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    PencemaranPerairan

    Yusli Wardiatno

    Departemen MSPFPIK IPB

    [email protected]

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    Kualitas air adalah karakter (sifat) air yang

    digambarkan oleh nilai-nilai dari berbagai

    macam faktor / karakteristik / komponen

    kualitas air (yang sering disebut sebagaiparameter kualitas air)

    KUALITAS AIR ?

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    Parameter Fisik:

    1. Warna

    2. Kecerahan (kedalaman Secchi)

    3. Kekeruhan

    4. Padatan tersuspensi (TSS)5. Padatan terlarut (TDS)

    6. Daya Hantar Listrik (conductivity)

    7. Temperatur

    8. Bau

    9. Rasa

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    Parameter Kimia:

    1. Salinitas

    2. Alkalinitas3. Kesadahan

    4. pH

    5. Oksigen terlarut (DO)

    6. BOD

    7. COD8. N (Amonia, Nitrat, Nitrit)

    9. P (total, Orthophosphate)

    10. Si

    11. Deterjen (surfactant)12. Minyak & lemak, hidrokarbon

    13. CN (sianida)

    14. H2S (sulfida)

    15. Phenols

    16. Fe (besi)17. Pestisida (organochlorine,

    organophosphate)

    18. Logam/logam berat: Hg

    Pb Cu

    Cd

    Cr+6

    Zn As

    Ni

    Se

    dll.

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    Parameter Mikrobiologi:

    1. Coliform

    2. Fecal coliform (E. coli)

    3. Bakteri pathogen: SalmonellaShigella dysenteriaeVibrio cholerae

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    Parameter Fisik: Parameter Kimia: Ket.

    1. Warna 1. Salinitas Kenyamanan

    2. Kecerahan (kedalaman Secchi) 2. Alkalinitas

    3. Kekeruhan 3. Kesadahan4. Padatan tersuspensi (TSS) 4. pH Kenyamanan

    5. Padatan terlarut (TDS) 5. Oksigen terlarut (D.O.) Nutrien

    6. Daya Hantar Listrik (conductivity) 6. BOD

    7. Temperatur 7. COD

    8. Bau 8. Ammonia Nitrat, Nitrit (N) Nutrien, Nuiss.

    9. Rasa 9. P (total, orthophosphate) Nutrien10. Si Nutrien

    11. Deterjen (surfaktan) Nuissance

    Parameter Mikrobiologi: 12. Minyak & Lemak, Hydrocarbon Nuissance

    1. Coliform 13. CN (sianida) Toxic

    2. Fecal coliform (E. coli) 14. H2S (sulfida) Toxic

    3. Bakteri pathogen lainnya.. (Salmonella, 15. Phenol Nuissance

    Shigella dysenteriae, Vibrio cholerae) 16. Fe (Besi)

    17. Logam berat: Hg, Pb, Cu, Cd, Cr6+,Zn, As, Se, Ni, dll.

    Toxic

    18. Pestisida (organokhlorin, organofosfat) Toxic

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    PARAMETER KUNCI

    fungsi perairan

    potensi pencemaran (jenis kegiatan, limbah)

    Baku mutu perairan

    sungai, danau, waduk

    laut

    Baku mutu air limbahsesuai jenis industri/

    kegiatan

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    KEP-51/MENLH/10/1995Baku Mutu Limbah Cair Kegiatan Industri

    KEP-52/MENLH/10/1995Baku Mutu Limbah Cair Kegiatan Perhotelan

    KEP-58/MENLH/12/1995Baku Mutu Limbah Cair Kegiatan Rumah Sakit.

    Sebagai acuan penentuan Parameter kunci :

    Industri soda kostik

    pelapisan logam

    penyamakan kulit

    minyak sawit

    pulp dan kertas

    karet

    gula

    tapioka

    tekstil

    pupuk urea

    ethanol

    MSG

    kayu lapis

    susu & mds

    minuman ringan

    sabun, deterjen & prod.

    minyak nabati

    industri bir

    baterai kering

    industri cat

    industri farmasi

    industri pestisida

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    KEP-51/MENLH/10/1995 Baku Mutu Limbah Cair Kegiatan

    Industri,

    KEP-52/MENLH/10/1995 Baku Mutu Limbah Cair KegiatanPerhotelan,

    KEP-58/MENLH/12/1995 Baku Mutu Limbah Cair Kegiatan

    Rumah Sakit, KEP-42/MENLH/10/1996 - Baku Mutu Limbah Cair kegiatan

    minyak dan gas serta panas bumi,

    Kep. MENLH No. 112 Tahun 2003 - Baku Mutu Air LimbahDomestik,

    Kep. MENLH No. 113 Tahun 2003 - Baku mutu air limbahkegiatan pertambangan batu bara.

