PROJECT PRE-FEASIBILITY REPORT - Welcome to ...environmentclearance.nic.in/writereaddata/FormB/TOR/PFR/...PROJECT PRE-FEASIBILITY REPORT AND ENV. MANAGEMENT PLAN ON PROPOSED PROJECT

PROJECT PRE-FEASIBILITY REPORT

AND ENV. MANAGEMENT PLAN

ON

PROPOSED PROJECT

FOR

MANUFACTURING OF ALKYD RESINS

AT

Sr. No. 165/p2, Plot No. 3 & 4, Galaxy Industrial, B/h. Vadalia Foods,

Village. Lothada, Taluka – Rajkot,

Dist. Rajkot - 360002.

Project Proponent:

Galaxy Polymers

Galaxy Polymers

Mfg. of Alkyd Resin 2

Chapter-0 EXECUTIVE SUMMARY

The project is summarized in the below table:

Table 0.1 Project Summary

PARTICULARS DETAILS Name of the Unit M/S. Galaxy Polymers Project Proponent Maheshbhai L. Vekariya Products Long Oil Alkyd Resin OR

Medium Oil Alkyd Resin OR Rosinated Oil Alkyd Resin OR Fast Drying Chain stop Alkyd Resin

Location Sr.No.165/ p2, Plot No. 3 & 4,Galaxy Industrial, B/H. Vadalia Foods, Village : Lothada, Taluka. Rajkot, Dist. Rajkot.

Nature of Project Manufacturing Unit Resources Resource type Requirement Source Land 750 m2 Own plot .The plot is N.A. land

designated for industrial purpose Building Total Built-up area = 279 m2

The required shed, plant and machinery to be constructed at the site.

Raw-materials Linseed Oil/Soya Oil/Castor Oil Soya/DCO Fatty Acid Pentaerythritol Glycerin Phthalic Anhydride Catalyst Xylene Benzoic acid

Local traders/market

Water 200 L/D Source: Borewell Power 30 HP Elect. Dept. (PGVCL) Fuel LDO-125 L/D Local traders Man-power Construction & comissioning: 2

Nos. Operarion- Managerial/skilled: 2 Nos. Unskilled: 2 Nos.

Priority to the local people

Galaxy Polymers


Pollution Potential & Mitigation Measures Parameter Potential Mitigation Wastewater

Domestic: 100 L/D Generation

Industrial: 90 L/D

The domestic effluent shall be disposed off through septic tank/ soak pit system.

Evaporator will be used to evaporate the effluent, there shall be zero discharge of industrial effluent.

Air Emissions Emission load from installations under continuous operation

PM: < 150 mg/Nm3 From TFH

SO2:<100 ppm NOx:< 50ppm

LDO will be used as fuel in TFH and a chimney height of 11m will be provided.

The process will be carried out in close condition; chemicals will be handled in a closed manner by pumping or by vacuum transfer to minimize chances of fugitive emissions

The loading – unloading and charging shall be done with pumps. The pump glands and piping will be checked regularly to ensure no leakage.

The manufacturing plant will be in shed which will be open from both sides and hence natural ventilation will be available.

Hazardous & solid waste Discarded bags – 500 kg/Y Empty drums -1000 Nos./Y

The Hazardous wastes will be handled, stored & transported as per CPCB/MoEF Guidelines

Discarded bags will be sold to GPCB approved recyclers.

Empty drums will be recycled/ sold to GPCB approved recyclers.

Noise Inside the plant: <80dB(A) Expected levels The major sources of noise

generation shall be the pumps and motors.

Balancing of shaft of motor and will be done during installation to reduce vibrational noise.

Regular oiling/ maintenance will be done.

Galaxy Polymers


Chapter-1 INTRODUCTION 1.1 THE PROJECT

M/s. Galaxy Polymers has planned to manufacture the products as mentioned in Table-

1.1 at Village Lothada, Sr.No.165/p2, Plot no. 3 & 4, Galaxy Industrial, B/h. Vadalia

Foods, Taluka Rajkot, Dist. Rajkot.

The list of products is provided in the below table:

Table 1.1

List of Proposed Products

Sr. No. Name of Product Quantity (MT/Month) 1. Long Oil Alkyd Resin 40 OR 2. Medium Oil Alkyd Resin 40 OR 3. Rosinated Oil Alkyd Resin 40 OR 4. Fast Drying Chain stop Alkyd Resin 40

1.2 PROJECT PROPONENT M/s. Galaxy Polymers is a new company. It is proprietary firm promoted by Mr. Mahesh L.

Vekariya.

