Ranking Light to Heavy Rare Earth Deposits Worldwide

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At the 2010 Prospector's and Developers Association of Canada (PDAC) Conference, David Lentz and Anthony Mariano gave a presentation on ranking and evaluating light to heavy rare earth deposits worldwide. This is that presentation.

Transcript

Ranking and evaluating light to heavy rare earth deposits worldwide

exploration considerations to economic assessment

Mushghi

Khudag

-

Mongolia

David Lentz amp Anthony N Mariano

Major Considerations

Assuming a favourable political climate and good logistics conditions determining the viability of deposits that can compete in the world market are as followshellip

1) Mineralogy and favourable lanthanide distribution

2) Grade and tonnage

3) Amenability to mining and mineral processing at low costs and successful chemical cracking of the individual lanthanides for their isolation

4) Acceptable low values of accompanying deleterious impurities

5) Minimum impact on the environment

Any lower production costs can significantly reduce the grade requirements

USGS facts

USGS facts

USGS facts

106 107 108 109 1010

Tonnes

of Ores

Gra

de (w

t)

01

10

10

100

Richardson amp Birkett

1996

GSCCarbonatites

Tonnes

of ore Richardson amp Birkett

1996

GSCPeralkalic

Richardson amp Birkett

1996

GSCPeralkalic

Tonnes

of ore Richardson amp Birkett

1996

GSC

Peralkalic

Kvanefjeld REE-U deposit Ilimaussaq Complex

bull

This new resource statement estimates the inventory of contained metal within

a 457 Mt

ore body to be 491 Mt

of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

Kvanefjeld REE-U deposit Ilimaussaq Complex

Kvanefjeld REE-U deposit

Model for Peralkalic Magma Systems

BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

Contact pegmatiteContact pegmatiteapliteaplite

EndograniticEndograniticpegmatitepegmatite

Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

WelsfordWelsford Dyke swarmsDyke swarms

Welsford

model

Marsh (1995)

Major Rare Earth Sources

Mineral

Composition

Occurrence

Bastnaumlsite

(Ce) (REE) CO3

F

Carbonatites

Monazite (Ce) (REE) PO4

Beach Sands Hydrothermal

Xenotime

(Y) (YREE) PO4

Beach Sands Hydrothermal

Loparite

(Ce) (REENaCa) (Ti NbTa)O3

Alkaline igneous massif

South China Clays (Ion-adsorbed REE+Y in Clays)

Uraninite

(REE and Y mdash

Released as dissolved elements

in rafinates

from uraninite)

Monazite pseudomorph

after apatite Monazite pseudomorph

after Rhabdophane

Florencite

pseudomorph

after pyrochlore Churchite

YPO4

middot2H2

O

Supergene Minerals ndash

MT Weld Australia

Apatite

with Substitutional

REE

Oka Quebec

Carbonatite

Nolanrsquos Bore Australia

Carbonatite

Mushgai

Khudag Mongolia

Carbonatite

Phalaborwa South Africa

Carbonatite

Kola Peninsula

Carbonatite

and Alkaline Massifs

Hoidas

Lake Saskatchewan

Hydrothermal in Granites

Mineville New York

Tailings from Magnetite Mining

Mineville may be the only Y and HREE dominant source currently known

HD -

176 mm HD -

44 mm

XPL MicrographsBastnaumlsite

in Carbonatite

Mountain Pass CA

BSE Image AncyliteHD ndash

07 mm

PPL Micrograph Ancylite

Ancylite

(Ce)

SrREE(CO3

)2

(OH)H2

O

LREE -

dominant ndash

50 wt REO

An exploration target in the

Bear Lodge Carbonatite

Complex of northeastern Wyoming

Red Wine Complex Labrador Dora Bay Alaska

Eudialyte

Na15

Ca6

(Fe2+Mn2+)3

Zr3

(SiNb)(Si25

O73

)(OOHH2

O)3

(CLOH)2

Eudialyite

may also contain Y and HREE

in amounts exceeding 4 wt The

mineral is easily dissolved in weak acids

but colloidal silica currently presents a

problem in the isolation of Y REE and Zr

oxides

Kipawa Quebec

Massive Britholite

(Ce) Oka Quebec

Britholite

(Ce) Concentrate from Skarn

Kipawa Quebec

Britholite

ndash

(REEYCa)5

(SiO4

PO4

)3

(OHF)

This mineral has the potential for occurring in ore quantities in skarn

associated with syenite

gneiss in Kipawa Quebec

Allanite

(Ce) (CeCaY)2

(AlFe2+Fe3+)3

(SiO4

)3

(OH)

Allanite

is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

Allanite

ndash

Hydrothermal Mountain Pass CA Allanite

ndash

Pegmatite Timmins Ontario

Eudialyte

and Mosandrite

in Peralkaline

Syenite

Kipawa Quebec

Britholite-Rich Skarn

All brown prisms are britholite

(Horizontal Distance ndash 46 mm)

Britholite

Concentrate

(mm scale)

Britholite

ndash

(CeYCa)5 (SiO4PO4 )3 (OHF)

Kipawa Quebec

Cathodoluminescence

Macrograph of Iimoriite

in Syenite

ndash

Bokan

Mountain

Mottled light blue and tan clusters -

Iimoriite

Red groundmass ndash

Feldspar

(Horizontal distance of rock slab ndash 46 mm)

Iimoriite

(Y)

Y2 (SiO4 )(CO3 )

Yttrofluorite

(CaY)F2

Iimoriite

Concentrate ndash

Bokan

MT (1 mm scale)

Wicheeda

Lake Heavy Mineral Composite mdash

(from samples 828951 52 53)

These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

As a final statement it should be emphasizedhellip

1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

Rare Earth Elements

bull

Name something of a misnomerndash

Rarest REEs

are over 200 times more

abundant then gold

bull

Variation in distribution for two reasons ndash

Compatibility with common rock forming materials

ndash

CosmicCrustal abundances

Crustal Abundances of Elements

Occurrencebull

REEs

occur mostly as

substitutional

impurities in many rock forming minerals

bull

Only a few the REE minerals have sufficient quantities to be considered important sources

bull

Defined as minerals having at least one site that is filled by REEs

andor Yttrium more often then any other elementMonazite

Rare Earth Minerals

bull

Form by primary crystalization

from magma or by hydrothermal reactions

bull

Found hosted in carbonate rocks in pegmatites

and as accessory minerals in

igneous rocks

bull

Stable REE minerals and can be concentrated in weathering zones

REE Mineralsbull

The most important REE minerals is bastnaumlsite

REE(CO3)F

bull

Other notable sources are ndash

Monazite REE(PO4) ndash

Xenotime

YPO4

bull

All may contain radioactive species such as thorium

and uraniumndash

are avoided as source materials

Bastnesitebull

Bastnasite

[(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

bull

Containing 60 to 70 rare earth oxides (REOs)

bull

REE site is most commonly filled by LREEs

and Y

Other REE mineralsbull

Monazite [(LREEYTh)PO4] ndash

Contains about 50ndash78 rare earth oxides

ndash

Forms in heavy mineral sands placer deposits associated with beach environments

bull

Xenotime

[(YPO4)] ndash

Contains 54ndash65 rare earth oxides

ndash

Yttrium Erbium and Cerium most common ndash

Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

Electron Configuration

bull

The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

bull

REEs

have same outer electronic configuration (+3) they differ in their number of 4f electrons

Electron Configuartion

REE Behaviorbull

Because of their shared behaviour REEs

tend to be

present in nature as a group All REEs

commonly substitute for one another in minerals

bull

Yet the REEs

are capable of showing great variation in their distributions

bull

Comes about due to ndash

Differences in ionic radius ndash

Crystal structure (Coordination Number)ndash

Basicity

of the mineral ndash

The elementrsquos solubility and ability to migrate in the environment ndash

Content of REEs

in source fluids

Ionic Radiusbull

The ionic radius of the REEs

is inversely related to atomic number

bull

The heavy rare earths are smaller ndash

more similar to Mn2+ (ionic radius 008 nanometers)

bull

LREEs

are largerndash

more comparable in size to Ca2+ (ionic radius 01 nanometer)

bull

Charge balance achieved through some sites being left vacant or

by coupled substitution with lower charged mineral (Na+)

In nanometers

Coordination Number

bull

Coordination number the number of atoms touching a particular atom in a crystal lattice

bull

Coordination number for this structure is 8

Coordination Numberbull

The heavy and light REEs

differ in the coordination

numbers (CN) with oxygenndash

HREEs

have CN between six to nine ndash

LREEs

have higher CNs

bull

Minerals with high CNs

associated with REE site

will favor LREEsndash

Bastnasite

CN = 11 ndash

Monazite CN = 9

bull

Those with low CNs

will preferentially select HREEs ndash

Xenotime

has a value of 8

Other Factorsbull

Minerals basicityndash

Alkalic

rocks host minerals with elevated LREE content ndash

Rocks with lower basicity

have lower amounts of LREEs

relative to their HREE content

bull

Solubilityndash

LREEs

are more soluble in water then the HREEsndash

Important characteristic for hydrothermally derived minerals

bull

MagmaHydrothermal fluid compositionndash

Minerals will take what they can get

REEs

and Economicsbull

The REEs

and Yttrium have a very broad range of applications mostly in high technology fields

bull

84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

bull

REEs

used primarily for automotive (25) petroleum (22) and metallurgic (20)

HREEs

and Magnetism

bull

HREEs

exhibit complex magnetic behaviour on account of electron structurendash

They share the same outer shell electron configuration (valence = +3)

ndash

Differ in number of 4f electrons

Applications in Magnetismbull

Terbium and

Dysprosium

bull

Components of Terfenol-D

alloy

with the formula Tb(03) Dy(07) Fe(19)

bull

Has the higher magnetostriction

then any other alloyndash

expands and contracts in magnetic field

bull

Developed by American Navy for sonar

systems ndash

Now has applications in magnetomechanical

sensors and other electronic devices

Applications in Magnetism

bull

Holmium

bull

Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

elements

bull

Creates the strongest artificially generated magnetic fieldsndash

In research where strong magnetic fields are needed

HREEs

and Nuclear Technology

bull

Dysprosium Homium Erbium

bull

High neutron

absorption cross-section ndash

Measure of probability of neutron capture

bull

Used in neutron-absorbing control rods in nuclear reactors

HREEs

and Nuclear Technology

bull

Lutetiumbull

Radioactive isotope used in radiometric dating

bull

Thulium bull

Stable thulium used as a radiation

source

in portable X-ray

devices

Mountain Passbull

Bastnasite

is the major REE mineral bull

High grade accessory mineral of igneous or hydrothermal originsbull

31 million tons of 886 by weight of rare earth oxides (REO) bull

Mining stopped in 1994 ndash

Thorium content of waste rock ndash

Availability of inexpensive REEs

from China

San Bernardino County

Bayan

Obobull

The worldrsquos primary source for both yttrium and the rare earth elements

bull

37 million tons of ore bull

Main REE source there is Bastnasite

World Production

Explorationbull

84 of REE imports to US are from China

bull

Increasing demand for high tech applications spurred increase in exploration in 2007

bull

Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

Lake as well as in

Malawi Africa

Environmental Considerations

bull

REE soil and food contaminationbull

Acid Mine Drainage and groundwater systems

bull

Radioactive elements

REE Fertilizerbull

In China REE enriched fertilizer has been used in crop fields since 1990

bull

At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

every year

bull

Research and agricultural practice that provides evidence that REEs

will improve crop quality an yield

bull

The ramifications environmental and human exposure to REEs

are not well understood

Investigation by T Liang et albull

Revealed that the average concentration of total REEs

in Chinese soil is

1768 mgkg ranging between 850 to 5227 mgkg

bull

In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

Implicationsbull

Human health effects not completely understood

bull

REE soil content shown to be detrimental to some plant speciesndash

100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

Acid Mine Drainage (AMD)bull

Rain waters contacts waste rock facilitating acid forming reactions

bull

Increases the capacity of the water to leach potentially harmful elements from waste piles

bull

Process mobilizes established ecotoxins

(lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

bull

Historically dismissed as minor environmental risk

Radioactive Elements

bull

REEs

associated with uranium and thorium

bull

Bastnesite 32 thorium

bull

Monazite sands 6 to 12 thorium oxide

bull

Ores containing radioactive elements are avoided as sources of REEs

Radioactive Hazardsbull

Mountain Pass

bull

Accidentsndash

In 1977 major pipeline break spilled over 2 million gallons of radioactive water

bull

Health Effectsndash

inflammatory bowel disease ndash

Prolonged seizures ndash

Cysts ndash

Cancers

bull

Waste Disposal ndash

Yucca Mountain

Summarybull

REE concentrations in the crust are rare

bull

Several geochemical factors influencing distribution including ionic radius and coordination number

bull

Main REE minerals are bastnasite monazite and xenotime

bull

Most important deposits are found at Bayan

Obo China and Mountain Pass USA

bull

Important electronic and nuclear applications

bull

Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

system contamination though acid mine drainage association with

radioactive elements

Referencesbull

E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

bull

Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

bull

G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

bull

B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

The Government of South Australia wwwpirsagovaubull

The US geological Survey Mineralsusgsgovbull

wwwelementsdatabasecombull

wwwastrolsaumichedu~cowleyintro2htmlbull

wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

webmineralcomdataMonazite-(Ce)shtmlbull

wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

wwwstevegbcomimagesscienceorbital_fillingpngbull

wwwchemicalelementscomelementseuhtmlbull

boomeriaorgchemlecturestextass2table10-9jpgbull

lostcontentquakecomfiles200802holmiumpngbull

chinageocitylocatorcomcitiesChinaQinghaibull

geowebrudruzal-Bayan-Obohtmbull

enwikipediaorgwikiSan_Bernardino_County_Californiabull

wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

enwikipediaorgwikiMonazitebull

webmineralcomdataBastnasite-(La)shtmlbull

wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

httpwwwavalonventurescombull

wwwnewsweekcomid43884bull

httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

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  • Slide Number 7
  • Slide Number 8
  • Slide Number 9
  • Slide Number 10
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Slide Number 15
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Slide Number 21
  • Slide Number 22
  • Slide Number 23
  • Slide Number 24
  • Slide Number 25
  • Slide Number 26
  • Slide Number 27
  • Slide Number 28
  • Slide Number 29
  • Slide Number 30
  • Slide Number 31
  • Slide Number 32
  • Slide Number 33
  • Slide Number 34
  • Slide Number 35
  • Slide Number 36
  • Slide Number 37
  • Slide Number 38
  • Slide Number 39
  • Slide Number 40
  • Slide Number 41
  • Slide Number 42
  • Slide Number 43
  • Slide Number 44
  • Slide Number 45
  • Slide Number 46
  • Slide Number 47
  • Slide Number 48
  • Slide Number 49
  • Slide Number 50
  • Slide Number 51
  • Rare Earth Elements
  • Crustal Abundances of Elements
  • Occurrence
  • Rare Earth Minerals
  • REE Minerals
  • Bastnesite
  • Other REE minerals
  • Electron Configuration
  • Electron Configuartion
  • REE Behavior
  • Ionic Radius
  • Coordination Number
  • Coordination Number
  • Other Factors
  • REEs and Economics
  • HREEs and Magnetism
  • Applications in Magnetism
  • Applications in Magnetism
  • HREEs and Nuclear Technology
  • HREEs and Nuclear Technology
  • Mountain Pass
  • Bayan Obo
  • World Production
  • Exploration
  • Environmental Considerations
  • REE Fertilizer
  • Investigation by T Liang et al
  • Implications
  • Acid Mine Drainage (AMD)
  • Radioactive Elements
  • Radioactive Hazards
  • Summary
  • References

    Major Considerations

    Assuming a favourable political climate and good logistics conditions determining the viability of deposits that can compete in the world market are as followshellip

    1) Mineralogy and favourable lanthanide distribution

    2) Grade and tonnage

    3) Amenability to mining and mineral processing at low costs and successful chemical cracking of the individual lanthanides for their isolation

    4) Acceptable low values of accompanying deleterious impurities

    5) Minimum impact on the environment

    Any lower production costs can significantly reduce the grade requirements

    USGS facts

    USGS facts

    USGS facts

    106 107 108 109 1010

    Tonnes

    of Ores

    Gra

    de (w

    t)

    01

    10

    10

    100

    Richardson amp Birkett

    1996

    GSCCarbonatites

    Tonnes

    of ore Richardson amp Birkett

    1996

    GSCPeralkalic

    Richardson amp Birkett

    1996

    GSCPeralkalic

    Tonnes

    of ore Richardson amp Birkett

    1996

    GSC

    Peralkalic

    Kvanefjeld REE-U deposit Ilimaussaq Complex

    bull

    This new resource statement estimates the inventory of contained metal within

    a 457 Mt

    ore body to be 491 Mt

    of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

    bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

    Kvanefjeld REE-U deposit Ilimaussaq Complex

    Kvanefjeld REE-U deposit

    Model for Peralkalic Magma Systems

    BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

    Contact pegmatiteContact pegmatiteapliteaplite

    EndograniticEndograniticpegmatitepegmatite

    Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

    APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

    WelsfordWelsford Dyke swarmsDyke swarms

    Welsford

    model

    Marsh (1995)

    Major Rare Earth Sources

    Mineral

    Composition

    Occurrence

    Bastnaumlsite

    (Ce) (REE) CO3

    F

    Carbonatites

    Monazite (Ce) (REE) PO4

    Beach Sands Hydrothermal

    Xenotime

    (Y) (YREE) PO4

    Beach Sands Hydrothermal

    Loparite

    (Ce) (REENaCa) (Ti NbTa)O3

    Alkaline igneous massif

    South China Clays (Ion-adsorbed REE+Y in Clays)

    Uraninite

    (REE and Y mdash

    Released as dissolved elements

    in rafinates

    from uraninite)

    Monazite pseudomorph

    after apatite Monazite pseudomorph

    after Rhabdophane

    Florencite

    pseudomorph

    after pyrochlore Churchite

    YPO4

    middot2H2

    O

    Supergene Minerals ndash

    MT Weld Australia

    Apatite

    with Substitutional

    REE

    Oka Quebec

    Carbonatite

    Nolanrsquos Bore Australia

    Carbonatite

    Mushgai

    Khudag Mongolia

    Carbonatite

    Phalaborwa South Africa

    Carbonatite

    Kola Peninsula

    Carbonatite

    and Alkaline Massifs

    Hoidas

    Lake Saskatchewan

    Hydrothermal in Granites

    Mineville New York

    Tailings from Magnetite Mining

    Mineville may be the only Y and HREE dominant source currently known

    HD -

    176 mm HD -

    44 mm

    XPL MicrographsBastnaumlsite

    in Carbonatite

    Mountain Pass CA

    BSE Image AncyliteHD ndash

    07 mm

    PPL Micrograph Ancylite

    Ancylite

    (Ce)

    SrREE(CO3

    )2

    (OH)H2

    O

    LREE -

    dominant ndash

    50 wt REO

    An exploration target in the

    Bear Lodge Carbonatite

    Complex of northeastern Wyoming

    Red Wine Complex Labrador Dora Bay Alaska

    Eudialyte

    Na15

    Ca6

    (Fe2+Mn2+)3

    Zr3

    (SiNb)(Si25

    O73

    )(OOHH2

    O)3

    (CLOH)2

    Eudialyite

    may also contain Y and HREE

    in amounts exceeding 4 wt The

    mineral is easily dissolved in weak acids

    but colloidal silica currently presents a

    problem in the isolation of Y REE and Zr

    oxides

    Kipawa Quebec

    Massive Britholite

    (Ce) Oka Quebec

    Britholite

    (Ce) Concentrate from Skarn

    Kipawa Quebec

    Britholite

    ndash

    (REEYCa)5

    (SiO4

    PO4

    )3

    (OHF)

    This mineral has the potential for occurring in ore quantities in skarn

    associated with syenite

    gneiss in Kipawa Quebec

    Allanite

    (Ce) (CeCaY)2

    (AlFe2+Fe3+)3

    (SiO4

    )3

    (OH)

    Allanite

    is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

    Allanite

    ndash

    Hydrothermal Mountain Pass CA Allanite

    ndash

    Pegmatite Timmins Ontario

    Eudialyte

    and Mosandrite

    in Peralkaline

    Syenite

    Kipawa Quebec

    Britholite-Rich Skarn

    All brown prisms are britholite

    (Horizontal Distance ndash 46 mm)

    Britholite

    Concentrate

    (mm scale)

    Britholite

    ndash

    (CeYCa)5 (SiO4PO4 )3 (OHF)

    Kipawa Quebec

    Cathodoluminescence

    Macrograph of Iimoriite

    in Syenite

    ndash

    Bokan

    Mountain

    Mottled light blue and tan clusters -

    Iimoriite

    Red groundmass ndash

    Feldspar

    (Horizontal distance of rock slab ndash 46 mm)

    Iimoriite

    (Y)

    Y2 (SiO4 )(CO3 )

    Yttrofluorite

    (CaY)F2

    Iimoriite

    Concentrate ndash

    Bokan

    MT (1 mm scale)

    Wicheeda

    Lake Heavy Mineral Composite mdash

    (from samples 828951 52 53)

    These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

    and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

    As a final statement it should be emphasizedhellip

    1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

    2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

    3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

    4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

    5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

    Rare Earth Elements

    bull

    Name something of a misnomerndash

    Rarest REEs

    are over 200 times more

    abundant then gold

    bull

    Variation in distribution for two reasons ndash

    Compatibility with common rock forming materials

    ndash

    CosmicCrustal abundances

    Crustal Abundances of Elements

    Occurrencebull

    REEs

    occur mostly as

    substitutional

    impurities in many rock forming minerals

    bull

    Only a few the REE minerals have sufficient quantities to be considered important sources

    bull

    Defined as minerals having at least one site that is filled by REEs

    andor Yttrium more often then any other elementMonazite

    Rare Earth Minerals

    bull

    Form by primary crystalization

    from magma or by hydrothermal reactions

    bull

    Found hosted in carbonate rocks in pegmatites

    and as accessory minerals in

    igneous rocks

    bull

    Stable REE minerals and can be concentrated in weathering zones

    REE Mineralsbull

    The most important REE minerals is bastnaumlsite

    REE(CO3)F

    bull

    Other notable sources are ndash

    Monazite REE(PO4) ndash

    Xenotime

    YPO4

    bull

    All may contain radioactive species such as thorium

    and uraniumndash

    are avoided as source materials

    Bastnesitebull

    Bastnasite

    [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

    bull

    Containing 60 to 70 rare earth oxides (REOs)

    bull

    REE site is most commonly filled by LREEs

    and Y

    Other REE mineralsbull

    Monazite [(LREEYTh)PO4] ndash

    Contains about 50ndash78 rare earth oxides

    ndash

    Forms in heavy mineral sands placer deposits associated with beach environments

    bull

    Xenotime

    [(YPO4)] ndash

    Contains 54ndash65 rare earth oxides

    ndash

    Yttrium Erbium and Cerium most common ndash

    Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

    Electron Configuration

    bull

    The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

    bull

    REEs

    have same outer electronic configuration (+3) they differ in their number of 4f electrons

    Electron Configuartion

    REE Behaviorbull

    Because of their shared behaviour REEs

    tend to be

    present in nature as a group All REEs

    commonly substitute for one another in minerals

    bull

    Yet the REEs

    are capable of showing great variation in their distributions

    bull

    Comes about due to ndash

    Differences in ionic radius ndash

    Crystal structure (Coordination Number)ndash

    Basicity

    of the mineral ndash

    The elementrsquos solubility and ability to migrate in the environment ndash

    Content of REEs

    in source fluids

    Ionic Radiusbull

    The ionic radius of the REEs

    is inversely related to atomic number

    bull

    The heavy rare earths are smaller ndash

    more similar to Mn2+ (ionic radius 008 nanometers)

    bull

    LREEs

    are largerndash

    more comparable in size to Ca2+ (ionic radius 01 nanometer)

    bull

    Charge balance achieved through some sites being left vacant or

    by coupled substitution with lower charged mineral (Na+)

    In nanometers

    Coordination Number

    bull

    Coordination number the number of atoms touching a particular atom in a crystal lattice

    bull

    Coordination number for this structure is 8

    Coordination Numberbull

    The heavy and light REEs

    differ in the coordination

    numbers (CN) with oxygenndash

    HREEs

    have CN between six to nine ndash

    LREEs

    have higher CNs

    bull

    Minerals with high CNs

    associated with REE site

    will favor LREEsndash

    Bastnasite

    CN = 11 ndash

    Monazite CN = 9

    bull

    Those with low CNs

    will preferentially select HREEs ndash

    Xenotime

    has a value of 8

    Other Factorsbull

    Minerals basicityndash

    Alkalic

    rocks host minerals with elevated LREE content ndash

    Rocks with lower basicity

    have lower amounts of LREEs

    relative to their HREE content

    bull

    Solubilityndash

    LREEs

    are more soluble in water then the HREEsndash

    Important characteristic for hydrothermally derived minerals

    bull

    MagmaHydrothermal fluid compositionndash

    Minerals will take what they can get

    REEs

    and Economicsbull

    The REEs

    and Yttrium have a very broad range of applications mostly in high technology fields

    bull

    84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

    bull

    REEs

    used primarily for automotive (25) petroleum (22) and metallurgic (20)

    HREEs

    and Magnetism

    bull

    HREEs

    exhibit complex magnetic behaviour on account of electron structurendash

    They share the same outer shell electron configuration (valence = +3)

    ndash

    Differ in number of 4f electrons

    Applications in Magnetismbull

    Terbium and

    Dysprosium

    bull

    Components of Terfenol-D

    alloy

    with the formula Tb(03) Dy(07) Fe(19)

    bull

    Has the higher magnetostriction

    then any other alloyndash

    expands and contracts in magnetic field

    bull

    Developed by American Navy for sonar

    systems ndash

    Now has applications in magnetomechanical

    sensors and other electronic devices

    Applications in Magnetism

    bull

    Holmium

    bull

    Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

    elements

    bull

    Creates the strongest artificially generated magnetic fieldsndash

    In research where strong magnetic fields are needed

    HREEs

    and Nuclear Technology

    bull

    Dysprosium Homium Erbium

    bull

    High neutron

    absorption cross-section ndash

    Measure of probability of neutron capture

    bull

    Used in neutron-absorbing control rods in nuclear reactors

    HREEs

    and Nuclear Technology

    bull

    Lutetiumbull

    Radioactive isotope used in radiometric dating

    bull

    Thulium bull

    Stable thulium used as a radiation

    source

    in portable X-ray

    devices

    Mountain Passbull

    Bastnasite

    is the major REE mineral bull

    High grade accessory mineral of igneous or hydrothermal originsbull

    31 million tons of 886 by weight of rare earth oxides (REO) bull

    Mining stopped in 1994 ndash

    Thorium content of waste rock ndash

    Availability of inexpensive REEs

    from China

    San Bernardino County

    Bayan

    Obobull

    The worldrsquos primary source for both yttrium and the rare earth elements

    bull

    37 million tons of ore bull

    Main REE source there is Bastnasite

    World Production

    Explorationbull

    84 of REE imports to US are from China

    bull

    Increasing demand for high tech applications spurred increase in exploration in 2007

    bull

    Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

    Lake as well as in

    Malawi Africa

    Environmental Considerations

    bull

    REE soil and food contaminationbull

    Acid Mine Drainage and groundwater systems

    bull

    Radioactive elements

    REE Fertilizerbull

    In China REE enriched fertilizer has been used in crop fields since 1990

    bull

    At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

    every year

    bull

    Research and agricultural practice that provides evidence that REEs

    will improve crop quality an yield

    bull

    The ramifications environmental and human exposure to REEs

    are not well understood

    Investigation by T Liang et albull

    Revealed that the average concentration of total REEs

    in Chinese soil is

    1768 mgkg ranging between 850 to 5227 mgkg

    bull

    In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

    Implicationsbull

    Human health effects not completely understood

    bull

    REE soil content shown to be detrimental to some plant speciesndash

    100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

    Acid Mine Drainage (AMD)bull

    Rain waters contacts waste rock facilitating acid forming reactions

    bull

    Increases the capacity of the water to leach potentially harmful elements from waste piles

    bull

    Process mobilizes established ecotoxins

    (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

    bull

    Historically dismissed as minor environmental risk

    Radioactive Elements

    bull

    REEs

    associated with uranium and thorium

    bull

    Bastnesite 32 thorium

    bull

    Monazite sands 6 to 12 thorium oxide

    bull

    Ores containing radioactive elements are avoided as sources of REEs

    Radioactive Hazardsbull

    Mountain Pass

    bull

    Accidentsndash

    In 1977 major pipeline break spilled over 2 million gallons of radioactive water

    bull

    Health Effectsndash

    inflammatory bowel disease ndash

    Prolonged seizures ndash

    Cysts ndash

    Cancers

    bull

    Waste Disposal ndash

    Yucca Mountain

    Summarybull

    REE concentrations in the crust are rare

    bull

    Several geochemical factors influencing distribution including ionic radius and coordination number

    bull

    Main REE minerals are bastnasite monazite and xenotime

    bull

    Most important deposits are found at Bayan

    Obo China and Mountain Pass USA

    bull

    Important electronic and nuclear applications

    bull

    Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

    system contamination though acid mine drainage association with

    radioactive elements

    Referencesbull

    E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

    bull

    Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

    bull

    G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

    bull

    B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

    The Government of South Australia wwwpirsagovaubull

    The US geological Survey Mineralsusgsgovbull

    wwwelementsdatabasecombull

    wwwastrolsaumichedu~cowleyintro2htmlbull

    wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

    webmineralcomdataMonazite-(Ce)shtmlbull

    wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

    wwwstevegbcomimagesscienceorbital_fillingpngbull

    wwwchemicalelementscomelementseuhtmlbull

    boomeriaorgchemlecturestextass2table10-9jpgbull

    lostcontentquakecomfiles200802holmiumpngbull

    chinageocitylocatorcomcitiesChinaQinghaibull

    geowebrudruzal-Bayan-Obohtmbull

    enwikipediaorgwikiSan_Bernardino_County_Californiabull

    wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

    enwikipediaorgwikiMonazitebull

    webmineralcomdataBastnasite-(La)shtmlbull

    wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

    httpwwwavalonventurescombull

    wwwnewsweekcomid43884bull

    httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

    httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

    • Slide Number 1
    • Slide Number 2
    • Slide Number 3
    • Slide Number 4
    • Slide Number 5
    • Slide Number 6
    • Slide Number 7
    • Slide Number 8
    • Slide Number 9
    • Slide Number 10
    • Slide Number 11
    • Slide Number 12
    • Slide Number 13
    • Slide Number 14
    • Slide Number 15
    • Slide Number 16
    • Slide Number 17
    • Slide Number 18
    • Slide Number 19
    • Slide Number 20
    • Slide Number 21
    • Slide Number 22
    • Slide Number 23
    • Slide Number 24
    • Slide Number 25
    • Slide Number 26
    • Slide Number 27
    • Slide Number 28
    • Slide Number 29
    • Slide Number 30
    • Slide Number 31
    • Slide Number 32
    • Slide Number 33
    • Slide Number 34
    • Slide Number 35
    • Slide Number 36
    • Slide Number 37
    • Slide Number 38
    • Slide Number 39
    • Slide Number 40
    • Slide Number 41
    • Slide Number 42
    • Slide Number 43
    • Slide Number 44
    • Slide Number 45
    • Slide Number 46
    • Slide Number 47
    • Slide Number 48
    • Slide Number 49
    • Slide Number 50
    • Slide Number 51
    • Rare Earth Elements
    • Crustal Abundances of Elements
    • Occurrence
    • Rare Earth Minerals
    • REE Minerals
    • Bastnesite
    • Other REE minerals
    • Electron Configuration
    • Electron Configuartion
    • REE Behavior
    • Ionic Radius
    • Coordination Number
    • Coordination Number
    • Other Factors
    • REEs and Economics
    • HREEs and Magnetism
    • Applications in Magnetism
    • Applications in Magnetism
    • HREEs and Nuclear Technology
    • HREEs and Nuclear Technology
    • Mountain Pass
    • Bayan Obo
    • World Production
    • Exploration
    • Environmental Considerations
    • REE Fertilizer
    • Investigation by T Liang et al
    • Implications
    • Acid Mine Drainage (AMD)
    • Radioactive Elements
    • Radioactive Hazards
    • Summary
    • References

      USGS facts

      USGS facts

      USGS facts

      106 107 108 109 1010

      Tonnes

      of Ores

      Gra

      de (w

      t)

      01

      10

      10

      100

      Richardson amp Birkett

      1996

      GSCCarbonatites

      Tonnes

      of ore Richardson amp Birkett

      1996

      GSCPeralkalic

      Richardson amp Birkett

      1996

      GSCPeralkalic

      Tonnes

      of ore Richardson amp Birkett

      1996

      GSC

      Peralkalic

      Kvanefjeld REE-U deposit Ilimaussaq Complex

      bull

      This new resource statement estimates the inventory of contained metal within

      a 457 Mt

      ore body to be 491 Mt

      of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

      bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

      Kvanefjeld REE-U deposit Ilimaussaq Complex

      Kvanefjeld REE-U deposit

      Model for Peralkalic Magma Systems

      BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

      Contact pegmatiteContact pegmatiteapliteaplite

      EndograniticEndograniticpegmatitepegmatite

      Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

      APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

      WelsfordWelsford Dyke swarmsDyke swarms

      Welsford

      model

      Marsh (1995)

      Major Rare Earth Sources

      Mineral

      Composition

      Occurrence

      Bastnaumlsite

      (Ce) (REE) CO3

      F

      Carbonatites

      Monazite (Ce) (REE) PO4

      Beach Sands Hydrothermal

      Xenotime

      (Y) (YREE) PO4

      Beach Sands Hydrothermal

      Loparite

      (Ce) (REENaCa) (Ti NbTa)O3

      Alkaline igneous massif

      South China Clays (Ion-adsorbed REE+Y in Clays)

      Uraninite

      (REE and Y mdash

      Released as dissolved elements

      in rafinates

      from uraninite)

      Monazite pseudomorph

      after apatite Monazite pseudomorph

      after Rhabdophane

      Florencite

      pseudomorph

      after pyrochlore Churchite

      YPO4

      middot2H2

      O

      Supergene Minerals ndash

      MT Weld Australia

      Apatite

      with Substitutional

      REE

      Oka Quebec

      Carbonatite

      Nolanrsquos Bore Australia

      Carbonatite

      Mushgai

      Khudag Mongolia

      Carbonatite

      Phalaborwa South Africa

      Carbonatite

      Kola Peninsula

      Carbonatite

      and Alkaline Massifs

      Hoidas

      Lake Saskatchewan

      Hydrothermal in Granites

      Mineville New York

      Tailings from Magnetite Mining

      Mineville may be the only Y and HREE dominant source currently known

      HD -

      176 mm HD -

      44 mm

      XPL MicrographsBastnaumlsite

      in Carbonatite

      Mountain Pass CA

      BSE Image AncyliteHD ndash

      07 mm

      PPL Micrograph Ancylite

      Ancylite

      (Ce)

      SrREE(CO3

      )2

      (OH)H2

      O

      LREE -

      dominant ndash

      50 wt REO

      An exploration target in the

      Bear Lodge Carbonatite

      Complex of northeastern Wyoming

      Red Wine Complex Labrador Dora Bay Alaska

      Eudialyte

      Na15

      Ca6

      (Fe2+Mn2+)3

      Zr3

      (SiNb)(Si25

      O73

      )(OOHH2

      O)3

      (CLOH)2

      Eudialyite

      may also contain Y and HREE

      in amounts exceeding 4 wt The

      mineral is easily dissolved in weak acids

      but colloidal silica currently presents a

      problem in the isolation of Y REE and Zr

      oxides

      Kipawa Quebec

      Massive Britholite

      (Ce) Oka Quebec

      Britholite

      (Ce) Concentrate from Skarn

      Kipawa Quebec

      Britholite

      ndash

      (REEYCa)5

      (SiO4

      PO4

      )3

      (OHF)

      This mineral has the potential for occurring in ore quantities in skarn

      associated with syenite

      gneiss in Kipawa Quebec

      Allanite

      (Ce) (CeCaY)2

      (AlFe2+Fe3+)3

      (SiO4

      )3

      (OH)

      Allanite

      is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

      Allanite

      ndash

      Hydrothermal Mountain Pass CA Allanite

      ndash

      Pegmatite Timmins Ontario

      Eudialyte

      and Mosandrite

      in Peralkaline

      Syenite

      Kipawa Quebec

      Britholite-Rich Skarn

      All brown prisms are britholite

      (Horizontal Distance ndash 46 mm)

      Britholite

      Concentrate

      (mm scale)

      Britholite

      ndash

      (CeYCa)5 (SiO4PO4 )3 (OHF)

      Kipawa Quebec

      Cathodoluminescence

      Macrograph of Iimoriite

      in Syenite

      ndash

      Bokan

      Mountain

      Mottled light blue and tan clusters -

      Iimoriite

      Red groundmass ndash

      Feldspar

      (Horizontal distance of rock slab ndash 46 mm)

      Iimoriite

      (Y)

      Y2 (SiO4 )(CO3 )

      Yttrofluorite

      (CaY)F2

      Iimoriite

      Concentrate ndash

      Bokan

      MT (1 mm scale)

      Wicheeda

      Lake Heavy Mineral Composite mdash

      (from samples 828951 52 53)

      These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

      and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

      As a final statement it should be emphasizedhellip

      1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

      2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

      3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

      4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

      5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

      Rare Earth Elements

      bull

      Name something of a misnomerndash

      Rarest REEs

      are over 200 times more

      abundant then gold

      bull

      Variation in distribution for two reasons ndash

      Compatibility with common rock forming materials

      ndash

      CosmicCrustal abundances

      Crustal Abundances of Elements

      Occurrencebull

      REEs

      occur mostly as

      substitutional

      impurities in many rock forming minerals

      bull

      Only a few the REE minerals have sufficient quantities to be considered important sources

      bull

      Defined as minerals having at least one site that is filled by REEs

      andor Yttrium more often then any other elementMonazite

      Rare Earth Minerals

      bull

      Form by primary crystalization

      from magma or by hydrothermal reactions

      bull

      Found hosted in carbonate rocks in pegmatites

      and as accessory minerals in

      igneous rocks

      bull

      Stable REE minerals and can be concentrated in weathering zones

      REE Mineralsbull

      The most important REE minerals is bastnaumlsite

      REE(CO3)F

      bull

      Other notable sources are ndash

      Monazite REE(PO4) ndash

      Xenotime

      YPO4

      bull

      All may contain radioactive species such as thorium

      and uraniumndash

      are avoided as source materials

      Bastnesitebull

      Bastnasite

      [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

      bull

      Containing 60 to 70 rare earth oxides (REOs)

      bull

      REE site is most commonly filled by LREEs

      and Y

      Other REE mineralsbull

      Monazite [(LREEYTh)PO4] ndash

      Contains about 50ndash78 rare earth oxides

      ndash

      Forms in heavy mineral sands placer deposits associated with beach environments

      bull

      Xenotime

      [(YPO4)] ndash

      Contains 54ndash65 rare earth oxides

      ndash

      Yttrium Erbium and Cerium most common ndash

      Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

      Electron Configuration

      bull

      The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

      bull

      REEs

      have same outer electronic configuration (+3) they differ in their number of 4f electrons

      Electron Configuartion

      REE Behaviorbull

      Because of their shared behaviour REEs

      tend to be

      present in nature as a group All REEs

      commonly substitute for one another in minerals

      bull

      Yet the REEs

      are capable of showing great variation in their distributions

      bull

      Comes about due to ndash

      Differences in ionic radius ndash

      Crystal structure (Coordination Number)ndash

      Basicity

      of the mineral ndash

      The elementrsquos solubility and ability to migrate in the environment ndash

      Content of REEs

      in source fluids

      Ionic Radiusbull

      The ionic radius of the REEs

      is inversely related to atomic number

      bull

      The heavy rare earths are smaller ndash

      more similar to Mn2+ (ionic radius 008 nanometers)

      bull

      LREEs

      are largerndash

      more comparable in size to Ca2+ (ionic radius 01 nanometer)

      bull

      Charge balance achieved through some sites being left vacant or

      by coupled substitution with lower charged mineral (Na+)

      In nanometers

      Coordination Number

      bull

      Coordination number the number of atoms touching a particular atom in a crystal lattice

      bull

      Coordination number for this structure is 8

      Coordination Numberbull

      The heavy and light REEs

      differ in the coordination

      numbers (CN) with oxygenndash

      HREEs

      have CN between six to nine ndash

      LREEs

      have higher CNs

      bull

      Minerals with high CNs

      associated with REE site

      will favor LREEsndash

      Bastnasite

      CN = 11 ndash

      Monazite CN = 9

      bull

      Those with low CNs

      will preferentially select HREEs ndash

      Xenotime

      has a value of 8

      Other Factorsbull

      Minerals basicityndash

      Alkalic

      rocks host minerals with elevated LREE content ndash

      Rocks with lower basicity

      have lower amounts of LREEs

      relative to their HREE content

      bull

      Solubilityndash

      LREEs

      are more soluble in water then the HREEsndash

      Important characteristic for hydrothermally derived minerals

      bull

      MagmaHydrothermal fluid compositionndash

      Minerals will take what they can get

      REEs

      and Economicsbull

      The REEs

      and Yttrium have a very broad range of applications mostly in high technology fields

      bull

      84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

      bull

      REEs

      used primarily for automotive (25) petroleum (22) and metallurgic (20)

      HREEs

      and Magnetism

      bull

      HREEs

      exhibit complex magnetic behaviour on account of electron structurendash

      They share the same outer shell electron configuration (valence = +3)

      ndash

      Differ in number of 4f electrons

      Applications in Magnetismbull

      Terbium and

      Dysprosium

      bull

      Components of Terfenol-D

      alloy

      with the formula Tb(03) Dy(07) Fe(19)

      bull

      Has the higher magnetostriction

      then any other alloyndash

      expands and contracts in magnetic field

      bull

      Developed by American Navy for sonar

      systems ndash

      Now has applications in magnetomechanical

      sensors and other electronic devices

      Applications in Magnetism

      bull

      Holmium

      bull

      Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

      elements

      bull

      Creates the strongest artificially generated magnetic fieldsndash

      In research where strong magnetic fields are needed

      HREEs

      and Nuclear Technology

      bull

      Dysprosium Homium Erbium

      bull

      High neutron

      absorption cross-section ndash

      Measure of probability of neutron capture

      bull

      Used in neutron-absorbing control rods in nuclear reactors

      HREEs

      and Nuclear Technology

      bull

      Lutetiumbull

      Radioactive isotope used in radiometric dating

      bull

      Thulium bull

      Stable thulium used as a radiation

      source

      in portable X-ray

      devices

      Mountain Passbull

      Bastnasite

      is the major REE mineral bull

      High grade accessory mineral of igneous or hydrothermal originsbull

      31 million tons of 886 by weight of rare earth oxides (REO) bull

      Mining stopped in 1994 ndash

      Thorium content of waste rock ndash

      Availability of inexpensive REEs

      from China

      San Bernardino County

      Bayan

      Obobull

      The worldrsquos primary source for both yttrium and the rare earth elements

      bull

      37 million tons of ore bull

      Main REE source there is Bastnasite

      World Production

      Explorationbull

      84 of REE imports to US are from China

      bull

      Increasing demand for high tech applications spurred increase in exploration in 2007

      bull

      Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

      Lake as well as in

      Malawi Africa

      Environmental Considerations

      bull

      REE soil and food contaminationbull

      Acid Mine Drainage and groundwater systems

      bull

      Radioactive elements

      REE Fertilizerbull

      In China REE enriched fertilizer has been used in crop fields since 1990

      bull

      At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

      every year

      bull

      Research and agricultural practice that provides evidence that REEs

      will improve crop quality an yield

      bull

      The ramifications environmental and human exposure to REEs

      are not well understood

      Investigation by T Liang et albull

      Revealed that the average concentration of total REEs

      in Chinese soil is

      1768 mgkg ranging between 850 to 5227 mgkg

      bull

      In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

      Implicationsbull

      Human health effects not completely understood

      bull

      REE soil content shown to be detrimental to some plant speciesndash

      100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

      Acid Mine Drainage (AMD)bull

      Rain waters contacts waste rock facilitating acid forming reactions

      bull

      Increases the capacity of the water to leach potentially harmful elements from waste piles

      bull

      Process mobilizes established ecotoxins

      (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

      bull

      Historically dismissed as minor environmental risk

      Radioactive Elements

      bull

      REEs

      associated with uranium and thorium

      bull

      Bastnesite 32 thorium

      bull

      Monazite sands 6 to 12 thorium oxide

      bull

      Ores containing radioactive elements are avoided as sources of REEs

      Radioactive Hazardsbull

      Mountain Pass

      bull

      Accidentsndash

      In 1977 major pipeline break spilled over 2 million gallons of radioactive water

      bull

      Health Effectsndash

      inflammatory bowel disease ndash

      Prolonged seizures ndash

      Cysts ndash

      Cancers

      bull

      Waste Disposal ndash

      Yucca Mountain

      Summarybull

      REE concentrations in the crust are rare

      bull

      Several geochemical factors influencing distribution including ionic radius and coordination number

      bull

      Main REE minerals are bastnasite monazite and xenotime

      bull

      Most important deposits are found at Bayan

      Obo China and Mountain Pass USA

      bull

      Important electronic and nuclear applications

      bull

      Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

      system contamination though acid mine drainage association with

      radioactive elements

      Referencesbull

      E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

      bull

      Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

      bull

      G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

      bull

      B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

      The Government of South Australia wwwpirsagovaubull

      The US geological Survey Mineralsusgsgovbull

      wwwelementsdatabasecombull

      wwwastrolsaumichedu~cowleyintro2htmlbull

      wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

      webmineralcomdataMonazite-(Ce)shtmlbull

      wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

      wwwstevegbcomimagesscienceorbital_fillingpngbull

      wwwchemicalelementscomelementseuhtmlbull

      boomeriaorgchemlecturestextass2table10-9jpgbull

      lostcontentquakecomfiles200802holmiumpngbull

      chinageocitylocatorcomcitiesChinaQinghaibull

      geowebrudruzal-Bayan-Obohtmbull

      enwikipediaorgwikiSan_Bernardino_County_Californiabull

      wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

      enwikipediaorgwikiMonazitebull

      webmineralcomdataBastnasite-(La)shtmlbull

      wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

      httpwwwavalonventurescombull

      wwwnewsweekcomid43884bull

      httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

      httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

      • Slide Number 1
      • Slide Number 2
      • Slide Number 3
      • Slide Number 4
      • Slide Number 5
      • Slide Number 6
      • Slide Number 7
      • Slide Number 8
      • Slide Number 9
      • Slide Number 10
      • Slide Number 11
      • Slide Number 12
      • Slide Number 13
      • Slide Number 14
      • Slide Number 15
      • Slide Number 16
      • Slide Number 17
      • Slide Number 18
      • Slide Number 19
      • Slide Number 20
      • Slide Number 21
      • Slide Number 22
      • Slide Number 23
      • Slide Number 24
      • Slide Number 25
      • Slide Number 26
      • Slide Number 27
      • Slide Number 28
      • Slide Number 29
      • Slide Number 30
      • Slide Number 31
      • Slide Number 32
      • Slide Number 33
      • Slide Number 34
      • Slide Number 35
      • Slide Number 36
      • Slide Number 37
      • Slide Number 38
      • Slide Number 39
      • Slide Number 40
      • Slide Number 41
      • Slide Number 42
      • Slide Number 43
      • Slide Number 44
      • Slide Number 45
      • Slide Number 46
      • Slide Number 47
      • Slide Number 48
      • Slide Number 49
      • Slide Number 50
      • Slide Number 51
      • Rare Earth Elements
      • Crustal Abundances of Elements
      • Occurrence
      • Rare Earth Minerals
      • REE Minerals
      • Bastnesite
      • Other REE minerals
      • Electron Configuration
      • Electron Configuartion
      • REE Behavior
      • Ionic Radius
      • Coordination Number
      • Coordination Number
      • Other Factors
      • REEs and Economics
      • HREEs and Magnetism
      • Applications in Magnetism
      • Applications in Magnetism
      • HREEs and Nuclear Technology
      • HREEs and Nuclear Technology
      • Mountain Pass
      • Bayan Obo
      • World Production
      • Exploration
      • Environmental Considerations
      • REE Fertilizer
      • Investigation by T Liang et al
      • Implications
      • Acid Mine Drainage (AMD)
      • Radioactive Elements
      • Radioactive Hazards
      • Summary
      • References

        USGS facts

        USGS facts

        106 107 108 109 1010

        Tonnes

        of Ores

        Gra

        de (w

        t)

        01

        10

        10

        100

        Richardson amp Birkett

        1996

        GSCCarbonatites

        Tonnes

        of ore Richardson amp Birkett

        1996

        GSCPeralkalic

        Richardson amp Birkett

        1996

        GSCPeralkalic

        Tonnes

        of ore Richardson amp Birkett

        1996

        GSC

        Peralkalic

        Kvanefjeld REE-U deposit Ilimaussaq Complex

        bull

        This new resource statement estimates the inventory of contained metal within

        a 457 Mt

        ore body to be 491 Mt

        of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

        bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

        Kvanefjeld REE-U deposit Ilimaussaq Complex

        Kvanefjeld REE-U deposit

        Model for Peralkalic Magma Systems

        BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

        Contact pegmatiteContact pegmatiteapliteaplite

        EndograniticEndograniticpegmatitepegmatite

        Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

        APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

        WelsfordWelsford Dyke swarmsDyke swarms

        Welsford

        model

        Marsh (1995)

        Major Rare Earth Sources

        Mineral

        Composition

        Occurrence

        Bastnaumlsite

        (Ce) (REE) CO3

        F

        Carbonatites

        Monazite (Ce) (REE) PO4

        Beach Sands Hydrothermal

        Xenotime

        (Y) (YREE) PO4

        Beach Sands Hydrothermal

        Loparite

        (Ce) (REENaCa) (Ti NbTa)O3

        Alkaline igneous massif

        South China Clays (Ion-adsorbed REE+Y in Clays)

        Uraninite

        (REE and Y mdash

        Released as dissolved elements

        in rafinates

        from uraninite)

        Monazite pseudomorph

        after apatite Monazite pseudomorph

        after Rhabdophane

        Florencite

        pseudomorph

        after pyrochlore Churchite

        YPO4

        middot2H2

        O

        Supergene Minerals ndash

        MT Weld Australia

        Apatite

        with Substitutional

        REE

        Oka Quebec

        Carbonatite

        Nolanrsquos Bore Australia

        Carbonatite

        Mushgai

        Khudag Mongolia

        Carbonatite

        Phalaborwa South Africa

        Carbonatite

        Kola Peninsula

        Carbonatite

        and Alkaline Massifs

        Hoidas

        Lake Saskatchewan

        Hydrothermal in Granites

        Mineville New York

        Tailings from Magnetite Mining

        Mineville may be the only Y and HREE dominant source currently known

        HD -

        176 mm HD -

        44 mm

        XPL MicrographsBastnaumlsite

        in Carbonatite

        Mountain Pass CA

        BSE Image AncyliteHD ndash

        07 mm

        PPL Micrograph Ancylite

        Ancylite

        (Ce)

        SrREE(CO3

        )2

        (OH)H2

        O

        LREE -

        dominant ndash

        50 wt REO

        An exploration target in the

        Bear Lodge Carbonatite

        Complex of northeastern Wyoming

        Red Wine Complex Labrador Dora Bay Alaska

        Eudialyte

        Na15

        Ca6

        (Fe2+Mn2+)3

        Zr3

        (SiNb)(Si25

        O73

        )(OOHH2

        O)3

        (CLOH)2

        Eudialyite

        may also contain Y and HREE

        in amounts exceeding 4 wt The

        mineral is easily dissolved in weak acids

        but colloidal silica currently presents a

        problem in the isolation of Y REE and Zr

        oxides

        Kipawa Quebec

        Massive Britholite

        (Ce) Oka Quebec

        Britholite

        (Ce) Concentrate from Skarn

        Kipawa Quebec

        Britholite

        ndash

        (REEYCa)5

        (SiO4

        PO4

        )3

        (OHF)

        This mineral has the potential for occurring in ore quantities in skarn

        associated with syenite

        gneiss in Kipawa Quebec

        Allanite

        (Ce) (CeCaY)2

        (AlFe2+Fe3+)3

        (SiO4

        )3

        (OH)

        Allanite

        is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

        Allanite

        ndash

        Hydrothermal Mountain Pass CA Allanite

        ndash

        Pegmatite Timmins Ontario

        Eudialyte

        and Mosandrite

        in Peralkaline

        Syenite

        Kipawa Quebec

        Britholite-Rich Skarn

        All brown prisms are britholite

        (Horizontal Distance ndash 46 mm)

        Britholite

        Concentrate

        (mm scale)

        Britholite

        ndash

        (CeYCa)5 (SiO4PO4 )3 (OHF)

        Kipawa Quebec

        Cathodoluminescence

        Macrograph of Iimoriite

        in Syenite

        ndash

        Bokan

        Mountain

        Mottled light blue and tan clusters -

        Iimoriite

        Red groundmass ndash

        Feldspar

        (Horizontal distance of rock slab ndash 46 mm)

        Iimoriite

        (Y)

        Y2 (SiO4 )(CO3 )

        Yttrofluorite

        (CaY)F2

        Iimoriite

        Concentrate ndash

        Bokan

        MT (1 mm scale)

        Wicheeda

        Lake Heavy Mineral Composite mdash

        (from samples 828951 52 53)

        These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

        and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

        As a final statement it should be emphasizedhellip

        1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

        2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

        3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

        4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

        5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

        Rare Earth Elements

        bull

        Name something of a misnomerndash

        Rarest REEs

        are over 200 times more

        abundant then gold

        bull

        Variation in distribution for two reasons ndash

        Compatibility with common rock forming materials

        ndash

        CosmicCrustal abundances

        Crustal Abundances of Elements

        Occurrencebull

        REEs

        occur mostly as

        substitutional

        impurities in many rock forming minerals

        bull

        Only a few the REE minerals have sufficient quantities to be considered important sources

        bull

        Defined as minerals having at least one site that is filled by REEs

        andor Yttrium more often then any other elementMonazite

        Rare Earth Minerals

        bull

        Form by primary crystalization

        from magma or by hydrothermal reactions

        bull

        Found hosted in carbonate rocks in pegmatites

        and as accessory minerals in

        igneous rocks

        bull

        Stable REE minerals and can be concentrated in weathering zones

        REE Mineralsbull

        The most important REE minerals is bastnaumlsite

        REE(CO3)F

        bull

        Other notable sources are ndash

        Monazite REE(PO4) ndash

        Xenotime

        YPO4

        bull

        All may contain radioactive species such as thorium

        and uraniumndash

        are avoided as source materials

        Bastnesitebull

        Bastnasite

        [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

        bull

        Containing 60 to 70 rare earth oxides (REOs)

        bull

        REE site is most commonly filled by LREEs

        and Y

        Other REE mineralsbull

        Monazite [(LREEYTh)PO4] ndash

        Contains about 50ndash78 rare earth oxides

        ndash

        Forms in heavy mineral sands placer deposits associated with beach environments

        bull

        Xenotime

        [(YPO4)] ndash

        Contains 54ndash65 rare earth oxides

        ndash

        Yttrium Erbium and Cerium most common ndash

        Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

        Electron Configuration

        bull

        The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

        bull

        REEs

        have same outer electronic configuration (+3) they differ in their number of 4f electrons

        Electron Configuartion

        REE Behaviorbull

        Because of their shared behaviour REEs

        tend to be

        present in nature as a group All REEs

        commonly substitute for one another in minerals

        bull

        Yet the REEs

        are capable of showing great variation in their distributions

        bull

        Comes about due to ndash

        Differences in ionic radius ndash

        Crystal structure (Coordination Number)ndash

        Basicity

        of the mineral ndash

        The elementrsquos solubility and ability to migrate in the environment ndash

        Content of REEs

        in source fluids

        Ionic Radiusbull

        The ionic radius of the REEs

        is inversely related to atomic number

        bull

        The heavy rare earths are smaller ndash

        more similar to Mn2+ (ionic radius 008 nanometers)

        bull

        LREEs

        are largerndash

        more comparable in size to Ca2+ (ionic radius 01 nanometer)

        bull

        Charge balance achieved through some sites being left vacant or

        by coupled substitution with lower charged mineral (Na+)

        In nanometers

        Coordination Number

        bull

        Coordination number the number of atoms touching a particular atom in a crystal lattice

        bull

        Coordination number for this structure is 8

        Coordination Numberbull

        The heavy and light REEs

        differ in the coordination

        numbers (CN) with oxygenndash

        HREEs

        have CN between six to nine ndash

        LREEs

        have higher CNs

        bull

        Minerals with high CNs

        associated with REE site

        will favor LREEsndash

        Bastnasite

        CN = 11 ndash

        Monazite CN = 9

        bull

        Those with low CNs

        will preferentially select HREEs ndash

        Xenotime

        has a value of 8

        Other Factorsbull

        Minerals basicityndash

        Alkalic

        rocks host minerals with elevated LREE content ndash

        Rocks with lower basicity

        have lower amounts of LREEs

        relative to their HREE content

        bull

        Solubilityndash

        LREEs

        are more soluble in water then the HREEsndash

        Important characteristic for hydrothermally derived minerals

        bull

        MagmaHydrothermal fluid compositionndash

        Minerals will take what they can get

        REEs

        and Economicsbull

        The REEs

        and Yttrium have a very broad range of applications mostly in high technology fields

        bull

        84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

        bull

        REEs

        used primarily for automotive (25) petroleum (22) and metallurgic (20)

        HREEs

        and Magnetism

        bull

        HREEs

        exhibit complex magnetic behaviour on account of electron structurendash

        They share the same outer shell electron configuration (valence = +3)

        ndash

        Differ in number of 4f electrons

        Applications in Magnetismbull

        Terbium and

        Dysprosium

        bull

        Components of Terfenol-D

        alloy

        with the formula Tb(03) Dy(07) Fe(19)

        bull

        Has the higher magnetostriction

        then any other alloyndash

        expands and contracts in magnetic field

        bull

        Developed by American Navy for sonar

        systems ndash

        Now has applications in magnetomechanical

        sensors and other electronic devices

        Applications in Magnetism

        bull

        Holmium

        bull

        Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

        elements

        bull

        Creates the strongest artificially generated magnetic fieldsndash

        In research where strong magnetic fields are needed

        HREEs

        and Nuclear Technology

        bull

        Dysprosium Homium Erbium

        bull

        High neutron

        absorption cross-section ndash

        Measure of probability of neutron capture

        bull

        Used in neutron-absorbing control rods in nuclear reactors

        HREEs

        and Nuclear Technology

        bull

        Lutetiumbull

        Radioactive isotope used in radiometric dating

        bull

        Thulium bull

        Stable thulium used as a radiation

        source

        in portable X-ray

        devices

        Mountain Passbull

        Bastnasite

        is the major REE mineral bull

        High grade accessory mineral of igneous or hydrothermal originsbull

        31 million tons of 886 by weight of rare earth oxides (REO) bull

        Mining stopped in 1994 ndash

        Thorium content of waste rock ndash

        Availability of inexpensive REEs

        from China

        San Bernardino County

        Bayan

        Obobull

        The worldrsquos primary source for both yttrium and the rare earth elements

        bull

        37 million tons of ore bull

        Main REE source there is Bastnasite

        World Production

        Explorationbull

        84 of REE imports to US are from China

        bull

        Increasing demand for high tech applications spurred increase in exploration in 2007

        bull

        Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

        Lake as well as in

        Malawi Africa

        Environmental Considerations

        bull

        REE soil and food contaminationbull

        Acid Mine Drainage and groundwater systems

        bull

        Radioactive elements

        REE Fertilizerbull

        In China REE enriched fertilizer has been used in crop fields since 1990

        bull

        At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

        every year

        bull

        Research and agricultural practice that provides evidence that REEs

        will improve crop quality an yield

        bull

        The ramifications environmental and human exposure to REEs

        are not well understood

        Investigation by T Liang et albull

        Revealed that the average concentration of total REEs

        in Chinese soil is

        1768 mgkg ranging between 850 to 5227 mgkg

        bull

        In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

        Implicationsbull

        Human health effects not completely understood

        bull

        REE soil content shown to be detrimental to some plant speciesndash

        100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

        Acid Mine Drainage (AMD)bull

        Rain waters contacts waste rock facilitating acid forming reactions

        bull

        Increases the capacity of the water to leach potentially harmful elements from waste piles

        bull

        Process mobilizes established ecotoxins

        (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

        bull

        Historically dismissed as minor environmental risk

        Radioactive Elements

        bull

        REEs

        associated with uranium and thorium

        bull

        Bastnesite 32 thorium

        bull

        Monazite sands 6 to 12 thorium oxide

        bull

        Ores containing radioactive elements are avoided as sources of REEs

        Radioactive Hazardsbull

        Mountain Pass

        bull

        Accidentsndash

        In 1977 major pipeline break spilled over 2 million gallons of radioactive water

        bull

        Health Effectsndash

        inflammatory bowel disease ndash

        Prolonged seizures ndash

        Cysts ndash

        Cancers

        bull

        Waste Disposal ndash

        Yucca Mountain

        Summarybull

        REE concentrations in the crust are rare

        bull

        Several geochemical factors influencing distribution including ionic radius and coordination number

        bull

        Main REE minerals are bastnasite monazite and xenotime

        bull

        Most important deposits are found at Bayan

        Obo China and Mountain Pass USA

        bull

        Important electronic and nuclear applications

        bull

        Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

        system contamination though acid mine drainage association with

        radioactive elements

        Referencesbull

        E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

        bull

        Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

        bull

        G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

        bull

        B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

        The Government of South Australia wwwpirsagovaubull

        The US geological Survey Mineralsusgsgovbull

        wwwelementsdatabasecombull

        wwwastrolsaumichedu~cowleyintro2htmlbull

        wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

        webmineralcomdataMonazite-(Ce)shtmlbull

        wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

        wwwstevegbcomimagesscienceorbital_fillingpngbull

        wwwchemicalelementscomelementseuhtmlbull

        boomeriaorgchemlecturestextass2table10-9jpgbull

        lostcontentquakecomfiles200802holmiumpngbull

        chinageocitylocatorcomcitiesChinaQinghaibull

        geowebrudruzal-Bayan-Obohtmbull

        enwikipediaorgwikiSan_Bernardino_County_Californiabull

        wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

        enwikipediaorgwikiMonazitebull

        webmineralcomdataBastnasite-(La)shtmlbull

        wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

        httpwwwavalonventurescombull

        wwwnewsweekcomid43884bull

        httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

        httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

        • Slide Number 1
        • Slide Number 2
        • Slide Number 3
        • Slide Number 4
        • Slide Number 5
        • Slide Number 6
        • Slide Number 7
        • Slide Number 8
        • Slide Number 9
        • Slide Number 10
        • Slide Number 11
        • Slide Number 12
        • Slide Number 13
        • Slide Number 14
        • Slide Number 15
        • Slide Number 16
        • Slide Number 17
        • Slide Number 18
        • Slide Number 19
        • Slide Number 20
        • Slide Number 21
        • Slide Number 22
        • Slide Number 23
        • Slide Number 24
        • Slide Number 25
        • Slide Number 26
        • Slide Number 27
        • Slide Number 28
        • Slide Number 29
        • Slide Number 30
        • Slide Number 31
        • Slide Number 32
        • Slide Number 33
        • Slide Number 34
        • Slide Number 35
        • Slide Number 36
        • Slide Number 37
        • Slide Number 38
        • Slide Number 39
        • Slide Number 40
        • Slide Number 41
        • Slide Number 42
        • Slide Number 43
        • Slide Number 44
        • Slide Number 45
        • Slide Number 46
        • Slide Number 47
        • Slide Number 48
        • Slide Number 49
        • Slide Number 50
        • Slide Number 51
        • Rare Earth Elements
        • Crustal Abundances of Elements
        • Occurrence
        • Rare Earth Minerals
        • REE Minerals
        • Bastnesite
        • Other REE minerals
        • Electron Configuration
        • Electron Configuartion
        • REE Behavior
        • Ionic Radius
        • Coordination Number
        • Coordination Number
        • Other Factors
        • REEs and Economics
        • HREEs and Magnetism
        • Applications in Magnetism
        • Applications in Magnetism
        • HREEs and Nuclear Technology
        • HREEs and Nuclear Technology
        • Mountain Pass
        • Bayan Obo
        • World Production
        • Exploration
        • Environmental Considerations
        • REE Fertilizer
        • Investigation by T Liang et al
        • Implications
        • Acid Mine Drainage (AMD)
        • Radioactive Elements
        • Radioactive Hazards
        • Summary
        • References

          USGS facts

          106 107 108 109 1010

          Tonnes

          of Ores

          Gra

          de (w

          t)

          01

          10

          10

          100

          Richardson amp Birkett

          1996

          GSCCarbonatites

          Tonnes

          of ore Richardson amp Birkett

          1996

          GSCPeralkalic

          Richardson amp Birkett

          1996

          GSCPeralkalic

          Tonnes

          of ore Richardson amp Birkett

          1996

          GSC

          Peralkalic

          Kvanefjeld REE-U deposit Ilimaussaq Complex

          bull

          This new resource statement estimates the inventory of contained metal within

          a 457 Mt

          ore body to be 491 Mt

          of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

          bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

          Kvanefjeld REE-U deposit Ilimaussaq Complex

          Kvanefjeld REE-U deposit

          Model for Peralkalic Magma Systems

          BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

          Contact pegmatiteContact pegmatiteapliteaplite

          EndograniticEndograniticpegmatitepegmatite

          Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

          APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

          WelsfordWelsford Dyke swarmsDyke swarms

          Welsford

          model

          Marsh (1995)

          Major Rare Earth Sources

          Mineral

          Composition

          Occurrence

          Bastnaumlsite

          (Ce) (REE) CO3

          F

          Carbonatites

          Monazite (Ce) (REE) PO4

          Beach Sands Hydrothermal

          Xenotime

          (Y) (YREE) PO4

          Beach Sands Hydrothermal

          Loparite

          (Ce) (REENaCa) (Ti NbTa)O3

          Alkaline igneous massif

          South China Clays (Ion-adsorbed REE+Y in Clays)

          Uraninite

          (REE and Y mdash

          Released as dissolved elements

          in rafinates

          from uraninite)

          Monazite pseudomorph

          after apatite Monazite pseudomorph

          after Rhabdophane

          Florencite

          pseudomorph

          after pyrochlore Churchite

          YPO4

          middot2H2

          O

          Supergene Minerals ndash

          MT Weld Australia

          Apatite

          with Substitutional

          REE

          Oka Quebec

          Carbonatite

          Nolanrsquos Bore Australia

          Carbonatite

          Mushgai

          Khudag Mongolia

          Carbonatite

          Phalaborwa South Africa

          Carbonatite

          Kola Peninsula

          Carbonatite

          and Alkaline Massifs

          Hoidas

          Lake Saskatchewan

          Hydrothermal in Granites

          Mineville New York

          Tailings from Magnetite Mining

          Mineville may be the only Y and HREE dominant source currently known

          HD -

          176 mm HD -

          44 mm

          XPL MicrographsBastnaumlsite

          in Carbonatite

          Mountain Pass CA

          BSE Image AncyliteHD ndash

          07 mm

          PPL Micrograph Ancylite

          Ancylite

          (Ce)

          SrREE(CO3

          )2

          (OH)H2

          O

          LREE -

          dominant ndash

          50 wt REO

          An exploration target in the

          Bear Lodge Carbonatite

          Complex of northeastern Wyoming

          Red Wine Complex Labrador Dora Bay Alaska

          Eudialyte

          Na15

          Ca6

          (Fe2+Mn2+)3

          Zr3

          (SiNb)(Si25

          O73

          )(OOHH2

          O)3

          (CLOH)2

          Eudialyite

          may also contain Y and HREE

          in amounts exceeding 4 wt The

          mineral is easily dissolved in weak acids

          but colloidal silica currently presents a

          problem in the isolation of Y REE and Zr

          oxides

          Kipawa Quebec

          Massive Britholite

          (Ce) Oka Quebec

          Britholite

          (Ce) Concentrate from Skarn

          Kipawa Quebec

          Britholite

          ndash

          (REEYCa)5

          (SiO4

          PO4

          )3

          (OHF)

          This mineral has the potential for occurring in ore quantities in skarn

          associated with syenite

          gneiss in Kipawa Quebec

          Allanite

          (Ce) (CeCaY)2

          (AlFe2+Fe3+)3

          (SiO4

          )3

          (OH)

          Allanite

          is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

          Allanite

          ndash

          Hydrothermal Mountain Pass CA Allanite

          ndash

          Pegmatite Timmins Ontario

          Eudialyte

          and Mosandrite

          in Peralkaline

          Syenite

          Kipawa Quebec

          Britholite-Rich Skarn

          All brown prisms are britholite

          (Horizontal Distance ndash 46 mm)

          Britholite

          Concentrate

          (mm scale)

          Britholite

          ndash

          (CeYCa)5 (SiO4PO4 )3 (OHF)

          Kipawa Quebec

          Cathodoluminescence

          Macrograph of Iimoriite

          in Syenite

          ndash

          Bokan

          Mountain

          Mottled light blue and tan clusters -

          Iimoriite

          Red groundmass ndash

          Feldspar

          (Horizontal distance of rock slab ndash 46 mm)

          Iimoriite

          (Y)

          Y2 (SiO4 )(CO3 )

          Yttrofluorite

          (CaY)F2

          Iimoriite

          Concentrate ndash

          Bokan

          MT (1 mm scale)

          Wicheeda

          Lake Heavy Mineral Composite mdash

          (from samples 828951 52 53)

          These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

          and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

          As a final statement it should be emphasizedhellip

          1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

          2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

          3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

          4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

          5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

          Rare Earth Elements

          bull

          Name something of a misnomerndash

          Rarest REEs

          are over 200 times more

          abundant then gold

          bull

          Variation in distribution for two reasons ndash

          Compatibility with common rock forming materials

          ndash

          CosmicCrustal abundances

          Crustal Abundances of Elements

          Occurrencebull

          REEs

          occur mostly as

          substitutional

          impurities in many rock forming minerals

          bull

          Only a few the REE minerals have sufficient quantities to be considered important sources

          bull

          Defined as minerals having at least one site that is filled by REEs

          andor Yttrium more often then any other elementMonazite

          Rare Earth Minerals

          bull

          Form by primary crystalization

          from magma or by hydrothermal reactions

          bull

          Found hosted in carbonate rocks in pegmatites

          and as accessory minerals in

          igneous rocks

          bull

          Stable REE minerals and can be concentrated in weathering zones

          REE Mineralsbull

          The most important REE minerals is bastnaumlsite

          REE(CO3)F

          bull

          Other notable sources are ndash

          Monazite REE(PO4) ndash

          Xenotime

          YPO4

          bull

          All may contain radioactive species such as thorium

          and uraniumndash

          are avoided as source materials

          Bastnesitebull

          Bastnasite

          [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

          bull

          Containing 60 to 70 rare earth oxides (REOs)

          bull

          REE site is most commonly filled by LREEs

          and Y

          Other REE mineralsbull

          Monazite [(LREEYTh)PO4] ndash

          Contains about 50ndash78 rare earth oxides

          ndash

          Forms in heavy mineral sands placer deposits associated with beach environments

          bull

          Xenotime

          [(YPO4)] ndash

          Contains 54ndash65 rare earth oxides

          ndash

          Yttrium Erbium and Cerium most common ndash

          Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

          Electron Configuration

          bull

          The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

          bull

          REEs

          have same outer electronic configuration (+3) they differ in their number of 4f electrons

          Electron Configuartion

          REE Behaviorbull

          Because of their shared behaviour REEs

          tend to be

          present in nature as a group All REEs

          commonly substitute for one another in minerals

          bull

          Yet the REEs

          are capable of showing great variation in their distributions

          bull

          Comes about due to ndash

          Differences in ionic radius ndash

          Crystal structure (Coordination Number)ndash

          Basicity

          of the mineral ndash

          The elementrsquos solubility and ability to migrate in the environment ndash

          Content of REEs

          in source fluids

          Ionic Radiusbull

          The ionic radius of the REEs

          is inversely related to atomic number

          bull

          The heavy rare earths are smaller ndash

          more similar to Mn2+ (ionic radius 008 nanometers)

          bull

          LREEs

          are largerndash

          more comparable in size to Ca2+ (ionic radius 01 nanometer)

          bull

          Charge balance achieved through some sites being left vacant or

          by coupled substitution with lower charged mineral (Na+)

          In nanometers

          Coordination Number

          bull

          Coordination number the number of atoms touching a particular atom in a crystal lattice

          bull

          Coordination number for this structure is 8

          Coordination Numberbull

          The heavy and light REEs

          differ in the coordination

          numbers (CN) with oxygenndash

          HREEs

          have CN between six to nine ndash

          LREEs

          have higher CNs

          bull

          Minerals with high CNs

          associated with REE site

          will favor LREEsndash

          Bastnasite

          CN = 11 ndash

          Monazite CN = 9

          bull

          Those with low CNs

          will preferentially select HREEs ndash

          Xenotime

          has a value of 8

          Other Factorsbull

          Minerals basicityndash

          Alkalic

          rocks host minerals with elevated LREE content ndash

          Rocks with lower basicity

          have lower amounts of LREEs

          relative to their HREE content

          bull

          Solubilityndash

          LREEs

          are more soluble in water then the HREEsndash

          Important characteristic for hydrothermally derived minerals

          bull

          MagmaHydrothermal fluid compositionndash

          Minerals will take what they can get

          REEs

          and Economicsbull

          The REEs

          and Yttrium have a very broad range of applications mostly in high technology fields

          bull

          84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

          bull

          REEs

          used primarily for automotive (25) petroleum (22) and metallurgic (20)

          HREEs

          and Magnetism

          bull

          HREEs

          exhibit complex magnetic behaviour on account of electron structurendash

          They share the same outer shell electron configuration (valence = +3)

          ndash

          Differ in number of 4f electrons

          Applications in Magnetismbull

          Terbium and

          Dysprosium

          bull

          Components of Terfenol-D

          alloy

          with the formula Tb(03) Dy(07) Fe(19)

          bull

          Has the higher magnetostriction

          then any other alloyndash

          expands and contracts in magnetic field

          bull

          Developed by American Navy for sonar

          systems ndash

          Now has applications in magnetomechanical

          sensors and other electronic devices

          Applications in Magnetism

          bull

          Holmium

          bull

          Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

          elements

          bull

          Creates the strongest artificially generated magnetic fieldsndash

          In research where strong magnetic fields are needed

          HREEs

          and Nuclear Technology

          bull

          Dysprosium Homium Erbium

          bull

          High neutron

          absorption cross-section ndash

          Measure of probability of neutron capture

          bull

          Used in neutron-absorbing control rods in nuclear reactors

          HREEs

          and Nuclear Technology

          bull

          Lutetiumbull

          Radioactive isotope used in radiometric dating

          bull

          Thulium bull

          Stable thulium used as a radiation

          source

          in portable X-ray

          devices

          Mountain Passbull

          Bastnasite

          is the major REE mineral bull

          High grade accessory mineral of igneous or hydrothermal originsbull

          31 million tons of 886 by weight of rare earth oxides (REO) bull

          Mining stopped in 1994 ndash

          Thorium content of waste rock ndash

          Availability of inexpensive REEs

          from China

          San Bernardino County

          Bayan

          Obobull

          The worldrsquos primary source for both yttrium and the rare earth elements

          bull

          37 million tons of ore bull

          Main REE source there is Bastnasite

          World Production

          Explorationbull

          84 of REE imports to US are from China

          bull

          Increasing demand for high tech applications spurred increase in exploration in 2007

          bull

          Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

          Lake as well as in

          Malawi Africa

          Environmental Considerations

          bull

          REE soil and food contaminationbull

          Acid Mine Drainage and groundwater systems

          bull

          Radioactive elements

          REE Fertilizerbull

          In China REE enriched fertilizer has been used in crop fields since 1990

          bull

          At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

          every year

          bull

          Research and agricultural practice that provides evidence that REEs

          will improve crop quality an yield

          bull

          The ramifications environmental and human exposure to REEs

          are not well understood

          Investigation by T Liang et albull

          Revealed that the average concentration of total REEs

          in Chinese soil is

          1768 mgkg ranging between 850 to 5227 mgkg

          bull

          In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

          Implicationsbull

          Human health effects not completely understood

          bull

          REE soil content shown to be detrimental to some plant speciesndash

          100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

          Acid Mine Drainage (AMD)bull

          Rain waters contacts waste rock facilitating acid forming reactions

          bull

          Increases the capacity of the water to leach potentially harmful elements from waste piles

          bull

          Process mobilizes established ecotoxins

          (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

          bull

          Historically dismissed as minor environmental risk

          Radioactive Elements

          bull

          REEs

          associated with uranium and thorium

          bull

          Bastnesite 32 thorium

          bull

          Monazite sands 6 to 12 thorium oxide

          bull

          Ores containing radioactive elements are avoided as sources of REEs

          Radioactive Hazardsbull

          Mountain Pass

          bull

          Accidentsndash

          In 1977 major pipeline break spilled over 2 million gallons of radioactive water

          bull

          Health Effectsndash

          inflammatory bowel disease ndash

          Prolonged seizures ndash

          Cysts ndash

          Cancers

          bull

          Waste Disposal ndash

          Yucca Mountain

          Summarybull

          REE concentrations in the crust are rare

          bull

          Several geochemical factors influencing distribution including ionic radius and coordination number

          bull

          Main REE minerals are bastnasite monazite and xenotime

          bull

          Most important deposits are found at Bayan

          Obo China and Mountain Pass USA

          bull

          Important electronic and nuclear applications

          bull

          Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

          system contamination though acid mine drainage association with

          radioactive elements

          Referencesbull

          E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

          bull

          Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

          bull

          G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

          bull

          B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

          The Government of South Australia wwwpirsagovaubull

          The US geological Survey Mineralsusgsgovbull

          wwwelementsdatabasecombull

          wwwastrolsaumichedu~cowleyintro2htmlbull

          wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

          webmineralcomdataMonazite-(Ce)shtmlbull

          wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

          wwwstevegbcomimagesscienceorbital_fillingpngbull

          wwwchemicalelementscomelementseuhtmlbull

          boomeriaorgchemlecturestextass2table10-9jpgbull

          lostcontentquakecomfiles200802holmiumpngbull

          chinageocitylocatorcomcitiesChinaQinghaibull

          geowebrudruzal-Bayan-Obohtmbull

          enwikipediaorgwikiSan_Bernardino_County_Californiabull

          wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

          enwikipediaorgwikiMonazitebull

          webmineralcomdataBastnasite-(La)shtmlbull

          wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

          httpwwwavalonventurescombull

          wwwnewsweekcomid43884bull

          httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

          httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

          • Slide Number 1
          • Slide Number 2
          • Slide Number 3
          • Slide Number 4
          • Slide Number 5
          • Slide Number 6
          • Slide Number 7
          • Slide Number 8
          • Slide Number 9
          • Slide Number 10
          • Slide Number 11
          • Slide Number 12
          • Slide Number 13
          • Slide Number 14
          • Slide Number 15
          • Slide Number 16
          • Slide Number 17
          • Slide Number 18
          • Slide Number 19
          • Slide Number 20
          • Slide Number 21
          • Slide Number 22
          • Slide Number 23
          • Slide Number 24
          • Slide Number 25
          • Slide Number 26
          • Slide Number 27
          • Slide Number 28
          • Slide Number 29
          • Slide Number 30
          • Slide Number 31
          • Slide Number 32
          • Slide Number 33
          • Slide Number 34
          • Slide Number 35
          • Slide Number 36
          • Slide Number 37
          • Slide Number 38
          • Slide Number 39
          • Slide Number 40
          • Slide Number 41
          • Slide Number 42
          • Slide Number 43
          • Slide Number 44
          • Slide Number 45
          • Slide Number 46
          • Slide Number 47
          • Slide Number 48
          • Slide Number 49
          • Slide Number 50
          • Slide Number 51
          • Rare Earth Elements
          • Crustal Abundances of Elements
          • Occurrence
          • Rare Earth Minerals
          • REE Minerals
          • Bastnesite
          • Other REE minerals
          • Electron Configuration
          • Electron Configuartion
          • REE Behavior
          • Ionic Radius
          • Coordination Number
          • Coordination Number
          • Other Factors
          • REEs and Economics
          • HREEs and Magnetism
          • Applications in Magnetism
          • Applications in Magnetism
          • HREEs and Nuclear Technology
          • HREEs and Nuclear Technology
          • Mountain Pass
          • Bayan Obo
          • World Production
          • Exploration
          • Environmental Considerations
          • REE Fertilizer
          • Investigation by T Liang et al
          • Implications
          • Acid Mine Drainage (AMD)
          • Radioactive Elements
          • Radioactive Hazards
          • Summary
          • References

            106 107 108 109 1010

            Tonnes

            of Ores

            Gra

            de (w

            t)

            01

            10

            10

            100

            Richardson amp Birkett

            1996

            GSCCarbonatites

            Tonnes

            of ore Richardson amp Birkett

            1996

            GSCPeralkalic

            Richardson amp Birkett

            1996

            GSCPeralkalic

            Tonnes

            of ore Richardson amp Birkett

            1996

            GSC

            Peralkalic

            Kvanefjeld REE-U deposit Ilimaussaq Complex

            bull

            This new resource statement estimates the inventory of contained metal within

            a 457 Mt

            ore body to be 491 Mt

            of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

            bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

            Kvanefjeld REE-U deposit Ilimaussaq Complex

            Kvanefjeld REE-U deposit

            Model for Peralkalic Magma Systems

            BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

            Contact pegmatiteContact pegmatiteapliteaplite

            EndograniticEndograniticpegmatitepegmatite

            Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

            APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

            WelsfordWelsford Dyke swarmsDyke swarms

            Welsford

            model

            Marsh (1995)

            Major Rare Earth Sources

            Mineral

            Composition

            Occurrence

            Bastnaumlsite

            (Ce) (REE) CO3

            F

            Carbonatites

            Monazite (Ce) (REE) PO4

            Beach Sands Hydrothermal

            Xenotime

            (Y) (YREE) PO4

            Beach Sands Hydrothermal

            Loparite

            (Ce) (REENaCa) (Ti NbTa)O3

            Alkaline igneous massif

            South China Clays (Ion-adsorbed REE+Y in Clays)

            Uraninite

            (REE and Y mdash

            Released as dissolved elements

            in rafinates

            from uraninite)

            Monazite pseudomorph

            after apatite Monazite pseudomorph

            after Rhabdophane

            Florencite

            pseudomorph

            after pyrochlore Churchite

            YPO4

            middot2H2

            O

            Supergene Minerals ndash

            MT Weld Australia

            Apatite

            with Substitutional

            REE

            Oka Quebec

            Carbonatite

            Nolanrsquos Bore Australia

            Carbonatite

            Mushgai

            Khudag Mongolia

            Carbonatite

            Phalaborwa South Africa

            Carbonatite

            Kola Peninsula

            Carbonatite

            and Alkaline Massifs

            Hoidas

            Lake Saskatchewan

            Hydrothermal in Granites

            Mineville New York

            Tailings from Magnetite Mining

            Mineville may be the only Y and HREE dominant source currently known

            HD -

            176 mm HD -

            44 mm

            XPL MicrographsBastnaumlsite

            in Carbonatite

            Mountain Pass CA

            BSE Image AncyliteHD ndash

            07 mm

            PPL Micrograph Ancylite

            Ancylite

            (Ce)

            SrREE(CO3

            )2

            (OH)H2

            O

            LREE -

            dominant ndash

            50 wt REO

            An exploration target in the

            Bear Lodge Carbonatite

            Complex of northeastern Wyoming

            Red Wine Complex Labrador Dora Bay Alaska

            Eudialyte

            Na15

            Ca6

            (Fe2+Mn2+)3

            Zr3

            (SiNb)(Si25

            O73

            )(OOHH2

            O)3

            (CLOH)2

            Eudialyite

            may also contain Y and HREE

            in amounts exceeding 4 wt The

            mineral is easily dissolved in weak acids

            but colloidal silica currently presents a

            problem in the isolation of Y REE and Zr

            oxides

            Kipawa Quebec

            Massive Britholite

            (Ce) Oka Quebec

            Britholite

            (Ce) Concentrate from Skarn

            Kipawa Quebec

            Britholite

            ndash

            (REEYCa)5

            (SiO4

            PO4

            )3

            (OHF)

            This mineral has the potential for occurring in ore quantities in skarn

            associated with syenite

            gneiss in Kipawa Quebec

            Allanite

            (Ce) (CeCaY)2

            (AlFe2+Fe3+)3

            (SiO4

            )3

            (OH)

            Allanite

            is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

            Allanite

            ndash

            Hydrothermal Mountain Pass CA Allanite

            ndash

            Pegmatite Timmins Ontario

            Eudialyte

            and Mosandrite

            in Peralkaline

            Syenite

            Kipawa Quebec

            Britholite-Rich Skarn

            All brown prisms are britholite

            (Horizontal Distance ndash 46 mm)

            Britholite

            Concentrate

            (mm scale)

            Britholite

            ndash

            (CeYCa)5 (SiO4PO4 )3 (OHF)

            Kipawa Quebec

            Cathodoluminescence

            Macrograph of Iimoriite

            in Syenite

            ndash

            Bokan

            Mountain

            Mottled light blue and tan clusters -

            Iimoriite

            Red groundmass ndash

            Feldspar

            (Horizontal distance of rock slab ndash 46 mm)

            Iimoriite

            (Y)

            Y2 (SiO4 )(CO3 )

            Yttrofluorite

            (CaY)F2

            Iimoriite

            Concentrate ndash

            Bokan

            MT (1 mm scale)

            Wicheeda

            Lake Heavy Mineral Composite mdash

            (from samples 828951 52 53)

            These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

            and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

            As a final statement it should be emphasizedhellip

            1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

            2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

            3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

            4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

            5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

            Rare Earth Elements

            bull

            Name something of a misnomerndash

            Rarest REEs

            are over 200 times more

            abundant then gold

            bull

            Variation in distribution for two reasons ndash

            Compatibility with common rock forming materials

            ndash

            CosmicCrustal abundances

            Crustal Abundances of Elements

            Occurrencebull

            REEs

            occur mostly as

            substitutional

            impurities in many rock forming minerals

            bull

            Only a few the REE minerals have sufficient quantities to be considered important sources

            bull

            Defined as minerals having at least one site that is filled by REEs

            andor Yttrium more often then any other elementMonazite

            Rare Earth Minerals

            bull

            Form by primary crystalization

            from magma or by hydrothermal reactions

            bull

            Found hosted in carbonate rocks in pegmatites

            and as accessory minerals in

            igneous rocks

            bull

            Stable REE minerals and can be concentrated in weathering zones

            REE Mineralsbull

            The most important REE minerals is bastnaumlsite

            REE(CO3)F

            bull

            Other notable sources are ndash

            Monazite REE(PO4) ndash

            Xenotime

            YPO4

            bull

            All may contain radioactive species such as thorium

            and uraniumndash

            are avoided as source materials

            Bastnesitebull

            Bastnasite

            [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

            bull

            Containing 60 to 70 rare earth oxides (REOs)

            bull

            REE site is most commonly filled by LREEs

            and Y

            Other REE mineralsbull

            Monazite [(LREEYTh)PO4] ndash

            Contains about 50ndash78 rare earth oxides

            ndash

            Forms in heavy mineral sands placer deposits associated with beach environments

            bull

            Xenotime

            [(YPO4)] ndash

            Contains 54ndash65 rare earth oxides

            ndash

            Yttrium Erbium and Cerium most common ndash

            Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

            Electron Configuration

            bull

            The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

            bull

            REEs

            have same outer electronic configuration (+3) they differ in their number of 4f electrons

            Electron Configuartion

            REE Behaviorbull

            Because of their shared behaviour REEs

            tend to be

            present in nature as a group All REEs

            commonly substitute for one another in minerals

            bull

            Yet the REEs

            are capable of showing great variation in their distributions

            bull

            Comes about due to ndash

            Differences in ionic radius ndash

            Crystal structure (Coordination Number)ndash

            Basicity

            of the mineral ndash

            The elementrsquos solubility and ability to migrate in the environment ndash

            Content of REEs

            in source fluids

            Ionic Radiusbull

            The ionic radius of the REEs

            is inversely related to atomic number

            bull

            The heavy rare earths are smaller ndash

            more similar to Mn2+ (ionic radius 008 nanometers)

            bull

            LREEs

            are largerndash

            more comparable in size to Ca2+ (ionic radius 01 nanometer)

            bull

            Charge balance achieved through some sites being left vacant or

            by coupled substitution with lower charged mineral (Na+)

            In nanometers

            Coordination Number

            bull

            Coordination number the number of atoms touching a particular atom in a crystal lattice

            bull

            Coordination number for this structure is 8

            Coordination Numberbull

            The heavy and light REEs

            differ in the coordination

            numbers (CN) with oxygenndash

            HREEs

            have CN between six to nine ndash

            LREEs

            have higher CNs

            bull

            Minerals with high CNs

            associated with REE site

            will favor LREEsndash

            Bastnasite

            CN = 11 ndash

            Monazite CN = 9

            bull

            Those with low CNs

            will preferentially select HREEs ndash

            Xenotime

            has a value of 8

            Other Factorsbull

            Minerals basicityndash

            Alkalic

            rocks host minerals with elevated LREE content ndash

            Rocks with lower basicity

            have lower amounts of LREEs

            relative to their HREE content

            bull

            Solubilityndash

            LREEs

            are more soluble in water then the HREEsndash

            Important characteristic for hydrothermally derived minerals

            bull

            MagmaHydrothermal fluid compositionndash

            Minerals will take what they can get

            REEs

            and Economicsbull

            The REEs

            and Yttrium have a very broad range of applications mostly in high technology fields

            bull

            84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

            bull

            REEs

            used primarily for automotive (25) petroleum (22) and metallurgic (20)

            HREEs

            and Magnetism

            bull

            HREEs

            exhibit complex magnetic behaviour on account of electron structurendash

            They share the same outer shell electron configuration (valence = +3)

            ndash

            Differ in number of 4f electrons

            Applications in Magnetismbull

            Terbium and

            Dysprosium

            bull

            Components of Terfenol-D

            alloy

            with the formula Tb(03) Dy(07) Fe(19)

            bull

            Has the higher magnetostriction

            then any other alloyndash

            expands and contracts in magnetic field

            bull

            Developed by American Navy for sonar

            systems ndash

            Now has applications in magnetomechanical

            sensors and other electronic devices

            Applications in Magnetism

            bull

            Holmium

            bull

            Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

            elements

            bull

            Creates the strongest artificially generated magnetic fieldsndash

            In research where strong magnetic fields are needed

            HREEs

            and Nuclear Technology

            bull

            Dysprosium Homium Erbium

            bull

            High neutron

            absorption cross-section ndash

            Measure of probability of neutron capture

            bull

            Used in neutron-absorbing control rods in nuclear reactors

            HREEs

            and Nuclear Technology

            bull

            Lutetiumbull

            Radioactive isotope used in radiometric dating

            bull

            Thulium bull

            Stable thulium used as a radiation

            source

            in portable X-ray

            devices

            Mountain Passbull

            Bastnasite

            is the major REE mineral bull

            High grade accessory mineral of igneous or hydrothermal originsbull

            31 million tons of 886 by weight of rare earth oxides (REO) bull

            Mining stopped in 1994 ndash

            Thorium content of waste rock ndash

            Availability of inexpensive REEs

            from China

            San Bernardino County

            Bayan

            Obobull

            The worldrsquos primary source for both yttrium and the rare earth elements

            bull

            37 million tons of ore bull

            Main REE source there is Bastnasite

            World Production

            Explorationbull

            84 of REE imports to US are from China

            bull

            Increasing demand for high tech applications spurred increase in exploration in 2007

            bull

            Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

            Lake as well as in

            Malawi Africa

            Environmental Considerations

            bull

            REE soil and food contaminationbull

            Acid Mine Drainage and groundwater systems

            bull

            Radioactive elements

            REE Fertilizerbull

            In China REE enriched fertilizer has been used in crop fields since 1990

            bull

            At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

            every year

            bull

            Research and agricultural practice that provides evidence that REEs

            will improve crop quality an yield

            bull

            The ramifications environmental and human exposure to REEs

            are not well understood

            Investigation by T Liang et albull

            Revealed that the average concentration of total REEs

            in Chinese soil is

            1768 mgkg ranging between 850 to 5227 mgkg

            bull

            In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

            Implicationsbull

            Human health effects not completely understood

            bull

            REE soil content shown to be detrimental to some plant speciesndash

            100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

            Acid Mine Drainage (AMD)bull

            Rain waters contacts waste rock facilitating acid forming reactions

            bull

            Increases the capacity of the water to leach potentially harmful elements from waste piles

            bull

            Process mobilizes established ecotoxins

            (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

            bull

            Historically dismissed as minor environmental risk

            Radioactive Elements

            bull

            REEs

            associated with uranium and thorium

            bull

            Bastnesite 32 thorium

            bull

            Monazite sands 6 to 12 thorium oxide

            bull

            Ores containing radioactive elements are avoided as sources of REEs

            Radioactive Hazardsbull

            Mountain Pass

            bull

            Accidentsndash

            In 1977 major pipeline break spilled over 2 million gallons of radioactive water

            bull

            Health Effectsndash

            inflammatory bowel disease ndash

            Prolonged seizures ndash

            Cysts ndash

            Cancers

            bull

            Waste Disposal ndash

            Yucca Mountain

            Summarybull

            REE concentrations in the crust are rare

            bull

            Several geochemical factors influencing distribution including ionic radius and coordination number

            bull

            Main REE minerals are bastnasite monazite and xenotime

            bull

            Most important deposits are found at Bayan

            Obo China and Mountain Pass USA

            bull

            Important electronic and nuclear applications

            bull

            Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

            system contamination though acid mine drainage association with

            radioactive elements

            Referencesbull

            E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

            bull

            Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

            bull

            G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

            bull

            B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

            The Government of South Australia wwwpirsagovaubull

            The US geological Survey Mineralsusgsgovbull

            wwwelementsdatabasecombull

            wwwastrolsaumichedu~cowleyintro2htmlbull

            wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

            webmineralcomdataMonazite-(Ce)shtmlbull

            wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

            wwwstevegbcomimagesscienceorbital_fillingpngbull

            wwwchemicalelementscomelementseuhtmlbull

            boomeriaorgchemlecturestextass2table10-9jpgbull

            lostcontentquakecomfiles200802holmiumpngbull

            chinageocitylocatorcomcitiesChinaQinghaibull

            geowebrudruzal-Bayan-Obohtmbull

            enwikipediaorgwikiSan_Bernardino_County_Californiabull

            wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

            enwikipediaorgwikiMonazitebull

            webmineralcomdataBastnasite-(La)shtmlbull

            wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

            httpwwwavalonventurescombull

            wwwnewsweekcomid43884bull

            httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

            httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

            • Slide Number 1
            • Slide Number 2
            • Slide Number 3
            • Slide Number 4
            • Slide Number 5
            • Slide Number 6
            • Slide Number 7
            • Slide Number 8
            • Slide Number 9
            • Slide Number 10
            • Slide Number 11
            • Slide Number 12
            • Slide Number 13
            • Slide Number 14
            • Slide Number 15
            • Slide Number 16
            • Slide Number 17
            • Slide Number 18
            • Slide Number 19
            • Slide Number 20
            • Slide Number 21
            • Slide Number 22
            • Slide Number 23
            • Slide Number 24
            • Slide Number 25
            • Slide Number 26
            • Slide Number 27
            • Slide Number 28
            • Slide Number 29
            • Slide Number 30
            • Slide Number 31
            • Slide Number 32
            • Slide Number 33
            • Slide Number 34
            • Slide Number 35
            • Slide Number 36
            • Slide Number 37
            • Slide Number 38
            • Slide Number 39
            • Slide Number 40
            • Slide Number 41
            • Slide Number 42
            • Slide Number 43
            • Slide Number 44
            • Slide Number 45
            • Slide Number 46
            • Slide Number 47
            • Slide Number 48
            • Slide Number 49
            • Slide Number 50
            • Slide Number 51
            • Rare Earth Elements
            • Crustal Abundances of Elements
            • Occurrence
            • Rare Earth Minerals
            • REE Minerals
            • Bastnesite
            • Other REE minerals
            • Electron Configuration
            • Electron Configuartion
            • REE Behavior
            • Ionic Radius
            • Coordination Number
            • Coordination Number
            • Other Factors
            • REEs and Economics
            • HREEs and Magnetism
            • Applications in Magnetism
            • Applications in Magnetism
            • HREEs and Nuclear Technology
            • HREEs and Nuclear Technology
            • Mountain Pass
            • Bayan Obo
            • World Production
            • Exploration
            • Environmental Considerations
            • REE Fertilizer
            • Investigation by T Liang et al
            • Implications
            • Acid Mine Drainage (AMD)
            • Radioactive Elements
            • Radioactive Hazards
            • Summary
            • References

