FYP Thesis

Catalytic Naphtha Reforming

By:

Nimrah Anwar

Syed Mustafa Hassan Zaidi

M. Haider Ali Khan

School of Chemical and Materials Engineering (SCME)

National University of Sciences and Technology (NUST)

June, 2015

i

Certificate

This is to certify that work in this thesis has been carried out by Ms. Nimrah Anwar, Mr.

Syed Mustafa Hassan Zaidi, and Mr. Haider Ali Khan completed under supervision of

Dr. Iftikhar Ahmad Salarzai in school of chemical and materials engineering (SCME),

National University of Sciences and Technology, H-12, Islamabad, Pakistan.

Supervisor: ______________

Dr. Iftikhar Ahmad Salarzai

Chemical Engineering Department

School of Chemical & Materials Engineering (SCME)

National University of Sciences and Technology (NUST), Islamabad

Submitted through:

HoD ______________________ Principal/ Dean __________________

Chemical Engineering SCME

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Acknowledgements

First and foremost we would like to offer our sincerest gratitude to our supervisor, Dr

Iftikhar Salarzai, who has supported us throughout our project with his patience and

knowledge whilst allowing us the room to work in our own way. He provided us with a

project that challenged our capabilities and believed that we would be able to truly deliver.

It was his encouragement and confidence that allowed us to persevere and deliver

something that we will always be proud of.

We would also like to use this opportunity to thank Mr. Khurram Manan of Phi-Tech

Solution. Mr. Manan’s willingness and enthusiasm to help us always caught us off-guard

as we did not know each other personally. It was his unconditional support that helped us

through so many roadblocks that we came across and it’s difficult to say where we would

be standing now without his help. We will always be grateful and appreciative of the

assistance that he provided us.

Dr. Mohsen Karimi research in the kinetics of the catalytic naphtha reforming allowed us

to model the reforming process in Aspen Plus. His paper provided us with the valuable data

without which we could not have begun our project. In addition to this, he provided us his

sincere advice and resources that allowed us to study the process in further depth and

troubleshoot any problems.

We would also like to thank the teachers of SCME and the class of 2011 that we were part

of for the past 4 years of ours bachelors. They have inspired us in every way and have

shaped and polished our skill that helped us a lot in this project and that will help us in our

future endeavors.

Lastly, we would like to dedicate this project to our families and loved ones for all their

support and prayers and the commitment that they showed to us despite difficulties. We

can never thank them enough for all they have done for us.

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Abstract

Naphtha reforming is one of the most important processes in refineries in which high value-

added reformate is produced by converting paraffins and naphthenes into high octane

gasoline and aromatics-rich products like benzene, toluene and xylene. Therefore it is

necessary to establish process simulation of naphtha reformer based on latest kinetics that

best represent the reforming process and develop the model to optimize, increase the

efficiency and maximize the yield of the processes. In this project, according to most recent

technological accomplishments in naphtha reforming, simulation of the reforming process

is done on ASPEN PLUS platform using lumped kinetic model based on 32 pseudo-

components of naphtha with 84 reforming reactions. In addition to the naphtha process

modelling, a “Soft Sensor” is also developed on MATLAB using Artificial Neural Network

(ANN) that predicts RON of the output reformate based on the input naphtha feed variables

WAIT, H2/HC ratio and PST.

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TABLE OF CONTENTS

CHAPTER 1: INTRODUCTION _____________________________________________________ 1

1.1. INTRODUCTION TO REFORMING: _________________________________________ 2

1.2. NAPHTHA: ___________________________________________________________ 2

1.3. CLASSIFICATION OF REFORMING PROCESSES: _______________________________ 2

1.4. ADVANTAGES OF CONTINOUS CATALYST REGENERATION: _____________________ 3

1.5. REFORMING PROCESS AND SCOPE: _______________________________________ 4

CHAPTER 2: LITERATURE REVIEW _________________________________________________ 5

2.1. LITERATURE REVIEW: _____________________________________________________ 6

CHAPTER 3: PROCESS DESCRIPTION _______________________________________________ 7

3.1. PROCESS FLOW DIAGRAM: _________________________________________________ 8

3.2. PROCESS UNITS __________________________________________________________ 8

3.3. PROCESS DESCRIPTION: ___________________________________________________ 9

CHAPTER 4: KINETIC MODEL AND REACTIONS ______________________________________ 11

4.1. KINETIC MODEL: ________________________________________________________ 12

4.2. REACTIONS: ____________________________________________________________ 13

4.2.1. Dehydrogenation _________________________________________________________ 13

4.2.2. Dehydrocyclization ________________________________________________________ 14

4.2.3. Isomerization _____________________________________________________________ 15

4.2.4. Transalkylation ___________________________________________________________ 16

4.2.5. Hydrocracking ____________________________________________________________ 17

4.2.6. Hydrodealkylation _________________________________________________________ 18

CHAPTER 5: NAPHTHA FEED COMPOSITION AND PROPERTIES _________________________ 19

5.1. REACTORS CONFIGURATION AND NAPHTHA FEED PROPERTIES: ___________________ 20

5.2. NAPHTHA FEED COMPOSITION: ____________________________________________ 21

CHAPTER 6: DESIGN OF THE EQUIPMENT __________________________________________ 22

6.1. PLUG FLOW REACTORS: __________________________________________________ 23

6.2. FURNACES: ____________________________________________________________ 26

6.3. FLASH VESSELS: _________________________________________________________ 28

6.4. HEAT EXCHANGERS AND COOLERS: _________________________________________ 30

6.5. COMPRESSORS: _________________________________________________________ 33

6.6. CENTRIFUGAL PUMPS: ___________________________________________________ 35

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CHAPTER 7: PROCESS SIMULATION, MASS AND ENERGY BALANCE, AND RESULTS _________ 37

7.1. ASPEN FLOWSHEET: _____________________________________________________ 38

7.2. TEMPERATURE AND COMPOSITION PROFILES OF THE REACTORS: _________________ 39

7.2.1. Reactor 1: _______________________________________________________________ 39

7.2.2. Reactor 2: _______________________________________________________________ 41

7.2.3. Reactor 3: _______________________________________________________________ 43

7.2.4. Reactor 4: _______________________________________________________________ 46

7.3. FLOWSHEET CONNECTIVITY BY STREAM: _____________________________________ 50

7.4. FLOWSHEET CONNECTIVITY BY BLOCK _______________________________________ 50

7.5. OVERALL FLOWSHEET BALANCE: ___________________________________________ 51

7.5.1. MASS AND ENERGY BALANCE ________________________________________________ 51

7.5.2. TOTAL BALANCE __________________________________________________________ 51

7.5.3. CO2 EQUIVALENT SUMMARY ________________________________________________ 51

7.6. COMPONENTS LIST: _____________________________________________________ 52

7.7. UNIT OPERATIONS AND PROCESSES INPUT AND RESULTS: _______________________ 53

7.7.1. BLOCK: B1 MODEL: HEATER ______________________________________________ 53




7.7.5. BLOCK: B5 MODEL: FLASH2 ______________________________________________ 61

7.7.6. BLOCK: B10 MODEL: PUMP _______________________________________________ 63

7.7.7. BLOCK: E-10 MODEL: HEATX ______________________________________________ 64

7.7.8. BLOCK: E-12 MODEL: HEATER _____________________________________________ 67

7.7.9. BLOCK: E-2 MODEL: HEATER ______________________________________________ 69








7.7.17. BLOCK: F-2 MODEL: FLASH2 _____________________________________________ 88

7.7.18. BLOCK: F-3 MODEL: FLASH2 _____________________________________________ 90

7.7.19. BLOCK: G-2 MODEL: COMPR _____________________________________________ 92

7.7.20. BLOCK: G-3 MODEL: PUMP ______________________________________________ 93

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7.7.21. BLOCK: R1 MODEL: RPLUG ______________________________________________ 94

7.7.22. BLOCK: R2 MODEL: RPLUG _____________________________________________ 102



7.8. STREAM RESULTS ______________________________________________________ 162

7.8.1. HP-RCY HYDROGEN NAP-HYD REFORM S1 ____________________________________ 162

7.8.2. S10 S11 S12 S15 S16 ______________________________________________________ 167

7.8.3. S17 S18 S19 S2 S20 _______________________________________________________ 172

7.8.4 S21 S22 S23 S24 S25_______________________________________________________ 177

7.8.5. S27 S28 S3 S30 S31 _______________________________________________________ 182

7.8.6. S32 S33 S34 S35 S36 ______________________________________________________ 187

7.8.7. S37 S4 S5 S6 S7 __________________________________________________________ 192

7.8.8. S8 _____________________________________________________________________ 197

CHAPTER 8: SOFT SENSOR TO PREDICT THE OCTANE NUMBER (RON) OF NAPHTHA REFORMATE ________________________________________________________________ 202

8.1. INTRODUCTION: _______________________________________________________ 203

8.2. ARTIFICIAL NEURON: ____________________________________________________ 204

8.3. BACK PROPAGATION ALGORITHM: _________________________________________ 205

8.4. SOFT SENSOR FOR THE NAPHTHA REFORMING INDUSTRY: ______________________ 205

8.5. PROCEDURE FOR DESIGNING THE ARTIFICIAL NUERAL NETWORK: ________________ 207

CHAPTER 9: COSTING AND INVESTMENT ANALYSIS _________________________________ 217

9.1. EXECUTIVE SUMMARY __________________________________________________ 218

9.2. RUN SUMMARY ________________________________________________________ 218

9.3. CASH FLOW ___________________________________________________________ 219

9.3.1. Sales Over a Period of 20 Years _____________________________________________ 220

9.3.2. Expenses Over a Period of 20 Years __________________________________________ 222

9.3.3. Costs Over a Period of 20 Years _____________________________________________ 224

9.3.4. Revenue Over a Period of 20 Years __________________________________________ 229

9.3.5. Cashflow Over a Period of 20 Years __________________________________________ 234

9.4. PROJECT SUMMARY ____________________________________________________ 238

9.5. EQUIPMENT COST ______________________________________________________ 245

9.6. UTILITIES COST ________________________________________________________ 246

9.7. RAW MATERIAL ________________________________________________________ 247

9.8. PRODUCTS ____________________________________________________________ 247

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CHAPTER 10: CONCLUSION AND BIBLIOGRAPHY ___________________________________ 248

10.1. CONCLUSION: ________________________________________________________ 249

10.2. REFERENCES _________________________________________________________ 251

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LIST OF FIGURES

Figure 1: Process Flow Diagram of CCR Process ____________________________________ 8

Figure 2: Simulation of Catalytic Naphtha Reformer on ASPEN PLUS ___________________ 38

Figure 3: Temperature Profile of Reactor 1 _______________________________________ 39

Figure 4: Composition Profile of Alkyl Cyclohexane in Reactor 1 ______________________ 39

Figure 5: Composition Profile of Aromatics in Reactor 1 _____________________________ 40

Figure 6: Composition Profile of Hydrogen in Reactor 1 _____________________________ 40

Figure 7: Temperature Profile of Reactor 2 _______________________________________ 41

Figure 8: Composition Profile of Alkyl Cyclohexane in Reactor 2 ______________________ 41

Figure 9: Composition Profile of Aromatics in Reactor 1 _____________________________ 42

Figure 10: Composition Profile of Hydrogen in Reactor 2 ____________________________ 42

Figure 11: Temperature Profile of Reactor 3 ______________________________________ 43

Figure 12: Composition Profile of N-Paraffins in Reactor 3 ___________________________ 43

Figure 13: Composition Profile of I-Paraffins in Reactor 3 ____________________________ 44

Figure 14: Composition Profile of Alkyl Cyclopentanes in Reactor 3 ____________________ 44

Figure 15: Composition Profile of Light Gases in Reactor 3 ___________________________ 45


Figure 17: Temperature Profile of Reactor 4 ______________________________________ 46

Figure 18: Composition Profile of Light Gases in Reactor 4 ___________________________ 46

Figure 19: Composition Profile of N-Paraffins in Reactor 4 ___________________________ 47

Figure 20: Composition Profile of I-Paraffins in Reactor 4 ____________________________ 47

Figure 21: Composition Profile of Alkyl Cyclohexane in Reactor 4 _____________________ 48

Figure 22: Composition Profile of Alkyl Cyclopentanes in Reactor 4 ____________________ 48

Figure 23: Composition Profile of Aromatics in Reactor 4 ____________________________ 49


Figure 25: Example of Multilayer Feed Forward Neural Network _____________________ 204

Figure 26: Basic Elements of a Neuron _________________________________________ 204

Figure 26: Basic Structure of Multilayer Feed Forward Neural Network to calculate RON __ 206

Figure 27: Summary of Soft Sensor Results ______________________________________ 212

Figure 28: Performance Results of the Soft Sensor ________________________________ 213

Figure 29: Regression Model of the Neural Network ______________________________ 214

Figure 30: Generalization Error _______________________________________________ 215

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LIST OF TABLES

Table 1: Rate constants and heat of reactions in Dehydrogenation reactions ___________________ 13

Table 2: Rate constants and heat of reaction in Paraffin Dehydrocyclization to Naphthene _______ 138

Table 3: Rate constants and heat of reactions in Paraffin Dehydrocyclization to Aromatic _________ 15

Table 4: Rate constants and heat of reactions in Isomerization of Naphthenes and Paraffins ______ 16

Table 5: Rate constants and heat of reactions in Isomerization of Aromatics ___________________ 16

Table 6: Rate constants and heat of reactions in Transalkylation _____________________________ 16

Table 7: Rate constants and heat of reactions in Cracking of Paraffins _________________________ 17

Table 8: Rate constants and heat of reactions in Cracking of Naphthenes ______________________ 18

Table 9: Rate constants and heat of reactions in Hydrodealkylations __________________________ 18

Table 10: Specifications of reactors, Feed, Product and Catalyst of plant for fresh catalyst ________ 20

1

CHAPTER 1: INTRODUCTION

2

1.1. INTRODUCTION TO REFORMING:

Naphtha reforming process is one of the key processes in petroleum refining for providing

high value-added reformate for the gasoline pool. It is also used for producing BTX

(benzene, toluene, and xylene) by conversion of paraffins and naphthenes to aromatics-

rich products which are the basic substances of the petrochemical processes. Hydrogen is

also considered as a main by-product and in the most refineries is used in hydrocracking,

hydrotreating, and other hydrogen consuming.

1.2. NAPHTHA: Full-range naphtha is the fraction of the crude oil with a boiling temperature between 30

and 200◦C, and constitutes typically 15–30 wt% of the crude oil. The naphtha used as

catalytic reforming feedstock is very complex usually consisting of about three hundred

hydrocarbons with carbon number ranging from one to twelve, and each of them

undergoes various reactions. Thus a detailed kinetic model considering all the components

and reactions is too complex. For this reason, attempts have been made to model naphtha

by considering groups of components (i.e. kinetic lumps also called pseudo components)

taking part in reforming reactions. Accordingly, various lumping kinetic models to

represent catalytic reforming reactions have been reported in the literature, which have

different levels of sophistication.

1.3. CLASSIFICATION OF REFORMING PROCESSES:

Based on the mode of catalyst regeneration, the reforming process is generally classified

into three types:

1. Semi regenerative.

2. Cyclic.

3. Continuous regenerative (moving bed).

3

Today, 60% of total capacity of reforming process is the semi regenerative scheme, while

the continuous regeneration and the cyclic have 28% and 12% of total capacity of

reforming, respectively. Due to many benefits of continuous regeneration, all new units

are designed based on this technology and old units are revamped to the continuous

regeneration process or are combined with this process.

1.4. ADVANTAGES OF CONTINOUS CATALYST

REGENERATION:

There are some advantages of CCR process against traditional methods, such as producing

higher octane reformate even working with a low feed quality, long time working of the

process due to lack of shut down, operating in the lower pressure by the low pressure drop,

using catalyst with less stability but higher selectivity and yield, requiring lower recycle

ratio, economic design, producing more reformate with higher aromatic content and

steady production of hydrogen with constant purity (93% compared to 80% in the semi

regenerative process).

In addition, the deposited coke in the semi regenerative reformer can be varied from a few

weight percent on the first reactor to 20 wt% coke in the last reactor. In the cyclic

regenerative reformers, catalyst regeneration is usually based on economics performance

for one or more of the reactors in there forming process loop. While in the CCR process

that operates with a platinum/tin catalyst, the deposited coke on the catalyst is usually

restricted to less than 7 wt% in the last reactor. Thus, according to these advantages of

CCR process the capacity of the CCR reforming units has increased quickly in the recent

years.

4

1.5. REFORMING PROCESS AND SCOPE:

Generally, the naphtha reforming unit consists of four reactors, catalyst regeneration unit,

distillation column which separates products into light hydrocarbons and reformates, and

due to endothermic reactions in the reforming process, inlet stream to each reactor is

preheated via a furnace.

Accomplished researches regard naphtha reforming process could be classified in three

categories. The first category consists of the accomplished studies on kinetic models of

catalytic naphtha reforming. Since naphtha is a complex mixture of approximately 300

components, similar components are lumped together into a pseudo component to reduce

the complexity of the reaction pathways and reaction kinetics. The second class of studies

have been focused on improving the operation and selectivity of the catalyst and reduce

the probability of coke formation on the catalyst surface by adding some metals such as

Sn, In, and Ge to the catalyst. The third category consists of the performed studies on

simulating and modeling novel configurations with better performance.

5

CHAPTER 2: LITERATURE REVIEW

6

2.1. LITERATURE REVIEW:

The first significant attempt to recognize different components within naphtha was

performed by Smith (1959). He characterized naphtha by three of its basic constituents;

paraffins, naphthenes, and aromatics.

In a more extensive attempt to model reforming reactions of whole naphtha, Krane et al.

(1960) divided naphtha into twenty components. They accounted for the presence of

various carbon numbers from C6 to C10 as well as the difference between paraffins,

naphthenes, and aromatics within each carbon number group. A total of fifty-three

reaction steps each represented by a pseudo-first order rate equation with respect to

hydrocarbon concentration were derived from experimental studies on whole naphtha.

Other studies about lumped kinetic have been done by Ramage et al. (1980), Wolff and

Kramarz (1979) and Jenkins and Stephens (1980). To satisfy various demands on the

reforming process, different pseudo components have been considered in the proposed

network kinetic models. Marin et al. (1983) and Froment (1987) published the reaction

network for the whole range of naphtha reforming. In addition, by considering this fact

that the reaction pathways derived for each carbon number fraction are almost identical to

each other, Ramage et al. (1987) used the same reaction network within each carbon

number group. Jorge and Eduardo (2000) proposed a 24 lumps model in order to model

the kinetics of catalytic naphtha reforming reactions. Hu et al. (2003) proposed kinetic

model with 17-lumpes while Weifeng et al. (2006) proposed kinetic model with 18-

lumpes.

As discussed in this literature survey, various studies have been done on the naphtha

reforming process, but few studies have been carried out on the continuous catalyst

regeneration system. Hongjun et al. (2010), Weifeng et al. (2007), and Mahdavian et al.

(2010) introduced modeling and simulations approaches for CCR process.

7

CHAPTER 3: PROCESS DESCRIPTION

8

3.1. PROCESS FLOW DIAGRAM:

Figure 1: Process Flow Diagram of CCR Process

3.2. PROCESS UNITS The CCR process consists of regeneration unit and adiabatic cross-flow reactors that are

arranged in a conventional side-by-side pattern. The first reactor is always smaller than

the other reactors and the last reactor is always the largest. In this process, each catalyst

particle moves continuously from the first reactor toward the last reactor. Then, catalyst

particles are sent to the regeneration unit to restore. Also, hydrotreated naphtha is

combined with the recycle hydrogen gas and, after heating to the desired reaction

temperature (798 K), it is sent to a series of reactors.

In the CCR process, spherical catalysts are used in the reactors to facilitate catalyst

circulation by gravity. Coked catalyst is withdrawn from the last reactor and sent to the

regeneration unit, then, regeneration of the catalyst is performed as the catalyst moves

9

down in the regeneration unit on a continuous basis. Regenerated catalyst is added to the

top of the first reactor to keep the efficiency of process at the certain level, and catalyst

regeneration leads to reduction in operating cost, whiles, poor catalyst will lead to low

product yields and increase in operating expense. The catalyst flows vertically in the

reactor; and the feed flows radially through the catalyst bed (reaction side) of the reactor,

thus cross flow pattern exist in the reactors.

3.3. PROCESS DESCRIPTION: Figure 1 shows the industrial flowsheet of a whole continuous catalytic reforming process

to produce aromatics and hydrogen. The naphtha feedstock is mixed with recycle gas and

then heated to required reaction temperature by heat exchanger E-1 and heater B-1. Since

the major reactions in the reactors are endothermic, catalytic reformers are designed with

multiple reactors and with heaters between the reactors to maintain reaction temperature

at operable levels. Accordingly, the reactant passes in the sequence of heating in heaters

B-1 to B-4 and reacting in reactors R-1 to R-4. The effluent from the last reactor R-4 is

cooled by heat exchanger E-1 and coolers E-2 to E-3 and then enters the product separator

F-1. The majority of flashed vapor, containing 80% to 90% (by mol) hydrogen, circulates

to join the naphtha feedstock as recycle gas. All that mentioned above is the reaction unit

of the reforming process, as presented within the thick line of Fig.2. Excess hydrogen

from separator F-1 passes to compressor G-1 and cooler E-4, and enters separator F-2.

After through compressor G-2 and pump G-3 respectively, the liquid from separator F-1

is mixed with the vapor from separator F-2. The mixture, comprised mostly of the desired

reformate product but also containing light gases, passes through coolers E-5 to E-6, heat

exchangers E-7 to E-10, ammonia cooler E-11 in sequence, and then enters separator F-

3. The flashed vapor, containing over 90% hydrogen, passes heat exchangers E-10 and E-

8 and is obtained as hydrogen product. The flashed liquid from F-3 is mixed with the

liquid from separator F-2 after through heat exchangers E-9 and E-7. The mixture is then

fed into distillation column D-1 after passing heat exchanger E-12. The distillate is

separated into two streams. One is vapor and is sent to the fuel gas system, the other is

liquid and is sent to the LPG (liquefied petroleum gas) system. The reformate product,

having removed the light gases, is acquired as the bottom from D-1 and fed into distillation

10

column D-2. The mixture of xylene, ethyl-benzene, and heavy aromatics is obtained as

the bottom product of D-2 and sent to the xylene unit. The distillate containing benzene,

toluene, and heavy paraffins is sent to the aromatics extraction unit.

11

CHAPTER 4: KINETIC MODEL AND

REACTIONS

12

4.1. KINETIC MODEL:

An effective kinetic model of naphtha reforming must represent all the major types of

reactions in the reforming process. A kinetic model inherently satisfies both heat and

material balances; because it takes into account the stoichiometry of the reactions.

As discussed, the naphtha feedstock consists of several hundred components and each of

them takes part in various reactions. Thus, presenting a detailed kinetics-based model

considering all components and reactions is infeasible. In past decades, many attempts

have been made (Marinet al., 1983; Froment, 1987; Ramage et al., 1987; Jorge and

Eduardo, 2000; Hu et al., 2003; Weifeng et al., 2006) to propose a perfect kinetic model

for naphtha reforming process by considering most kinetic lumps and reactions.

Padmavathi and Chaudhuri (1997) proposed appropriate model for naphtha reforming

kinetic, but in their model, some of the main lumps and reactions have been ignored.

Whiles in the reforming process, aromatics are the main products, 8-carbon aromatics

were not subdivided in details. In addition, some of the main reactions such as

dehydrocyclization of paraffins to aromatics, isomerization and transalkylation of

aromatics have been ignored. In the proposed model, 8-carbon aromatics are subdivided

to four lumps (ethyl benzene, para-xylene, meta-xylene and ortho-xylene) and the

variations of each of them are investigated. Also ignored reactions in Padmavathi and

Chaudhuri(1997) study, are characterized in Tables 1–9.

Proper kinetic modeling of reforming reactions is the key to effective representation of

the process over a wide operating range. The first effect of the kinetics of the reactions on

the product properties is the effect of operating variables on the octane number. Therefore,

by considering important kinetics in the reforming process and all of the accomplished

studies, in this project, modelling of the latest reaction network is done.

13

4.2. REACTIONS:

Paraffins, naphthenes and aromatics are the different hydrocarbon groups in the reforming

feedstock. In the presented model, the naphtha feedstock has been subdivided to

naphthenes (alkylcyclohexanes: ACH, alkylcyclopentanes:ACP), paraffins (normal

paraffins: NP, isoparaffins: IP), and aromatics (A) lumps with carbon numbers ranging

from C6to C9+,this kinetic model consists of 32 pseudo components with 84reactions. As

shown in Fig. 2, in this model, all of the main reactions are included, and the defined

pseudo components are related by major reforming reactions. In addition, rate constants

in the proposed model are obtained by optimization, so that deviation between output

results of model and commercial data is minimized. In the following, main reactions in

the reforming process are discussed, and the reactions, rate constants, characteristics and

the calculated heat of reactions are listed.

4.2.1. Dehydrogenation

Dehydrogenation reaction, due to produce high octane number aromatics, is a principal

reaction in the reforming process. Octane number is gained at a loss of volume, when a

naphthene is converted to an aromatic. This reaction is the fastest amongst all the

reforming reactions, thus reaches equilibrium very quickly and is catalyzed by the metallic

function of the catalyst. The reaction is endothermic and produces a sharp drop in

temperature. The needed reaction constants for calculating the reaction rate constants

(k1n) and equilibrium constants (K1n) are presented in Table 1.

14

4.2.2. Dehydrocyclization

Dehydrocyclization of paraffins to naphthenes and aromatics is a desirable reaction in the

reforming process because it induces the most considerable increase in octane number

among the naphtha reforming reactions. But unfortunately, these reactions are the most

difficult reaction to promote. The most reactions of dehydrocyclization are endothermic

and promoted by high temperature, low pressure and by both metallic and acidic functions

of the catalyst. The needed reaction constants for calculating the reaction rate constants

(k2n,k3n,k4n,k5n,k6n and k7n) and equilibrium constants K2n,K3n,K4n,K5n,K6n and

K7n) of dehydrocyclization reactions are presented in Tables 2 and 3.

15

4.2.3. Isomerization

Three types of isomerization reactions are investigated in the reforming process, including

isomerization of paraffins, naphthenes and aromatics. Paraffins isomerization rearranges

the molecule with essentially no change in the volume. These reactions are fast, slightly

exothermic and do not affect the number of carbon atoms. The reactions are unaffected

by pressure, whiles from a kinetic viewpoint, the equilibrium depends mainly on the

temperature. It should be mentioned that isomerization reactions are promoted by the

acidic function. The isomerization of alkylcyclopentanes into alkylcyclohexanes involves

a ring rearrangement. In the subsequent stage, the produced alkylcyclohexanes undergo

dehydrogenation reaction and produce aromatics. Thus, isomerization of naphthenes is

considered as a desirable reaction. Aromatics with 8-carbon atoms also undergo the

isomerization reactions, the isomerization between P-xylene, M-xylene and O-xylene

occur rapidly, while isomerization between ethylbenzene and xylene isomer occurs

slowly. Calculated constants for isomerization reactions of naphthenes, paraffins and

aromatics are shown in Tables 4 and 5.