The Proprietor of the company is engaged in manufacturing of oil paints. Above product is

raw material of oil paint. Details of proponent are given below:

Table 1.2 Details of Proponent

Sr. No. Particulars Details 1. Full name & Address of the

Project Proponent Mr. Maheshbhai L. Vekariya “Shriji”, Om Tirupati Balaji Park,Street No.2, Nr. Tapsi Hotel, Kothariya Ring road, Rajkot.

Galaxy Polymers


1.3 NATURE OF THE PROJECT

The proposed project involves the manufacturing of Alkyd Resins. This falls in category

5(f) of the schedule of the EIA notification 2006. As per amendment to EIA Notification,

2006 vide SO 1599 (E) dated 25/06/14, small units are defined as with water

consumption less than 25 KLPD, fuel consumption less than 25 TPD and not covered in

the category of MAH units as per the management, Storage, Import of Hazardous

chemical Rules (MSIHC rules)-1989, the proposed project is categorized as ‘B2’ category.

1.4 NEED FOR THE PROJECT

Alkyd resins have a wide usage as film forming substances with protection characteristics

at anticorrosive paints. Alkyd resins are thermoplastic polyester resins with polybasic acids

or their anhydrides. They are used in making protective coatings with good weathering

properties and are important ingredients in many synthetic paints due to their versatility

and low cost. We are manufacturing oil paints so alkyd resins are use for captive

consumption.

Galaxy Polymers


1.5 PROJECT COST

The proposed project cost will be around Rs.43.70 Lacs. The unit is covered under the

Small Scale Industrial Sector.

Environment Protection and safety systems have also been considered in planning the

Cost Projection. Green belt development, provision of fire extinguishers etc. is also

calculated. The below given table shows the break-up of the proposed project cost.

Table 1.3 Capital Cost Projection

Sr. No. Purpose Proposed Scenario

(Rs. in Lacs) 1. Land 4.20 2. Building 20.00 3. Plant and Machinery 15.00 4. Q.A. Lab set up 1.00 5. Env. Protection & Safety b) Safety Equipment (PPE, fire ext., ventilation, etc.) 2.00 c) Green belt development outer side of the premises 1.50 Total 43.70

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Chapter-2 PROJECT SITE 2.1 PROJECT LOCATION

The project site is located in the village of Lothada of Rajkot district and the site is

obtained N.A. order for general Industry purpose. The certificate confirming the same is

attached as Annexure-1.

Rajkot is very well connected to all the major Indian cities by air, railway and road. A number of

flights operate via the Rajkot Airport. A good network of roads also connect most of the major

cities of Gujarat such as Vadodara, Junagadh, Amreli, Bhavnagar, Jamnagar, Ahmedabad, Surat

etc. Rajkot is a main railway junction of Saurashtra, from where trains to all the major cities of

India

The location of the project site can be identified from the location map shown in Figure-2.1. The

salient features of the location of the project site are presented in the table given below:

Table 2.1 Salient features of the Project Site

Particulars Details Village Lothada Taluka/ Tehsil Rajkot District Rajkot Approx. Geographical positioning Lat: 22°10'36.85"N, Long: 70°50'59.25” E Neighbouring industries Surounding with Foundry units & one food unit Nearest Water body Aji Dam ~9.5 Km-N Nearest Highway NH 27 ~5.5 Km W Nearest Railway line/ Railway station Railway line ~3.72 Km-W,

Kotharia Railway station ~3.72 Km- W Nearest Airport/ Airbase Rajkot ~15 km –NW Protected Areas/ Sanctuaries None within 10 km Seismicity Seismic Zone-III (Moderate)

Galaxy Polymers


Fig- 2.1: Location of the Project Site

1 km Circle(proposed site)

10 Km radius

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2.2 SITE SELECTION

Following points were considered for selection of the site. • Location is well connected with highways, nearby Rajkot. • Own plot & it is suitable for proposed project. • Availability of resources like power supply, water, man power etc. • Closeness to the target market. • There are no ecological sensitive areas located within 10 km radius. • No any national park or wild life sanctuary located within 10 km radius.

2.3 SITE LAYOUT The site layout plan is attached as under:

Galaxy Polymers


Chapter-3 PROCESS TECHNOLOGY

The proposed products details like Process description, chemical reactions and

mass balance for each grade of products are as below.

