Conditioning used frying oil for conversion to biodiesel Shane Bird, Marie Stark, Kate Burlingame, Chuck Weatherspoon, John Neal French Fry Fuel Sponsored.

Conditioning used frying oil for conversion to biodiesel

Shane Bird, Marie Stark, Kate Burlingame,

Chuck Weatherspoon, John Neal

French Fry FuelSponsored by J.R. Simplot, Co.

Design Review Outline

Background Accomplishments Problem Definition Remove Particulate Matter Reduction of Water Content from Oil Reduction of FFA Content from Oil Integrated Solution Concepts Project Challenges Budget/Timeline Discussion Questions

Background

The J.R. Simplot Company generates 2 million pounds of waste oil each year.

Simplot would like to condition the oil and convert it to biodiesel, which would then be returned to Simplot to offset the diesel used in the transportation fleet.

Accomplishments

The waste oil generated in production lines forms two waste streams.

Team French Fry Fuel has performed numerous tests on the mainstream oil. We determined that it is suitable for conversion to biodiesel.

Problem Statement

The secondary waste stream generated, DAF (Dissolved Air Floatation) oil, is an economic drain on Simplot.

Our goal is to pretreat both elements of DAF oil, MOP (oil from plant clean-up) and WESP (wet electrostatic precipitator), before sending them to a biodiesel manufacturer.

In order to condition the oil, the team will design a system to remove free fatty acids, water, particulates, and other carbon impurities from the used oil to a specification defined by the biodiesel manufacturer.

<4% FFA <.1% Water by weight <50-100 micron particulate size

Integrated Solution

Self Cleaning Paper Filters

Biodiesel Conversion for FFA < 4%

Heat

FilterWater

RemovalEsterification for

FFA > 4%

Bag Filter

Falling FilmEvaporator

FlashEvaporator BD20

BeadsSulfuric

Acid

Test FFA Level

Test FFA Level & Water Content

Particulate Removal: Bag Filter

Advantages: Easy to clean. Filters large amounts

of particulates. Low start-up cost.

Disadvantages: Large particulate may

push through filter bags.

Manual maintenance. Felt Filter Bags Easy Access Filter-Bag

Housings Stainless Steel

http://www.mcmaster.com/

Particulate Removal: Self-Cleaning Paper Filter

http://www.heatandcontrol.com/product.asp?pid=46

Advantages: Self cleaning. Filters large amounts

of particulates. Low maintenance.

Disadvantage: High Start-up cost.

Continuous Paper Filter

FFA Reduction: Acid Esterification Using Sulfuric Acid

1. Sulfuric acid (catalyst) is dissolved in methanol, then added to the oil

2. While the reaction takes place continuous dewatering must also occur

Advantages: Can be batch or continuous Higher removal of FFA Make more fuel out of high

FFA feedstock

Disadvantages: Must remove water

continuously for high yields Potential hazardous chemical,

methanol utilized Increased chemical cost

FFA Reduction: BD20

This emerging technology uses the same principles as acid esterification.

Advantages: Treats oils with FFA ranging from 0.5 to 100% Fast reaction time High conversion efficiency Can treat oils with low levels of water Fewer toxic chemicals

Disadvantages Availability issues Unknown cost

Water Reduction: Falling Film Evaporator

Falling film evaporators work by allowing a film of the liquid to flow down the tubes of the heat exchanger.

Advantages: Will remove high water

content from fluids Works with low

temperature differences. Disadvantages:

Complicated design Requires higher heat

A: ProductB: VaporC: ConcentrateD: Heating SteamE: Condensate

1: Head2: Calandria3: Calandria, Lower part4: Mixing Channel

5: Vapor Separator

www.niroinc.com/evaporators_crystallizers/falling_film_evaporators.asp

Flash Evaporation(Water Removal)

Flash evaporation is the vaporization of a saturated liquid (in this case oil) as it undergoes a pressure reduction through a small orifice or throttling device.

The oil is heated and then sent via a pump to the feed inlet where it goes through a reduction in pressure. The applied heat and reduced pressure converts the water in the oil to a vapor.

Note: If the oil has greater than 5% water in it then multiple evaporators may be needed to remove that water to an acceptable level.

http://en.wikipedia.org/wiki/Flash_evaporation

Recommended Treatment Process

Heated

Agitated

Tank

Filter SystemEvaporator

Esterification

Methanol

Recovery

Q

Q

Water

Water

P P

P

P

P

To Blue Sky DAF Oil

Particles

(1)(2)

(3)

(1) Sample taken for Water content and FFA testing

(2) Send to Blue Sky if FFA ≤ 4% FFA

(3) Test for Water and FFA content

Cost for Full Scale Design

Process Unit Cost/Unit Est. Cost

Sulfuric Acid 5 190mL Bottles

$32.00

BD-20

Bag Filter Ea. $1200 $1500

Self Cleaning Ea. $100,000

Flash Evaporator Ea. $50,000

Falling Film Ea. $60,000

Design Challenges

Further lab analysis of the WESP and MOP oils will allow us to determine a treatment plan.

Hazardous chemicals near food processing plant.

Effective cost analysis. Bench-top model.

Timeline

Snapshot Day ……………….Nov. 30 2007

Semester End Report Due…Dec. 11 2007 Winter Break…………………Dec. 14 2007 Spring Semester Begins…….Jan. 9 2007 2nd Design Review………….Feb. ?? 2008 Final Report Due…………….May ?? 2008 Engineering Expo……………April 25 2008

Questions?

Ideas, Comments, or Suggestions