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Oil Technics FOR THE OIL RECYCLING INDUSTRY Oil Contamination Solutions
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Oil Technics Ltd(OTL):Demulsifers.

Jan 18, 2015

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OTL: If you are involved with waste oil treatments we may have the product for you?

OTL have been manufacturing and supplying waste oil treatment product solutions for over 20 years.
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Page 1: Oil Technics Ltd(OTL):Demulsifers.

OilTechnicsF O R T H E O I L R E C Y C L I N G I N D U S T R Y

Oily Water SeparatorsBio TubesAn astonishingly simple biological product that will reduce separatoroil discharges by up to 95%

Place an oil absorbing biologically active Bio Tube in youroily water separator and you have a workforce of millions onyour side.Each Bio Tube contains a blend of naturally occurring oilspecific bacteria that will digest their way through up to 2kg ofoil a week – every week.• Environmentally Friendly• Digests free surface oil releasing merely harmless CO2 andWater.

• The biological solution that reduces oil discharges fromoily water separators by up to 95%.

• Maintenance free and helps reduce clean out costs

European Approvals• Tested by the UK Environmental Agency with the conclusionthat: Bio Tubes digest up to 95% of diesel oil withoutany harmful or toxic bi-products.

• Tested by the Swiss Federal Laboratories on a 1:1 mix oflube oil/diesel in water and found that: Bio Tubesexceeded the Swiss oil degradation target of 30 daysby 60%.

• Tested by a major European Forecourt chain and foundthat: Bio Tubes reduce oil discharges from an averageof 500mg/Ltr to 19 mg/Ltr – a reduction of +95%.

Application - For use in industrial separators, bunds andoily water run offs.Simply place one Bio Tube in second chamber, place 2Bio Tubes in third chamber and replace every 6-8 months.

Manufactured by Oil Technics LtdWEBwww.oilbio.com

eShopwww.oilbio.com/shop

ENGLAND & WALESThe CroftAbbots WalkStaffordEngland UK ST16 3BN

Tel: +44 (0) 1785 222970Fax: +44 (0) 1785 225519

[email protected]

SCOTLAND & EXPORTLinton Business ParkGourdonAberdeenshireScotland UK DD10 0NH

Tel: +44 (0) 1561 361515Fax: +44 (0) 1561 361001

[email protected]

Oil Contamination Solutions

For further details, please visitwww.bio-tubes.com

Page 2: Oil Technics Ltd(OTL):Demulsifers.

Waste oil emulsions are simplymixtures of two “un-mixable” liquidsusually oil and water.

Typically emulsions contains three phases:

• The Dispersed Phase - Consisting of very smalluncoalesced droplets.

• The Continuous Phase - Which keeps thedroplets in suspension.

• The Interphase - Which binds the dispersedand continuous phasestogether.

Oil Treatment chemicals are designed to separate thesephases.

They do this by first making the emulsion unstable, thencoalescing together the individual water (or oil droplets)to form three continuous phases.

The best oil treatment chemical is the one that releasesfrom the emulsion the most free oil, water and solidsand has the least Interphase.

How to select a demulsifier using either the “Bottle” Test or a “Centrifuge” Test:

Equipment required: • Water Bath • 4 x 1L Graduated Tubes • 1ml Syringe

• Shake the emulsion sample vigorously, fill each tube and heat to 60°C.• Inject 2000 ppm of a range of selected demulsifiers leaving one tube as the “Control”. Shake each tubevigorously for 20 seconds in a horizontal and vertical direction and replace in the water bath at 70°C.

• Note the amount of free water, released oil and interphase produced in each sample and compare withthe BS & W obtained from a Dean and Stark analysis of the sample.

1. Bottle Test

Equipment required: • Centrifuge • 4 x 10ml Graduated Tubes

• Heat the oil sample to 60°C shake vigorously and pour into each centrifuge tube. Leaving one tube as thecontrol apply one drop from a range of demulsifiers to each tube and centrifuge for 10 minutes.Choose the solution which gives the best free water, solids, oil separation and least interphase.• The Centrifuge Test is more often used by operators who stream their waste oil emulsions and havedemulsifier experience.