3.1 REACTION CHEMISTRY

The chemistry principles of resin synthesis are simple. First, an acid/ anhydride react with glycol

to form an ester with release of a water molecule. i.e. The acid/ anhydride group (COOH or CO-

O-CO) reacts with the OH group to form an ester and a water molecule.

Galaxy Polymers


3.2 MANUFACTURING PROCESS

1. Manufacturing Process for Long Oil alkyd Resin

• Charge oil in reactor and start stirring.

• Heat till 1750 – 1800 C.

• Add catalyst and Glycerine and increase temperature up to 2650 – 2700 C.

• Check for clear monoglyceride.

• Cool to 1600 C and add pentaerythritol, xylene and Phthalic Anhydride.

• Start reflux and increase temperature slowly step by step up to 2250 C.

• Check reaction viscosity and acid value.

• Cool to 1300 C and unload the batch in blander.

• Thin down to required solids with mineral turpentine oil (MTO).

• Check for final QC parameters, filter and pack to barrels.

• Reflux water is send to ETP Collection tank.

2. Manufacturing Process for Medium Oil alkyd Resin


• Heat till 1750 – 1800 C.

• Add catalyst and Glycerine , increase temperature up to 2650 – 2700 C.

• Check for clear monoglyceride.

• Cool to 1600 C and add pentaerythritol, xylene and Phthalic Anhydride.

• Start reflux and increase temperature slowly step by step up to 2250 C.






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3. Manufacturing Process for Rosinated Oil alkyd Resin


• Heat till 1250 – 1300 C.

• Add xylene for reflux, pentaerythritol, xylene and Phthalic Anhydride.

• Start reflux and increase temperature up to 2750 C.

• Check reaction viscosity.





4. Manufacturing Process for Fast Drying Chain Stop Alkyd Resin

• Charge Fatty acid in reactor and start stirring.

• Heat till 800– 900 C.

• Add Phthalic Anhydride, pentaerythritol, Benzoic Acid, xylene and catalyst.

• Raise the temperature slowly to 2250 C.



• Thin down to required solids with xylene.



Galaxy Polymers


3.3 MATERIAL BALANCE

Fig – 3.1

Material Balance

1. Long oil alkyd resin Input Kg

Output Kg

Linseed Oil/Soya Oil/Castor Oil

68 Long oil alkyd resin

96

Pentaerythritol 10 Reflux water 04 Glycerine 02 Total 100 Phthalic Anhydride 17 Catalyst 01 Xylene 02 Total 100

2. Medium oil alkyd resin

Input Kg

Output Kg


58 Medium oil alkyd resin

96


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3. Rosinated oil Alkyd resin Input Kg

Output Kg


50 Rosinated oil alkyd resin

96


4. Fast Drying Chain Stop Alkyd Resin Input Kg

Output Kg Soya/DCO fatty acid 40 Fast Drying

Chain stop alkyd resin

96 Pentaerythritol 19 Benzoic acid 18 Phthalic Anhydride 20 Reflux water 04 Catalyst 01 Total 100 Xylene 02 Total 100

Galaxy Polymers


Chapter-4 RESOURCE REQUIREMENTS

The major resources for the project are land, raw-materials, power, fuel and man-power

etc.

4.1 LAND The total plot area is 750 Sq. m. The plot is presently non-agriculture Industrial plot. The break-up of area is provided in Table 4.1.

Table 4.1: Breakup of land

S. No. Description Approximate Area (m2) Approximate Area (%) 1. Buildup area 279.44 37.00 2. Greenbelt 125.00 17.00 3. Open land 346.00 46.00

TOTAL 750.44 100.00

4.2 BUILDING Building will have to be constructed for accommodating the plant & machinery, administrative office. The approximate requirement of construction material for the same is given below:

Table 4.2: Details of Construction Materials

Sr. No.

