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School of Applied SciencesKalinga Institute of Industrial Technology
Deemed to be University
BhubaneswarAn Institute of Eminence
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Table of Contents of Abstracts on Chemistry
Sl. No. Title of the Paper Page No.1 One pot process for the synthesis of ketone from
carboxylic acid using TMSCl as an activating agent
By Habtamu Gelaw Mekonnen, Samaresh Jana*
8
2 Kinetics of the adsorption and photodegradation of crystal violetand methylene blue from wastewater using titanate nanotube
By Saismrutiranjan Mohanty1, Shuvendu Singha1, SanjibMoulick2, Sanjoy Kumar Maji1
9
3 Electrochemistry of some electrodeposited binary alloys on stainlesssteel cathode
By Santosh Ku. Nathsharma1, Sasmita Mishra2, K.G.Mishra3,R.K.Paramguru4
10
4 Electrochemical studies on electroless silver plating on polyurethanecatheter
By Sasmita Mishra, Santosh Kumar Nathsharma, KrushnaGopal Mishra, Raja Kishore Paramguru
11
5 A simple synthesis of ketone from carboxylic acid using tosylchloride as an activator
By Debasis Sahoo and Samaresh Jana*
12
6 N-Heterocyclic resorcin[4]arene cavitands: A versatile
Platform for different applications
By Manini Nayak, Anita Pati*
13
7 Synthesis and characterization of Tetrazole derivatives fromThiourea precursor
By Kanyanjali Samal, Manini Nayak, Anita Pati,*
14
8 A comparative adsorption of Congo Red and Trypan Blue dyes onmgo nanoparticles: Kinetics, Thermodynamics and Isotherm Studies
By Barsharani Priyadarshini, Tapas Ranjan Sahoo*
15
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9 Influence of Mg doping on zno nps for enhanced adsorption activityof Congo Red dye
By Pragyan Parimita Rath, Tapas Ranjan Sahoo*
16
10 Bio-Synthesis of cubic ceo2 nanoparticles: Its Adsorption &Biological applications
By Sthitiprajna Muduli, Tapas Ranjan Sahoo*
17
11 Synthesis of mno2 nanoparticles: its Adsorptive applicationsBy Tanaswini Patra, Tapas Ranjan Sahoo
18
12 Nanoceria: A rare-earth nanoparticle as a promising anti-cancertherapeutic agent in colon cancer
By Sirish R. Panda, Tapas Ranjan Sahoo*
20
13 Fabrication of thermoplastic poly urethane and polyanilineconductive blend with improved mechanical, thermal and excellentdielectric properties: effect of swcnt and temperature
By K. Dash, B.P. Sahoo*
21
14 Development of poly (vinylidene fluoride) and polyaniline blendwith high dielectric permittivity, excellent electromagnetic shieldingeffectiveness and ultra low optical energy band gap: effect of ionicliquid and temperatureBy D. Meher, Suman, N. Karna, B.P. Sahoo*
22
15 Influence of graphene oxide, temperature and ionic liquid ondielectric relaxation behavior of poly (vinyl alcohol) basednanocomposite
By Ganeswar Sahu, Bibhu Prasad Sahoo*, Jasaswini Tripathy⃰
23
16Synthesis and characterization of carboxymethyl
cellulose-alginate based hybrid nanocomposite films with
antibacterial applications
ByMamata Das and Jasaswini Tripathy⃰
24
17 Interactions of cetyltrimethylammonium bromide with1,3-dioxolane in water: a study of viscosity and volumetricproperties
By Dayananda Sarangi1, Rojalin Sahu1#, Braja B. Nanda2#
25
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18 An assessment of geochemical behaviour of groundwater of interiordistricts of odisha
ByMadhusmita Behera, Tapan Kumar Bastia, Rojalin Sahu
26
19 Hybrid composite laminates from upe/esoa blend reinforced withchitosan and bamboo fiber:A study of mechanical and thermal properties
By Priyabrata Mohanty,Dibakar Behera*, Shiv kumari Panda,Tapan Kumar Bastia and Prasant Rath
27
Table of Contents of Abstracts on Mathematics
Sl. No. Title of the Paper Page No.1 Approximate solution of fractional order lane-emden type differential
equation by orthonormal bernoulli’spolynomialsby Biswajit Mallick, Prakash Kumar Sahu.
29
2 On double difference operators and their applicationsby S. Samantaray, L. P. Nayak and P. Baliarsingh
30
3 Scattering And Propagation Of Seismic WavesIn Elastic Mediaby A.K.Patnaik and S.K.Samal
31
4 A new approach of symmetric duality in nonlinear programming problemsBy G. Biswal, N Behera, S. Padhan
32
5 Effect of suction/blowing on heat-absorbing unsteady radiative Cassonfluid crossed a flat porous plate with conjugate heating and inclinedmagnetic fieldbyMahato and M. Das
33
6 Solution of Lane-Emden type equation using Aboodh Transform basedHomotopy Perturbation Methodby Tesfaye T. Shone, A. Patra and B.B. Mishra
34
7 Computation of a fuzzy linear programming problem with fuzzy decisionvariableby Admasu Tadesse, Manoranjan Sahoo and Srikumar Acharya
35
8 Multi-Objective Probabilistic Fractional Programming Problem InvolvingThree Parameter Log-Normal Random Variableby Berhanu Belay and Srikumar Acharya
36
9 Compressional Wave In a Thermally Conducting Elastic Mediumby Nirakara Pradhan and Sapan Kumar Samal
37
10 Multi-Objective Linear Fractional Stochastic Transportation Problemby Adane Abebaw Gessesse, R. Mishra and and M. M. Acharya
38
11 Upper bound on Hankel determinant for bounded turning functionassociated with Salagean difference operatorby Avaya Naik and Trailokya Panigrahi
39
12 Cubic B-spline Approach for Approximate Solution of one dimensionalHeat equation
40
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by Guesh Simretab Gebremedhin and Saumya Ranjan Jena13 Approximate solution of Initial value problem by Differential
Transformation MethodbyMinakshi Mohanty, Saumya Ranjan Jena and Satya KumarMishra
41
14 Formulation of Fuzzy Random Multi-level Linear Programming Problemsby G.C. Sasmal, S. K. BariK and S. Acharya
42
15 A Study On Some Mathematical Models On Attack Of Malicious ObjectsIn a Computer Network And Their Defencesby Swapnita Mohanty and A.K. Paul
43
16 Progressive Compound Rules for Numerical Integration of AnalyticFunctionsby Pabitra Ojha and P.K. Mohanty
44
17 The Progressive Quadrature Rules for Approximate Evaluation of RealDefinite Integralsby B. N.Dash, P.K.Mohanty and M. Hotta
45
18 On Fourier Series And Its Applicationsby Anwesha Mishra
46
19 Bimodal Character of Cyclone Climatology in the Bay of BengalModulated by Monsoon Seasonal Cycleby Kanak Lata Xalxo
47
Table of Contents of Abstracts on Physics
Sl. No. Title of the Paper Page No.1 Colossal dielectric and relaxor nature of bi modified ccto
thin film
By b A. K. Mishra M.Devi, Manas R. Panigrahi
49
2 Heterogeneous photocatalysis application using zinc oxide (zno)semiconductor nanoparticles prepared from its laboratory gradepowder precursor
By Rajashree Sahoo, Susanta Kumar Das*
50
3 Improved dielectric behavior and electrical properties of
Ba0.5Sr05TiO3 ceramics by Sn doping
By M. Das Pattanayak1, L. Biswal2
51
4 Reflectance - Temperature characteristics ofAlGaN semiconductor at three communication windows
By Sakti Prasan Mohanty1, C. S. Mishra2, S. K. Sahoo1*and G.Palai2*
52
5 ByMuralidhar Swain 53
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6 Site dependent proton affinity and fluoride affinity calculation ontoxic TABUN molecule: A DFT and CCSD(T) study
By D. K. Mahapatra and N. C. Bera*
54
7 Structural, electrical, magnetic and optical studies of transition
metal poped BiFeO3 multiferroic Nanoparticles Prepared By Sol –
Gel Technique
By Atul Kr. Sinha, B. Bhushan
55
8 Biomass derived carbon materials for energy storage application
By Luna Jena
56
9 Silver nanostructures: plasmon tunability, growth kinetics, andcatalytic applications
By B. K. Dadhich1, B.Bhushan1,*, and A. Priyam2
57
10 Recent developments in the energy-storage and capacitorperformance of sodium bismuth titanate based ceramics
By A. Singha and Dr. S. Praharaj and Dr. D. Rout
58
11 Study of scanning velocity effect on texturization of titanium sheet
by femtosecond laser in air
By Atal Mundamajhi, S.K.Das,
59
12 Structural, morphological and dielectric properties of bamboo
charcoal
By Dhani Soren
60
13 Synthesis, Characterization and Stability Study of Perovskite(CH3NH3PbI3) for Solar Cell Applications
By Ipsita Mohanty1, S. Mangal1*, S. Jana1 and U.P. Singh2
61
14 Growth of micro and nanostructures on si surface using laserworkstation attachment for solar cell application
By P. Chandrakanta Singh, Susanta Kumar Das*
62
15 Preparing ZnO thin films from its powder precursor 63
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ByMaher Alrefaee, Susanta Kumar Das(a)
16 Preparation of activated carbon with low cost oven based heatingsystem
By Sinmay Sahoo and Susanta Kumar Das*
64
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Abstract
on
Chemistry
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One pot process for the synthesis of ketone from carboxylic acidusing TMSCl as an activating agent
Habtamu Gelaw Mekonnen, Samaresh Jana*
Department of Chemistry, School of applied sciences, Kalinga Institute of Industrialtechnology (KIIT)-Deemed to be universi
ty, Bhubaneswar, 751024, Odisha, India
Abstract
Simple one pot procedure for the conversion of carboxylic acid toketone is described. Various carboxylic acids were converted to thecorresponding ketones in excellent manner in presence of tetra methylsilyl chloride (TMSCl) and organolithium reagents (n-BuLi). Aromatic,heteroaromatic and aliphatic acids are converted to the correspondingketones smoothly under the conditions using n-butyl lithium. In theprocess of converting different carboxylic acids using DCC as activator,we observed the low isolated yield of the desired products as we face aproblem duringpurification of ketone from by product. Hence, we havedeveloped an alternative method to accomplish this transformation,where trimethylsilyl chloride has been used to activate the carboxylicacid. In this process, the by product trimethylsilanol has been removedfrom the ketone easily using usual workup process.