              Tonnes

              of ore Richardson amp Birkett

              1996

              GSCPeralkalic

              Richardson amp Birkett

              1996

              GSCPeralkalic

              Tonnes

              of ore Richardson amp Birkett

              1996

              GSC

              Peralkalic

              Kvanefjeld REE-U deposit Ilimaussaq Complex

              bull

              This new resource statement estimates the inventory of contained metal within

              a 457 Mt

              ore body to be 491 Mt

              of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

              bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

              Kvanefjeld REE-U deposit Ilimaussaq Complex

              Kvanefjeld REE-U deposit

              Model for Peralkalic Magma Systems

              BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

              Contact pegmatiteContact pegmatiteapliteaplite

              EndograniticEndograniticpegmatitepegmatite

              Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

              APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

              WelsfordWelsford Dyke swarmsDyke swarms

              Welsford

              model

              Marsh (1995)

              Major Rare Earth Sources

              Mineral

              Composition

              Occurrence

              Bastnaumlsite

              (Ce) (REE) CO3

              F

              Carbonatites

              Monazite (Ce) (REE) PO4

              Beach Sands Hydrothermal

              Xenotime

              (Y) (YREE) PO4

              Beach Sands Hydrothermal

              Loparite

              (Ce) (REENaCa) (Ti NbTa)O3

              Alkaline igneous massif

              South China Clays (Ion-adsorbed REE+Y in Clays)

              Uraninite

              (REE and Y mdash

              Released as dissolved elements

              in rafinates

              from uraninite)

              Monazite pseudomorph

              after apatite Monazite pseudomorph

              after Rhabdophane

              Florencite

              pseudomorph

              after pyrochlore Churchite

              YPO4

              middot2H2

              O

              Supergene Minerals ndash

              MT Weld Australia

              Apatite

              with Substitutional

              REE

              Oka Quebec

              Carbonatite

              Nolanrsquos Bore Australia

              Carbonatite

              Mushgai

              Khudag Mongolia

              Carbonatite

              Phalaborwa South Africa

              Carbonatite

              Kola Peninsula

              Carbonatite

              and Alkaline Massifs

              Hoidas

              Lake Saskatchewan

              Hydrothermal in Granites

              Mineville New York

              Tailings from Magnetite Mining

              Mineville may be the only Y and HREE dominant source currently known

              HD -

              176 mm HD -

              44 mm

              XPL MicrographsBastnaumlsite

              in Carbonatite

              Mountain Pass CA

              BSE Image AncyliteHD ndash

              07 mm

              PPL Micrograph Ancylite

              Ancylite

              (Ce)

              SrREE(CO3

              )2

              (OH)H2

              O

              LREE -

              dominant ndash

              50 wt REO

              An exploration target in the

              Bear Lodge Carbonatite

              Complex of northeastern Wyoming

              Red Wine Complex Labrador Dora Bay Alaska

              Eudialyte

              Na15

              Ca6

              (Fe2+Mn2+)3

              Zr3

              (SiNb)(Si25

              O73

              )(OOHH2

              O)3

              (CLOH)2

              Eudialyite

              may also contain Y and HREE

              in amounts exceeding 4 wt The

              mineral is easily dissolved in weak acids

              but colloidal silica currently presents a

              problem in the isolation of Y REE and Zr

              oxides

              Kipawa Quebec

              Massive Britholite

              (Ce) Oka Quebec

              Britholite

              (Ce) Concentrate from Skarn

              Kipawa Quebec

              Britholite

              ndash

              (REEYCa)5

              (SiO4

              PO4

              )3

              (OHF)

              This mineral has the potential for occurring in ore quantities in skarn

              associated with syenite

              gneiss in Kipawa Quebec

              Allanite

              (Ce) (CeCaY)2

              (AlFe2+Fe3+)3

              (SiO4

              )3

              (OH)

              Allanite

              is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

              Allanite

              ndash

              Hydrothermal Mountain Pass CA Allanite

              ndash

              Pegmatite Timmins Ontario

              Eudialyte

              and Mosandrite

              in Peralkaline

              Syenite

              Kipawa Quebec

              Britholite-Rich Skarn

              All brown prisms are britholite

              (Horizontal Distance ndash 46 mm)

              Britholite

              Concentrate

              (mm scale)

              Britholite

              ndash

              (CeYCa)5 (SiO4PO4 )3 (OHF)

              Kipawa Quebec

              Cathodoluminescence

              Macrograph of Iimoriite

              in Syenite

              ndash

              Bokan

              Mountain

              Mottled light blue and tan clusters -

              Iimoriite

              Red groundmass ndash

              Feldspar

              (Horizontal distance of rock slab ndash 46 mm)

              Iimoriite

              (Y)

              Y2 (SiO4 )(CO3 )

              Yttrofluorite

              (CaY)F2

              Iimoriite

              Concentrate ndash

              Bokan

              MT (1 mm scale)

              Wicheeda

              Lake Heavy Mineral Composite mdash

              (from samples 828951 52 53)

              These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

              and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

              As a final statement it should be emphasizedhellip

              1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

              2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

              3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

              4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

              5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

              Rare Earth Elements

              bull

              Name something of a misnomerndash

              Rarest REEs

              are over 200 times more

              abundant then gold

              bull

              Variation in distribution for two reasons ndash

              Compatibility with common rock forming materials

              ndash

              CosmicCrustal abundances

              Crustal Abundances of Elements

              Occurrencebull

              REEs

              occur mostly as

              substitutional

              impurities in many rock forming minerals

              bull

              Only a few the REE minerals have sufficient quantities to be considered important sources

              bull

              Defined as minerals having at least one site that is filled by REEs

              andor Yttrium more often then any other elementMonazite

              Rare Earth Minerals

              bull

              Form by primary crystalization

              from magma or by hydrothermal reactions

              bull

              Found hosted in carbonate rocks in pegmatites

              and as accessory minerals in

              igneous rocks

              bull

              Stable REE minerals and can be concentrated in weathering zones

              REE Mineralsbull

              The most important REE minerals is bastnaumlsite

              REE(CO3)F

              bull

              Other notable sources are ndash

              Monazite REE(PO4) ndash

              Xenotime

              YPO4

              bull

              All may contain radioactive species such as thorium

              and uraniumndash

              are avoided as source materials

              Bastnesitebull

              Bastnasite

              [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

              bull

              Containing 60 to 70 rare earth oxides (REOs)

              bull

              REE site is most commonly filled by LREEs

              and Y

              Other REE mineralsbull

              Monazite [(LREEYTh)PO4] ndash

              Contains about 50ndash78 rare earth oxides

              ndash

              Forms in heavy mineral sands placer deposits associated with beach environments

              bull

              Xenotime

              [(YPO4)] ndash

              Contains 54ndash65 rare earth oxides

              ndash

              Yttrium Erbium and Cerium most common ndash

              Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

              Electron Configuration

              bull

              The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

              bull

              REEs

              have same outer electronic configuration (+3) they differ in their number of 4f electrons

              Electron Configuartion

              REE Behaviorbull

              Because of their shared behaviour REEs

              tend to be

              present in nature as a group All REEs

              commonly substitute for one another in minerals

              bull

              Yet the REEs

              are capable of showing great variation in their distributions

              bull

              Comes about due to ndash

              Differences in ionic radius ndash

              Crystal structure (Coordination Number)ndash

              Basicity

              of the mineral ndash

              The elementrsquos solubility and ability to migrate in the environment ndash

              Content of REEs

              in source fluids

              Ionic Radiusbull

              The ionic radius of the REEs

              is inversely related to atomic number

              bull

              The heavy rare earths are smaller ndash

              more similar to Mn2+ (ionic radius 008 nanometers)

              bull

              LREEs

              are largerndash

              more comparable in size to Ca2+ (ionic radius 01 nanometer)

              bull

              Charge balance achieved through some sites being left vacant or

              by coupled substitution with lower charged mineral (Na+)

              In nanometers

              Coordination Number

              bull

              Coordination number the number of atoms touching a particular atom in a crystal lattice

              bull

              Coordination number for this structure is 8

              Coordination Numberbull

              The heavy and light REEs

              differ in the coordination

              numbers (CN) with oxygenndash

              HREEs

              have CN between six to nine ndash

              LREEs

              have higher CNs

              bull

              Minerals with high CNs

              associated with REE site

              will favor LREEsndash

              Bastnasite

              CN = 11 ndash

              Monazite CN = 9

              bull

              Those with low CNs

              will preferentially select HREEs ndash

              Xenotime

              has a value of 8

              Other Factorsbull

              Minerals basicityndash

              Alkalic

              rocks host minerals with elevated LREE content ndash

              Rocks with lower basicity

              have lower amounts of LREEs

              relative to their HREE content

              bull

              Solubilityndash

              LREEs

              are more soluble in water then the HREEsndash

              Important characteristic for hydrothermally derived minerals

              bull

              MagmaHydrothermal fluid compositionndash

              Minerals will take what they can get

              REEs

              and Economicsbull

              The REEs

              and Yttrium have a very broad range of applications mostly in high technology fields

              bull

              84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

              bull

              REEs

              used primarily for automotive (25) petroleum (22) and metallurgic (20)

              HREEs

              and Magnetism

              bull

              HREEs

              exhibit complex magnetic behaviour on account of electron structurendash

              They share the same outer shell electron configuration (valence = +3)

              ndash

              Differ in number of 4f electrons

              Applications in Magnetismbull

              Terbium and

              Dysprosium

              bull

              Components of Terfenol-D

              alloy

              with the formula Tb(03) Dy(07) Fe(19)

              bull

              Has the higher magnetostriction

              then any other alloyndash

              expands and contracts in magnetic field

              bull

              Developed by American Navy for sonar

              systems ndash

              Now has applications in magnetomechanical

              sensors and other electronic devices

              Applications in Magnetism

              bull

              Holmium

              bull

              Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

              elements

              bull

              Creates the strongest artificially generated magnetic fieldsndash

              In research where strong magnetic fields are needed

              HREEs

              and Nuclear Technology

              bull

              Dysprosium Homium Erbium

              bull

              High neutron

              absorption cross-section ndash

              Measure of probability of neutron capture

              bull

              Used in neutron-absorbing control rods in nuclear reactors

              HREEs

              and Nuclear Technology

              bull

              Lutetiumbull

              Radioactive isotope used in radiometric dating

              bull

              Thulium bull

              Stable thulium used as a radiation

              source

              in portable X-ray

              devices

              Mountain Passbull

              Bastnasite

              is the major REE mineral bull

              High grade accessory mineral of igneous or hydrothermal originsbull

              31 million tons of 886 by weight of rare earth oxides (REO) bull

              Mining stopped in 1994 ndash

              Thorium content of waste rock ndash

              Availability of inexpensive REEs

              from China

              San Bernardino County

              Bayan

              Obobull

              The worldrsquos primary source for both yttrium and the rare earth elements

              bull

              37 million tons of ore bull

              Main REE source there is Bastnasite

              World Production

              Explorationbull

              84 of REE imports to US are from China

              bull

              Increasing demand for high tech applications spurred increase in exploration in 2007

              bull

              Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

              Lake as well as in

              Malawi Africa

              Environmental Considerations

              bull

              REE soil and food contaminationbull

              Acid Mine Drainage and groundwater systems

              bull

              Radioactive elements

              REE Fertilizerbull

              In China REE enriched fertilizer has been used in crop fields since 1990

              bull

              At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

              every year

              bull

              Research and agricultural practice that provides evidence that REEs

              will improve crop quality an yield

              bull

              The ramifications environmental and human exposure to REEs

              are not well understood

              Investigation by T Liang et albull

              Revealed that the average concentration of total REEs

              in Chinese soil is

              1768 mgkg ranging between 850 to 5227 mgkg

              bull

              In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

              Implicationsbull

              Human health effects not completely understood

              bull

              REE soil content shown to be detrimental to some plant speciesndash

              100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

              Acid Mine Drainage (AMD)bull

              Rain waters contacts waste rock facilitating acid forming reactions

              bull

              Increases the capacity of the water to leach potentially harmful elements from waste piles

              bull

              Process mobilizes established ecotoxins

              (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

              bull

              Historically dismissed as minor environmental risk

              Radioactive Elements

              bull

              REEs

              associated with uranium and thorium

              bull

              Bastnesite 32 thorium

              bull

              Monazite sands 6 to 12 thorium oxide

              bull

              Ores containing radioactive elements are avoided as sources of REEs

              Radioactive Hazardsbull

              Mountain Pass

              bull

              Accidentsndash

              In 1977 major pipeline break spilled over 2 million gallons of radioactive water

              bull

              Health Effectsndash

              inflammatory bowel disease ndash

              Prolonged seizures ndash

              Cysts ndash

              Cancers

              bull

              Waste Disposal ndash

              Yucca Mountain

              Summarybull

              REE concentrations in the crust are rare

              bull

              Several geochemical factors influencing distribution including ionic radius and coordination number

              bull

              Main REE minerals are bastnasite monazite and xenotime

              bull

              Most important deposits are found at Bayan

              Obo China and Mountain Pass USA

              bull

              Important electronic and nuclear applications

              bull

              Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

              system contamination though acid mine drainage association with

              radioactive elements

              Referencesbull

              E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

              bull

              Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

              bull

              G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

              bull

              B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

              The Government of South Australia wwwpirsagovaubull

              The US geological Survey Mineralsusgsgovbull

              wwwelementsdatabasecombull

              wwwastrolsaumichedu~cowleyintro2htmlbull

              wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

              webmineralcomdataMonazite-(Ce)shtmlbull

              wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

              wwwstevegbcomimagesscienceorbital_fillingpngbull

              wwwchemicalelementscomelementseuhtmlbull

              boomeriaorgchemlecturestextass2table10-9jpgbull

              lostcontentquakecomfiles200802holmiumpngbull

              chinageocitylocatorcomcitiesChinaQinghaibull

              geowebrudruzal-Bayan-Obohtmbull

              enwikipediaorgwikiSan_Bernardino_County_Californiabull

              wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

              enwikipediaorgwikiMonazitebull

              webmineralcomdataBastnasite-(La)shtmlbull

              wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

              httpwwwavalonventurescombull

              wwwnewsweekcomid43884bull

              httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

              httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

              • Slide Number 1
              • Slide Number 2
              • Slide Number 3
              • Slide Number 4
              • Slide Number 5
              • Slide Number 6
              • Slide Number 7
              • Slide Number 8
              • Slide Number 9
              • Slide Number 10
              • Slide Number 11
              • Slide Number 12
              • Slide Number 13
              • Slide Number 14
              • Slide Number 15
              • Slide Number 16
              • Slide Number 17
              • Slide Number 18
              • Slide Number 19
              • Slide Number 20
              • Slide Number 21
              • Slide Number 22
              • Slide Number 23
              • Slide Number 24
              • Slide Number 25
              • Slide Number 26
              • Slide Number 27
              • Slide Number 28
              • Slide Number 29
              • Slide Number 30
              • Slide Number 31
              • Slide Number 32
              • Slide Number 33
              • Slide Number 34
              • Slide Number 35
              • Slide Number 36
              • Slide Number 37
              • Slide Number 38
              • Slide Number 39
              • Slide Number 40
              • Slide Number 41
              • Slide Number 42
              • Slide Number 43
              • Slide Number 44
              • Slide Number 45
              • Slide Number 46
              • Slide Number 47
              • Slide Number 48
              • Slide Number 49
              • Slide Number 50
              • Slide Number 51
              • Rare Earth Elements
              • Crustal Abundances of Elements
              • Occurrence
              • Rare Earth Minerals
              • REE Minerals
              • Bastnesite
              • Other REE minerals
              • Electron Configuration
              • Electron Configuartion
              • REE Behavior
              • Ionic Radius
              • Coordination Number
              • Coordination Number
              • Other Factors
              • REEs and Economics
              • HREEs and Magnetism
              • Applications in Magnetism
              • Applications in Magnetism
              • HREEs and Nuclear Technology
              • HREEs and Nuclear Technology
              • Mountain Pass
              • Bayan Obo
              • World Production
              • Exploration
              • Environmental Considerations
              • REE Fertilizer
              • Investigation by T Liang et al
              • Implications
              • Acid Mine Drainage (AMD)
              • Radioactive Elements
              • Radioactive Hazards
              • Summary
              • References

                Richardson amp Birkett

                1996

                GSCPeralkalic

                Tonnes

                of ore Richardson amp Birkett

                1996

                GSC

                Peralkalic

                Kvanefjeld REE-U deposit Ilimaussaq Complex

                bull

                This new resource statement estimates the inventory of contained metal within

                a 457 Mt

                ore body to be 491 Mt

                of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

                bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

                Kvanefjeld REE-U deposit Ilimaussaq Complex

                Kvanefjeld REE-U deposit

                Model for Peralkalic Magma Systems

                BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

                Contact pegmatiteContact pegmatiteapliteaplite

                EndograniticEndograniticpegmatitepegmatite

                Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

                APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

                WelsfordWelsford Dyke swarmsDyke swarms

                Welsford

                model

                Marsh (1995)

                Major Rare Earth Sources

                Mineral

                Composition

                Occurrence

                Bastnaumlsite

                (Ce) (REE) CO3

                F

                Carbonatites

                Monazite (Ce) (REE) PO4

                Beach Sands Hydrothermal

                Xenotime

                (Y) (YREE) PO4

                Beach Sands Hydrothermal

                Loparite

                (Ce) (REENaCa) (Ti NbTa)O3

                Alkaline igneous massif

                South China Clays (Ion-adsorbed REE+Y in Clays)

                Uraninite

                (REE and Y mdash

                Released as dissolved elements

                in rafinates

                from uraninite)

                Monazite pseudomorph

                after apatite Monazite pseudomorph

                after Rhabdophane

                Florencite

                pseudomorph

                after pyrochlore Churchite

                YPO4

                middot2H2

                O

                Supergene Minerals ndash

                MT Weld Australia

                Apatite

                with Substitutional

                REE

                Oka Quebec

                Carbonatite

                Nolanrsquos Bore Australia

                Carbonatite

                Mushgai

                Khudag Mongolia

                Carbonatite

                Phalaborwa South Africa

                Carbonatite

                Kola Peninsula

                Carbonatite

                and Alkaline Massifs

                Hoidas

                Lake Saskatchewan

                Hydrothermal in Granites

                Mineville New York

                Tailings from Magnetite Mining

                Mineville may be the only Y and HREE dominant source currently known

                HD -

                176 mm HD -

                44 mm

                XPL MicrographsBastnaumlsite

                in Carbonatite

                Mountain Pass CA

                BSE Image AncyliteHD ndash

                07 mm

                PPL Micrograph Ancylite

                Ancylite

                (Ce)

                SrREE(CO3

                )2

                (OH)H2

                O

                LREE -

                dominant ndash

                50 wt REO

                An exploration target in the

                Bear Lodge Carbonatite

                Complex of northeastern Wyoming

                Red Wine Complex Labrador Dora Bay Alaska

                Eudialyte

                Na15

                Ca6

                (Fe2+Mn2+)3

                Zr3

                (SiNb)(Si25

                O73

                )(OOHH2

                O)3

                (CLOH)2

                Eudialyite

                may also contain Y and HREE

                in amounts exceeding 4 wt The

                mineral is easily dissolved in weak acids

                but colloidal silica currently presents a

                problem in the isolation of Y REE and Zr

                oxides

                Kipawa Quebec

                Massive Britholite

                (Ce) Oka Quebec

                Britholite

                (Ce) Concentrate from Skarn

                Kipawa Quebec

                Britholite

                ndash

                (REEYCa)5

                (SiO4

                PO4

                )3

                (OHF)

                This mineral has the potential for occurring in ore quantities in skarn

                associated with syenite

                gneiss in Kipawa Quebec

                Allanite

                (Ce) (CeCaY)2

                (AlFe2+Fe3+)3

                (SiO4

                )3

                (OH)

                Allanite

                is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                Allanite

                ndash

                Hydrothermal Mountain Pass CA Allanite

                ndash

                Pegmatite Timmins Ontario

                Eudialyte

                and Mosandrite

                in Peralkaline

                Syenite

                Kipawa Quebec

                Britholite-Rich Skarn

                All brown prisms are britholite

                (Horizontal Distance ndash 46 mm)

                Britholite

                Concentrate

                (mm scale)

                Britholite

                ndash

                (CeYCa)5 (SiO4PO4 )3 (OHF)

                Kipawa Quebec

                Cathodoluminescence

                Macrograph of Iimoriite

                in Syenite

                ndash

                Bokan

                Mountain

                Mottled light blue and tan clusters -

                Iimoriite

                Red groundmass ndash

                Feldspar

                (Horizontal distance of rock slab ndash 46 mm)

                Iimoriite

                (Y)

                Y2 (SiO4 )(CO3 )

                Yttrofluorite

                (CaY)F2

                Iimoriite

                Concentrate ndash

                Bokan

                MT (1 mm scale)

                Wicheeda

                Lake Heavy Mineral Composite mdash

                (from samples 828951 52 53)

                These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                As a final statement it should be emphasizedhellip

                1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                Rare Earth Elements

                bull

                Name something of a misnomerndash

                Rarest REEs

                are over 200 times more

                abundant then gold

                bull

                Variation in distribution for two reasons ndash

                Compatibility with common rock forming materials

                ndash

                CosmicCrustal abundances

                Crustal Abundances of Elements

                Occurrencebull

                REEs

                occur mostly as

                substitutional

                impurities in many rock forming minerals

                bull

                Only a few the REE minerals have sufficient quantities to be considered important sources

                bull

                Defined as minerals having at least one site that is filled by REEs

                andor Yttrium more often then any other elementMonazite

                Rare Earth Minerals

                bull

                Form by primary crystalization

                from magma or by hydrothermal reactions

                bull

                Found hosted in carbonate rocks in pegmatites

                and as accessory minerals in

                igneous rocks

                bull

                Stable REE minerals and can be concentrated in weathering zones

                REE Mineralsbull

                The most important REE minerals is bastnaumlsite

                REE(CO3)F

                bull

                Other notable sources are ndash

                Monazite REE(PO4) ndash

                Xenotime

                YPO4

                bull

                All may contain radioactive species such as thorium

                and uraniumndash

                are avoided as source materials

                Bastnesitebull

                Bastnasite

                [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                bull

                Containing 60 to 70 rare earth oxides (REOs)

                bull

                REE site is most commonly filled by LREEs

                and Y

                Other REE mineralsbull

                Monazite [(LREEYTh)PO4] ndash

                Contains about 50ndash78 rare earth oxides

                ndash

                Forms in heavy mineral sands placer deposits associated with beach environments

                bull

                Xenotime

                [(YPO4)] ndash

                Contains 54ndash65 rare earth oxides

                ndash

                Yttrium Erbium and Cerium most common ndash

                Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                Electron Configuration

                bull

                The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                bull

                REEs

                have same outer electronic configuration (+3) they differ in their number of 4f electrons

                Electron Configuartion

                REE Behaviorbull

                Because of their shared behaviour REEs

                tend to be

                present in nature as a group All REEs

                commonly substitute for one another in minerals

                bull

                Yet the REEs

                are capable of showing great variation in their distributions

                bull

                Comes about due to ndash

                Differences in ionic radius ndash

                Crystal structure (Coordination Number)ndash

                Basicity

                of the mineral ndash

                The elementrsquos solubility and ability to migrate in the environment ndash

                Content of REEs

                in source fluids

                Ionic Radiusbull

                The ionic radius of the REEs

                is inversely related to atomic number

                bull

                The heavy rare earths are smaller ndash

                more similar to Mn2+ (ionic radius 008 nanometers)

                bull

                LREEs

                are largerndash

                more comparable in size to Ca2+ (ionic radius 01 nanometer)

                bull

                Charge balance achieved through some sites being left vacant or

                by coupled substitution with lower charged mineral (Na+)

                In nanometers

                Coordination Number

                bull

                Coordination number the number of atoms touching a particular atom in a crystal lattice

                bull

                Coordination number for this structure is 8

                Coordination Numberbull

                The heavy and light REEs

                differ in the coordination

                numbers (CN) with oxygenndash

                HREEs

                have CN between six to nine ndash

                LREEs

                have higher CNs

                bull

                Minerals with high CNs

                associated with REE site

                will favor LREEsndash

                Bastnasite

                CN = 11 ndash

                Monazite CN = 9

                bull

                Those with low CNs

                will preferentially select HREEs ndash

                Xenotime

                has a value of 8

                Other Factorsbull

                Minerals basicityndash

                Alkalic

                rocks host minerals with elevated LREE content ndash

                Rocks with lower basicity

                have lower amounts of LREEs

                relative to their HREE content

                bull

                Solubilityndash

                LREEs

                are more soluble in water then the HREEsndash

                Important characteristic for hydrothermally derived minerals

                bull

                MagmaHydrothermal fluid compositionndash

                Minerals will take what they can get

                REEs

                and Economicsbull

                The REEs

                and Yttrium have a very broad range of applications mostly in high technology fields

                bull

                84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                bull

                REEs

                used primarily for automotive (25) petroleum (22) and metallurgic (20)

                HREEs

                and Magnetism

                bull

                HREEs

                exhibit complex magnetic behaviour on account of electron structurendash

                They share the same outer shell electron configuration (valence = +3)

                ndash

                Differ in number of 4f electrons

                Applications in Magnetismbull

                Terbium and

                Dysprosium

                bull

                Components of Terfenol-D

                alloy

                with the formula Tb(03) Dy(07) Fe(19)

                bull

                Has the higher magnetostriction

                then any other alloyndash

                expands and contracts in magnetic field

                bull

                Developed by American Navy for sonar

                systems ndash

                Now has applications in magnetomechanical

                sensors and other electronic devices

                Applications in Magnetism

                bull

                Holmium

                bull

                Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                elements

                bull

                Creates the strongest artificially generated magnetic fieldsndash

                In research where strong magnetic fields are needed

                HREEs

                and Nuclear Technology

                bull

                Dysprosium Homium Erbium

                bull

                High neutron

                absorption cross-section ndash

                Measure of probability of neutron capture

                bull

                Used in neutron-absorbing control rods in nuclear reactors

                HREEs

                and Nuclear Technology

                bull

                Lutetiumbull

                Radioactive isotope used in radiometric dating

                bull

                Thulium bull

                Stable thulium used as a radiation

                source

                in portable X-ray

                devices

                Mountain Passbull

                Bastnasite

                is the major REE mineral bull

                High grade accessory mineral of igneous or hydrothermal originsbull

                31 million tons of 886 by weight of rare earth oxides (REO) bull

                Mining stopped in 1994 ndash

                Thorium content of waste rock ndash

                Availability of inexpensive REEs

                from China

                San Bernardino County

                Bayan

                Obobull

                The worldrsquos primary source for both yttrium and the rare earth elements

                bull

                37 million tons of ore bull

                Main REE source there is Bastnasite

                World Production

                Explorationbull

                84 of REE imports to US are from China

                bull

                Increasing demand for high tech applications spurred increase in exploration in 2007

                bull

                Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                Lake as well as in

                Malawi Africa

                Environmental Considerations

                bull

                REE soil and food contaminationbull

                Acid Mine Drainage and groundwater systems

                bull

                Radioactive elements

                REE Fertilizerbull

                In China REE enriched fertilizer has been used in crop fields since 1990

                bull

                At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                every year

                bull

                Research and agricultural practice that provides evidence that REEs

                will improve crop quality an yield

                bull

                The ramifications environmental and human exposure to REEs

                are not well understood

                Investigation by T Liang et albull

                Revealed that the average concentration of total REEs

                in Chinese soil is

                1768 mgkg ranging between 850 to 5227 mgkg

                bull

                In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                Implicationsbull

                Human health effects not completely understood

                bull

                REE soil content shown to be detrimental to some plant speciesndash

                100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                Acid Mine Drainage (AMD)bull

                Rain waters contacts waste rock facilitating acid forming reactions

                bull

                Increases the capacity of the water to leach potentially harmful elements from waste piles

                bull

                Process mobilizes established ecotoxins

                (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                bull

                Historically dismissed as minor environmental risk

                Radioactive Elements

                bull

                REEs

                associated with uranium and thorium

                bull

                Bastnesite 32 thorium

                bull

                Monazite sands 6 to 12 thorium oxide

                bull

                Ores containing radioactive elements are avoided as sources of REEs

                Radioactive Hazardsbull

                Mountain Pass

                bull

                Accidentsndash

                In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                bull

                Health Effectsndash

                inflammatory bowel disease ndash

                Prolonged seizures ndash

                Cysts ndash

                Cancers

                bull

                Waste Disposal ndash

                Yucca Mountain

                Summarybull

                REE concentrations in the crust are rare

                bull

                Several geochemical factors influencing distribution including ionic radius and coordination number

                bull

                Main REE minerals are bastnasite monazite and xenotime

                bull

                Most important deposits are found at Bayan

                Obo China and Mountain Pass USA

                bull

                Important electronic and nuclear applications

                bull

                Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                system contamination though acid mine drainage association with

                radioactive elements

                Referencesbull

                E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                bull

                Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                bull

                G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                bull

                B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                The Government of South Australia wwwpirsagovaubull

                The US geological Survey Mineralsusgsgovbull

                wwwelementsdatabasecombull

                wwwastrolsaumichedu~cowleyintro2htmlbull

                wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                webmineralcomdataMonazite-(Ce)shtmlbull

                wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                wwwstevegbcomimagesscienceorbital_fillingpngbull

                wwwchemicalelementscomelementseuhtmlbull

                boomeriaorgchemlecturestextass2table10-9jpgbull

                lostcontentquakecomfiles200802holmiumpngbull

                chinageocitylocatorcomcitiesChinaQinghaibull

                geowebrudruzal-Bayan-Obohtmbull

                enwikipediaorgwikiSan_Bernardino_County_Californiabull

                wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                enwikipediaorgwikiMonazitebull

                webmineralcomdataBastnasite-(La)shtmlbull

                wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                httpwwwavalonventurescombull

                wwwnewsweekcomid43884bull

                httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                • Slide Number 1
                • Slide Number 2
                • Slide Number 3
                • Slide Number 4
                • Slide Number 5
                • Slide Number 6
                • Slide Number 7
                • Slide Number 8
                • Slide Number 9
                • Slide Number 10
                • Slide Number 11
                • Slide Number 12
                • Slide Number 13
                • Slide Number 14
                • Slide Number 15
                • Slide Number 16
                • Slide Number 17
                • Slide Number 18
                • Slide Number 19
                • Slide Number 20
                • Slide Number 21
                • Slide Number 22
                • Slide Number 23
                • Slide Number 24
                • Slide Number 25
                • Slide Number 26
                • Slide Number 27
                • Slide Number 28
                • Slide Number 29
                • Slide Number 30
                • Slide Number 31
                • Slide Number 32
                • Slide Number 33
                • Slide Number 34
                • Slide Number 35
                • Slide Number 36
                • Slide Number 37
                • Slide Number 38
                • Slide Number 39
                • Slide Number 40
                • Slide Number 41
                • Slide Number 42
                • Slide Number 43
                • Slide Number 44
                • Slide Number 45
                • Slide Number 46
                • Slide Number 47
                • Slide Number 48
                • Slide Number 49
                • Slide Number 50
                • Slide Number 51
                • Rare Earth Elements
                • Crustal Abundances of Elements
                • Occurrence
                • Rare Earth Minerals
                • REE Minerals
                • Bastnesite
                • Other REE minerals
                • Electron Configuration
                • Electron Configuartion
                • REE Behavior
                • Ionic Radius
                • Coordination Number
                • Coordination Number
                • Other Factors
                • REEs and Economics
                • HREEs and Magnetism
                • Applications in Magnetism
                • Applications in Magnetism
                • HREEs and Nuclear Technology
                • HREEs and Nuclear Technology
                • Mountain Pass
                • Bayan Obo
                • World Production
                • Exploration
                • Environmental Considerations
                • REE Fertilizer
                • Investigation by T Liang et al
                • Implications
                • Acid Mine Drainage (AMD)
                • Radioactive Elements
                • Radioactive Hazards
                • Summary
                • References

                  Tonnes

                  of ore Richardson amp Birkett

                  1996

                  GSC

                  Peralkalic

                  Kvanefjeld REE-U deposit Ilimaussaq Complex

                  bull

                  This new resource statement estimates the inventory of contained metal within

                  a 457 Mt

                  ore body to be 491 Mt

                  of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

                  bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

                  Kvanefjeld REE-U deposit Ilimaussaq Complex

                  Kvanefjeld REE-U deposit

                  Model for Peralkalic Magma Systems

                  BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

                  Contact pegmatiteContact pegmatiteapliteaplite

                  EndograniticEndograniticpegmatitepegmatite

                  Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

                  APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

                  WelsfordWelsford Dyke swarmsDyke swarms

                  Welsford

                  model

                  Marsh (1995)

                  Major Rare Earth Sources

                  Mineral

                  Composition

                  Occurrence

                  Bastnaumlsite

                  (Ce) (REE) CO3

                  F

                  Carbonatites

                  Monazite (Ce) (REE) PO4

                  Beach Sands Hydrothermal

                  Xenotime

                  (Y) (YREE) PO4

                  Beach Sands Hydrothermal

                  Loparite

                  (Ce) (REENaCa) (Ti NbTa)O3

                  Alkaline igneous massif

                  South China Clays (Ion-adsorbed REE+Y in Clays)

                  Uraninite

                  (REE and Y mdash

                  Released as dissolved elements

                  in rafinates

                  from uraninite)

                  Monazite pseudomorph

                  after apatite Monazite pseudomorph

                  after Rhabdophane

                  Florencite

                  pseudomorph

                  after pyrochlore Churchite

                  YPO4

                  middot2H2

                  O

                  Supergene Minerals ndash

                  MT Weld Australia

                  Apatite

                  with Substitutional

                  REE

                  Oka Quebec

                  Carbonatite

                  Nolanrsquos Bore Australia

                  Carbonatite

                  Mushgai

                  Khudag Mongolia

                  Carbonatite

                  Phalaborwa South Africa

                  Carbonatite

                  Kola Peninsula

                  Carbonatite

                  and Alkaline Massifs

                  Hoidas

                  Lake Saskatchewan

                  Hydrothermal in Granites

                  Mineville New York

                  Tailings from Magnetite Mining

                  Mineville may be the only Y and HREE dominant source currently known

                  HD -

                  176 mm HD -

                  44 mm

                  XPL MicrographsBastnaumlsite

                  in Carbonatite

                  Mountain Pass CA

                  BSE Image AncyliteHD ndash

                  07 mm

                  PPL Micrograph Ancylite

                  Ancylite

                  (Ce)

                  SrREE(CO3

                  )2

                  (OH)H2

                  O

                  LREE -

                  dominant ndash

                  50 wt REO

                  An exploration target in the

                  Bear Lodge Carbonatite

                  Complex of northeastern Wyoming

                  Red Wine Complex Labrador Dora Bay Alaska

                  Eudialyte

                  Na15

                  Ca6

                  (Fe2+Mn2+)3

                  Zr3

                  (SiNb)(Si25

                  O73

                  )(OOHH2

                  O)3

                  (CLOH)2

                  Eudialyite

                  may also contain Y and HREE

                  in amounts exceeding 4 wt The

                  mineral is easily dissolved in weak acids

                  but colloidal silica currently presents a

                  problem in the isolation of Y REE and Zr

                  oxides

                  Kipawa Quebec

                  Massive Britholite

                  (Ce) Oka Quebec

                  Britholite

                  (Ce) Concentrate from Skarn

                  Kipawa Quebec

                  Britholite

                  ndash

                  (REEYCa)5

                  (SiO4

                  PO4

                  )3

                  (OHF)

                  This mineral has the potential for occurring in ore quantities in skarn

                  associated with syenite

                  gneiss in Kipawa Quebec

                  Allanite

                  (Ce) (CeCaY)2

                  (AlFe2+Fe3+)3

                  (SiO4

                  )3

                  (OH)

                  Allanite

                  is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                  Allanite

                  ndash

                  Hydrothermal Mountain Pass CA Allanite

                  ndash

                  Pegmatite Timmins Ontario

                  Eudialyte

                  and Mosandrite

                  in Peralkaline

                  Syenite

                  Kipawa Quebec

                  Britholite-Rich Skarn

                  All brown prisms are britholite

                  (Horizontal Distance ndash 46 mm)

                  Britholite

                  Concentrate

                  (mm scale)

                  Britholite

                  ndash

                  (CeYCa)5 (SiO4PO4 )3 (OHF)

                  Kipawa Quebec

                  Cathodoluminescence

                  Macrograph of Iimoriite

                  in Syenite

                  ndash

                  Bokan

                  Mountain

                  Mottled light blue and tan clusters -

                  Iimoriite

                  Red groundmass ndash

                  Feldspar

                  (Horizontal distance of rock slab ndash 46 mm)

                  Iimoriite

                  (Y)

                  Y2 (SiO4 )(CO3 )

                  Yttrofluorite

                  (CaY)F2

                  Iimoriite

                  Concentrate ndash

                  Bokan

                  MT (1 mm scale)

                  Wicheeda

                  Lake Heavy Mineral Composite mdash

                  (from samples 828951 52 53)

                  These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                  and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                  As a final statement it should be emphasizedhellip

                  1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                  2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                  3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                  4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                  5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                  Rare Earth Elements

                  bull

                  Name something of a misnomerndash

                  Rarest REEs

                  are over 200 times more

                  abundant then gold

                  bull

                  Variation in distribution for two reasons ndash

                  Compatibility with common rock forming materials

                  ndash

                  CosmicCrustal abundances

                  Crustal Abundances of Elements

                  Occurrencebull

                  REEs

                  occur mostly as

                  substitutional

                  impurities in many rock forming minerals

                  bull

                  Only a few the REE minerals have sufficient quantities to be considered important sources

                  bull

                  Defined as minerals having at least one site that is filled by REEs

                  andor Yttrium more often then any other elementMonazite

                  Rare Earth Minerals

                  bull

                  Form by primary crystalization

                  from magma or by hydrothermal reactions

                  bull

                  Found hosted in carbonate rocks in pegmatites

                  and as accessory minerals in

                  igneous rocks

                  bull

                  Stable REE minerals and can be concentrated in weathering zones

                  REE Mineralsbull

                  The most important REE minerals is bastnaumlsite

                  REE(CO3)F

                  bull

                  Other notable sources are ndash

                  Monazite REE(PO4) ndash

                  Xenotime

                  YPO4

                  bull

                  All may contain radioactive species such as thorium

                  and uraniumndash

                  are avoided as source materials

                  Bastnesitebull

                  Bastnasite

                  [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                  bull

                  Containing 60 to 70 rare earth oxides (REOs)

                  bull

                  REE site is most commonly filled by LREEs

                  and Y

                  Other REE mineralsbull

                  Monazite [(LREEYTh)PO4] ndash

                  Contains about 50ndash78 rare earth oxides

                  ndash

                  Forms in heavy mineral sands placer deposits associated with beach environments

                  bull

                  Xenotime

                  [(YPO4)] ndash

                  Contains 54ndash65 rare earth oxides

                  ndash

                  Yttrium Erbium and Cerium most common ndash

                  Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                  Electron Configuration

                  bull

                  The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                  bull

                  REEs

                  have same outer electronic configuration (+3) they differ in their number of 4f electrons

                  Electron Configuartion

                  REE Behaviorbull

                  Because of their shared behaviour REEs

                  tend to be

                  present in nature as a group All REEs

                  commonly substitute for one another in minerals

                  bull

                  Yet the REEs

                  are capable of showing great variation in their distributions

                  bull

                  Comes about due to ndash

                  Differences in ionic radius ndash

                  Crystal structure (Coordination Number)ndash

                  Basicity

                  of the mineral ndash

                  The elementrsquos solubility and ability to migrate in the environment ndash

                  Content of REEs

                  in source fluids

                  Ionic Radiusbull

                  The ionic radius of the REEs

                  is inversely related to atomic number

                  bull

                  The heavy rare earths are smaller ndash

                  more similar to Mn2+ (ionic radius 008 nanometers)

                  bull

                  LREEs

                  are largerndash

                  more comparable in size to Ca2+ (ionic radius 01 nanometer)

                  bull

                  Charge balance achieved through some sites being left vacant or

                  by coupled substitution with lower charged mineral (Na+)

                  In nanometers

                  Coordination Number

                  bull

                  Coordination number the number of atoms touching a particular atom in a crystal lattice

                  bull

                  Coordination number for this structure is 8

                  Coordination Numberbull

                  The heavy and light REEs

                  differ in the coordination

                  numbers (CN) with oxygenndash

                  HREEs

                  have CN between six to nine ndash

                  LREEs

                  have higher CNs

                  bull

                  Minerals with high CNs

                  associated with REE site

                  will favor LREEsndash

                  Bastnasite

                  CN = 11 ndash

                  Monazite CN = 9

                  bull

                  Those with low CNs

                  will preferentially select HREEs ndash

                  Xenotime

                  has a value of 8

                  Other Factorsbull

                  Minerals basicityndash

                  Alkalic

                  rocks host minerals with elevated LREE content ndash

                  Rocks with lower basicity

                  have lower amounts of LREEs

                  relative to their HREE content

                  bull

                  Solubilityndash

                  LREEs

                  are more soluble in water then the HREEsndash

                  Important characteristic for hydrothermally derived minerals

                  bull

                  MagmaHydrothermal fluid compositionndash

                  Minerals will take what they can get

                  REEs

                  and Economicsbull

                  The REEs

                  and Yttrium have a very broad range of applications mostly in high technology fields

                  bull

                  84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                  bull

                  REEs

                  used primarily for automotive (25) petroleum (22) and metallurgic (20)

                  HREEs

                  and Magnetism

                  bull

                  HREEs

                  exhibit complex magnetic behaviour on account of electron structurendash

                  They share the same outer shell electron configuration (valence = +3)

                  ndash

                  Differ in number of 4f electrons

                  Applications in Magnetismbull

                  Terbium and

                  Dysprosium

                  bull

                  Components of Terfenol-D

                  alloy

                  with the formula Tb(03) Dy(07) Fe(19)

                  bull

                  Has the higher magnetostriction

                  then any other alloyndash

                  expands and contracts in magnetic field

                  bull

                  Developed by American Navy for sonar

                  systems ndash

                  Now has applications in magnetomechanical

                  sensors and other electronic devices

                  Applications in Magnetism

                  bull

                  Holmium

                  bull

                  Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                  elements

                  bull

                  Creates the strongest artificially generated magnetic fieldsndash

                  In research where strong magnetic fields are needed

                  HREEs

                  and Nuclear Technology

                  bull

                  Dysprosium Homium Erbium

                  bull

                  High neutron

                  absorption cross-section ndash

                  Measure of probability of neutron capture

                  bull

                  Used in neutron-absorbing control rods in nuclear reactors

                  HREEs

                  and Nuclear Technology

                  bull

                  Lutetiumbull

                  Radioactive isotope used in radiometric dating

                  bull

                  Thulium bull

                  Stable thulium used as a radiation

                  source

                  in portable X-ray

                  devices

                  Mountain Passbull

                  Bastnasite

                  is the major REE mineral bull

                  High grade accessory mineral of igneous or hydrothermal originsbull

                  31 million tons of 886 by weight of rare earth oxides (REO) bull

                  Mining stopped in 1994 ndash

                  Thorium content of waste rock ndash

                  Availability of inexpensive REEs

                  from China

                  San Bernardino County

                  Bayan

                  Obobull

                  The worldrsquos primary source for both yttrium and the rare earth elements

                  bull

                  37 million tons of ore bull

                  Main REE source there is Bastnasite

                  World Production

                  Explorationbull

                  84 of REE imports to US are from China

                  bull

                  Increasing demand for high tech applications spurred increase in exploration in 2007

                  bull

                  Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                  Lake as well as in

                  Malawi Africa

                  Environmental Considerations

                  bull

                  REE soil and food contaminationbull

                  Acid Mine Drainage and groundwater systems

                  bull

                  Radioactive elements

                  REE Fertilizerbull

                  In China REE enriched fertilizer has been used in crop fields since 1990

                  bull

                  At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                  every year

                  bull

                  Research and agricultural practice that provides evidence that REEs

                  will improve crop quality an yield

                  bull

                  The ramifications environmental and human exposure to REEs

                  are not well understood

                  Investigation by T Liang et albull

                  Revealed that the average concentration of total REEs

                  in Chinese soil is

                  1768 mgkg ranging between 850 to 5227 mgkg

                  bull

                  In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                  Implicationsbull

                  Human health effects not completely understood

                  bull

                  REE soil content shown to be detrimental to some plant speciesndash

                  100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                  Acid Mine Drainage (AMD)bull

                  Rain waters contacts waste rock facilitating acid forming reactions

                  bull

                  Increases the capacity of the water to leach potentially harmful elements from waste piles

                  bull

                  Process mobilizes established ecotoxins

                  (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                  bull

                  Historically dismissed as minor environmental risk

                  Radioactive Elements

                  bull

                  REEs

                  associated with uranium and thorium

                  bull

                  Bastnesite 32 thorium

                  bull

                  Monazite sands 6 to 12 thorium oxide

                  bull

                  Ores containing radioactive elements are avoided as sources of REEs

                  Radioactive Hazardsbull

                  Mountain Pass

                  bull

                  Accidentsndash

                  In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                  bull

                  Health Effectsndash

                  inflammatory bowel disease ndash

                  Prolonged seizures ndash

                  Cysts ndash

                  Cancers

                  bull

                  Waste Disposal ndash

                  Yucca Mountain

                  Summarybull

                  REE concentrations in the crust are rare

                  bull

                  Several geochemical factors influencing distribution including ionic radius and coordination number

                  bull

                  Main REE minerals are bastnasite monazite and xenotime

                  bull

                  Most important deposits are found at Bayan

                  Obo China and Mountain Pass USA

                  bull

                  Important electronic and nuclear applications

                  bull

                  Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                  system contamination though acid mine drainage association with

                  radioactive elements

                  Referencesbull

                  E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                  bull

                  Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                  bull

                  G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                  bull

                  B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                  The Government of South Australia wwwpirsagovaubull

                  The US geological Survey Mineralsusgsgovbull

                  wwwelementsdatabasecombull

                  wwwastrolsaumichedu~cowleyintro2htmlbull

                  wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                  webmineralcomdataMonazite-(Ce)shtmlbull

                  wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                  wwwstevegbcomimagesscienceorbital_fillingpngbull

                  wwwchemicalelementscomelementseuhtmlbull

                  boomeriaorgchemlecturestextass2table10-9jpgbull

                  lostcontentquakecomfiles200802holmiumpngbull

                  chinageocitylocatorcomcitiesChinaQinghaibull

                  geowebrudruzal-Bayan-Obohtmbull

                  enwikipediaorgwikiSan_Bernardino_County_Californiabull

                  wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                  enwikipediaorgwikiMonazitebull

                  webmineralcomdataBastnasite-(La)shtmlbull

                  wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                  httpwwwavalonventurescombull

                  wwwnewsweekcomid43884bull

                  httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                  httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                  • Slide Number 1
                  • Slide Number 2
                  • Slide Number 3
                  • Slide Number 4
                  • Slide Number 5
                  • Slide Number 6
                  • Slide Number 7
                  • Slide Number 8
                  • Slide Number 9
                  • Slide Number 10
                  • Slide Number 11
                  • Slide Number 12
                  • Slide Number 13
                  • Slide Number 14
                  • Slide Number 15
                  • Slide Number 16
                  • Slide Number 17
                  • Slide Number 18
                  • Slide Number 19
                  • Slide Number 20
                  • Slide Number 21
                  • Slide Number 22
                  • Slide Number 23
                  • Slide Number 24
                  • Slide Number 25
                  • Slide Number 26
                  • Slide Number 27
                  • Slide Number 28
                  • Slide Number 29
                  • Slide Number 30
                  • Slide Number 31
                  • Slide Number 32
                  • Slide Number 33
                  • Slide Number 34
                  • Slide Number 35
                  • Slide Number 36
                  • Slide Number 37
                  • Slide Number 38
                  • Slide Number 39
                  • Slide Number 40
                  • Slide Number 41
                  • Slide Number 42
                  • Slide Number 43
                  • Slide Number 44
                  • Slide Number 45
                  • Slide Number 46
                  • Slide Number 47
                  • Slide Number 48
                  • Slide Number 49
                  • Slide Number 50
                  • Slide Number 51
                  • Rare Earth Elements
                  • Crustal Abundances of Elements
                  • Occurrence
                  • Rare Earth Minerals
                  • REE Minerals
                  • Bastnesite
                  • Other REE minerals
                  • Electron Configuration
                  • Electron Configuartion
                  • REE Behavior
                  • Ionic Radius
                  • Coordination Number
                  • Coordination Number
                  • Other Factors
                  • REEs and Economics
                  • HREEs and Magnetism
                  • Applications in Magnetism
                  • Applications in Magnetism
                  • HREEs and Nuclear Technology
                  • HREEs and Nuclear Technology
                  • Mountain Pass
                  • Bayan Obo
                  • World Production
                  • Exploration
                  • Environmental Considerations
                  • REE Fertilizer
                  • Investigation by T Liang et al
                  • Implications
                  • Acid Mine Drainage (AMD)
                  • Radioactive Elements
                  • Radioactive Hazards
                  • Summary
                  • References

                    Kvanefjeld REE-U deposit Ilimaussaq Complex

                    bull

                    This new resource statement estimates the inventory of contained metal within

                    a 457 Mt

                    ore body to be 491 Mt

                    of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

                    bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

                    Kvanefjeld REE-U deposit Ilimaussaq Complex

                    Kvanefjeld REE-U deposit

                    Model for Peralkalic Magma Systems

                    BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

                    Contact pegmatiteContact pegmatiteapliteaplite

                    EndograniticEndograniticpegmatitepegmatite

                    Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

                    APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

                    WelsfordWelsford Dyke swarmsDyke swarms

                    Welsford

                    model

                    Marsh (1995)

                    Major Rare Earth Sources

                    Mineral

                    Composition

                    Occurrence

                    Bastnaumlsite

                    (Ce) (REE) CO3

                    F

                    Carbonatites

                    Monazite (Ce) (REE) PO4

                    Beach Sands Hydrothermal

                    Xenotime

                    (Y) (YREE) PO4

                    Beach Sands Hydrothermal

                    Loparite

                    (Ce) (REENaCa) (Ti NbTa)O3

                    Alkaline igneous massif

                    South China Clays (Ion-adsorbed REE+Y in Clays)

                    Uraninite

                    (REE and Y mdash

                    Released as dissolved elements

                    in rafinates

                    from uraninite)

                    Monazite pseudomorph

                    after apatite Monazite pseudomorph

                    after Rhabdophane

                    Florencite

                    pseudomorph

                    after pyrochlore Churchite

                    YPO4

                    middot2H2

                    O

                    Supergene Minerals ndash

                    MT Weld Australia

                    Apatite

                    with Substitutional

                    REE

                    Oka Quebec

                    Carbonatite

                    Nolanrsquos Bore Australia

                    Carbonatite

                    Mushgai

                    Khudag Mongolia

                    Carbonatite

                    Phalaborwa South Africa

                    Carbonatite

                    Kola Peninsula

                    Carbonatite

                    and Alkaline Massifs

                    Hoidas

                    Lake Saskatchewan

                    Hydrothermal in Granites

                    Mineville New York

                    Tailings from Magnetite Mining

                    Mineville may be the only Y and HREE dominant source currently known

                    HD -

                    176 mm HD -

                    44 mm

                    XPL MicrographsBastnaumlsite

                    in Carbonatite

                    Mountain Pass CA

                    BSE Image AncyliteHD ndash

                    07 mm

                    PPL Micrograph Ancylite

                    Ancylite

                    (Ce)

                    SrREE(CO3

                    )2

                    (OH)H2

                    O

                    LREE -

                    dominant ndash

                    50 wt REO

                    An exploration target in the

                    Bear Lodge Carbonatite

                    Complex of northeastern Wyoming

                    Red Wine Complex Labrador Dora Bay Alaska

                    Eudialyte

                    Na15

                    Ca6

                    (Fe2+Mn2+)3

                    Zr3

                    (SiNb)(Si25

                    O73

                    )(OOHH2

                    O)3

                    (CLOH)2

                    Eudialyite

                    may also contain Y and HREE

                    in amounts exceeding 4 wt The

                    mineral is easily dissolved in weak acids

                    but colloidal silica currently presents a

                    problem in the isolation of Y REE and Zr

                    oxides

                    Kipawa Quebec

                    Massive Britholite

                    (Ce) Oka Quebec

                    Britholite

                    (Ce) Concentrate from Skarn

                    Kipawa Quebec

                    Britholite

                    ndash

                    (REEYCa)5

                    (SiO4

                    PO4

                    )3

                    (OHF)

                    This mineral has the potential for occurring in ore quantities in skarn

                    associated with syenite

                    gneiss in Kipawa Quebec

                    Allanite

                    (Ce) (CeCaY)2

                    (AlFe2+Fe3+)3

                    (SiO4

                    )3

                    (OH)

                    Allanite

                    is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                    Allanite

                    ndash

                    Hydrothermal Mountain Pass CA Allanite

                    ndash

                    Pegmatite Timmins Ontario

                    Eudialyte

                    and Mosandrite

                    in Peralkaline

                    Syenite

                    Kipawa Quebec

                    Britholite-Rich Skarn

                    All brown prisms are britholite

                    (Horizontal Distance ndash 46 mm)

                    Britholite

                    Concentrate

                    (mm scale)

                    Britholite

                    ndash

                    (CeYCa)5 (SiO4PO4 )3 (OHF)

                    Kipawa Quebec

                    Cathodoluminescence

                    Macrograph of Iimoriite

                    in Syenite

                    ndash

                    Bokan

                    Mountain

                    Mottled light blue and tan clusters -

                    Iimoriite

                    Red groundmass ndash

                    Feldspar

                    (Horizontal distance of rock slab ndash 46 mm)

                    Iimoriite

                    (Y)

                    Y2 (SiO4 )(CO3 )

                    Yttrofluorite

                    (CaY)F2

                    Iimoriite

                    Concentrate ndash

                    Bokan

                    MT (1 mm scale)

                    Wicheeda

                    Lake Heavy Mineral Composite mdash

                    (from samples 828951 52 53)

                    These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                    and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                    As a final statement it should be emphasizedhellip

                    1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                    2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                    3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                    4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                    5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                    Rare Earth Elements

                    bull

                    Name something of a misnomerndash

                    Rarest REEs

                    are over 200 times more

                    abundant then gold

                    bull

                    Variation in distribution for two reasons ndash

                    Compatibility with common rock forming materials

                    ndash

                    CosmicCrustal abundances

                    Crustal Abundances of Elements

                    Occurrencebull

                    REEs

                    occur mostly as

                    substitutional

                    impurities in many rock forming minerals

                    bull

                    Only a few the REE minerals have sufficient quantities to be considered important sources

                    bull

                    Defined as minerals having at least one site that is filled by REEs

                    andor Yttrium more often then any other elementMonazite

                    Rare Earth Minerals

                    bull

                    Form by primary crystalization

                    from magma or by hydrothermal reactions

                    bull

                    Found hosted in carbonate rocks in pegmatites

                    and as accessory minerals in

                    igneous rocks

                    bull

                    Stable REE minerals and can be concentrated in weathering zones

                    REE Mineralsbull

                    The most important REE minerals is bastnaumlsite

                    REE(CO3)F

                    bull

                    Other notable sources are ndash

                    Monazite REE(PO4) ndash

                    Xenotime

                    YPO4

                    bull

                    All may contain radioactive species such as thorium

                    and uraniumndash

                    are avoided as source materials

                    Bastnesitebull

                    Bastnasite

                    [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                    bull

                    Containing 60 to 70 rare earth oxides (REOs)

                    bull

                    REE site is most commonly filled by LREEs

                    and Y

                    Other REE mineralsbull

                    Monazite [(LREEYTh)PO4] ndash

                    Contains about 50ndash78 rare earth oxides

                    ndash

                    Forms in heavy mineral sands placer deposits associated with beach environments

                    bull

                    Xenotime

                    [(YPO4)] ndash

                    Contains 54ndash65 rare earth oxides

                    ndash

                    Yttrium Erbium and Cerium most common ndash

                    Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                    Electron Configuration

                    bull

                    The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                    bull

                    REEs

                    have same outer electronic configuration (+3) they differ in their number of 4f electrons

                    Electron Configuartion

                    REE Behaviorbull

                    Because of their shared behaviour REEs

                    tend to be

                    present in nature as a group All REEs

                    commonly substitute for one another in minerals

                    bull

                    Yet the REEs

                    are capable of showing great variation in their distributions

                    bull

                    Comes about due to ndash

                    Differences in ionic radius ndash

                    Crystal structure (Coordination Number)ndash

                    Basicity

                    of the mineral ndash

                    The elementrsquos solubility and ability to migrate in the environment ndash

                    Content of REEs

                    in source fluids

                    Ionic Radiusbull

                    The ionic radius of the REEs

                    is inversely related to atomic number

                    bull

                    The heavy rare earths are smaller ndash

                    more similar to Mn2+ (ionic radius 008 nanometers)

                    bull

                    LREEs

                    are largerndash

                    more comparable in size to Ca2+ (ionic radius 01 nanometer)

                    bull

                    Charge balance achieved through some sites being left vacant or

                    by coupled substitution with lower charged mineral (Na+)

                    In nanometers

                    Coordination Number

                    bull

                    Coordination number the number of atoms touching a particular atom in a crystal lattice

                    bull

                    Coordination number for this structure is 8

                    Coordination Numberbull

                    The heavy and light REEs

                    differ in the coordination

                    numbers (CN) with oxygenndash

                    HREEs

                    have CN between six to nine ndash

                    LREEs

                    have higher CNs

                    bull

                    Minerals with high CNs

                    associated with REE site

                    will favor LREEsndash

                    Bastnasite

                    CN = 11 ndash

                    Monazite CN = 9

                    bull

                    Those with low CNs

                    will preferentially select HREEs ndash

                    Xenotime

                    has a value of 8

                    Other Factorsbull

                    Minerals basicityndash

                    Alkalic

                    rocks host minerals with elevated LREE content ndash

                    Rocks with lower basicity

                    have lower amounts of LREEs

                    relative to their HREE content

                    bull

                    Solubilityndash

                    LREEs

                    are more soluble in water then the HREEsndash

                    Important characteristic for hydrothermally derived minerals

                    bull

                    MagmaHydrothermal fluid compositionndash

                    Minerals will take what they can get

                    REEs

                    and Economicsbull

                    The REEs

                    and Yttrium have a very broad range of applications mostly in high technology fields

                    bull

                    84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                    bull

                    REEs

                    used primarily for automotive (25) petroleum (22) and metallurgic (20)

                    HREEs

                    and Magnetism

                    bull

                    HREEs

                    exhibit complex magnetic behaviour on account of electron structurendash

                    They share the same outer shell electron configuration (valence = +3)

                    ndash

                    Differ in number of 4f electrons

                    Applications in Magnetismbull

                    Terbium and

                    Dysprosium

                    bull

                    Components of Terfenol-D

                    alloy

                    with the formula Tb(03) Dy(07) Fe(19)

                    bull

                    Has the higher magnetostriction

                    then any other alloyndash

                    expands and contracts in magnetic field

                    bull

                    Developed by American Navy for sonar

                    systems ndash

                    Now has applications in magnetomechanical

                    sensors and other electronic devices

                    Applications in Magnetism

                    bull

                    Holmium

                    bull

                    Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                    elements

                    bull

                    Creates the strongest artificially generated magnetic fieldsndash

                    In research where strong magnetic fields are needed

                    HREEs

                    and Nuclear Technology

                    bull

                    Dysprosium Homium Erbium

                    bull

                    High neutron

                    absorption cross-section ndash

                    Measure of probability of neutron capture

                    bull

                    Used in neutron-absorbing control rods in nuclear reactors

                    HREEs

                    and Nuclear Technology

                    bull

                    Lutetiumbull

                    Radioactive isotope used in radiometric dating

                    bull

                    Thulium bull

                    Stable thulium used as a radiation

                    source

                    in portable X-ray

                    devices

                    Mountain Passbull

                    Bastnasite

                    is the major REE mineral bull

                    High grade accessory mineral of igneous or hydrothermal originsbull

                    31 million tons of 886 by weight of rare earth oxides (REO) bull

                    Mining stopped in 1994 ndash

                    Thorium content of waste rock ndash

                    Availability of inexpensive REEs

                    from China

                    San Bernardino County

                    Bayan

                    Obobull

                    The worldrsquos primary source for both yttrium and the rare earth elements

                    bull

                    37 million tons of ore bull

                    Main REE source there is Bastnasite

                    World Production

                    Explorationbull

                    84 of REE imports to US are from China

                    bull

                    Increasing demand for high tech applications spurred increase in exploration in 2007

                    bull

                    Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                    Lake as well as in

                    Malawi Africa

                    Environmental Considerations

                    bull

                    REE soil and food contaminationbull

                    Acid Mine Drainage and groundwater systems

                    bull

                    Radioactive elements

                    REE Fertilizerbull

                    In China REE enriched fertilizer has been used in crop fields since 1990

                    bull

                    At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                    every year

                    bull

                    Research and agricultural practice that provides evidence that REEs

                    will improve crop quality an yield

                    bull

                    The ramifications environmental and human exposure to REEs

                    are not well understood

                    Investigation by T Liang et albull

                    Revealed that the average concentration of total REEs

                    in Chinese soil is

                    1768 mgkg ranging between 850 to 5227 mgkg

                    bull

                    In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                    Implicationsbull

                    Human health effects not completely understood

                    bull

                    REE soil content shown to be detrimental to some plant speciesndash

                    100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                    Acid Mine Drainage (AMD)bull

                    Rain waters contacts waste rock facilitating acid forming reactions

                    bull

                    Increases the capacity of the water to leach potentially harmful elements from waste piles

                    bull

                    Process mobilizes established ecotoxins

                    (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                    bull

                    Historically dismissed as minor environmental risk

                    Radioactive Elements

                    bull

                    REEs

                    associated with uranium and thorium

                    bull

                    Bastnesite 32 thorium

                    bull

                    Monazite sands 6 to 12 thorium oxide

                    bull

                    Ores containing radioactive elements are avoided as sources of REEs

                    Radioactive Hazardsbull

                    Mountain Pass

                    bull

                    Accidentsndash

                    In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                    bull

                    Health Effectsndash

                    inflammatory bowel disease ndash

                    Prolonged seizures ndash

                    Cysts ndash

                    Cancers

                    bull

                    Waste Disposal ndash

                    Yucca Mountain

                    Summarybull

                    REE concentrations in the crust are rare

                    bull

                    Several geochemical factors influencing distribution including ionic radius and coordination number

                    bull

                    Main REE minerals are bastnasite monazite and xenotime

                    bull

                    Most important deposits are found at Bayan

                    Obo China and Mountain Pass USA

                    bull

                    Important electronic and nuclear applications

                    bull

                    Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                    system contamination though acid mine drainage association with

                    radioactive elements

                    Referencesbull

                    E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                    bull

                    Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                    bull

                    G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                    bull

                    B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                    The Government of South Australia wwwpirsagovaubull

                    The US geological Survey Mineralsusgsgovbull

                    wwwelementsdatabasecombull

                    wwwastrolsaumichedu~cowleyintro2htmlbull

                    wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                    webmineralcomdataMonazite-(Ce)shtmlbull

                    wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                    wwwstevegbcomimagesscienceorbital_fillingpngbull

                    wwwchemicalelementscomelementseuhtmlbull

                    boomeriaorgchemlecturestextass2table10-9jpgbull

                    lostcontentquakecomfiles200802holmiumpngbull

                    chinageocitylocatorcomcitiesChinaQinghaibull

                    geowebrudruzal-Bayan-Obohtmbull

                    enwikipediaorgwikiSan_Bernardino_County_Californiabull

                    wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                    enwikipediaorgwikiMonazitebull

                    webmineralcomdataBastnasite-(La)shtmlbull

                    wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                    httpwwwavalonventurescombull

                    wwwnewsweekcomid43884bull

                    httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                    httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                    • Slide Number 1
                    • Slide Number 2
                    • Slide Number 3
                    • Slide Number 4
                    • Slide Number 5
                    • Slide Number 6
                    • Slide Number 7
                    • Slide Number 8
                    • Slide Number 9
                    • Slide Number 10
                    • Slide Number 11
                    • Slide Number 12
                    • Slide Number 13
                    • Slide Number 14
                    • Slide Number 15
                    • Slide Number 16
                    • Slide Number 17
                    • Slide Number 18
                    • Slide Number 19
                    • Slide Number 20
                    • Slide Number 21
                    • Slide Number 22
                    • Slide Number 23
                    • Slide Number 24
                    • Slide Number 25
                    • Slide Number 26
                    • Slide Number 27
                    • Slide Number 28
                    • Slide Number 29
                    • Slide Number 30
                    • Slide Number 31
                    • Slide Number 32
                    • Slide Number 33
                    • Slide Number 34
                    • Slide Number 35
                    • Slide Number 36
                    • Slide Number 37
                    • Slide Number 38
                    • Slide Number 39
                    • Slide Number 40
                    • Slide Number 41
                    • Slide Number 42
                    • Slide Number 43
                    • Slide Number 44
                    • Slide Number 45
                    • Slide Number 46
                    • Slide Number 47
                    • Slide Number 48
                    • Slide Number 49
                    • Slide Number 50
                    • Slide Number 51
                    • Rare Earth Elements
                    • Crustal Abundances of Elements
                    • Occurrence
                    • Rare Earth Minerals
                    • REE Minerals
                    • Bastnesite
                    • Other REE minerals
                    • Electron Configuration
                    • Electron Configuartion
                    • REE Behavior
                    • Ionic Radius
                    • Coordination Number
                    • Coordination Number
                    • Other Factors
                    • REEs and Economics
                    • HREEs and Magnetism
                    • Applications in Magnetism
                    • Applications in Magnetism
                    • HREEs and Nuclear Technology
                    • HREEs and Nuclear Technology
                    • Mountain Pass
                    • Bayan Obo
                    • World Production
                    • Exploration
                    • Environmental Considerations
                    • REE Fertilizer
                    • Investigation by T Liang et al
                    • Implications
                    • Acid Mine Drainage (AMD)
                    • Radioactive Elements
                    • Radioactive Hazards
                    • Summary
                    • References

                      bull

                      This new resource statement estimates the inventory of contained metal within

                      a 457 Mt

                      ore body to be 491 Mt

                      of Total Rare Earth Oxide (TREO) 099 Mt and Zinc 012 Mt of Uranium Oxide (283 Mlbs) and 309 Mt of NaF

                      bull Indicated amp Inferred 457 Mt0028 U3O8 107 TREO 022 Zn at a015 U3O8 cut off

                      Kvanefjeld REE-U deposit Ilimaussaq Complex

                      Kvanefjeld REE-U deposit

                      Model for Peralkalic Magma Systems

                      BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

                      Contact pegmatiteContact pegmatiteapliteaplite

                      EndograniticEndograniticpegmatitepegmatite

                      Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

                      APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

                      WelsfordWelsford Dyke swarmsDyke swarms

                      Welsford

                      model

                      Marsh (1995)

                      Major Rare Earth Sources

                      Mineral

                      Composition

                      Occurrence

                      Bastnaumlsite

                      (Ce) (REE) CO3

                      F

                      Carbonatites

                      Monazite (Ce) (REE) PO4

                      Beach Sands Hydrothermal

                      Xenotime

                      (Y) (YREE) PO4

                      Beach Sands Hydrothermal

                      Loparite

                      (Ce) (REENaCa) (Ti NbTa)O3

                      Alkaline igneous massif

                      South China Clays (Ion-adsorbed REE+Y in Clays)

                      Uraninite

                      (REE and Y mdash

                      Released as dissolved elements

                      in rafinates

                      from uraninite)

                      Monazite pseudomorph

                      after apatite Monazite pseudomorph

                      after Rhabdophane

                      Florencite

                      pseudomorph

                      after pyrochlore Churchite

                      YPO4

                      middot2H2

                      O

                      Supergene Minerals ndash

                      MT Weld Australia

                      Apatite

                      with Substitutional

                      REE

                      Oka Quebec

                      Carbonatite

                      Nolanrsquos Bore Australia

                      Carbonatite

                      Mushgai

                      Khudag Mongolia

                      Carbonatite

                      Phalaborwa South Africa

                      Carbonatite

                      Kola Peninsula

                      Carbonatite

                      and Alkaline Massifs

                      Hoidas

                      Lake Saskatchewan

                      Hydrothermal in Granites

                      Mineville New York

                      Tailings from Magnetite Mining

                      Mineville may be the only Y and HREE dominant source currently known

                      HD -

                      176 mm HD -

                      44 mm

                      XPL MicrographsBastnaumlsite

                      in Carbonatite

                      Mountain Pass CA

                      BSE Image AncyliteHD ndash

                      07 mm

                      PPL Micrograph Ancylite

                      Ancylite

                      (Ce)

                      SrREE(CO3

                      )2

                      (OH)H2

                      O

                      LREE -

                      dominant ndash

                      50 wt REO

                      An exploration target in the

                      Bear Lodge Carbonatite

                      Complex of northeastern Wyoming

                      Red Wine Complex Labrador Dora Bay Alaska

                      Eudialyte

                      Na15

                      Ca6

                      (Fe2+Mn2+)3

                      Zr3

                      (SiNb)(Si25

                      O73

                      )(OOHH2

                      O)3

                      (CLOH)2

                      Eudialyite

                      may also contain Y and HREE

                      in amounts exceeding 4 wt The

                      mineral is easily dissolved in weak acids

                      but colloidal silica currently presents a

                      problem in the isolation of Y REE and Zr

                      oxides

                      Kipawa Quebec

                      Massive Britholite

                      (Ce) Oka Quebec

                      Britholite

                      (Ce) Concentrate from Skarn

                      Kipawa Quebec

                      Britholite

                      ndash

                      (REEYCa)5

                      (SiO4

                      PO4

                      )3

                      (OHF)

                      This mineral has the potential for occurring in ore quantities in skarn

                      associated with syenite

                      gneiss in Kipawa Quebec

                      Allanite

                      (Ce) (CeCaY)2

                      (AlFe2+Fe3+)3

                      (SiO4

                      )3

                      (OH)

                      Allanite

                      is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                      Allanite

                      ndash

                      Hydrothermal Mountain Pass CA Allanite

                      ndash

                      Pegmatite Timmins Ontario

                      Eudialyte

                      and Mosandrite

                      in Peralkaline

                      Syenite

                      Kipawa Quebec

                      Britholite-Rich Skarn

                      All brown prisms are britholite

                      (Horizontal Distance ndash 46 mm)

                      Britholite

                      Concentrate

                      (mm scale)

                      Britholite

                      ndash

                      (CeYCa)5 (SiO4PO4 )3 (OHF)

                      Kipawa Quebec

                      Cathodoluminescence

                      Macrograph of Iimoriite

                      in Syenite

                      ndash

                      Bokan

                      Mountain

                      Mottled light blue and tan clusters -

                      Iimoriite

                      Red groundmass ndash

                      Feldspar

                      (Horizontal distance of rock slab ndash 46 mm)

                      Iimoriite

                      (Y)

                      Y2 (SiO4 )(CO3 )

                      Yttrofluorite

                      (CaY)F2

                      Iimoriite

                      Concentrate ndash

                      Bokan

                      MT (1 mm scale)

                      Wicheeda

                      Lake Heavy Mineral Composite mdash

                      (from samples 828951 52 53)

                      These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                      and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                      As a final statement it should be emphasizedhellip

                      1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                      2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                      3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                      4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                      5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                      Rare Earth Elements

                      bull

                      Name something of a misnomerndash

                      Rarest REEs

                      are over 200 times more

                      abundant then gold

                      bull

                      Variation in distribution for two reasons ndash

                      Compatibility with common rock forming materials

                      ndash

                      CosmicCrustal abundances

                      Crustal Abundances of Elements

                      Occurrencebull

                      REEs

                      occur mostly as

                      substitutional

                      impurities in many rock forming minerals

                      bull

                      Only a few the REE minerals have sufficient quantities to be considered important sources

                      bull

                      Defined as minerals having at least one site that is filled by REEs

                      andor Yttrium more often then any other elementMonazite

                      Rare Earth Minerals

                      bull

                      Form by primary crystalization

                      from magma or by hydrothermal reactions

                      bull

                      Found hosted in carbonate rocks in pegmatites

                      and as accessory minerals in

                      igneous rocks

                      bull

                      Stable REE minerals and can be concentrated in weathering zones

                      REE Mineralsbull

                      The most important REE minerals is bastnaumlsite

                      REE(CO3)F

                      bull

                      Other notable sources are ndash

                      Monazite REE(PO4) ndash

                      Xenotime

                      YPO4

                      bull

                      All may contain radioactive species such as thorium

                      and uraniumndash

                      are avoided as source materials

                      Bastnesitebull

                      Bastnasite

                      [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                      bull

                      Containing 60 to 70 rare earth oxides (REOs)

                      bull

                      REE site is most commonly filled by LREEs

                      and Y

                      Other REE mineralsbull

                      Monazite [(LREEYTh)PO4] ndash

                      Contains about 50ndash78 rare earth oxides

                      ndash

                      Forms in heavy mineral sands placer deposits associated with beach environments

                      bull

                      Xenotime

                      [(YPO4)] ndash

                      Contains 54ndash65 rare earth oxides

                      ndash

                      Yttrium Erbium and Cerium most common ndash

                      Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                      Electron Configuration

                      bull

                      The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                      bull

                      REEs

                      have same outer electronic configuration (+3) they differ in their number of 4f electrons

                      Electron Configuartion

                      REE Behaviorbull

                      Because of their shared behaviour REEs

                      tend to be

                      present in nature as a group All REEs

                      commonly substitute for one another in minerals

                      bull

                      Yet the REEs

                      are capable of showing great variation in their distributions

                      bull

                      Comes about due to ndash

                      Differences in ionic radius ndash

                      Crystal structure (Coordination Number)ndash

                      Basicity

                      of the mineral ndash

                      The elementrsquos solubility and ability to migrate in the environment ndash

                      Content of REEs

                      in source fluids

                      Ionic Radiusbull

                      The ionic radius of the REEs

                      is inversely related to atomic number

                      bull

                      The heavy rare earths are smaller ndash

                      more similar to Mn2+ (ionic radius 008 nanometers)

                      bull

                      LREEs

                      are largerndash

                      more comparable in size to Ca2+ (ionic radius 01 nanometer)

                      bull

                      Charge balance achieved through some sites being left vacant or

                      by coupled substitution with lower charged mineral (Na+)

                      In nanometers

                      Coordination Number

                      bull

                      Coordination number the number of atoms touching a particular atom in a crystal lattice

                      bull

                      Coordination number for this structure is 8

                      Coordination Numberbull

                      The heavy and light REEs

                      differ in the coordination

                      numbers (CN) with oxygenndash

                      HREEs

                      have CN between six to nine ndash

                      LREEs

                      have higher CNs

                      bull

                      Minerals with high CNs

                      associated with REE site

                      will favor LREEsndash

                      Bastnasite

                      CN = 11 ndash

                      Monazite CN = 9

                      bull

                      Those with low CNs

                      will preferentially select HREEs ndash

                      Xenotime

                      has a value of 8

                      Other Factorsbull

                      Minerals basicityndash

                      Alkalic

                      rocks host minerals with elevated LREE content ndash

                      Rocks with lower basicity

                      have lower amounts of LREEs

                      relative to their HREE content

                      bull

                      Solubilityndash

                      LREEs

                      are more soluble in water then the HREEsndash

                      Important characteristic for hydrothermally derived minerals

                      bull

                      MagmaHydrothermal fluid compositionndash

                      Minerals will take what they can get

                      REEs

                      and Economicsbull

                      The REEs

                      and Yttrium have a very broad range of applications mostly in high technology fields

                      bull

                      84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                      bull

                      REEs

                      used primarily for automotive (25) petroleum (22) and metallurgic (20)

                      HREEs

                      and Magnetism

                      bull

                      HREEs

                      exhibit complex magnetic behaviour on account of electron structurendash

                      They share the same outer shell electron configuration (valence = +3)

                      ndash

                      Differ in number of 4f electrons

                      Applications in Magnetismbull

                      Terbium and

                      Dysprosium

                      bull

                      Components of Terfenol-D

                      alloy

                      with the formula Tb(03) Dy(07) Fe(19)

                      bull

                      Has the higher magnetostriction

                      then any other alloyndash

                      expands and contracts in magnetic field

                      bull

                      Developed by American Navy for sonar

                      systems ndash

                      Now has applications in magnetomechanical

                      sensors and other electronic devices

                      Applications in Magnetism

                      bull

                      Holmium

                      bull

                      Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                      elements

                      bull

                      Creates the strongest artificially generated magnetic fieldsndash

                      In research where strong magnetic fields are needed

                      HREEs

                      and Nuclear Technology

                      bull

                      Dysprosium Homium Erbium

                      bull

                      High neutron

                      absorption cross-section ndash

                      Measure of probability of neutron capture

                      bull

                      Used in neutron-absorbing control rods in nuclear reactors

                      HREEs

                      and Nuclear Technology

                      bull

                      Lutetiumbull

                      Radioactive isotope used in radiometric dating

                      bull

                      Thulium bull

                      Stable thulium used as a radiation

                      source

                      in portable X-ray

                      devices

                      Mountain Passbull

                      Bastnasite

                      is the major REE mineral bull

                      High grade accessory mineral of igneous or hydrothermal originsbull

                      31 million tons of 886 by weight of rare earth oxides (REO) bull

                      Mining stopped in 1994 ndash

                      Thorium content of waste rock ndash

                      Availability of inexpensive REEs

                      from China

                      San Bernardino County

                      Bayan

                      Obobull

                      The worldrsquos primary source for both yttrium and the rare earth elements

                      bull

                      37 million tons of ore bull

                      Main REE source there is Bastnasite

                      World Production

                      Explorationbull

                      84 of REE imports to US are from China

                      bull

                      Increasing demand for high tech applications spurred increase in exploration in 2007

                      bull

                      Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                      Lake as well as in

                      Malawi Africa

                      Environmental Considerations

                      bull

                      REE soil and food contaminationbull

                      Acid Mine Drainage and groundwater systems

                      bull

                      Radioactive elements

                      REE Fertilizerbull

                      In China REE enriched fertilizer has been used in crop fields since 1990

                      bull

                      At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                      every year

                      bull

                      Research and agricultural practice that provides evidence that REEs

                      will improve crop quality an yield

                      bull

                      The ramifications environmental and human exposure to REEs

                      are not well understood

                      Investigation by T Liang et albull

                      Revealed that the average concentration of total REEs

                      in Chinese soil is

                      1768 mgkg ranging between 850 to 5227 mgkg

                      bull

                      In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                      Implicationsbull

                      Human health effects not completely understood

                      bull

                      REE soil content shown to be detrimental to some plant speciesndash

                      100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                      Acid Mine Drainage (AMD)bull

                      Rain waters contacts waste rock facilitating acid forming reactions

                      bull

                      Increases the capacity of the water to leach potentially harmful elements from waste piles

                      bull

                      Process mobilizes established ecotoxins

                      (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                      bull

                      Historically dismissed as minor environmental risk

                      Radioactive Elements

                      bull

                      REEs

                      associated with uranium and thorium

                      bull

                      Bastnesite 32 thorium

                      bull

                      Monazite sands 6 to 12 thorium oxide

                      bull

                      Ores containing radioactive elements are avoided as sources of REEs

                      Radioactive Hazardsbull

                      Mountain Pass

                      bull

                      Accidentsndash

                      In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                      bull

                      Health Effectsndash

                      inflammatory bowel disease ndash

                      Prolonged seizures ndash

                      Cysts ndash

                      Cancers

                      bull

                      Waste Disposal ndash

                      Yucca Mountain

                      Summarybull

                      REE concentrations in the crust are rare

                      bull

                      Several geochemical factors influencing distribution including ionic radius and coordination number

                      bull

                      Main REE minerals are bastnasite monazite and xenotime

                      bull

                      Most important deposits are found at Bayan

                      Obo China and Mountain Pass USA

                      bull

                      Important electronic and nuclear applications

                      bull

                      Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                      system contamination though acid mine drainage association with

                      radioactive elements

                      Referencesbull

                      E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                      bull

                      Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                      bull

                      G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                      bull

                      B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                      The Government of South Australia wwwpirsagovaubull

                      The US geological Survey Mineralsusgsgovbull

                      wwwelementsdatabasecombull

                      wwwastrolsaumichedu~cowleyintro2htmlbull

                      wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                      webmineralcomdataMonazite-(Ce)shtmlbull

                      wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                      wwwstevegbcomimagesscienceorbital_fillingpngbull

                      wwwchemicalelementscomelementseuhtmlbull

                      boomeriaorgchemlecturestextass2table10-9jpgbull

                      lostcontentquakecomfiles200802holmiumpngbull

                      chinageocitylocatorcomcitiesChinaQinghaibull

                      geowebrudruzal-Bayan-Obohtmbull

                      enwikipediaorgwikiSan_Bernardino_County_Californiabull

                      wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                      enwikipediaorgwikiMonazitebull

                      webmineralcomdataBastnasite-(La)shtmlbull

                      wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                      httpwwwavalonventurescombull

                      wwwnewsweekcomid43884bull

                      httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                      httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                      • Slide Number 1
                      • Slide Number 2
                      • Slide Number 3
                      • Slide Number 4
                      • Slide Number 5
                      • Slide Number 6
                      • Slide Number 7
                      • Slide Number 8
                      • Slide Number 9
                      • Slide Number 10
                      • Slide Number 11
                      • Slide Number 12
                      • Slide Number 13
                      • Slide Number 14
                      • Slide Number 15
                      • Slide Number 16
                      • Slide Number 17
                      • Slide Number 18
                      • Slide Number 19
                      • Slide Number 20
                      • Slide Number 21
                      • Slide Number 22
                      • Slide Number 23
                      • Slide Number 24
                      • Slide Number 25
                      • Slide Number 26
                      • Slide Number 27
                      • Slide Number 28
                      • Slide Number 29
                      • Slide Number 30
                      • Slide Number 31
                      • Slide Number 32
                      • Slide Number 33
                      • Slide Number 34
                      • Slide Number 35
                      • Slide Number 36
                      • Slide Number 37
                      • Slide Number 38
                      • Slide Number 39
                      • Slide Number 40
                      • Slide Number 41
                      • Slide Number 42
                      • Slide Number 43
                      • Slide Number 44
                      • Slide Number 45
                      • Slide Number 46
                      • Slide Number 47
                      • Slide Number 48
                      • Slide Number 49
                      • Slide Number 50
                      • Slide Number 51
                      • Rare Earth Elements
                      • Crustal Abundances of Elements
                      • Occurrence
                      • Rare Earth Minerals
                      • REE Minerals
                      • Bastnesite
                      • Other REE minerals
                      • Electron Configuration
                      • Electron Configuartion
                      • REE Behavior
                      • Ionic Radius
                      • Coordination Number
                      • Coordination Number
                      • Other Factors
                      • REEs and Economics
                      • HREEs and Magnetism
                      • Applications in Magnetism
                      • Applications in Magnetism
                      • HREEs and Nuclear Technology
                      • HREEs and Nuclear Technology
                      • Mountain Pass
                      • Bayan Obo
                      • World Production
                      • Exploration
                      • Environmental Considerations
                      • REE Fertilizer
                      • Investigation by T Liang et al
                      • Implications
                      • Acid Mine Drainage (AMD)
                      • Radioactive Elements
                      • Radioactive Hazards
                      • Summary
                      • References

                        Kvanefjeld REE-U deposit

                        Model for Peralkalic Magma Systems

                        BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

                        Contact pegmatiteContact pegmatiteapliteaplite

                        EndograniticEndograniticpegmatitepegmatite

                        Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

                        APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

                        WelsfordWelsford Dyke swarmsDyke swarms

                        Welsford

                        model

                        Marsh (1995)

                        Major Rare Earth Sources

                        Mineral

                        Composition

                        Occurrence

                        Bastnaumlsite

                        (Ce) (REE) CO3

                        F

                        Carbonatites

                        Monazite (Ce) (REE) PO4

                        Beach Sands Hydrothermal

                        Xenotime

                        (Y) (YREE) PO4

                        Beach Sands Hydrothermal

                        Loparite

                        (Ce) (REENaCa) (Ti NbTa)O3

                        Alkaline igneous massif

                        South China Clays (Ion-adsorbed REE+Y in Clays)

                        Uraninite

                        (REE and Y mdash

                        Released as dissolved elements

                        in rafinates

                        from uraninite)

                        Monazite pseudomorph

                        after apatite Monazite pseudomorph

                        after Rhabdophane

                        Florencite

                        pseudomorph

                        after pyrochlore Churchite

                        YPO4

                        middot2H2

                        O

                        Supergene Minerals ndash

                        MT Weld Australia

                        Apatite

                        with Substitutional

                        REE

                        Oka Quebec

                        Carbonatite

                        Nolanrsquos Bore Australia

                        Carbonatite

                        Mushgai

                        Khudag Mongolia

                        Carbonatite

                        Phalaborwa South Africa

                        Carbonatite

                        Kola Peninsula

                        Carbonatite

                        and Alkaline Massifs

                        Hoidas

                        Lake Saskatchewan

                        Hydrothermal in Granites

                        Mineville New York

                        Tailings from Magnetite Mining

                        Mineville may be the only Y and HREE dominant source currently known

                        HD -

                        176 mm HD -

                        44 mm

                        XPL MicrographsBastnaumlsite

                        in Carbonatite

                        Mountain Pass CA

                        BSE Image AncyliteHD ndash

                        07 mm

                        PPL Micrograph Ancylite

                        Ancylite

                        (Ce)

                        SrREE(CO3

                        )2

                        (OH)H2

                        O

                        LREE -

                        dominant ndash

                        50 wt REO

                        An exploration target in the

                        Bear Lodge Carbonatite

                        Complex of northeastern Wyoming

                        Red Wine Complex Labrador Dora Bay Alaska

                        Eudialyte

                        Na15

                        Ca6

                        (Fe2+Mn2+)3

                        Zr3

                        (SiNb)(Si25

                        O73

                        )(OOHH2

                        O)3

                        (CLOH)2

                        Eudialyite

                        may also contain Y and HREE

                        in amounts exceeding 4 wt The

                        mineral is easily dissolved in weak acids

                        but colloidal silica currently presents a

                        problem in the isolation of Y REE and Zr

                        oxides

                        Kipawa Quebec

                        Massive Britholite

                        (Ce) Oka Quebec

                        Britholite

                        (Ce) Concentrate from Skarn

                        Kipawa Quebec

                        Britholite

                        ndash

                        (REEYCa)5

                        (SiO4

                        PO4

                        )3

                        (OHF)

                        This mineral has the potential for occurring in ore quantities in skarn

                        associated with syenite

                        gneiss in Kipawa Quebec

                        Allanite

                        (Ce) (CeCaY)2

                        (AlFe2+Fe3+)3

                        (SiO4

                        )3

                        (OH)

                        Allanite

                        is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                        Allanite

                        ndash

                        Hydrothermal Mountain Pass CA Allanite

                        ndash

                        Pegmatite Timmins Ontario

                        Eudialyte

                        and Mosandrite

                        in Peralkaline

                        Syenite

                        Kipawa Quebec

                        Britholite-Rich Skarn

                        All brown prisms are britholite

                        (Horizontal Distance ndash 46 mm)

                        Britholite

                        Concentrate

                        (mm scale)

                        Britholite

                        ndash

                        (CeYCa)5 (SiO4PO4 )3 (OHF)

                        Kipawa Quebec

                        Cathodoluminescence

                        Macrograph of Iimoriite

                        in Syenite

                        ndash

                        Bokan

                        Mountain

                        Mottled light blue and tan clusters -

                        Iimoriite

                        Red groundmass ndash

                        Feldspar

                        (Horizontal distance of rock slab ndash 46 mm)

                        Iimoriite

                        (Y)

                        Y2 (SiO4 )(CO3 )

                        Yttrofluorite

                        (CaY)F2

                        Iimoriite

                        Concentrate ndash

                        Bokan

                        MT (1 mm scale)

                        Wicheeda

                        Lake Heavy Mineral Composite mdash

                        (from samples 828951 52 53)

                        These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                        and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                        As a final statement it should be emphasizedhellip

                        1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                        2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                        3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                        4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                        5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                        Rare Earth Elements

                        bull

                        Name something of a misnomerndash

                        Rarest REEs

                        are over 200 times more

                        abundant then gold

                        bull

                        Variation in distribution for two reasons ndash

                        Compatibility with common rock forming materials

                        ndash

                        CosmicCrustal abundances

                        Crustal Abundances of Elements

                        Occurrencebull

                        REEs

                        occur mostly as

                        substitutional

                        impurities in many rock forming minerals

                        bull

                        Only a few the REE minerals have sufficient quantities to be considered important sources

                        bull

                        Defined as minerals having at least one site that is filled by REEs

                        andor Yttrium more often then any other elementMonazite

                        Rare Earth Minerals

                        bull

                        Form by primary crystalization

                        from magma or by hydrothermal reactions

                        bull

                        Found hosted in carbonate rocks in pegmatites

                        and as accessory minerals in

                        igneous rocks

                        bull

                        Stable REE minerals and can be concentrated in weathering zones

                        REE Mineralsbull

                        The most important REE minerals is bastnaumlsite

                        REE(CO3)F

                        bull

                        Other notable sources are ndash

                        Monazite REE(PO4) ndash

                        Xenotime

                        YPO4

                        bull

                        All may contain radioactive species such as thorium

                        and uraniumndash

                        are avoided as source materials

                        Bastnesitebull

                        Bastnasite

                        [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                        bull

                        Containing 60 to 70 rare earth oxides (REOs)

                        bull

                        REE site is most commonly filled by LREEs

                        and Y

                        Other REE mineralsbull

                        Monazite [(LREEYTh)PO4] ndash

                        Contains about 50ndash78 rare earth oxides

                        ndash

                        Forms in heavy mineral sands placer deposits associated with beach environments

                        bull

                        Xenotime

                        [(YPO4)] ndash

                        Contains 54ndash65 rare earth oxides

                        ndash

                        Yttrium Erbium and Cerium most common ndash

                        Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                        Electron Configuration

                        bull

                        The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                        bull

                        REEs

                        have same outer electronic configuration (+3) they differ in their number of 4f electrons

                        Electron Configuartion

                        REE Behaviorbull

                        Because of their shared behaviour REEs

                        tend to be

                        present in nature as a group All REEs

                        commonly substitute for one another in minerals

                        bull

                        Yet the REEs

                        are capable of showing great variation in their distributions

                        bull

                        Comes about due to ndash

                        Differences in ionic radius ndash

                        Crystal structure (Coordination Number)ndash

                        Basicity

                        of the mineral ndash

                        The elementrsquos solubility and ability to migrate in the environment ndash

                        Content of REEs

                        in source fluids

                        Ionic Radiusbull

                        The ionic radius of the REEs

                        is inversely related to atomic number

                        bull

                        The heavy rare earths are smaller ndash

                        more similar to Mn2+ (ionic radius 008 nanometers)

                        bull

                        LREEs

                        are largerndash

                        more comparable in size to Ca2+ (ionic radius 01 nanometer)

                        bull

                        Charge balance achieved through some sites being left vacant or

                        by coupled substitution with lower charged mineral (Na+)

                        In nanometers

                        Coordination Number

                        bull

                        Coordination number the number of atoms touching a particular atom in a crystal lattice

                        bull

                        Coordination number for this structure is 8

                        Coordination Numberbull

                        The heavy and light REEs

                        differ in the coordination

                        numbers (CN) with oxygenndash

                        HREEs

                        have CN between six to nine ndash

                        LREEs

                        have higher CNs

                        bull

                        Minerals with high CNs

                        associated with REE site

                        will favor LREEsndash

                        Bastnasite

                        CN = 11 ndash

                        Monazite CN = 9

                        bull

                        Those with low CNs

                        will preferentially select HREEs ndash

                        Xenotime

                        has a value of 8

                        Other Factorsbull

                        Minerals basicityndash

                        Alkalic

                        rocks host minerals with elevated LREE content ndash

                        Rocks with lower basicity

                        have lower amounts of LREEs

                        relative to their HREE content

                        bull

                        Solubilityndash

                        LREEs

                        are more soluble in water then the HREEsndash

                        Important characteristic for hydrothermally derived minerals

                        bull

                        MagmaHydrothermal fluid compositionndash

                        Minerals will take what they can get

                        REEs

                        and Economicsbull

                        The REEs

                        and Yttrium have a very broad range of applications mostly in high technology fields

                        bull

                        84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                        bull

                        REEs

                        used primarily for automotive (25) petroleum (22) and metallurgic (20)

                        HREEs

                        and Magnetism

                        bull

                        HREEs

                        exhibit complex magnetic behaviour on account of electron structurendash

                        They share the same outer shell electron configuration (valence = +3)

                        ndash

                        Differ in number of 4f electrons

                        Applications in Magnetismbull

                        Terbium and

                        Dysprosium

                        bull

                        Components of Terfenol-D

                        alloy

                        with the formula Tb(03) Dy(07) Fe(19)

                        bull

                        Has the higher magnetostriction

                        then any other alloyndash

                        expands and contracts in magnetic field

                        bull

                        Developed by American Navy for sonar

                        systems ndash

                        Now has applications in magnetomechanical

                        sensors and other electronic devices

                        Applications in Magnetism

                        bull

                        Holmium

                        bull

                        Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                        elements

                        bull

                        Creates the strongest artificially generated magnetic fieldsndash

                        In research where strong magnetic fields are needed

                        HREEs

                        and Nuclear Technology

                        bull

                        Dysprosium Homium Erbium

                        bull

                        High neutron

                        absorption cross-section ndash

                        Measure of probability of neutron capture

                        bull

                        Used in neutron-absorbing control rods in nuclear reactors

                        HREEs

                        and Nuclear Technology

                        bull

                        Lutetiumbull

                        Radioactive isotope used in radiometric dating

                        bull

                        Thulium bull

                        Stable thulium used as a radiation

                        source

                        in portable X-ray

                        devices

                        Mountain Passbull

                        Bastnasite

                        is the major REE mineral bull

                        High grade accessory mineral of igneous or hydrothermal originsbull

                        31 million tons of 886 by weight of rare earth oxides (REO) bull

                        Mining stopped in 1994 ndash

                        Thorium content of waste rock ndash

                        Availability of inexpensive REEs

                        from China

                        San Bernardino County

                        Bayan

                        Obobull

                        The worldrsquos primary source for both yttrium and the rare earth elements

                        bull

                        37 million tons of ore bull

                        Main REE source there is Bastnasite

                        World Production

                        Explorationbull

                        84 of REE imports to US are from China

                        bull

                        Increasing demand for high tech applications spurred increase in exploration in 2007

                        bull

                        Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                        Lake as well as in

                        Malawi Africa

                        Environmental Considerations

                        bull

                        REE soil and food contaminationbull

                        Acid Mine Drainage and groundwater systems

                        bull

                        Radioactive elements

                        REE Fertilizerbull

                        In China REE enriched fertilizer has been used in crop fields since 1990

                        bull

                        At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                        every year

                        bull

                        Research and agricultural practice that provides evidence that REEs

                        will improve crop quality an yield

                        bull

                        The ramifications environmental and human exposure to REEs

                        are not well understood

                        Investigation by T Liang et albull

                        Revealed that the average concentration of total REEs

                        in Chinese soil is

                        1768 mgkg ranging between 850 to 5227 mgkg

                        bull

                        In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                        Implicationsbull

                        Human health effects not completely understood

                        bull

                        REE soil content shown to be detrimental to some plant speciesndash

                        100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                        Acid Mine Drainage (AMD)bull

                        Rain waters contacts waste rock facilitating acid forming reactions

                        bull

                        Increases the capacity of the water to leach potentially harmful elements from waste piles

                        bull

                        Process mobilizes established ecotoxins

                        (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                        bull

                        Historically dismissed as minor environmental risk

                        Radioactive Elements

                        bull

                        REEs

                        associated with uranium and thorium

                        bull

                        Bastnesite 32 thorium

                        bull

                        Monazite sands 6 to 12 thorium oxide

                        bull

                        Ores containing radioactive elements are avoided as sources of REEs

                        Radioactive Hazardsbull

                        Mountain Pass

                        bull

                        Accidentsndash

                        In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                        bull

                        Health Effectsndash

                        inflammatory bowel disease ndash

                        Prolonged seizures ndash

                        Cysts ndash

                        Cancers

                        bull

                        Waste Disposal ndash

                        Yucca Mountain

                        Summarybull

                        REE concentrations in the crust are rare

                        bull

                        Several geochemical factors influencing distribution including ionic radius and coordination number