Construction Material

Quantity

1. Cement 15 MT 2. Bricks/Bela Stone 100 MT 3. Steel, Both Mild & TMT, Sections ISI 10 MT 4. Sand 20 MT 5. Kapachi 25 MT 6. Black Stones 20 MT 7. Gates & grilling (iron) 1 MT

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4.3 EQUIPMENTS

Based on process necessity list of the proposed machinery is shown in the table given

below:

Table 4.3: Details of Equipments

Sr. No. Equipment Capacity Nos. 1. Reactor S.S 1200 Kg 1 2. Blender S.S. 2200 kg 1 3. Cooling Tower 40 lpm 1 4. Thermic Fluid Heater 1 Lakh Kcal/Hr 1

4.4 RAW-MATERIALS

The proposed products are organic chemicals and the required raw materials will be

purchased from the local/ Indian market. Details of raw-material consumption are as

shown in the table given below:

Table 4.4

1. List of Raw Materials-for Long oil Alkyd Resin

Sr. No. Name of Raw material Source MT/Month 1 Linseed Oil/Soya Oil/Castor Oil Local Trader 28 2 Pentaerythritol Local Trader 04 3 Glycerine Local Trader 0.8 4 Phthalic Anhydride Local Trader 6.8 5 Catalyst Local Trader 0.4 6 Xylene Local Trader 0.8

2. List of Raw Materials-for Medium Oil Alkyd Resin


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3. List of Raw Materials-for Rosinated Oil Alkyd Resin


4. List of Raw Materials-for Fast Drying Chain Stop Alkyd Resin

Sr. No. Name of Raw material Source MT/Month 1 Soya/DCO fatty acid Local Trader 16 2 Pentaerythritol Local Trader 7.9 3 Benzoic Acid Local Trader 08 4 Phthalic Anhydride Local Trader 7.8 5 Catalyst Local Trader 0.4 6 Xylene Local Trader 0.8

4.5 POWER AND FUEL Electric power will be sourced from State Electricity Board. LDO will be used as fuel in

Thermic Fluid Heater. The details of the power and fuel requirement are in the table given

below:

Table 4.5 Power and Fuel Requirement

Sr. No. Name Requirement Source 1 LDO 125 L/D Local Traders 2 Energy - Electricity 20 HP PGVCL

4.6 MANPOWER

The manpower required for the project commissioning and operational activities will be

employed from the local area.

Table 4.6 Man Power Requirement

Phase of project Type of labor No. of workers

During operations Managerial/Skilled 2 Un-skilled 2

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4.7 WATER

The category wise bifurcation of the water requirement is given in the table below. There

will be no requirement of water in process. The water requirement will be only for cooling

purpose and domestic use. Moreover, the water of reaction to be generated in process

will be evaporated in the evaporator.

Table 4.7 Category-wise Water Requirement

Particulars L/D Ind. Cooling 100 Process Nil Domestic use 100 TOTAL 200

• For the proposed manufacturing activity the total water consumption will be 200 L/D • From that the domestic water consumption will be 100 L/D • Industrial water consumption for cooling makeup will be 100 L/D.

Rain water Harvesting The source water will be from bore-well. The unit has also proposed to carry rainwater

harvesting in their plant. The total rooftop catchment area will be 279 sq. mt. Hence,

considering the seasonal rainfall in Rajkot District at 800 mm, the groundwater recharge

through rainwater harvesting is estimated as below:

Total rainwater harvested = Catchment area (m2) x Avg.rainfall (m) x efficiency

= 279 x 0.8 x 0.8

= 178 m3 per annum.

The total water requirement per annum will be:

Maximum requirement per annum = Requirement per day (m3) x working days

= 0.2 x 315

= approx. 63 m3 per annum

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Chapter-5 MITIGATION MEASURES & EMP

Based on overall manufacturing & operation activities, the mitigation measures have been

proposed by the company for the control of the anticipated pollution load.

5.1 WASTE WATER MANAGEMENT

5.1.1 Wastewater Generation

The category-wise bifurcation of the anticipated wastewater generation details is given in

Table no. 5.1.

Table 5.1 Category-wise Wastewater Generation

Particulars L/day Industrial Process 80 Industrial Cooling 10 Domestic 100 TOTAL 190

• Total wastewater generation will be 190 L/D • From that 100 L/D Domestic wastewater will goes to soak pit via septic tank. • Industrial wastewater 90 L/D will be evaporated in Evaporator to achieve Zero discharge.

Fig-5.2: Water Balance Diagram (in L/day)

(90 L/D) Evaporator

Fresh Water

(200 L/D)

Domestic (100 L/D)

Cooling

(Fresh-100 L/D)

Process requirement

(Nil)

Septic tank/ soak pit

(100 L/D)

Water of reaction collected by

distillation (80 L/D)

Cooling + Process (10 + 80)=90 L/D

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5.1.2 Wastewater Characteristics

The water of reaction to be generated shall be collected by reflux. The characteristics of

wastewater & final outlet would be as follows:

Parameter pH SS TDS COD Value 6.8-7.5 200 mg/lit. 1500 mg/lit. 700 mg/lit.