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    Kep. MENLH No. 112 Tahun 2003:

    Baku Mutu Air Limbah Domestik

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    Industri/

    Kegiatan:

    Pen.

    kulit

    Miny.

    sawit

    Pulp

    krtas

    Ka-

    ret

    Gu-

    la

    Tapi

    oka

    Tek

    stil

    Pu-

    puk

    Eta-

    nol

    MS

    G

    Kayu

    lapis

    Susu

    &mds

    Soft

    drink

    Bir

    BOD l l l l l l l l l l l l lCOD l l l l l l l l l l l l lpH l l l l l l l l l l l l l l

    TSS l l l l l l l l l l l l l lMinyak-lemak l l l l l l

    Amonia l l l lPhenol l

    l

    Sulfida l l l lN total l l l lCyanida lCr l

    l

    Parameter dalam baku mutu air limbah berbagai industri ataukegiatan sesuai SK MENLH (1995, 1996, 2003)

    Sigid Hariyadi08

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    Parameter

    dalam bakumutu airlimbahberbagaiindustriataukegiatansesuai SKMENLH(1995, 1996,2003)

    Industri/Kegiatan:

    Sabund&mn

    Drycell

    Cat Farmsi

    Psti-sida

    Soda/ Cl2

    Plpslogam

    Ho-tel

    RS Mi-gas

    LNG Panasbumi

    Batubara

    Domestik

    BOD l l l l l l l lCOD l l l l l l lpH l l l l l l l l l l l l l lTSS l l l l l l l l l l lMinyak-lemak

    l l l l l l lAmonia l l l l lPhenol l l l lSulfida lN total lCyanida l lCr l l l lCu l l l lHg l l l lPb l l lCd l lNi l l lZn

    l l l lBenzene lToluene lBahanaktif l l H2S Fe

    PO4 Mn Ti Cl2 Cl2 As MnColiform, PO3-,radioaktifitas lTemperatur l l lSigid Hariyadi08

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    PERATURAN PEMERINTAH (PP) RI No. 82 Th. 2001TENTANG

    PENGELOLAAN KUALITAS AIR DAN PENGENDALIAN PENCEMARAN

    a. KELAS I: air peruntukan air baku air minum

    b. KELAS II: air peruntukan prasarana/sarana rekreasi air,budidaya ikan air tawar, peternakan,

    pengairan tanaman (pertanian)

    c. KELAS III: air peruntukan budidaya ikanair tawar,

    peternakan, pengairan tanaman (pertanian)

    d. KELAS IV: air untuk pengairantanaman (pertanian)

    KLASIFIKASI MUTU AIR (PASAL 8 ayat 1):

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    Keputusan MENLH No. 51 Tahun 2004ttgBAKU MUTU AIR LAUT

    Baku Mutu Air Laut untuk PERAIRAN PELABUHAN

    Baku Mutu Air Laut untuk WISATA BAHARI

    Baku Mutu Air Laut untuk BIOTA LAUT

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    BAKU MUTU AIR :

    KADAR / KONSENTRASI (mg/L)

    BEBAN (kg/ton produk ; g/m3)

    BOD = 20 mg/LDebit aliran = 10 L/dt

    Beban BOD = 20 mg/L x 10 L/dt = 200 mg/dt= 200 x 60 x 60 x 24

    = 17.280.000 mg/hari

    = 17,28 kg/hari

    Beban BOD = 100 mg/L x 20 m3/ton

    = 100 mg/L x 20.000 L/ton

    = 2000.000 mg/ton

    = 2 kg/ton produk

    BOD = 100 mg/L

    Vol limbah maks= 20 m3/ton

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    What is pollutionPollutionis the introduction by man, directly or indirectly,of substances or energy, to the aquatic environmentresulting in such deleterious effects as harm to living

    resources; hazard to human health; hindrance of aquatic

    activities including fishing; impairment of the quality for use

    of seawater; and reduction of ammenities.

    Contaminationis the presence of elevated concentrations of

    substances in the water, sediments or organisms, i.e.

    concentrations that are above the natural background level for

    the area and for the organism.

    United Nations Group of Experts on the Scientific Aspectsof Marine Polution GESAMP)

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    Non point Source :sources of water pollution that arescatteredor diffuse, not having a specific location.(i.e. from: farm fields, golf courses, cities,

    residentials, roads, clearcut forests, plantations,mines).

    Point Source : discharge of pollutants from single point.(i.e. from: factories, power plants, sewagetreatment plants, oil wells).

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    Watershed Map

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    The simple definition:

    It's the area of land that catches rain and

    snow and drains or seeps into a marsh,

    stream, river, lake or groundwater.

    What is a Watershed?