                        bull

                        Main REE minerals are bastnasite monazite and xenotime

                        bull

                        Most important deposits are found at Bayan

                        Obo China and Mountain Pass USA

                        bull

                        Important electronic and nuclear applications

                        bull

                        Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                        system contamination though acid mine drainage association with

                        radioactive elements

                        Referencesbull

                        E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                        bull

                        Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                        bull

                        G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                        bull

                        B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                        The Government of South Australia wwwpirsagovaubull

                        The US geological Survey Mineralsusgsgovbull

                        wwwelementsdatabasecombull

                        wwwastrolsaumichedu~cowleyintro2htmlbull

                        wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                        webmineralcomdataMonazite-(Ce)shtmlbull

                        wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                        wwwstevegbcomimagesscienceorbital_fillingpngbull

                        wwwchemicalelementscomelementseuhtmlbull

                        boomeriaorgchemlecturestextass2table10-9jpgbull

                        lostcontentquakecomfiles200802holmiumpngbull

                        chinageocitylocatorcomcitiesChinaQinghaibull

                        geowebrudruzal-Bayan-Obohtmbull

                        enwikipediaorgwikiSan_Bernardino_County_Californiabull

                        wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                        enwikipediaorgwikiMonazitebull

                        webmineralcomdataBastnasite-(La)shtmlbull

                        wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                        httpwwwavalonventurescombull

                        wwwnewsweekcomid43884bull

                        httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                        httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                        • Slide Number 1
                        • Slide Number 2
                        • Slide Number 3
                        • Slide Number 4
                        • Slide Number 5
                        • Slide Number 6
                        • Slide Number 7
                        • Slide Number 8
                        • Slide Number 9
                        • Slide Number 10
                        • Slide Number 11
                        • Slide Number 12
                        • Slide Number 13
                        • Slide Number 14
                        • Slide Number 15
                        • Slide Number 16
                        • Slide Number 17
                        • Slide Number 18
                        • Slide Number 19
                        • Slide Number 20
                        • Slide Number 21
                        • Slide Number 22
                        • Slide Number 23
                        • Slide Number 24
                        • Slide Number 25
                        • Slide Number 26
                        • Slide Number 27
                        • Slide Number 28
                        • Slide Number 29
                        • Slide Number 30
                        • Slide Number 31
                        • Slide Number 32
                        • Slide Number 33
                        • Slide Number 34
                        • Slide Number 35
                        • Slide Number 36
                        • Slide Number 37
                        • Slide Number 38
                        • Slide Number 39
                        • Slide Number 40
                        • Slide Number 41
                        • Slide Number 42
                        • Slide Number 43
                        • Slide Number 44
                        • Slide Number 45
                        • Slide Number 46
                        • Slide Number 47
                        • Slide Number 48
                        • Slide Number 49
                        • Slide Number 50
                        • Slide Number 51
                        • Rare Earth Elements
                        • Crustal Abundances of Elements
                        • Occurrence
                        • Rare Earth Minerals
                        • REE Minerals
                        • Bastnesite
                        • Other REE minerals
                        • Electron Configuration
                        • Electron Configuartion
                        • REE Behavior
                        • Ionic Radius
                        • Coordination Number
                        • Coordination Number
                        • Other Factors
                        • REEs and Economics
                        • HREEs and Magnetism
                        • Applications in Magnetism
                        • Applications in Magnetism
                        • HREEs and Nuclear Technology
                        • HREEs and Nuclear Technology
                        • Mountain Pass
                        • Bayan Obo
                        • World Production
                        • Exploration
                        • Environmental Considerations
                        • REE Fertilizer
                        • Investigation by T Liang et al
                        • Implications
                        • Acid Mine Drainage (AMD)
                        • Radioactive Elements
                        • Radioactive Hazards
                        • Summary
                        • References

                          Model for Peralkalic Magma Systems

                          BrecciasBrecciasBrecciasdiatremesdiatremesdiatremes

                          Contact pegmatiteContact pegmatiteapliteaplite

                          EndograniticEndograniticpegmatitepegmatite

                          Late Late apliteaplite--pegmatitepegmatitedike(sdike(s))

                          APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

                          WelsfordWelsford Dyke swarmsDyke swarms

                          Welsford

                          model

                          Marsh (1995)

                          Major Rare Earth Sources

                          Mineral

                          Composition

                          Occurrence

                          Bastnaumlsite

                          (Ce) (REE) CO3

                          F

                          Carbonatites

                          Monazite (Ce) (REE) PO4

                          Beach Sands Hydrothermal

                          Xenotime

                          (Y) (YREE) PO4

                          Beach Sands Hydrothermal

                          Loparite

                          (Ce) (REENaCa) (Ti NbTa)O3

                          Alkaline igneous massif

                          South China Clays (Ion-adsorbed REE+Y in Clays)

                          Uraninite

                          (REE and Y mdash

                          Released as dissolved elements

                          in rafinates

                          from uraninite)

                          Monazite pseudomorph

                          after apatite Monazite pseudomorph

                          after Rhabdophane

                          Florencite

                          pseudomorph

                          after pyrochlore Churchite

                          YPO4

                          middot2H2

                          O

                          Supergene Minerals ndash

                          MT Weld Australia

                          Apatite

                          with Substitutional

                          REE

                          Oka Quebec

                          Carbonatite

                          Nolanrsquos Bore Australia

                          Carbonatite

                          Mushgai

                          Khudag Mongolia

                          Carbonatite

                          Phalaborwa South Africa

                          Carbonatite

                          Kola Peninsula

                          Carbonatite

                          and Alkaline Massifs

                          Hoidas

                          Lake Saskatchewan

                          Hydrothermal in Granites

                          Mineville New York

                          Tailings from Magnetite Mining

                          Mineville may be the only Y and HREE dominant source currently known

                          HD -

                          176 mm HD -

                          44 mm

                          XPL MicrographsBastnaumlsite

                          in Carbonatite

                          Mountain Pass CA

                          BSE Image AncyliteHD ndash

                          07 mm

                          PPL Micrograph Ancylite

                          Ancylite

                          (Ce)

                          SrREE(CO3

                          )2

                          (OH)H2

                          O

                          LREE -

                          dominant ndash

                          50 wt REO

                          An exploration target in the

                          Bear Lodge Carbonatite

                          Complex of northeastern Wyoming

                          Red Wine Complex Labrador Dora Bay Alaska

                          Eudialyte

                          Na15

                          Ca6

                          (Fe2+Mn2+)3

                          Zr3

                          (SiNb)(Si25

                          O73

                          )(OOHH2

                          O)3

                          (CLOH)2

                          Eudialyite

                          may also contain Y and HREE

                          in amounts exceeding 4 wt The

                          mineral is easily dissolved in weak acids

                          but colloidal silica currently presents a

                          problem in the isolation of Y REE and Zr

                          oxides

                          Kipawa Quebec

                          Massive Britholite

                          (Ce) Oka Quebec

                          Britholite

                          (Ce) Concentrate from Skarn

                          Kipawa Quebec

                          Britholite

                          ndash

                          (REEYCa)5

                          (SiO4

                          PO4

                          )3

                          (OHF)

                          This mineral has the potential for occurring in ore quantities in skarn

                          associated with syenite

                          gneiss in Kipawa Quebec

                          Allanite

                          (Ce) (CeCaY)2

                          (AlFe2+Fe3+)3

                          (SiO4

                          )3

                          (OH)

                          Allanite

                          is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                          Allanite

                          ndash

                          Hydrothermal Mountain Pass CA Allanite

                          ndash

                          Pegmatite Timmins Ontario

                          Eudialyte

                          and Mosandrite

                          in Peralkaline

                          Syenite

                          Kipawa Quebec

                          Britholite-Rich Skarn

                          All brown prisms are britholite

                          (Horizontal Distance ndash 46 mm)

                          Britholite

                          Concentrate

                          (mm scale)

                          Britholite

                          ndash

                          (CeYCa)5 (SiO4PO4 )3 (OHF)

                          Kipawa Quebec

                          Cathodoluminescence

                          Macrograph of Iimoriite

                          in Syenite

                          ndash

                          Bokan

                          Mountain

                          Mottled light blue and tan clusters -

                          Iimoriite

                          Red groundmass ndash

                          Feldspar

                          (Horizontal distance of rock slab ndash 46 mm)

                          Iimoriite

                          (Y)

                          Y2 (SiO4 )(CO3 )

                          Yttrofluorite

                          (CaY)F2

                          Iimoriite

                          Concentrate ndash

                          Bokan

                          MT (1 mm scale)

                          Wicheeda

                          Lake Heavy Mineral Composite mdash

                          (from samples 828951 52 53)

                          These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                          and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                          As a final statement it should be emphasizedhellip

                          1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                          2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                          3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                          4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                          5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                          Rare Earth Elements

                          bull

                          Name something of a misnomerndash

                          Rarest REEs

                          are over 200 times more

                          abundant then gold

                          bull

                          Variation in distribution for two reasons ndash

                          Compatibility with common rock forming materials

                          ndash

                          CosmicCrustal abundances

                          Crustal Abundances of Elements

                          Occurrencebull

                          REEs

                          occur mostly as

                          substitutional

                          impurities in many rock forming minerals

                          bull

                          Only a few the REE minerals have sufficient quantities to be considered important sources

                          bull

                          Defined as minerals having at least one site that is filled by REEs

                          andor Yttrium more often then any other elementMonazite

                          Rare Earth Minerals

                          bull

                          Form by primary crystalization

                          from magma or by hydrothermal reactions

                          bull

                          Found hosted in carbonate rocks in pegmatites

                          and as accessory minerals in

                          igneous rocks

                          bull

                          Stable REE minerals and can be concentrated in weathering zones

                          REE Mineralsbull

                          The most important REE minerals is bastnaumlsite

                          REE(CO3)F

                          bull

                          Other notable sources are ndash

                          Monazite REE(PO4) ndash

                          Xenotime

                          YPO4

                          bull

                          All may contain radioactive species such as thorium

                          and uraniumndash

                          are avoided as source materials

                          Bastnesitebull

                          Bastnasite

                          [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                          bull

                          Containing 60 to 70 rare earth oxides (REOs)

                          bull

                          REE site is most commonly filled by LREEs

                          and Y

                          Other REE mineralsbull

                          Monazite [(LREEYTh)PO4] ndash

                          Contains about 50ndash78 rare earth oxides

                          ndash

                          Forms in heavy mineral sands placer deposits associated with beach environments

                          bull

                          Xenotime

                          [(YPO4)] ndash

                          Contains 54ndash65 rare earth oxides

                          ndash

                          Yttrium Erbium and Cerium most common ndash

                          Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                          Electron Configuration

                          bull

                          The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                          bull

                          REEs

                          have same outer electronic configuration (+3) they differ in their number of 4f electrons

                          Electron Configuartion

                          REE Behaviorbull

                          Because of their shared behaviour REEs

                          tend to be

                          present in nature as a group All REEs

                          commonly substitute for one another in minerals

                          bull

                          Yet the REEs

                          are capable of showing great variation in their distributions

                          bull

                          Comes about due to ndash

                          Differences in ionic radius ndash

                          Crystal structure (Coordination Number)ndash

                          Basicity

                          of the mineral ndash

                          The elementrsquos solubility and ability to migrate in the environment ndash

                          Content of REEs

                          in source fluids

                          Ionic Radiusbull

                          The ionic radius of the REEs

                          is inversely related to atomic number

                          bull

                          The heavy rare earths are smaller ndash

                          more similar to Mn2+ (ionic radius 008 nanometers)

                          bull

                          LREEs

                          are largerndash

                          more comparable in size to Ca2+ (ionic radius 01 nanometer)

                          bull

                          Charge balance achieved through some sites being left vacant or

                          by coupled substitution with lower charged mineral (Na+)

                          In nanometers

                          Coordination Number

                          bull

                          Coordination number the number of atoms touching a particular atom in a crystal lattice

                          bull

                          Coordination number for this structure is 8

                          Coordination Numberbull

                          The heavy and light REEs

                          differ in the coordination

                          numbers (CN) with oxygenndash

                          HREEs

                          have CN between six to nine ndash

                          LREEs

                          have higher CNs

                          bull

                          Minerals with high CNs

                          associated with REE site

                          will favor LREEsndash

                          Bastnasite

                          CN = 11 ndash

                          Monazite CN = 9

                          bull

                          Those with low CNs

                          will preferentially select HREEs ndash

                          Xenotime

                          has a value of 8

                          Other Factorsbull

                          Minerals basicityndash

                          Alkalic

                          rocks host minerals with elevated LREE content ndash

                          Rocks with lower basicity

                          have lower amounts of LREEs

                          relative to their HREE content

                          bull

                          Solubilityndash

                          LREEs

                          are more soluble in water then the HREEsndash

                          Important characteristic for hydrothermally derived minerals

                          bull

                          MagmaHydrothermal fluid compositionndash

                          Minerals will take what they can get

                          REEs

                          and Economicsbull

                          The REEs

                          and Yttrium have a very broad range of applications mostly in high technology fields

                          bull

                          84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                          bull

                          REEs

                          used primarily for automotive (25) petroleum (22) and metallurgic (20)

                          HREEs

                          and Magnetism

                          bull

                          HREEs

                          exhibit complex magnetic behaviour on account of electron structurendash

                          They share the same outer shell electron configuration (valence = +3)

                          ndash

                          Differ in number of 4f electrons

                          Applications in Magnetismbull

                          Terbium and

                          Dysprosium

                          bull

                          Components of Terfenol-D

                          alloy

                          with the formula Tb(03) Dy(07) Fe(19)

                          bull

                          Has the higher magnetostriction

                          then any other alloyndash

                          expands and contracts in magnetic field

                          bull

                          Developed by American Navy for sonar

                          systems ndash

                          Now has applications in magnetomechanical

                          sensors and other electronic devices

                          Applications in Magnetism

                          bull

                          Holmium

                          bull

                          Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                          elements

                          bull

                          Creates the strongest artificially generated magnetic fieldsndash

                          In research where strong magnetic fields are needed

                          HREEs

                          and Nuclear Technology

                          bull

                          Dysprosium Homium Erbium

                          bull

                          High neutron

                          absorption cross-section ndash

                          Measure of probability of neutron capture

                          bull

                          Used in neutron-absorbing control rods in nuclear reactors

                          HREEs

                          and Nuclear Technology

                          bull

                          Lutetiumbull

                          Radioactive isotope used in radiometric dating

                          bull

                          Thulium bull

                          Stable thulium used as a radiation

                          source

                          in portable X-ray

                          devices

                          Mountain Passbull

                          Bastnasite

                          is the major REE mineral bull

                          High grade accessory mineral of igneous or hydrothermal originsbull

                          31 million tons of 886 by weight of rare earth oxides (REO) bull

                          Mining stopped in 1994 ndash

                          Thorium content of waste rock ndash

                          Availability of inexpensive REEs

                          from China

                          San Bernardino County

                          Bayan

                          Obobull

                          The worldrsquos primary source for both yttrium and the rare earth elements

                          bull

                          37 million tons of ore bull

                          Main REE source there is Bastnasite

                          World Production

                          Explorationbull

                          84 of REE imports to US are from China

                          bull

                          Increasing demand for high tech applications spurred increase in exploration in 2007

                          bull

                          Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                          Lake as well as in

                          Malawi Africa

                          Environmental Considerations

                          bull

                          REE soil and food contaminationbull

                          Acid Mine Drainage and groundwater systems

                          bull

                          Radioactive elements

                          REE Fertilizerbull

                          In China REE enriched fertilizer has been used in crop fields since 1990

                          bull

                          At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                          every year

                          bull

                          Research and agricultural practice that provides evidence that REEs

                          will improve crop quality an yield

                          bull

                          The ramifications environmental and human exposure to REEs

                          are not well understood

                          Investigation by T Liang et albull

                          Revealed that the average concentration of total REEs

                          in Chinese soil is

                          1768 mgkg ranging between 850 to 5227 mgkg

                          bull

                          In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                          Implicationsbull

                          Human health effects not completely understood

                          bull

                          REE soil content shown to be detrimental to some plant speciesndash

                          100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                          Acid Mine Drainage (AMD)bull

                          Rain waters contacts waste rock facilitating acid forming reactions

                          bull

                          Increases the capacity of the water to leach potentially harmful elements from waste piles

                          bull

                          Process mobilizes established ecotoxins

                          (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                          bull

                          Historically dismissed as minor environmental risk

                          Radioactive Elements

                          bull

                          REEs

                          associated with uranium and thorium

                          bull

                          Bastnesite 32 thorium

                          bull

                          Monazite sands 6 to 12 thorium oxide

                          bull

                          Ores containing radioactive elements are avoided as sources of REEs

                          Radioactive Hazardsbull

                          Mountain Pass

                          bull

                          Accidentsndash

                          In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                          bull

                          Health Effectsndash

                          inflammatory bowel disease ndash

                          Prolonged seizures ndash

                          Cysts ndash

                          Cancers

                          bull

                          Waste Disposal ndash

                          Yucca Mountain

                          Summarybull

                          REE concentrations in the crust are rare

                          bull

                          Several geochemical factors influencing distribution including ionic radius and coordination number

                          bull

                          Main REE minerals are bastnasite monazite and xenotime

                          bull

                          Most important deposits are found at Bayan

                          Obo China and Mountain Pass USA

                          bull

                          Important electronic and nuclear applications

                          bull

                          Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                          system contamination though acid mine drainage association with

                          radioactive elements

                          Referencesbull

                          E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                          bull

                          Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                          bull

                          G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                          bull

                          B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                          The Government of South Australia wwwpirsagovaubull

                          The US geological Survey Mineralsusgsgovbull

                          wwwelementsdatabasecombull

                          wwwastrolsaumichedu~cowleyintro2htmlbull

                          wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                          webmineralcomdataMonazite-(Ce)shtmlbull

                          wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                          wwwstevegbcomimagesscienceorbital_fillingpngbull

                          wwwchemicalelementscomelementseuhtmlbull

                          boomeriaorgchemlecturestextass2table10-9jpgbull

                          lostcontentquakecomfiles200802holmiumpngbull

                          chinageocitylocatorcomcitiesChinaQinghaibull

                          geowebrudruzal-Bayan-Obohtmbull

                          enwikipediaorgwikiSan_Bernardino_County_Californiabull

                          wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                          enwikipediaorgwikiMonazitebull

                          webmineralcomdataBastnasite-(La)shtmlbull

                          wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                          httpwwwavalonventurescombull

                          wwwnewsweekcomid43884bull

                          httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                          httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                          • Slide Number 1
                          • Slide Number 2
                          • Slide Number 3
                          • Slide Number 4
                          • Slide Number 5
                          • Slide Number 6
                          • Slide Number 7
                          • Slide Number 8
                          • Slide Number 9
                          • Slide Number 10
                          • Slide Number 11
                          • Slide Number 12
                          • Slide Number 13
                          • Slide Number 14
                          • Slide Number 15
                          • Slide Number 16
                          • Slide Number 17
                          • Slide Number 18
                          • Slide Number 19
                          • Slide Number 20
                          • Slide Number 21
                          • Slide Number 22
                          • Slide Number 23
                          • Slide Number 24
                          • Slide Number 25
                          • Slide Number 26
                          • Slide Number 27
                          • Slide Number 28
                          • Slide Number 29
                          • Slide Number 30
                          • Slide Number 31
                          • Slide Number 32
                          • Slide Number 33
                          • Slide Number 34
                          • Slide Number 35
                          • Slide Number 36
                          • Slide Number 37
                          • Slide Number 38
                          • Slide Number 39
                          • Slide Number 40
                          • Slide Number 41
                          • Slide Number 42
                          • Slide Number 43
                          • Slide Number 44
                          • Slide Number 45
                          • Slide Number 46
                          • Slide Number 47
                          • Slide Number 48
                          • Slide Number 49
                          • Slide Number 50
                          • Slide Number 51
                          • Rare Earth Elements
                          • Crustal Abundances of Elements
                          • Occurrence
                          • Rare Earth Minerals
                          • REE Minerals
                          • Bastnesite
                          • Other REE minerals
                          • Electron Configuration
                          • Electron Configuartion
                          • REE Behavior
                          • Ionic Radius
                          • Coordination Number
                          • Coordination Number
                          • Other Factors
                          • REEs and Economics
                          • HREEs and Magnetism
                          • Applications in Magnetism
                          • Applications in Magnetism
                          • HREEs and Nuclear Technology
                          • HREEs and Nuclear Technology
                          • Mountain Pass
                          • Bayan Obo
                          • World Production
                          • Exploration
                          • Environmental Considerations
                          • REE Fertilizer
                          • Investigation by T Liang et al
                          • Implications
                          • Acid Mine Drainage (AMD)
                          • Radioactive Elements
                          • Radioactive Hazards
                          • Summary
                          • References

                            APLITERiebeckiteK-feldsparZircon(Baddellyite)Nb-Fe oxideAeschyniteFergusoniteEuxeniteREE carbonate

                            WelsfordWelsford Dyke swarmsDyke swarms

                            Welsford

                            model

                            Marsh (1995)

                            Major Rare Earth Sources

                            Mineral

                            Composition

                            Occurrence

                            Bastnaumlsite

                            (Ce) (REE) CO3

                            F

                            Carbonatites

                            Monazite (Ce) (REE) PO4

                            Beach Sands Hydrothermal

                            Xenotime

                            (Y) (YREE) PO4

                            Beach Sands Hydrothermal

                            Loparite

                            (Ce) (REENaCa) (Ti NbTa)O3

                            Alkaline igneous massif

                            South China Clays (Ion-adsorbed REE+Y in Clays)

                            Uraninite

                            (REE and Y mdash

                            Released as dissolved elements

                            in rafinates

                            from uraninite)

                            Monazite pseudomorph

                            after apatite Monazite pseudomorph

                            after Rhabdophane

                            Florencite

                            pseudomorph

                            after pyrochlore Churchite

                            YPO4

                            middot2H2

                            O

                            Supergene Minerals ndash

                            MT Weld Australia

                            Apatite

                            with Substitutional

                            REE

                            Oka Quebec

                            Carbonatite

                            Nolanrsquos Bore Australia

                            Carbonatite

                            Mushgai

                            Khudag Mongolia

                            Carbonatite

                            Phalaborwa South Africa

                            Carbonatite

                            Kola Peninsula

                            Carbonatite

                            and Alkaline Massifs

                            Hoidas

                            Lake Saskatchewan

                            Hydrothermal in Granites

                            Mineville New York

                            Tailings from Magnetite Mining

                            Mineville may be the only Y and HREE dominant source currently known

                            HD -

                            176 mm HD -

                            44 mm

                            XPL MicrographsBastnaumlsite

                            in Carbonatite

                            Mountain Pass CA

                            BSE Image AncyliteHD ndash

                            07 mm

                            PPL Micrograph Ancylite

                            Ancylite

                            (Ce)

                            SrREE(CO3

                            )2

                            (OH)H2

                            O

                            LREE -

                            dominant ndash

                            50 wt REO

                            An exploration target in the

                            Bear Lodge Carbonatite

                            Complex of northeastern Wyoming

                            Red Wine Complex Labrador Dora Bay Alaska

                            Eudialyte

                            Na15

                            Ca6

                            (Fe2+Mn2+)3

                            Zr3

                            (SiNb)(Si25

                            O73

                            )(OOHH2

                            O)3

                            (CLOH)2

                            Eudialyite

                            may also contain Y and HREE

                            in amounts exceeding 4 wt The

                            mineral is easily dissolved in weak acids

                            but colloidal silica currently presents a

                            problem in the isolation of Y REE and Zr

                            oxides

                            Kipawa Quebec

                            Massive Britholite

                            (Ce) Oka Quebec

                            Britholite

                            (Ce) Concentrate from Skarn

                            Kipawa Quebec

                            Britholite

                            ndash

                            (REEYCa)5

                            (SiO4

                            PO4

                            )3

                            (OHF)

                            This mineral has the potential for occurring in ore quantities in skarn

                            associated with syenite

                            gneiss in Kipawa Quebec

                            Allanite

                            (Ce) (CeCaY)2

                            (AlFe2+Fe3+)3

                            (SiO4

                            )3

                            (OH)

                            Allanite

                            is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                            Allanite

                            ndash

                            Hydrothermal Mountain Pass CA Allanite

                            ndash

                            Pegmatite Timmins Ontario

                            Eudialyte

                            and Mosandrite

                            in Peralkaline

                            Syenite

                            Kipawa Quebec

                            Britholite-Rich Skarn

                            All brown prisms are britholite

                            (Horizontal Distance ndash 46 mm)

                            Britholite

                            Concentrate

                            (mm scale)

                            Britholite

                            ndash

                            (CeYCa)5 (SiO4PO4 )3 (OHF)

                            Kipawa Quebec

                            Cathodoluminescence

                            Macrograph of Iimoriite

                            in Syenite

                            ndash

                            Bokan

                            Mountain

                            Mottled light blue and tan clusters -

                            Iimoriite

                            Red groundmass ndash

                            Feldspar

                            (Horizontal distance of rock slab ndash 46 mm)

                            Iimoriite

                            (Y)

                            Y2 (SiO4 )(CO3 )

                            Yttrofluorite

                            (CaY)F2

                            Iimoriite

                            Concentrate ndash

                            Bokan

                            MT (1 mm scale)

                            Wicheeda

                            Lake Heavy Mineral Composite mdash

                            (from samples 828951 52 53)

                            These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                            and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                            As a final statement it should be emphasizedhellip

                            1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                            2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                            3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                            4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                            5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                            Rare Earth Elements

                            bull

                            Name something of a misnomerndash

                            Rarest REEs

                            are over 200 times more

                            abundant then gold

                            bull

                            Variation in distribution for two reasons ndash

                            Compatibility with common rock forming materials

                            ndash

                            CosmicCrustal abundances

                            Crustal Abundances of Elements

                            Occurrencebull

                            REEs

                            occur mostly as

                            substitutional

                            impurities in many rock forming minerals

                            bull

                            Only a few the REE minerals have sufficient quantities to be considered important sources

                            bull

                            Defined as minerals having at least one site that is filled by REEs

                            andor Yttrium more often then any other elementMonazite

                            Rare Earth Minerals

                            bull

                            Form by primary crystalization

                            from magma or by hydrothermal reactions

                            bull

                            Found hosted in carbonate rocks in pegmatites

                            and as accessory minerals in

                            igneous rocks

                            bull

                            Stable REE minerals and can be concentrated in weathering zones

                            REE Mineralsbull

                            The most important REE minerals is bastnaumlsite

                            REE(CO3)F

                            bull

                            Other notable sources are ndash

                            Monazite REE(PO4) ndash

                            Xenotime

                            YPO4

                            bull

                            All may contain radioactive species such as thorium

                            and uraniumndash

                            are avoided as source materials

                            Bastnesitebull

                            Bastnasite

                            [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                            bull

                            Containing 60 to 70 rare earth oxides (REOs)

                            bull

                            REE site is most commonly filled by LREEs

                            and Y

                            Other REE mineralsbull

                            Monazite [(LREEYTh)PO4] ndash

                            Contains about 50ndash78 rare earth oxides

                            ndash

                            Forms in heavy mineral sands placer deposits associated with beach environments

                            bull

                            Xenotime

                            [(YPO4)] ndash

                            Contains 54ndash65 rare earth oxides

                            ndash

                            Yttrium Erbium and Cerium most common ndash

                            Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                            Electron Configuration

                            bull

                            The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                            bull

                            REEs

                            have same outer electronic configuration (+3) they differ in their number of 4f electrons

                            Electron Configuartion

                            REE Behaviorbull

                            Because of their shared behaviour REEs

                            tend to be

                            present in nature as a group All REEs

                            commonly substitute for one another in minerals

                            bull

                            Yet the REEs

                            are capable of showing great variation in their distributions

                            bull

                            Comes about due to ndash

                            Differences in ionic radius ndash

                            Crystal structure (Coordination Number)ndash

                            Basicity

                            of the mineral ndash

                            The elementrsquos solubility and ability to migrate in the environment ndash

                            Content of REEs

                            in source fluids

                            Ionic Radiusbull

                            The ionic radius of the REEs

                            is inversely related to atomic number

                            bull

                            The heavy rare earths are smaller ndash

                            more similar to Mn2+ (ionic radius 008 nanometers)

                            bull

                            LREEs

                            are largerndash

                            more comparable in size to Ca2+ (ionic radius 01 nanometer)

                            bull

                            Charge balance achieved through some sites being left vacant or

                            by coupled substitution with lower charged mineral (Na+)

                            In nanometers

                            Coordination Number

                            bull

                            Coordination number the number of atoms touching a particular atom in a crystal lattice

                            bull

                            Coordination number for this structure is 8

                            Coordination Numberbull

                            The heavy and light REEs

                            differ in the coordination

                            numbers (CN) with oxygenndash

                            HREEs

                            have CN between six to nine ndash

                            LREEs

                            have higher CNs

                            bull

                            Minerals with high CNs

                            associated with REE site

                            will favor LREEsndash

                            Bastnasite

                            CN = 11 ndash

                            Monazite CN = 9

                            bull

                            Those with low CNs

                            will preferentially select HREEs ndash

                            Xenotime

                            has a value of 8

                            Other Factorsbull

                            Minerals basicityndash

                            Alkalic

                            rocks host minerals with elevated LREE content ndash

                            Rocks with lower basicity

                            have lower amounts of LREEs

                            relative to their HREE content

                            bull

                            Solubilityndash

                            LREEs

                            are more soluble in water then the HREEsndash

                            Important characteristic for hydrothermally derived minerals

                            bull

                            MagmaHydrothermal fluid compositionndash

                            Minerals will take what they can get

                            REEs

                            and Economicsbull

                            The REEs

                            and Yttrium have a very broad range of applications mostly in high technology fields

                            bull

                            84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                            bull

                            REEs

                            used primarily for automotive (25) petroleum (22) and metallurgic (20)

                            HREEs

                            and Magnetism

                            bull

                            HREEs

                            exhibit complex magnetic behaviour on account of electron structurendash

                            They share the same outer shell electron configuration (valence = +3)

                            ndash

                            Differ in number of 4f electrons

                            Applications in Magnetismbull

                            Terbium and

                            Dysprosium

                            bull

                            Components of Terfenol-D

                            alloy

                            with the formula Tb(03) Dy(07) Fe(19)

                            bull

                            Has the higher magnetostriction

                            then any other alloyndash

                            expands and contracts in magnetic field

                            bull

                            Developed by American Navy for sonar

                            systems ndash

                            Now has applications in magnetomechanical

                            sensors and other electronic devices

                            Applications in Magnetism

                            bull

                            Holmium

                            bull

                            Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                            elements

                            bull

                            Creates the strongest artificially generated magnetic fieldsndash

                            In research where strong magnetic fields are needed

                            HREEs

                            and Nuclear Technology

                            bull

                            Dysprosium Homium Erbium

                            bull

                            High neutron

                            absorption cross-section ndash

                            Measure of probability of neutron capture

                            bull

                            Used in neutron-absorbing control rods in nuclear reactors

                            HREEs

                            and Nuclear Technology

                            bull

                            Lutetiumbull

                            Radioactive isotope used in radiometric dating

                            bull

                            Thulium bull

                            Stable thulium used as a radiation

                            source

                            in portable X-ray

                            devices

                            Mountain Passbull

                            Bastnasite

                            is the major REE mineral bull

                            High grade accessory mineral of igneous or hydrothermal originsbull

                            31 million tons of 886 by weight of rare earth oxides (REO) bull

                            Mining stopped in 1994 ndash

                            Thorium content of waste rock ndash

                            Availability of inexpensive REEs

                            from China

                            San Bernardino County

                            Bayan

                            Obobull

                            The worldrsquos primary source for both yttrium and the rare earth elements

                            bull

                            37 million tons of ore bull

                            Main REE source there is Bastnasite

                            World Production

                            Explorationbull

                            84 of REE imports to US are from China

                            bull

                            Increasing demand for high tech applications spurred increase in exploration in 2007

                            bull

                            Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                            Lake as well as in

                            Malawi Africa

                            Environmental Considerations

                            bull

                            REE soil and food contaminationbull

                            Acid Mine Drainage and groundwater systems

                            bull

                            Radioactive elements

                            REE Fertilizerbull

                            In China REE enriched fertilizer has been used in crop fields since 1990

                            bull

                            At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                            every year

                            bull

                            Research and agricultural practice that provides evidence that REEs

                            will improve crop quality an yield

                            bull

                            The ramifications environmental and human exposure to REEs

                            are not well understood

                            Investigation by T Liang et albull

                            Revealed that the average concentration of total REEs

                            in Chinese soil is

                            1768 mgkg ranging between 850 to 5227 mgkg

                            bull

                            In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                            Implicationsbull

                            Human health effects not completely understood

                            bull

                            REE soil content shown to be detrimental to some plant speciesndash

                            100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                            Acid Mine Drainage (AMD)bull

                            Rain waters contacts waste rock facilitating acid forming reactions

                            bull

                            Increases the capacity of the water to leach potentially harmful elements from waste piles

                            bull

                            Process mobilizes established ecotoxins

                            (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                            bull

                            Historically dismissed as minor environmental risk

                            Radioactive Elements

                            bull

                            REEs

                            associated with uranium and thorium

                            bull

                            Bastnesite 32 thorium

                            bull

                            Monazite sands 6 to 12 thorium oxide

                            bull

                            Ores containing radioactive elements are avoided as sources of REEs

                            Radioactive Hazardsbull

                            Mountain Pass

                            bull

                            Accidentsndash

                            In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                            bull

                            Health Effectsndash

                            inflammatory bowel disease ndash

                            Prolonged seizures ndash

                            Cysts ndash

                            Cancers

                            bull

                            Waste Disposal ndash

                            Yucca Mountain

                            Summarybull

                            REE concentrations in the crust are rare

                            bull

                            Several geochemical factors influencing distribution including ionic radius and coordination number

                            bull

                            Main REE minerals are bastnasite monazite and xenotime

                            bull

                            Most important deposits are found at Bayan

                            Obo China and Mountain Pass USA

                            bull

                            Important electronic and nuclear applications

                            bull

                            Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                            system contamination though acid mine drainage association with

                            radioactive elements

                            Referencesbull

                            E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                            bull

                            Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                            bull

                            G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                            bull

                            B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                            The Government of South Australia wwwpirsagovaubull

                            The US geological Survey Mineralsusgsgovbull

                            wwwelementsdatabasecombull

                            wwwastrolsaumichedu~cowleyintro2htmlbull

                            wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                            webmineralcomdataMonazite-(Ce)shtmlbull

                            wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                            wwwstevegbcomimagesscienceorbital_fillingpngbull

                            wwwchemicalelementscomelementseuhtmlbull

                            boomeriaorgchemlecturestextass2table10-9jpgbull

                            lostcontentquakecomfiles200802holmiumpngbull

                            chinageocitylocatorcomcitiesChinaQinghaibull

                            geowebrudruzal-Bayan-Obohtmbull

                            enwikipediaorgwikiSan_Bernardino_County_Californiabull

                            wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                            enwikipediaorgwikiMonazitebull

                            webmineralcomdataBastnasite-(La)shtmlbull

                            wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                            httpwwwavalonventurescombull

                            wwwnewsweekcomid43884bull

                            httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                            httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                            • Slide Number 1
                            • Slide Number 2
                            • Slide Number 3
                            • Slide Number 4
                            • Slide Number 5
                            • Slide Number 6
                            • Slide Number 7
                            • Slide Number 8
                            • Slide Number 9
                            • Slide Number 10
                            • Slide Number 11
                            • Slide Number 12
                            • Slide Number 13
                            • Slide Number 14
                            • Slide Number 15
                            • Slide Number 16
                            • Slide Number 17
                            • Slide Number 18
                            • Slide Number 19
                            • Slide Number 20
                            • Slide Number 21
                            • Slide Number 22
                            • Slide Number 23
                            • Slide Number 24
                            • Slide Number 25
                            • Slide Number 26
                            • Slide Number 27
                            • Slide Number 28
                            • Slide Number 29
                            • Slide Number 30
                            • Slide Number 31
                            • Slide Number 32
                            • Slide Number 33
                            • Slide Number 34
                            • Slide Number 35
                            • Slide Number 36
                            • Slide Number 37
                            • Slide Number 38
                            • Slide Number 39
                            • Slide Number 40
                            • Slide Number 41
                            • Slide Number 42
                            • Slide Number 43
                            • Slide Number 44
                            • Slide Number 45
                            • Slide Number 46
                            • Slide Number 47
                            • Slide Number 48
                            • Slide Number 49
                            • Slide Number 50
                            • Slide Number 51
                            • Rare Earth Elements
                            • Crustal Abundances of Elements
                            • Occurrence
                            • Rare Earth Minerals
                            • REE Minerals
                            • Bastnesite
                            • Other REE minerals
                            • Electron Configuration
                            • Electron Configuartion
                            • REE Behavior
                            • Ionic Radius
                            • Coordination Number
                            • Coordination Number
                            • Other Factors
                            • REEs and Economics
                            • HREEs and Magnetism
                            • Applications in Magnetism
                            • Applications in Magnetism
                            • HREEs and Nuclear Technology
                            • HREEs and Nuclear Technology
                            • Mountain Pass
                            • Bayan Obo
                            • World Production
                            • Exploration
                            • Environmental Considerations
                            • REE Fertilizer
                            • Investigation by T Liang et al
                            • Implications
                            • Acid Mine Drainage (AMD)
                            • Radioactive Elements
                            • Radioactive Hazards
                            • Summary
                            • References

                              Welsford

                              model

                              Marsh (1995)

                              Major Rare Earth Sources

                              Mineral

                              Composition

                              Occurrence

                              Bastnaumlsite

                              (Ce) (REE) CO3

                              F

                              Carbonatites

                              Monazite (Ce) (REE) PO4

                              Beach Sands Hydrothermal

                              Xenotime

                              (Y) (YREE) PO4

                              Beach Sands Hydrothermal

                              Loparite

                              (Ce) (REENaCa) (Ti NbTa)O3

                              Alkaline igneous massif

                              South China Clays (Ion-adsorbed REE+Y in Clays)

                              Uraninite

                              (REE and Y mdash

                              Released as dissolved elements

                              in rafinates

                              from uraninite)

                              Monazite pseudomorph

                              after apatite Monazite pseudomorph

                              after Rhabdophane

                              Florencite

                              pseudomorph

                              after pyrochlore Churchite

                              YPO4

                              middot2H2

                              O

                              Supergene Minerals ndash

                              MT Weld Australia

                              Apatite

                              with Substitutional

                              REE

                              Oka Quebec

                              Carbonatite

                              Nolanrsquos Bore Australia

                              Carbonatite

                              Mushgai

                              Khudag Mongolia

                              Carbonatite

                              Phalaborwa South Africa

                              Carbonatite

                              Kola Peninsula

                              Carbonatite

                              and Alkaline Massifs

                              Hoidas

                              Lake Saskatchewan

                              Hydrothermal in Granites

                              Mineville New York

                              Tailings from Magnetite Mining

                              Mineville may be the only Y and HREE dominant source currently known

                              HD -

                              176 mm HD -

                              44 mm

                              XPL MicrographsBastnaumlsite

                              in Carbonatite

                              Mountain Pass CA

                              BSE Image AncyliteHD ndash

                              07 mm

                              PPL Micrograph Ancylite

                              Ancylite

                              (Ce)

                              SrREE(CO3

                              )2

                              (OH)H2

                              O

                              LREE -

                              dominant ndash

                              50 wt REO

                              An exploration target in the

                              Bear Lodge Carbonatite

                              Complex of northeastern Wyoming

                              Red Wine Complex Labrador Dora Bay Alaska

                              Eudialyte

                              Na15

                              Ca6

                              (Fe2+Mn2+)3

                              Zr3

                              (SiNb)(Si25

                              O73

                              )(OOHH2

                              O)3

                              (CLOH)2

                              Eudialyite

                              may also contain Y and HREE

                              in amounts exceeding 4 wt The

                              mineral is easily dissolved in weak acids

                              but colloidal silica currently presents a

                              problem in the isolation of Y REE and Zr

                              oxides

                              Kipawa Quebec

                              Massive Britholite

                              (Ce) Oka Quebec

                              Britholite

                              (Ce) Concentrate from Skarn

                              Kipawa Quebec

                              Britholite

                              ndash

                              (REEYCa)5

                              (SiO4

                              PO4

                              )3

                              (OHF)

                              This mineral has the potential for occurring in ore quantities in skarn

                              associated with syenite

                              gneiss in Kipawa Quebec

                              Allanite

                              (Ce) (CeCaY)2

                              (AlFe2+Fe3+)3

                              (SiO4

                              )3

                              (OH)

                              Allanite

                              is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                              Allanite

                              ndash

                              Hydrothermal Mountain Pass CA Allanite

                              ndash

                              Pegmatite Timmins Ontario

                              Eudialyte

                              and Mosandrite

                              in Peralkaline

                              Syenite

                              Kipawa Quebec

                              Britholite-Rich Skarn

                              All brown prisms are britholite

                              (Horizontal Distance ndash 46 mm)

                              Britholite

                              Concentrate

                              (mm scale)

                              Britholite

                              ndash

                              (CeYCa)5 (SiO4PO4 )3 (OHF)

                              Kipawa Quebec

                              Cathodoluminescence

                              Macrograph of Iimoriite

                              in Syenite

                              ndash

                              Bokan

                              Mountain

                              Mottled light blue and tan clusters -

                              Iimoriite

                              Red groundmass ndash

                              Feldspar

                              (Horizontal distance of rock slab ndash 46 mm)

                              Iimoriite

                              (Y)

                              Y2 (SiO4 )(CO3 )

                              Yttrofluorite

                              (CaY)F2

                              Iimoriite

                              Concentrate ndash

                              Bokan

                              MT (1 mm scale)

                              Wicheeda

                              Lake Heavy Mineral Composite mdash

                              (from samples 828951 52 53)

                              These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                              and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                              As a final statement it should be emphasizedhellip

                              1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                              2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                              3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                              4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                              5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                              Rare Earth Elements

                              bull

                              Name something of a misnomerndash

                              Rarest REEs

                              are over 200 times more

                              abundant then gold

                              bull

                              Variation in distribution for two reasons ndash

                              Compatibility with common rock forming materials

                              ndash

                              CosmicCrustal abundances

                              Crustal Abundances of Elements

                              Occurrencebull

                              REEs

                              occur mostly as

                              substitutional

                              impurities in many rock forming minerals

                              bull

                              Only a few the REE minerals have sufficient quantities to be considered important sources

                              bull

                              Defined as minerals having at least one site that is filled by REEs

                              andor Yttrium more often then any other elementMonazite

                              Rare Earth Minerals

                              bull

                              Form by primary crystalization

                              from magma or by hydrothermal reactions

                              bull

                              Found hosted in carbonate rocks in pegmatites

                              and as accessory minerals in

                              igneous rocks

                              bull

                              Stable REE minerals and can be concentrated in weathering zones

                              REE Mineralsbull

                              The most important REE minerals is bastnaumlsite

                              REE(CO3)F

                              bull

                              Other notable sources are ndash

                              Monazite REE(PO4) ndash

                              Xenotime

                              YPO4

                              bull

                              All may contain radioactive species such as thorium

                              and uraniumndash

                              are avoided as source materials

                              Bastnesitebull

                              Bastnasite

                              [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                              bull

                              Containing 60 to 70 rare earth oxides (REOs)

                              bull

                              REE site is most commonly filled by LREEs

                              and Y

                              Other REE mineralsbull

                              Monazite [(LREEYTh)PO4] ndash

                              Contains about 50ndash78 rare earth oxides

                              ndash

                              Forms in heavy mineral sands placer deposits associated with beach environments

                              bull

                              Xenotime

                              [(YPO4)] ndash

                              Contains 54ndash65 rare earth oxides

                              ndash

                              Yttrium Erbium and Cerium most common ndash

                              Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                              Electron Configuration

                              bull

                              The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                              bull

                              REEs

                              have same outer electronic configuration (+3) they differ in their number of 4f electrons

                              Electron Configuartion

                              REE Behaviorbull

                              Because of their shared behaviour REEs

                              tend to be

                              present in nature as a group All REEs

                              commonly substitute for one another in minerals

                              bull

                              Yet the REEs

                              are capable of showing great variation in their distributions

                              bull

                              Comes about due to ndash

                              Differences in ionic radius ndash

                              Crystal structure (Coordination Number)ndash

                              Basicity

                              of the mineral ndash

                              The elementrsquos solubility and ability to migrate in the environment ndash

                              Content of REEs

                              in source fluids

                              Ionic Radiusbull

                              The ionic radius of the REEs

                              is inversely related to atomic number

                              bull

                              The heavy rare earths are smaller ndash

                              more similar to Mn2+ (ionic radius 008 nanometers)

                              bull

                              LREEs

                              are largerndash

                              more comparable in size to Ca2+ (ionic radius 01 nanometer)

                              bull

                              Charge balance achieved through some sites being left vacant or

                              by coupled substitution with lower charged mineral (Na+)

                              In nanometers

                              Coordination Number

                              bull

                              Coordination number the number of atoms touching a particular atom in a crystal lattice

                              bull

                              Coordination number for this structure is 8

                              Coordination Numberbull

                              The heavy and light REEs

                              differ in the coordination

                              numbers (CN) with oxygenndash

                              HREEs

                              have CN between six to nine ndash

                              LREEs

                              have higher CNs

                              bull

                              Minerals with high CNs

                              associated with REE site

                              will favor LREEsndash

                              Bastnasite

                              CN = 11 ndash

                              Monazite CN = 9

                              bull

                              Those with low CNs

                              will preferentially select HREEs ndash

                              Xenotime

                              has a value of 8

                              Other Factorsbull

                              Minerals basicityndash

                              Alkalic

                              rocks host minerals with elevated LREE content ndash

                              Rocks with lower basicity

                              have lower amounts of LREEs

                              relative to their HREE content

                              bull

                              Solubilityndash

                              LREEs

                              are more soluble in water then the HREEsndash

                              Important characteristic for hydrothermally derived minerals

                              bull

                              MagmaHydrothermal fluid compositionndash

                              Minerals will take what they can get

                              REEs

                              and Economicsbull

                              The REEs

                              and Yttrium have a very broad range of applications mostly in high technology fields

                              bull

                              84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                              bull

                              REEs

                              used primarily for automotive (25) petroleum (22) and metallurgic (20)

                              HREEs

                              and Magnetism

                              bull

                              HREEs

                              exhibit complex magnetic behaviour on account of electron structurendash

                              They share the same outer shell electron configuration (valence = +3)

                              ndash

                              Differ in number of 4f electrons

                              Applications in Magnetismbull

                              Terbium and

                              Dysprosium

                              bull

                              Components of Terfenol-D

                              alloy

                              with the formula Tb(03) Dy(07) Fe(19)

                              bull

                              Has the higher magnetostriction

                              then any other alloyndash

                              expands and contracts in magnetic field

                              bull

                              Developed by American Navy for sonar

                              systems ndash

                              Now has applications in magnetomechanical

                              sensors and other electronic devices

                              Applications in Magnetism

                              bull

                              Holmium

                              bull

                              Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                              elements

                              bull

                              Creates the strongest artificially generated magnetic fieldsndash

                              In research where strong magnetic fields are needed

                              HREEs

                              and Nuclear Technology

                              bull

                              Dysprosium Homium Erbium

                              bull

                              High neutron

                              absorption cross-section ndash

                              Measure of probability of neutron capture

                              bull

                              Used in neutron-absorbing control rods in nuclear reactors

                              HREEs

                              and Nuclear Technology

                              bull

                              Lutetiumbull

                              Radioactive isotope used in radiometric dating

                              bull

                              Thulium bull

                              Stable thulium used as a radiation

                              source

                              in portable X-ray

                              devices

                              Mountain Passbull

                              Bastnasite

                              is the major REE mineral bull

                              High grade accessory mineral of igneous or hydrothermal originsbull

                              31 million tons of 886 by weight of rare earth oxides (REO) bull

                              Mining stopped in 1994 ndash

                              Thorium content of waste rock ndash

                              Availability of inexpensive REEs

                              from China

                              San Bernardino County

                              Bayan

                              Obobull

                              The worldrsquos primary source for both yttrium and the rare earth elements

                              bull

                              37 million tons of ore bull

                              Main REE source there is Bastnasite

                              World Production

                              Explorationbull

                              84 of REE imports to US are from China

                              bull

                              Increasing demand for high tech applications spurred increase in exploration in 2007

                              bull

                              Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                              Lake as well as in

                              Malawi Africa

                              Environmental Considerations

                              bull

                              REE soil and food contaminationbull

                              Acid Mine Drainage and groundwater systems

                              bull

                              Radioactive elements

                              REE Fertilizerbull

                              In China REE enriched fertilizer has been used in crop fields since 1990

                              bull

                              At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                              every year

                              bull

                              Research and agricultural practice that provides evidence that REEs

                              will improve crop quality an yield

                              bull

                              The ramifications environmental and human exposure to REEs

                              are not well understood

                              Investigation by T Liang et albull

                              Revealed that the average concentration of total REEs

                              in Chinese soil is

                              1768 mgkg ranging between 850 to 5227 mgkg

                              bull

                              In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                              Implicationsbull

                              Human health effects not completely understood

                              bull

                              REE soil content shown to be detrimental to some plant speciesndash

                              100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                              Acid Mine Drainage (AMD)bull

                              Rain waters contacts waste rock facilitating acid forming reactions

                              bull

                              Increases the capacity of the water to leach potentially harmful elements from waste piles

                              bull

                              Process mobilizes established ecotoxins

                              (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                              bull

                              Historically dismissed as minor environmental risk

                              Radioactive Elements

                              bull

                              REEs

                              associated with uranium and thorium

                              bull

                              Bastnesite 32 thorium

                              bull

                              Monazite sands 6 to 12 thorium oxide

                              bull

                              Ores containing radioactive elements are avoided as sources of REEs

                              Radioactive Hazardsbull

                              Mountain Pass

                              bull

                              Accidentsndash

                              In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                              bull

                              Health Effectsndash

                              inflammatory bowel disease ndash

                              Prolonged seizures ndash

                              Cysts ndash

                              Cancers

                              bull

                              Waste Disposal ndash

                              Yucca Mountain

                              Summarybull

                              REE concentrations in the crust are rare

                              bull

                              Several geochemical factors influencing distribution including ionic radius and coordination number

                              bull

                              Main REE minerals are bastnasite monazite and xenotime

                              bull

                              Most important deposits are found at Bayan

                              Obo China and Mountain Pass USA

                              bull

                              Important electronic and nuclear applications

                              bull

                              Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                              system contamination though acid mine drainage association with

                              radioactive elements

                              Referencesbull

                              E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                              bull

                              Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                              bull

                              G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                              bull

                              B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                              The Government of South Australia wwwpirsagovaubull

                              The US geological Survey Mineralsusgsgovbull

                              wwwelementsdatabasecombull

                              wwwastrolsaumichedu~cowleyintro2htmlbull

                              wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                              webmineralcomdataMonazite-(Ce)shtmlbull

                              wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                              wwwstevegbcomimagesscienceorbital_fillingpngbull

                              wwwchemicalelementscomelementseuhtmlbull

                              boomeriaorgchemlecturestextass2table10-9jpgbull

                              lostcontentquakecomfiles200802holmiumpngbull

                              chinageocitylocatorcomcitiesChinaQinghaibull

                              geowebrudruzal-Bayan-Obohtmbull

                              enwikipediaorgwikiSan_Bernardino_County_Californiabull

                              wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                              enwikipediaorgwikiMonazitebull

                              webmineralcomdataBastnasite-(La)shtmlbull

                              wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                              httpwwwavalonventurescombull

                              wwwnewsweekcomid43884bull

                              httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                              httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                              • Slide Number 1
                              • Slide Number 2
                              • Slide Number 3
                              • Slide Number 4
                              • Slide Number 5
                              • Slide Number 6
                              • Slide Number 7
                              • Slide Number 8
                              • Slide Number 9
                              • Slide Number 10
                              • Slide Number 11
                              • Slide Number 12
                              • Slide Number 13
                              • Slide Number 14
                              • Slide Number 15
                              • Slide Number 16
                              • Slide Number 17
                              • Slide Number 18
                              • Slide Number 19
                              • Slide Number 20
                              • Slide Number 21
                              • Slide Number 22
                              • Slide Number 23
                              • Slide Number 24
                              • Slide Number 25
                              • Slide Number 26
                              • Slide Number 27
                              • Slide Number 28
                              • Slide Number 29
                              • Slide Number 30
                              • Slide Number 31
                              • Slide Number 32
                              • Slide Number 33
                              • Slide Number 34
                              • Slide Number 35
                              • Slide Number 36
                              • Slide Number 37
                              • Slide Number 38
                              • Slide Number 39
                              • Slide Number 40
                              • Slide Number 41
                              • Slide Number 42
                              • Slide Number 43
                              • Slide Number 44
                              • Slide Number 45
                              • Slide Number 46
                              • Slide Number 47
                              • Slide Number 48
                              • Slide Number 49
                              • Slide Number 50
                              • Slide Number 51
                              • Rare Earth Elements
                              • Crustal Abundances of Elements
                              • Occurrence
                              • Rare Earth Minerals
                              • REE Minerals
                              • Bastnesite
                              • Other REE minerals
                              • Electron Configuration
                              • Electron Configuartion
                              • REE Behavior
                              • Ionic Radius
                              • Coordination Number
                              • Coordination Number
                              • Other Factors
                              • REEs and Economics
                              • HREEs and Magnetism
                              • Applications in Magnetism
                              • Applications in Magnetism
                              • HREEs and Nuclear Technology
                              • HREEs and Nuclear Technology
                              • Mountain Pass
                              • Bayan Obo
                              • World Production
                              • Exploration
                              • Environmental Considerations
                              • REE Fertilizer
                              • Investigation by T Liang et al
                              • Implications
                              • Acid Mine Drainage (AMD)
                              • Radioactive Elements
                              • Radioactive Hazards
                              • Summary
                              • References

                                Major Rare Earth Sources

                                Mineral

                                Composition

                                Occurrence

                                Bastnaumlsite

                                (Ce) (REE) CO3

                                F

                                Carbonatites

                                Monazite (Ce) (REE) PO4

                                Beach Sands Hydrothermal

                                Xenotime

                                (Y) (YREE) PO4

                                Beach Sands Hydrothermal

                                Loparite

                                (Ce) (REENaCa) (Ti NbTa)O3

                                Alkaline igneous massif

                                South China Clays (Ion-adsorbed REE+Y in Clays)

                                Uraninite

                                (REE and Y mdash

                                Released as dissolved elements

                                in rafinates

                                from uraninite)

                                Monazite pseudomorph

                                after apatite Monazite pseudomorph

                                after Rhabdophane

                                Florencite

                                pseudomorph

                                after pyrochlore Churchite

                                YPO4

                                middot2H2

                                O

                                Supergene Minerals ndash

                                MT Weld Australia

                                Apatite

                                with Substitutional

                                REE

                                Oka Quebec

                                Carbonatite

                                Nolanrsquos Bore Australia

                                Carbonatite

                                Mushgai

                                Khudag Mongolia

                                Carbonatite

                                Phalaborwa South Africa

                                Carbonatite

                                Kola Peninsula

                                Carbonatite

                                and Alkaline Massifs

                                Hoidas

                                Lake Saskatchewan

                                Hydrothermal in Granites

                                Mineville New York

                                Tailings from Magnetite Mining

                                Mineville may be the only Y and HREE dominant source currently known

                                HD -

                                176 mm HD -

                                44 mm

                                XPL MicrographsBastnaumlsite

                                in Carbonatite

                                Mountain Pass CA

                                BSE Image AncyliteHD ndash

                                07 mm

                                PPL Micrograph Ancylite

                                Ancylite

                                (Ce)

                                SrREE(CO3

                                )2

                                (OH)H2

                                O

                                LREE -

                                dominant ndash

                                50 wt REO

                                An exploration target in the

                                Bear Lodge Carbonatite

                                Complex of northeastern Wyoming

                                Red Wine Complex Labrador Dora Bay Alaska

                                Eudialyte

                                Na15

                                Ca6

                                (Fe2+Mn2+)3

                                Zr3

                                (SiNb)(Si25

                                O73

                                )(OOHH2

                                O)3

                                (CLOH)2

                                Eudialyite

                                may also contain Y and HREE

                                in amounts exceeding 4 wt The

                                mineral is easily dissolved in weak acids

                                but colloidal silica currently presents a

                                problem in the isolation of Y REE and Zr

                                oxides

                                Kipawa Quebec

                                Massive Britholite

                                (Ce) Oka Quebec

                                Britholite

                                (Ce) Concentrate from Skarn

                                Kipawa Quebec

                                Britholite

                                ndash

                                (REEYCa)5

                                (SiO4

                                PO4

                                )3

                                (OHF)

                                This mineral has the potential for occurring in ore quantities in skarn

                                associated with syenite

                                gneiss in Kipawa Quebec

                                Allanite

                                (Ce) (CeCaY)2

                                (AlFe2+Fe3+)3

                                (SiO4

                                )3

                                (OH)

                                Allanite

                                is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                                Allanite

                                ndash

                                Hydrothermal Mountain Pass CA Allanite

                                ndash

                                Pegmatite Timmins Ontario

                                Eudialyte

                                and Mosandrite

                                in Peralkaline

                                Syenite

                                Kipawa Quebec

                                Britholite-Rich Skarn

                                All brown prisms are britholite

                                (Horizontal Distance ndash 46 mm)

                                Britholite

                                Concentrate

                                (mm scale)

                                Britholite

                                ndash

                                (CeYCa)5 (SiO4PO4 )3 (OHF)

                                Kipawa Quebec

                                Cathodoluminescence

                                Macrograph of Iimoriite

                                in Syenite

                                ndash

                                Bokan

                                Mountain

                                Mottled light blue and tan clusters -

                                Iimoriite

                                Red groundmass ndash

                                Feldspar

                                (Horizontal distance of rock slab ndash 46 mm)

                                Iimoriite

                                (Y)

                                Y2 (SiO4 )(CO3 )

                                Yttrofluorite

                                (CaY)F2

                                Iimoriite

                                Concentrate ndash

                                Bokan

                                MT (1 mm scale)

                                Wicheeda

                                Lake Heavy Mineral Composite mdash

                                (from samples 828951 52 53)

                                These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                As a final statement it should be emphasizedhellip

                                1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                Rare Earth Elements

                                bull

                                Name something of a misnomerndash

                                Rarest REEs

                                are over 200 times more

                                abundant then gold

                                bull

                                Variation in distribution for two reasons ndash

                                Compatibility with common rock forming materials

                                ndash

                                CosmicCrustal abundances

                                Crustal Abundances of Elements

                                Occurrencebull

                                REEs

                                occur mostly as

                                substitutional

                                impurities in many rock forming minerals

                                bull

                                Only a few the REE minerals have sufficient quantities to be considered important sources

                                bull

                                Defined as minerals having at least one site that is filled by REEs

                                andor Yttrium more often then any other elementMonazite

                                Rare Earth Minerals

                                bull

                                Form by primary crystalization

                                from magma or by hydrothermal reactions

                                bull

                                Found hosted in carbonate rocks in pegmatites

                                and as accessory minerals in

                                igneous rocks

                                bull

                                Stable REE minerals and can be concentrated in weathering zones

                                REE Mineralsbull

                                The most important REE minerals is bastnaumlsite

                                REE(CO3)F

                                bull

                                Other notable sources are ndash

                                Monazite REE(PO4) ndash

                                Xenotime

                                YPO4

                                bull

                                All may contain radioactive species such as thorium

                                and uraniumndash

                                are avoided as source materials

                                Bastnesitebull

                                Bastnasite

                                [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                bull

                                Containing 60 to 70 rare earth oxides (REOs)

                                bull

                                REE site is most commonly filled by LREEs

                                and Y

                                Other REE mineralsbull

                                Monazite [(LREEYTh)PO4] ndash

                                Contains about 50ndash78 rare earth oxides

                                ndash

                                Forms in heavy mineral sands placer deposits associated with beach environments

                                bull

                                Xenotime

                                [(YPO4)] ndash

                                Contains 54ndash65 rare earth oxides

                                ndash

                                Yttrium Erbium and Cerium most common ndash

                                Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                Electron Configuration

                                bull

                                The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                bull

                                REEs

                                have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                Electron Configuartion

                                REE Behaviorbull

                                Because of their shared behaviour REEs

                                tend to be

                                present in nature as a group All REEs

                                commonly substitute for one another in minerals

                                bull

                                Yet the REEs

                                are capable of showing great variation in their distributions

                                bull

                                Comes about due to ndash

                                Differences in ionic radius ndash

                                Crystal structure (Coordination Number)ndash

                                Basicity

                                of the mineral ndash

                                The elementrsquos solubility and ability to migrate in the environment ndash

                                Content of REEs

                                in source fluids

                                Ionic Radiusbull

                                The ionic radius of the REEs

                                is inversely related to atomic number

                                bull

                                The heavy rare earths are smaller ndash

                                more similar to Mn2+ (ionic radius 008 nanometers)

                                bull

                                LREEs

                                are largerndash

                                more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                bull

                                Charge balance achieved through some sites being left vacant or

                                by coupled substitution with lower charged mineral (Na+)

                                In nanometers

                                Coordination Number

                                bull

                                Coordination number the number of atoms touching a particular atom in a crystal lattice

                                bull

                                Coordination number for this structure is 8

                                Coordination Numberbull

                                The heavy and light REEs

                                differ in the coordination

                                numbers (CN) with oxygenndash

                                HREEs

                                have CN between six to nine ndash

                                LREEs

                                have higher CNs

                                bull

                                Minerals with high CNs

                                associated with REE site

                                will favor LREEsndash

                                Bastnasite

                                CN = 11 ndash

                                Monazite CN = 9

                                bull

                                Those with low CNs

                                will preferentially select HREEs ndash

                                Xenotime

                                has a value of 8

                                Other Factorsbull

                                Minerals basicityndash

                                Alkalic

                                rocks host minerals with elevated LREE content ndash

                                Rocks with lower basicity

                                have lower amounts of LREEs

                                relative to their HREE content

                                bull

                                Solubilityndash

                                LREEs

                                are more soluble in water then the HREEsndash

                                Important characteristic for hydrothermally derived minerals

                                bull

                                MagmaHydrothermal fluid compositionndash

                                Minerals will take what they can get

                                REEs

                                and Economicsbull

                                The REEs

                                and Yttrium have a very broad range of applications mostly in high technology fields

                                bull

                                84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                bull

                                REEs

                                used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                HREEs

                                and Magnetism

                                bull

                                HREEs

                                exhibit complex magnetic behaviour on account of electron structurendash

                                They share the same outer shell electron configuration (valence = +3)

                                ndash

                                Differ in number of 4f electrons

                                Applications in Magnetismbull

                                Terbium and

                                Dysprosium

                                bull

                                Components of Terfenol-D

                                alloy

                                with the formula Tb(03) Dy(07) Fe(19)

                                bull

                                Has the higher magnetostriction

                                then any other alloyndash

                                expands and contracts in magnetic field

                                bull

                                Developed by American Navy for sonar

                                systems ndash

                                Now has applications in magnetomechanical

                                sensors and other electronic devices

                                Applications in Magnetism

                                bull

                                Holmium

                                bull

                                Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                elements

                                bull

                                Creates the strongest artificially generated magnetic fieldsndash

                                In research where strong magnetic fields are needed

                                HREEs

                                and Nuclear Technology

                                bull

                                Dysprosium Homium Erbium

                                bull

                                High neutron

                                absorption cross-section ndash

                                Measure of probability of neutron capture

                                bull

                                Used in neutron-absorbing control rods in nuclear reactors

                                HREEs

                                and Nuclear Technology

                                bull

                                Lutetiumbull

                                Radioactive isotope used in radiometric dating

                                bull

                                Thulium bull

                                Stable thulium used as a radiation

                                source

                                in portable X-ray

                                devices

                                Mountain Passbull

                                Bastnasite

                                is the major REE mineral bull

                                High grade accessory mineral of igneous or hydrothermal originsbull

                                31 million tons of 886 by weight of rare earth oxides (REO) bull

                                Mining stopped in 1994 ndash

                                Thorium content of waste rock ndash

                                Availability of inexpensive REEs

                                from China

                                San Bernardino County

                                Bayan

                                Obobull

                                The worldrsquos primary source for both yttrium and the rare earth elements

                                bull

                                37 million tons of ore bull

                                Main REE source there is Bastnasite

                                World Production

                                Explorationbull

                                84 of REE imports to US are from China

                                bull

                                Increasing demand for high tech applications spurred increase in exploration in 2007

                                bull

                                Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                Lake as well as in

                                Malawi Africa

                                Environmental Considerations

                                bull

                                REE soil and food contaminationbull

                                Acid Mine Drainage and groundwater systems

                                bull

                                Radioactive elements

                                REE Fertilizerbull

                                In China REE enriched fertilizer has been used in crop fields since 1990

                                bull

                                At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                every year

                                bull

                                Research and agricultural practice that provides evidence that REEs

                                will improve crop quality an yield

                                bull

                                The ramifications environmental and human exposure to REEs

                                are not well understood

                                Investigation by T Liang et albull

                                Revealed that the average concentration of total REEs

                                in Chinese soil is

                                1768 mgkg ranging between 850 to 5227 mgkg

                                bull

                                In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                Implicationsbull

                                Human health effects not completely understood

                                bull

                                REE soil content shown to be detrimental to some plant speciesndash

                                100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                Acid Mine Drainage (AMD)bull

                                Rain waters contacts waste rock facilitating acid forming reactions

                                bull

                                Increases the capacity of the water to leach potentially harmful elements from waste piles

                                bull

                                Process mobilizes established ecotoxins

                                (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                bull

                                Historically dismissed as minor environmental risk

                                Radioactive Elements

                                bull

                                REEs

                                associated with uranium and thorium

                                bull

                                Bastnesite 32 thorium

                                bull

                                Monazite sands 6 to 12 thorium oxide

                                bull

                                Ores containing radioactive elements are avoided as sources of REEs

                                Radioactive Hazardsbull

                                Mountain Pass

                                bull

                                Accidentsndash

                                In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                bull

                                Health Effectsndash

                                inflammatory bowel disease ndash

                                Prolonged seizures ndash

                                Cysts ndash

                                Cancers

                                bull

                                Waste Disposal ndash

                                Yucca Mountain

                                Summarybull

                                REE concentrations in the crust are rare

                                bull

                                Several geochemical factors influencing distribution including ionic radius and coordination number

                                bull

                                Main REE minerals are bastnasite monazite and xenotime

                                bull

                                Most important deposits are found at Bayan

                                Obo China and Mountain Pass USA

                                bull

                                Important electronic and nuclear applications

                                bull

                                Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                system contamination though acid mine drainage association with

                                radioactive elements

                                Referencesbull

                                E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                bull

                                Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                bull

                                G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                bull

                                B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                The Government of South Australia wwwpirsagovaubull

                                The US geological Survey Mineralsusgsgovbull

                                wwwelementsdatabasecombull

                                wwwastrolsaumichedu~cowleyintro2htmlbull

                                wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                webmineralcomdataMonazite-(Ce)shtmlbull

                                wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                wwwstevegbcomimagesscienceorbital_fillingpngbull

                                wwwchemicalelementscomelementseuhtmlbull

                                boomeriaorgchemlecturestextass2table10-9jpgbull

                                lostcontentquakecomfiles200802holmiumpngbull

                                chinageocitylocatorcomcitiesChinaQinghaibull

                                geowebrudruzal-Bayan-Obohtmbull

                                enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                enwikipediaorgwikiMonazitebull

                                webmineralcomdataBastnasite-(La)shtmlbull

                                wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                httpwwwavalonventurescombull

                                wwwnewsweekcomid43884bull

                                httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                • Slide Number 1
                                • Slide Number 2
                                • Slide Number 3
                                • Slide Number 4
                                • Slide Number 5
                                • Slide Number 6
                                • Slide Number 7
                                • Slide Number 8
                                • Slide Number 9
                                • Slide Number 10
                                • Slide Number 11
                                • Slide Number 12
                                • Slide Number 13
                                • Slide Number 14
                                • Slide Number 15
                                • Slide Number 16
                                • Slide Number 17
                                • Slide Number 18
                                • Slide Number 19
                                • Slide Number 20
                                • Slide Number 21
                                • Slide Number 22
                                • Slide Number 23
                                • Slide Number 24
                                • Slide Number 25
                                • Slide Number 26
                                • Slide Number 27
                                • Slide Number 28
                                • Slide Number 29
                                • Slide Number 30
                                • Slide Number 31
                                • Slide Number 32
                                • Slide Number 33
                                • Slide Number 34
                                • Slide Number 35
                                • Slide Number 36
                                • Slide Number 37
                                • Slide Number 38
                                • Slide Number 39
                                • Slide Number 40
                                • Slide Number 41
                                • Slide Number 42
                                • Slide Number 43
                                • Slide Number 44
                                • Slide Number 45
                                • Slide Number 46
                                • Slide Number 47
                                • Slide Number 48
                                • Slide Number 49
                                • Slide Number 50
                                • Slide Number 51
                                • Rare Earth Elements
                                • Crustal Abundances of Elements
                                • Occurrence
                                • Rare Earth Minerals
                                • REE Minerals
                                • Bastnesite
                                • Other REE minerals
                                • Electron Configuration
                                • Electron Configuartion
                                • REE Behavior
                                • Ionic Radius
                                • Coordination Number
                                • Coordination Number
                                • Other Factors
                                • REEs and Economics
                                • HREEs and Magnetism
                                • Applications in Magnetism
                                • Applications in Magnetism
                                • HREEs and Nuclear Technology
                                • HREEs and Nuclear Technology
                                • Mountain Pass
                                • Bayan Obo
                                • World Production
                                • Exploration
                                • Environmental Considerations
                                • REE Fertilizer
                                • Investigation by T Liang et al
                                • Implications
                                • Acid Mine Drainage (AMD)
                                • Radioactive Elements
                                • Radioactive Hazards
                                • Summary
                                • References

                                  Monazite pseudomorph

                                  after apatite Monazite pseudomorph

                                  after Rhabdophane

                                  Florencite

                                  pseudomorph

                                  after pyrochlore Churchite

                                  YPO4

                                  middot2H2

                                  O

                                  Supergene Minerals ndash

                                  MT Weld Australia

                                  Apatite

                                  with Substitutional

                                  REE

                                  Oka Quebec

                                  Carbonatite

                                  Nolanrsquos Bore Australia

                                  Carbonatite

                                  Mushgai

                                  Khudag Mongolia

                                  Carbonatite

                                  Phalaborwa South Africa

                                  Carbonatite

                                  Kola Peninsula

                                  Carbonatite

                                  and Alkaline Massifs

                                  Hoidas

                                  Lake Saskatchewan

                                  Hydrothermal in Granites

                                  Mineville New York

                                  Tailings from Magnetite Mining

                                  Mineville may be the only Y and HREE dominant source currently known

                                  HD -

                                  176 mm HD -

                                  44 mm

                                  XPL MicrographsBastnaumlsite

                                  in Carbonatite

                                  Mountain Pass CA

                                  BSE Image AncyliteHD ndash

                                  07 mm

                                  PPL Micrograph Ancylite

                                  Ancylite

                                  (Ce)

                                  SrREE(CO3

                                  )2

                                  (OH)H2

                                  O

                                  LREE -

                                  dominant ndash

                                  50 wt REO

                                  An exploration target in the

                                  Bear Lodge Carbonatite

                                  Complex of northeastern Wyoming

                                  Red Wine Complex Labrador Dora Bay Alaska

                                  Eudialyte

                                  Na15

                                  Ca6

                                  (Fe2+Mn2+)3

                                  Zr3

                                  (SiNb)(Si25

                                  O73

                                  )(OOHH2

                                  O)3

                                  (CLOH)2

                                  Eudialyite

                                  may also contain Y and HREE

                                  in amounts exceeding 4 wt The

                                  mineral is easily dissolved in weak acids

                                  but colloidal silica currently presents a

                                  problem in the isolation of Y REE and Zr

                                  oxides

                                  Kipawa Quebec

                                  Massive Britholite

                                  (Ce) Oka Quebec

                                  Britholite

                                  (Ce) Concentrate from Skarn

                                  Kipawa Quebec

                                  Britholite

                                  ndash

                                  (REEYCa)5

                                  (SiO4

                                  PO4

                                  )3

                                  (OHF)

                                  This mineral has the potential for occurring in ore quantities in skarn

                                  associated with syenite

                                  gneiss in Kipawa Quebec

                                  Allanite

                                  (Ce) (CeCaY)2

                                  (AlFe2+Fe3+)3

                                  (SiO4

                                  )3

                                  (OH)

                                  Allanite

                                  is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                                  Allanite

                                  ndash

                                  Hydrothermal Mountain Pass CA Allanite

                                  ndash

                                  Pegmatite Timmins Ontario

                                  Eudialyte

                                  and Mosandrite

                                  in Peralkaline

                                  Syenite

                                  Kipawa Quebec

                                  Britholite-Rich Skarn

                                  All brown prisms are britholite

                                  (Horizontal Distance ndash 46 mm)

                                  Britholite

                                  Concentrate

                                  (mm scale)

                                  Britholite

                                  ndash

                                  (CeYCa)5 (SiO4PO4 )3 (OHF)

                                  Kipawa Quebec

                                  Cathodoluminescence

                                  Macrograph of Iimoriite

                                  in Syenite

                                  ndash

                                  Bokan

                                  Mountain

                                  Mottled light blue and tan clusters -

                                  Iimoriite

                                  Red groundmass ndash

                                  Feldspar

                                  (Horizontal distance of rock slab ndash 46 mm)

                                  Iimoriite

                                  (Y)

                                  Y2 (SiO4 )(CO3 )

                                  Yttrofluorite

                                  (CaY)F2

                                  Iimoriite

                                  Concentrate ndash

                                  Bokan

                                  MT (1 mm scale)

                                  Wicheeda

                                  Lake Heavy Mineral Composite mdash

                                  (from samples 828951 52 53)

                                  These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                  and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                  As a final statement it should be emphasizedhellip

                                  1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                  2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                  3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                  4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                  5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                  Rare Earth Elements

                                  bull

                                  Name something of a misnomerndash

                                  Rarest REEs

                                  are over 200 times more

                                  abundant then gold

                                  bull

                                  Variation in distribution for two reasons ndash

                                  Compatibility with common rock forming materials

                                  ndash

                                  CosmicCrustal abundances

                                  Crustal Abundances of Elements

                                  Occurrencebull

                                  REEs

                                  occur mostly as

                                  substitutional

                                  impurities in many rock forming minerals

                                  bull

                                  Only a few the REE minerals have sufficient quantities to be considered important sources

                                  bull

                                  Defined as minerals having at least one site that is filled by REEs

                                  andor Yttrium more often then any other elementMonazite

                                  Rare Earth Minerals

                                  bull

                                  Form by primary crystalization

                                  from magma or by hydrothermal reactions

                                  bull

                                  Found hosted in carbonate rocks in pegmatites

                                  and as accessory minerals in

                                  igneous rocks

                                  bull

                                  Stable REE minerals and can be concentrated in weathering zones

                                  REE Mineralsbull

                                  The most important REE minerals is bastnaumlsite

                                  REE(CO3)F

                                  bull

                                  Other notable sources are ndash

                                  Monazite REE(PO4) ndash

                                  Xenotime

                                  YPO4

                                  bull

                                  All may contain radioactive species such as thorium

                                  and uraniumndash

                                  are avoided as source materials

                                  Bastnesitebull

                                  Bastnasite

                                  [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                  bull

                                  Containing 60 to 70 rare earth oxides (REOs)

                                  bull

                                  REE site is most commonly filled by LREEs

                                  and Y

                                  Other REE mineralsbull

                                  Monazite [(LREEYTh)PO4] ndash

                                  Contains about 50ndash78 rare earth oxides

                                  ndash

                                  Forms in heavy mineral sands placer deposits associated with beach environments

                                  bull

                                  Xenotime

                                  [(YPO4)] ndash

                                  Contains 54ndash65 rare earth oxides

                                  ndash

                                  Yttrium Erbium and Cerium most common ndash

                                  Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                  Electron Configuration

                                  bull

                                  The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                  bull

                                  REEs

                                  have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                  Electron Configuartion

                                  REE Behaviorbull

                                  Because of their shared behaviour REEs

                                  tend to be

                                  present in nature as a group All REEs

                                  commonly substitute for one another in minerals

                                  bull

                                  Yet the REEs

                                  are capable of showing great variation in their distributions

                                  bull

                                  Comes about due to ndash

                                  Differences in ionic radius ndash

                                  Crystal structure (Coordination Number)ndash

                                  Basicity

                                  of the mineral ndash

                                  The elementrsquos solubility and ability to migrate in the environment ndash

                                  Content of REEs

                                  in source fluids

                                  Ionic Radiusbull

                                  The ionic radius of the REEs

                                  is inversely related to atomic number

                                  bull

                                  The heavy rare earths are smaller ndash

                                  more similar to Mn2+ (ionic radius 008 nanometers)

                                  bull

                                  LREEs

                                  are largerndash

                                  more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                  bull

                                  Charge balance achieved through some sites being left vacant or

                                  by coupled substitution with lower charged mineral (Na+)

                                  In nanometers

                                  Coordination Number

                                  bull

                                  Coordination number the number of atoms touching a particular atom in a crystal lattice

                                  bull

                                  Coordination number for this structure is 8

                                  Coordination Numberbull

                                  The heavy and light REEs

                                  differ in the coordination

                                  numbers (CN) with oxygenndash

                                  HREEs

                                  have CN between six to nine ndash

                                  LREEs

                                  have higher CNs

                                  bull

                                  Minerals with high CNs

                                  associated with REE site

                                  will favor LREEsndash

                                  Bastnasite

                                  CN = 11 ndash

                                  Monazite CN = 9

                                  bull

                                  Those with low CNs

                                  will preferentially select HREEs ndash

                                  Xenotime

                                  has a value of 8

                                  Other Factorsbull

                                  Minerals basicityndash

                                  Alkalic

                                  rocks host minerals with elevated LREE content ndash

                                  Rocks with lower basicity

                                  have lower amounts of LREEs

                                  relative to their HREE content

                                  bull

                                  Solubilityndash

                                  LREEs

                                  are more soluble in water then the HREEsndash

                                  Important characteristic for hydrothermally derived minerals

                                  bull

                                  MagmaHydrothermal fluid compositionndash

                                  Minerals will take what they can get

                                  REEs

                                  and Economicsbull

                                  The REEs

                                  and Yttrium have a very broad range of applications mostly in high technology fields

                                  bull

                                  84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                  bull

                                  REEs

                                  used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                  HREEs

                                  and Magnetism

                                  bull

                                  HREEs

                                  exhibit complex magnetic behaviour on account of electron structurendash

                                  They share the same outer shell electron configuration (valence = +3)

                                  ndash

                                  Differ in number of 4f electrons

                                  Applications in Magnetismbull

                                  Terbium and

                                  Dysprosium

                                  bull

                                  Components of Terfenol-D

                                  alloy

                                  with the formula Tb(03) Dy(07) Fe(19)

                                  bull

                                  Has the higher magnetostriction

                                  then any other alloyndash

                                  expands and contracts in magnetic field

                                  bull

                                  Developed by American Navy for sonar

                                  systems ndash

                                  Now has applications in magnetomechanical

                                  sensors and other electronic devices

                                  Applications in Magnetism

                                  bull

                                  Holmium

                                  bull

                                  Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                  elements

                                  bull

                                  Creates the strongest artificially generated magnetic fieldsndash

                                  In research where strong magnetic fields are needed

                                  HREEs

                                  and Nuclear Technology

                                  bull

                                  Dysprosium Homium Erbium

                                  bull

                                  High neutron

                                  absorption cross-section ndash

                                  Measure of probability of neutron capture

                                  bull

                                  Used in neutron-absorbing control rods in nuclear reactors

                                  HREEs

                                  and Nuclear Technology

                                  bull

                                  Lutetiumbull

                                  Radioactive isotope used in radiometric dating

                                  bull

                                  Thulium bull

                                  Stable thulium used as a radiation

                                  source

                                  in portable X-ray

                                  devices

                                  Mountain Passbull

                                  Bastnasite

                                  is the major REE mineral bull

                                  High grade accessory mineral of igneous or hydrothermal originsbull

                                  31 million tons of 886 by weight of rare earth oxides (REO) bull

                                  Mining stopped in 1994 ndash

                                  Thorium content of waste rock ndash

                                  Availability of inexpensive REEs

                                  from China

                                  San Bernardino County

                                  Bayan

                                  Obobull

                                  The worldrsquos primary source for both yttrium and the rare earth elements

                                  bull

                                  37 million tons of ore bull

                                  Main REE source there is Bastnasite

                                  World Production

                                  Explorationbull

                                  84 of REE imports to US are from China

                                  bull

                                  Increasing demand for high tech applications spurred increase in exploration in 2007

                                  bull

                                  Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                  Lake as well as in

                                  Malawi Africa

                                  Environmental Considerations

                                  bull

                                  REE soil and food contaminationbull

                                  Acid Mine Drainage and groundwater systems

                                  bull

                                  Radioactive elements

                                  REE Fertilizerbull

                                  In China REE enriched fertilizer has been used in crop fields since 1990

                                  bull

                                  At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                  every year

                                  bull

                                  Research and agricultural practice that provides evidence that REEs

                                  will improve crop quality an yield

                                  bull

                                  The ramifications environmental and human exposure to REEs

                                  are not well understood

                                  Investigation by T Liang et albull

                                  Revealed that the average concentration of total REEs

                                  in Chinese soil is

                                  1768 mgkg ranging between 850 to 5227 mgkg

                                  bull

                                  In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                  Implicationsbull

                                  Human health effects not completely understood

                                  bull

                                  REE soil content shown to be detrimental to some plant speciesndash

                                  100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                  Acid Mine Drainage (AMD)bull

                                  Rain waters contacts waste rock facilitating acid forming reactions

                                  bull

                                  Increases the capacity of the water to leach potentially harmful elements from waste piles

                                  bull

                                  Process mobilizes established ecotoxins

                                  (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                  bull

                                  Historically dismissed as minor environmental risk

                                  Radioactive Elements

                                  bull

                                  REEs

                                  associated with uranium and thorium

                                  bull

                                  Bastnesite 32 thorium

                                  bull

                                  Monazite sands 6 to 12 thorium oxide

                                  bull

                                  Ores containing radioactive elements are avoided as sources of REEs

                                  Radioactive Hazardsbull

                                  Mountain Pass

                                  bull

                                  Accidentsndash

                                  In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                  bull

                                  Health Effectsndash

                                  inflammatory bowel disease ndash

                                  Prolonged seizures ndash

                                  Cysts ndash

                                  Cancers

                                  bull

                                  Waste Disposal ndash

                                  Yucca Mountain

                                  Summarybull

                                  REE concentrations in the crust are rare

                                  bull

                                  Several geochemical factors influencing distribution including ionic radius and coordination number

                                  bull

                                  Main REE minerals are bastnasite monazite and xenotime

                                  bull

                                  Most important deposits are found at Bayan

                                  Obo China and Mountain Pass USA

                                  bull

                                  Important electronic and nuclear applications

                                  bull

                                  Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                  system contamination though acid mine drainage association with

                                  radioactive elements

                                  Referencesbull

                                  E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                  bull

                                  Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                  bull

                                  G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                  bull

                                  B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                  The Government of South Australia wwwpirsagovaubull

                                  The US geological Survey Mineralsusgsgovbull

                                  wwwelementsdatabasecombull

                                  wwwastrolsaumichedu~cowleyintro2htmlbull

                                  wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                  webmineralcomdataMonazite-(Ce)shtmlbull

                                  wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                  wwwstevegbcomimagesscienceorbital_fillingpngbull

                                  wwwchemicalelementscomelementseuhtmlbull

                                  boomeriaorgchemlecturestextass2table10-9jpgbull

                                  lostcontentquakecomfiles200802holmiumpngbull

                                  chinageocitylocatorcomcitiesChinaQinghaibull

                                  geowebrudruzal-Bayan-Obohtmbull

                                  enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                  wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                  enwikipediaorgwikiMonazitebull

                                  webmineralcomdataBastnasite-(La)shtmlbull

                                  wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                  httpwwwavalonventurescombull

                                  wwwnewsweekcomid43884bull

                                  httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                  httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                  • Slide Number 1
                                  • Slide Number 2
                                  • Slide Number 3
                                  • Slide Number 4
                                  • Slide Number 5
                                  • Slide Number 6
                                  • Slide Number 7
                                  • Slide Number 8
                                  • Slide Number 9
                                  • Slide Number 10
                                  • Slide Number 11
                                  • Slide Number 12
                                  • Slide Number 13
                                  • Slide Number 14
                                  • Slide Number 15
                                  • Slide Number 16
                                  • Slide Number 17
                                  • Slide Number 18
                                  • Slide Number 19
                                  • Slide Number 20
                                  • Slide Number 21
                                  • Slide Number 22
                                  • Slide Number 23
                                  • Slide Number 24
                                  • Slide Number 25
                                  • Slide Number 26
                                  • Slide Number 27
                                  • Slide Number 28
                                  • Slide Number 29
                                  • Slide Number 30
                                  • Slide Number 31
                                  • Slide Number 32
                                  • Slide Number 33
                                  • Slide Number 34
                                  • Slide Number 35
                                  • Slide Number 36
                                  • Slide Number 37
                                  • Slide Number 38
                                  • Slide Number 39
                                  • Slide Number 40
                                  • Slide Number 41
                                  • Slide Number 42
                                  • Slide Number 43
                                  • Slide Number 44
                                  • Slide Number 45
                                  • Slide Number 46
                                  • Slide Number 47
                                  • Slide Number 48
                                  • Slide Number 49
                                  • Slide Number 50
                                  • Slide Number 51
                                  • Rare Earth Elements
                                  • Crustal Abundances of Elements
                                  • Occurrence
                                  • Rare Earth Minerals
                                  • REE Minerals
                                  • Bastnesite
                                  • Other REE minerals
                                  • Electron Configuration
                                  • Electron Configuartion
                                  • REE Behavior
                                  • Ionic Radius
                                  • Coordination Number
                                  • Coordination Number
                                  • Other Factors
                                  • REEs and Economics
                                  • HREEs and Magnetism
                                  • Applications in Magnetism
                                  • Applications in Magnetism
                                  • HREEs and Nuclear Technology
                                  • HREEs and Nuclear Technology
                                  • Mountain Pass
                                  • Bayan Obo
                                  • World Production
                                  • Exploration
                                  • Environmental Considerations
                                  • REE Fertilizer
                                  • Investigation by T Liang et al
                                  • Implications
                                  • Acid Mine Drainage (AMD)
                                  • Radioactive Elements
                                  • Radioactive Hazards
                                  • Summary
                                  • References

                                    Apatite

                                    with Substitutional

                                    REE

                                    Oka Quebec

                                    Carbonatite

                                    Nolanrsquos Bore Australia

                                    Carbonatite

                                    Mushgai

                                    Khudag Mongolia

                                    Carbonatite

                                    Phalaborwa South Africa

                                    Carbonatite

                                    Kola Peninsula

                                    Carbonatite

                                    and Alkaline Massifs

                                    Hoidas

                                    Lake Saskatchewan

                                    Hydrothermal in Granites

                                    Mineville New York

                                    Tailings from Magnetite Mining

                                    Mineville may be the only Y and HREE dominant source currently known

                                    HD -

                                    176 mm HD -

                                    44 mm

                                    XPL MicrographsBastnaumlsite

                                    in Carbonatite

                                    Mountain Pass CA

                                    BSE Image AncyliteHD ndash

                                    07 mm

                                    PPL Micrograph Ancylite

                                    Ancylite

                                    (Ce)

                                    SrREE(CO3

                                    )2

                                    (OH)H2

                                    O

                                    LREE -

                                    dominant ndash

                                    50 wt REO

                                    An exploration target in the

                                    Bear Lodge Carbonatite

                                    Complex of northeastern Wyoming

                                    Red Wine Complex Labrador Dora Bay Alaska

                                    Eudialyte

                                    Na15

                                    Ca6

                                    (Fe2+Mn2+)3

                                    Zr3

                                    (SiNb)(Si25

                                    O73

                                    )(OOHH2

                                    O)3

                                    (CLOH)2

                                    Eudialyite

                                    may also contain Y and HREE

                                    in amounts exceeding 4 wt The

                                    mineral is easily dissolved in weak acids

                                    but colloidal silica currently presents a

                                    problem in the isolation of Y REE and Zr

                                    oxides

                                    Kipawa Quebec

                                    Massive Britholite

                                    (Ce) Oka Quebec

                                    Britholite

                                    (Ce) Concentrate from Skarn

                                    Kipawa Quebec

                                    Britholite

                                    ndash

                                    (REEYCa)5

                                    (SiO4

                                    PO4

                                    )3

                                    (OHF)

                                    This mineral has the potential for occurring in ore quantities in skarn

                                    associated with syenite

                                    gneiss in Kipawa Quebec

                                    Allanite

                                    (Ce) (CeCaY)2

                                    (AlFe2+Fe3+)3

                                    (SiO4

                                    )3

                                    (OH)

                                    Allanite

                                    is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                                    Allanite

                                    ndash

                                    Hydrothermal Mountain Pass CA Allanite

                                    ndash

                                    Pegmatite Timmins Ontario

                                    Eudialyte

                                    and Mosandrite

                                    in Peralkaline

                                    Syenite

                                    Kipawa Quebec

                                    Britholite-Rich Skarn

                                    All brown prisms are britholite

                                    (Horizontal Distance ndash 46 mm)

                                    Britholite

                                    Concentrate

                                    (mm scale)

                                    Britholite

                                    ndash

                                    (CeYCa)5 (SiO4PO4 )3 (OHF)

                                    Kipawa Quebec

                                    Cathodoluminescence

                                    Macrograph of Iimoriite

                                    in Syenite

                                    ndash

                                    Bokan

                                    Mountain

                                    Mottled light blue and tan clusters -

                                    Iimoriite

                                    Red groundmass ndash

                                    Feldspar

                                    (Horizontal distance of rock slab ndash 46 mm)

                                    Iimoriite

                                    (Y)

                                    Y2 (SiO4 )(CO3 )

                                    Yttrofluorite

                                    (CaY)F2

                                    Iimoriite

                                    Concentrate ndash

                                    Bokan

                                    MT (1 mm scale)

                                    Wicheeda

                                    Lake Heavy Mineral Composite mdash

                                    (from samples 828951 52 53)

                                    These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                    and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                    As a final statement it should be emphasizedhellip

                                    1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                    2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                    3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                    4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                    5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                    Rare Earth Elements

                                    bull

                                    Name something of a misnomerndash

                                    Rarest REEs

                                    are over 200 times more

                                    abundant then gold

                                    bull

                                    Variation in distribution for two reasons ndash

                                    Compatibility with common rock forming materials

                                    ndash

                                    CosmicCrustal abundances

                                    Crustal Abundances of Elements

                                    Occurrencebull

                                    REEs

                                    occur mostly as

                                    substitutional

                                    impurities in many rock forming minerals

                                    bull

                                    Only a few the REE minerals have sufficient quantities to be considered important sources

                                    bull

                                    Defined as minerals having at least one site that is filled by REEs

                                    andor Yttrium more often then any other elementMonazite

                                    Rare Earth Minerals

                                    bull

                                    Form by primary crystalization

                                    from magma or by hydrothermal reactions

                                    bull

                                    Found hosted in carbonate rocks in pegmatites

                                    and as accessory minerals in

                                    igneous rocks

                                    bull

                                    Stable REE minerals and can be concentrated in weathering zones

                                    REE Mineralsbull

                                    The most important REE minerals is bastnaumlsite

                                    REE(CO3)F

                                    bull

                                    Other notable sources are ndash

                                    Monazite REE(PO4) ndash

                                    Xenotime

                                    YPO4

                                    bull

                                    All may contain radioactive species such as thorium

                                    and uraniumndash

                                    are avoided as source materials

                                    Bastnesitebull

                                    Bastnasite

                                    [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                    bull

                                    Containing 60 to 70 rare earth oxides (REOs)

                                    bull

                                    REE site is most commonly filled by LREEs

                                    and Y

                                    Other REE mineralsbull

                                    Monazite [(LREEYTh)PO4] ndash

                                    Contains about 50ndash78 rare earth oxides

                                    ndash

                                    Forms in heavy mineral sands placer deposits associated with beach environments

                                    bull

                                    Xenotime

                                    [(YPO4)] ndash

                                    Contains 54ndash65 rare earth oxides

                                    ndash

                                    Yttrium Erbium and Cerium most common ndash

                                    Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                    Electron Configuration

                                    bull

                                    The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                    bull

                                    REEs

                                    have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                    Electron Configuartion

                                    REE Behaviorbull

                                    Because of their shared behaviour REEs

                                    tend to be

                                    present in nature as a group All REEs

                                    commonly substitute for one another in minerals

                                    bull

                                    Yet the REEs

                                    are capable of showing great variation in their distributions

                                    bull

                                    Comes about due to ndash

                                    Differences in ionic radius ndash

                                    Crystal structure (Coordination Number)ndash

                                    Basicity

                                    of the mineral ndash

                                    The elementrsquos solubility and ability to migrate in the environment ndash

                                    Content of REEs

                                    in source fluids

                                    Ionic Radiusbull

                                    The ionic radius of the REEs

                                    is inversely related to atomic number

                                    bull

                                    The heavy rare earths are smaller ndash

                                    more similar to Mn2+ (ionic radius 008 nanometers)

                                    bull

                                    LREEs

                                    are largerndash

                                    more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                    bull

                                    Charge balance achieved through some sites being left vacant or

                                    by coupled substitution with lower charged mineral (Na+)

                                    In nanometers

                                    Coordination Number

                                    bull

                                    Coordination number the number of atoms touching a particular atom in a crystal lattice

                                    bull

                                    Coordination number for this structure is 8

                                    Coordination Numberbull

                                    The heavy and light REEs

                                    differ in the coordination

                                    numbers (CN) with oxygenndash

                                    HREEs

                                    have CN between six to nine ndash

                                    LREEs

                                    have higher CNs

                                    bull

                                    Minerals with high CNs

                                    associated with REE site

                                    will favor LREEsndash

                                    Bastnasite

                                    CN = 11 ndash

                                    Monazite CN = 9

                                    bull

                                    Those with low CNs

                                    will preferentially select HREEs ndash

                                    Xenotime

                                    has a value of 8

                                    Other Factorsbull

                                    Minerals basicityndash

                                    Alkalic

                                    rocks host minerals with elevated LREE content ndash

                                    Rocks with lower basicity

                                    have lower amounts of LREEs

                                    relative to their HREE content

                                    bull

                                    Solubilityndash

                                    LREEs

                                    are more soluble in water then the HREEsndash

                                    Important characteristic for hydrothermally derived minerals

                                    bull

                                    MagmaHydrothermal fluid compositionndash

                                    Minerals will take what they can get

                                    REEs

                                    and Economicsbull

                                    The REEs

                                    and Yttrium have a very broad range of applications mostly in high technology fields

                                    bull

                                    84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                    bull

                                    REEs

                                    used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                    HREEs

                                    and Magnetism

                                    bull

                                    HREEs

                                    exhibit complex magnetic behaviour on account of electron structurendash

                                    They share the same outer shell electron configuration (valence = +3)

                                    ndash

                                    Differ in number of 4f electrons

                                    Applications in Magnetismbull

                                    Terbium and

                                    Dysprosium

                                    bull

                                    Components of Terfenol-D

                                    alloy

                                    with the formula Tb(03) Dy(07) Fe(19)

                                    bull

                                    Has the higher magnetostriction

                                    then any other alloyndash

                                    expands and contracts in magnetic field

                                    bull

                                    Developed by American Navy for sonar

                                    systems ndash

                                    Now has applications in magnetomechanical

                                    sensors and other electronic devices

                                    Applications in Magnetism

                                    bull

                                    Holmium

                                    bull

                                    Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                    elements