5.1.3 Wastewater treatment & disposal

Sr. No. Source Quantity and mode of disposal 1. Domestic sewage 100 L/D of sewage will be discharged to a septic tank and

soak‐pit system. 2. Industrial wastewater 1. Process effluent will be treated in proposed Effluent

Treatment Plant and Finally it will be evaporated. 2. Cooling tower blow down will be treated with process effluent and finally it will be evaporated.

Effluent Treatment Detail For process reflux water we will provide collection cum equalization tank of capacity 200 lit. We will provide Thermic Fluid Evaporator of capacity 50 it./Hr. As we will generate 90 lit./day effluent so evaporator will be sufficient for completely evaporate. Hence there shall be zero discharge of industrial effluent.

Fig-5.3: ETP Diagram

Collection tank Tank 200lit.

Evaporator 50 lit./hr.

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5.2 AIR EMISSIONS & CONTROL

5.2.1 Flue gas emissions

The company will install Thermic Fluid Heater (1 Lakh KCal/ Hr) for the heat requirement in the

process. The details of utility emissions and control measures are in the table given below:

Table no. 5.2

Utility Emissions and Control Measures

Installation Fuel Fuel Cons. Pollution Parameters

Emission rate/ Norms

Air Pollution Control System

TFH (1 Lakh KCal/

Hr)

LDO 125 Lit/day PM < 150 mg/Nm3 Stack Ht.: 11 m

SO2 < 100 ppm NOx < 50 ppm

5.2.2 Process gas emissions There shall be no process gas emissions from the proposed manufacturing activities.

5.2.3 Fugitive emissions

No low boiling materials or fine dust generating materials to be used in the process.

Hence, chances of fugitive emissions are less. Moreover, the process will be carried out in

close condition; chemicals will be handled in a closed manner by pumping or by vacuum

transfer to minimize chances of fugitive emissions. The loading – unloading and charging

shall be done with pumps. The pump glands and piping will be checked regularly to

ensure no leakage.

Work place monitoring will be carried out regularly for work place exposure level

measurement in Form No-37. The manufacturing plant will be in shed which will be open

from both sides and hence natural ventilation will be available.

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5.3 HAZARDOUS/ NON-HAZARDOUS WASTE MANAGEMENT

The following type of hazardous waste will be generated from the operational activities.

All the waste will be stored separately in a designated storage area.

Table 5.3 :Details of Hazardous Waste

Name of the

Waste Physical Prop.

Catg. Quantity Mode of Disposal

Discarded bags/ drums

HDPE/ LDPE 33.3 500 kg/year, 1000 Drums/year

Sale of bags to Reg. Recy. and Drums will be used for

filing of products

In addition to the above, proper management for hazardous waste as below:

Records of waste generation reuse and disposal will be maintained in log book as per the format

of Form-3 as per Hazardous and other Waste (Management and Transboundary Movement)

Rules, 2016.

• Transportation of hazardous waste to the reg. recycler will be governed as per the

guidelines and accompanied with Form-9.

• Annual returns of the disposal of wastes in Form-4 and Form-13 will be submitted

regularly to the local office of the GPCB.

5.4 NOISE CONTROL

No major sources of noise generation other than pumps and motors. Balancing of shaft of

motor and will be done during installation to reduce vibration noise. Regular oiling/

maintenance will be done.

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5.5 STORAGE, HANDLING & TRANSPORT OF HAZ. CHEMICALS

The details of storage and mode of transport of chemicals to be used are provided in the

Table 5.4 and their characteristics are provided in Table no 5.5.

Table 5.4

Storage facility of Raw Materials Sr. No.

Name of Raw Material Container Type

Physical form

At a time storage in MT

Max. Storage Capacity in MT

1. Fatty Acid Drums Liquid 10 15 2. Xylene Drums Liquid 1 2 3. Soya Oil/castor oil Drums Liquid 10 15 4. Glycerin Drums Liquid 3 5 5. Penta(Pentaerythritol) Bags Solid 7 10 6. Benzoic Acid Bags Solid 5 7 7. Phthalic Anhydride Bags Solid 10 15

Following steps will be adopted.

• SOP will be prepared and implemented.

• Proper storage area will be made for separation of incompatible chemicals and material

handling equipments will be used for safe material handling.