2. Centrifuge Test

Waste Oil Treatment Chemicals Absorbents

@ For more information, please visit these websites:www.oilpads.eu www.spillkit.eu

Oil Pads With The New MAXX TechnologyAbsorb up to 24 X their weight in oil – the most absorbentpad per kilogram on the market. With MAXX technologyless material is needed to pick up the same amount of oil,which results in lower disposal costs!Ideal for environmental and industrial applications wherelow costs and high absorbency are required.

Dispense-N-Dispose

A clever idea… Dispense and Dispose.

Dispenser Box for easy access to the sorbents.Disposal box and bags for easy off site removal of oilywaste.

Dispense-N-Dispose150 Oil or Maintenance Pads per box - 41cm x 51cm

1 2 3 4

5 6 7 8

Products

1 Oil & Chemical Pads

2 Oil Booms

3 SOCS

4 Spill Kits

5 Containment Products

6 Bilge Booms

7 Drain Covers

8 Spill Barrier

A sample of absorbents available from our websites

Oil Technics offers spill contractors an ex-stock range of pads, rolls, socs andbooms together with Spill Kits and oil containment products.

To view our full range, see our websites: www.oilpads.eu www.spillkit.eu

Page 3: Oil Technics Ltd(OTL):Demulsifers.

Oil DegreasersOil Technics manufacture a wide range of environmentally friendly, aqueous,solvent and biological oil degreasers.To view our full range please see our web site: www.degreasers.eu

Bio LF – Biological DegreaserA new concept in Industrial Degreasing. A Biological rich cleanerthat digests it’s own oily wash water!Bio LF is designed for use where oil discharges to separators isof concern.Containing oil specific bacteria designed to degrade oilcontamination, Bio LF when used together with our separatorBio Tubes (see last page), reduces oil effluent discharges byup to 95%.Bio LF is Separator Friendly and ideal for cleaning workshopfloors, yards, vehicles and for replacing paraffin or solvents inheated Parts Washers. Hazard label free when diluted 1:1.

Sobo Power – Aqueous DegreaserA truly general purpose aqueous heavy duty degreaser.Ideal for degreasing of components, work shop floors,industrial floors and similar areas contaminated by oil and grease.Sobo Power is also an excellent choice for steam cleaning vehiclesand oil tankers.Registered in Germany (UBA) as an environmentally acceptablechemical.Hazard label free when diluted greater than 1:5.

Application – For use in steam cleaners at a dilution from1:25 to 1:100 depending upon soiling.

Lemsolv Industrial– Solvent Degreaser

A highly efficient citrus based solvent degreaser for the removalof heavy oil, wax, asphaltines and bitumen emulsions.Lemsolv Industrial is water rinseable, biodegradable andseparator friendly. Apply undiluted to the oil contamination allowa contact time of 5-10 minutes and rinse clean. Can also be usedas a dip, spray or immersion solvent degreaser.

Sobo S Gold – Marine Use

An oil detergent that is approved toHOCNS (Gold Standard) for use incontrolled watersMeets EN858 and registered inGermany (UBA) as an environmentallyacceptable chemical.Danish Approval (1684-205).

For moreinformation,please visit:

www.degreasers.eu

@

Oil Treatment Chemicals can be either:• Demulsifiers used in treating water in oil emulsions (W/O)

• Reverse Demulsifiers used in treating oil in water emulsifiers (O/W).

Oil emulsions vary considerably and Oil Technics has a wide range of Demulsifiers and Reverse Demulsifiers to treatmost emulsions. We offer a free waste oil laboratory Demulsifier selection service.Below are listed some of those most frequently used waste oil chemical treatments.

Demulsifiers – For Waste Oil Emulsions

OT775 – De-Ashing DemulsifierFor use in treating lube oil emulsions containing oil, water and heavy metals (ash). OT 775 is a De-Ashing demulsifierdesigned to typically reduce the Ash content of treated emulsions by up to 80–90%.Note – This is a two part process using demulsifier OT 775 together with Sulphuric Acid.It is important to use OT775 with treatment tanks that have a corrosion resistant construction.

OT2456– Garage Oil DemulsifierDesigned to phase separate waste garage oil emulsions.

OT2375 – Centrifuge Aid and Ship Ballast DemulsifierDesigned to phase separate low sulphur fuel oils.