                                    bull

                                    Creates the strongest artificially generated magnetic fieldsndash

                                    In research where strong magnetic fields are needed

                                    HREEs

                                    and Nuclear Technology

                                    bull

                                    Dysprosium Homium Erbium

                                    bull

                                    High neutron

                                    absorption cross-section ndash

                                    Measure of probability of neutron capture

                                    bull

                                    Used in neutron-absorbing control rods in nuclear reactors

                                    HREEs

                                    and Nuclear Technology

                                    bull

                                    Lutetiumbull

                                    Radioactive isotope used in radiometric dating

                                    bull

                                    Thulium bull

                                    Stable thulium used as a radiation

                                    source

                                    in portable X-ray

                                    devices

                                    Mountain Passbull

                                    Bastnasite

                                    is the major REE mineral bull

                                    High grade accessory mineral of igneous or hydrothermal originsbull

                                    31 million tons of 886 by weight of rare earth oxides (REO) bull

                                    Mining stopped in 1994 ndash

                                    Thorium content of waste rock ndash

                                    Availability of inexpensive REEs

                                    from China

                                    San Bernardino County

                                    Bayan

                                    Obobull

                                    The worldrsquos primary source for both yttrium and the rare earth elements

                                    bull

                                    37 million tons of ore bull

                                    Main REE source there is Bastnasite

                                    World Production

                                    Explorationbull

                                    84 of REE imports to US are from China

                                    bull

                                    Increasing demand for high tech applications spurred increase in exploration in 2007

                                    bull

                                    Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                    Lake as well as in

                                    Malawi Africa

                                    Environmental Considerations

                                    bull

                                    REE soil and food contaminationbull

                                    Acid Mine Drainage and groundwater systems

                                    bull

                                    Radioactive elements

                                    REE Fertilizerbull

                                    In China REE enriched fertilizer has been used in crop fields since 1990

                                    bull

                                    At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                    every year

                                    bull

                                    Research and agricultural practice that provides evidence that REEs

                                    will improve crop quality an yield

                                    bull

                                    The ramifications environmental and human exposure to REEs

                                    are not well understood

                                    Investigation by T Liang et albull

                                    Revealed that the average concentration of total REEs

                                    in Chinese soil is

                                    1768 mgkg ranging between 850 to 5227 mgkg

                                    bull

                                    In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                    Implicationsbull

                                    Human health effects not completely understood

                                    bull

                                    REE soil content shown to be detrimental to some plant speciesndash

                                    100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                    Acid Mine Drainage (AMD)bull

                                    Rain waters contacts waste rock facilitating acid forming reactions

                                    bull

                                    Increases the capacity of the water to leach potentially harmful elements from waste piles

                                    bull

                                    Process mobilizes established ecotoxins

                                    (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                    bull

                                    Historically dismissed as minor environmental risk

                                    Radioactive Elements

                                    bull

                                    REEs

                                    associated with uranium and thorium

                                    bull

                                    Bastnesite 32 thorium

                                    bull

                                    Monazite sands 6 to 12 thorium oxide

                                    bull

                                    Ores containing radioactive elements are avoided as sources of REEs

                                    Radioactive Hazardsbull

                                    Mountain Pass

                                    bull

                                    Accidentsndash

                                    In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                    bull

                                    Health Effectsndash

                                    inflammatory bowel disease ndash

                                    Prolonged seizures ndash

                                    Cysts ndash

                                    Cancers

                                    bull

                                    Waste Disposal ndash

                                    Yucca Mountain

                                    Summarybull

                                    REE concentrations in the crust are rare

                                    bull

                                    Several geochemical factors influencing distribution including ionic radius and coordination number

                                    bull

                                    Main REE minerals are bastnasite monazite and xenotime

                                    bull

                                    Most important deposits are found at Bayan

                                    Obo China and Mountain Pass USA

                                    bull

                                    Important electronic and nuclear applications

                                    bull

                                    Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                    system contamination though acid mine drainage association with

                                    radioactive elements

                                    Referencesbull

                                    E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                    bull

                                    Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                    bull

                                    G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                    bull

                                    B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                    The Government of South Australia wwwpirsagovaubull

                                    The US geological Survey Mineralsusgsgovbull

                                    wwwelementsdatabasecombull

                                    wwwastrolsaumichedu~cowleyintro2htmlbull

                                    wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                    webmineralcomdataMonazite-(Ce)shtmlbull

                                    wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                    wwwstevegbcomimagesscienceorbital_fillingpngbull

                                    wwwchemicalelementscomelementseuhtmlbull

                                    boomeriaorgchemlecturestextass2table10-9jpgbull

                                    lostcontentquakecomfiles200802holmiumpngbull

                                    chinageocitylocatorcomcitiesChinaQinghaibull

                                    geowebrudruzal-Bayan-Obohtmbull

                                    enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                    wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                    enwikipediaorgwikiMonazitebull

                                    webmineralcomdataBastnasite-(La)shtmlbull

                                    wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                    httpwwwavalonventurescombull

                                    wwwnewsweekcomid43884bull

                                    httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                    httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                    • Slide Number 1
                                    • Slide Number 2
                                    • Slide Number 3
                                    • Slide Number 4
                                    • Slide Number 5
                                    • Slide Number 6
                                    • Slide Number 7
                                    • Slide Number 8
                                    • Slide Number 9
                                    • Slide Number 10
                                    • Slide Number 11
                                    • Slide Number 12
                                    • Slide Number 13
                                    • Slide Number 14
                                    • Slide Number 15
                                    • Slide Number 16
                                    • Slide Number 17
                                    • Slide Number 18
                                    • Slide Number 19
                                    • Slide Number 20
                                    • Slide Number 21
                                    • Slide Number 22
                                    • Slide Number 23
                                    • Slide Number 24
                                    • Slide Number 25
                                    • Slide Number 26
                                    • Slide Number 27
                                    • Slide Number 28
                                    • Slide Number 29
                                    • Slide Number 30
                                    • Slide Number 31
                                    • Slide Number 32
                                    • Slide Number 33
                                    • Slide Number 34
                                    • Slide Number 35
                                    • Slide Number 36
                                    • Slide Number 37
                                    • Slide Number 38
                                    • Slide Number 39
                                    • Slide Number 40
                                    • Slide Number 41
                                    • Slide Number 42
                                    • Slide Number 43
                                    • Slide Number 44
                                    • Slide Number 45
                                    • Slide Number 46
                                    • Slide Number 47
                                    • Slide Number 48
                                    • Slide Number 49
                                    • Slide Number 50
                                    • Slide Number 51
                                    • Rare Earth Elements
                                    • Crustal Abundances of Elements
                                    • Occurrence
                                    • Rare Earth Minerals
                                    • REE Minerals
                                    • Bastnesite
                                    • Other REE minerals
                                    • Electron Configuration
                                    • Electron Configuartion
                                    • REE Behavior
                                    • Ionic Radius
                                    • Coordination Number
                                    • Coordination Number
                                    • Other Factors
                                    • REEs and Economics
                                    • HREEs and Magnetism
                                    • Applications in Magnetism
                                    • Applications in Magnetism
                                    • HREEs and Nuclear Technology
                                    • HREEs and Nuclear Technology
                                    • Mountain Pass
                                    • Bayan Obo
                                    • World Production
                                    • Exploration
                                    • Environmental Considerations
                                    • REE Fertilizer
                                    • Investigation by T Liang et al
                                    • Implications
                                    • Acid Mine Drainage (AMD)
                                    • Radioactive Elements
                                    • Radioactive Hazards
                                    • Summary
                                    • References

                                      HD -

                                      176 mm HD -

                                      44 mm

                                      XPL MicrographsBastnaumlsite

                                      in Carbonatite

                                      Mountain Pass CA

                                      BSE Image AncyliteHD ndash

                                      07 mm

                                      PPL Micrograph Ancylite

                                      Ancylite

                                      (Ce)

                                      SrREE(CO3

                                      )2

                                      (OH)H2

                                      O

                                      LREE -

                                      dominant ndash

                                      50 wt REO

                                      An exploration target in the

                                      Bear Lodge Carbonatite

                                      Complex of northeastern Wyoming

                                      Red Wine Complex Labrador Dora Bay Alaska

                                      Eudialyte

                                      Na15

                                      Ca6

                                      (Fe2+Mn2+)3

                                      Zr3

                                      (SiNb)(Si25

                                      O73

                                      )(OOHH2

                                      O)3

                                      (CLOH)2

                                      Eudialyite

                                      may also contain Y and HREE

                                      in amounts exceeding 4 wt The

                                      mineral is easily dissolved in weak acids

                                      but colloidal silica currently presents a

                                      problem in the isolation of Y REE and Zr

                                      oxides

                                      Kipawa Quebec

                                      Massive Britholite

                                      (Ce) Oka Quebec

                                      Britholite

                                      (Ce) Concentrate from Skarn

                                      Kipawa Quebec

                                      Britholite

                                      ndash

                                      (REEYCa)5

                                      (SiO4

                                      PO4

                                      )3

                                      (OHF)

                                      This mineral has the potential for occurring in ore quantities in skarn

                                      associated with syenite

                                      gneiss in Kipawa Quebec

                                      Allanite

                                      (Ce) (CeCaY)2

                                      (AlFe2+Fe3+)3

                                      (SiO4

                                      )3

                                      (OH)

                                      Allanite

                                      is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                                      Allanite

                                      ndash

                                      Hydrothermal Mountain Pass CA Allanite

                                      ndash

                                      Pegmatite Timmins Ontario

                                      Eudialyte

                                      and Mosandrite

                                      in Peralkaline

                                      Syenite

                                      Kipawa Quebec

                                      Britholite-Rich Skarn

                                      All brown prisms are britholite

                                      (Horizontal Distance ndash 46 mm)

                                      Britholite

                                      Concentrate

                                      (mm scale)

                                      Britholite

                                      ndash

                                      (CeYCa)5 (SiO4PO4 )3 (OHF)

                                      Kipawa Quebec

                                      Cathodoluminescence

                                      Macrograph of Iimoriite

                                      in Syenite

                                      ndash

                                      Bokan

                                      Mountain

                                      Mottled light blue and tan clusters -

                                      Iimoriite

                                      Red groundmass ndash

                                      Feldspar

                                      (Horizontal distance of rock slab ndash 46 mm)

                                      Iimoriite

                                      (Y)

                                      Y2 (SiO4 )(CO3 )

                                      Yttrofluorite

                                      (CaY)F2

                                      Iimoriite

                                      Concentrate ndash

                                      Bokan

                                      MT (1 mm scale)

                                      Wicheeda

                                      Lake Heavy Mineral Composite mdash

                                      (from samples 828951 52 53)

                                      These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                      and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                      As a final statement it should be emphasizedhellip

                                      1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                      2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                      3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                      4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                      5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                      Rare Earth Elements

                                      bull

                                      Name something of a misnomerndash

                                      Rarest REEs

                                      are over 200 times more

                                      abundant then gold

                                      bull

                                      Variation in distribution for two reasons ndash

                                      Compatibility with common rock forming materials

                                      ndash

                                      CosmicCrustal abundances

                                      Crustal Abundances of Elements

                                      Occurrencebull

                                      REEs

                                      occur mostly as

                                      substitutional

                                      impurities in many rock forming minerals

                                      bull

                                      Only a few the REE minerals have sufficient quantities to be considered important sources

                                      bull

                                      Defined as minerals having at least one site that is filled by REEs

                                      andor Yttrium more often then any other elementMonazite

                                      Rare Earth Minerals

                                      bull

                                      Form by primary crystalization

                                      from magma or by hydrothermal reactions

                                      bull

                                      Found hosted in carbonate rocks in pegmatites

                                      and as accessory minerals in

                                      igneous rocks

                                      bull

                                      Stable REE minerals and can be concentrated in weathering zones

                                      REE Mineralsbull

                                      The most important REE minerals is bastnaumlsite

                                      REE(CO3)F

                                      bull

                                      Other notable sources are ndash

                                      Monazite REE(PO4) ndash

                                      Xenotime

                                      YPO4

                                      bull

                                      All may contain radioactive species such as thorium

                                      and uraniumndash

                                      are avoided as source materials

                                      Bastnesitebull

                                      Bastnasite

                                      [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                      bull

                                      Containing 60 to 70 rare earth oxides (REOs)

                                      bull

                                      REE site is most commonly filled by LREEs

                                      and Y

                                      Other REE mineralsbull

                                      Monazite [(LREEYTh)PO4] ndash

                                      Contains about 50ndash78 rare earth oxides

                                      ndash

                                      Forms in heavy mineral sands placer deposits associated with beach environments

                                      bull

                                      Xenotime

                                      [(YPO4)] ndash

                                      Contains 54ndash65 rare earth oxides

                                      ndash

                                      Yttrium Erbium and Cerium most common ndash

                                      Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                      Electron Configuration

                                      bull

                                      The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                      bull

                                      REEs

                                      have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                      Electron Configuartion

                                      REE Behaviorbull

                                      Because of their shared behaviour REEs

                                      tend to be

                                      present in nature as a group All REEs

                                      commonly substitute for one another in minerals

                                      bull

                                      Yet the REEs

                                      are capable of showing great variation in their distributions

                                      bull

                                      Comes about due to ndash

                                      Differences in ionic radius ndash

                                      Crystal structure (Coordination Number)ndash

                                      Basicity

                                      of the mineral ndash

                                      The elementrsquos solubility and ability to migrate in the environment ndash

                                      Content of REEs

                                      in source fluids

                                      Ionic Radiusbull

                                      The ionic radius of the REEs

                                      is inversely related to atomic number

                                      bull

                                      The heavy rare earths are smaller ndash

                                      more similar to Mn2+ (ionic radius 008 nanometers)

                                      bull

                                      LREEs

                                      are largerndash

                                      more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                      bull

                                      Charge balance achieved through some sites being left vacant or

                                      by coupled substitution with lower charged mineral (Na+)

                                      In nanometers

                                      Coordination Number

                                      bull

                                      Coordination number the number of atoms touching a particular atom in a crystal lattice

                                      bull

                                      Coordination number for this structure is 8

                                      Coordination Numberbull

                                      The heavy and light REEs

                                      differ in the coordination

                                      numbers (CN) with oxygenndash

                                      HREEs

                                      have CN between six to nine ndash

                                      LREEs

                                      have higher CNs

                                      bull

                                      Minerals with high CNs

                                      associated with REE site

                                      will favor LREEsndash

                                      Bastnasite

                                      CN = 11 ndash

                                      Monazite CN = 9

                                      bull

                                      Those with low CNs

                                      will preferentially select HREEs ndash

                                      Xenotime

                                      has a value of 8

                                      Other Factorsbull

                                      Minerals basicityndash

                                      Alkalic

                                      rocks host minerals with elevated LREE content ndash

                                      Rocks with lower basicity

                                      have lower amounts of LREEs

                                      relative to their HREE content

                                      bull

                                      Solubilityndash

                                      LREEs

                                      are more soluble in water then the HREEsndash

                                      Important characteristic for hydrothermally derived minerals

                                      bull

                                      MagmaHydrothermal fluid compositionndash

                                      Minerals will take what they can get

                                      REEs

                                      and Economicsbull

                                      The REEs

                                      and Yttrium have a very broad range of applications mostly in high technology fields

                                      bull

                                      84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                      bull

                                      REEs

                                      used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                      HREEs

                                      and Magnetism

                                      bull

                                      HREEs

                                      exhibit complex magnetic behaviour on account of electron structurendash

                                      They share the same outer shell electron configuration (valence = +3)

                                      ndash

                                      Differ in number of 4f electrons

                                      Applications in Magnetismbull

                                      Terbium and

                                      Dysprosium

                                      bull

                                      Components of Terfenol-D

                                      alloy

                                      with the formula Tb(03) Dy(07) Fe(19)

                                      bull

                                      Has the higher magnetostriction

                                      then any other alloyndash

                                      expands and contracts in magnetic field

                                      bull

                                      Developed by American Navy for sonar

                                      systems ndash

                                      Now has applications in magnetomechanical

                                      sensors and other electronic devices

                                      Applications in Magnetism

                                      bull

                                      Holmium

                                      bull

                                      Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                      elements

                                      bull

                                      Creates the strongest artificially generated magnetic fieldsndash

                                      In research where strong magnetic fields are needed

                                      HREEs

                                      and Nuclear Technology

                                      bull

                                      Dysprosium Homium Erbium

                                      bull

                                      High neutron

                                      absorption cross-section ndash

                                      Measure of probability of neutron capture

                                      bull

                                      Used in neutron-absorbing control rods in nuclear reactors

                                      HREEs

                                      and Nuclear Technology

                                      bull

                                      Lutetiumbull

                                      Radioactive isotope used in radiometric dating

                                      bull

                                      Thulium bull

                                      Stable thulium used as a radiation

                                      source

                                      in portable X-ray

                                      devices

                                      Mountain Passbull

                                      Bastnasite

                                      is the major REE mineral bull

                                      High grade accessory mineral of igneous or hydrothermal originsbull

                                      31 million tons of 886 by weight of rare earth oxides (REO) bull

                                      Mining stopped in 1994 ndash

                                      Thorium content of waste rock ndash

                                      Availability of inexpensive REEs

                                      from China

                                      San Bernardino County

                                      Bayan

                                      Obobull

                                      The worldrsquos primary source for both yttrium and the rare earth elements

                                      bull

                                      37 million tons of ore bull

                                      Main REE source there is Bastnasite

                                      World Production

                                      Explorationbull

                                      84 of REE imports to US are from China

                                      bull

                                      Increasing demand for high tech applications spurred increase in exploration in 2007

                                      bull

                                      Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                      Lake as well as in

                                      Malawi Africa

                                      Environmental Considerations

                                      bull

                                      REE soil and food contaminationbull

                                      Acid Mine Drainage and groundwater systems

                                      bull

                                      Radioactive elements

                                      REE Fertilizerbull

                                      In China REE enriched fertilizer has been used in crop fields since 1990

                                      bull

                                      At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                      every year

                                      bull

                                      Research and agricultural practice that provides evidence that REEs

                                      will improve crop quality an yield

                                      bull

                                      The ramifications environmental and human exposure to REEs

                                      are not well understood

                                      Investigation by T Liang et albull

                                      Revealed that the average concentration of total REEs

                                      in Chinese soil is

                                      1768 mgkg ranging between 850 to 5227 mgkg

                                      bull

                                      In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                      Implicationsbull

                                      Human health effects not completely understood

                                      bull

                                      REE soil content shown to be detrimental to some plant speciesndash

                                      100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                      Acid Mine Drainage (AMD)bull

                                      Rain waters contacts waste rock facilitating acid forming reactions

                                      bull

                                      Increases the capacity of the water to leach potentially harmful elements from waste piles

                                      bull

                                      Process mobilizes established ecotoxins

                                      (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                      bull

                                      Historically dismissed as minor environmental risk

                                      Radioactive Elements

                                      bull

                                      REEs

                                      associated with uranium and thorium

                                      bull

                                      Bastnesite 32 thorium

                                      bull

                                      Monazite sands 6 to 12 thorium oxide

                                      bull

                                      Ores containing radioactive elements are avoided as sources of REEs

                                      Radioactive Hazardsbull

                                      Mountain Pass

                                      bull

                                      Accidentsndash

                                      In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                      bull

                                      Health Effectsndash

                                      inflammatory bowel disease ndash

                                      Prolonged seizures ndash

                                      Cysts ndash

                                      Cancers

                                      bull

                                      Waste Disposal ndash

                                      Yucca Mountain

                                      Summarybull

                                      REE concentrations in the crust are rare

                                      bull

                                      Several geochemical factors influencing distribution including ionic radius and coordination number

                                      bull

                                      Main REE minerals are bastnasite monazite and xenotime

                                      bull

                                      Most important deposits are found at Bayan

                                      Obo China and Mountain Pass USA

                                      bull

                                      Important electronic and nuclear applications

                                      bull

                                      Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                      system contamination though acid mine drainage association with

                                      radioactive elements

                                      Referencesbull

                                      E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                      bull

                                      Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                      bull

                                      G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                      bull

                                      B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                      The Government of South Australia wwwpirsagovaubull

                                      The US geological Survey Mineralsusgsgovbull

                                      wwwelementsdatabasecombull

                                      wwwastrolsaumichedu~cowleyintro2htmlbull

                                      wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                      webmineralcomdataMonazite-(Ce)shtmlbull

                                      wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                      wwwstevegbcomimagesscienceorbital_fillingpngbull

                                      wwwchemicalelementscomelementseuhtmlbull

                                      boomeriaorgchemlecturestextass2table10-9jpgbull

                                      lostcontentquakecomfiles200802holmiumpngbull

                                      chinageocitylocatorcomcitiesChinaQinghaibull

                                      geowebrudruzal-Bayan-Obohtmbull

                                      enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                      wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                      enwikipediaorgwikiMonazitebull

                                      webmineralcomdataBastnasite-(La)shtmlbull

                                      wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                      httpwwwavalonventurescombull

                                      wwwnewsweekcomid43884bull

                                      httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                      httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                      • Slide Number 1
                                      • Slide Number 2
                                      • Slide Number 3
                                      • Slide Number 4
                                      • Slide Number 5
                                      • Slide Number 6
                                      • Slide Number 7
                                      • Slide Number 8
                                      • Slide Number 9
                                      • Slide Number 10
                                      • Slide Number 11
                                      • Slide Number 12
                                      • Slide Number 13
                                      • Slide Number 14
                                      • Slide Number 15
                                      • Slide Number 16
                                      • Slide Number 17
                                      • Slide Number 18
                                      • Slide Number 19
                                      • Slide Number 20
                                      • Slide Number 21
                                      • Slide Number 22
                                      • Slide Number 23
                                      • Slide Number 24
                                      • Slide Number 25
                                      • Slide Number 26
                                      • Slide Number 27
                                      • Slide Number 28
                                      • Slide Number 29
                                      • Slide Number 30
                                      • Slide Number 31
                                      • Slide Number 32
                                      • Slide Number 33
                                      • Slide Number 34
                                      • Slide Number 35
                                      • Slide Number 36
                                      • Slide Number 37
                                      • Slide Number 38
                                      • Slide Number 39
                                      • Slide Number 40
                                      • Slide Number 41
                                      • Slide Number 42
                                      • Slide Number 43
                                      • Slide Number 44
                                      • Slide Number 45
                                      • Slide Number 46
                                      • Slide Number 47
                                      • Slide Number 48
                                      • Slide Number 49
                                      • Slide Number 50
                                      • Slide Number 51
                                      • Rare Earth Elements
                                      • Crustal Abundances of Elements
                                      • Occurrence
                                      • Rare Earth Minerals
                                      • REE Minerals
                                      • Bastnesite
                                      • Other REE minerals
                                      • Electron Configuration
                                      • Electron Configuartion
                                      • REE Behavior
                                      • Ionic Radius
                                      • Coordination Number
                                      • Coordination Number
                                      • Other Factors
                                      • REEs and Economics
                                      • HREEs and Magnetism
                                      • Applications in Magnetism
                                      • Applications in Magnetism
                                      • HREEs and Nuclear Technology
                                      • HREEs and Nuclear Technology
                                      • Mountain Pass
                                      • Bayan Obo
                                      • World Production
                                      • Exploration
                                      • Environmental Considerations
                                      • REE Fertilizer
                                      • Investigation by T Liang et al
                                      • Implications
                                      • Acid Mine Drainage (AMD)
                                      • Radioactive Elements
                                      • Radioactive Hazards
                                      • Summary
                                      • References

                                        BSE Image AncyliteHD ndash

                                        07 mm

                                        PPL Micrograph Ancylite

                                        Ancylite

                                        (Ce)

                                        SrREE(CO3

                                        )2

                                        (OH)H2

                                        O

                                        LREE -

                                        dominant ndash

                                        50 wt REO

                                        An exploration target in the

                                        Bear Lodge Carbonatite

                                        Complex of northeastern Wyoming

                                        Red Wine Complex Labrador Dora Bay Alaska

                                        Eudialyte

                                        Na15

                                        Ca6

                                        (Fe2+Mn2+)3

                                        Zr3

                                        (SiNb)(Si25

                                        O73

                                        )(OOHH2

                                        O)3

                                        (CLOH)2

                                        Eudialyite

                                        may also contain Y and HREE

                                        in amounts exceeding 4 wt The

                                        mineral is easily dissolved in weak acids

                                        but colloidal silica currently presents a

                                        problem in the isolation of Y REE and Zr

                                        oxides

                                        Kipawa Quebec

                                        Massive Britholite

                                        (Ce) Oka Quebec

                                        Britholite

                                        (Ce) Concentrate from Skarn

                                        Kipawa Quebec

                                        Britholite

                                        ndash

                                        (REEYCa)5

                                        (SiO4

                                        PO4

                                        )3

                                        (OHF)

                                        This mineral has the potential for occurring in ore quantities in skarn

                                        associated with syenite

                                        gneiss in Kipawa Quebec

                                        Allanite

                                        (Ce) (CeCaY)2

                                        (AlFe2+Fe3+)3

                                        (SiO4

                                        )3

                                        (OH)

                                        Allanite

                                        is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                                        Allanite

                                        ndash

                                        Hydrothermal Mountain Pass CA Allanite

                                        ndash

                                        Pegmatite Timmins Ontario

                                        Eudialyte

                                        and Mosandrite

                                        in Peralkaline

                                        Syenite

                                        Kipawa Quebec

                                        Britholite-Rich Skarn

                                        All brown prisms are britholite

                                        (Horizontal Distance ndash 46 mm)

                                        Britholite

                                        Concentrate

                                        (mm scale)

                                        Britholite

                                        ndash

                                        (CeYCa)5 (SiO4PO4 )3 (OHF)

                                        Kipawa Quebec

                                        Cathodoluminescence

                                        Macrograph of Iimoriite

                                        in Syenite

                                        ndash

                                        Bokan

                                        Mountain

                                        Mottled light blue and tan clusters -

                                        Iimoriite

                                        Red groundmass ndash

                                        Feldspar

                                        (Horizontal distance of rock slab ndash 46 mm)

                                        Iimoriite

                                        (Y)

                                        Y2 (SiO4 )(CO3 )

                                        Yttrofluorite

                                        (CaY)F2

                                        Iimoriite

                                        Concentrate ndash

                                        Bokan

                                        MT (1 mm scale)

                                        Wicheeda

                                        Lake Heavy Mineral Composite mdash

                                        (from samples 828951 52 53)

                                        These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                        and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                        As a final statement it should be emphasizedhellip

                                        1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                        2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                        3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                        4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                        5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                        Rare Earth Elements

                                        bull

                                        Name something of a misnomerndash

                                        Rarest REEs

                                        are over 200 times more

                                        abundant then gold

                                        bull

                                        Variation in distribution for two reasons ndash

                                        Compatibility with common rock forming materials

                                        ndash

                                        CosmicCrustal abundances

                                        Crustal Abundances of Elements

                                        Occurrencebull

                                        REEs

                                        occur mostly as

                                        substitutional

                                        impurities in many rock forming minerals

                                        bull

                                        Only a few the REE minerals have sufficient quantities to be considered important sources

                                        bull

                                        Defined as minerals having at least one site that is filled by REEs

                                        andor Yttrium more often then any other elementMonazite

                                        Rare Earth Minerals

                                        bull

                                        Form by primary crystalization

                                        from magma or by hydrothermal reactions

                                        bull

                                        Found hosted in carbonate rocks in pegmatites

                                        and as accessory minerals in

                                        igneous rocks

                                        bull

                                        Stable REE minerals and can be concentrated in weathering zones

                                        REE Mineralsbull

                                        The most important REE minerals is bastnaumlsite

                                        REE(CO3)F

                                        bull

                                        Other notable sources are ndash

                                        Monazite REE(PO4) ndash

                                        Xenotime

                                        YPO4

                                        bull

                                        All may contain radioactive species such as thorium

                                        and uraniumndash

                                        are avoided as source materials

                                        Bastnesitebull

                                        Bastnasite

                                        [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                        bull

                                        Containing 60 to 70 rare earth oxides (REOs)

                                        bull

                                        REE site is most commonly filled by LREEs

                                        and Y

                                        Other REE mineralsbull

                                        Monazite [(LREEYTh)PO4] ndash

                                        Contains about 50ndash78 rare earth oxides

                                        ndash

                                        Forms in heavy mineral sands placer deposits associated with beach environments

                                        bull

                                        Xenotime

                                        [(YPO4)] ndash

                                        Contains 54ndash65 rare earth oxides

                                        ndash

                                        Yttrium Erbium and Cerium most common ndash

                                        Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                        Electron Configuration

                                        bull

                                        The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                        bull

                                        REEs

                                        have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                        Electron Configuartion

                                        REE Behaviorbull

                                        Because of their shared behaviour REEs

                                        tend to be

                                        present in nature as a group All REEs

                                        commonly substitute for one another in minerals

                                        bull

                                        Yet the REEs

                                        are capable of showing great variation in their distributions

                                        bull

                                        Comes about due to ndash

                                        Differences in ionic radius ndash

                                        Crystal structure (Coordination Number)ndash

                                        Basicity

                                        of the mineral ndash

                                        The elementrsquos solubility and ability to migrate in the environment ndash

                                        Content of REEs

                                        in source fluids

                                        Ionic Radiusbull

                                        The ionic radius of the REEs

                                        is inversely related to atomic number

                                        bull

                                        The heavy rare earths are smaller ndash

                                        more similar to Mn2+ (ionic radius 008 nanometers)

                                        bull

                                        LREEs

                                        are largerndash

                                        more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                        bull

                                        Charge balance achieved through some sites being left vacant or

                                        by coupled substitution with lower charged mineral (Na+)

                                        In nanometers

                                        Coordination Number

                                        bull

                                        Coordination number the number of atoms touching a particular atom in a crystal lattice

                                        bull

                                        Coordination number for this structure is 8

                                        Coordination Numberbull

                                        The heavy and light REEs

                                        differ in the coordination

                                        numbers (CN) with oxygenndash

                                        HREEs

                                        have CN between six to nine ndash

                                        LREEs

                                        have higher CNs

                                        bull

                                        Minerals with high CNs

                                        associated with REE site

                                        will favor LREEsndash

                                        Bastnasite

                                        CN = 11 ndash

                                        Monazite CN = 9

                                        bull

                                        Those with low CNs

                                        will preferentially select HREEs ndash

                                        Xenotime

                                        has a value of 8

                                        Other Factorsbull

                                        Minerals basicityndash

                                        Alkalic

                                        rocks host minerals with elevated LREE content ndash

                                        Rocks with lower basicity

                                        have lower amounts of LREEs

                                        relative to their HREE content

                                        bull

                                        Solubilityndash

                                        LREEs

                                        are more soluble in water then the HREEsndash

                                        Important characteristic for hydrothermally derived minerals

                                        bull

                                        MagmaHydrothermal fluid compositionndash

                                        Minerals will take what they can get

                                        REEs

                                        and Economicsbull

                                        The REEs

                                        and Yttrium have a very broad range of applications mostly in high technology fields

                                        bull

                                        84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                        bull

                                        REEs

                                        used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                        HREEs

                                        and Magnetism

                                        bull

                                        HREEs

                                        exhibit complex magnetic behaviour on account of electron structurendash

                                        They share the same outer shell electron configuration (valence = +3)

                                        ndash

                                        Differ in number of 4f electrons

                                        Applications in Magnetismbull

                                        Terbium and

                                        Dysprosium

                                        bull

                                        Components of Terfenol-D

                                        alloy

                                        with the formula Tb(03) Dy(07) Fe(19)

                                        bull

                                        Has the higher magnetostriction

                                        then any other alloyndash

                                        expands and contracts in magnetic field

                                        bull

                                        Developed by American Navy for sonar

                                        systems ndash

                                        Now has applications in magnetomechanical

                                        sensors and other electronic devices

                                        Applications in Magnetism

                                        bull

                                        Holmium

                                        bull

                                        Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                        elements

                                        bull

                                        Creates the strongest artificially generated magnetic fieldsndash

                                        In research where strong magnetic fields are needed

                                        HREEs

                                        and Nuclear Technology

                                        bull

                                        Dysprosium Homium Erbium

                                        bull

                                        High neutron

                                        absorption cross-section ndash

                                        Measure of probability of neutron capture

                                        bull

                                        Used in neutron-absorbing control rods in nuclear reactors

                                        HREEs

                                        and Nuclear Technology

                                        bull

                                        Lutetiumbull

                                        Radioactive isotope used in radiometric dating

                                        bull

                                        Thulium bull

                                        Stable thulium used as a radiation

                                        source

                                        in portable X-ray

                                        devices

                                        Mountain Passbull

                                        Bastnasite

                                        is the major REE mineral bull

                                        High grade accessory mineral of igneous or hydrothermal originsbull

                                        31 million tons of 886 by weight of rare earth oxides (REO) bull

                                        Mining stopped in 1994 ndash

                                        Thorium content of waste rock ndash

                                        Availability of inexpensive REEs

                                        from China

                                        San Bernardino County

                                        Bayan

                                        Obobull

                                        The worldrsquos primary source for both yttrium and the rare earth elements

                                        bull

                                        37 million tons of ore bull

                                        Main REE source there is Bastnasite

                                        World Production

                                        Explorationbull

                                        84 of REE imports to US are from China

                                        bull

                                        Increasing demand for high tech applications spurred increase in exploration in 2007

                                        bull

                                        Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                        Lake as well as in

                                        Malawi Africa

                                        Environmental Considerations

                                        bull

                                        REE soil and food contaminationbull

                                        Acid Mine Drainage and groundwater systems

                                        bull

                                        Radioactive elements

                                        REE Fertilizerbull

                                        In China REE enriched fertilizer has been used in crop fields since 1990

                                        bull

                                        At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                        every year

                                        bull

                                        Research and agricultural practice that provides evidence that REEs

                                        will improve crop quality an yield

                                        bull

                                        The ramifications environmental and human exposure to REEs

                                        are not well understood

                                        Investigation by T Liang et albull

                                        Revealed that the average concentration of total REEs

                                        in Chinese soil is

                                        1768 mgkg ranging between 850 to 5227 mgkg

                                        bull

                                        In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                        Implicationsbull

                                        Human health effects not completely understood

                                        bull

                                        REE soil content shown to be detrimental to some plant speciesndash

                                        100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                        Acid Mine Drainage (AMD)bull

                                        Rain waters contacts waste rock facilitating acid forming reactions

                                        bull

                                        Increases the capacity of the water to leach potentially harmful elements from waste piles

                                        bull

                                        Process mobilizes established ecotoxins

                                        (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                        bull

                                        Historically dismissed as minor environmental risk

                                        Radioactive Elements

                                        bull

                                        REEs

                                        associated with uranium and thorium

                                        bull

                                        Bastnesite 32 thorium

                                        bull

                                        Monazite sands 6 to 12 thorium oxide

                                        bull

                                        Ores containing radioactive elements are avoided as sources of REEs

                                        Radioactive Hazardsbull

                                        Mountain Pass

                                        bull

                                        Accidentsndash

                                        In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                        bull

                                        Health Effectsndash

                                        inflammatory bowel disease ndash

                                        Prolonged seizures ndash

                                        Cysts ndash

                                        Cancers

                                        bull

                                        Waste Disposal ndash

                                        Yucca Mountain

                                        Summarybull

                                        REE concentrations in the crust are rare

                                        bull

                                        Several geochemical factors influencing distribution including ionic radius and coordination number

                                        bull

                                        Main REE minerals are bastnasite monazite and xenotime

                                        bull

                                        Most important deposits are found at Bayan

                                        Obo China and Mountain Pass USA

                                        bull

                                        Important electronic and nuclear applications

                                        bull

                                        Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                        system contamination though acid mine drainage association with

                                        radioactive elements

                                        Referencesbull

                                        E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                        bull

                                        Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                        bull

                                        G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                        bull

                                        B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                        The Government of South Australia wwwpirsagovaubull

                                        The US geological Survey Mineralsusgsgovbull

                                        wwwelementsdatabasecombull

                                        wwwastrolsaumichedu~cowleyintro2htmlbull

                                        wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                        webmineralcomdataMonazite-(Ce)shtmlbull

                                        wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                        wwwstevegbcomimagesscienceorbital_fillingpngbull

                                        wwwchemicalelementscomelementseuhtmlbull

                                        boomeriaorgchemlecturestextass2table10-9jpgbull

                                        lostcontentquakecomfiles200802holmiumpngbull

                                        chinageocitylocatorcomcitiesChinaQinghaibull

                                        geowebrudruzal-Bayan-Obohtmbull

                                        enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                        wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                        enwikipediaorgwikiMonazitebull

                                        webmineralcomdataBastnasite-(La)shtmlbull

                                        wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                        httpwwwavalonventurescombull

                                        wwwnewsweekcomid43884bull

                                        httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                        httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                        • Slide Number 1
                                        • Slide Number 2
                                        • Slide Number 3
                                        • Slide Number 4
                                        • Slide Number 5
                                        • Slide Number 6
                                        • Slide Number 7
                                        • Slide Number 8
                                        • Slide Number 9
                                        • Slide Number 10
                                        • Slide Number 11
                                        • Slide Number 12
                                        • Slide Number 13
                                        • Slide Number 14
                                        • Slide Number 15
                                        • Slide Number 16
                                        • Slide Number 17
                                        • Slide Number 18
                                        • Slide Number 19
                                        • Slide Number 20
                                        • Slide Number 21
                                        • Slide Number 22
                                        • Slide Number 23
                                        • Slide Number 24
                                        • Slide Number 25
                                        • Slide Number 26
                                        • Slide Number 27
                                        • Slide Number 28
                                        • Slide Number 29
                                        • Slide Number 30
                                        • Slide Number 31
                                        • Slide Number 32
                                        • Slide Number 33
                                        • Slide Number 34
                                        • Slide Number 35
                                        • Slide Number 36
                                        • Slide Number 37
                                        • Slide Number 38
                                        • Slide Number 39
                                        • Slide Number 40
                                        • Slide Number 41
                                        • Slide Number 42
                                        • Slide Number 43
                                        • Slide Number 44
                                        • Slide Number 45
                                        • Slide Number 46
                                        • Slide Number 47
                                        • Slide Number 48
                                        • Slide Number 49
                                        • Slide Number 50
                                        • Slide Number 51
                                        • Rare Earth Elements
                                        • Crustal Abundances of Elements
                                        • Occurrence
                                        • Rare Earth Minerals
                                        • REE Minerals
                                        • Bastnesite
                                        • Other REE minerals
                                        • Electron Configuration
                                        • Electron Configuartion
                                        • REE Behavior
                                        • Ionic Radius
                                        • Coordination Number
                                        • Coordination Number
                                        • Other Factors
                                        • REEs and Economics
                                        • HREEs and Magnetism
                                        • Applications in Magnetism
                                        • Applications in Magnetism
                                        • HREEs and Nuclear Technology
                                        • HREEs and Nuclear Technology
                                        • Mountain Pass
                                        • Bayan Obo
                                        • World Production
                                        • Exploration
                                        • Environmental Considerations
                                        • REE Fertilizer
                                        • Investigation by T Liang et al
                                        • Implications
                                        • Acid Mine Drainage (AMD)
                                        • Radioactive Elements
                                        • Radioactive Hazards
                                        • Summary
                                        • References

                                          Red Wine Complex Labrador Dora Bay Alaska

                                          Eudialyte

                                          Na15

                                          Ca6

                                          (Fe2+Mn2+)3

                                          Zr3

                                          (SiNb)(Si25

                                          O73

                                          )(OOHH2

                                          O)3

                                          (CLOH)2

                                          Eudialyite

                                          may also contain Y and HREE

                                          in amounts exceeding 4 wt The

                                          mineral is easily dissolved in weak acids

                                          but colloidal silica currently presents a

                                          problem in the isolation of Y REE and Zr

                                          oxides

                                          Kipawa Quebec

                                          Massive Britholite

                                          (Ce) Oka Quebec

                                          Britholite

                                          (Ce) Concentrate from Skarn

                                          Kipawa Quebec

                                          Britholite

                                          ndash

                                          (REEYCa)5

                                          (SiO4

                                          PO4

                                          )3

                                          (OHF)

                                          This mineral has the potential for occurring in ore quantities in skarn

                                          associated with syenite

                                          gneiss in Kipawa Quebec

                                          Allanite

                                          (Ce) (CeCaY)2

                                          (AlFe2+Fe3+)3

                                          (SiO4

                                          )3

                                          (OH)

                                          Allanite

                                          is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                                          Allanite

                                          ndash

                                          Hydrothermal Mountain Pass CA Allanite

                                          ndash

                                          Pegmatite Timmins Ontario

                                          Eudialyte

                                          and Mosandrite

                                          in Peralkaline

                                          Syenite

                                          Kipawa Quebec

                                          Britholite-Rich Skarn

                                          All brown prisms are britholite

                                          (Horizontal Distance ndash 46 mm)

                                          Britholite

                                          Concentrate

                                          (mm scale)

                                          Britholite

                                          ndash

                                          (CeYCa)5 (SiO4PO4 )3 (OHF)

                                          Kipawa Quebec

                                          Cathodoluminescence

                                          Macrograph of Iimoriite

                                          in Syenite

                                          ndash

                                          Bokan

                                          Mountain

                                          Mottled light blue and tan clusters -

                                          Iimoriite

                                          Red groundmass ndash

                                          Feldspar

                                          (Horizontal distance of rock slab ndash 46 mm)

                                          Iimoriite

                                          (Y)

                                          Y2 (SiO4 )(CO3 )

                                          Yttrofluorite

                                          (CaY)F2

                                          Iimoriite

                                          Concentrate ndash

                                          Bokan

                                          MT (1 mm scale)

                                          Wicheeda

                                          Lake Heavy Mineral Composite mdash

                                          (from samples 828951 52 53)

                                          These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                          and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                          As a final statement it should be emphasizedhellip

                                          1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                          2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                          3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                          4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                          5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                          Rare Earth Elements

                                          bull

                                          Name something of a misnomerndash

                                          Rarest REEs

                                          are over 200 times more

                                          abundant then gold

                                          bull

                                          Variation in distribution for two reasons ndash

                                          Compatibility with common rock forming materials

                                          ndash

                                          CosmicCrustal abundances

                                          Crustal Abundances of Elements

                                          Occurrencebull

                                          REEs

                                          occur mostly as

                                          substitutional

                                          impurities in many rock forming minerals

                                          bull

                                          Only a few the REE minerals have sufficient quantities to be considered important sources

                                          bull

                                          Defined as minerals having at least one site that is filled by REEs

                                          andor Yttrium more often then any other elementMonazite

                                          Rare Earth Minerals

                                          bull

                                          Form by primary crystalization

                                          from magma or by hydrothermal reactions

                                          bull

                                          Found hosted in carbonate rocks in pegmatites

                                          and as accessory minerals in

                                          igneous rocks

                                          bull

                                          Stable REE minerals and can be concentrated in weathering zones

                                          REE Mineralsbull

                                          The most important REE minerals is bastnaumlsite

                                          REE(CO3)F

                                          bull

                                          Other notable sources are ndash

                                          Monazite REE(PO4) ndash

                                          Xenotime

                                          YPO4

                                          bull

                                          All may contain radioactive species such as thorium

                                          and uraniumndash

                                          are avoided as source materials

                                          Bastnesitebull

                                          Bastnasite

                                          [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                          bull

                                          Containing 60 to 70 rare earth oxides (REOs)

                                          bull

                                          REE site is most commonly filled by LREEs

                                          and Y

                                          Other REE mineralsbull

                                          Monazite [(LREEYTh)PO4] ndash

                                          Contains about 50ndash78 rare earth oxides

                                          ndash

                                          Forms in heavy mineral sands placer deposits associated with beach environments

                                          bull

                                          Xenotime

                                          [(YPO4)] ndash

                                          Contains 54ndash65 rare earth oxides

                                          ndash

                                          Yttrium Erbium and Cerium most common ndash

                                          Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                          Electron Configuration

                                          bull

                                          The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                          bull

                                          REEs

                                          have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                          Electron Configuartion

                                          REE Behaviorbull

                                          Because of their shared behaviour REEs

                                          tend to be

                                          present in nature as a group All REEs

                                          commonly substitute for one another in minerals

                                          bull

                                          Yet the REEs

                                          are capable of showing great variation in their distributions

                                          bull

                                          Comes about due to ndash

                                          Differences in ionic radius ndash

                                          Crystal structure (Coordination Number)ndash

                                          Basicity

                                          of the mineral ndash

                                          The elementrsquos solubility and ability to migrate in the environment ndash

                                          Content of REEs

                                          in source fluids

                                          Ionic Radiusbull

                                          The ionic radius of the REEs

                                          is inversely related to atomic number

                                          bull

                                          The heavy rare earths are smaller ndash

                                          more similar to Mn2+ (ionic radius 008 nanometers)

                                          bull

                                          LREEs

                                          are largerndash

                                          more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                          bull

                                          Charge balance achieved through some sites being left vacant or

                                          by coupled substitution with lower charged mineral (Na+)

                                          In nanometers

                                          Coordination Number

                                          bull

                                          Coordination number the number of atoms touching a particular atom in a crystal lattice

                                          bull

                                          Coordination number for this structure is 8

                                          Coordination Numberbull

                                          The heavy and light REEs

                                          differ in the coordination

                                          numbers (CN) with oxygenndash

                                          HREEs

                                          have CN between six to nine ndash

                                          LREEs

                                          have higher CNs

                                          bull

                                          Minerals with high CNs

                                          associated with REE site

                                          will favor LREEsndash

                                          Bastnasite

                                          CN = 11 ndash

                                          Monazite CN = 9

                                          bull

                                          Those with low CNs

                                          will preferentially select HREEs ndash

                                          Xenotime

                                          has a value of 8

                                          Other Factorsbull

                                          Minerals basicityndash

                                          Alkalic

                                          rocks host minerals with elevated LREE content ndash

                                          Rocks with lower basicity

                                          have lower amounts of LREEs

                                          relative to their HREE content

                                          bull

                                          Solubilityndash

                                          LREEs

                                          are more soluble in water then the HREEsndash

                                          Important characteristic for hydrothermally derived minerals

                                          bull

                                          MagmaHydrothermal fluid compositionndash

                                          Minerals will take what they can get

                                          REEs

                                          and Economicsbull

                                          The REEs

                                          and Yttrium have a very broad range of applications mostly in high technology fields

                                          bull

                                          84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                          bull

                                          REEs

                                          used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                          HREEs

                                          and Magnetism

                                          bull

                                          HREEs

                                          exhibit complex magnetic behaviour on account of electron structurendash

                                          They share the same outer shell electron configuration (valence = +3)

                                          ndash

                                          Differ in number of 4f electrons

                                          Applications in Magnetismbull

                                          Terbium and

                                          Dysprosium

                                          bull

                                          Components of Terfenol-D

                                          alloy

                                          with the formula Tb(03) Dy(07) Fe(19)

                                          bull

                                          Has the higher magnetostriction

                                          then any other alloyndash

                                          expands and contracts in magnetic field

                                          bull

                                          Developed by American Navy for sonar

                                          systems ndash

                                          Now has applications in magnetomechanical

                                          sensors and other electronic devices

                                          Applications in Magnetism

                                          bull

                                          Holmium

                                          bull

                                          Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                          elements

                                          bull

                                          Creates the strongest artificially generated magnetic fieldsndash

                                          In research where strong magnetic fields are needed

                                          HREEs

                                          and Nuclear Technology

                                          bull

                                          Dysprosium Homium Erbium

                                          bull

                                          High neutron

                                          absorption cross-section ndash

                                          Measure of probability of neutron capture

                                          bull

                                          Used in neutron-absorbing control rods in nuclear reactors

                                          HREEs

                                          and Nuclear Technology

                                          bull

                                          Lutetiumbull

                                          Radioactive isotope used in radiometric dating

                                          bull

                                          Thulium bull

                                          Stable thulium used as a radiation

                                          source

                                          in portable X-ray

                                          devices

                                          Mountain Passbull

                                          Bastnasite

                                          is the major REE mineral bull

                                          High grade accessory mineral of igneous or hydrothermal originsbull

                                          31 million tons of 886 by weight of rare earth oxides (REO) bull

                                          Mining stopped in 1994 ndash

                                          Thorium content of waste rock ndash

                                          Availability of inexpensive REEs

                                          from China

                                          San Bernardino County

                                          Bayan

                                          Obobull

                                          The worldrsquos primary source for both yttrium and the rare earth elements

                                          bull

                                          37 million tons of ore bull

                                          Main REE source there is Bastnasite

                                          World Production

                                          Explorationbull

                                          84 of REE imports to US are from China

                                          bull

                                          Increasing demand for high tech applications spurred increase in exploration in 2007

                                          bull

                                          Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                          Lake as well as in

                                          Malawi Africa

                                          Environmental Considerations

                                          bull

                                          REE soil and food contaminationbull

                                          Acid Mine Drainage and groundwater systems

                                          bull

                                          Radioactive elements

                                          REE Fertilizerbull

                                          In China REE enriched fertilizer has been used in crop fields since 1990

                                          bull

                                          At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                          every year

                                          bull

                                          Research and agricultural practice that provides evidence that REEs

                                          will improve crop quality an yield

                                          bull

                                          The ramifications environmental and human exposure to REEs

                                          are not well understood

                                          Investigation by T Liang et albull

                                          Revealed that the average concentration of total REEs

                                          in Chinese soil is

                                          1768 mgkg ranging between 850 to 5227 mgkg

                                          bull

                                          In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                          Implicationsbull

                                          Human health effects not completely understood

                                          bull

                                          REE soil content shown to be detrimental to some plant speciesndash

                                          100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                          Acid Mine Drainage (AMD)bull

                                          Rain waters contacts waste rock facilitating acid forming reactions

                                          bull

                                          Increases the capacity of the water to leach potentially harmful elements from waste piles

                                          bull

                                          Process mobilizes established ecotoxins

                                          (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                          bull

                                          Historically dismissed as minor environmental risk

                                          Radioactive Elements

                                          bull

                                          REEs

                                          associated with uranium and thorium

                                          bull

                                          Bastnesite 32 thorium

                                          bull

                                          Monazite sands 6 to 12 thorium oxide

                                          bull

                                          Ores containing radioactive elements are avoided as sources of REEs

                                          Radioactive Hazardsbull

                                          Mountain Pass

                                          bull

                                          Accidentsndash

                                          In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                          bull

                                          Health Effectsndash

                                          inflammatory bowel disease ndash

                                          Prolonged seizures ndash

                                          Cysts ndash

                                          Cancers

                                          bull

                                          Waste Disposal ndash

                                          Yucca Mountain

                                          Summarybull

                                          REE concentrations in the crust are rare

                                          bull

                                          Several geochemical factors influencing distribution including ionic radius and coordination number

                                          bull

                                          Main REE minerals are bastnasite monazite and xenotime

                                          bull

                                          Most important deposits are found at Bayan

                                          Obo China and Mountain Pass USA

                                          bull

                                          Important electronic and nuclear applications

                                          bull

                                          Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                          system contamination though acid mine drainage association with

                                          radioactive elements

                                          Referencesbull

                                          E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                          bull

                                          Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                          bull

                                          G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                          bull

                                          B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                          The Government of South Australia wwwpirsagovaubull

                                          The US geological Survey Mineralsusgsgovbull

                                          wwwelementsdatabasecombull

                                          wwwastrolsaumichedu~cowleyintro2htmlbull

                                          wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                          webmineralcomdataMonazite-(Ce)shtmlbull

                                          wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                          wwwstevegbcomimagesscienceorbital_fillingpngbull

                                          wwwchemicalelementscomelementseuhtmlbull

                                          boomeriaorgchemlecturestextass2table10-9jpgbull

                                          lostcontentquakecomfiles200802holmiumpngbull

                                          chinageocitylocatorcomcitiesChinaQinghaibull

                                          geowebrudruzal-Bayan-Obohtmbull

                                          enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                          wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                          enwikipediaorgwikiMonazitebull

                                          webmineralcomdataBastnasite-(La)shtmlbull

                                          wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                          httpwwwavalonventurescombull

                                          wwwnewsweekcomid43884bull

                                          httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                          httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                          • Slide Number 1
                                          • Slide Number 2
                                          • Slide Number 3
                                          • Slide Number 4
                                          • Slide Number 5
                                          • Slide Number 6
                                          • Slide Number 7
                                          • Slide Number 8
                                          • Slide Number 9
                                          • Slide Number 10
                                          • Slide Number 11
                                          • Slide Number 12
                                          • Slide Number 13
                                          • Slide Number 14
                                          • Slide Number 15
                                          • Slide Number 16
                                          • Slide Number 17
                                          • Slide Number 18
                                          • Slide Number 19
                                          • Slide Number 20
                                          • Slide Number 21
                                          • Slide Number 22
                                          • Slide Number 23
                                          • Slide Number 24
                                          • Slide Number 25
                                          • Slide Number 26
                                          • Slide Number 27
                                          • Slide Number 28
                                          • Slide Number 29
                                          • Slide Number 30
                                          • Slide Number 31
                                          • Slide Number 32
                                          • Slide Number 33
                                          • Slide Number 34
                                          • Slide Number 35
                                          • Slide Number 36
                                          • Slide Number 37
                                          • Slide Number 38
                                          • Slide Number 39
                                          • Slide Number 40
                                          • Slide Number 41
                                          • Slide Number 42
                                          • Slide Number 43
                                          • Slide Number 44
                                          • Slide Number 45
                                          • Slide Number 46
                                          • Slide Number 47
                                          • Slide Number 48
                                          • Slide Number 49
                                          • Slide Number 50
                                          • Slide Number 51
                                          • Rare Earth Elements
                                          • Crustal Abundances of Elements
                                          • Occurrence
                                          • Rare Earth Minerals
                                          • REE Minerals
                                          • Bastnesite
                                          • Other REE minerals
                                          • Electron Configuration
                                          • Electron Configuartion
                                          • REE Behavior
                                          • Ionic Radius
                                          • Coordination Number
                                          • Coordination Number
                                          • Other Factors
                                          • REEs and Economics
                                          • HREEs and Magnetism
                                          • Applications in Magnetism
                                          • Applications in Magnetism
                                          • HREEs and Nuclear Technology
                                          • HREEs and Nuclear Technology
                                          • Mountain Pass
                                          • Bayan Obo
                                          • World Production
                                          • Exploration
                                          • Environmental Considerations
                                          • REE Fertilizer
                                          • Investigation by T Liang et al
                                          • Implications
                                          • Acid Mine Drainage (AMD)
                                          • Radioactive Elements
                                          • Radioactive Hazards
                                          • Summary
                                          • References

                                            Massive Britholite

                                            (Ce) Oka Quebec

                                            Britholite

                                            (Ce) Concentrate from Skarn

                                            Kipawa Quebec

                                            Britholite

                                            ndash

                                            (REEYCa)5

                                            (SiO4

                                            PO4

                                            )3

                                            (OHF)

                                            This mineral has the potential for occurring in ore quantities in skarn

                                            associated with syenite

                                            gneiss in Kipawa Quebec

                                            Allanite

                                            (Ce) (CeCaY)2

                                            (AlFe2+Fe3+)3

                                            (SiO4

                                            )3

                                            (OH)

                                            Allanite

                                            is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                                            Allanite

                                            ndash

                                            Hydrothermal Mountain Pass CA Allanite

                                            ndash

                                            Pegmatite Timmins Ontario

                                            Eudialyte

                                            and Mosandrite

                                            in Peralkaline

                                            Syenite

                                            Kipawa Quebec

                                            Britholite-Rich Skarn

                                            All brown prisms are britholite

                                            (Horizontal Distance ndash 46 mm)

                                            Britholite

                                            Concentrate

                                            (mm scale)

                                            Britholite

                                            ndash

                                            (CeYCa)5 (SiO4PO4 )3 (OHF)

                                            Kipawa Quebec

                                            Cathodoluminescence

                                            Macrograph of Iimoriite

                                            in Syenite

                                            ndash

                                            Bokan

                                            Mountain

                                            Mottled light blue and tan clusters -

                                            Iimoriite

                                            Red groundmass ndash

                                            Feldspar

                                            (Horizontal distance of rock slab ndash 46 mm)

                                            Iimoriite

                                            (Y)

                                            Y2 (SiO4 )(CO3 )

                                            Yttrofluorite

                                            (CaY)F2

                                            Iimoriite

                                            Concentrate ndash

                                            Bokan

                                            MT (1 mm scale)

                                            Wicheeda

                                            Lake Heavy Mineral Composite mdash

                                            (from samples 828951 52 53)

                                            These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                            and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                            As a final statement it should be emphasizedhellip

                                            1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                            2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                            3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                            4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                            5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                            Rare Earth Elements

                                            bull

                                            Name something of a misnomerndash

                                            Rarest REEs

                                            are over 200 times more

                                            abundant then gold

                                            bull

                                            Variation in distribution for two reasons ndash

                                            Compatibility with common rock forming materials

                                            ndash

                                            CosmicCrustal abundances

                                            Crustal Abundances of Elements

                                            Occurrencebull

                                            REEs

                                            occur mostly as

                                            substitutional

                                            impurities in many rock forming minerals

                                            bull

                                            Only a few the REE minerals have sufficient quantities to be considered important sources

                                            bull

                                            Defined as minerals having at least one site that is filled by REEs

                                            andor Yttrium more often then any other elementMonazite

                                            Rare Earth Minerals

                                            bull

                                            Form by primary crystalization

                                            from magma or by hydrothermal reactions

                                            bull

                                            Found hosted in carbonate rocks in pegmatites

                                            and as accessory minerals in

                                            igneous rocks

                                            bull

                                            Stable REE minerals and can be concentrated in weathering zones

                                            REE Mineralsbull

                                            The most important REE minerals is bastnaumlsite

                                            REE(CO3)F

                                            bull

                                            Other notable sources are ndash

                                            Monazite REE(PO4) ndash

                                            Xenotime

                                            YPO4

                                            bull

                                            All may contain radioactive species such as thorium

                                            and uraniumndash

                                            are avoided as source materials

                                            Bastnesitebull

                                            Bastnasite

                                            [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                            bull

                                            Containing 60 to 70 rare earth oxides (REOs)

                                            bull

                                            REE site is most commonly filled by LREEs

                                            and Y

                                            Other REE mineralsbull

                                            Monazite [(LREEYTh)PO4] ndash

                                            Contains about 50ndash78 rare earth oxides

                                            ndash

                                            Forms in heavy mineral sands placer deposits associated with beach environments

                                            bull

                                            Xenotime

                                            [(YPO4)] ndash

                                            Contains 54ndash65 rare earth oxides

                                            ndash

                                            Yttrium Erbium and Cerium most common ndash

                                            Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                            Electron Configuration

                                            bull

                                            The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                            bull

                                            REEs

                                            have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                            Electron Configuartion

                                            REE Behaviorbull

                                            Because of their shared behaviour REEs

                                            tend to be

                                            present in nature as a group All REEs

                                            commonly substitute for one another in minerals

                                            bull

                                            Yet the REEs

                                            are capable of showing great variation in their distributions

                                            bull

                                            Comes about due to ndash

                                            Differences in ionic radius ndash

                                            Crystal structure (Coordination Number)ndash

                                            Basicity

                                            of the mineral ndash

                                            The elementrsquos solubility and ability to migrate in the environment ndash

                                            Content of REEs

                                            in source fluids

                                            Ionic Radiusbull

                                            The ionic radius of the REEs

                                            is inversely related to atomic number

                                            bull

                                            The heavy rare earths are smaller ndash

                                            more similar to Mn2+ (ionic radius 008 nanometers)

                                            bull

                                            LREEs

                                            are largerndash

                                            more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                            bull

                                            Charge balance achieved through some sites being left vacant or

                                            by coupled substitution with lower charged mineral (Na+)

                                            In nanometers

                                            Coordination Number

                                            bull

                                            Coordination number the number of atoms touching a particular atom in a crystal lattice

                                            bull

                                            Coordination number for this structure is 8

                                            Coordination Numberbull

                                            The heavy and light REEs

                                            differ in the coordination

                                            numbers (CN) with oxygenndash

                                            HREEs

                                            have CN between six to nine ndash

                                            LREEs

                                            have higher CNs

                                            bull

                                            Minerals with high CNs

                                            associated with REE site

                                            will favor LREEsndash

                                            Bastnasite

                                            CN = 11 ndash

                                            Monazite CN = 9

                                            bull

                                            Those with low CNs

                                            will preferentially select HREEs ndash

                                            Xenotime

                                            has a value of 8

                                            Other Factorsbull

                                            Minerals basicityndash

                                            Alkalic

                                            rocks host minerals with elevated LREE content ndash

                                            Rocks with lower basicity

                                            have lower amounts of LREEs

                                            relative to their HREE content

                                            bull

                                            Solubilityndash

                                            LREEs

                                            are more soluble in water then the HREEsndash

                                            Important characteristic for hydrothermally derived minerals

                                            bull

                                            MagmaHydrothermal fluid compositionndash

                                            Minerals will take what they can get

                                            REEs

                                            and Economicsbull

                                            The REEs

                                            and Yttrium have a very broad range of applications mostly in high technology fields

                                            bull

                                            84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                            bull

                                            REEs

                                            used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                            HREEs

                                            and Magnetism

                                            bull

                                            HREEs

                                            exhibit complex magnetic behaviour on account of electron structurendash

                                            They share the same outer shell electron configuration (valence = +3)

                                            ndash

                                            Differ in number of 4f electrons

                                            Applications in Magnetismbull

                                            Terbium and

                                            Dysprosium

                                            bull

                                            Components of Terfenol-D

                                            alloy

                                            with the formula Tb(03) Dy(07) Fe(19)

                                            bull

                                            Has the higher magnetostriction

                                            then any other alloyndash

                                            expands and contracts in magnetic field

                                            bull

                                            Developed by American Navy for sonar

                                            systems ndash

                                            Now has applications in magnetomechanical

                                            sensors and other electronic devices

                                            Applications in Magnetism

                                            bull

                                            Holmium

                                            bull

                                            Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                            elements

                                            bull

                                            Creates the strongest artificially generated magnetic fieldsndash

                                            In research where strong magnetic fields are needed

                                            HREEs

                                            and Nuclear Technology

                                            bull

                                            Dysprosium Homium Erbium

                                            bull

                                            High neutron

                                            absorption cross-section ndash

                                            Measure of probability of neutron capture

                                            bull

                                            Used in neutron-absorbing control rods in nuclear reactors

                                            HREEs

                                            and Nuclear Technology

                                            bull

                                            Lutetiumbull

                                            Radioactive isotope used in radiometric dating

                                            bull

                                            Thulium bull

                                            Stable thulium used as a radiation

                                            source

                                            in portable X-ray

                                            devices

                                            Mountain Passbull

                                            Bastnasite

                                            is the major REE mineral bull

                                            High grade accessory mineral of igneous or hydrothermal originsbull

                                            31 million tons of 886 by weight of rare earth oxides (REO) bull

                                            Mining stopped in 1994 ndash

                                            Thorium content of waste rock ndash

                                            Availability of inexpensive REEs

                                            from China

                                            San Bernardino County

                                            Bayan

                                            Obobull

                                            The worldrsquos primary source for both yttrium and the rare earth elements

                                            bull

                                            37 million tons of ore bull

                                            Main REE source there is Bastnasite

                                            World Production

                                            Explorationbull

                                            84 of REE imports to US are from China

                                            bull

                                            Increasing demand for high tech applications spurred increase in exploration in 2007

                                            bull

                                            Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                            Lake as well as in

                                            Malawi Africa

                                            Environmental Considerations

                                            bull

                                            REE soil and food contaminationbull

                                            Acid Mine Drainage and groundwater systems

                                            bull

                                            Radioactive elements

                                            REE Fertilizerbull

                                            In China REE enriched fertilizer has been used in crop fields since 1990

                                            bull

                                            At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                            every year

                                            bull

                                            Research and agricultural practice that provides evidence that REEs

                                            will improve crop quality an yield

                                            bull

                                            The ramifications environmental and human exposure to REEs

                                            are not well understood

                                            Investigation by T Liang et albull

                                            Revealed that the average concentration of total REEs

                                            in Chinese soil is

                                            1768 mgkg ranging between 850 to 5227 mgkg

                                            bull

                                            In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                            Implicationsbull

                                            Human health effects not completely understood

                                            bull

                                            REE soil content shown to be detrimental to some plant speciesndash

                                            100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                            Acid Mine Drainage (AMD)bull

                                            Rain waters contacts waste rock facilitating acid forming reactions

                                            bull

                                            Increases the capacity of the water to leach potentially harmful elements from waste piles

                                            bull

                                            Process mobilizes established ecotoxins

                                            (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                            bull

                                            Historically dismissed as minor environmental risk

                                            Radioactive Elements

                                            bull

                                            REEs

                                            associated with uranium and thorium

                                            bull

                                            Bastnesite 32 thorium

                                            bull

                                            Monazite sands 6 to 12 thorium oxide

                                            bull

                                            Ores containing radioactive elements are avoided as sources of REEs

                                            Radioactive Hazardsbull

                                            Mountain Pass

                                            bull

                                            Accidentsndash

                                            In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                            bull

                                            Health Effectsndash

                                            inflammatory bowel disease ndash

                                            Prolonged seizures ndash

                                            Cysts ndash

                                            Cancers

                                            bull

                                            Waste Disposal ndash

                                            Yucca Mountain

                                            Summarybull

                                            REE concentrations in the crust are rare

                                            bull

                                            Several geochemical factors influencing distribution including ionic radius and coordination number

                                            bull

                                            Main REE minerals are bastnasite monazite and xenotime

                                            bull

                                            Most important deposits are found at Bayan

                                            Obo China and Mountain Pass USA

                                            bull

                                            Important electronic and nuclear applications

                                            bull

                                            Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                            system contamination though acid mine drainage association with

                                            radioactive elements

                                            Referencesbull

                                            E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                            bull

                                            Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                            bull

                                            G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                            bull

                                            B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                            The Government of South Australia wwwpirsagovaubull

                                            The US geological Survey Mineralsusgsgovbull

                                            wwwelementsdatabasecombull

                                            wwwastrolsaumichedu~cowleyintro2htmlbull

                                            wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                            webmineralcomdataMonazite-(Ce)shtmlbull

                                            wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                            wwwstevegbcomimagesscienceorbital_fillingpngbull

                                            wwwchemicalelementscomelementseuhtmlbull

                                            boomeriaorgchemlecturestextass2table10-9jpgbull

                                            lostcontentquakecomfiles200802holmiumpngbull

                                            chinageocitylocatorcomcitiesChinaQinghaibull

                                            geowebrudruzal-Bayan-Obohtmbull

                                            enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                            wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                            enwikipediaorgwikiMonazitebull

                                            webmineralcomdataBastnasite-(La)shtmlbull

                                            wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                            httpwwwavalonventurescombull

                                            wwwnewsweekcomid43884bull

                                            httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                            httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                            • Slide Number 1
                                            • Slide Number 2
                                            • Slide Number 3
                                            • Slide Number 4
                                            • Slide Number 5
                                            • Slide Number 6
                                            • Slide Number 7
                                            • Slide Number 8
                                            • Slide Number 9
                                            • Slide Number 10
                                            • Slide Number 11
                                            • Slide Number 12
                                            • Slide Number 13
                                            • Slide Number 14
                                            • Slide Number 15
                                            • Slide Number 16
                                            • Slide Number 17
                                            • Slide Number 18
                                            • Slide Number 19
                                            • Slide Number 20
                                            • Slide Number 21
                                            • Slide Number 22
                                            • Slide Number 23
                                            • Slide Number 24
                                            • Slide Number 25
                                            • Slide Number 26
                                            • Slide Number 27
                                            • Slide Number 28
                                            • Slide Number 29
                                            • Slide Number 30
                                            • Slide Number 31
                                            • Slide Number 32
                                            • Slide Number 33
                                            • Slide Number 34
                                            • Slide Number 35
                                            • Slide Number 36
                                            • Slide Number 37
                                            • Slide Number 38
                                            • Slide Number 39
                                            • Slide Number 40
                                            • Slide Number 41
                                            • Slide Number 42
                                            • Slide Number 43
                                            • Slide Number 44
                                            • Slide Number 45
                                            • Slide Number 46
                                            • Slide Number 47
                                            • Slide Number 48
                                            • Slide Number 49
                                            • Slide Number 50
                                            • Slide Number 51
                                            • Rare Earth Elements
                                            • Crustal Abundances of Elements
                                            • Occurrence
                                            • Rare Earth Minerals
                                            • REE Minerals
                                            • Bastnesite
                                            • Other REE minerals
                                            • Electron Configuration
                                            • Electron Configuartion
                                            • REE Behavior
                                            • Ionic Radius
                                            • Coordination Number
                                            • Coordination Number
                                            • Other Factors
                                            • REEs and Economics
                                            • HREEs and Magnetism
                                            • Applications in Magnetism
                                            • Applications in Magnetism
                                            • HREEs and Nuclear Technology
                                            • HREEs and Nuclear Technology
                                            • Mountain Pass
                                            • Bayan Obo
                                            • World Production
                                            • Exploration
                                            • Environmental Considerations
                                            • REE Fertilizer
                                            • Investigation by T Liang et al
                                            • Implications
                                            • Acid Mine Drainage (AMD)
                                            • Radioactive Elements
                                            • Radioactive Hazards
                                            • Summary
                                            • References

                                              Allanite

                                              (Ce) (CeCaY)2

                                              (AlFe2+Fe3+)3

                                              (SiO4

                                              )3

                                              (OH)

                                              Allanite

                                              is found in abundant quantities in many different geologic environments and in almost all cases is LREE dominant Low quantities of sumREE+Y relative to bastnaumlsite and its refractory nature diminish its value as an economic source for REE and Y

                                              Allanite

                                              ndash

                                              Hydrothermal Mountain Pass CA Allanite

                                              ndash

                                              Pegmatite Timmins Ontario

                                              Eudialyte

                                              and Mosandrite

                                              in Peralkaline

                                              Syenite

                                              Kipawa Quebec

                                              Britholite-Rich Skarn

                                              All brown prisms are britholite

                                              (Horizontal Distance ndash 46 mm)

                                              Britholite

                                              Concentrate

                                              (mm scale)

                                              Britholite

                                              ndash

                                              (CeYCa)5 (SiO4PO4 )3 (OHF)

                                              Kipawa Quebec

                                              Cathodoluminescence

                                              Macrograph of Iimoriite

                                              in Syenite

                                              ndash

                                              Bokan

                                              Mountain

                                              Mottled light blue and tan clusters -

                                              Iimoriite

                                              Red groundmass ndash

                                              Feldspar

                                              (Horizontal distance of rock slab ndash 46 mm)

                                              Iimoriite

                                              (Y)

                                              Y2 (SiO4 )(CO3 )

                                              Yttrofluorite

                                              (CaY)F2

                                              Iimoriite

                                              Concentrate ndash

                                              Bokan

                                              MT (1 mm scale)

                                              Wicheeda

                                              Lake Heavy Mineral Composite mdash

                                              (from samples 828951 52 53)

                                              These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                              and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                              As a final statement it should be emphasizedhellip

                                              1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                              2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                              3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                              4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                              5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                              Rare Earth Elements

                                              bull

                                              Name something of a misnomerndash

                                              Rarest REEs

                                              are over 200 times more

                                              abundant then gold

                                              bull

                                              Variation in distribution for two reasons ndash

                                              Compatibility with common rock forming materials

                                              ndash

                                              CosmicCrustal abundances

                                              Crustal Abundances of Elements

                                              Occurrencebull

                                              REEs

                                              occur mostly as

                                              substitutional

                                              impurities in many rock forming minerals

                                              bull

                                              Only a few the REE minerals have sufficient quantities to be considered important sources

                                              bull

                                              Defined as minerals having at least one site that is filled by REEs

                                              andor Yttrium more often then any other elementMonazite

                                              Rare Earth Minerals

                                              bull

                                              Form by primary crystalization

                                              from magma or by hydrothermal reactions

                                              bull

                                              Found hosted in carbonate rocks in pegmatites

                                              and as accessory minerals in

                                              igneous rocks

                                              bull

                                              Stable REE minerals and can be concentrated in weathering zones

                                              REE Mineralsbull

                                              The most important REE minerals is bastnaumlsite

                                              REE(CO3)F

                                              bull

                                              Other notable sources are ndash

                                              Monazite REE(PO4) ndash

                                              Xenotime

                                              YPO4

                                              bull

                                              All may contain radioactive species such as thorium

                                              and uraniumndash

                                              are avoided as source materials

                                              Bastnesitebull

                                              Bastnasite

                                              [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                              bull

                                              Containing 60 to 70 rare earth oxides (REOs)

                                              bull

                                              REE site is most commonly filled by LREEs

                                              and Y

                                              Other REE mineralsbull

                                              Monazite [(LREEYTh)PO4] ndash

                                              Contains about 50ndash78 rare earth oxides

                                              ndash

                                              Forms in heavy mineral sands placer deposits associated with beach environments

                                              bull

                                              Xenotime

                                              [(YPO4)] ndash

                                              Contains 54ndash65 rare earth oxides

                                              ndash

                                              Yttrium Erbium and Cerium most common ndash

                                              Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                              Electron Configuration

                                              bull

                                              The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                              bull

                                              REEs

                                              have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                              Electron Configuartion

                                              REE Behaviorbull

                                              Because of their shared behaviour REEs

                                              tend to be

                                              present in nature as a group All REEs

                                              commonly substitute for one another in minerals

                                              bull

                                              Yet the REEs

                                              are capable of showing great variation in their distributions

                                              bull

                                              Comes about due to ndash

                                              Differences in ionic radius ndash

                                              Crystal structure (Coordination Number)ndash

                                              Basicity

                                              of the mineral ndash

                                              The elementrsquos solubility and ability to migrate in the environment ndash

                                              Content of REEs

                                              in source fluids

                                              Ionic Radiusbull

                                              The ionic radius of the REEs

                                              is inversely related to atomic number

                                              bull

                                              The heavy rare earths are smaller ndash

                                              more similar to Mn2+ (ionic radius 008 nanometers)

                                              bull

                                              LREEs

                                              are largerndash

                                              more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                              bull

                                              Charge balance achieved through some sites being left vacant or

                                              by coupled substitution with lower charged mineral (Na+)

                                              In nanometers

                                              Coordination Number

                                              bull

                                              Coordination number the number of atoms touching a particular atom in a crystal lattice

                                              bull

                                              Coordination number for this structure is 8

                                              Coordination Numberbull

                                              The heavy and light REEs

                                              differ in the coordination

                                              numbers (CN) with oxygenndash

                                              HREEs

                                              have CN between six to nine ndash

                                              LREEs

                                              have higher CNs

                                              bull

                                              Minerals with high CNs

                                              associated with REE site

                                              will favor LREEsndash

                                              Bastnasite

                                              CN = 11 ndash

                                              Monazite CN = 9

                                              bull

                                              Those with low CNs

                                              will preferentially select HREEs ndash

                                              Xenotime

                                              has a value of 8

                                              Other Factorsbull

                                              Minerals basicityndash

                                              Alkalic

                                              rocks host minerals with elevated LREE content ndash

                                              Rocks with lower basicity

                                              have lower amounts of LREEs

                                              relative to their HREE content

                                              bull

                                              Solubilityndash

                                              LREEs

                                              are more soluble in water then the HREEsndash

                                              Important characteristic for hydrothermally derived minerals

                                              bull

                                              MagmaHydrothermal fluid compositionndash

                                              Minerals will take what they can get

                                              REEs

                                              and Economicsbull

                                              The REEs

                                              and Yttrium have a very broad range of applications mostly in high technology fields

                                              bull

                                              84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                              bull

                                              REEs

                                              used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                              HREEs

                                              and Magnetism

                                              bull

                                              HREEs

                                              exhibit complex magnetic behaviour on account of electron structurendash

                                              They share the same outer shell electron configuration (valence = +3)

                                              ndash

                                              Differ in number of 4f electrons

                                              Applications in Magnetismbull

                                              Terbium and

                                              Dysprosium

                                              bull

                                              Components of Terfenol-D

                                              alloy

                                              with the formula Tb(03) Dy(07) Fe(19)

                                              bull

                                              Has the higher magnetostriction

                                              then any other alloyndash

                                              expands and contracts in magnetic field

                                              bull

                                              Developed by American Navy for sonar

                                              systems ndash

                                              Now has applications in magnetomechanical

                                              sensors and other electronic devices

                                              Applications in Magnetism

                                              bull

                                              Holmium

                                              bull

                                              Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                              elements

                                              bull

                                              Creates the strongest artificially generated magnetic fieldsndash

                                              In research where strong magnetic fields are needed

                                              HREEs

                                              and Nuclear Technology

                                              bull

                                              Dysprosium Homium Erbium

                                              bull

                                              High neutron

                                              absorption cross-section ndash

                                              Measure of probability of neutron capture

                                              bull

                                              Used in neutron-absorbing control rods in nuclear reactors

                                              HREEs

                                              and Nuclear Technology

                                              bull

                                              Lutetiumbull

                                              Radioactive isotope used in radiometric dating

                                              bull

                                              Thulium bull

                                              Stable thulium used as a radiation

                                              source

                                              in portable X-ray

                                              devices

                                              Mountain Passbull

                                              Bastnasite

                                              is the major REE mineral bull

                                              High grade accessory mineral of igneous or hydrothermal originsbull

                                              31 million tons of 886 by weight of rare earth oxides (REO) bull

                                              Mining stopped in 1994 ndash

                                              Thorium content of waste rock ndash

                                              Availability of inexpensive REEs

                                              from China

                                              San Bernardino County

                                              Bayan

                                              Obobull

                                              The worldrsquos primary source for both yttrium and the rare earth elements

                                              bull

                                              37 million tons of ore bull

                                              Main REE source there is Bastnasite

                                              World Production

                                              Explorationbull

                                              84 of REE imports to US are from China

                                              bull

                                              Increasing demand for high tech applications spurred increase in exploration in 2007

                                              bull

                                              Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                              Lake as well as in

                                              Malawi Africa

                                              Environmental Considerations

                                              bull

                                              REE soil and food contaminationbull

                                              Acid Mine Drainage and groundwater systems

                                              bull

                                              Radioactive elements

                                              REE Fertilizerbull

                                              In China REE enriched fertilizer has been used in crop fields since 1990

                                              bull

                                              At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                              every year

                                              bull

                                              Research and agricultural practice that provides evidence that REEs

                                              will improve crop quality an yield

                                              bull

                                              The ramifications environmental and human exposure to REEs

                                              are not well understood

                                              Investigation by T Liang et albull

                                              Revealed that the average concentration of total REEs

                                              in Chinese soil is

                                              1768 mgkg ranging between 850 to 5227 mgkg

                                              bull

                                              In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                              Implicationsbull

                                              Human health effects not completely understood

                                              bull

                                              REE soil content shown to be detrimental to some plant speciesndash

                                              100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                              Acid Mine Drainage (AMD)bull

                                              Rain waters contacts waste rock facilitating acid forming reactions

                                              bull

                                              Increases the capacity of the water to leach potentially harmful elements from waste piles

                                              bull

                                              Process mobilizes established ecotoxins

                                              (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                              bull

                                              Historically dismissed as minor environmental risk

                                              Radioactive Elements

                                              bull

                                              REEs

                                              associated with uranium and thorium

                                              bull

                                              Bastnesite 32 thorium

                                              bull

                                              Monazite sands 6 to 12 thorium oxide

                                              bull

                                              Ores containing radioactive elements are avoided as sources of REEs

                                              Radioactive Hazardsbull

                                              Mountain Pass

                                              bull

                                              Accidentsndash

                                              In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                              bull

                                              Health Effectsndash

                                              inflammatory bowel disease ndash

                                              Prolonged seizures ndash

                                              Cysts ndash

                                              Cancers

                                              bull

                                              Waste Disposal ndash

                                              Yucca Mountain

                                              Summarybull

                                              REE concentrations in the crust are rare

                                              bull

                                              Several geochemical factors influencing distribution including ionic radius and coordination number

                                              bull

                                              Main REE minerals are bastnasite monazite and xenotime

                                              bull

                                              Most important deposits are found at Bayan

                                              Obo China and Mountain Pass USA

                                              bull

                                              Important electronic and nuclear applications

                                              bull

                                              Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                              system contamination though acid mine drainage association with

                                              radioactive elements

                                              Referencesbull

                                              E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                              bull

                                              Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                              bull

                                              G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                              bull

                                              B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                              The Government of South Australia wwwpirsagovaubull

                                              The US geological Survey Mineralsusgsgovbull

                                              wwwelementsdatabasecombull

                                              wwwastrolsaumichedu~cowleyintro2htmlbull

                                              wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                              webmineralcomdataMonazite-(Ce)shtmlbull

                                              wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                              wwwstevegbcomimagesscienceorbital_fillingpngbull

                                              wwwchemicalelementscomelementseuhtmlbull

                                              boomeriaorgchemlecturestextass2table10-9jpgbull

                                              lostcontentquakecomfiles200802holmiumpngbull

                                              chinageocitylocatorcomcitiesChinaQinghaibull

                                              geowebrudruzal-Bayan-Obohtmbull

                                              enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                              wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                              enwikipediaorgwikiMonazitebull

                                              webmineralcomdataBastnasite-(La)shtmlbull

                                              wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                              httpwwwavalonventurescombull

                                              wwwnewsweekcomid43884bull

                                              httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                              httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                              • Slide Number 1
                                              • Slide Number 2
                                              • Slide Number 3
                                              • Slide Number 4
                                              • Slide Number 5
                                              • Slide Number 6
                                              • Slide Number 7
                                              • Slide Number 8
                                              • Slide Number 9
                                              • Slide Number 10
                                              • Slide Number 11
                                              • Slide Number 12
                                              • Slide Number 13
                                              • Slide Number 14
                                              • Slide Number 15
                                              • Slide Number 16
                                              • Slide Number 17
                                              • Slide Number 18
                                              • Slide Number 19
                                              • Slide Number 20
                                              • Slide Number 21
                                              • Slide Number 22
                                              • Slide Number 23
                                              • Slide Number 24
                                              • Slide Number 25
                                              • Slide Number 26
                                              • Slide Number 27
                                              • Slide Number 28
                                              • Slide Number 29
                                              • Slide Number 30
                                              • Slide Number 31
                                              • Slide Number 32
                                              • Slide Number 33
                                              • Slide Number 34
                                              • Slide Number 35
                                              • Slide Number 36
                                              • Slide Number 37
                                              • Slide Number 38
                                              • Slide Number 39
                                              • Slide Number 40
                                              • Slide Number 41
                                              • Slide Number 42
                                              • Slide Number 43
                                              • Slide Number 44
                                              • Slide Number 45
                                              • Slide Number 46
                                              • Slide Number 47
                                              • Slide Number 48
                                              • Slide Number 49
                                              • Slide Number 50
                                              • Slide Number 51
                                              • Rare Earth Elements
                                              • Crustal Abundances of Elements
                                              • Occurrence
                                              • Rare Earth Minerals
                                              • REE Minerals
                                              • Bastnesite
                                              • Other REE minerals
                                              • Electron Configuration
                                              • Electron Configuartion
                                              • REE Behavior
                                              • Ionic Radius
                                              • Coordination Number
                                              • Coordination Number
                                              • Other Factors
                                              • REEs and Economics
                                              • HREEs and Magnetism
                                              • Applications in Magnetism
                                              • Applications in Magnetism
                                              • HREEs and Nuclear Technology
                                              • HREEs and Nuclear Technology
                                              • Mountain Pass
                                              • Bayan Obo
                                              • World Production
                                              • Exploration
                                              • Environmental Considerations
                                              • REE Fertilizer
                                              • Investigation by T Liang et al
                                              • Implications
                                              • Acid Mine Drainage (AMD)
                                              • Radioactive Elements
                                              • Radioactive Hazards
                                              • Summary
                                              • References

                                                Eudialyte

                                                and Mosandrite

                                                in Peralkaline

                                                Syenite

                                                Kipawa Quebec

                                                Britholite-Rich Skarn

                                                All brown prisms are britholite

                                                (Horizontal Distance ndash 46 mm)

                                                Britholite

                                                Concentrate

                                                (mm scale)

                                                Britholite

                                                ndash

                                                (CeYCa)5 (SiO4PO4 )3 (OHF)

                                                Kipawa Quebec

                                                Cathodoluminescence

                                                Macrograph of Iimoriite

                                                in Syenite

                                                ndash

                                                Bokan

                                                Mountain

                                                Mottled light blue and tan clusters -

                                                Iimoriite

                                                Red groundmass ndash

                                                Feldspar

                                                (Horizontal distance of rock slab ndash 46 mm)

                                                Iimoriite

                                                (Y)

                                                Y2 (SiO4 )(CO3 )

                                                Yttrofluorite

                                                (CaY)F2

                                                Iimoriite

                                                Concentrate ndash

                                                Bokan

                                                MT (1 mm scale)

                                                Wicheeda

                                                Lake Heavy Mineral Composite mdash

                                                (from samples 828951 52 53)

                                                These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                                and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                                As a final statement it should be emphasizedhellip

                                                1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                                2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                                3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                                4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                                5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                                Rare Earth Elements

                                                bull

                                                Name something of a misnomerndash

                                                Rarest REEs

                                                are over 200 times more

                                                abundant then gold

                                                bull

                                                Variation in distribution for two reasons ndash

                                                Compatibility with common rock forming materials

                                                ndash

                                                CosmicCrustal abundances

                                                Crustal Abundances of Elements

                                                Occurrencebull

                                                REEs

                                                occur mostly as

                                                substitutional

                                                impurities in many rock forming minerals

                                                bull

                                                Only a few the REE minerals have sufficient quantities to be considered important sources

                                                bull

                                                Defined as minerals having at least one site that is filled by REEs

                                                andor Yttrium more often then any other elementMonazite

                                                Rare Earth Minerals

                                                bull

                                                Form by primary crystalization

                                                from magma or by hydrothermal reactions

                                                bull

                                                Found hosted in carbonate rocks in pegmatites

                                                and as accessory minerals in

                                                igneous rocks

                                                bull

                                                Stable REE minerals and can be concentrated in weathering zones

                                                REE Mineralsbull

                                                The most important REE minerals is bastnaumlsite

                                                REE(CO3)F

                                                bull

                                                Other notable sources are ndash

                                                Monazite REE(PO4) ndash

                                                Xenotime

                                                YPO4

                                                bull

                                                All may contain radioactive species such as thorium

                                                and uraniumndash

                                                are avoided as source materials

                                                Bastnesitebull

                                                Bastnasite

                                                [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                bull

                                                Containing 60 to 70 rare earth oxides (REOs)

                                                bull

                                                REE site is most commonly filled by LREEs

                                                and Y

                                                Other REE mineralsbull

                                                Monazite [(LREEYTh)PO4] ndash

                                                Contains about 50ndash78 rare earth oxides

                                                ndash

                                                Forms in heavy mineral sands placer deposits associated with beach environments

                                                bull

                                                Xenotime

                                                [(YPO4)] ndash

                                                Contains 54ndash65 rare earth oxides

                                                ndash

                                                Yttrium Erbium and Cerium most common ndash

                                                Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                Electron Configuration

                                                bull

                                                The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                bull

                                                REEs

                                                have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                Electron Configuartion

                                                REE Behaviorbull

                                                Because of their shared behaviour REEs

                                                tend to be

                                                present in nature as a group All REEs

                                                commonly substitute for one another in minerals

                                                bull

                                                Yet the REEs

                                                are capable of showing great variation in their distributions

                                                bull

                                                Comes about due to ndash

                                                Differences in ionic radius ndash

                                                Crystal structure (Coordination Number)ndash

                                                Basicity

                                                of the mineral ndash

                                                The elementrsquos solubility and ability to migrate in the environment ndash

                                                Content of REEs

                                                in source fluids

                                                Ionic Radiusbull

                                                The ionic radius of the REEs

                                                is inversely related to atomic number

                                                bull

                                                The heavy rare earths are smaller ndash

                                                more similar to Mn2+ (ionic radius 008 nanometers)

                                                bull

                                                LREEs

                                                are largerndash

                                                more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                bull

                                                Charge balance achieved through some sites being left vacant or

                                                by coupled substitution with lower charged mineral (Na+)

                                                In nanometers

                                                Coordination Number

                                                bull

                                                Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                bull

                                                Coordination number for this structure is 8

                                                Coordination Numberbull

                                                The heavy and light REEs

                                                differ in the coordination

                                                numbers (CN) with oxygenndash

                                                HREEs

                                                have CN between six to nine ndash

                                                LREEs

                                                have higher CNs

                                                bull

                                                Minerals with high CNs

                                                associated with REE site

                                                will favor LREEsndash

                                                Bastnasite

                                                CN = 11 ndash

                                                Monazite CN = 9

                                                bull

                                                Those with low CNs

                                                will preferentially select HREEs ndash

                                                Xenotime

                                                has a value of 8

                                                Other Factorsbull

                                                Minerals basicityndash

                                                Alkalic

                                                rocks host minerals with elevated LREE content ndash

                                                Rocks with lower basicity

                                                have lower amounts of LREEs

                                                relative to their HREE content

                                                bull

                                                Solubilityndash

                                                LREEs

                                                are more soluble in water then the HREEsndash

                                                Important characteristic for hydrothermally derived minerals

                                                bull

                                                MagmaHydrothermal fluid compositionndash

                                                Minerals will take what they can get

                                                REEs

                                                and Economicsbull

                                                The REEs

                                                and Yttrium have a very broad range of applications mostly in high technology fields

                                                bull

                                                84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                bull

                                                REEs

                                                used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                HREEs

                                                and Magnetism

                                                bull

                                                HREEs

                                                exhibit complex magnetic behaviour on account of electron structurendash

                                                They share the same outer shell electron configuration (valence = +3)

                                                ndash

                                                Differ in number of 4f electrons

                                                Applications in Magnetismbull

                                                Terbium and

                                                Dysprosium

                                                bull

                                                Components of Terfenol-D

                                                alloy

                                                with the formula Tb(03) Dy(07) Fe(19)

                                                bull

                                                Has the higher magnetostriction

                                                then any other alloyndash

                                                expands and contracts in magnetic field

                                                bull

                                                Developed by American Navy for sonar

                                                systems ndash

                                                Now has applications in magnetomechanical

                                                sensors and other electronic devices

                                                Applications in Magnetism

                                                bull

                                                Holmium

                                                bull

                                                Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                elements

                                                bull

                                                Creates the strongest artificially generated magnetic fieldsndash

                                                In research where strong magnetic fields are needed

                                                HREEs

                                                and Nuclear Technology

                                                bull

                                                Dysprosium Homium Erbium

                                                bull

                                                High neutron

                                                absorption cross-section ndash

                                                Measure of probability of neutron capture

                                                bull

                                                Used in neutron-absorbing control rods in nuclear reactors

                                                HREEs

                                                and Nuclear Technology

                                                bull

                                                Lutetiumbull

                                                Radioactive isotope used in radiometric dating

                                                bull

                                                Thulium bull

                                                Stable thulium used as a radiation

                                                source

                                                in portable X-ray

                                                devices

                                                Mountain Passbull

                                                Bastnasite

                                                is the major REE mineral bull

                                                High grade accessory mineral of igneous or hydrothermal originsbull

                                                31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                Mining stopped in 1994 ndash

                                                Thorium content of waste rock ndash

                                                Availability of inexpensive REEs

                                                from China

                                                San Bernardino County

                                                Bayan

                                                Obobull

                                                The worldrsquos primary source for both yttrium and the rare earth elements

                                                bull

                                                37 million tons of ore bull

                                                Main REE source there is Bastnasite

                                                World Production

                                                Explorationbull

                                                84 of REE imports to US are from China

                                                bull

                                                Increasing demand for high tech applications spurred increase in exploration in 2007

                                                bull

                                                Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                Lake as well as in

                                                Malawi Africa

                                                Environmental Considerations

                                                bull

                                                REE soil and food contaminationbull

                                                Acid Mine Drainage and groundwater systems

                                                bull

                                                Radioactive elements

                                                REE Fertilizerbull

                                                In China REE enriched fertilizer has been used in crop fields since 1990

                                                bull

                                                At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                every year

                                                bull

                                                Research and agricultural practice that provides evidence that REEs

                                                will improve crop quality an yield

                                                bull

                                                The ramifications environmental and human exposure to REEs

                                                are not well understood

                                                Investigation by T Liang et albull

                                                Revealed that the average concentration of total REEs

                                                in Chinese soil is

                                                1768 mgkg ranging between 850 to 5227 mgkg

                                                bull

                                                In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                Implicationsbull

                                                Human health effects not completely understood

                                                bull

                                                REE soil content shown to be detrimental to some plant speciesndash

                                                100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                Acid Mine Drainage (AMD)bull

                                                Rain waters contacts waste rock facilitating acid forming reactions

                                                bull

                                                Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                bull

                                                Process mobilizes established ecotoxins

                                                (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                bull

                                                Historically dismissed as minor environmental risk

                                                Radioactive Elements

                                                bull

                                                REEs

                                                associated with uranium and thorium

                                                bull

                                                Bastnesite 32 thorium

                                                bull

                                                Monazite sands 6 to 12 thorium oxide

                                                bull

                                                Ores containing radioactive elements are avoided as sources of REEs

                                                Radioactive Hazardsbull

                                                Mountain Pass

                                                bull

                                                Accidentsndash

                                                In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                bull

                                                Health Effectsndash

                                                inflammatory bowel disease ndash

                                                Prolonged seizures ndash

                                                Cysts ndash

                                                Cancers

                                                bull

                                                Waste Disposal ndash

                                                Yucca Mountain

                                                Summarybull

                                                REE concentrations in the crust are rare

                                                bull

                                                Several geochemical factors influencing distribution including ionic radius and coordination number

                                                bull

                                                Main REE minerals are bastnasite monazite and xenotime

                                                bull

                                                Most important deposits are found at Bayan

                                                Obo China and Mountain Pass USA

                                                bull

                                                Important electronic and nuclear applications

                                                bull

                                                Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                system contamination though acid mine drainage association with

                                                radioactive elements

                                                Referencesbull

                                                E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                bull

                                                Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                bull

                                                G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                bull

                                                B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                The Government of South Australia wwwpirsagovaubull

                                                The US geological Survey Mineralsusgsgovbull

                                                wwwelementsdatabasecombull

                                                wwwastrolsaumichedu~cowleyintro2htmlbull

                                                wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                webmineralcomdataMonazite-(Ce)shtmlbull

                                                wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                wwwchemicalelementscomelementseuhtmlbull

                                                boomeriaorgchemlecturestextass2table10-9jpgbull

                                                lostcontentquakecomfiles200802holmiumpngbull

                                                chinageocitylocatorcomcitiesChinaQinghaibull

                                                geowebrudruzal-Bayan-Obohtmbull

                                                enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                enwikipediaorgwikiMonazitebull

                                                webmineralcomdataBastnasite-(La)shtmlbull

                                                wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                httpwwwavalonventurescombull

                                                wwwnewsweekcomid43884bull

                                                httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                • Slide Number 1
                                                • Slide Number 2
                                                • Slide Number 3
                                                • Slide Number 4
                                                • Slide Number 5
                                                • Slide Number 6
                                                • Slide Number 7
                                                • Slide Number 8
                                                • Slide Number 9
                                                • Slide Number 10
                                                • Slide Number 11
                                                • Slide Number 12
                                                • Slide Number 13
                                                • Slide Number 14
                                                • Slide Number 15
                                                • Slide Number 16
                                                • Slide Number 17
                                                • Slide Number 18
                                                • Slide Number 19
                                                • Slide Number 20
                                                • Slide Number 21
                                                • Slide Number 22
                                                • Slide Number 23
                                                • Slide Number 24
                                                • Slide Number 25
                                                • Slide Number 26
                                                • Slide Number 27
                                                • Slide Number 28
                                                • Slide Number 29
                                                • Slide Number 30
                                                • Slide Number 31
                                                • Slide Number 32
                                                • Slide Number 33
                                                • Slide Number 34
                                                • Slide Number 35
                                                • Slide Number 36
                                                • Slide Number 37
                                                • Slide Number 38
                                                • Slide Number 39
                                                • Slide Number 40
                                                • Slide Number 41
                                                • Slide Number 42
                                                • Slide Number 43
                                                • Slide Number 44
                                                • Slide Number 45
                                                • Slide Number 46
                                                • Slide Number 47
                                                • Slide Number 48
                                                • Slide Number 49
                                                • Slide Number 50
                                                • Slide Number 51
                                                • Rare Earth Elements
                                                • Crustal Abundances of Elements
                                                • Occurrence
                                                • Rare Earth Minerals
                                                • REE Minerals
                                                • Bastnesite
                                                • Other REE minerals
                                                • Electron Configuration
                                                • Electron Configuartion
                                                • REE Behavior
                                                • Ionic Radius
                                                • Coordination Number
                                                • Coordination Number
                                                • Other Factors
                                                • REEs and Economics
                                                • HREEs and Magnetism
                                                • Applications in Magnetism
                                                • Applications in Magnetism
                                                • HREEs and Nuclear Technology
                                                • HREEs and Nuclear Technology
                                                • Mountain Pass
                                                • Bayan Obo
                                                • World Production
                                                • Exploration
                                                • Environmental Considerations
                                                • REE Fertilizer
                                                • Investigation by T Liang et al
                                                • Implications
                                                • Acid Mine Drainage (AMD)
                                                • Radioactive Elements
                                                • Radioactive Hazards
                                                • Summary
                                                • References

                                                  Britholite-Rich Skarn

                                                  All brown prisms are britholite

                                                  (Horizontal Distance ndash 46 mm)

                                                  Britholite

                                                  Concentrate

                                                  (mm scale)

