample were analysed for the remaining parameters with respect to 10 primary groundwater samples ndash thereby constituting an overall ratio of one duplicate per five primary samples (or 20) compared to a generally acceptable ratio of 110 samples (or 10) Intra- and inter-laboratory duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within the acceptable range with the exception of the following intra-laboratory duplicate sample pair MW9QW1 TCE (67) nitrate (147) and inter-laboratory duplicate sample pair MW9QW2 total CO2 (59) iron (190)

                manganese (183) potassium (64) nitrate (194) The elevated RPD for TCE in the intra-laboratory duplicate sample pair is considered to be related to the low concentration detected and does not alter the interpretation of the data The other RPD exceedances are not considered significant (ie in terms of overall data interpretation) as they were not obtained for identified COPC (as defined in Section 14)

                Rinsate blank samples Six equipment rinsate blank samples (one for each day of sampling) were collected from either the pump housing or a new HydraSleevetrade (final day of sampling only) and analysed for CHC to confirm the effectiveness of the decontamination procedures and the cleanliness of disposable equipment The analytical results obtained for the rinsate blank samples were all below the laboratory LOR thereby indicating that decontamination practices during the groundwater sampling program were acceptable and that no contamination was introduced by the use of the HydraSleevestrade

                Trip blank samples Six trip blank samples were included within containers (eskies) of sample bottles provided by the analytical laboratory and returned to the analytical laboratory All of the trip blank samples were analysed for CHC With the exception of TB187 which contained 1 microgL TCE the analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was limited impact on sample quality during storage or transport of the samples to the analytical laboratory

                PAGE 22 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Notes No duplicate QC samples were collected during the use of the HydraSleeveTM sampling technique as detailed in ANZECCARMCANZ (2000a) at least 5 (ie 120) duplicate samples should be analysed ndash the generally accepted industry standard however is 10 (110) including 5 intra-laboratory and 5 inter-laboratory duplicates

                512 Soil vapour

                Tables 52 presents conformance to field QAQC procedures undertaken as part of the soil vapour (passive and active) investigations

                Table 52 Field QAQC procedures ndash Soil vapour

                QAQC Item Detail

                Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) as well as ASTM (2001 2006) ITRC (2007) CRC CARE (2013) guidance and Fyfe SOPs Details are included in Table 41 and Appendix G (ie SGS sampling methodology sheet) During the use of summa canisters to sample the soil vapour bores leak testing was undertaken (as described in Table 41) Although small leaks or ambient drawdown appear to have occurred with respect to samples SV11_10m (003 helium) SV13_10m (003 helium) and SV1_10m (360 microgm3 IPA) ITRC (2007) and NJDEP (2013) state that ge 5 helium andor gt10 mgm3 IPA are required to be indicative of a significant leak or substantial ambient drawdown Given that the leaks were relatively small (ie 06 (helium) and 36 (IPA) of the levels considered indicative of a significant leak) the data from these bores were still considered to be valid ndash refer to SGS correspondence in Appendix G As detailed in Table 41 a small amount of vacuum was generally left in each summa canister at the end of the sampling procedure and was measured in the laboratory to check if any leaks had occurred during transit However samples SV11_10m SV12_30m as well as the helium blank were recorded as having zero vacuum upon receipt at the analytical laboratory A query lodged with SGS regarding this issue indicated that whereas the helium blank comprised a grab sample collected into a Tedlar bag directly from the helium cylinder (ie without the use of a gauge) the canisters used for samples SV11_10m and SV12_30 were filled during sampling so that there was no remaining vacuum ndash refer to field sampling documentation in Appendix G SGS stated that although it is good practice to have a small amount of vacuum remaining in a canister at the completion of sampling appropriate additional QC measures were employed and the absence of other common background VOCs (eg petroleum hydrocarbons) upon sample testing indicated that leakage had not occurred during transit In addition all canisters are fitted with quick connect one-way valves that are closed upon removal from the sampling train and canistersfittings are leak checked prior to leaving the laboratory and again in the field to ensure that they are leak free Refer to SGS correspondence in Appendix G The presence of detectable IPA (120 microgm3) and TCE (48 microgm3) in the helium blank was also queried with SGS who stated that this (ie variability in the quality of the high purity helium gas used) is not an uncommon occurrence The reason for collecting a helium blank sample is to identify any impurities present in the helium gas so that if a leak does occur during sampling it is possible to determine whether any target compounds could be introduced into the sample train Although a target compound (ie TCE) was detected in the blank the concentration is minor and even if a leak had occurred during sampling (of which there was no evidence) it would not have affected the overall results and data interpretation The presence of IPA in the helium blank is

                80607-1 REV1 30102017 PAGE 23

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                QAQC Item Detail

                suspected by SGS of having resulted from a handling issue in the field ndash ie sub-sampling from the helium cylinder (ie into a summa canister via a flex foil bag) in the vicinity of the high concentrations of IPA being used for leak detection Refer to SGS correspondence in Appendix G

                Sample preservation and storage

                Following collection the WMStrade units were placed into individual glass vials which were sealed and placed into foil bags for transport to the analytical laboratory at ambient temperature Summa canisters were stored in specially constructed cases during transport to the analytical laboratory at ambient temperature

                Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

                QC samples ndash WMStrade sampling

                During the first round of passive soil vapour sampling three additional WMStrade units were deployed in soil bores drilled adjacent to WMS 22 WMS 25 and WMS 28 to act as duplicate QC samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 8) Two trip blank samples were also included with samples transported from and to the analytical laboratory All of the QC samples were analysed by the primary laboratory Intra-duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within an acceptable range (ie lt30) The analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was negligible impact on sample quality during storage or transport of the samples to the analytical laboratory

                QC samples ndash soil vapour bore sampling

                Two intra-laboratory duplicate QC samples were analysed for CHC and general gases with respect to 24 primary soil vapour samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 83) compared to an acceptable ratio of 110 samples (or 10) Intra-laboratory duplicate RPDs were calculated where both samples had a reported concentration above the laboratory LOR All calculated RPDs for CHC and general gases were within an acceptable range (ie lt30) The analytical results obtained for the helium shroud (Tedlar bags) helium blank and IPA shroud (carbon tube) samples were all considered to be satisfactory

                Notes The American Society for Testing and Materials (ASTM) is an internationally recognised source of testing methods Although Appendix J of CRC CARE (2013) stipulates a 110 duplicate sampling ratio for active vapour sampling a specific ratio is not stipulated for passive vapour sampling

                52 Laboratory QAQC

                Laboratory QA procedures generally include the performance of a number of internal checks of data precision and accuracy that are aimed at assessing possible errors associated with sample preparation and analytical techniques Specific types of QC samples analysed by laboratories and the relevant acceptance criteria are as follows

                PAGE 24 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                internal laboratory replicate samples maximum RPD values of 20 to 50 although this varies depending on laboratory LOR

                spike recoveries results between 70 and 130 and

                laboratory controlmethod blanks results below the laboratory LOR

                Table 53 presents conformance to laboratory QAQC procedures undertaken as part of the overall investigation program

                Table 53 Laboratory QAQC procedures

                QAQC Item Detail

                Samples analysed and Samples were generally analysed within specified holding times ndash with the exception extracted within relevant of the following groundwater samples holding times SGS report no ME303457 nitrate was analysed two days late in some samples

                (MW5 MW17 MW26) SGS report no ME303475 nitrate was analysed one day late in all samples and EurofinsMGT report no 555810-W total CO2 was analysed five days late None of these holding time exceedances are considered to be significant with respect to the interpretation of the CHC data the determination of potential human healthenvironmental risks andor the determination of natural attenuation

                Laboratories used and The laboratories used (SGS Eurofins MGT and SMS Geotechnical) were NATA NATA accreditation accredited for the majority of the analyses undertaken

                The exception was SMS Geotechnical which was not NATA accredited for the calculations undertaken to derive some of the data ndash this is the case however for all geotechnical laboratories

                Appropriate analytical methodologies used

                Refer to the laboratory reports in Appendix G

                Laboratory limit of The laboratory LOR is the minimum concentration of an analyte (substance) that can reporting (LOR) be measured with a high degree of confidence that the analyte is present at or above

                that concentration The LOR are presented in the laboratory certificates of analysis (Appendix G) and are considered to be generally appropriate (ie below the adopted assessment criteria ndash refer to Section 62) ndash the following exceptions in soil vapour (ie considered to be due to interference associated with elevated concentrations of other compounds ndash refer to SGS correspondence in Appendix G) are discussed further in Table 101 VC in all of the WMStrade samples relative to the ASC NEPM (1999) interim soil

                vapour health investigation level (HIL) for residential land use cis-12-DCE and VC in two soil vapour bore samples (SV2_30m and SV3_30m)

                relative to the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land use and

                VC in two soil vapour bore samples (SV3_10m and SV7_30m) relative to the ASC NEPM (1999) interim soil vapour HIL for residential land use

                In addition to the above although ultra-trace analysis was requested the laboratory LOR for VC in groundwater (ie 1 microgL) is above the adopted NHMRCMRMMC (2011) potable guideline (ie 03 microgL) ndash refer to Section 612

                80607-1 REV1 30102017 PAGE 25

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                QAQC Item Detail

                Laboratory internal QC analyses

                Results obtained for the laboratory internal QC samples were generally within the acceptable limits of repeatability chemical extraction and detection with the exception of the following SGS report ME303457 matrix spike results for iron were outside normal tolerances

                due to the high concentrations of iron in the spiked sample ndash matrix spike results for iron could therefore not be calculated This is not considered to be a significant issue

                Full details regarding laboratory QAQC procedures and results are presented in the certified laboratory certificates contained in Appendix G

                Notes Since holding times were not specified in the SGS groundwater reports Fyfersquos assessment of holding times has been based on those adopted by EurofinsMGT (ie the secondary laboratory used for groundwater analysis) ie in accordance with Schedule B3 of the ASC NEPM (1999) also referred to as practical quantification limits (PQL)

                53 QAQC summary

                In summary it is considered that

                the field QAQC programs were generally undertaken with regard to relevant legislation standards andor guidelines and were sufficient for obtaining samples that are representative of site conditions and

                the overall laboratory QAQC procedures and results were adequate such that the laboratory analytical results obtained are of acceptable quality for addressing the key objectives outlined in Section 15

                PAGE 26 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                6 ASSESSMENT CRITERIA

                61 Groundwater

                611 Beneficial Use Assessment

                In accordance with Schedule B6 of the ASC NEPM (1999) and SA EPA (2009) a Beneficial Use Assessment (BUA) was undertaken to assess both the current and realistic future uses of groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area

                This was aimed at determining what groundwater uses need to be protected and assessing the risk(s) that groundwater may pose to human health and the environment (refer also to the VIRA in Section 9)

                As summarised in Table 61 the potential beneficial uses for groundwater within the Q1 aquifer that have been considered are as follows ndash taking into account the salinity of the groundwater the Environment Protection (Water Quality) Policy 2015 (Water Quality EPP 2015) the DEWNR (2017) WaterConnect database information presented in Section 222 and possible sensitive receptors located within andor within the vicinity of the Thebarton EPA Assessment Area

                The salinity of groundwater has been calculated to approximate 1230 to 3620 mgL TDS (refer to Section 7312) According to the Water Quality EPP 2015 the applicable environmental values for groundwater with salinity above 1200 mgL TDS but less than 3000 mgL TDS are irrigation livestock and aquaculture whereas the salinity is considered to be too high for potable use ndash although domestic irrigation is considered to be a potentially realistic use for this area (see below) livestock watering is considered unlikely to be undertaken in such an urban setting and no local water bodies (ie surface or groundwater) have been identified as being used for commercial aquaculture purposes

                The DEWNR (2017) WaterConnect database indicates that groundwater within the Q1 aquifer in the Thebarton area is accessed for drainage domestic and industrial purposes ndash domestic groundwater use could include garden irrigation plumbing water andor the filling of swimming pools (ie primary contact recreation) Although domestic groundwater extraction is considered unlikely to include potable use (ie due to its salinity and the availability of a reticulated mains water supply) potential mixing with rain watermains water could render it suitable (ie from a salinity perspective) for drinking

                As the closest freshwater surface water body the River Torrens is located approximately 03 km to the east and 07 km to the north and north-west of the northern portion of this area groundwater discharge from the Thebarton EPA Assessment Area into a freshwater aquatic ecosystem is considered possible However as the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area the potential for impact on a freshwater aquatic environment has not been confirmed

                80607-1 REV1 30102017 PAGE 27

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Since the closest marine surface water body Gulf St Vincent is located approximately 8 km to the west groundwater discharge from the Thebarton EPA Assessment Area into a marine aquatic ecosystem is not considered to be realistic

                Since volatile contaminants have been detected within the Q1 aquifer (refer to Section 7331) a potential vapour flux risk to future site users must be considered

                Given the measured depth of the Q1 aquifer beneath the site (ie approximately 1232 to 1585 m BGL ndash refer to Section 7311) it is considered unlikely that direct contact could occur between groundwater and building footingsunderground services

                Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area

                Environmental Values Beneficial Uses

                Water Quality EPP 2015

                environmental value

                SA EPA (2009) Potential

                Beneficial Uses

                Beneficial Use Assessment

                Considered Applicable

                Aquatic Ecosystem

                Marine Yes No

                Fresh Yes Possibly

                Potable - Yes Possibly

                Agriculture Irrigation - Yes Yes

                Livestock - Yes No

                Aquaculture - Yes No

                Recreation amp Aesthetics

                Primary contact Yes Possibly

                Aesthetics Yes Possibly

                Industrial - Yes Yes

                Human health in non-use scenarios

                Vapour flux -

                Yes Yes

                Buildings and structures

                Contact - Yes No

                Notes ie for underground waters with a background TDS level of between 1200 and 3000 mgL ndash note that although they are not listed as environmental values of groundwater in Schedule 1(3) of the Water Quality EPP 2015 aquatic ecosystems as well as recreation amp aesthetics are included as environmental values for waters in general in Part 1(6) of the document ie domestic irrigation only

                612 Groundwater beneficial use criteria

                The health and ecological criteria used for the assessment of the COPC (refer to Section 14) in groundwater have been based on the results of the BUA (Section 611) A summary of the references used to source the groundwater assessment criteria is provided in Table 62

                PAGE 28 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Table 62 Sources of adopted groundwater assessment criteria

                Beneficial Use Reference

                Freshwater Ecosystems No criteria available for COPC

                Potable NHMRCNRMMC (2011) Australian Drinking Water Guidelines

                WHO (2017) Guidelines for Drinking-water Quality ndash TCE only

                Irrigation No criteria available for COPC

                Primary contact recreation (including aesthetics)

                NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines but (with the exception of aesthetic guidelines) multiplied by a factor of 10 to take account of accidental ingestion rates as opposed to deliberate ingestion

                ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality ndash recreational values (TCE only)

                Human health in non-use scenarios ndash vapour flux Refer to the VIRA in Section 9

                Notes As there are no specific guidelines for industrial water these values are considered likely to be protective of this additional beneficial use The NHMRC (2008) guidelines are based on drinking water levels and assume a consumption factor of 2 L per day Therefore as recommended in the NHMRC (2008) document potable criteria (ie with the exception of aesthetic criteria) need to be adjusted by a factor of 10 to account for an accidental consumption rate of 100 to 200 ml per day As noted in ANZECCARMCANZ (2000b) although recreational guidelines are protective of ingestion recreational waters should also not contain any chemicals that can cause skin irritation likewise although not specifically addressed by recreational water criteria inhalation may also represent a source of exposure with respect to some (ie volatile) contaminants In the absence of a NHMRCNRMMC (2011) drinking water guideline for TCE the ANZECCARMCANZ (2000b) recreational criterion (30 microgL) has been adopted However if the NHMRC (2008) rule of multiplying potable (healthshybased) guidelines by 10 is applied to the WHO (2017) drinking water guideline of 20 microgL a recreational guideline of 200 microgL would be more applicable

                62 Soil vapour

                The ASC NEPM (1999) interim soil vapour health investigation levels (HILs) for volatile organic chlorinated compounds (VOCCs) have been adopted (ie in the first instance ndash refer to Section 7331) as Tier 1 soil vapour assessment criteria ndash relevant land use scenarios within the Thebarton EPA Assessment Area include residential (HIL AB) and commercialindustrial (HIL D)

                These criteria have been further adjustedappended for the purposes of the VIRA Tier 1 assessment ndash refer to Section 94

                80607-1 REV1 30102017 PAGE 29

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                7 RESULTS

                71 Surface and sub surface soil conditions

                711 Field observations

                Groundwater well and soil vapour borehole log reports are included in Appendices H to J and provide details of the soil profile encountered at each sampling location

                Where encountered fill materials extended to depths of between 01 and 09 m BGL and included a range of different soil types (sand gravelcrushed rock silt) with only minimal waste inclusions (ie asphalt glass andor metal fragments) identified at some locations

                The underlying natural soil profile (encountered to the maximum drill depth of 19 m BGL) was dominated by low to medium plasticity brown to red-brown silty clays and sand claysclayey sands some of which contained sub-angular to rounded gravels that included river pebbles andor comprised fine distinct lenses in places Groundwater well MW17 also included a 15 m thick layer of gravel at depth (ie 12 to 135 m BGL) ndash ie consistent with the depth of groundwater within the Q1 aquifer

                During the course of the drilling works no odours or visual indicators of contamination were detected and measured PID readings ranged up to 6 ppm but were generally lt3 ppm

                712 Soil geotechnical testing

                A table of geotechnical testing results is presented in Appendix L (Table 1) and a copy of the certified laboratory report is included in Appendix G Photographs of soil cores are included in Appendix N

                The results were interpreted to indicate the following

                The soil core samples submitted for PSD analysis were dominated by clay with lesser amounts of fine to medium gravel andor fine to coarse-grained sand ndash all samples analysed were classified as either CLAY or Sandy CLAY with one sample classified as Clayey SAND The classifications obtained from the laboratory were deemed to be generally consistent with the descriptions on the groundwater well log reports (Appendix H) although the PSD results did not specify silt as a significant secondary component

                The moisture content of the analysed soil core samples ranged from 65 to 231 Moisture content with respect to soil type depth and location has been considered in more detail for the purposes of the VIRA (Section 9) The degree of saturation for the analysed soil cores samples ranged from 218 to 964

                Measured bulk density ranged from 160 to 212 tm3 specimen dry density from 141 to 184 tm3 and specific gravity from 255 to 281 tm3

                The measured void ratio ranged from 043 to 088 whereas porosity ranged from 032 to 047

                80607-1 REV1 30102017 PAGE 31

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                72 Waterloo Membrane Samplerstrade A table of WMStrade analytical results (ie from both rounds of sampling) is presented in Appendix L (Table 2) and copies of certified laboratory reports are included in Appendix G8

                Of the 41 WMStrade units deployed across the Thebarton EPA Assessment Area during the two sampling rounds 20 returned measurable concentrations of CHC including TCE PCE cis-12-DCE trans-12-DCE andor 11-DCE Although no VC was detected the laboratory LOR in all samples (ie 35 to 50 microgm3) was above the ASC NEPM (1999) soil vapour interim HIL for residential land use (30 microgm3) ndash refer also to Table 53

                Detectable COPC concentrations are summarised in Table 71 relative to the ASC NEPM (1999) soil vapour interim HILs along with the closest soil vapour bore andor groundwater monitoring well locations Measured TCE concentrations are detailed on Figure 3

                A comparison of the Round 1 and 2 WMStrade results (ie for closely located units9) is presented in Table 72 ndash the results indicate a general order of magnitude correlation of the results for most COPC with the exception of PCE for which lower concentrations were obtained during Round 2 As the Round 1 and 2 WMStrade units were located within different soil bores and deployed at different times some variability in the results is to be expected In addition and as discussed in Section 74 the WMStrade units have been used during this assessment as a (semi-quantitative) screening tool (ie to assist with the siting of the permanent soil vapour bores) with the results obtained from the soil vapour bores considered more representative of actual subsurface conditions

                Table 71 Detectable Waterloo Membrane Samplertrade CHC results

                Sample ID

                Location Closest land uses

                CHC concentration (microgm3) Closest soil vapour bore

                andor groundwater

                well

                TCE PCE cis-12shyDCE

                trans-12shyDCE

                11shyDCE

                VC

                WMS 1 Goodenough Street CI 35 -

                WMS 6 Maria Street CI 32 -

                WMS 7 Maria Street CI and R 1900 45 SV2 MW5

                WMS 8 Maria Street CI and R 12000 37 SV4

                WMS 11 Admella Street CI 71000 260 19 20 36 SV5 MW02

                WMS 14 George Street CI 46000 45 SV6 MW11

                WMS 18 Admella Street CI 4200 34 MW14

                WMS 19 Albert Street CI 11000 42 SV10MW15

                WMS 21 Chapel Street CI 10 -

                WMS 22 Admella Street CI 38 SV9

                WMS 24 Chapel Street CI 230 62 10 11 48 MW17

                8 Note that the original laboratory report for the Round 1 WMStrade samples was found to be incorrect (ie following receipt of the soil vapour bore and Round 2 WMStrade sample results) and was subsequently re-issued by SGS

                9 only two of which were sufficiently co-located for comparative purposes ndash Round 2 locations WMS 39 and WMS 41 were not within the immediate vicinity of Round 1 WMStrade bores (ie the closest Round 1 bores were approximately 30 m away)

                PAGE 32 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Sample ID

                Location Closest land uses

                CHC concentration (microgm3) Closest soil vapour bore

                andor groundwater

                well

                TCE PCE cis-12shyDCE

                trans-12shyDCE

                11shyDCE

                VC

                WMS 25 Albert Street CI and R 1400 20 MW17

                WMS 27 Light Terrace CI 64 62 SV11 MW19

                WMS 32 Holland Street R 16 -

                WMS 34 James Street R 11 -

                WMS 37 Dew Street R 44 -

                WMS 38 Maria Street CI and R 13000 56 SV2 MW5

                WMS 39 Maria Street CI and R 1300 SV4

                WMS 40 Admella Street CI 110000 97 SV5 MW02

                WMS 41 George Street CI 18000 10 SV7 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

                Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform (up to 530 microgm3) was also detected in WMS 8 WMS 11 WMS 14 WMS 16 WMS 18 WMS 19 WM 25 WMS 33 WMS 40 and WMS 41 interim soil vapour health investigation level (HIL)

                Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units

                Bore ID

                Depth (m)

                Location CHC concentration (microgm3)

                TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

                WMS 8 10 Maria Street 12000 37 lt95 lt99 lt22 lt36

                WMS 38 13000 56 lt11 lt11 lt25 lt41

                Relative percentage difference 8 147 - - - -

                WMS 11 10 Admella Street 71000 260 19 20 36 lt37

                WMS 40 110000 97 lt11 lt11 lt25 lt41

                Relative percentage difference 43 91 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

                80607-1 REV1 30102017 PAGE 33

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                73 Groundwater

                731 Field measurements

                A table of groundwater field parameters is presented in Appendix L (Table 3) and groundwater field sampling sheets are included in Appendix E

                7311 Groundwater elevation and flow direction

                The depth to water within the Q1 aquifer beneath the Thebarton EPA Assessment Area on 18 July 2017 ranged from 12323 to 15854 m below top of casing (BTOC)10 and 4469 to 5070 m AHD

                Groundwater elevation contours constructed from the July 2017 gauging data indicated that the overall groundwater flow direction within the Q1 aquifer was north-westerly consistent with expected regional groundwater flow The groundwater contours and inferred flow direction are shown on Figure 4

                7312 Field parameters

                As detailed in Table 51 field measurements were recorded during low flow purging (ie prior to micropurge sampling) of monitoring wells and immediately following the collection of HydraSleeveTM samples

                The field parameter readings recorded for the monitoring wells immediately prior to (low flow micropurge) and after (HydraSleeveTM) sampling indicated the following (as summarised in Table 3 Appendix L)

                groundwater pH ranged from 6 8 to 79 thereby indicating neutral conditions

                electrical conductivity (EC) measurements ranged from 189 to 556 mScm and were found to be reasonably consistent across the area thereby indicating that it is underlain by moderately saline water (ie approximating 1230 to 3620 mgL TDS11)

                redox concentrations ranged from -20 to 624 mV thereby indicating slightly reducing to strongly oxygenating conditions

                measured dissolved oxygen (DO) concentrations ranged from 04 to 78 ppm indicating slightly to highly oxygenated water and

                temperature ranged from 173 to 224oC

                Observations recorded during sampling indicated that the groundwater was clear to brown and only slightly to moderately turbid at most locations ndash the higher turbidity at MW18 and MW19 (combined with poor recharge) contributed towards the decision to use a HydraSleeveTM sampling method No odours or sheen were observed in any of the wells during gauging or sampling

                10 ie approximating m BGL 11 ie calculated by multiplying the field EC data by 065

                PAGE 34 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                732 Hydraulic conductivity

                Rising and falling head aquifer permeability (ldquoslugrdquo) tests were conducted on 10 groundwater wells (refer to Table 31 and Figure 2) to assess the hydraulic conductivity (K) of the Q1 aquifer

                To obtain estimates of near-well horizontal hydraulic conductivity for each well tested the slug test data were analysed by Arcadis using AQTESOLV for Windowstrade (Duffield 2007) following the guidelines presented in Butler (1998) ndash normalised displacement data collected from each test are plotted against time in Appendix A of the Arcadis report (refer to Appendix O) Since only one set of tests were performed at each well the reproducibility of the results as well as the dependence of the results on the initial displacement could not be verified or demonstrated As such multiple relevant and applicable solutions were applied to each test to account for that uncertainty (ie to ensure consistency of normalised response at each well regardless of initial displacement)

                Table 73 presents a summary of the range and average estimated hydraulic conductivity values (and corresponding analytical solutions used) for each well tested The results indicate that hydraulic conductivities ranged from approximately 0073 to 37 mday with an overall average of approximately 1 mday

                Table 73 Hydraulic conductivities (rising and falling head tests)

                Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

                (mday) Hydraulic Conductivity

                (mday)

                MW02 Falling head 011 to 014 DA CBP HV

                012 Rising head 0073 to 015 BR DA

                MW3 Falling head 034 to 062 BR DA

                047 Rising head 030 to 062 BR DA

                MW7 Falling head 075 to 25 BR DA

                139 Rising head 055 to 175 BR DA

                MW14 Falling head 011 to 021 BR DA

                014 Rising head 009 to 015 BR DA

                MW17 Falling head 21 to 22 DA KGS

                220 Rising head 225 to 244 DA KGS

                MW20 Falling head 22 to 37 BR DA HV

                256 Rising head 06 to 32 BR DA

                MW21 Falling head 073 to 123 BR DA

                084 Rising head 054 to 084 BR DA

                MW23 Falling head 088 to 162 BR DA

                101 Rising head 031 to 122 BR DA

                80607-1 REV1 30102017 PAGE 35

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

                (mday) Hydraulic Conductivity

                (mday)

                MW25 Falling head 10 to 18 BR DA CBP HV

                132 Rising head 049 to 17 BR DA

                MW26 Falling head 019 to 036 BR DA

                023 Rising head 010 to 029 BR DA

                Overall average K (mday) 1028 Notes References BR = Bouwer and Rice (1976) CBP = Cooper et al (1967) DA = Dagan (1978) HV = Hvorslev (1951) KGS = Hyder et al (1994)

                The monitoring wells that exhibited lower permeabilities (ie MW02 MW3 MW14 and MW26) were noted to be generally located in the up-gradient (south-eastern) portion of the Thebarton EPA Assessment Area whereas monitoring wells showing relatively higher permeabilities (ie MW7 MW17 MW20 MW21 MW23 and MW25) are generally located in the down-gradient (north-western) portion These results were considered by Arcadis to suggest a possible hydrogeologic transition from the south-east to the north-west AQTESOLV solution plots for each analysis are provided as Appendix A of the Arcadis report (Appendix O)

                As slug test results can be influenced by a number of factors which are difficult to avoid when performing and analysing slug test results hydraulic conductivity estimates derived from slug tests should be considered to be the lower bound of the hydraulic conductivity of the formation in the vicinity of the well (Butler 1998) However Arcadis also noted that the results obtained for the Thebarton EPA Assessment Area were similar to those reported for other areas of Adelaide with average values of 1 and 27 mday (refer to Appendix O)

                The slug test results were used by Arcadis in their groundwater fate and transport model (refer to Section 8)

                733 Analytical results

                Tables of groundwater analytical results are presented in Appendix L (Tables 4 and 5) and copies of certified laboratory reports are included in Appendix G

                7331 Chlorinated hydrocarbon compounds

                A table of CHC results is included in Appendix L (Table 4) and a plan showing their distribution in groundwater beneath the Thebarton EPA Assessment Area is included as Figure 5 Detectable CHC concentrations are summarised in Table 74 relative to the adopted potable and primary contact recreation criteria ndash the closest soil vapour bore locations are also detailed

                PAGE 36 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Table 74 Detectable groundwater CHC results

                Sample ID

                Location CHC concentration (microgL) Closest soil vapour bore

                TCE PCE cis-12shyDCE

                trans-12-DCE

                11-DCE VC Carbon tetrachloride

                MW02 Admella Street 20000 38 7 15 SV5

                MW3 Admella Street 69 SV1

                MW5 Maria Street 29000 3 21 2 6 SV2 SV3

                MW6 Maria Street 29 SV4

                MW9 Albert Street 2 -

                MW11 George Street 4900 3 4 1 7 SV6 SV7

                MW12 George Street 700 SV8

                MW14 Admella Street 1000 4 2 SV9

                MW15 Albert Street 180 SV10

                MW17 Chapel Street 24 -

                MW18 Dew Street 5 -

                MW20 Light Terrace 70 SV12

                MW21 Light Terrace 23 SV13

                MW23 Dew Street 21 -

                MW25 Smith Street 2 5 -

                MW26 Kintore Street 2 -

                Potable 20 50 60 30 03 3

                Primary contact recreation

                30 500 600 300 30 30

                Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Chloroform was also detected in a number of wells (MW02 MW3 MW5 MW8 MW11 MW12 and MW19 to MW25) ndash refer to Table 4 in Appendix L Although no VC was detected the laboratory LOR (1 microgL) exceeded the adopted potable criterion NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from WHO (2017) Guidelines for Drinking-water Quality NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

                The results indicate that the highest TCE concentrations (20000 to 29000 microgL) were measured in wells MW02 and MW5 located in the immediate vicinity of the former Austral property and that the TCE plume extends in a general north-westerly direction (ie consistent with the inferred groundwater flow direction

                80607-1 REV1 30102017 PAGE 37

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                within the Q1 aquifer) Although lesser concentrations of PCE 12-DCE (cis- andor trans) andor 11-DCE were present in some wells no VC was detected and the main COPC was identified as TCE

                A number of wells within the Thebarton EPA Assessment Area contained TCE concentrations that exceeded the adopted potable andor primary contact recreation criteria Although the extent of the TCE plume was not delineated to the north-west (but was delineated in all other directions) with detectable TCE concentrations (ie up to 21 microgL) identified beneath both Smith Street and Dew Street these concentrations were below the adopted primary contact recreation criterion (but not necessarily the adopted potable value ndash ie MW23)

                The background well (MW4) located across James Congdon Drive (to the east of the southern portion of the Thebarton EPA Assessment Area) did not contain any measurable CHC concentrations

                7332 Other measured groundwater parameters

                Major cations and anions

                The laboratory results obtained for the remaining groundwater analytes are summarised in Appendix L (Table 5)

                The groundwater ionic data obtained from selected wells across the Thebarton EPA Assessment Area are graphically represented on a Piper diagram in Figure 71 The results indicate a relatively consistent groundwater composition across the area thereby indicating that the groundwater sampled from these wells is derived from a single aquifer Ionic charge balance ranged from 32 to 22 with the highest value (22) calculated for MW12 indicating that additional anions (ie not measured as part of this study) could be present

                PAGE 38 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Figure 71 Piper diagram

                Natural attenuation parameters

                With respect to the measured natural attenuation parameters (ie DO nitrate iron sulfate CO2 and manganese) the following wells were selected based on their locations relative to the inferred extent of the CHC plume

                MW26 located on Kintore Street to the south (and hydraulically up-gradient) of the former Austral property (ie the suspected source site)

                MW02 and MW5 located within the immediate vicinity of the former Austral property and the area of maximum CHC contamination

                MW9 MW12 and MW17 located on Albert Street George Street and Chapel Street respectively to the north-west (and hydraulically down-gradient) of the former Austral property

                80607-1 REV1 30102017 PAGE 39

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                MW21 and MW22 located on Light Terrace and Cawthorne Street respectively to the northshywestnorth-north-west (and further hydraulically down-gradient) of the former Austral property and

                MW8 and MW23 located on Smith Street and Dew Street respectively representing the furthest wells to the northnorth-west of the former Austral property

                According to Wiedemeier et al (1998) the most important process in the degradation of CHC is the process of reductive dechlorination Although daughter products of TCE (ie 12-DCE) are present in groundwater (and soil vapour) at scattered locations within the Thebarton EPA Assessment Area they are not considered indicative of substantial breakdown of TCE ndash refer also to the Arcadis report in Appendix O as summarised in Section 8 In addition the analysis of the natural attenuation parameters data constituting physical and chemical indicators of biodegradation processes has not provided a definitive secondary line of evidence

                74 Soil vapour bores A table of soil vapour bore analytical results is presented in Appendix L (Table 6) and a copy of the certified laboratory report is included in Appendix G

                Of the soil vapour bores installed to 10 andor 30 m BGL within the Thebarton EPA Assessment Area the majority (ie with the exception of the 10 m deep bores installed as SV11 and SV13 and located on Light Terrace) returned measurable concentrations of CHC dominated by TCE and to a lesser extent (and only at some locations) PCE Detectable soil vapour CHC concentrations are summarised in Table 75 whereas CHC concentrations and inferred soil vapour TCE concentration contours are detailed on Figures 6 (1 m BGL) and 7 (3 m BGL)

                The TCE results which have been used to predict indoor air concentrations as part of the VIRA (refer to Section 9) suggest the following

                the highest concentration (1000000 microgL) was detected at 3 m BGL in soil vapour bore SV3 located in the vicinity of residential and commercialindustrial properties (including the former Austral property) on Maria Street

                where nested wells were tested soil vapour CHC concentrations were higher at depth consistent with a groundwater source

                TCE PCE and 11-DCE are all assumed to represent primary contaminants with 12-DCE representing a break-down product of TCE andor PCE

                although no VC was detected the laboratory LOR in some samples (ie up to 490 microgm3 in samples with the highest measured TCE concentrations) was above the ASC NEPM (1999) interim soil vapour HIL for residential land use (30 microgm3) ndash refer to Table 53 and

                although the extent of the soil vapour plume has apparently not been delineated (ie in any direction) by the existing soil vapour bores it extends in a north-westerly direction (and hydraulically down-

                PAGE 40 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                gradient) from the suspected source site (ie the former Austral property) and corresponds well with the groundwater TCE plume (refer to Figure 5)

                A comparison of the results obtained for the WMStrade units (WMS 38 to WMS 41) deployed during the second round of sampling and the closest soil vapour bore data (10 m BGL) is provided in Table 76 Although the results indicate good correlation for TCE and PCE in SV5WMS 40 as well as TCE in SV7WMS 41 the remaining results were more variable ndash this supports the use of the WMStrade units as an initial (semishyquantitative) screening tool with follow-up soil vapour bore data considered to provide more quantitative results

                Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area

                Bore ID

                Depth (m)

                Location Closest land

                uses

                CHC concentration (microgm3)

                TCE PCE cis-12shyDCE

                trans-12-DCE

                11-DCE VC

                SV1 10 Admella Street CI and R 6300 78

                30 21000 21

                SV2 10 Maria Street CI and R 51000 39 21 39

                30 940000

                SV3 10 Maria Street CI and R 210000 6500 5900

                30 1000000 15000 14000

                SV4 10 Maria Street CI and R 17000 31

                30 43000 90 30

                SV5 10 Admella Street CI 100000 84

                30 160000 310 20 33

                SV6 10 George Street CI 22000 12

                30 150000 56

                SV7 10 George Street CI 22000 19

                30 110000

                SV8 10 George Street CI 2300 62

                30 14000 19

                SV9 10 Chapel Street CI 170

                30 260

                SV10 10 Albert Street CI 93

                30 51

                SV12 10 Light Terrace CI 16

                30 55 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

                Notes Shaded cells indicate concentrations were below the laboratory LOR

                80607-1 REV1 30102017 PAGE 41

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Where (field andor laboratory) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform was also detected in a number of samplesinterim soil vapour health investigation level (HIL)

                Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores

                Bore ID

                Depth (m)

                Location CHC concentration (microgm3)

                TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

                SV2 10 Maria Street 51000 39 21 lt13 39 lt89

                WMS 38 13000 56 lt11 lt11 lt25 lt41

                Relative percentage difference 119 150 - - - -

                SV4 10 Maria Street 17000 31 lt18 lt14 lt14 lt92

                WMS 39 1300 lt52 lt11 lt11 lt25 lt41

                Relative percentage difference 172 - - - - -

                SV5 10 Admella Street 100000 84 lt44 lt33 lt33 lt22

                WMS 40 110000 97 lt11 lt11 lt25 lt41

                Relative percentage difference 95 14 - - - -

                SV7 10 George Street 22000 19 lt37 lt27 lt27 lt18

                WMS 41 18000 10 lt11 lt11 lt25 lt41

                Relative percentage difference 20 62 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

                PAGE 42 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                8 GROUNDWATER FATE AND TRANSPORT MODELLING

                Arcadis were commissioned by Fyfe to undertake preliminary fate and transport modelling of the groundwater CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained groundwater data The Arcadis report is included as Appendix O

                The aim of the modelling was to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton area in order that potential future groundwater restrictions could be applied by the EPA (ie via the potential future definition of a GPA) to protect human health

                81 Groundwater flow modelling

                The MODFLOW code a publicly-available groundwater flow simulation program developed by the United States Geological Survey (USGS) as described by McDonald and Harbaugh (1988) was used to construct a groundwater flow model It was developed for a horizontal area of approximately 25 km2 (ie to minimise possible boundary effects within the assessment area itself12) and was rotated 45deg counter-clockwise to align with the prevailing (north-westerly) groundwater flow direction The model extended approximately 23 km in a south-east to north-west direction and approximately 11 km in a south-west to north-east direction (ie perpendicular to groundwater flow) Whereas a 4 m grid spacing was used within the area of the plume and its migration pathway (ie to enhance model accuracy and precision) a broader 15 m grid was adopted outside the specific area of interest Vertically the model adopted a single 20 m thick layer as representative of the hydrostratigraphy of the Q1 aquifer sediments beneath the area but it was noted that only the bottom portion (ie few metres) of this model layer are actually saturated and therefore active in the model

                An informal sensitivity analysis performed as part of the model calibration process indicated that the model was most sensitive to changes in hydraulic conductivity and recharge ndash this was not unexpected given the relatively flat hydraulic gradient and relatively narrow range of estimated values for both model parameters (ie based on reasonably low uncertainty) The final calibrated value for aquifer recharge adopted in the model was 295 mmyear consistent with results reported for nearby sites as well as regional estimates Likewise the final calibrated hydraulic conductivity values for the up-gradient (06 mday) and down-gradient (2 mday) zones were consistent with both the site-specific slug test data and results obtained for other nearby EPA assessment areas The final calibrated down-gradient constant head elevation was 15 m AHD It was concluded by Arcadis that the groundwater flow model was well calibrated and could therefore serve as an appropriate basis for the development of a site-specific solute transport model

                82 Solute transport modelling

                A site-specific (three-dimensional) solute transport model using the MT3DMS transport code of Zheng (1990) was developed by Arcadis to predict the fate and transport of groundwater contaminants (specifically

                12 Further information regarding boundary effects is provided in the Arcadis report (Appendix O)

                80607-1 REV1 30102017 PAGE 43

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                CHC) under current conditions over a period of 100 years This dual-domain mass transport model was used in conjunction with the groundwater flow model developed through the use of MODFLOW (as detailed above) assuming the following

                The primary COPC is TCE ndash the initial concentration distribution of TCE in groundwater was based on the recent (July 2017) monitoring data

                The age of the groundwater TCE plume was assumed to be up to about 90 years ndash ie based on the history of industrial land use (specifically the former Austral facility) in the area

                Although lesser amounts of other CHC are present in groundwater the lack of significant daughter products of TCE has been interpreted to indicate that substantial biodegradation is not occurring (ie as a conservative approach)

                Although a CHC source was not explicitly incorporated into the solute transport model the MT3DMS transport code indirectly accounts for on-going contaminant mass contribution to the dissolved-phase plume

                The fate and transport of TCE within the area of interest involves the processes of advection adsorption dilution and diffusion ndash however given that recharge via the infiltration of precipitation was considered to be insignificant dilution effects were assumed to be minimal

                Two porosity values (ie dual domain) are relevant to the movement of contaminants in the subshysurface with adopted values based on site-specific geology and Payne et al (2008) ndash whereby the two domains are in equilibrium

                ― mobile porosity that portion of the formation with the highest permeability where advective transport dominates ndash assumed to be 5 (high) 10 (intermediate) or 15 (low) for different mobility transport conditions and

                ― immobile porosity lower permeability portions of the formation where diffusion is dominant ndash assumed to be 15

                As discussed in Section 732 hydraulic conductivity values of 06 mday (south-eastern approximate quarter of the modelling area) and 2 mday (northern approximate three-quarters of the modelling area) were adopted to reflect the hydrogeologic transition (ie from the south-east to the north-west) interpreted from the slug test data

                The adopted TCE retardation factor of 147 for intermediate mobility transport conditions was based on the following