R OH
Oi) TMSCl, Base, THF
R R'
O
ii) R'-M, -20 0C
R = Alkyl, aryl, heteroaryl
Key Words: One- pot conversion, carboxylic acid, ketone, Tetra methyl silylchloride
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Kinetics of the adsorption and photodegradation of crystal violet and methyleneblue from wastewater using titanate nanotube
Saismrutiranjan Mohanty1, Shuvendu Singha1, Sanjib Moulick2, Sanjoy Kumar Maji1
1Department of Chemistry, School of Applied Sciences, KIIT Deemed to be University,Odisha, Bhubaneswar-751024, India,
2School of Civil Engineering, KIIT Deemed to be University, Odisha,Bhubaneswar-751024, India
Abstract
Titanate nanotubes (TNTs) were synthesized hydrothermally at 150-160oC andcharacterized by SEM/EDX and TEM. The synthesized TNTs were employed toremove crystal violet (CV) and methylene blue (MB) from synthetic wastewater.Experimental results suggested that 3 g/L dose of TNTs could efficiently remove~95% and ~98% of CV and MB respectively at initial concentrations of 20 g/L and 10g/L at a pH of 6.8±0.2 and at an stirring speed of 520±20 rpm. The exclusion of dyesfrom aqueous media followed two kinds of mechanisms i.e., adsorption in dark andphotodegradation in UV-light. The adsorption process of both the dyes followed thepseudo-second-order reaction model, whereas, for photodegradation it was arbitrary.The rate limiting step of the adsorption process was explained utilizing the diffusionmodel in terms of film diffusion and pore diffusion. The plausible photodegradationmechanism was proposed. Evaluated diffusion co-efficient values suggested that theadsorption process follows neither the pore diffusion nor the film diffusion model.The economy of the exhausted material was understood by turnover study and theresult suggested the gradual suppression of uptaking the solute on TNT surfaces.
Key words: TNT, CV, MB, Adsorption/photodegradation, kinetics, rate limiting step
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Electrochemistry of some electrodeposited binary alloys on stainless steelcathode
Santosh Ku. Nathsharma1, Sasmita Mishra2, K.G.Mishra3, R.K.Paramguru41, 2, 3-Department of Chemistry, School of Applied Sciences,4-School of MechanicalEngineering, Kalinga Institute of Industrial Technology, Deemed to be University,
BhubaneswarEmail: sknathsharma5388@gmail.com
Abstract
Electrodeposition of the bimetallic alloys is generally applied to a substrate surface inorder to produce a modified substrate system with enhanced mechanical, magnetic,optical or anticorrosive properties. Co-Cu and Fe-Co alloys, deposited on copper,platinum or silicon substrates, have been presenting great interest due to their possibleuse in data store systems and sensor technology. The above mentioned applicationsare based on the magneto resistance properties presented by these alloys, whichpromotes a great variation of electrical resistance in an external magnetic field.However, these properties can only be observed in a metastable solid solutioncontaining few amounts of cobalt in a copper or iron matrix, enhancing thesegregation of small Co precipitates, forming a granular alloy. Though there are somestudies on the magnetic properties of these alloys but there is still scope to improvethe magnetic properties. The present work therefore reveals the electrodeposition ofCo-Cu and Fe-Co magnetic bimetallic alloys on stainless steel electrode from sulfatebath of metals containing suitable additives at different parameters like pH,concentration, current density and temperature to understand their effect on thedeposited alloy in addition to its improve magnetic property. The electrochemicalkinetics of deposition has been studied by Cyclic Voltammetry. The cathodic currentefficiency and composition of Co-Cu and Fe-Co alloy deposits were studied indifferent parametric conditions. The structure of the deposited alloys wascharacterized by X-ray diffraction technique which confirms the formation of a singlesolid solution phase of the alloy system. The surface morphology and elementalanalysis of the deposits have been characterized by SEM and EDX. The magneticproperties have been assessed from the M-H hysteresis curves obtained from theVSM.
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Electrochemical studies on electroless silver plating on polyurethane catheter
Sasmita Mishra, Santosh Kumar Nathsharma, Krushna Gopal Mishra, Raja KishoreParamguru
Abstract
Among all other deposition techniques, the electroless deposition is considered as themost simple and cost effective autocatalytic process. Any kinds of non metallicsurface can be deposited with metals to improve the desired functional properties. Themetal ions are reduced by the electrons obtained from the oxidation of reducing agenton the catalytic surface in suitable aqueous solution. The present work revealselectroless deposition of nano size silver onto polyurethane catheter to improve itsantibacterial property. The size of deposit is regulated through control of silver metalions concentration and immersion time and also by monitoring the mixed current (im)from electrochemical deposition mechanism. A lower rate of deposition is achievedunder anodic diffusion control mechanism and is effected by lowering the [Ag+] andtime of deposition in the electroless plating bath. The size of the deposit is alsoreduced in the process. The size and morphology of the silver plated polyurethane hasbeen characterized by SEM and XRD. The thermodynamic expressions for Em (mixedpotential) and kinetic expressions for im (mixed current) are derived usingButler-Volmer equation and intersection point of superimposed partial cathodic andanodic partial polarization curves. The kinetic and mechanism of the silver depositionprocess is also investigated. The antibacterial behaviour of electroless depositednanosilver moiety on Polyurethane Catheter (PU) substrate on Pseudomonasaeruginosa was demonstrated using zone inhibition test in this study.
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A simple synthesis of ketone from carboxylic acid using tosyl chloride as anactivator
Debasis Sahoo and Samaresh Jana*
Department Of Chemistry, School of Applied Sciences, KIIT University,Bhubaneswar-751024, Odisha, India
Abstract
An effective process for the conversion of carboxylic acid to ketone has beendiscovered. In this process, carboxylic acid has been activated using p-toluenesulphonyl group. Under the optimized condition, aromatic, aliphatic heteroaromaticcarboxylic acids have been proved to be good substrates for this methodology. Theby-product of this reaction can be removed very easily during work up process. Also,one equivalent of organometallic reagent is sufficient to complete this transformation.The key advantage of this process is the ketone has been accessed from acid using oneequivalent of organometallic reagent.
Figure 1: Scheme for ketone synthesis
Reference-Sahoo, D.;Sarkar, S.; Jana, S, Tetrahedron letters 2019,60,151084.
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N-Heterocyclic resorcin[4]arene cavitands: A versatile
Platform for different applications
Manini Nayak, Anita Pati*
Department of Chemistry, School of Applied Sciences, KIIT Deemed to be University,Bhubaneswar-751024, Odisha
Abstract
Calix resorcin[4]arene cavitands have been recognized as a highly versatile class ofcompounds since their first appearance in the chemistry around thirty years ago.These cavitands have a bowl-shaped aromatic cavity of molecular dimensions, whichcan be decorated at the upper and lower rims with a variety of functional groups,heterocyclic systems etc. They are efficient molecular receptors for host-guestinteraction, pH sensing, chemical sensing, catalysis, molecular recognition as well astunable building blocks in the formation of covalent and metallo-supramolecularcages. Thus in view of the wide spread applications of Calix resorcin[4]arenecavitands, the present work is based on the synthesis, characterization of pyridine andtriazole based resorcin[4]arene cavitands and their versatile application in the field ofcatalysis, pH sensor, metallo-supramolecular cage formation etc.
Key Words: Calix resorcin [4] arene, Cavitand
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Synthesis and characterization of Tetrazole derivatives from Thiourea precursor
Kanyanjali Samal, Manini Nayak, Anita Pati,*
Email: anitapatifch@kiit.ac.inDepartment of Chemistry, School of Applied Sciences, KIIT Deemed to be University,
Bhubaneswar-751024, Odisha
Abstract
Tetrazoles are essential structural motif in many compounds that are widely used inthe field of medicine, biochemistry, pharmacology, and materials. The first tetrazolesynthesis was reported in 1885. Various methods of synthesis of tetrazole and itsderivatives are already reported in the literature. However in the present work ourmain focus is to use the solvent-free green approach to synthesize tetrazole derivativesusing thiourea precursor. Both symmetrical and unsymmetrical thiourea was used asthe synthetic precursor for the synthesis of tetrazole derivatives. Copper (I) andCs2CO3 are used as catalyst for the condensation reaction. This type of protocol givesaccess to amino-substituted tetrazole and triazoles via oxidative desulfurization oftheir respective procedures followed by intra and intermolecular attack of suitablenucleophiles. Characterization of the synthesized molecule has been done by using IRand NMR spectroscopy. Further confirmation of the molecule using Mass data andSingle-crystal XRD is under progress.
R2
NH
NH
R1
SCUSO4.5H2O/Cs2CO3 N N
R2C
R1
NaN3
R2R1
NH
NN
NN
Keywords: Thiourea, Tetrazole, solvent-free green method
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A comparative adsorption of Congo Red and Trypan Blue dyes on mgonanoparticles: Kinetics, Thermodynamics and Isotherm Studies
Barsharani Priyadarshini, Tapas Ranjan Sahoo*
Department of Chemistry, School of Applied Sciences, KIIT deemed to be University,Bhubaneswar 24, Odisha, India
*Corresponding author E-mail: trsahoofch@kiit.ac.in
Abstract
The current research study focuses on synthesis of MgO nanoparticles by microwave-assistedcombustion method and the removal of Congo Red (CR) and Trypan blue(TB) dyes from aqueoussolution. The crystallite size of the MgO nanoparticles was calculated to be 18nm from X-Raydiffraction pattern. The sample was further characterized by FTIR, TGA and SEM techniques.Theeffect of operating parameters were on adsorption process like MgO dosage, dye concentration,solution pH, agitation speed and temperature in were examined through batch experiments. It wasfound that, 0.2g of MgO NPs showed maximum removal efficiency of both the dyes (more than 98%),for 25ppm of dye concentration at an acidic pH(3-4). Thermodynamic parameters such as ΔG0, ΔH0
and ΔS0were calculated and the negative values of ΔH0 (-0.028 kJmol-1 for CR and -0.158 kJmol-1forTB) corresponds to an exothermic nature of the adsorption process and the positive values of ΔS0
(0.051 and 0.058 Jmol-1K-1 for CR and TB respectively) show increased randomness of the dye andadsorbent.The study of isotherm models revealed that the Freundlich model better fits to theexperimental equilibrium data than the Langmuir model suggesting heterogeneous surface of thenanoparticles. In addition, adsorption kinetic data followed a pseudo-second-order rate for both thedyes.