16

4.2.4. Transalkylation

Transalkylation is the reaction between two similar or dis-similar molecules involving

transfer of an alkyl group. In the alkyl-transfer reactions, shift of alkyl groups from one

ring to the other, depends on the number of alkyl groups on the aromatic ring/s, the type

of alkyl substituent/s and the chain length. In the proposed model, transalkylation between

aromatics is considered. Two toluene rings can disproportionate to produce one benzene

ring and one Para xylene ring, in addition, two Ortho-xylene rings disproportionate to

produce one toluene and higher aromatics (A9+). These reactions are promoted by the

catalyst metallic function, and with increase in the reaction temperature, the conversion

increases. It should be mentioned that transalkylation occurs mainly in very severe

conditions of pressure. Calculated constants for reaction rate in the transalkylation

reactions are presented in Table 6

17

4.2.5. Hydrocracking

Breaking of carbon bonds in the reforming is called hydrocracking. Bond’s breaking can

occur at any position along the hydrocarbon chain. This reaction by removing the low

octane number paraffins and naphthenes from reformate and producing lighter

hydrocarbons, such as methane, ethane and propane, helps to improve the octane in the

products. Hydrocracking is an irreversible reaction and is favored at high temperature and

high pressure, also is catalyzed by the acidic or metallic function of the catalyst. Reaction

constants for hydrocracking of paraffins and naphthenes are shown in Tables 7 and 8,

respectively.

18

4.2.6. Hydrodealkylation

Hydrodealkylation is the breakage (or cleavage) of the branched radical of aromatics ring

in presence of hydrogen. Like hydrocracking, this reaction is favored by high temperature

and high pressure also it is an irreversible reaction, and promoted by the metallic function

of the catalyst. Hydrodealkylation is the slowest of all the reforming reactions. This

reaction is desirable because it changes the relative equilibrium distribution of the

aromatics in favor of benzene and octane number. The needed hydrodealkylation

constants to calculate the reaction rate constants (k16n) is presented in Table 9.

19

CHAPTER 5: NAPHTHA FEED

COMPOSITION AND PROPERTIES

20

5.1. REACTORS CONFIGURATION AND NAPHTHA FEED

PROPERTIES:

The specification of conventional process such as reactors, feed, product and catalyst are

shown in Table 10.

21

5.2. NAPHTHA FEED COMPOSITION: The mole fraction and molecular weight of the pseudo components in the inlet naphtha

feed is given below:

22

CHAPTER 6: DESIGN OF THE

EQUIPMENT

23

In the following chapter, we have discussed the design specification as well as the

respective design equations used by Aspen Plus to design and size equipment.

6.1. PLUG FLOW REACTORS:

The RPlug model represents an ideal plug-flow reactor with one or more phases. The model

assumes perfect radial mixing within and between the phases, phase equilibrium, and no-

slip conditions between the phases (e.g., the phases all have the same residence time).

Since our reactors are assumed to be adiabatic, we don’t need to give any specifications

regarding this and temperature is calculated at each axial position based on the enthalpy

balance. The RPlug model assumes a cylindrical geometry. The length, diameter, and

number of tubes are specified. The process fluid is assumed to move through the tubes. The

phase volumes cannot be specified independently. Instead, the RPlug model assumes that

the phases move through the reactor without slipping past each other. This assumption is

valid for situations where one phase is dispersed as droplets or bubbles in a second,

continuous phase, such as dew in a vapor phase or small gas bubbles in a liquid phase. This

assumption is not valid for multiphase plug flow reactors with controlled levels.

With this assumption in place, the reactor residence time is equal to the residence time of

each phase present in the reactor. The residence time is calculated by numerical integration.

The formula used to calculate residence time is as follows:

24

RPlug uses an integral method to solve mass, energy, and component attribute conservation

equations for each differential element of reactor length. These equations have the form

(for each component and for enthalpy):

For enthalpy, the term dH/dz due to heat transfer depends on the heat transfer option. For

transfer from thermal fluid, the term is:

Heat of reaction is accounted for by the change in the reference state due to the change in

composition. RPlug integrates these variables while keeping the integration error below a

specified tolerance. The integration error is applied to scaled variables to keep all error

relative to the magnitude of the variable.

RPlug uses a variable-step-size Gear algorithm during this integration to solve the

differential form of the conservation equations. Each equation is solved for in each element

using a trial-and-error method. The Convergence method on the Convergence | Integration

25

Loop sheet is used correct each wrong guess to a new value. Integration convergence

tolerance on the Convergence | Integration Loop sheet determines how tightly these

equations are solved. Tight (small) tolerances result in small steps, long run times, and

increased model accuracy.

The design specifications of each of our reactors are given below:

Name PACKED R1

PACKED R2

PACKED R3

PACKED R4

User tag number R1 R2 R3 R4

Vessel diameter [ft] 4.5 4.5 4.5 4.5

Vessel height [ft] 28 34 40 50.5 Design gauge pressure [psig] 96.601454 90.074756 83.548057 77.021359

Design temperature [F] 1026.73 1026.73 1026.729991 1026.73

Operating temperature [F] 976.73 976.73 976.729991 976.73

Total packing height [ft] 27 33 39 49.5

26

6.2. FURNACES:

The furnaces that we have used can be represented by the heater block in Aspen Plus.

Heater can be used to represent heaters, coolers, mixers, valves, or tanks. The Heater block

allows you to specify the temperature or heat duty of the unit, but does not carry out

rigorous heat exchange equations. Any number of feed streams can be specified for the

Heater block. This block follows the same mixing rules as the Mixer model.

The heater can be supplied different specifications such as outlet temperature or

temperature change. In either case, the heater is converged using the following equation to

solve the energy balance:

27

The area of cylindrical furnaces can be calculated using the following formula:

The design specifications of the box type furnace that we used are the following:

Name EFU BOX EFU BOX EFU BOX EFU BOX

User tag number B1 B2 B3 B4

Material 304S 304S 304S 304S

Duty [mmbtu/h] 448.335437 37.375034 7.022129 129.35946 Standard gas flow rate [cfm] 2283.021956 45150.28187 51644.1338 58444.7947

Process type LIQ GAS GAS GAS Design gauge pressure [psig] 492.172873 96.601454 90.067643 83.548057

Design temperature [F] 1026.73 1026.73 1026.73 1026.73

28

6.3. FLASH VESSELS:

A vapor-liquid separator drum is a vertical vessel into which a liquid and vapor mixture

(or a flashing liquid) is fed and wherein the liquid is separated by gravity, falls to the bottom

of the vessel, and is withdrawn. The vapor travels upward at a design velocity which

minimizes the entrainment of any liquid droplets in the vapor as it exits the top of the

vessel.

The size a vapor-liquid separator drum (or knock-out pot, or flash drum, or compressor

suction drum) should be dictated by the anticipated flow rate of vapor and liquid from the

drum. The following sizing methodology is based on the assumption that those flow rates

are known.

The vessel diameter is calculated by the Souders-Brown equation to determine the

maximum allowable vapor velocity:

V = (k) [ (dL - dV) / dV ]^0.5

Where:

V = maximum allowable vapor velocity, m/sec

dL = liquid density, kg/m3

dV = vapor density, kg/m3

k = 0.107 m/s (when the drum includes a de-entraining mesh pad)

The cross-sectional area of the drum A = (vapor flow rate, m3/s) / (vapor velocity V, m/s)

And D, the drum diameter (m) = ( 4 A / 3.1416 )^ 0.5

In Aspen Plus, Flash performs rigorous 2 (vapor liquid) or 3 (vapor liquid liquid) phase

equilibrium calculations. Flash2 produces one vapor outlet stream, one liquid outlet stream,

and optional water decant stream. You can use Flash2 to model flashes, evaporators, knock

out drums, and any other single stage separators, with sufficient vapor disengagement

space. Optionally, you can specify a percentage of the liquid phase to be entrained in the

vapor stream. The design specifications of our flash vessels are given below:

29

Name B5-flash F-3-flash F-2-flash

Liquid volume [gal] 9756.37346 4840.73001 4716.60873

Vessel diameter [ft] 9 6.5 6.5

Vessel height [ft] 20.5 19.5 19

Design g. pressure [PSI] 358.738155 499.42476 155.341738

Design temperature [F] 250 250 250

Op. temperature [F] 103.73 122.221159 103.73

30

6.4. HEAT EXCHANGERS AND COOLERS:

In Aspen Plus, furnaces and heaters are essentially the same thing in the way they are

converged. The description for furnaces has already been discussed above and the same

principles apply to the other heaters simulated in the flow sheet.

On the other hand, the heat exchangers that we have used are primarily shell and tube heat

exchangers. Shell and tube heat exchangers consist of series of tubes. One set of these tubes

contains the fluid that must be either heated or cooled. The second fluid runs over the tubes

that are being heated or cooled so that it can either provide the heat or absorb the heat

required. A set of tubes is called the tube bundle and can be made up of several types of

tubes: plain, longitudinally finned, etc. Shell and tube heat exchangers are typically used for

high-pressure applications (with pressures greater than 30 bar and temperatures greater than

260 °C).

In Aspen Plus, heat exchangers are represented by the block HeatX. HeatX has these

calculation methods: shortcut, detailed, and rigorous methods for several Aspen EDR heat

exchanger programs. Use the Calculation frame on the Setup | Specifications sheet to specify

the appropriate calculation method.

With the shortcut calculation method you can simulate a heat exchanger block with the

minimum amount of required input. The shortcut calculation does not require exchanger

configuration or geometry data.

With the detailed calculation method, you can use exchanger geometry to estimate:

Film coefficients

Pressure drops

Log-mean temperature difference correction factor

The detailed calculation method provides more specification options for HeatX, but it also

requires more input. The detailed calculation method provides defaults for many options.

You can change the defaults to gain complete control over the calculations. The following

table lists these options with valid values. The values are described in the following sections.

31

The rigorous methods allow you to rate or simulate the performance of existing equipment.

Some of them also allow the design of new equipment and cost estimation. In addition to the

more rigorous heat transfer and hydraulic analyses, the program will also determine possible

operational problems such as vibration or excessive velocities. The modules used in the

rigorous methods are the same as those used in the Aspen EDR standalone product for shell

and tube heat exchanger analysis.

We used the shortcut method to simulate our heat exchangers since it required the least input.

The HeatX model determines the outlet stream conditions based on heat and material

balances and uses a constant value for the heat transfer coefficient to estimate the surface

area requirement. A different heat transfer coefficient for each heat transfer zone of the

exchanger, indexed by the phase for the hot and cold streams.

The following tables show the different design specifications for each of the heaters and heat

exchangers used.

Name EXCH E-2 EXCH E-12 EXCH E-4

User tag number E-2 E-12 E-4

Heat transfer area [SF] 12048.7339 17369.25857 9.786988

Front end TEMA symbol B B B

Shell TEMA symbol E E E

Rear end TEMA symbol M M M

Tube design gauge pressure [psi] 60.304 435.304 98.662492

Tube design temperature [F] 810.704264 494.6 250

Tube operating temperature [F] 95 444.6 95

Tube outside diameter [in] 1 1 1 Shell design gauge pressure [psig] 77.021359 285.304 155.341738

Shell design temperature [F] 810.704264 490.33 250

Shell operating temperature [F] 760.704264 440.33 103.781329

Tube length extended [ft] 20 20 20

Tube pitch [in] 1.25 1.25 1.25

Number of tube passes 1 1 1

Number of shell passes 1 1 1

32








Tube design temperature [F] 377.8 377.8 250

Tube operating temperature [F] 327.8 327.8 140.245615


Shell design temperature [F] 250 250 250



Tube pitch [in] 1.25 1.25 1.25










Tube design temperature [F] 250 250 303.13

Tube operating temperature [F] 140.236945 140.236585 95


Shell design temperature [F] 250 250 303.13



Tube pitch [in] 1.25 1.25 1.25



33

6.5. COMPRESSORS:

In a centrifugal compressor, energy is transferred from a set of rotating impeller blades to

the gas. The designation “centrifugal” implies that the gas flow is radial, and the energy

transfer is caused from a change in the centrifugal forces acting on the gas. Centrifugal

compressors deliver high flow capacity per unit of installed space and weight, have good

reliability, and require significantly less maintenance than reciprocating compressors.

However, the performance characteristic of centrifugal compressors is more easily affected

by changes in gas conditions than is the performance of reciprocating compressors.

In Aspen Plus, there are several options of compressors to choose from. We chose the

isentropic compressor to model the one we have in our process flow diagram. The head

developed for a compressor to change the pressure of a stream from the inlet pressure P1

to the outlet pressure P2 is given by:

where V is the molar volume and subscripts 1 and 2 refer to inlet and outlet conditions,

respectively.

To use this equation, the integral must be evaluated, which requires information on the

path followed by the fluid from inlet to outlet. In a polytropic compression process, the

relationship of P and V is given by PVn = C where n is the polytropic exponent and C is a

constant. For an isothermal process, n=1, while for an isentropic process, n=k, the ratio of

the heat capacities Cp/Cv.

This equation is only correct for perfect gases. The actual enthalpy change per mole of

gas for a compression process is calculated using an efficiency factor:

34

Where h is the isentropic or polytropic efficiency. The efficiency is assumed constant along

the integration path.

The indicated horsepower is defined as the total enthalpy change in the stream:

where F is the molar flow rate.

The table below gives the specifications of the compressor used.

Name CENTRIF G-2

User tag number G-2

Actual gas flow rate Inlet [CFM] 7.938132

Design gauge pressure Inlet [PSIG] 130.341738

Design gauge pressure Outlet [PSIG] 449.42476

Driver power [HP] 9.709963

Molecular weight 2.704956

Specific heat ratio 1.421792

Compressibility factor Inlet 1.005341

Compressibility factor Outlet 1.016172

Driver type MOTOR

35

6.6. CENTRIFUGAL PUMPS:

Centrifugal pumps are used to transport fluids by the conversion of rotational kinetic

energy to the hydrodynamic energy of the fluid flow. The rotational energy typically comes

from an engine or electric motor. The fluid enters the pump impeller along or near to the

rotating axis and is accelerated by the impeller, flowing radially outward into a diffuser or

volute chamber (casing), from where it exits.

Pump is designed to handle a single liquid phase. For special cases, you can specify two-

or three-phase calculations to determine the outlet stream conditions and to compute the

fluid density used in the pump equations. The accuracy of the results depends on a number

of factors, such as the relative amounts of the phases present, the compressibility of the

fluid, and the efficiency specified.

Specific speed and suction specific speed are two important parameters that define the

suitability of a pump design for its intended conditions. The pump specific speed is defined

as:

36

Suction specific speed (Nss) is an index number for a centrifugal pump and is used to define

its suction characteristic. It is defined as follows:

The design specifications for the two pumps are shown in the table below.

Name CENTRIF B10 CENTRIF G-3

User tag number B10 G-3

Liquid flow rate [GPM] 569.652768 569.652768

Fluid specific gravity 0.786094 0.786094

Design gauge pressure [PSIG] 155.341738 499.42476

Design temperature [DEG F] 250 250

Fluid viscosity [CPOISE] 0.5 0.5

Pump efficiency [PERCENT] 71.6326 71.6326

37

CHAPTER 7: PROCESS SIMULATION,

MASS AND ENERGY BALANCE, AND

RESULTS

38

In this Chapter, we will discuss the detailed modelling of Naphtha Reformer on ASPEN

PLUS based on the latest and comprehensive kinetic model as discussed earlier that

consists of 32 pseudo components and 84 reforming reactions

Also we will discuss in detail the

Input specifications of every unit block in the process flowsheet,

Overall material and energy balance of each pseudo component

Material and energy balance across every flowsheet unit

Properties of every stream present in the flowsheet

Detailed results of every flowsheet unit including reactors, furnaces, flash

separator, heat exchangers, pumps and compressors

Vapor liquid equilibrium

Composition profiles of each of the 32 pseudo components in all the reactors

Temperature profile of reactors

7.1. ASPEN FLOWSHEET: Figure 2 shows the process flowsheet of our simulation on ASPEN PLUS and the following

report discuss the modelling and simulation of the flowsheet in detail

Figure 2: Simulation of Catalytic Naphtha Reformer on ASPEN PLUS

39

7.2. TEMPERATURE AND COMPOSITION PROFILES OF THE

REACTORS:

7.2.1. Reactor 1:

Figure 3: Temperature Profile of Reactor 1

Figure 4: Composition Profile of Alkyl Cyclohexane in Reactor 1

40

Figure 5: Composition Profile of Aromatics in Reactor 1

Figure 6: Composition Profile of Hydrogen in Reactor 1

41

7.2.2. Reactor 2:



42



43

7.2.3. Reactor 3:


Figure 12: Composition Profile of N-Paraffins in Reactor 3

44

Figure 13: Composition Profile of I-Paraffins in Reactor 3

Figure 14: Composition Profile of Alkyl Cyclopentanes in Reactor 3

45

Figure 15: Composition Profile of Light Gases in Reactor 3


46

7.2.4. Reactor 4:


Figure 18: Composition Profile of Light Gases in Reactor 4

47

Figure 19: Composition Profile of N-Paraffins in Reactor 4

Figure 20: Composition Profile of I-Paraffins in Reactor 4

48


Figure 22: Composition Profile of Alkyl Cyclopentanes in Reactor 4

49



50

7.3. FLOWSHEET CONNECTIVITY BY STREAM: STREAM SOURCE DEST STREAM SOURCE DEST NAP-HYD ---- B7 S10 E-2 E-3 S11 E-3 B5 S19 G-3 E-5 S16 E-4 F-2 S17 F-2 G-2 S32 F-2 B6 S18 G-2 E-5 S20 E-5 E-6 S21 E-6 E-7 S35 E-7 B6 S22 E-7 E-8 HYDROGEN E-8 ---- S23 E-8 E-9 S31 E-9 E-7 S24 E-9 E-10 S28 E-10 E-8 S25 E-10 F-3 S27 F-3 E-10 S30 F-3 E-9 REFORM E-12 ---- S3 R1 B2 S5 R2 B3 S8 R3 B4 S34 R4 E-2 S2 B1 R1 S4 B2 R2 S6 B3 R3 S33 B4 R4 HP-RCY B5 ---- S12 B5 B9 S37 B6 E-12 S36 B7 B1 S1 B9 B10 S7 B9 G-3 S15 B10 E-4

7.4. FLOWSHEET CONNECTIVITY BY BLOCK BLOCK INLETS OUTLETS E-2 S34 S10 E-3 S10 S11 G-3 S7 S19 E-4 S15 S16 F-2 S16 S17 S32 G-2 S17 S18 E-5 S18 S19 S20 E-6 S20 S21 E-7 S31 S21 S35 S22 E-8 S28 S22 HYDROGEN S23 E-9 S30 S23 S31 S24 E-10 S27 S24 S28 S25 F-3 S25 S27 S30 E-12 S37 REFORM R1 S2 S3 R2 S4 S5 R3 S6 S8 R4 S33 S34 B1 S36 S2 B2 S3 S4 B3 S5 S6 B4 S8 S33 B5 S11 HP-RCY S12 B6 S32 S35 S37 B7 NAP-HYD S36 B9 S12 S1 S7 B10 S1 S15

51

7.5. OVERALL FLOWSHEET BALANCE:

7.5.1. MASS AND ENERGY BALANCE

IN OUT GENERATION RELATIVE DIFF. CONVENTIONAL COMPONENTS (KMOL/SEC) METHA-01 0.394730E-01 0.161258 0.121785 -0.571436E-13 ETHAN-01 0.432145E-01 0.779090E-01 0.346945E-01 -0.334881E-13 PROPA-01 0.377893E-01 0.377893E-01 0.121364E-09 0.189129E-13 N-BUT-01 0.198300E-01 0.198289E-01 -0.110115E-05 0.116873E-12 ISOBU-01 0.136565E-01 0.136576E-01 0.110129E-05 0.866241E-13 N-PEN-01 0.654766E-02 0.654730E-02 -0.360829E-06 0.199498E-12 2-MET-01 0.142178E-01 0.142181E-01 0.360847E-06 0.186916E-12 N-HEX-01 0.428404E-01 0.170789E-01 -0.257614E-01 0.996931E-13 2-MET-02 0.434016E-01 0.177129E-01 -0.256887E-01 0.984039E-13 N-HEP-01 0.546262E-01 0.214261E-01 -0.332000E-01 0.106129E-12 2-MET-03 0.587418E-01 0.233827E-01 -0.353592E-01 0.105958E-12 N-OCT-01 0.447111E-01 0.110220E-02 -0.436089E-01 0.694007E-14 2:2:4-01 0.632317E-01 0.193708E-02 -0.612946E-01 0.817203E-14 N-NON-01 0.291838E-01 0.104225E-01 -0.187614E-01 0.100040E-12 2:2:5-01 0.456465E-01 0.174362E-01 -0.282103E-01 0.105497E-12 CYCLO-01 0.144048E-01 0.309933E-05 -0.144017E-01 0.114399E-15 METHY-01 0.157144E-01 0.107997E-04 -0.157036E-01 0.789122E-16 ETHYL-01 0.215137E-01 0.933248E-05 -0.215044E-01 0.526794E-16 N-PRO-01 0.336737E-02 0.211257E-05 -0.336525E-02 0.182619E-15 CYCLO-02 0.187076E-03 0.187076E-03 0.126617E-09 0.233125E-12 METHY-02 0.561228E-02 0.560860E-02 -0.367512E-05 0.256239E-12 ETHYL-02 0.121599E-01 0.121469E-01 -0.130307E-04 0.272907E-12 N-PRO-02 0.157144E-01 0.156968E-01 -0.175545E-04 0.278627E-12 N-BUT-02 0.224491E-02 0.224237E-02 -0.254150E-05 0.280310E-12 BENZE-01 0.160885E-01 0.176696 0.160608 0.261225E-12 TOLUE-01 0.203913E-01 0.653040E-01 0.449127E-01 0.274564E-12 M-XYL-01 0.280614E-02 0.335531E-01 0.307469E-01 0.279598E-12 O-XYL-01 0.299321E-02 0.549563E-01 0.519631E-01 0.279923E-12 P-XYL-01 0.673473E-02 0.218134E-01 0.150787E-01 0.279453E-12 ETHYL-03 0.392859E-02 0.182629E-01 0.143343E-01 0.279449E-12 N-PRO-03 0.486397E-02 0.141429E-01 0.927895E-02 0.280761E-12 HYDRO-01 1.16473 2.26091 1.09617 -0.616761E-13

7.5.2. TOTAL BALANCE

MOLE(KMOL/SEC) 1.87057 3.12325 1.25268 -0.142188E-15 MASS(KG/SEC ) 64.8992 64.9016 -0.380335E-04 ENTHALPY(WATT ) -0.127685E+09 -0.174651E+08 -0.863217

7.5.3. CO2 EQUIVALENT SUMMARY

FEED STREAMS CO2E 15.8311 KG/SEC PRODUCT STREAMS CO2E 64.6744 KG/SEC NET STREAMS CO2E PRODUCTION 48.8433 KG/SEC TOTAL CO2E PRODUCTION 48.8433 KG/SEC

52

7.6. COMPONENTS LIST: ID TYPE ALIAS NAME WATER C H2O WATER METHA-01 C CH4 METHANE ETHAN-01 C C2H6 ETHANE PROPA-01 C C3H8 PROPANE N-BUT-01 C C4H10-1 N-BUTANE ISOBU-01 C C4H10-2 ISOBUTANE N-PEN-01 C C5H12-1 N-PENTANE 2-MET-01 C C5H12-2 2-METHYL-BUTANE N-HEX-01 C C6H14-1 N-HEXANE 2-MET-02 C C6H14-2 2-METHYL-PENTANE N-HEP-01 C C7H16-1 N-HEPTANE 2-MET-03 C C7H16-2 2-METHYLHEXANE N-OCT-01 C C8H18-1 N-OCTANE 2:2:4-01 C C8H18-13 2,2,4-TRIMETHYLPENTANE N-NON-01 C C9H20-1 N-NONANE 2:2:5-01 C C9H20-4 2,2,5-TRIMETHYLHEXANE CYCLO-01 C C6H12-1 CYCLOHEXANE METHY-01 C C7H14-6 METHYLCYCLOHEXANE ETHYL-01 C C8H16-8 ETHYLCYCLOHEXANE N-PRO-01 C C9H18-1 N-PROPYLCYCLOHEXANE CYCLO-02 C C5H10-1 CYCLOPENTANE METHY-02 C C6H12-2 METHYLCYCLOPENTANE ETHYL-02 C C7H14-5 ETHYLCYCLOPENTANE N-PRO-02 C C8H16-14 N-PROPYLCYCLOPENTANE N-BUT-02 C C9H18-D1 N-BUTYLCYCLOPENTANE BENZE-01 C C6H6 BENZENE TOLUE-01 C C7H8 TOLUENE M-XYL-01 C C8H10-2 M-XYLENE O-XYL-01 C C8H10-1 O-XYLENE P-XYL-01 C C8H10-3 P-XYLENE ETHYL-03 C C8H10-4 ETHYLBENZENE N-PRO-03 C C9H12-1 N-PROPYLBENZENE HYDRO-01 C H2 HYDROGEN

53

7.7. UNIT OPERATIONS AND PROCESSES INPUT AND RESULTS:

7.7.1. BLOCK: B1 MODEL: HEATER

INLET STREAM: S36 OUTLET STREAM: S2 PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE FREE WATER OPTION SET: STMNBS2 NBS STEAM TABLE SOLUBLE WATER OPTION: SOLU DATA + STM TAB

MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 1.87057 1.87057 0.00000 MASS(KG/SEC ) 64.8992 64.8992 0.00000 ENTHALPY(WATT ) -0.127685E+09 -0.941865E+07 -0.926235

CO2 EQUIVALENT SUMMARY

FEED STREAMS CO2E 15.8311 KG/SEC PRODUCT STREAMS CO2E 15.8311 KG/SEC NET STREAMS CO2E PRODUCTION 0.00000 KG/SEC UTILITIES CO2E PRODUCTION 0.00000 KG/SEC TOTAL CO2E PRODUCTION 0.00000 KG/SEC

INPUT DATA

TWO PHASE TP FLASH FREE WATER CONSIDERED SPECIFIED TEMPERATURE K 798.000 SPECIFIED PRESSURE N/SQM 595,000. MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000

RESULTS

OUTLET TEMPERATURE K 798.00 OUTLET PRESSURE N/SQM 0.59500E+06 HEAT DUTY WATT 0.11827E+09 OUTLET VAPOR FRACTION 1.0000 OUTLET: 1ST LIQUID/TOTAL LIQUID 1.0000