                ― an assumed organic carbon fraction of 01 (US EPA 1996 amp 2009) ndash this was varied to 005 and 2 to assess alternate (ie high versus low) mobility transport conditions

                ― an assumed organic carbon adsorption co-efficient of 61 Lkg (US EPA 2017a)

                PAGE 44 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                ― a calculated partition co-efficient of 0061 Lkg ndash this was varied to 129 and 178 Lkg to assess alternate (ie high versus low) mobility transport conditions and

                ― an average soil bulk density of 192 gcm3 (based on measured geochemical data ndash refer to Table 1 Appendix L)

                An optimum mass transfer co-efficient (MTC) was based on simulated flux distribution in the groundwater flow model whereby

                ― the calculated MTC in the model ranged from approximately 38E-08day-1 to 37E-05 day-1 and

                ― the average MTC was 185E-05day-1

                The site-specific solute transport model was used in predictive mode to assess the long-term (eg 100 year) potential migration of the groundwater TCE plume and to support the EPA in the potential future definition of an appropriate GPA The model was calibrated against the current extent (ie concentrations of TCE above 1 microgL have migrated approximately 500 m from the suspected source site13) and expected age (ie up to about 90 years) of the plume The results indicate that the leading edge of the TCE (ie the 1 microgL contour) is estimated to migrate between approximately 400 and 620 m over a period of 100 years under low to high mobility transport conditions14 with intermediate transport conditions resulting in an estimated migration of 500 m By comparison no significant lateral plume expansion would be expected to occur Figures 5 to 17 of the Arcadis report (Appendix O) show the predicted extent of the TCE plume at 5 10 50 and 100 years under low to high mobility transport conditions

                Figure 81 shows the predicted extent of the 1 microgL TCE boundary in 100 years under intermediate transport conditions ndash it is recommended that this information be used to support the EPA in establishing a potential future GPA

                The Arcadis report notes that given the available site information (site history potential source area(s) and uncertainty associated with the current plume extent) and degree of model calibration (flow model parameter values are consistent with site-specific data as well as regionalnearby studies while transport parameter values are consistent with literatureindustry standards) the model-predicted migration of approximately 500 m over 100 years is considered to be a reasonable representation of future conditions

                Key uncertainties associated with the modelling were identified as including the following

                current plume extents (ie down-gradient delineation)

                site-specific fraction organic values (or site-specific partition coefficient estimates) and

                site-specific porosity estimates

                13 although it was noted that there is uncertainty with respect to the current extent of the TCE plume since all three down-gradient monitoring wells (MW18 MW23 and MW25) have TCE concentrations above 1 μgL

                14 ie assuming different values for mobileimmobile porosity the TCE distribution (sorption) coefficient and the TCE retardation factor

                80607-1 REV1 30102017 PAGE 45

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Lesser uncertainties were considered to include site-specific bulk hydraulic conductivity estimates and determination of the presence or absence of naturally-occurring TCE degradation

                Additional site investigation and data collection (eg multi-well pumping tests for bulk hydraulic conductivity estimates site-specific fraction organic carbon andor distribution (sorption) coefficient additional down-gradient plume delineation) would help to further refine the model and increase confidence in the predictive results

                Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green) relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple)

                PAGE 46 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                9 VAPOUR INTRUSION RISK ASSESSMENT

                Arcadis were commissioned by Fyfe to undertake a Vapour Intrusion Risk Assessment (VIRA) of the soil vapour CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained (ie August 2017) permanent soil vapour bore data The Arcadis report is included as Appendix P

                91 Objective

                The main objective of the VIRA was to evaluate the potential risk to human health from vapour intrusion related to the concentrations of CHC identified in soil vapour within the Thebarton EPA Assessment Area

                92 Areas of interest

                The following areas of specific interest (ie located within the Thebarton EPA Assessment Area) were identified for the purpose of this VIRA

                commercialindustrial properties (assumed slab on grade construction) including the former Austral property (ie the suspected source site) and

                residential properties (slab on grade crawl space and basement constructions)

                Potential exposure by trenchmaintenanceutility workers has also been considered (qualitatively)

                93 Risk assessment approach

                The VIRA was conducted in accordance with the ASC NEPM (1999) enHealth (2012a) and other relevant Australian guidance documents as well as guidance documents issued by the US EPA and other international regulatory agencies (where applicable)

                The conduct of the risk assessment was based on a multiple lines of evidence approach using the available site-specific information collected as part of the scope of works detailed in Section 32

                The following information was used as a basis for the VIRA

                CHC including TCE PCE and DCE (11- cis-12- and trans-12-) have been identified within soil vapour andor groundwater within the Thebarton EPA Assessment Area ndash the analytical data indicate that TCE constitutes between about 95 and 100 of the CHC identified in groundwater and soil vapour

                TCE has been considered as the risk driver for the VIRA (ie based on its toxicity and concentrations in soil vapour and groundwater) ndash although TCE PCE 12-DCE 11-DCE and VC have all been included as COPC for the Tier 1 screening assessment (Section 94) the Tier 2 assessment (Section 95) has

                80607-1 REV1 30102017 PAGE 47

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                concentrated on TCE PCE and 11-DCE (ie due to their presence at concentrations that exceeded the adopted Tier 1 screening criteria)

                The CHC identified within the Thebarton EPA Assessment Area are volatile chemicals and could potentially pose a risk to human health via the vapour intrusion pathway Although the source area has yet to be confirmed the CHC concentrations observed in groundwater and soil vapour are considered likely to have originated from the former Austral property (as discussed in Section 12)

                The natural soils underlying the fill material (where present) in the Thebarton EPA Assessment Area are typified by the Quaternary age soils and sediments of the Adelaide Plains with the Pooraka Formation and Hindmarsh Clay units considered to dominate the upper soil profile

                The soil geotechnical data and soil vapour results collected by Fyfe (as discussed in Sections 712 and 74 respectively) have been used for the VIRA

                A two-tier approach was adopted for the VIRA The first tier (herein referred to as the Tier 1 assessment) was conducted by comparing the measured soil vapour TCE concentrations to published guideline values adjusted (conservatively) to account for attenuation from sub-slab soil into indoor air The second tier (herein referred to as the Tier 2 assessment) involved the comparison of predicted indoor air TCE concentrations to adopted indoor air criteria or response levels

                94 Tier 1 assessment

                As detailed in Section 74 the initial Tier 1 (screening risk) assessment involved comparing measured soil vapour COPC concentrations with the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land uses (refer to Table 74) Given that the development of the interim soil vapour HILs was based on very conservative assumptions the initial Tier 1 assessment provided only a first-pass screening assessment of the data to determine if further risk assessment would be required

                The interim soil vapour HILs are applicable for the assessment of soil vapour at 0 to 1 m beneath the floor of a building They were based on adopted toxicity reference values (TRV) and relevant exposure parameters (ie adjusted for different land uses) as well as an assumed soil vapour to indoor air attenuation factor of 01

                The soil vapour to indoor air attenuation factor (01) was based on the US EPA (2002) recommended default attenuation factors for the generic screening step of a tiered vapour intrusion assessment process As discussed in the US EPA (2002) document the default attenuation factor of 01 for sub-slab soil vapour was based on a US EPA database of empirical attenuation factors calculated using measurements of indoor air and soil vapours from different sites In 2012 the US EPA provided an updated database which was accompanied by an evaluation and statistical analysis of attenuation factors for volatile CHC in residential buildings US EPA (2012) found the sub-slab to indoor air attenuation factor of 003 to be the 95th percentile In 2015 the revised sub-slab attenuation factor (003) was adopted by the US EPA

                PAGE 48 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                The revised sub-slab to indoor air attenuation factor of 003 was adopted to derive modified residential and commercialindustrial soil vapour HILs for the Tier 1 assessment The modified residential soil vapour HILs are presented in Table 91 relative to the maximum CHC concentrations obtained for soil vapour within the Thebarton EPA Assessment Area

                The Tier 1 assessment based on a comparison of the COPC concentrations measured in soil vapour at various locations within the Thebarton EPA Assessment Area with the modified residential soil vapour HILs detailed in Table 91 indicated the following

                TCE concentrations exceeded the adopted criterion in SV1 to SV9 whereas

                the concentrations of PCE and 11-DCE exceeded the adopted criteria in SV3 only

                These locations were identified as requiring further assessment (ie Tier 2 VIRA ndash refer to Section 95)15

                Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs

                Compound ASC NEPM (1999) HIL

                (microgm3)

                Modified Tier 1 HIL (microgm3)

                (AF = 003)

                Maximum measured soil vapour concentration (microgm3)

                Acceptable

                Location 1 m BGL Location 3 m BGL

                11-DCE 7000 SV3 5900 SV3 14000 No ndash Tier 2 required

                cis-12-DCE 80 265 SV2 21 SV4 30 Yes

                trans-12-DCE 80 265 - ND SV5 20 Yes

                PCE 2000 6650 SV3 6500 SV3 15000 No ndash Tier 2 required

                TCE 20 65 SV3 210000 SV3 100000 0

                No ndash Tier 2 required

                VC 30 100 - ND - ND Yes Notes Values in bold exceed the modified residential soil vapour HILs cis-12-DCE HIL adopted as surrogate screening criterion based on US EPA (2017b) regional screening level for residential air elevated laboratory LOR (ie above modified Tier 1 HIL) also reported Abbreviations AF = attenuation factor HIL = health investigation level ND = non detect

                95 Tier 2 assessment

                951 Tier 2 assessment criteria

                The Tier 2 VIRA criteria for the residential zone comprise HIL-based residential indoor air criteria for the COPC (refer to Section 94) along with the residential indoor air level response ranges for TCE that were

                15 Note that all locations were subjected to the Tier 2 VIRA in this assessment

                80607-1 REV1 30102017 PAGE 49

                EPA REF 0524111 FINAL REPORT

                STAGE 1 ENVIRONMENTAL ASSESSMENT

                THEBARTON ASSESSMENT AREA

                initially developed by the EPA and SA Health for the EPA Assessment Area at Clovelly Park and Mitchell

                Park These screening criteria and indoor air response ranges as detailed in SA EPA (2014) and

                reproduced in Figure 91 are now widely adopted in South Australia for the assessment of TCE relating

                to indoor air exposure

                Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels

                Note The no action response level is applicable where a soil vapour concentration is below the laboratory LOR (ie ND or ldquonon-

                detectrdquo assumed to be lt01 microgm3)

                PAGE 50 80607-1 REV1 | 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                952 Vapour intrusion modelling

                For this VIRA exposure point concentrations (EPCs) of COPC in the indoor air of buildings with a slab on grade crawl space or basement construction were estimated using conservative screening assumptions and the Johnson and Ettinger (1991) vapour transport and mixing model (ie the JampE model)

                The algorithms applied in the JampE (1991) model are detailed in Appendix A of the Arcadis report whereas the modelling spreadsheets for each scenario are provided in Appendix B ndash the Arcadis report is attached to this report as Appendix P

                9521 Input parameters

                The input parameters adopted for the vapour intrusion modelling relate to the following

                the construction type and details of existing or proposed buildings ndash refer to Table 92 for adopted building input parameters

                the nature of the soil profile ndash refer to Table 93 for adopted soil input parameters (0 to 1 m BGL) and

                the contaminant source concentrations ndash refer to Table 6 in Appendix L

                Table 92 Tier 2 vapour intrusion modelling ndash building input parameters

                Parameter Units Adopted value Reference

                Residential Commercial industrial

                Width of Building cm 1000 2000 Friebel and Nadebaum (2011)

                Length of Building cm 1500 2000

                Height of Room cm 240 300

                Height of crawl space cm 30 - Assumption for crawl space

                Attenuation from basement to ground floor air

                - 01 01 Friebel and Nadebaum (2011)

                Air Exchange Rate (AER)

                Indoor per hour 06 083 Friebel and Nadebaum (2011)

                Crawl space per hour 06 - Friebel and Nadebaum (2011)

                Basement per hour 06 - As per residential (indoor)

                Fraction of Cracks in Walls and foundation

                - 0001 0001 Friebel and Nadebaum (2011)

                Qsoil cm 3s 300 277 Calculated from QsoilQbuilding ratio of 0005 (residential) and 0001 (commercial)

                80607-1 REV1 30102017 PAGE 51

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters

                Parameter Units Adopted value Reference

                Depth cm 100 Depth of shallow soil vapour data

                Total porosity - 047 Site specific geotechnical data ndash ie averaged from MW3 and MW11 shallow samples (refer to Table 1 in Appendix L) Air filled porosity - 030

                Water filled porosity - 017 Notes ie representing a conservative approach whereby data for the shallow samples with the highest total porosity and lowest degree of saturation (and therefore the highest air filled porosity) have been adopted

                The site specific attenuation factors calculated within the vapour intrusion models (Appendix B of the Arcadis report) are summarised in Table 94 These are chemical and depth specific values applicable to each building construction scenario These attenuation factors have been applied to the soil vapour data measured across the Thebarton EPA Assessment Area to calculate indoor air concentrations (residential properties only) in proximity to each soil vapour location ndash for commercialindustrial properties (slab on grade) indoor air concentrations have only been calculated with respect to the soil vapour data obtained for SV3 (ie the soil vapour bore with the highest measured TCE concentrations)

                Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air

                Scenario Attenuation factor

                Residential ndash slab on grade 706 x 10-4

                Residential ndash crawl space 209 x 10-3

                Residential ndash basement 113 x 10-1

                Commercial ndash slab on grade 408 x 10-4

                Notes ie soil vapour intrusion to indoor air of residential living spaces refer to Section 953 for a discussion of potential vapour intrusion risks associated with commercialindustrial properties

                The chemical parameters of the COPC adopted in the JampE model were updated with data from the chemical database in the Risk Assessment Information System (RAIS 2016) as detailed in Table 95

                Table 95 Summary of chemical parameters adopted for vapour intrusion modelling

                Chemical Diffusivity in Air Diffusivity in Water Solubility Henryrsquos Law Molecular weight (Dair) Water (Dwater) (S) Constant 25oC (gmol)

                (cm2s) (cm2s) (mgL) (unitless)

                11-DCE 00863 0000011 2420 107 969

                PCE 00505 000000946 206 0724 166

                TCE 00687 00000102 1280 0403 131

                PAGE 52 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                9522 Predicted indoor air concentrations

                Residential The predicted indoor air concentrations for each soil vapour data point as calculated by Arcadis for the three residential building scenarios (ie slab on grade crawl space and basement) are presented in Appendix C of the Arcadis report (included in this report as Appendix P)

                Table 96 provides a comparison of predicted indoor air concentrations against the EPA response levels detailed in Section 951 (Figure 91) ndash ie using the 1 m soil vapour data space for slab on grade and crawl space scenarios versus the 3 m soil vapour data for basements

                It should be noted that if residential properties within the Thebarton EPA Assessment Area have basements however the vapour intrusion risks will increase whereas slab on grade construction will carry a lesser vapour intrusion risk (as detailed in Table 96)

                Commercialindustrial The predicted indoor air concentrations as calculated by Arcadis for a commercialindustrial (ie slab on grade) land use scenario with respect to the soil vapour data obtained for SV3 (ie maximum measured soil vapour concentrations) are as follows

                11-DCE 3 microgm3

                PCE 19 microgm3 and

                TCE 86 microgm3

                As these values are not directly comparable to the EPA response levels developed for residential land use further discussion of potential vapour intrusion risks to human health under a commercialindustrial land use

                scenario is included in Section 953

                As discussed for residential properties the vapour intrusion risks may increase if basements are present

                80607-1 REV1 30102017 PAGE 53

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Table 96 Comparison of predicted residential indoor air concentrations with SA EPA response levels

                Indoor Air Concentration Ranges (microgmsup3) SA EPA response levels

                non-detect No action

                gt non-detect to lt2 Validation

                2 to lt20 Investigation

                20 to lt200 Intervention

                ge200 Accelerated Intervention

                Soil vapour bore

                Sample depth

                (m)

                Soil vapour TCE concentration

                (microgmsup3)

                Predicted indoor air concentration (microgmsup3)

                Residential scenario

                Slab on grade Crawl space Basement

                Attenuation factor

                7 x 10-4 2 x 10-3 1 x 10-1

                SV1 10 5700 4 11

                SV1 30 21000 2100

                SV2 10 51000 36 102

                SV2 30 890000 89000

                SV2 (FD) 30 940000 94000

                SV3 10 210000 147 420

                SV3 30 1000000 100000

                SV4 10 17000 12 34

                SV4 30 43000 4300

                SV5 10 100000 70 200

                SV5 30 160000 16000

                SV6 10 22000 15 44

                SV6 (FD) 10 22000 15 44

                SV6 30 150000 15000

                SV6 (FD) 30 140000 14000

                SV7 10 22000 15 44

                SV7 30 110000 11000

                SV8 10 2300 2 5

                SV8 30 14000 1400

                SV9 10 170 012 030

                SV9 30 260 26

                SV10 10 9 0007 0019

                SV10 30 51 51

                SV11 10 lt18 - -

                SV12 10 16 0011 0032

                SV12 30 55 55

                SV13 10 lt21 - -

                PAGE 54 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Notes With respect to the predicted indoor air CHC concentrations in the Arcadis VIRA report (refer to Appendix P) the results in Table 5 were calculated for SV3 using the unrounded attenuation factors presented in Appendix B (and Table 94 of this report) whereas the TCE indoor air concentrations in Appendix C (as summarised in Table 96) were calculated using rounded attenuation factors ndash this does not change the overall interpretation of the results Abbreviations FD = field duplicate

                9523 Sensitivity analysis

                Table 97 presents a qualitative sensitivity analysis for some of the input variables used in the modelling ndash it includes the range of practical values for each variable the value used in the risk assessment the relative model sensitivity and the uncertainty associated with the variable

                Although Arcadis note that a number of parameters used within the risk assessment have a moderate degree of uncertainty associated with them thereby suggesting that the modelling may be sensitive to changes in these parameters values used to define these parameters were selected to be conservative This is considered to have resulted in an assessment which is expected to be conservative and to over-estimate actual risk

                Table 97 Summary of model input parameters subjected to sensitivity analysis

                Input Range of values Value adopted Sensitivity of calculated input parameters variable

                Soil physical parameters

                Total porosity

                Varies by soil type generally 03 to 05

                047 Site-specific

                Indoor air concentrations will decrease with increasing total porosity Moderate sensitivity parameter decreasing by 50 will increase predicted concentration by a factor of 4

                Air filled porosity

                Varies by soil type generally 015 to 03

                03 Site-specific

                Indoor air concentrations will increase with increasing air filled porosity Moderate to high sensitivity parameter reduction by 50 decreases concentration by a factor of 10

                Water filled porosity

                Varies by soil type from 005 (fill or

                sand) to 03 (clay)

                017 Site-specific

                Negligible impact on predicted indoor air concentrations although may decrease with increasing moisture content Very low sensitivity parameter

                Building parameters

                Air exchange rate (AER)

                Varies from 05 hr-1

                in smaller buildings to gt2 hr-1

                06 hr-1 for residential structures

                083 hr-1 for commercial

                Indoor air concentrations will decrease with increasing air exchange Moderate sensitivity parameter has linear relationship with predicted concentrations conservative assumptions used

                80607-1 REV1 30102017 PAGE 55

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Input Range of values Value adopted Sensitivity of calculated input parameters variable

                Advective flow rates

                Varies depending on building size and

                AER

                300 cm3sec Calculated from building AER and

                ratio of 0005

                Indoor air concentrations will increase with increasing advective flow Low sensitivity parameter particularly within normal range of potential values The assumption that advective flow is occurring into a building at all times is generally conservative for Australian settings Advection is unlikely to occur under a crawl space home and diffusive transport is the dominant transport mechanism

                Building size Variable Variable consistent with

                Friebel and Nadebaum (2011)

                Indoor air concentrations decrease with increasing building volume

                Very low sensitivity parameter

                9524 Uncertainties

                The following uncertainties were identified in the Arcadis report (Appendix P)

                Vapour transport modelling

                The use of a model to predict the migration of vapour from a sub-surface source to indoor air requires the simplification of many complex processes in the sub-surface as well as the potential for entry and dispersion within a building or outdoor air To address this simplification the vapour models available (and adopted in this assessment) are considered to be conservative such that uncertainties are addressed through the overshyestimation of likely concentrations

                It should be noted that the vapour model used is designed to be a first tier screening tool and is considered likely to over-estimate air concentrations due to the incorporation of a number of conservative assumptions including the following

                chemical concentrations in soil vapour were assumed to remain constant over the duration of exposure (ie it was assumed that the source was non-depleting and not subject to natural biodegradation processes)

                the maximum reported soil vapour concentrations were assumed to be present beneath nearby dwellings and

                the occurrence of steady well-mixed vapour dispersion within the enclosed or ambient mixing space

                Overall the vapour modelling undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

                PAGE 56 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Toxicological Data

                In general the available scientific information involves the extrapolation of toxicity information from studies involving experimental laboratory animals with some validation of observable health effects obtained through epidemiological studies

                This may introduce two types of uncertainties into the risk assessment as follows

                those related to extrapolating from one species to another and

                those related to extrapolating from the high exposure doses usually used in experimental animal studies to the lower doses usually estimated for human exposure situations

                In order to adjust for these uncertainties toxicity values commonly incorporate safety factors that may vary from 10 to 10000

                Overall the toxicological data presented in this assessment are considered to be current and adequate for the assessment of risks to human health associated with potential exposure to the COPC identified The uncertainties inherent in the toxicological values adopted are considered likely to result in an over-estimation of actual risk

                953 Potential vapour intrusion risks associated with commercialindustrial properties

                An assessment of potential vapour intrusion risks to workers at commercialindustrial properties (slab on grade construction) within the Thebarton EPA Assessment Area was undertaken by Arcadis using the methodology published by US EPA (2009) and incorporated into the ASC NEPM (1999) This approach recommends adjustment of the measured or estimated contaminant concentrations in air to account for site specific exposures by the relevant receptors as follows

                Ca ET EF EDECinh = days hours AT 365 24 year day

                Where

                ECinh = Exposure Adjusted Air Concentration (mgm3) Ca = Chemical Concentration in Air (mgm3) ET = Exposure Time (hoursday) EF = Exposure Frequency (daysyear) ED = Exposure Duration (years) AT = Averaging Time (years)

                = 70 years for non-threshold carcinogens = ED for chemicals assessed based on threshold effects

                80607-1 REV1 30102017 PAGE 57

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Exposure parameters were selected from Australian sources (enHealth 2012b ASC NEPM 1999) for the receptor groups evaluated or were based on site specific factors Table 98 presents an overview of the parameters used whereas adopted inhalation TRVs are presented in Table 99

                Risk was characterised for threshold and non-threshold effects for the COPC ndash spreadsheets presenting the risk calculations are provided in Appendix B of the Arcadis report (as included in Appendix P) For commercialindustrial properties the non-threshold risk level was calculated to be 3 x 10-5 (compared to a target risk level of 1 x 10-5) whereas the threshold risk level was calculated to be 10 (compared to a target risk level of 1) ndash these results indicated a potentially unacceptable vapour intrusion risk to commercialindustrial workers in the vicinity of the maximum soil vapour CHC concentrations (ie at SV3 ndash worst-case scenario based on maximum soil vapour concentrations)

                Table 98 Exposure parameters ndash Commercialindustrial workers

                Exposure parameter Units Value Reference

                Exposure frequency days year 365 ASC NEPM (1999)

                Exposure duration years 30 ASC NEPM (1999)

                Exposure time indoors hoursday 8 ASC NEPM (1999)

                Averaging time

                Non-threshold

                threshold

                Years

                years

                70

                30 ASC NEPM (1999)

                Table 99 Adopted inhalation toxicity reference values

                COPC Toxicity reference values

                Non-threshold (microgm3)

                Reference Threshold (microgm3)

                Reference

                11-DCE NA - 80 ATSDR (1994)

                PCE NA - 200 WHO (2006)

                TCE 41 US EPA (2011) IRIS 2 US EPA (2011) IRIS Notes Abbreviations NA = not applicable

                954 Potential risks to trenchmaintenanceutility workers

                Although trenchmaintenanceutility workers may be exposed to soil vapour concentrations as measured at 1 m BGL due to the short-term nature of such works their total intakes of TCE and other CHC will be low Assuming that a trenchmaintenanceutility worker may be exposed to TCE for a limited number of working days throughout the year (eg 20 days of 8 hours duration within an excavation) their intake will be approximately one fiftieth of the intake of a resident (who is assumed to be exposed 21 hours a day for 365 days a year)

                PAGE 58 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Therefore the management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air)

                96 Conclusions

                On the basis of the available data and the assessment presented in the Arcadis VIRA report (Appendix P) the following conclusions were provided

                Health risks for residents due to the intrusion of CHC in soil vapour into residential buildings with a slab on grade crawl space or basement construction were calculated to be above the adopted EPA response levels and risks to residents may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

                Health risks for commercial workers due to the intrusion of CHC in soil vapour into buildings with a slab on grade construction were calculated to be above the adopted target risk levels and risks to workers may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

                In the absence of specific information regarding building construction within the Thebarton EPA Assessment Area the predicted indoor air concentrations calculated from the 1 m BGL soil vapour data for a residential crawl space scenario are summarised in Table 910

                Table 910 Summary of properties with predicted indoor air concentrations (residential crawl space) above adopted EPA response levels

                EPA response level No of residential properties affected Indoor air concentration (microgm3) Response

                non-detect to lt2 Validation 9

                2 to lt20 Investigation 10

                20 to lt200 Intervention 8

                ge200 Accelerated intervention 3 Notes According to information provided by the EPA there are approximately 130 residential properties located in the Thebarton EPA Assessment Area calculated on the basis of cadastral boundaries ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial facility ndash these data would therefore need to be confirmed via a property survey

                80607-1 REV1 30102017 PAGE 59

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                10 CONCEPTUAL SITE MODEL

                As detailed in Table 101 a CSM has been developed for the Thebarton EPA Assessment Area on the basis of historical information (as summarised in Section 12 as well as Appendices A and B) and the data obtained during the recent Fyfe investigation program

                Table 101 Summary of existing information for the Thebarton EPA Assessment Area

                Topic Summarised Information

                Site Characterisation

                Identification of Assessment Area

                An approximately 27 ha Assessment Area located within the suburb of Thebarton has been defined by the EPA The boundaries of this area are detailed in Section 21 and illustrated on Figure 1

                History of land use Properties located within the Thebarton EPA Assessment Area have been used for a mixture of commercialindustrial and low density residential land uses over time Current commercialindustrial properties include a beverage factory in the north-eastern portion of the assessment area a refrigeration equipment facility a car dealership two hotels (at least one of which has a cellarbasement) automotive and other workshops and the Ice Arena Former commercialindustrial activities have been identified as including a gas works a mechanicrsquos workshop sheet metal working facilities and a farm machinery manufacturer

                Historical investigations

                Reports provided to Fyfe by the EPA that pertain to previous investigations undertaken within the Thebarton EPA Assessment Area have been reviewed and summarised in Appendix A Additional historical information is included in Appendix B

                Local geology Natural soils encountered from the surfacenear surface to the maximum drill depth of 19 m BGL across the Thebarton EPA Assessment Area were considered to be indicative of the Quaternary Pooraka and Hindmarsh Clay formations Whereas fill materials (ie sand gravelcrushed rock andor silt) were encountered to depths of up to 09 m BGL at a number of sampling locations underlying natural soils comprised mainly low to medium plasticity silty or sandy clays with variable gravel contents Geotechnical testing of subsurface soil samples collected from 10 drill cores indicated that the PSD comprised predominantly claysilt with lesser components of sand andor gravel ndash these soil samples were mostly classified as Clay although some were classified as Sandy Clay or Clayey Sand According to Stapledon (1971) the Hindmarsh Clay unit typically contains many structural features and defects which greatly influence its permeability thereby resulting in potential preferential pathways for the vertical and lateral movement of soil vapour and groundwater Such features were not specifically observed during the recent drilling and soil logging work although some gravel lenseslayers were identified

                Hydrogeology In accordance with Gerges (2006) and his classification of the Adelaide metropolitan area into a number of zones based on their individual hydrogeological characteristics the Thebarton EPA Assessment Area is located within Zone 3 (subzone 3E) to the west of the Para Fault It contains five to six Quaternary aquifers and three or four Tertiary aquifers Based on the most recent investigations the depth to water within the Q1 aquifer in the Thebarton EPA Assessment Area ranges from approximately 123 to 159 m BGL and groundwater flows in a general north-westerly direction with a relatively flat hydraulic gradient (000062 to 00012) Salinity levels (based on field EC readings) range from approximately 1230 to 3620 mgL TDS and a groundwater flow velocity range of approximately 44 to 23 myear has

                80607-1 REV1 30102017 PAGE 61

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Topic Summarised Information

                been inferred As detailed in Section 222 a search of the DEWNR (2017) WaterConnect database identified 59 bores within the general Thebarton area of which 18 are located within the Thebarton EPA Assessment Area Although (where recorded) bores were listed as having been installed primarily for monitoring investigation or observation purpose other purposes (for presumed Quaternary aquifer bores) included drainage domestic and industrial A BUA has identified realistic groundwater uses as potentially including potable residential irrigation and primary contact recreationaesthetics Based on proximity to the River Torrens freshwater ecosystem protection has also been considered ndash however since the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area this may not be a realistic beneficial use Since volatile contaminants have been detected within the Q1 aquifer a potential vapour flux risk to future site users has also been considered

                Hydrology No surface water bodies have been identified within the Thebarton EPA Assessment Area The closest surface water body is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west Current stormwater run-off within the Thebarton EPA Assessment Area is expected to be collected by localised (and engineered) drainage systems

                Fyfe Investigation Results

                Groundwater impacts Contaminants identified in groundwater beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected source site (ie the former Austral sheet metal works) in accordance with the predominant flow direction associated with the Q1 aquifer (refer to Figures 4 and 5) The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) but its north-western extent has not yet been determined (whereas its extent has been defined in all other directions)

                Soil vapour impacts Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction (refer to Figures 6 and 7) and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion The soil vapour samples with the maximum TCE concentrations (ie SV3_10m and SV3_30m) also had the highest PCE and 11-DCE concentrations (or elevated LOR) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-) Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE (ie SV2_30m SV3_10m SV3_30m and SV7_30m) exceeded the adopted HILs for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE

                PAGE 62 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Topic Summarised Information

                degradation has not yet resulted in its production (ie at measureable levels) Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

                Potential Exposure Pathways

                Contaminants of Based on the results of historical investigations the EPA identified a number of CHC as being of Potential Concern concern for the Thebarton EPA Assessment Area The main COPC was identified as TCE with

                additional COPC including PCE 12-DCE (cis- and trans-) VC and 11-DCE Further detail is provided in Section 14 These COPC were confirmed by the Fyfe investigations with TCE identified as both the main contaminant in groundwater and soil vapour and the main driver in terms of potential human health risks associated with vapour intrusion into buildings within the Thebarton EPA Assessment Area (refer to Section 9)

                Suspected source and The suspected source of the identified CHC groundwater (and soil vapour) impacts within the affected media Thebarton EPA Assessment Area is the former Austral sheet metal works located over multiple

                allotments between George and Maria Streets from the 1920s until the 1960s-1970s Previous investigations (Appendix A) had identified groundwater CHC impacts on part of this suspected source site The Fyfe investigations have concentrated on impacts within groundwater and soil vapour across the Thebarton EPA Assessment Area both of which generally correlate with the inferred north-westerly groundwater flow direction and are considered to be related to the previously identified dissolved phase groundwater CHC impacts

                Sensitive receptors The following sensitive receptors have been identified as potentially relevant to the Thebarton EPA Assessment Area Ecological groundwater ecosystems within the assessment area extending to at least Dew and Smith

                Streets (ie as the north-western extent of the groundwater CHC plume has not yet been determined) and

                the freshwater ecosystem of the River Torrens located at a distance of approximately 07 km in a hydraulically down-gradient (ie north-westerly) direction but not necessarily representing a groundwater receiving environment

                Human current and future occupants of and visitors to residential properties current and future workers on the source site and other commercialindustrial properties

                within the area current and future underground trenchmaintenanceutility workers and down-gradient groundwater bore users

                Contaminant Possible contaminant transport mechanisms associated with the CHC-impacted groundwater transport identified within the Q1 aquifer beneath the Thebarton EPA Assessment Area include mechanisms flow through the aquifer to a hydraulically down-gradient surface water body andor down-

                gradient groundwater bores vapour generation andor flow via subsurface preferential pathways (eg service trenches

                more permeable soils) and downward movement into underlying aquifers (eg dense non-aqueous phase liquid

                (DNAPL))

                80607-1 REV1 30102017 PAGE 63

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Topic Summarised Information

                Exposure Possible exposure mechanisms associated with impacted groundwater within the Thebarton mechanisms EPA Assessment Area include

                direct contact (eg during extractionuse of groundwater) incidental ingestion (eg during extractionuse of groundwater) and inhalation of vapours (eg during extractionuse of groundwater andor as a result of

                vapour intrusion into buildings)

                Assessment of Risk

                Groundwater risks The recent groundwater analytical results have indicated that the Q1 aquifer beneath the Thebarton EPA Assessment Area contains measurable concentrations of CHC (mainly TCE but also including PCE 12-DCE andor 11-DCE at some locations) Measured concentrations of TCE exceeded the adopted assessment criteria for potable andor primary contact recreation in wells MW02 MW3 MW5 MW6 MW11 MW12 MW14 MW15 MW17 MW20 MW21 and MW23 located on Admella Maria George Albert and Dew Streets as well as Light Terrace with maximum concentrations corresponding to the ldquocorerdquo area of the plume One well (MW25) contained a concentration of carbon tetrachloride that exceeded the adopted potable criterion Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

                Groundwater fate Although scattered detectable concentrations of 12-DCE have been measured in groundwater and transport across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE modelling daughter products has been interpreted to indicate that substantial dechlorination is not

                occurring Groundwater fate and transport modelling (refer to Section 8 and Appendix O) has predicted that the likely extent of the dissolved phase groundwater TCE plume over the next 100 years will extend by another 500 m beyond the boundaries of the current Thebarton EPA Assessment Area However no significant lateral plume expansion is expected

                Vapour intrusion risks A VIRA (refer to Section 9 and Appendix P) was undertaken to assess potential risks to human health from the intrusion of CHC vapours (primarily TCE) into indoor air from soil vapour The predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction in the absence of specific structural information) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and therefore require further action as follows 10 properties within the investigation range (2 to lt20 microgm3) eight properties within the intervention range (20 to lt200 microgm3) and three properties within accelerated intervention range (ge200 microgm3) All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3

                (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as

                PAGE 64 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Topic Summarised Information

                selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which are expected to be overly-conservative) ndash these results will be documented in a subsequent report Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed Management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air)

                Complete Exposure Pathways

                Identified pathways and areas of potential risk

                Based on the results of the recent Fyfe investigations (including the VIRA) and taking into account available historical information (Appendices A and B) and DEWNR (2017) WaterConnect bore information the following complete exposure pathways and associated risks are considered possible for the Thebarton EPA Assessment Area exposure (direct contact incidental ingestion andor inhalation of vapours) during use of

                groundwater for domestic (eg drinking water plumbing garden irrigation) andor recreational (eg filling of swimming poolsspas) purposes

                vapour intrusion into indoor air within 30 residential propertieslocated within the vicinity of soil vapour bores SV1 to SV9 (assuming crawl space construction) ndash although 19 of these properties are predicted to be in the validationinvestigation action level range 11 are predicted to be in the intervention action level range (with actual indoor air monitoring results for properties within the intervention action level range pending)

                vapour intrusion into residential cellarsbasements (if present) in the vicinity of soil vapour bores SV1 to SV10 and SV12 and

                vapour intrusion into the indoor air of commercialindustrial properties ndash although actual risks to site workers would require further specific considerationassessment

                In addition although only assessed in a qualitative manner to date trenchmaintenanceutility workers may also be at risk where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

                Notes calculated on the basis of cadastral boundaries and assuming crawl space construction ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial premises a property survey would be required to confirm building construction details and the number of individual residences affected

                80607-1 REV1 30102017 PAGE 65

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                11 CONCLUSIONS

                Between May and August 2017 Fyfe undertook an investigation of groundwater and soil vapour CHC impacts within an EPA-designated Assessment Area located in Thebarton South Australia The results of the investigation have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties A CSM has been developed from the field analytical and modelling results as presented in Section 10

                The following conclusions have been reached

                Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were present within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m in groundwater well MW17

                Groundwater within the Q1 aquifer is located at a depth of approximately 123 to 159 m BGL and flows in a general north-westerly direction (refer to Figure 4) ndash the closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred16 and the groundwater gradient beneath the Thebarton EPA Assessment area is relatively flat (ie 000062 to 00012)

                Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified to include domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux as assessed by the VIRA) and possibly also potable Although freshwater ecosystem protection was also considered the River Torrens is thought to comprise either a recharge boundary (ie discharging to local groundwater) or to not actually be hydraulically connected to the Q1 aquifer in this area

                Groundwater beneath parts of the Thebarton EPA Assessment Area contains detectable concentrations of various CHC and includes TCE and carbon tetrachloride (one location only) levels that exceed the adopted assessment criteria for potable use andor primary contact recreation ndash thereby indicating that groundwater would be unsuitable for drinking or the filling of swimming poolsspas In addition vapour flux could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the groundwater could be odorous

                16 ie as calculated by Fyfe based on available data

                80607-1 REV1 30102017 PAGE 67

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                The groundwater and soil vapour CHC impacts identified beneath parts of the Thebarton EPA Assessment Area are considered likely to have emanated from the former Austral sheet metal works located over multiple allotments between George and Maria Streets from the 1920s until the 1960sshy1970s The possible presence of on-going (primary andor secondary) source(s) at this property has not yet been investigated

                As depicted on Figures 6 and 7 the current extent of the soil vapour CHC (ie dominated by TCE) impacts has been determined to correspond to the mapped distribution of the groundwater TCE impacts (Figure 5) and is considered to be directly related to groundwater (rather than soil) CHC impacts Although no soil vapour impacts were detected at 1 m BGL in SV11 and SV1317 located near the eastern and western ends of Light Terrace respectively the north-western extents of the groundwater and soil vapour CHC impacts have not yet been determined In addition although the extent of the groundwater TCE plume has been delineated in all other directions the soil vapour TCE plume has not been delineated in any direction

                TCE is considered to be a primary contaminant as well as the dominant (ie in terms of concentration and extent) CHC in both groundwater and soil vapour ndash the presence of PCE and 11-DCE suggests however that more than one primary contaminant is present Although the detectable concentrations of 12-DCE (cis- and trans) are considered to have resulted from the breakdown of TCEPCE no VC has been detected in either groundwater or soil vapour ndash the scattered distribution and relatively low concentrations of 12-DCE as well as the absence of measurable VC have been interpreted to indicate that significant dechlorination of the primary contaminants has not occurred (despite the likely age of the plume ndash ie possibly up to about 90 years old)

                Although the COPC adopted for the soil vapour assessment program included various CHC (ie with TCE identified as the dominant contaminant in groundwater and soil vapour) the Tier 1 VIRA confirmed that TCE PCE and 11-DCE all exceeded the adopted vapour intrusion HILs Based primarily on its greater toxicity however the risk driver for the Thebarton EPA Assessment Area is considered to be TCE

                The VIRA (Tier 2) results for predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and that require further action as follows

                ― 10 properties within the investigation range (2 to lt20 microgm3)

                ― eight properties within the intervention range (20 to lt200 microgm3) and

                ― three properties within accelerated intervention range (ge200 microgm3)

                All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming

                17 noting that the laboratory LOR for TCE was elevated as compared to the other soil vapour samples

                PAGE 68 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises ndash refer to Table 96

                Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentration obtained for soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

                Although only assessed in a qualitative manner trenchmaintenanceutility workers may be at risk in areas where TCE concentrations at 1 m BGL are greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) ndash in this case appropriate management measures would be required to be adopted This should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

                80607-1 REV1 30102017 PAGE 69

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                12 DATA GAPS

                Based on the results obtained during the recent Fyfe investigations as well as available historical information (Appendices A and B) the following data gaps have been identified for the Thebarton EPA Assessment Area

                property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

                groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

                the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

                the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

                80607-1 REV1 30102017 PAGE 71

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                13 REFERENCES

                ANZECCARMCANZ (2000a) Australian Guidelines for Water Quality Monitoring and Reporting

                ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

                ASTM (2001) Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations ASTM Guide D7663-12

                ASTM (2006) Standard Guide for Soil Gas Monitoring in the Vadose Zone ASTM Guide D5314-92

                ATSDR (1994) Toxicological profile ndash 11-Dichloroethene httpswwwatsdrcdcgovToxProfilestpaspid=722amptid=130

                AustralianNew Zealand Standard (1998) Water Quality Sampling Part 1 Guidance on the Design of Sampling Programs Sampling Techniques and the Preservation and Handling of Samples ASNZS 566711998

                AustralianNew Zealand Standard (1998) Water Quality Sampling Part 11 Guidance on Sampling of Groundwaters ASNZS 5667111998

                Bouwer H and Rice RC (1976) A Slug Test Method for Determining Hydraulic Conductivity of Unconfined Aquifers with Completely or Partially Penetrating Wells Water Resources Research vol 12 no 3 pp 423-428

                Butler JJ Jr (1998) The Design Performance and Analysis of Slug Tests

                Cooper HH Bredehoeft JD and Papadopulos SS (1967) Response of a Finite-Diameter Well to an Instantaneous Charge of Water Water Resources Research vol 3 no 1 pp 263-269