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Influence of Mg doping on zno nps for enhanced adsorption activity of CongoRed dye
Pragyan Parimita Rath, Tapas Ranjan Sahoo*
Department of Chemistry, School of Applied Sciences, KIIT deemed to be University,Bhubaneswar 24, Odisha, India
*Corresponding author E-mail: trsahoofch@kiit.ac.in
Abstract
A facile microwave-assisted combustion method was adopted to synthesize pure ZnO and Mg-dopedZnO nanoparticles (NPs), and characterization of the NPs and the sorption behavior with Congo Red(CR) Azo dye was extensively investigated. The structure, morphology and chemical assay of thesynthesized NPs were studied with respect to the pure and 2% Mg-doped ZnO samples. The X-raydiffraction pattern confirmed the presence of crystalline, cubic phase with fluorite structure of both theNPs. The morphological differences between the pure and Mg-doped ZnO NPs were evaluated byFE-SEM, which revealed that the NPs were in the nanoscale regime with irregular crystallinemorphology having a grain size of ~18–45 nm. N2 adsorption/desorption isotherms measured at−196 °C suggested a Type II structure with limited hysteresis loops, likely due to some interparticleporosity. The BET SSA ZnO NPs obtained was found to be 32m2 g−1, indicating about its potential insorption processes. Batch adsorption study for the removal of CR carried out showed that, theMg-doped NPs showed higher loading efficiency (125 mg・g−1) than the ZnO NPs (25 mg・g−1)counterpart. This was corroborated by the isotherm results in which the CR dye sorption followed aFreundlich Isotherm model for both un doped ZnO and Mg-doped ZnO NPs. The sorption of CR dyefollowed a pseudo-second order kinetics. The negative ΔG° (−31.91 and −109.41 kJ mol−1) showedthe feasibility of the adsorption process. The ΔH° was determined as +13.74 kJ mol−1 and 50.7 kJmol−1 for ZnO NPs and Mg doped-ZnO NPs respectively, confirming the endothermic nature of theadsorption for removing CR dye from the solution.
Publication:1. P.P. Rath, S.S. Behera, B. Priyadarshinia, S.R. Panda, D. Mandal, T. Sahoo, S. Mishra, Tapas R.Sahoo*, P.K. Parhi, Applied Surface Science (IF:5.155), 491 (2019) 256-266.
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Bio-Synthesis of cubic ceo2 nanoparticles: Its Adsorption & Biologicalapplications
Sthitiprajna Muduli, Tapas Ranjan Sahoo*
Department of Chemistry, School of Applied Sciences, KIIT deemed to be University,Bhubaneswar 24, Odisha, India
*Corresponding author E-mail: trsahoofch@kiit.ac.in
Abstract
With passage of time, environmental pollution due to the contaminating industrialeffluents has become a global concern. Effluents from the textile and dye industriesinclude coloured dyes having a large amount of suspended organic solids. Again, thesubstantial influence of nanostructures are also growing day by day. Considering that,the rare earth metal oxide, CeO2 nanoparticles have been used for the elimination ofthe toxic azo dyes. A facile green synthesis method was adopted to synthesize pureCeO2 nanoparticles (NPs) and characterization of the NPs and the sorption behaviourwith Reactive Blue (RB) Azo dye was extensively investigated. The X-ray diffractionpattern confirmed the presence of crystalline, cubic phase with fluorite structure of theNPs. The morphological analysis of the pure CeO2 NPs were evaluated by SEM,which revealed that the NPs were in the Nano scale regime with irregular grain size.Batch adsorption study for the removal of Reactive Blue (RB) carried out whichshowed that the CeO2 NPs showed a very high loading efficiency and a removalefficiency of 98%. This was corroborated by the isotherm results in which the RB dyesorption followed a Freundlich Isotherm model for CeO2 NPs. The sorption of RB dyefollowed a pseudo-second order kinetics. The adsorption capacity at differentequilibrium concentrations of the dye solution directed establishment of monolayerand chemisorption occurrences. The antimicrobial studies & it revealed that themaximum zone of inhibition was observed against gram (+ve) positive bacteria athigher concentrations of CeO2 NPs.
References[1] Makarov, V. V., Love, A. J., Sinitsyna, O. V., Makarova, S. S., Yaminsky, I. V., Taliansky, M. E.,&Kalinina, N. O. (2014). ActaNaturae (англоязычнаяверсия), 6(1 (20)).
[2] Sharma, J. K., Srivastava, P., Ameen, S., Akhtar, M. S., Sengupta, S. K., & Singh, G. (2017).Materials Research Bulletin, 91, 98-107.
[3]Surendra, T. V., &Roopan, S. M. (2016). Journal of Photochemistry and Photobiology B:Biology, 161, 122-128.
[4]Maensiri, S., Masingboon, C., Laokul, P., Jareonboon, W., Promarak, V., Anderson, P. L.,&Seraphin, S. (2007). Crystal growth & design, 7(5), 950-955.
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Synthesis of mno2 nanoparticles: its Adsorptive applicationsTanaswini Patra, Tapas Ranjan Sahoo
School of Applied Sciences, KIIT Deemed to be University,Bhubaneswar-24, India
AbstractIn consequence of time, the growing demand of population and high industrializationproduces excessive amount of organic contaminations from various sources.Particularly the organic dyes are generally treated as a noxious pollutant in variousfields because they are toxic, mutagenic or carcinogenic in nature. Thereby, itscontamination with the fresh water bodies of environment not only become seriousthreat to the aquatic life but also to the human lives or living organisms. So, theirconcentration needs to be reduced before their discharge into water bodies. In recentyears various techniques or methods are being practiced by the researchers forremoval of dye from industrial effluents including photo catalytic degradation,sonochemical degradation, ozone treatment, micellar enhanced ultra-filtration, ionexchange membranes, electrochemical degradation, integrated chemical–biologicaldegradation, integrated iron (III) photo assisted biological treatment, solarphoto-Fenton and biological processes and Fenton-biological treatment, coagulationand also adsorption. Adsorption is one of the most attracting technologies. Theadsorption process is eco-friendly and the availability of a wide range of adsorbents ishigh. Transition metal oxide nanoparticles as advanced environment and energymaterials require very well adsorption performance to apply in practice. Metal oxidenanoparticles has been attracting a research interest owing to its outstanding physicaland chemical properties for which it was used in various fields like gas sensors,chemical sensors, biosensors, superconductors, photo catalyst, optoelectronic devices,cosmetics etc. Herein, we report for the first time the development of an economicaland sustainable nano manganese metal oxide by sol gel method at 400°C usingAcaciaconcina as a reducing agent and manganese nitrate as fuel. The synthesizedmetal oxides NPs are characterized by different characterizations techniques. Thestructural characterization of the MnO2 are carried out by X-ray powder diffractionspectra which shows that the NPs are crystalline in nature with a crystallite size ofaround 32 nm. The surface morphologies and size of the MnO2 are determined bySEM and TEM images. From the results it shows that the oxides are seems like ofporous coral reefs as found in sea. The photophysical properties of the metal oxidesare carried out using UV-Visible diffused reflectance spectra. The functional groupand bonding between the metal to oxygen has been analyzed using the FT-IR spectra.The influence of reaction temperature was also studied while synthesis to obtaincontrolled particle sized NPs. On increasing the reaction temperature to 900°C Mn3O4
NPs were synthesized which were confirmed by doing the above-mentionedcharacterizations. The successfully synthesized NPs have been applied as anadsorbent material for the adsorption of organic dyes like reactive blue. At the time ofadsorption, the different parameters were varied and their kinetics, isotherms andthermodynamic were also studied are calculated. From the above out comes we have
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concluded that the synthesized metal oxide nano particles are useful of the adsorptionof organic dye from aqueous medium as well as these are applicable in the removal oforganic pollutants from the industrial effluents.
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Nanoceria: A rare-earth nanoparticle as a promising anti-cancer therapeuticagent in colon cancer
Sirish R. Panda, Tapas Ranjan Sahoo*
Department of Chemistry, School of Applied Sciences, KIIT Deemed to be University,Bhubaneswar, 751024, Odisha, India
*Corresponding author E-mail: trsahoofch@kiit.ac.in
Abstract
The bioactivity and physical characteristics of CeO2 nanoparticles are dependent to agreat extent on the type of the particle, particle size and defects. Herein, pure CeO2
nanoparticles (NPs) was prepared by using a facile and cost effectivemicrowave-assisted combustion synthesis (MACS). The samples were thoroughlycharacterized by various techniques and tested as anti-cancer therapeutic agent incolon cancer. The structural investigations (X-ray Powder Diffraction) revealed theformation of single phase cubic fluorite-type structure of CeO2 with Fm-3m spacegroup. Morphological analysis (FESEM), demonstrated the aggregation of irregularnanoparticles with grain size ~20-40nm. To have more knowledge on the samplemorphology, TEM and HRTEM images were taken.TEM image showed ceria NPswith squared shape and particle size in 50-95nm range. Furthermore, HR-TEMmicrographs confirmed the crystallinity of the CeO2 sample, which was explored bycalculating the distance between the fringes in the corresponding Fourier transformedimage. The BET specific surface area (SSA) of as synthesized ceria nanoparticles,was observe to be 25m2/g. UV- Vis spectral analysis reveals that the direct band gapof CeO2 nanoparticles is about 2.8eV. It was interesting to observe that, the asprepared NPs exhibit remarkable differential cytotoxicity towards healthy (BHK 121,Baby Hamster Kidney cells) and human colon cancer cells (HCT116). Nuclearfragmentation assay indicated clear DNA fragmentation in HCT116 cells, whereasintact nucleus was observed in normal cells, suggesting ceria induced apoptotic celldeath in colon cancer cells. In sum, MACS generated ceria nanoparticles coulduncover a new approach in cancer therapy.References[1] A.Y. Chow, Nat. Educ. 3 (2010) 7–12.[2] G.S. Dite, A.S. Whittemore, J.A. Knight, E.M. John, R.L. Milne, I.L. Andrulis,M.S. Southey, M. Mre, G.G. Giles, A. Miron, A.L. Phipps, D.W. West, J.L. Hopper,Br. J. Canc. 103 (2010) 1103–1108.[3] R.A. Smith, V. Cokkinides, D. Brooks, D. Saslow, O.W. Brawley, CA cancer, J.Clin.60 (2010) 99–119.[4] T.G. Cotter, Nat. Rev. Cancer 9 (7) (2009) 501–507 (2009).[5] K. Bardhan, K. Liu, Cancers 5 (2013) 676–713.[6] X. Gao, J. Tyson McDonald, M. Naidu, P. Hahnfeldt, L. Hlatky, Stem Cell. Int.2014(2014) 1–8.