54

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) METHA-01 0.211E-01 0.211E-01 0.00 0.211E-01 ETHAN-01 0.231E-01 0.231E-01 0.00 0.231E-01 PROPA-01 0.202E-01 0.202E-01 0.00 0.202E-01 N-BUT-01 0.106E-01 0.106E-01 0.00 0.106E-01 ISOBU-01 0.730E-02 0.730E-02 0.00 0.730E-02 N-PEN-01 0.350E-02 0.350E-02 0.00 0.350E-02 2-MET-01 0.760E-02 0.760E-02 0.00 0.760E-02 N-HEX-01 0.229E-01 0.229E-01 0.00 0.229E-01 2-MET-02 0.232E-01 0.232E-01 0.00 0.232E-01 N-HEP-01 0.292E-01 0.292E-01 0.00 0.292E-01 2-MET-03 0.314E-01 0.314E-01 0.00 0.314E-01 N-OCT-01 0.239E-01 0.239E-01 0.00 0.239E-01 2:2:4-01 0.338E-01 0.338E-01 0.00 0.338E-01 N-NON-01 0.156E-01 0.156E-01 0.00 0.156E-01 2:2:5-01 0.244E-01 0.244E-01 0.00 0.244E-01 CYCLO-01 0.770E-02 0.770E-02 0.00 0.770E-02 METHY-01 0.840E-02 0.840E-02 0.00 0.840E-02 ETHYL-01 0.115E-01 0.115E-01 0.00 0.115E-01 N-PRO-01 0.180E-02 0.180E-02 0.00 0.180E-02 CYCLO-02 0.100E-03 0.100E-03 0.00 0.100E-03 METHY-02 0.300E-02 0.300E-02 0.00 0.300E-02 ETHYL-02 0.650E-02 0.650E-02 0.00 0.650E-02 N-PRO-02 0.840E-02 0.840E-02 0.00 0.840E-02 N-BUT-02 0.120E-02 0.120E-02 0.00 0.120E-02 BENZE-01 0.860E-02 0.860E-02 0.00 0.860E-02 TOLUE-01 0.109E-01 0.109E-01 0.00 0.109E-01 M-XYL-01 0.150E-02 0.150E-02 0.00 0.150E-02 O-XYL-01 0.160E-02 0.160E-02 0.00 0.160E-02 P-XYL-01 0.360E-02 0.360E-02 0.00 0.360E-02 ETHYL-03 0.210E-02 0.210E-02 0.00 0.210E-02 N-PRO-03 0.260E-02 0.260E-02 0.00 0.260E-02 HYDRO-01 0.623 0.623 0.00 0.623

55



MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 2.01030 2.01030 0.00000 MASS(KG/SEC ) 64.8992 64.8992 -0.218968E-15 ENTHALPY(WATT ) -0.941865E+07 440512. -1.04677



INPUT DATA


RESULTS


56


57



MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 2.03568 2.03568 0.00000 MASS(KG/SEC ) 64.9017 64.9017 0.00000 ENTHALPY(WATT ) 440512. 0.229288E+07 -0.807878



INPUT DATA


RESULTS


58

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) METHA-01 0.194E-01 0.194E-01 0.00 0.194E-01 ETHAN-01 0.212E-01 0.212E-01 0.00 0.212E-01 PROPA-01 0.186E-01 0.186E-01 0.00 0.186E-01 N-BUT-01 0.974E-02 0.974E-02 0.00 0.974E-02 ISOBU-01 0.671E-02 0.671E-02 0.00 0.671E-02 N-PEN-01 0.322E-02 0.322E-02 0.00 0.322E-02 2-MET-01 0.698E-02 0.698E-02 0.00 0.698E-02 N-HEX-01 0.210E-01 0.210E-01 0.00 0.210E-01 2-MET-02 0.213E-01 0.213E-01 0.00 0.213E-01 N-HEP-01 0.268E-01 0.268E-01 0.00 0.268E-01 2-MET-03 0.289E-01 0.289E-01 0.00 0.289E-01 N-OCT-01 0.220E-01 0.220E-01 0.00 0.220E-01 2:2:4-01 0.311E-01 0.311E-01 0.00 0.311E-01 N-NON-01 0.143E-01 0.143E-01 0.00 0.143E-01 2:2:5-01 0.224E-01 0.224E-01 0.00 0.224E-01 CYCLO-02 0.919E-04 0.919E-04 0.00 0.919E-04 METHY-02 0.276E-02 0.276E-02 0.00 0.276E-02 ETHYL-02 0.597E-02 0.597E-02 0.00 0.597E-02 N-PRO-02 0.772E-02 0.772E-02 0.00 0.772E-02 N-BUT-02 0.110E-02 0.110E-02 0.00 0.110E-02 BENZE-01 0.150E-01 0.150E-01 0.00 0.150E-01 TOLUE-01 0.177E-01 0.177E-01 0.00 0.177E-01 M-XYL-01 0.392E-02 0.392E-02 0.00 0.392E-02 O-XYL-01 0.419E-02 0.419E-02 0.00 0.419E-02 P-XYL-01 0.596E-02 0.596E-02 0.00 0.596E-02 ETHYL-03 0.459E-02 0.459E-02 0.00 0.459E-02 N-PRO-03 0.405E-02 0.405E-02 0.00 0.405E-02 HYDRO-01 0.653 0.653 0.00 0.653

59



MASS AND ENERGY BALANCE

IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 2.56515 2.56515 0.00000 MASS(KG/SEC ) 64.9017 64.9017 0.00000 ENTHALPY(WATT ) 0.229288E+07 0.364166E+08 -0.937038



INPUT DATA


RESULTS


60

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) METHA-01 0.154E-01 0.154E-01 0.00 0.154E-01 ETHAN-01 0.168E-01 0.168E-01 0.00 0.168E-01 PROPA-01 0.147E-01 0.147E-01 0.00 0.147E-01 N-BUT-01 0.773E-02 0.773E-02 0.00 0.773E-02 ISOBU-01 0.532E-02 0.532E-02 0.00 0.532E-02 N-PEN-01 0.255E-02 0.255E-02 0.00 0.255E-02 2-MET-01 0.554E-02 0.554E-02 0.00 0.554E-02 N-HEX-01 0.128E-01 0.128E-01 0.00 0.128E-01 2-MET-02 0.131E-01 0.131E-01 0.00 0.131E-01 N-HEP-01 0.163E-01 0.163E-01 0.00 0.163E-01 2-MET-03 0.176E-01 0.176E-01 0.00 0.176E-01 N-OCT-01 0.632E-02 0.632E-02 0.00 0.632E-02 2:2:4-01 0.945E-02 0.945E-02 0.00 0.945E-02 N-NON-01 0.847E-02 0.847E-02 0.00 0.847E-02 2:2:5-01 0.135E-01 0.135E-01 0.00 0.135E-01 CYCLO-02 0.729E-04 0.729E-04 0.00 0.729E-04 METHY-02 0.219E-02 0.219E-02 0.00 0.219E-02 ETHYL-02 0.474E-02 0.474E-02 0.00 0.474E-02 N-PRO-02 0.613E-02 0.613E-02 0.00 0.613E-02 N-BUT-02 0.875E-03 0.875E-03 0.00 0.875E-03 BENZE-01 0.196E-01 0.196E-01 0.00 0.196E-01 TOLUE-01 0.244E-01 0.244E-01 0.00 0.244E-01 M-XYL-01 0.970E-02 0.970E-02 0.00 0.970E-02 O-XYL-01 0.101E-01 0.101E-01 0.00 0.101E-01 P-XYL-01 0.112E-01 0.112E-01 0.00 0.112E-01 ETHYL-03 0.101E-01 0.101E-01 0.00 0.101E-01 N-PRO-03 0.104E-01 0.104E-01 0.00 0.104E-01 HYDRO-01 0.725 0.725 0.00 0.725

61

7.7.5. BLOCK: B5 MODEL: FLASH2

INLET STREAM: S11 OUTLET VAPOR STREAM: HP-RCY OUTLET LIQUID STREAM: S12 PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE FREE WATER OPTION SET: STMNBS2 NBS STEAM TABLE SOLUBLE WATER OPTION: SOLU DATA + STM TAB

MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 3.12325 3.12325 -0.142188E-15 MASS(KG/SEC ) 64.9016 64.9016 0.212610E-12 ENTHALPY(WATT ) -0.505352E+08 -0.536059E+08 0.572825E-01



INPUT DATA

TWO PHASE TP FLASH FREE WATER CONSIDERED SPECIFIED TEMPERATURE K 313.000 SPECIFIED PRESSURE N/SQM 2,230,000. MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000

RESULTS

OUTLET TEMPERATURE K 313.00 OUTLET PRESSURE N/SQM 0.22300E+07 HEAT DUTY WATT -0.30707E+07 VAPOR FRACTION 0.81824 1ST LIQUID/TOTAL LIQUID 1.0000

62

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) K1(I) METHA-01 0.516E-01 0.467E-02 0.00 0.621E-01 13.3 ETHAN-01 0.249E-01 0.119E-01 0.00 0.278E-01 2.35 PROPA-01 0.121E-01 0.159E-01 0.00 0.113E-01 0.711 N-BUT-01 0.635E-02 0.183E-01 0.00 0.370E-02 0.202 ISOBU-01 0.437E-02 0.105E-01 0.00 0.302E-02 0.289 N-PEN-01 0.210E-02 0.880E-02 0.00 0.608E-03 0.692E-01 2-MET-01 0.455E-02 0.182E-01 0.00 0.152E-02 0.838E-01 N-HEX-01 0.547E-02 0.273E-01 0.00 0.611E-03 0.223E-01 2-MET-02 0.567E-02 0.276E-01 0.00 0.811E-03 0.295E-01 N-HEP-01 0.686E-02 0.365E-01 0.00 0.274E-03 0.750E-02 2-MET-03 0.749E-02 0.393E-01 0.00 0.416E-03 0.106E-01 N-OCT-01 0.353E-03 0.192E-02 0.00 0.485E-05 0.253E-02 2:2:4-01 0.620E-03 0.328E-02 0.00 0.284E-04 0.864E-02 N-NON-01 0.334E-02 0.183E-01 0.00 0.171E-04 0.936E-03 2:2:5-01 0.558E-02 0.302E-01 0.00 0.110E-03 0.363E-02 CYCLO-01 0.992E-06 0.516E-05 0.00 0.656E-07 0.127E-01 METHY-01 0.346E-05 0.185E-04 0.00 0.118E-06 0.638E-02 ETHYL-01 0.299E-05 0.163E-04 0.00 0.377E-07 0.232E-02 N-PRO-01 0.676E-06 0.371E-05 0.00 0.361E-08 0.975E-03 CYCLO-02 0.599E-04 0.283E-03 0.00 0.103E-04 0.363E-01 METHY-02 0.180E-02 0.917E-02 0.00 0.159E-03 0.173E-01 ETHYL-02 0.389E-02 0.209E-01 0.00 0.117E-03 0.559E-02 N-PRO-02 0.503E-02 0.274E-01 0.00 0.529E-04 0.193E-02 N-BUT-02 0.718E-03 0.394E-02 0.00 0.274E-05 0.695E-03 BENZE-01 0.566E-01 0.293 0.00 0.409E-02 0.140E-01 TOLUE-01 0.209E-01 0.113 0.00 0.512E-03 0.454E-02 M-XYL-01 0.107E-01 0.588E-01 0.00 0.763E-04 0.130E-02 O-XYL-01 0.176E-01 0.963E-01 0.00 0.107E-03 0.111E-02 P-XYL-01 0.698E-02 0.382E-01 0.00 0.516E-04 0.135E-02 ETHYL-03 0.585E-02 0.320E-01 0.00 0.487E-04 0.153E-02 N-PRO-03 0.453E-02 0.248E-01 0.00 0.146E-04 0.588E-03 HYDRO-01 0.724 0.101E-01 0.00 0.882 87.6

63

7.7.6. BLOCK: B10 MODEL: PUMP



IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.283834 0.283834 0.00000 MASS(KG/SEC ) 25.6848 25.6848 -0.138320E-15 ENTHALPY(WATT ) -0.153587E+08 -0.153875E+08 0.187062E-02

CO2 EQUIVALENT SUMMARY FEED STREAMS CO2E 0.531376 KG/SEC PRODUCT STREAMS CO2E 0.531376 KG/SEC NET STREAMS CO2E PRODUCTION 0.00000 KG/SEC UTILITIES CO2E PRODUCTION 0.00000 KG/SEC TOTAL CO2E PRODUCTION 0.00000 KG/SEC

INPUT DATA

OUTLET PRESSURE N/SQM 1,000,000. DRIVER EFFICIENCY 1.00000 FLASH SPECIFICATIONS: LIQUID PHASE CALCULATION NO FLASH PERFORMED FREE WATER CONSIDERED MAXIMUM NUMBER OF ITERATIONS 30 TOLERANCE 0.000100000

RESULTS

VOLUMETRIC FLOW RATE CUM/SEC 0.032669 PRESSURE CHANGE N/SQM -1,230,000. NPSH AVAILABLE J/KG 0.0 FLUID POWER WATT -40,183.2 BRAKE POWER WATT -28,784.3 ELECTRICITY WATT -28,784.3 PUMP EFFICIENCY USED 0.71633 NET WORK REQUIRED WATT -28,784.3 HEAD DEVELOPED J/KG -1,564.48

64

7.7.7. BLOCK: E-10 MODEL: HEATX

HOT SIDE: --------- INLET STREAM: S27 OUTLET STREAM: S28 PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE FREE WATER OPTION SET: STMNBS2 NBS STEAM TABLE SOLUBLE WATER OPTION: SOLU DATA + STM TAB COLD SIDE: ---------- INLET STREAM: S24 OUTLET STREAM: S25 PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE FREE WATER OPTION SET: STMNBS2 NBS STEAM TABLE SOLUBLE WATER OPTION: SOLU DATA + STM TAB

MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.287063 0.287063 0.00000 MASS(KG/SEC ) 25.6952 25.6952 0.00000 ENTHALPY(WATT ) -0.158153E+08 -0.158153E+08 0.353324E-15


INPUT DATA FLASH SPECS FOR HOT SIDE: TWO PHASE FLASH FREE WATER CONSIDERED MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000 FLASH SPECS FOR COLD SIDE: TWO PHASE FLASH FREE WATER CONSIDERED MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000 FLOW DIRECTION AND SPECIFICATION: COUNTERCURRENT HEAT EXCHANGER SPECIFIED HOT APPROACH TEMP SPECIFIED VALUE K 5.0000 TEMPERATURE TOLERANCE K 0.01000 LMTD CORRECTION FACTOR 1.00000

65

PRESSURE SPECIFICATION: HOT SIDE PRESSURE DROP N/SQM 0.0000 COLD SIDE PRESSURE DROP N/SQM 0.0000 HEAT TRANSFER COEFFICIENT SPECIFICATION: HOT LIQUID COLD LIQUID WATT/SQM-K 850.0000 HOT 2-PHASE COLD LIQUID WATT/SQM-K 850.0000 HOT VAPOR COLD LIQUID WATT/SQM-K 850.0000 HOT LIQUID COLD 2-PHASE WATT/SQM-K 850.0000 HOT 2-PHASE COLD 2-PHASE WATT/SQM-K 850.0000 HOT VAPOR COLD 2-PHASE WATT/SQM-K 850.0000 HOT LIQUID COLD VAPOR WATT/SQM-K 850.0000 HOT 2-PHASE COLD VAPOR WATT/SQM-K 850.0000 HOT VAPOR COLD VAPOR WATT/SQM-K 850.0000

OVERALL RESULTS STREAMS: -------------------------------------- | | S27 ----->| HOT |-----> S28 T= 3.1300D+02 | | T= 3.0800D+02 P= 3.1000D+06 | | P= 3.1000D+06 V= 1.0000D+00 | | V= 9.9948D-01 | | S25 <-----| COLD |<----- S24 T= 3.0300D+02 | | T= 3.0300D+02 P= 3.2000D+06 | | P= 3.2000D+06 V= 3.5936D-03 | | V= 3.5939D-03 -------------------------------------- DUTY AND AREA: CALCULATED HEAT DUTY WATT 171.9239 CALCULATED (REQUIRED) AREA SQM 0.0280 ACTUAL EXCHANGER AREA SQM 0.0280 PER CENT OVER-DESIGN 0.0000 HEAT TRANSFER COEFFICIENT: AVERAGE COEFFICIENT (DIRTY) WATT/SQM-K 850.0000 UA (DIRTY) J/SEC-K 23.8386 LOG-MEAN TEMPERATURE DIFFERENCE: LMTD CORRECTION FACTOR 1.0000 LMTD (CORRECTED) K 7.2120 NUMBER OF SHELLS IN SERIES 1 PRESSURE DROP: HOTSIDE, TOTAL N/SQM 0.0000 COLDSIDE, TOTAL N/SQM 0.0000

66

ZONE RESULTS TEMPERATURE LEAVING EACH ZONE: HOT ------------------------------------------------------------- | | HOT IN | COND | HOT OUT ------> | |------> 313.0 | | 308.0 | | COLDOUT | BOIL | COLDIN <------ | |<------ 303.0 | | 303.0 | | ------------------------------------------------------------- COLD ZONE HEAT TRANSFER AND AREA: ZONE HEAT DUTY AREA LMTD AVERAGE U UA WATT SQM K WATT/SQM-K J/SEC-K 1 171.924 0.0280 7.2120 850.0000 23.8386

67

7.7.8. BLOCK: E-12 MODEL: HEATER

INLET STREAM: S37 OUTLET STREAM: REFORM PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE FREE WATER OPTION SET: STMNBS2 NBS STEAM TABLE SOLUBLE WATER OPTION: SOLU DATA + STM TAB

MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.566680 0.566680 0.00000 MASS(KG/SEC ) 51.3651 51.3651 0.00000 ENTHALPY(WATT ) -0.477600E+08 0.544065E+07 -1.11392


INPUT DATA TWO PHASE TP FLASH FREE WATER CONSIDERED SPECIFIED TEMPERATURE K 500.000 SPECIFIED PRESSURE N/SQM 101,325. MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000

RESULTS


68

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) K1(I) METHA-01 0.459E-02 0.159E-03 0.00 0.459E-02 282. ETHAN-01 0.119E-01 0.829E-03 0.00 0.119E-01 139. PROPA-01 0.159E-01 0.186E-02 0.00 0.159E-01 83.2 N-BUT-01 0.183E-01 0.366E-02 0.00 0.183E-01 48.6 ISOBU-01 0.105E-01 0.183E-02 0.00 0.105E-01 55.6 N-PEN-01 0.881E-02 0.284E-02 0.00 0.881E-02 30.2 2-MET-01 0.182E-01 0.545E-02 0.00 0.182E-01 32.5 N-HEX-01 0.274E-01 0.143E-01 0.00 0.274E-01 18.7 2-MET-02 0.276E-01 0.130E-01 0.00 0.276E-01 20.7 N-HEP-01 0.366E-01 0.303E-01 0.00 0.366E-01 11.7 2-MET-03 0.394E-01 0.289E-01 0.00 0.394E-01 13.2 N-OCT-01 0.192E-02 0.253E-02 0.00 0.192E-02 7.41 2:2:4-01 0.329E-02 0.293E-02 0.00 0.329E-02 10.9 N-NON-01 0.183E-01 0.375E-01 0.00 0.183E-01 4.76 2:2:5-01 0.303E-01 0.405E-01 0.00 0.303E-01 7.28 CYCLO-01 0.517E-05 0.350E-05 0.00 0.517E-05 14.4 METHY-01 0.185E-04 0.177E-04 0.00 0.185E-04 10.2 ETHYL-01 0.163E-04 0.268E-04 0.00 0.163E-04 5.92 N-PRO-01 0.371E-05 0.951E-05 0.00 0.371E-05 3.80 CYCLO-02 0.284E-03 0.117E-03 0.00 0.284E-03 23.6 METHY-02 0.918E-02 0.538E-02 0.00 0.918E-02 16.6 ETHYL-02 0.209E-01 0.202E-01 0.00 0.209E-01 10.1 N-PRO-02 0.275E-01 0.417E-01 0.00 0.275E-01 6.41 N-BUT-02 0.394E-02 0.942E-02 0.00 0.394E-02 4.08 BENZE-01 0.293 0.178 0.00 0.293 16.0 TOLUE-01 0.113 0.113 0.00 0.113 9.72 M-XYL-01 0.589E-01 0.975E-01 0.00 0.589E-01 5.88 O-XYL-01 0.965E-01 0.173 0.00 0.965E-01 5.44 P-XYL-01 0.383E-01 0.631E-01 0.00 0.383E-01 5.90 ETHYL-03 0.320E-01 0.510E-01 0.00 0.320E-01 6.12 N-PRO-03 0.249E-01 0.606E-01 0.00 0.249E-01 4.00 HYDRO-01 0.850E-02 0.139E-03 0.00 0.850E-02 597.

69



MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 3.12325 3.12325 0.00000 MASS(KG/SEC ) 64.9016 64.9016 0.00000 ENTHALPY(WATT ) 0.364166E+08 0.105812E+09 -0.655838



INPUT DATA

TWO PHASE TP FLASH FREE WATER CONSIDERED SPECIFIED TEMPERATURE CHANGE K 282.000 SPECIFIED PRESSURE N/SQM 430,000. MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000

RESULTS


70


71



MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 3.12325 3.12325 0.00000 MASS(KG/SEC ) 64.9016 64.9016 0.00000 ENTHALPY(WATT ) 0.105812E+09 -0.505352E+08 1.47759



INPUT DATA


RESULTS OUTLET TEMPERATURE K 313.00 OUTLET PRESSURE N/SQM 0.40000E+06 HEAT DUTY WATT -0.15635E+09 OUTLET VAPOR FRACTION 0.85574 OUTLET: 1ST LIQUID/TOTAL LIQUID 1.0000

72

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) K1(I) K2(I) METHA-01 0.516E-01 0.826E-03 0.00 0.602E-01 72.9 ETHAN-01 0.249E-01 0.230E-02 0.00 0.288E-01 12.5 PROPA-01 0.121E-01 0.361E-02 0.00 0.135E-01 3.75 N-BUT-01 0.635E-02 0.614E-02 0.00 0.638E-02 1.04 ISOBU-01 0.437E-02 0.306E-02 0.00 0.459E-02 1.50 N-PEN-01 0.210E-02 0.475E-02 0.00 0.165E-02 0.348 2-MET-01 0.455E-02 0.892E-02 0.00 0.382E-02 0.428 N-HEX-01 0.547E-02 0.228E-01 0.00 0.255E-02 0.112 2-MET-02 0.567E-02 0.209E-01 0.00 0.310E-02 0.148 N-HEP-01 0.686E-02 0.390E-01 0.00 0.145E-02 0.372E-01 2-MET-03 0.749E-02 0.396E-01 0.00 0.207E-02 0.524E-01 N-OCT-01 0.353E-03 0.228E-02 0.00 0.282E-04 0.124E-01 2:2:4-01 0.620E-03 0.343E-02 0.00 0.147E-03 0.427E-01 N-NON-01 0.334E-02 0.225E-01 0.00 0.101E-03 0.448E-02 2:2:5-01 0.558E-02 0.350E-01 0.00 0.621E-03 0.177E-01 CYCLO-01 0.992E-06 0.501E-05 0.00 0.315E-06 0.627E-01 METHY-01 0.346E-05 0.202E-04 0.00 0.632E-06 0.312E-01 ETHYL-01 0.299E-05 0.194E-04 0.00 0.217E-06 0.112E-01 N-PRO-01 0.676E-06 0.456E-05 0.00 0.212E-07 0.465E-02 CYCLO-02 0.599E-04 0.200E-03 0.00 0.363E-04 0.182 METHY-02 0.180E-02 0.824E-02 0.00 0.709E-03 0.860E-01 ETHYL-02 0.389E-02 0.232E-01 0.00 0.633E-03 0.273E-01 N-PRO-02 0.503E-02 0.330E-01 0.00 0.307E-03 0.929E-02 N-BUT-02 0.718E-03 0.488E-02 0.00 0.161E-04 0.330E-02 BENZE-01 0.566E-01 0.279 0.00 0.191E-01 0.686E-01 TOLUE-01 0.209E-01 0.128 0.00 0.280E-02 0.218E-01 M-XYL-01 0.107E-01 0.718E-01 0.00 0.445E-03 0.619E-02 O-XYL-01 0.176E-01 0.118 0.00 0.621E-03 0.525E-02 P-XYL-01 0.698E-02 0.466E-01 0.00 0.300E-03 0.644E-02 ETHYL-03 0.585E-02 0.389E-01 0.00 0.283E-03 0.729E-02 N-PRO-03 0.453E-02 0.309E-01 0.00 0.856E-04 0.277E-02 HYDRO-01 0.724 0.170E-02 0.00 0.846 497.

73



MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.283834 0.283834 0.00000 MASS(KG/SEC ) 25.6848 25.6848 0.00000 ENTHALPY(WATT ) -0.153875E+08 -0.201632E+08 0.236852



INPUT DATA


RESULTS

OUTLET TEMPERATURE K 200.00 OUTLET PRESSURE N/SQM 0.10000E+07 HEAT DUTY WATT -0.47757E+07 OUTLET VAPOR FRACTION 0.78950E-02 OUTLET: 1ST LIQUID/TOTAL LIQUID 1.0000

74

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) K1(I) K2(I) METHA-01 0.467E-02 0.438E-02 0.00 0.403E-01 9.20 ETHAN-01 0.119E-01 0.119E-01 0.00 0.348E-02 0.291 PROPA-01 0.159E-01 0.160E-01 0.00 0.451E-03 0.282E-01 N-BUT-01 0.183E-01 0.184E-01 0.00 0.445E-04 0.242E-02 ISOBU-01 0.105E-01 0.105E-01 0.00 0.533E-04 0.505E-02 N-PEN-01 0.880E-02 0.887E-02 0.00 0.258E-05 0.291E-03 2-MET-01 0.182E-01 0.183E-01 0.00 0.835E-05 0.456E-03 N-HEX-01 0.273E-01 0.276E-01 0.00 0.847E-06 0.307E-04 2-MET-02 0.276E-01 0.278E-01 0.00 0.157E-05 0.565E-04 N-HEP-01 0.365E-01 0.368E-01 0.00 0.128E-06 0.349E-05 2-MET-03 0.393E-01 0.396E-01 0.00 0.292E-06 0.737E-05 N-OCT-01 0.192E-02 0.194E-02 0.00 0.748E-09 0.387E-06 2:2:4-01 0.328E-02 0.331E-02 0.00 0.216E-07 0.653E-05 N-NON-01 0.183E-01 0.184E-01 0.00 0.993E-09 0.539E-07 2:2:5-01 0.302E-01 0.305E-01 0.00 0.370E-07 0.121E-05 CYCLO-01 0.516E-05 0.521E-05 0.00 0.762E-10 0.146E-04 METHY-01 0.185E-04 0.186E-04 0.00 0.767E-10 0.412E-05 ETHYL-01 0.163E-04 0.164E-04 0.00 0.121E-10 0.739E-06 N-PRO-01 0.371E-05 0.373E-05 0.00 0.606E-12 0.162E-06 CYCLO-02 0.283E-03 0.286E-03 0.00 0.283E-07 0.990E-04 METHY-02 0.917E-02 0.924E-02 0.00 0.223E-06 0.241E-04 ETHYL-02 0.209E-01 0.210E-01 0.00 0.567E-07 0.270E-05 N-PRO-02 0.274E-01 0.276E-01 0.00 0.867E-08 0.314E-06 N-BUT-02 0.394E-02 0.397E-02 0.00 0.165E-09 0.416E-07 BENZE-01 0.293 0.295 0.00 0.462E-05 0.156E-04 TOLUE-01 0.113 0.114 0.00 0.193E-06 0.170E-05 M-XYL-01 0.588E-01 0.592E-01 0.00 0.783E-08 0.132E-06 O-XYL-01 0.963E-01 0.971E-01 0.00 0.101E-07 0.104E-06 P-XYL-01 0.382E-01 0.385E-01 0.00 0.565E-08 0.147E-06 ETHYL-03 0.320E-01 0.322E-01 0.00 0.644E-08 0.200E-06 N-PRO-03 0.248E-01 0.250E-01 0.00 0.769E-09 0.307E-07 HYDRO-01 0.101E-01 0.255E-02 0.00 0.956 375.