                CRC CARE (2013) Petroleum Hydrocarbon Vapour Intrusion Assessment ndash Australian Guidance CRC CARE Technical Report No 23 July 2013

                Dagan G (1978) A Note on Packer Slug and Recovery Tests in Unconfined Aquifers Water Resources Research vol 14 no 5 pp 929-934

                Department of Environment Water and Natural Resources (DEWNR 2017) Water Connect Master Register of All Bores Primary Industries and Resources South Australia

                Duffield G (2007) AQTESOLVreg Professional Version 45 Hydrosolve Inc

                enHealth (2012a) Environmental Health Risk Assessment - Guidelines for assessing human health risks from environmental hazards enHealth Council

                enHealth (2012b) Australian Exposure Factor Guidance Handbook enHealth Council

                Environment Protection Act 1993

                80607-1 REV1 30102017 PAGE 73

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                Environment Protection Regulations 2009

                Friebel E and Nadebaum P (2011) Health Screening Levels for Petroleum Hydrocarbons in Soil and Groundwater CRC CARE Technical Report No 10

                Gerges NZ (1999) The Geology and Hydrogeology of the Adelaide Metropolitan Area Flinders University (South Australia) PhD thesis (unpublished)

                Gerges NZ (2006) Overview of the Hydrogeology of the Adelaide Metropolitan Area DWLBC Report 200610

                Golder Associates (1994) Contamination Assessment George Street Thebarton SA Report to United Land dated 9 December 1994

                Hvorslev MJ (1951) Time Lag and Soil Permeability in Ground-Water Observations Bulletin no 36 Waterways Exper Sta Corps of Engrs US Army Vicksburg Mississippi pp 1-50

                Hyder Z Butler JJ Jr McElwee CD and Liu W (1994) Slug Tests in Partially Penetrating Wells Water Resources Research vol 30 no 11 pp 2945-2957

                ITRC (2007) Vapor Intrusion Pathway - A Practical Guidance

                Johnson PC and Ettinger RA (1991) Heuristic Model for Predicting the Intrusion Rate of Contaminant Vapors

                into Buildings Environ Sci Technology 251445-1452

                McDonald M G and Harbaugh A W (1988) A Modular Three-Dimensional Finite-Difference Ground-Water Flow Model Techniques of Water-Resources Investigations Book 6 Chapter A1 U S Geological Survey

                NEPM (1999) National Environment Protection (Assessment of Site Contamination) Measure Schedules B1 to

                B9 National Environment Protection Council Australia

                NHMRC (2008) Guidelines for Managing Risks in Recreational Water

                NHMRCNRMMC (2011) Australian Drinking Water Guidelines (as revised in 2016)

                NJDEP (2013) Site Remediation Program Vapor Intrusion Technical Guidance (Version 31)

                NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme (2nd edition)

                Payne FC Quinnan JA and Potter ST (2008) Remediation Hydraulics CRC Press Boca Raton FL

                RAIS (2016) Chemical Specific Parameters for Trichloroethylene Risk Assessment Information System Office of Environmental Management US Department of Energy

                REM (2005a) George St Thebarton Site ndash Stage 2 Investigations Report to Luca Group dated 26 August 2005

                REM (2005b) Stage 3 Environmental Site Assessment George St Thebarton SA Report to Luca Group dated 23 November 2005

                SA Department of Mines and Energy (1969) 1250000 Adelaide Geological Map Sheet Sheet S1 54-9

                PAGE 74 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                SA EPA (2007) Regulatory Monitoring and Testing Groundwater Sampling

                SA EPA (2009) Guidelines for the Assessment and Remediation of Groundwater Contamination

                SA EPA (2014) Clovelly Park Mitchell Park Project Management Team Assessment Program Flip Book November 2014

                SA EPA (2015) Environment Protection (Water Quality) Policy

                Standards Australia (1993) Geotechnical Site Investigations AS1726-1993

                Standards Australia (2005) Guide to the Sampling and Investigation of Potentially Contaminated Soil Part 1 Non-Volatile and Semi-Volatile Compounds AS44821-2005

                Stapledon DH (1971) Changes and Structural Defects Developed in some South Australian Clays and their Engineering Consequences Proceedings of Symposium on Soils and Earth Structures in Arid Climates Adelaide 1970

                US EPA (1996) Soil Screening Guidance Technical Background Document Office of Emergency and Remedial Response Washington DC EPA540R95128

                US EPA (1999) Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air Second Edition Compendium Method TO-15 Determination Of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed By Gas Chromatography Mass Spectrometry (GCMS) EPA625R-96010b

                US EPA (2002) OSWER Draft Guidance for Evaluating the Vapour Intrusion to Indoor Air Pathway from Groundwater and Soils (Subsurface Vapour Intrusion Guidance) EPA530-D-02-004

                US EPA (2009) EPArsquos Risk-Screening Environmental Indicators (RSEI) Methodology Office of Pollution Prevention and Toxics Washington DC

                US EPA (2011) IRIS (Integrated Risk Information System) Trichloroethylene Chemical Assessment Summary httpscfpubepagovnceairisiris_documentsdocumentssubst0199_summarypdf

                US EPA (2012) EPArsquos Vapor Intrusion Database Evaluation and Characterization of Attenuation Factors for Chlorinated Volatile Organic Compounds and Residential Buildings

                US EPA (2015) OSWER Technical Guide for Assessing and Mitigating the Vapour Intrusion Pathway from Subsurface Vapour Sources to Indoor Air

                US EPA (2017a) Regional Screening Levels (RSLs) - Generic Tables (June 2017) httpswwwepagovriskregional-screening-levels-rsls-generic-tables-june-2017

                US EPA (2017b) Regional Screening Levels for Chemical Contaminants at Superfund Sites httpwwwepagovreg3hwmdriskhumanrb-concentration_tableGeneric_Tablesindexhtm

                80607-1 REV1 30102017 PAGE 75

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                WHO (2006) Air Quality Guidelines for Europe Second Edition WHO Regional Publications European Series No 91

                WHO (2017) Guidelines for Drinking-water Quality Fourth edition (incorporating the first addendum)

                Wiedemeier T Swanson M Moutoux D Gordon E Wilson J Wilson B Kampbell D Haas P Miller R Hansen J and Chapelle F (1998) Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water National Risk Management Research Laboratory Office of Research and Development US EPA

                Zheng C (1990) MT3D A Modular Three-Dimensional Transport Model for Simulation of Advection Dispersion and Chemical Reactions of Contaminants in Groundwater Systems Prepared for US EPA by Robert S Kerr Environmental Research Laboratory Ada Oklahoma developed by SS Papadopulos amp Associates Inc Rockville Maryland

                PAGE 76 80607-1 REV1 30102017

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                14 STATEMENT OF LIMITATIONS

                The opinions and conclusions presented in this report are specific to the conditions of the Thebarton EPA Assessment Area and the state of legislation currently enacted as at the date of this report Fyfe does not make any representation or warranty that the opinions and conclusions in this report will be applicable in the future as there may be changes in the condition of the Thebarton EPA Assessment Area applicable legislation or other factors that would affect the opinions and conclusions contained in this report

                Fyfe has used the degree of skill and care ordinarily exercised by reputable members of our profession practising in the same or similar locality This report has been prepared for the South Australian Environment Protection Authority for the specific purpose identified in the report Fyfe accepts no liability or responsibility to any third party for the accuracy of any information contained in the report or any opinion or conclusion expressed in the report Neither the whole of the report nor any part or reference thereto may be in any way used relied upon or reproduced by any third party without Fyfersquos prior written approval This report must be read in its entirety including all tables and attachments

                80607-1 REV1 30102017 PAGE 77

                EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                FIGURES

                Figure 1 Site Location and Assessment Area

                Figure 2 Assessment Point Locations

                Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan

                Figure 4 Groundwater Elevation Contour Plan

                Figure 5 Groundwater Concentration Plan

                Figure 6 Soil Vapour Concentration Plan (10m)

                Figure 7 Soil Vapour Concentration Plan (30m)

                80607-1 REV1 30102017 PAGE 79

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                DEW

                STREET

                DEW

                STREET

                CHAPEL STREETCHAPEL STREET

                PAR

                KER

                STREET

                PAR

                KER

                STREET

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                LIGHT TERRACELIGHT TERRACE

                DEW

                STREET

                DEW

                STREET

                WA

                LSH ST

                WA

                LSH ST

                AD

                MELLA

                STREET

                AD

                MELLA

                STREET

                ALB

                ERT STR

                EETA

                LBER

                T STREET

                HO

                LLAN

                D ST

                REET

                HO

                LLAN

                D ST

                REET

                RANDOLPH STREET

                RANDOLPH STREET

                JAM

                ES STREET

                JAM

                ES STREET

                DOVE STREET

                DOVE STREET

                SMITH STREETSMITH STREET

                MARIA STREETMARIA STREET

                GEORGE STREETGEORGE STREET

                KINTORE STREET

                KINTORE STREET

                PORT ROAD

                PORT ROAD

                PORT ROAD

                PORT ROAD

                CAW

                THO

                RN

                E STR

                EETC

                AWTH

                OR

                NE ST

                REET

                DEVON STREETDEVON STREET

                KINTORE STREETKINTORE STREET

                GOODENOUGH STREETGOODENOUGH STREET

                LIVESTR

                ON

                G PATH

                WAY

                LIVESTR

                ON

                G PATH

                WAY

                CCAAWW

                TTHHOO

                RRNN

                EE SSTTRR

                EEEETT

                HHOO

                LLLLAANN

                DD SSTT

                RREEEETT

                DE

                DEW

                SW

                STREET

                TREET

                JJAM

                EA

                MES S

                S STREET

                TREET

                DDOOVVEE SSTTRREEEETT

                LLIIVVEESSTTRR

                OONN

                GG PPAATTHH

                WWAAYY

                LIGHT TERRLIGHT TERRAACECE

                AD

                MELLA

                SA

                DM

                ELLA STR

                EETTR

                EET

                CHAPEL SCHAPEL STREETTREET

                AALLBB

                EERRTT SSTTRR

                EEEETT

                GEGEORORGE SGE STREETTREET

                PPOORRTT RROOAADD

                PPOORRTT RROOAADD

                DDEEWW

                SSTTRREEEETT

                MMAARRIIAA SSTTRREEEETT

                JJAAMM

                EESS CCOO

                NNGG

                DDOO

                NN DD

                RRIIVV

                EE

                WWAA

                LLSSHH SSTT

                SSMMIITTHH SSTTRREEEETT

                RRANDOLPH S

                ANDOLPH STREETTREET

                PPOORR

                TT RROO

                AADD

                PPOORR

                TT RROO

                AADD

                KKIINNTTOORREE SSTTRREEEETT

                KKIINNTTOORREE SSTTRREEEETT

                PPAARR

                KKEERR

                SSTTRREEEETT

                GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                DDEEVVOONN SSTTRREEEETT

                ASSESSMENT AREA

                CBD

                750m

                LEGEND

                EPA ASSESSMENT AREA

                CADASTRE

                12500 A3

                0 25 50 m

                CLIENT

                SA EPA

                PROJECT

                FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

                EPA THEBARTON ASSESSMENT AREA - STAGE 1

                TITLE

                FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

                PROJECT NO DATE CREATED

                80607-1 290917

                80607_Fig 1 - Site Location and Assessment Areaai REV 1 gt 290917

                LE

                VE

                L 1

                12

                4 S

                OU

                TH

                TE

                RR

                AC

                E

                AD

                EL

                AID

                E S

                A 5

                00

                0

                P

                H

                (08

                ) 8

                23

                2 9

                08

                8

                F

                AX

                (0

                8)

                82

                32

                90

                99

                EM

                AIL

                in

                fo

                fyfe

                co

                ma

                u

                W

                EB

                fy

                fec

                om

                au

                AB

                N

                57

                00

                8 1

                16 1

                30

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                DEW

                STREET

                DEW

                STREET

                CHAPEL STREETCHAPEL STREET

                PAR

                KER

                STREET

                PAR

                KER

                STREET

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                LIGHT TERRACELIGHT TERRACE

                DEW

                STREET

                DEW

                STREET

                WA

                LSH ST

                WA

                LSH ST

                AD

                MELLA

                STREET

                AD

                MELLA

                STREET

                ALB

                ERT STR

                EETA

                LBER

                T STREET

                HO

                LLAN

                D ST

                REET

                HO

                LLAN

                D ST

                REET

                RANDOLPH STREET

                RANDOLPH STREET

                JAM

                ES STREET

                JAM

                ES STREET

                DOVE STREET

                DOVE STREET

                SMITH STREETSMITH STREET

                MARIA STREETMARIA STREET

                GEORGE STREETGEORGE STREET

                KINTORE STREET

                KINTORE STREET

                PORT ROAD

                PORT ROAD

                PORT ROAD

                PORT ROAD

                CAW

                THO

                RN

                E STR

                EETC

                AWTH

                OR

                NE ST

                REET

                DEVON STREETDEVON STREET

                KINTORE STREETKINTORE STREET

                GOODENOUGH STREETGOODENOUGH STREET

                LIVESTR

                ON

                G PATH

                WAY

                LIVESTR

                ON

                G PATH

                WAY

                SV1SV1

                SV2SV2

                SV3SV3SV4SV4

                SV5SV5

                SV6SV6

                SV7SV7SV8SV8

                SV9SV9

                SV10SV10

                SV11SV11SV12SV12

                SV13SV13

                MW1MW1

                MW02MW02

                MW3MW3

                MW4MW4MW5MW5MW6MW6

                MW7MW7

                MW8MW8

                MW9MW9

                MW10MW10MW11MW11

                MW12MW12MW13MW13

                MW14MW14MW15MW15

                MW16MW16

                MW17MW17

                MW18MW18

                MW19MW19

                MW20MW20

                MW21MW21

                MW22MW22

                MW23MW23

                MW24MW24

                MW25MW25

                MW26MW26

                WMS2WMS2WMS1WMS1

                WMS3WMS3WMS4WMS4WMS5WMS5

                WMS6WMS6

                WMS7WMS7WMS8WMS8

                WMS9WMS9WMS10WMS10

                WMS11WMS11

                WMS12WMS12

                WMS13WMS13WMS14WMS14

                WMS15WMS15

                WMS41WMS41

                WMS40WMS40

                WMS39WMS39WMS38WMS38

                WMS16WMS16

                WMS17WMS17

                WMS18WMS18WMS19WMS19

                WMS20WMS20

                WMS21WMS21WMS22WMS22

                WMS23WMS23WMS24WMS24

                WMS25WMS25

                WMS26WMS26

                WMS27WMS27WMS28WMS28WMS29WMS29

                WMS30WMS30

                WMS31WMS31

                WMS32WMS32

                WMS33WMS33

                WMS34WMS34

                WMS35WMS35

                WMS36WMS36

                WMS37WMS37

                WWAA

                LLSSHHSSTT

                SSMMIITTHH SSTTRREEEETT

                RRANDOLPH S

                ANDOLPH STREETTREET

                PPOORR

                TT RROO

                AADD

                PPOORR

                TT RROO

                AADD

                CCAAWW

                TTHHOO

                RRNN

                EE SSTTRR

                EEEETT

                JJAM

                EA

                MES S

                S STREET

                TREET

                HHOO

                LLLLAANN

                DDSSTT

                RREEEETT

                DE

                DEW

                SW

                STREET

                TREET

                DDOOVVEE SSTTRREEEETT

                LLIIVVEESSTTRR

                OONN

                GGPPAATTHH

                WWAAYY

                LIGHT TERRLIGHT TERRAACECE

                CHAPEL SCHAPEL STREETTREET

                AALLBB

                EERRTT SSTTRR

                EEEETT

                AD

                MELLA

                SA

                DM

                ELLA STR

                EETTR

                EET

                GEGEORORGE SGE STREETTREET

                PPOORRTT RROOAADD PPOORRTT RROOAADD

                DDEEWW

                SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

                JJAAMM

                EESS CCOO

                NNGG

                DDOO

                NN DD

                RRIIVV

                EE

                KKIINNTTOORREE SSTTRREEEETT

                KKIINNTTOORREE SSTTRREEEETT

                PPAARR

                KKEERR

                SSTTRREEEETT

                GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                DDEEVVOONN SSTTRREEEETT

                FIGURE 2 ASSESSMENT POINT LOCATIONS

                MMWW88

                MW2MW244 WMS3WMS355

                MW2MW255

                WMS3WMS366

                WMS3WMS377

                WMS3WMS311

                MW2MW222WMS34WMS34

                MW2MW233 WMS3WMS322

                WMS3WMS333

                WMS2WMS277WMS2WMS299 WMS2WMS288

                SSV12V12 SSVV1111 MW19MW19

                MW18MW18 SSVV1133 MW2MW200 WMS3WMS300

                MW2MW211 WMS2WMS255

                WMS2WMS266

                MW17MW17 WMS2WMS244

                WMS2WMS233

                WMS2WMS222 WMS2WMS211

                SSVV99

                SSV10V10WMS2WMS200 MW14MW14MW15MW15 WMS18WMS18

                WMS19WMS19 MW16MW16

                WMS13WMS13MW10MW10 WMS14WMS14MMWW1111SVSV77WMS15WMS15SSVV88WMS16WMS16

                SVSV66WMS4WMS411MW13MW13 LEGENDMW12MW12

                WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS17WMS17 WMS40WMS40 SSVV55 MW0MW022MW9MW9 GROUNDWATER MONITORING WELL

                WMS11WMS11 WMS6WMS6 SOIL VAPOUR BORE

                WATERLOO MEMBRANE SAMPLERTM - ROUND 2

                SVSV22WMS8WMS8SVSVWMS12WMS12 44 WMS7WMS7 MW4MW4MMWW SVSV66 33 MW5MW5WMS3WMS388

                WMS3WMS399 MW7MW7 EPA ASSESSMENT AREAWMS10WMS10 WMS9WMS9

                SVSV11 CADASTRE

                MW3MW3

                MW1MW1 WMS3WMS3WMS4WMS4MW2MW266 WMS5WMS5 12500 A3

                0 25 50 m

                CLIENT

                SA EPAWMS1WMS1

                WMS2WMS2 PROJECT

                EPA THEBARTON ASSESSMENT AREA - STAGE 1

                TITLE

                FIGURE 2 ASSESSMENT POINT LOCATIONS

                PROJECT NO DATE CREATED

                80607-1 280917

                80607_Fig 2 - Assessment Point Locationsai REV 1 gt 280917

                LE

                VE

                L 1

                12

                4 S

                OU

                TH

                TE

                RR

                AC

                E

                AD

                EL

                AID

                E S

                A 5

                00

                0

                PH

                (0

                8)

                82

                32

                90

                88

                F

                AX

                (0

                8)

                82

                32

                90

                99

                E

                MA

                IL

                info

                fy

                fec

                om

                au

                W

                EB

                fy

                fec

                om

                au

                A

                BN

                5

                7 0

                08

                116

                13

                0

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                DEW

                STREET

                DEW

                STREET

                CHAPEL STREETCHAPEL STREET

                PAR

                KER

                STREET

                PAR

                KER

                STREET

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                LIGHT TERRACELIGHT TERRACE

                DEW

                STREET

                DEW

                STREET

                WA

                LSH ST

                WA

                LSH ST

                AD

                MELLA

                STREET

                AD

                MELLA

                STREET

                ALB

                ERT STR

                EETA

                LBER

                T STREET

                HO

                LLAN

                D ST

                REET

                HO

                LLAN

                D ST

                REET

                RANDOLPH STREET

                RANDOLPH STREET

                JAM

                ES STREET

                JAM

                ES STREET

                DOVE STREET

                DOVE STREET

                SMITH STREETSMITH STREET

                MARIA STREETMARIA STREET

                GEORGE STREETGEORGE STREET

                KINTORE STREET

                KINTORE STREET

                PORT ROAD

                PORT ROAD

                PORT ROAD

                PORT ROAD

                CAW

                THO

                RN

                E STR

                EETC

                AWTH

                OR

                NE ST

                REET

                DEVON STREETDEVON STREET

                KINTORE STREETKINTORE STREET

                GOODENOUGH STREETGOODENOUGH STREET

                LIVESTR

                ON

                G PATH

                WAY

                LIVESTR

                ON

                G PATH

                WAY

                WMS2WMS2WMS1WMS1

                WMS3WMS3WMS4WMS4

                WMS5WMS5

                WMS6WMS6

                WMS7WMS7WMS8WMS8

                WMS9WMS9

                WMS10WMS10

                WMS11WMS11

                WMS12WMS12

                WMS13WMS13WMS14WMS14

                WMS15WMS15 WMS41WMS41

                WMS40WMS40

                WMS39WMS39WMS38WMS38

                WMS16WMS16

                WMS17WMS17

                WMS18WMS18WMS19WMS19WMS20WMS20

                WMS21WMS21WMS22WMS22

                WMS23WMS23WMS24WMS24

                WMS25WMS25

                WMS26WMS26

                WMS27WMS27WMS28WMS28WMS29WMS29

                WMS30WMS30

                WMS31WMS31

                WMS32WMS32WMS33WMS33

                WMS34WMS34

                WMS35WMS35

                WMS36WMS36

                WMS37WMS37

                WWAA

                LLSSHHSSTT

                SSMMIITTHH SSTTRREEEETT

                RRANDOLPH S

                ANDOLPH STREETTREET

                PPOORR

                TT RROO

                AADD

                PPOORR

                TT RROO

                AADD

                CCAAWW

                TTHHOO

                RRNN

                EE SSTTRR

                EEEETT

                JJAM

                EA

                MES S

                S STREET

                TREET

                HHOO

                LLLLAANN

                DDSSTT

                RREEEETT

                DE

                DEW

                SW

                STREET

                TREET

                DDOOVVEE SSTTRREEEETT

                LLIIVVEESSTTRR

                OONN

                GGPPAATTHH

                WWAAYY

                LIGHT TERRLIGHT TERRAACECE

                AD

                MELLA

                SA

                DM

                ELLA STR

                EETTR

                EET

                AALLBB

                EERRTT SSTTRR

                EEEETT

                CHAPEL SCHAPEL STREETTREET

                GEGEORORGE SGE STREETTREET

                PPOORRTT RROOAADD PPOORRTT RROOAADD

                DDEEWW

                SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

                JJAAMM

                EESS CCOO

                NNGG

                DDOO

                NN DD

                RRIIVV

                EE

                KKIINNTTOORREE SSTTRREEEETT

                KKIINNTTOORREE SSTTRREEEETT

                PPAARR

                KKEERR

                SSTTRREEEETT

                GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                DDEEVVOONN SSTTRREEEETT

                FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

                TCE CONCENTRATION PLAN

                WMS3WMS355 TCE lt78

                WMS3WMS366 TCE lt77WMS3WMS377

                TCE 44

                WMS3WMS311 TCE lt78

                WMS34WMS34 TCE 11

                WMS3WMS322WMS3WMS333 TCE lt78TCE lt79

                WMS2WMS277WMS2WMS299 WMS2WMS288 TCE 64 TCE lt77 TCE lt8

                WMS3WMS300 TCE lt8

                WMS2WMS255

                WMS2WMS266 TCE 1400(D)

                WMS2WMS222 TCE 38 WMS2WMS211

                TCE lt79

                TCE lt78

                WMS2WMS233 WMS2WMS244 TCE lt77

                TCE 230

                WMS2WMS200 WMS19WMS19TCE lt78 WMS18WMS18 TCE 11000

                TCE 4200

                WMS13WMS13 WMS14WMS14 TCE lt79

                WMS4WMS411WMS15WMS15 TCE 46000WMS16WMS16 TCE 18000 LEGENDTCE lt8

                TCE lt78WMS17WMS17 WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS40WMS40TCE lt79

                TCE 110000 WATERLOO MEMBRANE SAMPLERTM - ROUND 2WMS11WMS11

                TCE 71000WMS12WMS12 EPA ASSESSMENT AREA

                CADASTRE

                WMS6WMS6 TCE lt58 WMS8WMS8 WMS3WMS388 TCE 32WMS7WMS7WMS3WMS399

                TCE 12000 TCE 13000 TCE 1900TCE 1300WMS9WMS9 TCE lt58 NotesWMS10WMS10

                All concentrations are in μgm3 TCE lt58

                D = Duplicate result

                WMS3WMS3WMS4WMS4 12500 A3

                LE

                VE

                L 1

                12

                4 S

                OU

                TH

                TE

                RR

                AC

                E

                AD

                EL

                AID

                E S

                A 5

                00

                0

                PH

                (0

                8)

                82

                32

                90

                88

                F

                AX

                (0

                8)

                82

                32

                90

                99

                E

                MA

                IL

                info

                fy

                fec

                om

                au

                W

                EB

                fy

                fec

                om

                au

                A

                BN

                5

                7 0

                08

                116

                13

                0

                TCE lt57WMS5WMS5 TCE lt57 TCE lt58 0 25 50

                m

                CLIENT

                SA EPA

                WMS2WMS2 TCE lt56

                WMS1WMS1 TCE lt56

                PROJECT

                EPA THEBARTON ASSESSMENT AREA - STAGE 1

                TITLE

                FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

                TCE CONCENTRATION PLAN

                PROJECT NO DATE CREATED

                80607-1 241017

                80607_Fig 3 - WMS TCE Concentration Planai REV 1 gt 241017

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                DEW

                STREET

                DEW

                STREET

                CHAPEL STREETCHAPEL STREET

                PAR

                KER

                STREET

                PAR

                KER

                STREET

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                LIGHT TERRACELIGHT TERRACE

                DEW

                STREET

                DEW

                STREET

                WA

                LSH ST

                WA

                LSH ST

                AD

                MELLA

                STREET

                AD

                MELLA

                STREET

                ALB

                ERT STR

                EETA

                LBER

                T STREET

                HO

                LLAN

                D ST

                REET

                HO

                LLAN

                D ST

                REET

                RANDOLPH STREET

                RANDOLPH STREET

                JAM

                ES STREET

                JAM

                ES STREET

                DOVE STREET

                DOVE STREET

                SMITH STREETSMITH STREET

                MARIA STREETMARIA STREET

                GEORGE STREETGEORGE STREET

                KINTORE STREET

                KINTORE STREET

                PORT ROAD

                PORT ROAD

                PORT ROAD

                PORT ROAD

                CAW

                THO

                RN

                E STR

                EETC

                AWTH

                OR

                NE ST

                REET

                DEVON STREETDEVON STREET

                KINTORE STREETKINTORE STREET

                GOODENOUGH STREETGOODENOUGH STREET

                LIVESTR

                ON

                G PATH

                WAY

                LIVESTR

                ON

                G PATH

                WAY

                MW1MW1

                MW02MW02

                MW3MW3

                MW4MW4MW5MW5

                MW6MW6

                MW7MW7

                MW8MW8

                MW9MW9

                MW10MW10MW11MW11

                MW12MW12

                MW13MW13

                MW14MW14

                MW15MW15

                MW16MW16

                MW17MW17

                MW18MW18

                MW19MW19MW20MW20

                MW21MW21

                MW22MW22

                MW23MW23

                MW24MW24

                MW25MW25

                MW26MW26

                WWAA

                LLSSHHSSTT

                SSMMIITTHH SSTTRREEEETT

                4

                466

                PPOORR

                TT RROO

                AADD

                PPOORR

                TT RROO

                AADD

                RRANDOLPH S

                ANDOLPH STREETTREET 4455

                DE

                DEW

                SW

                STREET

                TREET

                JJAM

                EA

                MES S

                S STREET

                TREET

                HHOO

                LLLLAANN

                DD SSTT

                RREEEETT

                CCAAWW

                TTHHOO

                RRNN

                EE SSTTRR

                EEEETT 4477

                DDOOVVEE SSTTRREEEETT

                4455

                4488

                LLIIVVEESSTTRR

                OONN

                GGPPAATTHH

                WWAAYY

                4455

                LIGHT TERRLIGHT TERRAACECE

                AD

                MELLA

                SA

                DM

                ELLA STR

                EETTR

                EET

                4466

                CHAPEL SCHAPEL STREETTREET

                4477 AA

                LLBBEERR

                TT SSTTRREEEETT

                4499

                GR4466 OUND

                FLOW DIREW

                GEGEORORGE SGE STREETTREET ATER C

                4488 TION

                PPOORRTT RROOAADD PPOORRTT RROOAADD 55

                00 DD

                EEWW SSTTRR

                EEEETT 4499

                MMAARRIIAA SSTTRREEEETT

                4477

                5500

                JJAAMM

                EESS CCOO

                NNGG

                DDOO

                NN DD

                RRIIVV

                EE

                88 44

                KKIINNTTOORREE SSTTRREEEETT

                KKIINNTTOORREE SSTTRREEEETT

                PPAARR

                KKEERR

                SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                5500

                4499

                DDEEVVOONN SSTTRREEEETT

                FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

                Groundwater SWL MMWW88 Monitoring Well (m AHD)

                MW1 5011 MW2MW244

                MW02 4786

                MW3 484

                MW2MW255 MW4 507

                MW5 4833

                MW6 4794

                MW7 4703

                MW8 4581

                MW9 4728

                MW10 4871

                MW11 4785 MW2MW222

                MW12 4689

                MW13 4662

                MW2MW233 MW14 4723

                MW15 464

                MW16 4577

                MW17 4619

                MW18 4538

                MW19 4735

                MW20 457

                MW21 4531

                MW22 4501

                MW23 4497

                MW24 4537

                MW25 4469

                MW26 4918

                MW19MW19 MW2MW200

                MW2MW211MW18MW18

                MW17MW17

                MW14MW14

                MW15MW15

                MW16MW16

                MW10MW10 LEGEND MMWW1111

                GROUNDWATER MONITORING WELLMW12MW12

                50 INFERRED GROUNDWATER ELEVATION CONTOUR

                MW13MW13

                MW0MW022 INFERRED GROUNDWATER FLOW DIRECTION

                EPA ASSESSMENT AREA

                MW9MW9

                MW5MW5 CADASTREMMWW66 MW4MW4

                MW7MW7 Note This is one interpretation only Other interpretations possibleMW3MW3

                12500 A3

                0 25 50 m

                CLIENT

                SA EPA

                PROJECT

                EPA THEBARTON ASSESSMENT AREA - STAGE 1

                TITLE

                FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

                PROJECT NO DATE CREATED

                80607-1 290917

                MW1MW1 MW2MW266

                80607_Fig 4 - Groundwater Elevation Contour Planai REV 1 gt 290917

                LE

                VE

                L 1

                12

                4 S

                OU

                TH

                TE

                RR

                AC

                E

                AD

                EL

                AID

                E S

                A 5

                00

                0

                PH

                (0

                8)

                82

                32

                90

                88

                F

                AX

                (0

                8)

                82

                32

                90

                99

                E

                MA

                IL

                info

                fy

                fec

                om

                au

                W

                EB

                fy

                fec

                om

                au

                A

                BN

                5

                7 0

                08

                116

                13

                0

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                DEW

                STREET

                DEW

                STREET

                CHAPEL STREETCHAPEL STREET

                PAR

                KER

                STREET

                PAR

                KER

                STREET

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                LIGHT TERRACELIGHT TERRACE

                DEW

                STREET

                DEW

                STREET

                WA

                LSH ST

                WA

                LSH ST

                AD

                MELLA

                STREET

                AD

                MELLA

                STREET

                ALB

                ERT STR

                EETA

                LBER

                T STREET

                HO

                LLAN

                D ST

                REET

                HO

                LLAN

                D ST

                REET

                RANDOLPH STREET

                RANDOLPH STREET

                JAM

                ES STREET

                JAM

                ES STREET

                DOVE STREET

                DOVE STREET

                SMITH STREETSMITH STREET

                MARIA STREETMARIA STREET

                GEORGE STREETGEORGE STREET

                KINTORE STREET

                KINTORE STREET

                PORT ROAD

                PORT ROAD

                PORT ROAD

                PORT ROAD

                CAW

                THO

                RN

                E STR

                EETC

                AWTH

                OR

                NE ST

                REET

                DEVON STREETDEVON STREET

                KINTORE STREETKINTORE STREET

                GOODENOUGH STREETGOODENOUGH STREET

                LIVESTR

                ON

                G PATH

                WAY

                LIVESTR

                ON

                G PATH

                WAY

                MW1MW1

                MW02MW02

                MW3MW3

                MW4MW4

                MW5MW5

                MW6MW6

                MW7MW7

                MW8MW8

                MW9MW9

                MW10MW10MW11MW11

                MW12MW12

                MW13MW13

                MW14MW14

                MW15MW15

                MW16MW16

                MW17MW17

                MW18MW18

                MW19MW19MW20MW20

                MW21MW21

                MW22MW22

                MW23MW23

                MW24MW24

                MW25MW25

                MW26MW26

                WWAA

                LLSSHHSSTT

                SSMMIITTHH SSTTRREEEETT

                ndnd

                RRANDOLPH S

                ANDOLPH STREETTREET

                PPOORR

                TTRR

                OOAA

                DD

                PPOORR

                TTRR

                OOAA

                DD

                JJAM

                EA

                MES S

                S STREET

                TREET

                HHOO

                LLLLAANN

                DDSSTT

                RREEEETT

                CCAAWW

                TTHHOO

                RRNN

                EESSTT

                RREEEETT

                DE

                DEW

                SW

                STREET

                TREET

                DDOOVVEE SSTTRREEEETT

                LLIIVVEESSTTRR

                OONN

                GGPPAATTHH

                WWAAYY

                LIGHT TERRLIGHT TERRAACECE

                AD

                MELLA

                SA

                DM

                ELLA STR

                EETTR

                EET

                AALLBB

                EERRTT SSTTRR

                EEEETT

                CHAPEL SCHAPEL STREETTREET

                ndnd ndnd

                100100

                11000000

                GEGEORORGE SGE STREETTREET

                1010000000

                PPOORRTT RROOAADD PPOORRTT RROOAADD

                DDEEWW

                SSTTRREEEETT

                1010000000 11000000 MMAARRIIAA SSTTRREEEETT

                100100

                JJAAMM

                EESSCC

                OONN

                GGDD

                OONN

                DDRR

                IIVVEE

                KKIINNTTOORREE SSTTRREEEETT ndnd

                KKIINNTTOORREE SSTTRREEEETT

                PPAARR

                KKEERR

                SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                DDEEVVOONN SSTTRREEEETT

                FIGURE 5 GROUNDWATER CONCENTRATION PLAN

                MW2MW244

                MMWW88 TCE lt1

                PCE lt1

                11-DCE lt1TCE lt1

                12-DCE lt1PCE lt1

                11-DCE lt1MW2MW255 12-DCE lt1

                TCE 2

                PCE lt1

                11-DCE lt1

                12-DCE lt1

                MW2MW222 TCE lt1

                PCE lt1

                11-DCE lt1MW2MW233 12-DCE lt1

                TCE 21

                PCE lt1

                11-DCE lt1

                12-DCE lt1

                MW19MW19 TCE lt1

                MW2MW200 TCE 70 PCE lt1MW2MW211 PCE lt1MW18MW18 11-DCE lt1

                TCE 23 11-DCE lt1TCE 5 12-DCE lt1 PCE lt1 12-DCE lt1PCE lt1 11-DCE lt1

                11-DCE lt1 12-DCE lt1

                12-DCE lt1

                MW17MW17 LEGENDTCE 24 MW14MW14

                PCE lt1 TCE 1100 lt1 MW15MW15 GROUNDWATER MONITORING WELL11-DCE PCE lt1

                12-DCE lt1 TCE 180 11-DCE 2MW16MW16 100 INFERRED TCE GROUNDWATERPCE lt1 12-DCE 4 CONCENTRATION CONTOURSTCE lt1 11-DCE lt1 PCE lt1 12-DCE lt1 11-DCE lt1

                12-DCE lt1 MMWW1111

                EPA ASSESSMENT AREAMW10MW10

                TCE lt1 CADASTREMW12MW12 TCE lt14900 PCE

                lt1 11-DCE lt1TCE 700 PCEMW13MW13 12-DCE lt1 TCE CONCENTRATIONS (μgL)lt1 11-DCE 7PCE

                TCE lt1 lt1 12-DCE 511-DCE gtnd to lt100 100 to lt1000 1000 to lt10000

                MW0MW022PCE lt1 12-DCE lt1 2100011-DCE lt1 MW9MW9 TCE

                PCE lt112-DCE lt1 TCE 2(D) 11-DCE 15PCE lt1 MW5MW5

                10000 to 29000

                nd = non-detect (lt1)12-DCE 4511-DCE lt1 MMWW66 TCE 29000 MW4MW4 12-DCE lt1

                PCE 3 TCE lt1 NotesTCE 29 11-DCE 6MW7MW7 PCE lt1PCE lt1 This is one interpretation only Other interpretations possible12-DCE 23TCE lt1 11-DCE lt111-DCE lt1 All concentrations are in μgL

                12-DCE includes cis and trans PCE lt1 MW3MW3 12-DCE lt112-DCE lt1 11-DCE lt1

                TCE 69 D = Duplicate result12-DCE lt1 PCE lt1

                11-DCE lt1

                12-DCE lt1 MW1MW1

                12500 A3MW2MW266 TCE lt1

                TCE 2 PCE lt1

                PCE lt1 11-DCE lt1

                11-DCE lt1 12-DCE lt1

                12-DCE lt1

                LE

                VE

                L 1

                12

                4 S

                OU

                TH

                TE

                RR

                AC

                E

                AD

                EL

                AID

                E S

                A 5

                00

                0

                PH

                (0

                8)

                82

                32

                90

                88

                F

                AX

                (0

                8)

                82

                32

                90

                99

                E

                MA

                IL

                info

                fy

                fec

                om

                au

                W

                EB

                fy

                fec

                om

                au

                A

                BN

                5

                7 0

                08

                116

                13

                0

                0 25 50 m

                CLIENT

                SA EPA

                PROJECT

                EPA THEBARTON ASSESSMENT AREA - STAGE 1

                TITLE

                FIGURE 5 GROUNDWATER CONCENTRATION PLAN

                PROJECT NO DATE CREATED

                80607-1 280917

                80607_Fig 5 - Groundwater TCE Concentration Plan r2ai REV 2 gt 280917

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                DEW

                STREET

                DEW

                STREET

                CHAPEL STREETCHAPEL STREET

                PAR

                KER

                STREET

                PAR

                KER

                STREET

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                LIGHT TERRACELIGHT TERRACE

                DEW

                STREET

                DEW

                STREET

                WA

                LSH ST

                WA

                LSH ST

                AD

                MELLA

                STREET

                AD

                MELLA

                STREET

                ALB

                ERT STR

                EETA

                LBER

                T STREET

                HO

                LLAN

                D ST

                REET

                HO

                LLAN

                D ST

                REET

                RANDOLPH STREET

                RANDOLPH STREET

                JAM

                ES STREET

                JAM

                ES STREET

                DOVE STREET

                DOVE STREET

                SMITH STREETSMITH STREET

                MARIA STREETMARIA STREET

                GEORGE STREETGEORGE STREET

                KINTORE STREET

                KINTORE STREET

                PORT ROAD

                PORT ROAD

                PORT ROAD

                PORT ROAD

                CAW

                THO

                RN

                E STR

                EETC

                AWTH

                OR

                NE ST

                REET

                DEVON STREETDEVON STREET

                KINTORE STREETKINTORE STREET

                GOODENOUGH STREETGOODENOUGH STREET

                LIVESTR

                ON

                G PATH

                WAY

                LIVESTR

                ON

                G PATH

                WAY

                SV1SV1

                SV2SV2SV3SV3SV4SV4

                SV5SV5

                SV7SV7SV8SV8

                SV9SV9

                SV10SV10

                SV11SV11SV12SV12

                SV13SV13

                SV6SV6

                WWAA

                LLSSHHSSTT

                SSMMIITTHH SSTTRREEEETT

                RRANDOLPH S

                ANDOLPH STREETTREET

                PPOORR

                TTRR

                OOAA

                DD

                PPOORR

                TTRR

                OOAA

                DD

                CCAAWW

                TTHHOO

                RRNN

                EESSTT

                RREEEETT

                HHOO

                LLLLAANN

                DDSSTT

                RREEEETT

                JJAM

                EA

                MES S

                S STREET

                TREET

                DE

                DEW

                SW

                STREET

                TREET

                DDOOVVEE SSTTRREEEETT

                00

                LLIIVVEESSTTRR

                OONN

                GGPPAATTHH

                WWAAYY

                LIGHT TERRLIGHT TERRAACECE

                AD

                MELLA

                SA

                DM

                ELLA STR

                EETTR

                EET

                CHAPEL SCHAPEL STREETTREET

                00

                AALLBB

                EERRTT SSTTRR

                EEEETT

                1010

                GEGEORORGE SGE STREETTREET

                000000

                PPOORRTT RROOAADD

                100100000

                000

                1010

                PPOORRTT RROOAADD

                000000

                DDEEWW

                SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

                JJAAMM

                EESSCC

                OONN

                GGDD

                OONN

                DDRR

                IIVVEE

                KKIINNTTOORREE SSTTRREEEETT 00

                KKIINNTTOORREE SSTTRREEEETT

                PPAARR

                KKEERR

                SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                DDEEVVOONN SSTTRREEEETT

                FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

                SSVV1111 SSV12V12 TCE lt18

                SSVV1133 TCE 16

                PCE lt54 TCE lt21

                11-DCE lt29 PCE lt25

                12-DCE lt39 11-DCE lt14

                12-DCE lt18

                PCE lt22

                11-DCE lt12

                12-DCE lt16

                TCE 170

                PCE lt54

                11-DCE lt3

                12-DCE lt39 LEGEND SSVV99

                SSV10V10 SOIL VAPOUR BORE

                TCE lt21 0 INFERRED TCE SOIL VAPOUR CONTOUR PCE lt25

                TCE 2200011-DCE lt14 EPA ASSESSMENT AREA

                PCE 1912-DCE lt18

                11-DCE lt27 CADASTRE

                12-DCE lt37 SVSV66SVSV77

                SSVV88 TCE 22000

                TCE 2300 PCE 12 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)TCE 100000 PCE 62 11-DCE lt29PCE 84 0 to lt10000SSVV55lt2711-DCE 12-DCE lt2911-DCE lt33 10000 to lt100000

                100000 to 210000 12-DCE lt36 12-DCE lt44

                TCE 17000 SVSV44 SVSV22SVSV33 NotePCE 31 TCE 51000TCE 210000 This is one interpretation only Other interpretations possible11-DCE lt14 PCE 39PCE 650012-DCE lt18 39 Estimated extent of plume has utilised groundwater11-DCE11-DCE 5900 12-DCE 21 concentration data12-DCE lt71

                SVSV11 All concentrations are in (μgmsup3)

                TCE 6300(LD) 12-DCE includes cis and trans PCE 78 LD = Laboratory duplicate result 11-DCE lt29

                12-DCE lt38

                12500 A3

                0 25 50 m

                CLIENT

                SA EPA

                PROJECT

                EPA THEBARTON ASSESSMENT AREA - STAGE 1

                TITLE

                FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

                PROJECT NO DATE CREATED

                80607-1 290917

                80607_Fig 6 - Soil Vapour TCE Concentration Plan - 1mai REV 2 gt 290917

                LE

                VE

                L 1

                12

                4 S

                OU

                TH

                TE

                RR

                AC

                E

                AD

                EL

                AID

                E S

                A 5

                00

                0

                PH

                (0

                8)

                82

                32

                90

                88

                F

                AX

                (0

                8)

                82

                32

                90

                99

                E

                MA

                IL

                info

                fy

                fec

                om

                au

                W

                EB

                fy

                fec

                om

                au

                A

                BN

                5

                7 0

                08

                116

                13

                0

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                JAM

                ES CO

                NG

                DO

                N D

                RIV

                E

                DEW

                STREET

                DEW

                STREET

                CHAPEL STREETCHAPEL STREET

                PAR

                KER

                STREET

                PAR

                KER

                STREET

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                POR

                T RO

                AD

                LIGHT TERRACELIGHT TERRACE

                DEW

                STREET

                DEW

                STREET

                WA

                LSH ST

                WA

                LSH ST

                AD

                MELLA

                STREET

                AD

                MELLA

                STREET

                ALB

                ERT STR

                EETA

                LBER

                T STREET

                HO

                LLAN

                D ST

                REET

                HO

                LLAN

                D ST

                REET

                RANDOLPH STREET

                RANDOLPH STREET

                JAM

                ES STREET

                JAM

                ES STREET

                DOVE STREET

                DOVE STREET

                SMITH STREETSMITH STREET

                MARIA STREETMARIA STREET

                GEORGE STREETGEORGE STREET

                KINTORE STREET

                KINTORE STREET

                PORT ROAD

                PORT ROAD

                PORT ROAD

                PORT ROAD

                CAW

                THO

                RN

                E STR

                EETC

                AWTH

                OR

                NE ST

                REET

                DEVON STREETDEVON STREET

                KINTORE STREETKINTORE STREET

                GOODENOUGH STREETGOODENOUGH STREET

                LIVESTR

                ON

                G PATH

                WAY

                LIVESTR

                ON

                G PATH

                WAY

                SV1SV1

                SV2SV2SV3SV3SV4SV4

                SV5SV5

                SV7SV7SV8SV8

                SV9SV9

                SV10SV10

                SV12SV12

                SV6SV6

                WWAA

                LLSSHHSSTT

                SSMMIITTHH SSTTRREEEETT

                RRANDOLPH S

                ANDOLPH STREETTREET

                PPOORR

                TTRR

                OOAA

                DD

                PPOORR

                TTRR

                OOAA

                DD

                CCAAWW

                TTHHOO

                RRNN

                EESSTT

                RREEEETT

                HHOO

                LLLLAANN

                DDSSTT

                RREEEETT

                DE

                DEW

                SW

                STREET

                TREET

                JJAM

                EA

                MES S

                S STREET

                TREET

                DDOOVVEE SSTTRREEEETT

                00

                LIGHT TERRLIGHT TERRAACECE

                LLIIVVEESSTTRR

                OONN

                GGPPAATTHH

                WWAAYY

                AD

                MELLA

                SA

                DM

                ELLA STR

                EETTR

                EET

                CHAPEL SCHAPEL STREETTREET

                00

                1010000000

                AALLBB

                EERRTT SSTTRR

                EEEETT

                100100 000

                000 GEGEORORGE SGE STREETTREET

                PPOORRTT RROOAADD 11000000000

                000 PPOORRTT RROOAADD

                DDEEWW

                SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

                100100000000

                JJAAMM

                EESSCC

                OONN

                GGDD

                OONN

                DDRR

                IIVVEE

                1010000000

                KKIINNTTOORREE SSTTRREEEETT

                00

                KKIINNTTOORREE SSTTRREEEETT

                PPAARR

                KKEERR

                SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                DDEEVVOONN SSTTRREEEETT

                FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

                SSV12V12 TCE 55

                PCE lt45

                11-DCE lt24

                12-DCE lt32

                TCE 260

                PCE lt51

                11-DCE lt28

                12-DCE

                SSVV99

                lt37 LEGEND

                SSV10V10 SOIL VAPOUR BORE

                TCE 51 0 INFERRED TCE SOIL VAPOUR CONTOURPCE lt53

                TCE 11000011-DCE lt29

                EPA ASSESSMENT AREAPCE lt13012-DCE lt39

                11-DCE lt69

                CADASTRE12-DCE lt92 SVSV66SVSV77

                SSVV88 TCE 150000

                TCE 14000 56 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)PCETCE 160000 PCE 19 11-DCE lt30PCE 310 0 to lt10000SSVV5511-DCE lt26 12-DCE lt3911-DCE 33 10000 to lt100000

                100000 to lt1000000 1000000

                12-DCE lt35 12-DCE 20

                TCE 43000 SVSV44 SVSV22SVSV33 NotePCE 90 TCE 940000(FD)TCE 1000000 This is one interpretation only Other interpretations possible11-DCE lt15 PCE 15000PCE 1500012-DCE 30 14000 Estimated extent of plume has utilised groundwater11-DCE11-DCE 14000 12-DCE lt930 concentration data12-DCE lt930

                All concentrations are in (μgmsup3) 12-DCE includes cis and trans

                SVSV11 TCE 21000

                FD = Field Duplicate resultPCE 21

                11-DCE lt57

                12-DCE lt76

                12500 A3

                0 25 50 m

                CLIENT

                SA EPA

                PROJECT

                EPA THEBARTON ASSESSMENT AREA - STAGE 1

                TITLE

                FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

                PROJECT NO DATE CREATED

                80607-1 290917

                80607_Fig 7 - Soil Vapour TCE Concentration Plan - 3m r2ai REV 2 gt 290917

                LE

                VE

                L 1

                12

                4 S

                OU

                TH

                TE

                RR

                AC

                E

                AD

                EL

                AID

                E S

                A 5

                00

                0

                PH

                (0

                8)

                82

                32

                90

                88

                F

                AX

                (0

                8)

                82

                32

                90

                99

                E

                MA

                IL

                info

                fy

                fec

                om

                au

                W

                EB

                fy

                fec

                om

                au

                A

                BN

                5

                7 0

                08

                116

                13

                0

                • THEBARTON ASSESSMENT AREA STAGE 1 ENVIRONMENTAL ASSESSMENT FINAL REPORT | EPA REF 0524111 30 OCTOBER 2017 VOLUME 1 REPORT13
                • This report is formatted to print Double Sided
                • TITLE PAGE13
                • CONTENTS13
                • LIST OF ACRONYMS13
                • EXECUTIVE SUMMARY13
                • 1 INTRODUCTION
                  • 11 Purpose
                  • 12 General background information
                  • 13 Definition of the assessment area
                  • 14 Identification of contaminants of potential concern
                  • 15 Objectives
                    • 2 CHARACTERISATION OF THE ASSESSMENT AREA
                      • 21 Site identification
                      • 22 Regional geology and hydrogeology
                      • 23 Data quality objectives
                        • 3 SCOPE OF WORK
                          • 31 Preliminary work
                          • 32 Field investigation and laboratory analysis program
                          • 33 Data interpretation
                            • 4 METHODOLOGY
                              • 41 Field methodologies
                              • 42 Laboratory analysis
                                • 5 QUALITY ASSURANCE AND QUALITY CONTROL
                                  • 51 Field QAQC
                                  • 52 Laboratory QAQC
                                  • 53 QAQC summary
                                    • 6 ASSESSMENT CRITERIA
                                      • 61 Groundwater
                                      • 62 Soil vapour
                                        • 7 RESULTS
                                          • 71 Surface and sub surface soil conditions
                                          • 72 Waterloo Membrane Samplerstrade
                                          • 73 Groundwater
                                          • 74 Soil vapour bores
                                            • 8 GROUNDWATER FATE AND TRANSPORT MODELLING
                                              • 81 Groundwater flow modelling
                                              • 82 Solute transport modelling
                                                • 9 VAPOUR INTRUSION RISK ASSESSMENT
                                                  • 91 Objective
                                                  • 92 Areas of interest
                                                  • 93 Risk assessment approach
                                                  • 94 Tier 1 assessment
                                                  • 95 Tier 2 assessment
                                                  • 96 Conclusions
                                                    • 10 CONCEPTUAL SITE MODEL
                                                    • 11 CONCLUSIONS
                                                    • 12 DATA GAPS
                                                    • 13 REFERENCES
                                                    • 14 STATEMENT OF LIMITATIONS
                                                    • FIGURES13
                                                    • FIGURE 1 SITE LOCATION AND ASSESSMENT AREA
                                                    • FIGURE 2 ASSESSMENT POINT LOCATIONS
                                                    • FIGURE 3 WATERLOO MEMBRANE SAMPLERTM TCE CONCENTRATION PLAN13
                                                    • FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN
                                                    • FIGURE 5 GROUNDWATER CONCENTRATION PLAN
                                                    • FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)
                                                    • FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  EF Exposure Frequency

                  EMP Environmental Management Plan

                  EPA Environment Protection Authority

                  EPC Exposure Point Concentration

                  EPP Environment Protection Policy

                  ET Exposure Time

                  GPA Groundwater Prohibition Area

                  GPR Ground Penetrating Radar

                  GPS Global Positioning System

                  HHRA Human Health Risk Assessment

                  HIL Health Investigation Level

                  HSP Health and safety Plan

                  IPA Isopropyl Alcohol (isopropanol or 2-propanol)

                  IRIS Integrated Risk Information System

                  ITRC Interstate Technology and Regulatory Council

                  JampE Johnson and Ettinger

                  JHA Job Hazard Analysis

                  LNAPL Light Non-Aqueous Phase Liquid

                  LOR Limit of Reporting

                  MGA Map Grid of Australia

                  MQO Measuring Quality Objectives

                  MTC Mass Transfer Co-efficient

                  NA Not Applicable

                  NAPL Non-Aqueous Phase Liquid

                  NATA National Association of Testing Authorities

                  ND Non Detect

                  NEPM National Environment Protection Measure

                  NHMRC National Health and Medical Research Council

                  NJDEP New Jersey Department of Environmental Protection

                  NRMMC National Resource Management Ministerial Council

                  PAH Polycyclic Aromatic Hydrocarbons

                  PCE Tetrachloroethene (perchloroethylene)

                  PID Photoionisation Detector

                  PQL Practical Quantification Limit

                  PSD Particle Size Distribution

                  QA Quality Assurance

                  80607-1 REV1 30102017 PAGE VI

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  QC Quality Control

                  RAIS Risk Assessment Information System

                  RFQ Request for Quote

                  REM Resource and Environmental Management

                  RPD Relative Percentage Difference

                  RSL Regional Screening Level

                  SA EPA South Australian Environment Protection Authority

                  SAQP Sampling and Analysis Quality Plan

                  SOP Standard Operating Procedure

                  SVOC Semi-Volatile Organic Compound

                  SWL Standing Water Level

                  SWMS Safe Work Method Statement

                  111-TCA 111-trichloroethane

                  TCE Trichloroethene

                  TDS Total Dissolved Solids

                  TRH Total Recoverable Hydrocarbons1

                  TRV Toxicity Reference Value

                  US EPA United Stated Environment Protection Agency

                  USGS United States Geological Survey

                  VC Vinyl Chloride

                  VIRA Vapour Intrusion Risk Assessment

                  VOC Volatile Organic Compound

                  VOCC Volatile Organic Chlorinated Compound

                  WHO World Health Organisation

                  WMStrade Waterloo Membrane Samplertrade

                  TRH = measurable amount of petroleum-based hydrocarbon (ie complex mixture of crude oil and natural gas (gt 250 compounds) including aromatics aliphatics paraffins unsaturated alkanes and naphthalenes) plus various other compounds including fatty acids esters humic acids phthalates and sterols

                  80607-1 REV1 30102017 PAGE VII

                  1

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  EXECUTIVE SUMMARY

                  Background information

                  An approximate 27 hectare mixed use area of Thebarton has been designated by the South Australian Environment Protection Authority (EPA) as the Thebarton EPA Assessment Area

                  The former Austral sheet metal works (Austral) property located over multiple allotments between George and Maria Streets from the 1920s until the 1960s-1970s has been identified as a possible source of dissolved phase groundwater chlorinated hydrocarbon (CHC) contamination Groundwater CHC impacts within the uppermost (Quaternary ndash Q1) aquifer were identified as extending in a general north-westerly direction (consistent with regional groundwater flow direction) from the south-eastern portion of the Thebarton EPA Assessment Area and having resulted in the generation of soil vapour containing elevated concentrations of CHC

                  The boundaries of the Thebarton EPA Assessment Area were established on the basis of the following

                  the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street (part of the former Austral property) and 39 Smith Street (hydraulically down-gradient of the former Austral property) in Thebarton

                  the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

                  the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

                  Key objectives

                  The results of the recent investigations undertaken by Fyfe have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties within the Thebarton EPA Assessment Area

                  The key objectives detailed by the EPA were to

                  further delineate the chlorinated hydrocarbon contamination in groundwater

                  further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

                  undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

                  80607-1 REV1 30102017 PAGE VIII

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  With respect to the VIRA the EPA requested that there be specific consideration of

                  residential properties (slab on grade)

                  residential properties (crawl space)

                  residential properties (with basement) and

                  trenchmaintenanceutility workers that may be working in the vicinity of the contamination

                  Site conditions

                  Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were identified within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m below ground level (BGL) during the drilling of groundwater well MW17 the latter consistent with the depth of groundwater within the Q1 aquifer

                  Soil

                  Groundwater within the Q1 aquifer is located at a depth of approximately 123 to Groundwater 159 m BGL and flows in a general north-westerly direction The closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred and the groundwater gradient is relatively flat (ie 000062 to 00012)

                  Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified (based on factors such a groundwater salinity registered bore use and the locations of potential sensitive receptors) as including domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux) and possibly also potable

                  Contaminants of Potential Concern (COPC)

                  The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans-) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

                  80607-1 REV1 30102017 PAGE IX

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Scope of work

                  A groundwater and soil vapour monitoring program was undertaken by Fyfe across the Thebarton EPA Assessment Area between May and August 2017 It involved the following scope of work

                  installation of a total of 41 WMStrade units to 1 m BGL in an approximate grid-pattern across the entire assessment area (Round 1) and at specific targeted locations (Round 2) followed by laboratory analysis of retrieved sample units for specific CHC

                  drilling and installation of 25 groundwater wells to depths of between 15 and 19 m BGL including a background well to the east of the southern portion of the assessment area

                  testing of 30 selected groundwater well drill core samples for geotechnical parameters

                  gauging and sampling of the 25 newly installed groundwater wells as well as an existing well located in Admella Street followed by laboratory analysis of all samples for specific CHC and 10 selected samples for major cationsanions natural attenuation parameters and additional nutrients

                  aquifer permeability (rising and falling head ldquoslugrdquo) testing of 10 groundwater wells

                  drilling and installation of 13 soil vapour bores including 11 nested bores (ie to 1 and 3 m BGL) and two bores to 1 m BGL and

                  sampling of all soil vapour bores followed by laboratory analysis of samples for specific CHC and general gases

                  The soil vapour data were used to undertake a VIRA aimed at predicting indoor air concentrations of TCE under various land use and building construction scenarios In order to validate the results of the modelling which includes a number of conservative assumptions and is therefore expected to over-estimate potential risk the EPA has commissioned indoor air monitoring in a number of residential properties within the Thebarton EPA Assessment Area ndash the indoor air monitoring results will be reported under separate cover

                  Groundwater fate and transport modelling was undertaken to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton EPA Assessment Area The provision of this information is aimed at supporting the definition (extent and geometry) of a potential future Groundwater Prohibition Area (GPA) to be designated by the EPA in accordance with the provisions of Section S103S of the Environment Protection Act 1993

                  80607-1 REV1 30102017 PAGE X

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Identified impacts

                  Contaminants identified in the Q1 aquifer beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down

                  Groundwater

                  (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested

                  The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected (Austral) source site in accordance with the predominant flow direction associated with the Q1 aquifer The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) ndash whereas its north-western extent has not yet been determined the groundwater CHC plume has been delineated in all other directions

                  Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion

                  Soil vapour

                  The soil vapour samples with the maximum TCE concentrations also had the highest PCE and 11-DCE concentrations (or elevated laboratory limits of reporting (LOR)) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-)

                  Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE exceeded the adopted health investigation levels (HILs) for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE degradation has not yet resulted in its production

                  Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

                  80607-1 REV1 30102017 PAGE XI

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Assessment of risk

                  Measured concentrations of TCE exceeded the adopted assessment criteria for potable use andor primary contact recreation in wells located on Admella Maria George Albert Chapel and Dew Streets as well as Light Terrace ndash with the highest concentrations corresponding to the ldquocorerdquo area of the plume One well on Albert Street also contained a concentration of carbon tetrachloride that exceeded the respective potable criterion

                  Groundwater risks

                  Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous

                  Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

                  The groundwater modelling undertaken by Arcadis involved the development of an Groundwater fate and transport initial groundwater flow model using MODFLOW followed by the development of a modelling site-specific (three-dimensional) solute transport model using the MT3DMS transport

                  code

                  The results of this modelling were interpreted to indicate the following

                  although scattered detectable concentrations of 12-DCE have been measured in groundwater across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE daughter products indicate that substantial dechlorination is not occurring and

                  the dissolved phase groundwater TCE plume is predicted to extend by another 500 m (ie beyond the boundaries of the current Thebarton EPA Assessment Area) over the next 100 years whereas no significant lateral plume expansion is expected

                  The VIRA undertaken by Arcadis involved a two-tier assessment approach Whereas Vapour intrusion the Tier 1 screening risk assessment compared the measured soil vapour CHC concentrations to (modified) guideline values the Tier 2 risk assessment involved the application of the Johnson and Ettinger vapour intrusion model to predict indoor air CHC concentrations for residential (slab on grade crawl space and basement construction) and commercialindustrial (slab on grade construction) properties across the assessment area Site-specific geotechnical parameters and soil vapour data collected from 1 and 3 m BGL throughout the Thebarton EPA Assessment Area were used in the modelling It should be noted that overall the vapour modelling

                  risks

                  80607-1 REV1 30102017 PAGE XII

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

                  The results of the VIRA with respect to the predicted indoor air concentrations of TCE within residential properties (assuming crawl space construction) versus adopted EPA response levels indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air that require further action as follows

                  10 properties within the investigation range (2 to lt20 microgm3)

                  eight properties within the intervention range (20 to lt200 microgm3) and

                  three properties within accelerated intervention range (ge200 microgm3)

                  All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises

                  Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which is expected to be overly-conservative) ndash these results will be documented in a subsequent report

                  Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie as determined for the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

                  A qualitative assessment of potential risks to subsurface trenchmaintenanceutility workers indicated that exposure management may be required in areas where TCE concentrations at 1 m BGL are above 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific health and safety plan (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a photoionisation detector (PID) unit providing increased ventilation and using appropriate personal protective equipment (eg gas masks) as required

                  80607-1 REV1 30102017 PAGE XIII

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Data gaps

                  Based on the results obtained during the recent Fyfe investigations as well as available historical information the following data gaps have been identified for the Thebarton EPA Assessment Area

                  property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

                  groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

                  the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

                  the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

                  Notes ie the interim soil vapour HILs adopted from the National Environment (Assessment of Site Contamination) Measure 1999 (as revised in 2013 ndash ie the ASC NEPM (1999)) but assuming a sub-slab to indoor air attenuation factor of 003 as compared to the value of 01 adopted by the ASC NEPM (1999)

                  80607-1 REV1 30102017 PAGE XIV

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  1 INTRODUCTION

                  11 Purpose

                  Fyfe Pty Ltd (Fyfe) was commissioned by the South Australian Environment Protection Authority (SA EPA referred to herein as the EPA) to undertake Stage 1 groundwater and soil vapour investigation works groundwater fate and transport modelling and a human health vapour intrusion risk assessment (VIRA) within an EPA designated assessment area located within Thebarton South Australia (herein referred to as the Thebarton EPA Assessment Area) The location and extent of the Thebarton EPA Assessment Area referenced within this document is identified on Figure 1

                  12 General background information

                  Previous environmental assessment work undertaken since 1994 (as summarised in Appendix A) combined with historical information provided by the EPA (as included in Appendix B) indicates that the Thebarton EPA Assessment Area has been used for mixed residential and commercialindustrial purposes over time

                  Groundwater impacts2 identified within the uppermost (Quaternary ndash Q1) aquifer in the vicinity of the former Austral sheet metal works (Austral) on George Street included both petroleum hydrocarbons (ie diesel fuel) as well as chlorinated hydrocarbon compounds (CHC) such as trichloroethene (TCE) and were first notified to the EPA in 2006

                  Available historical information for the Austral property (ie the suspected source site) indicates that it operated from the 1920s until the 1960s-1970s and occupied an extensive area of Thebarton including

                  part of the southern side of George Street extending from about half way between East Terrace3 and Admella Street (ie 11-25 George Street) to the west of Admella Street (ie 31-35 George Street)

                  the entire northern side of Maria Street from East Terrace to the west of Admella Street

                  part of the southern side of Maria Street (ie from 21 Maria Street) to Admella Street and

                  25-27 East Terrace

                  2 Note that the term ldquoimpactrdquo has been used by Fyfe to indicate identified concentrations of compounds (specifically chlorinated hydrocarbons) that are not naturally occurring (ie concentrations above background that have resulted from anthropogenic activities) The use of this term does not denote that the presence of these compounds represents a risk to either human health or the environment and the term ldquoimpactrdquo is therefore not directly interchangeable with the term ldquoSite Contaminationrdquo the latter defined under the Environment Protection Act 1993 to include actual or potential harm to human health andor the environment

                  3 now James Congdon Drive

                  80607-1 REV1 30102017 PAGE 1

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Historical newspaper articles described the Austral property as hosting a factory that extended over more than three acres and included an electroplating facility In 1938 it was described as the largest aluminium utensil manufacturing company in the southern hemisphere

                  Other potential sources of groundwater contamination4 identified within the Thebarton EPA Assessment Area include a former gas works (ie located to the south and south-east of the Austral property and including the current Ice Arena property) a mechanicrsquos workshop another sheet metal working facility and a farm machinery manufacturer

                  The Stage 1 assessment work described herein was commissioned by the EPA to determine whether historical contamination in the vicinity of George Street was presenting a risk to human health or the environment

                  13 Definition of the assessment area

                  As detailed on Figure 1 the current EPA Assessment Area covers an area of approximately 27 ha within the suburb of Thebarton located approximately 2 km north-west of the Adelaide central business district (CBD)

                  The boundaries of the Thebarton EPA Assessment Area were established by the EPA on the basis of the following

                  the previous identification of groundwater CHC contamination associated with properties located at 31-37 George Street and 39 Smith Street in Thebarton (refer to Appendix A)

                  the fact that although the George Street property (andor the broader Austral facility of which it formed a part) was suspected to be located in the vicinity of the source the specific source site had not yet been confirmed and

                  the identification of an inferred (general) north-westerly groundwater flow direction within the Q1 aquifer

                  14 Identification of contaminants of potential concern

                  The contaminants of potential concern (COPC) for the Thebarton EPA Assessment Area comprise a number of CHC The main COPC has been identified as trichloroethene (TCE) a solvent historically used for metal cleaningdegreasing activities in various manufacturing industries Additional COPC identified for the assessment area include the breakdown products of TCE namely 12-dichloroethene (12-DCE cis- and trans) and vinyl chloride (VC) as well as other solvents such as tetrachloroethene (PCE) and 11-dichloroethene (11-DCE)

                  Site Contamination is defined by the Environment Protection Act 1993 as existing if chemical substances are present on or below the surface of a site in concentrations above background the contaminants are there as a result of activity at the site or elsewhere and their presence has resulted in actual or potential harm (that is not trivial) to the health and safety of human beings taking into account current and proposed land uses or water or the environment

                  PAGE 2 80607-1 REV1 30102017

                  4

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  15 Objectives

                  As defined by the EPA the key objectives of the recent Stage 1 environmental assessment program undertaken within the Thebarton EPA Assessment Area (refer to Figure 1) were to

                  further delineate the chlorinated hydrocarbon contamination in groundwater

                  further delineate the chlorinated hydrocarbon contamination in soil vapour initially using Waterloo Membrane Samplers (WMStrade) and

                  undertake a Human Health Risk Assessment Vapour Intrusion Risk Assessment (HHRAVIRA) based on the data collected

                  With respect to the VIRA the EPA requested that there be specific consideration of

                  residential properties (slab on grade)

                  residential properties (crawl space)

                  residential properties (with basement) and

                  trenchmaintenanceutility workers that may be working in the vicinity of the contamination

                  80607-1 REV1 30102017 PAGE 3

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  2 CHARACTERISATION OF THE ASSESSMENT AREA

                  21 Site identification

                  For the purpose of this investigation program the Thebarton EPA Assessment Area (as delineated in Figure 1) has been defined by the following roadways

                  North northern verge of Smith Street

                  South Maria Street (between Dew Street and Albert Street) portion of Parker Street (between Maria Street and Goodenough Street) and Goodenough Street (between Parker Street and James Congdon Drive)

                  East western verge of Port Road and James Congdon Drive and

                  West western verge of Dew Street

                  22 Regional geology and hydrogeology

                  221 Geology

                  The Thebarton area is located within the Adelaide Plains approximately 8 km to the east of Gulf St Vincent and to the west of the Para Fault It lies within the Golden Grove ndash Adelaide Embayment area of the St Vincent Basin which consists of a succession of Tertiary and Quaternary age sediments (with thicknesses of up to 600 m) overlying basement rocks

                  The 1250000 Adelaide geological map (SA Department of Mines and Energy 1969) indicates that the near-surface geology of the area consists primarily of Quaternary aged soils and sediments including the Pooraka and Hindmarsh Clay formations The Pleistocene aged Pooraka Formation generally comprises a thickness of approximately 10 m and is of alluvial origin comprising sandy clays and clayey to sandy silts interbedded with layers of clay sand andor gravel The underlying Pleistocene aged Hindmarsh Clay Formation represents the basal unit of the Adelaide Plains and has a maximum general thickness of more than 100 m It generally comprises a basal gravel layer a middle layer of mottled medium to high plasticity (red-brown yellow brown greygreen to orange) often stiff to hard clays and an upper layer of fluvial and alluvial red-brown silty sand Gerges (1999) describes Hindmarsh Clay as comprising a mottled brown to pale olive grey predominantly clay formation that becomes green grey towards the basal section (approximately 16 to 20 m below ground level (BGL)) and is characterised by an increasing gravel content with depth

                  Underlying the Hindmarsh Clay are sands and limestone of Tertiary age which are in turn underlain by metamorphosed basement rock of the Proterozoic Umberatana Group

                  80607-1 REV1 30102017 PAGE 5

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  222 Hydrogeology

                  According to Gerges (2006) the aquifers identified within the Quaternary aged sediments of the Adelaide Plains are typically found within the coarser interbedded silt sand and gravel layers of the Hindmarsh Clay Formation and vary greatly in thickness (typically from 1 to 18 m) lithology and hydraulic conductivity Confining beds between the Quaternary aquifers consist of clay and silt layers and range in thickness from 1 to 20 m These confining beds vary in terms of the amount of coarser grained material they contain their bulk hydraulic conductivity andor the presence and density of fractures In addition their absence in some areas allows direct hydraulic connection between the aquifers

                  The Thebarton area is located within Hydrogeological Zone 3 (Subzone 3E) of Gerges (2006) This zone contains five to six Quaternary aquifers and three to four almost flat-lying Tertiary aquifers The first Tertiary aquifer estimated by Gerges (2006) to be intersected at a depth of approximately 130 m BGL near the Para Fault is most frequently accessed for industrial and recreational groundwater use

                  The Q1 aquifer assessed as part of the current investigations is typically located at depths of between 3 and 10 m BGL beneath the Adelaide Plains with an average thickness of 2 m The Q1 aquifer contains water of variable salinity with Subzone 3E including a range of 500 to 3500 mgL total dissolved solids (TDS) The gradient of the Q1 aquifer is generally flat (particularly to the west of the Para Fault) and flow direction is typically towards the north-west

                  A search of the registered bore database maintained by the Department of Environment Water and Natural Resources (DEWNR (2017) WaterConnect database) identified 59 bores within the general Thebarton area of which 18 are located in the Thebarton EPA Assessment Area Although eight bores were installed for monitoring purposes on or immediately adjacent to the property located at 31-37 George Street (ie part of the former Austral facility) it is understood that only one bore (6628-21951 ndash located within the Admella Street roadway intersecting the Q1 aquifer and identified as MW01 in Appendix A but MW02 by Fyfe5) remains in situ

                  In addition to numerous monitoringinvestigationobservation bores the Q1 aquifer within the general (ie broader) Thebarton area is recorded in the DEWNR (2017) database as being accessed for drainage domestic and industrial purposes

                  DEWNR (2017) information for registered bores located within the general Thebarton area is included in Appendix C whereas information for bores located within the Thebarton EPA Assessment Area (excluding those associated with the property at 31-37 George Street and installed solely for monitoring purposes6) is summarised in Table 21

                  5 This existing groundwater well was identified as MW02 by Fyfe in accordance with the markings on the gatic cover and the DEWNR (2017) WaterConnect bore identification details although it was originally installed as MW01 by REM (refer to discussion of previous reports in Appendix A)

                  6 ie 6628-21951 6628-21952 6628-22229 to 6628-22233 and 6628-22236

                  PAGE 6 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Table 21 Information regarding registered groundwater bores located within the Thebarton EPA Assessment Area

                  Bore ID Location Purpose Status Maximu SWL Salinity Yield Aquifer m well (m (mgL (Lsec

                  Tertiary (T1)

                  depth BGL) TDS) ) (m BGL)

                  125 6628-516 Coca Cola plant Rehabilitated 138 1963 794

                  6628-1435 Coca Cola plant Backfilled 184 212 921 392 Tertiary (T1)

                  6628-4576 Corner of Admella amp Chapel Streets

                  125 1454 445 Tertiary (T1)

                  6628-7724 Coca Cola plant Observation 155 2017 1272 1516 Tertiary (T1)

                  6628-7725 Coca Cola plant Observation 127 3016 1100 1005 Tertiary (T1)

                  6628-12516 Coca Cola plant Industrial Backfilled 210 212 1300 1875 Tertiary (T1)

                  6628-20663 39 Smith Street Irrigation 121 1105 50 Tertiary (T1)

                  6628-20969 39 Smith Street Industrial 30 14 1535 25 Quaternary (Q1)

                  6628shy21951

                  Admella Street 20 Quaternary (Q1)

                  6628-22395 21 James Congdon Drive

                  20 157 1541 05 Quaternary

                  6628-23525 41 Maria Street 206 273 1078 10 Tertiary (T1)

                  Notes Shading indicates that information was not recorded in the database as interpreted from information provided in the database ndash approximate only in some instances

                  ie MW02 as included in the groundwater monitoring program of Fyfe ndash refer to Table 31 Abbreviations BGL = below ground level SWL = standing water level TDS = total dissolved solids

                  23 Data quality objectives

                  The Data Quality Objective (DQO) process as described in Australian Standard AS44821-2005 and the National Environment Protection (Assessment of Site Contamination) Measure (ASC NEPM 1999)7

                  Schedule B2 Guideline on Data Collection Sample Design and Reporting and more fully documented in the NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme involves a seven-step iterative approach that was initially developed by the United States Environment Protection Agency (US EPA) to facilitate the systematic planning and verification of contaminated sites assessment projects

                  As stated in Schedule B2 of the ASC NEPM (1999) the first six steps of the DQO process comprise the development of qualitative and quantitative statements that define the objectives of the site assessment program and the quantity and quality of data needed to inform risk-based decisions These steps enable the

                  All references to the ASC NEPM (1999) refer to the version amended on 16 May 2013

                  80607-1 REV1 30102017 PAGE 7

                  7

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  project team to communicate the goals decisions constraints (eg time budget) and uncertainties associated with the project and detail how they are to be addressed The seventh step comprises the development of a Sampling and Analysis Quality Plan (SAQP) to generate the data required to adequately characterise site contamination issues and assess their associated potential environmental and human health risks under the proposed land use scenario

                  The DQOs defined for the Thebarton EPA Assessment Area are summarised in Table 22

                  Table 22 Data Quality Objectives

                  Objective Comment

                  Step 1 ndash Statement of the Problem According to information provided to Fyfe by the EPA (as summarised in Appendix A) a property located at 31-37 George Street (immediately west of Admella Street) in Thebarton and historically occupied by part of the Austral facility had been found to be underlain by groundwater CHC (primarily TCE) impacts More recent reporting to the EPA for a property at 39 Smith Street located approximately 350 m north-west (and hydraulically down-gradient) of the George Street property indicated that detectable CHC (predominantly TCE) were also present within groundwater Since this area of Thebarton is occupied by a mixture of commercialindustrial and residential properties and the source and extent of the CHC impacts within the Q1 aquifer had not yet been determined potential risks to human health andor the environment had yet to be assessed

                  Step 2 ndash The Decision that Needs The assessment works commissioned by the EPA were necessitated to to Result from the Investigation investigate the source extent and magnitude of the groundwater CHC

                  contamination beneath a designated area of Thebarton (ie that included both the George Street and Smith Street properties) and to understand the possible risk to public health from potential vapour generation Fyfe have therefore undertaken vapour modelling and intrusion risk assessment works aimed at evaluating whether concentrations of identified groundwater andor soil vapour contaminants pose an unacceptable risk to human health In addition groundwater fate and transport modelling has been undertaken to predict the extent of the plume This will assist the EPA to determine a potential future Groundwater Prohibition Area (GPA) in accordance with the provisions of Section 103S of the Environment Protection Act 1993

                  Step 3 ndash Inputs to the Decision The information that was required to resolve the decision statement included the collection of physical and chemical data from across the Thebarton EPA Assessment Area The collected data as well as physical observations regarding the geology of the area and possible preferential contaminant pathways was used to determine potential risks to human health via groundwater fate and transport and vapour intrusion modelling

                  Step 4 ndash Boundaries of the Investigation

                  The lateral boundaries of the Thebarton EPA Assessment Area are as defined in Sections 13 and 21 as depicted on Figure 1 Vertically the investigations extended as far as the maximum drilled depth (19 m BGL)

                  Step 5 ndash Decision Rules The decision rule will be based upon the identification of predicted indoor air concentrations of CHC compounds associated with groundwater andor soil vapour impacts which exceed adopted response levels

                  PAGE 8 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Objective Comment

                  Step 6 ndash Decision Error Tolerances The purpose of establishing decision error tolerance is to control the acceptable degree of uncertainty upon which decisions are made in order to avoid the making of an incorrect decision and to enable identification of additional investigation monitoring or remediation activities required on the basis of accurate data for the protection of human health and the environment The Measuring Quality Objectives (MQO) include the quality assurance (QA) activities that were conducted during the assessment the quality control (QC) acceptance criteria applicable to the assessment and the adopted Data Quality Indicators (DQIs) as follows (and further discussed in Section 5) completeness ndash a measure of the amount of useable data from a data

                  collection activity comparability ndash the confidence (expressed qualitatively) that data may be

                  considered to be equivalent for each sampling and analytical event representativeness ndash the confidence (expressed qualitatively) that data

                  are representative of each media present on the site precision ndash a quantitative measure of the variability (or reproducibility) of

                  data and accuracy (bias) ndash a quantitative measure of the closeness of reported data

                  to the true value

                  Step 7 ndash Optimisation of the Data collection was undertaken in general accordance with the Sample Collection Design methodologies outlined in the relevant documentsguidelines referenced

                  throughout this report As determined by the EPA the data collection design included targeted sampling to investigate and delineate areas of potential groundwater and soil vapour contamination and to assess potential associated human health risks

                  80607-1 REV1 30102017 PAGE 9

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  3 SCOPE OF WORK

                  The scope of work undertaken by Fyfe was generally consistent with that requested within the original EPA request for quote (RFQ) dated 27 March 2017 Some modifications to the original workscope occurred based on site findings and additional site information was collected where required and as agreed with the EPA in order to achieve the EPArsquos project objectives outlined in Section 15

                  As identified in the RFQ the scope of work was designed to

                  provide an initial delineation of CHC impacts in soil vapour through the deployment of Waterloo Membrane Samplers (WMStrade) as a screening tool

                  further delineate the previously identified CHC impacts in groundwater

                  decide based on the results of the WMStrade and groundwater results the need for the number of and the locations of permanent soil vapour monitoring bores

                  identify the nature extent and potential source area(s) of the identified CHC impacts in groundwater andor soil vapour

                  determine the likely fate and transport of the groundwater CHC plume to support the establishment of a potential future GPA

                  determine the potential human health (including vapour intrusion) risk(s) on the basis of the data collected and

                  ascertain whether or not a public health risk exists within the Thebarton EPA Assessment Area

                  The scope of work is further detailed in Section 32 Variations from the scope of work originally requested in the EPA RFQ were agreed with the EPA during the course of the project and included the following

                  deployment of an additional four WMStrade units ndash ie 41 in total as compared to the original allowance of 37

                  installation (and sampling) of an additional six nested soil vapour bores (to depths of 1 and 3 m BGL) ndash ie 11 in total as compared to the original allowance of five

                  installation (and sampling) two individually located (ie as opposed to the nested locations) soil vapour bores to a depth of 1 m BGL ndash ie as compared to the original allowance of 10

                  installation (and sampling) of 25 groundwater monitoring wells ndash ie as compared to the original allowance of 20 and

                  sampling of an existing well in Admella Street (MW02) ndash ie not included in the original EPA scope

                  80607-1 REV1 30102017 PAGE 11

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  31 Preliminary work

                  Preliminary work involved the following

                  review and summation of all available historical reports (as supplied by the EPA) ndash refer to Appendix A

                  development of a preliminary (working) conceptual site model (CSM) based on a review of the historical data

                  preparation of a detailed health and safety plan covering all aspects and stages of the work and

                  detailed planning with key stakeholders prior to the execution of the field investigation program

                  32 Field investigation and laboratory analysis program

                  The scope of the field investigation program undertaken by Fyfe between 31 May and 28 August 2017 is summarised in Table 31 whereas the scope of the laboratory testing program is summarised in Table 32

                  A plan showing the various assessment point locations is included as Figure 2

                  Table 31 Scope of field investigation program ndash May to August 2017

                  Scope Item Description of works Date of works

                  Passive soil vapour sampling ndash Round 1

                  Thirty-seven WMStrade units identified as WMS 1 to WMS 37 were installed within the soil profile to 1 m BGL at scattered (approximately grid-like) locations across the Thebarton EPA Assessment Area

                  31 May and 1 to 2 June

                  The WMStrade units were extracted and forwarded to the analytical laboratory 7 June

                  Soil bores were located using a hand-held global positioning system (GPS) unit before being backfilled with (drillerrsquos) sand

                  7 August

                  Monitoring well drilling and installation

                  Individual groundwater well permits were obtained from DEWNR prior to well installation ndash copies of the well permits are included in Appendix D Groundwater monitoring wells (MW1 MW3 and MW5 to MW26) were installed to depths of between 15 and 19 m BGL at 24 locations across the Thebarton EPA Assessment Area Background well MW4 was installed to 19 m BGL within a public recreational area located across James Congdon Drive to the east (ie near the south-eastern corner of the Thebarton EPA Assessment Area) All 25 newly installed wells were developed following installation

                  28 to 30 June 3 to 7 July and 10 to 14 July

                  Geotechnical soil testing

                  Intact soil cores collected during the drilling of 10 groundwater wells (MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25) were forwarded to the analytical laboratory for geotechnical testing

                  Groundwater gauging

                  All 25 newly installed monitoring wells (MW1 and MW3 to MW26) as well as the existing Admella Street well (MW02) were gauged to assess total well depth standing water level (SWL) and the presenceabsence of non aqueous phase liquid (NAPL) This was undertaken as a discrete event prior to the commencement of groundwater sampling

                  18 July

                  PAGE 12 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Scope Item Description of works Date of works

                  Groundwater sampling

                  All 26 existing and newly installed wells were sampled using a combination of low flow (micropurge) and HydraSleevetrade sampling techniques (as recorded on the field sampling sheets in Appendix E) ndash samples were forwarded to the analytical laboratories