                                                  Britholite

                                                  ndash

                                                  (CeYCa)5 (SiO4PO4 )3 (OHF)

                                                  Kipawa Quebec

                                                  Cathodoluminescence

                                                  Macrograph of Iimoriite

                                                  in Syenite

                                                  ndash

                                                  Bokan

                                                  Mountain

                                                  Mottled light blue and tan clusters -

                                                  Iimoriite

                                                  Red groundmass ndash

                                                  Feldspar

                                                  (Horizontal distance of rock slab ndash 46 mm)

                                                  Iimoriite

                                                  (Y)

                                                  Y2 (SiO4 )(CO3 )

                                                  Yttrofluorite

                                                  (CaY)F2

                                                  Iimoriite

                                                  Concentrate ndash

                                                  Bokan

                                                  MT (1 mm scale)

                                                  Wicheeda

                                                  Lake Heavy Mineral Composite mdash

                                                  (from samples 828951 52 53)

                                                  These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                                  and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                                  As a final statement it should be emphasizedhellip

                                                  1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                                  2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                                  3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                                  4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                                  5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                                  Rare Earth Elements

                                                  bull

                                                  Name something of a misnomerndash

                                                  Rarest REEs

                                                  are over 200 times more

                                                  abundant then gold

                                                  bull

                                                  Variation in distribution for two reasons ndash

                                                  Compatibility with common rock forming materials

                                                  ndash

                                                  CosmicCrustal abundances

                                                  Crustal Abundances of Elements

                                                  Occurrencebull

                                                  REEs

                                                  occur mostly as

                                                  substitutional

                                                  impurities in many rock forming minerals

                                                  bull

                                                  Only a few the REE minerals have sufficient quantities to be considered important sources

                                                  bull

                                                  Defined as minerals having at least one site that is filled by REEs

                                                  andor Yttrium more often then any other elementMonazite

                                                  Rare Earth Minerals

                                                  bull

                                                  Form by primary crystalization

                                                  from magma or by hydrothermal reactions

                                                  bull

                                                  Found hosted in carbonate rocks in pegmatites

                                                  and as accessory minerals in

                                                  igneous rocks

                                                  bull

                                                  Stable REE minerals and can be concentrated in weathering zones

                                                  REE Mineralsbull

                                                  The most important REE minerals is bastnaumlsite

                                                  REE(CO3)F

                                                  bull

                                                  Other notable sources are ndash

                                                  Monazite REE(PO4) ndash

                                                  Xenotime

                                                  YPO4

                                                  bull

                                                  All may contain radioactive species such as thorium

                                                  and uraniumndash

                                                  are avoided as source materials

                                                  Bastnesitebull

                                                  Bastnasite

                                                  [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                  bull

                                                  Containing 60 to 70 rare earth oxides (REOs)

                                                  bull

                                                  REE site is most commonly filled by LREEs

                                                  and Y

                                                  Other REE mineralsbull

                                                  Monazite [(LREEYTh)PO4] ndash

                                                  Contains about 50ndash78 rare earth oxides

                                                  ndash

                                                  Forms in heavy mineral sands placer deposits associated with beach environments

                                                  bull

                                                  Xenotime

                                                  [(YPO4)] ndash

                                                  Contains 54ndash65 rare earth oxides

                                                  ndash

                                                  Yttrium Erbium and Cerium most common ndash

                                                  Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                  Electron Configuration

                                                  bull

                                                  The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                  bull

                                                  REEs

                                                  have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                  Electron Configuartion

                                                  REE Behaviorbull

                                                  Because of their shared behaviour REEs

                                                  tend to be

                                                  present in nature as a group All REEs

                                                  commonly substitute for one another in minerals

                                                  bull

                                                  Yet the REEs

                                                  are capable of showing great variation in their distributions

                                                  bull

                                                  Comes about due to ndash

                                                  Differences in ionic radius ndash

                                                  Crystal structure (Coordination Number)ndash

                                                  Basicity

                                                  of the mineral ndash

                                                  The elementrsquos solubility and ability to migrate in the environment ndash

                                                  Content of REEs

                                                  in source fluids

                                                  Ionic Radiusbull

                                                  The ionic radius of the REEs

                                                  is inversely related to atomic number

                                                  bull

                                                  The heavy rare earths are smaller ndash

                                                  more similar to Mn2+ (ionic radius 008 nanometers)

                                                  bull

                                                  LREEs

                                                  are largerndash

                                                  more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                  bull

                                                  Charge balance achieved through some sites being left vacant or

                                                  by coupled substitution with lower charged mineral (Na+)

                                                  In nanometers

                                                  Coordination Number

                                                  bull

                                                  Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                  bull

                                                  Coordination number for this structure is 8

                                                  Coordination Numberbull

                                                  The heavy and light REEs

                                                  differ in the coordination

                                                  numbers (CN) with oxygenndash

                                                  HREEs

                                                  have CN between six to nine ndash

                                                  LREEs

                                                  have higher CNs

                                                  bull

                                                  Minerals with high CNs

                                                  associated with REE site

                                                  will favor LREEsndash

                                                  Bastnasite

                                                  CN = 11 ndash

                                                  Monazite CN = 9

                                                  bull

                                                  Those with low CNs

                                                  will preferentially select HREEs ndash

                                                  Xenotime

                                                  has a value of 8

                                                  Other Factorsbull

                                                  Minerals basicityndash

                                                  Alkalic

                                                  rocks host minerals with elevated LREE content ndash

                                                  Rocks with lower basicity

                                                  have lower amounts of LREEs

                                                  relative to their HREE content

                                                  bull

                                                  Solubilityndash

                                                  LREEs

                                                  are more soluble in water then the HREEsndash

                                                  Important characteristic for hydrothermally derived minerals

                                                  bull

                                                  MagmaHydrothermal fluid compositionndash

                                                  Minerals will take what they can get

                                                  REEs

                                                  and Economicsbull

                                                  The REEs

                                                  and Yttrium have a very broad range of applications mostly in high technology fields

                                                  bull

                                                  84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                  bull

                                                  REEs

                                                  used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                  HREEs

                                                  and Magnetism

                                                  bull

                                                  HREEs

                                                  exhibit complex magnetic behaviour on account of electron structurendash

                                                  They share the same outer shell electron configuration (valence = +3)

                                                  ndash

                                                  Differ in number of 4f electrons

                                                  Applications in Magnetismbull

                                                  Terbium and

                                                  Dysprosium

                                                  bull

                                                  Components of Terfenol-D

                                                  alloy

                                                  with the formula Tb(03) Dy(07) Fe(19)

                                                  bull

                                                  Has the higher magnetostriction

                                                  then any other alloyndash

                                                  expands and contracts in magnetic field

                                                  bull

                                                  Developed by American Navy for sonar

                                                  systems ndash

                                                  Now has applications in magnetomechanical

                                                  sensors and other electronic devices

                                                  Applications in Magnetism

                                                  bull

                                                  Holmium

                                                  bull

                                                  Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                  elements

                                                  bull

                                                  Creates the strongest artificially generated magnetic fieldsndash

                                                  In research where strong magnetic fields are needed

                                                  HREEs

                                                  and Nuclear Technology

                                                  bull

                                                  Dysprosium Homium Erbium

                                                  bull

                                                  High neutron

                                                  absorption cross-section ndash

                                                  Measure of probability of neutron capture

                                                  bull

                                                  Used in neutron-absorbing control rods in nuclear reactors

                                                  HREEs

                                                  and Nuclear Technology

                                                  bull

                                                  Lutetiumbull

                                                  Radioactive isotope used in radiometric dating

                                                  bull

                                                  Thulium bull

                                                  Stable thulium used as a radiation

                                                  source

                                                  in portable X-ray

                                                  devices

                                                  Mountain Passbull

                                                  Bastnasite

                                                  is the major REE mineral bull

                                                  High grade accessory mineral of igneous or hydrothermal originsbull

                                                  31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                  Mining stopped in 1994 ndash

                                                  Thorium content of waste rock ndash

                                                  Availability of inexpensive REEs

                                                  from China

                                                  San Bernardino County

                                                  Bayan

                                                  Obobull

                                                  The worldrsquos primary source for both yttrium and the rare earth elements

                                                  bull

                                                  37 million tons of ore bull

                                                  Main REE source there is Bastnasite

                                                  World Production

                                                  Explorationbull

                                                  84 of REE imports to US are from China

                                                  bull

                                                  Increasing demand for high tech applications spurred increase in exploration in 2007

                                                  bull

                                                  Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                  Lake as well as in

                                                  Malawi Africa

                                                  Environmental Considerations

                                                  bull

                                                  REE soil and food contaminationbull

                                                  Acid Mine Drainage and groundwater systems

                                                  bull

                                                  Radioactive elements

                                                  REE Fertilizerbull

                                                  In China REE enriched fertilizer has been used in crop fields since 1990

                                                  bull

                                                  At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                  every year

                                                  bull

                                                  Research and agricultural practice that provides evidence that REEs

                                                  will improve crop quality an yield

                                                  bull

                                                  The ramifications environmental and human exposure to REEs

                                                  are not well understood

                                                  Investigation by T Liang et albull

                                                  Revealed that the average concentration of total REEs

                                                  in Chinese soil is

                                                  1768 mgkg ranging between 850 to 5227 mgkg

                                                  bull

                                                  In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                  Implicationsbull

                                                  Human health effects not completely understood

                                                  bull

                                                  REE soil content shown to be detrimental to some plant speciesndash

                                                  100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                  Acid Mine Drainage (AMD)bull

                                                  Rain waters contacts waste rock facilitating acid forming reactions

                                                  bull

                                                  Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                  bull

                                                  Process mobilizes established ecotoxins

                                                  (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                  bull

                                                  Historically dismissed as minor environmental risk

                                                  Radioactive Elements

                                                  bull

                                                  REEs

                                                  associated with uranium and thorium

                                                  bull

                                                  Bastnesite 32 thorium

                                                  bull

                                                  Monazite sands 6 to 12 thorium oxide

                                                  bull

                                                  Ores containing radioactive elements are avoided as sources of REEs

                                                  Radioactive Hazardsbull

                                                  Mountain Pass

                                                  bull

                                                  Accidentsndash

                                                  In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                  bull

                                                  Health Effectsndash

                                                  inflammatory bowel disease ndash

                                                  Prolonged seizures ndash

                                                  Cysts ndash

                                                  Cancers

                                                  bull

                                                  Waste Disposal ndash

                                                  Yucca Mountain

                                                  Summarybull

                                                  REE concentrations in the crust are rare

                                                  bull

                                                  Several geochemical factors influencing distribution including ionic radius and coordination number

                                                  bull

                                                  Main REE minerals are bastnasite monazite and xenotime

                                                  bull

                                                  Most important deposits are found at Bayan

                                                  Obo China and Mountain Pass USA

                                                  bull

                                                  Important electronic and nuclear applications

                                                  bull

                                                  Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                  system contamination though acid mine drainage association with

                                                  radioactive elements

                                                  Referencesbull

                                                  E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                  bull

                                                  Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                  bull

                                                  G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                  bull

                                                  B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                  The Government of South Australia wwwpirsagovaubull

                                                  The US geological Survey Mineralsusgsgovbull

                                                  wwwelementsdatabasecombull

                                                  wwwastrolsaumichedu~cowleyintro2htmlbull

                                                  wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                  webmineralcomdataMonazite-(Ce)shtmlbull

                                                  wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                  wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                  wwwchemicalelementscomelementseuhtmlbull

                                                  boomeriaorgchemlecturestextass2table10-9jpgbull

                                                  lostcontentquakecomfiles200802holmiumpngbull

                                                  chinageocitylocatorcomcitiesChinaQinghaibull

                                                  geowebrudruzal-Bayan-Obohtmbull

                                                  enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                  wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                  enwikipediaorgwikiMonazitebull

                                                  webmineralcomdataBastnasite-(La)shtmlbull

                                                  wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                  httpwwwavalonventurescombull

                                                  wwwnewsweekcomid43884bull

                                                  httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                  httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                  • Slide Number 1
                                                  • Slide Number 2
                                                  • Slide Number 3
                                                  • Slide Number 4
                                                  • Slide Number 5
                                                  • Slide Number 6
                                                  • Slide Number 7
                                                  • Slide Number 8
                                                  • Slide Number 9
                                                  • Slide Number 10
                                                  • Slide Number 11
                                                  • Slide Number 12
                                                  • Slide Number 13
                                                  • Slide Number 14
                                                  • Slide Number 15
                                                  • Slide Number 16
                                                  • Slide Number 17
                                                  • Slide Number 18
                                                  • Slide Number 19
                                                  • Slide Number 20
                                                  • Slide Number 21
                                                  • Slide Number 22
                                                  • Slide Number 23
                                                  • Slide Number 24
                                                  • Slide Number 25
                                                  • Slide Number 26
                                                  • Slide Number 27
                                                  • Slide Number 28
                                                  • Slide Number 29
                                                  • Slide Number 30
                                                  • Slide Number 31
                                                  • Slide Number 32
                                                  • Slide Number 33
                                                  • Slide Number 34
                                                  • Slide Number 35
                                                  • Slide Number 36
                                                  • Slide Number 37
                                                  • Slide Number 38
                                                  • Slide Number 39
                                                  • Slide Number 40
                                                  • Slide Number 41
                                                  • Slide Number 42
                                                  • Slide Number 43
                                                  • Slide Number 44
                                                  • Slide Number 45
                                                  • Slide Number 46
                                                  • Slide Number 47
                                                  • Slide Number 48
                                                  • Slide Number 49
                                                  • Slide Number 50
                                                  • Slide Number 51
                                                  • Rare Earth Elements
                                                  • Crustal Abundances of Elements
                                                  • Occurrence
                                                  • Rare Earth Minerals
                                                  • REE Minerals
                                                  • Bastnesite
                                                  • Other REE minerals
                                                  • Electron Configuration
                                                  • Electron Configuartion
                                                  • REE Behavior
                                                  • Ionic Radius
                                                  • Coordination Number
                                                  • Coordination Number
                                                  • Other Factors
                                                  • REEs and Economics
                                                  • HREEs and Magnetism
                                                  • Applications in Magnetism
                                                  • Applications in Magnetism
                                                  • HREEs and Nuclear Technology
                                                  • HREEs and Nuclear Technology
                                                  • Mountain Pass
                                                  • Bayan Obo
                                                  • World Production
                                                  • Exploration
                                                  • Environmental Considerations
                                                  • REE Fertilizer
                                                  • Investigation by T Liang et al
                                                  • Implications
                                                  • Acid Mine Drainage (AMD)
                                                  • Radioactive Elements
                                                  • Radioactive Hazards
                                                  • Summary
                                                  • References

                                                    Cathodoluminescence

                                                    Macrograph of Iimoriite

                                                    in Syenite

                                                    ndash

                                                    Bokan

                                                    Mountain

                                                    Mottled light blue and tan clusters -

                                                    Iimoriite

                                                    Red groundmass ndash

                                                    Feldspar

                                                    (Horizontal distance of rock slab ndash 46 mm)

                                                    Iimoriite

                                                    (Y)

                                                    Y2 (SiO4 )(CO3 )

                                                    Yttrofluorite

                                                    (CaY)F2

                                                    Iimoriite

                                                    Concentrate ndash

                                                    Bokan

                                                    MT (1 mm scale)

                                                    Wicheeda

                                                    Lake Heavy Mineral Composite mdash

                                                    (from samples 828951 52 53)

                                                    These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                                    and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                                    As a final statement it should be emphasizedhellip

                                                    1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                                    2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                                    3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                                    4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                                    5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                                    Rare Earth Elements

                                                    bull

                                                    Name something of a misnomerndash

                                                    Rarest REEs

                                                    are over 200 times more

                                                    abundant then gold

                                                    bull

                                                    Variation in distribution for two reasons ndash

                                                    Compatibility with common rock forming materials

                                                    ndash

                                                    CosmicCrustal abundances

                                                    Crustal Abundances of Elements

                                                    Occurrencebull

                                                    REEs

                                                    occur mostly as

                                                    substitutional

                                                    impurities in many rock forming minerals

                                                    bull

                                                    Only a few the REE minerals have sufficient quantities to be considered important sources

                                                    bull

                                                    Defined as minerals having at least one site that is filled by REEs

                                                    andor Yttrium more often then any other elementMonazite

                                                    Rare Earth Minerals

                                                    bull

                                                    Form by primary crystalization

                                                    from magma or by hydrothermal reactions

                                                    bull

                                                    Found hosted in carbonate rocks in pegmatites

                                                    and as accessory minerals in

                                                    igneous rocks

                                                    bull

                                                    Stable REE minerals and can be concentrated in weathering zones

                                                    REE Mineralsbull

                                                    The most important REE minerals is bastnaumlsite

                                                    REE(CO3)F

                                                    bull

                                                    Other notable sources are ndash

                                                    Monazite REE(PO4) ndash

                                                    Xenotime

                                                    YPO4

                                                    bull

                                                    All may contain radioactive species such as thorium

                                                    and uraniumndash

                                                    are avoided as source materials

                                                    Bastnesitebull

                                                    Bastnasite

                                                    [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                    bull

                                                    Containing 60 to 70 rare earth oxides (REOs)

                                                    bull

                                                    REE site is most commonly filled by LREEs

                                                    and Y

                                                    Other REE mineralsbull

                                                    Monazite [(LREEYTh)PO4] ndash

                                                    Contains about 50ndash78 rare earth oxides

                                                    ndash

                                                    Forms in heavy mineral sands placer deposits associated with beach environments

                                                    bull

                                                    Xenotime

                                                    [(YPO4)] ndash

                                                    Contains 54ndash65 rare earth oxides

                                                    ndash

                                                    Yttrium Erbium and Cerium most common ndash

                                                    Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                    Electron Configuration

                                                    bull

                                                    The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                    bull

                                                    REEs

                                                    have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                    Electron Configuartion

                                                    REE Behaviorbull

                                                    Because of their shared behaviour REEs

                                                    tend to be

                                                    present in nature as a group All REEs

                                                    commonly substitute for one another in minerals

                                                    bull

                                                    Yet the REEs

                                                    are capable of showing great variation in their distributions

                                                    bull

                                                    Comes about due to ndash

                                                    Differences in ionic radius ndash

                                                    Crystal structure (Coordination Number)ndash

                                                    Basicity

                                                    of the mineral ndash

                                                    The elementrsquos solubility and ability to migrate in the environment ndash

                                                    Content of REEs

                                                    in source fluids

                                                    Ionic Radiusbull

                                                    The ionic radius of the REEs

                                                    is inversely related to atomic number

                                                    bull

                                                    The heavy rare earths are smaller ndash

                                                    more similar to Mn2+ (ionic radius 008 nanometers)

                                                    bull

                                                    LREEs

                                                    are largerndash

                                                    more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                    bull

                                                    Charge balance achieved through some sites being left vacant or

                                                    by coupled substitution with lower charged mineral (Na+)

                                                    In nanometers

                                                    Coordination Number

                                                    bull

                                                    Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                    bull

                                                    Coordination number for this structure is 8

                                                    Coordination Numberbull

                                                    The heavy and light REEs

                                                    differ in the coordination

                                                    numbers (CN) with oxygenndash

                                                    HREEs

                                                    have CN between six to nine ndash

                                                    LREEs

                                                    have higher CNs

                                                    bull

                                                    Minerals with high CNs

                                                    associated with REE site

                                                    will favor LREEsndash

                                                    Bastnasite

                                                    CN = 11 ndash

                                                    Monazite CN = 9

                                                    bull

                                                    Those with low CNs

                                                    will preferentially select HREEs ndash

                                                    Xenotime

                                                    has a value of 8

                                                    Other Factorsbull

                                                    Minerals basicityndash

                                                    Alkalic

                                                    rocks host minerals with elevated LREE content ndash

                                                    Rocks with lower basicity

                                                    have lower amounts of LREEs

                                                    relative to their HREE content

                                                    bull

                                                    Solubilityndash

                                                    LREEs

                                                    are more soluble in water then the HREEsndash

                                                    Important characteristic for hydrothermally derived minerals

                                                    bull

                                                    MagmaHydrothermal fluid compositionndash

                                                    Minerals will take what they can get

                                                    REEs

                                                    and Economicsbull

                                                    The REEs

                                                    and Yttrium have a very broad range of applications mostly in high technology fields

                                                    bull

                                                    84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                    bull

                                                    REEs

                                                    used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                    HREEs

                                                    and Magnetism

                                                    bull

                                                    HREEs

                                                    exhibit complex magnetic behaviour on account of electron structurendash

                                                    They share the same outer shell electron configuration (valence = +3)

                                                    ndash

                                                    Differ in number of 4f electrons

                                                    Applications in Magnetismbull

                                                    Terbium and

                                                    Dysprosium

                                                    bull

                                                    Components of Terfenol-D

                                                    alloy

                                                    with the formula Tb(03) Dy(07) Fe(19)

                                                    bull

                                                    Has the higher magnetostriction

                                                    then any other alloyndash

                                                    expands and contracts in magnetic field

                                                    bull

                                                    Developed by American Navy for sonar

                                                    systems ndash

                                                    Now has applications in magnetomechanical

                                                    sensors and other electronic devices

                                                    Applications in Magnetism

                                                    bull

                                                    Holmium

                                                    bull

                                                    Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                    elements

                                                    bull

                                                    Creates the strongest artificially generated magnetic fieldsndash

                                                    In research where strong magnetic fields are needed

                                                    HREEs

                                                    and Nuclear Technology

                                                    bull

                                                    Dysprosium Homium Erbium

                                                    bull

                                                    High neutron

                                                    absorption cross-section ndash

                                                    Measure of probability of neutron capture

                                                    bull

                                                    Used in neutron-absorbing control rods in nuclear reactors

                                                    HREEs

                                                    and Nuclear Technology

                                                    bull

                                                    Lutetiumbull

                                                    Radioactive isotope used in radiometric dating

                                                    bull

                                                    Thulium bull

                                                    Stable thulium used as a radiation

                                                    source

                                                    in portable X-ray

                                                    devices

                                                    Mountain Passbull

                                                    Bastnasite

                                                    is the major REE mineral bull

                                                    High grade accessory mineral of igneous or hydrothermal originsbull

                                                    31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                    Mining stopped in 1994 ndash

                                                    Thorium content of waste rock ndash

                                                    Availability of inexpensive REEs

                                                    from China

                                                    San Bernardino County

                                                    Bayan

                                                    Obobull

                                                    The worldrsquos primary source for both yttrium and the rare earth elements

                                                    bull

                                                    37 million tons of ore bull

                                                    Main REE source there is Bastnasite

                                                    World Production

                                                    Explorationbull

                                                    84 of REE imports to US are from China

                                                    bull

                                                    Increasing demand for high tech applications spurred increase in exploration in 2007

                                                    bull

                                                    Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                    Lake as well as in

                                                    Malawi Africa

                                                    Environmental Considerations

                                                    bull

                                                    REE soil and food contaminationbull

                                                    Acid Mine Drainage and groundwater systems

                                                    bull

                                                    Radioactive elements

                                                    REE Fertilizerbull

                                                    In China REE enriched fertilizer has been used in crop fields since 1990

                                                    bull

                                                    At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                    every year

                                                    bull

                                                    Research and agricultural practice that provides evidence that REEs

                                                    will improve crop quality an yield

                                                    bull

                                                    The ramifications environmental and human exposure to REEs

                                                    are not well understood

                                                    Investigation by T Liang et albull

                                                    Revealed that the average concentration of total REEs

                                                    in Chinese soil is

                                                    1768 mgkg ranging between 850 to 5227 mgkg

                                                    bull

                                                    In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                    Implicationsbull

                                                    Human health effects not completely understood

                                                    bull

                                                    REE soil content shown to be detrimental to some plant speciesndash

                                                    100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                    Acid Mine Drainage (AMD)bull

                                                    Rain waters contacts waste rock facilitating acid forming reactions

                                                    bull

                                                    Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                    bull

                                                    Process mobilizes established ecotoxins

                                                    (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                    bull

                                                    Historically dismissed as minor environmental risk

                                                    Radioactive Elements

                                                    bull

                                                    REEs

                                                    associated with uranium and thorium

                                                    bull

                                                    Bastnesite 32 thorium

                                                    bull

                                                    Monazite sands 6 to 12 thorium oxide

                                                    bull

                                                    Ores containing radioactive elements are avoided as sources of REEs

                                                    Radioactive Hazardsbull

                                                    Mountain Pass

                                                    bull

                                                    Accidentsndash

                                                    In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                    bull

                                                    Health Effectsndash

                                                    inflammatory bowel disease ndash

                                                    Prolonged seizures ndash

                                                    Cysts ndash

                                                    Cancers

                                                    bull

                                                    Waste Disposal ndash

                                                    Yucca Mountain

                                                    Summarybull

                                                    REE concentrations in the crust are rare

                                                    bull

                                                    Several geochemical factors influencing distribution including ionic radius and coordination number

                                                    bull

                                                    Main REE minerals are bastnasite monazite and xenotime

                                                    bull

                                                    Most important deposits are found at Bayan

                                                    Obo China and Mountain Pass USA

                                                    bull

                                                    Important electronic and nuclear applications

                                                    bull

                                                    Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                    system contamination though acid mine drainage association with

                                                    radioactive elements

                                                    Referencesbull

                                                    E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                    bull

                                                    Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                    bull

                                                    G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                    bull

                                                    B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                    The Government of South Australia wwwpirsagovaubull

                                                    The US geological Survey Mineralsusgsgovbull

                                                    wwwelementsdatabasecombull

                                                    wwwastrolsaumichedu~cowleyintro2htmlbull

                                                    wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                    webmineralcomdataMonazite-(Ce)shtmlbull

                                                    wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                    wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                    wwwchemicalelementscomelementseuhtmlbull

                                                    boomeriaorgchemlecturestextass2table10-9jpgbull

                                                    lostcontentquakecomfiles200802holmiumpngbull

                                                    chinageocitylocatorcomcitiesChinaQinghaibull

                                                    geowebrudruzal-Bayan-Obohtmbull

                                                    enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                    wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                    enwikipediaorgwikiMonazitebull

                                                    webmineralcomdataBastnasite-(La)shtmlbull

                                                    wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                    httpwwwavalonventurescombull

                                                    wwwnewsweekcomid43884bull

                                                    httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                    httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                    • Slide Number 1
                                                    • Slide Number 2
                                                    • Slide Number 3
                                                    • Slide Number 4
                                                    • Slide Number 5
                                                    • Slide Number 6
                                                    • Slide Number 7
                                                    • Slide Number 8
                                                    • Slide Number 9
                                                    • Slide Number 10
                                                    • Slide Number 11
                                                    • Slide Number 12
                                                    • Slide Number 13
                                                    • Slide Number 14
                                                    • Slide Number 15
                                                    • Slide Number 16
                                                    • Slide Number 17
                                                    • Slide Number 18
                                                    • Slide Number 19
                                                    • Slide Number 20
                                                    • Slide Number 21
                                                    • Slide Number 22
                                                    • Slide Number 23
                                                    • Slide Number 24
                                                    • Slide Number 25
                                                    • Slide Number 26
                                                    • Slide Number 27
                                                    • Slide Number 28
                                                    • Slide Number 29
                                                    • Slide Number 30
                                                    • Slide Number 31
                                                    • Slide Number 32
                                                    • Slide Number 33
                                                    • Slide Number 34
                                                    • Slide Number 35
                                                    • Slide Number 36
                                                    • Slide Number 37
                                                    • Slide Number 38
                                                    • Slide Number 39
                                                    • Slide Number 40
                                                    • Slide Number 41
                                                    • Slide Number 42
                                                    • Slide Number 43
                                                    • Slide Number 44
                                                    • Slide Number 45
                                                    • Slide Number 46
                                                    • Slide Number 47
                                                    • Slide Number 48
                                                    • Slide Number 49
                                                    • Slide Number 50
                                                    • Slide Number 51
                                                    • Rare Earth Elements
                                                    • Crustal Abundances of Elements
                                                    • Occurrence
                                                    • Rare Earth Minerals
                                                    • REE Minerals
                                                    • Bastnesite
                                                    • Other REE minerals
                                                    • Electron Configuration
                                                    • Electron Configuartion
                                                    • REE Behavior
                                                    • Ionic Radius
                                                    • Coordination Number
                                                    • Coordination Number
                                                    • Other Factors
                                                    • REEs and Economics
                                                    • HREEs and Magnetism
                                                    • Applications in Magnetism
                                                    • Applications in Magnetism
                                                    • HREEs and Nuclear Technology
                                                    • HREEs and Nuclear Technology
                                                    • Mountain Pass
                                                    • Bayan Obo
                                                    • World Production
                                                    • Exploration
                                                    • Environmental Considerations
                                                    • REE Fertilizer
                                                    • Investigation by T Liang et al
                                                    • Implications
                                                    • Acid Mine Drainage (AMD)
                                                    • Radioactive Elements
                                                    • Radioactive Hazards
                                                    • Summary
                                                    • References

                                                      Iimoriite

                                                      (Y)

                                                      Y2 (SiO4 )(CO3 )

                                                      Yttrofluorite

                                                      (CaY)F2

                                                      Iimoriite

                                                      Concentrate ndash

                                                      Bokan

                                                      MT (1 mm scale)

                                                      Wicheeda

                                                      Lake Heavy Mineral Composite mdash

                                                      (from samples 828951 52 53)

                                                      These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                                      and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                                      As a final statement it should be emphasizedhellip

                                                      1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                                      2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                                      3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                                      4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                                      5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                                      Rare Earth Elements

                                                      bull

                                                      Name something of a misnomerndash

                                                      Rarest REEs

                                                      are over 200 times more

                                                      abundant then gold

                                                      bull

                                                      Variation in distribution for two reasons ndash

                                                      Compatibility with common rock forming materials

                                                      ndash

                                                      CosmicCrustal abundances

                                                      Crustal Abundances of Elements

                                                      Occurrencebull

                                                      REEs

                                                      occur mostly as

                                                      substitutional

                                                      impurities in many rock forming minerals

                                                      bull

                                                      Only a few the REE minerals have sufficient quantities to be considered important sources

                                                      bull

                                                      Defined as minerals having at least one site that is filled by REEs

                                                      andor Yttrium more often then any other elementMonazite

                                                      Rare Earth Minerals

                                                      bull

                                                      Form by primary crystalization

                                                      from magma or by hydrothermal reactions

                                                      bull

                                                      Found hosted in carbonate rocks in pegmatites

                                                      and as accessory minerals in

                                                      igneous rocks

                                                      bull

                                                      Stable REE minerals and can be concentrated in weathering zones

                                                      REE Mineralsbull

                                                      The most important REE minerals is bastnaumlsite

                                                      REE(CO3)F

                                                      bull

                                                      Other notable sources are ndash

                                                      Monazite REE(PO4) ndash

                                                      Xenotime

                                                      YPO4

                                                      bull

                                                      All may contain radioactive species such as thorium

                                                      and uraniumndash

                                                      are avoided as source materials

                                                      Bastnesitebull

                                                      Bastnasite

                                                      [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                      bull

                                                      Containing 60 to 70 rare earth oxides (REOs)

                                                      bull

                                                      REE site is most commonly filled by LREEs

                                                      and Y

                                                      Other REE mineralsbull

                                                      Monazite [(LREEYTh)PO4] ndash

                                                      Contains about 50ndash78 rare earth oxides

                                                      ndash

                                                      Forms in heavy mineral sands placer deposits associated with beach environments

                                                      bull

                                                      Xenotime

                                                      [(YPO4)] ndash

                                                      Contains 54ndash65 rare earth oxides

                                                      ndash

                                                      Yttrium Erbium and Cerium most common ndash

                                                      Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                      Electron Configuration

                                                      bull

                                                      The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                      bull

                                                      REEs

                                                      have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                      Electron Configuartion

                                                      REE Behaviorbull

                                                      Because of their shared behaviour REEs

                                                      tend to be

                                                      present in nature as a group All REEs

                                                      commonly substitute for one another in minerals

                                                      bull

                                                      Yet the REEs

                                                      are capable of showing great variation in their distributions

                                                      bull

                                                      Comes about due to ndash

                                                      Differences in ionic radius ndash

                                                      Crystal structure (Coordination Number)ndash

                                                      Basicity

                                                      of the mineral ndash

                                                      The elementrsquos solubility and ability to migrate in the environment ndash

                                                      Content of REEs

                                                      in source fluids

                                                      Ionic Radiusbull

                                                      The ionic radius of the REEs

                                                      is inversely related to atomic number

                                                      bull

                                                      The heavy rare earths are smaller ndash

                                                      more similar to Mn2+ (ionic radius 008 nanometers)

                                                      bull

                                                      LREEs

                                                      are largerndash

                                                      more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                      bull

                                                      Charge balance achieved through some sites being left vacant or

                                                      by coupled substitution with lower charged mineral (Na+)

                                                      In nanometers

                                                      Coordination Number

                                                      bull

                                                      Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                      bull

                                                      Coordination number for this structure is 8

                                                      Coordination Numberbull

                                                      The heavy and light REEs

                                                      differ in the coordination

                                                      numbers (CN) with oxygenndash

                                                      HREEs

                                                      have CN between six to nine ndash

                                                      LREEs

                                                      have higher CNs

                                                      bull

                                                      Minerals with high CNs

                                                      associated with REE site

                                                      will favor LREEsndash

                                                      Bastnasite

                                                      CN = 11 ndash

                                                      Monazite CN = 9

                                                      bull

                                                      Those with low CNs

                                                      will preferentially select HREEs ndash

                                                      Xenotime

                                                      has a value of 8

                                                      Other Factorsbull

                                                      Minerals basicityndash

                                                      Alkalic

                                                      rocks host minerals with elevated LREE content ndash

                                                      Rocks with lower basicity

                                                      have lower amounts of LREEs

                                                      relative to their HREE content

                                                      bull

                                                      Solubilityndash

                                                      LREEs

                                                      are more soluble in water then the HREEsndash

                                                      Important characteristic for hydrothermally derived minerals

                                                      bull

                                                      MagmaHydrothermal fluid compositionndash

                                                      Minerals will take what they can get

                                                      REEs

                                                      and Economicsbull

                                                      The REEs

                                                      and Yttrium have a very broad range of applications mostly in high technology fields

                                                      bull

                                                      84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                      bull

                                                      REEs

                                                      used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                      HREEs

                                                      and Magnetism

                                                      bull

                                                      HREEs

                                                      exhibit complex magnetic behaviour on account of electron structurendash

                                                      They share the same outer shell electron configuration (valence = +3)

                                                      ndash

                                                      Differ in number of 4f electrons

                                                      Applications in Magnetismbull

                                                      Terbium and

                                                      Dysprosium

                                                      bull

                                                      Components of Terfenol-D

                                                      alloy

                                                      with the formula Tb(03) Dy(07) Fe(19)

                                                      bull

                                                      Has the higher magnetostriction

                                                      then any other alloyndash

                                                      expands and contracts in magnetic field

                                                      bull

                                                      Developed by American Navy for sonar

                                                      systems ndash

                                                      Now has applications in magnetomechanical

                                                      sensors and other electronic devices

                                                      Applications in Magnetism

                                                      bull

                                                      Holmium

                                                      bull

                                                      Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                      elements

                                                      bull

                                                      Creates the strongest artificially generated magnetic fieldsndash

                                                      In research where strong magnetic fields are needed

                                                      HREEs

                                                      and Nuclear Technology

                                                      bull

                                                      Dysprosium Homium Erbium

                                                      bull

                                                      High neutron

                                                      absorption cross-section ndash

                                                      Measure of probability of neutron capture

                                                      bull

                                                      Used in neutron-absorbing control rods in nuclear reactors

                                                      HREEs

                                                      and Nuclear Technology

                                                      bull

                                                      Lutetiumbull

                                                      Radioactive isotope used in radiometric dating

                                                      bull

                                                      Thulium bull

                                                      Stable thulium used as a radiation

                                                      source

                                                      in portable X-ray

                                                      devices

                                                      Mountain Passbull

                                                      Bastnasite

                                                      is the major REE mineral bull

                                                      High grade accessory mineral of igneous or hydrothermal originsbull

                                                      31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                      Mining stopped in 1994 ndash

                                                      Thorium content of waste rock ndash

                                                      Availability of inexpensive REEs

                                                      from China

                                                      San Bernardino County

                                                      Bayan

                                                      Obobull

                                                      The worldrsquos primary source for both yttrium and the rare earth elements

                                                      bull

                                                      37 million tons of ore bull

                                                      Main REE source there is Bastnasite

                                                      World Production

                                                      Explorationbull

                                                      84 of REE imports to US are from China

                                                      bull

                                                      Increasing demand for high tech applications spurred increase in exploration in 2007

                                                      bull

                                                      Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                      Lake as well as in

                                                      Malawi Africa

                                                      Environmental Considerations

                                                      bull

                                                      REE soil and food contaminationbull

                                                      Acid Mine Drainage and groundwater systems

                                                      bull

                                                      Radioactive elements

                                                      REE Fertilizerbull

                                                      In China REE enriched fertilizer has been used in crop fields since 1990

                                                      bull

                                                      At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                      every year

                                                      bull

                                                      Research and agricultural practice that provides evidence that REEs

                                                      will improve crop quality an yield

                                                      bull

                                                      The ramifications environmental and human exposure to REEs

                                                      are not well understood

                                                      Investigation by T Liang et albull

                                                      Revealed that the average concentration of total REEs

                                                      in Chinese soil is

                                                      1768 mgkg ranging between 850 to 5227 mgkg

                                                      bull

                                                      In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                      Implicationsbull

                                                      Human health effects not completely understood

                                                      bull

                                                      REE soil content shown to be detrimental to some plant speciesndash

                                                      100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                      Acid Mine Drainage (AMD)bull

                                                      Rain waters contacts waste rock facilitating acid forming reactions

                                                      bull

                                                      Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                      bull

                                                      Process mobilizes established ecotoxins

                                                      (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                      bull

                                                      Historically dismissed as minor environmental risk

                                                      Radioactive Elements

                                                      bull

                                                      REEs

                                                      associated with uranium and thorium

                                                      bull

                                                      Bastnesite 32 thorium

                                                      bull

                                                      Monazite sands 6 to 12 thorium oxide

                                                      bull

                                                      Ores containing radioactive elements are avoided as sources of REEs

                                                      Radioactive Hazardsbull

                                                      Mountain Pass

                                                      bull

                                                      Accidentsndash

                                                      In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                      bull

                                                      Health Effectsndash

                                                      inflammatory bowel disease ndash

                                                      Prolonged seizures ndash

                                                      Cysts ndash

                                                      Cancers

                                                      bull

                                                      Waste Disposal ndash

                                                      Yucca Mountain

                                                      Summarybull

                                                      REE concentrations in the crust are rare

                                                      bull

                                                      Several geochemical factors influencing distribution including ionic radius and coordination number

                                                      bull

                                                      Main REE minerals are bastnasite monazite and xenotime

                                                      bull

                                                      Most important deposits are found at Bayan

                                                      Obo China and Mountain Pass USA

                                                      bull

                                                      Important electronic and nuclear applications

                                                      bull

                                                      Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                      system contamination though acid mine drainage association with

                                                      radioactive elements

                                                      Referencesbull

                                                      E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                      bull

                                                      Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                      bull

                                                      G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                      bull

                                                      B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                      The Government of South Australia wwwpirsagovaubull

                                                      The US geological Survey Mineralsusgsgovbull

                                                      wwwelementsdatabasecombull

                                                      wwwastrolsaumichedu~cowleyintro2htmlbull

                                                      wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                      webmineralcomdataMonazite-(Ce)shtmlbull

                                                      wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                      wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                      wwwchemicalelementscomelementseuhtmlbull

                                                      boomeriaorgchemlecturestextass2table10-9jpgbull

                                                      lostcontentquakecomfiles200802holmiumpngbull

                                                      chinageocitylocatorcomcitiesChinaQinghaibull

                                                      geowebrudruzal-Bayan-Obohtmbull

                                                      enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                      wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                      enwikipediaorgwikiMonazitebull

                                                      webmineralcomdataBastnasite-(La)shtmlbull

                                                      wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                      httpwwwavalonventurescombull

                                                      wwwnewsweekcomid43884bull

                                                      httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                      httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                      • Slide Number 1
                                                      • Slide Number 2
                                                      • Slide Number 3
                                                      • Slide Number 4
                                                      • Slide Number 5
                                                      • Slide Number 6
                                                      • Slide Number 7
                                                      • Slide Number 8
                                                      • Slide Number 9
                                                      • Slide Number 10
                                                      • Slide Number 11
                                                      • Slide Number 12
                                                      • Slide Number 13
                                                      • Slide Number 14
                                                      • Slide Number 15
                                                      • Slide Number 16
                                                      • Slide Number 17
                                                      • Slide Number 18
                                                      • Slide Number 19
                                                      • Slide Number 20
                                                      • Slide Number 21
                                                      • Slide Number 22
                                                      • Slide Number 23
                                                      • Slide Number 24
                                                      • Slide Number 25
                                                      • Slide Number 26
                                                      • Slide Number 27
                                                      • Slide Number 28
                                                      • Slide Number 29
                                                      • Slide Number 30
                                                      • Slide Number 31
                                                      • Slide Number 32
                                                      • Slide Number 33
                                                      • Slide Number 34
                                                      • Slide Number 35
                                                      • Slide Number 36
                                                      • Slide Number 37
                                                      • Slide Number 38
                                                      • Slide Number 39
                                                      • Slide Number 40
                                                      • Slide Number 41
                                                      • Slide Number 42
                                                      • Slide Number 43
                                                      • Slide Number 44
                                                      • Slide Number 45
                                                      • Slide Number 46
                                                      • Slide Number 47
                                                      • Slide Number 48
                                                      • Slide Number 49
                                                      • Slide Number 50
                                                      • Slide Number 51
                                                      • Rare Earth Elements
                                                      • Crustal Abundances of Elements
                                                      • Occurrence
                                                      • Rare Earth Minerals
                                                      • REE Minerals
                                                      • Bastnesite
                                                      • Other REE minerals
                                                      • Electron Configuration
                                                      • Electron Configuartion
                                                      • REE Behavior
                                                      • Ionic Radius
                                                      • Coordination Number
                                                      • Coordination Number
                                                      • Other Factors
                                                      • REEs and Economics
                                                      • HREEs and Magnetism
                                                      • Applications in Magnetism
                                                      • Applications in Magnetism
                                                      • HREEs and Nuclear Technology
                                                      • HREEs and Nuclear Technology
                                                      • Mountain Pass
                                                      • Bayan Obo
                                                      • World Production
                                                      • Exploration
                                                      • Environmental Considerations
                                                      • REE Fertilizer
                                                      • Investigation by T Liang et al
                                                      • Implications
                                                      • Acid Mine Drainage (AMD)
                                                      • Radioactive Elements
                                                      • Radioactive Hazards
                                                      • Summary
                                                      • References

                                                        Iimoriite

                                                        Concentrate ndash

                                                        Bokan

                                                        MT (1 mm scale)

                                                        Wicheeda

                                                        Lake Heavy Mineral Composite mdash

                                                        (from samples 828951 52 53)

                                                        These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                                        and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                                        As a final statement it should be emphasizedhellip

                                                        1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                                        2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                                        3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                                        4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                                        5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                                        Rare Earth Elements

                                                        bull

                                                        Name something of a misnomerndash

                                                        Rarest REEs

                                                        are over 200 times more

                                                        abundant then gold

                                                        bull

                                                        Variation in distribution for two reasons ndash

                                                        Compatibility with common rock forming materials

                                                        ndash

                                                        CosmicCrustal abundances

                                                        Crustal Abundances of Elements

                                                        Occurrencebull

                                                        REEs

                                                        occur mostly as

                                                        substitutional

                                                        impurities in many rock forming minerals

                                                        bull

                                                        Only a few the REE minerals have sufficient quantities to be considered important sources

                                                        bull

                                                        Defined as minerals having at least one site that is filled by REEs

                                                        andor Yttrium more often then any other elementMonazite

                                                        Rare Earth Minerals

                                                        bull

                                                        Form by primary crystalization

                                                        from magma or by hydrothermal reactions

                                                        bull

                                                        Found hosted in carbonate rocks in pegmatites

                                                        and as accessory minerals in

                                                        igneous rocks

                                                        bull

                                                        Stable REE minerals and can be concentrated in weathering zones

                                                        REE Mineralsbull

                                                        The most important REE minerals is bastnaumlsite

                                                        REE(CO3)F

                                                        bull

                                                        Other notable sources are ndash

                                                        Monazite REE(PO4) ndash

                                                        Xenotime

                                                        YPO4

                                                        bull

                                                        All may contain radioactive species such as thorium

                                                        and uraniumndash

                                                        are avoided as source materials

                                                        Bastnesitebull

                                                        Bastnasite

                                                        [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                        bull

                                                        Containing 60 to 70 rare earth oxides (REOs)

                                                        bull

                                                        REE site is most commonly filled by LREEs

                                                        and Y

                                                        Other REE mineralsbull

                                                        Monazite [(LREEYTh)PO4] ndash

                                                        Contains about 50ndash78 rare earth oxides

                                                        ndash

                                                        Forms in heavy mineral sands placer deposits associated with beach environments

                                                        bull

                                                        Xenotime

                                                        [(YPO4)] ndash

                                                        Contains 54ndash65 rare earth oxides

                                                        ndash

                                                        Yttrium Erbium and Cerium most common ndash

                                                        Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                        Electron Configuration

                                                        bull

                                                        The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                        bull

                                                        REEs

                                                        have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                        Electron Configuartion

                                                        REE Behaviorbull

                                                        Because of their shared behaviour REEs

                                                        tend to be

                                                        present in nature as a group All REEs

                                                        commonly substitute for one another in minerals

                                                        bull

                                                        Yet the REEs

                                                        are capable of showing great variation in their distributions

                                                        bull

                                                        Comes about due to ndash

                                                        Differences in ionic radius ndash

                                                        Crystal structure (Coordination Number)ndash

                                                        Basicity

                                                        of the mineral ndash

                                                        The elementrsquos solubility and ability to migrate in the environment ndash

                                                        Content of REEs

                                                        in source fluids

                                                        Ionic Radiusbull

                                                        The ionic radius of the REEs

                                                        is inversely related to atomic number

                                                        bull

                                                        The heavy rare earths are smaller ndash

                                                        more similar to Mn2+ (ionic radius 008 nanometers)

                                                        bull

                                                        LREEs

                                                        are largerndash

                                                        more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                        bull

                                                        Charge balance achieved through some sites being left vacant or

                                                        by coupled substitution with lower charged mineral (Na+)

                                                        In nanometers

                                                        Coordination Number

                                                        bull

                                                        Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                        bull

                                                        Coordination number for this structure is 8

                                                        Coordination Numberbull

                                                        The heavy and light REEs

                                                        differ in the coordination

                                                        numbers (CN) with oxygenndash

                                                        HREEs

                                                        have CN between six to nine ndash

                                                        LREEs

                                                        have higher CNs

                                                        bull

                                                        Minerals with high CNs

                                                        associated with REE site

                                                        will favor LREEsndash

                                                        Bastnasite

                                                        CN = 11 ndash

                                                        Monazite CN = 9

                                                        bull

                                                        Those with low CNs

                                                        will preferentially select HREEs ndash

                                                        Xenotime

                                                        has a value of 8

                                                        Other Factorsbull

                                                        Minerals basicityndash

                                                        Alkalic

                                                        rocks host minerals with elevated LREE content ndash

                                                        Rocks with lower basicity

                                                        have lower amounts of LREEs

                                                        relative to their HREE content

                                                        bull

                                                        Solubilityndash

                                                        LREEs

                                                        are more soluble in water then the HREEsndash

                                                        Important characteristic for hydrothermally derived minerals

                                                        bull

                                                        MagmaHydrothermal fluid compositionndash

                                                        Minerals will take what they can get

                                                        REEs

                                                        and Economicsbull

                                                        The REEs

                                                        and Yttrium have a very broad range of applications mostly in high technology fields

                                                        bull

                                                        84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                        bull

                                                        REEs

                                                        used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                        HREEs

                                                        and Magnetism

                                                        bull

                                                        HREEs

                                                        exhibit complex magnetic behaviour on account of electron structurendash

                                                        They share the same outer shell electron configuration (valence = +3)

                                                        ndash

                                                        Differ in number of 4f electrons

                                                        Applications in Magnetismbull

                                                        Terbium and

                                                        Dysprosium

                                                        bull

                                                        Components of Terfenol-D

                                                        alloy

                                                        with the formula Tb(03) Dy(07) Fe(19)

                                                        bull

                                                        Has the higher magnetostriction

                                                        then any other alloyndash

                                                        expands and contracts in magnetic field

                                                        bull

                                                        Developed by American Navy for sonar

                                                        systems ndash

                                                        Now has applications in magnetomechanical

                                                        sensors and other electronic devices

                                                        Applications in Magnetism

                                                        bull

                                                        Holmium

                                                        bull

                                                        Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                        elements

                                                        bull

                                                        Creates the strongest artificially generated magnetic fieldsndash

                                                        In research where strong magnetic fields are needed

                                                        HREEs

                                                        and Nuclear Technology

                                                        bull

                                                        Dysprosium Homium Erbium

                                                        bull

                                                        High neutron

                                                        absorption cross-section ndash

                                                        Measure of probability of neutron capture

                                                        bull

                                                        Used in neutron-absorbing control rods in nuclear reactors

                                                        HREEs

                                                        and Nuclear Technology

                                                        bull

                                                        Lutetiumbull

                                                        Radioactive isotope used in radiometric dating

                                                        bull

                                                        Thulium bull

                                                        Stable thulium used as a radiation

                                                        source

                                                        in portable X-ray

                                                        devices

                                                        Mountain Passbull

                                                        Bastnasite

                                                        is the major REE mineral bull

                                                        High grade accessory mineral of igneous or hydrothermal originsbull

                                                        31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                        Mining stopped in 1994 ndash

                                                        Thorium content of waste rock ndash

                                                        Availability of inexpensive REEs

                                                        from China

                                                        San Bernardino County

                                                        Bayan

                                                        Obobull

                                                        The worldrsquos primary source for both yttrium and the rare earth elements

                                                        bull

                                                        37 million tons of ore bull

                                                        Main REE source there is Bastnasite

                                                        World Production

                                                        Explorationbull

                                                        84 of REE imports to US are from China

                                                        bull

                                                        Increasing demand for high tech applications spurred increase in exploration in 2007

                                                        bull

                                                        Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                        Lake as well as in

                                                        Malawi Africa

                                                        Environmental Considerations

                                                        bull

                                                        REE soil and food contaminationbull

                                                        Acid Mine Drainage and groundwater systems

                                                        bull

                                                        Radioactive elements

                                                        REE Fertilizerbull

                                                        In China REE enriched fertilizer has been used in crop fields since 1990

                                                        bull

                                                        At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                        every year

                                                        bull

                                                        Research and agricultural practice that provides evidence that REEs

                                                        will improve crop quality an yield

                                                        bull

                                                        The ramifications environmental and human exposure to REEs

                                                        are not well understood

                                                        Investigation by T Liang et albull

                                                        Revealed that the average concentration of total REEs

                                                        in Chinese soil is

                                                        1768 mgkg ranging between 850 to 5227 mgkg

                                                        bull

                                                        In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                        Implicationsbull

                                                        Human health effects not completely understood

                                                        bull

                                                        REE soil content shown to be detrimental to some plant speciesndash

                                                        100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                        Acid Mine Drainage (AMD)bull

                                                        Rain waters contacts waste rock facilitating acid forming reactions

                                                        bull

                                                        Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                        bull

                                                        Process mobilizes established ecotoxins

                                                        (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                        bull

                                                        Historically dismissed as minor environmental risk

                                                        Radioactive Elements

                                                        bull

                                                        REEs

                                                        associated with uranium and thorium

                                                        bull

                                                        Bastnesite 32 thorium

                                                        bull

                                                        Monazite sands 6 to 12 thorium oxide

                                                        bull

                                                        Ores containing radioactive elements are avoided as sources of REEs

                                                        Radioactive Hazardsbull

                                                        Mountain Pass

                                                        bull

                                                        Accidentsndash

                                                        In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                        bull

                                                        Health Effectsndash

                                                        inflammatory bowel disease ndash

                                                        Prolonged seizures ndash

                                                        Cysts ndash

                                                        Cancers

                                                        bull

                                                        Waste Disposal ndash

                                                        Yucca Mountain

                                                        Summarybull

                                                        REE concentrations in the crust are rare

                                                        bull

                                                        Several geochemical factors influencing distribution including ionic radius and coordination number

                                                        bull

                                                        Main REE minerals are bastnasite monazite and xenotime

                                                        bull

                                                        Most important deposits are found at Bayan

                                                        Obo China and Mountain Pass USA

                                                        bull

                                                        Important electronic and nuclear applications

                                                        bull

                                                        Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                        system contamination though acid mine drainage association with

                                                        radioactive elements

                                                        Referencesbull

                                                        E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                        bull

                                                        Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                        bull

                                                        G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                        bull

                                                        B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                        The Government of South Australia wwwpirsagovaubull

                                                        The US geological Survey Mineralsusgsgovbull

                                                        wwwelementsdatabasecombull

                                                        wwwastrolsaumichedu~cowleyintro2htmlbull

                                                        wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                        webmineralcomdataMonazite-(Ce)shtmlbull

                                                        wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                        wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                        wwwchemicalelementscomelementseuhtmlbull

                                                        boomeriaorgchemlecturestextass2table10-9jpgbull

                                                        lostcontentquakecomfiles200802holmiumpngbull

                                                        chinageocitylocatorcomcitiesChinaQinghaibull

                                                        geowebrudruzal-Bayan-Obohtmbull

                                                        enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                        wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                        enwikipediaorgwikiMonazitebull

                                                        webmineralcomdataBastnasite-(La)shtmlbull

                                                        wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                        httpwwwavalonventurescombull

                                                        wwwnewsweekcomid43884bull

                                                        httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                        httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                        • Slide Number 1
                                                        • Slide Number 2
                                                        • Slide Number 3
                                                        • Slide Number 4
                                                        • Slide Number 5
                                                        • Slide Number 6
                                                        • Slide Number 7
                                                        • Slide Number 8
                                                        • Slide Number 9
                                                        • Slide Number 10
                                                        • Slide Number 11
                                                        • Slide Number 12
                                                        • Slide Number 13
                                                        • Slide Number 14
                                                        • Slide Number 15
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                                                        • Slide Number 17
                                                        • Slide Number 18
                                                        • Slide Number 19
                                                        • Slide Number 20
                                                        • Slide Number 21
                                                        • Slide Number 22
                                                        • Slide Number 23
                                                        • Slide Number 24
                                                        • Slide Number 25
                                                        • Slide Number 26
                                                        • Slide Number 27
                                                        • Slide Number 28
                                                        • Slide Number 29
                                                        • Slide Number 30
                                                        • Slide Number 31
                                                        • Slide Number 32
                                                        • Slide Number 33
                                                        • Slide Number 34
                                                        • Slide Number 35
                                                        • Slide Number 36
                                                        • Slide Number 37
                                                        • Slide Number 38
                                                        • Slide Number 39
                                                        • Slide Number 40
                                                        • Slide Number 41
                                                        • Slide Number 42
                                                        • Slide Number 43
                                                        • Slide Number 44
                                                        • Slide Number 45
                                                        • Slide Number 46
                                                        • Slide Number 47
                                                        • Slide Number 48
                                                        • Slide Number 49
                                                        • Slide Number 50
                                                        • Slide Number 51
                                                        • Rare Earth Elements
                                                        • Crustal Abundances of Elements
                                                        • Occurrence
                                                        • Rare Earth Minerals
                                                        • REE Minerals
                                                        • Bastnesite
                                                        • Other REE minerals
                                                        • Electron Configuration
                                                        • Electron Configuartion
                                                        • REE Behavior
                                                        • Ionic Radius
                                                        • Coordination Number
                                                        • Coordination Number
                                                        • Other Factors
                                                        • REEs and Economics
                                                        • HREEs and Magnetism
                                                        • Applications in Magnetism
                                                        • Applications in Magnetism
                                                        • HREEs and Nuclear Technology
                                                        • HREEs and Nuclear Technology
                                                        • Mountain Pass
                                                        • Bayan Obo
                                                        • World Production
                                                        • Exploration
                                                        • Environmental Considerations
                                                        • REE Fertilizer
                                                        • Investigation by T Liang et al
                                                        • Implications
                                                        • Acid Mine Drainage (AMD)
                                                        • Radioactive Elements
                                                        • Radioactive Hazards
                                                        • Summary
                                                        • References

                                                          Wicheeda

                                                          Lake Heavy Mineral Composite mdash

                                                          (from samples 828951 52 53)

                                                          These grains range in size between 02 and 05 mm The left micrograph consists of major monazite and parisite

                                                          and minor grains of pyrite Dolomite is also attached to some of these grains The right micrograph shows selective reflection of the green part of the visible spectrum under unfiltered shortwave UV examination This test is diagnostic for the identification of LREE minerals

                                                          As a final statement it should be emphasizedhellip

                                                          1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                                          2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                                          3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                                          4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                                          5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                                          Rare Earth Elements

                                                          bull

                                                          Name something of a misnomerndash

                                                          Rarest REEs

                                                          are over 200 times more

                                                          abundant then gold

                                                          bull

                                                          Variation in distribution for two reasons ndash

                                                          Compatibility with common rock forming materials

                                                          ndash

                                                          CosmicCrustal abundances

                                                          Crustal Abundances of Elements

                                                          Occurrencebull

                                                          REEs

                                                          occur mostly as

                                                          substitutional

                                                          impurities in many rock forming minerals

                                                          bull

                                                          Only a few the REE minerals have sufficient quantities to be considered important sources

                                                          bull

                                                          Defined as minerals having at least one site that is filled by REEs

                                                          andor Yttrium more often then any other elementMonazite

                                                          Rare Earth Minerals

                                                          bull

                                                          Form by primary crystalization

                                                          from magma or by hydrothermal reactions

                                                          bull

                                                          Found hosted in carbonate rocks in pegmatites

                                                          and as accessory minerals in

                                                          igneous rocks

                                                          bull

                                                          Stable REE minerals and can be concentrated in weathering zones

                                                          REE Mineralsbull

                                                          The most important REE minerals is bastnaumlsite

                                                          REE(CO3)F

                                                          bull

                                                          Other notable sources are ndash

                                                          Monazite REE(PO4) ndash

                                                          Xenotime

                                                          YPO4

                                                          bull

                                                          All may contain radioactive species such as thorium

                                                          and uraniumndash

                                                          are avoided as source materials

                                                          Bastnesitebull

                                                          Bastnasite

                                                          [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                          bull

                                                          Containing 60 to 70 rare earth oxides (REOs)

                                                          bull

                                                          REE site is most commonly filled by LREEs

                                                          and Y

                                                          Other REE mineralsbull

                                                          Monazite [(LREEYTh)PO4] ndash

                                                          Contains about 50ndash78 rare earth oxides

                                                          ndash

                                                          Forms in heavy mineral sands placer deposits associated with beach environments

                                                          bull

                                                          Xenotime

                                                          [(YPO4)] ndash

                                                          Contains 54ndash65 rare earth oxides

                                                          ndash

                                                          Yttrium Erbium and Cerium most common ndash

                                                          Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                          Electron Configuration

                                                          bull

                                                          The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                          bull

                                                          REEs

                                                          have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                          Electron Configuartion

                                                          REE Behaviorbull

                                                          Because of their shared behaviour REEs

                                                          tend to be

                                                          present in nature as a group All REEs

                                                          commonly substitute for one another in minerals

                                                          bull

                                                          Yet the REEs

                                                          are capable of showing great variation in their distributions

                                                          bull

                                                          Comes about due to ndash

                                                          Differences in ionic radius ndash

                                                          Crystal structure (Coordination Number)ndash

                                                          Basicity

                                                          of the mineral ndash

                                                          The elementrsquos solubility and ability to migrate in the environment ndash

                                                          Content of REEs

                                                          in source fluids

                                                          Ionic Radiusbull

                                                          The ionic radius of the REEs

                                                          is inversely related to atomic number

                                                          bull

                                                          The heavy rare earths are smaller ndash

                                                          more similar to Mn2+ (ionic radius 008 nanometers)

                                                          bull

                                                          LREEs

                                                          are largerndash

                                                          more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                          bull

                                                          Charge balance achieved through some sites being left vacant or

                                                          by coupled substitution with lower charged mineral (Na+)

                                                          In nanometers

                                                          Coordination Number

                                                          bull

                                                          Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                          bull

                                                          Coordination number for this structure is 8

                                                          Coordination Numberbull

                                                          The heavy and light REEs

                                                          differ in the coordination

                                                          numbers (CN) with oxygenndash

                                                          HREEs

                                                          have CN between six to nine ndash

                                                          LREEs

                                                          have higher CNs

                                                          bull

                                                          Minerals with high CNs

                                                          associated with REE site

                                                          will favor LREEsndash

                                                          Bastnasite

                                                          CN = 11 ndash

                                                          Monazite CN = 9

                                                          bull

                                                          Those with low CNs

                                                          will preferentially select HREEs ndash

                                                          Xenotime

                                                          has a value of 8

                                                          Other Factorsbull

                                                          Minerals basicityndash

                                                          Alkalic

                                                          rocks host minerals with elevated LREE content ndash

                                                          Rocks with lower basicity

                                                          have lower amounts of LREEs

                                                          relative to their HREE content

                                                          bull

                                                          Solubilityndash

                                                          LREEs

                                                          are more soluble in water then the HREEsndash

                                                          Important characteristic for hydrothermally derived minerals

                                                          bull

                                                          MagmaHydrothermal fluid compositionndash

                                                          Minerals will take what they can get

                                                          REEs

                                                          and Economicsbull

                                                          The REEs

                                                          and Yttrium have a very broad range of applications mostly in high technology fields

                                                          bull

                                                          84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                          bull

                                                          REEs

                                                          used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                          HREEs

                                                          and Magnetism

                                                          bull

                                                          HREEs

                                                          exhibit complex magnetic behaviour on account of electron structurendash

                                                          They share the same outer shell electron configuration (valence = +3)

                                                          ndash

                                                          Differ in number of 4f electrons

                                                          Applications in Magnetismbull

                                                          Terbium and

                                                          Dysprosium

                                                          bull

                                                          Components of Terfenol-D

                                                          alloy

                                                          with the formula Tb(03) Dy(07) Fe(19)

                                                          bull

                                                          Has the higher magnetostriction

                                                          then any other alloyndash

                                                          expands and contracts in magnetic field

                                                          bull

                                                          Developed by American Navy for sonar

                                                          systems ndash

                                                          Now has applications in magnetomechanical

                                                          sensors and other electronic devices

                                                          Applications in Magnetism

                                                          bull

                                                          Holmium

                                                          bull

                                                          Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                          elements

                                                          bull

                                                          Creates the strongest artificially generated magnetic fieldsndash

                                                          In research where strong magnetic fields are needed

                                                          HREEs

                                                          and Nuclear Technology

                                                          bull

                                                          Dysprosium Homium Erbium

                                                          bull

                                                          High neutron

                                                          absorption cross-section ndash

                                                          Measure of probability of neutron capture

                                                          bull

                                                          Used in neutron-absorbing control rods in nuclear reactors

                                                          HREEs

                                                          and Nuclear Technology

                                                          bull

                                                          Lutetiumbull

                                                          Radioactive isotope used in radiometric dating

                                                          bull

                                                          Thulium bull

                                                          Stable thulium used as a radiation

                                                          source

                                                          in portable X-ray

                                                          devices

                                                          Mountain Passbull

                                                          Bastnasite

                                                          is the major REE mineral bull

                                                          High grade accessory mineral of igneous or hydrothermal originsbull

                                                          31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                          Mining stopped in 1994 ndash

                                                          Thorium content of waste rock ndash

                                                          Availability of inexpensive REEs

                                                          from China

                                                          San Bernardino County

                                                          Bayan

                                                          Obobull

                                                          The worldrsquos primary source for both yttrium and the rare earth elements

                                                          bull

                                                          37 million tons of ore bull

                                                          Main REE source there is Bastnasite

                                                          World Production

                                                          Explorationbull

                                                          84 of REE imports to US are from China

                                                          bull

                                                          Increasing demand for high tech applications spurred increase in exploration in 2007

                                                          bull

                                                          Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                          Lake as well as in

                                                          Malawi Africa

                                                          Environmental Considerations

                                                          bull

                                                          REE soil and food contaminationbull

                                                          Acid Mine Drainage and groundwater systems

                                                          bull

                                                          Radioactive elements

                                                          REE Fertilizerbull

                                                          In China REE enriched fertilizer has been used in crop fields since 1990

                                                          bull

                                                          At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                          every year

                                                          bull

                                                          Research and agricultural practice that provides evidence that REEs

                                                          will improve crop quality an yield

                                                          bull

                                                          The ramifications environmental and human exposure to REEs

                                                          are not well understood

                                                          Investigation by T Liang et albull

                                                          Revealed that the average concentration of total REEs

                                                          in Chinese soil is

                                                          1768 mgkg ranging between 850 to 5227 mgkg

                                                          bull

                                                          In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                          Implicationsbull

                                                          Human health effects not completely understood

                                                          bull

                                                          REE soil content shown to be detrimental to some plant speciesndash

                                                          100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                          Acid Mine Drainage (AMD)bull

                                                          Rain waters contacts waste rock facilitating acid forming reactions

                                                          bull

                                                          Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                          bull

                                                          Process mobilizes established ecotoxins

                                                          (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                          bull

                                                          Historically dismissed as minor environmental risk

                                                          Radioactive Elements

                                                          bull

                                                          REEs

                                                          associated with uranium and thorium

                                                          bull

                                                          Bastnesite 32 thorium

                                                          bull

                                                          Monazite sands 6 to 12 thorium oxide

                                                          bull

                                                          Ores containing radioactive elements are avoided as sources of REEs

                                                          Radioactive Hazardsbull

                                                          Mountain Pass

                                                          bull

                                                          Accidentsndash

                                                          In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                          bull

                                                          Health Effectsndash

                                                          inflammatory bowel disease ndash

                                                          Prolonged seizures ndash

                                                          Cysts ndash

                                                          Cancers

                                                          bull

                                                          Waste Disposal ndash

                                                          Yucca Mountain

                                                          Summarybull

                                                          REE concentrations in the crust are rare

                                                          bull

                                                          Several geochemical factors influencing distribution including ionic radius and coordination number

                                                          bull

                                                          Main REE minerals are bastnasite monazite and xenotime

                                                          bull

                                                          Most important deposits are found at Bayan

                                                          Obo China and Mountain Pass USA

                                                          bull

                                                          Important electronic and nuclear applications

                                                          bull

                                                          Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                          system contamination though acid mine drainage association with

                                                          radioactive elements

                                                          Referencesbull

                                                          E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                          bull

                                                          Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                          bull

                                                          G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                          bull

                                                          B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                          The Government of South Australia wwwpirsagovaubull

                                                          The US geological Survey Mineralsusgsgovbull

                                                          wwwelementsdatabasecombull

                                                          wwwastrolsaumichedu~cowleyintro2htmlbull

                                                          wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                          webmineralcomdataMonazite-(Ce)shtmlbull

                                                          wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                          wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                          wwwchemicalelementscomelementseuhtmlbull

                                                          boomeriaorgchemlecturestextass2table10-9jpgbull

                                                          lostcontentquakecomfiles200802holmiumpngbull

                                                          chinageocitylocatorcomcitiesChinaQinghaibull

                                                          geowebrudruzal-Bayan-Obohtmbull

                                                          enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                          wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                          enwikipediaorgwikiMonazitebull

                                                          webmineralcomdataBastnasite-(La)shtmlbull

                                                          wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                          httpwwwavalonventurescombull

                                                          wwwnewsweekcomid43884bull

                                                          httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                          httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                          • Slide Number 1
                                                          • Slide Number 2
                                                          • Slide Number 3
                                                          • Slide Number 4
                                                          • Slide Number 5
                                                          • Slide Number 6
                                                          • Slide Number 7
                                                          • Slide Number 8
                                                          • Slide Number 9
                                                          • Slide Number 10
                                                          • Slide Number 11
                                                          • Slide Number 12
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                                                          • Slide Number 14
                                                          • Slide Number 15
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                                                          • Slide Number 17
                                                          • Slide Number 18
                                                          • Slide Number 19
                                                          • Slide Number 20
                                                          • Slide Number 21
                                                          • Slide Number 22
                                                          • Slide Number 23
                                                          • Slide Number 24
                                                          • Slide Number 25
                                                          • Slide Number 26
                                                          • Slide Number 27
                                                          • Slide Number 28
                                                          • Slide Number 29
                                                          • Slide Number 30
                                                          • Slide Number 31
                                                          • Slide Number 32
                                                          • Slide Number 33
                                                          • Slide Number 34
                                                          • Slide Number 35
                                                          • Slide Number 36
                                                          • Slide Number 37
                                                          • Slide Number 38
                                                          • Slide Number 39
                                                          • Slide Number 40
                                                          • Slide Number 41
                                                          • Slide Number 42
                                                          • Slide Number 43
                                                          • Slide Number 44
                                                          • Slide Number 45
                                                          • Slide Number 46
                                                          • Slide Number 47
                                                          • Slide Number 48
                                                          • Slide Number 49
                                                          • Slide Number 50
                                                          • Slide Number 51
                                                          • Rare Earth Elements
                                                          • Crustal Abundances of Elements
                                                          • Occurrence
                                                          • Rare Earth Minerals
                                                          • REE Minerals
                                                          • Bastnesite
                                                          • Other REE minerals
                                                          • Electron Configuration
                                                          • Electron Configuartion
                                                          • REE Behavior
                                                          • Ionic Radius
                                                          • Coordination Number
                                                          • Coordination Number
                                                          • Other Factors
                                                          • REEs and Economics
                                                          • HREEs and Magnetism
                                                          • Applications in Magnetism
                                                          • Applications in Magnetism
                                                          • HREEs and Nuclear Technology
                                                          • HREEs and Nuclear Technology
                                                          • Mountain Pass
                                                          • Bayan Obo
                                                          • World Production
                                                          • Exploration
                                                          • Environmental Considerations
                                                          • REE Fertilizer
                                                          • Investigation by T Liang et al
                                                          • Implications
                                                          • Acid Mine Drainage (AMD)
                                                          • Radioactive Elements
                                                          • Radioactive Hazards
                                                          • Summary
                                                          • References

                                                            As a final statement it should be emphasizedhellip

                                                            1) Carbonatites containing as much as 5 wt LREE must compete with Bayan Obo Maoniuping and Mountain Pass which have much higher grade and have established physical and chemical processing plants

                                                            2) Deposits that are mineralized with allanite and LREE-enriched apatite can not compete economically with carbonatites or peralkalic systems that have the high REE mineralogy

                                                            3) Naturally higher radioactivity in all REE systems makes them easier to find with airborne and ground gamma-ray spectrometry

                                                            4) Uraniferous systems commonly have anomalous LREE amp HREE which has been recovered in some deposits ie rafinates from uranium mining

                                                            5) Although ion-adsorbed REE in clays from South China provide the bulk of HREE to the market place in other countries high costs for labor and necessary supplies power costs and environmental restrictions may render similar deposits uneconomical

                                                            Rare Earth Elements

                                                            bull

                                                            Name something of a misnomerndash

                                                            Rarest REEs

                                                            are over 200 times more

                                                            abundant then gold

                                                            bull

                                                            Variation in distribution for two reasons ndash

                                                            Compatibility with common rock forming materials

                                                            ndash

                                                            CosmicCrustal abundances

                                                            Crustal Abundances of Elements

                                                            Occurrencebull

                                                            REEs

                                                            occur mostly as

                                                            substitutional

                                                            impurities in many rock forming minerals

                                                            bull

                                                            Only a few the REE minerals have sufficient quantities to be considered important sources

                                                            bull

                                                            Defined as minerals having at least one site that is filled by REEs

                                                            andor Yttrium more often then any other elementMonazite

                                                            Rare Earth Minerals

                                                            bull

                                                            Form by primary crystalization

                                                            from magma or by hydrothermal reactions

                                                            bull

                                                            Found hosted in carbonate rocks in pegmatites

                                                            and as accessory minerals in

                                                            igneous rocks

                                                            bull

                                                            Stable REE minerals and can be concentrated in weathering zones

                                                            REE Mineralsbull

                                                            The most important REE minerals is bastnaumlsite

                                                            REE(CO3)F

                                                            bull

                                                            Other notable sources are ndash

                                                            Monazite REE(PO4) ndash

                                                            Xenotime

                                                            YPO4

                                                            bull

                                                            All may contain radioactive species such as thorium

                                                            and uraniumndash

                                                            are avoided as source materials

                                                            Bastnesitebull

                                                            Bastnasite

                                                            [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                            bull

                                                            Containing 60 to 70 rare earth oxides (REOs)

                                                            bull

                                                            REE site is most commonly filled by LREEs

                                                            and Y

                                                            Other REE mineralsbull

                                                            Monazite [(LREEYTh)PO4] ndash

                                                            Contains about 50ndash78 rare earth oxides

                                                            ndash

                                                            Forms in heavy mineral sands placer deposits associated with beach environments

                                                            bull

                                                            Xenotime

                                                            [(YPO4)] ndash

                                                            Contains 54ndash65 rare earth oxides

                                                            ndash

                                                            Yttrium Erbium and Cerium most common ndash

                                                            Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                            Electron Configuration

                                                            bull

                                                            The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                            bull

                                                            REEs

                                                            have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                            Electron Configuartion

                                                            REE Behaviorbull

                                                            Because of their shared behaviour REEs

                                                            tend to be

                                                            present in nature as a group All REEs

                                                            commonly substitute for one another in minerals

                                                            bull

                                                            Yet the REEs

                                                            are capable of showing great variation in their distributions

                                                            bull

                                                            Comes about due to ndash

                                                            Differences in ionic radius ndash

                                                            Crystal structure (Coordination Number)ndash

                                                            Basicity

                                                            of the mineral ndash

                                                            The elementrsquos solubility and ability to migrate in the environment ndash

                                                            Content of REEs

                                                            in source fluids

                                                            Ionic Radiusbull

                                                            The ionic radius of the REEs

                                                            is inversely related to atomic number

                                                            bull

                                                            The heavy rare earths are smaller ndash

                                                            more similar to Mn2+ (ionic radius 008 nanometers)

                                                            bull

                                                            LREEs

                                                            are largerndash

                                                            more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                            bull

                                                            Charge balance achieved through some sites being left vacant or

                                                            by coupled substitution with lower charged mineral (Na+)

                                                            In nanometers

                                                            Coordination Number

                                                            bull

                                                            Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                            bull

                                                            Coordination number for this structure is 8

                                                            Coordination Numberbull

                                                            The heavy and light REEs

                                                            differ in the coordination

                                                            numbers (CN) with oxygenndash

                                                            HREEs

                                                            have CN between six to nine ndash

                                                            LREEs

                                                            have higher CNs

                                                            bull

                                                            Minerals with high CNs

                                                            associated with REE site

                                                            will favor LREEsndash

                                                            Bastnasite

                                                            CN = 11 ndash

                                                            Monazite CN = 9

                                                            bull

                                                            Those with low CNs

                                                            will preferentially select HREEs ndash

                                                            Xenotime

                                                            has a value of 8

                                                            Other Factorsbull

                                                            Minerals basicityndash

                                                            Alkalic

                                                            rocks host minerals with elevated LREE content ndash

                                                            Rocks with lower basicity

                                                            have lower amounts of LREEs

                                                            relative to their HREE content

                                                            bull

                                                            Solubilityndash

                                                            LREEs

                                                            are more soluble in water then the HREEsndash

                                                            Important characteristic for hydrothermally derived minerals

                                                            bull

                                                            MagmaHydrothermal fluid compositionndash

                                                            Minerals will take what they can get

                                                            REEs

                                                            and Economicsbull

                                                            The REEs

                                                            and Yttrium have a very broad range of applications mostly in high technology fields

                                                            bull

                                                            84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                            bull

                                                            REEs

                                                            used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                            HREEs

                                                            and Magnetism

                                                            bull

                                                            HREEs

                                                            exhibit complex magnetic behaviour on account of electron structurendash

                                                            They share the same outer shell electron configuration (valence = +3)

                                                            ndash

                                                            Differ in number of 4f electrons

                                                            Applications in Magnetismbull

                                                            Terbium and

                                                            Dysprosium

                                                            bull

                                                            Components of Terfenol-D

                                                            alloy

                                                            with the formula Tb(03) Dy(07) Fe(19)

                                                            bull

                                                            Has the higher magnetostriction

                                                            then any other alloyndash

                                                            expands and contracts in magnetic field

                                                            bull

                                                            Developed by American Navy for sonar

                                                            systems ndash

                                                            Now has applications in magnetomechanical

                                                            sensors and other electronic devices

                                                            Applications in Magnetism

                                                            bull

                                                            Holmium

                                                            bull

                                                            Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                            elements

                                                            bull

                                                            Creates the strongest artificially generated magnetic fieldsndash

                                                            In research where strong magnetic fields are needed

                                                            HREEs

                                                            and Nuclear Technology

                                                            bull

                                                            Dysprosium Homium Erbium

                                                            bull

                                                            High neutron

                                                            absorption cross-section ndash

                                                            Measure of probability of neutron capture

                                                            bull

                                                            Used in neutron-absorbing control rods in nuclear reactors

                                                            HREEs

                                                            and Nuclear Technology

                                                            bull

                                                            Lutetiumbull

                                                            Radioactive isotope used in radiometric dating

                                                            bull

                                                            Thulium bull

                                                            Stable thulium used as a radiation

                                                            source

                                                            in portable X-ray

                                                            devices

                                                            Mountain Passbull

                                                            Bastnasite

                                                            is the major REE mineral bull

                                                            High grade accessory mineral of igneous or hydrothermal originsbull

                                                            31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                            Mining stopped in 1994 ndash

                                                            Thorium content of waste rock ndash

                                                            Availability of inexpensive REEs

                                                            from China

                                                            San Bernardino County

                                                            Bayan

                                                            Obobull

                                                            The worldrsquos primary source for both yttrium and the rare earth elements

                                                            bull

                                                            37 million tons of ore bull

                                                            Main REE source there is Bastnasite

                                                            World Production

                                                            Explorationbull

                                                            84 of REE imports to US are from China

                                                            bull

                                                            Increasing demand for high tech applications spurred increase in exploration in 2007

                                                            bull

                                                            Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                            Lake as well as in

                                                            Malawi Africa

                                                            Environmental Considerations

                                                            bull

                                                            REE soil and food contaminationbull

                                                            Acid Mine Drainage and groundwater systems

                                                            bull

                                                            Radioactive elements

                                                            REE Fertilizerbull

                                                            In China REE enriched fertilizer has been used in crop fields since 1990

                                                            bull

                                                            At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                            every year

                                                            bull

                                                            Research and agricultural practice that provides evidence that REEs

                                                            will improve crop quality an yield

                                                            bull

                                                            The ramifications environmental and human exposure to REEs

                                                            are not well understood

                                                            Investigation by T Liang et albull

                                                            Revealed that the average concentration of total REEs

                                                            in Chinese soil is

                                                            1768 mgkg ranging between 850 to 5227 mgkg

                                                            bull

                                                            In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                            Implicationsbull

                                                            Human health effects not completely understood

                                                            bull

                                                            REE soil content shown to be detrimental to some plant speciesndash

                                                            100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                            Acid Mine Drainage (AMD)bull

                                                            Rain waters contacts waste rock facilitating acid forming reactions

                                                            bull

                                                            Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                            bull

                                                            Process mobilizes established ecotoxins

                                                            (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                            bull

                                                            Historically dismissed as minor environmental risk

                                                            Radioactive Elements

                                                            bull

                                                            REEs

                                                            associated with uranium and thorium

                                                            bull

                                                            Bastnesite 32 thorium

                                                            bull

                                                            Monazite sands 6 to 12 thorium oxide

                                                            bull

                                                            Ores containing radioactive elements are avoided as sources of REEs

                                                            Radioactive Hazardsbull

                                                            Mountain Pass

                                                            bull

                                                            Accidentsndash

                                                            In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                            bull

                                                            Health Effectsndash

                                                            inflammatory bowel disease ndash

                                                            Prolonged seizures ndash

                                                            Cysts ndash

                                                            Cancers

                                                            bull

                                                            Waste Disposal ndash

                                                            Yucca Mountain

                                                            Summarybull

                                                            REE concentrations in the crust are rare

                                                            bull

                                                            Several geochemical factors influencing distribution including ionic radius and coordination number

                                                            bull

                                                            Main REE minerals are bastnasite monazite and xenotime

                                                            bull

                                                            Most important deposits are found at Bayan

                                                            Obo China and Mountain Pass USA

                                                            bull

                                                            Important electronic and nuclear applications

                                                            bull

                                                            Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                            system contamination though acid mine drainage association with

                                                            radioactive elements

                                                            Referencesbull

                                                            E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                            bull

                                                            Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                            bull

                                                            G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                            bull

                                                            B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                            The Government of South Australia wwwpirsagovaubull

                                                            The US geological Survey Mineralsusgsgovbull

                                                            wwwelementsdatabasecombull

                                                            wwwastrolsaumichedu~cowleyintro2htmlbull

                                                            wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                            webmineralcomdataMonazite-(Ce)shtmlbull

                                                            wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                            wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                            wwwchemicalelementscomelementseuhtmlbull

                                                            boomeriaorgchemlecturestextass2table10-9jpgbull

                                                            lostcontentquakecomfiles200802holmiumpngbull

                                                            chinageocitylocatorcomcitiesChinaQinghaibull

                                                            geowebrudruzal-Bayan-Obohtmbull

                                                            enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                            wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                            enwikipediaorgwikiMonazitebull

                                                            webmineralcomdataBastnasite-(La)shtmlbull

                                                            wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                            httpwwwavalonventurescombull

                                                            wwwnewsweekcomid43884bull

                                                            httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                            httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                            • Slide Number 1
                                                            • Slide Number 2
                                                            • Slide Number 3
                                                            • Slide Number 4
                                                            • Slide Number 5
                                                            • Slide Number 6
                                                            • Slide Number 7
                                                            • Slide Number 8
                                                            • Slide Number 9
                                                            • Slide Number 10
                                                            • Slide Number 11
                                                            • Slide Number 12
                                                            • Slide Number 13
                                                            • Slide Number 14
                                                            • Slide Number 15
                                                            • Slide Number 16
                                                            • Slide Number 17
                                                            • Slide Number 18
                                                            • Slide Number 19
                                                            • Slide Number 20
                                                            • Slide Number 21
                                                            • Slide Number 22
                                                            • Slide Number 23
                                                            • Slide Number 24
                                                            • Slide Number 25
                                                            • Slide Number 26
                                                            • Slide Number 27
                                                            • Slide Number 28
                                                            • Slide Number 29
                                                            • Slide Number 30
                                                            • Slide Number 31
                                                            • Slide Number 32
                                                            • Slide Number 33
                                                            • Slide Number 34
                                                            • Slide Number 35
                                                            • Slide Number 36
                                                            • Slide Number 37
                                                            • Slide Number 38
                                                            • Slide Number 39
                                                            • Slide Number 40
                                                            • Slide Number 41
                                                            • Slide Number 42
                                                            • Slide Number 43
                                                            • Slide Number 44
                                                            • Slide Number 45
                                                            • Slide Number 46
                                                            • Slide Number 47
                                                            • Slide Number 48
                                                            • Slide Number 49
                                                            • Slide Number 50
                                                            • Slide Number 51
                                                            • Rare Earth Elements
                                                            • Crustal Abundances of Elements
                                                            • Occurrence
                                                            • Rare Earth Minerals
                                                            • REE Minerals
                                                            • Bastnesite
                                                            • Other REE minerals
                                                            • Electron Configuration
                                                            • Electron Configuartion
                                                            • REE Behavior
                                                            • Ionic Radius
                                                            • Coordination Number
                                                            • Coordination Number
                                                            • Other Factors
                                                            • REEs and Economics
                                                            • HREEs and Magnetism
                                                            • Applications in Magnetism
                                                            • Applications in Magnetism
                                                            • HREEs and Nuclear Technology
                                                            • HREEs and Nuclear Technology
                                                            • Mountain Pass
                                                            • Bayan Obo
                                                            • World Production
                                                            • Exploration
                                                            • Environmental Considerations
                                                            • REE Fertilizer
                                                            • Investigation by T Liang et al
                                                            • Implications
                                                            • Acid Mine Drainage (AMD)
                                                            • Radioactive Elements
                                                            • Radioactive Hazards
                                                            • Summary
                                                            • References

                                                              Rare Earth Elements

                                                              bull

                                                              Name something of a misnomerndash

                                                              Rarest REEs

                                                              are over 200 times more

                                                              abundant then gold

                                                              bull

                                                              Variation in distribution for two reasons ndash

                                                              Compatibility with common rock forming materials

                                                              ndash

                                                              CosmicCrustal abundances

                                                              Crustal Abundances of Elements

                                                              Occurrencebull

                                                              REEs

                                                              occur mostly as

                                                              substitutional

                                                              impurities in many rock forming minerals

                                                              bull

                                                              Only a few the REE minerals have sufficient quantities to be considered important sources

                                                              bull

                                                              Defined as minerals having at least one site that is filled by REEs

                                                              andor Yttrium more often then any other elementMonazite

                                                              Rare Earth Minerals

                                                              bull

                                                              Form by primary crystalization

                                                              from magma or by hydrothermal reactions

                                                              bull

                                                              Found hosted in carbonate rocks in pegmatites

                                                              and as accessory minerals in

                                                              igneous rocks

                                                              bull

                                                              Stable REE minerals and can be concentrated in weathering zones

                                                              REE Mineralsbull

                                                              The most important REE minerals is bastnaumlsite

                                                              REE(CO3)F

                                                              bull

                                                              Other notable sources are ndash

                                                              Monazite REE(PO4) ndash

                                                              Xenotime

                                                              YPO4

                                                              bull

                                                              All may contain radioactive species such as thorium

                                                              and uraniumndash

                                                              are avoided as source materials

                                                              Bastnesitebull

                                                              Bastnasite

                                                              [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                              bull

                                                              Containing 60 to 70 rare earth oxides (REOs)

                                                              bull

                                                              REE site is most commonly filled by LREEs

                                                              and Y

                                                              Other REE mineralsbull

                                                              Monazite [(LREEYTh)PO4] ndash

                                                              Contains about 50ndash78 rare earth oxides

                                                              ndash

                                                              Forms in heavy mineral sands placer deposits associated with beach environments

                                                              bull

                                                              Xenotime

                                                              [(YPO4)] ndash

                                                              Contains 54ndash65 rare earth oxides

                                                              ndash

                                                              Yttrium Erbium and Cerium most common ndash

                                                              Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                              Electron Configuration

                                                              bull

                                                              The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                              bull

                                                              REEs

                                                              have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                              Electron Configuartion

                                                              REE Behaviorbull

                                                              Because of their shared behaviour REEs

                                                              tend to be

                                                              present in nature as a group All REEs

                                                              commonly substitute for one another in minerals

                                                              bull

                                                              Yet the REEs

                                                              are capable of showing great variation in their distributions

                                                              bull

                                                              Comes about due to ndash

                                                              Differences in ionic radius ndash

                                                              Crystal structure (Coordination Number)ndash

                                                              Basicity

                                                              of the mineral ndash

                                                              The elementrsquos solubility and ability to migrate in the environment ndash

                                                              Content of REEs

                                                              in source fluids

                                                              Ionic Radiusbull

                                                              The ionic radius of the REEs

                                                              is inversely related to atomic number

                                                              bull

                                                              The heavy rare earths are smaller ndash

                                                              more similar to Mn2+ (ionic radius 008 nanometers)

                                                              bull

                                                              LREEs

                                                              are largerndash

                                                              more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                              bull

                                                              Charge balance achieved through some sites being left vacant or

                                                              by coupled substitution with lower charged mineral (Na+)

                                                              In nanometers

                                                              Coordination Number

                                                              bull

                                                              Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                              bull

                                                              Coordination number for this structure is 8

                                                              Coordination Numberbull

                                                              The heavy and light REEs

                                                              differ in the coordination

                                                              numbers (CN) with oxygenndash

                                                              HREEs

                                                              have CN between six to nine ndash

                                                              LREEs

                                                              have higher CNs

                                                              bull

                                                              Minerals with high CNs

                                                              associated with REE site

                                                              will favor LREEsndash

                                                              Bastnasite

                                                              CN = 11 ndash

                                                              Monazite CN = 9

                                                              bull

                                                              Those with low CNs

                                                              will preferentially select HREEs ndash

                                                              Xenotime

                                                              has a value of 8

                                                              Other Factorsbull

                                                              Minerals basicityndash

                                                              Alkalic

                                                              rocks host minerals with elevated LREE content ndash

                                                              Rocks with lower basicity

                                                              have lower amounts of LREEs

                                                              relative to their HREE content

                                                              bull

                                                              Solubilityndash

                                                              LREEs

                                                              are more soluble in water then the HREEsndash

                                                              Important characteristic for hydrothermally derived minerals

                                                              bull

                                                              MagmaHydrothermal fluid compositionndash

                                                              Minerals will take what they can get

                                                              REEs

                                                              and Economicsbull

                                                              The REEs

                                                              and Yttrium have a very broad range of applications mostly in high technology fields

                                                              bull

                                                              84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                              bull

                                                              REEs

                                                              used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                              HREEs

                                                              and Magnetism

                                                              bull

                                                              HREEs

                                                              exhibit complex magnetic behaviour on account of electron structurendash

                                                              They share the same outer shell electron configuration (valence = +3)

                                                              ndash

                                                              Differ in number of 4f electrons

                                                              Applications in Magnetismbull

                                                              Terbium and

                                                              Dysprosium

                                                              bull

                                                              Components of Terfenol-D

                                                              alloy

                                                              with the formula Tb(03) Dy(07) Fe(19)

                                                              bull

                                                              Has the higher magnetostriction

                                                              then any other alloyndash

                                                              expands and contracts in magnetic field

                                                              bull

                                                              Developed by American Navy for sonar

                                                              systems ndash

                                                              Now has applications in magnetomechanical

                                                              sensors and other electronic devices

                                                              Applications in Magnetism

                                                              bull

                                                              Holmium

                                                              bull

                                                              Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                              elements

                                                              bull

                                                              Creates the strongest artificially generated magnetic fieldsndash

                                                              In research where strong magnetic fields are needed

                                                              HREEs

                                                              and Nuclear Technology

                                                              bull

                                                              Dysprosium Homium Erbium

                                                              bull

                                                              High neutron

                                                              absorption cross-section ndash

                                                              Measure of probability of neutron capture

                                                              bull

                                                              Used in neutron-absorbing control rods in nuclear reactors

                                                              HREEs

                                                              and Nuclear Technology

                                                              bull

                                                              Lutetiumbull

                                                              Radioactive isotope used in radiometric dating

                                                              bull

                                                              Thulium bull

                                                              Stable thulium used as a radiation

                                                              source

                                                              in portable X-ray

                                                              devices

                                                              Mountain Passbull

                                                              Bastnasite

                                                              is the major REE mineral bull

                                                              High grade accessory mineral of igneous or hydrothermal originsbull

                                                              31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                              Mining stopped in 1994 ndash

                                                              Thorium content of waste rock ndash

                                                              Availability of inexpensive REEs

                                                              from China

                                                              San Bernardino County

                                                              Bayan

                                                              Obobull

                                                              The worldrsquos primary source for both yttrium and the rare earth elements

                                                              bull

                                                              37 million tons of ore bull

                                                              Main REE source there is Bastnasite

                                                              World Production

                                                              Explorationbull

                                                              84 of REE imports to US are from China

                                                              bull

                                                              Increasing demand for high tech applications spurred increase in exploration in 2007

                                                              bull

                                                              Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                              Lake as well as in

                                                              Malawi Africa

                                                              Environmental Considerations

                                                              bull

                                                              REE soil and food contaminationbull

                                                              Acid Mine Drainage and groundwater systems

                                                              bull

                                                              Radioactive elements

                                                              REE Fertilizerbull

                                                              In China REE enriched fertilizer has been used in crop fields since 1990

                                                              bull

                                                              At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                              every year

                                                              bull

                                                              Research and agricultural practice that provides evidence that REEs

                                                              will improve crop quality an yield

                                                              bull

                                                              The ramifications environmental and human exposure to REEs

                                                              are not well understood

                                                              Investigation by T Liang et albull

                                                              Revealed that the average concentration of total REEs

                                                              in Chinese soil is

                                                              1768 mgkg ranging between 850 to 5227 mgkg

                                                              bull

                                                              In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                              Implicationsbull

                                                              Human health effects not completely understood

                                                              bull

                                                              REE soil content shown to be detrimental to some plant speciesndash

                                                              100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                              Acid Mine Drainage (AMD)bull

                                                              Rain waters contacts waste rock facilitating acid forming reactions

                                                              bull

                                                              Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                              bull

                                                              Process mobilizes established ecotoxins

                                                              (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                              bull

                                                              Historically dismissed as minor environmental risk

                                                              Radioactive Elements

                                                              bull

                                                              REEs

                                                              associated with uranium and thorium

                                                              bull

                                                              Bastnesite 32 thorium

                                                              bull

                                                              Monazite sands 6 to 12 thorium oxide

                                                              bull

                                                              Ores containing radioactive elements are avoided as sources of REEs

                                                              Radioactive Hazardsbull

                                                              Mountain Pass

                                                              bull

                                                              Accidentsndash

                                                              In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                              bull

                                                              Health Effectsndash

                                                              inflammatory bowel disease ndash

                                                              Prolonged seizures ndash

                                                              Cysts ndash

                                                              Cancers

                                                              bull

                                                              Waste Disposal ndash

                                                              Yucca Mountain

                                                              Summarybull

                                                              REE concentrations in the crust are rare

                                                              bull

                                                              Several geochemical factors influencing distribution including ionic radius and coordination number

                                                              bull

                                                              Main REE minerals are bastnasite monazite and xenotime

                                                              bull

                                                              Most important deposits are found at Bayan

                                                              Obo China and Mountain Pass USA

                                                              bull

                                                              Important electronic and nuclear applications

                                                              bull

                                                              Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                              system contamination though acid mine drainage association with

                                                              radioactive elements

                                                              Referencesbull

                                                              E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                              bull

                                                              Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                              bull

                                                              G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                              bull

                                                              B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                              The Government of South Australia wwwpirsagovaubull

                                                              The US geological Survey Mineralsusgsgovbull

                                                              wwwelementsdatabasecombull

                                                              wwwastrolsaumichedu~cowleyintro2htmlbull

                                                              wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                              webmineralcomdataMonazite-(Ce)shtmlbull

                                                              wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                              wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                              wwwchemicalelementscomelementseuhtmlbull

                                                              boomeriaorgchemlecturestextass2table10-9jpgbull

                                                              lostcontentquakecomfiles200802holmiumpngbull

                                                              chinageocitylocatorcomcitiesChinaQinghaibull

                                                              geowebrudruzal-Bayan-Obohtmbull

                                                              enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                              wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                              enwikipediaorgwikiMonazitebull

                                                              webmineralcomdataBastnasite-(La)shtmlbull

                                                              wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                              httpwwwavalonventurescombull

                                                              wwwnewsweekcomid43884bull

                                                              httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                              httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                              • Slide Number 1
                                                              • Slide Number 2
                                                              • Slide Number 3
                                                              • Slide Number 4
                                                              • Slide Number 5
                                                              • Slide Number 6
                                                              • Slide Number 7
                                                              • Slide Number 8
                                                              • Slide Number 9
                                                              • Slide Number 10
                                                              • Slide Number 11
                                                              • Slide Number 12
                                                              • Slide Number 13
                                                              • Slide Number 14
                                                              • Slide Number 15
                                                              • Slide Number 16
                                                              • Slide Number 17
                                                              • Slide Number 18
                                                              • Slide Number 19
                                                              • Slide Number 20
                                                              • Slide Number 21
                                                              • Slide Number 22
                                                              • Slide Number 23
                                                              • Slide Number 24
                                                              • Slide Number 25
                                                              • Slide Number 26
                                                              • Slide Number 27
                                                              • Slide Number 28
                                                              • Slide Number 29
                                                              • Slide Number 30
                                                              • Slide Number 31
                                                              • Slide Number 32
                                                              • Slide Number 33
                                                              • Slide Number 34
                                                              • Slide Number 35
                                                              • Slide Number 36
                                                              • Slide Number 37
                                                              • Slide Number 38
                                                              • Slide Number 39
                                                              • Slide Number 40
                                                              • Slide Number 41
                                                              • Slide Number 42
                                                              • Slide Number 43
                                                              • Slide Number 44
                                                              • Slide Number 45
                                                              • Slide Number 46
                                                              • Slide Number 47
                                                              • Slide Number 48
                                                              • Slide Number 49
                                                              • Slide Number 50
                                                              • Slide Number 51
                                                              • Rare Earth Elements
                                                              • Crustal Abundances of Elements
                                                              • Occurrence
                                                              • Rare Earth Minerals
                                                              • REE Minerals
                                                              • Bastnesite
                                                              • Other REE minerals
                                                              • Electron Configuration
                                                              • Electron Configuartion
                                                              • REE Behavior
                                                              • Ionic Radius
                                                              • Coordination Number
                                                              • Coordination Number
                                                              • Other Factors
                                                              • REEs and Economics
                                                              • HREEs and Magnetism
                                                              • Applications in Magnetism
                                                              • Applications in Magnetism
                                                              • HREEs and Nuclear Technology
                                                              • HREEs and Nuclear Technology
                                                              • Mountain Pass
                                                              • Bayan Obo
                                                              • World Production
                                                              • Exploration
                                                              • Environmental Considerations
                                                              • REE Fertilizer
                                                              • Investigation by T Liang et al
                                                              • Implications
                                                              • Acid Mine Drainage (AMD)
                                                              • Radioactive Elements
                                                              • Radioactive Hazards
                                                              • Summary
                                                              • References