75


INLET STREAMS: S18 S19 OUTLET STREAM: S20 PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE FREE WATER OPTION SET: STMNBS2 NBS STEAM TABLE SOLUBLE WATER OPTION: SOLU DATA + STM TAB

MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.286075 0.286075 0.00000 MASS(KG/SEC ) 25.6908 25.6908 0.138287E-15 ENTHALPY(WATT ) -0.153211E+08 -0.148351E+08 -0.317227E-01



INPUT DATA

TWO PHASE TP FLASH FREE WATER CONSIDERED SPECIFIED TEMPERATURE CHANGE K 10.0000 SPECIFIED PRESSURE N/SQM 3,200,000. MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000

RESULTS

OUTLET TEMPERATURE K 323.29 OUTLET PRESSURE N/SQM 0.32000E+07 HEAT DUTY WATT 0.48603E+06 OUTLET VAPOR FRACTION 0.21721E-02 OUTLET: 1ST LIQUID/TOTAL LIQUID 1.0000

76

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) K1(I) K2(I) METHA-01 0.495E-02 0.485E-02 0.00 0.476E-01 9.81 ETHAN-01 0.118E-01 0.118E-01 0.00 0.225E-01 1.91 PROPA-01 0.157E-01 0.157E-01 0.00 0.971E-02 0.617 N-BUT-01 0.181E-01 0.182E-01 0.00 0.342E-02 0.188 ISOBU-01 0.104E-01 0.104E-01 0.00 0.274E-02 0.263 N-PEN-01 0.873E-02 0.874E-02 0.00 0.597E-03 0.683E-01 2-MET-01 0.180E-01 0.181E-01 0.00 0.148E-02 0.817E-01 N-HEX-01 0.271E-01 0.272E-01 0.00 0.639E-03 0.235E-01 2-MET-02 0.273E-01 0.274E-01 0.00 0.834E-03 0.305E-01 N-HEP-01 0.362E-01 0.363E-01 0.00 0.303E-03 0.834E-02 2-MET-03 0.390E-01 0.391E-01 0.00 0.453E-03 0.116E-01 N-OCT-01 0.190E-02 0.191E-02 0.00 0.575E-05 0.301E-02 2:2:4-01 0.326E-02 0.327E-02 0.00 0.309E-04 0.947E-02 N-NON-01 0.181E-01 0.182E-01 0.00 0.215E-04 0.118E-02 2:2:5-01 0.300E-01 0.301E-01 0.00 0.125E-03 0.417E-02 CYCLO-01 0.512E-05 0.513E-05 0.00 0.698E-07 0.136E-01 METHY-01 0.183E-04 0.184E-04 0.00 0.130E-06 0.707E-02 ETHYL-01 0.161E-04 0.162E-04 0.00 0.434E-07 0.268E-02 N-PRO-01 0.368E-05 0.368E-05 0.00 0.433E-08 0.118E-02 CYCLO-02 0.281E-03 0.282E-03 0.00 0.104E-04 0.369E-01 METHY-02 0.909E-02 0.911E-02 0.00 0.167E-03 0.183E-01 ETHYL-02 0.207E-01 0.208E-01 0.00 0.130E-03 0.627E-02 N-PRO-02 0.272E-01 0.273E-01 0.00 0.629E-04 0.231E-02 N-BUT-02 0.391E-02 0.392E-02 0.00 0.344E-05 0.879E-03 BENZE-01 0.291 0.291 0.00 0.435E-02 0.149E-01 TOLUE-01 0.112 0.112 0.00 0.579E-03 0.517E-02 M-XYL-01 0.583E-01 0.584E-01 0.00 0.930E-04 0.159E-02 O-XYL-01 0.956E-01 0.958E-01 0.00 0.130E-03 0.136E-02 P-XYL-01 0.379E-01 0.380E-01 0.00 0.626E-04 0.165E-02 ETHYL-03 0.317E-01 0.318E-01 0.00 0.586E-04 0.184E-02 N-PRO-03 0.247E-01 0.247E-01 0.00 0.185E-04 0.749E-03 HYDRO-01 0.175E-01 0.156E-01 0.00 0.904 58.1

77



MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.286075 0.286075 0.00000 MASS(KG/SEC ) 25.6908 25.6908 0.00000 ENTHALPY(WATT ) -0.148351E+08 -0.280988E+08 0.472037



INPUT DATA


RESULTS

OUTLET TEMPERATURE K 10.000 OUTLET PRESSURE N/SQM 0.32000E+07 HEAT DUTY WATT -0.13264E+08 OUTLET VAPOR FRACTION 0.17494E-01 OUTLET: 1ST LIQUID/TOTAL LIQUID 1.0000

78

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) K1(I) METHA-01 0.495E-02 0.504E-02 0.00 0.448E-08 0.890E-06 ETHAN-01 0.118E-01 0.120E-01 0.00 0.256E-03 0.214E-01 PROPA-01 0.157E-01 0.160E-01 0.00 0.168E-03 0.105E-01 N-BUT-01 0.181E-01 0.185E-01 0.00 0.633E-04 0.343E-02 ISOBU-01 0.104E-01 0.106E-01 0.00 0.537E-04 0.509E-02 N-PEN-01 0.873E-02 0.888E-02 0.00 0.105E-04 0.118E-02 2-MET-01 0.180E-01 0.184E-01 0.00 0.291E-04 0.158E-02 N-HEX-01 0.271E-01 0.276E-01 0.00 0.867E-05 0.314E-03 2-MET-02 0.273E-01 0.278E-01 0.00 0.148E-04 0.531E-03 N-HEP-01 0.362E-01 0.369E-01 0.00 0.227E-05 0.616E-04 2-MET-03 0.390E-01 0.397E-01 0.00 0.725E-05 0.183E-03 N-OCT-01 0.190E-02 0.194E-02 0.00 0.689E-07 0.356E-04 2:2:4-01 0.326E-02 0.332E-02 0.00 0.769E-06 0.232E-03 N-NON-01 0.181E-01 0.185E-01 0.00 0.232E-06 0.126E-04 2:2:5-01 0.300E-01 0.305E-01 0.00 0.303E-05 0.993E-04 CYCLO-01 0.512E-05 0.522E-05 0.00 0.225E-08 0.432E-03 METHY-01 0.183E-04 0.187E-04 0.00 0.457E-08 0.245E-03 ETHYL-01 0.161E-04 0.164E-04 0.00 0.229E-08 0.139E-03 N-PRO-01 0.368E-05 0.374E-05 0.00 0.299E-09 0.798E-04 CYCLO-02 0.281E-03 0.286E-03 0.00 0.268E-06 0.936E-03 METHY-02 0.909E-02 0.926E-02 0.00 0.439E-05 0.474E-03 ETHYL-02 0.207E-01 0.211E-01 0.00 0.344E-05 0.163E-03 N-PRO-02 0.272E-01 0.277E-01 0.00 0.141E-05 0.508E-04 N-BUT-02 0.391E-02 0.398E-02 0.00 0.709E-07 0.178E-04 BENZE-01 0.291 0.296 0.00 0.120E-03 0.406E-03 TOLUE-01 0.112 0.114 0.00 0.149E-04 0.131E-03 M-XYL-01 0.583E-01 0.593E-01 0.00 0.190E-05 0.321E-04 O-XYL-01 0.956E-01 0.973E-01 0.00 0.311E-05 0.320E-04 P-XYL-01 0.379E-01 0.386E-01 0.00 0.134E-05 0.348E-04 ETHYL-03 0.317E-01 0.323E-01 0.00 0.143E-05 0.444E-04 N-PRO-03 0.247E-01 0.251E-01 0.00 0.428E-06 0.171E-04 HYDRO-01 0.175E-01 0.114E-06 0.00 0.999 0.878E+07

79



MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.571162 0.571162 0.00000 MASS(KG/SEC ) 51.3772 51.3772 0.00000 ENTHALPY(WATT ) -0.555581E+08 -0.555583E+08 0.331043E-05



INPUT DATA FLASH SPECS FOR HOT SIDE: TWO PHASE FLASH FREE WATER CONSIDERED MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000 FLASH SPECS FOR COLD SIDE: TWO PHASE FLASH FREE WATER CONSIDERED MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000 FLOW DIRECTION AND SPECIFICATION: COUNTERCURRENT HEAT EXCHANGER SPECIFIED MIN OUTLET TEMP APPR SPECIFIED VALUE K 5.0000 LMTD CORRECTION FACTOR 1.00000

80

PRESSURE SPECIFICATION: HOT SIDE PRESSURE DROP N/SQM 0.0000 COLD SIDE PRESSURE DROP N/SQM 0.0000 HEAT TRANSFER COEFFICIENT SPECIFICATION: HOT LIQUID COLD LIQUID WATT/SQM-K 850.0000 HOT 2-PHASE COLD LIQUID WATT/SQM-K 850.0000 HOT VAPOR COLD LIQUID WATT/SQM-K 850.0000 HOT LIQUID COLD 2-PHASE WATT/SQM-K 850.0000 HOT 2-PHASE COLD 2-PHASE WATT/SQM-K 850.0000 HOT VAPOR COLD 2-PHASE WATT/SQM-K 850.0000 HOT LIQUID COLD VAPOR WATT/SQM-K 850.0000 HOT 2-PHASE COLD VAPOR WATT/SQM-K 850.0000 HOT VAPOR COLD VAPOR WATT/SQM-K 850.0000

OVERALL RESULTS STREAMS: -------------------------------------- | | S31 ----->| HOT |-----> S35 T= 1.9662D+01 | | T= 1.7148D+01 P= 3.1000D+06 | | P= 3.1000D+06 V= 1.4574D-02 | | V= 1.4500D-02 | | S22 <-----| COLD |<----- S21 T= 1.2143D+01 | | T= 1.0000D+01 P= 3.2000D+06 | | P= 3.2000D+06 V= 1.7507D-02 | | V= 1.7494D-02 -------------------------------------- DUTY AND AREA: CALCULATED HEAT DUTY WATT 151139.6190 CALCULATED (REQUIRED) AREA SQM 24.2567 ACTUAL EXCHANGER AREA SQM 24.2567 PER CENT OVER-DESIGN 0.0000 HEAT TRANSFER COEFFICIENT: AVERAGE COEFFICIENT (DIRTY) WATT/SQM-K 850.0000 UA (DIRTY) J/SEC-K 20618.2362 LOG-MEAN TEMPERATURE DIFFERENCE: LMTD CORRECTION FACTOR 1.0000 LMTD (CORRECTED) K 7.3304 NUMBER OF SHELLS IN SERIES 1 PRESSURE DROP: HOTSIDE, TOTAL N/SQM 0.0000 COLDSIDE, TOTAL N/SQM 0.0000

81


82


HOT SIDE: --------- INLET STREAM: S28 OUTLET STREAM: HYDROGEN PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE FREE WATER OPTION SET: STMNBS2 NBS STEAM TABLE SOLUBLE WATER OPTION: SOLU DATA + STM TAB COLD SIDE: ---------- INLET STREAM: S22 OUTLET STREAM: S23 PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE FREE WATER OPTION SET: STMNBS2 NBS STEAM TABLE SOLUBLE WATER OPTION: SOLU DATA + STM TAB

MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.287063 0.287063 0.00000 MASS(KG/SEC ) 25.6952 25.6952 0.00000 ENTHALPY(WATT ) -0.279542E+08 -0.279542E+08 -0.586926E-10



INPUT DATA FLASH SPECS FOR HOT SIDE: TWO PHASE FLASH FREE WATER CONSIDERED MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000 FLASH SPECS FOR COLD SIDE: TWO PHASE FLASH FREE WATER CONSIDERED MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000 FLOW DIRECTION AND SPECIFICATION: COUNTERCURRENT HEAT EXCHANGER

83

SPECIFIED MIN OUTLET TEMP APPR SPECIFIED VALUE K 10.0000 LMTD CORRECTION FACTOR 1.00000 PRESSURE SPECIFICATION: HOT SIDE PRESSURE DROP N/SQM 0.0000 COLD SIDE PRESSURE DROP N/SQM 0.0000 HEAT TRANSFER COEFFICIENT SPECIFICATION: HOT LIQUID COLD LIQUID WATT/SQM-K 850.0000 HOT 2-PHASE COLD LIQUID WATT/SQM-K 850.0000 HOT VAPOR COLD LIQUID WATT/SQM-K 850.0000 HOT LIQUID COLD 2-PHASE WATT/SQM-K 850.0000 HOT 2-PHASE COLD 2-PHASE WATT/SQM-K 850.0000 HOT VAPOR COLD 2-PHASE WATT/SQM-K 850.0000 HOT LIQUID COLD VAPOR WATT/SQM-K 850.0000 HOT 2-PHASE COLD VAPOR WATT/SQM-K 850.0000 HOT VAPOR COLD VAPOR WATT/SQM-K 850.0000

OVERALL RESULTS STREAMS: -------------------------------------- | | S28 ----->| HOT |-----> HYDROGEN T= 3.0800D+02 | | T= 2.2294D+01 P= 3.1000D+06 | | P= 3.1000D+06 V= 9.9948D-01 | | V= 0.0000D+00 | | S23 <-----| COLD |<----- S22 T= 1.2301D+01 | | T= 1.2143D+01 P= 3.2000D+06 | | P= 3.2000D+06 V= 1.7508D-02 | | V= 1.7507D-02 -------------------------------------- DUTY AND AREA: CALCULATED HEAT DUTY WATT 10786.1818 CALCULATED (REQUIRED) AREA SQM 0.1498 ACTUAL EXCHANGER AREA SQM 0.1498 PER CENT OVER-DESIGN 0.0000 HEAT TRANSFER COEFFICIENT: AVERAGE COEFFICIENT (DIRTY) WATT/SQM-K 850.0000 UA (DIRTY) J/SEC-K 127.3634 LOG-MEAN TEMPERATURE DIFFERENCE: LMTD CORRECTION FACTOR 1.0000 LMTD (CORRECTED) K 84.6883 NUMBER OF SHELLS IN SERIES 1 PRESSURE DROP: HOTSIDE, TOTAL N/SQM 0.0000 COLDSIDE, TOTAL N/SQM 0.0000

84


85



MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.571162 0.571162 0.00000 MASS(KG/SEC ) 51.3772 51.3772 -0.138299E-15 ENTHALPY(WATT ) -0.432682E+08 -0.432682E+08 0.00000



INPUT DATA FLASH SPECS FOR HOT SIDE: TWO PHASE FLASH FREE WATER CONSIDERED MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000 FLASH SPECS FOR COLD SIDE: TWO PHASE FLASH FREE WATER CONSIDERED MAXIMUM NO. ITERATIONS 30 CONVERGENCE TOLERANCE 0.000100000 FLOW DIRECTION AND SPECIFICATION:

86

COUNTERCURRENT HEAT EXCHANGER SPECIFIED COLD APPROACH TEMP SPECIFIED VALUE K 10.0000 TEMPERATURE TOLERANCE K 0.01000 LMTD CORRECTION FACTOR 1.00000 PRESSURE SPECIFICATION: HOT SIDE PRESSURE DROP N/SQM 0.0000 COLD SIDE PRESSURE DROP N/SQM 0.0000 HEAT TRANSFER COEFFICIENT SPECIFICATION: HOT LIQUID COLD LIQUID WATT/SQM-K 850.0000 HOT 2-PHASE COLD LIQUID WATT/SQM-K 850.0000 HOT VAPOR COLD LIQUID WATT/SQM-K 850.0000 HOT LIQUID COLD 2-PHASE WATT/SQM-K 850.0000 HOT 2-PHASE COLD 2-PHASE WATT/SQM-K 850.0000 HOT VAPOR COLD 2-PHASE WATT/SQM-K 850.0000 HOT LIQUID COLD VAPOR WATT/SQM-K 850.0000 HOT 2-PHASE COLD VAPOR WATT/SQM-K 850.0000 HOT VAPOR COLD VAPOR WATT/SQM-K 850.0000

OVERALL RESULTS STREAMS: -------------------------------------- | | S30 ----->| HOT |-----> S31 T= 3.1300D+02 | | T= 1.9662D+01 P= 3.1000D+06 | | P= 3.1000D+06 V= 0.0000D+00 | | V= 1.4574D-02 | | S24 <-----| COLD |<----- S23 T= 3.0300D+02 | | T= 1.2301D+01 P= 3.2000D+06 | | P= 3.2000D+06 V= 3.5939D-03 | | V= 1.7508D-02 -------------------------------------- DUTY AND AREA: CALCULATED HEAT DUTY WATT 12127948.3695 CALCULATED (REQUIRED) AREA SQM 1656.5517 ACTUAL EXCHANGER AREA SQM 1656.5517 PER CENT OVER-DESIGN 0.0000 HEAT TRANSFER COEFFICIENT: AVERAGE COEFFICIENT (DIRTY) WATT/SQM-K 850.0000 UA (DIRTY) J/SEC-K 1408068.9253 LOG-MEAN TEMPERATURE DIFFERENCE: LMTD CORRECTION FACTOR 1.0000 LMTD (CORRECTED) K 8.6132 NUMBER OF SHELLS IN SERIES 1 PRESSURE DROP: HOTSIDE, TOTAL N/SQM 0.0000

87

COLDSIDE, TOTAL N/SQM 0.0000

ZONE RESULTS TEMPERATURE LEAVING EACH ZONE: HOT ------------------------------------------------------------- | | HOT IN | LIQ | HOT OUT ------> | |------> 313.0 | | 19.7 | | COLDOUT | BOIL | COLDIN <------ | |<------ 303.0 | | 12.3 | | ------------------------------------------------------------- COLD ZONE HEAT TRANSFER AND AREA: ZONE HEAT DUTY AREA LMTD AVERAGE U UA WATT SQM K WATT/SQM-K J/SEC-K 1 12127948.369 1656.5517 8.6132 850.0000 1408068.9253

88

7.7.17. BLOCK: F-2 MODEL: FLASH2

INLET STREAM: S16 OUTLET VAPOR STREAM: S17 OUTLET LIQUID STREAM: S32 PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE FREE WATER OPTION SET: STMNBS2 NBS STEAM TABLE SOLUBLE WATER OPTION: SOLU DATA + STM TAB

MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.283834 0.283834 -0.391152E-15 MASS(KG/SEC ) 25.6848 25.6848 -0.650104E-14 ENTHALPY(WATT ) -0.201632E+08 -0.201632E+08 0.369513E-15



INPUT DATA


RESULTS

OUTLET TEMPERATURE K 200.00 OUTLET PRESSURE N/SQM 0.10000E+07 HEAT DUTY WATT 0.42295E-08 VAPOR FRACTION 0.78950E-02 1ST LIQUID/TOTAL LIQUID 1.0000

89

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) K1(I) METHA-01 0.467E-02 0.438E-02 0.00 0.403E-01 9.20 ETHAN-01 0.119E-01 0.119E-01 0.00 0.348E-02 0.291 PROPA-01 0.159E-01 0.160E-01 0.00 0.451E-03 0.282E-01 N-BUT-01 0.183E-01 0.184E-01 0.00 0.445E-04 0.242E-02 ISOBU-01 0.105E-01 0.105E-01 0.00 0.533E-04 0.505E-02 N-PEN-01 0.880E-02 0.887E-02 0.00 0.258E-05 0.291E-03 2-MET-01 0.182E-01 0.183E-01 0.00 0.835E-05 0.456E-03 N-HEX-01 0.273E-01 0.276E-01 0.00 0.847E-06 0.307E-04 2-MET-02 0.276E-01 0.278E-01 0.00 0.157E-05 0.565E-04 N-HEP-01 0.365E-01 0.368E-01 0.00 0.128E-06 0.349E-05 2-MET-03 0.393E-01 0.396E-01 0.00 0.292E-06 0.737E-05 N-OCT-01 0.192E-02 0.194E-02 0.00 0.748E-09 0.387E-06 2:2:4-01 0.328E-02 0.331E-02 0.00 0.216E-07 0.653E-05 N-NON-01 0.183E-01 0.184E-01 0.00 0.993E-09 0.539E-07 2:2:5-01 0.302E-01 0.305E-01 0.00 0.370E-07 0.121E-05 CYCLO-01 0.516E-05 0.521E-05 0.00 0.762E-10 0.146E-04 METHY-01 0.185E-04 0.186E-04 0.00 0.767E-10 0.412E-05 ETHYL-01 0.163E-04 0.164E-04 0.00 0.121E-10 0.739E-06 N-PRO-01 0.371E-05 0.373E-05 0.00 0.606E-12 0.162E-06 CYCLO-02 0.283E-03 0.286E-03 0.00 0.283E-07 0.990E-04 METHY-02 0.917E-02 0.924E-02 0.00 0.223E-06 0.241E-04 ETHYL-02 0.209E-01 0.210E-01 0.00 0.567E-07 0.270E-05 N-PRO-02 0.274E-01 0.276E-01 0.00 0.867E-08 0.314E-06 N-BUT-02 0.394E-02 0.397E-02 0.00 0.165E-09 0.416E-07 BENZE-01 0.293 0.295 0.00 0.462E-05 0.156E-04 TOLUE-01 0.113 0.114 0.00 0.193E-06 0.170E-05 M-XYL-01 0.588E-01 0.592E-01 0.00 0.783E-08 0.132E-06 O-XYL-01 0.963E-01 0.971E-01 0.00 0.101E-07 0.104E-06 P-XYL-01 0.382E-01 0.385E-01 0.00 0.565E-08 0.147E-06 ETHYL-03 0.320E-01 0.322E-01 0.00 0.644E-08 0.200E-06 N-PRO-03 0.248E-01 0.250E-01 0.00 0.769E-09 0.307E-07 HYDRO-01 0.101E-01 0.255E-02 0.00 0.956 375.

90

7.7.18. BLOCK: F-3 MODEL: FLASH2

INLET STREAM: S25 OUTLET VAPOR STREAM: S27 OUTLET LIQUID STREAM: S30 PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE FREE WATER OPTION SET: STMNBS2 NBS STEAM TABLE SOLUBLE WATER OPTION: SOLU DATA + STM TAB

MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.286075 0.286075 0.194044E-15 MASS(KG/SEC ) 25.6908 25.6908 0.276575E-15 ENTHALPY(WATT ) -0.158087E+08 -0.153378E+08 -0.297865E-01



INPUT DATA


RESULTS

OUTLET TEMPERATURE K 313.00 OUTLET PRESSURE N/SQM 0.31000E+07 HEAT DUTY WATT 0.47089E+06 VAPOR FRACTION 0.34546E-02 1ST LIQUID/TOTAL LIQUID 1.0000

91

V-L1-L2 PHASE EQUILIBRIUM : COMP F(I) X1(I) X2(I) Y(I) K1(I) K2(I) METHA-01 0.495E-02 0.480E-02 0.00 0.465E-01 9.69 ETHAN-01 0.118E-01 0.118E-01 0.00 0.202E-01 1.72 PROPA-01 0.157E-01 0.158E-01 0.00 0.822E-02 0.522 N-BUT-01 0.181E-01 0.182E-01 0.00 0.272E-02 0.149 ISOBU-01 0.104E-01 0.104E-01 0.00 0.222E-02 0.213 N-PEN-01 0.873E-02 0.876E-02 0.00 0.449E-03 0.513E-01 2-MET-01 0.180E-01 0.181E-01 0.00 0.112E-02 0.621E-01 N-HEX-01 0.271E-01 0.272E-01 0.00 0.452E-03 0.166E-01 2-MET-02 0.273E-01 0.274E-01 0.00 0.601E-03 0.219E-01 N-HEP-01 0.362E-01 0.364E-01 0.00 0.202E-03 0.556E-02 2-MET-03 0.390E-01 0.391E-01 0.00 0.309E-03 0.790E-02 N-OCT-01 0.190E-02 0.191E-02 0.00 0.362E-05 0.190E-02 2:2:4-01 0.326E-02 0.327E-02 0.00 0.211E-04 0.646E-02 N-NON-01 0.181E-01 0.182E-01 0.00 0.128E-04 0.705E-03 2:2:5-01 0.300E-01 0.301E-01 0.00 0.820E-04 0.273E-02 CYCLO-01 0.512E-05 0.514E-05 0.00 0.486E-07 0.945E-02 METHY-01 0.183E-04 0.184E-04 0.00 0.877E-07 0.476E-02 ETHYL-01 0.161E-04 0.162E-04 0.00 0.281E-07 0.174E-02 N-PRO-01 0.368E-05 0.369E-05 0.00 0.270E-08 0.733E-03 CYCLO-02 0.281E-03 0.282E-03 0.00 0.758E-05 0.269E-01 METHY-02 0.909E-02 0.912E-02 0.00 0.117E-03 0.129E-01 ETHYL-02 0.207E-01 0.208E-01 0.00 0.866E-04 0.417E-02 N-PRO-02 0.272E-01 0.273E-01 0.00 0.395E-04 0.145E-02 N-BUT-02 0.391E-02 0.392E-02 0.00 0.205E-05 0.523E-03 BENZE-01 0.291 0.292 0.00 0.302E-02 0.104E-01 TOLUE-01 0.112 0.112 0.00 0.380E-03 0.338E-02 M-XYL-01 0.583E-01 0.585E-01 0.00 0.569E-04 0.973E-03 O-XYL-01 0.956E-01 0.959E-01 0.00 0.794E-04 0.827E-03 P-XYL-01 0.379E-01 0.380E-01 0.00 0.384E-04 0.101E-02 ETHYL-03 0.317E-01 0.318E-01 0.00 0.363E-04 0.114E-02 N-PRO-03 0.247E-01 0.247E-01 0.00 0.109E-04 0.442E-03 HYDRO-01 0.175E-01 0.144E-01 0.00 0.913 63.5

92

7.7.19. BLOCK: G-2 MODEL: COMPR


MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.224087E-02 0.224087E-02 0.00000 MASS(KG/SEC ) 0.606145E-02 0.606145E-02 -0.143095E-15 ENTHALPY(WATT ) -13859.7 -6616.16 -0.522634

CO2 EQUIVALENT SUMMARY FEED STREAMS CO2E 0.362438E-01 KG/SEC PRODUCT STREAMS CO2E 0.362438E-01 KG/SEC NET STREAMS CO2E PRODUCTION 0.00000 KG/SEC UTILITIES CO2E PRODUCTION 0.00000 KG/SEC TOTAL CO2E PRODUCTION 0.00000 KG/SEC