                  18 to 21 and 24 to 25 July

                  Aquifer testing Aquifer permeability (slug) testing was undertaken on 10 wells (MW02 MW3 MW7 MW14 MW17 MW20 MW21 MW23 MW25 and MW26) Data was subsequently evaluated by Arcadis Pty Ltd (Arcadis) to estimate the hydraulic conductivity of the aquifer beneath the Thebarton EPA Assessment Area (refer to Section 732)

                  28 July

                  Soil vapour bore drilling and installation

                  Following the receipt of the groundwater data 11 nested soil vapour bores (SV1 to SV10 and SV12) were installed to a depth of 1 and 3 m BGL at selected locations within the Thebarton EPA Assessment Area Two additional soil vapour bores (SV11 and SV13) were installed to a depth of 1 m BGL

                  18 21 and 22 August

                  Active soil vapour sampling

                  Sampling of soil vapour bores was undertaken using summa canister (TO-15) sample collection methods Vapour (canister) and general gas (Tedlar bag) samples were extracted from all 13 locations (ie SV1 to SV13) including the 11 nested bores

                  24 August

                  Passive soil vapour sampling ndash Round 2

                  Following the receipt of the groundwater data and for the purposes of comparison with the soil vapour bore data an additional four WMStrade units (WMS 38 to WMS 41) were installed within the soil profile to 1 m BGL at targeted locations across the Thebarton EPA Assessment Area (ie within approximately 1 m of soil vapour bores SV2 SV4 SV5 and SV7) Soil bores were located using a hand-held GPS unit

                  18 August

                  The WMStrade units were extracted and forwarded to the analytical laboratory and the soil bores were backfilled with (drillerrsquos) sand

                  24 August

                  Surveying The locations of all soil vapour bores and groundwater wells were surveyed by a licensed surveyor relative to the Map Grid of Australia (MGA) 1994 and the top of each bore was surveyed relative to Australian Height Datum (AHD) The survey data are included in Appendix F

                  22 July and 28 August

                  Notes as determined by the EPA

                  Table 32 Scope of laboratory testing program

                  Scope Item Description of works

                  Soil geotechnical testing

                  Soil samples from each of three depths within core samples collected during the drilling of groundwater wells MW3 MW5 MW7 MW11 MW12 MW17 MW19 MW21 MW22 and MW25 were analysed for particle size distribution (PSD) moisture content including degree of saturation bulk density dry density and specific gravity void ratio and porosity

                  80607-1 REV1 30102017 PAGE 13

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Scope Item Description of works

                  Groundwater testing Groundwater samples from all 26 wells were analysed for the COPC detailed in Section 14 As requested by the EPA groundwater samples from selected wells (MW02 MW5 MW8 MW9 MW12 MW17 MW21 MW22 MW23 and MW26) were also analysed for the following major cations and anions (calcium magnesium sodium potassium chloride and alkalinity)

                  and natural attenuation parameters (carbon dioxide (CO2) sulfate iron manganese nitrate) Additional components reported by the analytical laboratory included nitrite and nitrate + nitrite

                  Soil vapour testing The WMStrade units deployed during each of Rounds 1 and 2 were analysed for the COPC detailed in Section 14 The soil vapour (summa canister) samples were analysed for the COPC detailed in Section 14 as well as 2-propanol and general gases (helium hydrogen oxygen nitrogen methane carbon dioxide ethane propane butane iso-butane pentane iso-pentane hexane argon carbon monoxide and ethylene)

                  Notes Specific sample depths are detailed in the relevant laboratory reports in Appendix G also known as isopropyl alcohol isopropanol or IPA

                  33 Data interpretation

                  Following the receipt and collation of the field and laboratory data hydrogeological (fate and transport) and VIRA modelling (refer to Sections 8 and 9 respectively) were undertaken to enable an assessment of risk and to refine the CSM (Section 10)

                  PAGE 14 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  4 METHODOLOGY

                  41 Field methodologies

                  Prior to the commencement of the field investigations a site specific Health and Safety Plan (HSP) including Safe Work Method Statements (SWMS) and a Job Hazard Analysis (JHA) was prepared ndash all personnel working at the site were required to read understand sign and conform to the HSP

                  Each proposed drilling location was cleared of underground services by a professional service location company (Pipeline Technologies) using conventional (electronic) service detection methods as well as ground penetrating radar (GPR) Where underground or overhead services were present andor deemed to be a potential safety risk during drilling activities the drill location was moved to an area considered by the Fyfe representative and service locator to be safe All changes to drilling locations were notified to EPA and recorded on a site plan for future reference

                  Given that works were undertaken within suburban streets Fyfe employed the services of a qualified traffic management company (Altus Traffic) during drilling activities in order to ensure safety for pedestrians and road users minimal disruption to traffic flow and the provision of a safe working environment

                  Field methodologies as detailed in Table 41 were undertaken in accordance with Fyfersquos standard operating procedures (SOPs) Relevant field sampling sheets are included in Appendices F (groundwater) and G (soil vapour ndash combined field sampling sheets and chain of custody (COC) documents) and borehole log reports are presented in Appendices H (groundwater) I (WMStrade) and J (soil vapour)

                  Table 41 Summary of field methodologies

                  Activity Details

                  Passive soil bore sampling The soil bores used to deploy the WMStrade units were hand augered by personnel from Fyfe and Aussie Probe to a depth of 1 m BGL SGS Australia (SGS) personnel suspended each WMStrade unit into its respective borehole from a string The hole was then sealed with an expandable foam plug inside a polyethylene sleeve and the string suspending the sampler was connected to a temporary plastic cap at the ground surface The Round 1 WMStrade units were deployed for periods of between six and seven days whereas the Round 2 WMStrade units were all deployed for six days Following retrieval by SGS each WMStrade unit was placed into a sealed glass vial and a labelled foil bag The WMStrade units did not require chilling during transport to the analytical laboratory Borehole log reports are included in Appendix I whereas combined field sampling sheets and COC documents are presented in Appendix G

                  80607-1 REV1 30102017 PAGE 15

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Activity Details

                  Groundwater well Groundwater wells were drilled by WB Drilling using a combination of hand augering installation mechanical pushtube and solid auger techniques

                  Following the completion of drilling each borehole was fitted with 50 mm class 18 uPVC casing with a basal 6 m long section of slotted well screen A filter pack comprising clean graded sands of suitable size to provide sufficient inflow of groundwater was installed within the annular space between the borehole and the well casing and extended from the base of the screened interval to approximately 1 m above the termination of the slotted casing A 1 m long bentonite collar comprising pelleted or granulated bentonite was placed above the filter pack to prevent water seepage downward along the well casing or borehole from ground surface Each well was grouted up to surface level and fitted with a (lockable) steel gatic cover the latter flush mounted to prevent tripping andor other hazards Groundwater well log reports are included in Appendix H

                  Soil logging and Soil logging was undertaken in general accordance with the ASC NEPM (1999) which geotechnical sampling endorses AS1726-1993 In addition to the requirements of AS1726-1993 particular

                  attention was paid during logging to any lithological variations such as sandgravel lenses or secondary porosity (such as clay fracturing) which may act as potential preferential pathways for contaminant vapourgroundwater migration through the sub-surface as well as the presence of fill material andor any olfactory or visual evidence of contamination Soil descriptions have been included on the logs in Appendices H to J Cores for geotechnical analysis were collected using push tube sampling methodologies to obtain undisturbed samples Section(s) of core to be tested were retained (intact) within the pushtube liners and capped at each end for storage and transport to the analytical laboratory

                  Field screening of soils Field screening of individual soil layers was undertaken at the majority of the drilling locations and involved the use of a photoionisation (PID) unit fitted with an 117 eV lamp (ie as considered suitable for the detection of CHC) The PID unit was calibrated by the hire company prior to delivery and was checked on a daily basis against an isobutylene calibration gas of known concentration Field screen samples were collected with care to ensure that each sample was representative of the soil stratum from which it was collected and experienced minimal loss of volatile compounds The soil material was placed immediately into a zip lock bag and sealed ensuring the bag was half filled (ie such that the volume ratio of soil to air was equal) Soil clumps within the bag were manually broken up and the bag was left to rest for a minimum of five minutes but no longer than 20 minutes Prior to testing the bag was shaken vigorously to release any vapours within the soil To test the tip of the PID probe was inserted into the bag and the maximum volatile organic compound (VOC) reading recorded after a nominal 10 second period or when the reading had peaked Results were recorded on the appropriate bore log sheets presented in Appendices H to J

                  Groundwater well Following installation the wells were developed by purging a minimum of four well development volumes (ie until stable parameters were obtained andor until the well purged dry) from

                  the casing with a steel bailer andor twister pump to ensure hydraulic connectivity with the aquifer formation

                  Groundwater gauging Groundwater levels in the newly installed and existing monitoring wells located across the Thebarton EPA Assessment Area were gauged using an interface probe prior to the commencement of the groundwater sampling program All monitoring wells were gauged for SWL the potential presence of NAPL and the total well depth Groundwater field gauging results are presented in Appendix E

                  PAGE 16 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Activity Details

                  Groundwater sampling The majority of the wells were sampled using low flow (micropurge) techniques Where recovery was particularly low (ie MW4 MW8 MW15 MW18 MW19 and MW24) and unsuitable for low flow (micropurge) sampling the original sampling technique was abandoned and a HydraSleeveTM (no purge) methodology was used instead Groundwater samples were collected in laboratory-supplied screw top bottles containing appropriate preservative (if required) with no headspace allowed Samples were chilled during storage and transport to the analytical laboratory Disposable nitrile gloves worn by field personnel were changed prior to the collection of each sample Samples for metals (ie iron manganese) analysis were filtered in the field using 045 microm filters Groundwater field sampling sheets are presented in Appendix E

                  Low Flow Methodology The low flow sampling technique involved the following the pump was placed close to the bottom of the screened interval the flow rate (up to 05 Lmin) was regulated to maintain an acceptable level of

                  drawdown with minimal fluctuation of the dynamic water level during pumping and sampling

                  groundwater drawdown was monitored constantly during purging and sampling using an interface probe

                  water quality parameters were considered to have stabilised when the following ranges were recorded over three consecutive readings ndash electrical conductivity plusmn 5 ndash pH plusmn 01 ndash temperature plusmn 02degC ndash dissolved oxygen plusmn 10 ndash redox potential plusmn 10 mV

                  the stabilisation parameters were recorded on field logging sheets after every one litre of groundwater purged using a calibrated water quality meter and a flow cell suspended in a bucket with litre intervals marked and

                  samples were collected once three consecutive stabilisation parameters were recorded and a volume of between 28 and 6 litres was purged prior to sampling

                  HydraSleeveTM Methodology The HydraSleeveTM sampling technique involved attaching a stainless steel weight to the bottom and a wire tether clip to the throat of the HydraSleeveTM before lowering it into the water column to the desired depth and allowing it to fill with groundwater After a minimum period of 24 hours the HydraSleeveTM was quickly and smoothly withdrawn from the well and the contents were transferred into the sample containers Water quality parameters were measured after samples were decanted ndash either within the water remaining in the HydraSleeveTM or within a grab sample collected using a disposable bailer

                  Hydraulic testing Rising and falling head permeability (ldquoslugrdquo) tests were undertaken to estimate the hydraulic conductivity (K) of the aquifer within various parts of the Thebarton EPA Assessment Area The falling-head tests were initiated by quickly inserting a 1285 m long and 36 mm diameter solid PVC cylinder (slug) into the water column at each well to produce a sufficient sudden rise in the water level The subsequent ldquofallrdquo back to the static water level (recovery) was measured and recorded automatically and in real-time using a

                  80607-1 REV1 30102017 PAGE 17

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Activity Details

                  pressure transducerdata logger programmed to record water levels at a one second interval After static water level conditions returned in the well the rising-head test was initiated by quickly removing the slug from the well to create a sudden drop in the water column height As with the falling-head test the rise of the water level back to a static condition (recovery) was automatically recorded

                  Soil vapour bore Soil vapour bores were drilled by Aussie Probe using a combination of hand augering and installation mechanical pushtube techniques

                  Within each 3 m deep soil vapour bore teflon tubing attached to a soil vapour probe was inserted to the base of the hole which had been prefilled with approximately 005 m of clean filter pack sand An additional 045 m of sand (ie approximately 05 m in total) was then added to the hole and topped by a bentonite plug seal of approximately 05 m thickness A second soil vapour probe was installed at a depth of about 1 m within a 05 m sand pack which was overlain by bentonite to a depth of about 02 to 03 m BGL The two 1 m deep soil vapour bores were installed in a similar manner with a sand pack extending from the base to about 05 to 06 m BGL overlain by a bentonite plug to 03 m BGL Each installation was completed with grout to surface and topped with a standard flush-mounted gatic cover Soil vapour bore log reports are included in Appendix J

                  Soil vapour sampling All soil vapour sampling works were undertaken by SGS using suitably trained and experienced personnel ndash SGS holds National Association of Testing Authorities (NATA) accreditation for all soil vapour sampling and laboratory analytical works Combined field sampling sheets and COC documents are presented in Appendix G Soil vapour samples were collected using summa canisters and analysed using the US EPA (1999) TO-15 method Sampling involved the connection of a passivated 1 L stainless steel canister to the teflon tubing extending from the soil vapour probe and the use of a soil gas sampling train to restrict flow to a maximum rate of 200 mLmin Canister vacuum pressure was monitored during sampling to enable calculation of the volume of sample drawn into the canister ndash the small amount of vacuum left in the canister at the end of the sampling procedure was measured in the laboratory to check if any leaks occurred during transit (refer to further discussion in Table 52) A shroud was set up around the sampling point and tracer chemicals were introduced at high concentrations by flooding the shroud with helium and placing a cloth soaked with IPA into the shroud Each canister was cleaned and certified by SGS prior to use (refer to Appendix G) and backshyup coconut shell carbon sorbent tube samples were also collected (but not analysed) Summa canisters did not require chilling during transport to the analytical laboratory

                  Waste disposal Waste water and surplus soil corescuttings were stored together within 205 litre drums in the rear car park of a commercialindustrial property at 19-21 James Congdon Drive (as organised by the EPA) prior to removaldisposal by a licensed waste removal company (Cleanaway) Analytical results pertaining to the soils were forwarded to the licensed receiving facility and all of the soil was classified as lsquoWaste Fillrsquo in accordance with the Environment Protection Regulations 2009 The waste transport certificates are included in Appendix K

                  PAGE 18 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  42 Laboratory analysis

                  The following laboratories were used for the analysis of the environmental samples

                  complete soil cores for geotechnical sample analysis were forwarded to SMS Geotechnical

                  primary groundwater samples collected by Fyfe were analysed at the SGS laboratory whereas secondary groundwater samples were forwarded to EurofinsMGT and

                  soil vapour (including WMStrade) samples collected by SGS were analysed at their laboratory

                  80607-1 REV1 30102017 PAGE 19

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  5 QUALITY ASSURANCE AND QUALITY CONTROL

                  Data quality is typically discussed in terms of the DQIs presented in Table 22 ndash ie completeness comparability representativeness precision and accuracy In order to assess the quality of the data collected during the Fyfe investigation program against these DQIs specific QAQC procedures were implemented during both the field sampling and laboratory analysis programs as detailed in the following sections

                  51 Field QAQC

                  Field QA procedures undertaken during the recent investigations included the collection of the following QC samples aimed at assessing possible errors associated with cross contamination as well as inconsistencies in sampling andor laboratory analytical techniques

                  intra-laboratory duplicate (duplicate) samples submitted to the same (primary laboratory) to assess variation in analyte concentrations between samples collected from the same sampling point andor the repeatability (precision) of the analytical procedures

                  inter-laboratory duplicate (split or triplicate) samples submitted to a second laboratory to check on the analytical proficiency (accuracy) of the results produced by the primary laboratory

                  equipment rinsate blank samples collected during groundwater sampling only and used to assess cross-contamination that may have occurred from sampling equipment during sampling and

                  trip blank samples used to assess whether cross-contamination may have occurred between samples during transport

                  Whereas analyte concentrations within the rinsate and trip blank samples should be below the laboratory limit of reporting (LOR) the inter- and intra-laboratory duplicate sample results are assessed via the calculation of a relative percentage difference (RPD) as follows

                  (Concentration 1 minus Concentration 2) x 100RPD = (Concentration 1 + Concentration 2) 2

                  Maximum RPDs of 30 (inorganics) and 50 (organics) are generally considered acceptable with higher RPD values often recorded where concentrations of an analyte approach the laboratory LOR

                  All field QC sample results are included in the summary data tables in Appendix L

                  511 Groundwater

                  Table 51 presents conformance to field QAQC procedures undertaken as part of the groundwater investigations

                  80607-1 REV1 30102017 PAGE 21

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Table 51 Field QAQC procedures ndash Groundwater

                  QAQC Item Detail

                  Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) AustralianNew Zealand standards ASNZS 566711998 and ASNZS 5667111998 SA EPA (2007) and Fyfe SOPs Details are provided in Table 41

                  Calibration of field equipment

                  Documentation regarding the calibration of field equipment is included in Appendix M

                  Decontamination of All disposable equipment (tubing pump bladders plastic bailers bailer cord and equipment HydraSleeveTM units) were replaced between wells Re-usable equipment (micropurge pump

                  interface probe and HydraSleeveTM weights) was decontaminated between sampling locations using potable water and Decon 90trade phosphate free detergent

                  Sample preservation and storage

                  Samples were kept in laboratory supplied containers in a portable chilled insulated box (esky) prior to and during transport to the laboratory

                  Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

                  Duplicate samples Two intra-laboratory and two inter-laboratory duplicate samples were analysed for CHC with respect to 26 primary groundwater samples ndash thereby constituting an overall ratio of approximately one duplicate per 65 primary samples (or 15) compared to a generally acceptable ratio of 110 samples (or 10) One intra-laboratory and one inter-laboratory duplicate sample were analysed for the remaining parameters with respect to 10 primary groundwater samples ndash thereby constituting an overall ratio of one duplicate per five primary samples (or 20) compared to a generally acceptable ratio of 110 samples (or 10) Intra- and inter-laboratory duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within the acceptable range with the exception of the following intra-laboratory duplicate sample pair MW9QW1 TCE (67) nitrate (147) and inter-laboratory duplicate sample pair MW9QW2 total CO2 (59) iron (190)

                  manganese (183) potassium (64) nitrate (194) The elevated RPD for TCE in the intra-laboratory duplicate sample pair is considered to be related to the low concentration detected and does not alter the interpretation of the data The other RPD exceedances are not considered significant (ie in terms of overall data interpretation) as they were not obtained for identified COPC (as defined in Section 14)

                  Rinsate blank samples Six equipment rinsate blank samples (one for each day of sampling) were collected from either the pump housing or a new HydraSleevetrade (final day of sampling only) and analysed for CHC to confirm the effectiveness of the decontamination procedures and the cleanliness of disposable equipment The analytical results obtained for the rinsate blank samples were all below the laboratory LOR thereby indicating that decontamination practices during the groundwater sampling program were acceptable and that no contamination was introduced by the use of the HydraSleevestrade

                  Trip blank samples Six trip blank samples were included within containers (eskies) of sample bottles provided by the analytical laboratory and returned to the analytical laboratory All of the trip blank samples were analysed for CHC With the exception of TB187 which contained 1 microgL TCE the analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was limited impact on sample quality during storage or transport of the samples to the analytical laboratory

                  PAGE 22 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Notes No duplicate QC samples were collected during the use of the HydraSleeveTM sampling technique as detailed in ANZECCARMCANZ (2000a) at least 5 (ie 120) duplicate samples should be analysed ndash the generally accepted industry standard however is 10 (110) including 5 intra-laboratory and 5 inter-laboratory duplicates

                  512 Soil vapour

                  Tables 52 presents conformance to field QAQC procedures undertaken as part of the soil vapour (passive and active) investigations

                  Table 52 Field QAQC procedures ndash Soil vapour

                  QAQC Item Detail

                  Field procedures Field procedures were undertaken in accordance with the ASC NEPM (1999) as well as ASTM (2001 2006) ITRC (2007) CRC CARE (2013) guidance and Fyfe SOPs Details are included in Table 41 and Appendix G (ie SGS sampling methodology sheet) During the use of summa canisters to sample the soil vapour bores leak testing was undertaken (as described in Table 41) Although small leaks or ambient drawdown appear to have occurred with respect to samples SV11_10m (003 helium) SV13_10m (003 helium) and SV1_10m (360 microgm3 IPA) ITRC (2007) and NJDEP (2013) state that ge 5 helium andor gt10 mgm3 IPA are required to be indicative of a significant leak or substantial ambient drawdown Given that the leaks were relatively small (ie 06 (helium) and 36 (IPA) of the levels considered indicative of a significant leak) the data from these bores were still considered to be valid ndash refer to SGS correspondence in Appendix G As detailed in Table 41 a small amount of vacuum was generally left in each summa canister at the end of the sampling procedure and was measured in the laboratory to check if any leaks had occurred during transit However samples SV11_10m SV12_30m as well as the helium blank were recorded as having zero vacuum upon receipt at the analytical laboratory A query lodged with SGS regarding this issue indicated that whereas the helium blank comprised a grab sample collected into a Tedlar bag directly from the helium cylinder (ie without the use of a gauge) the canisters used for samples SV11_10m and SV12_30 were filled during sampling so that there was no remaining vacuum ndash refer to field sampling documentation in Appendix G SGS stated that although it is good practice to have a small amount of vacuum remaining in a canister at the completion of sampling appropriate additional QC measures were employed and the absence of other common background VOCs (eg petroleum hydrocarbons) upon sample testing indicated that leakage had not occurred during transit In addition all canisters are fitted with quick connect one-way valves that are closed upon removal from the sampling train and canistersfittings are leak checked prior to leaving the laboratory and again in the field to ensure that they are leak free Refer to SGS correspondence in Appendix G The presence of detectable IPA (120 microgm3) and TCE (48 microgm3) in the helium blank was also queried with SGS who stated that this (ie variability in the quality of the high purity helium gas used) is not an uncommon occurrence The reason for collecting a helium blank sample is to identify any impurities present in the helium gas so that if a leak does occur during sampling it is possible to determine whether any target compounds could be introduced into the sample train Although a target compound (ie TCE) was detected in the blank the concentration is minor and even if a leak had occurred during sampling (of which there was no evidence) it would not have affected the overall results and data interpretation The presence of IPA in the helium blank is

                  80607-1 REV1 30102017 PAGE 23

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  QAQC Item Detail

                  suspected by SGS of having resulted from a handling issue in the field ndash ie sub-sampling from the helium cylinder (ie into a summa canister via a flex foil bag) in the vicinity of the high concentrations of IPA being used for leak detection Refer to SGS correspondence in Appendix G

                  Sample preservation and storage

                  Following collection the WMStrade units were placed into individual glass vials which were sealed and placed into foil bags for transport to the analytical laboratory at ambient temperature Summa canisters were stored in specially constructed cases during transport to the analytical laboratory at ambient temperature

                  Sample tracking COC documentation was used for the transport of all samples to the laboratory and is included in Appendix G

                  QC samples ndash WMStrade sampling

                  During the first round of passive soil vapour sampling three additional WMStrade units were deployed in soil bores drilled adjacent to WMS 22 WMS 25 and WMS 28 to act as duplicate QC samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 8) Two trip blank samples were also included with samples transported from and to the analytical laboratory All of the QC samples were analysed by the primary laboratory Intra-duplicate sample RPDs were calculated where both data sets had a reported concentration above the specific analyte laboratory LOR All calculated RPDs for CHC were within an acceptable range (ie lt30) The analytical results obtained for the trip blank samples were all below the laboratory LOR thereby indicating that there was negligible impact on sample quality during storage or transport of the samples to the analytical laboratory

                  QC samples ndash soil vapour bore sampling

                  Two intra-laboratory duplicate QC samples were analysed for CHC and general gases with respect to 24 primary soil vapour samples ndash thereby constituting a ratio of approximately one duplicate per 12 primary samples (or 83) compared to an acceptable ratio of 110 samples (or 10) Intra-laboratory duplicate RPDs were calculated where both samples had a reported concentration above the laboratory LOR All calculated RPDs for CHC and general gases were within an acceptable range (ie lt30) The analytical results obtained for the helium shroud (Tedlar bags) helium blank and IPA shroud (carbon tube) samples were all considered to be satisfactory

                  Notes The American Society for Testing and Materials (ASTM) is an internationally recognised source of testing methods Although Appendix J of CRC CARE (2013) stipulates a 110 duplicate sampling ratio for active vapour sampling a specific ratio is not stipulated for passive vapour sampling

                  52 Laboratory QAQC

                  Laboratory QA procedures generally include the performance of a number of internal checks of data precision and accuracy that are aimed at assessing possible errors associated with sample preparation and analytical techniques Specific types of QC samples analysed by laboratories and the relevant acceptance criteria are as follows

                  PAGE 24 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  internal laboratory replicate samples maximum RPD values of 20 to 50 although this varies depending on laboratory LOR

                  spike recoveries results between 70 and 130 and

                  laboratory controlmethod blanks results below the laboratory LOR

                  Table 53 presents conformance to laboratory QAQC procedures undertaken as part of the overall investigation program

                  Table 53 Laboratory QAQC procedures

                  QAQC Item Detail

                  Samples analysed and Samples were generally analysed within specified holding times ndash with the exception extracted within relevant of the following groundwater samples holding times SGS report no ME303457 nitrate was analysed two days late in some samples

                  (MW5 MW17 MW26) SGS report no ME303475 nitrate was analysed one day late in all samples and EurofinsMGT report no 555810-W total CO2 was analysed five days late None of these holding time exceedances are considered to be significant with respect to the interpretation of the CHC data the determination of potential human healthenvironmental risks andor the determination of natural attenuation

                  Laboratories used and The laboratories used (SGS Eurofins MGT and SMS Geotechnical) were NATA NATA accreditation accredited for the majority of the analyses undertaken

                  The exception was SMS Geotechnical which was not NATA accredited for the calculations undertaken to derive some of the data ndash this is the case however for all geotechnical laboratories

                  Appropriate analytical methodologies used

                  Refer to the laboratory reports in Appendix G

                  Laboratory limit of The laboratory LOR is the minimum concentration of an analyte (substance) that can reporting (LOR) be measured with a high degree of confidence that the analyte is present at or above

                  that concentration The LOR are presented in the laboratory certificates of analysis (Appendix G) and are considered to be generally appropriate (ie below the adopted assessment criteria ndash refer to Section 62) ndash the following exceptions in soil vapour (ie considered to be due to interference associated with elevated concentrations of other compounds ndash refer to SGS correspondence in Appendix G) are discussed further in Table 101 VC in all of the WMStrade samples relative to the ASC NEPM (1999) interim soil

                  vapour health investigation level (HIL) for residential land use cis-12-DCE and VC in two soil vapour bore samples (SV2_30m and SV3_30m)

                  relative to the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land use and

                  VC in two soil vapour bore samples (SV3_10m and SV7_30m) relative to the ASC NEPM (1999) interim soil vapour HIL for residential land use

                  In addition to the above although ultra-trace analysis was requested the laboratory LOR for VC in groundwater (ie 1 microgL) is above the adopted NHMRCMRMMC (2011) potable guideline (ie 03 microgL) ndash refer to Section 612

                  80607-1 REV1 30102017 PAGE 25

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  QAQC Item Detail

                  Laboratory internal QC analyses

                  Results obtained for the laboratory internal QC samples were generally within the acceptable limits of repeatability chemical extraction and detection with the exception of the following SGS report ME303457 matrix spike results for iron were outside normal tolerances

                  due to the high concentrations of iron in the spiked sample ndash matrix spike results for iron could therefore not be calculated This is not considered to be a significant issue

                  Full details regarding laboratory QAQC procedures and results are presented in the certified laboratory certificates contained in Appendix G

                  Notes Since holding times were not specified in the SGS groundwater reports Fyfersquos assessment of holding times has been based on those adopted by EurofinsMGT (ie the secondary laboratory used for groundwater analysis) ie in accordance with Schedule B3 of the ASC NEPM (1999) also referred to as practical quantification limits (PQL)

                  53 QAQC summary

                  In summary it is considered that

                  the field QAQC programs were generally undertaken with regard to relevant legislation standards andor guidelines and were sufficient for obtaining samples that are representative of site conditions and

                  the overall laboratory QAQC procedures and results were adequate such that the laboratory analytical results obtained are of acceptable quality for addressing the key objectives outlined in Section 15

                  PAGE 26 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  6 ASSESSMENT CRITERIA

                  61 Groundwater

                  611 Beneficial Use Assessment

                  In accordance with Schedule B6 of the ASC NEPM (1999) and SA EPA (2009) a Beneficial Use Assessment (BUA) was undertaken to assess both the current and realistic future uses of groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area

                  This was aimed at determining what groundwater uses need to be protected and assessing the risk(s) that groundwater may pose to human health and the environment (refer also to the VIRA in Section 9)

                  As summarised in Table 61 the potential beneficial uses for groundwater within the Q1 aquifer that have been considered are as follows ndash taking into account the salinity of the groundwater the Environment Protection (Water Quality) Policy 2015 (Water Quality EPP 2015) the DEWNR (2017) WaterConnect database information presented in Section 222 and possible sensitive receptors located within andor within the vicinity of the Thebarton EPA Assessment Area

                  The salinity of groundwater has been calculated to approximate 1230 to 3620 mgL TDS (refer to Section 7312) According to the Water Quality EPP 2015 the applicable environmental values for groundwater with salinity above 1200 mgL TDS but less than 3000 mgL TDS are irrigation livestock and aquaculture whereas the salinity is considered to be too high for potable use ndash although domestic irrigation is considered to be a potentially realistic use for this area (see below) livestock watering is considered unlikely to be undertaken in such an urban setting and no local water bodies (ie surface or groundwater) have been identified as being used for commercial aquaculture purposes

                  The DEWNR (2017) WaterConnect database indicates that groundwater within the Q1 aquifer in the Thebarton area is accessed for drainage domestic and industrial purposes ndash domestic groundwater use could include garden irrigation plumbing water andor the filling of swimming pools (ie primary contact recreation) Although domestic groundwater extraction is considered unlikely to include potable use (ie due to its salinity and the availability of a reticulated mains water supply) potential mixing with rain watermains water could render it suitable (ie from a salinity perspective) for drinking

                  As the closest freshwater surface water body the River Torrens is located approximately 03 km to the east and 07 km to the north and north-west of the northern portion of this area groundwater discharge from the Thebarton EPA Assessment Area into a freshwater aquatic ecosystem is considered possible However as the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area the potential for impact on a freshwater aquatic environment has not been confirmed

                  80607-1 REV1 30102017 PAGE 27

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Since the closest marine surface water body Gulf St Vincent is located approximately 8 km to the west groundwater discharge from the Thebarton EPA Assessment Area into a marine aquatic ecosystem is not considered to be realistic

                  Since volatile contaminants have been detected within the Q1 aquifer (refer to Section 7331) a potential vapour flux risk to future site users must be considered

                  Given the measured depth of the Q1 aquifer beneath the site (ie approximately 1232 to 1585 m BGL ndash refer to Section 7311) it is considered unlikely that direct contact could occur between groundwater and building footingsunderground services

                  Table 61 Assessment of groundwater beneficial uses for Thebarton EPA Assessment Area

                  Environmental Values Beneficial Uses

                  Water Quality EPP 2015

                  environmental value

                  SA EPA (2009) Potential

                  Beneficial Uses

                  Beneficial Use Assessment

                  Considered Applicable

                  Aquatic Ecosystem

                  Marine Yes No

                  Fresh Yes Possibly

                  Potable - Yes Possibly

                  Agriculture Irrigation - Yes Yes

                  Livestock - Yes No

                  Aquaculture - Yes No

                  Recreation amp Aesthetics

                  Primary contact Yes Possibly

                  Aesthetics Yes Possibly

                  Industrial - Yes Yes

                  Human health in non-use scenarios

                  Vapour flux -

                  Yes Yes

                  Buildings and structures

                  Contact - Yes No

                  Notes ie for underground waters with a background TDS level of between 1200 and 3000 mgL ndash note that although they are not listed as environmental values of groundwater in Schedule 1(3) of the Water Quality EPP 2015 aquatic ecosystems as well as recreation amp aesthetics are included as environmental values for waters in general in Part 1(6) of the document ie domestic irrigation only

                  612 Groundwater beneficial use criteria

                  The health and ecological criteria used for the assessment of the COPC (refer to Section 14) in groundwater have been based on the results of the BUA (Section 611) A summary of the references used to source the groundwater assessment criteria is provided in Table 62

                  PAGE 28 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Table 62 Sources of adopted groundwater assessment criteria

                  Beneficial Use Reference

                  Freshwater Ecosystems No criteria available for COPC

                  Potable NHMRCNRMMC (2011) Australian Drinking Water Guidelines

                  WHO (2017) Guidelines for Drinking-water Quality ndash TCE only

                  Irrigation No criteria available for COPC

                  Primary contact recreation (including aesthetics)

                  NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines but (with the exception of aesthetic guidelines) multiplied by a factor of 10 to take account of accidental ingestion rates as opposed to deliberate ingestion

                  ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality ndash recreational values (TCE only)

                  Human health in non-use scenarios ndash vapour flux Refer to the VIRA in Section 9

                  Notes As there are no specific guidelines for industrial water these values are considered likely to be protective of this additional beneficial use The NHMRC (2008) guidelines are based on drinking water levels and assume a consumption factor of 2 L per day Therefore as recommended in the NHMRC (2008) document potable criteria (ie with the exception of aesthetic criteria) need to be adjusted by a factor of 10 to account for an accidental consumption rate of 100 to 200 ml per day As noted in ANZECCARMCANZ (2000b) although recreational guidelines are protective of ingestion recreational waters should also not contain any chemicals that can cause skin irritation likewise although not specifically addressed by recreational water criteria inhalation may also represent a source of exposure with respect to some (ie volatile) contaminants In the absence of a NHMRCNRMMC (2011) drinking water guideline for TCE the ANZECCARMCANZ (2000b) recreational criterion (30 microgL) has been adopted However if the NHMRC (2008) rule of multiplying potable (healthshybased) guidelines by 10 is applied to the WHO (2017) drinking water guideline of 20 microgL a recreational guideline of 200 microgL would be more applicable

                  62 Soil vapour

                  The ASC NEPM (1999) interim soil vapour health investigation levels (HILs) for volatile organic chlorinated compounds (VOCCs) have been adopted (ie in the first instance ndash refer to Section 7331) as Tier 1 soil vapour assessment criteria ndash relevant land use scenarios within the Thebarton EPA Assessment Area include residential (HIL AB) and commercialindustrial (HIL D)

                  These criteria have been further adjustedappended for the purposes of the VIRA Tier 1 assessment ndash refer to Section 94

                  80607-1 REV1 30102017 PAGE 29

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  7 RESULTS

                  71 Surface and sub surface soil conditions

                  711 Field observations

                  Groundwater well and soil vapour borehole log reports are included in Appendices H to J and provide details of the soil profile encountered at each sampling location

                  Where encountered fill materials extended to depths of between 01 and 09 m BGL and included a range of different soil types (sand gravelcrushed rock silt) with only minimal waste inclusions (ie asphalt glass andor metal fragments) identified at some locations

                  The underlying natural soil profile (encountered to the maximum drill depth of 19 m BGL) was dominated by low to medium plasticity brown to red-brown silty clays and sand claysclayey sands some of which contained sub-angular to rounded gravels that included river pebbles andor comprised fine distinct lenses in places Groundwater well MW17 also included a 15 m thick layer of gravel at depth (ie 12 to 135 m BGL) ndash ie consistent with the depth of groundwater within the Q1 aquifer

                  During the course of the drilling works no odours or visual indicators of contamination were detected and measured PID readings ranged up to 6 ppm but were generally lt3 ppm

                  712 Soil geotechnical testing

                  A table of geotechnical testing results is presented in Appendix L (Table 1) and a copy of the certified laboratory report is included in Appendix G Photographs of soil cores are included in Appendix N

                  The results were interpreted to indicate the following

                  The soil core samples submitted for PSD analysis were dominated by clay with lesser amounts of fine to medium gravel andor fine to coarse-grained sand ndash all samples analysed were classified as either CLAY or Sandy CLAY with one sample classified as Clayey SAND The classifications obtained from the laboratory were deemed to be generally consistent with the descriptions on the groundwater well log reports (Appendix H) although the PSD results did not specify silt as a significant secondary component

                  The moisture content of the analysed soil core samples ranged from 65 to 231 Moisture content with respect to soil type depth and location has been considered in more detail for the purposes of the VIRA (Section 9) The degree of saturation for the analysed soil cores samples ranged from 218 to 964

                  Measured bulk density ranged from 160 to 212 tm3 specimen dry density from 141 to 184 tm3 and specific gravity from 255 to 281 tm3

                  The measured void ratio ranged from 043 to 088 whereas porosity ranged from 032 to 047

                  80607-1 REV1 30102017 PAGE 31

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  72 Waterloo Membrane Samplerstrade A table of WMStrade analytical results (ie from both rounds of sampling) is presented in Appendix L (Table 2) and copies of certified laboratory reports are included in Appendix G8

                  Of the 41 WMStrade units deployed across the Thebarton EPA Assessment Area during the two sampling rounds 20 returned measurable concentrations of CHC including TCE PCE cis-12-DCE trans-12-DCE andor 11-DCE Although no VC was detected the laboratory LOR in all samples (ie 35 to 50 microgm3) was above the ASC NEPM (1999) soil vapour interim HIL for residential land use (30 microgm3) ndash refer also to Table 53

                  Detectable COPC concentrations are summarised in Table 71 relative to the ASC NEPM (1999) soil vapour interim HILs along with the closest soil vapour bore andor groundwater monitoring well locations Measured TCE concentrations are detailed on Figure 3

                  A comparison of the Round 1 and 2 WMStrade results (ie for closely located units9) is presented in Table 72 ndash the results indicate a general order of magnitude correlation of the results for most COPC with the exception of PCE for which lower concentrations were obtained during Round 2 As the Round 1 and 2 WMStrade units were located within different soil bores and deployed at different times some variability in the results is to be expected In addition and as discussed in Section 74 the WMStrade units have been used during this assessment as a (semi-quantitative) screening tool (ie to assist with the siting of the permanent soil vapour bores) with the results obtained from the soil vapour bores considered more representative of actual subsurface conditions

                  Table 71 Detectable Waterloo Membrane Samplertrade CHC results

                  Sample ID

                  Location Closest land uses

                  CHC concentration (microgm3) Closest soil vapour bore

                  andor groundwater

                  well

                  TCE PCE cis-12shyDCE

                  trans-12shyDCE

                  11shyDCE

                  VC

                  WMS 1 Goodenough Street CI 35 -

                  WMS 6 Maria Street CI 32 -

                  WMS 7 Maria Street CI and R 1900 45 SV2 MW5

                  WMS 8 Maria Street CI and R 12000 37 SV4

                  WMS 11 Admella Street CI 71000 260 19 20 36 SV5 MW02

                  WMS 14 George Street CI 46000 45 SV6 MW11

                  WMS 18 Admella Street CI 4200 34 MW14

                  WMS 19 Albert Street CI 11000 42 SV10MW15

                  WMS 21 Chapel Street CI 10 -

                  WMS 22 Admella Street CI 38 SV9

                  WMS 24 Chapel Street CI 230 62 10 11 48 MW17

                  8 Note that the original laboratory report for the Round 1 WMStrade samples was found to be incorrect (ie following receipt of the soil vapour bore and Round 2 WMStrade sample results) and was subsequently re-issued by SGS

                  9 only two of which were sufficiently co-located for comparative purposes ndash Round 2 locations WMS 39 and WMS 41 were not within the immediate vicinity of Round 1 WMStrade bores (ie the closest Round 1 bores were approximately 30 m away)

                  PAGE 32 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Sample ID

                  Location Closest land uses

                  CHC concentration (microgm3) Closest soil vapour bore

                  andor groundwater

                  well

                  TCE PCE cis-12shyDCE

                  trans-12shyDCE

                  11shyDCE

                  VC

                  WMS 25 Albert Street CI and R 1400 20 MW17

                  WMS 27 Light Terrace CI 64 62 SV11 MW19

                  WMS 32 Holland Street R 16 -

                  WMS 34 James Street R 11 -

                  WMS 37 Dew Street R 44 -

                  WMS 38 Maria Street CI and R 13000 56 SV2 MW5

                  WMS 39 Maria Street CI and R 1300 SV4

                  WMS 40 Admella Street CI 110000 97 SV5 MW02

                  WMS 41 George Street CI 18000 10 SV7 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

                  Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform (up to 530 microgm3) was also detected in WMS 8 WMS 11 WMS 14 WMS 16 WMS 18 WMS 19 WM 25 WMS 33 WMS 40 and WMS 41 interim soil vapour health investigation level (HIL)

                  Table 72 Comparison of CHC data for Round 1 and 2 WMStrade units

                  Bore ID

                  Depth (m)

                  Location CHC concentration (microgm3)

                  TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

                  WMS 8 10 Maria Street 12000 37 lt95 lt99 lt22 lt36

                  WMS 38 13000 56 lt11 lt11 lt25 lt41

                  Relative percentage difference 8 147 - - - -

                  WMS 11 10 Admella Street 71000 260 19 20 36 lt37

                  WMS 40 110000 97 lt11 lt11 lt25 lt41

                  Relative percentage difference 43 91 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

                  80607-1 REV1 30102017 PAGE 33

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  73 Groundwater

                  731 Field measurements

                  A table of groundwater field parameters is presented in Appendix L (Table 3) and groundwater field sampling sheets are included in Appendix E