21 | P a g e
Fabrication of thermoplastic poly urethane and polyaniline conductive blendwith improved mechanical, thermal and excellent dielectric properties: effect of
swcnt and temperatureK. Dash, B.P. Sahoo*
School of Applied Sciences (Chemistry)KIIT Deemed to University*bibhuprasadfch@kiit.ac.in
Abstract
A novel multifunctional nanocomposites based on thermoplastic polyurethane (TPU),emerladine salt form of conductive Polyaniline (PANI) and single wall carbonnanotubes (SWCNT) with very high mechanical, thermal and excellent dielectricproperties has been fabricated successfully using solvent casting technique. Thedispersion pattern of nano wire form of conductive PANI and SWCNT in the TPUmatrix is observed from the field emission scanning electron microscope (FESEM) andthe interconnectivity between the PANI nanowire as well as the SWCNT in theinterface is clearly visualized in FESEM photomicrographs. The interfacial interactionbetween the constituents in terms of hydrogen bonding has been confirmed from theFTIR and Raman spectra. The enhancement in tensile strength at 10 weight percentage(wt%) PANI loading explores the reinforcing nature of PANI on TPU matrix. However,at higher loading level of PANI, the tensile strength deteriorates because of theimmiscibility. The increase in thermal stability of the TPU/PANI blend in comparisonto PANI again confirms the establishment of chemical linkages in the interface. Theeffect of PANI loading and temperature on the dielectric relaxation behavior has beenexplored in a wide range of frequency (1-106 Hz). The easiness in the polarization ofthe dipoles in the emerladine salt moiety of PANI and electronic polarization inSWCNT has been confirmed from the improved value of dielectric permittivity (εʹ). Theconductive channels formed by the PANI and SWCNT phases facilitate the tunnelingand hopping mode of conduction which is reflected in the form of improved ACconductivity (σac) and reduction in impedance (Zʹ and Zʹʹ) value. The substantialimprovement in εʹ and σac of TPU/PANI/SWCNT nanocomposites at ultra low loadinglevel of SWCNT (0.5wt%) in comparison to unfilled TPU/PANI blend is theuniqueness of this study. The effect of temperature on εʹ and σac ensures the negativetemperature coefficient (NTC) behavior of resistance of both the TPU/PANI blend aswell as the TPU/PANI/SWCNT blend nanocomposites.
22 | P a g e
Development of poly (vinylidene fluoride) and polyaniline blend with highdielectric permittivity, excellent electromagnetic shielding effectiveness and ultra
low optical energy band gap: effect of ionic liquid and temperature
D. Meher, Suman, N. Karna, B.P. Sahoo*School of Applied Sciences (Chemistry)
KIIT Deemed to University*bibhuprasadfch@kiit.ac.in
Abstract
Electrically conductive polymer blends have attracted profound attention as dielectricmaterials. However, achieving isotropic behavior, electrical stability and low currentleakage is still challenging. Here we have synthesized a conductive polymer blend ofPolyaniline (PANI) and Poly (vinylidene fluoride) (PVDF) exhibiting relatively highdielectric permittivity (εʹ) together with low band gap. Ionic liquid (IL) has beenincorporated and the effect of IL in the dielectric properties are explored. Theinterfacial adhesion, morphology and the dielectric polarization of the blends areinvestigated. The electromagnetic shielding effectiveness (EMISE) of the conductiveblends is studied in X-band frequency range. The electrical stability and decrease incurrent loss of the blends has been analyzed through I–V characteristics. The findingsreveal that with increase in PANI loading in the temperature range of 25–100 °C andIL incorporation results in excellent dielectric properties for charge storageapplications. The high efficiency of absorption and low transmission ofelectromagnetic radiation by the conductive blends is the main reason for excellentEMISE possessed by the systems which can be used for shielding applications inelectronics. The increase in electrical stability and decrease in current leakage abilityappear in the form of narrow band gap.
23 | P a g e
Influence of graphene oxide, temperature and ionic liquid ondielectric relaxation behavior of poly (vinyl alcohol) basednanocomposite
Ganeswar Sahu, Bibhu Prasad Sahoo*, Jasaswini Tripathy⃰ , School of AppliedSciences, KIIT Deemed to be University, Bhubaneswar-751024, Odisha, India.bibhuprasadfch@kiit.ac.in jtripathyfch@kiit.ac.in
Abstract
Electrically conductive polymer nanocomposites with high dielectric properties have
generated tremendous momentum throughout the world due to their versatile
dielectric applications in research and industrial developments. PVA-GO polymer
nanocomposites were fabricated by solvent casting technique. The effect of variation
in GO loading and temperature on the dielectric relaxation behavior of PVA-GO
polymer nanocomposites with and without 1-Allyl-3-methyl imidazolium chloride
(AMIC) has been studied. The microstructure morphology of the nanocomposites
films have been explored using scanning electron microscopy (SEM). Uniform
dispersion of GO in the nanocomposites is achieved in presence of ionic liquid, which
is confirmed by the high resolution transmission electron microscopic (HRTEM)
microphotographs. The dielectric relaxation characteristics such as permittivity (εʹ),
real and imaginary impedance (Zʹ and Zʹʹ), AC conductivity (σac) of virgin PVA as
well as the PVA-GO nanocomposites have been investigated in the frequency range
of 1Hz - 106 Hz at different filler loading over a wide range of temperatures (25 -
150 °C) for the PVA-GO polymer nanocomposites with and without AMIC ionic
liquid. The εʹ and σac significantly increased with increase in highly polarizable GO
loading and temperature while the impedance decreased. The dielectric properties of
the polymer nanocomposites also enhanced due to the incorporation of the ionic liquid.
The variation of ε′ with filler loading has been explained based on the interfacial
polarization of the GO within a heterogeneous system. The increase in σac and the
decrease in impedance with the incorporation of GO explains the formation of
crosslinked and closely spaced conductive networks in the PVA matrix and due to the
relaxation dynamics of polymer chains at the polymer- filler interface. The Nyquist
plot showing significant decrease in the area under the semicircle with increase in GO
loading level and temperature confirmed the increase in charge storing ability of the
developed polymer nanocomposites.
24 | P a g e
Synthesis and characterization of carboxymethyl cellulose-alginate based
hybrid nanocomposite films with antibacterial applications
Mamata Das and Jasaswini Tripathy⃰
Department of Chemistry,School of Applied Sciences,
KIIT Deemed to be University, Bhubaneswar-751024, Odisha, Indiajtripathyfch@kiit.ac.inContact No-9777322066
Abstract
Polymeric nanocomposites have been extensively used in food industry, packaging,
biomedical applications, protective films. Embedding metal nanoparticles and
graphene based nanofillers into the polymer matrices enhances the functions of these
functional materials in an effective way. Carboxymethyl
cellulose/Alginate/Graphene oxide/Ag nanoparticles based hybrid nanocomposite
films have been prepared by solvent casting method. The silver nanoparticles have
been prepared via the in situ reduction of silver nitrate salt in the polymeric solution
where the polymeric solution acts as the stabilizing agent. The polymeric
nanocomposite was characterized by FTIR Spectroscopy, XRD, SEM, TEM and
TGA-Analysis. The formation silver nanoparticles have been confirmed by UV-Vis
spectroscopy. Further the formation of silver nanoparticles is evident from the XRD
patterns of polymer nanocomposites. The presence of graphene oxide has been
confirmed from the corresponding peaks observed in the FTIR-spectra analysis as
well as thermogravimetric analysis of the polymer nanocomposites. The films
showed very good antibacterial activity on Escherichia coli.
25 | P a g e
Interactions of cetyltrimethylammonium bromide with 1,3-dioxolane in water: astudy of viscosity and volumetric properties
Dayananda Sarangi1, Rojalin Sahu1#, Braja B. Nanda2#
1Department of Chemistry, KIIT University, Bhubaneswar- 751024, Odisha,
India2P.G. Department of Chemistry, Vikram Deb Autonomous College,
Jeypore-764001, Odisha, India
Corresponding authors’ Email: bbnanda.driems@gmail.com,
rojalinsahu.chem@gmail.com
Abstract
Densities and viscosities of ternary mixtures containing cetyltrimethyl ammoniumbromide (CTAB) in aqueous solution of 1,3-dioxolane have been measured at 5 Kintervals from 298.15 to 313.15 K and at atmospheric pressure. The volumetricproperties of CTAB in water as well as in an organic solvent like 1,3-dioxolane havebeen investigated. Apparent molar volume (Vφ) and viscosity of CTAB weredetermined at T = (298.15-313.15) K and used to estimate standard partial molarvolume (Vφ0 ), standard partial molar isobaric expansivity (Eφ0 ), Helper′s constant((∂2Vφ0 / ∂T2)p).The experimental results of viscosity and density have been analyzedby using Jones-Dole equation and Masson equation. Further the values of constants Aand B of Jones-Dole equation were estimated. The values of constants A and B ofJones-Dole equation have been interpreted in terms of solute-solute and solute-solventinteractions. The standard partial molar volume,Vφ0 at infinite dilution weredetermined from Masson equations. The structure making/breaking capacity of soluteis interpreted with the help of Helper equation. From these values, we can estimate thestructure making or structure breaking nature of the molecule in a given solution. Thepositive value of Helper′s constant (∂2Vφ0 /∂T2)p and the negative value of dB/dTshows that CTAB in studied organic solvent predominantly acts as a structure-maker.
Keywords: 1,3-Dioxolane, Cetyltrimethylammonium bromide, Ion-solventinteractions, Jones-Dole equation
26 | P a g e
An assessment of geochemical behaviour of groundwater of interior districts ofodisha
Madhusmita Behera, Tapan Kumar Bastia, Rojalin Sahu
Department of Chemistry, KIIT University, Bhubaneswar- 751024, Odisha,
India
Abstract
The study possesses an objective to assess the groundwater quality, human healthhazards, possible mitigations and remedies in the interior districts of Odisha with aspecific study area at Gajapati and Rayagada, in these two southern tribal districtsgroundwater is the only source of drinking water. Total 200 numbers of samplesincluding both pre and post-monsoon periods were collected from the study area andanalysed in the laboratory. Tests of water quality parameters like pH, TDS, DO, EC,ORP, alkalinity, salinity, hardness, ammonia, TN and TP; significant anions like NO3-,NO2-,SO42-, PO43-, SiO33-, Cl- and F-; some selective dissolved metals like Na, K, Ca,Mg, Fe, Mn, Co, Ni, Cu, Zn, Cd, Cr and Pb have been done. Focus was given onfluoride concentration and its test was carried out by SPANDʼs method. Theconcentration of fluoride in groundwater of this region varied in the range of 0.0 to1.9 mg/L. About 30% of the samples possessed high concentration of fluoride i.e.above 1.5mg/L. Factors like weathering of rocks and evaporation of groundwater areresponsible for high concentration of fluoride in these areas. The post monsoon datasampling and analysis are over. Two papers have been communicated on the findingsof pre monsoon period. Another paper is in the process of drafting. After theacceptance of the papers the thesis work will be done.