OT99 – High Water Content DemulsifierDesigned to phase separate high water content waste oil emulsions.

@ For more information, please visitwww.demulsifiers.eu

Reverse Demulsifiers – Water in Oil Emulsions

WT507 – Oil “Polishing” Reverse DemulsifierDesigned to separate, at ambient temperatures, light oil in water emulsions.

WT525 – Coolant Oil Reverse DemulsifierDesigned to separate, at ambient temperatures, waste cutting oil and coolant emulsions.

Oily Sludge Emulsions – Tank bottoms

WT620/OS88 – De-oiling SludgesCombined sludge demulsifier with water treatment agent especially designed for separating tank bottoms, crude oiland refinery oil sludges.

Oil Dispersant – Marine Application

Disperse 1040Type 2/3 oil slick dispersant. Dilute with water for aerial spraying or use as a concentrate on beach or rocks.

Page 4: Oil Technics Ltd(OTL):Demulsifers.

Application - Water wet the oil stain. Shake OT8 prior to use(to put the bacteria into suspension) and pour over the oilstains. Brush in vigourously until the liquid changes colourfrom white to a dark brown. Leave in place for 15-20 minutesand rinse off for an oil free surface.

Oil BioremediationAll of the products shown have been designed to handle oil contaminationfrom Diesel to Heavy Fuel Oil.

• Tested in the UK by the Environmental Agency (England) and found toproduce no harmful or toxic biproducts.• Tested by the Swiss Federal Laboratories and found to exceed by +60% thedegradation result required under OECO 301F.

The bacteria used in these products are classified in Europe as Type 1 i.e. unlikely to cause infection.

Oil contaminated gravel, stones and top soil

For those familiar with bioremediation composting our drypowder bacteria, S-Oil Treat is the composting bacteria ofchoice.With a bacterial count of 4 x 109 cfu/ml and anapplication rate as low as 0.25 kg per metre cube ofcontaminated soil.

The photo shows the bio remediation by composting of apipeline spill in The Oman. S-Oil Treat was applied to30,000 tonnes of oil contaminated soil achieving a 99%reduction in Total Hydrocarbons and Polycylic Aromatics(see website www.oilbio.com for full report).Oil contaminated soil

Cleaning road spills

Road Bio is an oil spill detergent that removes hydrocarbon,greases and liquid paint spills from Road Surfaces.Containing a blend of biodegradable cleaning surfactantsRoad Bio cleans spills on roads without causing an emulsionor contributing to surface erosion.

Bio Gel – Oil Contaminated Gravel

S-Oil Treat – Oil Contaminated Soil

Road Bio – Oil Contaminated Roads

European Approvals:German UBA (No 3406-0025) - An environmentally acceptablecleaning chemical.

Dutch Rijkwaterstaat - Awarded highest overall marks for cleaningefficiency road erosion, environmental impact, cost and dilution.

Shipping oil contaminated stones and gravel to landfill isexpensive. Bio Gel removes oil in situ.It is a biological solution that is simply poured over the oilcontaminated stones or gravel and left to digest.Stir thoroughly before application, spread lightly over theoil using a soft brush and leave for 2-3 weeks (1-2 weeks inhot climates). Turn over the treated upper area using a forkand re-apply to achieve a totally oil free surface. Suitablefor use in the bioremediation of oil storage areas, tankbunds, transformer footings and railway lines, etc.

OT8

Used by Industrial contractors in cleaning refineries,forecourts, oil pipes, oil storage depots and by the general publicfor removing oil stains from hard surfaces.

OT8 is our flagship biogical chemical with sales to cleaningprofessionals in Europe, Australia and the Middle East for over15 years.

@ For more information, please visitwww.oilbio.com

Biological Oil Stain Remover for Hard Surfaces

Before

After

Bio TA

Oil Stains on Tarmac and Asphalt roads canquickly erode and break down surfacestructures.

The solution is to degrade the oil stain usingBio TA, a biological oil stain remover that rapidlyremoves and digests oil contamination.Will not erode or degrade Tarmac or Asphaltsurfaces.