                                                                Crustal Abundances of Elements

                                                                Occurrencebull

                                                                REEs

                                                                occur mostly as

                                                                substitutional

                                                                impurities in many rock forming minerals

                                                                bull

                                                                Only a few the REE minerals have sufficient quantities to be considered important sources

                                                                bull

                                                                Defined as minerals having at least one site that is filled by REEs

                                                                andor Yttrium more often then any other elementMonazite

                                                                Rare Earth Minerals

                                                                bull

                                                                Form by primary crystalization

                                                                from magma or by hydrothermal reactions

                                                                bull

                                                                Found hosted in carbonate rocks in pegmatites

                                                                and as accessory minerals in

                                                                igneous rocks

                                                                bull

                                                                Stable REE minerals and can be concentrated in weathering zones

                                                                REE Mineralsbull

                                                                The most important REE minerals is bastnaumlsite

                                                                REE(CO3)F

                                                                bull

                                                                Other notable sources are ndash

                                                                Monazite REE(PO4) ndash

                                                                Xenotime

                                                                YPO4

                                                                bull

                                                                All may contain radioactive species such as thorium

                                                                and uraniumndash

                                                                are avoided as source materials

                                                                Bastnesitebull

                                                                Bastnasite

                                                                [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                                bull

                                                                Containing 60 to 70 rare earth oxides (REOs)

                                                                bull

                                                                REE site is most commonly filled by LREEs

                                                                and Y

                                                                Other REE mineralsbull

                                                                Monazite [(LREEYTh)PO4] ndash

                                                                Contains about 50ndash78 rare earth oxides

                                                                ndash

                                                                Forms in heavy mineral sands placer deposits associated with beach environments

                                                                bull

                                                                Xenotime

                                                                [(YPO4)] ndash

                                                                Contains 54ndash65 rare earth oxides

                                                                ndash

                                                                Yttrium Erbium and Cerium most common ndash

                                                                Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                                Electron Configuration

                                                                bull

                                                                The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                                bull

                                                                REEs

                                                                have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                                Electron Configuartion

                                                                REE Behaviorbull

                                                                Because of their shared behaviour REEs

                                                                tend to be

                                                                present in nature as a group All REEs

                                                                commonly substitute for one another in minerals

                                                                bull

                                                                Yet the REEs

                                                                are capable of showing great variation in their distributions

                                                                bull

                                                                Comes about due to ndash

                                                                Differences in ionic radius ndash

                                                                Crystal structure (Coordination Number)ndash

                                                                Basicity

                                                                of the mineral ndash

                                                                The elementrsquos solubility and ability to migrate in the environment ndash

                                                                Content of REEs

                                                                in source fluids

                                                                Ionic Radiusbull

                                                                The ionic radius of the REEs

                                                                is inversely related to atomic number

                                                                bull

                                                                The heavy rare earths are smaller ndash

                                                                more similar to Mn2+ (ionic radius 008 nanometers)

                                                                bull

                                                                LREEs

                                                                are largerndash

                                                                more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                                bull

                                                                Charge balance achieved through some sites being left vacant or

                                                                by coupled substitution with lower charged mineral (Na+)

                                                                In nanometers

                                                                Coordination Number

                                                                bull

                                                                Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                bull

                                                                Coordination number for this structure is 8

                                                                Coordination Numberbull

                                                                The heavy and light REEs

                                                                differ in the coordination

                                                                numbers (CN) with oxygenndash

                                                                HREEs

                                                                have CN between six to nine ndash

                                                                LREEs

                                                                have higher CNs

                                                                bull

                                                                Minerals with high CNs

                                                                associated with REE site

                                                                will favor LREEsndash

                                                                Bastnasite

                                                                CN = 11 ndash

                                                                Monazite CN = 9

                                                                bull

                                                                Those with low CNs

                                                                will preferentially select HREEs ndash

                                                                Xenotime

                                                                has a value of 8

                                                                Other Factorsbull

                                                                Minerals basicityndash

                                                                Alkalic

                                                                rocks host minerals with elevated LREE content ndash

                                                                Rocks with lower basicity

                                                                have lower amounts of LREEs

                                                                relative to their HREE content

                                                                bull

                                                                Solubilityndash

                                                                LREEs

                                                                are more soluble in water then the HREEsndash

                                                                Important characteristic for hydrothermally derived minerals

                                                                bull

                                                                MagmaHydrothermal fluid compositionndash

                                                                Minerals will take what they can get

                                                                REEs

                                                                and Economicsbull

                                                                The REEs

                                                                and Yttrium have a very broad range of applications mostly in high technology fields

                                                                bull

                                                                84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                bull

                                                                REEs

                                                                used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                HREEs

                                                                and Magnetism

                                                                bull

                                                                HREEs

                                                                exhibit complex magnetic behaviour on account of electron structurendash

                                                                They share the same outer shell electron configuration (valence = +3)

                                                                ndash

                                                                Differ in number of 4f electrons

                                                                Applications in Magnetismbull

                                                                Terbium and

                                                                Dysprosium

                                                                bull

                                                                Components of Terfenol-D

                                                                alloy

                                                                with the formula Tb(03) Dy(07) Fe(19)

                                                                bull

                                                                Has the higher magnetostriction

                                                                then any other alloyndash

                                                                expands and contracts in magnetic field

                                                                bull

                                                                Developed by American Navy for sonar

                                                                systems ndash

                                                                Now has applications in magnetomechanical

                                                                sensors and other electronic devices

                                                                Applications in Magnetism

                                                                bull

                                                                Holmium

                                                                bull

                                                                Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                elements

                                                                bull

                                                                Creates the strongest artificially generated magnetic fieldsndash

                                                                In research where strong magnetic fields are needed

                                                                HREEs

                                                                and Nuclear Technology

                                                                bull

                                                                Dysprosium Homium Erbium

                                                                bull

                                                                High neutron

                                                                absorption cross-section ndash

                                                                Measure of probability of neutron capture

                                                                bull

                                                                Used in neutron-absorbing control rods in nuclear reactors

                                                                HREEs

                                                                and Nuclear Technology

                                                                bull

                                                                Lutetiumbull

                                                                Radioactive isotope used in radiometric dating

                                                                bull

                                                                Thulium bull

                                                                Stable thulium used as a radiation

                                                                source

                                                                in portable X-ray

                                                                devices

                                                                Mountain Passbull

                                                                Bastnasite

                                                                is the major REE mineral bull

                                                                High grade accessory mineral of igneous or hydrothermal originsbull

                                                                31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                Mining stopped in 1994 ndash

                                                                Thorium content of waste rock ndash

                                                                Availability of inexpensive REEs

                                                                from China

                                                                San Bernardino County

                                                                Bayan

                                                                Obobull

                                                                The worldrsquos primary source for both yttrium and the rare earth elements

                                                                bull

                                                                37 million tons of ore bull

                                                                Main REE source there is Bastnasite

                                                                World Production

                                                                Explorationbull

                                                                84 of REE imports to US are from China

                                                                bull

                                                                Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                bull

                                                                Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                Lake as well as in

                                                                Malawi Africa

                                                                Environmental Considerations

                                                                bull

                                                                REE soil and food contaminationbull

                                                                Acid Mine Drainage and groundwater systems

                                                                bull

                                                                Radioactive elements

                                                                REE Fertilizerbull

                                                                In China REE enriched fertilizer has been used in crop fields since 1990

                                                                bull

                                                                At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                every year

                                                                bull

                                                                Research and agricultural practice that provides evidence that REEs

                                                                will improve crop quality an yield

                                                                bull

                                                                The ramifications environmental and human exposure to REEs

                                                                are not well understood

                                                                Investigation by T Liang et albull

                                                                Revealed that the average concentration of total REEs

                                                                in Chinese soil is

                                                                1768 mgkg ranging between 850 to 5227 mgkg

                                                                bull

                                                                In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                Implicationsbull

                                                                Human health effects not completely understood

                                                                bull

                                                                REE soil content shown to be detrimental to some plant speciesndash

                                                                100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                Acid Mine Drainage (AMD)bull

                                                                Rain waters contacts waste rock facilitating acid forming reactions

                                                                bull

                                                                Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                bull

                                                                Process mobilizes established ecotoxins

                                                                (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                bull

                                                                Historically dismissed as minor environmental risk

                                                                Radioactive Elements

                                                                bull

                                                                REEs

                                                                associated with uranium and thorium

                                                                bull

                                                                Bastnesite 32 thorium

                                                                bull

                                                                Monazite sands 6 to 12 thorium oxide

                                                                bull

                                                                Ores containing radioactive elements are avoided as sources of REEs

                                                                Radioactive Hazardsbull

                                                                Mountain Pass

                                                                bull

                                                                Accidentsndash

                                                                In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                bull

                                                                Health Effectsndash

                                                                inflammatory bowel disease ndash

                                                                Prolonged seizures ndash

                                                                Cysts ndash

                                                                Cancers

                                                                bull

                                                                Waste Disposal ndash

                                                                Yucca Mountain

                                                                Summarybull

                                                                REE concentrations in the crust are rare

                                                                bull

                                                                Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                bull

                                                                Main REE minerals are bastnasite monazite and xenotime

                                                                bull

                                                                Most important deposits are found at Bayan

                                                                Obo China and Mountain Pass USA

                                                                bull

                                                                Important electronic and nuclear applications

                                                                bull

                                                                Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                system contamination though acid mine drainage association with

                                                                radioactive elements

                                                                Referencesbull

                                                                E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                bull

                                                                Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                bull

                                                                G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                bull

                                                                B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                The Government of South Australia wwwpirsagovaubull

                                                                The US geological Survey Mineralsusgsgovbull

                                                                wwwelementsdatabasecombull

                                                                wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                webmineralcomdataMonazite-(Ce)shtmlbull

                                                                wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                wwwchemicalelementscomelementseuhtmlbull

                                                                boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                lostcontentquakecomfiles200802holmiumpngbull

                                                                chinageocitylocatorcomcitiesChinaQinghaibull

                                                                geowebrudruzal-Bayan-Obohtmbull

                                                                enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                enwikipediaorgwikiMonazitebull

                                                                webmineralcomdataBastnasite-(La)shtmlbull

                                                                wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                httpwwwavalonventurescombull

                                                                wwwnewsweekcomid43884bull

                                                                httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                • Slide Number 1
                                                                • Slide Number 2
                                                                • Slide Number 3
                                                                • Slide Number 4
                                                                • Slide Number 5
                                                                • Slide Number 6
                                                                • Slide Number 7
                                                                • Slide Number 8
                                                                • Slide Number 9
                                                                • Slide Number 10
                                                                • Slide Number 11
                                                                • Slide Number 12
                                                                • Slide Number 13
                                                                • Slide Number 14
                                                                • Slide Number 15
                                                                • Slide Number 16
                                                                • Slide Number 17
                                                                • Slide Number 18
                                                                • Slide Number 19
                                                                • Slide Number 20
                                                                • Slide Number 21
                                                                • Slide Number 22
                                                                • Slide Number 23
                                                                • Slide Number 24
                                                                • Slide Number 25
                                                                • Slide Number 26
                                                                • Slide Number 27
                                                                • Slide Number 28
                                                                • Slide Number 29
                                                                • Slide Number 30
                                                                • Slide Number 31
                                                                • Slide Number 32
                                                                • Slide Number 33
                                                                • Slide Number 34
                                                                • Slide Number 35
                                                                • Slide Number 36
                                                                • Slide Number 37
                                                                • Slide Number 38
                                                                • Slide Number 39
                                                                • Slide Number 40
                                                                • Slide Number 41
                                                                • Slide Number 42
                                                                • Slide Number 43
                                                                • Slide Number 44
                                                                • Slide Number 45
                                                                • Slide Number 46
                                                                • Slide Number 47
                                                                • Slide Number 48
                                                                • Slide Number 49
                                                                • Slide Number 50
                                                                • Slide Number 51
                                                                • Rare Earth Elements
                                                                • Crustal Abundances of Elements
                                                                • Occurrence
                                                                • Rare Earth Minerals
                                                                • REE Minerals
                                                                • Bastnesite
                                                                • Other REE minerals
                                                                • Electron Configuration
                                                                • Electron Configuartion
                                                                • REE Behavior
                                                                • Ionic Radius
                                                                • Coordination Number
                                                                • Coordination Number
                                                                • Other Factors
                                                                • REEs and Economics
                                                                • HREEs and Magnetism
                                                                • Applications in Magnetism
                                                                • Applications in Magnetism
                                                                • HREEs and Nuclear Technology
                                                                • HREEs and Nuclear Technology
                                                                • Mountain Pass
                                                                • Bayan Obo
                                                                • World Production
                                                                • Exploration
                                                                • Environmental Considerations
                                                                • REE Fertilizer
                                                                • Investigation by T Liang et al
                                                                • Implications
                                                                • Acid Mine Drainage (AMD)
                                                                • Radioactive Elements
                                                                • Radioactive Hazards
                                                                • Summary
                                                                • References

                                                                  Occurrencebull

                                                                  REEs

                                                                  occur mostly as

                                                                  substitutional

                                                                  impurities in many rock forming minerals

                                                                  bull

                                                                  Only a few the REE minerals have sufficient quantities to be considered important sources

                                                                  bull

                                                                  Defined as minerals having at least one site that is filled by REEs

                                                                  andor Yttrium more often then any other elementMonazite

                                                                  Rare Earth Minerals

                                                                  bull

                                                                  Form by primary crystalization

                                                                  from magma or by hydrothermal reactions

                                                                  bull

                                                                  Found hosted in carbonate rocks in pegmatites

                                                                  and as accessory minerals in

                                                                  igneous rocks

                                                                  bull

                                                                  Stable REE minerals and can be concentrated in weathering zones

                                                                  REE Mineralsbull

                                                                  The most important REE minerals is bastnaumlsite

                                                                  REE(CO3)F

                                                                  bull

                                                                  Other notable sources are ndash

                                                                  Monazite REE(PO4) ndash

                                                                  Xenotime

                                                                  YPO4

                                                                  bull

                                                                  All may contain radioactive species such as thorium

                                                                  and uraniumndash

                                                                  are avoided as source materials

                                                                  Bastnesitebull

                                                                  Bastnasite

                                                                  [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                                  bull

                                                                  Containing 60 to 70 rare earth oxides (REOs)

                                                                  bull

                                                                  REE site is most commonly filled by LREEs

                                                                  and Y

                                                                  Other REE mineralsbull

                                                                  Monazite [(LREEYTh)PO4] ndash

                                                                  Contains about 50ndash78 rare earth oxides

                                                                  ndash

                                                                  Forms in heavy mineral sands placer deposits associated with beach environments

                                                                  bull

                                                                  Xenotime

                                                                  [(YPO4)] ndash

                                                                  Contains 54ndash65 rare earth oxides

                                                                  ndash

                                                                  Yttrium Erbium and Cerium most common ndash

                                                                  Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                                  Electron Configuration

                                                                  bull

                                                                  The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                                  bull

                                                                  REEs

                                                                  have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                                  Electron Configuartion

                                                                  REE Behaviorbull

                                                                  Because of their shared behaviour REEs

                                                                  tend to be

                                                                  present in nature as a group All REEs

                                                                  commonly substitute for one another in minerals

                                                                  bull

                                                                  Yet the REEs

                                                                  are capable of showing great variation in their distributions

                                                                  bull

                                                                  Comes about due to ndash

                                                                  Differences in ionic radius ndash

                                                                  Crystal structure (Coordination Number)ndash

                                                                  Basicity

                                                                  of the mineral ndash

                                                                  The elementrsquos solubility and ability to migrate in the environment ndash

                                                                  Content of REEs

                                                                  in source fluids

                                                                  Ionic Radiusbull

                                                                  The ionic radius of the REEs

                                                                  is inversely related to atomic number

                                                                  bull

                                                                  The heavy rare earths are smaller ndash

                                                                  more similar to Mn2+ (ionic radius 008 nanometers)

                                                                  bull

                                                                  LREEs

                                                                  are largerndash

                                                                  more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                                  bull

                                                                  Charge balance achieved through some sites being left vacant or

                                                                  by coupled substitution with lower charged mineral (Na+)

                                                                  In nanometers

                                                                  Coordination Number

                                                                  bull

                                                                  Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                  bull

                                                                  Coordination number for this structure is 8

                                                                  Coordination Numberbull

                                                                  The heavy and light REEs

                                                                  differ in the coordination

                                                                  numbers (CN) with oxygenndash

                                                                  HREEs

                                                                  have CN between six to nine ndash

                                                                  LREEs

                                                                  have higher CNs

                                                                  bull

                                                                  Minerals with high CNs

                                                                  associated with REE site

                                                                  will favor LREEsndash

                                                                  Bastnasite

                                                                  CN = 11 ndash

                                                                  Monazite CN = 9

                                                                  bull

                                                                  Those with low CNs

                                                                  will preferentially select HREEs ndash

                                                                  Xenotime

                                                                  has a value of 8

                                                                  Other Factorsbull

                                                                  Minerals basicityndash

                                                                  Alkalic

                                                                  rocks host minerals with elevated LREE content ndash

                                                                  Rocks with lower basicity

                                                                  have lower amounts of LREEs

                                                                  relative to their HREE content

                                                                  bull

                                                                  Solubilityndash

                                                                  LREEs

                                                                  are more soluble in water then the HREEsndash

                                                                  Important characteristic for hydrothermally derived minerals

                                                                  bull

                                                                  MagmaHydrothermal fluid compositionndash

                                                                  Minerals will take what they can get

                                                                  REEs

                                                                  and Economicsbull

                                                                  The REEs

                                                                  and Yttrium have a very broad range of applications mostly in high technology fields

                                                                  bull

                                                                  84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                  bull

                                                                  REEs

                                                                  used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                  HREEs

                                                                  and Magnetism

                                                                  bull

                                                                  HREEs

                                                                  exhibit complex magnetic behaviour on account of electron structurendash

                                                                  They share the same outer shell electron configuration (valence = +3)

                                                                  ndash

                                                                  Differ in number of 4f electrons

                                                                  Applications in Magnetismbull

                                                                  Terbium and

                                                                  Dysprosium

                                                                  bull

                                                                  Components of Terfenol-D

                                                                  alloy

                                                                  with the formula Tb(03) Dy(07) Fe(19)

                                                                  bull

                                                                  Has the higher magnetostriction

                                                                  then any other alloyndash

                                                                  expands and contracts in magnetic field

                                                                  bull

                                                                  Developed by American Navy for sonar

                                                                  systems ndash

                                                                  Now has applications in magnetomechanical

                                                                  sensors and other electronic devices

                                                                  Applications in Magnetism

                                                                  bull

                                                                  Holmium

                                                                  bull

                                                                  Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                  elements

                                                                  bull

                                                                  Creates the strongest artificially generated magnetic fieldsndash

                                                                  In research where strong magnetic fields are needed

                                                                  HREEs

                                                                  and Nuclear Technology

                                                                  bull

                                                                  Dysprosium Homium Erbium

                                                                  bull

                                                                  High neutron

                                                                  absorption cross-section ndash

                                                                  Measure of probability of neutron capture

                                                                  bull

                                                                  Used in neutron-absorbing control rods in nuclear reactors

                                                                  HREEs

                                                                  and Nuclear Technology

                                                                  bull

                                                                  Lutetiumbull

                                                                  Radioactive isotope used in radiometric dating

                                                                  bull

                                                                  Thulium bull

                                                                  Stable thulium used as a radiation

                                                                  source

                                                                  in portable X-ray

                                                                  devices

                                                                  Mountain Passbull

                                                                  Bastnasite

                                                                  is the major REE mineral bull

                                                                  High grade accessory mineral of igneous or hydrothermal originsbull

                                                                  31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                  Mining stopped in 1994 ndash

                                                                  Thorium content of waste rock ndash

                                                                  Availability of inexpensive REEs

                                                                  from China

                                                                  San Bernardino County

                                                                  Bayan

                                                                  Obobull

                                                                  The worldrsquos primary source for both yttrium and the rare earth elements

                                                                  bull

                                                                  37 million tons of ore bull

                                                                  Main REE source there is Bastnasite

                                                                  World Production

                                                                  Explorationbull

                                                                  84 of REE imports to US are from China

                                                                  bull

                                                                  Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                  bull

                                                                  Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                  Lake as well as in

                                                                  Malawi Africa

                                                                  Environmental Considerations

                                                                  bull

                                                                  REE soil and food contaminationbull

                                                                  Acid Mine Drainage and groundwater systems

                                                                  bull

                                                                  Radioactive elements

                                                                  REE Fertilizerbull

                                                                  In China REE enriched fertilizer has been used in crop fields since 1990

                                                                  bull

                                                                  At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                  every year

                                                                  bull

                                                                  Research and agricultural practice that provides evidence that REEs

                                                                  will improve crop quality an yield

                                                                  bull

                                                                  The ramifications environmental and human exposure to REEs

                                                                  are not well understood

                                                                  Investigation by T Liang et albull

                                                                  Revealed that the average concentration of total REEs

                                                                  in Chinese soil is

                                                                  1768 mgkg ranging between 850 to 5227 mgkg

                                                                  bull

                                                                  In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                  Implicationsbull

                                                                  Human health effects not completely understood

                                                                  bull

                                                                  REE soil content shown to be detrimental to some plant speciesndash

                                                                  100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                  Acid Mine Drainage (AMD)bull

                                                                  Rain waters contacts waste rock facilitating acid forming reactions

                                                                  bull

                                                                  Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                  bull

                                                                  Process mobilizes established ecotoxins

                                                                  (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                  bull

                                                                  Historically dismissed as minor environmental risk

                                                                  Radioactive Elements

                                                                  bull

                                                                  REEs

                                                                  associated with uranium and thorium

                                                                  bull

                                                                  Bastnesite 32 thorium

                                                                  bull

                                                                  Monazite sands 6 to 12 thorium oxide

                                                                  bull

                                                                  Ores containing radioactive elements are avoided as sources of REEs

                                                                  Radioactive Hazardsbull

                                                                  Mountain Pass

                                                                  bull

                                                                  Accidentsndash

                                                                  In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                  bull

                                                                  Health Effectsndash

                                                                  inflammatory bowel disease ndash

                                                                  Prolonged seizures ndash

                                                                  Cysts ndash

                                                                  Cancers

                                                                  bull

                                                                  Waste Disposal ndash

                                                                  Yucca Mountain

                                                                  Summarybull

                                                                  REE concentrations in the crust are rare

                                                                  bull

                                                                  Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                  bull

                                                                  Main REE minerals are bastnasite monazite and xenotime

                                                                  bull

                                                                  Most important deposits are found at Bayan

                                                                  Obo China and Mountain Pass USA

                                                                  bull

                                                                  Important electronic and nuclear applications

                                                                  bull

                                                                  Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                  system contamination though acid mine drainage association with

                                                                  radioactive elements

                                                                  Referencesbull

                                                                  E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                  bull

                                                                  Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                  bull

                                                                  G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                  bull

                                                                  B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                  The Government of South Australia wwwpirsagovaubull

                                                                  The US geological Survey Mineralsusgsgovbull

                                                                  wwwelementsdatabasecombull

                                                                  wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                  wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                  webmineralcomdataMonazite-(Ce)shtmlbull

                                                                  wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                  wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                  wwwchemicalelementscomelementseuhtmlbull

                                                                  boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                  lostcontentquakecomfiles200802holmiumpngbull

                                                                  chinageocitylocatorcomcitiesChinaQinghaibull

                                                                  geowebrudruzal-Bayan-Obohtmbull

                                                                  enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                  wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                  enwikipediaorgwikiMonazitebull

                                                                  webmineralcomdataBastnasite-(La)shtmlbull

                                                                  wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                  httpwwwavalonventurescombull

                                                                  wwwnewsweekcomid43884bull

                                                                  httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                  httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                  • Slide Number 1
                                                                  • Slide Number 2
                                                                  • Slide Number 3
                                                                  • Slide Number 4
                                                                  • Slide Number 5
                                                                  • Slide Number 6
                                                                  • Slide Number 7
                                                                  • Slide Number 8
                                                                  • Slide Number 9
                                                                  • Slide Number 10
                                                                  • Slide Number 11
                                                                  • Slide Number 12
                                                                  • Slide Number 13
                                                                  • Slide Number 14
                                                                  • Slide Number 15
                                                                  • Slide Number 16
                                                                  • Slide Number 17
                                                                  • Slide Number 18
                                                                  • Slide Number 19
                                                                  • Slide Number 20
                                                                  • Slide Number 21
                                                                  • Slide Number 22
                                                                  • Slide Number 23
                                                                  • Slide Number 24
                                                                  • Slide Number 25
                                                                  • Slide Number 26
                                                                  • Slide Number 27
                                                                  • Slide Number 28
                                                                  • Slide Number 29
                                                                  • Slide Number 30
                                                                  • Slide Number 31
                                                                  • Slide Number 32
                                                                  • Slide Number 33
                                                                  • Slide Number 34
                                                                  • Slide Number 35
                                                                  • Slide Number 36
                                                                  • Slide Number 37
                                                                  • Slide Number 38
                                                                  • Slide Number 39
                                                                  • Slide Number 40
                                                                  • Slide Number 41
                                                                  • Slide Number 42
                                                                  • Slide Number 43
                                                                  • Slide Number 44
                                                                  • Slide Number 45
                                                                  • Slide Number 46
                                                                  • Slide Number 47
                                                                  • Slide Number 48
                                                                  • Slide Number 49
                                                                  • Slide Number 50
                                                                  • Slide Number 51
                                                                  • Rare Earth Elements
                                                                  • Crustal Abundances of Elements
                                                                  • Occurrence
                                                                  • Rare Earth Minerals
                                                                  • REE Minerals
                                                                  • Bastnesite
                                                                  • Other REE minerals
                                                                  • Electron Configuration
                                                                  • Electron Configuartion
                                                                  • REE Behavior
                                                                  • Ionic Radius
                                                                  • Coordination Number
                                                                  • Coordination Number
                                                                  • Other Factors
                                                                  • REEs and Economics
                                                                  • HREEs and Magnetism
                                                                  • Applications in Magnetism
                                                                  • Applications in Magnetism
                                                                  • HREEs and Nuclear Technology
                                                                  • HREEs and Nuclear Technology
                                                                  • Mountain Pass
                                                                  • Bayan Obo
                                                                  • World Production
                                                                  • Exploration
                                                                  • Environmental Considerations
                                                                  • REE Fertilizer
                                                                  • Investigation by T Liang et al
                                                                  • Implications
                                                                  • Acid Mine Drainage (AMD)
                                                                  • Radioactive Elements
                                                                  • Radioactive Hazards
                                                                  • Summary
                                                                  • References

                                                                    Rare Earth Minerals

                                                                    bull

                                                                    Form by primary crystalization

                                                                    from magma or by hydrothermal reactions

                                                                    bull

                                                                    Found hosted in carbonate rocks in pegmatites

                                                                    and as accessory minerals in

                                                                    igneous rocks

                                                                    bull

                                                                    Stable REE minerals and can be concentrated in weathering zones

                                                                    REE Mineralsbull

                                                                    The most important REE minerals is bastnaumlsite

                                                                    REE(CO3)F

                                                                    bull

                                                                    Other notable sources are ndash

                                                                    Monazite REE(PO4) ndash

                                                                    Xenotime

                                                                    YPO4

                                                                    bull

                                                                    All may contain radioactive species such as thorium

                                                                    and uraniumndash

                                                                    are avoided as source materials

                                                                    Bastnesitebull

                                                                    Bastnasite

                                                                    [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                                    bull

                                                                    Containing 60 to 70 rare earth oxides (REOs)

                                                                    bull

                                                                    REE site is most commonly filled by LREEs

                                                                    and Y

                                                                    Other REE mineralsbull

                                                                    Monazite [(LREEYTh)PO4] ndash

                                                                    Contains about 50ndash78 rare earth oxides

                                                                    ndash

                                                                    Forms in heavy mineral sands placer deposits associated with beach environments

                                                                    bull

                                                                    Xenotime

                                                                    [(YPO4)] ndash

                                                                    Contains 54ndash65 rare earth oxides

                                                                    ndash

                                                                    Yttrium Erbium and Cerium most common ndash

                                                                    Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                                    Electron Configuration

                                                                    bull

                                                                    The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                                    bull

                                                                    REEs

                                                                    have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                                    Electron Configuartion

                                                                    REE Behaviorbull

                                                                    Because of their shared behaviour REEs

                                                                    tend to be

                                                                    present in nature as a group All REEs

                                                                    commonly substitute for one another in minerals

                                                                    bull

                                                                    Yet the REEs

                                                                    are capable of showing great variation in their distributions

                                                                    bull

                                                                    Comes about due to ndash

                                                                    Differences in ionic radius ndash

                                                                    Crystal structure (Coordination Number)ndash

                                                                    Basicity

                                                                    of the mineral ndash

                                                                    The elementrsquos solubility and ability to migrate in the environment ndash

                                                                    Content of REEs

                                                                    in source fluids

                                                                    Ionic Radiusbull

                                                                    The ionic radius of the REEs

                                                                    is inversely related to atomic number

                                                                    bull

                                                                    The heavy rare earths are smaller ndash

                                                                    more similar to Mn2+ (ionic radius 008 nanometers)

                                                                    bull

                                                                    LREEs

                                                                    are largerndash

                                                                    more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                                    bull

                                                                    Charge balance achieved through some sites being left vacant or

                                                                    by coupled substitution with lower charged mineral (Na+)

                                                                    In nanometers

                                                                    Coordination Number

                                                                    bull

                                                                    Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                    bull

                                                                    Coordination number for this structure is 8

                                                                    Coordination Numberbull

                                                                    The heavy and light REEs

                                                                    differ in the coordination

                                                                    numbers (CN) with oxygenndash

                                                                    HREEs

                                                                    have CN between six to nine ndash

                                                                    LREEs

                                                                    have higher CNs

                                                                    bull

                                                                    Minerals with high CNs

                                                                    associated with REE site

                                                                    will favor LREEsndash

                                                                    Bastnasite

                                                                    CN = 11 ndash

                                                                    Monazite CN = 9

                                                                    bull

                                                                    Those with low CNs

                                                                    will preferentially select HREEs ndash

                                                                    Xenotime

                                                                    has a value of 8

                                                                    Other Factorsbull

                                                                    Minerals basicityndash

                                                                    Alkalic

                                                                    rocks host minerals with elevated LREE content ndash

                                                                    Rocks with lower basicity

                                                                    have lower amounts of LREEs

                                                                    relative to their HREE content

                                                                    bull

                                                                    Solubilityndash

                                                                    LREEs

                                                                    are more soluble in water then the HREEsndash

                                                                    Important characteristic for hydrothermally derived minerals

                                                                    bull

                                                                    MagmaHydrothermal fluid compositionndash

                                                                    Minerals will take what they can get

                                                                    REEs

                                                                    and Economicsbull

                                                                    The REEs

                                                                    and Yttrium have a very broad range of applications mostly in high technology fields

                                                                    bull

                                                                    84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                    bull

                                                                    REEs

                                                                    used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                    HREEs

                                                                    and Magnetism

                                                                    bull

                                                                    HREEs

                                                                    exhibit complex magnetic behaviour on account of electron structurendash

                                                                    They share the same outer shell electron configuration (valence = +3)

                                                                    ndash

                                                                    Differ in number of 4f electrons

                                                                    Applications in Magnetismbull

                                                                    Terbium and

                                                                    Dysprosium

                                                                    bull

                                                                    Components of Terfenol-D

                                                                    alloy

                                                                    with the formula Tb(03) Dy(07) Fe(19)

                                                                    bull

                                                                    Has the higher magnetostriction

                                                                    then any other alloyndash

                                                                    expands and contracts in magnetic field

                                                                    bull

                                                                    Developed by American Navy for sonar

                                                                    systems ndash

                                                                    Now has applications in magnetomechanical

                                                                    sensors and other electronic devices

                                                                    Applications in Magnetism

                                                                    bull

                                                                    Holmium

                                                                    bull

                                                                    Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                    elements

                                                                    bull

                                                                    Creates the strongest artificially generated magnetic fieldsndash

                                                                    In research where strong magnetic fields are needed

                                                                    HREEs

                                                                    and Nuclear Technology

                                                                    bull

                                                                    Dysprosium Homium Erbium

                                                                    bull

                                                                    High neutron

                                                                    absorption cross-section ndash

                                                                    Measure of probability of neutron capture

                                                                    bull

                                                                    Used in neutron-absorbing control rods in nuclear reactors

                                                                    HREEs

                                                                    and Nuclear Technology

                                                                    bull

                                                                    Lutetiumbull

                                                                    Radioactive isotope used in radiometric dating

                                                                    bull

                                                                    Thulium bull

                                                                    Stable thulium used as a radiation

                                                                    source

                                                                    in portable X-ray

                                                                    devices

                                                                    Mountain Passbull

                                                                    Bastnasite

                                                                    is the major REE mineral bull

                                                                    High grade accessory mineral of igneous or hydrothermal originsbull

                                                                    31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                    Mining stopped in 1994 ndash

                                                                    Thorium content of waste rock ndash

                                                                    Availability of inexpensive REEs

                                                                    from China

                                                                    San Bernardino County

                                                                    Bayan

                                                                    Obobull

                                                                    The worldrsquos primary source for both yttrium and the rare earth elements

                                                                    bull

                                                                    37 million tons of ore bull

                                                                    Main REE source there is Bastnasite

                                                                    World Production

                                                                    Explorationbull

                                                                    84 of REE imports to US are from China

                                                                    bull

                                                                    Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                    bull

                                                                    Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                    Lake as well as in

                                                                    Malawi Africa

                                                                    Environmental Considerations

                                                                    bull

                                                                    REE soil and food contaminationbull

                                                                    Acid Mine Drainage and groundwater systems

                                                                    bull

                                                                    Radioactive elements

                                                                    REE Fertilizerbull

                                                                    In China REE enriched fertilizer has been used in crop fields since 1990

                                                                    bull

                                                                    At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                    every year

                                                                    bull

                                                                    Research and agricultural practice that provides evidence that REEs

                                                                    will improve crop quality an yield

                                                                    bull

                                                                    The ramifications environmental and human exposure to REEs

                                                                    are not well understood

                                                                    Investigation by T Liang et albull

                                                                    Revealed that the average concentration of total REEs

                                                                    in Chinese soil is

                                                                    1768 mgkg ranging between 850 to 5227 mgkg

                                                                    bull

                                                                    In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                    Implicationsbull

                                                                    Human health effects not completely understood

                                                                    bull

                                                                    REE soil content shown to be detrimental to some plant speciesndash

                                                                    100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                    Acid Mine Drainage (AMD)bull

                                                                    Rain waters contacts waste rock facilitating acid forming reactions

                                                                    bull

                                                                    Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                    bull

                                                                    Process mobilizes established ecotoxins

                                                                    (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                    bull

                                                                    Historically dismissed as minor environmental risk

                                                                    Radioactive Elements

                                                                    bull

                                                                    REEs

                                                                    associated with uranium and thorium

                                                                    bull

                                                                    Bastnesite 32 thorium

                                                                    bull

                                                                    Monazite sands 6 to 12 thorium oxide

                                                                    bull

                                                                    Ores containing radioactive elements are avoided as sources of REEs

                                                                    Radioactive Hazardsbull

                                                                    Mountain Pass

                                                                    bull

                                                                    Accidentsndash

                                                                    In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                    bull

                                                                    Health Effectsndash

                                                                    inflammatory bowel disease ndash

                                                                    Prolonged seizures ndash

                                                                    Cysts ndash

                                                                    Cancers

                                                                    bull

                                                                    Waste Disposal ndash

                                                                    Yucca Mountain

                                                                    Summarybull

                                                                    REE concentrations in the crust are rare

                                                                    bull

                                                                    Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                    bull

                                                                    Main REE minerals are bastnasite monazite and xenotime

                                                                    bull

                                                                    Most important deposits are found at Bayan

                                                                    Obo China and Mountain Pass USA

                                                                    bull

                                                                    Important electronic and nuclear applications

                                                                    bull

                                                                    Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                    system contamination though acid mine drainage association with

                                                                    radioactive elements

                                                                    Referencesbull

                                                                    E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                    bull

                                                                    Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                    bull

                                                                    G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                    bull

                                                                    B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                    The Government of South Australia wwwpirsagovaubull

                                                                    The US geological Survey Mineralsusgsgovbull

                                                                    wwwelementsdatabasecombull

                                                                    wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                    wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                    webmineralcomdataMonazite-(Ce)shtmlbull

                                                                    wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                    wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                    wwwchemicalelementscomelementseuhtmlbull

                                                                    boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                    lostcontentquakecomfiles200802holmiumpngbull

                                                                    chinageocitylocatorcomcitiesChinaQinghaibull

                                                                    geowebrudruzal-Bayan-Obohtmbull

                                                                    enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                    wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                    enwikipediaorgwikiMonazitebull

                                                                    webmineralcomdataBastnasite-(La)shtmlbull

                                                                    wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                    httpwwwavalonventurescombull

                                                                    wwwnewsweekcomid43884bull

                                                                    httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                    httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                    • Slide Number 1
                                                                    • Slide Number 2
                                                                    • Slide Number 3
                                                                    • Slide Number 4
                                                                    • Slide Number 5
                                                                    • Slide Number 6
                                                                    • Slide Number 7
                                                                    • Slide Number 8
                                                                    • Slide Number 9
                                                                    • Slide Number 10
                                                                    • Slide Number 11
                                                                    • Slide Number 12
                                                                    • Slide Number 13
                                                                    • Slide Number 14
                                                                    • Slide Number 15
                                                                    • Slide Number 16
                                                                    • Slide Number 17
                                                                    • Slide Number 18
                                                                    • Slide Number 19
                                                                    • Slide Number 20
                                                                    • Slide Number 21
                                                                    • Slide Number 22
                                                                    • Slide Number 23
                                                                    • Slide Number 24
                                                                    • Slide Number 25
                                                                    • Slide Number 26
                                                                    • Slide Number 27
                                                                    • Slide Number 28
                                                                    • Slide Number 29
                                                                    • Slide Number 30
                                                                    • Slide Number 31
                                                                    • Slide Number 32
                                                                    • Slide Number 33
                                                                    • Slide Number 34
                                                                    • Slide Number 35
                                                                    • Slide Number 36
                                                                    • Slide Number 37
                                                                    • Slide Number 38
                                                                    • Slide Number 39
                                                                    • Slide Number 40
                                                                    • Slide Number 41
                                                                    • Slide Number 42
                                                                    • Slide Number 43
                                                                    • Slide Number 44
                                                                    • Slide Number 45
                                                                    • Slide Number 46
                                                                    • Slide Number 47
                                                                    • Slide Number 48
                                                                    • Slide Number 49
                                                                    • Slide Number 50
                                                                    • Slide Number 51
                                                                    • Rare Earth Elements
                                                                    • Crustal Abundances of Elements
                                                                    • Occurrence
                                                                    • Rare Earth Minerals
                                                                    • REE Minerals
                                                                    • Bastnesite
                                                                    • Other REE minerals
                                                                    • Electron Configuration
                                                                    • Electron Configuartion
                                                                    • REE Behavior
                                                                    • Ionic Radius
                                                                    • Coordination Number
                                                                    • Coordination Number
                                                                    • Other Factors
                                                                    • REEs and Economics
                                                                    • HREEs and Magnetism
                                                                    • Applications in Magnetism
                                                                    • Applications in Magnetism
                                                                    • HREEs and Nuclear Technology
                                                                    • HREEs and Nuclear Technology
                                                                    • Mountain Pass
                                                                    • Bayan Obo
                                                                    • World Production
                                                                    • Exploration
                                                                    • Environmental Considerations
                                                                    • REE Fertilizer
                                                                    • Investigation by T Liang et al
                                                                    • Implications
                                                                    • Acid Mine Drainage (AMD)
                                                                    • Radioactive Elements
                                                                    • Radioactive Hazards
                                                                    • Summary
                                                                    • References

                                                                      REE Mineralsbull

                                                                      The most important REE minerals is bastnaumlsite

                                                                      REE(CO3)F

                                                                      bull

                                                                      Other notable sources are ndash

                                                                      Monazite REE(PO4) ndash

                                                                      Xenotime

                                                                      YPO4

                                                                      bull

                                                                      All may contain radioactive species such as thorium

                                                                      and uraniumndash

                                                                      are avoided as source materials

                                                                      Bastnesitebull

                                                                      Bastnasite

                                                                      [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                                      bull

                                                                      Containing 60 to 70 rare earth oxides (REOs)

                                                                      bull

                                                                      REE site is most commonly filled by LREEs

                                                                      and Y

                                                                      Other REE mineralsbull

                                                                      Monazite [(LREEYTh)PO4] ndash

                                                                      Contains about 50ndash78 rare earth oxides

                                                                      ndash

                                                                      Forms in heavy mineral sands placer deposits associated with beach environments

                                                                      bull

                                                                      Xenotime

                                                                      [(YPO4)] ndash

                                                                      Contains 54ndash65 rare earth oxides

                                                                      ndash

                                                                      Yttrium Erbium and Cerium most common ndash

                                                                      Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                                      Electron Configuration

                                                                      bull

                                                                      The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                                      bull

                                                                      REEs

                                                                      have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                                      Electron Configuartion

                                                                      REE Behaviorbull

                                                                      Because of their shared behaviour REEs

                                                                      tend to be

                                                                      present in nature as a group All REEs

                                                                      commonly substitute for one another in minerals

                                                                      bull

                                                                      Yet the REEs

                                                                      are capable of showing great variation in their distributions

                                                                      bull

                                                                      Comes about due to ndash

                                                                      Differences in ionic radius ndash

                                                                      Crystal structure (Coordination Number)ndash

                                                                      Basicity

                                                                      of the mineral ndash

                                                                      The elementrsquos solubility and ability to migrate in the environment ndash

                                                                      Content of REEs

                                                                      in source fluids

                                                                      Ionic Radiusbull

                                                                      The ionic radius of the REEs

                                                                      is inversely related to atomic number

                                                                      bull

                                                                      The heavy rare earths are smaller ndash

                                                                      more similar to Mn2+ (ionic radius 008 nanometers)

                                                                      bull

                                                                      LREEs

                                                                      are largerndash

                                                                      more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                                      bull

                                                                      Charge balance achieved through some sites being left vacant or

                                                                      by coupled substitution with lower charged mineral (Na+)

                                                                      In nanometers

                                                                      Coordination Number

                                                                      bull

                                                                      Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                      bull

                                                                      Coordination number for this structure is 8

                                                                      Coordination Numberbull

                                                                      The heavy and light REEs

                                                                      differ in the coordination

                                                                      numbers (CN) with oxygenndash

                                                                      HREEs

                                                                      have CN between six to nine ndash

                                                                      LREEs

                                                                      have higher CNs

                                                                      bull

                                                                      Minerals with high CNs

                                                                      associated with REE site

                                                                      will favor LREEsndash

                                                                      Bastnasite

                                                                      CN = 11 ndash

                                                                      Monazite CN = 9

                                                                      bull

                                                                      Those with low CNs

                                                                      will preferentially select HREEs ndash

                                                                      Xenotime

                                                                      has a value of 8

                                                                      Other Factorsbull

                                                                      Minerals basicityndash

                                                                      Alkalic

                                                                      rocks host minerals with elevated LREE content ndash

                                                                      Rocks with lower basicity

                                                                      have lower amounts of LREEs

                                                                      relative to their HREE content

                                                                      bull

                                                                      Solubilityndash

                                                                      LREEs

                                                                      are more soluble in water then the HREEsndash

                                                                      Important characteristic for hydrothermally derived minerals

                                                                      bull

                                                                      MagmaHydrothermal fluid compositionndash

                                                                      Minerals will take what they can get

                                                                      REEs

                                                                      and Economicsbull

                                                                      The REEs

                                                                      and Yttrium have a very broad range of applications mostly in high technology fields

                                                                      bull

                                                                      84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                      bull

                                                                      REEs

                                                                      used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                      HREEs

                                                                      and Magnetism

                                                                      bull

                                                                      HREEs

                                                                      exhibit complex magnetic behaviour on account of electron structurendash

                                                                      They share the same outer shell electron configuration (valence = +3)

                                                                      ndash

                                                                      Differ in number of 4f electrons

                                                                      Applications in Magnetismbull

                                                                      Terbium and

                                                                      Dysprosium

                                                                      bull

                                                                      Components of Terfenol-D

                                                                      alloy

                                                                      with the formula Tb(03) Dy(07) Fe(19)

                                                                      bull

                                                                      Has the higher magnetostriction

                                                                      then any other alloyndash

                                                                      expands and contracts in magnetic field

                                                                      bull

                                                                      Developed by American Navy for sonar

                                                                      systems ndash

                                                                      Now has applications in magnetomechanical

                                                                      sensors and other electronic devices

                                                                      Applications in Magnetism

                                                                      bull

                                                                      Holmium

                                                                      bull

                                                                      Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                      elements

                                                                      bull

                                                                      Creates the strongest artificially generated magnetic fieldsndash

                                                                      In research where strong magnetic fields are needed

                                                                      HREEs

                                                                      and Nuclear Technology

                                                                      bull

                                                                      Dysprosium Homium Erbium

                                                                      bull

                                                                      High neutron

                                                                      absorption cross-section ndash

                                                                      Measure of probability of neutron capture

                                                                      bull

                                                                      Used in neutron-absorbing control rods in nuclear reactors

                                                                      HREEs

                                                                      and Nuclear Technology

                                                                      bull

                                                                      Lutetiumbull

                                                                      Radioactive isotope used in radiometric dating

                                                                      bull

                                                                      Thulium bull

                                                                      Stable thulium used as a radiation

                                                                      source

                                                                      in portable X-ray

                                                                      devices

                                                                      Mountain Passbull

                                                                      Bastnasite

                                                                      is the major REE mineral bull

                                                                      High grade accessory mineral of igneous or hydrothermal originsbull

                                                                      31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                      Mining stopped in 1994 ndash

                                                                      Thorium content of waste rock ndash

                                                                      Availability of inexpensive REEs

                                                                      from China

                                                                      San Bernardino County

                                                                      Bayan

                                                                      Obobull

                                                                      The worldrsquos primary source for both yttrium and the rare earth elements

                                                                      bull

                                                                      37 million tons of ore bull

                                                                      Main REE source there is Bastnasite

                                                                      World Production

                                                                      Explorationbull

                                                                      84 of REE imports to US are from China

                                                                      bull

                                                                      Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                      bull

                                                                      Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                      Lake as well as in

                                                                      Malawi Africa

                                                                      Environmental Considerations

                                                                      bull

                                                                      REE soil and food contaminationbull

                                                                      Acid Mine Drainage and groundwater systems

                                                                      bull

                                                                      Radioactive elements

                                                                      REE Fertilizerbull

                                                                      In China REE enriched fertilizer has been used in crop fields since 1990

                                                                      bull

                                                                      At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                      every year

                                                                      bull

                                                                      Research and agricultural practice that provides evidence that REEs

                                                                      will improve crop quality an yield

                                                                      bull

                                                                      The ramifications environmental and human exposure to REEs

                                                                      are not well understood

                                                                      Investigation by T Liang et albull

                                                                      Revealed that the average concentration of total REEs

                                                                      in Chinese soil is

                                                                      1768 mgkg ranging between 850 to 5227 mgkg

                                                                      bull

                                                                      In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                      Implicationsbull

                                                                      Human health effects not completely understood

                                                                      bull

                                                                      REE soil content shown to be detrimental to some plant speciesndash

                                                                      100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                      Acid Mine Drainage (AMD)bull

                                                                      Rain waters contacts waste rock facilitating acid forming reactions

                                                                      bull

                                                                      Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                      bull

                                                                      Process mobilizes established ecotoxins

                                                                      (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                      bull

                                                                      Historically dismissed as minor environmental risk

                                                                      Radioactive Elements

                                                                      bull

                                                                      REEs

                                                                      associated with uranium and thorium

                                                                      bull

                                                                      Bastnesite 32 thorium

                                                                      bull

                                                                      Monazite sands 6 to 12 thorium oxide

                                                                      bull

                                                                      Ores containing radioactive elements are avoided as sources of REEs

                                                                      Radioactive Hazardsbull

                                                                      Mountain Pass

                                                                      bull

                                                                      Accidentsndash

                                                                      In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                      bull

                                                                      Health Effectsndash

                                                                      inflammatory bowel disease ndash

                                                                      Prolonged seizures ndash

                                                                      Cysts ndash

                                                                      Cancers

                                                                      bull

                                                                      Waste Disposal ndash

                                                                      Yucca Mountain

                                                                      Summarybull

                                                                      REE concentrations in the crust are rare

                                                                      bull

                                                                      Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                      bull

                                                                      Main REE minerals are bastnasite monazite and xenotime

                                                                      bull

                                                                      Most important deposits are found at Bayan

                                                                      Obo China and Mountain Pass USA

                                                                      bull

                                                                      Important electronic and nuclear applications

                                                                      bull

                                                                      Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                      system contamination though acid mine drainage association with

                                                                      radioactive elements

                                                                      Referencesbull

                                                                      E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                      bull

                                                                      Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                      bull

                                                                      G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                      bull

                                                                      B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                      The Government of South Australia wwwpirsagovaubull

                                                                      The US geological Survey Mineralsusgsgovbull

                                                                      wwwelementsdatabasecombull

                                                                      wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                      wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                      webmineralcomdataMonazite-(Ce)shtmlbull

                                                                      wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                      wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                      wwwchemicalelementscomelementseuhtmlbull

                                                                      boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                      lostcontentquakecomfiles200802holmiumpngbull

                                                                      chinageocitylocatorcomcitiesChinaQinghaibull

                                                                      geowebrudruzal-Bayan-Obohtmbull

                                                                      enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                      wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                      enwikipediaorgwikiMonazitebull

                                                                      webmineralcomdataBastnasite-(La)shtmlbull

                                                                      wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                      httpwwwavalonventurescombull

                                                                      wwwnewsweekcomid43884bull

                                                                      httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                      httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                      • Slide Number 1
                                                                      • Slide Number 2
                                                                      • Slide Number 3
                                                                      • Slide Number 4
                                                                      • Slide Number 5
                                                                      • Slide Number 6
                                                                      • Slide Number 7
                                                                      • Slide Number 8
                                                                      • Slide Number 9
                                                                      • Slide Number 10
                                                                      • Slide Number 11
                                                                      • Slide Number 12
                                                                      • Slide Number 13
                                                                      • Slide Number 14
                                                                      • Slide Number 15
                                                                      • Slide Number 16
                                                                      • Slide Number 17
                                                                      • Slide Number 18
                                                                      • Slide Number 19
                                                                      • Slide Number 20
                                                                      • Slide Number 21
                                                                      • Slide Number 22
                                                                      • Slide Number 23
                                                                      • Slide Number 24
                                                                      • Slide Number 25
                                                                      • Slide Number 26
                                                                      • Slide Number 27
                                                                      • Slide Number 28
                                                                      • Slide Number 29
                                                                      • Slide Number 30
                                                                      • Slide Number 31
                                                                      • Slide Number 32
                                                                      • Slide Number 33
                                                                      • Slide Number 34
                                                                      • Slide Number 35
                                                                      • Slide Number 36
                                                                      • Slide Number 37
                                                                      • Slide Number 38
                                                                      • Slide Number 39
                                                                      • Slide Number 40
                                                                      • Slide Number 41
                                                                      • Slide Number 42
                                                                      • Slide Number 43
                                                                      • Slide Number 44
                                                                      • Slide Number 45
                                                                      • Slide Number 46
                                                                      • Slide Number 47
                                                                      • Slide Number 48
                                                                      • Slide Number 49
                                                                      • Slide Number 50
                                                                      • Slide Number 51
                                                                      • Rare Earth Elements
                                                                      • Crustal Abundances of Elements
                                                                      • Occurrence
                                                                      • Rare Earth Minerals
                                                                      • REE Minerals
                                                                      • Bastnesite
                                                                      • Other REE minerals
                                                                      • Electron Configuration
                                                                      • Electron Configuartion
                                                                      • REE Behavior
                                                                      • Ionic Radius
                                                                      • Coordination Number
                                                                      • Coordination Number
                                                                      • Other Factors
                                                                      • REEs and Economics
                                                                      • HREEs and Magnetism
                                                                      • Applications in Magnetism
                                                                      • Applications in Magnetism
                                                                      • HREEs and Nuclear Technology
                                                                      • HREEs and Nuclear Technology
                                                                      • Mountain Pass
                                                                      • Bayan Obo
                                                                      • World Production
                                                                      • Exploration
                                                                      • Environmental Considerations
                                                                      • REE Fertilizer
                                                                      • Investigation by T Liang et al
                                                                      • Implications
                                                                      • Acid Mine Drainage (AMD)
                                                                      • Radioactive Elements
                                                                      • Radioactive Hazards
                                                                      • Summary
                                                                      • References

                                                                        Bastnesitebull

                                                                        Bastnasite

                                                                        [(REE)(CO3)F] is the worldrsquos most important source of rare earth elements

                                                                        bull

                                                                        Containing 60 to 70 rare earth oxides (REOs)

                                                                        bull

                                                                        REE site is most commonly filled by LREEs

                                                                        and Y

                                                                        Other REE mineralsbull

                                                                        Monazite [(LREEYTh)PO4] ndash

                                                                        Contains about 50ndash78 rare earth oxides

                                                                        ndash

                                                                        Forms in heavy mineral sands placer deposits associated with beach environments

                                                                        bull

                                                                        Xenotime

                                                                        [(YPO4)] ndash

                                                                        Contains 54ndash65 rare earth oxides

                                                                        ndash

                                                                        Yttrium Erbium and Cerium most common ndash

                                                                        Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                                        Electron Configuration

                                                                        bull

                                                                        The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                                        bull

                                                                        REEs

                                                                        have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                                        Electron Configuartion

                                                                        REE Behaviorbull

                                                                        Because of their shared behaviour REEs

                                                                        tend to be

                                                                        present in nature as a group All REEs

                                                                        commonly substitute for one another in minerals

                                                                        bull

                                                                        Yet the REEs

                                                                        are capable of showing great variation in their distributions

                                                                        bull

                                                                        Comes about due to ndash

                                                                        Differences in ionic radius ndash

                                                                        Crystal structure (Coordination Number)ndash

                                                                        Basicity

                                                                        of the mineral ndash

                                                                        The elementrsquos solubility and ability to migrate in the environment ndash

                                                                        Content of REEs

                                                                        in source fluids

                                                                        Ionic Radiusbull

                                                                        The ionic radius of the REEs

                                                                        is inversely related to atomic number

                                                                        bull

                                                                        The heavy rare earths are smaller ndash

                                                                        more similar to Mn2+ (ionic radius 008 nanometers)

                                                                        bull

                                                                        LREEs

                                                                        are largerndash

                                                                        more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                                        bull

                                                                        Charge balance achieved through some sites being left vacant or

                                                                        by coupled substitution with lower charged mineral (Na+)

                                                                        In nanometers

                                                                        Coordination Number

                                                                        bull

                                                                        Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                        bull

                                                                        Coordination number for this structure is 8

                                                                        Coordination Numberbull

                                                                        The heavy and light REEs

                                                                        differ in the coordination

                                                                        numbers (CN) with oxygenndash

                                                                        HREEs

                                                                        have CN between six to nine ndash

                                                                        LREEs

                                                                        have higher CNs

                                                                        bull

                                                                        Minerals with high CNs

                                                                        associated with REE site

                                                                        will favor LREEsndash

                                                                        Bastnasite

                                                                        CN = 11 ndash

                                                                        Monazite CN = 9

                                                                        bull

                                                                        Those with low CNs

                                                                        will preferentially select HREEs ndash

                                                                        Xenotime

                                                                        has a value of 8

                                                                        Other Factorsbull

                                                                        Minerals basicityndash

                                                                        Alkalic

                                                                        rocks host minerals with elevated LREE content ndash

                                                                        Rocks with lower basicity

                                                                        have lower amounts of LREEs

                                                                        relative to their HREE content

                                                                        bull

                                                                        Solubilityndash

                                                                        LREEs

                                                                        are more soluble in water then the HREEsndash

                                                                        Important characteristic for hydrothermally derived minerals

                                                                        bull

                                                                        MagmaHydrothermal fluid compositionndash

                                                                        Minerals will take what they can get

                                                                        REEs

                                                                        and Economicsbull

                                                                        The REEs

                                                                        and Yttrium have a very broad range of applications mostly in high technology fields

                                                                        bull

                                                                        84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                        bull

                                                                        REEs

                                                                        used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                        HREEs

                                                                        and Magnetism

                                                                        bull

                                                                        HREEs

                                                                        exhibit complex magnetic behaviour on account of electron structurendash

                                                                        They share the same outer shell electron configuration (valence = +3)

                                                                        ndash

                                                                        Differ in number of 4f electrons

                                                                        Applications in Magnetismbull

                                                                        Terbium and

                                                                        Dysprosium

                                                                        bull

                                                                        Components of Terfenol-D

                                                                        alloy

                                                                        with the formula Tb(03) Dy(07) Fe(19)

                                                                        bull

                                                                        Has the higher magnetostriction

                                                                        then any other alloyndash

                                                                        expands and contracts in magnetic field

                                                                        bull

                                                                        Developed by American Navy for sonar

                                                                        systems ndash

                                                                        Now has applications in magnetomechanical

                                                                        sensors and other electronic devices

                                                                        Applications in Magnetism

                                                                        bull

                                                                        Holmium

                                                                        bull

                                                                        Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                        elements

                                                                        bull

                                                                        Creates the strongest artificially generated magnetic fieldsndash

                                                                        In research where strong magnetic fields are needed

                                                                        HREEs

                                                                        and Nuclear Technology

                                                                        bull

                                                                        Dysprosium Homium Erbium

                                                                        bull

                                                                        High neutron

                                                                        absorption cross-section ndash

                                                                        Measure of probability of neutron capture

                                                                        bull

                                                                        Used in neutron-absorbing control rods in nuclear reactors

                                                                        HREEs

                                                                        and Nuclear Technology

                                                                        bull

                                                                        Lutetiumbull

                                                                        Radioactive isotope used in radiometric dating

                                                                        bull

                                                                        Thulium bull

                                                                        Stable thulium used as a radiation

                                                                        source

                                                                        in portable X-ray

                                                                        devices

                                                                        Mountain Passbull

                                                                        Bastnasite

                                                                        is the major REE mineral bull

                                                                        High grade accessory mineral of igneous or hydrothermal originsbull

                                                                        31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                        Mining stopped in 1994 ndash

                                                                        Thorium content of waste rock ndash

                                                                        Availability of inexpensive REEs

                                                                        from China

                                                                        San Bernardino County

                                                                        Bayan

                                                                        Obobull

                                                                        The worldrsquos primary source for both yttrium and the rare earth elements

                                                                        bull

                                                                        37 million tons of ore bull

                                                                        Main REE source there is Bastnasite

                                                                        World Production

                                                                        Explorationbull

                                                                        84 of REE imports to US are from China

                                                                        bull

                                                                        Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                        bull

                                                                        Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                        Lake as well as in

                                                                        Malawi Africa

                                                                        Environmental Considerations

                                                                        bull

                                                                        REE soil and food contaminationbull

                                                                        Acid Mine Drainage and groundwater systems

                                                                        bull

                                                                        Radioactive elements

                                                                        REE Fertilizerbull

                                                                        In China REE enriched fertilizer has been used in crop fields since 1990

                                                                        bull

                                                                        At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                        every year

                                                                        bull

                                                                        Research and agricultural practice that provides evidence that REEs

                                                                        will improve crop quality an yield

                                                                        bull

                                                                        The ramifications environmental and human exposure to REEs

                                                                        are not well understood

                                                                        Investigation by T Liang et albull

                                                                        Revealed that the average concentration of total REEs

                                                                        in Chinese soil is

                                                                        1768 mgkg ranging between 850 to 5227 mgkg

                                                                        bull

                                                                        In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                        Implicationsbull

                                                                        Human health effects not completely understood

                                                                        bull

                                                                        REE soil content shown to be detrimental to some plant speciesndash

                                                                        100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                        Acid Mine Drainage (AMD)bull

                                                                        Rain waters contacts waste rock facilitating acid forming reactions

                                                                        bull

                                                                        Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                        bull

                                                                        Process mobilizes established ecotoxins

                                                                        (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                        bull

                                                                        Historically dismissed as minor environmental risk

                                                                        Radioactive Elements

                                                                        bull

                                                                        REEs

                                                                        associated with uranium and thorium

                                                                        bull

                                                                        Bastnesite 32 thorium

                                                                        bull

                                                                        Monazite sands 6 to 12 thorium oxide

                                                                        bull

                                                                        Ores containing radioactive elements are avoided as sources of REEs

                                                                        Radioactive Hazardsbull

                                                                        Mountain Pass

                                                                        bull

                                                                        Accidentsndash

                                                                        In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                        bull

                                                                        Health Effectsndash

                                                                        inflammatory bowel disease ndash

                                                                        Prolonged seizures ndash

                                                                        Cysts ndash

                                                                        Cancers

                                                                        bull

                                                                        Waste Disposal ndash

                                                                        Yucca Mountain

                                                                        Summarybull

                                                                        REE concentrations in the crust are rare

                                                                        bull

                                                                        Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                        bull

                                                                        Main REE minerals are bastnasite monazite and xenotime

                                                                        bull

                                                                        Most important deposits are found at Bayan

                                                                        Obo China and Mountain Pass USA

                                                                        bull

                                                                        Important electronic and nuclear applications

                                                                        bull

                                                                        Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                        system contamination though acid mine drainage association with

                                                                        radioactive elements

                                                                        Referencesbull

                                                                        E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                        bull

                                                                        Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                        bull

                                                                        G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                        bull

                                                                        B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                        The Government of South Australia wwwpirsagovaubull

                                                                        The US geological Survey Mineralsusgsgovbull

                                                                        wwwelementsdatabasecombull

                                                                        wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                        wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                        webmineralcomdataMonazite-(Ce)shtmlbull

                                                                        wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                        wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                        wwwchemicalelementscomelementseuhtmlbull

                                                                        boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                        lostcontentquakecomfiles200802holmiumpngbull

                                                                        chinageocitylocatorcomcitiesChinaQinghaibull

                                                                        geowebrudruzal-Bayan-Obohtmbull

                                                                        enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                        wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                        enwikipediaorgwikiMonazitebull

                                                                        webmineralcomdataBastnasite-(La)shtmlbull

                                                                        wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                        httpwwwavalonventurescombull

                                                                        wwwnewsweekcomid43884bull

                                                                        httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                        httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                        • Slide Number 1
                                                                        • Slide Number 2
                                                                        • Slide Number 3
                                                                        • Slide Number 4
                                                                        • Slide Number 5
                                                                        • Slide Number 6
                                                                        • Slide Number 7
                                                                        • Slide Number 8
                                                                        • Slide Number 9
                                                                        • Slide Number 10
                                                                        • Slide Number 11
                                                                        • Slide Number 12
                                                                        • Slide Number 13
                                                                        • Slide Number 14
                                                                        • Slide Number 15
                                                                        • Slide Number 16
                                                                        • Slide Number 17
                                                                        • Slide Number 18
                                                                        • Slide Number 19
                                                                        • Slide Number 20
                                                                        • Slide Number 21
                                                                        • Slide Number 22
                                                                        • Slide Number 23
                                                                        • Slide Number 24
                                                                        • Slide Number 25
                                                                        • Slide Number 26
                                                                        • Slide Number 27
                                                                        • Slide Number 28
                                                                        • Slide Number 29
                                                                        • Slide Number 30
                                                                        • Slide Number 31
                                                                        • Slide Number 32
                                                                        • Slide Number 33
                                                                        • Slide Number 34
                                                                        • Slide Number 35
                                                                        • Slide Number 36
                                                                        • Slide Number 37
                                                                        • Slide Number 38
                                                                        • Slide Number 39
                                                                        • Slide Number 40
                                                                        • Slide Number 41
                                                                        • Slide Number 42
                                                                        • Slide Number 43
                                                                        • Slide Number 44
                                                                        • Slide Number 45
                                                                        • Slide Number 46
                                                                        • Slide Number 47
                                                                        • Slide Number 48
                                                                        • Slide Number 49
                                                                        • Slide Number 50
                                                                        • Slide Number 51
                                                                        • Rare Earth Elements
                                                                        • Crustal Abundances of Elements
                                                                        • Occurrence
                                                                        • Rare Earth Minerals
                                                                        • REE Minerals
                                                                        • Bastnesite
                                                                        • Other REE minerals
                                                                        • Electron Configuration
                                                                        • Electron Configuartion
                                                                        • REE Behavior
                                                                        • Ionic Radius
                                                                        • Coordination Number
                                                                        • Coordination Number
                                                                        • Other Factors
                                                                        • REEs and Economics
                                                                        • HREEs and Magnetism
                                                                        • Applications in Magnetism
                                                                        • Applications in Magnetism
                                                                        • HREEs and Nuclear Technology
                                                                        • HREEs and Nuclear Technology
                                                                        • Mountain Pass
                                                                        • Bayan Obo
                                                                        • World Production
                                                                        • Exploration
                                                                        • Environmental Considerations
                                                                        • REE Fertilizer
                                                                        • Investigation by T Liang et al
                                                                        • Implications
                                                                        • Acid Mine Drainage (AMD)
                                                                        • Radioactive Elements
                                                                        • Radioactive Hazards
                                                                        • Summary
                                                                        • References

                                                                          Other REE mineralsbull

                                                                          Monazite [(LREEYTh)PO4] ndash

                                                                          Contains about 50ndash78 rare earth oxides

                                                                          ndash

                                                                          Forms in heavy mineral sands placer deposits associated with beach environments

                                                                          bull

                                                                          Xenotime

                                                                          [(YPO4)] ndash

                                                                          Contains 54ndash65 rare earth oxides

                                                                          ndash

                                                                          Yttrium Erbium and Cerium most common ndash

                                                                          Found in heavy mineral sands can also be a component in pegmatite and igneous rocks

                                                                          Electron Configuration

                                                                          bull

                                                                          The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                                          bull

                                                                          REEs

                                                                          have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                                          Electron Configuartion

                                                                          REE Behaviorbull

                                                                          Because of their shared behaviour REEs

                                                                          tend to be

                                                                          present in nature as a group All REEs

                                                                          commonly substitute for one another in minerals

                                                                          bull

                                                                          Yet the REEs

                                                                          are capable of showing great variation in their distributions

                                                                          bull

                                                                          Comes about due to ndash

                                                                          Differences in ionic radius ndash

                                                                          Crystal structure (Coordination Number)ndash

                                                                          Basicity

                                                                          of the mineral ndash

                                                                          The elementrsquos solubility and ability to migrate in the environment ndash

                                                                          Content of REEs

                                                                          in source fluids

                                                                          Ionic Radiusbull

                                                                          The ionic radius of the REEs

                                                                          is inversely related to atomic number

                                                                          bull

                                                                          The heavy rare earths are smaller ndash

                                                                          more similar to Mn2+ (ionic radius 008 nanometers)

                                                                          bull

                                                                          LREEs

                                                                          are largerndash

                                                                          more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                                          bull

                                                                          Charge balance achieved through some sites being left vacant or

                                                                          by coupled substitution with lower charged mineral (Na+)

                                                                          In nanometers

                                                                          Coordination Number

                                                                          bull

                                                                          Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                          bull

                                                                          Coordination number for this structure is 8

                                                                          Coordination Numberbull

                                                                          The heavy and light REEs

                                                                          differ in the coordination

                                                                          numbers (CN) with oxygenndash

                                                                          HREEs

                                                                          have CN between six to nine ndash

                                                                          LREEs

                                                                          have higher CNs

                                                                          bull

                                                                          Minerals with high CNs

                                                                          associated with REE site

                                                                          will favor LREEsndash

                                                                          Bastnasite

                                                                          CN = 11 ndash

                                                                          Monazite CN = 9

                                                                          bull

                                                                          Those with low CNs

                                                                          will preferentially select HREEs ndash

                                                                          Xenotime

                                                                          has a value of 8

                                                                          Other Factorsbull

                                                                          Minerals basicityndash

                                                                          Alkalic

                                                                          rocks host minerals with elevated LREE content ndash

                                                                          Rocks with lower basicity

                                                                          have lower amounts of LREEs

                                                                          relative to their HREE content

                                                                          bull

                                                                          Solubilityndash

                                                                          LREEs

                                                                          are more soluble in water then the HREEsndash

                                                                          Important characteristic for hydrothermally derived minerals

                                                                          bull

                                                                          MagmaHydrothermal fluid compositionndash

                                                                          Minerals will take what they can get

                                                                          REEs

                                                                          and Economicsbull

                                                                          The REEs

                                                                          and Yttrium have a very broad range of applications mostly in high technology fields

                                                                          bull

                                                                          84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                          bull

                                                                          REEs

                                                                          used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                          HREEs

                                                                          and Magnetism

                                                                          bull

                                                                          HREEs

                                                                          exhibit complex magnetic behaviour on account of electron structurendash

                                                                          They share the same outer shell electron configuration (valence = +3)

                                                                          ndash

                                                                          Differ in number of 4f electrons

                                                                          Applications in Magnetismbull

                                                                          Terbium and

                                                                          Dysprosium

                                                                          bull

                                                                          Components of Terfenol-D

                                                                          alloy

                                                                          with the formula Tb(03) Dy(07) Fe(19)

                                                                          bull

                                                                          Has the higher magnetostriction

                                                                          then any other alloyndash

                                                                          expands and contracts in magnetic field

                                                                          bull

                                                                          Developed by American Navy for sonar

                                                                          systems ndash

                                                                          Now has applications in magnetomechanical

                                                                          sensors and other electronic devices

                                                                          Applications in Magnetism

                                                                          bull

                                                                          Holmium

                                                                          bull

                                                                          Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                          elements

                                                                          bull

                                                                          Creates the strongest artificially generated magnetic fieldsndash

                                                                          In research where strong magnetic fields are needed

                                                                          HREEs

                                                                          and Nuclear Technology

                                                                          bull

                                                                          Dysprosium Homium Erbium

                                                                          bull

                                                                          High neutron

                                                                          absorption cross-section ndash

                                                                          Measure of probability of neutron capture

                                                                          bull

                                                                          Used in neutron-absorbing control rods in nuclear reactors

                                                                          HREEs

                                                                          and Nuclear Technology

                                                                          bull

                                                                          Lutetiumbull

                                                                          Radioactive isotope used in radiometric dating

                                                                          bull

                                                                          Thulium bull

                                                                          Stable thulium used as a radiation

                                                                          source

                                                                          in portable X-ray

                                                                          devices

                                                                          Mountain Passbull

                                                                          Bastnasite

                                                                          is the major REE mineral bull

                                                                          High grade accessory mineral of igneous or hydrothermal originsbull

                                                                          31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                          Mining stopped in 1994 ndash

                                                                          Thorium content of waste rock ndash

                                                                          Availability of inexpensive REEs

                                                                          from China

                                                                          San Bernardino County

                                                                          Bayan

                                                                          Obobull

                                                                          The worldrsquos primary source for both yttrium and the rare earth elements

                                                                          bull

                                                                          37 million tons of ore bull

                                                                          Main REE source there is Bastnasite

                                                                          World Production

                                                                          Explorationbull

                                                                          84 of REE imports to US are from China

                                                                          bull

                                                                          Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                          bull

                                                                          Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                          Lake as well as in

                                                                          Malawi Africa

                                                                          Environmental Considerations

                                                                          bull

                                                                          REE soil and food contaminationbull

                                                                          Acid Mine Drainage and groundwater systems

                                                                          bull

                                                                          Radioactive elements

                                                                          REE Fertilizerbull

                                                                          In China REE enriched fertilizer has been used in crop fields since 1990

                                                                          bull

                                                                          At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                          every year

                                                                          bull

                                                                          Research and agricultural practice that provides evidence that REEs

                                                                          will improve crop quality an yield

                                                                          bull

                                                                          The ramifications environmental and human exposure to REEs

                                                                          are not well understood

                                                                          Investigation by T Liang et albull

                                                                          Revealed that the average concentration of total REEs

                                                                          in Chinese soil is

                                                                          1768 mgkg ranging between 850 to 5227 mgkg

                                                                          bull

                                                                          In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                          Implicationsbull

                                                                          Human health effects not completely understood

                                                                          bull

                                                                          REE soil content shown to be detrimental to some plant speciesndash

                                                                          100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                          Acid Mine Drainage (AMD)bull

                                                                          Rain waters contacts waste rock facilitating acid forming reactions

                                                                          bull

                                                                          Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                          bull

                                                                          Process mobilizes established ecotoxins

                                                                          (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                          bull

                                                                          Historically dismissed as minor environmental risk

                                                                          Radioactive Elements

                                                                          bull

                                                                          REEs

                                                                          associated with uranium and thorium

                                                                          bull

                                                                          Bastnesite 32 thorium

                                                                          bull

                                                                          Monazite sands 6 to 12 thorium oxide

                                                                          bull

                                                                          Ores containing radioactive elements are avoided as sources of REEs

                                                                          Radioactive Hazardsbull

                                                                          Mountain Pass

                                                                          bull

                                                                          Accidentsndash

                                                                          In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                          bull

                                                                          Health Effectsndash

                                                                          inflammatory bowel disease ndash

                                                                          Prolonged seizures ndash

                                                                          Cysts ndash

                                                                          Cancers

                                                                          bull

                                                                          Waste Disposal ndash

                                                                          Yucca Mountain

                                                                          Summarybull

                                                                          REE concentrations in the crust are rare

                                                                          bull

                                                                          Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                          bull

                                                                          Main REE minerals are bastnasite monazite and xenotime

                                                                          bull

                                                                          Most important deposits are found at Bayan

                                                                          Obo China and Mountain Pass USA

                                                                          bull

                                                                          Important electronic and nuclear applications

                                                                          bull

                                                                          Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                          system contamination though acid mine drainage association with

                                                                          radioactive elements

                                                                          Referencesbull

                                                                          E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                          bull

                                                                          Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                          bull

                                                                          G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                          bull

                                                                          B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                          The Government of South Australia wwwpirsagovaubull

                                                                          The US geological Survey Mineralsusgsgovbull

                                                                          wwwelementsdatabasecombull

                                                                          wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                          wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                          webmineralcomdataMonazite-(Ce)shtmlbull

                                                                          wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                          wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                          wwwchemicalelementscomelementseuhtmlbull

                                                                          boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                          lostcontentquakecomfiles200802holmiumpngbull

                                                                          chinageocitylocatorcomcitiesChinaQinghaibull

                                                                          geowebrudruzal-Bayan-Obohtmbull

                                                                          enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                          wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                          enwikipediaorgwikiMonazitebull

                                                                          webmineralcomdataBastnasite-(La)shtmlbull

                                                                          wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                          httpwwwavalonventurescombull

                                                                          wwwnewsweekcomid43884bull

                                                                          httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                          httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                          • Slide Number 1
                                                                          • Slide Number 2
                                                                          • Slide Number 3
                                                                          • Slide Number 4
                                                                          • Slide Number 5
                                                                          • Slide Number 6
                                                                          • Slide Number 7
                                                                          • Slide Number 8
                                                                          • Slide Number 9
                                                                          • Slide Number 10
                                                                          • Slide Number 11
                                                                          • Slide Number 12
                                                                          • Slide Number 13
                                                                          • Slide Number 14
                                                                          • Slide Number 15
                                                                          • Slide Number 16
                                                                          • Slide Number 17
                                                                          • Slide Number 18
                                                                          • Slide Number 19
                                                                          • Slide Number 20
                                                                          • Slide Number 21
                                                                          • Slide Number 22
                                                                          • Slide Number 23
                                                                          • Slide Number 24
                                                                          • Slide Number 25
                                                                          • Slide Number 26
                                                                          • Slide Number 27
                                                                          • Slide Number 28
                                                                          • Slide Number 29
                                                                          • Slide Number 30
                                                                          • Slide Number 31
                                                                          • Slide Number 32
                                                                          • Slide Number 33
                                                                          • Slide Number 34
                                                                          • Slide Number 35
                                                                          • Slide Number 36
                                                                          • Slide Number 37
                                                                          • Slide Number 38
                                                                          • Slide Number 39
                                                                          • Slide Number 40
                                                                          • Slide Number 41
                                                                          • Slide Number 42
                                                                          • Slide Number 43
                                                                          • Slide Number 44
                                                                          • Slide Number 45
                                                                          • Slide Number 46
                                                                          • Slide Number 47
                                                                          • Slide Number 48
                                                                          • Slide Number 49
                                                                          • Slide Number 50
                                                                          • Slide Number 51
                                                                          • Rare Earth Elements
                                                                          • Crustal Abundances of Elements
                                                                          • Occurrence
                                                                          • Rare Earth Minerals
                                                                          • REE Minerals
                                                                          • Bastnesite
                                                                          • Other REE minerals
                                                                          • Electron Configuration
                                                                          • Electron Configuartion
                                                                          • REE Behavior
                                                                          • Ionic Radius
                                                                          • Coordination Number
                                                                          • Coordination Number
                                                                          • Other Factors
                                                                          • REEs and Economics
                                                                          • HREEs and Magnetism
                                                                          • Applications in Magnetism
                                                                          • Applications in Magnetism
                                                                          • HREEs and Nuclear Technology
                                                                          • HREEs and Nuclear Technology
                                                                          • Mountain Pass
                                                                          • Bayan Obo
                                                                          • World Production
                                                                          • Exploration
                                                                          • Environmental Considerations
                                                                          • REE Fertilizer
                                                                          • Investigation by T Liang et al
                                                                          • Implications
                                                                          • Acid Mine Drainage (AMD)
                                                                          • Radioactive Elements
                                                                          • Radioactive Hazards
                                                                          • Summary
                                                                          • References

                                                                            Electron Configuration

                                                                            bull

                                                                            The similarities in chemical and physical properties arise due to the grouprsquos common electron configuration

                                                                            bull

                                                                            REEs

                                                                            have same outer electronic configuration (+3) they differ in their number of 4f electrons

                                                                            Electron Configuartion

                                                                            REE Behaviorbull

                                                                            Because of their shared behaviour REEs

                                                                            tend to be

                                                                            present in nature as a group All REEs

                                                                            commonly substitute for one another in minerals

                                                                            bull

                                                                            Yet the REEs

                                                                            are capable of showing great variation in their distributions

                                                                            bull

                                                                            Comes about due to ndash

                                                                            Differences in ionic radius ndash

                                                                            Crystal structure (Coordination Number)ndash

                                                                            Basicity

                                                                            of the mineral ndash

                                                                            The elementrsquos solubility and ability to migrate in the environment ndash

                                                                            Content of REEs

                                                                            in source fluids

                                                                            Ionic Radiusbull

                                                                            The ionic radius of the REEs

                                                                            is inversely related to atomic number

                                                                            bull

                                                                            The heavy rare earths are smaller ndash

                                                                            more similar to Mn2+ (ionic radius 008 nanometers)

                                                                            bull

                                                                            LREEs

                                                                            are largerndash

                                                                            more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                                            bull

                                                                            Charge balance achieved through some sites being left vacant or

                                                                            by coupled substitution with lower charged mineral (Na+)

                                                                            In nanometers

                                                                            Coordination Number

                                                                            bull

                                                                            Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                            bull

                                                                            Coordination number for this structure is 8

                                                                            Coordination Numberbull

                                                                            The heavy and light REEs

                                                                            differ in the coordination

                                                                            numbers (CN) with oxygenndash

                                                                            HREEs

                                                                            have CN between six to nine ndash

                                                                            LREEs

                                                                            have higher CNs

                                                                            bull

                                                                            Minerals with high CNs

                                                                            associated with REE site

                                                                            will favor LREEsndash

                                                                            Bastnasite

                                                                            CN = 11 ndash

                                                                            Monazite CN = 9

                                                                            bull

                                                                            Those with low CNs

                                                                            will preferentially select HREEs ndash

                                                                            Xenotime

                                                                            has a value of 8

                                                                            Other Factorsbull

                                                                            Minerals basicityndash

                                                                            Alkalic

                                                                            rocks host minerals with elevated LREE content ndash

                                                                            Rocks with lower basicity

                                                                            have lower amounts of LREEs

                                                                            relative to their HREE content

                                                                            bull

                                                                            Solubilityndash

                                                                            LREEs

                                                                            are more soluble in water then the HREEsndash

                                                                            Important characteristic for hydrothermally derived minerals

                                                                            bull

                                                                            MagmaHydrothermal fluid compositionndash

                                                                            Minerals will take what they can get

                                                                            REEs

                                                                            and Economicsbull

                                                                            The REEs

                                                                            and Yttrium have a very broad range of applications mostly in high technology fields

                                                                            bull

                                                                            84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                            bull

                                                                            REEs

                                                                            used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                            HREEs

                                                                            and Magnetism

                                                                            bull

                                                                            HREEs

                                                                            exhibit complex magnetic behaviour on account of electron structurendash

                                                                            They share the same outer shell electron configuration (valence = +3)

                                                                            ndash

                                                                            Differ in number of 4f electrons

                                                                            Applications in Magnetismbull

                                                                            Terbium and

                                                                            Dysprosium

                                                                            bull

                                                                            Components of Terfenol-D

                                                                            alloy

                                                                            with the formula Tb(03) Dy(07) Fe(19)

                                                                            bull

                                                                            Has the higher magnetostriction

                                                                            then any other alloyndash

                                                                            expands and contracts in magnetic field

                                                                            bull

                                                                            Developed by American Navy for sonar

                                                                            systems ndash

                                                                            Now has applications in magnetomechanical

                                                                            sensors and other electronic devices

                                                                            Applications in Magnetism

                                                                            bull

                                                                            Holmium

                                                                            bull

                                                                            Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                            elements

                                                                            bull

                                                                            Creates the strongest artificially generated magnetic fieldsndash

                                                                            In research where strong magnetic fields are needed

                                                                            HREEs

                                                                            and Nuclear Technology

                                                                            bull

                                                                            Dysprosium Homium Erbium

                                                                            bull

                                                                            High neutron

                                                                            absorption cross-section ndash

                                                                            Measure of probability of neutron capture

                                                                            bull

                                                                            Used in neutron-absorbing control rods in nuclear reactors

                                                                            HREEs

                                                                            and Nuclear Technology

                                                                            bull

                                                                            Lutetiumbull

                                                                            Radioactive isotope used in radiometric dating

                                                                            bull

                                                                            Thulium bull

                                                                            Stable thulium used as a radiation

                                                                            source

                                                                            in portable X-ray

                                                                            devices

                                                                            Mountain Passbull

                                                                            Bastnasite

                                                                            is the major REE mineral bull

                                                                            High grade accessory mineral of igneous or hydrothermal originsbull

                                                                            31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                            Mining stopped in 1994 ndash

                                                                            Thorium content of waste rock ndash

                                                                            Availability of inexpensive REEs

                                                                            from China

                                                                            San Bernardino County

                                                                            Bayan

                                                                            Obobull

                                                                            The worldrsquos primary source for both yttrium and the rare earth elements

                                                                            bull

                                                                            37 million tons of ore bull

                                                                            Main REE source there is Bastnasite

                                                                            World Production

                                                                            Explorationbull

                                                                            84 of REE imports to US are from China

                                                                            bull

                                                                            Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                            bull

                                                                            Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                            Lake as well as in

                                                                            Malawi Africa

                                                                            Environmental Considerations

                                                                            bull

                                                                            REE soil and food contaminationbull

                                                                            Acid Mine Drainage and groundwater systems

                                                                            bull

                                                                            Radioactive elements

                                                                            REE Fertilizerbull

                                                                            In China REE enriched fertilizer has been used in crop fields since 1990

                                                                            bull

                                                                            At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                            every year

                                                                            bull

                                                                            Research and agricultural practice that provides evidence that REEs

                                                                            will improve crop quality an yield

                                                                            bull

                                                                            The ramifications environmental and human exposure to REEs

                                                                            are not well understood

                                                                            Investigation by T Liang et albull

                                                                            Revealed that the average concentration of total REEs

                                                                            in Chinese soil is

                                                                            1768 mgkg ranging between 850 to 5227 mgkg

                                                                            bull

                                                                            In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                            Implicationsbull

                                                                            Human health effects not completely understood

                                                                            bull

                                                                            REE soil content shown to be detrimental to some plant speciesndash

                                                                            100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                            Acid Mine Drainage (AMD)bull

                                                                            Rain waters contacts waste rock facilitating acid forming reactions

                                                                            bull

                                                                            Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                            bull

                                                                            Process mobilizes established ecotoxins

                                                                            (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                            bull

                                                                            Historically dismissed as minor environmental risk

                                                                            Radioactive Elements

                                                                            bull

                                                                            REEs

                                                                            associated with uranium and thorium

                                                                            bull

                                                                            Bastnesite 32 thorium

                                                                            bull

                                                                            Monazite sands 6 to 12 thorium oxide

                                                                            bull

                                                                            Ores containing radioactive elements are avoided as sources of REEs

                                                                            Radioactive Hazardsbull

                                                                            Mountain Pass

                                                                            bull

                                                                            Accidentsndash

                                                                            In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                            bull

                                                                            Health Effectsndash

                                                                            inflammatory bowel disease ndash

                                                                            Prolonged seizures ndash

                                                                            Cysts ndash

                                                                            Cancers

                                                                            bull

                                                                            Waste Disposal ndash

                                                                            Yucca Mountain

                                                                            Summarybull

                                                                            REE concentrations in the crust are rare

                                                                            bull

                                                                            Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                            bull

                                                                            Main REE minerals are bastnasite monazite and xenotime

                                                                            bull

                                                                            Most important deposits are found at Bayan

                                                                            Obo China and Mountain Pass USA

                                                                            bull

                                                                            Important electronic and nuclear applications

                                                                            bull

                                                                            Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                            system contamination though acid mine drainage association with

                                                                            radioactive elements

                                                                            Referencesbull

                                                                            E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                            bull

                                                                            Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                            bull

                                                                            G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                            bull

                                                                            B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                            The Government of South Australia wwwpirsagovaubull

                                                                            The US geological Survey Mineralsusgsgovbull

                                                                            wwwelementsdatabasecombull

                                                                            wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                            wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                            webmineralcomdataMonazite-(Ce)shtmlbull

                                                                            wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                            wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                            wwwchemicalelementscomelementseuhtmlbull

                                                                            boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                            lostcontentquakecomfiles200802holmiumpngbull

                                                                            chinageocitylocatorcomcitiesChinaQinghaibull

                                                                            geowebrudruzal-Bayan-Obohtmbull

                                                                            enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                            wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                            enwikipediaorgwikiMonazitebull

                                                                            webmineralcomdataBastnasite-(La)shtmlbull

                                                                            wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                            httpwwwavalonventurescombull

                                                                            wwwnewsweekcomid43884bull

                                                                            httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                            httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                            • Slide Number 1
                                                                            • Slide Number 2
                                                                            • Slide Number 3
                                                                            • Slide Number 4
                                                                            • Slide Number 5
                                                                            • Slide Number 6
                                                                            • Slide Number 7
                                                                            • Slide Number 8
                                                                            • Slide Number 9
                                                                            • Slide Number 10
                                                                            • Slide Number 11
                                                                            • Slide Number 12
                                                                            • Slide Number 13
                                                                            • Slide Number 14
                                                                            • Slide Number 15
                                                                            • Slide Number 16
                                                                            • Slide Number 17
                                                                            • Slide Number 18
                                                                            • Slide Number 19
                                                                            • Slide Number 20
                                                                            • Slide Number 21
                                                                            • Slide Number 22
                                                                            • Slide Number 23
                                                                            • Slide Number 24
                                                                            • Slide Number 25
                                                                            • Slide Number 26
                                                                            • Slide Number 27
                                                                            • Slide Number 28
                                                                            • Slide Number 29
                                                                            • Slide Number 30
                                                                            • Slide Number 31
                                                                            • Slide Number 32
                                                                            • Slide Number 33
                                                                            • Slide Number 34
                                                                            • Slide Number 35
                                                                            • Slide Number 36
                                                                            • Slide Number 37
                                                                            • Slide Number 38
                                                                            • Slide Number 39
                                                                            • Slide Number 40
                                                                            • Slide Number 41
                                                                            • Slide Number 42
                                                                            • Slide Number 43
                                                                            • Slide Number 44
                                                                            • Slide Number 45
                                                                            • Slide Number 46
                                                                            • Slide Number 47
                                                                            • Slide Number 48
                                                                            • Slide Number 49
                                                                            • Slide Number 50
                                                                            • Slide Number 51
                                                                            • Rare Earth Elements
                                                                            • Crustal Abundances of Elements
                                                                            • Occurrence
                                                                            • Rare Earth Minerals
                                                                            • REE Minerals
                                                                            • Bastnesite
                                                                            • Other REE minerals
                                                                            • Electron Configuration
                                                                            • Electron Configuartion
                                                                            • REE Behavior
                                                                            • Ionic Radius
                                                                            • Coordination Number
                                                                            • Coordination Number
                                                                            • Other Factors
                                                                            • REEs and Economics
                                                                            • HREEs and Magnetism
                                                                            • Applications in Magnetism
                                                                            • Applications in Magnetism
                                                                            • HREEs and Nuclear Technology
                                                                            • HREEs and Nuclear Technology
                                                                            • Mountain Pass
                                                                            • Bayan Obo
                                                                            • World Production
                                                                            • Exploration
                                                                            • Environmental Considerations
                                                                            • REE Fertilizer
                                                                            • Investigation by T Liang et al
                                                                            • Implications
                                                                            • Acid Mine Drainage (AMD)
                                                                            • Radioactive Elements
                                                                            • Radioactive Hazards
                                                                            • Summary
                                                                            • References

                                                                              Electron Configuartion

                                                                              REE Behaviorbull

                                                                              Because of their shared behaviour REEs

                                                                              tend to be

                                                                              present in nature as a group All REEs

                                                                              commonly substitute for one another in minerals

                                                                              bull

                                                                              Yet the REEs

                                                                              are capable of showing great variation in their distributions

                                                                              bull

                                                                              Comes about due to ndash

                                                                              Differences in ionic radius ndash

                                                                              Crystal structure (Coordination Number)ndash

                                                                              Basicity

                                                                              of the mineral ndash

                                                                              The elementrsquos solubility and ability to migrate in the environment ndash

                                                                              Content of REEs

                                                                              in source fluids

                                                                              Ionic Radiusbull

                                                                              The ionic radius of the REEs

                                                                              is inversely related to atomic number

                                                                              bull

                                                                              The heavy rare earths are smaller ndash

                                                                              more similar to Mn2+ (ionic radius 008 nanometers)

                                                                              bull

                                                                              LREEs

                                                                              are largerndash

                                                                              more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                                              bull

                                                                              Charge balance achieved through some sites being left vacant or

                                                                              by coupled substitution with lower charged mineral (Na+)

                                                                              In nanometers

                                                                              Coordination Number

                                                                              bull

                                                                              Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                              bull

                                                                              Coordination number for this structure is 8

                                                                              Coordination Numberbull

                                                                              The heavy and light REEs

                                                                              differ in the coordination

                                                                              numbers (CN) with oxygenndash

                                                                              HREEs

                                                                              have CN between six to nine ndash

                                                                              LREEs

                                                                              have higher CNs

                                                                              bull

                                                                              Minerals with high CNs

                                                                              associated with REE site

                                                                              will favor LREEsndash

                                                                              Bastnasite

                                                                              CN = 11 ndash

                                                                              Monazite CN = 9

                                                                              bull

                                                                              Those with low CNs

                                                                              will preferentially select HREEs ndash

                                                                              Xenotime

                                                                              has a value of 8

                                                                              Other Factorsbull

                                                                              Minerals basicityndash

                                                                              Alkalic

                                                                              rocks host minerals with elevated LREE content ndash

                                                                              Rocks with lower basicity

                                                                              have lower amounts of LREEs

                                                                              relative to their HREE content

                                                                              bull

                                                                              Solubilityndash

                                                                              LREEs

                                                                              are more soluble in water then the HREEsndash

                                                                              Important characteristic for hydrothermally derived minerals

                                                                              bull

                                                                              MagmaHydrothermal fluid compositionndash

                                                                              Minerals will take what they can get

                                                                              REEs

                                                                              and Economicsbull

                                                                              The REEs

                                                                              and Yttrium have a very broad range of applications mostly in high technology fields

                                                                              bull

                                                                              84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                              bull

                                                                              REEs

                                                                              used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                              HREEs

                                                                              and Magnetism

                                                                              bull

                                                                              HREEs

                                                                              exhibit complex magnetic behaviour on account of electron structurendash

                                                                              They share the same outer shell electron configuration (valence = +3)

                                                                              ndash

                                                                              Differ in number of 4f electrons

                                                                              Applications in Magnetismbull

                                                                              Terbium and

                                                                              Dysprosium

                                                                              bull

                                                                              Components of Terfenol-D

                                                                              alloy

                                                                              with the formula Tb(03) Dy(07) Fe(19)

                                                                              bull

                                                                              Has the higher magnetostriction

                                                                              then any other alloyndash

                                                                              expands and contracts in magnetic field

                                                                              bull

                                                                              Developed by American Navy for sonar

                                                                              systems ndash

                                                                              Now has applications in magnetomechanical

                                                                              sensors and other electronic devices

                                                                              Applications in Magnetism

                                                                              bull

                                                                              Holmium

                                                                              bull

                                                                              Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                              elements

                                                                              bull

                                                                              Creates the strongest artificially generated magnetic fieldsndash

                                                                              In research where strong magnetic fields are needed

                                                                              HREEs

                                                                              and Nuclear Technology

                                                                              bull

                                                                              Dysprosium Homium Erbium

                                                                              bull

                                                                              High neutron

                                                                              absorption cross-section ndash

                                                                              Measure of probability of neutron capture

                                                                              bull

                                                                              Used in neutron-absorbing control rods in nuclear reactors

                                                                              HREEs

                                                                              and Nuclear Technology

                                                                              bull

                                                                              Lutetiumbull

                                                                              Radioactive isotope used in radiometric dating

                                                                              bull

                                                                              Thulium bull

                                                                              Stable thulium used as a radiation

                                                                              source

                                                                              in portable X-ray

                                                                              devices

                                                                              Mountain Passbull

                                                                              Bastnasite

                                                                              is the major REE mineral bull

                                                                              High grade accessory mineral of igneous or hydrothermal originsbull

                                                                              31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                              Mining stopped in 1994 ndash

                                                                              Thorium content of waste rock ndash

                                                                              Availability of inexpensive REEs

                                                                              from China

                                                                              San Bernardino County

                                                                              Bayan

                                                                              Obobull

                                                                              The worldrsquos primary source for both yttrium and the rare earth elements

                                                                              bull

                                                                              37 million tons of ore bull

                                                                              Main REE source there is Bastnasite

                                                                              World Production

                                                                              Explorationbull

                                                                              84 of REE imports to US are from China

                                                                              bull

                                                                              Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                              bull

                                                                              Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                              Lake as well as in

                                                                              Malawi Africa

                                                                              Environmental Considerations

                                                                              bull

                                                                              REE soil and food contaminationbull

                                                                              Acid Mine Drainage and groundwater systems

                                                                              bull

                                                                              Radioactive elements

                                                                              REE Fertilizerbull

                                                                              In China REE enriched fertilizer has been used in crop fields since 1990

                                                                              bull

                                                                              At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                              every year

                                                                              bull

                                                                              Research and agricultural practice that provides evidence that REEs

                                                                              will improve crop quality an yield

                                                                              bull

                                                                              The ramifications environmental and human exposure to REEs

                                                                              are not well understood

                                                                              Investigation by T Liang et albull

                                                                              Revealed that the average concentration of total REEs

                                                                              in Chinese soil is

                                                                              1768 mgkg ranging between 850 to 5227 mgkg

                                                                              bull

                                                                              In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                              Implicationsbull

                                                                              Human health effects not completely understood

                                                                              bull

                                                                              REE soil content shown to be detrimental to some plant speciesndash

                                                                              100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                              Acid Mine Drainage (AMD)bull