27 | P a g e
Hybrid composite laminates from upe/esoa blend reinforced with chitosan andbamboo fiber:
A study of mechanical and thermal properties
Priyabrata Mohanty,Dibakar Behera*, Shiv kumari Panda, Tapan Kumar Bastia andPrasant Rath
School of Applied Sciences (Chemistry),KIIT University, Bhubaneswar, Odisha, India
Abstract
The development of an inter-cross-linked polymer network of thermoset-thermosetblends have been extensively studied due to their enhanced mechanical properties.Among various polymer blends, modifications of unsaturated poly ester (UPE) resinwith epoxidized soybean oil acrylate (ESOA) combinations are an attractive route topromote the performance of the thermoset matrix and to overcome the inferiorproperties of both the components. Biodegradable and effectively accessible chitosanbiodegradable waste material can shape the new stage for cutting-edge innovationitems. Blend of both recyclable fibrous reinforcement and eco-friendly filler with twomiscible thermosetting polymers will provide enhanced properties. At this time, weutilize chitosan up to 15wt% (based on matrix weight) as reinforcing filler. At last, aninteresting result was built up by confirming that chitosan filled chemically tailoredbamboo and UPE/ESOA (80:20) biocomposites offered enhanced properties by10wt% of the filler concentration with the most enhancements in wholeproperties.They have extensive variety of applications in the sector of low costhousing and structural projects, structural laminates.
Keywords: UPE -ESOA blend; Mechanical properties; Dynamic mechanical analysis;thermal stability.
*Author for Correspondence: E-mail -dibakar.beherafch@kiit.ac.in, Tel: +91-9238591455
28 | P a g e
Abstract
on
Mathematics
29 | P a g e
Approximate solution of fractional order lane-emden typedifferential equation by orthonormal bernoulli’s polynomials
Biswajit Mallick and Prakash Kumar SahuDepartment of Mathematics
Abstract
An approximate method based on orthonormal Bernoulli’s polynomials together with
their operational matrices is applied for solving fractional order differential equations
of Lane-Emden type. The preliminaries of fractional calculus are first presented.
Operational matrices of fractional derivative and integer order derivative are
constructed in this article. Convergence analysis of orthonormal Bernoulli’s
polynomials is proposed here. By using this method, the fractional Lane-Emden
differential equation converted into a system of algebraic equations by applying some
suitable collocation points and this system can be simplified by an appropriate
numerical method. Examples are illustrated to show the validity and applicability of
the present method.
Keywords: Bernoulli’s Polynomials, Orthonormal, Fractional Calculus, Lane-Emden
Equations.
30 | P a g e
On double difference operators and their applicationsS. Samantaray, L. P. Nayak and P. Baliarsingh
Department of Mathematics
Abstract
The prime objective of this work is to define a new double difference operator with
arbitraryorder via which new classes of difference double sequences spaces are
introduced. Results ontopological structures, dual spaces and four-dimensional matrix
mappings related to the proposeddifference double sequence spaces are discussed and
it is observed that the obtained results areunified and more generalized one which can
easily accumulate in both classical and fractionalcases. Also, we have used the idea to
approximate the fractional ordinary and partial derivativesof certain functions.
Key words: Sequence Spaces, Double sequence Spaces, Difference double sequence
Spaces
31 | P a g e
Scattering and propagation of seismic wavesIn elastic media
A.K. Patnaik and S. K. SamalDepartment of Mathematics
Abstract
Study of propagation and scattering of seismic waves through various layers of earth
has, always, been stirring enormous curiosity among researchers to enrich more
insight into earth’s interior construct, explore the existence of mineral reserves lying
underneath and to know the cause and devastation of earth quake. Considering its
relevance and applications, we study the phenomena of diffraction and reflection of
scalar impulsive SH waves generated from an impulsive point source by spherical
cavity embedded in an inhomogeneous medium. Furthermore, we study love type
surface wave propagation in curved layers lying over a curved homogeneous isotropic
half space and in an initially stressed fibre reinforced medium lying over a monoclinic
half space. These problems are analytically formulated into differential equations of
wave motion. The solutions of displacement field of diffraction and reflection are
obtained by taking Laplace and Legendre transforms, using boundary conditions as
required by physical nature of the problems and evaluating the contour integrals
resulted by Legendre inversion by residue and steepest descent methods
asymptotically. These yield diffraction and reflection events in shadow and
illuminated zones respectively. WKB and variable separable methods and required
transformations are used to solve wave equations of love type surface waves. The
numerical results of the solutions are illustrated graphically. Indeed, it is found the
influence of inhomogeneity factor of the medium on the displacement solutions of
diffracted and reflected SH-waves, effect of radii of curvature of curved layers love
type surface waves, initial stress of fibre reinforced medium and anisotropic
parameter of monoclinic half space on the phase velocity of Love waves.
Keywords: Diffraction, Reflection, Love type surface waves, curved layer,
monoclinic medium.
32 | P a g e
A new approach of symmetric dualityin nonlinear programming problems
G. Biswal, N Behera, S. PadhanDepartment of Mathematics
Abstract
In the frame work, a pair of Mond-Weir type third order symmetric nonlinear
programming problems is introduced. Appropriate duality theorems are established
for the newly formulated third order symmetric dual problems under the assumptions
of third order boncavity and bonvexity. The proposed works deals with suitable
numerical examples. The outcomes are generalization of some of the previously
existing outcomes.
Keywords: Third order symmetric dual; Mond-Weir type dual; Bonvexity;
Boncavity; Duality results.
33 | P a g e
Effect of suction/blowing on heat-absorbing unsteady radiativeCasson fluid crossed a flat porous plate with conjugate heatingand inclined magnetic field
R. Mahato and M. DasDepartment of Mathematics
Abstract
This article studies the effect of suction / blowing, inclined magnetic field, and
chemical reaction on heat- absorbing unsteady radiative Casson fluid crossed a flat
porous plate in porous medium. Further, the mass and heat transfer analysis are
examined under the influence of conjugate mass and heat transfer phenomena at the
boundary. The governing equations of the model viz. the energy, mass transfer, and
momentum are transformed into the non-dimensional form adopting suitable
non-dimensional variables and parameters. The exact analytic solutions of the model
for fluid temperature and concentration are obtained using Laplace transform
technique whilst, the solution for the fluid velocity has been obtained analytically by
using the Laplace transform technique and then inverted numerically with the help of
the INVLAP routine of MATLAB. The expressions for fluid velocity, temperature,
and concentration are obtained and discussed graphically for various physical
parameters influencing the fluid flow model taking into account the case of both
suction and blowing. Further, the solution when the Casson fluid parameter
is also obtained as special cases. Results for the skin friction coefficient,
Sherwood number, and Nusselt number are numerically computed and presented
them in tabular form. An increment for the inclination angle of the magnetic field
enhances the fluid velocity while it has a reverse effect on Skin friction. Increasing
the Schmidt number Sc leads to a reduction in fluid concentration and increasing the
value of thermal radiation accelerates fluid temperature. This fluid flow model has
several industrial applications in the field of chemical, polymer, and medical
sciences, etc.
Keywords: Suction, Blowing, Porous medium, Casson fluid, Conjugate heat and
mass transfer, inclined magnetic field, Thermal radiation.
34 | P a g e
Solution of lane-emden type equation using aboodh transform basedhomotopy perturbation method
Tesfaye T. Shone, A. Patra and B.B. MishraDepartment of Mathematics
Abstract
Lane-emden equation arises from model in the area of mathematical physicas and
astrophysics. By using Aboodh transform Lane-emden type equatio is transformed
into a first order differential equation and for the nonlinear parts perturbation
techniques is used. The result shows the method used is simple to use and powerful
tool.
35 | P a g e
Computation of a fuzzy linear programming problem
with fuzzy decision variable
Admasu Tadesse, Manoranjan Sahoo and Srikumar AcharyaDepartment of Mathematics
Abstract
A realistic assumption of parameters and decision variables in the existing world is
not precise; we consider both unrestricted coefficients and non-negative decision
variables as a triangular fuzzy number to solve a fuzzy linear programming problem
with fuzzy decision variable. In proposed problem we consider a maximization of
fuzzy linear programming problem with equality constraints. To maximize the
objective function we minimize left spread, maximize the core value and the right
spread value. Fuzzy equality constraints can’t be used directly to solve the proposed
mathematical model. The fuzzy equality is defuzzied and after defuzzification a risk
side which is represented in left hand side of constraints is compared with risk side of
right hand side defuzzification value. We equate the core and right spread values of
each left hand side constraints with the corresponding values of right hand side source
constraints respectively. Similarly we have optimized the objective function by
considering the spreadness of the triangular fuzzy parameter i.e. in a maximized
objective function, risk of obtaining a profit is minimized, core of the objective
function is maximized and finally the possibility of obtaining high profit is also
maximized. This results a multi objective linear programming problem. The resultant
crisp linear programming problem is solved using sequential goal programming
approach. Numerical example is given to illustrate the proposed method.
Keywords: Fuzzy Linear programming; Fuzzy Variable; Triangular Fuzzy Number
36 | P a g e
Multi-objective probabilistic fractional programming problem
involving three parameter log-normal random variable
Berhanu Belay and Srikumar AcharyaDepartment of Mathematics
Abstract
A method for solving multi-objective probabilistic fractional programming problem is
proposed. The uncertain parameters are random variables that follow three parameters
log-normal distribution. Since the proposed mathematical model is probabilistic, it is
difficult to solve directly. The problem is solved in two steps. In the first step
multi-objective probabilistic fractional programming problem is changed to
equivalent multi-objective fractional programming problem. In the second step
sequential goal programming approach is applied to solve the resulting
multi-objective fractional programming problem. The single objective fractional
programming problem is solved by complementary method. Finally the single
objective programming problem is solved by using LINGO. A numerical example is
presented to illustrate the proposed method.
Keywords: Multi-objective programming problem, Probabilistic programming
problem, Fractional programming problem, Log normal distribution, Sequential goal
programming.
37 | P a g e
Compressional wave in a thermally conducting elastic medium
Nirakara Pradhan and Sapan Kumar SamalDepartment of Mathematics
Abstract
The compressional wave propagation in a thermally conducting elastic medium has
been investigated. Considering the equations of motions of compressional wave in
displacement and temperature field, the frequency equation has been derived. The
dispersion and damping equations have been derived for the propagation of
compressional wave in four materials copper, steel, aluminum and lead. Effect of
phase velocity and damping co- efficient are shown graphically. It is found that the
increase in wavenumber results the decrease in phase velocity and increase in
damping coefficient.