Biological Oil Stain Remover for Tarmac andAsphalt Surfaces

Application - To apply Bio TA shake thecontainer vigorously before application(to put the liquid bacteria into suspension).Water wet the oil stain and apply Bio TAneat to the oil stain, brush in and leave for15-20 minutes before water rinsing clean.

Page 5: Oil Technics Ltd(OTL):Demulsifers.

Application - Water wet the oil stain. Shake OT8 prior to use(to put the bacteria into suspension) and pour over the oilstains. Brush in vigourously until the liquid changes colourfrom white to a dark brown. Leave in place for 15-20 minutesand rinse off for an oil free surface.

Oil BioremediationAll of the products shown have been designed to handle oil contaminationfrom Diesel to Heavy Fuel Oil.

• Tested in the UK by the Environmental Agency (England) and found toproduce no harmful or toxic biproducts.• Tested by the Swiss Federal Laboratories and found to exceed by +60% thedegradation result required under OECO 301F.

The bacteria used in these products are classified in Europe as Type 1 i.e. unlikely to cause infection.

Oil contaminated gravel, stones and top soil

For those familiar with bioremediation composting our drypowder bacteria, S-Oil Treat is the composting bacteria ofchoice.With a bacterial count of 4 x 109 cfu/ml and anapplication rate as low as 0.25 kg per metre cube ofcontaminated soil.

The photo shows the bio remediation by composting of apipeline spill in The Oman. S-Oil Treat was applied to30,000 tonnes of oil contaminated soil achieving a 99%reduction in Total Hydrocarbons and Polycylic Aromatics(see website www.oilbio.com for full report).Oil contaminated soil

Cleaning road spills

Road Bio is an oil spill detergent that removes hydrocarbon,greases and liquid paint spills from Road Surfaces.Containing a blend of biodegradable cleaning surfactantsRoad Bio cleans spills on roads without causing an emulsionor contributing to surface erosion.

Bio Gel – Oil Contaminated Gravel

S-Oil Treat – Oil Contaminated Soil

Road Bio – Oil Contaminated Roads

European Approvals:German UBA (No 3406-0025) - An environmentally acceptablecleaning chemical.

Dutch Rijkwaterstaat - Awarded highest overall marks for cleaningefficiency road erosion, environmental impact, cost and dilution.

Shipping oil contaminated stones and gravel to landfill isexpensive. Bio Gel removes oil in situ.It is a biological solution that is simply poured over the oilcontaminated stones or gravel and left to digest.Stir thoroughly before application, spread lightly over theoil using a soft brush and leave for 2-3 weeks (1-2 weeks inhot climates). Turn over the treated upper area using a forkand re-apply to achieve a totally oil free surface. Suitablefor use in the bioremediation of oil storage areas, tankbunds, transformer footings and railway lines, etc.

OT8

Used by Industrial contractors in cleaning refineries,forecourts, oil pipes, oil storage depots and by the general publicfor removing oil stains from hard surfaces.

OT8 is our flagship biogical chemical with sales to cleaningprofessionals in Europe, Australia and the Middle East for over15 years.

@ For more information, please visitwww.oilbio.com

Biological Oil Stain Remover for Hard Surfaces

Before

After

Bio TA

Oil Stains on Tarmac and Asphalt roads canquickly erode and break down surfacestructures.

The solution is to degrade the oil stain usingBio TA, a biological oil stain remover that rapidlyremoves and digests oil contamination.Will not erode or degrade Tarmac or Asphaltsurfaces.

Biological Oil Stain Remover for Tarmac andAsphalt Surfaces

Application - To apply Bio TA shake thecontainer vigorously before application(to put the liquid bacteria into suspension).Water wet the oil stain and apply Bio TAneat to the oil stain, brush in and leave for15-20 minutes before water rinsing clean.

Page 6: Oil Technics Ltd(OTL):Demulsifers.

Oil DegreasersOil Technics manufacture a wide range of environmentally friendly, aqueous,solvent and biological oil degreasers.To view our full range please see our web site: www.degreasers.eu

Bio LF – Biological DegreaserA new concept in Industrial Degreasing. A Biological rich cleanerthat digests it’s own oily wash water!Bio LF is designed for use where oil discharges to separators isof concern.Containing oil specific bacteria designed to degrade oilcontamination, Bio LF when used together with our separatorBio Tubes (see last page), reduces oil effluent discharges byup to 95%.Bio LF is Separator Friendly and ideal for cleaning workshopfloors, yards, vehicles and for replacing paraffin or solvents inheated Parts Washers. Hazard label free when diluted 1:1.