                  7311 Groundwater elevation and flow direction

                  The depth to water within the Q1 aquifer beneath the Thebarton EPA Assessment Area on 18 July 2017 ranged from 12323 to 15854 m below top of casing (BTOC)10 and 4469 to 5070 m AHD

                  Groundwater elevation contours constructed from the July 2017 gauging data indicated that the overall groundwater flow direction within the Q1 aquifer was north-westerly consistent with expected regional groundwater flow The groundwater contours and inferred flow direction are shown on Figure 4

                  7312 Field parameters

                  As detailed in Table 51 field measurements were recorded during low flow purging (ie prior to micropurge sampling) of monitoring wells and immediately following the collection of HydraSleeveTM samples

                  The field parameter readings recorded for the monitoring wells immediately prior to (low flow micropurge) and after (HydraSleeveTM) sampling indicated the following (as summarised in Table 3 Appendix L)

                  groundwater pH ranged from 6 8 to 79 thereby indicating neutral conditions

                  electrical conductivity (EC) measurements ranged from 189 to 556 mScm and were found to be reasonably consistent across the area thereby indicating that it is underlain by moderately saline water (ie approximating 1230 to 3620 mgL TDS11)

                  redox concentrations ranged from -20 to 624 mV thereby indicating slightly reducing to strongly oxygenating conditions

                  measured dissolved oxygen (DO) concentrations ranged from 04 to 78 ppm indicating slightly to highly oxygenated water and

                  temperature ranged from 173 to 224oC

                  Observations recorded during sampling indicated that the groundwater was clear to brown and only slightly to moderately turbid at most locations ndash the higher turbidity at MW18 and MW19 (combined with poor recharge) contributed towards the decision to use a HydraSleeveTM sampling method No odours or sheen were observed in any of the wells during gauging or sampling

                  10 ie approximating m BGL 11 ie calculated by multiplying the field EC data by 065

                  PAGE 34 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  732 Hydraulic conductivity

                  Rising and falling head aquifer permeability (ldquoslugrdquo) tests were conducted on 10 groundwater wells (refer to Table 31 and Figure 2) to assess the hydraulic conductivity (K) of the Q1 aquifer

                  To obtain estimates of near-well horizontal hydraulic conductivity for each well tested the slug test data were analysed by Arcadis using AQTESOLV for Windowstrade (Duffield 2007) following the guidelines presented in Butler (1998) ndash normalised displacement data collected from each test are plotted against time in Appendix A of the Arcadis report (refer to Appendix O) Since only one set of tests were performed at each well the reproducibility of the results as well as the dependence of the results on the initial displacement could not be verified or demonstrated As such multiple relevant and applicable solutions were applied to each test to account for that uncertainty (ie to ensure consistency of normalised response at each well regardless of initial displacement)

                  Table 73 presents a summary of the range and average estimated hydraulic conductivity values (and corresponding analytical solutions used) for each well tested The results indicate that hydraulic conductivities ranged from approximately 0073 to 37 mday with an overall average of approximately 1 mday

                  Table 73 Hydraulic conductivities (rising and falling head tests)

                  Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

                  (mday) Hydraulic Conductivity

                  (mday)

                  MW02 Falling head 011 to 014 DA CBP HV

                  012 Rising head 0073 to 015 BR DA

                  MW3 Falling head 034 to 062 BR DA

                  047 Rising head 030 to 062 BR DA

                  MW7 Falling head 075 to 25 BR DA

                  139 Rising head 055 to 175 BR DA

                  MW14 Falling head 011 to 021 BR DA

                  014 Rising head 009 to 015 BR DA

                  MW17 Falling head 21 to 22 DA KGS

                  220 Rising head 225 to 244 DA KGS

                  MW20 Falling head 22 to 37 BR DA HV

                  256 Rising head 06 to 32 BR DA

                  MW21 Falling head 073 to 123 BR DA

                  084 Rising head 054 to 084 BR DA

                  MW23 Falling head 088 to 162 BR DA

                  101 Rising head 031 to 122 BR DA

                  80607-1 REV1 30102017 PAGE 35

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Groundwater Test Type Range of Estimated Applied Analytical Average Well Hydraulic Conductivity Solution Estimated

                  (mday) Hydraulic Conductivity

                  (mday)

                  MW25 Falling head 10 to 18 BR DA CBP HV

                  132 Rising head 049 to 17 BR DA

                  MW26 Falling head 019 to 036 BR DA

                  023 Rising head 010 to 029 BR DA

                  Overall average K (mday) 1028 Notes References BR = Bouwer and Rice (1976) CBP = Cooper et al (1967) DA = Dagan (1978) HV = Hvorslev (1951) KGS = Hyder et al (1994)

                  The monitoring wells that exhibited lower permeabilities (ie MW02 MW3 MW14 and MW26) were noted to be generally located in the up-gradient (south-eastern) portion of the Thebarton EPA Assessment Area whereas monitoring wells showing relatively higher permeabilities (ie MW7 MW17 MW20 MW21 MW23 and MW25) are generally located in the down-gradient (north-western) portion These results were considered by Arcadis to suggest a possible hydrogeologic transition from the south-east to the north-west AQTESOLV solution plots for each analysis are provided as Appendix A of the Arcadis report (Appendix O)

                  As slug test results can be influenced by a number of factors which are difficult to avoid when performing and analysing slug test results hydraulic conductivity estimates derived from slug tests should be considered to be the lower bound of the hydraulic conductivity of the formation in the vicinity of the well (Butler 1998) However Arcadis also noted that the results obtained for the Thebarton EPA Assessment Area were similar to those reported for other areas of Adelaide with average values of 1 and 27 mday (refer to Appendix O)

                  The slug test results were used by Arcadis in their groundwater fate and transport model (refer to Section 8)

                  733 Analytical results

                  Tables of groundwater analytical results are presented in Appendix L (Tables 4 and 5) and copies of certified laboratory reports are included in Appendix G

                  7331 Chlorinated hydrocarbon compounds

                  A table of CHC results is included in Appendix L (Table 4) and a plan showing their distribution in groundwater beneath the Thebarton EPA Assessment Area is included as Figure 5 Detectable CHC concentrations are summarised in Table 74 relative to the adopted potable and primary contact recreation criteria ndash the closest soil vapour bore locations are also detailed

                  PAGE 36 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Table 74 Detectable groundwater CHC results

                  Sample ID

                  Location CHC concentration (microgL) Closest soil vapour bore

                  TCE PCE cis-12shyDCE

                  trans-12-DCE

                  11-DCE VC Carbon tetrachloride

                  MW02 Admella Street 20000 38 7 15 SV5

                  MW3 Admella Street 69 SV1

                  MW5 Maria Street 29000 3 21 2 6 SV2 SV3

                  MW6 Maria Street 29 SV4

                  MW9 Albert Street 2 -

                  MW11 George Street 4900 3 4 1 7 SV6 SV7

                  MW12 George Street 700 SV8

                  MW14 Admella Street 1000 4 2 SV9

                  MW15 Albert Street 180 SV10

                  MW17 Chapel Street 24 -

                  MW18 Dew Street 5 -

                  MW20 Light Terrace 70 SV12

                  MW21 Light Terrace 23 SV13

                  MW23 Dew Street 21 -

                  MW25 Smith Street 2 5 -

                  MW26 Kintore Street 2 -

                  Potable 20 50 60 30 03 3

                  Primary contact recreation

                  30 500 600 300 30 30

                  Notes Shaded cells indicate concentrations were below the laboratory LOR Where (field) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Chloroform was also detected in a number of wells (MW02 MW3 MW5 MW8 MW11 MW12 and MW19 to MW25) ndash refer to Table 4 in Appendix L Although no VC was detected the laboratory LOR (1 microgL) exceeded the adopted potable criterion NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from WHO (2017) Guidelines for Drinking-water Quality NHMRC (2008) Guidelines for Managing Risks in Recreational Water ndash based on NHMRCNRMMC (2011) Australian Drinking Water Guidelines TCE criterion from ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

                  The results indicate that the highest TCE concentrations (20000 to 29000 microgL) were measured in wells MW02 and MW5 located in the immediate vicinity of the former Austral property and that the TCE plume extends in a general north-westerly direction (ie consistent with the inferred groundwater flow direction

                  80607-1 REV1 30102017 PAGE 37

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  within the Q1 aquifer) Although lesser concentrations of PCE 12-DCE (cis- andor trans) andor 11-DCE were present in some wells no VC was detected and the main COPC was identified as TCE

                  A number of wells within the Thebarton EPA Assessment Area contained TCE concentrations that exceeded the adopted potable andor primary contact recreation criteria Although the extent of the TCE plume was not delineated to the north-west (but was delineated in all other directions) with detectable TCE concentrations (ie up to 21 microgL) identified beneath both Smith Street and Dew Street these concentrations were below the adopted primary contact recreation criterion (but not necessarily the adopted potable value ndash ie MW23)

                  The background well (MW4) located across James Congdon Drive (to the east of the southern portion of the Thebarton EPA Assessment Area) did not contain any measurable CHC concentrations

                  7332 Other measured groundwater parameters

                  Major cations and anions

                  The laboratory results obtained for the remaining groundwater analytes are summarised in Appendix L (Table 5)

                  The groundwater ionic data obtained from selected wells across the Thebarton EPA Assessment Area are graphically represented on a Piper diagram in Figure 71 The results indicate a relatively consistent groundwater composition across the area thereby indicating that the groundwater sampled from these wells is derived from a single aquifer Ionic charge balance ranged from 32 to 22 with the highest value (22) calculated for MW12 indicating that additional anions (ie not measured as part of this study) could be present

                  PAGE 38 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Figure 71 Piper diagram

                  Natural attenuation parameters

                  With respect to the measured natural attenuation parameters (ie DO nitrate iron sulfate CO2 and manganese) the following wells were selected based on their locations relative to the inferred extent of the CHC plume

                  MW26 located on Kintore Street to the south (and hydraulically up-gradient) of the former Austral property (ie the suspected source site)

                  MW02 and MW5 located within the immediate vicinity of the former Austral property and the area of maximum CHC contamination

                  MW9 MW12 and MW17 located on Albert Street George Street and Chapel Street respectively to the north-west (and hydraulically down-gradient) of the former Austral property

                  80607-1 REV1 30102017 PAGE 39

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  MW21 and MW22 located on Light Terrace and Cawthorne Street respectively to the northshywestnorth-north-west (and further hydraulically down-gradient) of the former Austral property and

                  MW8 and MW23 located on Smith Street and Dew Street respectively representing the furthest wells to the northnorth-west of the former Austral property

                  According to Wiedemeier et al (1998) the most important process in the degradation of CHC is the process of reductive dechlorination Although daughter products of TCE (ie 12-DCE) are present in groundwater (and soil vapour) at scattered locations within the Thebarton EPA Assessment Area they are not considered indicative of substantial breakdown of TCE ndash refer also to the Arcadis report in Appendix O as summarised in Section 8 In addition the analysis of the natural attenuation parameters data constituting physical and chemical indicators of biodegradation processes has not provided a definitive secondary line of evidence

                  74 Soil vapour bores A table of soil vapour bore analytical results is presented in Appendix L (Table 6) and a copy of the certified laboratory report is included in Appendix G

                  Of the soil vapour bores installed to 10 andor 30 m BGL within the Thebarton EPA Assessment Area the majority (ie with the exception of the 10 m deep bores installed as SV11 and SV13 and located on Light Terrace) returned measurable concentrations of CHC dominated by TCE and to a lesser extent (and only at some locations) PCE Detectable soil vapour CHC concentrations are summarised in Table 75 whereas CHC concentrations and inferred soil vapour TCE concentration contours are detailed on Figures 6 (1 m BGL) and 7 (3 m BGL)

                  The TCE results which have been used to predict indoor air concentrations as part of the VIRA (refer to Section 9) suggest the following

                  the highest concentration (1000000 microgL) was detected at 3 m BGL in soil vapour bore SV3 located in the vicinity of residential and commercialindustrial properties (including the former Austral property) on Maria Street

                  where nested wells were tested soil vapour CHC concentrations were higher at depth consistent with a groundwater source

                  TCE PCE and 11-DCE are all assumed to represent primary contaminants with 12-DCE representing a break-down product of TCE andor PCE

                  although no VC was detected the laboratory LOR in some samples (ie up to 490 microgm3 in samples with the highest measured TCE concentrations) was above the ASC NEPM (1999) interim soil vapour HIL for residential land use (30 microgm3) ndash refer to Table 53 and

                  although the extent of the soil vapour plume has apparently not been delineated (ie in any direction) by the existing soil vapour bores it extends in a north-westerly direction (and hydraulically down-

                  PAGE 40 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  gradient) from the suspected source site (ie the former Austral property) and corresponds well with the groundwater TCE plume (refer to Figure 5)

                  A comparison of the results obtained for the WMStrade units (WMS 38 to WMS 41) deployed during the second round of sampling and the closest soil vapour bore data (10 m BGL) is provided in Table 76 Although the results indicate good correlation for TCE and PCE in SV5WMS 40 as well as TCE in SV7WMS 41 the remaining results were more variable ndash this supports the use of the WMStrade units as an initial (semishyquantitative) screening tool with follow-up soil vapour bore data considered to provide more quantitative results

                  Table 75 Detectable soil vapour bore CHC results for Thebarton EPA Assessment Area

                  Bore ID

                  Depth (m)

                  Location Closest land

                  uses

                  CHC concentration (microgm3)

                  TCE PCE cis-12shyDCE

                  trans-12-DCE

                  11-DCE VC

                  SV1 10 Admella Street CI and R 6300 78

                  30 21000 21

                  SV2 10 Maria Street CI and R 51000 39 21 39

                  30 940000

                  SV3 10 Maria Street CI and R 210000 6500 5900

                  30 1000000 15000 14000

                  SV4 10 Maria Street CI and R 17000 31

                  30 43000 90 30

                  SV5 10 Admella Street CI 100000 84

                  30 160000 310 20 33

                  SV6 10 George Street CI 22000 12

                  30 150000 56

                  SV7 10 George Street CI 22000 19

                  30 110000

                  SV8 10 George Street CI 2300 62

                  30 14000 19

                  SV9 10 Chapel Street CI 170

                  30 260

                  SV10 10 Albert Street CI 93

                  30 51

                  SV12 10 Light Terrace CI 16

                  30 55 ASC NEPM (1999) HIL - Residential 20 2000 80 - - 30 ASC NEPM (1999) HIL ndash Commercialindustrial 80 8000 300 - - 100

                  Notes Shaded cells indicate concentrations were below the laboratory LOR

                  80607-1 REV1 30102017 PAGE 41

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Where (field andor laboratory) duplicate QC samples were analysed the maximum concentrations have been adopted for data interpretation purposes Concentrations in italics exceed adopted assessment criteria Closest land uses CI = commercialindustrial R = residential Chloroform was also detected in a number of samplesinterim soil vapour health investigation level (HIL)

                  Table 76 Comparison of CHC data for Round 2 WMStrade units and closest soil vapour bores

                  Bore ID

                  Depth (m)

                  Location CHC concentration (microgm3)

                  TCE PCE cis-12-DCE trans-12-DCE 11-DCE VC

                  SV2 10 Maria Street 51000 39 21 lt13 39 lt89

                  WMS 38 13000 56 lt11 lt11 lt25 lt41

                  Relative percentage difference 119 150 - - - -

                  SV4 10 Maria Street 17000 31 lt18 lt14 lt14 lt92

                  WMS 39 1300 lt52 lt11 lt11 lt25 lt41

                  Relative percentage difference 172 - - - - -

                  SV5 10 Admella Street 100000 84 lt44 lt33 lt33 lt22

                  WMS 40 110000 97 lt11 lt11 lt25 lt41

                  Relative percentage difference 95 14 - - - -

                  SV7 10 George Street 22000 19 lt37 lt27 lt27 lt18

                  WMS 41 18000 10 lt11 lt11 lt25 lt41

                  Relative percentage difference 20 62 - - - -Notes Shaded cells indicate concentrations were below the laboratory LOR

                  PAGE 42 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  8 GROUNDWATER FATE AND TRANSPORT MODELLING

                  Arcadis were commissioned by Fyfe to undertake preliminary fate and transport modelling of the groundwater CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained groundwater data The Arcadis report is included as Appendix O

                  The aim of the modelling was to provide a preliminary estimate of the future extent of CHC impacted groundwater within the Thebarton area in order that potential future groundwater restrictions could be applied by the EPA (ie via the potential future definition of a GPA) to protect human health

                  81 Groundwater flow modelling

                  The MODFLOW code a publicly-available groundwater flow simulation program developed by the United States Geological Survey (USGS) as described by McDonald and Harbaugh (1988) was used to construct a groundwater flow model It was developed for a horizontal area of approximately 25 km2 (ie to minimise possible boundary effects within the assessment area itself12) and was rotated 45deg counter-clockwise to align with the prevailing (north-westerly) groundwater flow direction The model extended approximately 23 km in a south-east to north-west direction and approximately 11 km in a south-west to north-east direction (ie perpendicular to groundwater flow) Whereas a 4 m grid spacing was used within the area of the plume and its migration pathway (ie to enhance model accuracy and precision) a broader 15 m grid was adopted outside the specific area of interest Vertically the model adopted a single 20 m thick layer as representative of the hydrostratigraphy of the Q1 aquifer sediments beneath the area but it was noted that only the bottom portion (ie few metres) of this model layer are actually saturated and therefore active in the model

                  An informal sensitivity analysis performed as part of the model calibration process indicated that the model was most sensitive to changes in hydraulic conductivity and recharge ndash this was not unexpected given the relatively flat hydraulic gradient and relatively narrow range of estimated values for both model parameters (ie based on reasonably low uncertainty) The final calibrated value for aquifer recharge adopted in the model was 295 mmyear consistent with results reported for nearby sites as well as regional estimates Likewise the final calibrated hydraulic conductivity values for the up-gradient (06 mday) and down-gradient (2 mday) zones were consistent with both the site-specific slug test data and results obtained for other nearby EPA assessment areas The final calibrated down-gradient constant head elevation was 15 m AHD It was concluded by Arcadis that the groundwater flow model was well calibrated and could therefore serve as an appropriate basis for the development of a site-specific solute transport model

                  82 Solute transport modelling

                  A site-specific (three-dimensional) solute transport model using the MT3DMS transport code of Zheng (1990) was developed by Arcadis to predict the fate and transport of groundwater contaminants (specifically

                  12 Further information regarding boundary effects is provided in the Arcadis report (Appendix O)

                  80607-1 REV1 30102017 PAGE 43

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  CHC) under current conditions over a period of 100 years This dual-domain mass transport model was used in conjunction with the groundwater flow model developed through the use of MODFLOW (as detailed above) assuming the following

                  The primary COPC is TCE ndash the initial concentration distribution of TCE in groundwater was based on the recent (July 2017) monitoring data

                  The age of the groundwater TCE plume was assumed to be up to about 90 years ndash ie based on the history of industrial land use (specifically the former Austral facility) in the area

                  Although lesser amounts of other CHC are present in groundwater the lack of significant daughter products of TCE has been interpreted to indicate that substantial biodegradation is not occurring (ie as a conservative approach)

                  Although a CHC source was not explicitly incorporated into the solute transport model the MT3DMS transport code indirectly accounts for on-going contaminant mass contribution to the dissolved-phase plume

                  The fate and transport of TCE within the area of interest involves the processes of advection adsorption dilution and diffusion ndash however given that recharge via the infiltration of precipitation was considered to be insignificant dilution effects were assumed to be minimal

                  Two porosity values (ie dual domain) are relevant to the movement of contaminants in the subshysurface with adopted values based on site-specific geology and Payne et al (2008) ndash whereby the two domains are in equilibrium

                  ― mobile porosity that portion of the formation with the highest permeability where advective transport dominates ndash assumed to be 5 (high) 10 (intermediate) or 15 (low) for different mobility transport conditions and

                  ― immobile porosity lower permeability portions of the formation where diffusion is dominant ndash assumed to be 15

                  As discussed in Section 732 hydraulic conductivity values of 06 mday (south-eastern approximate quarter of the modelling area) and 2 mday (northern approximate three-quarters of the modelling area) were adopted to reflect the hydrogeologic transition (ie from the south-east to the north-west) interpreted from the slug test data

                  The adopted TCE retardation factor of 147 for intermediate mobility transport conditions was based on the following

                  ― an assumed organic carbon fraction of 01 (US EPA 1996 amp 2009) ndash this was varied to 005 and 2 to assess alternate (ie high versus low) mobility transport conditions

                  ― an assumed organic carbon adsorption co-efficient of 61 Lkg (US EPA 2017a)

                  PAGE 44 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  ― a calculated partition co-efficient of 0061 Lkg ndash this was varied to 129 and 178 Lkg to assess alternate (ie high versus low) mobility transport conditions and

                  ― an average soil bulk density of 192 gcm3 (based on measured geochemical data ndash refer to Table 1 Appendix L)

                  An optimum mass transfer co-efficient (MTC) was based on simulated flux distribution in the groundwater flow model whereby

                  ― the calculated MTC in the model ranged from approximately 38E-08day-1 to 37E-05 day-1 and

                  ― the average MTC was 185E-05day-1

                  The site-specific solute transport model was used in predictive mode to assess the long-term (eg 100 year) potential migration of the groundwater TCE plume and to support the EPA in the potential future definition of an appropriate GPA The model was calibrated against the current extent (ie concentrations of TCE above 1 microgL have migrated approximately 500 m from the suspected source site13) and expected age (ie up to about 90 years) of the plume The results indicate that the leading edge of the TCE (ie the 1 microgL contour) is estimated to migrate between approximately 400 and 620 m over a period of 100 years under low to high mobility transport conditions14 with intermediate transport conditions resulting in an estimated migration of 500 m By comparison no significant lateral plume expansion would be expected to occur Figures 5 to 17 of the Arcadis report (Appendix O) show the predicted extent of the TCE plume at 5 10 50 and 100 years under low to high mobility transport conditions

                  Figure 81 shows the predicted extent of the 1 microgL TCE boundary in 100 years under intermediate transport conditions ndash it is recommended that this information be used to support the EPA in establishing a potential future GPA

                  The Arcadis report notes that given the available site information (site history potential source area(s) and uncertainty associated with the current plume extent) and degree of model calibration (flow model parameter values are consistent with site-specific data as well as regionalnearby studies while transport parameter values are consistent with literatureindustry standards) the model-predicted migration of approximately 500 m over 100 years is considered to be a reasonable representation of future conditions

                  Key uncertainties associated with the modelling were identified as including the following

                  current plume extents (ie down-gradient delineation)

                  site-specific fraction organic values (or site-specific partition coefficient estimates) and

                  site-specific porosity estimates

                  13 although it was noted that there is uncertainty with respect to the current extent of the TCE plume since all three down-gradient monitoring wells (MW18 MW23 and MW25) have TCE concentrations above 1 μgL

                  14 ie assuming different values for mobileimmobile porosity the TCE distribution (sorption) coefficient and the TCE retardation factor

                  80607-1 REV1 30102017 PAGE 45

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Lesser uncertainties were considered to include site-specific bulk hydraulic conductivity estimates and determination of the presence or absence of naturally-occurring TCE degradation

                  Additional site investigation and data collection (eg multi-well pumping tests for bulk hydraulic conductivity estimates site-specific fraction organic carbon andor distribution (sorption) coefficient additional down-gradient plume delineation) would help to further refine the model and increase confidence in the predictive results

                  Figure 81 Predictive TCE (1 microgL) plume extent after 100 years (ie shown in green) relative to the boundary of the Thebarton EPA Assessment Area (red) and the extent of the modelling area (purple)

                  PAGE 46 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  9 VAPOUR INTRUSION RISK ASSESSMENT

                  Arcadis were commissioned by Fyfe to undertake a Vapour Intrusion Risk Assessment (VIRA) of the soil vapour CHC impacts detected within the Thebarton EPA Assessment Area based on the recently obtained (ie August 2017) permanent soil vapour bore data The Arcadis report is included as Appendix P

                  91 Objective

                  The main objective of the VIRA was to evaluate the potential risk to human health from vapour intrusion related to the concentrations of CHC identified in soil vapour within the Thebarton EPA Assessment Area

                  92 Areas of interest

                  The following areas of specific interest (ie located within the Thebarton EPA Assessment Area) were identified for the purpose of this VIRA

                  commercialindustrial properties (assumed slab on grade construction) including the former Austral property (ie the suspected source site) and

                  residential properties (slab on grade crawl space and basement constructions)

                  Potential exposure by trenchmaintenanceutility workers has also been considered (qualitatively)

                  93 Risk assessment approach

                  The VIRA was conducted in accordance with the ASC NEPM (1999) enHealth (2012a) and other relevant Australian guidance documents as well as guidance documents issued by the US EPA and other international regulatory agencies (where applicable)

                  The conduct of the risk assessment was based on a multiple lines of evidence approach using the available site-specific information collected as part of the scope of works detailed in Section 32

                  The following information was used as a basis for the VIRA

                  CHC including TCE PCE and DCE (11- cis-12- and trans-12-) have been identified within soil vapour andor groundwater within the Thebarton EPA Assessment Area ndash the analytical data indicate that TCE constitutes between about 95 and 100 of the CHC identified in groundwater and soil vapour

                  TCE has been considered as the risk driver for the VIRA (ie based on its toxicity and concentrations in soil vapour and groundwater) ndash although TCE PCE 12-DCE 11-DCE and VC have all been included as COPC for the Tier 1 screening assessment (Section 94) the Tier 2 assessment (Section 95) has

                  80607-1 REV1 30102017 PAGE 47

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  concentrated on TCE PCE and 11-DCE (ie due to their presence at concentrations that exceeded the adopted Tier 1 screening criteria)

                  The CHC identified within the Thebarton EPA Assessment Area are volatile chemicals and could potentially pose a risk to human health via the vapour intrusion pathway Although the source area has yet to be confirmed the CHC concentrations observed in groundwater and soil vapour are considered likely to have originated from the former Austral property (as discussed in Section 12)

                  The natural soils underlying the fill material (where present) in the Thebarton EPA Assessment Area are typified by the Quaternary age soils and sediments of the Adelaide Plains with the Pooraka Formation and Hindmarsh Clay units considered to dominate the upper soil profile

                  The soil geotechnical data and soil vapour results collected by Fyfe (as discussed in Sections 712 and 74 respectively) have been used for the VIRA

                  A two-tier approach was adopted for the VIRA The first tier (herein referred to as the Tier 1 assessment) was conducted by comparing the measured soil vapour TCE concentrations to published guideline values adjusted (conservatively) to account for attenuation from sub-slab soil into indoor air The second tier (herein referred to as the Tier 2 assessment) involved the comparison of predicted indoor air TCE concentrations to adopted indoor air criteria or response levels

                  94 Tier 1 assessment

                  As detailed in Section 74 the initial Tier 1 (screening risk) assessment involved comparing measured soil vapour COPC concentrations with the ASC NEPM (1999) interim soil vapour HILs for residential and commercialindustrial land uses (refer to Table 74) Given that the development of the interim soil vapour HILs was based on very conservative assumptions the initial Tier 1 assessment provided only a first-pass screening assessment of the data to determine if further risk assessment would be required

                  The interim soil vapour HILs are applicable for the assessment of soil vapour at 0 to 1 m beneath the floor of a building They were based on adopted toxicity reference values (TRV) and relevant exposure parameters (ie adjusted for different land uses) as well as an assumed soil vapour to indoor air attenuation factor of 01

                  The soil vapour to indoor air attenuation factor (01) was based on the US EPA (2002) recommended default attenuation factors for the generic screening step of a tiered vapour intrusion assessment process As discussed in the US EPA (2002) document the default attenuation factor of 01 for sub-slab soil vapour was based on a US EPA database of empirical attenuation factors calculated using measurements of indoor air and soil vapours from different sites In 2012 the US EPA provided an updated database which was accompanied by an evaluation and statistical analysis of attenuation factors for volatile CHC in residential buildings US EPA (2012) found the sub-slab to indoor air attenuation factor of 003 to be the 95th percentile In 2015 the revised sub-slab attenuation factor (003) was adopted by the US EPA

                  PAGE 48 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  The revised sub-slab to indoor air attenuation factor of 003 was adopted to derive modified residential and commercialindustrial soil vapour HILs for the Tier 1 assessment The modified residential soil vapour HILs are presented in Table 91 relative to the maximum CHC concentrations obtained for soil vapour within the Thebarton EPA Assessment Area

                  The Tier 1 assessment based on a comparison of the COPC concentrations measured in soil vapour at various locations within the Thebarton EPA Assessment Area with the modified residential soil vapour HILs detailed in Table 91 indicated the following

                  TCE concentrations exceeded the adopted criterion in SV1 to SV9 whereas

                  the concentrations of PCE and 11-DCE exceeded the adopted criteria in SV3 only

                  These locations were identified as requiring further assessment (ie Tier 2 VIRA ndash refer to Section 95)15

                  Table 91 Tier 1 assessment ndash ASC NEPM (1999) and modified residential soil vapour HILs

                  Compound ASC NEPM (1999) HIL

                  (microgm3)

                  Modified Tier 1 HIL (microgm3)

                  (AF = 003)

                  Maximum measured soil vapour concentration (microgm3)

                  Acceptable

                  Location 1 m BGL Location 3 m BGL

                  11-DCE 7000 SV3 5900 SV3 14000 No ndash Tier 2 required

                  cis-12-DCE 80 265 SV2 21 SV4 30 Yes

                  trans-12-DCE 80 265 - ND SV5 20 Yes

                  PCE 2000 6650 SV3 6500 SV3 15000 No ndash Tier 2 required

                  TCE 20 65 SV3 210000 SV3 100000 0

                  No ndash Tier 2 required

                  VC 30 100 - ND - ND Yes Notes Values in bold exceed the modified residential soil vapour HILs cis-12-DCE HIL adopted as surrogate screening criterion based on US EPA (2017b) regional screening level for residential air elevated laboratory LOR (ie above modified Tier 1 HIL) also reported Abbreviations AF = attenuation factor HIL = health investigation level ND = non detect

                  95 Tier 2 assessment

                  951 Tier 2 assessment criteria

                  The Tier 2 VIRA criteria for the residential zone comprise HIL-based residential indoor air criteria for the COPC (refer to Section 94) along with the residential indoor air level response ranges for TCE that were

                  15 Note that all locations were subjected to the Tier 2 VIRA in this assessment

                  80607-1 REV1 30102017 PAGE 49

                  EPA REF 0524111 FINAL REPORT

                  STAGE 1 ENVIRONMENTAL ASSESSMENT

                  THEBARTON ASSESSMENT AREA

                  initially developed by the EPA and SA Health for the EPA Assessment Area at Clovelly Park and Mitchell

                  Park These screening criteria and indoor air response ranges as detailed in SA EPA (2014) and

                  reproduced in Figure 91 are now widely adopted in South Australia for the assessment of TCE relating

                  to indoor air exposure

                  Figure 91 TCE indoor air screening criteria and the corresponding site-specific response levels

                  Note The no action response level is applicable where a soil vapour concentration is below the laboratory LOR (ie ND or ldquonon-

                  detectrdquo assumed to be lt01 microgm3)

                  PAGE 50 80607-1 REV1 | 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  952 Vapour intrusion modelling

                  For this VIRA exposure point concentrations (EPCs) of COPC in the indoor air of buildings with a slab on grade crawl space or basement construction were estimated using conservative screening assumptions and the Johnson and Ettinger (1991) vapour transport and mixing model (ie the JampE model)

                  The algorithms applied in the JampE (1991) model are detailed in Appendix A of the Arcadis report whereas the modelling spreadsheets for each scenario are provided in Appendix B ndash the Arcadis report is attached to this report as Appendix P

                  9521 Input parameters

                  The input parameters adopted for the vapour intrusion modelling relate to the following

                  the construction type and details of existing or proposed buildings ndash refer to Table 92 for adopted building input parameters

                  the nature of the soil profile ndash refer to Table 93 for adopted soil input parameters (0 to 1 m BGL) and

                  the contaminant source concentrations ndash refer to Table 6 in Appendix L

                  Table 92 Tier 2 vapour intrusion modelling ndash building input parameters

                  Parameter Units Adopted value Reference

                  Residential Commercial industrial

                  Width of Building cm 1000 2000 Friebel and Nadebaum (2011)

                  Length of Building cm 1500 2000

                  Height of Room cm 240 300

                  Height of crawl space cm 30 - Assumption for crawl space

                  Attenuation from basement to ground floor air

                  - 01 01 Friebel and Nadebaum (2011)

                  Air Exchange Rate (AER)

                  Indoor per hour 06 083 Friebel and Nadebaum (2011)

                  Crawl space per hour 06 - Friebel and Nadebaum (2011)

                  Basement per hour 06 - As per residential (indoor)

                  Fraction of Cracks in Walls and foundation

                  - 0001 0001 Friebel and Nadebaum (2011)

                  Qsoil cm 3s 300 277 Calculated from QsoilQbuilding ratio of 0005 (residential) and 0001 (commercial)

                  80607-1 REV1 30102017 PAGE 51

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Table 93 Tier 2 vapour intrusion modelling ndash soil input parameters

                  Parameter Units Adopted value Reference

                  Depth cm 100 Depth of shallow soil vapour data

                  Total porosity - 047 Site specific geotechnical data ndash ie averaged from MW3 and MW11 shallow samples (refer to Table 1 in Appendix L) Air filled porosity - 030

                  Water filled porosity - 017 Notes ie representing a conservative approach whereby data for the shallow samples with the highest total porosity and lowest degree of saturation (and therefore the highest air filled porosity) have been adopted

                  The site specific attenuation factors calculated within the vapour intrusion models (Appendix B of the Arcadis report) are summarised in Table 94 These are chemical and depth specific values applicable to each building construction scenario These attenuation factors have been applied to the soil vapour data measured across the Thebarton EPA Assessment Area to calculate indoor air concentrations (residential properties only) in proximity to each soil vapour location ndash for commercialindustrial properties (slab on grade) indoor air concentrations have only been calculated with respect to the soil vapour data obtained for SV3 (ie the soil vapour bore with the highest measured TCE concentrations)

                  Table 94 Adopted attenuation factors for TCE in soil vapour to indoor air

                  Scenario Attenuation factor

                  Residential ndash slab on grade 706 x 10-4

                  Residential ndash crawl space 209 x 10-3

                  Residential ndash basement 113 x 10-1

                  Commercial ndash slab on grade 408 x 10-4

                  Notes ie soil vapour intrusion to indoor air of residential living spaces refer to Section 953 for a discussion of potential vapour intrusion risks associated with commercialindustrial properties

                  The chemical parameters of the COPC adopted in the JampE model were updated with data from the chemical database in the Risk Assessment Information System (RAIS 2016) as detailed in Table 95

                  Table 95 Summary of chemical parameters adopted for vapour intrusion modelling

                  Chemical Diffusivity in Air Diffusivity in Water Solubility Henryrsquos Law Molecular weight (Dair) Water (Dwater) (S) Constant 25oC (gmol)

                  (cm2s) (cm2s) (mgL) (unitless)

                  11-DCE 00863 0000011 2420 107 969

                  PCE 00505 000000946 206 0724 166

                  TCE 00687 00000102 1280 0403 131

                  PAGE 52 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  9522 Predicted indoor air concentrations

                  Residential The predicted indoor air concentrations for each soil vapour data point as calculated by Arcadis for the three residential building scenarios (ie slab on grade crawl space and basement) are presented in Appendix C of the Arcadis report (included in this report as Appendix P)

                  Table 96 provides a comparison of predicted indoor air concentrations against the EPA response levels detailed in Section 951 (Figure 91) ndash ie using the 1 m soil vapour data space for slab on grade and crawl space scenarios versus the 3 m soil vapour data for basements

                  It should be noted that if residential properties within the Thebarton EPA Assessment Area have basements however the vapour intrusion risks will increase whereas slab on grade construction will carry a lesser vapour intrusion risk (as detailed in Table 96)

                  Commercialindustrial The predicted indoor air concentrations as calculated by Arcadis for a commercialindustrial (ie slab on grade) land use scenario with respect to the soil vapour data obtained for SV3 (ie maximum measured soil vapour concentrations) are as follows

                  11-DCE 3 microgm3

                  PCE 19 microgm3 and

                  TCE 86 microgm3

                  As these values are not directly comparable to the EPA response levels developed for residential land use further discussion of potential vapour intrusion risks to human health under a commercialindustrial land use

                  scenario is included in Section 953

                  As discussed for residential properties the vapour intrusion risks may increase if basements are present

                  80607-1 REV1 30102017 PAGE 53

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Table 96 Comparison of predicted residential indoor air concentrations with SA EPA response levels

                  Indoor Air Concentration Ranges (microgmsup3) SA EPA response levels

                  non-detect No action

                  gt non-detect to lt2 Validation

                  2 to lt20 Investigation

                  20 to lt200 Intervention

                  ge200 Accelerated Intervention

                  Soil vapour bore

                  Sample depth

                  (m)

                  Soil vapour TCE concentration

                  (microgmsup3)

                  Predicted indoor air concentration (microgmsup3)

                  Residential scenario

                  Slab on grade Crawl space Basement

                  Attenuation factor

                  7 x 10-4 2 x 10-3 1 x 10-1

                  SV1 10 5700 4 11

                  SV1 30 21000 2100

                  SV2 10 51000 36 102

                  SV2 30 890000 89000

                  SV2 (FD) 30 940000 94000

                  SV3 10 210000 147 420

                  SV3 30 1000000 100000

                  SV4 10 17000 12 34

                  SV4 30 43000 4300

                  SV5 10 100000 70 200

                  SV5 30 160000 16000

                  SV6 10 22000 15 44

                  SV6 (FD) 10 22000 15 44

                  SV6 30 150000 15000

                  SV6 (FD) 30 140000 14000

                  SV7 10 22000 15 44

                  SV7 30 110000 11000

                  SV8 10 2300 2 5

                  SV8 30 14000 1400

                  SV9 10 170 012 030

                  SV9 30 260 26

                  SV10 10 9 0007 0019

                  SV10 30 51 51

                  SV11 10 lt18 - -

                  SV12 10 16 0011 0032

                  SV12 30 55 55

                  SV13 10 lt21 - -

                  PAGE 54 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Notes With respect to the predicted indoor air CHC concentrations in the Arcadis VIRA report (refer to Appendix P) the results in Table 5 were calculated for SV3 using the unrounded attenuation factors presented in Appendix B (and Table 94 of this report) whereas the TCE indoor air concentrations in Appendix C (as summarised in Table 96) were calculated using rounded attenuation factors ndash this does not change the overall interpretation of the results Abbreviations FD = field duplicate

                  9523 Sensitivity analysis

                  Table 97 presents a qualitative sensitivity analysis for some of the input variables used in the modelling ndash it includes the range of practical values for each variable the value used in the risk assessment the relative model sensitivity and the uncertainty associated with the variable

                  Although Arcadis note that a number of parameters used within the risk assessment have a moderate degree of uncertainty associated with them thereby suggesting that the modelling may be sensitive to changes in these parameters values used to define these parameters were selected to be conservative This is considered to have resulted in an assessment which is expected to be conservative and to over-estimate actual risk

                  Table 97 Summary of model input parameters subjected to sensitivity analysis

                  Input Range of values Value adopted Sensitivity of calculated input parameters variable

                  Soil physical parameters

                  Total porosity

                  Varies by soil type generally 03 to 05

                  047 Site-specific

                  Indoor air concentrations will decrease with increasing total porosity Moderate sensitivity parameter decreasing by 50 will increase predicted concentration by a factor of 4

                  Air filled porosity

                  Varies by soil type generally 015 to 03

                  03 Site-specific

                  Indoor air concentrations will increase with increasing air filled porosity Moderate to high sensitivity parameter reduction by 50 decreases concentration by a factor of 10

                  Water filled porosity

                  Varies by soil type from 005 (fill or

                  sand) to 03 (clay)

                  017 Site-specific

                  Negligible impact on predicted indoor air concentrations although may decrease with increasing moisture content Very low sensitivity parameter

                  Building parameters

                  Air exchange rate (AER)

                  Varies from 05 hr-1

                  in smaller buildings to gt2 hr-1

                  06 hr-1 for residential structures

                  083 hr-1 for commercial

                  Indoor air concentrations will decrease with increasing air exchange Moderate sensitivity parameter has linear relationship with predicted concentrations conservative assumptions used

                  80607-1 REV1 30102017 PAGE 55

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Input Range of values Value adopted Sensitivity of calculated input parameters variable

                  Advective flow rates

                  Varies depending on building size and

                  AER

                  300 cm3sec Calculated from building AER and

                  ratio of 0005

                  Indoor air concentrations will increase with increasing advective flow Low sensitivity parameter particularly within normal range of potential values The assumption that advective flow is occurring into a building at all times is generally conservative for Australian settings Advection is unlikely to occur under a crawl space home and diffusive transport is the dominant transport mechanism

                  Building size Variable Variable consistent with

                  Friebel and Nadebaum (2011)

                  Indoor air concentrations decrease with increasing building volume

                  Very low sensitivity parameter

                  9524 Uncertainties

                  The following uncertainties were identified in the Arcadis report (Appendix P)

                  Vapour transport modelling

                  The use of a model to predict the migration of vapour from a sub-surface source to indoor air requires the simplification of many complex processes in the sub-surface as well as the potential for entry and dispersion within a building or outdoor air To address this simplification the vapour models available (and adopted in this assessment) are considered to be conservative such that uncertainties are addressed through the overshyestimation of likely concentrations