• Material issuing procedure will be prepared and implemented as per batch requirement.

• Flame-proof area.

• Flame-proof equipments.

• Proper ventilation.

• Fire fighting equipment.

• PPEs.

• Safety shower, eye wash.

• Drum handling trolley.

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Table 5.5 Characteristics of Raw Materials

1. Fatty Acid

Sr. No. Properties Description 1. Chemical Name : Fatty acid 2. Molecular Weight : ----- 3. Appearance : Liquid Yellow wish brown 4. Flash Point : 185 0C 5. Fire Point : No data available 6. Boiling Point : >300 0C 7. Melting Point : >25 0C 8. Solubility : In Soluble in Cold water 9. Specific Gravity : No data available 10. CAS. No. : 68308-53-2 11. Protective Equipment : Eye Protection-Safety Goggles Hand Protection-

Compatible resistance Gloves Respiratory Protection- Non Required

12. Toxicological Information : 4640 mg/kg 13. Fire Extinguishing Measures : Not Flammable 14. First Aid Measures : Eye contact- check for & removal any contact

lenses immediately flush eye with Plenty of water for at least 15 minute. Occasionally lifting upper & lower eyelids. Get medial attention if symptoms occur. Skin contact-if in case of contact flush skin plenty of water at least 15 minute. While removing contaminated clothes. Wash clothing before reuse. Clean shoes before reuse get medical attention if symptoms occur. Inhalation- move exposed person to fresh air, if not breathing is irregular give artificial respiration or oxygen by trained person. Never give anything by mouth. Loosen tight Clothing such as collar ,tie, belt, get medical attention if symptoms is occur Ingestion-Wash out mouth with fresh water Do not inducing vomiting unless directed to do by medical person. Never give anything by mouth to unconscious person. Get medical attention if symptoms occurs

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2. Xylene

Sr. No. Properties Description 1. Chemical Name : Dimethylbenzene 2. Molecular Weight : 106gm/mole 3. Appearance : Colourless 4. Flash Point : 37.7 °C 5. Fire Point : No data available 6. Boiling Point : 137-140 °C 7. Melting Point : No data available 8. Solubility : Not Soluble 9. Specific Gravity : 0.864 at 20/4 °C (water=1) 10. CAS. No. : 1330-20-7 11. Protective Equipment : Provide approved canister or air supplied mask,

face shield, plastic gloves, boots& apron 12. Toxicological Information : 4300 mg/kg 13. Fire Extinguishing Measures : Co2,Form,Dry chemical Powder 14. First Aid Measures : Inhalation removes the victim to fresh,

Administer artificial respiration or oxygen if necessary. Ingestion- Do not induce vomiting, Skin-Wash the affected area with plenty of water and soap Eyes-Irrigate with plenty of water for 15 mins. Seek medical aid treatment

3. Glycerin

Sr. No. Properties Description 1. Chemical Name : Glycerin 2. Molecular Weight : 92 gm/mole 3. Appearance : Colourless or Yellow 4. Flash Point : 166.5 °C 5. Fire Point : No data available 6. Boiling Point : 290 °C 7. Melting Point : 17.9 °C 8. Solubility : Miscible 9. Specific Gravity : 1.261 at 20 0C 10. CAS. No. : 56-81-5 11. Protective Equipment : Provide rubber gloves and goggles 12. Toxicological Information : 12600 mg/kg 13. Fire Extinguishing Measures : Alcohol Form,Co2,Dry Chemical Powder Water or

form may causes frothing. 14. First Aid Measures : Non-Hazardous

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4. Pentaerythritol

Sr. No. Properties Description 1. Chemical Name : 2,2-bis(hydroxymethayle),1,3 propanediol 2. Molecular Weight : 136.15gm/mole 3. Appearance : Solid 4. Flash Point : No data available 5. Fire Point : No data available 6. Boiling Point : Decomposes 7. Melting Point : 260°C 8. Solubility : Partially Soluble in cold water 9. Specific Gravity : 1.396 ( water=1) 10. CAS. No. : 115-77-5 11. Protective Equipment : Gloves, Lab coat, dust respirator be sure to use

approved or certified respirator or euaivalent, wear appropriate respirator ventilation in adequate, wear safety glasses.