    Watershed = catchment area = daerah aliran sungai (DAS)

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    the ability of a body of water to cleanse itself;its capacity to receive waste waters or toxic

    assimilative capacity:

    materials without deleterious effects andwithout damage to aquatic life or humanswho consume the water

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    lasifikasi limbah(Clark, 1986):

    1. Limbah mudah urai(degradable wastes)

    2. Limbah mudah luruh(dissipating wastes)3. Partikel (particulate)

    4. Limbah konservatif/awet(conservative wastes)

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    1 . Limbah mudah urai(degradable wastes)limbah organikdekomposisi (CO2, NH3)

    limbah domestik, perkotaan

    limbah pertanian, pabrik gula, kertas (pulp) limbah pengolahan makanan, minuman minyak, dll.

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    2. Limbah mudah luruh(dissipating wastes) dgn cepat kehilangan daya rusak/racun begitu

    masuk ke perairan

    panas: faktor debit, arus

    asam-basa: laut punya kapasitas buffer yang besar

    Cyanide: terdissosiasi dgn cepat di air laut, dampak kecil

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    3. Partikel (particulate)

    debu/partikel lumpur/tanah, penambangan pasir

    abu sisa pembakaran (batubara)

    plastik

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    4. Limbah konservatif/awet(conservative wastes)tidak dapat terdekomposisi & tidak hilang/luruh

    logam berat

    halogenated hydrocarbons (pestisida, PCB, POPS)

    radioaktifitas

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    Infectious Agents (pathogens, parasites, bacteria, virus, etc.) Oxygen-Demanding Wastes (BOD, sampah) Inorganic Chemicals (acids, salts, toxic metals, nutrients) Organic Chemicals (pesticides, PCB, dioxin, oil, detergents,

    plastics)

    Sediment Particulates) Thermal Pollution Radioactive Pollution Oil Pollution, Detergents, etc.)

    Other classification of Pollution Types:

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    OXYGEN-DEMANDING WASTES

    Examples: Organic waste such as animal manure andplant debris that can be decomposed by aerobic(oxygen-requiring) bacteria

    Major Human Sources: Sewage, animal feedlots,paper mills, and food processing facilities

    Harmful Effects: Large populations of bacteria

    decomposing these wastes can degrade water qualityby depleting water of dissolved oxygen. This causesfish and other forms of oxygen-consuming aquatic lifeto die.

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    Pollution of Streams Oxygen sag curve Factors influencing recovery: flow

    rates and amount of pollutants

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    Ocean Pollution Sources

    Fig. 22-11 p. 504

    C S d Ch k B

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    Case Study: Chesapeake Bay

    Largest US estuary

    Relativelyshallow

    Slow flushingaction to Atlantic

    (1% of waste is

    flushed into Atlantic

    Major problems withdissolved O2 due to

    eutrophication (NO3

    and P04)

    Fallen oyster, crabsand fish harvest due

    to pollution,

    overfishing and

    diseases

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    Referensi

    5. http://homepage.mac.com/wsscott/Planbook/Environmental%20Studies/Nov132007/4-24-2003.ppt

    Water Pollution6. http://facstaff.gpc.edu/~apennima/ENVS/Water-Pollution.ppt Water Pollution & Cleanup

    1. APHA. 2005. Standard methods for the examination of water and wastewater. 21st

    ed. American Public Health Association, American Water Works Association and

    Water Pollution Control Federation. Washington D.C.

    2. CLARK, R.B. 1986. Marine Pollution. Clarendon Press, Oxford. 215 p.

    3. LAWS, E.A. 1993. Aquatic Pollution : An introductory text. Wiley Interscience,New York. 611p.

    4. MASON, C.F. 1991. Biology of freshwater pollution. 2nd ed. Longman Scientific &

    Technical, Essex, U.K. 351 p.

    7. COASTAL POLLUTION: Effects on L iving Resources and Humans (pdf),

    by: Carl J. Sindermann (2006)

    http://homepage.mac.com/wsscott/Planbook/Environmental%20Studies/Nov132007/4-24-2003.ppthttp://facstaff.gpc.edu/~apennima/ENVS/Water-Pollution.ppthttp://facstaff.gpc.edu/~apennima/ENVS/Water-Pollution.ppthttp://facstaff.gpc.edu/~apennima/ENVS/Water-Pollution.ppthttp://facstaff.gpc.edu/~apennima/ENVS/Water-Pollution.ppthttp://homepage.mac.com/wsscott/Planbook/Environmental%20Studies/Nov132007/4-24-2003.ppthttp://homepage.mac.com/wsscott/Planbook/Environmental%20Studies/Nov132007/4-24-2003.ppthttp://homepage.mac.com/wsscott/Planbook/Environmental%20Studies/Nov132007/4-24-2003.ppthttp://homepage.mac.com/wsscott/Planbook/Environmental%20Studies/Nov132007/4-24-2003.ppthttp://homepage.mac.com/wsscott/Planbook/Environmental%20Studies/Nov132007/4-24-2003.ppt