                  It should be noted that the vapour model used is designed to be a first tier screening tool and is considered likely to over-estimate air concentrations due to the incorporation of a number of conservative assumptions including the following

                  chemical concentrations in soil vapour were assumed to remain constant over the duration of exposure (ie it was assumed that the source was non-depleting and not subject to natural biodegradation processes)

                  the maximum reported soil vapour concentrations were assumed to be present beneath nearby dwellings and

                  the occurrence of steady well-mixed vapour dispersion within the enclosed or ambient mixing space

                  Overall the vapour modelling undertaken is expected to provide an over-estimation of the actual vapour exposure concentrations

                  PAGE 56 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Toxicological Data

                  In general the available scientific information involves the extrapolation of toxicity information from studies involving experimental laboratory animals with some validation of observable health effects obtained through epidemiological studies

                  This may introduce two types of uncertainties into the risk assessment as follows

                  those related to extrapolating from one species to another and

                  those related to extrapolating from the high exposure doses usually used in experimental animal studies to the lower doses usually estimated for human exposure situations

                  In order to adjust for these uncertainties toxicity values commonly incorporate safety factors that may vary from 10 to 10000

                  Overall the toxicological data presented in this assessment are considered to be current and adequate for the assessment of risks to human health associated with potential exposure to the COPC identified The uncertainties inherent in the toxicological values adopted are considered likely to result in an over-estimation of actual risk

                  953 Potential vapour intrusion risks associated with commercialindustrial properties

                  An assessment of potential vapour intrusion risks to workers at commercialindustrial properties (slab on grade construction) within the Thebarton EPA Assessment Area was undertaken by Arcadis using the methodology published by US EPA (2009) and incorporated into the ASC NEPM (1999) This approach recommends adjustment of the measured or estimated contaminant concentrations in air to account for site specific exposures by the relevant receptors as follows

                  Ca ET EF EDECinh = days hours AT 365 24 year day

                  Where

                  ECinh = Exposure Adjusted Air Concentration (mgm3) Ca = Chemical Concentration in Air (mgm3) ET = Exposure Time (hoursday) EF = Exposure Frequency (daysyear) ED = Exposure Duration (years) AT = Averaging Time (years)

                  = 70 years for non-threshold carcinogens = ED for chemicals assessed based on threshold effects

                  80607-1 REV1 30102017 PAGE 57

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Exposure parameters were selected from Australian sources (enHealth 2012b ASC NEPM 1999) for the receptor groups evaluated or were based on site specific factors Table 98 presents an overview of the parameters used whereas adopted inhalation TRVs are presented in Table 99

                  Risk was characterised for threshold and non-threshold effects for the COPC ndash spreadsheets presenting the risk calculations are provided in Appendix B of the Arcadis report (as included in Appendix P) For commercialindustrial properties the non-threshold risk level was calculated to be 3 x 10-5 (compared to a target risk level of 1 x 10-5) whereas the threshold risk level was calculated to be 10 (compared to a target risk level of 1) ndash these results indicated a potentially unacceptable vapour intrusion risk to commercialindustrial workers in the vicinity of the maximum soil vapour CHC concentrations (ie at SV3 ndash worst-case scenario based on maximum soil vapour concentrations)

                  Table 98 Exposure parameters ndash Commercialindustrial workers

                  Exposure parameter Units Value Reference

                  Exposure frequency days year 365 ASC NEPM (1999)

                  Exposure duration years 30 ASC NEPM (1999)

                  Exposure time indoors hoursday 8 ASC NEPM (1999)

                  Averaging time

                  Non-threshold

                  threshold

                  Years

                  years

                  70

                  30 ASC NEPM (1999)

                  Table 99 Adopted inhalation toxicity reference values

                  COPC Toxicity reference values

                  Non-threshold (microgm3)

                  Reference Threshold (microgm3)

                  Reference

                  11-DCE NA - 80 ATSDR (1994)

                  PCE NA - 200 WHO (2006)

                  TCE 41 US EPA (2011) IRIS 2 US EPA (2011) IRIS Notes Abbreviations NA = not applicable

                  954 Potential risks to trenchmaintenanceutility workers

                  Although trenchmaintenanceutility workers may be exposed to soil vapour concentrations as measured at 1 m BGL due to the short-term nature of such works their total intakes of TCE and other CHC will be low Assuming that a trenchmaintenanceutility worker may be exposed to TCE for a limited number of working days throughout the year (eg 20 days of 8 hours duration within an excavation) their intake will be approximately one fiftieth of the intake of a resident (who is assumed to be exposed 21 hours a day for 365 days a year)

                  PAGE 58 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Therefore the management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air)

                  96 Conclusions

                  On the basis of the available data and the assessment presented in the Arcadis VIRA report (Appendix P) the following conclusions were provided

                  Health risks for residents due to the intrusion of CHC in soil vapour into residential buildings with a slab on grade crawl space or basement construction were calculated to be above the adopted EPA response levels and risks to residents may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

                  Health risks for commercial workers due to the intrusion of CHC in soil vapour into buildings with a slab on grade construction were calculated to be above the adopted target risk levels and risks to workers may therefore be unacceptable within some parts of the Thebarton EPA Assessment Area

                  In the absence of specific information regarding building construction within the Thebarton EPA Assessment Area the predicted indoor air concentrations calculated from the 1 m BGL soil vapour data for a residential crawl space scenario are summarised in Table 910

                  Table 910 Summary of properties with predicted indoor air concentrations (residential crawl space) above adopted EPA response levels

                  EPA response level No of residential properties affected Indoor air concentration (microgm3) Response

                  non-detect to lt2 Validation 9

                  2 to lt20 Investigation 10

                  20 to lt200 Intervention 8

                  ge200 Accelerated intervention 3 Notes According to information provided by the EPA there are approximately 130 residential properties located in the Thebarton EPA Assessment Area calculated on the basis of cadastral boundaries ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial facility ndash these data would therefore need to be confirmed via a property survey

                  80607-1 REV1 30102017 PAGE 59

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  10 CONCEPTUAL SITE MODEL

                  As detailed in Table 101 a CSM has been developed for the Thebarton EPA Assessment Area on the basis of historical information (as summarised in Section 12 as well as Appendices A and B) and the data obtained during the recent Fyfe investigation program

                  Table 101 Summary of existing information for the Thebarton EPA Assessment Area

                  Topic Summarised Information

                  Site Characterisation

                  Identification of Assessment Area

                  An approximately 27 ha Assessment Area located within the suburb of Thebarton has been defined by the EPA The boundaries of this area are detailed in Section 21 and illustrated on Figure 1

                  History of land use Properties located within the Thebarton EPA Assessment Area have been used for a mixture of commercialindustrial and low density residential land uses over time Current commercialindustrial properties include a beverage factory in the north-eastern portion of the assessment area a refrigeration equipment facility a car dealership two hotels (at least one of which has a cellarbasement) automotive and other workshops and the Ice Arena Former commercialindustrial activities have been identified as including a gas works a mechanicrsquos workshop sheet metal working facilities and a farm machinery manufacturer

                  Historical investigations

                  Reports provided to Fyfe by the EPA that pertain to previous investigations undertaken within the Thebarton EPA Assessment Area have been reviewed and summarised in Appendix A Additional historical information is included in Appendix B

                  Local geology Natural soils encountered from the surfacenear surface to the maximum drill depth of 19 m BGL across the Thebarton EPA Assessment Area were considered to be indicative of the Quaternary Pooraka and Hindmarsh Clay formations Whereas fill materials (ie sand gravelcrushed rock andor silt) were encountered to depths of up to 09 m BGL at a number of sampling locations underlying natural soils comprised mainly low to medium plasticity silty or sandy clays with variable gravel contents Geotechnical testing of subsurface soil samples collected from 10 drill cores indicated that the PSD comprised predominantly claysilt with lesser components of sand andor gravel ndash these soil samples were mostly classified as Clay although some were classified as Sandy Clay or Clayey Sand According to Stapledon (1971) the Hindmarsh Clay unit typically contains many structural features and defects which greatly influence its permeability thereby resulting in potential preferential pathways for the vertical and lateral movement of soil vapour and groundwater Such features were not specifically observed during the recent drilling and soil logging work although some gravel lenseslayers were identified

                  Hydrogeology In accordance with Gerges (2006) and his classification of the Adelaide metropolitan area into a number of zones based on their individual hydrogeological characteristics the Thebarton EPA Assessment Area is located within Zone 3 (subzone 3E) to the west of the Para Fault It contains five to six Quaternary aquifers and three or four Tertiary aquifers Based on the most recent investigations the depth to water within the Q1 aquifer in the Thebarton EPA Assessment Area ranges from approximately 123 to 159 m BGL and groundwater flows in a general north-westerly direction with a relatively flat hydraulic gradient (000062 to 00012) Salinity levels (based on field EC readings) range from approximately 1230 to 3620 mgL TDS and a groundwater flow velocity range of approximately 44 to 23 myear has

                  80607-1 REV1 30102017 PAGE 61

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Topic Summarised Information

                  been inferred As detailed in Section 222 a search of the DEWNR (2017) WaterConnect database identified 59 bores within the general Thebarton area of which 18 are located within the Thebarton EPA Assessment Area Although (where recorded) bores were listed as having been installed primarily for monitoring investigation or observation purpose other purposes (for presumed Quaternary aquifer bores) included drainage domestic and industrial A BUA has identified realistic groundwater uses as potentially including potable residential irrigation and primary contact recreationaesthetics Based on proximity to the River Torrens freshwater ecosystem protection has also been considered ndash however since the River Torrens is considered to be either a recharge boundary (ie discharging to local groundwater) or not actually hydraulically connected to the Q1 aquifer in this area this may not be a realistic beneficial use Since volatile contaminants have been detected within the Q1 aquifer a potential vapour flux risk to future site users has also been considered

                  Hydrology No surface water bodies have been identified within the Thebarton EPA Assessment Area The closest surface water body is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west Current stormwater run-off within the Thebarton EPA Assessment Area is expected to be collected by localised (and engineered) drainage systems

                  Fyfe Investigation Results

                  Groundwater impacts Contaminants identified in groundwater beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE Although TCE PCE and 11-DCE are all considered to represent primary contaminants TCE is considered to be the main COPC (ie with the highest concentrations and greatest distribution) By comparison cis- and trans-12-DCE which are considered to represent break-down (ie daughter) products of TCE andor PCE occur at relatively minor concentrations at scattered locations and were not considered indicative of significant TCE breakdown (ie via dechlorination) Although VC represents another (expected) daughter product of TCE it was not detected in any of the groundwater wells tested The groundwater TCE plume is considered to have migrated in a north-westerly direction from the suspected source site (ie the former Austral sheet metal works) in accordance with the predominant flow direction associated with the Q1 aquifer (refer to Figures 4 and 5) The plume has been traced as far west and north as Dew Street and Smith Street respectively within the Thebarton EPA Assessment Area (ie the extent of the monitoring well network installed by Fyfe) but its north-western extent has not yet been determined (whereas its extent has been defined in all other directions)

                  Soil vapour impacts Contaminants identified in soil vapour beneath the Thebarton EPA Assessment Area include TCE PCE 12-DCE (cis- and trans-) and 11-DCE The distribution of TCE in soil vapour at 1 and 3 m BGL generally correlates with the north-westerly groundwater flow direction (refer to Figures 6 and 7) and is therefore considered to be a product of volatilisation from the groundwater CHC plume ndash the consistent decrease in soil vapour concentrations with decreasing depth also supports this conclusion The soil vapour samples with the maximum TCE concentrations (ie SV3_10m and SV3_30m) also had the highest PCE and 11-DCE concentrations (or elevated LOR) thereby suggesting that they could represent co-contaminants (ie from a similar source areaactivity) These samples also had elevated LOR for 12-DCE (cis- and trans-) Although VC was not detected in any of the soil vapour samples the laboratory LOR for VC in most of the samples with the highest concentrations of TCE (ie SV2_30m SV3_10m SV3_30m and SV7_30m) exceeded the adopted HILs for residential andor commercialindustrial land use Although the absence of VC in soil vapour cannot therefore be confirmed its absence at detectable levels in groundwater suggests that (limited) TCE

                  PAGE 62 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Topic Summarised Information

                  degradation has not yet resulted in its production (ie at measureable levels) Although the extent of the soil vapour TCE plume has not yet been determined (ie in any direction) it is expected to have a similar extent to that of the identified groundwater plume (ie as the groundwater CHC impacts represent the source of the measured soil vapour CHC concentrations)

                  Potential Exposure Pathways

                  Contaminants of Based on the results of historical investigations the EPA identified a number of CHC as being of Potential Concern concern for the Thebarton EPA Assessment Area The main COPC was identified as TCE with

                  additional COPC including PCE 12-DCE (cis- and trans-) VC and 11-DCE Further detail is provided in Section 14 These COPC were confirmed by the Fyfe investigations with TCE identified as both the main contaminant in groundwater and soil vapour and the main driver in terms of potential human health risks associated with vapour intrusion into buildings within the Thebarton EPA Assessment Area (refer to Section 9)

                  Suspected source and The suspected source of the identified CHC groundwater (and soil vapour) impacts within the affected media Thebarton EPA Assessment Area is the former Austral sheet metal works located over multiple

                  allotments between George and Maria Streets from the 1920s until the 1960s-1970s Previous investigations (Appendix A) had identified groundwater CHC impacts on part of this suspected source site The Fyfe investigations have concentrated on impacts within groundwater and soil vapour across the Thebarton EPA Assessment Area both of which generally correlate with the inferred north-westerly groundwater flow direction and are considered to be related to the previously identified dissolved phase groundwater CHC impacts

                  Sensitive receptors The following sensitive receptors have been identified as potentially relevant to the Thebarton EPA Assessment Area Ecological groundwater ecosystems within the assessment area extending to at least Dew and Smith

                  Streets (ie as the north-western extent of the groundwater CHC plume has not yet been determined) and

                  the freshwater ecosystem of the River Torrens located at a distance of approximately 07 km in a hydraulically down-gradient (ie north-westerly) direction but not necessarily representing a groundwater receiving environment

                  Human current and future occupants of and visitors to residential properties current and future workers on the source site and other commercialindustrial properties

                  within the area current and future underground trenchmaintenanceutility workers and down-gradient groundwater bore users

                  Contaminant Possible contaminant transport mechanisms associated with the CHC-impacted groundwater transport identified within the Q1 aquifer beneath the Thebarton EPA Assessment Area include mechanisms flow through the aquifer to a hydraulically down-gradient surface water body andor down-

                  gradient groundwater bores vapour generation andor flow via subsurface preferential pathways (eg service trenches

                  more permeable soils) and downward movement into underlying aquifers (eg dense non-aqueous phase liquid

                  (DNAPL))

                  80607-1 REV1 30102017 PAGE 63

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Topic Summarised Information

                  Exposure Possible exposure mechanisms associated with impacted groundwater within the Thebarton mechanisms EPA Assessment Area include

                  direct contact (eg during extractionuse of groundwater) incidental ingestion (eg during extractionuse of groundwater) and inhalation of vapours (eg during extractionuse of groundwater andor as a result of

                  vapour intrusion into buildings)

                  Assessment of Risk

                  Groundwater risks The recent groundwater analytical results have indicated that the Q1 aquifer beneath the Thebarton EPA Assessment Area contains measurable concentrations of CHC (mainly TCE but also including PCE 12-DCE andor 11-DCE at some locations) Measured concentrations of TCE exceeded the adopted assessment criteria for potable andor primary contact recreation in wells MW02 MW3 MW5 MW6 MW11 MW12 MW14 MW15 MW17 MW20 MW21 and MW23 located on Admella Maria George Albert and Dew Streets as well as Light Terrace with maximum concentrations corresponding to the ldquocorerdquo area of the plume One well (MW25) contained a concentration of carbon tetrachloride that exceeded the adopted potable criterion Although groundwater vapour flux has mainly been addressed by the VIRA it could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the CHC impacted groundwater could be odorous Additional parameters measured for the purpose of establishing general aquifer conditions (including whether conditions may be amenable to the breakdown of CHC) have also been reported ndash no clear secondary lines of evidence for the occurrence of natural attenuation have been identified

                  Groundwater fate Although scattered detectable concentrations of 12-DCE have been measured in groundwater and transport across the Thebarton EPA Assessment Area the absence of significant and ubiquitous TCE modelling daughter products has been interpreted to indicate that substantial dechlorination is not

                  occurring Groundwater fate and transport modelling (refer to Section 8 and Appendix O) has predicted that the likely extent of the dissolved phase groundwater TCE plume over the next 100 years will extend by another 500 m beyond the boundaries of the current Thebarton EPA Assessment Area However no significant lateral plume expansion is expected

                  Vapour intrusion risks A VIRA (refer to Section 9 and Appendix P) was undertaken to assess potential risks to human health from the intrusion of CHC vapours (primarily TCE) into indoor air from soil vapour The predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction in the absence of specific structural information) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and therefore require further action as follows 10 properties within the investigation range (2 to lt20 microgm3) eight properties within the intervention range (20 to lt200 microgm3) and three properties within accelerated intervention range (ge200 microgm3) All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3

                  (assuming crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises Where permission has been granted by the ownersoccupiers indoor air monitoring of properties within the 20 to lt200 microgm3 and ge200 microgm3 response level ranges as well as

                  PAGE 64 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Topic Summarised Information

                  selected adjoining properties has been commissioned by the EPA to validate the results of the VIRA modelling (ie which are expected to be overly-conservative) ndash these results will be documented in a subsequent report Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentrations in soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed Management of exposures by trenchmaintenanceutility workers may be required in areas where TCE at 1 m BGL is greater than 100 microgm3 (ie corresponding to 50 times the acceptable concentration for indoor air)

                  Complete Exposure Pathways

                  Identified pathways and areas of potential risk

                  Based on the results of the recent Fyfe investigations (including the VIRA) and taking into account available historical information (Appendices A and B) and DEWNR (2017) WaterConnect bore information the following complete exposure pathways and associated risks are considered possible for the Thebarton EPA Assessment Area exposure (direct contact incidental ingestion andor inhalation of vapours) during use of

                  groundwater for domestic (eg drinking water plumbing garden irrigation) andor recreational (eg filling of swimming poolsspas) purposes

                  vapour intrusion into indoor air within 30 residential propertieslocated within the vicinity of soil vapour bores SV1 to SV9 (assuming crawl space construction) ndash although 19 of these properties are predicted to be in the validationinvestigation action level range 11 are predicted to be in the intervention action level range (with actual indoor air monitoring results for properties within the intervention action level range pending)

                  vapour intrusion into residential cellarsbasements (if present) in the vicinity of soil vapour bores SV1 to SV10 and SV12 and

                  vapour intrusion into the indoor air of commercialindustrial properties ndash although actual risks to site workers would require further specific considerationassessment

                  In addition although only assessed in a qualitative manner to date trenchmaintenanceutility workers may also be at risk where TCE at 1 m BGL is greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) Exposure management should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

                  Notes calculated on the basis of cadastral boundaries and assuming crawl space construction ndash some properties host more than one residence whereas some have one residence across two properties andor also host a commercial premises a property survey would be required to confirm building construction details and the number of individual residences affected

                  80607-1 REV1 30102017 PAGE 65

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  11 CONCLUSIONS

                  Between May and August 2017 Fyfe undertook an investigation of groundwater and soil vapour CHC impacts within an EPA-designated Assessment Area located in Thebarton South Australia The results of the investigation have been used to assess potential vapour intrusion to indoor air risks within residential and commercialindustrial properties A CSM has been developed from the field analytical and modelling results as presented in Section 10

                  The following conclusions have been reached

                  Subsurface geological conditions are generally consistent across the Thebarton EPA Assessment Area and are dominated by the sediments (ie low to medium plasticity silty or sandy clays with variable gravel contents) of the Pooraka and Hindmarsh Clay formations While there is some potential for structural defects and coarser horizons to act as preferential pathways (lateral and vertical) for soil vapour movement no significant spatially-consistent features were identified during the recent soil drillinglogging work ndash although thin gravel lenses were present within the subsurface at some locations and a 15 m thick layer of gravel was encountered at 12 to 135 m in groundwater well MW17

                  Groundwater within the Q1 aquifer is located at a depth of approximately 123 to 159 m BGL and flows in a general north-westerly direction (refer to Figure 4) ndash the closest surface water receptor is the River Torrens located approximately 03 km to the east and 07 km to the north and north-west A groundwater flow velocity range of approximately 44 to 23 myear has been inferred16 and the groundwater gradient beneath the Thebarton EPA Assessment area is relatively flat (ie 000062 to 00012)

                  Beneficial uses for groundwater within the Q1 aquifer beneath the Thebarton EPA Assessment Area have been identified to include domestic irrigation primary contact recreationaesthetics human health in non-use scenarios (ie vapour flux as assessed by the VIRA) and possibly also potable Although freshwater ecosystem protection was also considered the River Torrens is thought to comprise either a recharge boundary (ie discharging to local groundwater) or to not actually be hydraulically connected to the Q1 aquifer in this area

                  Groundwater beneath parts of the Thebarton EPA Assessment Area contains detectable concentrations of various CHC and includes TCE and carbon tetrachloride (one location only) levels that exceed the adopted assessment criteria for potable use andor primary contact recreation ndash thereby indicating that groundwater would be unsuitable for drinking or the filling of swimming poolsspas In addition vapour flux could also occur during the extraction of groundwater for domestic use and in terms of aesthetic considerations the groundwater could be odorous

                  16 ie as calculated by Fyfe based on available data

                  80607-1 REV1 30102017 PAGE 67

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  The groundwater and soil vapour CHC impacts identified beneath parts of the Thebarton EPA Assessment Area are considered likely to have emanated from the former Austral sheet metal works located over multiple allotments between George and Maria Streets from the 1920s until the 1960sshy1970s The possible presence of on-going (primary andor secondary) source(s) at this property has not yet been investigated

                  As depicted on Figures 6 and 7 the current extent of the soil vapour CHC (ie dominated by TCE) impacts has been determined to correspond to the mapped distribution of the groundwater TCE impacts (Figure 5) and is considered to be directly related to groundwater (rather than soil) CHC impacts Although no soil vapour impacts were detected at 1 m BGL in SV11 and SV1317 located near the eastern and western ends of Light Terrace respectively the north-western extents of the groundwater and soil vapour CHC impacts have not yet been determined In addition although the extent of the groundwater TCE plume has been delineated in all other directions the soil vapour TCE plume has not been delineated in any direction

                  TCE is considered to be a primary contaminant as well as the dominant (ie in terms of concentration and extent) CHC in both groundwater and soil vapour ndash the presence of PCE and 11-DCE suggests however that more than one primary contaminant is present Although the detectable concentrations of 12-DCE (cis- and trans) are considered to have resulted from the breakdown of TCEPCE no VC has been detected in either groundwater or soil vapour ndash the scattered distribution and relatively low concentrations of 12-DCE as well as the absence of measurable VC have been interpreted to indicate that significant dechlorination of the primary contaminants has not occurred (despite the likely age of the plume ndash ie possibly up to about 90 years old)

                  Although the COPC adopted for the soil vapour assessment program included various CHC (ie with TCE identified as the dominant contaminant in groundwater and soil vapour) the Tier 1 VIRA confirmed that TCE PCE and 11-DCE all exceeded the adopted vapour intrusion HILs Based primarily on its greater toxicity however the risk driver for the Thebarton EPA Assessment Area is considered to be TCE

                  The VIRA (Tier 2) results for predicted indoor air concentrations of TCE within the residential portion (assuming crawl space construction) of the Thebarton EPA Assessment Area indicated that 21 (ie of approximately 130 residential properties) were predicted to have detectable levels of TCE in indoor air and that require further action as follows

                  ― 10 properties within the investigation range (2 to lt20 microgm3)

                  ― eight properties within the intervention range (20 to lt200 microgm3) and

                  ― three properties within accelerated intervention range (ge200 microgm3)

                  All remaining residential properties in the Thebarton EPA Assessment Area are considered to be safe from soil vapour intrusion with predicted indoor air concentrations of TCE below 2 microgm3 (assuming

                  17 noting that the laboratory LOR for TCE was elevated as compared to the other soil vapour samples

                  PAGE 68 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  crawl space construction) Based on the results of the VIRA however substantially increased risks are likely to exist should cellarsbasements be present whereas risks may be lower for slab on grade construction premises ndash refer to Table 96

                  Calculated vapour intrusion risks to workers within commercialindustrial properties (slab on grade construction) across at least part of the Thebarton EPA Assessment Area (ie based on the maximum soil vapour CHC concentration obtained for soil vapour bore SV3 located on Maria Street) are considered to be unacceptable Although a basementcellar is known to be present at one commercial property on George Street vapour intrusion risks to subsurface structures associated with commercialindustrial properties have not yet been assessed

                  Although only assessed in a qualitative manner trenchmaintenanceutility workers may be at risk in areas where TCE concentrations at 1 m BGL are greater than 100 microgm3 (or 50 times the acceptable concentration for indoor air) ndash in this case appropriate management measures would be required to be adopted This should involve the development of a site-specific HSP (prior to the commencement of work in the affected area) that details measures such as restricting personnel exposure times monitoring volatile compounds using a PID unit providing increased ventilation and using appropriate PPE (eg gas masks) as required

                  80607-1 REV1 30102017 PAGE 69

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  12 DATA GAPS

                  Based on the results obtained during the recent Fyfe investigations as well as available historical information (Appendices A and B) the following data gaps have been identified for the Thebarton EPA Assessment Area

                  property information assumed for the vapour intrusion modelling has not been confirmed (ie current land use (residential versus commercial) building construction type (slab crawl space presence of basements and cellars including cellarsbasements for commercial properties)

                  groundwater uses considered for the beneficial use assessment have not been confirmed (whether bores are registered or not)

                  the conclusions are based on a single sampling event meaning the understanding of temporal and spatial variation is limited for both groundwater and soil vapour and

                  the groundwater contamination has not been fully delineated in the hydraulically down-gradient direction (north-west) and hence the groundwater fate and transport modelling is not validated

                  80607-1 REV1 30102017 PAGE 71

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  13 REFERENCES

                  ANZECCARMCANZ (2000a) Australian Guidelines for Water Quality Monitoring and Reporting

                  ANZECCARMCANZ (2000b) Australian and New Zealand Guidelines for Fresh and Marine Water Quality

                  ASTM (2001) Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations ASTM Guide D7663-12

                  ASTM (2006) Standard Guide for Soil Gas Monitoring in the Vadose Zone ASTM Guide D5314-92

                  ATSDR (1994) Toxicological profile ndash 11-Dichloroethene httpswwwatsdrcdcgovToxProfilestpaspid=722amptid=130

                  AustralianNew Zealand Standard (1998) Water Quality Sampling Part 1 Guidance on the Design of Sampling Programs Sampling Techniques and the Preservation and Handling of Samples ASNZS 566711998

                  AustralianNew Zealand Standard (1998) Water Quality Sampling Part 11 Guidance on Sampling of Groundwaters ASNZS 5667111998

                  Bouwer H and Rice RC (1976) A Slug Test Method for Determining Hydraulic Conductivity of Unconfined Aquifers with Completely or Partially Penetrating Wells Water Resources Research vol 12 no 3 pp 423-428

                  Butler JJ Jr (1998) The Design Performance and Analysis of Slug Tests

                  Cooper HH Bredehoeft JD and Papadopulos SS (1967) Response of a Finite-Diameter Well to an Instantaneous Charge of Water Water Resources Research vol 3 no 1 pp 263-269

                  CRC CARE (2013) Petroleum Hydrocarbon Vapour Intrusion Assessment ndash Australian Guidance CRC CARE Technical Report No 23 July 2013

                  Dagan G (1978) A Note on Packer Slug and Recovery Tests in Unconfined Aquifers Water Resources Research vol 14 no 5 pp 929-934

                  Department of Environment Water and Natural Resources (DEWNR 2017) Water Connect Master Register of All Bores Primary Industries and Resources South Australia

                  Duffield G (2007) AQTESOLVreg Professional Version 45 Hydrosolve Inc

                  enHealth (2012a) Environmental Health Risk Assessment - Guidelines for assessing human health risks from environmental hazards enHealth Council

                  enHealth (2012b) Australian Exposure Factor Guidance Handbook enHealth Council

                  Environment Protection Act 1993

                  80607-1 REV1 30102017 PAGE 73

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  Environment Protection Regulations 2009

                  Friebel E and Nadebaum P (2011) Health Screening Levels for Petroleum Hydrocarbons in Soil and Groundwater CRC CARE Technical Report No 10

                  Gerges NZ (1999) The Geology and Hydrogeology of the Adelaide Metropolitan Area Flinders University (South Australia) PhD thesis (unpublished)

                  Gerges NZ (2006) Overview of the Hydrogeology of the Adelaide Metropolitan Area DWLBC Report 200610

                  Golder Associates (1994) Contamination Assessment George Street Thebarton SA Report to United Land dated 9 December 1994

                  Hvorslev MJ (1951) Time Lag and Soil Permeability in Ground-Water Observations Bulletin no 36 Waterways Exper Sta Corps of Engrs US Army Vicksburg Mississippi pp 1-50

                  Hyder Z Butler JJ Jr McElwee CD and Liu W (1994) Slug Tests in Partially Penetrating Wells Water Resources Research vol 30 no 11 pp 2945-2957

                  ITRC (2007) Vapor Intrusion Pathway - A Practical Guidance

                  Johnson PC and Ettinger RA (1991) Heuristic Model for Predicting the Intrusion Rate of Contaminant Vapors

                  into Buildings Environ Sci Technology 251445-1452

                  McDonald M G and Harbaugh A W (1988) A Modular Three-Dimensional Finite-Difference Ground-Water Flow Model Techniques of Water-Resources Investigations Book 6 Chapter A1 U S Geological Survey

                  NEPM (1999) National Environment Protection (Assessment of Site Contamination) Measure Schedules B1 to

                  B9 National Environment Protection Council Australia

                  NHMRC (2008) Guidelines for Managing Risks in Recreational Water

                  NHMRCNRMMC (2011) Australian Drinking Water Guidelines (as revised in 2016)

                  NJDEP (2013) Site Remediation Program Vapor Intrusion Technical Guidance (Version 31)

                  NSW DEC (2006) Guidelines for the NSW Site Auditor Scheme (2nd edition)

                  Payne FC Quinnan JA and Potter ST (2008) Remediation Hydraulics CRC Press Boca Raton FL

                  RAIS (2016) Chemical Specific Parameters for Trichloroethylene Risk Assessment Information System Office of Environmental Management US Department of Energy

                  REM (2005a) George St Thebarton Site ndash Stage 2 Investigations Report to Luca Group dated 26 August 2005

                  REM (2005b) Stage 3 Environmental Site Assessment George St Thebarton SA Report to Luca Group dated 23 November 2005

                  SA Department of Mines and Energy (1969) 1250000 Adelaide Geological Map Sheet Sheet S1 54-9

                  PAGE 74 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  SA EPA (2007) Regulatory Monitoring and Testing Groundwater Sampling

                  SA EPA (2009) Guidelines for the Assessment and Remediation of Groundwater Contamination

                  SA EPA (2014) Clovelly Park Mitchell Park Project Management Team Assessment Program Flip Book November 2014

                  SA EPA (2015) Environment Protection (Water Quality) Policy

                  Standards Australia (1993) Geotechnical Site Investigations AS1726-1993

                  Standards Australia (2005) Guide to the Sampling and Investigation of Potentially Contaminated Soil Part 1 Non-Volatile and Semi-Volatile Compounds AS44821-2005

                  Stapledon DH (1971) Changes and Structural Defects Developed in some South Australian Clays and their Engineering Consequences Proceedings of Symposium on Soils and Earth Structures in Arid Climates Adelaide 1970

                  US EPA (1996) Soil Screening Guidance Technical Background Document Office of Emergency and Remedial Response Washington DC EPA540R95128

                  US EPA (1999) Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air Second Edition Compendium Method TO-15 Determination Of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed By Gas Chromatography Mass Spectrometry (GCMS) EPA625R-96010b

                  US EPA (2002) OSWER Draft Guidance for Evaluating the Vapour Intrusion to Indoor Air Pathway from Groundwater and Soils (Subsurface Vapour Intrusion Guidance) EPA530-D-02-004

                  US EPA (2009) EPArsquos Risk-Screening Environmental Indicators (RSEI) Methodology Office of Pollution Prevention and Toxics Washington DC

                  US EPA (2011) IRIS (Integrated Risk Information System) Trichloroethylene Chemical Assessment Summary httpscfpubepagovnceairisiris_documentsdocumentssubst0199_summarypdf

                  US EPA (2012) EPArsquos Vapor Intrusion Database Evaluation and Characterization of Attenuation Factors for Chlorinated Volatile Organic Compounds and Residential Buildings

                  US EPA (2015) OSWER Technical Guide for Assessing and Mitigating the Vapour Intrusion Pathway from Subsurface Vapour Sources to Indoor Air

                  US EPA (2017a) Regional Screening Levels (RSLs) - Generic Tables (June 2017) httpswwwepagovriskregional-screening-levels-rsls-generic-tables-june-2017

                  US EPA (2017b) Regional Screening Levels for Chemical Contaminants at Superfund Sites httpwwwepagovreg3hwmdriskhumanrb-concentration_tableGeneric_Tablesindexhtm

                  80607-1 REV1 30102017 PAGE 75

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  WHO (2006) Air Quality Guidelines for Europe Second Edition WHO Regional Publications European Series No 91

                  WHO (2017) Guidelines for Drinking-water Quality Fourth edition (incorporating the first addendum)

                  Wiedemeier T Swanson M Moutoux D Gordon E Wilson J Wilson B Kampbell D Haas P Miller R Hansen J and Chapelle F (1998) Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water National Risk Management Research Laboratory Office of Research and Development US EPA

                  Zheng C (1990) MT3D A Modular Three-Dimensional Transport Model for Simulation of Advection Dispersion and Chemical Reactions of Contaminants in Groundwater Systems Prepared for US EPA by Robert S Kerr Environmental Research Laboratory Ada Oklahoma developed by SS Papadopulos amp Associates Inc Rockville Maryland

                  PAGE 76 80607-1 REV1 30102017

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  14 STATEMENT OF LIMITATIONS

                  The opinions and conclusions presented in this report are specific to the conditions of the Thebarton EPA Assessment Area and the state of legislation currently enacted as at the date of this report Fyfe does not make any representation or warranty that the opinions and conclusions in this report will be applicable in the future as there may be changes in the condition of the Thebarton EPA Assessment Area applicable legislation or other factors that would affect the opinions and conclusions contained in this report

                  Fyfe has used the degree of skill and care ordinarily exercised by reputable members of our profession practising in the same or similar locality This report has been prepared for the South Australian Environment Protection Authority for the specific purpose identified in the report Fyfe accepts no liability or responsibility to any third party for the accuracy of any information contained in the report or any opinion or conclusion expressed in the report Neither the whole of the report nor any part or reference thereto may be in any way used relied upon or reproduced by any third party without Fyfersquos prior written approval This report must be read in its entirety including all tables and attachments

                  80607-1 REV1 30102017 PAGE 77

                  EPA REF 0524111 FINAL REPORT STAGE 1 ENVIRONMENTAL ASSESSMENT THEBARTON ASSESSMENT AREA

                  FIGURES

                  Figure 1 Site Location and Assessment Area

                  Figure 2 Assessment Point Locations

                  Figure 3 Waterloo Membrane Samplertrade TCE Concentration Plan

                  Figure 4 Groundwater Elevation Contour Plan

                  Figure 5 Groundwater Concentration Plan

                  Figure 6 Soil Vapour Concentration Plan (10m)

                  Figure 7 Soil Vapour Concentration Plan (30m)

                  80607-1 REV1 30102017 PAGE 79

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  DEW

                  STREET

                  DEW

                  STREET

                  CHAPEL STREETCHAPEL STREET

                  PAR

                  KER

                  STREET

                  PAR

                  KER

                  STREET

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  LIGHT TERRACELIGHT TERRACE

                  DEW

                  STREET

                  DEW

                  STREET

                  WA

                  LSH ST

                  WA

                  LSH ST

                  AD

                  MELLA

                  STREET

                  AD

                  MELLA

                  STREET

                  ALB

                  ERT STR

                  EETA

                  LBER

                  T STREET

                  HO

                  LLAN

                  D ST

                  REET

                  HO

                  LLAN

                  D ST

                  REET

                  RANDOLPH STREET

                  RANDOLPH STREET

                  JAM

                  ES STREET

                  JAM

                  ES STREET

                  DOVE STREET

                  DOVE STREET

                  SMITH STREETSMITH STREET

                  MARIA STREETMARIA STREET

                  GEORGE STREETGEORGE STREET

                  KINTORE STREET

                  KINTORE STREET

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  CAW

                  THO

                  RN

                  E STR

                  EETC

                  AWTH

                  OR

                  NE ST

                  REET

                  DEVON STREETDEVON STREET

                  KINTORE STREETKINTORE STREET

                  GOODENOUGH STREETGOODENOUGH STREET

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  CCAAWW

                  TTHHOO

                  RRNN

                  EE SSTTRR

                  EEEETT

                  HHOO

                  LLLLAANN

                  DD SSTT

                  RREEEETT

                  DE

                  DEW

                  SW

                  STREET

                  TREET

                  JJAM

                  EA

                  MES S

                  S STREET

                  TREET

                  DDOOVVEE SSTTRREEEETT

                  LLIIVVEESSTTRR

                  OONN

                  GG PPAATTHH

                  WWAAYY

                  LIGHT TERRLIGHT TERRAACECE

                  AD

                  MELLA

                  SA

                  DM

                  ELLA STR

                  EETTR

                  EET

                  CHAPEL SCHAPEL STREETTREET

                  AALLBB

                  EERRTT SSTTRR

                  EEEETT

                  GEGEORORGE SGE STREETTREET

                  PPOORRTT RROOAADD

                  PPOORRTT RROOAADD

                  DDEEWW

                  SSTTRREEEETT

                  MMAARRIIAA SSTTRREEEETT

                  JJAAMM

                  EESS CCOO

                  NNGG

                  DDOO

                  NN DD

                  RRIIVV

                  EE

                  WWAA

                  LLSSHH SSTT

                  SSMMIITTHH SSTTRREEEETT

                  RRANDOLPH S

                  ANDOLPH STREETTREET

                  PPOORR

                  TT RROO

                  AADD

                  PPOORR

                  TT RROO

                  AADD

                  KKIINNTTOORREE SSTTRREEEETT

                  KKIINNTTOORREE SSTTRREEEETT

                  PPAARR

                  KKEERR

                  SSTTRREEEETT

                  GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                  DDEEVVOONN SSTTRREEEETT

                  ASSESSMENT AREA

                  CBD

                  750m

                  LEGEND

                  EPA ASSESSMENT AREA

                  CADASTRE

                  12500 A3

                  0 25 50 m

                  CLIENT

                  SA EPA

                  PROJECT

                  FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

                  EPA THEBARTON ASSESSMENT AREA - STAGE 1

                  TITLE

                  FIGURE 1 SITE LOCATION AND ASSESSMENT AREA

                  PROJECT NO DATE CREATED

                  80607-1 290917

                  80607_Fig 1 - Site Location and Assessment Areaai REV 1 gt 290917

                  LE

                  VE

                  L 1

                  12

                  4 S

                  OU

                  TH

                  TE

                  RR

                  AC

                  E

                  AD

                  EL

                  AID

                  E S

                  A 5

                  00

                  0

                  P

                  H

                  (08

                  ) 8

                  23

                  2 9

                  08

                  8

                  F

                  AX

                  (0

                  8)

                  82

                  32

                  90

                  99

                  EM

                  AIL

                  in

                  fo

                  fyfe

                  co

                  ma

                  u

                  W

                  EB

                  fy

                  fec

                  om

                  au

                  AB

                  N

                  57

                  00

                  8 1

                  16 1

                  30

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  DEW

                  STREET

                  DEW

                  STREET

                  CHAPEL STREETCHAPEL STREET

                  PAR

                  KER

                  STREET

                  PAR

                  KER

                  STREET

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  LIGHT TERRACELIGHT TERRACE

