Metamaterials and Metafilms: Overview and Applications Christopher L. Holloway National Institute of Standards of Technology (NIST) EEEL Electromagnetics Division U.S. Department of Commerce, Boulder Laboratories 325 Broadway, Boulder, CO 80305 email: [email protected], Phone: 303-497-6184 Cooperative research effort between NIST and CU Edward Kuester, James Baker-Jarvis, John Ladbury, Pavel Kabos, Michael D. Janezic, Andrew Dienstfrey, Steven Russek, and Derik Love Also the DARPA/BOEING Team with NIST, UofA, UCSD, DUKE, UofPenn, UofI
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Metamaterials and Metafilms: Overview and Applications
Christopher L. HollowayNational Institute of Standards of Technology (NIST)
EEEL Electromagnetics Division
U.S. Department of Commerce, Boulder Laboratories325 Broadway, Boulder, CO 80305
OUTLINEMetamaterials• Discussion on Artificial Composite Materials• Negative Index Materials and Applications• Historical Perspective of Negative Materials• Effective Properties of Spherical Particle Composites• Negative Permittivity and Permeability of Spherical Particle Composites
Metafilm• Define Metafilmn• Derivation of a Generalized Sheet Transition Conditions (GSTCs) for a
Metafilm• Reflection and Transmission Properties• Total Reflection and Transmission Conditions• “Smart” surface: Controllable Scatterers• A New Class of Controllable Surface: YIG Spherical Particles
Composite Materials
• Permittivity arises from the induced electric-dipole response of a large number of small particles.
• Classically, these particles have been atoms or molecules, but in the past 60 years so-called artificial dielectrics have been developed whose “atoms” are small objects, large compared to atomic dimensions, but still small compared to the wavelength.
• The effective or averaged field E, D, H, and B are then related to each other by the usual expressions
ED ε= HB μ=where ε
and μ are related to the polarizability densities of the scatterers in space.
In this description, details of the field behavior on the scale of the scatterer size and separation are lost, and often are not of practical interest.
For many common materials ε
and μ
are positive, but there are exceptions.
Negative εr and μr
When one (but not both) of εr and μr is negative, plane waves decay exponentially, like modes below cutoff in a waveguide. However, when both εr and μr are negative, waves can still propagate in such a medium since the product εμ
remain positive. In this case (“backward wave”), the phase of the wave moves in the opposite direction from that of the energy flow.
• Veselago: Many authors have attributed the first study of such media to Veselago in 1968, but Sivukhin in 1957 briefly examined the properties of these materials.
• Mandelshtam: Veslago and Sivukhim as well as Silin in 1972 give credit to the much earlier work of L.I. Mandelshtam work 1945.
• Lamb: Mandelshtam himself referred to a 1904 paper of Lamb, who may have been the first person to suggest the existence of backward waves (his examples involved mechanical systems rather than electromagnetic waves).
• Schuster: In his 1904 book on optics, Schuster briefly notes Lambs’s work, and gives a speculative discussion of its implications for optical refraction, should a material with such properties ever be found.
• Engineered Materials: More recently, many other authors have studied the properties and potential applications of negative-index materials in detail.
Metamaterial Structures and Their Location in the ε , μ
Phase Space
ε
μ
Majority of isotropic dielectrics
Plasma-like behavior,k < 0, evanescent wave
∑ 20− 1 =
ωωε
2
where
Negative index materials
Propagating waves
me /4 220 Ν= πω
k < 0, evanescent wave
μ
and ε
close to zero
3-D array of inclusions embedded in a background matrix
• We need to emphasize that when we say metamaterials, we do not JUST mean materials that have negative index behavior.
• We mean synthetic (or engineered) materials that have a uniquely designed μ
and/or ε
behavior. That is, μ
and/or ε
of a
material that are not currently available.
• Existing materials can be tweaked, but the designed materials gives us revolutionary possibilities in electromagnetic behavior.
Normal -VS- Negative Materials
Positive Materials Negative Materials
Propagation in Negative Materials
Applications of NIM
x
zmetafilm
conductorconductor
Region A Region B
z=d1 z=-d2z=0
n1>0DNGn2<0
d1 d2
1. Perfect Lens
2. Resonant of Various Sizes
3. Antennas
x
yz
Typical scatterer at rl
4. Controllable “Smart” Surfaces
Other Applications
• THz devices and switches (a 20 ps was just demonstrated)
• bio-medical applications • quantum levitation• new devices• quasi-optical circuits• reducing EMI in radiation or detecting systems• miniaturization devices• enhancement of nonlinear properties• sub-wavelength resolution• superlenses• imaging • impedance matching• dynamic control of materials and optics
Pendry and Smith NIM
In practice, these structures are quite complicated to fabricate.