                                                                              Rain waters contacts waste rock facilitating acid forming reactions

                                                                              bull

                                                                              Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                              bull

                                                                              Process mobilizes established ecotoxins

                                                                              (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                              bull

                                                                              Historically dismissed as minor environmental risk

                                                                              Radioactive Elements

                                                                              bull

                                                                              REEs

                                                                              associated with uranium and thorium

                                                                              bull

                                                                              Bastnesite 32 thorium

                                                                              bull

                                                                              Monazite sands 6 to 12 thorium oxide

                                                                              bull

                                                                              Ores containing radioactive elements are avoided as sources of REEs

                                                                              Radioactive Hazardsbull

                                                                              Mountain Pass

                                                                              bull

                                                                              Accidentsndash

                                                                              In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                              bull

                                                                              Health Effectsndash

                                                                              inflammatory bowel disease ndash

                                                                              Prolonged seizures ndash

                                                                              Cysts ndash

                                                                              Cancers

                                                                              bull

                                                                              Waste Disposal ndash

                                                                              Yucca Mountain

                                                                              Summarybull

                                                                              REE concentrations in the crust are rare

                                                                              bull

                                                                              Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                              bull

                                                                              Main REE minerals are bastnasite monazite and xenotime

                                                                              bull

                                                                              Most important deposits are found at Bayan

                                                                              Obo China and Mountain Pass USA

                                                                              bull

                                                                              Important electronic and nuclear applications

                                                                              bull

                                                                              Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                              system contamination though acid mine drainage association with

                                                                              radioactive elements

                                                                              Referencesbull

                                                                              E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                              bull

                                                                              Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                              bull

                                                                              G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                              bull

                                                                              B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                              The Government of South Australia wwwpirsagovaubull

                                                                              The US geological Survey Mineralsusgsgovbull

                                                                              wwwelementsdatabasecombull

                                                                              wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                              wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                              webmineralcomdataMonazite-(Ce)shtmlbull

                                                                              wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                              wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                              wwwchemicalelementscomelementseuhtmlbull

                                                                              boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                              lostcontentquakecomfiles200802holmiumpngbull

                                                                              chinageocitylocatorcomcitiesChinaQinghaibull

                                                                              geowebrudruzal-Bayan-Obohtmbull

                                                                              enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                              wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                              enwikipediaorgwikiMonazitebull

                                                                              webmineralcomdataBastnasite-(La)shtmlbull

                                                                              wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                              httpwwwavalonventurescombull

                                                                              wwwnewsweekcomid43884bull

                                                                              httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                              httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                              • Slide Number 1
                                                                              • Slide Number 2
                                                                              • Slide Number 3
                                                                              • Slide Number 4
                                                                              • Slide Number 5
                                                                              • Slide Number 6
                                                                              • Slide Number 7
                                                                              • Slide Number 8
                                                                              • Slide Number 9
                                                                              • Slide Number 10
                                                                              • Slide Number 11
                                                                              • Slide Number 12
                                                                              • Slide Number 13
                                                                              • Slide Number 14
                                                                              • Slide Number 15
                                                                              • Slide Number 16
                                                                              • Slide Number 17
                                                                              • Slide Number 18
                                                                              • Slide Number 19
                                                                              • Slide Number 20
                                                                              • Slide Number 21
                                                                              • Slide Number 22
                                                                              • Slide Number 23
                                                                              • Slide Number 24
                                                                              • Slide Number 25
                                                                              • Slide Number 26
                                                                              • Slide Number 27
                                                                              • Slide Number 28
                                                                              • Slide Number 29
                                                                              • Slide Number 30
                                                                              • Slide Number 31
                                                                              • Slide Number 32
                                                                              • Slide Number 33
                                                                              • Slide Number 34
                                                                              • Slide Number 35
                                                                              • Slide Number 36
                                                                              • Slide Number 37
                                                                              • Slide Number 38
                                                                              • Slide Number 39
                                                                              • Slide Number 40
                                                                              • Slide Number 41
                                                                              • Slide Number 42
                                                                              • Slide Number 43
                                                                              • Slide Number 44
                                                                              • Slide Number 45
                                                                              • Slide Number 46
                                                                              • Slide Number 47
                                                                              • Slide Number 48
                                                                              • Slide Number 49
                                                                              • Slide Number 50
                                                                              • Slide Number 51
                                                                              • Rare Earth Elements
                                                                              • Crustal Abundances of Elements
                                                                              • Occurrence
                                                                              • Rare Earth Minerals
                                                                              • REE Minerals
                                                                              • Bastnesite
                                                                              • Other REE minerals
                                                                              • Electron Configuration
                                                                              • Electron Configuartion
                                                                              • REE Behavior
                                                                              • Ionic Radius
                                                                              • Coordination Number
                                                                              • Coordination Number
                                                                              • Other Factors
                                                                              • REEs and Economics
                                                                              • HREEs and Magnetism
                                                                              • Applications in Magnetism
                                                                              • Applications in Magnetism
                                                                              • HREEs and Nuclear Technology
                                                                              • HREEs and Nuclear Technology
                                                                              • Mountain Pass
                                                                              • Bayan Obo
                                                                              • World Production
                                                                              • Exploration
                                                                              • Environmental Considerations
                                                                              • REE Fertilizer
                                                                              • Investigation by T Liang et al
                                                                              • Implications
                                                                              • Acid Mine Drainage (AMD)
                                                                              • Radioactive Elements
                                                                              • Radioactive Hazards
                                                                              • Summary
                                                                              • References

                                                                                REE Behaviorbull

                                                                                Because of their shared behaviour REEs

                                                                                tend to be

                                                                                present in nature as a group All REEs

                                                                                commonly substitute for one another in minerals

                                                                                bull

                                                                                Yet the REEs

                                                                                are capable of showing great variation in their distributions

                                                                                bull

                                                                                Comes about due to ndash

                                                                                Differences in ionic radius ndash

                                                                                Crystal structure (Coordination Number)ndash

                                                                                Basicity

                                                                                of the mineral ndash

                                                                                The elementrsquos solubility and ability to migrate in the environment ndash

                                                                                Content of REEs

                                                                                in source fluids

                                                                                Ionic Radiusbull

                                                                                The ionic radius of the REEs

                                                                                is inversely related to atomic number

                                                                                bull

                                                                                The heavy rare earths are smaller ndash

                                                                                more similar to Mn2+ (ionic radius 008 nanometers)

                                                                                bull

                                                                                LREEs

                                                                                are largerndash

                                                                                more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                                                bull

                                                                                Charge balance achieved through some sites being left vacant or

                                                                                by coupled substitution with lower charged mineral (Na+)

                                                                                In nanometers

                                                                                Coordination Number

                                                                                bull

                                                                                Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                                bull

                                                                                Coordination number for this structure is 8

                                                                                Coordination Numberbull

                                                                                The heavy and light REEs

                                                                                differ in the coordination

                                                                                numbers (CN) with oxygenndash

                                                                                HREEs

                                                                                have CN between six to nine ndash

                                                                                LREEs

                                                                                have higher CNs

                                                                                bull

                                                                                Minerals with high CNs

                                                                                associated with REE site

                                                                                will favor LREEsndash

                                                                                Bastnasite

                                                                                CN = 11 ndash

                                                                                Monazite CN = 9

                                                                                bull

                                                                                Those with low CNs

                                                                                will preferentially select HREEs ndash

                                                                                Xenotime

                                                                                has a value of 8

                                                                                Other Factorsbull

                                                                                Minerals basicityndash

                                                                                Alkalic

                                                                                rocks host minerals with elevated LREE content ndash

                                                                                Rocks with lower basicity

                                                                                have lower amounts of LREEs

                                                                                relative to their HREE content

                                                                                bull

                                                                                Solubilityndash

                                                                                LREEs

                                                                                are more soluble in water then the HREEsndash

                                                                                Important characteristic for hydrothermally derived minerals

                                                                                bull

                                                                                MagmaHydrothermal fluid compositionndash

                                                                                Minerals will take what they can get

                                                                                REEs

                                                                                and Economicsbull

                                                                                The REEs

                                                                                and Yttrium have a very broad range of applications mostly in high technology fields

                                                                                bull

                                                                                84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                                bull

                                                                                REEs

                                                                                used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                                HREEs

                                                                                and Magnetism

                                                                                bull

                                                                                HREEs

                                                                                exhibit complex magnetic behaviour on account of electron structurendash

                                                                                They share the same outer shell electron configuration (valence = +3)

                                                                                ndash

                                                                                Differ in number of 4f electrons

                                                                                Applications in Magnetismbull

                                                                                Terbium and

                                                                                Dysprosium

                                                                                bull

                                                                                Components of Terfenol-D

                                                                                alloy

                                                                                with the formula Tb(03) Dy(07) Fe(19)

                                                                                bull

                                                                                Has the higher magnetostriction

                                                                                then any other alloyndash

                                                                                expands and contracts in magnetic field

                                                                                bull

                                                                                Developed by American Navy for sonar

                                                                                systems ndash

                                                                                Now has applications in magnetomechanical

                                                                                sensors and other electronic devices

                                                                                Applications in Magnetism

                                                                                bull

                                                                                Holmium

                                                                                bull

                                                                                Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                                elements

                                                                                bull

                                                                                Creates the strongest artificially generated magnetic fieldsndash

                                                                                In research where strong magnetic fields are needed

                                                                                HREEs

                                                                                and Nuclear Technology

                                                                                bull

                                                                                Dysprosium Homium Erbium

                                                                                bull

                                                                                High neutron

                                                                                absorption cross-section ndash

                                                                                Measure of probability of neutron capture

                                                                                bull

                                                                                Used in neutron-absorbing control rods in nuclear reactors

                                                                                HREEs

                                                                                and Nuclear Technology

                                                                                bull

                                                                                Lutetiumbull

                                                                                Radioactive isotope used in radiometric dating

                                                                                bull

                                                                                Thulium bull

                                                                                Stable thulium used as a radiation

                                                                                source

                                                                                in portable X-ray

                                                                                devices

                                                                                Mountain Passbull

                                                                                Bastnasite

                                                                                is the major REE mineral bull

                                                                                High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                Mining stopped in 1994 ndash

                                                                                Thorium content of waste rock ndash

                                                                                Availability of inexpensive REEs

                                                                                from China

                                                                                San Bernardino County

                                                                                Bayan

                                                                                Obobull

                                                                                The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                bull

                                                                                37 million tons of ore bull

                                                                                Main REE source there is Bastnasite

                                                                                World Production

                                                                                Explorationbull

                                                                                84 of REE imports to US are from China

                                                                                bull

                                                                                Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                bull

                                                                                Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                Lake as well as in

                                                                                Malawi Africa

                                                                                Environmental Considerations

                                                                                bull

                                                                                REE soil and food contaminationbull

                                                                                Acid Mine Drainage and groundwater systems

                                                                                bull

                                                                                Radioactive elements

                                                                                REE Fertilizerbull

                                                                                In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                bull

                                                                                At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                every year

                                                                                bull

                                                                                Research and agricultural practice that provides evidence that REEs

                                                                                will improve crop quality an yield

                                                                                bull

                                                                                The ramifications environmental and human exposure to REEs

                                                                                are not well understood

                                                                                Investigation by T Liang et albull

                                                                                Revealed that the average concentration of total REEs

                                                                                in Chinese soil is

                                                                                1768 mgkg ranging between 850 to 5227 mgkg

                                                                                bull

                                                                                In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                Implicationsbull

                                                                                Human health effects not completely understood

                                                                                bull

                                                                                REE soil content shown to be detrimental to some plant speciesndash

                                                                                100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                Acid Mine Drainage (AMD)bull

                                                                                Rain waters contacts waste rock facilitating acid forming reactions

                                                                                bull

                                                                                Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                bull

                                                                                Process mobilizes established ecotoxins

                                                                                (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                bull

                                                                                Historically dismissed as minor environmental risk

                                                                                Radioactive Elements

                                                                                bull

                                                                                REEs

                                                                                associated with uranium and thorium

                                                                                bull

                                                                                Bastnesite 32 thorium

                                                                                bull

                                                                                Monazite sands 6 to 12 thorium oxide

                                                                                bull

                                                                                Ores containing radioactive elements are avoided as sources of REEs

                                                                                Radioactive Hazardsbull

                                                                                Mountain Pass

                                                                                bull

                                                                                Accidentsndash

                                                                                In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                bull

                                                                                Health Effectsndash

                                                                                inflammatory bowel disease ndash

                                                                                Prolonged seizures ndash

                                                                                Cysts ndash

                                                                                Cancers

                                                                                bull

                                                                                Waste Disposal ndash

                                                                                Yucca Mountain

                                                                                Summarybull

                                                                                REE concentrations in the crust are rare

                                                                                bull

                                                                                Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                bull

                                                                                Main REE minerals are bastnasite monazite and xenotime

                                                                                bull

                                                                                Most important deposits are found at Bayan

                                                                                Obo China and Mountain Pass USA

                                                                                bull

                                                                                Important electronic and nuclear applications

                                                                                bull

                                                                                Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                system contamination though acid mine drainage association with

                                                                                radioactive elements

                                                                                Referencesbull

                                                                                E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                bull

                                                                                Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                bull

                                                                                G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                bull

                                                                                B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                The Government of South Australia wwwpirsagovaubull

                                                                                The US geological Survey Mineralsusgsgovbull

                                                                                wwwelementsdatabasecombull

                                                                                wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                wwwchemicalelementscomelementseuhtmlbull

                                                                                boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                lostcontentquakecomfiles200802holmiumpngbull

                                                                                chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                geowebrudruzal-Bayan-Obohtmbull

                                                                                enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                enwikipediaorgwikiMonazitebull

                                                                                webmineralcomdataBastnasite-(La)shtmlbull

                                                                                wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                httpwwwavalonventurescombull

                                                                                wwwnewsweekcomid43884bull

                                                                                httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                • Slide Number 1
                                                                                • Slide Number 2
                                                                                • Slide Number 3
                                                                                • Slide Number 4
                                                                                • Slide Number 5
                                                                                • Slide Number 6
                                                                                • Slide Number 7
                                                                                • Slide Number 8
                                                                                • Slide Number 9
                                                                                • Slide Number 10
                                                                                • Slide Number 11
                                                                                • Slide Number 12
                                                                                • Slide Number 13
                                                                                • Slide Number 14
                                                                                • Slide Number 15
                                                                                • Slide Number 16
                                                                                • Slide Number 17
                                                                                • Slide Number 18
                                                                                • Slide Number 19
                                                                                • Slide Number 20
                                                                                • Slide Number 21
                                                                                • Slide Number 22
                                                                                • Slide Number 23
                                                                                • Slide Number 24
                                                                                • Slide Number 25
                                                                                • Slide Number 26
                                                                                • Slide Number 27
                                                                                • Slide Number 28
                                                                                • Slide Number 29
                                                                                • Slide Number 30
                                                                                • Slide Number 31
                                                                                • Slide Number 32
                                                                                • Slide Number 33
                                                                                • Slide Number 34
                                                                                • Slide Number 35
                                                                                • Slide Number 36
                                                                                • Slide Number 37
                                                                                • Slide Number 38
                                                                                • Slide Number 39
                                                                                • Slide Number 40
                                                                                • Slide Number 41
                                                                                • Slide Number 42
                                                                                • Slide Number 43
                                                                                • Slide Number 44
                                                                                • Slide Number 45
                                                                                • Slide Number 46
                                                                                • Slide Number 47
                                                                                • Slide Number 48
                                                                                • Slide Number 49
                                                                                • Slide Number 50
                                                                                • Slide Number 51
                                                                                • Rare Earth Elements
                                                                                • Crustal Abundances of Elements
                                                                                • Occurrence
                                                                                • Rare Earth Minerals
                                                                                • REE Minerals
                                                                                • Bastnesite
                                                                                • Other REE minerals
                                                                                • Electron Configuration
                                                                                • Electron Configuartion
                                                                                • REE Behavior
                                                                                • Ionic Radius
                                                                                • Coordination Number
                                                                                • Coordination Number
                                                                                • Other Factors
                                                                                • REEs and Economics
                                                                                • HREEs and Magnetism
                                                                                • Applications in Magnetism
                                                                                • Applications in Magnetism
                                                                                • HREEs and Nuclear Technology
                                                                                • HREEs and Nuclear Technology
                                                                                • Mountain Pass
                                                                                • Bayan Obo
                                                                                • World Production
                                                                                • Exploration
                                                                                • Environmental Considerations
                                                                                • REE Fertilizer
                                                                                • Investigation by T Liang et al
                                                                                • Implications
                                                                                • Acid Mine Drainage (AMD)
                                                                                • Radioactive Elements
                                                                                • Radioactive Hazards
                                                                                • Summary
                                                                                • References

                                                                                  Ionic Radiusbull

                                                                                  The ionic radius of the REEs

                                                                                  is inversely related to atomic number

                                                                                  bull

                                                                                  The heavy rare earths are smaller ndash

                                                                                  more similar to Mn2+ (ionic radius 008 nanometers)

                                                                                  bull

                                                                                  LREEs

                                                                                  are largerndash

                                                                                  more comparable in size to Ca2+ (ionic radius 01 nanometer)

                                                                                  bull

                                                                                  Charge balance achieved through some sites being left vacant or

                                                                                  by coupled substitution with lower charged mineral (Na+)

                                                                                  In nanometers

                                                                                  Coordination Number

                                                                                  bull

                                                                                  Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                                  bull

                                                                                  Coordination number for this structure is 8

                                                                                  Coordination Numberbull

                                                                                  The heavy and light REEs

                                                                                  differ in the coordination

                                                                                  numbers (CN) with oxygenndash

                                                                                  HREEs

                                                                                  have CN between six to nine ndash

                                                                                  LREEs

                                                                                  have higher CNs

                                                                                  bull

                                                                                  Minerals with high CNs

                                                                                  associated with REE site

                                                                                  will favor LREEsndash

                                                                                  Bastnasite

                                                                                  CN = 11 ndash

                                                                                  Monazite CN = 9

                                                                                  bull

                                                                                  Those with low CNs

                                                                                  will preferentially select HREEs ndash

                                                                                  Xenotime

                                                                                  has a value of 8

                                                                                  Other Factorsbull

                                                                                  Minerals basicityndash

                                                                                  Alkalic

                                                                                  rocks host minerals with elevated LREE content ndash

                                                                                  Rocks with lower basicity

                                                                                  have lower amounts of LREEs

                                                                                  relative to their HREE content

                                                                                  bull

                                                                                  Solubilityndash

                                                                                  LREEs

                                                                                  are more soluble in water then the HREEsndash

                                                                                  Important characteristic for hydrothermally derived minerals

                                                                                  bull

                                                                                  MagmaHydrothermal fluid compositionndash

                                                                                  Minerals will take what they can get

                                                                                  REEs

                                                                                  and Economicsbull

                                                                                  The REEs

                                                                                  and Yttrium have a very broad range of applications mostly in high technology fields

                                                                                  bull

                                                                                  84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                                  bull

                                                                                  REEs

                                                                                  used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                                  HREEs

                                                                                  and Magnetism

                                                                                  bull

                                                                                  HREEs

                                                                                  exhibit complex magnetic behaviour on account of electron structurendash

                                                                                  They share the same outer shell electron configuration (valence = +3)

                                                                                  ndash

                                                                                  Differ in number of 4f electrons

                                                                                  Applications in Magnetismbull

                                                                                  Terbium and

                                                                                  Dysprosium

                                                                                  bull

                                                                                  Components of Terfenol-D

                                                                                  alloy

                                                                                  with the formula Tb(03) Dy(07) Fe(19)

                                                                                  bull

                                                                                  Has the higher magnetostriction

                                                                                  then any other alloyndash

                                                                                  expands and contracts in magnetic field

                                                                                  bull

                                                                                  Developed by American Navy for sonar

                                                                                  systems ndash

                                                                                  Now has applications in magnetomechanical

                                                                                  sensors and other electronic devices

                                                                                  Applications in Magnetism

                                                                                  bull

                                                                                  Holmium

                                                                                  bull

                                                                                  Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                                  elements

                                                                                  bull

                                                                                  Creates the strongest artificially generated magnetic fieldsndash

                                                                                  In research where strong magnetic fields are needed

                                                                                  HREEs

                                                                                  and Nuclear Technology

                                                                                  bull

                                                                                  Dysprosium Homium Erbium

                                                                                  bull

                                                                                  High neutron

                                                                                  absorption cross-section ndash

                                                                                  Measure of probability of neutron capture

                                                                                  bull

                                                                                  Used in neutron-absorbing control rods in nuclear reactors

                                                                                  HREEs

                                                                                  and Nuclear Technology

                                                                                  bull

                                                                                  Lutetiumbull

                                                                                  Radioactive isotope used in radiometric dating

                                                                                  bull

                                                                                  Thulium bull

                                                                                  Stable thulium used as a radiation

                                                                                  source

                                                                                  in portable X-ray

                                                                                  devices

                                                                                  Mountain Passbull

                                                                                  Bastnasite

                                                                                  is the major REE mineral bull

                                                                                  High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                  31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                  Mining stopped in 1994 ndash

                                                                                  Thorium content of waste rock ndash

                                                                                  Availability of inexpensive REEs

                                                                                  from China

                                                                                  San Bernardino County

                                                                                  Bayan

                                                                                  Obobull

                                                                                  The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                  bull

                                                                                  37 million tons of ore bull

                                                                                  Main REE source there is Bastnasite

                                                                                  World Production

                                                                                  Explorationbull

                                                                                  84 of REE imports to US are from China

                                                                                  bull

                                                                                  Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                  bull

                                                                                  Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                  Lake as well as in

                                                                                  Malawi Africa

                                                                                  Environmental Considerations

                                                                                  bull

                                                                                  REE soil and food contaminationbull

                                                                                  Acid Mine Drainage and groundwater systems

                                                                                  bull

                                                                                  Radioactive elements

                                                                                  REE Fertilizerbull

                                                                                  In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                  bull

                                                                                  At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                  every year

                                                                                  bull

                                                                                  Research and agricultural practice that provides evidence that REEs

                                                                                  will improve crop quality an yield

                                                                                  bull

                                                                                  The ramifications environmental and human exposure to REEs

                                                                                  are not well understood

                                                                                  Investigation by T Liang et albull

                                                                                  Revealed that the average concentration of total REEs

                                                                                  in Chinese soil is

                                                                                  1768 mgkg ranging between 850 to 5227 mgkg

                                                                                  bull

                                                                                  In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                  Implicationsbull

                                                                                  Human health effects not completely understood

                                                                                  bull

                                                                                  REE soil content shown to be detrimental to some plant speciesndash

                                                                                  100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                  Acid Mine Drainage (AMD)bull

                                                                                  Rain waters contacts waste rock facilitating acid forming reactions

                                                                                  bull

                                                                                  Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                  bull

                                                                                  Process mobilizes established ecotoxins

                                                                                  (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                  bull

                                                                                  Historically dismissed as minor environmental risk

                                                                                  Radioactive Elements

                                                                                  bull

                                                                                  REEs

                                                                                  associated with uranium and thorium

                                                                                  bull

                                                                                  Bastnesite 32 thorium

                                                                                  bull

                                                                                  Monazite sands 6 to 12 thorium oxide

                                                                                  bull

                                                                                  Ores containing radioactive elements are avoided as sources of REEs

                                                                                  Radioactive Hazardsbull

                                                                                  Mountain Pass

                                                                                  bull

                                                                                  Accidentsndash

                                                                                  In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                  bull

                                                                                  Health Effectsndash

                                                                                  inflammatory bowel disease ndash

                                                                                  Prolonged seizures ndash

                                                                                  Cysts ndash

                                                                                  Cancers

                                                                                  bull

                                                                                  Waste Disposal ndash

                                                                                  Yucca Mountain

                                                                                  Summarybull

                                                                                  REE concentrations in the crust are rare

                                                                                  bull

                                                                                  Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                  bull

                                                                                  Main REE minerals are bastnasite monazite and xenotime

                                                                                  bull

                                                                                  Most important deposits are found at Bayan

                                                                                  Obo China and Mountain Pass USA

                                                                                  bull

                                                                                  Important electronic and nuclear applications

                                                                                  bull

                                                                                  Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                  system contamination though acid mine drainage association with

                                                                                  radioactive elements

                                                                                  Referencesbull

                                                                                  E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                  bull

                                                                                  Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                  bull

                                                                                  G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                  bull

                                                                                  B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                  The Government of South Australia wwwpirsagovaubull

                                                                                  The US geological Survey Mineralsusgsgovbull

                                                                                  wwwelementsdatabasecombull

                                                                                  wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                  wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                  webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                  wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                  wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                  wwwchemicalelementscomelementseuhtmlbull

                                                                                  boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                  lostcontentquakecomfiles200802holmiumpngbull

                                                                                  chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                  geowebrudruzal-Bayan-Obohtmbull

                                                                                  enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                  wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                  enwikipediaorgwikiMonazitebull

                                                                                  webmineralcomdataBastnasite-(La)shtmlbull

                                                                                  wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                  httpwwwavalonventurescombull

                                                                                  wwwnewsweekcomid43884bull

                                                                                  httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                  httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                  • Slide Number 1
                                                                                  • Slide Number 2
                                                                                  • Slide Number 3
                                                                                  • Slide Number 4
                                                                                  • Slide Number 5
                                                                                  • Slide Number 6
                                                                                  • Slide Number 7
                                                                                  • Slide Number 8
                                                                                  • Slide Number 9
                                                                                  • Slide Number 10
                                                                                  • Slide Number 11
                                                                                  • Slide Number 12
                                                                                  • Slide Number 13
                                                                                  • Slide Number 14
                                                                                  • Slide Number 15
                                                                                  • Slide Number 16
                                                                                  • Slide Number 17
                                                                                  • Slide Number 18
                                                                                  • Slide Number 19
                                                                                  • Slide Number 20
                                                                                  • Slide Number 21
                                                                                  • Slide Number 22
                                                                                  • Slide Number 23
                                                                                  • Slide Number 24
                                                                                  • Slide Number 25
                                                                                  • Slide Number 26
                                                                                  • Slide Number 27
                                                                                  • Slide Number 28
                                                                                  • Slide Number 29
                                                                                  • Slide Number 30
                                                                                  • Slide Number 31
                                                                                  • Slide Number 32
                                                                                  • Slide Number 33
                                                                                  • Slide Number 34
                                                                                  • Slide Number 35
                                                                                  • Slide Number 36
                                                                                  • Slide Number 37
                                                                                  • Slide Number 38
                                                                                  • Slide Number 39
                                                                                  • Slide Number 40
                                                                                  • Slide Number 41
                                                                                  • Slide Number 42
                                                                                  • Slide Number 43
                                                                                  • Slide Number 44
                                                                                  • Slide Number 45
                                                                                  • Slide Number 46
                                                                                  • Slide Number 47
                                                                                  • Slide Number 48
                                                                                  • Slide Number 49
                                                                                  • Slide Number 50
                                                                                  • Slide Number 51
                                                                                  • Rare Earth Elements
                                                                                  • Crustal Abundances of Elements
                                                                                  • Occurrence
                                                                                  • Rare Earth Minerals
                                                                                  • REE Minerals
                                                                                  • Bastnesite
                                                                                  • Other REE minerals
                                                                                  • Electron Configuration
                                                                                  • Electron Configuartion
                                                                                  • REE Behavior
                                                                                  • Ionic Radius
                                                                                  • Coordination Number
                                                                                  • Coordination Number
                                                                                  • Other Factors
                                                                                  • REEs and Economics
                                                                                  • HREEs and Magnetism
                                                                                  • Applications in Magnetism
                                                                                  • Applications in Magnetism
                                                                                  • HREEs and Nuclear Technology
                                                                                  • HREEs and Nuclear Technology
                                                                                  • Mountain Pass
                                                                                  • Bayan Obo
                                                                                  • World Production
                                                                                  • Exploration
                                                                                  • Environmental Considerations
                                                                                  • REE Fertilizer
                                                                                  • Investigation by T Liang et al
                                                                                  • Implications
                                                                                  • Acid Mine Drainage (AMD)
                                                                                  • Radioactive Elements
                                                                                  • Radioactive Hazards
                                                                                  • Summary
                                                                                  • References

                                                                                    Coordination Number

                                                                                    bull

                                                                                    Coordination number the number of atoms touching a particular atom in a crystal lattice

                                                                                    bull

                                                                                    Coordination number for this structure is 8

                                                                                    Coordination Numberbull

                                                                                    The heavy and light REEs

                                                                                    differ in the coordination

                                                                                    numbers (CN) with oxygenndash

                                                                                    HREEs

                                                                                    have CN between six to nine ndash

                                                                                    LREEs

                                                                                    have higher CNs

                                                                                    bull

                                                                                    Minerals with high CNs

                                                                                    associated with REE site

                                                                                    will favor LREEsndash

                                                                                    Bastnasite

                                                                                    CN = 11 ndash

                                                                                    Monazite CN = 9

                                                                                    bull

                                                                                    Those with low CNs

                                                                                    will preferentially select HREEs ndash

                                                                                    Xenotime

                                                                                    has a value of 8

                                                                                    Other Factorsbull

                                                                                    Minerals basicityndash

                                                                                    Alkalic

                                                                                    rocks host minerals with elevated LREE content ndash

                                                                                    Rocks with lower basicity

                                                                                    have lower amounts of LREEs

                                                                                    relative to their HREE content

                                                                                    bull

                                                                                    Solubilityndash

                                                                                    LREEs

                                                                                    are more soluble in water then the HREEsndash

                                                                                    Important characteristic for hydrothermally derived minerals

                                                                                    bull

                                                                                    MagmaHydrothermal fluid compositionndash

                                                                                    Minerals will take what they can get

                                                                                    REEs

                                                                                    and Economicsbull

                                                                                    The REEs

                                                                                    and Yttrium have a very broad range of applications mostly in high technology fields

                                                                                    bull

                                                                                    84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                                    bull

                                                                                    REEs

                                                                                    used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                                    HREEs

                                                                                    and Magnetism

                                                                                    bull

                                                                                    HREEs

                                                                                    exhibit complex magnetic behaviour on account of electron structurendash

                                                                                    They share the same outer shell electron configuration (valence = +3)

                                                                                    ndash

                                                                                    Differ in number of 4f electrons

                                                                                    Applications in Magnetismbull

                                                                                    Terbium and

                                                                                    Dysprosium

                                                                                    bull

                                                                                    Components of Terfenol-D

                                                                                    alloy

                                                                                    with the formula Tb(03) Dy(07) Fe(19)

                                                                                    bull

                                                                                    Has the higher magnetostriction

                                                                                    then any other alloyndash

                                                                                    expands and contracts in magnetic field

                                                                                    bull

                                                                                    Developed by American Navy for sonar

                                                                                    systems ndash

                                                                                    Now has applications in magnetomechanical

                                                                                    sensors and other electronic devices

                                                                                    Applications in Magnetism

                                                                                    bull

                                                                                    Holmium

                                                                                    bull

                                                                                    Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                                    elements

                                                                                    bull

                                                                                    Creates the strongest artificially generated magnetic fieldsndash

                                                                                    In research where strong magnetic fields are needed

                                                                                    HREEs

                                                                                    and Nuclear Technology

                                                                                    bull

                                                                                    Dysprosium Homium Erbium

                                                                                    bull

                                                                                    High neutron

                                                                                    absorption cross-section ndash

                                                                                    Measure of probability of neutron capture

                                                                                    bull

                                                                                    Used in neutron-absorbing control rods in nuclear reactors

                                                                                    HREEs

                                                                                    and Nuclear Technology

                                                                                    bull

                                                                                    Lutetiumbull

                                                                                    Radioactive isotope used in radiometric dating

                                                                                    bull

                                                                                    Thulium bull

                                                                                    Stable thulium used as a radiation

                                                                                    source

                                                                                    in portable X-ray

                                                                                    devices

                                                                                    Mountain Passbull

                                                                                    Bastnasite

                                                                                    is the major REE mineral bull

                                                                                    High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                    31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                    Mining stopped in 1994 ndash

                                                                                    Thorium content of waste rock ndash

                                                                                    Availability of inexpensive REEs

                                                                                    from China

                                                                                    San Bernardino County

                                                                                    Bayan

                                                                                    Obobull

                                                                                    The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                    bull

                                                                                    37 million tons of ore bull

                                                                                    Main REE source there is Bastnasite

                                                                                    World Production

                                                                                    Explorationbull

                                                                                    84 of REE imports to US are from China

                                                                                    bull

                                                                                    Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                    bull

                                                                                    Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                    Lake as well as in

                                                                                    Malawi Africa

                                                                                    Environmental Considerations

                                                                                    bull

                                                                                    REE soil and food contaminationbull

                                                                                    Acid Mine Drainage and groundwater systems

                                                                                    bull

                                                                                    Radioactive elements

                                                                                    REE Fertilizerbull

                                                                                    In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                    bull

                                                                                    At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                    every year

                                                                                    bull

                                                                                    Research and agricultural practice that provides evidence that REEs

                                                                                    will improve crop quality an yield

                                                                                    bull

                                                                                    The ramifications environmental and human exposure to REEs

                                                                                    are not well understood

                                                                                    Investigation by T Liang et albull

                                                                                    Revealed that the average concentration of total REEs

                                                                                    in Chinese soil is

                                                                                    1768 mgkg ranging between 850 to 5227 mgkg

                                                                                    bull

                                                                                    In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                    Implicationsbull

                                                                                    Human health effects not completely understood

                                                                                    bull

                                                                                    REE soil content shown to be detrimental to some plant speciesndash

                                                                                    100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                    Acid Mine Drainage (AMD)bull

                                                                                    Rain waters contacts waste rock facilitating acid forming reactions

                                                                                    bull

                                                                                    Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                    bull

                                                                                    Process mobilizes established ecotoxins

                                                                                    (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                    bull

                                                                                    Historically dismissed as minor environmental risk

                                                                                    Radioactive Elements

                                                                                    bull

                                                                                    REEs

                                                                                    associated with uranium and thorium

                                                                                    bull

                                                                                    Bastnesite 32 thorium

                                                                                    bull

                                                                                    Monazite sands 6 to 12 thorium oxide

                                                                                    bull

                                                                                    Ores containing radioactive elements are avoided as sources of REEs

                                                                                    Radioactive Hazardsbull

                                                                                    Mountain Pass

                                                                                    bull

                                                                                    Accidentsndash

                                                                                    In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                    bull

                                                                                    Health Effectsndash

                                                                                    inflammatory bowel disease ndash

                                                                                    Prolonged seizures ndash

                                                                                    Cysts ndash

                                                                                    Cancers

                                                                                    bull

                                                                                    Waste Disposal ndash

                                                                                    Yucca Mountain

                                                                                    Summarybull

                                                                                    REE concentrations in the crust are rare

                                                                                    bull

                                                                                    Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                    bull

                                                                                    Main REE minerals are bastnasite monazite and xenotime

                                                                                    bull

                                                                                    Most important deposits are found at Bayan

                                                                                    Obo China and Mountain Pass USA

                                                                                    bull

                                                                                    Important electronic and nuclear applications

                                                                                    bull

                                                                                    Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                    system contamination though acid mine drainage association with

                                                                                    radioactive elements

                                                                                    Referencesbull

                                                                                    E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                    bull

                                                                                    Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                    bull

                                                                                    G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                    bull

                                                                                    B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                    The Government of South Australia wwwpirsagovaubull

                                                                                    The US geological Survey Mineralsusgsgovbull

                                                                                    wwwelementsdatabasecombull

                                                                                    wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                    wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                    webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                    wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                    wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                    wwwchemicalelementscomelementseuhtmlbull

                                                                                    boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                    lostcontentquakecomfiles200802holmiumpngbull

                                                                                    chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                    geowebrudruzal-Bayan-Obohtmbull

                                                                                    enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                    wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                    enwikipediaorgwikiMonazitebull

                                                                                    webmineralcomdataBastnasite-(La)shtmlbull

                                                                                    wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                    httpwwwavalonventurescombull

                                                                                    wwwnewsweekcomid43884bull

                                                                                    httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                    httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                    • Slide Number 1
                                                                                    • Slide Number 2
                                                                                    • Slide Number 3
                                                                                    • Slide Number 4
                                                                                    • Slide Number 5
                                                                                    • Slide Number 6
                                                                                    • Slide Number 7
                                                                                    • Slide Number 8
                                                                                    • Slide Number 9
                                                                                    • Slide Number 10
                                                                                    • Slide Number 11
                                                                                    • Slide Number 12
                                                                                    • Slide Number 13
                                                                                    • Slide Number 14
                                                                                    • Slide Number 15
                                                                                    • Slide Number 16
                                                                                    • Slide Number 17
                                                                                    • Slide Number 18
                                                                                    • Slide Number 19
                                                                                    • Slide Number 20
                                                                                    • Slide Number 21
                                                                                    • Slide Number 22
                                                                                    • Slide Number 23
                                                                                    • Slide Number 24
                                                                                    • Slide Number 25
                                                                                    • Slide Number 26
                                                                                    • Slide Number 27
                                                                                    • Slide Number 28
                                                                                    • Slide Number 29
                                                                                    • Slide Number 30
                                                                                    • Slide Number 31
                                                                                    • Slide Number 32
                                                                                    • Slide Number 33
                                                                                    • Slide Number 34
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                                                                                    • Slide Number 36
                                                                                    • Slide Number 37
                                                                                    • Slide Number 38
                                                                                    • Slide Number 39
                                                                                    • Slide Number 40
                                                                                    • Slide Number 41
                                                                                    • Slide Number 42
                                                                                    • Slide Number 43
                                                                                    • Slide Number 44
                                                                                    • Slide Number 45
                                                                                    • Slide Number 46
                                                                                    • Slide Number 47
                                                                                    • Slide Number 48
                                                                                    • Slide Number 49
                                                                                    • Slide Number 50
                                                                                    • Slide Number 51
                                                                                    • Rare Earth Elements
                                                                                    • Crustal Abundances of Elements
                                                                                    • Occurrence
                                                                                    • Rare Earth Minerals
                                                                                    • REE Minerals
                                                                                    • Bastnesite
                                                                                    • Other REE minerals
                                                                                    • Electron Configuration
                                                                                    • Electron Configuartion
                                                                                    • REE Behavior
                                                                                    • Ionic Radius
                                                                                    • Coordination Number
                                                                                    • Coordination Number
                                                                                    • Other Factors
                                                                                    • REEs and Economics
                                                                                    • HREEs and Magnetism
                                                                                    • Applications in Magnetism
                                                                                    • Applications in Magnetism
                                                                                    • HREEs and Nuclear Technology
                                                                                    • HREEs and Nuclear Technology
                                                                                    • Mountain Pass
                                                                                    • Bayan Obo
                                                                                    • World Production
                                                                                    • Exploration
                                                                                    • Environmental Considerations
                                                                                    • REE Fertilizer
                                                                                    • Investigation by T Liang et al
                                                                                    • Implications
                                                                                    • Acid Mine Drainage (AMD)
                                                                                    • Radioactive Elements
                                                                                    • Radioactive Hazards
                                                                                    • Summary
                                                                                    • References

                                                                                      Coordination Numberbull

                                                                                      The heavy and light REEs

                                                                                      differ in the coordination

                                                                                      numbers (CN) with oxygenndash

                                                                                      HREEs

                                                                                      have CN between six to nine ndash

                                                                                      LREEs

                                                                                      have higher CNs

                                                                                      bull

                                                                                      Minerals with high CNs

                                                                                      associated with REE site

                                                                                      will favor LREEsndash

                                                                                      Bastnasite

                                                                                      CN = 11 ndash

                                                                                      Monazite CN = 9

                                                                                      bull

                                                                                      Those with low CNs

                                                                                      will preferentially select HREEs ndash

                                                                                      Xenotime

                                                                                      has a value of 8

                                                                                      Other Factorsbull

                                                                                      Minerals basicityndash

                                                                                      Alkalic

                                                                                      rocks host minerals with elevated LREE content ndash

                                                                                      Rocks with lower basicity

                                                                                      have lower amounts of LREEs

                                                                                      relative to their HREE content

                                                                                      bull

                                                                                      Solubilityndash

                                                                                      LREEs

                                                                                      are more soluble in water then the HREEsndash

                                                                                      Important characteristic for hydrothermally derived minerals

                                                                                      bull

                                                                                      MagmaHydrothermal fluid compositionndash

                                                                                      Minerals will take what they can get

                                                                                      REEs

                                                                                      and Economicsbull

                                                                                      The REEs

                                                                                      and Yttrium have a very broad range of applications mostly in high technology fields

                                                                                      bull

                                                                                      84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                                      bull

                                                                                      REEs

                                                                                      used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                                      HREEs

                                                                                      and Magnetism

                                                                                      bull

                                                                                      HREEs

                                                                                      exhibit complex magnetic behaviour on account of electron structurendash

                                                                                      They share the same outer shell electron configuration (valence = +3)

                                                                                      ndash

                                                                                      Differ in number of 4f electrons

                                                                                      Applications in Magnetismbull

                                                                                      Terbium and

                                                                                      Dysprosium

                                                                                      bull

                                                                                      Components of Terfenol-D

                                                                                      alloy

                                                                                      with the formula Tb(03) Dy(07) Fe(19)

                                                                                      bull

                                                                                      Has the higher magnetostriction

                                                                                      then any other alloyndash

                                                                                      expands and contracts in magnetic field

                                                                                      bull

                                                                                      Developed by American Navy for sonar

                                                                                      systems ndash

                                                                                      Now has applications in magnetomechanical

                                                                                      sensors and other electronic devices

                                                                                      Applications in Magnetism

                                                                                      bull

                                                                                      Holmium

                                                                                      bull

                                                                                      Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                                      elements

                                                                                      bull

                                                                                      Creates the strongest artificially generated magnetic fieldsndash

                                                                                      In research where strong magnetic fields are needed

                                                                                      HREEs

                                                                                      and Nuclear Technology

                                                                                      bull

                                                                                      Dysprosium Homium Erbium

                                                                                      bull

                                                                                      High neutron

                                                                                      absorption cross-section ndash

                                                                                      Measure of probability of neutron capture

                                                                                      bull

                                                                                      Used in neutron-absorbing control rods in nuclear reactors

                                                                                      HREEs

                                                                                      and Nuclear Technology

                                                                                      bull

                                                                                      Lutetiumbull

                                                                                      Radioactive isotope used in radiometric dating

                                                                                      bull

                                                                                      Thulium bull

                                                                                      Stable thulium used as a radiation

                                                                                      source

                                                                                      in portable X-ray

                                                                                      devices

                                                                                      Mountain Passbull

                                                                                      Bastnasite

                                                                                      is the major REE mineral bull

                                                                                      High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                      31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                      Mining stopped in 1994 ndash

                                                                                      Thorium content of waste rock ndash

                                                                                      Availability of inexpensive REEs

                                                                                      from China

                                                                                      San Bernardino County

                                                                                      Bayan

                                                                                      Obobull

                                                                                      The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                      bull

                                                                                      37 million tons of ore bull

                                                                                      Main REE source there is Bastnasite

                                                                                      World Production

                                                                                      Explorationbull

                                                                                      84 of REE imports to US are from China

                                                                                      bull

                                                                                      Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                      bull

                                                                                      Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                      Lake as well as in

                                                                                      Malawi Africa

                                                                                      Environmental Considerations

                                                                                      bull

                                                                                      REE soil and food contaminationbull

                                                                                      Acid Mine Drainage and groundwater systems

                                                                                      bull

                                                                                      Radioactive elements

                                                                                      REE Fertilizerbull

                                                                                      In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                      bull

                                                                                      At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                      every year

                                                                                      bull

                                                                                      Research and agricultural practice that provides evidence that REEs

                                                                                      will improve crop quality an yield

                                                                                      bull

                                                                                      The ramifications environmental and human exposure to REEs

                                                                                      are not well understood

                                                                                      Investigation by T Liang et albull

                                                                                      Revealed that the average concentration of total REEs

                                                                                      in Chinese soil is

                                                                                      1768 mgkg ranging between 850 to 5227 mgkg

                                                                                      bull

                                                                                      In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                      Implicationsbull

                                                                                      Human health effects not completely understood

                                                                                      bull

                                                                                      REE soil content shown to be detrimental to some plant speciesndash

                                                                                      100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                      Acid Mine Drainage (AMD)bull

                                                                                      Rain waters contacts waste rock facilitating acid forming reactions

                                                                                      bull

                                                                                      Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                      bull

                                                                                      Process mobilizes established ecotoxins

                                                                                      (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                      bull

                                                                                      Historically dismissed as minor environmental risk

                                                                                      Radioactive Elements

                                                                                      bull

                                                                                      REEs

                                                                                      associated with uranium and thorium

                                                                                      bull

                                                                                      Bastnesite 32 thorium

                                                                                      bull

                                                                                      Monazite sands 6 to 12 thorium oxide

                                                                                      bull

                                                                                      Ores containing radioactive elements are avoided as sources of REEs

                                                                                      Radioactive Hazardsbull

                                                                                      Mountain Pass

                                                                                      bull

                                                                                      Accidentsndash

                                                                                      In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                      bull

                                                                                      Health Effectsndash

                                                                                      inflammatory bowel disease ndash

                                                                                      Prolonged seizures ndash

                                                                                      Cysts ndash

                                                                                      Cancers

                                                                                      bull

                                                                                      Waste Disposal ndash

                                                                                      Yucca Mountain

                                                                                      Summarybull

                                                                                      REE concentrations in the crust are rare

                                                                                      bull

                                                                                      Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                      bull

                                                                                      Main REE minerals are bastnasite monazite and xenotime

                                                                                      bull

                                                                                      Most important deposits are found at Bayan

                                                                                      Obo China and Mountain Pass USA

                                                                                      bull

                                                                                      Important electronic and nuclear applications

                                                                                      bull

                                                                                      Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                      system contamination though acid mine drainage association with

                                                                                      radioactive elements

                                                                                      Referencesbull

                                                                                      E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                      bull

                                                                                      Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                      bull

                                                                                      G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                      bull

                                                                                      B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                      The Government of South Australia wwwpirsagovaubull

                                                                                      The US geological Survey Mineralsusgsgovbull

                                                                                      wwwelementsdatabasecombull

                                                                                      wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                      wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                      webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                      wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                      wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                      wwwchemicalelementscomelementseuhtmlbull

                                                                                      boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                      lostcontentquakecomfiles200802holmiumpngbull

                                                                                      chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                      geowebrudruzal-Bayan-Obohtmbull

                                                                                      enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                      wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                      enwikipediaorgwikiMonazitebull

                                                                                      webmineralcomdataBastnasite-(La)shtmlbull

                                                                                      wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                      httpwwwavalonventurescombull

                                                                                      wwwnewsweekcomid43884bull

                                                                                      httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                      httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                      • Slide Number 1
                                                                                      • Slide Number 2
                                                                                      • Slide Number 3
                                                                                      • Slide Number 4
                                                                                      • Slide Number 5
                                                                                      • Slide Number 6
                                                                                      • Slide Number 7
                                                                                      • Slide Number 8
                                                                                      • Slide Number 9
                                                                                      • Slide Number 10
                                                                                      • Slide Number 11
                                                                                      • Slide Number 12
                                                                                      • Slide Number 13
                                                                                      • Slide Number 14
                                                                                      • Slide Number 15
                                                                                      • Slide Number 16
                                                                                      • Slide Number 17
                                                                                      • Slide Number 18
                                                                                      • Slide Number 19
                                                                                      • Slide Number 20
                                                                                      • Slide Number 21
                                                                                      • Slide Number 22
                                                                                      • Slide Number 23
                                                                                      • Slide Number 24
                                                                                      • Slide Number 25
                                                                                      • Slide Number 26
                                                                                      • Slide Number 27
                                                                                      • Slide Number 28
                                                                                      • Slide Number 29
                                                                                      • Slide Number 30
                                                                                      • Slide Number 31
                                                                                      • Slide Number 32
                                                                                      • Slide Number 33
                                                                                      • Slide Number 34
                                                                                      • Slide Number 35
                                                                                      • Slide Number 36
                                                                                      • Slide Number 37
                                                                                      • Slide Number 38
                                                                                      • Slide Number 39
                                                                                      • Slide Number 40
                                                                                      • Slide Number 41
                                                                                      • Slide Number 42
                                                                                      • Slide Number 43
                                                                                      • Slide Number 44
                                                                                      • Slide Number 45
                                                                                      • Slide Number 46
                                                                                      • Slide Number 47
                                                                                      • Slide Number 48
                                                                                      • Slide Number 49
                                                                                      • Slide Number 50
                                                                                      • Slide Number 51
                                                                                      • Rare Earth Elements
                                                                                      • Crustal Abundances of Elements
                                                                                      • Occurrence
                                                                                      • Rare Earth Minerals
                                                                                      • REE Minerals
                                                                                      • Bastnesite
                                                                                      • Other REE minerals
                                                                                      • Electron Configuration
                                                                                      • Electron Configuartion
                                                                                      • REE Behavior
                                                                                      • Ionic Radius
                                                                                      • Coordination Number
                                                                                      • Coordination Number
                                                                                      • Other Factors
                                                                                      • REEs and Economics
                                                                                      • HREEs and Magnetism
                                                                                      • Applications in Magnetism
                                                                                      • Applications in Magnetism
                                                                                      • HREEs and Nuclear Technology
                                                                                      • HREEs and Nuclear Technology
                                                                                      • Mountain Pass
                                                                                      • Bayan Obo
                                                                                      • World Production
                                                                                      • Exploration
                                                                                      • Environmental Considerations
                                                                                      • REE Fertilizer
                                                                                      • Investigation by T Liang et al
                                                                                      • Implications
                                                                                      • Acid Mine Drainage (AMD)
                                                                                      • Radioactive Elements
                                                                                      • Radioactive Hazards
                                                                                      • Summary
                                                                                      • References

                                                                                        Other Factorsbull

                                                                                        Minerals basicityndash

                                                                                        Alkalic

                                                                                        rocks host minerals with elevated LREE content ndash

                                                                                        Rocks with lower basicity

                                                                                        have lower amounts of LREEs

                                                                                        relative to their HREE content

                                                                                        bull

                                                                                        Solubilityndash

                                                                                        LREEs

                                                                                        are more soluble in water then the HREEsndash

                                                                                        Important characteristic for hydrothermally derived minerals

                                                                                        bull

                                                                                        MagmaHydrothermal fluid compositionndash

                                                                                        Minerals will take what they can get

                                                                                        REEs

                                                                                        and Economicsbull

                                                                                        The REEs

                                                                                        and Yttrium have a very broad range of applications mostly in high technology fields

                                                                                        bull

                                                                                        84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                                        bull

                                                                                        REEs

                                                                                        used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                                        HREEs

                                                                                        and Magnetism

                                                                                        bull

                                                                                        HREEs

                                                                                        exhibit complex magnetic behaviour on account of electron structurendash

                                                                                        They share the same outer shell electron configuration (valence = +3)

                                                                                        ndash

                                                                                        Differ in number of 4f electrons

                                                                                        Applications in Magnetismbull

                                                                                        Terbium and

                                                                                        Dysprosium

                                                                                        bull

                                                                                        Components of Terfenol-D

                                                                                        alloy

                                                                                        with the formula Tb(03) Dy(07) Fe(19)

                                                                                        bull

                                                                                        Has the higher magnetostriction

                                                                                        then any other alloyndash

                                                                                        expands and contracts in magnetic field

                                                                                        bull

                                                                                        Developed by American Navy for sonar

                                                                                        systems ndash

                                                                                        Now has applications in magnetomechanical

                                                                                        sensors and other electronic devices

                                                                                        Applications in Magnetism

                                                                                        bull

                                                                                        Holmium

                                                                                        bull

                                                                                        Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                                        elements

                                                                                        bull

                                                                                        Creates the strongest artificially generated magnetic fieldsndash

                                                                                        In research where strong magnetic fields are needed

                                                                                        HREEs

                                                                                        and Nuclear Technology

                                                                                        bull

                                                                                        Dysprosium Homium Erbium

                                                                                        bull

                                                                                        High neutron

                                                                                        absorption cross-section ndash

                                                                                        Measure of probability of neutron capture

                                                                                        bull

                                                                                        Used in neutron-absorbing control rods in nuclear reactors

                                                                                        HREEs

                                                                                        and Nuclear Technology

                                                                                        bull

                                                                                        Lutetiumbull

                                                                                        Radioactive isotope used in radiometric dating

                                                                                        bull

                                                                                        Thulium bull

                                                                                        Stable thulium used as a radiation

                                                                                        source

                                                                                        in portable X-ray

                                                                                        devices

                                                                                        Mountain Passbull

                                                                                        Bastnasite

                                                                                        is the major REE mineral bull

                                                                                        High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                        31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                        Mining stopped in 1994 ndash

                                                                                        Thorium content of waste rock ndash

                                                                                        Availability of inexpensive REEs

                                                                                        from China

                                                                                        San Bernardino County

                                                                                        Bayan

                                                                                        Obobull

                                                                                        The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                        bull

                                                                                        37 million tons of ore bull

                                                                                        Main REE source there is Bastnasite

                                                                                        World Production

                                                                                        Explorationbull

                                                                                        84 of REE imports to US are from China

                                                                                        bull

                                                                                        Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                        bull

                                                                                        Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                        Lake as well as in

                                                                                        Malawi Africa

                                                                                        Environmental Considerations

                                                                                        bull

                                                                                        REE soil and food contaminationbull

                                                                                        Acid Mine Drainage and groundwater systems

                                                                                        bull

                                                                                        Radioactive elements

                                                                                        REE Fertilizerbull

                                                                                        In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                        bull

                                                                                        At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                        every year

                                                                                        bull

                                                                                        Research and agricultural practice that provides evidence that REEs

                                                                                        will improve crop quality an yield

                                                                                        bull

                                                                                        The ramifications environmental and human exposure to REEs

                                                                                        are not well understood

                                                                                        Investigation by T Liang et albull

                                                                                        Revealed that the average concentration of total REEs

                                                                                        in Chinese soil is

                                                                                        1768 mgkg ranging between 850 to 5227 mgkg

                                                                                        bull

                                                                                        In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                        Implicationsbull

                                                                                        Human health effects not completely understood

                                                                                        bull

                                                                                        REE soil content shown to be detrimental to some plant speciesndash

                                                                                        100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                        Acid Mine Drainage (AMD)bull

                                                                                        Rain waters contacts waste rock facilitating acid forming reactions

                                                                                        bull

                                                                                        Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                        bull

                                                                                        Process mobilizes established ecotoxins

                                                                                        (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                        bull

                                                                                        Historically dismissed as minor environmental risk

                                                                                        Radioactive Elements

                                                                                        bull

                                                                                        REEs

                                                                                        associated with uranium and thorium

                                                                                        bull

                                                                                        Bastnesite 32 thorium

                                                                                        bull

                                                                                        Monazite sands 6 to 12 thorium oxide

                                                                                        bull

                                                                                        Ores containing radioactive elements are avoided as sources of REEs

                                                                                        Radioactive Hazardsbull

                                                                                        Mountain Pass

                                                                                        bull

                                                                                        Accidentsndash

                                                                                        In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                        bull

                                                                                        Health Effectsndash

                                                                                        inflammatory bowel disease ndash

                                                                                        Prolonged seizures ndash

                                                                                        Cysts ndash

                                                                                        Cancers

                                                                                        bull

                                                                                        Waste Disposal ndash

                                                                                        Yucca Mountain

                                                                                        Summarybull

                                                                                        REE concentrations in the crust are rare

                                                                                        bull

                                                                                        Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                        bull

                                                                                        Main REE minerals are bastnasite monazite and xenotime

                                                                                        bull

                                                                                        Most important deposits are found at Bayan

                                                                                        Obo China and Mountain Pass USA

                                                                                        bull

                                                                                        Important electronic and nuclear applications

                                                                                        bull

                                                                                        Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                        system contamination though acid mine drainage association with

                                                                                        radioactive elements

                                                                                        Referencesbull

                                                                                        E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                        bull

                                                                                        Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                        bull

                                                                                        G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                        bull

                                                                                        B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                        The Government of South Australia wwwpirsagovaubull

                                                                                        The US geological Survey Mineralsusgsgovbull

                                                                                        wwwelementsdatabasecombull

                                                                                        wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                        wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                        webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                        wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                        wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                        wwwchemicalelementscomelementseuhtmlbull

                                                                                        boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                        lostcontentquakecomfiles200802holmiumpngbull

                                                                                        chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                        geowebrudruzal-Bayan-Obohtmbull

                                                                                        enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                        wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                        enwikipediaorgwikiMonazitebull

                                                                                        webmineralcomdataBastnasite-(La)shtmlbull

                                                                                        wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                        httpwwwavalonventurescombull

                                                                                        wwwnewsweekcomid43884bull

                                                                                        httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                        httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                        • Slide Number 1
                                                                                        • Slide Number 2
                                                                                        • Slide Number 3
                                                                                        • Slide Number 4
                                                                                        • Slide Number 5
                                                                                        • Slide Number 6
                                                                                        • Slide Number 7
                                                                                        • Slide Number 8
                                                                                        • Slide Number 9
                                                                                        • Slide Number 10
                                                                                        • Slide Number 11
                                                                                        • Slide Number 12
                                                                                        • Slide Number 13
                                                                                        • Slide Number 14
                                                                                        • Slide Number 15
                                                                                        • Slide Number 16
                                                                                        • Slide Number 17
                                                                                        • Slide Number 18
                                                                                        • Slide Number 19
                                                                                        • Slide Number 20
                                                                                        • Slide Number 21
                                                                                        • Slide Number 22
                                                                                        • Slide Number 23
                                                                                        • Slide Number 24
                                                                                        • Slide Number 25
                                                                                        • Slide Number 26
                                                                                        • Slide Number 27
                                                                                        • Slide Number 28
                                                                                        • Slide Number 29
                                                                                        • Slide Number 30
                                                                                        • Slide Number 31
                                                                                        • Slide Number 32
                                                                                        • Slide Number 33
                                                                                        • Slide Number 34
                                                                                        • Slide Number 35
                                                                                        • Slide Number 36
                                                                                        • Slide Number 37
                                                                                        • Slide Number 38
                                                                                        • Slide Number 39
                                                                                        • Slide Number 40
                                                                                        • Slide Number 41
                                                                                        • Slide Number 42
                                                                                        • Slide Number 43
                                                                                        • Slide Number 44
                                                                                        • Slide Number 45
                                                                                        • Slide Number 46
                                                                                        • Slide Number 47
                                                                                        • Slide Number 48
                                                                                        • Slide Number 49
                                                                                        • Slide Number 50
                                                                                        • Slide Number 51
                                                                                        • Rare Earth Elements
                                                                                        • Crustal Abundances of Elements
                                                                                        • Occurrence
                                                                                        • Rare Earth Minerals
                                                                                        • REE Minerals
                                                                                        • Bastnesite
                                                                                        • Other REE minerals
                                                                                        • Electron Configuration
                                                                                        • Electron Configuartion
                                                                                        • REE Behavior
                                                                                        • Ionic Radius
                                                                                        • Coordination Number
                                                                                        • Coordination Number
                                                                                        • Other Factors
                                                                                        • REEs and Economics
                                                                                        • HREEs and Magnetism
                                                                                        • Applications in Magnetism
                                                                                        • Applications in Magnetism
                                                                                        • HREEs and Nuclear Technology
                                                                                        • HREEs and Nuclear Technology
                                                                                        • Mountain Pass
                                                                                        • Bayan Obo
                                                                                        • World Production
                                                                                        • Exploration
                                                                                        • Environmental Considerations
                                                                                        • REE Fertilizer
                                                                                        • Investigation by T Liang et al
                                                                                        • Implications
                                                                                        • Acid Mine Drainage (AMD)
                                                                                        • Radioactive Elements
                                                                                        • Radioactive Hazards
                                                                                        • Summary
                                                                                        • References

                                                                                          REEs

                                                                                          and Economicsbull

                                                                                          The REEs

                                                                                          and Yttrium have a very broad range of applications mostly in high technology fields

                                                                                          bull

                                                                                          84 of Y acquired by the United States used in light and cathode ray tube phosphors The remainder was used in ceramics (7) electronics (7) and metallurgy (2)

                                                                                          bull

                                                                                          REEs

                                                                                          used primarily for automotive (25) petroleum (22) and metallurgic (20)

                                                                                          HREEs

                                                                                          and Magnetism

                                                                                          bull

                                                                                          HREEs

                                                                                          exhibit complex magnetic behaviour on account of electron structurendash

                                                                                          They share the same outer shell electron configuration (valence = +3)

                                                                                          ndash

                                                                                          Differ in number of 4f electrons

                                                                                          Applications in Magnetismbull

                                                                                          Terbium and

                                                                                          Dysprosium

                                                                                          bull

                                                                                          Components of Terfenol-D

                                                                                          alloy

                                                                                          with the formula Tb(03) Dy(07) Fe(19)

                                                                                          bull

                                                                                          Has the higher magnetostriction

                                                                                          then any other alloyndash

                                                                                          expands and contracts in magnetic field

                                                                                          bull

                                                                                          Developed by American Navy for sonar

                                                                                          systems ndash

                                                                                          Now has applications in magnetomechanical

                                                                                          sensors and other electronic devices

                                                                                          Applications in Magnetism

                                                                                          bull

                                                                                          Holmium

                                                                                          bull

                                                                                          Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                                          elements

                                                                                          bull

                                                                                          Creates the strongest artificially generated magnetic fieldsndash

                                                                                          In research where strong magnetic fields are needed

                                                                                          HREEs

                                                                                          and Nuclear Technology

                                                                                          bull

                                                                                          Dysprosium Homium Erbium

                                                                                          bull

                                                                                          High neutron

                                                                                          absorption cross-section ndash

                                                                                          Measure of probability of neutron capture

                                                                                          bull

                                                                                          Used in neutron-absorbing control rods in nuclear reactors

                                                                                          HREEs

                                                                                          and Nuclear Technology

                                                                                          bull

                                                                                          Lutetiumbull

                                                                                          Radioactive isotope used in radiometric dating

                                                                                          bull

                                                                                          Thulium bull

                                                                                          Stable thulium used as a radiation

                                                                                          source

                                                                                          in portable X-ray

                                                                                          devices

                                                                                          Mountain Passbull

                                                                                          Bastnasite

                                                                                          is the major REE mineral bull

                                                                                          High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                          31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                          Mining stopped in 1994 ndash

                                                                                          Thorium content of waste rock ndash

                                                                                          Availability of inexpensive REEs

                                                                                          from China

                                                                                          San Bernardino County

                                                                                          Bayan

                                                                                          Obobull

                                                                                          The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                          bull

                                                                                          37 million tons of ore bull

                                                                                          Main REE source there is Bastnasite

                                                                                          World Production

                                                                                          Explorationbull

                                                                                          84 of REE imports to US are from China

                                                                                          bull

                                                                                          Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                          bull

                                                                                          Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                          Lake as well as in

                                                                                          Malawi Africa

                                                                                          Environmental Considerations

                                                                                          bull

                                                                                          REE soil and food contaminationbull

                                                                                          Acid Mine Drainage and groundwater systems

                                                                                          bull

                                                                                          Radioactive elements

                                                                                          REE Fertilizerbull

                                                                                          In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                          bull

                                                                                          At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                          every year

                                                                                          bull

                                                                                          Research and agricultural practice that provides evidence that REEs

                                                                                          will improve crop quality an yield

                                                                                          bull

                                                                                          The ramifications environmental and human exposure to REEs

                                                                                          are not well understood

                                                                                          Investigation by T Liang et albull

                                                                                          Revealed that the average concentration of total REEs

                                                                                          in Chinese soil is

                                                                                          1768 mgkg ranging between 850 to 5227 mgkg

                                                                                          bull

                                                                                          In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                          Implicationsbull

                                                                                          Human health effects not completely understood

                                                                                          bull

                                                                                          REE soil content shown to be detrimental to some plant speciesndash

                                                                                          100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                          Acid Mine Drainage (AMD)bull

                                                                                          Rain waters contacts waste rock facilitating acid forming reactions

                                                                                          bull

                                                                                          Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                          bull

                                                                                          Process mobilizes established ecotoxins

                                                                                          (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                          bull

                                                                                          Historically dismissed as minor environmental risk

                                                                                          Radioactive Elements

                                                                                          bull

                                                                                          REEs

                                                                                          associated with uranium and thorium

                                                                                          bull

                                                                                          Bastnesite 32 thorium

                                                                                          bull

                                                                                          Monazite sands 6 to 12 thorium oxide

                                                                                          bull

                                                                                          Ores containing radioactive elements are avoided as sources of REEs

                                                                                          Radioactive Hazardsbull

                                                                                          Mountain Pass

                                                                                          bull

                                                                                          Accidentsndash

                                                                                          In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                          bull

                                                                                          Health Effectsndash

                                                                                          inflammatory bowel disease ndash

                                                                                          Prolonged seizures ndash

                                                                                          Cysts ndash

                                                                                          Cancers

                                                                                          bull

                                                                                          Waste Disposal ndash

                                                                                          Yucca Mountain

                                                                                          Summarybull

                                                                                          REE concentrations in the crust are rare

                                                                                          bull

                                                                                          Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                          bull

                                                                                          Main REE minerals are bastnasite monazite and xenotime

                                                                                          bull

                                                                                          Most important deposits are found at Bayan

                                                                                          Obo China and Mountain Pass USA

                                                                                          bull

                                                                                          Important electronic and nuclear applications

                                                                                          bull

                                                                                          Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                          system contamination though acid mine drainage association with

                                                                                          radioactive elements

                                                                                          Referencesbull

                                                                                          E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                          bull

                                                                                          Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                          bull

                                                                                          G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                          bull

                                                                                          B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                          The Government of South Australia wwwpirsagovaubull

                                                                                          The US geological Survey Mineralsusgsgovbull

                                                                                          wwwelementsdatabasecombull

                                                                                          wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                          wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                          webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                          wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                          wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                          wwwchemicalelementscomelementseuhtmlbull

                                                                                          boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                          lostcontentquakecomfiles200802holmiumpngbull

                                                                                          chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                          geowebrudruzal-Bayan-Obohtmbull

                                                                                          enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                          wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                          enwikipediaorgwikiMonazitebull

                                                                                          webmineralcomdataBastnasite-(La)shtmlbull

                                                                                          wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                          httpwwwavalonventurescombull

                                                                                          wwwnewsweekcomid43884bull

                                                                                          httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                          httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                          • Slide Number 1
                                                                                          • Slide Number 2
                                                                                          • Slide Number 3
                                                                                          • Slide Number 4
                                                                                          • Slide Number 5
                                                                                          • Slide Number 6
                                                                                          • Slide Number 7
                                                                                          • Slide Number 8
                                                                                          • Slide Number 9
                                                                                          • Slide Number 10
                                                                                          • Slide Number 11
                                                                                          • Slide Number 12
                                                                                          • Slide Number 13
                                                                                          • Slide Number 14
                                                                                          • Slide Number 15
                                                                                          • Slide Number 16
                                                                                          • Slide Number 17
                                                                                          • Slide Number 18
                                                                                          • Slide Number 19
                                                                                          • Slide Number 20
                                                                                          • Slide Number 21
                                                                                          • Slide Number 22
                                                                                          • Slide Number 23
                                                                                          • Slide Number 24
                                                                                          • Slide Number 25
                                                                                          • Slide Number 26
                                                                                          • Slide Number 27
                                                                                          • Slide Number 28
                                                                                          • Slide Number 29
                                                                                          • Slide Number 30
                                                                                          • Slide Number 31
                                                                                          • Slide Number 32
                                                                                          • Slide Number 33
                                                                                          • Slide Number 34
                                                                                          • Slide Number 35
                                                                                          • Slide Number 36
                                                                                          • Slide Number 37
                                                                                          • Slide Number 38
                                                                                          • Slide Number 39
                                                                                          • Slide Number 40
                                                                                          • Slide Number 41
                                                                                          • Slide Number 42
                                                                                          • Slide Number 43
                                                                                          • Slide Number 44
                                                                                          • Slide Number 45
                                                                                          • Slide Number 46
                                                                                          • Slide Number 47
                                                                                          • Slide Number 48
                                                                                          • Slide Number 49
                                                                                          • Slide Number 50
                                                                                          • Slide Number 51
                                                                                          • Rare Earth Elements
                                                                                          • Crustal Abundances of Elements
                                                                                          • Occurrence
                                                                                          • Rare Earth Minerals
                                                                                          • REE Minerals
                                                                                          • Bastnesite
                                                                                          • Other REE minerals
                                                                                          • Electron Configuration
                                                                                          • Electron Configuartion
                                                                                          • REE Behavior
                                                                                          • Ionic Radius
                                                                                          • Coordination Number
                                                                                          • Coordination Number
                                                                                          • Other Factors
                                                                                          • REEs and Economics
                                                                                          • HREEs and Magnetism
                                                                                          • Applications in Magnetism
                                                                                          • Applications in Magnetism
                                                                                          • HREEs and Nuclear Technology
                                                                                          • HREEs and Nuclear Technology
                                                                                          • Mountain Pass
                                                                                          • Bayan Obo
                                                                                          • World Production
                                                                                          • Exploration
                                                                                          • Environmental Considerations
                                                                                          • REE Fertilizer
                                                                                          • Investigation by T Liang et al
                                                                                          • Implications
                                                                                          • Acid Mine Drainage (AMD)
                                                                                          • Radioactive Elements
                                                                                          • Radioactive Hazards
                                                                                          • Summary
                                                                                          • References

                                                                                            HREEs

                                                                                            and Magnetism

                                                                                            bull

                                                                                            HREEs

                                                                                            exhibit complex magnetic behaviour on account of electron structurendash

                                                                                            They share the same outer shell electron configuration (valence = +3)

                                                                                            ndash

                                                                                            Differ in number of 4f electrons

                                                                                            Applications in Magnetismbull

                                                                                            Terbium and

                                                                                            Dysprosium

                                                                                            bull

                                                                                            Components of Terfenol-D

                                                                                            alloy

                                                                                            with the formula Tb(03) Dy(07) Fe(19)

                                                                                            bull

                                                                                            Has the higher magnetostriction

                                                                                            then any other alloyndash

                                                                                            expands and contracts in magnetic field

                                                                                            bull

                                                                                            Developed by American Navy for sonar

                                                                                            systems ndash

                                                                                            Now has applications in magnetomechanical

                                                                                            sensors and other electronic devices

                                                                                            Applications in Magnetism

                                                                                            bull

                                                                                            Holmium

                                                                                            bull

                                                                                            Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                                            elements

                                                                                            bull

                                                                                            Creates the strongest artificially generated magnetic fieldsndash

                                                                                            In research where strong magnetic fields are needed

                                                                                            HREEs

                                                                                            and Nuclear Technology

                                                                                            bull

                                                                                            Dysprosium Homium Erbium

                                                                                            bull

                                                                                            High neutron

                                                                                            absorption cross-section ndash

                                                                                            Measure of probability of neutron capture

                                                                                            bull

                                                                                            Used in neutron-absorbing control rods in nuclear reactors

                                                                                            HREEs

                                                                                            and Nuclear Technology

                                                                                            bull

                                                                                            Lutetiumbull

                                                                                            Radioactive isotope used in radiometric dating

                                                                                            bull

                                                                                            Thulium bull

                                                                                            Stable thulium used as a radiation

                                                                                            source

                                                                                            in portable X-ray

                                                                                            devices

                                                                                            Mountain Passbull

                                                                                            Bastnasite

                                                                                            is the major REE mineral bull

                                                                                            High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                            31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                            Mining stopped in 1994 ndash

                                                                                            Thorium content of waste rock ndash

                                                                                            Availability of inexpensive REEs

                                                                                            from China

                                                                                            San Bernardino County

                                                                                            Bayan

                                                                                            Obobull

                                                                                            The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                            bull

                                                                                            37 million tons of ore bull

                                                                                            Main REE source there is Bastnasite

                                                                                            World Production

                                                                                            Explorationbull

                                                                                            84 of REE imports to US are from China

                                                                                            bull

                                                                                            Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                            bull

                                                                                            Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                            Lake as well as in

                                                                                            Malawi Africa

                                                                                            Environmental Considerations

                                                                                            bull

                                                                                            REE soil and food contaminationbull

                                                                                            Acid Mine Drainage and groundwater systems

                                                                                            bull

                                                                                            Radioactive elements

                                                                                            REE Fertilizerbull

                                                                                            In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                            bull

                                                                                            At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                            every year

                                                                                            bull

                                                                                            Research and agricultural practice that provides evidence that REEs

                                                                                            will improve crop quality an yield

                                                                                            bull

                                                                                            The ramifications environmental and human exposure to REEs

                                                                                            are not well understood

                                                                                            Investigation by T Liang et albull

                                                                                            Revealed that the average concentration of total REEs

                                                                                            in Chinese soil is

                                                                                            1768 mgkg ranging between 850 to 5227 mgkg

                                                                                            bull

                                                                                            In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                            Implicationsbull

                                                                                            Human health effects not completely understood

                                                                                            bull

                                                                                            REE soil content shown to be detrimental to some plant speciesndash

                                                                                            100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                            Acid Mine Drainage (AMD)bull

                                                                                            Rain waters contacts waste rock facilitating acid forming reactions

                                                                                            bull

                                                                                            Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                            bull

                                                                                            Process mobilizes established ecotoxins

                                                                                            (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                            bull

                                                                                            Historically dismissed as minor environmental risk

                                                                                            Radioactive Elements

                                                                                            bull

                                                                                            REEs

                                                                                            associated with uranium and thorium

                                                                                            bull

                                                                                            Bastnesite 32 thorium

                                                                                            bull

                                                                                            Monazite sands 6 to 12 thorium oxide

                                                                                            bull

                                                                                            Ores containing radioactive elements are avoided as sources of REEs

                                                                                            Radioactive Hazardsbull

                                                                                            Mountain Pass

                                                                                            bull

                                                                                            Accidentsndash

                                                                                            In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                            bull

                                                                                            Health Effectsndash

                                                                                            inflammatory bowel disease ndash

                                                                                            Prolonged seizures ndash

                                                                                            Cysts ndash

                                                                                            Cancers

                                                                                            bull

                                                                                            Waste Disposal ndash

                                                                                            Yucca Mountain

                                                                                            Summarybull

                                                                                            REE concentrations in the crust are rare

                                                                                            bull

                                                                                            Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                            bull

                                                                                            Main REE minerals are bastnasite monazite and xenotime

                                                                                            bull

                                                                                            Most important deposits are found at Bayan

                                                                                            Obo China and Mountain Pass USA

                                                                                            bull

                                                                                            Important electronic and nuclear applications

                                                                                            bull

                                                                                            Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                            system contamination though acid mine drainage association with

                                                                                            radioactive elements

                                                                                            Referencesbull

                                                                                            E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                            bull

                                                                                            Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                            bull

                                                                                            G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                            bull

                                                                                            B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                            The Government of South Australia wwwpirsagovaubull

                                                                                            The US geological Survey Mineralsusgsgovbull

                                                                                            wwwelementsdatabasecombull

                                                                                            wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                            wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                            webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                            wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                            wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                            wwwchemicalelementscomelementseuhtmlbull

                                                                                            boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                            lostcontentquakecomfiles200802holmiumpngbull

                                                                                            chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                            geowebrudruzal-Bayan-Obohtmbull

                                                                                            enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                            wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                            enwikipediaorgwikiMonazitebull

                                                                                            webmineralcomdataBastnasite-(La)shtmlbull

                                                                                            wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                            httpwwwavalonventurescombull

                                                                                            wwwnewsweekcomid43884bull

                                                                                            httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                            httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                            • Slide Number 1
                                                                                            • Slide Number 2
                                                                                            • Slide Number 3
                                                                                            • Slide Number 4
                                                                                            • Slide Number 5
                                                                                            • Slide Number 6
                                                                                            • Slide Number 7
                                                                                            • Slide Number 8
                                                                                            • Slide Number 9
                                                                                            • Slide Number 10
                                                                                            • Slide Number 11
                                                                                            • Slide Number 12
                                                                                            • Slide Number 13
                                                                                            • Slide Number 14
                                                                                            • Slide Number 15
                                                                                            • Slide Number 16
                                                                                            • Slide Number 17
                                                                                            • Slide Number 18
                                                                                            • Slide Number 19
                                                                                            • Slide Number 20
                                                                                            • Slide Number 21
                                                                                            • Slide Number 22
                                                                                            • Slide Number 23
                                                                                            • Slide Number 24
                                                                                            • Slide Number 25
                                                                                            • Slide Number 26
                                                                                            • Slide Number 27
                                                                                            • Slide Number 28
                                                                                            • Slide Number 29
                                                                                            • Slide Number 30
                                                                                            • Slide Number 31
                                                                                            • Slide Number 32
                                                                                            • Slide Number 33
                                                                                            • Slide Number 34
                                                                                            • Slide Number 35
                                                                                            • Slide Number 36
                                                                                            • Slide Number 37
                                                                                            • Slide Number 38
                                                                                            • Slide Number 39
                                                                                            • Slide Number 40
                                                                                            • Slide Number 41
                                                                                            • Slide Number 42
                                                                                            • Slide Number 43
                                                                                            • Slide Number 44
                                                                                            • Slide Number 45
                                                                                            • Slide Number 46
                                                                                            • Slide Number 47
                                                                                            • Slide Number 48
                                                                                            • Slide Number 49
                                                                                            • Slide Number 50
                                                                                            • Slide Number 51
                                                                                            • Rare Earth Elements
                                                                                            • Crustal Abundances of Elements
                                                                                            • Occurrence
                                                                                            • Rare Earth Minerals
                                                                                            • REE Minerals
                                                                                            • Bastnesite
                                                                                            • Other REE minerals
                                                                                            • Electron Configuration
                                                                                            • Electron Configuartion
                                                                                            • REE Behavior
                                                                                            • Ionic Radius
                                                                                            • Coordination Number
                                                                                            • Coordination Number
                                                                                            • Other Factors
                                                                                            • REEs and Economics
                                                                                            • HREEs and Magnetism
                                                                                            • Applications in Magnetism
                                                                                            • Applications in Magnetism
                                                                                            • HREEs and Nuclear Technology
                                                                                            • HREEs and Nuclear Technology
                                                                                            • Mountain Pass
                                                                                            • Bayan Obo
                                                                                            • World Production
                                                                                            • Exploration
                                                                                            • Environmental Considerations
                                                                                            • REE Fertilizer
                                                                                            • Investigation by T Liang et al
                                                                                            • Implications
                                                                                            • Acid Mine Drainage (AMD)
                                                                                            • Radioactive Elements
                                                                                            • Radioactive Hazards
                                                                                            • Summary
                                                                                            • References

                                                                                              Applications in Magnetismbull

                                                                                              Terbium and

                                                                                              Dysprosium

                                                                                              bull

                                                                                              Components of Terfenol-D

                                                                                              alloy

                                                                                              with the formula Tb(03) Dy(07) Fe(19)

                                                                                              bull

                                                                                              Has the higher magnetostriction

                                                                                              then any other alloyndash

                                                                                              expands and contracts in magnetic field

                                                                                              bull

                                                                                              Developed by American Navy for sonar

                                                                                              systems ndash

                                                                                              Now has applications in magnetomechanical

                                                                                              sensors and other electronic devices

                                                                                              Applications in Magnetism

                                                                                              bull

                                                                                              Holmium

                                                                                              bull

                                                                                              Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                                              elements

                                                                                              bull

                                                                                              Creates the strongest artificially generated magnetic fieldsndash

                                                                                              In research where strong magnetic fields are needed

                                                                                              HREEs

                                                                                              and Nuclear Technology

                                                                                              bull

                                                                                              Dysprosium Homium Erbium

                                                                                              bull

                                                                                              High neutron

                                                                                              absorption cross-section ndash

                                                                                              Measure of probability of neutron capture

                                                                                              bull

                                                                                              Used in neutron-absorbing control rods in nuclear reactors

                                                                                              HREEs

                                                                                              and Nuclear Technology

                                                                                              bull

                                                                                              Lutetiumbull

                                                                                              Radioactive isotope used in radiometric dating

                                                                                              bull

                                                                                              Thulium bull

                                                                                              Stable thulium used as a radiation

                                                                                              source

                                                                                              in portable X-ray

                                                                                              devices

                                                                                              Mountain Passbull

                                                                                              Bastnasite

                                                                                              is the major REE mineral bull

                                                                                              High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                              31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                              Mining stopped in 1994 ndash

                                                                                              Thorium content of waste rock ndash

                                                                                              Availability of inexpensive REEs

                                                                                              from China

                                                                                              San Bernardino County

                                                                                              Bayan

                                                                                              Obobull

                                                                                              The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                              bull

                                                                                              37 million tons of ore bull

                                                                                              Main REE source there is Bastnasite

                                                                                              World Production

                                                                                              Explorationbull

                                                                                              84 of REE imports to US are from China

                                                                                              bull

                                                                                              Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                              bull

                                                                                              Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                              Lake as well as in

                                                                                              Malawi Africa

                                                                                              Environmental Considerations

                                                                                              bull

                                                                                              REE soil and food contaminationbull

                                                                                              Acid Mine Drainage and groundwater systems

                                                                                              bull

                                                                                              Radioactive elements

                                                                                              REE Fertilizerbull

                                                                                              In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                              bull

                                                                                              At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                              every year

                                                                                              bull

                                                                                              Research and agricultural practice that provides evidence that REEs

                                                                                              will improve crop quality an yield

                                                                                              bull

                                                                                              The ramifications environmental and human exposure to REEs

                                                                                              are not well understood

                                                                                              Investigation by T Liang et albull

                                                                                              Revealed that the average concentration of total REEs

                                                                                              in Chinese soil is

                                                                                              1768 mgkg ranging between 850 to 5227 mgkg

                                                                                              bull

                                                                                              In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                              Implicationsbull

                                                                                              Human health effects not completely understood

                                                                                              bull

                                                                                              REE soil content shown to be detrimental to some plant speciesndash

                                                                                              100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                              Acid Mine Drainage (AMD)bull

                                                                                              Rain waters contacts waste rock facilitating acid forming reactions

                                                                                              bull

                                                                                              Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                              bull

                                                                                              Process mobilizes established ecotoxins

                                                                                              (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                              bull

                                                                                              Historically dismissed as minor environmental risk

                                                                                              Radioactive Elements

                                                                                              bull

                                                                                              REEs

                                                                                              associated with uranium and thorium

                                                                                              bull

                                                                                              Bastnesite 32 thorium

                                                                                              bull

                                                                                              Monazite sands 6 to 12 thorium oxide

                                                                                              bull

                                                                                              Ores containing radioactive elements are avoided as sources of REEs

                                                                                              Radioactive Hazardsbull

                                                                                              Mountain Pass

                                                                                              bull

                                                                                              Accidentsndash

                                                                                              In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                              bull

                                                                                              Health Effectsndash

                                                                                              inflammatory bowel disease ndash

                                                                                              Prolonged seizures ndash

                                                                                              Cysts ndash

                                                                                              Cancers

                                                                                              bull

                                                                                              Waste Disposal ndash

                                                                                              Yucca Mountain

                                                                                              Summarybull

                                                                                              REE concentrations in the crust are rare

                                                                                              bull

                                                                                              Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                              bull

                                                                                              Main REE minerals are bastnasite monazite and xenotime

                                                                                              bull

                                                                                              Most important deposits are found at Bayan

                                                                                              Obo China and Mountain Pass USA

                                                                                              bull

                                                                                              Important electronic and nuclear applications

                                                                                              bull

                                                                                              Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                              system contamination though acid mine drainage association with

                                                                                              radioactive elements

                                                                                              Referencesbull

                                                                                              E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                              bull

                                                                                              Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                              bull

                                                                                              G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                              bull

                                                                                              B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                              The Government of South Australia wwwpirsagovaubull

                                                                                              The US geological Survey Mineralsusgsgovbull

                                                                                              wwwelementsdatabasecombull

                                                                                              wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                              wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                              webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                              wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                              wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                              wwwchemicalelementscomelementseuhtmlbull

                                                                                              boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                              lostcontentquakecomfiles200802holmiumpngbull

                                                                                              chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                              geowebrudruzal-Bayan-Obohtmbull

                                                                                              enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                              wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                              enwikipediaorgwikiMonazitebull

                                                                                              webmineralcomdataBastnasite-(La)shtmlbull

                                                                                              wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                              httpwwwavalonventurescombull

                                                                                              wwwnewsweekcomid43884bull

                                                                                              httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                              httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                              • Slide Number 1
                                                                                              • Slide Number 2
                                                                                              • Slide Number 3
                                                                                              • Slide Number 4
                                                                                              • Slide Number 5
                                                                                              • Slide Number 6
                                                                                              • Slide Number 7
                                                                                              • Slide Number 8
                                                                                              • Slide Number 9
                                                                                              • Slide Number 10
                                                                                              • Slide Number 11
                                                                                              • Slide Number 12
                                                                                              • Slide Number 13
                                                                                              • Slide Number 14
                                                                                              • Slide Number 15
                                                                                              • Slide Number 16
                                                                                              • Slide Number 17
                                                                                              • Slide Number 18
                                                                                              • Slide Number 19
                                                                                              • Slide Number 20
                                                                                              • Slide Number 21
                                                                                              • Slide Number 22
                                                                                              • Slide Number 23
                                                                                              • Slide Number 24
                                                                                              • Slide Number 25
                                                                                              • Slide Number 26
                                                                                              • Slide Number 27
                                                                                              • Slide Number 28
                                                                                              • Slide Number 29
                                                                                              • Slide Number 30
                                                                                              • Slide Number 31
                                                                                              • Slide Number 32
                                                                                              • Slide Number 33
                                                                                              • Slide Number 34
                                                                                              • Slide Number 35
                                                                                              • Slide Number 36
                                                                                              • Slide Number 37
                                                                                              • Slide Number 38
                                                                                              • Slide Number 39
                                                                                              • Slide Number 40
                                                                                              • Slide Number 41
                                                                                              • Slide Number 42
                                                                                              • Slide Number 43
                                                                                              • Slide Number 44
                                                                                              • Slide Number 45
                                                                                              • Slide Number 46
                                                                                              • Slide Number 47
                                                                                              • Slide Number 48
                                                                                              • Slide Number 49
                                                                                              • Slide Number 50
                                                                                              • Slide Number 51
                                                                                              • Rare Earth Elements
                                                                                              • Crustal Abundances of Elements
                                                                                              • Occurrence
                                                                                              • Rare Earth Minerals
                                                                                              • REE Minerals
                                                                                              • Bastnesite
                                                                                              • Other REE minerals
                                                                                              • Electron Configuration
                                                                                              • Electron Configuartion
                                                                                              • REE Behavior
                                                                                              • Ionic Radius
                                                                                              • Coordination Number
                                                                                              • Coordination Number
                                                                                              • Other Factors
                                                                                              • REEs and Economics
                                                                                              • HREEs and Magnetism
                                                                                              • Applications in Magnetism
                                                                                              • Applications in Magnetism
                                                                                              • HREEs and Nuclear Technology
                                                                                              • HREEs and Nuclear Technology
                                                                                              • Mountain Pass
                                                                                              • Bayan Obo
                                                                                              • World Production
                                                                                              • Exploration
                                                                                              • Environmental Considerations
                                                                                              • REE Fertilizer
                                                                                              • Investigation by T Liang et al
                                                                                              • Implications
                                                                                              • Acid Mine Drainage (AMD)
                                                                                              • Radioactive Elements
                                                                                              • Radioactive Hazards
                                                                                              • Summary
                                                                                              • References

                                                                                                Applications in Magnetism

                                                                                                bull

                                                                                                Holmium

                                                                                                bull

                                                                                                Possesses the highest magnetic moment (106microB) of any of the naturally-occurring

                                                                                                elements

                                                                                                bull

                                                                                                Creates the strongest artificially generated magnetic fieldsndash

                                                                                                In research where strong magnetic fields are needed

                                                                                                HREEs

                                                                                                and Nuclear Technology

                                                                                                bull

                                                                                                Dysprosium Homium Erbium

                                                                                                bull

                                                                                                High neutron

                                                                                                absorption cross-section ndash

                                                                                                Measure of probability of neutron capture

                                                                                                bull

                                                                                                Used in neutron-absorbing control rods in nuclear reactors

                                                                                                HREEs

                                                                                                and Nuclear Technology

                                                                                                bull

                                                                                                Lutetiumbull

                                                                                                Radioactive isotope used in radiometric dating

                                                                                                bull

                                                                                                Thulium bull

                                                                                                Stable thulium used as a radiation

                                                                                                source

                                                                                                in portable X-ray

                                                                                                devices

                                                                                                Mountain Passbull

                                                                                                Bastnasite

                                                                                                is the major REE mineral bull

                                                                                                High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                                31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                                Mining stopped in 1994 ndash

                                                                                                Thorium content of waste rock ndash

                                                                                                Availability of inexpensive REEs

                                                                                                from China

                                                                                                San Bernardino County

                                                                                                Bayan

                                                                                                Obobull

                                                                                                The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                                bull

                                                                                                37 million tons of ore bull

                                                                                                Main REE source there is Bastnasite

                                                                                                World Production

                                                                                                Explorationbull

                                                                                                84 of REE imports to US are from China

                                                                                                bull

                                                                                                Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                                bull

                                                                                                Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                                Lake as well as in

                                                                                                Malawi Africa

                                                                                                Environmental Considerations

                                                                                                bull

                                                                                                REE soil and food contaminationbull

                                                                                                Acid Mine Drainage and groundwater systems

                                                                                                bull

                                                                                                Radioactive elements

                                                                                                REE Fertilizerbull

                                                                                                In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                                bull

                                                                                                At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                                every year

                                                                                                bull

                                                                                                Research and agricultural practice that provides evidence that REEs

                                                                                                will improve crop quality an yield

                                                                                                bull

                                                                                                The ramifications environmental and human exposure to REEs

                                                                                                are not well understood

                                                                                                Investigation by T Liang et albull

                                                                                                Revealed that the average concentration of total REEs

                                                                                                in Chinese soil is

                                                                                                1768 mgkg ranging between 850 to 5227 mgkg

                                                                                                bull

                                                                                                In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                                Implicationsbull

                                                                                                Human health effects not completely understood

                                                                                                bull

                                                                                                REE soil content shown to be detrimental to some plant speciesndash

                                                                                                100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                Acid Mine Drainage (AMD)bull

                                                                                                Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                bull

                                                                                                Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                bull

                                                                                                Process mobilizes established ecotoxins

                                                                                                (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                bull

                                                                                                Historically dismissed as minor environmental risk

                                                                                                Radioactive Elements

                                                                                                bull

                                                                                                REEs

                                                                                                associated with uranium and thorium

                                                                                                bull

                                                                                                Bastnesite 32 thorium

                                                                                                bull

                                                                                                Monazite sands 6 to 12 thorium oxide

                                                                                                bull

                                                                                                Ores containing radioactive elements are avoided as sources of REEs

                                                                                                Radioactive Hazardsbull

                                                                                                Mountain Pass

                                                                                                bull

                                                                                                Accidentsndash

                                                                                                In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                bull

                                                                                                Health Effectsndash

                                                                                                inflammatory bowel disease ndash

                                                                                                Prolonged seizures ndash

                                                                                                Cysts ndash

                                                                                                Cancers

                                                                                                bull

                                                                                                Waste Disposal ndash

                                                                                                Yucca Mountain

                                                                                                Summarybull

                                                                                                REE concentrations in the crust are rare

                                                                                                bull

                                                                                                Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                bull

                                                                                                Main REE minerals are bastnasite monazite and xenotime

                                                                                                bull

                                                                                                Most important deposits are found at Bayan

                                                                                                Obo China and Mountain Pass USA

                                                                                                bull

                                                                                                Important electronic and nuclear applications

                                                                                                bull

                                                                                                Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                system contamination though acid mine drainage association with

                                                                                                radioactive elements

                                                                                                Referencesbull

                                                                                                E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                bull

                                                                                                Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                bull

                                                                                                G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                bull

                                                                                                B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                The Government of South Australia wwwpirsagovaubull

                                                                                                The US geological Survey Mineralsusgsgovbull

                                                                                                wwwelementsdatabasecombull

                                                                                                wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                wwwchemicalelementscomelementseuhtmlbull

                                                                                                boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                lostcontentquakecomfiles200802holmiumpngbull

                                                                                                chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                geowebrudruzal-Bayan-Obohtmbull

                                                                                                enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                enwikipediaorgwikiMonazitebull

                                                                                                webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                httpwwwavalonventurescombull

                                                                                                wwwnewsweekcomid43884bull

                                                                                                httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                • Slide Number 1
                                                                                                • Slide Number 2
                                                                                                • Slide Number 3
                                                                                                • Slide Number 4
                                                                                                • Slide Number 5
                                                                                                • Slide Number 6
                                                                                                • Slide Number 7
                                                                                                • Slide Number 8
                                                                                                • Slide Number 9
                                                                                                • Slide Number 10
                                                                                                • Slide Number 11
                                                                                                • Slide Number 12
                                                                                                • Slide Number 13
                                                                                                • Slide Number 14
                                                                                                • Slide Number 15
                                                                                                • Slide Number 16
                                                                                                • Slide Number 17
                                                                                                • Slide Number 18
                                                                                                • Slide Number 19
                                                                                                • Slide Number 20
                                                                                                • Slide Number 21
                                                                                                • Slide Number 22
                                                                                                • Slide Number 23
                                                                                                • Slide Number 24
                                                                                                • Slide Number 25
                                                                                                • Slide Number 26
                                                                                                • Slide Number 27
                                                                                                • Slide Number 28
                                                                                                • Slide Number 29
                                                                                                • Slide Number 30
                                                                                                • Slide Number 31
                                                                                                • Slide Number 32
                                                                                                • Slide Number 33
                                                                                                • Slide Number 34
                                                                                                • Slide Number 35
                                                                                                • Slide Number 36
                                                                                                • Slide Number 37
                                                                                                • Slide Number 38
                                                                                                • Slide Number 39
                                                                                                • Slide Number 40
                                                                                                • Slide Number 41
                                                                                                • Slide Number 42
                                                                                                • Slide Number 43
                                                                                                • Slide Number 44
                                                                                                • Slide Number 45
                                                                                                • Slide Number 46
                                                                                                • Slide Number 47
                                                                                                • Slide Number 48
                                                                                                • Slide Number 49
                                                                                                • Slide Number 50
                                                                                                • Slide Number 51
                                                                                                • Rare Earth Elements
                                                                                                • Crustal Abundances of Elements
                                                                                                • Occurrence
                                                                                                • Rare Earth Minerals
                                                                                                • REE Minerals
                                                                                                • Bastnesite
                                                                                                • Other REE minerals
                                                                                                • Electron Configuration
                                                                                                • Electron Configuartion
                                                                                                • REE Behavior
                                                                                                • Ionic Radius
                                                                                                • Coordination Number
                                                                                                • Coordination Number
                                                                                                • Other Factors
                                                                                                • REEs and Economics
                                                                                                • HREEs and Magnetism
                                                                                                • Applications in Magnetism
                                                                                                • Applications in Magnetism
                                                                                                • HREEs and Nuclear Technology
                                                                                                • HREEs and Nuclear Technology
                                                                                                • Mountain Pass
                                                                                                • Bayan Obo
                                                                                                • World Production
                                                                                                • Exploration
                                                                                                • Environmental Considerations
                                                                                                • REE Fertilizer
                                                                                                • Investigation by T Liang et al
                                                                                                • Implications
                                                                                                • Acid Mine Drainage (AMD)
                                                                                                • Radioactive Elements
                                                                                                • Radioactive Hazards
                                                                                                • Summary
                                                                                                • References

                                                                                                  HREEs

                                                                                                  and Nuclear Technology

                                                                                                  bull

                                                                                                  Dysprosium Homium Erbium

                                                                                                  bull

                                                                                                  High neutron

                                                                                                  absorption cross-section ndash

                                                                                                  Measure of probability of neutron capture

                                                                                                  bull

                                                                                                  Used in neutron-absorbing control rods in nuclear reactors

                                                                                                  HREEs

                                                                                                  and Nuclear Technology

                                                                                                  bull

                                                                                                  Lutetiumbull

                                                                                                  Radioactive isotope used in radiometric dating

                                                                                                  bull

                                                                                                  Thulium bull

                                                                                                  Stable thulium used as a radiation

                                                                                                  source

                                                                                                  in portable X-ray

                                                                                                  devices

                                                                                                  Mountain Passbull

                                                                                                  Bastnasite

                                                                                                  is the major REE mineral bull

                                                                                                  High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                                  31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                                  Mining stopped in 1994 ndash

                                                                                                  Thorium content of waste rock ndash

                                                                                                  Availability of inexpensive REEs

                                                                                                  from China

                                                                                                  San Bernardino County

                                                                                                  Bayan

                                                                                                  Obobull

                                                                                                  The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                                  bull