12. Toxicological Information : 18500 mg/kg 13. Fire Extinguishing Measures : Small Fire- Use Dry Chemical Powder. Large Fire-

Use water spary,fog or foam Do not use water jet

14. First Aid Measures : Eye immediately flush eye with running water at least 15 minute, keep eyelids open Cold water may be used. Skin Contact -After contact with skin Immediately wash with plenty of water thoroughly wash contaminated skin with running water and non abrasive soap, cold Water may be used, Cover the irritated with An emollient.if irritation persists, seek medical attention. Inhalation-allow to victim rest at well ventilated area. seek immediately medical attention Ingestion-Do Not Inducing Vomiting, Loosen tight clothing Such as Cooler,tight,belt or waistband, if the victim is not breathing Perform mouth to mouth Resuscitation, Seek immediately medical Attention.

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5. Benzoic Acid

Sr. No. Properties Description 1. Chemical Name : Benzoic acid 2. Molecular Weight : 120 gm/mole 3. Appearance : Colour less to white 4. Flash Point : Data Not available 5. Fire Point : Data Not available 6. Boiling Point : 249 °C 7. Melting Point : 121.7 °C 8. Solubility : Soluble in water at 30 °C 9. Specific Gravity : 1.316at 28 0C(Water=1) 10. CAS. No. : 65-85-0 11. Protective Equipment : Provide dust respirator, Safety goggles, Organic

respirator for fume, hand gloves, body overclothing and shoes.

12. Toxicological Information : 2530 mg/kg 13. Fire Extinguishing Measures : Carbon Dioxide, Dry Chemical Powder, water

Spary mist, 14. First Aid Measures : Inhalation: Remove the victim to fresh air area.

Skin: wash with plenty of water and soap. Eyes: wash with plenty of water for 15 mins. seek medical aid

6. Phthalic Anhydride

Sr. No. Properties Description 1. Chemical Name : Phthalic Anhydride 2. Molecular Weight : 148gm/mole 3. Appearance : White needles 4. Flash Point : 1650C 5. Fire Point : Data Not available 6. Boiling Point : 295 (Sublimes) °C 7. Melting Point : 131.2°C 8. Solubility : Soluble in water at 30 °C 9. Specific Gravity : 1.53 at 20 /4 0C 10. CAS. No. : 85-44-9 11. Protective Equipment : Provide rubber apron, rubber shoes, face shield,

approved vapour respirator, leather or rubber hand gloves

12. Toxicological Information : 4020 mg/kg 13. Fire Extinguishing Measures : CO2, Dry chemical powder. 14. First Aid Measures : Inhalation gargle with water and give sedatives

cough mixure.ingestion- induce Vomiting, give water or milk, skin & eyes-If affected, wash with plenty of water. Seek medical aid

5.6 HEALTH AND SAFETY MEASURES

The likely physical hazards due to handling of hazardous chemicals are identified and

MSDS is uploaded.

Moreover transport activity will be through drums, so there will be manual loading and

unloading and no unloading through pipe at the site. Hence, the risk of static charge

generation during transfer of such chemicals is not significant.

Below mentioned is the summary proposed safety measures to be taken at site for control

of anticipated hazards.

Table 5.6 Summary of Hazards & Proposed Safety Measures

Sr. No.

Activity/ Hazard Mitigation Measures

1. Fire and Toxic hazard during storage and handling of chemicals

• Nearest fire station is at Rajkot @~15Km. • Adequate nos. of fire extinguishers will be installed in the

entire plant area and storage area. • Flame-proof fittings will be provided. • Use of non-sparking tools will be ensured. • De-matching will be practised in the plant and store area. • Proper grounding will be provided to all the reactors/ vessels

and piping to avoid accumulation of a static charge. • PPE like face mask, safety gloves, safety goggles, apron etc.

will be provided to avoid contact with chemicals and their use will be ensured during handling of chemicals.

• Full covered clothing will be ensured to avoid contact with skin • Workers will be advised to remove clothing that has

accidentally become wet or significantly contaminated. • Eyewash fountains and/or quick drench facilities will be

provided near plant area. • Shed will be open on both sides for proper natural ventilation • RM Stores will be covered to avoid contact with direct heat/

sunlight • Storage of chemicals will only be in drums / bags. • At least 10% of the volume of the Container will be left as

vapor space for adequate protection. • Mechanical seals and high quality pressure and temperature

gauges and safety valves to be provided to all reactors. • Transfer/ charging of liquid chemicals will be done by pumps,

29

Sr. No.