Composite NIMEffective Medium: The problem of effective-medium theory and modeling the
electromagnetic response of inclusions embedded in a host material has a long history going back to Maxwell and Rayleigh
Lewin’s work: One notable work is that of Lewin [1947], who, by solving the boundary-value problem of spheres a a medium, obtained a description of the effective material properties of a spherical particle medium.
Our Work : Using Lewin’s work, we have illustrated that the effective materials properties (ε
and μ) of a composite composed of spherical particles can become simultaneously negative.
1. We will show that this “new” class of material can behave in a way similar to that of an array of geometrically more complicated conducting scatterers.
2. This results suggests the possibility of developing negative-index materials that could be fabricated much more simply than those that have been proposed up until now.
DNG Materials Composed of Magneto-Dielectric Spherical Particles Embedded in a Matrix
Holloway, et al., IEEE Transactions on AP, October 2003
⎟⎟⎟⎟
⎠
⎞
⎜⎜⎜⎜
⎝
⎛
−−+
+=
fe
e
frre
vbFbF
v
2)(2)(
311
θθ
εε⎟⎟⎟⎟
⎠
⎞
⎜⎜⎜⎜
⎝
⎛
−−+
+=
fm
m
frre
vbFbF
v
2)(2)(
311
θθ
μμ
2
1
εε
=eb2
1
μμ
=mb 3
3
34
pav f
π=
θθθθθθθθcossin)1(
)cossin(2)(2 +−
−=F
2'20 rrak μεθ =
where
and
and
Functional Behavior of F(θ)
0 1 2 3 4 5 6 7 8 9 10
θ
-20
-15
-10
-5
0
5
10
15
20
θ
θθθθθθθθcossin)1(
)cossin(2)( 2 +−−
=F
We then ask: can this result in negative-index behavior?
This question can be answered by investing ε
and μ
as a function θ.
Negative εr and μr
Recall:
⎟⎟⎟⎟
⎠
⎞
⎜⎜⎜⎜
⎝
⎛
−−+
+=
fe
e
frre
vbFbF
v
2)(2)(
311
θθεε
We see that εr <0 if:
1
2)(2)(
3−<
−−+
fe
e
f
vbFbF
v
θθ
Since be >0, the following condition on F(θ)
guarantee that εr <0
f
fe
f
fe v
vbF
vv
b21
12)(
12
+−
−<<−+
− θ
F(θ)
MUST be negative, and from the figure above, we see that this is possible!
We find a similar condition on F(θ)
to guarantee that μr <0.
NIM Composed of Spherical Particles
0.02 0.04 0.06 0.08 0.10koa
-10.0
-8.0
-6.0
-4.0
-2.0
0.0
2.0
4.0
6.0
8.0
10.0
ε re
, μre
ε1=1, ε2=40, μ1=1, μ2=200, and f=0.5
εre
μre
Between 0<k0 a<0.1 there are two regions where both e and m become negative simultaneously.
Producing a negative-index material.
It is possible to have εr negative over the same region where μr negative by having:
'2
'1
'2
'1 // rrrr μμεε =
0.02 0.04 0.06 0.08 0.10koa
-10.0
-8.0
-6.0
-4.0
-2.0
0.0
2.0
4.0
6.0
8.0
10.0
ε re,
μ re
ε1=1, ε2=200, μ1=1, μ2=200, and f=0.5
εre
μre
Impedance matched material!
NIM Composed of Spherical Particles
0.02 0.04 0.06 0.08 0.10koa
-10.0
-8.0
-6.0
-4.0
-2.0
0.0
2.0
4.0
6.0
8.0
10.0
ε re
, μre
ε1=1, ε2=40, μ1=1, μ2=200, and f=0.5
εre
μre
The bandwidth of the materials is influenced by vf
, and the product of “εr μr” .