Key words: Compression, Phase velocity, Dispersion, Damping Coefficients.
38 | P a g e
Multi-objective linear fractional stochastic transportationproblem
Adane Abebaw Gessesse, R. Mishra and M. M. Acharya
Department of Mathematics
Abstract
In real life, there exists an exchange of goods from some sources to known
destinations through a transportation media. However, at the time of transportation,
there is a need for minimizing more than one objective, which is conflicting and
non-commensurable. Also, distributions will be done by maintaining good
relationships between some parameters. These parameters may happen in the form of
actual /standard transportation cost, shipping cost/preferred route, total
return/investment, etc. Besides, these parameters may not be deterministic. In this
thesis, a mathematical model called multi-objective linear fractional stochastic
transportation problem is proposed for handling such a problem. Uncertainties are
handled using both classical and evolutionary algorithmic techniques. The supply and
demand parameters of the constraints are continuous random variables. In the
classical approaches, initially, the random constraints are transformed into equivalent
deterministic constraints using a chance constraint method. The multi-objective
fractional transportation problem is converted into a multi-objective transportation
problem using an equivalent transformation theorem. On the other hand, the
evolutionary algorithmic method called stochastic simulation-based GA approach
solves the problem without finding its deterministic equivalent. Feasibility regarding
probability constraints is maintained throughout the problem. Different numerical
case studies are modeled for illustration of the model as well as the methodology.
39 | P a g e
Upper bound on Hankel determinant for bounded turning functionassociated with Salagean difference operator
Avaya Naik and Trailokya PanigrahiDepartment of Mathematics
Abstract
Let represent the class of all functions h of the form n
nn zazzh
2
)( which are
analytic in the open unit disc 1||: zCz satisfying normalization condition
01)0()0( hh . Let S be the subclass of consist of univalent functions. A
function h said to be of bounded turning if and only if ).(0)(Re zzh We
denote such class of functions by R. By making use of Salagean difference operatorD we introduce a new function class
})0{,,10()( 0 NNRR which generalizes the class of functions
of bounded turning of order alpha. We investigate upper bounds on the third Hankel
determinant for this class Our results generalize the results of earlier researchers in
this direction.
Key words and Phrases: Univalent function, Hankel determinant, Salagean
difference operator, Functions of bounded turning
2010 Mathematics Subject Classification: 30C45, 30C50
40 | P a g e
Cubic B-spline approach for approximate solutionof one dimensional heat equation
Guesh Simretab Gebremedhin and Saumya Ranjan JenaDepartment of Mathematics
Abstract
A cubic B-spline collocation scheme is proposed for the approximate solution of one
dimensional heat equation. Two test problems are taken to test the efficiency and
accuracy for the present method. Stability analysis is investigated and funds to be
unconditional stable. The present method is compared with others and to analytical
solution.
41 | P a g e
Approximate solution of initial value problem by differentialtransformation method
Minakshi Mohanty, Saumya Ranjan Jena and Satya Kumar MishraDepartment of Mathematics
Abstract
The present article uses the Differential Transformation Method to solve second and
third order IVPs along with electrical circuit problems. The method is well established
by taking three different examples where the analytical and numerical results are
compared and converge to a fair degree of accuracy. The results obtained suggest that
the present technique can be treated as an efficient and alternative method for solving
initial and boundary value problems.
42 | P a g e
Formulation of fuzzy random multi-level linear programmingproblems
G.C. Sasmal, S. K. BariK and S. AcharyaDepartment of Mathematics
Abstract
The present study constitutes the multi-level linear programming problems with the
right hand side parameters of the constraints in both first level and second level as
fuzzy random variables. It is difficult to solve the proposed mathematical
programming model immediately due to presence of uncertain parameters. A newly
originated methodology is established to find the crisp equivalent deterministic
models. Then the models are solved by using well known fuzzy programming
approach. A numerical example is evidenced to exemplify the usefulness of the
suggested methodological analysis and solution process.
43 | P a g e
A study on some mathematical models on attack ofMalicious objects in a computer network and their defences
Swapnita Mohanty and A.K. PaulDepartment of Mathematics
Abstract
In this research topic we propose some mathematical model to give an idea on how
long the malicious objects may prevail in a computer network and how we can
minimize its harmful effects. Once a mathematical model has been formulated we will
calculate the basic reproduction number of the proposed model, stability of the model
at the equilibrium points. The basic reproduction number will give the idea about the
epidemic character in the computer network. The numerical methods are employed to
solve and simulate the equations developed. The simulated results help us to
understand the spread and control of malicious codes in computer network.
44 | P a g e
Progressive compound rules for numerical integration
Of integral of analytic functions
Pabitra Ojha and P.K. Mohanty
Department of Mathematics
Abstract
Some compound rules of progressive type for the approximate evaluations of
complex integrals of analytic functions over a line segment have been constructed in
this paper. Rules have been examined by numerically integrating some standard test
integrals and their respective order of convergency has been determined. A numerical
scheme has been developed for the numerical computation of the Cauchy type
oscillatory integral. The scheme is the composition of quadrature rule meant for the
approximate evaluation of Cauchy principal value of the singular integral and a quasi
exact quadrature meant for the numerical integration of Fylon type integrals. The
error bounds are determined and the scheme numerically verified by some standard
test integrals. The solution of the hyper singular integral equation is derived by using
two methods. The first is based on reducing it to a pair of Abel integrals. The second
is based on expansion of the unknown function in terms of Chebyshev polynomials.
45 | P a g e
The progressive quadrature rules for approximate evaluation of realdefinite integrals
B. N.Dash, P.K.Mohanty and M. HottaDepartment of Mathematics
Abstract
A class of progressive quadrature rules for the approximate evaluation of real definite
integrals has been proposed in this paper. Rules have been examined with standard
test integrals and their respective error bounds have been determined.
We used a class of progressive quadrature rules for the numerical integration of real
definite integral
1
1
;I f f x dx
where f x is assumed as a continuously differentiable function in the range of
integration.
In this paper we have made a modest attempt to formulate a sequence of quadrature
rule nR f of precision (2n+3) from two classes of rules of suitable precision,
keeping in mind:
1. rules are to be of progressive;
2. well-conditioned; and
3. there will be no further occurrence of error like truncation error, round-off
error etc.
i.e. 11 ;n n n n
n n
R f A R f B G f I fA B
where algebraic degree of precision nR f = algebraic degree of precision
; 1G f n .Based on the scheme given in the above, a sequence of progressive
quadrature rules 1 2 3 4, , ,R f R f R f R f and 5R f of precisions 5, 7, 9, 11
and 13 respectively have been constructed. The numerical values of the error
constants ; 1 1 5ke r k corresponding to the quadrature rules
; 1 1 5kR f k have been evaluated for the different values of 1r .
46 | P a g e
On fourier series and its applicationsAnwesha Mishra
Department of Mathematics
Abstract
In the last few decades, Fourier series received growing interest among researchers
and scientists as it has given a new dimension in approximating signals. In the past,
approximation of signals by using summability theory was investigated by several
researchers. Later, the approximation of signals was studied in different function
spaces such as Lipschitz, Holder, Zygmund and Besov. In the present paper, the main
focus is to review the literature based on degree of approximation of signals (or
functions) belonging to generalized Lipschitz / Zygmund classes by using the product
mean of Fourier series / Conjugate Fourier series / Derived Fourier series and then to
establish a result for better approximation of signals.
Keywords: Summability theory, approximation theory, Fourier coefficient,
approximation of signals, Lipschitz classes
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Bimodal character of cyclone climatology in the bay of bengalmodulated by monsoon seasonal cycle
Kanak Lata XalxoDepartment of Mathematics
Abstract
The causes of different annual cycle of Tropical cyclone (TC) frequency over the Bayof Bengal (BoB) were investigated through the diagnosis of a genesis potential index(GPI) with the use of NCEP Reanalysis dataset covering 1981-2009. The relativecontributions of four environmental parameters were assessed quantitatively. Thestudy indicated that the strong vertical shear alone from boreal spring to summercannot overcome the relative humidity effect .It is the combine effect of vertical shear,vorticity, and sea surface temperature (SST) that leads to the GPI minimum in borealsummer. It is observed that TC frequency in October-November is higher than that inApril-May which is primarily attributed to the differences of mean relative humiditybetween the two periods. In contrast, more super cyclones (category 4 or above) occurin April-May than in October-November. The study suggested, greater ocean heatcontent, the first branch of northward-propagating intraseasonal oscillations (ISOs)associated with the monsoon onset over the BoB, and stronger ISO intensity inApril-May are favorable environmental conditions for cyclone intensification.
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Abstract
on
Physics
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Colossal dielectric and relaxor nature of bi modified ccto thin film
A. K. Mishra M.Devi, Manas R. Panigrahi
AbstractBismuth modified CCTO ceramic thin film is deposited on ITO by modified sol-gelroute. The prepared film is subjected to X-Ray diffraction which shows the cubicperovskite structure. The Scanning Electron Microscope (SEM) micrographs showrandomly oriented and dense rod like microstructure.. The dielectric constant of thefilm is measured in the frequency range 100Hz- 1MHz with variation in temperaturefrom 100-600 K. It is observed that with increasing frequency dielectric constantdecreases and the rate of decrease of dielectric constant with frequencies increaseswith increasing temperature. This may be due to the easy formation of asymmetriccovalent bonds with oxygen ion by Bi3+, which increases the polarizability ofelectronic displacement. It is also observed that the dielectric loss decreases withincreasing frequency. As the temperature increases, the dielectric loss also increasesat low frequency regions. The typical relaxor behaviour of the material is confirmedby peaks broadening at low frequency with increasing temperature and the peaks shiftto low frequency region with decreasing temperature. This relaxation behaviour arisesdue to space charge polarization. The broad band spectrum of high dielectric constantis also seen over the studied temperature range.