                                                                                                  37 million tons of ore bull

                                                                                                  Main REE source there is Bastnasite

                                                                                                  World Production

                                                                                                  Explorationbull

                                                                                                  84 of REE imports to US are from China

                                                                                                  bull

                                                                                                  Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                                  bull

                                                                                                  Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                                  Lake as well as in

                                                                                                  Malawi Africa

                                                                                                  Environmental Considerations

                                                                                                  bull

                                                                                                  REE soil and food contaminationbull

                                                                                                  Acid Mine Drainage and groundwater systems

                                                                                                  bull

                                                                                                  Radioactive elements

                                                                                                  REE Fertilizerbull

                                                                                                  In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                                  bull

                                                                                                  At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                                  every year

                                                                                                  bull

                                                                                                  Research and agricultural practice that provides evidence that REEs

                                                                                                  will improve crop quality an yield

                                                                                                  bull

                                                                                                  The ramifications environmental and human exposure to REEs

                                                                                                  are not well understood

                                                                                                  Investigation by T Liang et albull

                                                                                                  Revealed that the average concentration of total REEs

                                                                                                  in Chinese soil is

                                                                                                  1768 mgkg ranging between 850 to 5227 mgkg

                                                                                                  bull

                                                                                                  In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                                  Implicationsbull

                                                                                                  Human health effects not completely understood

                                                                                                  bull

                                                                                                  REE soil content shown to be detrimental to some plant speciesndash

                                                                                                  100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                  Acid Mine Drainage (AMD)bull

                                                                                                  Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                  bull

                                                                                                  Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                  bull

                                                                                                  Process mobilizes established ecotoxins

                                                                                                  (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                  bull

                                                                                                  Historically dismissed as minor environmental risk

                                                                                                  Radioactive Elements

                                                                                                  bull

                                                                                                  REEs

                                                                                                  associated with uranium and thorium

                                                                                                  bull

                                                                                                  Bastnesite 32 thorium

                                                                                                  bull

                                                                                                  Monazite sands 6 to 12 thorium oxide

                                                                                                  bull

                                                                                                  Ores containing radioactive elements are avoided as sources of REEs

                                                                                                  Radioactive Hazardsbull

                                                                                                  Mountain Pass

                                                                                                  bull

                                                                                                  Accidentsndash

                                                                                                  In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                  bull

                                                                                                  Health Effectsndash

                                                                                                  inflammatory bowel disease ndash

                                                                                                  Prolonged seizures ndash

                                                                                                  Cysts ndash

                                                                                                  Cancers

                                                                                                  bull

                                                                                                  Waste Disposal ndash

                                                                                                  Yucca Mountain

                                                                                                  Summarybull

                                                                                                  REE concentrations in the crust are rare

                                                                                                  bull

                                                                                                  Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                  bull

                                                                                                  Main REE minerals are bastnasite monazite and xenotime

                                                                                                  bull

                                                                                                  Most important deposits are found at Bayan

                                                                                                  Obo China and Mountain Pass USA

                                                                                                  bull

                                                                                                  Important electronic and nuclear applications

                                                                                                  bull

                                                                                                  Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                  system contamination though acid mine drainage association with

                                                                                                  radioactive elements

                                                                                                  Referencesbull

                                                                                                  E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                  bull

                                                                                                  Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                  bull

                                                                                                  G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                  bull

                                                                                                  B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                  The Government of South Australia wwwpirsagovaubull

                                                                                                  The US geological Survey Mineralsusgsgovbull

                                                                                                  wwwelementsdatabasecombull

                                                                                                  wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                  wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                  webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                  wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                  wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                  wwwchemicalelementscomelementseuhtmlbull

                                                                                                  boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                  lostcontentquakecomfiles200802holmiumpngbull

                                                                                                  chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                  geowebrudruzal-Bayan-Obohtmbull

                                                                                                  enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                  wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                  enwikipediaorgwikiMonazitebull

                                                                                                  webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                  wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                  httpwwwavalonventurescombull

                                                                                                  wwwnewsweekcomid43884bull

                                                                                                  httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                  httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                  • Slide Number 1
                                                                                                  • Slide Number 2
                                                                                                  • Slide Number 3
                                                                                                  • Slide Number 4
                                                                                                  • Slide Number 5
                                                                                                  • Slide Number 6
                                                                                                  • Slide Number 7
                                                                                                  • Slide Number 8
                                                                                                  • Slide Number 9
                                                                                                  • Slide Number 10
                                                                                                  • Slide Number 11
                                                                                                  • Slide Number 12
                                                                                                  • Slide Number 13
                                                                                                  • Slide Number 14
                                                                                                  • Slide Number 15
                                                                                                  • Slide Number 16
                                                                                                  • Slide Number 17
                                                                                                  • Slide Number 18
                                                                                                  • Slide Number 19
                                                                                                  • Slide Number 20
                                                                                                  • Slide Number 21
                                                                                                  • Slide Number 22
                                                                                                  • Slide Number 23
                                                                                                  • Slide Number 24
                                                                                                  • Slide Number 25
                                                                                                  • Slide Number 26
                                                                                                  • Slide Number 27
                                                                                                  • Slide Number 28
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                                                                                                  • Slide Number 30
                                                                                                  • Slide Number 31
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                                                                                                  • Slide Number 33
                                                                                                  • Slide Number 34
                                                                                                  • Slide Number 35
                                                                                                  • Slide Number 36
                                                                                                  • Slide Number 37
                                                                                                  • Slide Number 38
                                                                                                  • Slide Number 39
                                                                                                  • Slide Number 40
                                                                                                  • Slide Number 41
                                                                                                  • Slide Number 42
                                                                                                  • Slide Number 43
                                                                                                  • Slide Number 44
                                                                                                  • Slide Number 45
                                                                                                  • Slide Number 46
                                                                                                  • Slide Number 47
                                                                                                  • Slide Number 48
                                                                                                  • Slide Number 49
                                                                                                  • Slide Number 50
                                                                                                  • Slide Number 51
                                                                                                  • Rare Earth Elements
                                                                                                  • Crustal Abundances of Elements
                                                                                                  • Occurrence
                                                                                                  • Rare Earth Minerals
                                                                                                  • REE Minerals
                                                                                                  • Bastnesite
                                                                                                  • Other REE minerals
                                                                                                  • Electron Configuration
                                                                                                  • Electron Configuartion
                                                                                                  • REE Behavior
                                                                                                  • Ionic Radius
                                                                                                  • Coordination Number
                                                                                                  • Coordination Number
                                                                                                  • Other Factors
                                                                                                  • REEs and Economics
                                                                                                  • HREEs and Magnetism
                                                                                                  • Applications in Magnetism
                                                                                                  • Applications in Magnetism
                                                                                                  • HREEs and Nuclear Technology
                                                                                                  • HREEs and Nuclear Technology
                                                                                                  • Mountain Pass
                                                                                                  • Bayan Obo
                                                                                                  • World Production
                                                                                                  • Exploration
                                                                                                  • Environmental Considerations
                                                                                                  • REE Fertilizer
                                                                                                  • Investigation by T Liang et al
                                                                                                  • Implications
                                                                                                  • Acid Mine Drainage (AMD)
                                                                                                  • Radioactive Elements
                                                                                                  • Radioactive Hazards
                                                                                                  • Summary
                                                                                                  • References

                                                                                                    HREEs

                                                                                                    and Nuclear Technology

                                                                                                    bull

                                                                                                    Lutetiumbull

                                                                                                    Radioactive isotope used in radiometric dating

                                                                                                    bull

                                                                                                    Thulium bull

                                                                                                    Stable thulium used as a radiation

                                                                                                    source

                                                                                                    in portable X-ray

                                                                                                    devices

                                                                                                    Mountain Passbull

                                                                                                    Bastnasite

                                                                                                    is the major REE mineral bull

                                                                                                    High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                                    31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                                    Mining stopped in 1994 ndash

                                                                                                    Thorium content of waste rock ndash

                                                                                                    Availability of inexpensive REEs

                                                                                                    from China

                                                                                                    San Bernardino County

                                                                                                    Bayan

                                                                                                    Obobull

                                                                                                    The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                                    bull

                                                                                                    37 million tons of ore bull

                                                                                                    Main REE source there is Bastnasite

                                                                                                    World Production

                                                                                                    Explorationbull

                                                                                                    84 of REE imports to US are from China

                                                                                                    bull

                                                                                                    Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                                    bull

                                                                                                    Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                                    Lake as well as in

                                                                                                    Malawi Africa

                                                                                                    Environmental Considerations

                                                                                                    bull

                                                                                                    REE soil and food contaminationbull

                                                                                                    Acid Mine Drainage and groundwater systems

                                                                                                    bull

                                                                                                    Radioactive elements

                                                                                                    REE Fertilizerbull

                                                                                                    In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                                    bull

                                                                                                    At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                                    every year

                                                                                                    bull

                                                                                                    Research and agricultural practice that provides evidence that REEs

                                                                                                    will improve crop quality an yield

                                                                                                    bull

                                                                                                    The ramifications environmental and human exposure to REEs

                                                                                                    are not well understood

                                                                                                    Investigation by T Liang et albull

                                                                                                    Revealed that the average concentration of total REEs

                                                                                                    in Chinese soil is

                                                                                                    1768 mgkg ranging between 850 to 5227 mgkg

                                                                                                    bull

                                                                                                    In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                                    Implicationsbull

                                                                                                    Human health effects not completely understood

                                                                                                    bull

                                                                                                    REE soil content shown to be detrimental to some plant speciesndash

                                                                                                    100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                    Acid Mine Drainage (AMD)bull

                                                                                                    Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                    bull

                                                                                                    Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                    bull

                                                                                                    Process mobilizes established ecotoxins

                                                                                                    (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                    bull

                                                                                                    Historically dismissed as minor environmental risk

                                                                                                    Radioactive Elements

                                                                                                    bull

                                                                                                    REEs

                                                                                                    associated with uranium and thorium

                                                                                                    bull

                                                                                                    Bastnesite 32 thorium

                                                                                                    bull

                                                                                                    Monazite sands 6 to 12 thorium oxide

                                                                                                    bull

                                                                                                    Ores containing radioactive elements are avoided as sources of REEs

                                                                                                    Radioactive Hazardsbull

                                                                                                    Mountain Pass

                                                                                                    bull

                                                                                                    Accidentsndash

                                                                                                    In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                    bull

                                                                                                    Health Effectsndash

                                                                                                    inflammatory bowel disease ndash

                                                                                                    Prolonged seizures ndash

                                                                                                    Cysts ndash

                                                                                                    Cancers

                                                                                                    bull

                                                                                                    Waste Disposal ndash

                                                                                                    Yucca Mountain

                                                                                                    Summarybull

                                                                                                    REE concentrations in the crust are rare

                                                                                                    bull

                                                                                                    Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                    bull

                                                                                                    Main REE minerals are bastnasite monazite and xenotime

                                                                                                    bull

                                                                                                    Most important deposits are found at Bayan

                                                                                                    Obo China and Mountain Pass USA

                                                                                                    bull

                                                                                                    Important electronic and nuclear applications

                                                                                                    bull

                                                                                                    Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                    system contamination though acid mine drainage association with

                                                                                                    radioactive elements

                                                                                                    Referencesbull

                                                                                                    E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                    bull

                                                                                                    Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                    bull

                                                                                                    G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                    bull

                                                                                                    B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                    The Government of South Australia wwwpirsagovaubull

                                                                                                    The US geological Survey Mineralsusgsgovbull

                                                                                                    wwwelementsdatabasecombull

                                                                                                    wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                    wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                    webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                    wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                    wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                    wwwchemicalelementscomelementseuhtmlbull

                                                                                                    boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                    lostcontentquakecomfiles200802holmiumpngbull

                                                                                                    chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                    geowebrudruzal-Bayan-Obohtmbull

                                                                                                    enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                    wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                    enwikipediaorgwikiMonazitebull

                                                                                                    webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                    wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                    httpwwwavalonventurescombull

                                                                                                    wwwnewsweekcomid43884bull

                                                                                                    httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                    httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                    • Slide Number 1
                                                                                                    • Slide Number 2
                                                                                                    • Slide Number 3
                                                                                                    • Slide Number 4
                                                                                                    • Slide Number 5
                                                                                                    • Slide Number 6
                                                                                                    • Slide Number 7
                                                                                                    • Slide Number 8
                                                                                                    • Slide Number 9
                                                                                                    • Slide Number 10
                                                                                                    • Slide Number 11
                                                                                                    • Slide Number 12
                                                                                                    • Slide Number 13
                                                                                                    • Slide Number 14
                                                                                                    • Slide Number 15
                                                                                                    • Slide Number 16
                                                                                                    • Slide Number 17
                                                                                                    • Slide Number 18
                                                                                                    • Slide Number 19
                                                                                                    • Slide Number 20
                                                                                                    • Slide Number 21
                                                                                                    • Slide Number 22
                                                                                                    • Slide Number 23
                                                                                                    • Slide Number 24
                                                                                                    • Slide Number 25
                                                                                                    • Slide Number 26
                                                                                                    • Slide Number 27
                                                                                                    • Slide Number 28
                                                                                                    • Slide Number 29
                                                                                                    • Slide Number 30
                                                                                                    • Slide Number 31
                                                                                                    • Slide Number 32
                                                                                                    • Slide Number 33
                                                                                                    • Slide Number 34
                                                                                                    • Slide Number 35
                                                                                                    • Slide Number 36
                                                                                                    • Slide Number 37
                                                                                                    • Slide Number 38
                                                                                                    • Slide Number 39
                                                                                                    • Slide Number 40
                                                                                                    • Slide Number 41
                                                                                                    • Slide Number 42
                                                                                                    • Slide Number 43
                                                                                                    • Slide Number 44
                                                                                                    • Slide Number 45
                                                                                                    • Slide Number 46
                                                                                                    • Slide Number 47
                                                                                                    • Slide Number 48
                                                                                                    • Slide Number 49
                                                                                                    • Slide Number 50
                                                                                                    • Slide Number 51
                                                                                                    • Rare Earth Elements
                                                                                                    • Crustal Abundances of Elements
                                                                                                    • Occurrence
                                                                                                    • Rare Earth Minerals
                                                                                                    • REE Minerals
                                                                                                    • Bastnesite
                                                                                                    • Other REE minerals
                                                                                                    • Electron Configuration
                                                                                                    • Electron Configuartion
                                                                                                    • REE Behavior
                                                                                                    • Ionic Radius
                                                                                                    • Coordination Number
                                                                                                    • Coordination Number
                                                                                                    • Other Factors
                                                                                                    • REEs and Economics
                                                                                                    • HREEs and Magnetism
                                                                                                    • Applications in Magnetism
                                                                                                    • Applications in Magnetism
                                                                                                    • HREEs and Nuclear Technology
                                                                                                    • HREEs and Nuclear Technology
                                                                                                    • Mountain Pass
                                                                                                    • Bayan Obo
                                                                                                    • World Production
                                                                                                    • Exploration
                                                                                                    • Environmental Considerations
                                                                                                    • REE Fertilizer
                                                                                                    • Investigation by T Liang et al
                                                                                                    • Implications
                                                                                                    • Acid Mine Drainage (AMD)
                                                                                                    • Radioactive Elements
                                                                                                    • Radioactive Hazards
                                                                                                    • Summary
                                                                                                    • References

                                                                                                      Mountain Passbull

                                                                                                      Bastnasite

                                                                                                      is the major REE mineral bull

                                                                                                      High grade accessory mineral of igneous or hydrothermal originsbull

                                                                                                      31 million tons of 886 by weight of rare earth oxides (REO) bull

                                                                                                      Mining stopped in 1994 ndash

                                                                                                      Thorium content of waste rock ndash

                                                                                                      Availability of inexpensive REEs

                                                                                                      from China

                                                                                                      San Bernardino County

                                                                                                      Bayan

                                                                                                      Obobull

                                                                                                      The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                                      bull

                                                                                                      37 million tons of ore bull

                                                                                                      Main REE source there is Bastnasite

                                                                                                      World Production

                                                                                                      Explorationbull

                                                                                                      84 of REE imports to US are from China

                                                                                                      bull

                                                                                                      Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                                      bull

                                                                                                      Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                                      Lake as well as in

                                                                                                      Malawi Africa

                                                                                                      Environmental Considerations

                                                                                                      bull

                                                                                                      REE soil and food contaminationbull

                                                                                                      Acid Mine Drainage and groundwater systems

                                                                                                      bull

                                                                                                      Radioactive elements

                                                                                                      REE Fertilizerbull

                                                                                                      In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                                      bull

                                                                                                      At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                                      every year

                                                                                                      bull

                                                                                                      Research and agricultural practice that provides evidence that REEs

                                                                                                      will improve crop quality an yield

                                                                                                      bull

                                                                                                      The ramifications environmental and human exposure to REEs

                                                                                                      are not well understood

                                                                                                      Investigation by T Liang et albull

                                                                                                      Revealed that the average concentration of total REEs

                                                                                                      in Chinese soil is

                                                                                                      1768 mgkg ranging between 850 to 5227 mgkg

                                                                                                      bull

                                                                                                      In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                                      Implicationsbull

                                                                                                      Human health effects not completely understood

                                                                                                      bull

                                                                                                      REE soil content shown to be detrimental to some plant speciesndash

                                                                                                      100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                      Acid Mine Drainage (AMD)bull

                                                                                                      Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                      bull

                                                                                                      Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                      bull

                                                                                                      Process mobilizes established ecotoxins

                                                                                                      (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                      bull

                                                                                                      Historically dismissed as minor environmental risk

                                                                                                      Radioactive Elements

                                                                                                      bull

                                                                                                      REEs

                                                                                                      associated with uranium and thorium

                                                                                                      bull

                                                                                                      Bastnesite 32 thorium

                                                                                                      bull

                                                                                                      Monazite sands 6 to 12 thorium oxide

                                                                                                      bull

                                                                                                      Ores containing radioactive elements are avoided as sources of REEs

                                                                                                      Radioactive Hazardsbull

                                                                                                      Mountain Pass

                                                                                                      bull

                                                                                                      Accidentsndash

                                                                                                      In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                      bull

                                                                                                      Health Effectsndash

                                                                                                      inflammatory bowel disease ndash

                                                                                                      Prolonged seizures ndash

                                                                                                      Cysts ndash

                                                                                                      Cancers

                                                                                                      bull

                                                                                                      Waste Disposal ndash

                                                                                                      Yucca Mountain

                                                                                                      Summarybull

                                                                                                      REE concentrations in the crust are rare

                                                                                                      bull

                                                                                                      Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                      bull

                                                                                                      Main REE minerals are bastnasite monazite and xenotime

                                                                                                      bull

                                                                                                      Most important deposits are found at Bayan

                                                                                                      Obo China and Mountain Pass USA

                                                                                                      bull

                                                                                                      Important electronic and nuclear applications

                                                                                                      bull

                                                                                                      Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                      system contamination though acid mine drainage association with

                                                                                                      radioactive elements

                                                                                                      Referencesbull

                                                                                                      E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                      bull

                                                                                                      Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                      bull

                                                                                                      G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                      bull

                                                                                                      B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                      The Government of South Australia wwwpirsagovaubull

                                                                                                      The US geological Survey Mineralsusgsgovbull

                                                                                                      wwwelementsdatabasecombull

                                                                                                      wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                      wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                      webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                      wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                      wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                      wwwchemicalelementscomelementseuhtmlbull

                                                                                                      boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                      lostcontentquakecomfiles200802holmiumpngbull

                                                                                                      chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                      geowebrudruzal-Bayan-Obohtmbull

                                                                                                      enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                      wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                      enwikipediaorgwikiMonazitebull

                                                                                                      webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                      wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                      httpwwwavalonventurescombull

                                                                                                      wwwnewsweekcomid43884bull

                                                                                                      httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                      httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                      • Slide Number 1
                                                                                                      • Slide Number 2
                                                                                                      • Slide Number 3
                                                                                                      • Slide Number 4
                                                                                                      • Slide Number 5
                                                                                                      • Slide Number 6
                                                                                                      • Slide Number 7
                                                                                                      • Slide Number 8
                                                                                                      • Slide Number 9
                                                                                                      • Slide Number 10
                                                                                                      • Slide Number 11
                                                                                                      • Slide Number 12
                                                                                                      • Slide Number 13
                                                                                                      • Slide Number 14
                                                                                                      • Slide Number 15
                                                                                                      • Slide Number 16
                                                                                                      • Slide Number 17
                                                                                                      • Slide Number 18
                                                                                                      • Slide Number 19
                                                                                                      • Slide Number 20
                                                                                                      • Slide Number 21
                                                                                                      • Slide Number 22
                                                                                                      • Slide Number 23
                                                                                                      • Slide Number 24
                                                                                                      • Slide Number 25
                                                                                                      • Slide Number 26
                                                                                                      • Slide Number 27
                                                                                                      • Slide Number 28
                                                                                                      • Slide Number 29
                                                                                                      • Slide Number 30
                                                                                                      • Slide Number 31
                                                                                                      • Slide Number 32
                                                                                                      • Slide Number 33
                                                                                                      • Slide Number 34
                                                                                                      • Slide Number 35
                                                                                                      • Slide Number 36
                                                                                                      • Slide Number 37
                                                                                                      • Slide Number 38
                                                                                                      • Slide Number 39
                                                                                                      • Slide Number 40
                                                                                                      • Slide Number 41
                                                                                                      • Slide Number 42
                                                                                                      • Slide Number 43
                                                                                                      • Slide Number 44
                                                                                                      • Slide Number 45
                                                                                                      • Slide Number 46
                                                                                                      • Slide Number 47
                                                                                                      • Slide Number 48
                                                                                                      • Slide Number 49
                                                                                                      • Slide Number 50
                                                                                                      • Slide Number 51
                                                                                                      • Rare Earth Elements
                                                                                                      • Crustal Abundances of Elements
                                                                                                      • Occurrence
                                                                                                      • Rare Earth Minerals
                                                                                                      • REE Minerals
                                                                                                      • Bastnesite
                                                                                                      • Other REE minerals
                                                                                                      • Electron Configuration
                                                                                                      • Electron Configuartion
                                                                                                      • REE Behavior
                                                                                                      • Ionic Radius
                                                                                                      • Coordination Number
                                                                                                      • Coordination Number
                                                                                                      • Other Factors
                                                                                                      • REEs and Economics
                                                                                                      • HREEs and Magnetism
                                                                                                      • Applications in Magnetism
                                                                                                      • Applications in Magnetism
                                                                                                      • HREEs and Nuclear Technology
                                                                                                      • HREEs and Nuclear Technology
                                                                                                      • Mountain Pass
                                                                                                      • Bayan Obo
                                                                                                      • World Production
                                                                                                      • Exploration
                                                                                                      • Environmental Considerations
                                                                                                      • REE Fertilizer
                                                                                                      • Investigation by T Liang et al
                                                                                                      • Implications
                                                                                                      • Acid Mine Drainage (AMD)
                                                                                                      • Radioactive Elements
                                                                                                      • Radioactive Hazards
                                                                                                      • Summary
                                                                                                      • References

                                                                                                        Bayan

                                                                                                        Obobull

                                                                                                        The worldrsquos primary source for both yttrium and the rare earth elements

                                                                                                        bull

                                                                                                        37 million tons of ore bull

                                                                                                        Main REE source there is Bastnasite

                                                                                                        World Production

                                                                                                        Explorationbull

                                                                                                        84 of REE imports to US are from China

                                                                                                        bull

                                                                                                        Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                                        bull

                                                                                                        Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                                        Lake as well as in

                                                                                                        Malawi Africa

                                                                                                        Environmental Considerations

                                                                                                        bull

                                                                                                        REE soil and food contaminationbull

                                                                                                        Acid Mine Drainage and groundwater systems

                                                                                                        bull

                                                                                                        Radioactive elements

                                                                                                        REE Fertilizerbull

                                                                                                        In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                                        bull

                                                                                                        At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                                        every year

                                                                                                        bull

                                                                                                        Research and agricultural practice that provides evidence that REEs

                                                                                                        will improve crop quality an yield

                                                                                                        bull

                                                                                                        The ramifications environmental and human exposure to REEs

                                                                                                        are not well understood

                                                                                                        Investigation by T Liang et albull

                                                                                                        Revealed that the average concentration of total REEs

                                                                                                        in Chinese soil is

                                                                                                        1768 mgkg ranging between 850 to 5227 mgkg

                                                                                                        bull

                                                                                                        In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                                        Implicationsbull

                                                                                                        Human health effects not completely understood

                                                                                                        bull

                                                                                                        REE soil content shown to be detrimental to some plant speciesndash

                                                                                                        100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                        Acid Mine Drainage (AMD)bull

                                                                                                        Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                        bull

                                                                                                        Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                        bull

                                                                                                        Process mobilizes established ecotoxins

                                                                                                        (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                        bull

                                                                                                        Historically dismissed as minor environmental risk

                                                                                                        Radioactive Elements

                                                                                                        bull

                                                                                                        REEs

                                                                                                        associated with uranium and thorium

                                                                                                        bull

                                                                                                        Bastnesite 32 thorium

                                                                                                        bull

                                                                                                        Monazite sands 6 to 12 thorium oxide

                                                                                                        bull

                                                                                                        Ores containing radioactive elements are avoided as sources of REEs

                                                                                                        Radioactive Hazardsbull

                                                                                                        Mountain Pass

                                                                                                        bull

                                                                                                        Accidentsndash

                                                                                                        In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                        bull

                                                                                                        Health Effectsndash

                                                                                                        inflammatory bowel disease ndash

                                                                                                        Prolonged seizures ndash

                                                                                                        Cysts ndash

                                                                                                        Cancers

                                                                                                        bull

                                                                                                        Waste Disposal ndash

                                                                                                        Yucca Mountain

                                                                                                        Summarybull

                                                                                                        REE concentrations in the crust are rare

                                                                                                        bull

                                                                                                        Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                        bull

                                                                                                        Main REE minerals are bastnasite monazite and xenotime

                                                                                                        bull

                                                                                                        Most important deposits are found at Bayan

                                                                                                        Obo China and Mountain Pass USA

                                                                                                        bull

                                                                                                        Important electronic and nuclear applications

                                                                                                        bull

                                                                                                        Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                        system contamination though acid mine drainage association with

                                                                                                        radioactive elements

                                                                                                        Referencesbull

                                                                                                        E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                        bull

                                                                                                        Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                        bull

                                                                                                        G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                        bull

                                                                                                        B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                        The Government of South Australia wwwpirsagovaubull

                                                                                                        The US geological Survey Mineralsusgsgovbull

                                                                                                        wwwelementsdatabasecombull

                                                                                                        wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                        wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                        webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                        wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                        wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                        wwwchemicalelementscomelementseuhtmlbull

                                                                                                        boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                        lostcontentquakecomfiles200802holmiumpngbull

                                                                                                        chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                        geowebrudruzal-Bayan-Obohtmbull

                                                                                                        enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                        wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                        enwikipediaorgwikiMonazitebull

                                                                                                        webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                        wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                        httpwwwavalonventurescombull

                                                                                                        wwwnewsweekcomid43884bull

                                                                                                        httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                        httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                        • Slide Number 1
                                                                                                        • Slide Number 2
                                                                                                        • Slide Number 3
                                                                                                        • Slide Number 4
                                                                                                        • Slide Number 5
                                                                                                        • Slide Number 6
                                                                                                        • Slide Number 7
                                                                                                        • Slide Number 8
                                                                                                        • Slide Number 9
                                                                                                        • Slide Number 10
                                                                                                        • Slide Number 11
                                                                                                        • Slide Number 12
                                                                                                        • Slide Number 13
                                                                                                        • Slide Number 14
                                                                                                        • Slide Number 15
                                                                                                        • Slide Number 16
                                                                                                        • Slide Number 17
                                                                                                        • Slide Number 18
                                                                                                        • Slide Number 19
                                                                                                        • Slide Number 20
                                                                                                        • Slide Number 21
                                                                                                        • Slide Number 22
                                                                                                        • Slide Number 23
                                                                                                        • Slide Number 24
                                                                                                        • Slide Number 25
                                                                                                        • Slide Number 26
                                                                                                        • Slide Number 27
                                                                                                        • Slide Number 28
                                                                                                        • Slide Number 29
                                                                                                        • Slide Number 30
                                                                                                        • Slide Number 31
                                                                                                        • Slide Number 32
                                                                                                        • Slide Number 33
                                                                                                        • Slide Number 34
                                                                                                        • Slide Number 35
                                                                                                        • Slide Number 36
                                                                                                        • Slide Number 37
                                                                                                        • Slide Number 38
                                                                                                        • Slide Number 39
                                                                                                        • Slide Number 40
                                                                                                        • Slide Number 41
                                                                                                        • Slide Number 42
                                                                                                        • Slide Number 43
                                                                                                        • Slide Number 44
                                                                                                        • Slide Number 45
                                                                                                        • Slide Number 46
                                                                                                        • Slide Number 47
                                                                                                        • Slide Number 48
                                                                                                        • Slide Number 49
                                                                                                        • Slide Number 50
                                                                                                        • Slide Number 51
                                                                                                        • Rare Earth Elements
                                                                                                        • Crustal Abundances of Elements
                                                                                                        • Occurrence
                                                                                                        • Rare Earth Minerals
                                                                                                        • REE Minerals
                                                                                                        • Bastnesite
                                                                                                        • Other REE minerals
                                                                                                        • Electron Configuration
                                                                                                        • Electron Configuartion
                                                                                                        • REE Behavior
                                                                                                        • Ionic Radius
                                                                                                        • Coordination Number
                                                                                                        • Coordination Number
                                                                                                        • Other Factors
                                                                                                        • REEs and Economics
                                                                                                        • HREEs and Magnetism
                                                                                                        • Applications in Magnetism
                                                                                                        • Applications in Magnetism
                                                                                                        • HREEs and Nuclear Technology
                                                                                                        • HREEs and Nuclear Technology
                                                                                                        • Mountain Pass
                                                                                                        • Bayan Obo
                                                                                                        • World Production
                                                                                                        • Exploration
                                                                                                        • Environmental Considerations
                                                                                                        • REE Fertilizer
                                                                                                        • Investigation by T Liang et al
                                                                                                        • Implications
                                                                                                        • Acid Mine Drainage (AMD)
                                                                                                        • Radioactive Elements
                                                                                                        • Radioactive Hazards
                                                                                                        • Summary
                                                                                                        • References

                                                                                                          World Production

                                                                                                          Explorationbull

                                                                                                          84 of REE imports to US are from China

                                                                                                          bull

                                                                                                          Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                                          bull

                                                                                                          Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                                          Lake as well as in

                                                                                                          Malawi Africa

                                                                                                          Environmental Considerations

                                                                                                          bull

                                                                                                          REE soil and food contaminationbull

                                                                                                          Acid Mine Drainage and groundwater systems

                                                                                                          bull

                                                                                                          Radioactive elements

                                                                                                          REE Fertilizerbull

                                                                                                          In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                                          bull

                                                                                                          At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                                          every year

                                                                                                          bull

                                                                                                          Research and agricultural practice that provides evidence that REEs

                                                                                                          will improve crop quality an yield

                                                                                                          bull

                                                                                                          The ramifications environmental and human exposure to REEs

                                                                                                          are not well understood

                                                                                                          Investigation by T Liang et albull

                                                                                                          Revealed that the average concentration of total REEs

                                                                                                          in Chinese soil is

                                                                                                          1768 mgkg ranging between 850 to 5227 mgkg

                                                                                                          bull

                                                                                                          In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                                          Implicationsbull

                                                                                                          Human health effects not completely understood

                                                                                                          bull

                                                                                                          REE soil content shown to be detrimental to some plant speciesndash

                                                                                                          100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                          Acid Mine Drainage (AMD)bull

                                                                                                          Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                          bull

                                                                                                          Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                          bull

                                                                                                          Process mobilizes established ecotoxins

                                                                                                          (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                          bull

                                                                                                          Historically dismissed as minor environmental risk

                                                                                                          Radioactive Elements

                                                                                                          bull

                                                                                                          REEs

                                                                                                          associated with uranium and thorium

                                                                                                          bull

                                                                                                          Bastnesite 32 thorium

                                                                                                          bull

                                                                                                          Monazite sands 6 to 12 thorium oxide

                                                                                                          bull

                                                                                                          Ores containing radioactive elements are avoided as sources of REEs

                                                                                                          Radioactive Hazardsbull

                                                                                                          Mountain Pass

                                                                                                          bull

                                                                                                          Accidentsndash

                                                                                                          In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                          bull

                                                                                                          Health Effectsndash

                                                                                                          inflammatory bowel disease ndash

                                                                                                          Prolonged seizures ndash

                                                                                                          Cysts ndash

                                                                                                          Cancers

                                                                                                          bull

                                                                                                          Waste Disposal ndash

                                                                                                          Yucca Mountain

                                                                                                          Summarybull

                                                                                                          REE concentrations in the crust are rare

                                                                                                          bull

                                                                                                          Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                          bull

                                                                                                          Main REE minerals are bastnasite monazite and xenotime

                                                                                                          bull

                                                                                                          Most important deposits are found at Bayan

                                                                                                          Obo China and Mountain Pass USA

                                                                                                          bull

                                                                                                          Important electronic and nuclear applications

                                                                                                          bull

                                                                                                          Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                          system contamination though acid mine drainage association with

                                                                                                          radioactive elements

                                                                                                          Referencesbull

                                                                                                          E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                          bull

                                                                                                          Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                          bull

                                                                                                          G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                          bull

                                                                                                          B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                          The Government of South Australia wwwpirsagovaubull

                                                                                                          The US geological Survey Mineralsusgsgovbull

                                                                                                          wwwelementsdatabasecombull

                                                                                                          wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                          wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                          webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                          wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                          wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                          wwwchemicalelementscomelementseuhtmlbull

                                                                                                          boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                          lostcontentquakecomfiles200802holmiumpngbull

                                                                                                          chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                          geowebrudruzal-Bayan-Obohtmbull

                                                                                                          enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                          wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                          enwikipediaorgwikiMonazitebull

                                                                                                          webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                          wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                          httpwwwavalonventurescombull

                                                                                                          wwwnewsweekcomid43884bull

                                                                                                          httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                          httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                          • Slide Number 1
                                                                                                          • Slide Number 2
                                                                                                          • Slide Number 3
                                                                                                          • Slide Number 4
                                                                                                          • Slide Number 5
                                                                                                          • Slide Number 6
                                                                                                          • Slide Number 7
                                                                                                          • Slide Number 8
                                                                                                          • Slide Number 9
                                                                                                          • Slide Number 10
                                                                                                          • Slide Number 11
                                                                                                          • Slide Number 12
                                                                                                          • Slide Number 13
                                                                                                          • Slide Number 14
                                                                                                          • Slide Number 15
                                                                                                          • Slide Number 16
                                                                                                          • Slide Number 17
                                                                                                          • Slide Number 18
                                                                                                          • Slide Number 19
                                                                                                          • Slide Number 20
                                                                                                          • Slide Number 21
                                                                                                          • Slide Number 22
                                                                                                          • Slide Number 23
                                                                                                          • Slide Number 24
                                                                                                          • Slide Number 25
                                                                                                          • Slide Number 26
                                                                                                          • Slide Number 27
                                                                                                          • Slide Number 28
                                                                                                          • Slide Number 29
                                                                                                          • Slide Number 30
                                                                                                          • Slide Number 31
                                                                                                          • Slide Number 32
                                                                                                          • Slide Number 33
                                                                                                          • Slide Number 34
                                                                                                          • Slide Number 35
                                                                                                          • Slide Number 36
                                                                                                          • Slide Number 37
                                                                                                          • Slide Number 38
                                                                                                          • Slide Number 39
                                                                                                          • Slide Number 40
                                                                                                          • Slide Number 41
                                                                                                          • Slide Number 42
                                                                                                          • Slide Number 43
                                                                                                          • Slide Number 44
                                                                                                          • Slide Number 45
                                                                                                          • Slide Number 46
                                                                                                          • Slide Number 47
                                                                                                          • Slide Number 48
                                                                                                          • Slide Number 49
                                                                                                          • Slide Number 50
                                                                                                          • Slide Number 51
                                                                                                          • Rare Earth Elements
                                                                                                          • Crustal Abundances of Elements
                                                                                                          • Occurrence
                                                                                                          • Rare Earth Minerals
                                                                                                          • REE Minerals
                                                                                                          • Bastnesite
                                                                                                          • Other REE minerals
                                                                                                          • Electron Configuration
                                                                                                          • Electron Configuartion
                                                                                                          • REE Behavior
                                                                                                          • Ionic Radius
                                                                                                          • Coordination Number
                                                                                                          • Coordination Number
                                                                                                          • Other Factors
                                                                                                          • REEs and Economics
                                                                                                          • HREEs and Magnetism
                                                                                                          • Applications in Magnetism
                                                                                                          • Applications in Magnetism
                                                                                                          • HREEs and Nuclear Technology
                                                                                                          • HREEs and Nuclear Technology
                                                                                                          • Mountain Pass
                                                                                                          • Bayan Obo
                                                                                                          • World Production
                                                                                                          • Exploration
                                                                                                          • Environmental Considerations
                                                                                                          • REE Fertilizer
                                                                                                          • Investigation by T Liang et al
                                                                                                          • Implications
                                                                                                          • Acid Mine Drainage (AMD)
                                                                                                          • Radioactive Elements
                                                                                                          • Radioactive Hazards
                                                                                                          • Summary
                                                                                                          • References

                                                                                                            Explorationbull

                                                                                                            84 of REE imports to US are from China

                                                                                                            bull

                                                                                                            Increasing demand for high tech applications spurred increase in exploration in 2007

                                                                                                            bull

                                                                                                            Economic assessments of known deposits such as Canadian Thor Lake and Hoidas

                                                                                                            Lake as well as in

                                                                                                            Malawi Africa

                                                                                                            Environmental Considerations

                                                                                                            bull

                                                                                                            REE soil and food contaminationbull

                                                                                                            Acid Mine Drainage and groundwater systems

                                                                                                            bull

                                                                                                            Radioactive elements

                                                                                                            REE Fertilizerbull

                                                                                                            In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                                            bull

                                                                                                            At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                                            every year

                                                                                                            bull

                                                                                                            Research and agricultural practice that provides evidence that REEs

                                                                                                            will improve crop quality an yield

                                                                                                            bull

                                                                                                            The ramifications environmental and human exposure to REEs

                                                                                                            are not well understood

                                                                                                            Investigation by T Liang et albull

                                                                                                            Revealed that the average concentration of total REEs

                                                                                                            in Chinese soil is

                                                                                                            1768 mgkg ranging between 850 to 5227 mgkg

                                                                                                            bull

                                                                                                            In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                                            Implicationsbull

                                                                                                            Human health effects not completely understood

                                                                                                            bull

                                                                                                            REE soil content shown to be detrimental to some plant speciesndash

                                                                                                            100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                            Acid Mine Drainage (AMD)bull

                                                                                                            Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                            bull

                                                                                                            Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                            bull

                                                                                                            Process mobilizes established ecotoxins

                                                                                                            (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                            bull

                                                                                                            Historically dismissed as minor environmental risk

                                                                                                            Radioactive Elements

                                                                                                            bull

                                                                                                            REEs

                                                                                                            associated with uranium and thorium

                                                                                                            bull

                                                                                                            Bastnesite 32 thorium

                                                                                                            bull

                                                                                                            Monazite sands 6 to 12 thorium oxide

                                                                                                            bull

                                                                                                            Ores containing radioactive elements are avoided as sources of REEs

                                                                                                            Radioactive Hazardsbull

                                                                                                            Mountain Pass

                                                                                                            bull

                                                                                                            Accidentsndash

                                                                                                            In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                            bull

                                                                                                            Health Effectsndash

                                                                                                            inflammatory bowel disease ndash

                                                                                                            Prolonged seizures ndash

                                                                                                            Cysts ndash

                                                                                                            Cancers

                                                                                                            bull

                                                                                                            Waste Disposal ndash

                                                                                                            Yucca Mountain

                                                                                                            Summarybull

                                                                                                            REE concentrations in the crust are rare

                                                                                                            bull

                                                                                                            Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                            bull

                                                                                                            Main REE minerals are bastnasite monazite and xenotime

                                                                                                            bull

                                                                                                            Most important deposits are found at Bayan

                                                                                                            Obo China and Mountain Pass USA

                                                                                                            bull

                                                                                                            Important electronic and nuclear applications

                                                                                                            bull

                                                                                                            Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                            system contamination though acid mine drainage association with

                                                                                                            radioactive elements

                                                                                                            Referencesbull

                                                                                                            E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                            bull

                                                                                                            Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                            bull

                                                                                                            G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                            bull

                                                                                                            B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                            The Government of South Australia wwwpirsagovaubull

                                                                                                            The US geological Survey Mineralsusgsgovbull

                                                                                                            wwwelementsdatabasecombull

                                                                                                            wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                            wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                            webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                            wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                            wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                            wwwchemicalelementscomelementseuhtmlbull

                                                                                                            boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                            lostcontentquakecomfiles200802holmiumpngbull

                                                                                                            chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                            geowebrudruzal-Bayan-Obohtmbull

                                                                                                            enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                            wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                            enwikipediaorgwikiMonazitebull

                                                                                                            webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                            wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                            httpwwwavalonventurescombull

                                                                                                            wwwnewsweekcomid43884bull

                                                                                                            httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                            httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                            • Slide Number 1
                                                                                                            • Slide Number 2
                                                                                                            • Slide Number 3
                                                                                                            • Slide Number 4
                                                                                                            • Slide Number 5
                                                                                                            • Slide Number 6
                                                                                                            • Slide Number 7
                                                                                                            • Slide Number 8
                                                                                                            • Slide Number 9
                                                                                                            • Slide Number 10
                                                                                                            • Slide Number 11
                                                                                                            • Slide Number 12
                                                                                                            • Slide Number 13
                                                                                                            • Slide Number 14
                                                                                                            • Slide Number 15
                                                                                                            • Slide Number 16
                                                                                                            • Slide Number 17
                                                                                                            • Slide Number 18
                                                                                                            • Slide Number 19
                                                                                                            • Slide Number 20
                                                                                                            • Slide Number 21
                                                                                                            • Slide Number 22
                                                                                                            • Slide Number 23
                                                                                                            • Slide Number 24
                                                                                                            • Slide Number 25
                                                                                                            • Slide Number 26
                                                                                                            • Slide Number 27
                                                                                                            • Slide Number 28
                                                                                                            • Slide Number 29
                                                                                                            • Slide Number 30
                                                                                                            • Slide Number 31
                                                                                                            • Slide Number 32
                                                                                                            • Slide Number 33
                                                                                                            • Slide Number 34
                                                                                                            • Slide Number 35
                                                                                                            • Slide Number 36
                                                                                                            • Slide Number 37
                                                                                                            • Slide Number 38
                                                                                                            • Slide Number 39
                                                                                                            • Slide Number 40
                                                                                                            • Slide Number 41
                                                                                                            • Slide Number 42
                                                                                                            • Slide Number 43
                                                                                                            • Slide Number 44
                                                                                                            • Slide Number 45
                                                                                                            • Slide Number 46
                                                                                                            • Slide Number 47
                                                                                                            • Slide Number 48
                                                                                                            • Slide Number 49
                                                                                                            • Slide Number 50
                                                                                                            • Slide Number 51
                                                                                                            • Rare Earth Elements
                                                                                                            • Crustal Abundances of Elements
                                                                                                            • Occurrence
                                                                                                            • Rare Earth Minerals
                                                                                                            • REE Minerals
                                                                                                            • Bastnesite
                                                                                                            • Other REE minerals
                                                                                                            • Electron Configuration
                                                                                                            • Electron Configuartion
                                                                                                            • REE Behavior
                                                                                                            • Ionic Radius
                                                                                                            • Coordination Number
                                                                                                            • Coordination Number
                                                                                                            • Other Factors
                                                                                                            • REEs and Economics
                                                                                                            • HREEs and Magnetism
                                                                                                            • Applications in Magnetism
                                                                                                            • Applications in Magnetism
                                                                                                            • HREEs and Nuclear Technology
                                                                                                            • HREEs and Nuclear Technology
                                                                                                            • Mountain Pass
                                                                                                            • Bayan Obo
                                                                                                            • World Production
                                                                                                            • Exploration
                                                                                                            • Environmental Considerations
                                                                                                            • REE Fertilizer
                                                                                                            • Investigation by T Liang et al
                                                                                                            • Implications
                                                                                                            • Acid Mine Drainage (AMD)
                                                                                                            • Radioactive Elements
                                                                                                            • Radioactive Hazards
                                                                                                            • Summary
                                                                                                            • References

                                                                                                              Environmental Considerations

                                                                                                              bull

                                                                                                              REE soil and food contaminationbull

                                                                                                              Acid Mine Drainage and groundwater systems

                                                                                                              bull

                                                                                                              Radioactive elements

                                                                                                              REE Fertilizerbull

                                                                                                              In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                                              bull

                                                                                                              At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                                              every year

                                                                                                              bull

                                                                                                              Research and agricultural practice that provides evidence that REEs

                                                                                                              will improve crop quality an yield

                                                                                                              bull

                                                                                                              The ramifications environmental and human exposure to REEs

                                                                                                              are not well understood

                                                                                                              Investigation by T Liang et albull

                                                                                                              Revealed that the average concentration of total REEs

                                                                                                              in Chinese soil is

                                                                                                              1768 mgkg ranging between 850 to 5227 mgkg

                                                                                                              bull

                                                                                                              In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                                              Implicationsbull

                                                                                                              Human health effects not completely understood

                                                                                                              bull

                                                                                                              REE soil content shown to be detrimental to some plant speciesndash

                                                                                                              100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                              Acid Mine Drainage (AMD)bull

                                                                                                              Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                              bull

                                                                                                              Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                              bull

                                                                                                              Process mobilizes established ecotoxins

                                                                                                              (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                              bull

                                                                                                              Historically dismissed as minor environmental risk

                                                                                                              Radioactive Elements

                                                                                                              bull

                                                                                                              REEs

                                                                                                              associated with uranium and thorium

                                                                                                              bull

                                                                                                              Bastnesite 32 thorium

                                                                                                              bull

                                                                                                              Monazite sands 6 to 12 thorium oxide

                                                                                                              bull

                                                                                                              Ores containing radioactive elements are avoided as sources of REEs

                                                                                                              Radioactive Hazardsbull

                                                                                                              Mountain Pass

                                                                                                              bull

                                                                                                              Accidentsndash

                                                                                                              In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                              bull

                                                                                                              Health Effectsndash

                                                                                                              inflammatory bowel disease ndash

                                                                                                              Prolonged seizures ndash

                                                                                                              Cysts ndash

                                                                                                              Cancers

                                                                                                              bull

                                                                                                              Waste Disposal ndash

                                                                                                              Yucca Mountain

                                                                                                              Summarybull

                                                                                                              REE concentrations in the crust are rare

                                                                                                              bull

                                                                                                              Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                              bull

                                                                                                              Main REE minerals are bastnasite monazite and xenotime

                                                                                                              bull

                                                                                                              Most important deposits are found at Bayan

                                                                                                              Obo China and Mountain Pass USA

                                                                                                              bull

                                                                                                              Important electronic and nuclear applications

                                                                                                              bull

                                                                                                              Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                              system contamination though acid mine drainage association with

                                                                                                              radioactive elements

                                                                                                              Referencesbull

                                                                                                              E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                              bull

                                                                                                              Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                              bull

                                                                                                              G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                              bull

                                                                                                              B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                              The Government of South Australia wwwpirsagovaubull

                                                                                                              The US geological Survey Mineralsusgsgovbull

                                                                                                              wwwelementsdatabasecombull

                                                                                                              wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                              wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                              webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                              wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                              wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                              wwwchemicalelementscomelementseuhtmlbull

                                                                                                              boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                              lostcontentquakecomfiles200802holmiumpngbull

                                                                                                              chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                              geowebrudruzal-Bayan-Obohtmbull

                                                                                                              enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                              wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                              enwikipediaorgwikiMonazitebull

                                                                                                              webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                              wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                              httpwwwavalonventurescombull

                                                                                                              wwwnewsweekcomid43884bull

                                                                                                              httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                              httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                              • Slide Number 1
                                                                                                              • Slide Number 2
                                                                                                              • Slide Number 3
                                                                                                              • Slide Number 4
                                                                                                              • Slide Number 5
                                                                                                              • Slide Number 6
                                                                                                              • Slide Number 7
                                                                                                              • Slide Number 8
                                                                                                              • Slide Number 9
                                                                                                              • Slide Number 10
                                                                                                              • Slide Number 11
                                                                                                              • Slide Number 12
                                                                                                              • Slide Number 13
                                                                                                              • Slide Number 14
                                                                                                              • Slide Number 15
                                                                                                              • Slide Number 16
                                                                                                              • Slide Number 17
                                                                                                              • Slide Number 18
                                                                                                              • Slide Number 19
                                                                                                              • Slide Number 20
                                                                                                              • Slide Number 21
                                                                                                              • Slide Number 22
                                                                                                              • Slide Number 23
                                                                                                              • Slide Number 24
                                                                                                              • Slide Number 25
                                                                                                              • Slide Number 26
                                                                                                              • Slide Number 27
                                                                                                              • Slide Number 28
                                                                                                              • Slide Number 29
                                                                                                              • Slide Number 30
                                                                                                              • Slide Number 31
                                                                                                              • Slide Number 32
                                                                                                              • Slide Number 33
                                                                                                              • Slide Number 34
                                                                                                              • Slide Number 35
                                                                                                              • Slide Number 36
                                                                                                              • Slide Number 37
                                                                                                              • Slide Number 38
                                                                                                              • Slide Number 39
                                                                                                              • Slide Number 40
                                                                                                              • Slide Number 41
                                                                                                              • Slide Number 42
                                                                                                              • Slide Number 43
                                                                                                              • Slide Number 44
                                                                                                              • Slide Number 45
                                                                                                              • Slide Number 46
                                                                                                              • Slide Number 47
                                                                                                              • Slide Number 48
                                                                                                              • Slide Number 49
                                                                                                              • Slide Number 50
                                                                                                              • Slide Number 51
                                                                                                              • Rare Earth Elements
                                                                                                              • Crustal Abundances of Elements
                                                                                                              • Occurrence
                                                                                                              • Rare Earth Minerals
                                                                                                              • REE Minerals
                                                                                                              • Bastnesite
                                                                                                              • Other REE minerals
                                                                                                              • Electron Configuration
                                                                                                              • Electron Configuartion
                                                                                                              • REE Behavior
                                                                                                              • Ionic Radius
                                                                                                              • Coordination Number
                                                                                                              • Coordination Number
                                                                                                              • Other Factors
                                                                                                              • REEs and Economics
                                                                                                              • HREEs and Magnetism
                                                                                                              • Applications in Magnetism
                                                                                                              • Applications in Magnetism
                                                                                                              • HREEs and Nuclear Technology
                                                                                                              • HREEs and Nuclear Technology
                                                                                                              • Mountain Pass
                                                                                                              • Bayan Obo
                                                                                                              • World Production
                                                                                                              • Exploration
                                                                                                              • Environmental Considerations
                                                                                                              • REE Fertilizer
                                                                                                              • Investigation by T Liang et al
                                                                                                              • Implications
                                                                                                              • Acid Mine Drainage (AMD)
                                                                                                              • Radioactive Elements
                                                                                                              • Radioactive Hazards
                                                                                                              • Summary
                                                                                                              • References

                                                                                                                REE Fertilizerbull

                                                                                                                In China REE enriched fertilizer has been used in crop fields since 1990

                                                                                                                bull

                                                                                                                At the turn of the century 50 to 100 million tons of REEs were being applied to an area of about 4 million hectares

                                                                                                                every year

                                                                                                                bull

                                                                                                                Research and agricultural practice that provides evidence that REEs

                                                                                                                will improve crop quality an yield

                                                                                                                bull

                                                                                                                The ramifications environmental and human exposure to REEs

                                                                                                                are not well understood

                                                                                                                Investigation by T Liang et albull

                                                                                                                Revealed that the average concentration of total REEs

                                                                                                                in Chinese soil is

                                                                                                                1768 mgkg ranging between 850 to 5227 mgkg

                                                                                                                bull

                                                                                                                In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                                                Implicationsbull

                                                                                                                Human health effects not completely understood

                                                                                                                bull

                                                                                                                REE soil content shown to be detrimental to some plant speciesndash

                                                                                                                100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                                Acid Mine Drainage (AMD)bull

                                                                                                                Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                                bull

                                                                                                                Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                                bull

                                                                                                                Process mobilizes established ecotoxins

                                                                                                                (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                                bull

                                                                                                                Historically dismissed as minor environmental risk

                                                                                                                Radioactive Elements

                                                                                                                bull

                                                                                                                REEs

                                                                                                                associated with uranium and thorium

                                                                                                                bull

                                                                                                                Bastnesite 32 thorium

                                                                                                                bull

                                                                                                                Monazite sands 6 to 12 thorium oxide

                                                                                                                bull

                                                                                                                Ores containing radioactive elements are avoided as sources of REEs

                                                                                                                Radioactive Hazardsbull

                                                                                                                Mountain Pass

                                                                                                                bull

                                                                                                                Accidentsndash

                                                                                                                In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                                bull

                                                                                                                Health Effectsndash

                                                                                                                inflammatory bowel disease ndash

                                                                                                                Prolonged seizures ndash

                                                                                                                Cysts ndash

                                                                                                                Cancers

                                                                                                                bull

                                                                                                                Waste Disposal ndash

                                                                                                                Yucca Mountain

                                                                                                                Summarybull

                                                                                                                REE concentrations in the crust are rare

                                                                                                                bull

                                                                                                                Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                                bull

                                                                                                                Main REE minerals are bastnasite monazite and xenotime

                                                                                                                bull

                                                                                                                Most important deposits are found at Bayan

                                                                                                                Obo China and Mountain Pass USA

                                                                                                                bull

                                                                                                                Important electronic and nuclear applications

                                                                                                                bull

                                                                                                                Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                                system contamination though acid mine drainage association with

                                                                                                                radioactive elements

                                                                                                                Referencesbull

                                                                                                                E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                                bull

                                                                                                                Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                                bull

                                                                                                                G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                                bull

                                                                                                                B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                                The Government of South Australia wwwpirsagovaubull

                                                                                                                The US geological Survey Mineralsusgsgovbull

                                                                                                                wwwelementsdatabasecombull

                                                                                                                wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                                wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                                webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                                wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                                wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                                wwwchemicalelementscomelementseuhtmlbull

                                                                                                                boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                                lostcontentquakecomfiles200802holmiumpngbull

                                                                                                                chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                                geowebrudruzal-Bayan-Obohtmbull

                                                                                                                enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                                wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                                enwikipediaorgwikiMonazitebull

                                                                                                                webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                                wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                                httpwwwavalonventurescombull

                                                                                                                wwwnewsweekcomid43884bull

                                                                                                                httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                                httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                                • Slide Number 1
                                                                                                                • Slide Number 2
                                                                                                                • Slide Number 3
                                                                                                                • Slide Number 4
                                                                                                                • Slide Number 5
                                                                                                                • Slide Number 6
                                                                                                                • Slide Number 7
                                                                                                                • Slide Number 8
                                                                                                                • Slide Number 9
                                                                                                                • Slide Number 10
                                                                                                                • Slide Number 11
                                                                                                                • Slide Number 12
                                                                                                                • Slide Number 13
                                                                                                                • Slide Number 14
                                                                                                                • Slide Number 15
                                                                                                                • Slide Number 16
                                                                                                                • Slide Number 17
                                                                                                                • Slide Number 18
                                                                                                                • Slide Number 19
                                                                                                                • Slide Number 20
                                                                                                                • Slide Number 21
                                                                                                                • Slide Number 22
                                                                                                                • Slide Number 23
                                                                                                                • Slide Number 24
                                                                                                                • Slide Number 25
                                                                                                                • Slide Number 26
                                                                                                                • Slide Number 27
                                                                                                                • Slide Number 28
                                                                                                                • Slide Number 29
                                                                                                                • Slide Number 30
                                                                                                                • Slide Number 31
                                                                                                                • Slide Number 32
                                                                                                                • Slide Number 33
                                                                                                                • Slide Number 34
                                                                                                                • Slide Number 35
                                                                                                                • Slide Number 36
                                                                                                                • Slide Number 37
                                                                                                                • Slide Number 38
                                                                                                                • Slide Number 39
                                                                                                                • Slide Number 40
                                                                                                                • Slide Number 41
                                                                                                                • Slide Number 42
                                                                                                                • Slide Number 43
                                                                                                                • Slide Number 44
                                                                                                                • Slide Number 45
                                                                                                                • Slide Number 46
                                                                                                                • Slide Number 47
                                                                                                                • Slide Number 48
                                                                                                                • Slide Number 49
                                                                                                                • Slide Number 50
                                                                                                                • Slide Number 51
                                                                                                                • Rare Earth Elements
                                                                                                                • Crustal Abundances of Elements
                                                                                                                • Occurrence
                                                                                                                • Rare Earth Minerals
                                                                                                                • REE Minerals
                                                                                                                • Bastnesite
                                                                                                                • Other REE minerals
                                                                                                                • Electron Configuration
                                                                                                                • Electron Configuartion
                                                                                                                • REE Behavior
                                                                                                                • Ionic Radius
                                                                                                                • Coordination Number
                                                                                                                • Coordination Number
                                                                                                                • Other Factors
                                                                                                                • REEs and Economics
                                                                                                                • HREEs and Magnetism
                                                                                                                • Applications in Magnetism
                                                                                                                • Applications in Magnetism
                                                                                                                • HREEs and Nuclear Technology
                                                                                                                • HREEs and Nuclear Technology
                                                                                                                • Mountain Pass
                                                                                                                • Bayan Obo
                                                                                                                • World Production
                                                                                                                • Exploration
                                                                                                                • Environmental Considerations
                                                                                                                • REE Fertilizer
                                                                                                                • Investigation by T Liang et al
                                                                                                                • Implications
                                                                                                                • Acid Mine Drainage (AMD)
                                                                                                                • Radioactive Elements
                                                                                                                • Radioactive Hazards
                                                                                                                • Summary
                                                                                                                • References

                                                                                                                  Investigation by T Liang et albull

                                                                                                                  Revealed that the average concentration of total REEs

                                                                                                                  in Chinese soil is

                                                                                                                  1768 mgkg ranging between 850 to 5227 mgkg

                                                                                                                  bull

                                                                                                                  In wheat grains the REE distribution as similar to that of the soil with a content about 3 or 4 orders of magnitude

                                                                                                                  Implicationsbull

                                                                                                                  Human health effects not completely understood

                                                                                                                  bull

                                                                                                                  REE soil content shown to be detrimental to some plant speciesndash

                                                                                                                  100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                                  Acid Mine Drainage (AMD)bull

                                                                                                                  Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                                  bull

                                                                                                                  Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                                  bull

                                                                                                                  Process mobilizes established ecotoxins

                                                                                                                  (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                                  bull

                                                                                                                  Historically dismissed as minor environmental risk

                                                                                                                  Radioactive Elements

                                                                                                                  bull

                                                                                                                  REEs

                                                                                                                  associated with uranium and thorium

                                                                                                                  bull

                                                                                                                  Bastnesite 32 thorium

                                                                                                                  bull

                                                                                                                  Monazite sands 6 to 12 thorium oxide

                                                                                                                  bull

                                                                                                                  Ores containing radioactive elements are avoided as sources of REEs

                                                                                                                  Radioactive Hazardsbull

                                                                                                                  Mountain Pass

                                                                                                                  bull

                                                                                                                  Accidentsndash

                                                                                                                  In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                                  bull

                                                                                                                  Health Effectsndash

                                                                                                                  inflammatory bowel disease ndash

                                                                                                                  Prolonged seizures ndash

                                                                                                                  Cysts ndash

                                                                                                                  Cancers

                                                                                                                  bull

                                                                                                                  Waste Disposal ndash

                                                                                                                  Yucca Mountain

                                                                                                                  Summarybull

                                                                                                                  REE concentrations in the crust are rare

                                                                                                                  bull

                                                                                                                  Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                                  bull

                                                                                                                  Main REE minerals are bastnasite monazite and xenotime

                                                                                                                  bull

                                                                                                                  Most important deposits are found at Bayan

                                                                                                                  Obo China and Mountain Pass USA

                                                                                                                  bull

                                                                                                                  Important electronic and nuclear applications

                                                                                                                  bull

                                                                                                                  Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                                  system contamination though acid mine drainage association with

                                                                                                                  radioactive elements

                                                                                                                  Referencesbull

                                                                                                                  E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                                  bull

                                                                                                                  Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                                  bull

                                                                                                                  G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                                  bull

                                                                                                                  B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                                  The Government of South Australia wwwpirsagovaubull

                                                                                                                  The US geological Survey Mineralsusgsgovbull

                                                                                                                  wwwelementsdatabasecombull

                                                                                                                  wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                                  wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                                  webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                                  wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                                  wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                                  wwwchemicalelementscomelementseuhtmlbull

                                                                                                                  boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                                  lostcontentquakecomfiles200802holmiumpngbull

                                                                                                                  chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                                  geowebrudruzal-Bayan-Obohtmbull

                                                                                                                  enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                                  wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                                  enwikipediaorgwikiMonazitebull

                                                                                                                  webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                                  wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                                  httpwwwavalonventurescombull

                                                                                                                  wwwnewsweekcomid43884bull

                                                                                                                  httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                                  httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                                  • Slide Number 1
                                                                                                                  • Slide Number 2
                                                                                                                  • Slide Number 3
                                                                                                                  • Slide Number 4
                                                                                                                  • Slide Number 5
                                                                                                                  • Slide Number 6
                                                                                                                  • Slide Number 7
                                                                                                                  • Slide Number 8
                                                                                                                  • Slide Number 9
                                                                                                                  • Slide Number 10
                                                                                                                  • Slide Number 11
                                                                                                                  • Slide Number 12
                                                                                                                  • Slide Number 13
                                                                                                                  • Slide Number 14
                                                                                                                  • Slide Number 15
                                                                                                                  • Slide Number 16
                                                                                                                  • Slide Number 17
                                                                                                                  • Slide Number 18
                                                                                                                  • Slide Number 19
                                                                                                                  • Slide Number 20
                                                                                                                  • Slide Number 21
                                                                                                                  • Slide Number 22
                                                                                                                  • Slide Number 23
                                                                                                                  • Slide Number 24
                                                                                                                  • Slide Number 25
                                                                                                                  • Slide Number 26
                                                                                                                  • Slide Number 27
                                                                                                                  • Slide Number 28
                                                                                                                  • Slide Number 29
                                                                                                                  • Slide Number 30
                                                                                                                  • Slide Number 31
                                                                                                                  • Slide Number 32
                                                                                                                  • Slide Number 33
                                                                                                                  • Slide Number 34
                                                                                                                  • Slide Number 35
                                                                                                                  • Slide Number 36
                                                                                                                  • Slide Number 37
                                                                                                                  • Slide Number 38
                                                                                                                  • Slide Number 39
                                                                                                                  • Slide Number 40
                                                                                                                  • Slide Number 41
                                                                                                                  • Slide Number 42
                                                                                                                  • Slide Number 43
                                                                                                                  • Slide Number 44
                                                                                                                  • Slide Number 45
                                                                                                                  • Slide Number 46
                                                                                                                  • Slide Number 47
                                                                                                                  • Slide Number 48
                                                                                                                  • Slide Number 49
                                                                                                                  • Slide Number 50
                                                                                                                  • Slide Number 51
                                                                                                                  • Rare Earth Elements
                                                                                                                  • Crustal Abundances of Elements
                                                                                                                  • Occurrence
                                                                                                                  • Rare Earth Minerals
                                                                                                                  • REE Minerals
                                                                                                                  • Bastnesite
                                                                                                                  • Other REE minerals
                                                                                                                  • Electron Configuration
                                                                                                                  • Electron Configuartion
                                                                                                                  • REE Behavior
                                                                                                                  • Ionic Radius
                                                                                                                  • Coordination Number
                                                                                                                  • Coordination Number
                                                                                                                  • Other Factors
                                                                                                                  • REEs and Economics
                                                                                                                  • HREEs and Magnetism
                                                                                                                  • Applications in Magnetism
                                                                                                                  • Applications in Magnetism
                                                                                                                  • HREEs and Nuclear Technology
                                                                                                                  • HREEs and Nuclear Technology
                                                                                                                  • Mountain Pass
                                                                                                                  • Bayan Obo
                                                                                                                  • World Production
                                                                                                                  • Exploration
                                                                                                                  • Environmental Considerations
                                                                                                                  • REE Fertilizer
                                                                                                                  • Investigation by T Liang et al
                                                                                                                  • Implications
                                                                                                                  • Acid Mine Drainage (AMD)
                                                                                                                  • Radioactive Elements
                                                                                                                  • Radioactive Hazards
                                                                                                                  • Summary
                                                                                                                  • References

                                                                                                                    Implicationsbull

                                                                                                                    Human health effects not completely understood

                                                                                                                    bull

                                                                                                                    REE soil content shown to be detrimental to some plant speciesndash

                                                                                                                    100 of ryegrass specimens involved in the study that were reared with REE fertilizer showed poor development relative to the control group that was reared without elevated exposures to REEs

                                                                                                                    Acid Mine Drainage (AMD)bull

                                                                                                                    Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                                    bull

                                                                                                                    Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                                    bull

                                                                                                                    Process mobilizes established ecotoxins

                                                                                                                    (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                                    bull

                                                                                                                    Historically dismissed as minor environmental risk

                                                                                                                    Radioactive Elements

                                                                                                                    bull

                                                                                                                    REEs

                                                                                                                    associated with uranium and thorium

                                                                                                                    bull

                                                                                                                    Bastnesite 32 thorium

                                                                                                                    bull

                                                                                                                    Monazite sands 6 to 12 thorium oxide

                                                                                                                    bull

                                                                                                                    Ores containing radioactive elements are avoided as sources of REEs

                                                                                                                    Radioactive Hazardsbull

                                                                                                                    Mountain Pass

                                                                                                                    bull

                                                                                                                    Accidentsndash

                                                                                                                    In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                                    bull

                                                                                                                    Health Effectsndash

                                                                                                                    inflammatory bowel disease ndash

                                                                                                                    Prolonged seizures ndash

                                                                                                                    Cysts ndash

                                                                                                                    Cancers

                                                                                                                    bull

                                                                                                                    Waste Disposal ndash

                                                                                                                    Yucca Mountain

                                                                                                                    Summarybull

                                                                                                                    REE concentrations in the crust are rare

                                                                                                                    bull

                                                                                                                    Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                                    bull

                                                                                                                    Main REE minerals are bastnasite monazite and xenotime

                                                                                                                    bull

                                                                                                                    Most important deposits are found at Bayan

                                                                                                                    Obo China and Mountain Pass USA

                                                                                                                    bull

                                                                                                                    Important electronic and nuclear applications

                                                                                                                    bull

                                                                                                                    Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                                    system contamination though acid mine drainage association with

                                                                                                                    radioactive elements

                                                                                                                    Referencesbull

                                                                                                                    E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                                    bull

                                                                                                                    Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                                    bull

                                                                                                                    G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                                    bull

                                                                                                                    B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                                    The Government of South Australia wwwpirsagovaubull

                                                                                                                    The US geological Survey Mineralsusgsgovbull

                                                                                                                    wwwelementsdatabasecombull

                                                                                                                    wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                                    wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                                    webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                                    wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                                    wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                                    wwwchemicalelementscomelementseuhtmlbull

                                                                                                                    boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                                    lostcontentquakecomfiles200802holmiumpngbull

                                                                                                                    chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                                    geowebrudruzal-Bayan-Obohtmbull

                                                                                                                    enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                                    wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                                    enwikipediaorgwikiMonazitebull

                                                                                                                    webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                                    wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                                    httpwwwavalonventurescombull

                                                                                                                    wwwnewsweekcomid43884bull

                                                                                                                    httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                                    httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                                    • Slide Number 1
                                                                                                                    • Slide Number 2
                                                                                                                    • Slide Number 3
                                                                                                                    • Slide Number 4
                                                                                                                    • Slide Number 5
                                                                                                                    • Slide Number 6
                                                                                                                    • Slide Number 7
                                                                                                                    • Slide Number 8
                                                                                                                    • Slide Number 9
                                                                                                                    • Slide Number 10
                                                                                                                    • Slide Number 11
                                                                                                                    • Slide Number 12
                                                                                                                    • Slide Number 13
                                                                                                                    • Slide Number 14
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                                                                                                                    • Slide Number 16
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                                                                                                                    • Slide Number 18
                                                                                                                    • Slide Number 19
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                                                                                                                    • Slide Number 21
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                                                                                                                    • Slide Number 24
                                                                                                                    • Slide Number 25
                                                                                                                    • Slide Number 26
                                                                                                                    • Slide Number 27
                                                                                                                    • Slide Number 28
                                                                                                                    • Slide Number 29
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                                                                                                                    • Slide Number 32
                                                                                                                    • Slide Number 33
                                                                                                                    • Slide Number 34
                                                                                                                    • Slide Number 35
                                                                                                                    • Slide Number 36
                                                                                                                    • Slide Number 37
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                                                                                                                    • Slide Number 40
                                                                                                                    • Slide Number 41
                                                                                                                    • Slide Number 42
                                                                                                                    • Slide Number 43
                                                                                                                    • Slide Number 44
                                                                                                                    • Slide Number 45
                                                                                                                    • Slide Number 46
                                                                                                                    • Slide Number 47
                                                                                                                    • Slide Number 48
                                                                                                                    • Slide Number 49
                                                                                                                    • Slide Number 50
                                                                                                                    • Slide Number 51
                                                                                                                    • Rare Earth Elements
                                                                                                                    • Crustal Abundances of Elements
                                                                                                                    • Occurrence
                                                                                                                    • Rare Earth Minerals
                                                                                                                    • REE Minerals
                                                                                                                    • Bastnesite
                                                                                                                    • Other REE minerals
                                                                                                                    • Electron Configuration
                                                                                                                    • Electron Configuartion
                                                                                                                    • REE Behavior
                                                                                                                    • Ionic Radius
                                                                                                                    • Coordination Number
                                                                                                                    • Coordination Number
                                                                                                                    • Other Factors
                                                                                                                    • REEs and Economics
                                                                                                                    • HREEs and Magnetism
                                                                                                                    • Applications in Magnetism
                                                                                                                    • Applications in Magnetism
                                                                                                                    • HREEs and Nuclear Technology
                                                                                                                    • HREEs and Nuclear Technology
                                                                                                                    • Mountain Pass
                                                                                                                    • Bayan Obo
                                                                                                                    • World Production
                                                                                                                    • Exploration
                                                                                                                    • Environmental Considerations
                                                                                                                    • REE Fertilizer
                                                                                                                    • Investigation by T Liang et al
                                                                                                                    • Implications
                                                                                                                    • Acid Mine Drainage (AMD)
                                                                                                                    • Radioactive Elements
                                                                                                                    • Radioactive Hazards
                                                                                                                    • Summary
                                                                                                                    • References

                                                                                                                      Acid Mine Drainage (AMD)bull

                                                                                                                      Rain waters contacts waste rock facilitating acid forming reactions

                                                                                                                      bull

                                                                                                                      Increases the capacity of the water to leach potentially harmful elements from waste piles

                                                                                                                      bull

                                                                                                                      Process mobilizes established ecotoxins

                                                                                                                      (lead and mercury) as well as elements whose effects are less understood namely the rare earth elements

                                                                                                                      bull

                                                                                                                      Historically dismissed as minor environmental risk

                                                                                                                      Radioactive Elements

                                                                                                                      bull

                                                                                                                      REEs

                                                                                                                      associated with uranium and thorium

                                                                                                                      bull

                                                                                                                      Bastnesite 32 thorium

                                                                                                                      bull

                                                                                                                      Monazite sands 6 to 12 thorium oxide

                                                                                                                      bull

                                                                                                                      Ores containing radioactive elements are avoided as sources of REEs

                                                                                                                      Radioactive Hazardsbull

                                                                                                                      Mountain Pass

                                                                                                                      bull

                                                                                                                      Accidentsndash

                                                                                                                      In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                                      bull

                                                                                                                      Health Effectsndash

                                                                                                                      inflammatory bowel disease ndash

                                                                                                                      Prolonged seizures ndash

                                                                                                                      Cysts ndash

                                                                                                                      Cancers

                                                                                                                      bull

                                                                                                                      Waste Disposal ndash

                                                                                                                      Yucca Mountain

                                                                                                                      Summarybull

                                                                                                                      REE concentrations in the crust are rare

                                                                                                                      bull

                                                                                                                      Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                                      bull

                                                                                                                      Main REE minerals are bastnasite monazite and xenotime

                                                                                                                      bull

                                                                                                                      Most important deposits are found at Bayan

                                                                                                                      Obo China and Mountain Pass USA

                                                                                                                      bull

                                                                                                                      Important electronic and nuclear applications

                                                                                                                      bull

                                                                                                                      Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                                      system contamination though acid mine drainage association with

                                                                                                                      radioactive elements

                                                                                                                      Referencesbull

                                                                                                                      E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                                      bull

                                                                                                                      Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                                      bull

                                                                                                                      G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                                      bull

                                                                                                                      B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                                      The Government of South Australia wwwpirsagovaubull

                                                                                                                      The US geological Survey Mineralsusgsgovbull

                                                                                                                      wwwelementsdatabasecombull

                                                                                                                      wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                                      wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                                      webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                                      wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                                      wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                                      wwwchemicalelementscomelementseuhtmlbull

                                                                                                                      boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                                      lostcontentquakecomfiles200802holmiumpngbull

                                                                                                                      chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                                      geowebrudruzal-Bayan-Obohtmbull

                                                                                                                      enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                                      wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                                      enwikipediaorgwikiMonazitebull

                                                                                                                      webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                                      wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                                      httpwwwavalonventurescombull

                                                                                                                      wwwnewsweekcomid43884bull

                                                                                                                      httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                                      httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                                      • Slide Number 1
                                                                                                                      • Slide Number 2
                                                                                                                      • Slide Number 3
                                                                                                                      • Slide Number 4
                                                                                                                      • Slide Number 5
                                                                                                                      • Slide Number 6
                                                                                                                      • Slide Number 7
                                                                                                                      • Slide Number 8
                                                                                                                      • Slide Number 9
                                                                                                                      • Slide Number 10
                                                                                                                      • Slide Number 11
                                                                                                                      • Slide Number 12
                                                                                                                      • Slide Number 13
                                                                                                                      • Slide Number 14
                                                                                                                      • Slide Number 15
                                                                                                                      • Slide Number 16
                                                                                                                      • Slide Number 17
                                                                                                                      • Slide Number 18
                                                                                                                      • Slide Number 19
                                                                                                                      • Slide Number 20
                                                                                                                      • Slide Number 21
                                                                                                                      • Slide Number 22
                                                                                                                      • Slide Number 23
                                                                                                                      • Slide Number 24
                                                                                                                      • Slide Number 25
                                                                                                                      • Slide Number 26
                                                                                                                      • Slide Number 27
                                                                                                                      • Slide Number 28
                                                                                                                      • Slide Number 29
                                                                                                                      • Slide Number 30
                                                                                                                      • Slide Number 31
                                                                                                                      • Slide Number 32
                                                                                                                      • Slide Number 33
                                                                                                                      • Slide Number 34
                                                                                                                      • Slide Number 35
                                                                                                                      • Slide Number 36
                                                                                                                      • Slide Number 37
                                                                                                                      • Slide Number 38
                                                                                                                      • Slide Number 39
                                                                                                                      • Slide Number 40
                                                                                                                      • Slide Number 41
                                                                                                                      • Slide Number 42
                                                                                                                      • Slide Number 43
                                                                                                                      • Slide Number 44
                                                                                                                      • Slide Number 45
                                                                                                                      • Slide Number 46
                                                                                                                      • Slide Number 47
                                                                                                                      • Slide Number 48
                                                                                                                      • Slide Number 49
                                                                                                                      • Slide Number 50
                                                                                                                      • Slide Number 51
                                                                                                                      • Rare Earth Elements
                                                                                                                      • Crustal Abundances of Elements
                                                                                                                      • Occurrence
                                                                                                                      • Rare Earth Minerals
                                                                                                                      • REE Minerals
                                                                                                                      • Bastnesite
                                                                                                                      • Other REE minerals
                                                                                                                      • Electron Configuration
                                                                                                                      • Electron Configuartion
                                                                                                                      • REE Behavior
                                                                                                                      • Ionic Radius
                                                                                                                      • Coordination Number
                                                                                                                      • Coordination Number
                                                                                                                      • Other Factors
                                                                                                                      • REEs and Economics
                                                                                                                      • HREEs and Magnetism
                                                                                                                      • Applications in Magnetism
                                                                                                                      • Applications in Magnetism
                                                                                                                      • HREEs and Nuclear Technology
                                                                                                                      • HREEs and Nuclear Technology
                                                                                                                      • Mountain Pass
                                                                                                                      • Bayan Obo
                                                                                                                      • World Production
                                                                                                                      • Exploration
                                                                                                                      • Environmental Considerations
                                                                                                                      • REE Fertilizer
                                                                                                                      • Investigation by T Liang et al
                                                                                                                      • Implications
                                                                                                                      • Acid Mine Drainage (AMD)
                                                                                                                      • Radioactive Elements
                                                                                                                      • Radioactive Hazards
                                                                                                                      • Summary
                                                                                                                      • References

                                                                                                                        Radioactive Elements

                                                                                                                        bull

                                                                                                                        REEs

                                                                                                                        associated with uranium and thorium

                                                                                                                        bull

                                                                                                                        Bastnesite 32 thorium

                                                                                                                        bull

                                                                                                                        Monazite sands 6 to 12 thorium oxide

                                                                                                                        bull

                                                                                                                        Ores containing radioactive elements are avoided as sources of REEs

                                                                                                                        Radioactive Hazardsbull

                                                                                                                        Mountain Pass

                                                                                                                        bull

                                                                                                                        Accidentsndash

                                                                                                                        In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                                        bull

                                                                                                                        Health Effectsndash

                                                                                                                        inflammatory bowel disease ndash

                                                                                                                        Prolonged seizures ndash

                                                                                                                        Cysts ndash

                                                                                                                        Cancers

                                                                                                                        bull

                                                                                                                        Waste Disposal ndash

                                                                                                                        Yucca Mountain

                                                                                                                        Summarybull

                                                                                                                        REE concentrations in the crust are rare

                                                                                                                        bull

                                                                                                                        Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                                        bull

                                                                                                                        Main REE minerals are bastnasite monazite and xenotime

                                                                                                                        bull

                                                                                                                        Most important deposits are found at Bayan

                                                                                                                        Obo China and Mountain Pass USA

                                                                                                                        bull

                                                                                                                        Important electronic and nuclear applications

                                                                                                                        bull

                                                                                                                        Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                                        system contamination though acid mine drainage association with

                                                                                                                        radioactive elements

                                                                                                                        Referencesbull

                                                                                                                        E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                                        bull

                                                                                                                        Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                                        bull

                                                                                                                        G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                                        bull

                                                                                                                        B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                                        The Government of South Australia wwwpirsagovaubull

                                                                                                                        The US geological Survey Mineralsusgsgovbull

                                                                                                                        wwwelementsdatabasecombull

                                                                                                                        wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                                        wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                                        webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                                        wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                                        wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                                        wwwchemicalelementscomelementseuhtmlbull

                                                                                                                        boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                                        lostcontentquakecomfiles200802holmiumpngbull

                                                                                                                        chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                                        geowebrudruzal-Bayan-Obohtmbull

                                                                                                                        enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                                        wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                                        enwikipediaorgwikiMonazitebull

                                                                                                                        webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                                        wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                                        httpwwwavalonventurescombull

                                                                                                                        wwwnewsweekcomid43884bull

                                                                                                                        httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                                        httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                                        • Slide Number 1
                                                                                                                        • Slide Number 2
                                                                                                                        • Slide Number 3
                                                                                                                        • Slide Number 4
                                                                                                                        • Slide Number 5
                                                                                                                        • Slide Number 6
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                                                                                                                        • Slide Number 8
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                                                                                                                        • Slide Number 11
                                                                                                                        • Slide Number 12
                                                                                                                        • Slide Number 13
                                                                                                                        • Slide Number 14
                                                                                                                        • Slide Number 15
                                                                                                                        • Slide Number 16
                                                                                                                        • Slide Number 17
                                                                                                                        • Slide Number 18
                                                                                                                        • Slide Number 19
                                                                                                                        • Slide Number 20
                                                                                                                        • Slide Number 21
                                                                                                                        • Slide Number 22
                                                                                                                        • Slide Number 23
                                                                                                                        • Slide Number 24
                                                                                                                        • Slide Number 25
                                                                                                                        • Slide Number 26
                                                                                                                        • Slide Number 27
                                                                                                                        • Slide Number 28
                                                                                                                        • Slide Number 29
                                                                                                                        • Slide Number 30
                                                                                                                        • Slide Number 31
                                                                                                                        • Slide Number 32
                                                                                                                        • Slide Number 33
                                                                                                                        • Slide Number 34
                                                                                                                        • Slide Number 35
                                                                                                                        • Slide Number 36
                                                                                                                        • Slide Number 37
                                                                                                                        • Slide Number 38
                                                                                                                        • Slide Number 39
                                                                                                                        • Slide Number 40
                                                                                                                        • Slide Number 41
                                                                                                                        • Slide Number 42
                                                                                                                        • Slide Number 43
                                                                                                                        • Slide Number 44
                                                                                                                        • Slide Number 45
                                                                                                                        • Slide Number 46
                                                                                                                        • Slide Number 47
                                                                                                                        • Slide Number 48
                                                                                                                        • Slide Number 49
                                                                                                                        • Slide Number 50
                                                                                                                        • Slide Number 51
                                                                                                                        • Rare Earth Elements
                                                                                                                        • Crustal Abundances of Elements
                                                                                                                        • Occurrence
                                                                                                                        • Rare Earth Minerals
                                                                                                                        • REE Minerals
                                                                                                                        • Bastnesite
                                                                                                                        • Other REE minerals
                                                                                                                        • Electron Configuration
                                                                                                                        • Electron Configuartion
                                                                                                                        • REE Behavior
                                                                                                                        • Ionic Radius
                                                                                                                        • Coordination Number
                                                                                                                        • Coordination Number
                                                                                                                        • Other Factors
                                                                                                                        • REEs and Economics
                                                                                                                        • HREEs and Magnetism
                                                                                                                        • Applications in Magnetism
                                                                                                                        • Applications in Magnetism
                                                                                                                        • HREEs and Nuclear Technology
                                                                                                                        • HREEs and Nuclear Technology
                                                                                                                        • Mountain Pass
                                                                                                                        • Bayan Obo
                                                                                                                        • World Production
                                                                                                                        • Exploration
                                                                                                                        • Environmental Considerations
                                                                                                                        • REE Fertilizer
                                                                                                                        • Investigation by T Liang et al
                                                                                                                        • Implications
                                                                                                                        • Acid Mine Drainage (AMD)
                                                                                                                        • Radioactive Elements
                                                                                                                        • Radioactive Hazards
                                                                                                                        • Summary
                                                                                                                        • References

                                                                                                                          Radioactive Hazardsbull

                                                                                                                          Mountain Pass

                                                                                                                          bull

                                                                                                                          Accidentsndash

                                                                                                                          In 1977 major pipeline break spilled over 2 million gallons of radioactive water

                                                                                                                          bull

                                                                                                                          Health Effectsndash

                                                                                                                          inflammatory bowel disease ndash

                                                                                                                          Prolonged seizures ndash

                                                                                                                          Cysts ndash

                                                                                                                          Cancers

                                                                                                                          bull

                                                                                                                          Waste Disposal ndash

                                                                                                                          Yucca Mountain

                                                                                                                          Summarybull

                                                                                                                          REE concentrations in the crust are rare

                                                                                                                          bull

                                                                                                                          Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                                          bull

                                                                                                                          Main REE minerals are bastnasite monazite and xenotime

                                                                                                                          bull

                                                                                                                          Most important deposits are found at Bayan

                                                                                                                          Obo China and Mountain Pass USA

                                                                                                                          bull

                                                                                                                          Important electronic and nuclear applications

                                                                                                                          bull

                                                                                                                          Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                                          system contamination though acid mine drainage association with

                                                                                                                          radioactive elements

                                                                                                                          Referencesbull

                                                                                                                          E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                                          bull

                                                                                                                          Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                                          bull

                                                                                                                          G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                                          bull

                                                                                                                          B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                                          The Government of South Australia wwwpirsagovaubull

                                                                                                                          The US geological Survey Mineralsusgsgovbull

                                                                                                                          wwwelementsdatabasecombull

                                                                                                                          wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                                          wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                                          webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                                          wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                                          wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                                          wwwchemicalelementscomelementseuhtmlbull

                                                                                                                          boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                                          lostcontentquakecomfiles200802holmiumpngbull

                                                                                                                          chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                                          geowebrudruzal-Bayan-Obohtmbull

                                                                                                                          enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                                          wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                                          enwikipediaorgwikiMonazitebull

                                                                                                                          webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                                          wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                                          httpwwwavalonventurescombull

                                                                                                                          wwwnewsweekcomid43884bull

                                                                                                                          httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                                          httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                                          • Slide Number 1
                                                                                                                          • Slide Number 2
                                                                                                                          • Slide Number 3
                                                                                                                          • Slide Number 4
                                                                                                                          • Slide Number 5
                                                                                                                          • Slide Number 6
                                                                                                                          • Slide Number 7
                                                                                                                          • Slide Number 8
                                                                                                                          • Slide Number 9
                                                                                                                          • Slide Number 10
                                                                                                                          • Slide Number 11
                                                                                                                          • Slide Number 12
                                                                                                                          • Slide Number 13
                                                                                                                          • Slide Number 14
                                                                                                                          • Slide Number 15
                                                                                                                          • Slide Number 16
                                                                                                                          • Slide Number 17
                                                                                                                          • Slide Number 18
                                                                                                                          • Slide Number 19
                                                                                                                          • Slide Number 20
                                                                                                                          • Slide Number 21
                                                                                                                          • Slide Number 22
                                                                                                                          • Slide Number 23
                                                                                                                          • Slide Number 24
                                                                                                                          • Slide Number 25
                                                                                                                          • Slide Number 26
                                                                                                                          • Slide Number 27
                                                                                                                          • Slide Number 28
                                                                                                                          • Slide Number 29
                                                                                                                          • Slide Number 30
                                                                                                                          • Slide Number 31
                                                                                                                          • Slide Number 32
                                                                                                                          • Slide Number 33
                                                                                                                          • Slide Number 34
                                                                                                                          • Slide Number 35
                                                                                                                          • Slide Number 36
                                                                                                                          • Slide Number 37
                                                                                                                          • Slide Number 38
                                                                                                                          • Slide Number 39
                                                                                                                          • Slide Number 40
                                                                                                                          • Slide Number 41
                                                                                                                          • Slide Number 42
                                                                                                                          • Slide Number 43
                                                                                                                          • Slide Number 44
                                                                                                                          • Slide Number 45
                                                                                                                          • Slide Number 46
                                                                                                                          • Slide Number 47
                                                                                                                          • Slide Number 48
                                                                                                                          • Slide Number 49
                                                                                                                          • Slide Number 50
                                                                                                                          • Slide Number 51
                                                                                                                          • Rare Earth Elements
                                                                                                                          • Crustal Abundances of Elements
                                                                                                                          • Occurrence
                                                                                                                          • Rare Earth Minerals
                                                                                                                          • REE Minerals
                                                                                                                          • Bastnesite
                                                                                                                          • Other REE minerals
                                                                                                                          • Electron Configuration
                                                                                                                          • Electron Configuartion
                                                                                                                          • REE Behavior
                                                                                                                          • Ionic Radius
                                                                                                                          • Coordination Number
                                                                                                                          • Coordination Number
                                                                                                                          • Other Factors
                                                                                                                          • REEs and Economics
                                                                                                                          • HREEs and Magnetism
                                                                                                                          • Applications in Magnetism
                                                                                                                          • Applications in Magnetism
                                                                                                                          • HREEs and Nuclear Technology
                                                                                                                          • HREEs and Nuclear Technology
                                                                                                                          • Mountain Pass
                                                                                                                          • Bayan Obo
                                                                                                                          • World Production
                                                                                                                          • Exploration
                                                                                                                          • Environmental Considerations
                                                                                                                          • REE Fertilizer
                                                                                                                          • Investigation by T Liang et al
                                                                                                                          • Implications
                                                                                                                          • Acid Mine Drainage (AMD)
                                                                                                                          • Radioactive Elements
                                                                                                                          • Radioactive Hazards
                                                                                                                          • Summary
                                                                                                                          • References

                                                                                                                            Summarybull

                                                                                                                            REE concentrations in the crust are rare

                                                                                                                            bull

                                                                                                                            Several geochemical factors influencing distribution including ionic radius and coordination number

                                                                                                                            bull

                                                                                                                            Main REE minerals are bastnasite monazite and xenotime

                                                                                                                            bull

                                                                                                                            Most important deposits are found at Bayan

                                                                                                                            Obo China and Mountain Pass USA

                                                                                                                            bull

                                                                                                                            Important electronic and nuclear applications

                                                                                                                            bull

                                                                                                                            Environmental concerns associated with REE production and use are exposure to the environment and people liberation and water

                                                                                                                            system contamination though acid mine drainage association with

                                                                                                                            radioactive elements

                                                                                                                            Referencesbull

                                                                                                                            E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                                            bull

                                                                                                                            Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                                            bull

                                                                                                                            G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                                            bull

                                                                                                                            B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                                            The Government of South Australia wwwpirsagovaubull

                                                                                                                            The US geological Survey Mineralsusgsgovbull

                                                                                                                            wwwelementsdatabasecombull

                                                                                                                            wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                                            wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                                            webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                                            wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                                            wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                                            wwwchemicalelementscomelementseuhtmlbull

                                                                                                                            boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                                            lostcontentquakecomfiles200802holmiumpngbull

                                                                                                                            chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                                            geowebrudruzal-Bayan-Obohtmbull

                                                                                                                            enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                                            wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                                            enwikipediaorgwikiMonazitebull

                                                                                                                            webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                                            wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                                            httpwwwavalonventurescombull

                                                                                                                            wwwnewsweekcomid43884bull

                                                                                                                            httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                                            httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                                            • Slide Number 1
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                                                                                                                            • Slide Number 46
                                                                                                                            • Slide Number 47
                                                                                                                            • Slide Number 48
                                                                                                                            • Slide Number 49
                                                                                                                            • Slide Number 50
                                                                                                                            • Slide Number 51
                                                                                                                            • Rare Earth Elements
                                                                                                                            • Crustal Abundances of Elements
                                                                                                                            • Occurrence
                                                                                                                            • Rare Earth Minerals
                                                                                                                            • REE Minerals
                                                                                                                            • Bastnesite
                                                                                                                            • Other REE minerals
                                                                                                                            • Electron Configuration
                                                                                                                            • Electron Configuartion
                                                                                                                            • REE Behavior
                                                                                                                            • Ionic Radius
                                                                                                                            • Coordination Number
                                                                                                                            • Coordination Number
                                                                                                                            • Other Factors
                                                                                                                            • REEs and Economics
                                                                                                                            • HREEs and Magnetism
                                                                                                                            • Applications in Magnetism
                                                                                                                            • Applications in Magnetism
                                                                                                                            • HREEs and Nuclear Technology
                                                                                                                            • HREEs and Nuclear Technology
                                                                                                                            • Mountain Pass
                                                                                                                            • Bayan Obo
                                                                                                                            • World Production
                                                                                                                            • Exploration
                                                                                                                            • Environmental Considerations
                                                                                                                            • REE Fertilizer
                                                                                                                            • Investigation by T Liang et al
                                                                                                                            • Implications
                                                                                                                            • Acid Mine Drainage (AMD)
                                                                                                                            • Radioactive Elements
                                                                                                                            • Radioactive Hazards
                                                                                                                            • Summary
                                                                                                                            • References

                                                                                                                              Referencesbull

                                                                                                                              E Orvini M Speziali A Salvini C Herborg ldquoRare earth elements determination in environmental matrices by INAArdquo Microchemical Journal 67 2000 97-104

                                                                                                                              bull

                                                                                                                              Tao Liang et al ldquoEnvironmental biogeochemical behaviors of rare earth elements in soi-plant systemsrdquo Environmental Geochemistry and health 27 2005 301-311

                                                                                                                              bull

                                                                                                                              G Protano and F Riccobono ldquoHigh contents of rare earth elements (REEs) in stream wates of a CU-Pb-Zn mining areardquo Environmental Pollution 117 2002 499-514

                                                                                                                              bull

                                                                                                                              B Lipin ldquoGeochemistry and mineralogy of rare earth elementsrdquo Mineralogical Association of America 1989bull

                                                                                                                              The Government of South Australia wwwpirsagovaubull

                                                                                                                              The US geological Survey Mineralsusgsgovbull

                                                                                                                              wwwelementsdatabasecombull

                                                                                                                              wwwastrolsaumichedu~cowleyintro2htmlbull

                                                                                                                              wwwjohnbetts-finemineralscomjhbnycgifs40129htmbull

                                                                                                                              webmineralcomdataMonazite-(Ce)shtmlbull

                                                                                                                              wwwnaturecomnaturejournalv446n7136absnature05668htmlbull

                                                                                                                              wwwstevegbcomimagesscienceorbital_fillingpngbull

                                                                                                                              wwwchemicalelementscomelementseuhtmlbull

                                                                                                                              boomeriaorgchemlecturestextass2table10-9jpgbull

                                                                                                                              lostcontentquakecomfiles200802holmiumpngbull

                                                                                                                              chinageocitylocatorcomcitiesChinaQinghaibull

                                                                                                                              geowebrudruzal-Bayan-Obohtmbull

                                                                                                                              enwikipediaorgwikiSan_Bernardino_County_Californiabull

                                                                                                                              wwwworldcountriesinfoMapsRegionEurope-450-Italyjpgbull

                                                                                                                              enwikipediaorgwikiMonazitebull

                                                                                                                              webmineralcomdataBastnasite-(La)shtmlbull

                                                                                                                              wwwgbrworgindexphpoption=com_contentampview=categoryamplayout=blogampid=58ampItemid=73bull

                                                                                                                              httpwwwavalonventurescombull

                                                                                                                              wwwnewsweekcomid43884bull

                                                                                                                              httpaccipiterhawk-conservancyorgMeadowMuses200608shtmlbull

                                                                                                                              httpwwwcsescitechacukabout_usFrontiers2007Hughes20-20Lanthanide20contraction20- 20CSE20Frontiers202007pdf

                                                                                                                              • Slide Number 1
                                                                                                                              • Slide Number 2
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                                                                                                                              • Slide Number 31
                                                                                                                              • Slide Number 32
                                                                                                                              • Slide Number 33
                                                                                                                              • Slide Number 34
                                                                                                                              • Slide Number 35
                                                                                                                              • Slide Number 36
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                                                                                                                              • Slide Number 40
                                                                                                                              • Slide Number 41
                                                                                                                              • Slide Number 42
                                                                                                                              • Slide Number 43
                                                                                                                              • Slide Number 44
                                                                                                                              • Slide Number 45
                                                                                                                              • Slide Number 46
                                                                                                                              • Slide Number 47
                                                                                                                              • Slide Number 48
                                                                                                                              • Slide Number 49
                                                                                                                              • Slide Number 50
                                                                                                                              • Slide Number 51
                                                                                                                              • Rare Earth Elements
                                                                                                                              • Crustal Abundances of Elements
                                                                                                                              • Occurrence
                                                                                                                              • Rare Earth Minerals
                                                                                                                              • REE Minerals
                                                                                                                              • Bastnesite
                                                                                                                              • Other REE minerals
                                                                                                                              • Electron Configuration
                                                                                                                              • Electron Configuartion
                                                                                                                              • REE Behavior
                                                                                                                              • Ionic Radius
                                                                                                                              • Coordination Number
                                                                                                                              • Coordination Number
                                                                                                                              • Other Factors
                                                                                                                              • REEs and Economics
                                                                                                                              • HREEs and Magnetism
                                                                                                                              • Applications in Magnetism
                                                                                                                              • Applications in Magnetism
                                                                                                                              • HREEs and Nuclear Technology
                                                                                                                              • HREEs and Nuclear Technology
                                                                                                                              • Mountain Pass
                                                                                                                              • Bayan Obo
                                                                                                                              • World Production
                                                                                                                              • Exploration
                                                                                                                              • Environmental Considerations
                                                                                                                              • REE Fertilizer
                                                                                                                              • Investigation by T Liang et al
                                                                                                                              • Implications
                                                                                                                              • Acid Mine Drainage (AMD)
                                                                                                                              • Radioactive Elements
                                                                                                                              • Radioactive Hazards
                                                                                                                              • Summary
                                                                                                                              • References

                                                                                                                                top related