0.02 0.04 0.06 0.08 0.10koa
-10.0
-8.0
-6.0
-4.0
-2.0
0.0
2.0
4.0
6.0
8.0
10.0
ε re,
μ re
ε1=1, ε2=200, μ1=1, μ2=200, and f=0.5
εre
μre
5.5% Bandwidth800022 =με
1.1% Bandwidth4000022 =με
Also notice that the first resonance in the first figure occurs at k0 a=0.048, while the first resonance in the second figure occurs at k0 a=0.022.
In this material has no complicated metallic scatterers and the composite based on a spherical-particle array has the added advantage of being isotropic.
Lossy Spherical Particle DNG Materials
0.06 0.07 0.08 0.09 0.10koa
-25.0
-20.0
-15.0
-10.0
-5.0
0.0
5.0
10.0
15.0
20.0
25.0
Re[ε
re]
ε1=1, ε2=50, μ1=1, μ2=50, and f=0.5
tanδ=0.00
tanδ=0.01
tanδ=0.02
tanδ=0.04
tanδ=0.20
1) Notice that for this example, the real part of the effective permittivity can still be negative for loss tangents as large as 0.04.
2) However, for larger values of the loss tangents the resonance is damped out and the real partof the effective permittivity remains positive.
3) This shows that if the inclusion (i.e., the spherical particle) becomes too lossy, negative-index properties cannot be realized.
Other Types of Array of Resonant Inclusions
From a scattering-theory viewpoint, negative effective permeability and permittivity of a composite structure are possible if the effective electric and/or magnetic polarizabilities exhibit a characteristic resonant behavior, hence it should be no surprise that the spherical particles, and any magneto-dielectric inclusion for that matter, behave in the same manner as arrays of more complicated conducting scatterers.
This approach can be readily extended to other geometries and to other types of inclusions.
Spherical ParticlesMetamaterials
• We show how a composite medium realized by an array of spherical particles embedded in a background matrix can yield an effective negative permeability and permittivity.
• The type of composite material (magneto-dielectric spherical particles embedded in a matrix) introduces a new class of potential negative-index materials.
• In this approach no complicated metallic scatterers are required and the composite based on a spherical-particle array has the added advantage of being isotropic.
• This approach can be readily extended to other geometries and to other types of inclusions.
Applications
Antennas Composed of Metamaterials
Four-Layer Cylindrical 825 MHz Structure
12 mm loop for 825 MHz antenna
825 MHz antenna: loop with four-layer cylindrical material
Magnetic EZ-Antenna: Ground Plane-Center of ChamberMagnetic EZ-Antenna: No Ground Plane-Center of ChamberMagnetic EZ-Antenna: On Chamber Wall3 cm Loop antenna
Other Applications: Cloaking and Focusing (Optical Frequencies)
Opportunities:•Beyond the diffraction limit•Atom layers are periodic structures
Challenges:•Color•Geometry
Cloaking Objects: i.e., Disappearing Objects
Cloaking Objects: i.e., Disappearing Objects
Cloaking Objects: i.e., Disappearing Objects
Make the cover a metamaterial
Coat object with a material
Cloaking Objects: i.e., Disappearing Objects
Cloaking Objects: i.e., Disappearing Objects
Cloaking Objects: i.e., Disappearing Objects
Make the cover a metamaterial
Environmentalist
I am filing for a patent as soon as the talk is over!!!!
Cloaking: Science Top 10 Achievements for 2006
Schuring et al., Metamaterial Electromagnetic Cloak at Microwave Frequencies,Science Magazine, Oct 2006
Metamaterial over cylinder: NumericalScattering from Cylinder
Metamaterial over cylinder: Experimental Results: cloaking???
Is it Cloaked?? Some people think NOT!RF INVISIBILITY USING METAMATERIALS: HARRY POTTER’S CLOAK OR THE EMPEROR’S NEW CLOTHES?, Per-Simon Kildal et al, IEEE Trans on Antenna and Propagation, 2007.
Enhancing Objects
Magic Dust
Weak tank return
RF - ID
f
f
Electromagnetic Tunneling
R=1 T=0
Fill small waveguide with ε=0 (or approximately 0).
R=0 T=1
Ramifications: Smaller Waveguides and Waveguide Junctions
Quantum Levitation: CASIMIR Effect Enhancement
Attraction Force for very small t
A Quantum Mechanical Effect: Like Black Body Radiation
normal material
normal materialt
( )( ) ⎥
⎦
⎤⎢⎣
⎡
⋅−⋅
= −
−∞
∫ ∫ dK
dK
eRReRRTrK
kddAdF
3
3
221
221
30
2//
2
1222
ππξ
R1,2 for functions of ε and μ of the materials.