                  DEW

                  STREET

                  DEW

                  STREET

                  WA

                  LSH ST

                  WA

                  LSH ST

                  AD

                  MELLA

                  STREET

                  AD

                  MELLA

                  STREET

                  ALB

                  ERT STR

                  EETA

                  LBER

                  T STREET

                  HO

                  LLAN

                  D ST

                  REET

                  HO

                  LLAN

                  D ST

                  REET

                  RANDOLPH STREET

                  RANDOLPH STREET

                  JAM

                  ES STREET

                  JAM

                  ES STREET

                  DOVE STREET

                  DOVE STREET

                  SMITH STREETSMITH STREET

                  MARIA STREETMARIA STREET

                  GEORGE STREETGEORGE STREET

                  KINTORE STREET

                  KINTORE STREET

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  CAW

                  THO

                  RN

                  E STR

                  EETC

                  AWTH

                  OR

                  NE ST

                  REET

                  DEVON STREETDEVON STREET

                  KINTORE STREETKINTORE STREET

                  GOODENOUGH STREETGOODENOUGH STREET

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  SV1SV1

                  SV2SV2

                  SV3SV3SV4SV4

                  SV5SV5

                  SV6SV6

                  SV7SV7SV8SV8

                  SV9SV9

                  SV10SV10

                  SV11SV11SV12SV12

                  SV13SV13

                  MW1MW1

                  MW02MW02

                  MW3MW3

                  MW4MW4MW5MW5MW6MW6

                  MW7MW7

                  MW8MW8

                  MW9MW9

                  MW10MW10MW11MW11

                  MW12MW12MW13MW13

                  MW14MW14MW15MW15

                  MW16MW16

                  MW17MW17

                  MW18MW18

                  MW19MW19

                  MW20MW20

                  MW21MW21

                  MW22MW22

                  MW23MW23

                  MW24MW24

                  MW25MW25

                  MW26MW26

                  WMS2WMS2WMS1WMS1

                  WMS3WMS3WMS4WMS4WMS5WMS5

                  WMS6WMS6

                  WMS7WMS7WMS8WMS8

                  WMS9WMS9WMS10WMS10

                  WMS11WMS11

                  WMS12WMS12

                  WMS13WMS13WMS14WMS14

                  WMS15WMS15

                  WMS41WMS41

                  WMS40WMS40

                  WMS39WMS39WMS38WMS38

                  WMS16WMS16

                  WMS17WMS17

                  WMS18WMS18WMS19WMS19

                  WMS20WMS20

                  WMS21WMS21WMS22WMS22

                  WMS23WMS23WMS24WMS24

                  WMS25WMS25

                  WMS26WMS26

                  WMS27WMS27WMS28WMS28WMS29WMS29

                  WMS30WMS30

                  WMS31WMS31

                  WMS32WMS32

                  WMS33WMS33

                  WMS34WMS34

                  WMS35WMS35

                  WMS36WMS36

                  WMS37WMS37

                  WWAA

                  LLSSHHSSTT

                  SSMMIITTHH SSTTRREEEETT

                  RRANDOLPH S

                  ANDOLPH STREETTREET

                  PPOORR

                  TT RROO

                  AADD

                  PPOORR

                  TT RROO

                  AADD

                  CCAAWW

                  TTHHOO

                  RRNN

                  EE SSTTRR

                  EEEETT

                  JJAM

                  EA

                  MES S

                  S STREET

                  TREET

                  HHOO

                  LLLLAANN

                  DDSSTT

                  RREEEETT

                  DE

                  DEW

                  SW

                  STREET

                  TREET

                  DDOOVVEE SSTTRREEEETT

                  LLIIVVEESSTTRR

                  OONN

                  GGPPAATTHH

                  WWAAYY

                  LIGHT TERRLIGHT TERRAACECE

                  CHAPEL SCHAPEL STREETTREET

                  AALLBB

                  EERRTT SSTTRR

                  EEEETT

                  AD

                  MELLA

                  SA

                  DM

                  ELLA STR

                  EETTR

                  EET

                  GEGEORORGE SGE STREETTREET

                  PPOORRTT RROOAADD PPOORRTT RROOAADD

                  DDEEWW

                  SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

                  JJAAMM

                  EESS CCOO

                  NNGG

                  DDOO

                  NN DD

                  RRIIVV

                  EE

                  KKIINNTTOORREE SSTTRREEEETT

                  KKIINNTTOORREE SSTTRREEEETT

                  PPAARR

                  KKEERR

                  SSTTRREEEETT

                  GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                  DDEEVVOONN SSTTRREEEETT

                  FIGURE 2 ASSESSMENT POINT LOCATIONS

                  MMWW88

                  MW2MW244 WMS3WMS355

                  MW2MW255

                  WMS3WMS366

                  WMS3WMS377

                  WMS3WMS311

                  MW2MW222WMS34WMS34

                  MW2MW233 WMS3WMS322

                  WMS3WMS333

                  WMS2WMS277WMS2WMS299 WMS2WMS288

                  SSV12V12 SSVV1111 MW19MW19

                  MW18MW18 SSVV1133 MW2MW200 WMS3WMS300

                  MW2MW211 WMS2WMS255

                  WMS2WMS266

                  MW17MW17 WMS2WMS244

                  WMS2WMS233

                  WMS2WMS222 WMS2WMS211

                  SSVV99

                  SSV10V10WMS2WMS200 MW14MW14MW15MW15 WMS18WMS18

                  WMS19WMS19 MW16MW16

                  WMS13WMS13MW10MW10 WMS14WMS14MMWW1111SVSV77WMS15WMS15SSVV88WMS16WMS16

                  SVSV66WMS4WMS411MW13MW13 LEGENDMW12MW12

                  WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS17WMS17 WMS40WMS40 SSVV55 MW0MW022MW9MW9 GROUNDWATER MONITORING WELL

                  WMS11WMS11 WMS6WMS6 SOIL VAPOUR BORE

                  WATERLOO MEMBRANE SAMPLERTM - ROUND 2

                  SVSV22WMS8WMS8SVSVWMS12WMS12 44 WMS7WMS7 MW4MW4MMWW SVSV66 33 MW5MW5WMS3WMS388

                  WMS3WMS399 MW7MW7 EPA ASSESSMENT AREAWMS10WMS10 WMS9WMS9

                  SVSV11 CADASTRE

                  MW3MW3

                  MW1MW1 WMS3WMS3WMS4WMS4MW2MW266 WMS5WMS5 12500 A3

                  0 25 50 m

                  CLIENT

                  SA EPAWMS1WMS1

                  WMS2WMS2 PROJECT

                  EPA THEBARTON ASSESSMENT AREA - STAGE 1

                  TITLE

                  FIGURE 2 ASSESSMENT POINT LOCATIONS

                  PROJECT NO DATE CREATED

                  80607-1 280917

                  80607_Fig 2 - Assessment Point Locationsai REV 1 gt 280917

                  LE

                  VE

                  L 1

                  12

                  4 S

                  OU

                  TH

                  TE

                  RR

                  AC

                  E

                  AD

                  EL

                  AID

                  E S

                  A 5

                  00

                  0

                  PH

                  (0

                  8)

                  82

                  32

                  90

                  88

                  F

                  AX

                  (0

                  8)

                  82

                  32

                  90

                  99

                  E

                  MA

                  IL

                  info

                  fy

                  fec

                  om

                  au

                  W

                  EB

                  fy

                  fec

                  om

                  au

                  A

                  BN

                  5

                  7 0

                  08

                  116

                  13

                  0

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  DEW

                  STREET

                  DEW

                  STREET

                  CHAPEL STREETCHAPEL STREET

                  PAR

                  KER

                  STREET

                  PAR

                  KER

                  STREET

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  LIGHT TERRACELIGHT TERRACE

                  DEW

                  STREET

                  DEW

                  STREET

                  WA

                  LSH ST

                  WA

                  LSH ST

                  AD

                  MELLA

                  STREET

                  AD

                  MELLA

                  STREET

                  ALB

                  ERT STR

                  EETA

                  LBER

                  T STREET

                  HO

                  LLAN

                  D ST

                  REET

                  HO

                  LLAN

                  D ST

                  REET

                  RANDOLPH STREET

                  RANDOLPH STREET

                  JAM

                  ES STREET

                  JAM

                  ES STREET

                  DOVE STREET

                  DOVE STREET

                  SMITH STREETSMITH STREET

                  MARIA STREETMARIA STREET

                  GEORGE STREETGEORGE STREET

                  KINTORE STREET

                  KINTORE STREET

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  CAW

                  THO

                  RN

                  E STR

                  EETC

                  AWTH

                  OR

                  NE ST

                  REET

                  DEVON STREETDEVON STREET

                  KINTORE STREETKINTORE STREET

                  GOODENOUGH STREETGOODENOUGH STREET

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  WMS2WMS2WMS1WMS1

                  WMS3WMS3WMS4WMS4

                  WMS5WMS5

                  WMS6WMS6

                  WMS7WMS7WMS8WMS8

                  WMS9WMS9

                  WMS10WMS10

                  WMS11WMS11

                  WMS12WMS12

                  WMS13WMS13WMS14WMS14

                  WMS15WMS15 WMS41WMS41

                  WMS40WMS40

                  WMS39WMS39WMS38WMS38

                  WMS16WMS16

                  WMS17WMS17

                  WMS18WMS18WMS19WMS19WMS20WMS20

                  WMS21WMS21WMS22WMS22

                  WMS23WMS23WMS24WMS24

                  WMS25WMS25

                  WMS26WMS26

                  WMS27WMS27WMS28WMS28WMS29WMS29

                  WMS30WMS30

                  WMS31WMS31

                  WMS32WMS32WMS33WMS33

                  WMS34WMS34

                  WMS35WMS35

                  WMS36WMS36

                  WMS37WMS37

                  WWAA

                  LLSSHHSSTT

                  SSMMIITTHH SSTTRREEEETT

                  RRANDOLPH S

                  ANDOLPH STREETTREET

                  PPOORR

                  TT RROO

                  AADD

                  PPOORR

                  TT RROO

                  AADD

                  CCAAWW

                  TTHHOO

                  RRNN

                  EE SSTTRR

                  EEEETT

                  JJAM

                  EA

                  MES S

                  S STREET

                  TREET

                  HHOO

                  LLLLAANN

                  DDSSTT

                  RREEEETT

                  DE

                  DEW

                  SW

                  STREET

                  TREET

                  DDOOVVEE SSTTRREEEETT

                  LLIIVVEESSTTRR

                  OONN

                  GGPPAATTHH

                  WWAAYY

                  LIGHT TERRLIGHT TERRAACECE

                  AD

                  MELLA

                  SA

                  DM

                  ELLA STR

                  EETTR

                  EET

                  AALLBB

                  EERRTT SSTTRR

                  EEEETT

                  CHAPEL SCHAPEL STREETTREET

                  GEGEORORGE SGE STREETTREET

                  PPOORRTT RROOAADD PPOORRTT RROOAADD

                  DDEEWW

                  SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

                  JJAAMM

                  EESS CCOO

                  NNGG

                  DDOO

                  NN DD

                  RRIIVV

                  EE

                  KKIINNTTOORREE SSTTRREEEETT

                  KKIINNTTOORREE SSTTRREEEETT

                  PPAARR

                  KKEERR

                  SSTTRREEEETT

                  GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                  DDEEVVOONN SSTTRREEEETT

                  FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

                  TCE CONCENTRATION PLAN

                  WMS3WMS355 TCE lt78

                  WMS3WMS366 TCE lt77WMS3WMS377

                  TCE 44

                  WMS3WMS311 TCE lt78

                  WMS34WMS34 TCE 11

                  WMS3WMS322WMS3WMS333 TCE lt78TCE lt79

                  WMS2WMS277WMS2WMS299 WMS2WMS288 TCE 64 TCE lt77 TCE lt8

                  WMS3WMS300 TCE lt8

                  WMS2WMS255

                  WMS2WMS266 TCE 1400(D)

                  WMS2WMS222 TCE 38 WMS2WMS211

                  TCE lt79

                  TCE lt78

                  WMS2WMS233 WMS2WMS244 TCE lt77

                  TCE 230

                  WMS2WMS200 WMS19WMS19TCE lt78 WMS18WMS18 TCE 11000

                  TCE 4200

                  WMS13WMS13 WMS14WMS14 TCE lt79

                  WMS4WMS411WMS15WMS15 TCE 46000WMS16WMS16 TCE 18000 LEGENDTCE lt8

                  TCE lt78WMS17WMS17 WATERLOO MEMBRANE SAMPLERTM - ROUND 1WMS40WMS40TCE lt79

                  TCE 110000 WATERLOO MEMBRANE SAMPLERTM - ROUND 2WMS11WMS11

                  TCE 71000WMS12WMS12 EPA ASSESSMENT AREA

                  CADASTRE

                  WMS6WMS6 TCE lt58 WMS8WMS8 WMS3WMS388 TCE 32WMS7WMS7WMS3WMS399

                  TCE 12000 TCE 13000 TCE 1900TCE 1300WMS9WMS9 TCE lt58 NotesWMS10WMS10

                  All concentrations are in μgm3 TCE lt58

                  D = Duplicate result

                  WMS3WMS3WMS4WMS4 12500 A3

                  LE

                  VE

                  L 1

                  12

                  4 S

                  OU

                  TH

                  TE

                  RR

                  AC

                  E

                  AD

                  EL

                  AID

                  E S

                  A 5

                  00

                  0

                  PH

                  (0

                  8)

                  82

                  32

                  90

                  88

                  F

                  AX

                  (0

                  8)

                  82

                  32

                  90

                  99

                  E

                  MA

                  IL

                  info

                  fy

                  fec

                  om

                  au

                  W

                  EB

                  fy

                  fec

                  om

                  au

                  A

                  BN

                  5

                  7 0

                  08

                  116

                  13

                  0

                  TCE lt57WMS5WMS5 TCE lt57 TCE lt58 0 25 50

                  m

                  CLIENT

                  SA EPA

                  WMS2WMS2 TCE lt56

                  WMS1WMS1 TCE lt56

                  PROJECT

                  EPA THEBARTON ASSESSMENT AREA - STAGE 1

                  TITLE

                  FIGURE 3 WATERLOO MEMBRANE SAMPLERTM

                  TCE CONCENTRATION PLAN

                  PROJECT NO DATE CREATED

                  80607-1 241017

                  80607_Fig 3 - WMS TCE Concentration Planai REV 1 gt 241017

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  DEW

                  STREET

                  DEW

                  STREET

                  CHAPEL STREETCHAPEL STREET

                  PAR

                  KER

                  STREET

                  PAR

                  KER

                  STREET

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  LIGHT TERRACELIGHT TERRACE

                  DEW

                  STREET

                  DEW

                  STREET

                  WA

                  LSH ST

                  WA

                  LSH ST

                  AD

                  MELLA

                  STREET

                  AD

                  MELLA

                  STREET

                  ALB

                  ERT STR

                  EETA

                  LBER

                  T STREET

                  HO

                  LLAN

                  D ST

                  REET

                  HO

                  LLAN

                  D ST

                  REET

                  RANDOLPH STREET

                  RANDOLPH STREET

                  JAM

                  ES STREET

                  JAM

                  ES STREET

                  DOVE STREET

                  DOVE STREET

                  SMITH STREETSMITH STREET

                  MARIA STREETMARIA STREET

                  GEORGE STREETGEORGE STREET

                  KINTORE STREET

                  KINTORE STREET

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  CAW

                  THO

                  RN

                  E STR

                  EETC

                  AWTH

                  OR

                  NE ST

                  REET

                  DEVON STREETDEVON STREET

                  KINTORE STREETKINTORE STREET

                  GOODENOUGH STREETGOODENOUGH STREET

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  MW1MW1

                  MW02MW02

                  MW3MW3

                  MW4MW4MW5MW5

                  MW6MW6

                  MW7MW7

                  MW8MW8

                  MW9MW9

                  MW10MW10MW11MW11

                  MW12MW12

                  MW13MW13

                  MW14MW14

                  MW15MW15

                  MW16MW16

                  MW17MW17

                  MW18MW18

                  MW19MW19MW20MW20

                  MW21MW21

                  MW22MW22

                  MW23MW23

                  MW24MW24

                  MW25MW25

                  MW26MW26

                  WWAA

                  LLSSHHSSTT

                  SSMMIITTHH SSTTRREEEETT

                  4

                  466

                  PPOORR

                  TT RROO

                  AADD

                  PPOORR

                  TT RROO

                  AADD

                  RRANDOLPH S

                  ANDOLPH STREETTREET 4455

                  DE

                  DEW

                  SW

                  STREET

                  TREET

                  JJAM

                  EA

                  MES S

                  S STREET

                  TREET

                  HHOO

                  LLLLAANN

                  DD SSTT

                  RREEEETT

                  CCAAWW

                  TTHHOO

                  RRNN

                  EE SSTTRR

                  EEEETT 4477

                  DDOOVVEE SSTTRREEEETT

                  4455

                  4488

                  LLIIVVEESSTTRR

                  OONN

                  GGPPAATTHH

                  WWAAYY

                  4455

                  LIGHT TERRLIGHT TERRAACECE

                  AD

                  MELLA

                  SA

                  DM

                  ELLA STR

                  EETTR

                  EET

                  4466

                  CHAPEL SCHAPEL STREETTREET

                  4477 AA

                  LLBBEERR

                  TT SSTTRREEEETT

                  4499

                  GR4466 OUND

                  FLOW DIREW

                  GEGEORORGE SGE STREETTREET ATER C

                  4488 TION

                  PPOORRTT RROOAADD PPOORRTT RROOAADD 55

                  00 DD

                  EEWW SSTTRR

                  EEEETT 4499

                  MMAARRIIAA SSTTRREEEETT

                  4477

                  5500

                  JJAAMM

                  EESS CCOO

                  NNGG

                  DDOO

                  NN DD

                  RRIIVV

                  EE

                  88 44

                  KKIINNTTOORREE SSTTRREEEETT

                  KKIINNTTOORREE SSTTRREEEETT

                  PPAARR

                  KKEERR

                  SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                  5500

                  4499

                  DDEEVVOONN SSTTRREEEETT

                  FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

                  Groundwater SWL MMWW88 Monitoring Well (m AHD)

                  MW1 5011 MW2MW244

                  MW02 4786

                  MW3 484

                  MW2MW255 MW4 507

                  MW5 4833

                  MW6 4794

                  MW7 4703

                  MW8 4581

                  MW9 4728

                  MW10 4871

                  MW11 4785 MW2MW222

                  MW12 4689

                  MW13 4662

                  MW2MW233 MW14 4723

                  MW15 464

                  MW16 4577

                  MW17 4619

                  MW18 4538

                  MW19 4735

                  MW20 457

                  MW21 4531

                  MW22 4501

                  MW23 4497

                  MW24 4537

                  MW25 4469

                  MW26 4918

                  MW19MW19 MW2MW200

                  MW2MW211MW18MW18

                  MW17MW17

                  MW14MW14

                  MW15MW15

                  MW16MW16

                  MW10MW10 LEGEND MMWW1111

                  GROUNDWATER MONITORING WELLMW12MW12

                  50 INFERRED GROUNDWATER ELEVATION CONTOUR

                  MW13MW13

                  MW0MW022 INFERRED GROUNDWATER FLOW DIRECTION

                  EPA ASSESSMENT AREA

                  MW9MW9

                  MW5MW5 CADASTREMMWW66 MW4MW4

                  MW7MW7 Note This is one interpretation only Other interpretations possibleMW3MW3

                  12500 A3

                  0 25 50 m

                  CLIENT

                  SA EPA

                  PROJECT

                  EPA THEBARTON ASSESSMENT AREA - STAGE 1

                  TITLE

                  FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN

                  PROJECT NO DATE CREATED

                  80607-1 290917

                  MW1MW1 MW2MW266

                  80607_Fig 4 - Groundwater Elevation Contour Planai REV 1 gt 290917

                  LE

                  VE

                  L 1

                  12

                  4 S

                  OU

                  TH

                  TE

                  RR

                  AC

                  E

                  AD

                  EL

                  AID

                  E S

                  A 5

                  00

                  0

                  PH

                  (0

                  8)

                  82

                  32

                  90

                  88

                  F

                  AX

                  (0

                  8)

                  82

                  32

                  90

                  99

                  E

                  MA

                  IL

                  info

                  fy

                  fec

                  om

                  au

                  W

                  EB

                  fy

                  fec

                  om

                  au

                  A

                  BN

                  5

                  7 0

                  08

                  116

                  13

                  0

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  DEW

                  STREET

                  DEW

                  STREET

                  CHAPEL STREETCHAPEL STREET

                  PAR

                  KER

                  STREET

                  PAR

                  KER

                  STREET

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  LIGHT TERRACELIGHT TERRACE

                  DEW

                  STREET

                  DEW

                  STREET

                  WA

                  LSH ST

                  WA

                  LSH ST

                  AD

                  MELLA

                  STREET

                  AD

                  MELLA

                  STREET

                  ALB

                  ERT STR

                  EETA

                  LBER

                  T STREET

                  HO

                  LLAN

                  D ST

                  REET

                  HO

                  LLAN

                  D ST

                  REET

                  RANDOLPH STREET

                  RANDOLPH STREET

                  JAM

                  ES STREET

                  JAM

                  ES STREET

                  DOVE STREET

                  DOVE STREET

                  SMITH STREETSMITH STREET

                  MARIA STREETMARIA STREET

                  GEORGE STREETGEORGE STREET

                  KINTORE STREET

                  KINTORE STREET

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  CAW

                  THO

                  RN

                  E STR

                  EETC

                  AWTH

                  OR

                  NE ST

                  REET

                  DEVON STREETDEVON STREET

                  KINTORE STREETKINTORE STREET

                  GOODENOUGH STREETGOODENOUGH STREET

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  MW1MW1

                  MW02MW02

                  MW3MW3

                  MW4MW4

                  MW5MW5

                  MW6MW6

                  MW7MW7

                  MW8MW8

                  MW9MW9

                  MW10MW10MW11MW11

                  MW12MW12

                  MW13MW13

                  MW14MW14

                  MW15MW15

                  MW16MW16

                  MW17MW17

                  MW18MW18

                  MW19MW19MW20MW20

                  MW21MW21

                  MW22MW22

                  MW23MW23

                  MW24MW24

                  MW25MW25

                  MW26MW26

                  WWAA

                  LLSSHHSSTT

                  SSMMIITTHH SSTTRREEEETT

                  ndnd

                  RRANDOLPH S

                  ANDOLPH STREETTREET

                  PPOORR

                  TTRR

                  OOAA

                  DD

                  PPOORR

                  TTRR

                  OOAA

                  DD

                  JJAM

                  EA

                  MES S

                  S STREET

                  TREET

                  HHOO

                  LLLLAANN

                  DDSSTT

                  RREEEETT

                  CCAAWW

                  TTHHOO

                  RRNN

                  EESSTT

                  RREEEETT

                  DE

                  DEW

                  SW

                  STREET

                  TREET

                  DDOOVVEE SSTTRREEEETT

                  LLIIVVEESSTTRR

                  OONN

                  GGPPAATTHH

                  WWAAYY

                  LIGHT TERRLIGHT TERRAACECE

                  AD

                  MELLA

                  SA

                  DM

                  ELLA STR

                  EETTR

                  EET

                  AALLBB

                  EERRTT SSTTRR

                  EEEETT

                  CHAPEL SCHAPEL STREETTREET

                  ndnd ndnd

                  100100

                  11000000

                  GEGEORORGE SGE STREETTREET

                  1010000000

                  PPOORRTT RROOAADD PPOORRTT RROOAADD

                  DDEEWW

                  SSTTRREEEETT

                  1010000000 11000000 MMAARRIIAA SSTTRREEEETT

                  100100

                  JJAAMM

                  EESSCC

                  OONN

                  GGDD

                  OONN

                  DDRR

                  IIVVEE

                  KKIINNTTOORREE SSTTRREEEETT ndnd

                  KKIINNTTOORREE SSTTRREEEETT

                  PPAARR

                  KKEERR

                  SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                  DDEEVVOONN SSTTRREEEETT

                  FIGURE 5 GROUNDWATER CONCENTRATION PLAN

                  MW2MW244

                  MMWW88 TCE lt1

                  PCE lt1

                  11-DCE lt1TCE lt1

                  12-DCE lt1PCE lt1

                  11-DCE lt1MW2MW255 12-DCE lt1

                  TCE 2

                  PCE lt1

                  11-DCE lt1

                  12-DCE lt1

                  MW2MW222 TCE lt1

                  PCE lt1

                  11-DCE lt1MW2MW233 12-DCE lt1

                  TCE 21

                  PCE lt1

                  11-DCE lt1

                  12-DCE lt1

                  MW19MW19 TCE lt1

                  MW2MW200 TCE 70 PCE lt1MW2MW211 PCE lt1MW18MW18 11-DCE lt1

                  TCE 23 11-DCE lt1TCE 5 12-DCE lt1 PCE lt1 12-DCE lt1PCE lt1 11-DCE lt1

                  11-DCE lt1 12-DCE lt1

                  12-DCE lt1

                  MW17MW17 LEGENDTCE 24 MW14MW14

                  PCE lt1 TCE 1100 lt1 MW15MW15 GROUNDWATER MONITORING WELL11-DCE PCE lt1

                  12-DCE lt1 TCE 180 11-DCE 2MW16MW16 100 INFERRED TCE GROUNDWATERPCE lt1 12-DCE 4 CONCENTRATION CONTOURSTCE lt1 11-DCE lt1 PCE lt1 12-DCE lt1 11-DCE lt1

                  12-DCE lt1 MMWW1111

                  EPA ASSESSMENT AREAMW10MW10

                  TCE lt1 CADASTREMW12MW12 TCE lt14900 PCE

                  lt1 11-DCE lt1TCE 700 PCEMW13MW13 12-DCE lt1 TCE CONCENTRATIONS (μgL)lt1 11-DCE 7PCE

                  TCE lt1 lt1 12-DCE 511-DCE gtnd to lt100 100 to lt1000 1000 to lt10000

                  MW0MW022PCE lt1 12-DCE lt1 2100011-DCE lt1 MW9MW9 TCE

                  PCE lt112-DCE lt1 TCE 2(D) 11-DCE 15PCE lt1 MW5MW5

                  10000 to 29000

                  nd = non-detect (lt1)12-DCE 4511-DCE lt1 MMWW66 TCE 29000 MW4MW4 12-DCE lt1

                  PCE 3 TCE lt1 NotesTCE 29 11-DCE 6MW7MW7 PCE lt1PCE lt1 This is one interpretation only Other interpretations possible12-DCE 23TCE lt1 11-DCE lt111-DCE lt1 All concentrations are in μgL

                  12-DCE includes cis and trans PCE lt1 MW3MW3 12-DCE lt112-DCE lt1 11-DCE lt1

                  TCE 69 D = Duplicate result12-DCE lt1 PCE lt1

                  11-DCE lt1

                  12-DCE lt1 MW1MW1

                  12500 A3MW2MW266 TCE lt1

                  TCE 2 PCE lt1

                  PCE lt1 11-DCE lt1

                  11-DCE lt1 12-DCE lt1

                  12-DCE lt1

                  LE

                  VE

                  L 1

                  12

                  4 S

                  OU

                  TH

                  TE

                  RR

                  AC

                  E

                  AD

                  EL

                  AID

                  E S

                  A 5

                  00

                  0

                  PH

                  (0

                  8)

                  82

                  32

                  90

                  88

                  F

                  AX

                  (0

                  8)

                  82

                  32

                  90

                  99

                  E

                  MA

                  IL

                  info

                  fy

                  fec

                  om

                  au

                  W

                  EB

                  fy

                  fec

                  om

                  au

                  A

                  BN

                  5

                  7 0

                  08

                  116

                  13

                  0

                  0 25 50 m

                  CLIENT

                  SA EPA

                  PROJECT

                  EPA THEBARTON ASSESSMENT AREA - STAGE 1

                  TITLE

                  FIGURE 5 GROUNDWATER CONCENTRATION PLAN

                  PROJECT NO DATE CREATED

                  80607-1 280917

                  80607_Fig 5 - Groundwater TCE Concentration Plan r2ai REV 2 gt 280917

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  DEW

                  STREET

                  DEW

                  STREET

                  CHAPEL STREETCHAPEL STREET

                  PAR

                  KER

                  STREET

                  PAR

                  KER

                  STREET

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  LIGHT TERRACELIGHT TERRACE

                  DEW

                  STREET

                  DEW

                  STREET

                  WA

                  LSH ST

                  WA

                  LSH ST

                  AD

                  MELLA

                  STREET

                  AD

                  MELLA

                  STREET

                  ALB

                  ERT STR

                  EETA

                  LBER

                  T STREET

                  HO

                  LLAN

                  D ST

                  REET

                  HO

                  LLAN

                  D ST

                  REET

                  RANDOLPH STREET

                  RANDOLPH STREET

                  JAM

                  ES STREET

                  JAM

                  ES STREET

                  DOVE STREET

                  DOVE STREET

                  SMITH STREETSMITH STREET

                  MARIA STREETMARIA STREET

                  GEORGE STREETGEORGE STREET

                  KINTORE STREET

                  KINTORE STREET

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  CAW

                  THO

                  RN

                  E STR

                  EETC

                  AWTH

                  OR

                  NE ST

                  REET

                  DEVON STREETDEVON STREET

                  KINTORE STREETKINTORE STREET

                  GOODENOUGH STREETGOODENOUGH STREET

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  SV1SV1

                  SV2SV2SV3SV3SV4SV4

                  SV5SV5

                  SV7SV7SV8SV8

                  SV9SV9

                  SV10SV10

                  SV11SV11SV12SV12

                  SV13SV13

                  SV6SV6

                  WWAA

                  LLSSHHSSTT

                  SSMMIITTHH SSTTRREEEETT

                  RRANDOLPH S

                  ANDOLPH STREETTREET

                  PPOORR

                  TTRR

                  OOAA

                  DD

                  PPOORR

                  TTRR

                  OOAA

                  DD

                  CCAAWW

                  TTHHOO

                  RRNN

                  EESSTT

                  RREEEETT

                  HHOO

                  LLLLAANN

                  DDSSTT

                  RREEEETT

                  JJAM

                  EA

                  MES S

                  S STREET

                  TREET

                  DE

                  DEW

                  SW

                  STREET

                  TREET

                  DDOOVVEE SSTTRREEEETT

                  00

                  LLIIVVEESSTTRR

                  OONN

                  GGPPAATTHH

                  WWAAYY

                  LIGHT TERRLIGHT TERRAACECE

                  AD

                  MELLA

                  SA

                  DM

                  ELLA STR

                  EETTR

                  EET

                  CHAPEL SCHAPEL STREETTREET

                  00

                  AALLBB

                  EERRTT SSTTRR

                  EEEETT

                  1010

                  GEGEORORGE SGE STREETTREET

                  000000

                  PPOORRTT RROOAADD

                  100100000

                  000

                  1010

                  PPOORRTT RROOAADD

                  000000

                  DDEEWW

                  SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

                  JJAAMM

                  EESSCC

                  OONN

                  GGDD

                  OONN

                  DDRR

                  IIVVEE

                  KKIINNTTOORREE SSTTRREEEETT 00

                  KKIINNTTOORREE SSTTRREEEETT

                  PPAARR

                  KKEERR

                  SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                  DDEEVVOONN SSTTRREEEETT

                  FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

                  SSVV1111 SSV12V12 TCE lt18

                  SSVV1133 TCE 16

                  PCE lt54 TCE lt21

                  11-DCE lt29 PCE lt25

                  12-DCE lt39 11-DCE lt14

                  12-DCE lt18

                  PCE lt22

                  11-DCE lt12

                  12-DCE lt16

                  TCE 170

                  PCE lt54

                  11-DCE lt3

                  12-DCE lt39 LEGEND SSVV99

                  SSV10V10 SOIL VAPOUR BORE

                  TCE lt21 0 INFERRED TCE SOIL VAPOUR CONTOUR PCE lt25

                  TCE 2200011-DCE lt14 EPA ASSESSMENT AREA

                  PCE 1912-DCE lt18

                  11-DCE lt27 CADASTRE

                  12-DCE lt37 SVSV66SVSV77

                  SSVV88 TCE 22000

                  TCE 2300 PCE 12 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)TCE 100000 PCE 62 11-DCE lt29PCE 84 0 to lt10000SSVV55lt2711-DCE 12-DCE lt2911-DCE lt33 10000 to lt100000

                  100000 to 210000 12-DCE lt36 12-DCE lt44

                  TCE 17000 SVSV44 SVSV22SVSV33 NotePCE 31 TCE 51000TCE 210000 This is one interpretation only Other interpretations possible11-DCE lt14 PCE 39PCE 650012-DCE lt18 39 Estimated extent of plume has utilised groundwater11-DCE11-DCE 5900 12-DCE 21 concentration data12-DCE lt71

                  SVSV11 All concentrations are in (μgmsup3)

                  TCE 6300(LD) 12-DCE includes cis and trans PCE 78 LD = Laboratory duplicate result 11-DCE lt29

                  12-DCE lt38

                  12500 A3

                  0 25 50 m

                  CLIENT

                  SA EPA

                  PROJECT

                  EPA THEBARTON ASSESSMENT AREA - STAGE 1

                  TITLE

                  FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)

                  PROJECT NO DATE CREATED

                  80607-1 290917

                  80607_Fig 6 - Soil Vapour TCE Concentration Plan - 1mai REV 2 gt 290917

                  LE

                  VE

                  L 1

                  12

                  4 S

                  OU

                  TH

                  TE

                  RR

                  AC

                  E

                  AD

                  EL

                  AID

                  E S

                  A 5

                  00

                  0

                  PH

                  (0

                  8)

                  82

                  32

                  90

                  88

                  F

                  AX

                  (0

                  8)

                  82

                  32

                  90

                  99

                  E

                  MA

                  IL

                  info

                  fy

                  fec

                  om

                  au

                  W

                  EB

                  fy

                  fec

                  om

                  au

                  A

                  BN

                  5

                  7 0

                  08

                  116

                  13

                  0

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  JAM

                  ES CO

                  NG

                  DO

                  N D

                  RIV

                  E

                  DEW

                  STREET

                  DEW

                  STREET

                  CHAPEL STREETCHAPEL STREET

                  PAR

                  KER

                  STREET

                  PAR

                  KER

                  STREET

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  POR

                  T RO

                  AD

                  LIGHT TERRACELIGHT TERRACE

                  DEW

                  STREET

                  DEW

                  STREET

                  WA

                  LSH ST

                  WA

                  LSH ST

                  AD

                  MELLA

                  STREET

                  AD

                  MELLA

                  STREET

                  ALB

                  ERT STR

                  EETA

                  LBER

                  T STREET

                  HO

                  LLAN

                  D ST

                  REET

                  HO

                  LLAN

                  D ST

                  REET

                  RANDOLPH STREET

                  RANDOLPH STREET

                  JAM

                  ES STREET

                  JAM

                  ES STREET

                  DOVE STREET

                  DOVE STREET

                  SMITH STREETSMITH STREET

                  MARIA STREETMARIA STREET

                  GEORGE STREETGEORGE STREET

                  KINTORE STREET

                  KINTORE STREET

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  PORT ROAD

                  CAW

                  THO

                  RN

                  E STR

                  EETC

                  AWTH

                  OR

                  NE ST

                  REET

                  DEVON STREETDEVON STREET

                  KINTORE STREETKINTORE STREET

                  GOODENOUGH STREETGOODENOUGH STREET

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  LIVESTR

                  ON

                  G PATH

                  WAY

                  SV1SV1

                  SV2SV2SV3SV3SV4SV4

                  SV5SV5

                  SV7SV7SV8SV8

                  SV9SV9

                  SV10SV10

                  SV12SV12

                  SV6SV6

                  WWAA

                  LLSSHHSSTT

                  SSMMIITTHH SSTTRREEEETT

                  RRANDOLPH S

                  ANDOLPH STREETTREET

                  PPOORR

                  TTRR

                  OOAA

                  DD

                  PPOORR

                  TTRR

                  OOAA

                  DD

                  CCAAWW

                  TTHHOO

                  RRNN

                  EESSTT

                  RREEEETT

                  HHOO

                  LLLLAANN

                  DDSSTT

                  RREEEETT

                  DE

                  DEW

                  SW

                  STREET

                  TREET

                  JJAM

                  EA

                  MES S

                  S STREET

                  TREET

                  DDOOVVEE SSTTRREEEETT

                  00

                  LIGHT TERRLIGHT TERRAACECE

                  LLIIVVEESSTTRR

                  OONN

                  GGPPAATTHH

                  WWAAYY

                  AD

                  MELLA

                  SA

                  DM

                  ELLA STR

                  EETTR

                  EET

                  CHAPEL SCHAPEL STREETTREET

                  00

                  1010000000

                  AALLBB

                  EERRTT SSTTRR

                  EEEETT

                  100100 000

                  000 GEGEORORGE SGE STREETTREET

                  PPOORRTT RROOAADD 11000000000

                  000 PPOORRTT RROOAADD

                  DDEEWW

                  SSTTRREEEETT MMAARRIIAA SSTTRREEEETT

                  100100000000

                  JJAAMM

                  EESSCC

                  OONN

                  GGDD

                  OONN

                  DDRR

                  IIVVEE

                  1010000000

                  KKIINNTTOORREE SSTTRREEEETT

                  00

                  KKIINNTTOORREE SSTTRREEEETT

                  PPAARR

                  KKEERR

                  SSTTRREEEETT GGOOOODDEENNOOUUGGHH SSTTRREEEETT

                  DDEEVVOONN SSTTRREEEETT

                  FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

                  SSV12V12 TCE 55

                  PCE lt45

                  11-DCE lt24

                  12-DCE lt32

                  TCE 260

                  PCE lt51

                  11-DCE lt28

                  12-DCE

                  SSVV99

                  lt37 LEGEND

                  SSV10V10 SOIL VAPOUR BORE

                  TCE 51 0 INFERRED TCE SOIL VAPOUR CONTOURPCE lt53

                  TCE 11000011-DCE lt29

                  EPA ASSESSMENT AREAPCE lt13012-DCE lt39

                  11-DCE lt69

                  CADASTRE12-DCE lt92 SVSV66SVSV77

                  SSVV88 TCE 150000

                  TCE 14000 56 SOIL VAPOUR TCE CONCENTRATIONS (μgmsup3)PCETCE 160000 PCE 19 11-DCE lt30PCE 310 0 to lt10000SSVV5511-DCE lt26 12-DCE lt3911-DCE 33 10000 to lt100000

                  100000 to lt1000000 1000000

                  12-DCE lt35 12-DCE 20

                  TCE 43000 SVSV44 SVSV22SVSV33 NotePCE 90 TCE 940000(FD)TCE 1000000 This is one interpretation only Other interpretations possible11-DCE lt15 PCE 15000PCE 1500012-DCE 30 14000 Estimated extent of plume has utilised groundwater11-DCE11-DCE 14000 12-DCE lt930 concentration data12-DCE lt930

                  All concentrations are in (μgmsup3) 12-DCE includes cis and trans

                  SVSV11 TCE 21000

                  FD = Field Duplicate resultPCE 21

                  11-DCE lt57

                  12-DCE lt76

                  12500 A3

                  0 25 50 m

                  CLIENT

                  SA EPA

                  PROJECT

                  EPA THEBARTON ASSESSMENT AREA - STAGE 1

                  TITLE

                  FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

                  PROJECT NO DATE CREATED

                  80607-1 290917

                  80607_Fig 7 - Soil Vapour TCE Concentration Plan - 3m r2ai REV 2 gt 290917

                  LE

                  VE

                  L 1

                  12

                  4 S

                  OU

                  TH

                  TE

                  RR

                  AC

                  E

                  AD

                  EL

                  AID

                  E S

                  A 5

                  00

                  0

                  PH

                  (0

                  8)

                  82

                  32

                  90

                  88

                  F

                  AX

                  (0

                  8)

                  82

                  32

                  90

                  99

                  E

                  MA

                  IL

                  info

                  fy

                  fec

                  om

                  au

                  W

                  EB

                  fy

                  fec

                  om

                  au

                  A

                  BN

                  5

                  7 0

                  08

                  116

                  13

                  0

                  • THEBARTON ASSESSMENT AREA STAGE 1 ENVIRONMENTAL ASSESSMENT FINAL REPORT | EPA REF 0524111 30 OCTOBER 2017 VOLUME 1 REPORT13
                  • This report is formatted to print Double Sided
                  • TITLE PAGE13
                  • CONTENTS13
                  • LIST OF ACRONYMS13
                  • EXECUTIVE SUMMARY13
                  • 1 INTRODUCTION
                    • 11 Purpose
                    • 12 General background information
                    • 13 Definition of the assessment area
                    • 14 Identification of contaminants of potential concern
                    • 15 Objectives
                      • 2 CHARACTERISATION OF THE ASSESSMENT AREA
                        • 21 Site identification
                        • 22 Regional geology and hydrogeology
                        • 23 Data quality objectives
                          • 3 SCOPE OF WORK
                            • 31 Preliminary work
                            • 32 Field investigation and laboratory analysis program
                            • 33 Data interpretation
                              • 4 METHODOLOGY
                                • 41 Field methodologies
                                • 42 Laboratory analysis
                                  • 5 QUALITY ASSURANCE AND QUALITY CONTROL
                                    • 51 Field QAQC
                                    • 52 Laboratory QAQC
                                    • 53 QAQC summary
                                      • 6 ASSESSMENT CRITERIA
                                        • 61 Groundwater
                                        • 62 Soil vapour
                                          • 7 RESULTS
                                            • 71 Surface and sub surface soil conditions
                                            • 72 Waterloo Membrane Samplerstrade
                                            • 73 Groundwater
                                            • 74 Soil vapour bores
                                              • 8 GROUNDWATER FATE AND TRANSPORT MODELLING
                                                • 81 Groundwater flow modelling
                                                • 82 Solute transport modelling
                                                  • 9 VAPOUR INTRUSION RISK ASSESSMENT
                                                    • 91 Objective
                                                    • 92 Areas of interest
                                                    • 93 Risk assessment approach
                                                    • 94 Tier 1 assessment
                                                    • 95 Tier 2 assessment
                                                    • 96 Conclusions
                                                      • 10 CONCEPTUAL SITE MODEL
                                                      • 11 CONCLUSIONS
                                                      • 12 DATA GAPS
                                                      • 13 REFERENCES
                                                      • 14 STATEMENT OF LIMITATIONS
                                                      • FIGURES13
                                                      • FIGURE 1 SITE LOCATION AND ASSESSMENT AREA
                                                      • FIGURE 2 ASSESSMENT POINT LOCATIONS
                                                      • FIGURE 3 WATERLOO MEMBRANE SAMPLERTM TCE CONCENTRATION PLAN13
                                                      • FIGURE 4 GROUNDWATER ELEVATION CONTOUR PLAN
                                                      • FIGURE 5 GROUNDWATER CONCENTRATION PLAN
                                                      • FIGURE 6 SOIL VAPOUR CONCENTRATION PLAN (10m)
                                                      • FIGURE 7 SOIL VAPOUR CONCENTRATION PLAN (30m)

                    top related