INPUT DATA ISENTROPIC CENTRIFUGAL COMPRESSOR OUTLET PRESSURE N/SQM 3,200,000. ISENTROPIC EFFICIENCY 0.72000 MECHANICAL EFFICIENCY 1.00000

RESULTS INDICATED HORSEPOWER REQUIREMENT WATT 7,243.55 BRAKE HORSEPOWER REQUIREMENT WATT 7,243.55 NET WORK REQUIRED WATT 7,243.55 POWER LOSSES WATT 0.0 ISENTROPIC HORSEPOWER REQUIREMENT WATT 5,215.35 CALCULATED OUTLET TEMP K 311.238 ISENTROPIC TEMPERATURE K 280.415 EFFICIENCY (POLYTR/ISENTR) USED 0.72000 OUTLET VAPOR FRACTION 1.00000 HEAD DEVELOPED, J/KG 860,413. MECHANICAL EFFICIENCY USED 1.00000 INLET HEAT CAPACITY RATIO 1.42179 INLET VOLUMETRIC FLOW RATE , CUM/SEC 0.0037462 OUTLET VOLUMETRIC FLOW RATE, CUM/SEC 0.0018414 INLET COMPRESSIBILITY FACTOR 1.00534 OUTLET COMPRESSIBILITY FACTOR 1.01617 AV. ISENT. VOL. EXPONENT 1.42964 AV. ISENT. TEMP EXPONENT 1.40954 AV. ACTUAL VOL. EXPONENT 1.63780 AV. ACTUAL TEMP EXPONENT 1.61345

93

7.7.20. BLOCK: G-3 MODEL: PUMP


MASS AND ENERGY BALANCE IN OUT RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 0.283834 0.283834 0.00000 MASS(KG/SEC ) 25.6848 25.6848 -0.138320E-15 ENTHALPY(WATT ) -0.153587E+08 -0.153145E+08 -0.288035E-02


INPUT DATA

OUTLET PRESSURE N/SQM 3,200,000. DRIVER EFFICIENCY 1.00000 FLASH SPECIFICATIONS: LIQUID PHASE CALCULATION NO FLASH PERFORMED FREE WATER CONSIDERED MAXIMUM NUMBER OF ITERATIONS 30 TOLERANCE 0.000100000

RESULTS

VOLUMETRIC FLOW RATE CUM/SEC 0.032669 PRESSURE CHANGE N/SQM 970,000. NPSH AVAILABLE J/KG 0.0 FLUID POWER WATT 31,689.2 BRAKE POWER WATT 44,238.5 ELECTRICITY WATT 44,238.5 PUMP EFFICIENCY USED 0.71633 NET WORK REQUIRED WATT 44,238.5 HEAD DEVELOPED J/KG 1,233.77

94

7.7.21. BLOCK: R1 MODEL: RPLUG

INLET STREAM: S2 OUTLET STREAM: S3 PROPERTY OPTION SET: SRK SOAVE-REDLICH-KWONG EQUATION OF STATE SOLUBLE WATER OPTION: SOLU DATA + STM TAB

MASS AND ENERGY BALANCE IN OUT GENERATION RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 1.87057 2.01030 0.139723 0.00000 MASS(KG/SEC ) 64.8992 64.8992 0.114275E-06 ENTHALPY(WATT ) -0.941865E+07 -0.941865E+07 -0.395523E-15



INPUT DATA REACTOR TYPE: ADIABATIC VAPOR FLUID PHASE REACTOR TUBE LENGTH METER 8.5000 REACTOR DIAMETER METER 1.2500 REACTOR RISE METER 0.0000 NUMBER OF REACTOR TUBES 1 REACTOR VOLUME CUM 10.431 PRESSURE DROP OPTION: SPECIFIED HOLDUP OPTION: NO-SLIP ERROR TOLERANCE 0.10000E-03 INTEGRATION METHOD GEAR CORRECTOR METHOD NEWTON INITIAL STEP SIZE FACTOR 0.10000E-01 CORRECTOR TOLERANCE FACTOR 0.10000 MAXIMUM NUMBER OF STEPS 1000 REACTION PARAGRAPH ID: DEHYDRO TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL

95

STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 -1.0000 BENZE-01 1.0000 HYDRO-01 3.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 -1.0000 TOLUE-01 1.0000 HYDRO-01 3.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 -1.0000 M-XYL-01 1.0000 HYDRO-01 3.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED ETHYL-01 -1.0000 O-XYL-01 1.0000 HYDRO-01 3.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED ETHYL-01 -1.0000 P-XYL-01 1.0000 HYDRO-01 3.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED ETHYL-01 -1.0000 ETHYL-03 1.0000 HYDRO-01 3.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED N-PRO-01 -1.0000 N-PRO-03 1.0000 HYDRO-01 3.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES 7 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 18.750 0.16224E+09 0.0000 2 20.700 0.16224E+09 0.0000 3 17.890 0.16224E+09 0.0000 4 19.150 0.16224E+09 0.0000 5 18.660 0.16224E+09 0.0000 6 18.710 0.16224E+09 0.0000 7 20.380 0.16224E+09 0.0000

96

POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED N-PRO-01 1.0000

RESULTS REACTOR DUTY WATT 0.0000 RESIDENCE TIME SEC 0.49123 REACTOR MINIMUM TEMPERATURE K 757.13 REACTOR MAXIMUM TEMPERATURE K 798.00

RESULTS PROFILE (PROCESS STREAM) LENGTH PRESSURE TEMPERATURE VAPOR FRAC RES-TIME METER N/SQM K SEC 0.0000 0.59500E+06 798.00 1.0000 0.0000 0.85000 0.59500E+06 779.35 1.0000 0.49583E-01 1.7000 0.59500E+06 772.21 1.0000 0.98882E-01 2.5500 0.59500E+06 768.02 1.0000 0.14806 3.4000 0.59500E+06 765.17 1.0000 0.19718 4.2500 0.59500E+06 763.05 1.0000 0.24625 5.1000 0.59500E+06 761.39 1.0000 0.29528 5.9500 0.59500E+06 760.03 1.0000 0.34430 6.8000 0.59500E+06 758.90 1.0000 0.39329 7.6500 0.59500E+06 757.95 1.0000 0.44226 8.5000 0.59500E+06 757.13 1.0000 0.49123

97

LENGTH DUTY LIQUID HOLDUP METER WATT 0.0000 0.0000 0.0000 0.85000 0.0000 0.0000 1.7000 0.0000 0.0000 2.5500 0.0000 0.0000 3.4000 0.0000 0.0000 4.2500 0.0000 0.0000 5.1000 0.0000 0.0000 5.9500 0.0000 0.0000 6.8000 0.0000 0.0000 7.6500 0.0000 0.0000 8.5000 0.0000 0.0000

TOTAL MOLE FRACTION PROFILE (PROCESS STREAM) LENGTH METHA-01 ETHAN-01 PROPA-01 N-BUT-01 METER 0.0000 0.21102E-01 0.23102E-01 0.20202E-01 0.10601E-01 0.85000 0.20393E-01 0.22326E-01 0.19523E-01 0.10245E-01 1.7000 0.20139E-01 0.22048E-01 0.19280E-01 0.10117E-01 2.5500 0.19994E-01 0.21890E-01 0.19142E-01 0.10045E-01 3.4000 0.19898E-01 0.21784E-01 0.19049E-01 0.99962E-02 4.2500 0.19828E-01 0.21707E-01 0.18982E-01 0.99608E-02 5.1000 0.19773E-01 0.21647E-01 0.18930E-01 0.99334E-02 5.9500 0.19729E-01 0.21599E-01 0.18887E-01 0.99112E-02 6.8000 0.19692E-01 0.21559E-01 0.18852E-01 0.98928E-02 7.6500 0.19662E-01 0.21525E-01 0.18823E-01 0.98774E-02 8.5000 0.19635E-01 0.21497E-01 0.18798E-01 0.98642E-02 LENGTH ISOBU-01 N-PEN-01 2-MET-01 N-HEX-01 METER 0.0000 0.73007E-02 0.35004E-02 0.76008E-02 0.22902E-01 0.85000 0.70553E-02 0.33827E-02 0.73453E-02 0.22132E-01 1.7000 0.69674E-02 0.33405E-02 0.72537E-02 0.21857E-01 2.5500 0.69175E-02 0.33166E-02 0.72018E-02 0.21700E-01 3.4000 0.68842E-02 0.33006E-02 0.71671E-02 0.21596E-01 4.2500 0.68598E-02 0.32890E-02 0.71417E-02 0.21519E-01 5.1000 0.68409E-02 0.32799E-02 0.71220E-02 0.21460E-01 5.9500 0.68256E-02 0.32726E-02 0.71061E-02 0.21412E-01 6.8000 0.68130E-02 0.32665E-02 0.70930E-02 0.21372E-01 7.6500 0.68024E-02 0.32614E-02 0.70819E-02 0.21339E-01 8.5000 0.67933E-02 0.32571E-02 0.70725E-02 0.21310E-01 LENGTH 2-MET-02 N-HEP-01 2-MET-03 N-OCT-01 METER 0.0000 0.23202E-01 0.29203E-01 0.31403E-01 0.23902E-01 0.85000 0.22422E-01 0.28221E-01 0.30347E-01 0.23099E-01 1.7000 0.22143E-01 0.27870E-01 0.29969E-01 0.22811E-01 2.5500 0.21984E-01 0.27670E-01 0.29755E-01 0.22648E-01 3.4000 0.21878E-01 0.27537E-01 0.29611E-01 0.22539E-01

98

4.2500 0.21801E-01 0.27439E-01 0.29507E-01 0.22459E-01 5.1000 0.21741E-01 0.27364E-01 0.29425E-01 0.22397E-01 5.9500 0.21692E-01 0.27302E-01 0.29359E-01 0.22347E-01 6.8000 0.21652E-01 0.27252E-01 0.29305E-01 0.22306E-01 7.6500 0.21619E-01 0.27210E-01 0.29260E-01 0.22271E-01 8.5000 0.21590E-01 0.27173E-01 0.29220E-01 0.22241E-01 LENGTH 2:2:4-01 N-NON-01 2:2:5-01 CYCLO-01 METER 0.0000 0.33803E-01 0.15602E-01 0.24402E-01 0.77008E-02 0.85000 0.32667E-01 0.15077E-01 0.23582E-01 0.57569E-02 1.7000 0.32260E-01 0.14889E-01 0.23288E-01 0.47796E-02 2.5500 0.32029E-01 0.14783E-01 0.23122E-01 0.41090E-02 3.4000 0.31875E-01 0.14711E-01 0.23010E-01 0.35989E-02 4.2500 0.31762E-01 0.14659E-01 0.22929E-01 0.31899E-02 5.1000 0.31674E-01 0.14619E-01 0.22865E-01 0.28507E-02 5.9500 0.31603E-01 0.14586E-01 0.22814E-01 0.25632E-02 6.8000 0.31545E-01 0.14559E-01 0.22772E-01 0.23161E-02 7.6500 0.31496E-01 0.14537E-01 0.22737E-01 0.21016E-02 8.5000 0.31454E-01 0.14517E-01 0.22706E-01 0.19132E-02 LENGTH METHY-01 ETHYL-01 N-PRO-01 CYCLO-02 METER 0.0000 0.84008E-02 0.11501E-01 0.18002E-02 0.10001E-03 0.85000 0.61148E-02 0.40214E-02 0.13161E-02 0.96648E-04 1.7000 0.49861E-02 0.19992E-02 0.10763E-02 0.95444E-04 2.5500 0.42228E-02 0.11173E-02 0.91379E-03 0.94760E-04 3.4000 0.36496E-02 0.66626E-03 0.79149E-03 0.94304E-04 4.2500 0.31957E-02 0.41631E-03 0.69443E-03 0.93970E-04 5.1000 0.28235E-02 0.26717E-03 0.61469E-03 0.93711E-04 5.9500 0.25113E-02 0.17430E-03 0.54771E-03 0.93501E-04 6.8000 0.22459E-02 0.11693E-03 0.49066E-03 0.93329E-04 7.6500 0.20177E-02 0.82260E-04 0.44152E-03 0.93183E-04 8.5000 0.18194E-02 0.60056E-04 0.39875E-03 0.93059E-04 LENGTH METHY-02 ETHYL-02 N-PRO-02 N-BUT-02 METER 0.0000 0.30003E-02 0.65007E-02 0.84008E-02 0.12001E-02 0.85000 0.28994E-02 0.62821E-02 0.81184E-02 0.11598E-02 1.7000 0.28633E-02 0.62038E-02 0.80173E-02 0.11453E-02 2.5500 0.28428E-02 0.61594E-02 0.79599E-02 0.11371E-02 3.4000 0.28291E-02 0.61297E-02 0.79215E-02 0.11316E-02 4.2500 0.28191E-02 0.61081E-02 0.78935E-02 0.11276E-02 5.1000 0.28113E-02 0.60912E-02 0.78717E-02 0.11245E-02 5.9500 0.28050E-02 0.60776E-02 0.78541E-02 0.11220E-02 6.8000 0.27999E-02 0.60664E-02 0.78396E-02 0.11199E-02 7.6500 0.27955E-02 0.60569E-02 0.78274E-02 0.11182E-02 8.5000 0.27918E-02 0.60488E-02 0.78169E-02 0.11167E-02

99

LENGTH BENZE-01 TOLUE-01 M-XYL-01 O-XYL-01 METER 0.0000 0.86009E-02 0.10901E-01 0.15002E-02 0.16002E-02 0.85000 0.99968E-02 0.12538E-01 0.31551E-02 0.33719E-02 1.7000 0.10778E-01 0.13435E-01 0.35899E-02 0.38374E-02 2.5500 0.11337E-01 0.14066E-01 0.37728E-02 0.40332E-02 3.4000 0.11773E-01 0.14551E-01 0.38618E-02 0.41284E-02 4.2500 0.12127E-01 0.14941E-01 0.39076E-02 0.41775E-02 5.1000 0.12424E-01 0.15263E-01 0.39324E-02 0.42041E-02 5.9500 0.12678E-01 0.15534E-01 0.39458E-02 0.42185E-02 6.8000 0.12896E-01 0.15767E-01 0.39522E-02 0.42253E-02 7.6500 0.13087E-01 0.15967E-01 0.39544E-02 0.42276E-02 8.5000 0.13255E-01 0.16141E-01 0.39544E-02 0.42277E-02 LENGTH P-XYL-01 ETHYL-03 N-PRO-03 HYDRO-01 METER 0.0000 0.36004E-02 0.21002E-02 0.26003E-02 0.62266 0.85000 0.52581E-02 0.38131E-02 0.29364E-02 0.63535 1.7000 0.56871E-02 0.42615E-02 0.31232E-02 0.63989 2.5500 0.58640E-02 0.44491E-02 0.32557E-02 0.64247 3.4000 0.59475E-02 0.45397E-02 0.33579E-02 0.64419 4.2500 0.59885E-02 0.45859E-02 0.34403E-02 0.64545 5.1000 0.60091E-02 0.46105E-02 0.35086E-02 0.64643 5.9500 0.60188E-02 0.46234E-02 0.35664E-02 0.64722 6.8000 0.60220E-02 0.46292E-02 0.36158E-02 0.64787 7.6500 0.60213E-02 0.46307E-02 0.36585E-02 0.64842 8.5000 0.60188E-02 0.46300E-02 0.36958E-02 0.64889

TOTAL MASS FRACTION PROFILE (PROCESS STREAM) LENGTH METHA-01 ETHAN-01 PROPA-01 N-BUT-01 METER 0.0000 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 0.85000 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 1.7000 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 2.5500 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 3.4000 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 4.2500 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 5.1000 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 5.9500 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 6.8000 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 7.6500 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 8.5000 0.97574E-02 0.20022E-01 0.25676E-01 0.17759E-01 LENGTH ISOBU-01 N-PEN-01 2-MET-01 N-HEX-01 METER 0.0000 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 0.85000 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 1.7000 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01

100

2.5500 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 3.4000 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 4.2500 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 5.1000 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 5.9500 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 6.8000 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 7.6500 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 8.5000 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 LENGTH 2-MET-02 N-HEP-01 2-MET-03 N-OCT-01 METER 0.0000 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 0.85000 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 1.7000 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 2.5500 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 3.4000 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 4.2500 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 5.1000 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 5.9500 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 6.8000 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 7.6500 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 8.5000 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 LENGTH 2:2:4-01 N-NON-01 2:2:5-01 CYCLO-01 METER 0.0000 0.11129 0.57674E-01 0.90208E-01 0.18680E-01 0.85000 0.11129 0.57674E-01 0.90208E-01 0.14450E-01 1.7000 0.11129 0.57674E-01 0.90208E-01 0.12149E-01 2.5500 0.11129 0.57674E-01 0.90208E-01 0.10519E-01 3.4000 0.11129 0.57674E-01 0.90208E-01 0.92581E-02 4.2500 0.11129 0.57674E-01 0.90208E-01 0.82351E-02 5.1000 0.11129 0.57674E-01 0.90208E-01 0.73797E-02 5.9500 0.11129 0.57674E-01 0.90208E-01 0.66503E-02 6.8000 0.11129 0.57674E-01 0.90208E-01 0.60205E-02 7.6500 0.11129 0.57674E-01 0.90208E-01 0.54712E-02 8.5000 0.11129 0.57674E-01 0.90208E-01 0.49875E-02 LENGTH METHY-01 ETHYL-01 N-PRO-01 CYCLO-02 METER 0.0000 0.23774E-01 0.37198E-01 0.65501E-02 0.20216E-03 0.85000 0.17907E-01 0.13459E-01 0.49552E-02 0.20216E-03 1.7000 0.14786E-01 0.67754E-02 0.41036E-02 0.20216E-03 2.5500 0.12612E-01 0.38137E-02 0.35091E-02 0.20216E-03 3.4000 0.10953E-01 0.22853E-02 0.30541E-02 0.20216E-03 4.2500 0.96251E-02 0.14330E-02 0.26891E-02 0.20216E-03 5.1000 0.85274E-02 0.92220E-03 0.23869E-02 0.20216E-03 5.9500 0.76017E-02 0.60297E-03 0.21316E-02 0.20216E-03 6.8000 0.68108E-02 0.40525E-03 0.19131E-02 0.20216E-03 7.6500 0.61284E-02 0.28554E-03 0.17242E-02 0.20216E-03 8.5000 0.55334E-02 0.20875E-03 0.15592E-02 0.20216E-03

101

LENGTH METHY-02 ETHYL-02 N-PRO-02 N-BUT-02 METER 0.0000 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 0.85000 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 1.7000 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 2.5500 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 3.4000 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 4.2500 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 5.1000 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 5.9500 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 6.8000 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 7.6500 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 8.5000 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 LENGTH BENZE-01 TOLUE-01 M-XYL-01 O-XYL-01 METER 0.0000 0.19364E-01 0.28950E-01 0.45904E-02 0.48964E-02 0.85000 0.23290E-01 0.34456E-01 0.99903E-02 0.10677E-01 1.7000 0.25426E-01 0.37385E-01 0.11511E-01 0.12304E-01 2.5500 0.26938E-01 0.39424E-01 0.12184E-01 0.13025E-01 3.4000 0.28109E-01 0.40981E-01 0.12532E-01 0.13397E-01 4.2500 0.29058E-01 0.42228E-01 0.12726E-01 0.13605E-01 5.1000 0.29852E-01 0.43258E-01 0.12842E-01 0.13729E-01 5.9500 0.30529E-01 0.44126E-01 0.12915E-01 0.13807E-01 6.8000 0.31114E-01 0.44868E-01 0.12960E-01 0.13855E-01 7.6500 0.31623E-01 0.45509E-01 0.12987E-01 0.13884E-01 8.5000 0.32072E-01 0.46067E-01 0.13004E-01 0.13903E-01 LENGTH P-XYL-01 ETHYL-03 N-PRO-03 HYDRO-01 METER 0.0000 0.11017E-01 0.64266E-02 0.90080E-02 0.36179E-01 0.85000 0.16649E-01 0.12074E-01 0.10526E-01 0.38200E-01 1.7000 0.18235E-01 0.13664E-01 0.11337E-01 0.38958E-01 2.5500 0.18938E-01 0.14368E-01 0.11903E-01 0.39397E-01 3.4000 0.19300E-01 0.14732E-01 0.12336E-01 0.39694E-01 4.2500 0.19502E-01 0.14935E-01 0.12684E-01 0.39913E-01 5.1000 0.19624E-01 0.15056E-01 0.12972E-01 0.40084E-01 5.9500 0.19699E-01 0.15132E-01 0.13215E-01 0.40223E-01 6.8000 0.19746E-01 0.15179E-01 0.13423E-01 0.40338E-01 7.6500 0.19775E-01 0.15208E-01 0.13603E-01 0.40435E-01 8.5000 0.19793E-01 0.15226E-01 0.13760E-01 0.40519E-01

102



MASS AND ENERGY BALANCE IN OUT GENERATION RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 2.01030 2.03568 0.253815E-01 0.00000 MASS(KG/SEC ) 64.8992 64.9017 -0.389536E-04 ENTHALPY(WATT ) 440512. 440512. -0.132136E-15


INPUT DATA REACTOR TYPE: ADIABATIC VAPOR FLUID PHASE REACTOR TUBE LENGTH METER 10.350 REACTOR DIAMETER METER 1.2500 REACTOR RISE METER 0.0000 NUMBER OF REACTOR TUBES 1 REACTOR VOLUME CUM 12.701 PRESSURE DROP OPTION: FRICTIONAL CORRELATION FRICTIONAL CORRELATION: BEGGS-BRILL HOLDUP OPTION: NO-SLIP ERROR TOLERANCE 0.10000E-03 INTEGRATION METHOD GEAR CORRECTOR METHOD NEWTON INITIAL STEP SIZE FACTOR 0.10000E-01 CORRECTOR TOLERANCE FACTOR 0.10000 MAXIMUM NUMBER OF STEPS 1000 REACTION PARAGRAPH ID: DEHYDRO TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL

103


104

POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED N-PRO-01 1.0000

RESULTS

REACTOR DUTY WATT 0.0000 RESIDENCE TIME SEC 0.52133 REACTOR MINIMUM TEMPERATURE K 790.41 REACTOR MAXIMUM TEMPERATURE K 798.00

RESULTS PROFILE (PROCESS STREAM) LENGTH PRESSURE TEMPERATURE VAPOR FRAC RES-TIME METER N/SQM K SEC 0.0000 0.55000E+06 798.00 1.0000 0.0000 1.0350 0.55000E+06 792.82 1.0000 0.52210E-01 2.0700 0.54999E+06 791.31 1.0000 0.10436 3.1050 0.54999E+06 790.77 1.0000 0.15649 4.1400 0.54998E+06 790.56 1.0000 0.20861 5.1750 0.54998E+06 790.49 1.0000 0.26074 6.2100 0.54997E+06 790.46 1.0000 0.31286 7.2450 0.54997E+06 790.44 1.0000 0.36497 8.2800 0.54996E+06 790.43 1.0000 0.41709 9.3150 0.54996E+06 790.42 1.0000 0.46921 10.350 0.54995E+06 790.41 1.0000 0.52133

105

LENGTH DUTY LIQUID HOLDUP METER WATT 0.0000 0.0000 0.0000 1.0350 0.0000 0.0000 2.0700 0.0000 0.0000 3.1050 0.0000 0.0000 4.1400 0.0000 0.0000 5.1750 0.0000 0.0000 6.2100 0.0000 0.0000 7.2450 0.0000 0.0000 8.2800 0.0000 0.0000 9.3150 0.0000 0.0000 10.350 0.0000 0.0000

TOTAL MOLE FRACTION PROFILE (PROCESS STREAM) LENGTH METHA-01 ETHAN-01 PROPA-01 N-BUT-01 METER 0.0000 0.19635E-01 0.21497E-01 0.18798E-01 0.98642E-02 1.0350 0.19468E-01 0.21313E-01 0.18637E-01 0.97799E-02 2.0700 0.19419E-01 0.21260E-01 0.18591E-01 0.97558E-02 3.1050 0.19402E-01 0.21241E-01 0.18575E-01 0.97471E-02 4.1400 0.19396E-01 0.21234E-01 0.18568E-01 0.97438E-02 5.1750 0.19393E-01 0.21232E-01 0.18566E-01 0.97426E-02 6.2100 0.19392E-01 0.21231E-01 0.18565E-01 0.97421E-02 7.2450 0.19392E-01 0.21230E-01 0.18565E-01 0.97419E-02 8.2800 0.19391E-01 0.21229E-01 0.18564E-01 0.97416E-02 9.3150 0.19391E-01 0.21229E-01 0.18564E-01 0.97414E-02 10.350 0.19391E-01 0.21229E-01 0.18564E-01 0.97413E-02 LENGTH ISOBU-01 N-PEN-01 2-MET-01 N-HEX-01 METER 0.0000 0.67933E-02 0.32571E-02 0.70725E-02 0.21310E-01 1.0350 0.67352E-02 0.32292E-02 0.70120E-02 0.21128E-01 2.0700 0.67186E-02 0.32212E-02 0.69947E-02 0.21076E-01 3.1050 0.67126E-02 0.32184E-02 0.69885E-02 0.21057E-01 4.1400 0.67104E-02 0.32173E-02 0.69861E-02 0.21050E-01 5.1750 0.67095E-02 0.32169E-02 0.69853E-02 0.21048E-01 6.2100 0.67092E-02 0.32167E-02 0.69849E-02 0.21047E-01 7.2450 0.67090E-02 0.32167E-02 0.69848E-02 0.21046E-01 8.2800 0.67089E-02 0.32166E-02 0.69846E-02 0.21046E-01 9.3150 0.67087E-02 0.32165E-02 0.69844E-02 0.21045E-01 10.350 0.67086E-02 0.32165E-02 0.69843E-02 0.21045E-01 LENGTH 2-MET-02 N-HEP-01 2-MET-03 N-OCT-01 METER 0.0000 0.21590E-01 0.27173E-01 0.29220E-01 0.22241E-01 1.0350 0.21405E-01 0.26941E-01 0.28971E-01 0.22051E-01 2.0700 0.21352E-01 0.26874E-01 0.28899E-01 0.21996E-01 3.1050 0.21333E-01 0.26851E-01 0.28874E-01 0.21977E-01 4.1400 0.21326E-01 0.26841E-01 0.28864E-01 0.21970E-01 5.1750 0.21323E-01 0.26838E-01 0.28860E-01 0.21967E-01