Metamaterial
Metamaterialt
Repulsive ForceIf we tune the material propertiesjudiciously we can get a repulsive force. Levitating
Plates
Quantum Levitation: Applications
1) Levitation cars, trains, and planes: probably not.
2) Levitation of atoms and molecules: probably yes.
Metamaterial
Metamaterial
Metafilm: 2-D Equivalent of a Metamaterial
2-D Slice
In general
The scatterers can be any generic shape, i.e., split rings, sphere, or any other shape.
For many applications, metafilms can be used in place of the metamaterials. Metafilms have the advantage of taking less physical space than do full 3-D metamaterial structures.
MetafilmA metafilm is a two-dimensional equivalent of a
metamaterial.
These scatterers are assumed to be characterized completely by their electric and magnetic polarizabilities and their density of distribution on the surface.
Metafilm
Metafilm: How do we analyze them?
For a metamaterial we typically use effective medium theory.
What about a metafilm?
d is not uniquely defined!
Thus, the effective material properties are not uniquely defined.
metafilm effective medium
d=?
There are several papers a year being published with this miss-interpretation!
Effective Boundary Condition for a Metafilm
Final form for effective BC when scatterer spacing is small compared to λ(see Kuester, Mohamed, Holloway, IEEE Trans. AP, October 2003):
[ ] 000
0|| ===
∇×−•=×+
− zzzMStzztESzz HaEjHa ααω
[ ] zzzzEStztMSzz
aEHjaE ×∇−•−=× ===
+
− 000
0|| ααωμ
RN
N
RN
N
RN
NzM
zMzMS
yM
yMyMS
xM
xMxMS
21
,
41
,
41 ,
,
,
,
,
,
αα
ααα
ααα
α−
=+
=+
=
RN
N
RN
N
RN
NzE
zEzES
yE
yEyES
xE
xExES
21
,
41
,
41 ,
,
,
,
,
,
αα
ααα
ααα
α+
=−
=−
=
where
We need anefficient modeling approach
A metafilm is characterized by effective transmission-type boundary conditions,as opposed to the effective-medium description used for a metamaterial.
Oblique Incident Plane Wave on a Metafilm
z
x
θ
ayEi ayEr
ayEt
z
x
θ
ayEi ayEr
ayEt
( )
( ) ( )θαθααθ
θααα
θααα
22022
0
22
0
sincoscos2
sin2
1
sin2
1
zMS
xMS
yES
zMS
yES
xMS
zMS
yES
xMS
kjk
k
T−−+−⎟
⎠⎞
⎜⎝⎛+
−⎟⎠⎞
⎜⎝⎛−
=
TE incident wave:
and
( )
( ) ( )θαθααθ
θααα
θαθααθ
22022
0
220
sincoscos2
sin2
1
sincoscos2
zMS
xMS
yES
zMS
yES
xMS
zMS
xMS
yES
kj
k
kj
−−+−⎟⎠⎞
⎜⎝⎛+
−+=Γ
see Holloway et al, IEEE Transactions on EMC, 2005
Oblique Incident Plane Wave on a Metafilm
( )
( ) ( )θαθααθ
θααα
θααα
22022
0
22
0
sincoscos2
sin2
1
sin2
1
zES
xES
yMS
zES
yMS
xES
zES
yMS
xES
kjk
k
T−−−−⎟
⎠⎞
⎜⎝⎛+
−⎟⎠⎞
⎜⎝⎛−
=
( )
( ) ( )θαθααθ
θααα
θαθααθ
22022
0
220
sincoscos2
sin2
1
sincoscos2
zES
xES
yMS
zES
yMS
xES
zES
xMS
yES
kj
k
kj
−−−−⎟⎠
⎞⎜⎝
⎛+
−+=Γ
TM incident wave:
and
z
x
θ
ayHi ayHr
ayHt
z
x
θ
ayHi ayHr
ayHt
see Holloway et al, IEEE Transactions on EMC, 2005
Controllable SurfacesFrom above we saw that the transmission and reflection properties of the surface were a function of the polarizabilities. Thus, by controlling the polarizabilities, one can control the surface and in turn the transmission and reflection properties.