Activity/ Hazard Mitigation Measures

wherever possible. • Provision of necessary hoppers will be made for Transfer/

charging of solid material. • In case of accidental spillage of chemical, it will be controlled

with reference to respective MSDS document. • Availability of MSDS will be ensured. • The layout will include provisions for more than one escape

route in the event of an emergency. 2. Reactivity hazard • The process needs temperature upto 2750C. Hence, a provision

of Limpted Coil oil circulation will be made to initiate the reaction, which will then be stopped after a certain time period.

3. Injury hazard during mechanical operations

• All rotary parts viz. motors of pumps, agitators etc. shall be provided proper guarding.

• Use of PPE like safety shoes and helmets will be ensured. • First-aid box will be provided in plant area.

4. Transportation • The hazardous material will be transported only in drums. • Ensure with the suppliers of RM that the drivers are licensed

and trained for safe transportation, spill control and emergency actions.

• Ensure that all containers are pasted with the precaution and indication signs of the material stored within.

5. Maintaining of Health records

• All records shall be maintained as per Factory Act. • Regular Health Check ups shall be done as per Factory Act.

6. Training and competence issues

• Establishing of the Standard operating procedures to ensure safe operations.

• Selected personnel will be identified and trained for fire fighting and providing first aid.

• Regular training will be provided to all employees for first aid and handling of emergency situations.

7. Communication of hazards/ accidents

• Adequate no. of sign boards will be provided in local language. • Emergency telephone nos. will be displayed. • Manual call bells will be provided for communication of

emergency. • Assembly point will be designated.

30

5.7 ENVIRONMENT, HEALTH & SAFETY MANAGEMENT CELL

The company being a small unit, with only 4 nos. of people a small cell will be set up for

fire fighting and safety. Proprietor or Site incharge will be responsible for maintaining

records of all the data, documents and information in line with the statutory

requirements.

5.8 POST PROJECT ENVIRONMENT MONITORING PLAN

The proposed post-project monitoring plan is given below:

Table 5.7

Environmental Monitoring Plan

Component Parameter Frequency Air – Ambient PM2.5, PM10, SO2, NOx Quarterly-Third party

monitoring Stack monitoring TFH stack: PM, SO2, NOx Quarterly-Third party

monitoring Noise monitoring Noise levels in decibels Quarterly-Third party

monitoring Haz. Waste management

Maintaining records of generation, receipt & disposal in Form-3

Daily

Filing of annual returns in Form-4 for haz. Waste handling

Every year by 31st Jan

Maintaining records of transportation in Form-9

While sending for disposal

Submission of returns of used oil in Form-13

Every year by 31st Jan

CC&A Obtaining consent to operate (and renewal) under Air & Water Acts and authorization under HW rules.

Every 5 years or before expiry of validity

Water cess Filing of annual returns for cess incurred on water consumption

Every year by 30th Sept

Environmental Statement

Submission of audit statement in form-V Every year by 30th Sept

Compliance of EC conditions

Submission of compliance reports Half yearly on 1st June & 1st Dec

31

5.9 GREENBELT DEVELOPMENT

We shall develop greenbelt inside & outside the plant. The proposed plantation of species

like Baval, Saptaparni, Limbdo , Silk cotton, Boganvilla , Akhdo, Garmalo, Saru, Coconut

tree , Gulmohar , Eucalyptus, Vad, Umber, Pipal, Pipli ,Gandharaj, Conical & Spherical

Asopalav, Karanj, etc will be undertaken. We shall allocate a budget of Rs. 5000/- per

annum for the development of greenbelt.

5.10 SOCIAL DEVELOPMENT PROGRAMS

The size of the project is small; therefore manpower requirement will also be lesser. The

project will employ 2 numbers of unskilled workers and 2 numbers of

supervisory/managerial personnel. All the manpower will be utilized from local Area.

The company intends to donate 2% of the profit to agencies like NGOs or social welfare

societies for projects carried out in nearby village for their welfare and upliftment.

5.11 BUDGETARY PROVISIONS FOR EHS

The capital cost for EHS system is estimated to be around Rs. 3.5 Lakhs and the provision

of recurring expenditure is Rs. 0.50 Lakhs per annum.

PROJECT PRE-FEASIBILITY REPORT - Welcome to ...environmentclearance.nic.in/writereaddata/FormB/TOR/PFR/...PROJECT PRE-FEASIBILITY REPORT AND ENV. MANAGEMENT PLAN ON PROPOSED PROJECT

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