106

6.2100 0.21322E-01 0.26837E-01 0.28859E-01 0.21966E-01 7.2450 0.21322E-01 0.26836E-01 0.28858E-01 0.21965E-01 8.2800 0.21321E-01 0.26835E-01 0.28857E-01 0.21965E-01 9.3150 0.21321E-01 0.26835E-01 0.28857E-01 0.21964E-01 10.350 0.21320E-01 0.26834E-01 0.28856E-01 0.21964E-01 LENGTH 2:2:4-01 N-NON-01 2:2:5-01 CYCLO-01 METER 0.0000 0.31454E-01 0.14517E-01 0.22706E-01 0.19132E-02 1.0350 0.31185E-01 0.14393E-01 0.22512E-01 0.64097E-03 2.0700 0.31108E-01 0.14358E-01 0.22457E-01 0.24609E-03 3.1050 0.31080E-01 0.14345E-01 0.22437E-01 0.98251E-04 4.1400 0.31070E-01 0.14340E-01 0.22429E-01 0.39413E-04 5.1750 0.31066E-01 0.14338E-01 0.22426E-01 0.16590E-04 6.2100 0.31065E-01 0.14337E-01 0.22425E-01 0.78120E-05 7.2450 0.31064E-01 0.14337E-01 0.22425E-01 0.36869E-05 8.2800 0.31063E-01 0.14337E-01 0.22424E-01 0.22730E-06 9.3150 0.31062E-01 0.14336E-01 0.22424E-01 0.0000 10.350 0.31062E-01 0.14336E-01 0.22423E-01 0.0000 LENGTH METHY-01 ETHYL-01 N-PRO-01 CYCLO-02 METER 0.0000 0.18194E-02 0.60056E-04 0.39875E-03 0.93059E-04 1.0350 0.54321E-03 0.16997E-06 0.12133E-03 0.92263E-04 2.0700 0.19021E-03 0.14138E-07 0.43124E-04 0.92036E-04 3.1050 0.69779E-04 0.0000 0.16037E-04 0.91954E-04 4.1400 0.25670E-04 0.0000 0.59826E-05 0.91923E-04 5.1750 0.10136E-04 0.15955E-08 0.23856E-05 0.91911E-04 6.2100 0.46506E-05 0.0000 0.10975E-05 0.91907E-04 7.2450 0.12356E-05 0.0000 0.33242E-06 0.91905E-04 8.2800 0.0000 0.0000 0.0000 0.91902E-04 9.3150 0.0000 0.0000 0.0000 0.91900E-04 10.350 0.0000 0.0000 0.0000 0.91899E-04 LENGTH METHY-02 ETHYL-02 N-PRO-02 N-BUT-02 METER 0.0000 0.27918E-02 0.60488E-02 0.78169E-02 0.11167E-02 1.0350 0.27679E-02 0.59971E-02 0.77501E-02 0.11072E-02 2.0700 0.27611E-02 0.59823E-02 0.77310E-02 0.11044E-02 3.1050 0.27586E-02 0.59770E-02 0.77241E-02 0.11034E-02 4.1400 0.27577E-02 0.59750E-02 0.77215E-02 0.11031E-02 5.1750 0.27573E-02 0.59742E-02 0.77206E-02 0.11029E-02 6.2100 0.27572E-02 0.59740E-02 0.77202E-02 0.11029E-02 7.2450 0.27571E-02 0.59738E-02 0.77200E-02 0.11029E-02 8.2800 0.27571E-02 0.59736E-02 0.77198E-02 0.11028E-02 9.3150 0.27570E-02 0.59735E-02 0.77196E-02 0.11028E-02 10.350 0.27570E-02 0.59734E-02 0.77195E-02 0.11028E-02

107



108

3.1050 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 4.1400 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 5.1750 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 6.2100 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 7.2450 0.12230E-01 0.72791E-02 0.15806E-01 0.56885E-01 8.2800 0.12230E-01 0.72790E-02 0.15806E-01 0.56884E-01 9.3150 0.12230E-01 0.72789E-02 0.15806E-01 0.56883E-01 10.350 0.12230E-01 0.72788E-02 0.15805E-01 0.56883E-01 LENGTH 2-MET-02 N-HEP-01 2-MET-03 N-OCT-01 METER 0.0000 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 1.0350 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 2.0700 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 3.1050 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 4.1400 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 5.1750 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 6.2100 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 7.2450 0.57630E-01 0.84341E-01 0.90695E-01 0.78696E-01 8.2800 0.57630E-01 0.84340E-01 0.90694E-01 0.78695E-01 9.3150 0.57629E-01 0.84338E-01 0.90693E-01 0.78694E-01 10.350 0.57628E-01 0.84338E-01 0.90692E-01 0.78693E-01 LENGTH 2:2:4-01 N-NON-01 2:2:5-01 CYCLO-01 METER 0.0000 0.11129 0.57674E-01 0.90208E-01 0.49875E-02 1.0350 0.11129 0.57674E-01 0.90208E-01 0.16853E-02 2.0700 0.11129 0.57674E-01 0.90208E-01 0.64866E-03 3.1050 0.11129 0.57674E-01 0.90208E-01 0.25921E-03 4.1400 0.11129 0.57674E-01 0.90208E-01 0.10402E-03 5.1750 0.11129 0.57674E-01 0.90208E-01 0.43788E-04 6.2100 0.11129 0.57674E-01 0.90208E-01 0.20620E-04 7.2450 0.11129 0.57674E-01 0.90208E-01 0.97320E-05 8.2800 0.11129 0.57673E-01 0.90207E-01 0.60000E-06 9.3150 0.11129 0.57672E-01 0.90205E-01 0.0000 10.350 0.11129 0.57671E-01 0.90204E-01 0.0000 LENGTH METHY-01 ETHYL-01 N-PRO-01 CYCLO-02 METER 0.0000 0.55334E-02 0.20875E-03 0.15592E-02 0.20216E-03 1.0350 0.16663E-02 0.59588E-06 0.47854E-03 0.20216E-03 2.0700 0.58493E-03 0.49690E-07 0.17050E-03 0.20216E-03 3.1050 0.21477E-03 0.0000 0.63462E-04 0.20216E-03 4.1400 0.79036E-04 0.0000 0.23683E-04 0.20216E-03 5.1750 0.31211E-04 0.56151E-08 0.94450E-05 0.20216E-03 6.2100 0.14322E-04 0.0000 0.43453E-05 0.20216E-03 7.2450 0.38052E-05 0.0000 0.13162E-05 0.20216E-03 8.2800 0.0000 0.0000 0.0000 0.20216E-03 9.3150 0.0000 0.0000 0.0000 0.20216E-03 10.350 0.0000 0.0000 0.0000 0.20215E-03

109

LENGTH METHY-02 ETHYL-02 N-PRO-02 N-BUT-02 METER 0.0000 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 1.0350 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 2.0700 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 3.1050 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 4.1400 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 5.1750 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 6.2100 0.72779E-02 0.18397E-01 0.27171E-01 0.43667E-02 7.2450 0.72778E-02 0.18397E-01 0.27171E-01 0.43667E-02 8.2800 0.72778E-02 0.18397E-01 0.27170E-01 0.43667E-02 9.3150 0.72776E-02 0.18396E-01 0.27170E-01 0.43666E-02 10.350 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 LENGTH BENZE-01 TOLUE-01 M-XYL-01 O-XYL-01 METER 0.0000 0.32072E-01 0.46067E-01 0.13004E-01 0.13903E-01 1.0350 0.35137E-01 0.49696E-01 0.13052E-01 0.13954E-01 2.0700 0.36099E-01 0.50711E-01 0.13052E-01 0.13954E-01 3.1050 0.36461E-01 0.51058E-01 0.13052E-01 0.13954E-01 4.1400 0.36605E-01 0.51186E-01 0.13052E-01 0.13954E-01 5.1750 0.36661E-01 0.51230E-01 0.13052E-01 0.13954E-01 6.2100 0.36682E-01 0.51246E-01 0.13052E-01 0.13954E-01 7.2450 0.36692E-01 0.51256E-01 0.13052E-01 0.13954E-01 8.2800 0.36700E-01 0.51267E-01 0.13052E-01 0.13954E-01 9.3150 0.36706E-01 0.51275E-01 0.13051E-01 0.13953E-01 10.350 0.36710E-01 0.51278E-01 0.13051E-01 0.13953E-01 LENGTH P-XYL-01 ETHYL-03 N-PRO-03 HYDRO-01 METER 0.0000 0.19793E-01 0.15226E-01 0.13760E-01 0.40519E-01 1.0350 0.19842E-01 0.15276E-01 0.14789E-01 0.41057E-01 2.0700 0.19842E-01 0.15276E-01 0.15082E-01 0.41213E-01 3.1050 0.19842E-01 0.15276E-01 0.15184E-01 0.41269E-01 4.1400 0.19842E-01 0.15276E-01 0.15222E-01 0.41290E-01 5.1750 0.19842E-01 0.15276E-01 0.15235E-01 0.41298E-01 6.2100 0.19842E-01 0.15276E-01 0.15240E-01 0.41301E-01 7.2450 0.19843E-01 0.15276E-01 0.15243E-01 0.41303E-01 8.2800 0.19842E-01 0.15276E-01 0.15246E-01 0.41304E-01 9.3150 0.19842E-01 0.15275E-01 0.15248E-01 0.41304E-01 10.350 0.19842E-01 0.15275E-01 0.15249E-01 0.41305E-01

110




IN OUT GENERATION RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 2.03568 2.56515 0.529475 -0.173124E-15 MASS(KG/SEC ) 64.9017 64.9017 0.408067E-06 ENTHALPY(WATT ) 0.229288E+07 0.229288E+07 0.00000

CO2 EQUIVALENT SUMMARY FEED STREAMS CO2E 15.8311 KG/SEC PRODUCT STREAMS CO2E 15.8311 KG/SEC NET STREAMS CO2E PRODUCTION 0.288982E-07 KG/SEC UTILITIES CO2E PRODUCTION 0.00000 KG/SEC TOTAL CO2E PRODUCTION 0.288982E-07 KG/SEC

INPUT DATA REACTOR TYPE: ADIABATIC VAPOR FLUID PHASE REACTOR TUBE LENGTH METER 12.100 REACTOR DIAMETER METER 1.3000 REACTOR RISE METER 0.0000 NUMBER OF REACTOR TUBES 1 REACTOR VOLUME CUM 16.061 PRESSURE DROP OPTION: SPECIFIED HOLDUP OPTION: NO-SLIP ERROR TOLERANCE 0.40000E-01 INTEGRATION METHOD GEAR CORRECTOR METHOD NEWTON INITIAL STEP SIZE FACTOR 0.10000E-01 CORRECTOR TOLERANCE FACTOR 0.10000 MAXIMUM NUMBER OF STEPS 1000 REACTION PARAGRAPH ID: DHCYCLI1 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL

111

STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED N-HEX-01 1.0000 CYCLO-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-HEP-01 1.0000 METHY-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-OCT-01 1.0000 ETHYL-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-NON-01 1.0000 N-PRO-01 -1.0000 HYDRO-01 -1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 24.370 0.27548E+09 0.0000 2 29.100 0.27548E+09 0.0000 3 27.810 0.27548E+09 0.0000 4 29.760 0.27548E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PRO-01 1.0000

112

REACTION PARAGRAPH ID: DHCYCLI2 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED 2-MET-02 1.0000 CYCLO-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED 2-MET-03 1.0000 METHY-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2:2:4-01 1.0000 ETHYL-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2:2:5-01 1.0000 N-PRO-01 -1.0000 HYDRO-01 -1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 26.360 0.27548E+09 0.0000 2 25.750 0.27548E+09 0.0000 3 29.000 0.27548E+09 0.0000 4 29.760 0.27548E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 1.0000

113

REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PRO-01 1.0000 REACTION PARAGRAPH ID: DHCYCLI3 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED N-PEN-01 -1.0000 CYCLO-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-HEX-01 -1.0000 METHY-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-HEP-01 -1.0000 ETHYL-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-OCT-01 -1.0000 N-PRO-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-NON-01 -1.0000 N-BUT-02 1.0000 HYDRO-01 1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES

114

RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 30.750 0.27548E+09 0.0000 2 31.940 0.27548E+09 0.0000 3 33.430 0.27548E+09 0.0000 4 31.310 0.27548E+09 0.0000 5 32.960 0.27548E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED N-PEN-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-HEX-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-NON-01 1.0000 REACTION PARAGRAPH ID: DHCYCLI4 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED 2-MET-01 -1.0000 CYCLO-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED 2-MET-02 -1.0000 METHY-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2-MET-03 -1.0000 ETHYL-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2:2:4-01 -1.0000 N-PRO-02 1.0000 HYDRO-01 1.0000

115

REACTION NUMBER: 5 SUBSTREAM: MIXED 2:2:5-01 -1.0000 N-BUT-02 1.0000 HYDRO-01 1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 29.830 0.27548E+09 0.0000 2 30.870 0.27548E+09 0.0000 3 32.950 0.27548E+09 0.0000 4 34.190 0.27548E+09 0.0000 5 32.960 0.27548E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED 2-MET-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED 2-MET-02 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2-MET-03 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED 2:2:5-01 1.0000 REACTION PARAGRAPH ID: DHCYCLI5 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL

116

STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED N-HEX-01 -1.0000 BENZE-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-HEP-01 -1.0000 TOLUE-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-OCT-01 -1.0000 M-XYL-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-OCT-01 -1.0000 O-XYL-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-OCT-01 -1.0000 P-XYL-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED N-OCT-01 -1.0000 ETHYL-03 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED N-NON-01 -1.0000 N-PRO-03 1.0000 HYDRO-01 4.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES 7 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 16.870 0.15692E+09 0.0000 2 17.170 0.15692E+09 0.0000 3 17.320 0.15692E+09 0.0000 4 17.890 0.15692E+09 0.0000 5 17.010 0.15692E+09 0.0000 6 16.960 0.15692E+09 0.0000 7 18.900 0.15692E+09 0.0000

117

POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED N-HEX-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-HEP-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED N-NON-01 1.0000 REACTION PARAGRAPH ID: DHCYCLI6 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED 2-MET-02 -1.0000 BENZE-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED 2-MET-03 -1.0000 TOLUE-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2:2:4-01 -1.0000 M-XYL-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2:2:4-01 -1.0000 O-XYL-01 1.0000 HYDRO-01 4.0000

118

REACTION NUMBER: 5 SUBSTREAM: MIXED 2:2:4-01 -1.0000 P-XYL-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED 2:2:4-01 -1.0000 ETHYL-03 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED 2:2:5-01 -1.0000 N-PRO-03 1.0000 HYDRO-01 4.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES 7 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 16.440 0.15692E+09 0.0000 2 16.900 0.15692E+09 0.0000 3 16.270 0.15692E+09 0.0000 4 16.780 0.15692E+09 0.0000 5 16.040 0.15692E+09 0.0000 6 15.930 0.15692E+09 0.0000 7 17.660 0.15692E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED 2-MET-02 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED 2-MET-03 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2:2:4-01 1.0000

119

REACTION NUMBER: 4 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED 2:2:5-01 1.0000 REACTION PARAGRAPH ID: QUACK1 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED METHA-01 2.0000 ETHAN-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHA-01 1.0000 ETHAN-01 1.0000 PROPA-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED METHA-01 0.66667 ETHAN-01 0.66667 PROPA-01 0.66667 N-BUT-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED METHA-01 0.50000 ETHAN-01 0.50000 PROPA-01 0.50000 N-BUT-01 0.50000 N-PEN-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED METHA-01 0.40000 ETHAN-01 0.40000 PROPA-01 0.40000 N-BUT-01 0.40000 N-PEN-01 0.40000 N-HEX-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED METHA-01 0.46667 ETHAN-01 0.46667 PROPA-01 0.46667 N-BUT-01 0.46667 N-PEN-01 0.46667 N-HEP-01 -1.0000 HYDRO-01 -1.3333

120

REACTION NUMBER: 7 SUBSTREAM: MIXED METHA-01 0.53333 ETHAN-01 0.53333 PROPA-01 0.53333 N-BUT-01 0.53333 N-PEN-01 0.53333 N-OCT-01 -1.0000 HYDRO-01 -1.6667 REACTION NUMBER: 8 SUBSTREAM: MIXED METHA-01 0.60000 ETHAN-01 0.60000 PROPA-01 0.60000 N-BUT-01 0.60000 N-PEN-01 0.60000 N-NON-01 -1.0000 HYDRO-01 -2.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES 7 KINETIC V 0.0000 PARTIALPRES 8 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 37.850 0.28796E+09 0.0000 2 39.950 0.28796E+09 0.0000 3 40.150 0.28796E+09 0.0000 4 41.600 0.28796E+09 0.0000 5 42.080 0.28796E+09 0.0000 6 42.480 0.28796E+09 0.0000 7 40.530 0.28796E+09 0.0000 8 43.850 0.28796E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED ETHAN-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED PROPA-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PEN-01 1.0000

121

REACTION NUMBER: 5 SUBSTREAM: MIXED N-HEX-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED N-HEP-01 1.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 8 SUBSTREAM: MIXED N-NON-01 1.0000 REACTION PARAGRAPH ID: QUACK2 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED METHA-01 1.5000 ETHAN-01 0.50000 PROPA-01 0.50000 ISOBU-01 -1.0000 HYDRO-01 -1.5000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHA-01 0.50000 ETHAN-01 0.50000 PROPA-01 0.50000 ISOBU-01 0.50000 2-MET-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED METHA-01 0.40000 ETHAN-01 0.40000 PROPA-01 0.40000 ISOBU-01 0.40000 2-MET-01 0.40000 2-MET-02 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED METHA-01 0.46667 ETHAN-01 0.46667 PROPA-01 0.46667 ISOBU-01 0.46667 2-MET-01 0.46667 2-MET-03 -1.0000 HYDRO-01 -1.3333 REACTION NUMBER: 5 SUBSTREAM: MIXED METHA-01 0.53333 ETHAN-01 0.53333 PROPA-01 0.53333 ISOBU-01 0.53333 2-MET-01 0.53333 2:2:4-01 -1.0000 HYDRO-01 -1.6667

122

REACTION NUMBER: 6 SUBSTREAM: MIXED METHA-01 0.60000 ETHAN-01 0.60000 PROPA-01 0.60000 ISOBU-01 0.60000 2-MET-01 0.60000 2:2:5-01 -1.0000 HYDRO-01 -2.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 36.150 0.28796E+09 0.0000 2 41.570 0.28796E+09 0.0000 3 40.530 0.28796E+09 0.0000 4 41.570 0.28796E+09 0.0000 5 41.510 0.28796E+09 0.0000 6 42.930 0.28796E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED ISOBU-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2-MET-02 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2-MET-03 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED 2:2:5-01 1.0000

123

REACTION PARAGRAPH ID: QUACK3 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED METHA-01 0.40000 ETHAN-01 0.40000 PROPA-01 0.40000 N-BUT-01 0.40000 N-PEN-01 0.40000 CYCLO-01 -1.0000 HYDRO-01 -2.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHA-01 0.46667 ETHAN-01 0.46667 PROPA-01 0.46667 N-BUT-01 0.46667 N-PEN-01 0.46667 METHY-01 -1.0000 HYDRO-01 -2.3333 REACTION NUMBER: 3 SUBSTREAM: MIXED METHA-01 0.53333 ETHAN-01 0.53333 PROPA-01 0.53333 N-BUT-01 0.53333 N-PEN-01 0.53333 ETHYL-01 -1.0000 HYDRO-01 -2.6667 REACTION NUMBER: 4 SUBSTREAM: MIXED METHA-01 0.60000 ETHAN-01 0.60000 PROPA-01 0.60000 N-BUT-01 0.60000 N-PEN-01 0.60000 N-PRO-01 -1.0000 HYDRO-01 -3.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 42.150 0.28796E+09 0.0000 2 44.700 0.28796E+09 0.0000 3 43.900 0.28796E+09 0.0000 4 44.150 0.28796E+09 0.0000

124

POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PRO-01 1.0000 REACTION PARAGRAPH ID: QUACK4 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED METHA-01 0.50000 ETHAN-01 0.50000 PROPA-01 0.50000 N-BUT-01 0.50000 CYCLO-02 -1.0000 HYDRO-01 -2.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHA-01 0.40000 ETHAN-01 0.40000 PROPA-01 0.40000 N-BUT-01 0.40000 N-PEN-01 0.40000 METHY-02 -1.0000 HYDRO-01 -2.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED METHA-01 0.46667 ETHAN-01 0.46667 PROPA-01 0.46667 N-BUT-01 0.46667 N-PEN-01 0.46667 ETHYL-02 -1.0000 HYDRO-01 -2.3333 REACTION NUMBER: 4 SUBSTREAM: MIXED METHA-01 0.53333 ETHAN-01 0.53333 PROPA-01 0.53333 N-BUT-01 0.53333 N-PEN-01 0.53333 N-PRO-02 -1.0000 HYDRO-01 -2.6667 REACTION NUMBER: 5 SUBSTREAM: MIXED METHA-01 0.60000 ETHAN-01 0.60000 PROPA-01 0.60000 N-BUT-01 0.60000 N-PEN-01 0.60000 N-BUT-02 -1.0000 HYDRO-01 -3.0000

125

REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 40.230 0.28796E+09 0.0000 2 41.550 0.28796E+09 0.0000 3 43.750 0.28796E+09 0.0000 4 43.650 0.28796E+09 0.0000 5 44.150 0.28796E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-02 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-02 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-02 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PRO-02 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-BUT-02 1.0000


126

RESULTS PROFILE (PROCESS STREAM) LENGTH PRESSURE TEMPERATURE VAPOR FRAC RES-TIME METER N/SQM K SEC 0.0000 0.50500E+06 798.00 1.0000 0.0000 1.2100 0.50500E+06 717.23 1.0000 0.58302E-01 2.4200 0.50500E+06 696.77 1.0000 0.11648 3.6300 0.50500E+06 682.78 1.0000 0.17457 4.8400 0.50500E+06 673.95 1.0000 0.23264 6.0500 0.50500E+06 667.97 1.0000 0.29072 7.2600 0.50500E+06 663.48 1.0000 0.34882 8.4700 0.50500E+06 660.19 1.0000 0.40694 9.6800 0.50500E+06 656.99 1.0000 0.46509 10.890 0.50500E+06 654.50 1.0000 0.52326 12.100 0.50500E+06 652.27 1.0000 0.58146 LENGTH DUTY LIQUID HOLDUP METER WATT 0.0000 0.0000 0.0000 1.2100 0.0000 0.0000 2.4200 0.0000 0.0000 3.6300 0.0000 0.0000 4.8400 0.0000 0.0000 6.0500 0.0000 0.0000 7.2600 0.0000 0.0000 8.4700 0.0000 0.0000 9.6800 0.0000 0.0000 10.890 0.0000 0.0000 12.100 0.0000 0.0000

TOTAL MOLE FRACTION PROFILE (PROCESS STREAM) LENGTH METHA-01 ETHAN-01 PROPA-01 N-BUT-01 METER 0.0000 0.19391E-01 0.21229E-01 0.18564E-01 0.97413E-02 1.2100 0.16904E-01 0.18506E-01 0.16183E-01 0.84919E-02 2.4200 0.16388E-01 0.17942E-01 0.15689E-01 0.82331E-02 3.6300 0.16057E-01 0.17579E-01 0.15372E-01 0.80666E-02 4.8400 0.15856E-01 0.17359E-01 0.15180E-01 0.79656E-02 6.0500 0.15723E-01 0.17214E-01 0.15053E-01 0.78990E-02 7.2600 0.15626E-01 0.17107E-01 0.14959E-01 0.78499E-02 8.4700 0.15555E-01 0.17029E-01 0.14892E-01 0.78144E-02 9.6800 0.15487E-01 0.16955E-01 0.14826E-01 0.77802E-02 10.890 0.15435E-01 0.16898E-01 0.14776E-01 0.77539E-02 12.100 0.15388E-01 0.16847E-01 0.14732E-01 0.77306E-02 LENGTH ISOBU-01 N-PEN-01 2-MET-01 N-HEX-01 METER 0.0000 0.67086E-02 0.32165E-02 0.69843E-02 0.21045E-01 1.2100 0.58482E-02 0.28039E-02 0.60886E-02 0.16108E-01 2.4200 0.56699E-02 0.27185E-02 0.59030E-02 0.14996E-01

127

3.6300 0.55553E-02 0.26635E-02 0.57836E-02 0.14293E-01 4.8400 0.54858E-02 0.26302E-02 0.57112E-02 0.13861E-01 6.0500 0.54399E-02 0.26082E-02 0.56634E-02 0.13571E-01 7.2600 0.54061E-02 0.25920E-02 0.56282E-02 0.13355E-01 8.4700 0.53816E-02 0.25802E-02 0.56027E-02 0.13196E-01 9.6800 0.53581E-02 0.25689E-02 0.55783E-02 0.13044E-01 10.890 0.53400E-02 0.25603E-02 0.55594E-02 0.12926E-01 12.100 0.53239E-02 0.25525E-02 0.55427E-02 0.12820E-01 LENGTH 2-MET-02 N-HEP-01 2-MET-03 N-OCT-01 METER 0.0000 0.21320E-01 0.26834E-01 0.28856E-01 0.21964E-01 1.2100 0.16372E-01 0.20493E-01 0.22082E-01 0.11735E-01 2.4200 0.15257E-01 0.19066E-01 0.20556E-01 0.98775E-02 3.6300 0.14552E-01 0.18163E-01 0.19592E-01 0.86468E-02 4.8400 0.14118E-01 0.17608E-01 0.18999E-01 0.79177E-02 6.0500 0.13828E-01 0.17236E-01 0.18601E-01 0.74496E-02 7.2600 0.13611E-01 0.16958E-01 0.18305E-01 0.71125E-02 8.4700 0.13451E-01 0.16754E-01 0.18086E-01 0.68761E-02 9.6800 0.13299E-01 0.16559E-01 0.17878E-01 0.66466E-02 10.890 0.13180E-01 0.16407E-01 0.17715E-01 0.64742E-02 12.100 0.13074E-01 0.16271E-01 0.17570E-01 0.63219E-02 LENGTH 2:2:4-01 N-NON-01 2:2:5-01 CYCLO-02 METER 0.0000 0.31062E-01 0.14336E-01 0.22423E-01 0.91899E-04 1.2100 0.17028E-01 0.10807E-01 0.17062E-01 0.80113E-04 2.4200 0.14429E-01 0.10015E-01 0.15855E-01 0.77670E-04 3.6300 0.12718E-01 0.95137E-02 0.15092E-01 0.76100E-04 4.8400 0.11699E-01 0.92057E-02 0.14623E-01 0.75148E-04 6.0500 0.11043E-01 0.89994E-02 0.14309E-01 0.74519E-04 7.2600 0.10568E-01 0.88457E-02 0.14075E-01 0.74056E-04 8.4700 0.10233E-01 0.87325E-02 0.13902E-01 0.73720E-04 9.6800 0.99093E-02 0.86244E-02 0.13738E-01 0.73398E-04 10.890 0.96648E-02 0.85403E-02 0.13609E-01 0.73150E-04 12.100 0.94486E-02 0.84651E-02 0.13495E-01 0.72930E-04 LENGTH METHY-02 ETHYL-02 N-PRO-02 N-BUT-02 METER 0.0000 0.27570E-02 0.59734E-02 0.77195E-02 0.11028E-02 1.2100 0.24034E-02 0.52073E-02 0.67295E-02 0.96135E-03 2.4200 0.23301E-02 0.50486E-02 0.65243E-02 0.93204E-03 3.6300 0.22830E-02 0.49465E-02 0.63924E-02 0.91320E-03 4.8400 0.22544E-02 0.48846E-02 0.63124E-02 0.90177E-03 6.0500 0.22356E-02 0.48437E-02 0.62596E-02 0.89423E-03 7.2600 0.22217E-02 0.48136E-02 0.62207E-02 0.88867E-03 8.4700 0.22116E-02 0.47918E-02 0.61925E-02 0.88464E-03 9.6800 0.22019E-02 0.47709E-02 0.61654E-02 0.88078E-03 10.890 0.21945E-02 0.47548E-02 0.61446E-02 0.87780E-03 12.100 0.21879E-02 0.47404E-02 0.61261E-02 0.87516E-03