Resonator with Dielectric Disk Scatterers: Loss Effects
Resonator with dielectric metafilm
2r
p
Metafilm: Oblate Spheroidal
Dielectric Disks
d1 =d2 =0.75 cm; r=0.46 cm; p=1 cm; Disk thickness=0.046 cm; εr =12.0; tan δ=0.04
GSTC model: fr =8.53 GHz, Q=137
d1 +d2
Resonator without metafilm,but uniformly filled with dielectric
Result: fr =2.98 GHz, Q=25
d1 =d2 =0.75 cm; εr =12.0; tan δ=0.04
x
zmetafilm
conductorconductor
z=d1 z=-d1z=0
HFSS: fr =8.61 GHz, Q=114Tradeoff exists betweensize/frequency reduction and Q
Metafilm or Metamaterial Expired Structures
I.A. Ibrahheem and M. Koch, “Coplanar waveguide metamaterilas: The role of bandwidth modifying slots”, Appl. Phys Lett, 2007
Biomedical Applications
Measurement of fluids, cell counts, and contaminants
Booth, Holloway, and Orloff
1 2 3 4 5Frequency (GHz)
-30
-20
-10
0
|S21
| (d
B)
1 mm cover layer: εr=1.0
1 mm cover layer: εr=4.0
1 mm cover layer: εr=88.0
Summary: Metafilm -- the 2-D Equivalent of a Metamaterial
• The surface version of a metamaterial has been given the name metafilm, which consists of arranging electrically small scatterers (characterized by their electric and magnetic polarizabilities) into a two-dimensional pattern at a surface or interface.
• For many applications, metafilms can be used in place of the metamaterials. Metafilms have the advantage of taking less physical space than do full 3-D metamaterial structures.
• We have shown that a metafilm is better characterized by effective transmission-type boundary conditions, as opposed to the effective-medium description used for a metamaterial. The BC is expressed in terms of theelectric and magnetic polarizabilities of the scatterers.
• Numerical comparison show that this BC is valid and accurate in modeling the metafilm.
• We discussed various applications for metafilms.
Summary: NIST’s Role
realistic materials
realistic applications
Reality
??Gain in Passive Materials??
"'"' μμμεεε jandj −=−=
Published Dataset 1
Published Dataset 2
Fresnel Reflection: Is it Valid?
[ ][ ] 0
0=−×
=−×
BAn
BAn
HHaEEa
AB
B
AB
AB
T
R
ηηη
ηηηη
+=
+−
=
2
Obtained by AssumingRegion B
Region A
x
y
Ei Er
Et
εA, μA
εB, μB
Interaction at an Interface of a Composite
which gives
Region B
Region Ax
y
p
p
ε0, μ0
ε0, μ0
∂AB [ ][ ] AeBaveAn
AmBaveAn
EpjHHa
HpjEEa
αω
αω
=−×
=−×
,
,
New Boundary Condition
corFresnel
corFresnel
TpjTT
RpjRR
λ
λ
+=
+=
Ramifications
If p/λ
is small then,
Fresnel
Fresnel
TTRR
⇒⇒
If not, corrections are needed.
•One of the consequence of these correction terms will be apparent in retrieval algorithms used to determine the effective material properties of composites.
•The basic assumption used in developing retrieval algorithms of material properties uses theclassical Fresnel coefficients and/or the assumption that the fields are continues across the material of interest.
•In fact, this could very well explain some of the non-physical results obtained when the effective material properties are measurement in some of the new metamaterials.
•We are presently using the BCs to develop new material properties retrieval algorithms for these new type of metamaterials.
Summary
• We need to emphasize that when we say metamaterials, we do not JUST mean materials that have negative index behavior.
• We mean synthetic (or engineered) materials that have a uniquely designed μ
and/or ε
behavior. That is, μ
and/or ε
of a
material that are not currently available.
• Existing materials can be tweaked, but the designed materials give us revolutionary possibilities in material behavior.
Other Applications
• THz devices and switches (a 20 ps was just demonstrated)
• bio-medical applications • quantum levitation• new devices• quasi-optical circuits• reducing EMI in radiation or detecting systems• miniaturization devices• enhancement of nonlinear properties• sub-wavelength resolution• superlenses• imaging • impedance matching• dynamic control of materials and optics
Other Applications of Metamaterials and Metafilms???