Sobo Power – Aqueous DegreaserA truly general purpose aqueous heavy duty degreaser.Ideal for degreasing of components, work shop floors,industrial floors and similar areas contaminated by oil and grease.Sobo Power is also an excellent choice for steam cleaning vehiclesand oil tankers.Registered in Germany (UBA) as an environmentally acceptablechemical.Hazard label free when diluted greater than 1:5.

Application – For use in steam cleaners at a dilution from1:25 to 1:100 depending upon soiling.

Lemsolv Industrial– Solvent Degreaser

A highly efficient citrus based solvent degreaser for the removalof heavy oil, wax, asphaltines and bitumen emulsions.Lemsolv Industrial is water rinseable, biodegradable andseparator friendly. Apply undiluted to the oil contamination allowa contact time of 5-10 minutes and rinse clean. Can also be usedas a dip, spray or immersion solvent degreaser.

Sobo S Gold – Marine Use

An oil detergent that is approved toHOCNS (Gold Standard) for use incontrolled watersMeets EN858 and registered inGermany (UBA) as an environmentallyacceptable chemical.Danish Approval (1684-205).

For moreinformation,please visit:

www.degreasers.eu

@

Oil Treatment Chemicals can be either:• Demulsifiers used in treating water in oil emulsions (W/O)

• Reverse Demulsifiers used in treating oil in water emulsifiers (O/W).

Oil emulsions vary considerably and Oil Technics has a wide range of Demulsifiers and Reverse Demulsifiers to treatmost emulsions. We offer a free waste oil laboratory Demulsifier selection service.Below are listed some of those most frequently used waste oil chemical treatments.

Demulsifiers – For Waste Oil Emulsions

OT775 – De-Ashing DemulsifierFor use in treating lube oil emulsions containing oil, water and heavy metals (ash). OT 775 is a De-Ashing demulsifierdesigned to typically reduce the Ash content of treated emulsions by up to 80–90%.Note – This is a two part process using demulsifier OT 775 together with Sulphuric Acid.It is important to use OT775 with treatment tanks that have a corrosion resistant construction.

OT2456– Garage Oil DemulsifierDesigned to phase separate waste garage oil emulsions.

OT2375 – Centrifuge Aid and Ship Ballast DemulsifierDesigned to phase separate low sulphur fuel oils.

OT99 – High Water Content DemulsifierDesigned to phase separate high water content waste oil emulsions.

@ For more information, please visitwww.demulsifiers.eu

Reverse Demulsifiers – Water in Oil Emulsions

WT507 – Oil “Polishing” Reverse DemulsifierDesigned to separate, at ambient temperatures, light oil in water emulsions.

WT525 – Coolant Oil Reverse DemulsifierDesigned to separate, at ambient temperatures, waste cutting oil and coolant emulsions.

Oily Sludge Emulsions – Tank bottoms

WT620/OS88 – De-oiling SludgesCombined sludge demulsifier with water treatment agent especially designed for separating tank bottoms, crude oiland refinery oil sludges.

Oil Dispersant – Marine Application

Disperse 1040Type 2/3 oil slick dispersant. Dilute with water for aerial spraying or use as a concentrate on beach or rocks.

Page 7: Oil Technics Ltd(OTL):Demulsifers.

Waste oil emulsions are simplymixtures of two “un-mixable” liquidsusually oil and water.

Typically emulsions contains three phases:

• The Dispersed Phase - Consisting of very smalluncoalesced droplets.

• The Continuous Phase - Which keeps thedroplets in suspension.

• The Interphase - Which binds the dispersedand continuous phasestogether.

Oil Treatment chemicals are designed to separate thesephases.

They do this by first making the emulsion unstable, thencoalescing together the individual water (or oil droplets)to form three continuous phases.

The best oil treatment chemical is the one that releasesfrom the emulsion the most free oil, water and solidsand has the least Interphase.