128



129

3.6300 0.12230E-01 0.72788E-02 0.15805E-01 0.46654E-01 4.8400 0.12230E-01 0.72788E-02 0.15805E-01 0.45816E-01 6.0500 0.12230E-01 0.72788E-02 0.15805E-01 0.45237E-01 7.2600 0.12230E-01 0.72788E-02 0.15805E-01 0.44795E-01 8.4700 0.12230E-01 0.72788E-02 0.15805E-01 0.44463E-01 9.6800 0.12230E-01 0.72788E-02 0.15805E-01 0.44144E-01 10.890 0.12230E-01 0.72788E-02 0.15805E-01 0.43891E-01 12.100 0.12230E-01 0.72788E-02 0.15805E-01 0.43664E-01 LENGTH 2-MET-02 N-HEP-01 2-MET-03 N-OCT-01 METER 0.0000 0.57628E-01 0.84338E-01 0.90692E-01 0.78693E-01 1.2100 0.50764E-01 0.73884E-01 0.79613E-01 0.48231E-01 2.4200 0.48793E-01 0.70898E-01 0.76442E-01 0.41872E-01 3.6300 0.47499E-01 0.68935E-01 0.74358E-01 0.37412E-01 4.8400 0.46668E-01 0.67675E-01 0.73021E-01 0.34691E-01 6.0500 0.46093E-01 0.66804E-01 0.72096E-01 0.32916E-01 7.2600 0.45654E-01 0.66140E-01 0.71390E-01 0.31623E-01 8.4700 0.45324E-01 0.65641E-01 0.70860E-01 0.30711E-01 9.6800 0.45007E-01 0.65161E-01 0.70350E-01 0.29816E-01 10.890 0.44756E-01 0.64782E-01 0.69947E-01 0.29141E-01 12.100 0.44530E-01 0.64440E-01 0.69584E-01 0.28542E-01 LENGTH 2:2:4-01 N-NON-01 2:2:5-01 CYCLO-02 METER 0.0000 0.11129 0.57671E-01 0.90204E-01 0.20215E-03 1.2100 0.69982E-01 0.49871E-01 0.78732E-01 0.20215E-03 2.4200 0.61168E-01 0.47667E-01 0.75466E-01 0.20215E-03 3.6300 0.55025E-01 0.46217E-01 0.73318E-01 0.20215E-03 4.8400 0.51261E-01 0.45287E-01 0.71940E-01 0.20215E-03 6.0500 0.48793E-01 0.44646E-01 0.70988E-01 0.20215E-03 7.2600 0.46987E-01 0.44158E-01 0.70262E-01 0.20215E-03 8.4700 0.45706E-01 0.43791E-01 0.69717E-01 0.20215E-03 9.6800 0.44452E-01 0.43439E-01 0.69193E-01 0.20215E-03 10.890 0.43503E-01 0.43161E-01 0.68779E-01 0.20215E-03 12.100 0.42658E-01 0.42911E-01 0.68406E-01 0.20215E-03 LENGTH METHY-02 ETHYL-02 N-PRO-02 N-BUT-02 METER 0.0000 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 1.2100 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 2.4200 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 3.6300 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 4.8400 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 6.0500 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 7.2600 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 8.4700 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 9.6800 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 10.890 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 12.100 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02

130

LENGTH BENZE-01 TOLUE-01 M-XYL-01 O-XYL-01 METER 0.0000 0.36710E-01 0.51278E-01 0.13051E-01 0.13953E-01 1.2100 0.49220E-01 0.71078E-01 0.29746E-01 0.31182E-01 2.4200 0.52806E-01 0.76740E-01 0.33275E-01 0.34825E-01 3.6300 0.55162E-01 0.80460E-01 0.35742E-01 0.37370E-01 4.8400 0.56675E-01 0.82849E-01 0.37250E-01 0.38927E-01 6.0500 0.57722E-01 0.84500E-01 0.38238E-01 0.39946E-01 7.2600 0.58520E-01 0.85760E-01 0.38958E-01 0.40690E-01 8.4700 0.59120E-01 0.86707E-01 0.39469E-01 0.41216E-01 9.6800 0.59697E-01 0.87616E-01 0.39968E-01 0.41732E-01 10.890 0.60153E-01 0.88336E-01 0.40346E-01 0.42122E-01 12.100 0.60564E-01 0.88983E-01 0.40682E-01 0.42469E-01 LENGTH P-XYL-01 ETHYL-03 N-PRO-03 HYDRO-01 METER 0.0000 0.19842E-01 0.15275E-01 0.15249E-01 0.41305E-01 1.2100 0.36274E-01 0.31622E-01 0.33310E-01 0.50607E-01 2.4200 0.39748E-01 0.35078E-01 0.38436E-01 0.52887E-01 3.6300 0.42176E-01 0.37493E-01 0.41808E-01 0.54431E-01 4.8400 0.43660E-01 0.38970E-01 0.43971E-01 0.55399E-01 6.0500 0.44632E-01 0.39937E-01 0.45464E-01 0.56051E-01 7.2600 0.45342E-01 0.40642E-01 0.46602E-01 0.56539E-01 8.4700 0.45844E-01 0.41142E-01 0.47456E-01 0.56896E-01 9.6800 0.46336E-01 0.41631E-01 0.48277E-01 0.57242E-01 10.890 0.46708E-01 0.42001E-01 0.48926E-01 0.57510E-01 12.100 0.47038E-01 0.42330E-01 0.49510E-01 0.57750E-01

131



MASS AND ENERGY BALANCE IN OUT GENERATION RELATIVE DIFF. TOTAL BALANCE MOLE(KMOL/SEC) 2.56515 3.12325 0.558098 0.142188E-15 MASS(KG/SEC ) 64.9017 64.9016 0.397714E-06 ENTHALPY(WATT ) 0.364166E+08 0.364166E+08 0.00000



INPUT DATA REACTOR TYPE: ADIABATIC VAPOR FLUID PHASE REACTOR TUBE LENGTH METER 15.390 REACTOR DIAMETER METER 1.3000 REACTOR RISE METER 0.0000 NUMBER OF REACTOR TUBES 1 REACTOR VOLUME CUM 20.427 PRESSURE DROP OPTION: SPECIFIED HOLDUP OPTION: NO-SLIP ERROR TOLERANCE 0.10000E-03 INTEGRATION METHOD GEAR CORRECTOR METHOD NEWTON INITIAL STEP SIZE FACTOR 0.10000E-01 CORRECTOR TOLERANCE FACTOR 0.10000 MAXIMUM NUMBER OF STEPS 1000 REACTION PARAGRAPH ID: DEHYDRO TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL

132


133

POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED N-PRO-01 1.0000 REACTION PARAGRAPH ID: DHCYCLI1 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED N-HEX-01 1.0000 CYCLO-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-HEP-01 1.0000 METHY-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-OCT-01 1.0000 ETHYL-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-NON-01 1.0000 N-PRO-01 -1.0000 HYDRO-01 -1.0000 REAC-DATA ENTRIES:

134

REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 24.370 0.27548E+09 0.0000 2 29.100 0.27548E+09 0.0000 3 27.810 0.27548E+09 0.0000 4 29.760 0.27548E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PRO-01 1.0000 REACTION PARAGRAPH ID: DHCYCLI2 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED 2-MET-02 1.0000 CYCLO-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED 2-MET-03 1.0000 METHY-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 3

135

SUBSTREAM: MIXED 2:2:4-01 1.0000 ETHYL-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2:2:5-01 1.0000 N-PRO-01 -1.0000 HYDRO-01 -1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 26.360 0.27548E+09 0.0000 2 25.750 0.27548E+09 0.0000 3 29.000 0.27548E+09 0.0000 4 29.760 0.27548E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PRO-01 1.0000 REACTION PARAGRAPH ID: DHCYCLI3 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY:

136

REACTION NUMBER: 1 SUBSTREAM: MIXED N-PEN-01 -1.0000 CYCLO-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-HEX-01 -1.0000 METHY-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-HEP-01 -1.0000 ETHYL-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-OCT-01 -1.0000 N-PRO-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-NON-01 -1.0000 N-BUT-02 1.0000 HYDRO-01 1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 30.750 0.27548E+09 0.0000 2 31.940 0.27548E+09 0.0000 3 33.430 0.27548E+09 0.0000 4 31.310 0.27548E+09 0.0000 5 32.960 0.27548E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED N-PEN-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-HEX-01 1.0000

137

REACTION NUMBER: 4 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-NON-01 1.0000 REACTION PARAGRAPH ID: DHCYCLI4 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED 2-MET-01 -1.0000 CYCLO-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED 2-MET-02 -1.0000 METHY-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2-MET-03 -1.0000 ETHYL-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2:2:4-01 -1.0000 N-PRO-02 1.0000 HYDRO-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED 2:2:5-01 -1.0000 N-BUT-02 1.0000 HYDRO-01 1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 29.830 0.27548E+09 0.0000

138

2 30.870 0.27548E+09 0.0000 3 32.950 0.27548E+09 0.0000 4 34.190 0.27548E+09 0.0000 5 32.960 0.27548E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED 2-MET-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED 2-MET-02 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2-MET-03 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED 2:2:5-01 1.0000 REACTION PARAGRAPH ID: DHCYCLI5 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED N-HEX-01 -1.0000 BENZE-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-HEP-01 -1.0000 TOLUE-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-OCT-01 -1.0000 M-XYL-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-OCT-01 -1.0000 O-XYL-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-OCT-01 -1.0000 P-XYL-01 1.0000 HYDRO-01 4.0000

139

REACTION NUMBER: 6 SUBSTREAM: MIXED N-OCT-01 -1.0000 ETHYL-03 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED N-NON-01 -1.0000 N-PRO-03 1.0000 HYDRO-01 4.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES 7 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 16.870 0.15692E+09 0.0000 2 17.170 0.15692E+09 0.0000 3 17.320 0.15692E+09 0.0000 4 17.890 0.15692E+09 0.0000 5 17.010 0.15692E+09 0.0000 6 16.960 0.15692E+09 0.0000 7 18.900 0.15692E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED N-HEX-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-HEP-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 5

140

SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED N-NON-01 1.0000 REACTION PARAGRAPH ID: DHCYCLI6 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED 2-MET-02 -1.0000 BENZE-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED 2-MET-03 -1.0000 TOLUE-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2:2:4-01 -1.0000 M-XYL-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2:2:4-01 -1.0000 O-XYL-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED 2:2:4-01 -1.0000 P-XYL-01 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED 2:2:4-01 -1.0000 ETHYL-03 1.0000 HYDRO-01 4.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED 2:2:5-01 -1.0000 N-PRO-03 1.0000 HYDRO-01 4.0000 REAC-DATA ENTRIES:

141

REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES 7 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 16.440 0.15692E+09 0.0000 2 16.900 0.15692E+09 0.0000 3 16.270 0.15692E+09 0.0000 4 16.780 0.15692E+09 0.0000 5 16.040 0.15692E+09 0.0000 6 15.930 0.15692E+09 0.0000 7 17.660 0.15692E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED 2-MET-02 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED 2-MET-03 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 7

142

SUBSTREAM: MIXED 2:2:5-01 1.0000 REACTION PARAGRAPH ID: HYDROALK TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED METHA-01 1.0000 BENZE-01 1.0000 TOLUE-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHA-01 1.0000 TOLUE-01 1.0000 P-XYL-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHAN-01 1.0000 BENZE-01 1.0000 ETHYL-03 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED METHA-01 1.0000 O-XYL-01 1.0000 N-PRO-03 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED ETHAN-01 1.0000 TOLUE-01 1.0000 N-PRO-03 -1.0000 HYDRO-01 -1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS:

143

REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 7.6400 0.14910E+09 0.0000 2 5.5700 0.14910E+09 0.0000 3 5.5500 0.14910E+09 0.0000 4 8.9100 0.14910E+09 0.0000 5 5.5700 0.14910E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED TOLUE-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED P-XYL-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-03 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PRO-03 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-PRO-03 1.0000 REACTION PARAGRAPH ID: ISOARO TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED O-XYL-01 -1.0000 P-XYL-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED M-XYL-01 1.0000 O-XYL-01 -1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED M-XYL-01 -1.0000 ETHYL-03 1.0000

144

REACTION NUMBER: 4 SUBSTREAM: MIXED O-XYL-01 -1.0000 ETHYL-03 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED P-XYL-01 1.0000 ETHYL-03 -1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED M-XYL-01 -1.0000 P-XYL-01 1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 25.210 0.17672E+09 0.0000 2 24.500 0.17672E+09 0.0000 3 24.530 0.17672E+09 0.0000 4 25.170 0.17672E+09 0.0000 5 25.840 0.17672E+09 0.0000 6 24.470 0.17672E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED O-XYL-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED O-XYL-01 1.0000

145

REACTION NUMBER: 3 SUBSTREAM: MIXED M-XYL-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED O-XYL-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED ETHYL-03 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED M-XYL-01 1.0000 REACTION PARAGRAPH ID: ISONAP TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 1.0000 METHY-02 -1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 1.0000 ETHYL-02 -1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 1.0000 N-PRO-02 -1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PRO-01 1.0000 N-BUT-02 -1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS:

146

REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 15.110 0.19810E+09 0.0000 2 24.730 0.19810E+09 0.0000 3 25.780 0.19810E+09 0.0000 4 26.130 0.19810E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED METHY-02 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED ETHYL-02 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-PRO-02 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-BUT-02 1.0000 REACTION PARAGRAPH ID: ISOPAR TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED N-BUT-01 -1.0000 ISOBU-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-PEN-01 -1.0000 2-MET-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-HEX-01 -1.0000 2-MET-02 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-HEP-01 -1.0000 2-MET-03 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-OCT-01 -1.0000 2:2:4-01 1.0000

147

REACTION NUMBER: 6 SUBSTREAM: MIXED N-NON-01 -1.0000 2:2:5-01 1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 25.080 0.21632E+09 0.0000 2 24.890 0.21632E+09 0.0000 3 24.700 0.21632E+09 0.0000 4 24.150 0.21632E+09 0.0000 5 25.540 0.21632E+09 0.0000 6 24.480 0.21632E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED N-BUT-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED N-PEN-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED N-HEX-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-HEP-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-OCT-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED N-NON-01 1.0000 REACTION PARAGRAPH ID: QUACK1 TYPE: POWERLAW GLOBAL BASES:

148

KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED METHA-01 2.0000 ETHAN-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHA-01 1.0000 ETHAN-01 1.0000 PROPA-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED METHA-01 0.66667 ETHAN-01 0.66667 PROPA-01 0.66667 N-BUT-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED METHA-01 0.50000 ETHAN-01 0.50000 PROPA-01 0.50000 N-BUT-01 0.50000 N-PEN-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED METHA-01 0.40000 ETHAN-01 0.40000 PROPA-01 0.40000 N-BUT-01 0.40000 N-PEN-01 0.40000 N-HEX-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED METHA-01 0.46667 ETHAN-01 0.46667 PROPA-01 0.46667 N-BUT-01 0.46667 N-PEN-01 0.46667 N-HEP-01 -1.0000 HYDRO-01 -1.3333 REACTION NUMBER: 7 SUBSTREAM: MIXED METHA-01 0.53333 ETHAN-01 0.53333 PROPA-01 0.53333 N-BUT-01 0.53333 N-PEN-01 0.53333 N-OCT-01 -1.0000 HYDRO-01 -1.6667 REACTION NUMBER: 8 SUBSTREAM: MIXED METHA-01 0.60000 ETHAN-01 0.60000 PROPA-01 0.60000 N-BUT-01 0.60000 N-PEN-01 0.60000 N-NON-01 -1.0000 HYDRO-01 -2.0000 ASPEN PLUS PLAT: WINDOWS VER: 30.0

149

REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES 7 KINETIC V 0.0000 PARTIALPRES 8 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 37.850 0.28796E+09 0.0000 2 39.950 0.28796E+09 0.0000 3 40.150 0.28796E+09 0.0000 4 41.600 0.28796E+09 0.0000 5 42.080 0.28796E+09 0.0000 6 42.480 0.28796E+09 0.0000 7 40.530 0.28796E+09 0.0000 8 43.850 0.28796E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED ETHAN-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED PROPA-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PEN-01 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-HEX-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED N-HEP-01 1.0000 REACTION NUMBER: 7 SUBSTREAM: MIXED N-OCT-01 1.0000

150

REACTION NUMBER: 8 SUBSTREAM: MIXED N-NON-01 1.0000 REACTION PARAGRAPH ID: QUACK2 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED METHA-01 1.5000 ETHAN-01 0.50000 PROPA-01 0.50000 ISOBU-01 -1.0000 HYDRO-01 -1.5000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHA-01 0.50000 ETHAN-01 0.50000 PROPA-01 0.50000 ISOBU-01 0.50000 2-MET-01 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED METHA-01 0.40000 ETHAN-01 0.40000 PROPA-01 0.40000 ISOBU-01 0.40000 2-MET-01 0.40000 2-MET-02 -1.0000 HYDRO-01 -1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED METHA-01 0.46667 ETHAN-01 0.46667 PROPA-01 0.46667 ISOBU-01 0.46667 2-MET-01 0.46667 2-MET-03 -1.0000 HYDRO-01 -1.3333 REACTION NUMBER: 5 SUBSTREAM: MIXED METHA-01 0.53333 ETHAN-01 0.53333 PROPA-01 0.53333 ISOBU-01 0.53333 2-MET-01 0.53333 2:2:4-01 -1.0000 HYDRO-01 -1.6667 REACTION NUMBER: 6 SUBSTREAM: MIXED METHA-01 0.60000 ETHAN-01 0.60000 PROPA-01 0.60000 ISOBU-01 0.60000 2-MET-01 0.60000 2:2:5-01 -1.0000 HYDRO-01 -2.0000

151

REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES 6 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 36.150 0.28796E+09 0.0000 2 41.570 0.28796E+09 0.0000 3 40.530 0.28796E+09 0.0000 4 41.570 0.28796E+09 0.0000 5 41.510 0.28796E+09 0.0000 6 42.930 0.28796E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED ISOBU-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED 2-MET-02 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED 2-MET-03 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED 2:2:4-01 1.0000 REACTION NUMBER: 6 SUBSTREAM: MIXED 2:2:5-01 1.0000 REACTION PARAGRAPH ID: QUACK3 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL

152

STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED METHA-01 0.40000 ETHAN-01 0.40000 PROPA-01 0.40000 N-BUT-01 0.40000 N-PEN-01 0.40000 CYCLO-01 -1.0000 HYDRO-01 -2.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHA-01 0.46667 ETHAN-01 0.46667 PROPA-01 0.46667 N-BUT-01 0.46667 N-PEN-01 0.46667 METHY-01 -1.0000 HYDRO-01 -2.3333 REACTION NUMBER: 3 SUBSTREAM: MIXED METHA-01 0.53333 ETHAN-01 0.53333 PROPA-01 0.53333 N-BUT-01 0.53333 N-PEN-01 0.53333 ETHYL-01 -1.0000 HYDRO-01 -2.6667 REACTION NUMBER: 4 SUBSTREAM: MIXED METHA-01 0.60000 ETHAN-01 0.60000 PROPA-01 0.60000 N-BUT-01 0.60000 N-PEN-01 0.60000 N-PRO-01 -1.0000 HYDRO-01 -3.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 42.150 0.28796E+09 0.0000 2 44.700 0.28796E+09 0.0000 3 43.900 0.28796E+09 0.0000 4 44.150 0.28796E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-01 1.0000

153

REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-01 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-01 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PRO-01 1.0000 REACTION PARAGRAPH ID: QUACK4 TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL REACTION NUMBER: 1 SUBSTREAM: MIXED METHA-01 0.50000 ETHAN-01 0.50000 PROPA-01 0.50000 N-BUT-01 0.50000 CYCLO-02 -1.0000 HYDRO-01 -2.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHA-01 0.40000 ETHAN-01 0.40000 PROPA-01 0.40000 N-BUT-01 0.40000 N-PEN-01 0.40000 METHY-02 -1.0000 HYDRO-01 -2.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED METHA-01 0.46667 ETHAN-01 0.46667 PROPA-01 0.46667 N-BUT-01 0.46667 N-PEN-01 0.46667 ETHYL-02 -1.0000 HYDRO-01 -2.3333 REACTION NUMBER: 4 SUBSTREAM: MIXED METHA-01 0.53333 ETHAN-01 0.53333 PROPA-01 0.53333 N-BUT-01 0.53333 N-PEN-01 0.53333 N-PRO-02 -1.0000 HYDRO-01 -2.6667 REACTION NUMBER: 5 SUBSTREAM: MIXED METHA-01 0.60000 ETHAN-01 0.60000 PROPA-01 0.60000 N-BUT-01 0.60000 N-PEN-01 0.60000 N-BUT-02 -1.0000 HYDRO-01 -3.0000

154

REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES 3 KINETIC V 0.0000 PARTIALPRES 4 KINETIC V 0.0000 PARTIALPRES 5 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 40.230 0.28796E+09 0.0000 2 41.550 0.28796E+09 0.0000 3 43.750 0.28796E+09 0.0000 4 43.650 0.28796E+09 0.0000 5 44.150 0.28796E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED CYCLO-02 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED METHY-02 1.0000 REACTION NUMBER: 3 SUBSTREAM: MIXED ETHYL-02 1.0000 REACTION NUMBER: 4 SUBSTREAM: MIXED N-PRO-02 1.0000 REACTION NUMBER: 5 SUBSTREAM: MIXED N-BUT-02 1.0000 REACTION PARAGRAPH ID: TRANSALK TYPE: POWERLAW GLOBAL BASES: KBASIS MOLE-GAMMA CBASIS MOLARITY SBASIS GLOBAL

155

STOICHIOMETRY: REACTION NUMBER: 1 SUBSTREAM: MIXED BENZE-01 1.0000 TOLUE-01 -2.0000 P-XYL-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED TOLUE-01 1.0000 O-XYL-01 -2.0000 N-PRO-03 1.0000 REAC-DATA ENTRIES: REACTION NO TYPE PHASE DELT BASIS K 1 KINETIC V 0.0000 PARTIALPRES 2 KINETIC V 0.0000 PARTIALPRES RATE PARAMETERS: REACTION NO PREEXP. FACTOR ACT. ENERGY TEMP. EXPONENT REF. TEMP J/KMOL K 1 16.680 0.17662E+09 0.0000 2 15.480 0.17662E+09 0.0000 POWERLAW EXPONENTS: REACTION NUMBER: 1 SUBSTREAM: MIXED TOLUE-01 1.0000 REACTION NUMBER: 2 SUBSTREAM: MIXED O-XYL-01 1.0000


156

RESULTS PROFILE (PROCESS STREAM) LENGTH PRESSURE TEMPERATURE VAPOR FRAC RES-TIME METER N/SQM K SEC 0.0000 0.46000E+06 798.00 1.0000 0.0000 1.5390 0.46000E+06 723.05 1.0000 0.54111E-01 3.0780 0.46000E+06 708.84 1.0000 0.10784 4.6170 0.46000E+06 700.70 1.0000 0.16144 6.1560 0.46000E+06 695.09 1.0000 0.21497 7.6950 0.46000E+06 690.81 1.0000 0.26844 9.2340 0.46000E+06 687.35 1.0000 0.32186 10.773 0.46000E+06 684.48 1.0000 0.37525 12.312 0.46000E+06 682.03 1.0000 0.42861 13.851 0.46000E+06 679.89 1.0000 0.48195 15.390 0.46000E+06 677.99 1.0000 0.53526 LENGTH DUTY LIQUID HOLDUP METER WATT 0.0000 0.0000 0.0000 1.5390 0.0000 0.0000 3.0780 0.0000 0.0000 4.6170 0.0000 0.0000 6.1560 0.0000 0.0000 7.6950 0.0000 0.0000 9.2340 0.0000 0.0000 10.773 0.0000 0.0000 12.312 0.0000 0.0000 13.851 0.0000 0.0000 15.390 0.0000 0.0000

TOTAL MOLE FRACTION PROFILE (PROCESS STREAM) LENGTH METHA-01 ETHAN-01 PROPA-01 N-BUT-01 METER 0.0000 0.15388E-01 0.16847E-01 0.14732E-01 0.77306E-02 1.5390 0.32776E-01 0.20850E-01 0.13032E-01 0.68386E-02 3.0780 0.37780E-01 0.21990E-01 0.12735E-01 0.66823E-02 4.6170 0.40987E-01 0.22702E-01 0.12566E-01 0.65939E-02 6.1560 0.43377E-01 0.23222E-01 0.12450E-01 0.65331E-02 7.6950 0.45301E-01 0.23634E-01 0.12362E-01 0.64868E-02 9.2340 0.46916E-01 0.23975E-01 0.12291E-01 0.64496E-02 10.773 0.48309E-01 0.24266E-01 0.12233E-01 0.64187E-02 12.312 0.49536E-01 0.24519E-01 0.12182E-01 0.63923E-02 13.851 0.50635E-01 0.24743E-01 0.12138E-01 0.63693E-02 15.390 0.51631E-01 0.24945E-01 0.12099E-01 0.63488E-02