Keywords: Colossal Dielectric; Bi doped CCTO; Thin Film; Microstructure
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Heterogeneous photocatalysis application using zinc oxide (zno) semiconductornanoparticles prepared from its laboratory grade powder precursor
Rajashree Sahoo, Susanta Kumar Das*
Dept. of Physics, School of Applied Sciences, KIIT Deemed to be University, Odisha,751024, India
*Corresponding author. E-mail address: skdasfpy@kiit.ac.in
Email id: rajashreesahoo92@gmail.com
Abstract
Currently, the rapid industrialization has brought hazardous dye pollutants into thewater. This is a serious threat to environment. In recent years, interest inphotocatalysis has focused on the use of metal oxide semiconductor materials asphotocatalysts for the removal of dyes. Zinc oxide (ZnO) is an II–VI compoundsemiconductor, having properties like direct band gap (Eg~3.3 eV) and largeexcitation binding energy (~60meV at room temperature). Many works have beenreported on use of commercial ZnO nanoparticles for photocatalysis reaction.However, in all these works the ZnO nanoparticles used are generally of ACSor reagent grades which are quite expensive. For reduction of the cost, in this workZnO nanoparticles are prepared from commercial laboratory grade ZnO powder andcharacterized by XRD, TEM, PL studies. UV photocatalytic dye decomposition studywas done using these ZnO nanoparticles. Particularly, the reaction kinetics andreaction rate are estimated by monitoring various dye decomposition activity. Thephotocatalysis studies with scavengers are done to find the mechanism of thephotocatalytic decomposition process. The performance of these nanoparticles iscompared with respect to benchmark commercial TiO2 nanoparticles (Degussa P25).Artificial visible light and solar photocatalytic dye decomposition have also beenstudied.
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Improved dielectric behavior and electrical properties of
Ba0.5Sr05TiO3 ceramics by Sn doping
M. Das Pattanayak1, L. Biswal2
1* Deptt. Of Physics, Fakir Mohan College, Balasore , Odisha.
2* Deptt. Of Physics, School of Applied Sciences, KIIT Deemed University, Bhubaneswar,Odisha.
Abstract
Polycrystalline samples of Ba0.5Sr0.5Ti O3 with Stannic Oxide (with 1%,3%,5%and7% doping) were prepared from high purity ingredients using a high-temperaturesolid-state reaction technique in a suitable stoichiometry ratio with BaCO3, SrCO3,TiO2 and SnO2 as raw materials. XRD study confirms single phase compound wellagreed with cubic parameters using standard software POWD. The SEM pictureshow clear grain and grain boundaries. As variable dielectric constant and high losstangent create hindrance for tunable devices, this work aims at obtaining a stablebehavior of dielectric constant over ambient temperature and frequency band.Significant modification in the permittivity and loss tangent of BST of different Sndoped ratios was observed over a range of frequency 1kHz to 1 MHz. Compleximpedance spectroscopy of the samples at different temperatures indicated NonDebye type of relaxation. The AC/DC conductivity spectra derived for the differentcompositions explained clearly about the electrical processes and mechanisminvolved in the synthesized materials. Comparatively stable behavior of dielectricconstant over ambient temperature and frequency band of some sample(5% Sn doped)as well as moderate value of loss tangent (of the order 0.02) held promise forapplication in tuned circuits.
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Reflectance - Temperature characteristics of AlGaN semiconductor at threecommunication windows
Sakti Prasan Mohanty1, C. S. Mishra2, S. K. Sahoo1*and G. Palai2*
1Department of Physics, Kalinga Institute of Industrial Technology (KIIT), Deemed to be University,Bhubaneswar-751024, India
2Gandhi Institute for Technological Advancement (GITA), Bhubaneswar, India
*Corresponding authors: gpalai28@gmail.com (G. Palai), physushant@gmail.com (S. K. Sahoo)
Abstract
This paper reports the temperature variation of reflectance with respect to AlGaNwave guide structure on Silicon substrate. Plane wave expansion technique isemployed for simulation to exhibit the reflectance pertaining to AlGaN wave guidestructure. The simulation results show the approximate linear variation of reflectancewith respect to temperature in the aforementioned AlGaN wave guide at threecommunication windows (850nm, 1310nm, 1550nm). Such characteristic study yieldswith accuracy, the realization of temperature dependence of reflectance.
Keywords: Plane wave expansion, AlGaN, Reflectance, Temperature.
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Muralidhar Swain, Research Scholar, Department of Physics(SAS).Kalinga Institute of Industrial Technology(KIIT), Deemed to be University,Bhubaneswar.Roll No: 1581022, Registration No: 15611544253
Abstract
Pyroelectricity is the property of certain materials. It is explained as the ability ofcertain materials to generate a momentary voltage if they are heated or cooled. Thechange in temperature modifies the position of the atoms in the crystal structure, sothat polarization of the material changes. This polarization gives rise to a voltageacross the material.The binary nitrides GaN, InN, AlN and their alloys are verypromising candidates for high power and high frequency applications due to theirtuneable band gap, elevated thermal stability, large mechanical hardness, largedielectric constant, high electron velocity, large breakdown electric field and highresistance to harsh environment. They can be used for violet, blue and green lightemitting devices and for high electron mobility transistors at high temperature. Animportant feature of heterostructures made from these nitrides is the existence ofpolarization charges at the hetero-interface due to spontaneous and piezoelectricpolarization. This polarization generates an electric field which radically influencesthe distribution and mobility of carriers. They have deep impact on optical, thermaland electrical properties of the heterostructures. As III–nitrides are used in hightemperature and high power operations, the change in temperature in the materialinfluences directly the polarization mechanism. Thus, it is required to explore whathappens to the polarization mechanism under heating; and how it influences theperformance of the devices fabricated from III-V nitrides. In this work, pyroelectriceffect and thermal properties of binaries nitrides (AlN, GaN and InN) have beeninvestigated taking into consideration of built-in-polarization field.
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Site dependent proton affinity and fluoride affinity calculation on toxic TABUNmolecule: A DFT and CCSD(T) study
D. K. Mahapatra and N. C. Bera*
ncberafpy@kiit.ac.in
Department of Physics, School of Applied Sciences, KIIT University, Bhubaneswar751 024.
Abstract
During last few decades scientists are giving emphasis on detoxification of chemicalwarfare agents by adopting different experimental techniques. In rent years due hugedevelopment in computer hardware and software, the computational research hasimproved a lot and the computational results using different quantum chemicalmethods gives quite reasonable accuracy to structure, photophysical and magneticproperties of molecules. Here we have applied DFT based hybrid B3LYP methodfollowed by very expensive ab initio CCSD(T) method to study the proton affinity(PA) and Fluoride affinity (FA) of Tabun molecules. The proton (H+) and fluoride (F-)adduct reaction are the most fundamental cationic and anionic reaction thereforeyields the basis thermodynamic parameters, necessary for stability and reactionprofile calculation. Here we have considered proton and fluoride coming from allprobable direction to interact the molecule and each approaches gives different protonadduct or fluoride adduct structure. 49 different approaches has been consideredwhich gives different proton affinity of the molecules and in some cases we seeabstraction of H2 and CH4 molecules and some cases dissociation of the moleculewhich lead to the detoxification of the molecules.
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Structural, electrical, magnetic and optical studies of transition metal poped
BiFeO3 multiferroic Nanoparticles Prepared By Sol – Gel Technique
Atul Kr. Sinha, B. Bhushan
Dept. Of Physics, School of Applied Sciences, KIIT deemed to be University,Bhubaneswar
*E-mail:bhavyaiuc@gmail.com
Abstract
Chromium and Cobalt doped BiFeO3 (BFO) nanoparticles were synthesized by afacile sol-gel route. XRD confirmed the phase pure formation of pristine BFO, 1%and 3% Cr-doped BFO and all Co-doped BFO nanoparticles. However, slightimpurity phase appeared in 5% and 7% Cr-doped samples.The crystallite sizes asdetermined by Scherrer equation were found to be 46 nm, 44 nm, 39 nm, 37 nm and34 nm respectively for pure BiFeO3 , 1% , 3%, 5% and 7% Cr doped BFOrespectively whereas 50 nm, 48 nm, 45 nm and 43 nm for 1%, 3%, 5% and 7% Cobaltdoped BFO respectively. The phase purity and stoichiometry of all samples wereconfirmed from EDX, no other elements were observed other than Bi, Fe, Cr, Co andO. From X-ray photoelectron spectroscopy (XPS), it was observed that the valencestate of Fe in Cr-doped BFO and Co-doped BFO was +3. The valence state of Co incobalt doped BFO was found to be +3 by XPS analysis. Mössbauer study alsoconfirmed that the oxidation state of Fe in Cr and Co doped bismuth ferrite samples isof the order of +3 high spin states. The magnetic hysteresis loop measured at roomtemperature exhibited a weak ferromagnetic behavior of the samples and themagnetization was enhanced with the increase in Cr and Co doping concentration.Saturation magnetization increases and coercive field decreases with the increase inCr and Co doping concentration. BFO with 1% Cr doped posseses a higher remnantpolarization and coercive electric field as compared to other Cr doped and pure BFOnanoparticles whereas BFO with.5% Co doped posseses a higher remnant polarizationand coercive electric field as compared to other Co doped and pure BFO nanoparticles.Dielectric constant is decreased by increasing frequency range. Absorption spectra isrecorded in the UV visible range of electromagnetic spectrum and band gap energy iscalculated by Tauc Equation and first derivative of absorption spectra. Band gapenergy is enhanced by the substitution of Chromium and cobalt in Fe site of BismuthFerrite.The above synthesized material shows multiferroic properties and is quitefavourable for data storage application.
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Biomass derived carbon materials for energy storage application
Luna Jena , Roll No 1681078 Reg No 16651451518
School of Applied Sciences, KIIT University, Bhubaneswar, India
Abstract
Locally collected mature bamboo stems were carbonized at 6000C-7000C for 2hoursfollowed by ball milling of the chars for 10 hrs. AC conductivity and dielectricbehavior of as obtained bamboo charcoal samples were analyzed by X-ray diffractionand subsequently by an LCR meter at radio wave frequencies (1Hz- 1MHz). XRDanalysis proves presence of amorphous peaks at 2θ = 240 and 220 attributed to the(002) network of amorphous carbon structures. The dielectric response shows strongfrequency dependence in the 1Hz to 1MHz range exhibiting typical dielectricrelaxation at higher frequencies. Thus bamboo charcoal obtained from abundantlyavailable, renewable bamboo biomass sources can be a potential low cost precursorfor obtaining suitable dielectric materials for energy storage applications.
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Silver nanostructures: plasmon tunability, growth kinetics, and catalyticapplications
B. K. Dadhich1, B.Bhushan1,*, and A. Priyam2
1Department of Physics, KIIT, Deemed to be University, Bhubaneswar2Department of Chemistry, Central University of South Bihar, Gaya
*E-mail:bhavyaiuc@gmail.com
Abstract
In recent decades, metal nanostructures have attracted increasing interest due to theirshape- and size-dependent optical properties based on surface plasmon resonance(SPR) in a wide range of fields. Thus, a number of studies on synthesis and SPRproperties of gold or silver nanoparticles in a variety of shapes such as nanorod,nanoprism, nanoplate and nanocube have been reported so far from the viewpoints offundamental understanding of their shape-dependent SPR and SPR-based applicationsincluding catalysis, chemical and biochemical sensing, optical labeling, fluorescenceenhancement, and surface enhanced Raman scattering. Here, we have synthesizedhollow silver nanocubes, nanoshells, and nanopyramid for tunable SPR. As-preparedHAgNCs have been used solely to understand the dynamics of plasmonicphotocatalysis over the entire visible range which can change because of the variationin size, shape, and structure of the nanocrystals. By subtle tuning of SPR peak andmolar extinction coefficient, the hollow nanostructures can be made to harvest mostof the solar energies through the processes such as plasmonic photocatalysis.
