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" Sp (i
., ~H )- -F ~'"
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F .oi. LJev..( pYc4(. ~~ V, tM..A"" v~ '" ;j{ . -7
,",O'L\ .,
DI{ (G;~~ssc4~)
__--:-_G_r_o-.,;~ I.t~ ...
v = (E> ) dD.l) rt-l~ t4et k,oJ.,...,,.,A- t(U
1fAA'1/UJ(, (!/ Tt. ~ ~4u.. <M >" /1t
(,',,'r .f~ IcI-tA
"c."~ "",'..f.A. $/tt;tF~
..Il..'" (14010'1(", 7>4_..~«f, /"" ) t.st. t(,t(.. I~l~( N So~~ ,t"W\'1l
;...- q).'}tA~ !r~ #'iM ct..d/~ I olA.1l O/;U r;- =0,
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alu., f)"\ ~ I o(d SOlo/O t, /
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Nt6e- ~4lA''1J~r''''
Sr 1 .: 1 ,
4 A )- ß>k (S(J f H - U
- f k (S,f N -W)
~ii !'-:= -51!" ~ ~w , S c -t /4. r
}
- (~-rN) litT e--
~ ~ 't1 ~ ... "'"'" ~Cl"J ~l o{v Itt&.o"",· [J.l.. ~ lte....~ .r"W1"" 1IO
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e wi'..( l4ttL ttM fi.JQ i "/c:", ,(('t~.'cJ.~ .
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Rev~$"~Lc. t ..... ~Cl> .. M ~ .. DU.l4o.~ r -' r +f(r J
I.JO~ oUt' J~"~,,,'l ( ~) ~11 11(, t\..1l(.u J
dU = Sp (H dj)
d~ : .cp (N cl.j)
~S = - I( Sp (iMf tl..f)
-t..t
2.) Aib,·fu....., i,,(- ;:~ 1r,J,~..t.... tJ. r.....J. 6<
i .n. (T,V.I = -kT t.- ole; '= V - T~ - rW (= - l'V )
c:::U (T,V,!") ,,.
(T1~ + rl,. ) t. iG.
~ -4S Cf,V/r ) = - (~~ )V,t = ,(..
~'" ", ?-T ~ ?~
~ kT -~
(= - ~r (T, V't) = ?V l.. i(" )V- (:~) ~r
..,. ~., (T, ",t) - (:;) T,' k-I
~,.. -? l.. i"
F.:, clu' L(D... Pr(m; ~.'t..-j...,.'f{ "'U -. = (~:) ~V - (~~ )T,V
tT <(W - <N») ~'1 ~ 0
1) Cl"", il ,;U f:'r e 'I.Lf~;(.. - "<-.( T,.,-(.~ -y,"""'-- ~4Je,..~1A.. :
~(~ E)l = «H-<Ihr> kT1. C v
(4 t-.Jr .. <(w- <.1) r '> • kT N/V '"Xi
&Ees <.)
3-20
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dv.'
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t-.o
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e... l~~ G «AI ,t« !/N = (Ic ~ CVN --. c.
Zc.f t.4c-. /",,0 ... h'"",lAl't,,{A'4 SfJ<--u.r&4._ ist SiAl 1tf',A,A. ~(J';~K...> k,,11 (0. I~ d/~ Fd-l Itt:t,,~ t1 fC41o. I e(1ft' olc.t . ~t CJCJk. r-.o c,.....,(
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1-lJ
j)j l ~~ ~. '" 'JP"" d..M 1M.-, JQ\.u. "....~ tlc,(,,'{ I 0(. ( . J~
pL.4.. l.4.. t4~ tUl.tt...k.... ntlo.>r( ~_ 6{u- e~0l"~ (~-kr
~ t't«.. ~~''''''~ ). ~~~ ~V" VJ. e.~ 6d<'do)4. (0 ..
t.(.v,t,,-,A 1fM'~ <1/) = v kA.,( t,.{,u ])1dr.ki4.. Q t.;itr,'1)
:: - k Sp i {l' + k Ip f~ t.. f~
~ Sp § (~fk -t-.;) -+ ~ rp(( f~ -i )e..iM )
.. - H{r -(",lI(
~
o " ,. ,. '"
~ ~p j'l-t- 5f~kl+~V
..S Ci]- s Cr;] k L: <rl§ (lA.!~-(.I)lt) r
~
JI
- k Z L/r <r I .t... .~ Ir ') r . wr
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'-Ir Wr ;/
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