How to select a demulsifier using either the “Bottle” Test or a “Centrifuge” Test:

Equipment required: • Water Bath • 4 x 1L Graduated Tubes • 1ml Syringe

• Shake the emulsion sample vigorously, fill each tube and heat to 60°C.• Inject 2000 ppm of a range of selected demulsifiers leaving one tube as the “Control”. Shake each tubevigorously for 20 seconds in a horizontal and vertical direction and replace in the water bath at 70°C.

• Note the amount of free water, released oil and interphase produced in each sample and compare withthe BS & W obtained from a Dean and Stark analysis of the sample.

1. Bottle Test

Equipment required: • Centrifuge • 4 x 10ml Graduated Tubes

• Heat the oil sample to 60°C shake vigorously and pour into each centrifuge tube. Leaving one tube as thecontrol apply one drop from a range of demulsifiers to each tube and centrifuge for 10 minutes.Choose the solution which gives the best free water, solids, oil separation and least interphase.• The Centrifuge Test is more often used by operators who stream their waste oil emulsions and havedemulsifier experience.

2. Centrifuge Test

Waste Oil Treatment Chemicals Absorbents

@ For more information, please visit these websites:www.oilpads.eu www.spillkit.eu

Oil Pads With The New MAXX TechnologyAbsorb up to 24 X their weight in oil – the most absorbentpad per kilogram on the market. With MAXX technologyless material is needed to pick up the same amount of oil,which results in lower disposal costs!Ideal for environmental and industrial applications wherelow costs and high absorbency are required.

Dispense-N-Dispose

A clever idea… Dispense and Dispose.

Dispenser Box for easy access to the sorbents.Disposal box and bags for easy off site removal of oilywaste.

Dispense-N-Dispose150 Oil or Maintenance Pads per box - 41cm x 51cm

1 2 3 4

5 6 7 8

Products

1 Oil & Chemical Pads

2 Oil Booms

3 SOCS

4 Spill Kits

5 Containment Products

6 Bilge Booms

7 Drain Covers

8 Spill Barrier

A sample of absorbents available from our websites

Oil Technics offers spill contractors an ex-stock range of pads, rolls, socs andbooms together with Spill Kits and oil containment products.

To view our full range, see our websites: www.oilpads.eu www.spillkit.eu

Page 8: Oil Technics Ltd(OTL):Demulsifers.

OilTechnicsF O R T H E O I L R E C Y C L I N G I N D U S T R Y

Oily Water SeparatorsBio TubesAn astonishingly simple biological product that will reduce separatoroil discharges by up to 95%

Place an oil absorbing biologically active Bio Tube in youroily water separator and you have a workforce of millions onyour side.Each Bio Tube contains a blend of naturally occurring oilspecific bacteria that will digest their way through up to 2kg ofoil a week – every week.• Environmentally Friendly• Digests free surface oil releasing merely harmless CO2 andWater.

• The biological solution that reduces oil discharges fromoily water separators by up to 95%.

• Maintenance free and helps reduce clean out costs

European Approvals• Tested by the UK Environmental Agency with the conclusionthat: Bio Tubes digest up to 95% of diesel oil withoutany harmful or toxic bi-products.

• Tested by the Swiss Federal Laboratories on a 1:1 mix oflube oil/diesel in water and found that: Bio Tubesexceeded the Swiss oil degradation target of 30 daysby 60%.

• Tested by a major European Forecourt chain and foundthat: Bio Tubes reduce oil discharges from an averageof 500mg/Ltr to 19 mg/Ltr – a reduction of +95%.

Application - For use in industrial separators, bunds andoily water run offs.Simply place one Bio Tube in second chamber, place 2Bio Tubes in third chamber and replace every 6-8 months.

Manufactured by Oil Technics LtdWEBwww.oilbio.com

eShopwww.oilbio.com/shop

ENGLAND & WALESThe CroftAbbots WalkStaffordEngland UK ST16 3BN

Tel: +44 (0) 1785 222970Fax: +44 (0) 1785 225519

[email protected]

SCOTLAND & EXPORTLinton Business ParkGourdonAberdeenshireScotland UK DD10 0NH

Tel: +44 (0) 1561 361515Fax: +44 (0) 1561 361001

[email protected]

Oil Contamination Solutions

For further details, please visitwww.bio-tubes.com