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Recent developments in the energy-storage and capacitor performance of sodiumbismuth titanate based ceramics
A. SinghaSupervisors: Dr. S. Praharaj and Dr. D. Rout
School of Applied Sciences (Physics), KIIT UniversityBhubaneswar, Odisha-751024
Abstract
In this revolutionizing era of electronic and electrical devices, the ceramic capacitorswith high dielectric constants and energy storage capacity have a major contributionto the development of efficient method for the storage and distribution of theelectrical power. Due to faster charge-discharge rates (order of nano second) andhigher power density (up to 108 W/kg), they satisfy the requirement of super highpower electronics and systems. However, the current technology is facing challengesto develop a reliable, high temperature (>> 200 °C) and high capacitance ceramicmaterial to be used in a plethora of applications where electronics is exposed to hightemperatures, such as deep oil drilling, aviation, space exploration, automobiles,nuclear reactors etc. There are two major concerns that need to be addressed-temperature stable (i) permittivity and (ii) high energy storage efficiency with a broadworking range. Na0.5Bi0.5TiO3 based compositions with high Curie temperature,diffused dielectric peak and; high ᧭ٺ�� and low �� have proved to potentialcapacitor/energy storage materials in recent times. In spite such attractive properties,few compositions such as NBT-BT, NBT-BKT-KNN, NBT-BT-NN, NBT-BT-NBN,NBT-SBT-NN etc have been investigated so far. A rigorous research in this directionmay bring a revolution in the performance of this family of ceramics.
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Study of scanning velocity effect on texturization of titanium sheet by
femtosecond laser in air
Atal Mundamajhi, S.K.Das,
Dept. of Physics, School of Applied Sciences, Kalinga Institute Of Industrial
Technology, Deemed to be University, Bhubaneswar, Odisha, 751024, IndiaEmail: skdasfp@kiit.ac.in
Abstract
Laser induced periodic surface structures (LIPSS) of titanium surface provides arequired characteristics simple way for uniformity, reproducible, functionalization ofsurface and nanostructuring for the control of optical, chemical or mechanicalproperties. The modified surface increases the surface area and incorporation ofoxygen. The laser based surface texturing is widely accepted to generate the LIPSSbecause of it posses many advantages such as non-contact, high machining precision,non-pollution and easy method. In this work studies have been done on scanningvelocity effect on texturization of Titanium sheet by femtosecond laser in air.
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Structural, morphological and dielectric properties of bamboo charcoal
Dhani Soren
School of Applied Sciences, KIIT University
Abstract
Structural, morphological, and dielectric properties of bamboo charcoal as afunctional biomaterial bears a lot of importance because of its' abundance,renewability, non toxicity, sustainability, biocompatibility, easy processing and lowcost. Bamboo charcoal samples were prepared from five year old mature bamboostems collected from local forest division, by carbonization method in a tube furnaceat temperatures ranging from 400 oC to 700 oC, in nitrogen atmosphere, with a heatingrate of 100/min for 2 hrs followed by manual grinding in a mortar and pestle.
Structural characterization has been performed using X-ray diffraction (XRD) andfield emission scanning electron microscopy (FESEM). From XRD diffractionpattern, amorphous nature of bamboo charcoal with 002 and 100/101 reflections wereobserved. FESEM analyses show honeycomb like porous structure with differentpore sizes.
Bamboo charcoal samples were pelletized and their dielectric constant, dielectric lossand ac conductivity were measured using LCR meter in the frequency range1Hz-1MHz. The dielectric constant and dielectric loss decreased with increase infrequency up to 100Hz and then saturated. This decrease was low at low and mediumfrequencies, and very high at high frequencies, may be due to interfacial polarizationtaking place in the material. Dielectric constant, dielectric loss and ac conductivityvalue at 1KHz was estimated as 56 F/m, 31, 10-4 - 10-7S/m respectively. Due to highdielectric constant and low loss as compared to the other carbon materials it can beused as a promising material for energy storage applications.
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Synthesis, Characterization and Stability Study of Perovskite (CH3NH3PbI3) forSolar Cell Applications
Ipsita Mohanty1, S. Mangal1*, S. Jana1 and U.P. Singh2
1School of Applied Sciences, Kalinga Institute of Industrial Technology (KIIT), Bhubaneswar, India751024
2School of Electronics Engineering, Kalinga Institute of Industrial Technology (KIIT), Bhubaneswar,India 751024
*sutanufpy@kiit.ac.in
Abstract
In the present time, perovskite solar cells have a great scientific and technical interestbecause of its tremendous potential in harnessing solar energy to produceunconventional green energy. Perovskite materials have high carrier mobility andlong diffusion lengths, which make it an exception as a light harvester material. Alongwith remarkable properties, metal halide perovskites are easy to synthesize and costefficient. Due to the absorption onset of less than 800 nm in the solar spectrum,organo-lead halide perovskite act as a great light harvester. Due to its high absorptioncoefficient, it is crucial for photovoltaic applications. In our work, we have firstsynthesized perovskite i.e. methylammonium lead iodide (CH3NH3PbI3) powder usingwet chemical synthesis. Then CH3NH3PbI3 thin films were deposited on glasssubstrates using doctor-blade and spin-coating methods. A brief characterization studyof both the CH3NH3PbI3 powder and films were done. The compositional andstructural analysis of the CH3NH3PbI3 powder has been characterized using ED-XRFand XRD and the optical and electrical properties were also studied using UV-VISspectrophotometer and Hall Effect measurement system respectively. Thecharacterization result indicates a basic compositional difference between the powderand films due to the involvement of solvent during deposition of films. Also asystematic study was done to understand the stability of fabricated perovskite thinfilm layer. Four different samples were characterized as: (i) As prepared, (ii) 15 daysafter synthesis, (iii) 30 days after synthesis, and (iv) Annealed sample. Thecharacterization result shows that with course of time, the degradation of sample andchange in its properties are observed.
Keywords: Perovskite, CH3NH3PbI3, characterization, stability, thinfilms
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Growth of micro and nanostructures on si surface using laser workstationattachment for solar cell application
P. Chandrakanta Singh, Susanta Kumar Das*
Dept. of Physics, School of Applied Sciences, KIIT Deemed to be University,Bhubaneswar, 751024, India
*Corresponding author: skdasfpy@kiit.ac.in
Abstract
The investigation has been done on the growth of microstructures on silicon (Si)surface using Nitrogen (N2) nanosecond (ns) laser processing in air medium by LaserWorkstation Attachment (LWA). The wavelength, pulse duration and pulse energy ofthe used laser are 337nm, ~3.5ns and 170µJ respectively. The sample scanningvelocity was varied from 0.5-0.05 mm/s at constant repetition rate of 20Hz. Theexperiment was done in a single linear line scanning mode for short region. Themorphological characterizations of the produced microtextured Si were done byImageJ software calibrated USB Digital Microscope Endoscope (UDME) Camera andField Emission Scanning Electron Microscope (FESEM). The periods of generatedmicro-textured Si varied from 15µm to 3µm with decrease of velocity from 0.3mm/sto 0.05mm/s. In the optimized condition of large area surface texture it isdemonstrated that the reflectance be reduced of low as to 10% (from 45 %) for abroad wavelength range. The reported method for processing optimization involves asingle step dry etching process as well advantageous to minimize of processing steps.
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Preparing ZnO thin films from its powder precursor
Maher Alrefaee, Susanta Kumar Das(a)
Dept. of Physics, School of Applied Sciences, Kalinga Institute of IndustrialTechnology Deemed to be University, Bhubaneswar, Odisha, 751024. India
(a) Corresponding author: skdasfpy@kiit.ac.in
Abstract
Zinc oxide (ZnO) thin films have been studied widely because of their specialchemical and physical properties such as optical transparency, electrical conductivity,piezoelectricity, low cost and chemical stability, large excitonic band energy, goodchemical and thermal stability, high availability in nature and nontoxicity. Thesefeatures have made ZnO thin films very attractive for different applications such asgas sensors, transducers, solar cells, luminescent materials, transparent conductors,heat mirrors, and semiconductor heterojunctions. Now-a-days, various methods havebeen used for the synthesis of ZnO thin films such as pulsed-laser deposition, RFmagnetron sputtering, chemical vapor deposition, spray pyrolysis, chemical bathdeposition and the sol–gel process. In all these conventional works Zn acetate, ZnNitrate or Zn Chloride etc. are taken as precursors. Recently it has been demonstratedthat a non-conventional method can be adopted to grow metal oxide thin film from itspowder precursor. This has been demonstrated for growth of TiO2 thin film. In thepresent work, ZnO thin films were prepared successfully using a similarunconventional method on glass substrates. The prepared films were annealed attemperatures 250oC, 500oC and 750oC. The Optical microscope images have shownthat the thin films have a good uniformity. The average thickness of the thin films asmeasured by gravimetry technique method was 689 nm. A processing parameterdependent electrical behaviour has been observed.
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Preparation of activated carbon with low cost oven based heating system
Sinmay Sahoo and Susanta Kumar Das*
Department of Physics, School of Applied Sciences, KIIT Deemed to beUniversity
Abstract
Activated carbon, a widely used adsorbent in industrial processes, is composed of amicro porous, homogenous structure with high surface area and shows radiationstability. The process for producing high-efficiency activated carbon is not completelyinvestigated in developing countries. Furthermore, there are many problems with theregeneration of used activated carbon. Nowadays, there is a great interest in findinginexpensive and effective alternatives to the existing commercial activated carbon.Exploring effective and low-cost activated carbon may contribute to environmentalsustainability and offer benefits for future commercial applications. The cost ofactivated carbon prepared from biomaterials is very low Activated carbon has beenused intensively studied in recent decades for a wide variety of application such asMedical uses, Adsorption of natural Gas, Cosmetics use, drink water and Airpurification.
Preparation of Activated Charcoal-
(Fig. Dry charcoal powder) (Fig. Aq. Sol. of CaCl2 used for Activation of the Charcoal) (Fig, Paste of charcoal and CaCl2) (Fig. Low cost
heating system)
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