157

LENGTH ISOBU-01 N-PEN-01 2-MET-01 N-HEX-01 METER 0.0000 0.53239E-02 0.25525E-02 0.55427E-02 0.12820E-01 1.5390 0.47100E-02 0.22580E-02 0.49034E-02 0.83894E-02 3.0780 0.46024E-02 0.22064E-02 0.47914E-02 0.75016E-02 4.6170 0.45416E-02 0.21772E-02 0.47280E-02 0.69817E-02 6.1560 0.44997E-02 0.21572E-02 0.46844E-02 0.66164E-02 7.6950 0.44679E-02 0.21419E-02 0.46513E-02 0.63339E-02 9.2340 0.44423E-02 0.21296E-02 0.46246E-02 0.61041E-02 10.773 0.44210E-02 0.21194E-02 0.46025E-02 0.59111E-02 12.312 0.44028E-02 0.21107E-02 0.45835E-02 0.57449E-02 13.851 0.43870E-02 0.21031E-02 0.45670E-02 0.55988E-02 15.390 0.43729E-02 0.20963E-02 0.45524E-02 0.54683E-02 LENGTH 2-MET-02 N-HEP-01 2-MET-03 N-OCT-01 METER 0.0000 0.13074E-01 0.16271E-01 0.17570E-01 0.63219E-02 1.5390 0.86224E-02 0.10591E-01 0.11493E-01 0.16246E-02 3.0780 0.77274E-02 0.94554E-02 0.10275E-01 0.11053E-02 4.6170 0.72027E-02 0.87910E-02 0.95620E-02 0.85693E-03 6.1560 0.68336E-02 0.83244E-02 0.90609E-02 0.70749E-03 7.6950 0.65479E-02 0.79638E-02 0.86735E-02 0.60424E-03 9.2340 0.63154E-02 0.76706E-02 0.83584E-02 0.52804E-03 10.773 0.61200E-02 0.74245E-02 0.80938E-02 0.46964E-03 12.312 0.59516E-02 0.72126E-02 0.78658E-02 0.42316E-03 13.851 0.58035E-02 0.70264E-02 0.76655E-02 0.38499E-03 15.390 0.56713E-02 0.68602E-02 0.74866E-02 0.35290E-03 LENGTH 2:2:4-01 N-NON-01 2:2:5-01 CYCLO-01 METER 0.0000 0.94486E-02 0.84651E-02 0.13495E-01 0.0000 1.5390 0.26156E-02 0.53423E-02 0.87077E-02 0.70003E-06 3.0780 0.18183E-02 0.47263E-02 0.77540E-02 0.80214E-06 4.6170 0.14306E-02 0.43679E-02 0.71969E-02 0.85662E-06 6.1560 0.11941E-02 0.41172E-02 0.68062E-02 0.89242E-06 7.6950 0.10293E-02 0.39241E-02 0.65044E-02 0.91880E-06 9.2340 0.90657E-03 0.37675E-02 0.62593E-02 0.93942E-06 10.773 0.81180E-03 0.36364E-02 0.60537E-02 0.95611E-06 12.312 0.73587E-03 0.35238E-02 0.58767E-02 0.97004E-06 13.851 0.67318E-03 0.34250E-02 0.57213E-02 0.98195E-06 15.390 0.62021E-03 0.33371E-02 0.55827E-02 0.99234E-06 LENGTH METHY-01 ETHYL-01 N-PRO-01 CYCLO-02 METER 0.0000 0.0000 0.0000 0.0000 0.72930E-04 1.5390 0.24624E-05 0.26826E-05 0.48094E-06 0.64517E-04 3.0780 0.28148E-05 0.28858E-05 0.54999E-06 0.63043E-04 4.6170 0.30012E-05 0.29598E-05 0.58657E-06 0.62209E-04 6.1560 0.31229E-05 0.29910E-05 0.61047E-06 0.61636E-04 7.6950 0.32122E-05 0.30046E-05 0.62801E-06 0.61200E-04 9.2340 0.32815E-05 0.30088E-05 0.64166E-06 0.60849E-04

158

10.773 0.33374E-05 0.30074E-05 0.65266E-06 0.60557E-04 12.312 0.33839E-05 0.30027E-05 0.66182E-06 0.60308E-04 13.851 0.34235E-05 0.29960E-05 0.66962E-06 0.60091E-04 15.390 0.34578E-05 0.29881E-05 0.67640E-06 0.59898E-04 LENGTH METHY-02 ETHYL-02 N-PRO-02 N-BUT-02 METER 0.0000 0.21879E-02 0.47404E-02 0.61261E-02 0.87516E-03 1.5390 0.19348E-02 0.41909E-02 0.54158E-02 0.77368E-03 3.0780 0.18904E-02 0.40947E-02 0.52914E-02 0.75590E-03 4.6170 0.18653E-02 0.40402E-02 0.52210E-02 0.74584E-03 6.1560 0.18481E-02 0.40027E-02 0.51726E-02 0.73893E-03 7.6950 0.18349E-02 0.39742E-02 0.51357E-02 0.73367E-03 9.2340 0.18244E-02 0.39513E-02 0.51061E-02 0.72943E-03 10.773 0.18156E-02 0.39323E-02 0.50815E-02 0.72592E-03 12.312 0.18081E-02 0.39160E-02 0.50605E-02 0.72291E-03 13.851 0.18016E-02 0.39018E-02 0.50421E-02 0.72029E-03 15.390 0.17958E-02 0.38892E-02 0.50258E-02 0.71796E-03 LENGTH BENZE-01 TOLUE-01 M-XYL-01 O-XYL-01 METER 0.0000 0.19617E-01 0.24435E-01 0.96954E-02 0.10121E-01 1.5390 0.37715E-01 0.24283E-01 0.10864E-01 0.15062E-01 3.0780 0.42751E-01 0.23671E-01 0.10893E-01 0.15911E-01 4.6170 0.45963E-01 0.23166E-01 0.10882E-01 0.16380E-01 6.1560 0.48352E-01 0.22734E-01 0.10862E-01 0.16696E-01 7.6950 0.50271E-01 0.22354E-01 0.10841E-01 0.16931E-01 9.2340 0.51880E-01 0.22014E-01 0.10820E-01 0.17116E-01 10.773 0.53268E-01 0.21704E-01 0.10799E-01 0.17267E-01 12.312 0.54489E-01 0.21420E-01 0.10779E-01 0.17393E-01 13.851 0.55583E-01 0.21156E-01 0.10761E-01 0.17501E-01 15.390 0.56574E-01 0.20909E-01 0.10743E-01 0.17596E-01 LENGTH P-XYL-01 ETHYL-03 N-PRO-03 HYDRO-01 METER 0.0000 0.11210E-01 0.10088E-01 0.10422E-01 0.72483 1.5390 0.97241E-02 0.84712E-02 0.72820E-02 0.73146 3.0780 0.90284E-02 0.77862E-02 0.64823E-02 0.73023 4.6170 0.85641E-02 0.73370E-02 0.59956E-02 0.72908 6.1560 0.82119E-02 0.69999E-02 0.56464E-02 0.72808 7.6950 0.79266E-02 0.67291E-02 0.53736E-02 0.72720 9.2340 0.76863E-02 0.65024E-02 0.51503E-02 0.72641 10.773 0.74788E-02 0.63076E-02 0.49620E-02 0.72570 12.312 0.72959E-02 0.61368E-02 0.47992E-02 0.72505 13.851 0.71323E-02 0.59847E-02 0.46561E-02 0.72445 15.390 0.69842E-02 0.58474E-02 0.45283E-02 0.72390

159

TOTAL MASS FRACTION PROFILE (PROCESS STREAM) LENGTH METHA-01 ETHAN-01 PROPA-01 N-BUT-01 METER 0.0000 0.97570E-02 0.20021E-01 0.25675E-01 0.17759E-01 1.5390 0.23492E-01 0.28010E-01 0.25675E-01 0.17758E-01 3.0780 0.27711E-01 0.30232E-01 0.25675E-01 0.17758E-01 4.6170 0.30467E-01 0.31629E-01 0.25675E-01 0.17758E-01 6.1560 0.32543E-01 0.32655E-01 0.25675E-01 0.17758E-01 7.6950 0.34229E-01 0.33471E-01 0.25675E-01 0.17758E-01 9.2340 0.35653E-01 0.34150E-01 0.25675E-01 0.17758E-01 10.773 0.36889E-01 0.34730E-01 0.25675E-01 0.17758E-01 12.312 0.37982E-01 0.35237E-01 0.25675E-01 0.17758E-01 13.851 0.38965E-01 0.35689E-01 0.25675E-01 0.17758E-01 15.390 0.39860E-01 0.36095E-01 0.25675E-01 0.17758E-01 LENGTH ISOBU-01 N-PEN-01 2-MET-01 N-HEX-01 METER 0.0000 0.12230E-01 0.72788E-02 0.15805E-01 0.43664E-01 1.5390 0.12231E-01 0.72785E-02 0.15806E-01 0.32300E-01 3.0780 0.12231E-01 0.72785E-02 0.15806E-01 0.29557E-01 4.6170 0.12231E-01 0.72785E-02 0.15806E-01 0.27878E-01 6.1560 0.12231E-01 0.72784E-02 0.15806E-01 0.26664E-01 7.6950 0.12231E-01 0.72784E-02 0.15806E-01 0.25708E-01 9.2340 0.12231E-01 0.72784E-02 0.15806E-01 0.24918E-01 10.773 0.12231E-01 0.72784E-02 0.15806E-01 0.24246E-01 12.312 0.12231E-01 0.72784E-02 0.15806E-01 0.23662E-01 13.851 0.12231E-01 0.72784E-02 0.15806E-01 0.23143E-01 15.390 0.12231E-01 0.72784E-02 0.15806E-01 0.22677E-01 LENGTH 2-MET-02 N-HEP-01 2-MET-03 N-OCT-01 METER 0.0000 0.44530E-01 0.64440E-01 0.69584E-01 0.28542E-01 1.5390 0.33197E-01 0.47414E-01 0.51450E-01 0.82909E-02 3.0780 0.30447E-01 0.43319E-01 0.47074E-01 0.57726E-02 4.6170 0.28760E-01 0.40816E-01 0.44395E-01 0.45356E-02 6.1560 0.27540E-01 0.39008E-01 0.42459E-01 0.37794E-02 7.6950 0.26577E-01 0.37585E-01 0.40934E-01 0.32509E-02 9.2340 0.25781E-01 0.36410E-01 0.39674E-01 0.28573E-02 10.773 0.25103E-01 0.35411E-01 0.38603E-01 0.25535E-02 12.312 0.24513E-01 0.34542E-01 0.37671E-01 0.23103E-02 13.851 0.23990E-01 0.33772E-01 0.36844E-01 0.21095E-02 15.390 0.23519E-01 0.33080E-01 0.36101E-01 0.19399E-02 LENGTH 2:2:4-01 N-NON-01 2:2:5-01 CYCLO-01 METER 0.0000 0.42658E-01 0.42911E-01 0.68406E-01 0.0000 1.5390 0.13348E-01 0.30612E-01 0.49896E-01 0.26321E-05 3.0780 0.94967E-02 0.27715E-01 0.45470E-01 0.30866E-05 4.6170 0.75719E-02 0.25957E-01 0.42769E-01 0.33404E-05

160

6.1560 0.63790E-02 0.24695E-01 0.40823E-01 0.35124E-05 7.6950 0.55375E-02 0.23704E-01 0.39291E-01 0.36420E-05 9.2340 0.49056E-02 0.22890E-01 0.38028E-01 0.37452E-05 10.773 0.44139E-02 0.22200E-01 0.36956E-01 0.38301E-05 12.312 0.40176E-02 0.21601E-01 0.36024E-01 0.39019E-05 13.851 0.36886E-02 0.21071E-01 0.35199E-01 0.39641E-05 15.390 0.34093E-02 0.20596E-01 0.34456E-01 0.40190E-05

LENGTH METHY-01 ETHYL-01 N-PRO-01 CYCLO-02

METER 0.0000 0.0000 0.0000 0.0000 0.20215E-03 1.5390 0.10802E-04 0.13449E-04 0.27125E-05 0.20215E-03 3.0780 0.12636E-04 0.14806E-04 0.31745E-05 0.20215E-03 4.6170 0.13654E-04 0.15389E-04 0.34310E-05 0.20215E-03 6.1560 0.14340E-04 0.15696E-04 0.36040E-05 0.20215E-03 7.6950 0.14855E-04 0.15880E-04 0.37340E-05 0.20215E-03 9.2340 0.15263E-04 0.15994E-04 0.38371E-05 0.20215E-03 10.773 0.15598E-04 0.16063E-04 0.39217E-05 0.20215E-03 12.312 0.15880E-04 0.16104E-04 0.39932E-05 0.20215E-03 13.851 0.16124E-04 0.16126E-04 0.40549E-05 0.20215E-03 15.390 0.16338E-04 0.16136E-04 0.41091E-05 0.20215E-03 LENGTH METHY-02 ETHYL-02 N-PRO-02 N-BUT-02 METER 0.0000 0.72776E-02 0.18396E-01 0.27170E-01 0.43665E-02 1.5390 0.72747E-02 0.18384E-01 0.27152E-01 0.43636E-02 3.0780 0.72742E-02 0.18382E-01 0.27148E-01 0.43630E-02 4.6170 0.72738E-02 0.18381E-01 0.27146E-01 0.43626E-02 6.1560 0.72736E-02 0.18380E-01 0.27144E-01 0.43624E-02 7.6950 0.72734E-02 0.18379E-01 0.27143E-01 0.43622E-02 9.2340 0.72732E-02 0.18378E-01 0.27142E-01 0.43620E-02 10.773 0.72731E-02 0.18378E-01 0.27141E-01 0.43619E-02 12.312 0.72730E-02 0.18377E-01 0.27141E-01 0.43618E-02 13.851 0.72729E-02 0.18377E-01 0.27140E-01 0.43617E-02 15.390 0.72728E-02 0.18376E-01 0.27139E-01 0.43616E-02 LENGTH BENZE-01 TOLUE-01 M-XYL-01 O-XYL-01 METER 0.0000 0.60564E-01 0.88983E-01 0.40682E-01 0.42469E-01 1.5390 0.13162 0.99960E-01 0.51531E-01 0.71441E-01 3.0780 0.15268 0.99718E-01 0.52875E-01 0.77233E-01 4.6170 0.16636 0.98901E-01 0.53531E-01 0.80577E-01 6.1560 0.17663 0.97959E-01 0.53930E-01 0.82891E-01 7.6950 0.18495 0.97010E-01 0.54207E-01 0.84658E-01 9.2340 0.19197 0.96084E-01 0.54413E-01 0.86077E-01 10.773 0.19805 0.95189E-01 0.54570E-01 0.87254E-01 12.312 0.20343 0.94328E-01 0.54696E-01 0.88255E-01 13.851 0.20826 0.93502E-01 0.54799E-01 0.89127E-01 15.390 0.21266 0.92710E-01 0.54886E-01 0.89897E-01

161

LENGTH P-XYL-01 ETHYL-03 N-PRO-03 HYDRO-01 METER 0.0000 0.47038E-01 0.42330E-01 0.49510E-01 0.57750E-01 1.5390 0.46123E-01 0.40180E-01 0.39103E-01 0.65878E-01 3.0780 0.43824E-01 0.37795E-01 0.35623E-01 0.67305E-01 4.6170 0.42128E-01 0.36092E-01 0.33390E-01 0.68101E-01 6.1560 0.40771E-01 0.34754E-01 0.31738E-01 0.68639E-01 7.6950 0.39635E-01 0.33647E-01 0.30420E-01 0.69045E-01 9.2340 0.38655E-01 0.32701E-01 0.29324E-01 0.69368E-01 10.773 0.37793E-01 0.31874E-01 0.28387E-01 0.69633E-01 12.312 0.37021E-01 0.31139E-01 0.27570E-01 0.69858E-01 13.851 0.36322E-01 0.30477E-01 0.26844E-01 0.70053E-01 15.390 0.35682E-01 0.29874E-01 0.26191E-01 0.70225E-01

162

7.8. STREAM RESULTS

7.8.1. HP-RCY HYDROGEN NAP-HYD REFORM S1

STREAM ID HP-RCY HYDROGEN NAP-HYD REFORM S1 FROM : B5 E-8 ---- E-12 B9 TO : ---- ---- B7 ---- B10 SUBSTREAM: MIXED PHASE: VAPOR LIQUID MIXED VAPOR LIQUID COMPONENTS: KMOL/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 0.1586 4.5996-05 3.9473-02 2.6038-03 1.3249-03 ETHAN-01 7.1173-02 1.9989-05 4.3215-02 6.7163-03 3.3681-03 PROPA-01 2.8791-02 8.1261-06 3.7789-02 8.9900-03 4.4991-03 N-BUT-01 9.4557-03 2.6862-06 1.9830-02 1.0371-02 5.1866-03 ISOBU-01 7.7206-03 2.1913-06 1.3657-02 5.9348-03 2.9685-03 N-PEN-01 1.5545-03 4.4357-07 6.5477-03 4.9924-03 2.4964-03 2-MET-01 3.8952-03 1.1106-06 1.4218-02 1.0322-02 5.1615-03 N-HEX-01 1.5613-03 4.4656-07 4.2840-02 1.5517-02 7.7588-03 2-MET-02 2.0736-03 5.9370-07 4.3402-02 1.5639-02 7.8197-03 N-HEP-01 6.9961-04 1.9974-07 5.4626-02 2.0726-02 1.0363-02 2-MET-03 1.0626-03 3.0553-07 5.8742-02 2.2320-02 1.1160-02 N-OCT-01 1.2390-05 3.5812-09 4.4711-02 1.0898-03 5.4490-04 2:2:4-01 7.2539-05 2.0893-08 6.3232-02 1.8645-03 9.3227-04 N-NON-01 4.3716-05 1.2689-08 2.9184-02 1.0379-02 5.1894-03 2:2:5-01 2.8026-04 8.1055-08 4.5647-02 1.7156-02 8.5780-03 CYCLO-01 1.6772-07 4.7996-11 1.4405-02 2.9316-06 1.4658-06 METHY-01 3.0169-07 8.6631-11 1.5714-02 1.0498-05 5.2490-06 ETHYL-01 9.6315-08 2.7784-11 2.1514-02 9.2361-06 4.6181-06 N-PRO-01 9.2293-09 2.6722-12 3.3674-03 2.1033-06 1.0517-06 CYCLO-02 2.6281-05 7.4930-09 1.8708-04 1.6079-04 8.0398-05 METHY-02 4.0564-04 1.1605-07 5.6123-03 5.2028-03 2.6015-03 ETHYL-02 2.9798-04 8.5608-08 1.2160-02 1.1849-02 5.9245-03 N-PRO-02 1.3531-04 3.9036-08 1.5714-02 1.5561-02 7.7808-03 N-BUT-02 6.9925-06 2.0259-09 2.2449-03 2.2354-03 1.1177-03 BENZE-01 1.0447-02 2.9844-06 1.6089-02 0.1662 8.3125-02 TOLUE-01 1.3082-03 3.7532-07 2.0391-02 6.3995-02 3.1998-02 M-XYL-01 1.9511-04 5.6233-08 2.8061-03 3.3358-02 1.6679-02 O-XYL-01 2.7217-04 7.8433-08 2.9932-03 5.4684-02 2.7342-02 P-XYL-01 1.3174-04 3.7971-08 6.7347-03 2.1682-02 1.0841-02 ETHYL-03 1.2458-04 3.5885-08 3.9286-03 1.8138-02 9.0692-03 N-PRO-03 3.7335-05 1.0797-08 4.8640-03 1.4106-02 7.0528-03 HYDRO-01 2.2552 9.0224-04 1.1647 4.8164-03 2.8593-03 COMPONENTS: STD CUM/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 8.4947-03 2.4634-06 2.1141-03 1.3946-04 7.0960-05 ETHAN-01 6.0292-03 1.6933-06 3.6608-03 5.6895-04 2.8532-04 PROPA-01 2.5090-03 7.0814-07 3.2931-03 7.8343-04 3.9207-04 N-BUT-01 9.4286-04 2.6785-07 1.9773-03 1.0341-03 5.1717-04 ISOBU-01 7.9928-04 2.2685-07 1.4138-03 6.1440-04 3.0731-04 N-PEN-01 1.7825-04 5.0864-08 7.5082-04 5.7248-04 2.8626-04 2-MET-01 4.5114-04 1.2863-07 1.6467-03 1.1955-03 5.9780-04 N-HEX-01 2.0318-04 5.8114-08 5.5752-03 2.0194-03 1.0097-03

163

2-MET-02 2.7235-04 7.7980-08 5.7006-03 2.0541-03 1.0271-03 N-HEP-01 1.0213-04 2.9160-08 7.9748-03 3.0258-03 1.5129-03 STREAM ID HP-RCY HYDROGEN NAP-HYD REFORM S1 N-OCT-01 2.0077-06 5.8029-10 7.2449-03 1.7659-04 8.8295-05 2:2:4-01 1.1933-05 3.4370-09 1.0402-02 3.0672-04 1.5336-04 N-NON-01 7.7889-06 2.2608-09 5.1997-03 1.8492-03 9.2459-04 2:2:5-01 5.0180-05 1.4513-08 8.1728-03 3.0717-03 1.5359-03 CYCLO-01 1.8062-08 5.1685-12 1.5512-03 3.1569-07 1.5785-07 METHY-01 3.8367-08 1.1017-11 1.9984-03 1.3350-06 6.6753-07 ETHYL-01 1.3776-08 3.9742-12 3.0772-03 1.3211-06 6.6055-07 N-PRO-01 1.4641-09 4.2391-13 5.3419-04 3.3367-07 1.6683-07 CYCLO-02 2.4624-06 7.0206-10 1.7528-05 1.5065-05 7.5329-06 METHY-02 4.5414-05 1.2993-08 6.2832-04 5.8248-04 2.9125-04 ETHYL-02 3.8038-05 1.0928-08 1.5522-03 1.5125-03 7.5626-04 N-PRO-02 1.9495-05 5.6245-09 2.2642-03 2.2422-03 1.1211-03 N-BUT-02 1.1298-06 3.2733-10 3.6271-04 3.6117-04 1.8059-04 BENZE-01 9.2466-04 2.6414-07 1.4240-03 1.4714-02 7.3573-03 TOLUE-01 1.3856-04 3.9753-08 2.1598-03 6.7783-03 3.3892-03 M-XYL-01 2.3897-05 6.8874-09 3.4369-04 4.0856-03 2.0428-03 O-XYL-01 3.2732-05 9.4326-09 3.5998-04 6.5765-03 3.2883-03 P-XYL-01 1.6193-05 4.6670-09 8.2777-04 2.6649-03 1.3325-03 ETHYL-03 1.5206-05 4.3802-09 4.7953-04 2.2140-03 1.1070-03 N-PRO-03 5.1907-06 1.5011-09 6.7624-04 1.9611-03 9.8056-04 HYDRO-01 0.1208 4.8322-05 6.2381-02 2.5796-04 1.5314-04 TOTAL CUM/SEC 0.1423 5.4453-05 0.1544 6.4664-02 3.2359-02 COMPONENTS: STD VOL FRAC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 5.9714-02 4.5239-02 1.3692-02 2.1566-03 2.1929-03 ETHAN-01 4.2382-02 3.1096-02 2.3709-02 8.7985-03 8.8172-03 PROPA-01 1.7637-02 1.3005-02 2.1328-02 1.2115-02 1.2116-02 N-BUT-01 6.6279-03 4.9188-03 1.2806-02 1.5992-02 1.5982-02 ISOBU-01 5.6186-03 4.1660-03 9.1564-03 9.5014-03 9.4970-03 N-PEN-01 1.2530-03 9.3408-04 4.8627-03 8.8531-03 8.8464-03 2-MET-01 3.1713-03 2.3622-03 1.0665-02 1.8487-02 1.8474-02 N-HEX-01 1.4283-03 1.0672-03 3.6108-02 3.1229-02 3.1203-02 2-MET-02 1.9145-03 1.4320-03 3.6920-02 3.1765-02 3.1740-02 N-HEP-01 7.1796-04 5.3550-04 5.1649-02 4.6793-02 4.6754-02 2-MET-03 1.0987-03 8.2527-04 5.5958-02 5.0769-02 5.0727-02 N-OCT-01 1.4113-05 1.0657-05 4.6922-02 2.7309-03 2.7286-03 2:2:4-01 8.3884-05 6.3118-05 6.7368-02 4.7433-03 4.7394-03 N-NON-01 5.4753-05 4.1519-05 3.3676-02 2.8597-02 2.8573-02 2:2:5-01 3.5274-04 2.6651-04 5.2931-02 4.7502-02 4.7463-02 CYCLO-01 1.2697-07 9.4916-08 1.0046-02 4.8820-06 4.8780-06 METHY-01 2.6970-07 2.0232-07 1.2943-02 2.0646-05 2.0629-05 ETHYL-01 9.6843-08 7.2983-08 1.9930-02 2.0430-05 2.0413-05 N-PRO-01 1.0292-08 7.7848-09 3.4597-03 5.1600-06 5.1557-06 CYCLO-02 1.7310-05 1.2893-05 1.1352-04 2.3297-04 2.3279-04 METHY-02 3.1924-04 2.3860-04 4.0693-03 9.0079-03 9.0005-03 ETHYL-02 2.6739-04 2.0068-04 1.0053-02 2.3390-02 2.3371-02 N-PRO-02 1.3704-04 1.0329-04 1.4664-02 3.4674-02 3.4645-02 N-BUT-02 7.9420-06 6.0113-06 2.3491-03 5.5854-03 5.5807-03 BENZE-01 6.4999-03 4.8508-03 9.2224-03 0.2275 0.2274 TOLUE-01 9.7400-04 7.3003-04 1.3988-02 0.1048 0.1047

164

M-XYL-01 1.6799-04 1.2648-04 2.2259-03 6.3183-02 6.3130-02 O-XYL-01 2.3009-04 1.7322-04 2.3314-03 0.1017 0.1016 STREAM ID HP-RCY HYDROGEN NAP-HYD REFORM S1 P-XYL-01 1.1383-04 8.5706-05 5.3611-03 4.1212-02 4.1177-02 ETHYL-03 1.0689-04 8.0440-05 3.1057-03 3.4238-02 3.4210-02 N-PRO-03 3.6489-05 2.7566-05 4.3797-03 3.0328-02 3.0302-02 HYDRO-01 0.8491 0.8874 0.4040 3.9892-03 4.7325-03 TOTAL CUM/SEC 0.1423 5.4453-05 0.1544 6.4664-02 3.2359-02 TOTAL FLOW: KMOL/SEC 2.5556 9.8828-04 1.8706 0.5667 0.2838 KG/SEC 13.5321 4.3812-03 64.8992 51.3651 25.6848 CUM/SEC 3.0118 2.0783-05 1.0774 22.9340 3.2669-02 STATE VARIABLES: TEMP K 313.0000 22.2945 298.1500 500.0000 313.0000 PRES N/SQM 2.2300+06 3.1000+06 3.1500+06 1.0133+05 2.2300+06 VFRAC 1.0000 0.0 0.6641 1.0000 0.0 LFRAC 0.0 1.0000 0.3359 0.0 1.0000 SFRAC 0.0 0.0 0.0 0.0 0.0 ENTHALPY: J/KMOL -8.9562+06 -1.7592+07 -6.8260+07 9.6009+06 -5.4112+07 J/KG -1.6914+06 -3.9682+06 -1.9674+06 1.0592+05 -5.9797+05 WATT -2.2888+07 -1.7386+04 -1.2769+08 5.4407+06 -1.5359+07 ENTROPY: J/KMOL-K -3.8645+04 4.9467+04 -2.4825+05 -2.5756+05 -4.2443+05 J/KG-K -7298.2790 1.1158+04 -7155.2857 -2841.5515 -4690.2053 DENSITY: KMOL/CUM 0.8485 47.5510 1.7362 2.4709-02 8.6881 KG/CUM 4.4931 210.8042 60.2368 2.2397 786.2050 AVG MW 5.2951 4.4332 34.6948 90.6422 90.4921 MIXED SUBSTREAM PROPERTIES: *** ALL PHASES *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 4616.3517 1.3387 1148.8791 75.7861 38.5624 ETHAN-01 3276.4839 0.9202 1989.4088 309.1874 155.0538 PROPA-01 1363.4828 0.3848 1789.6126 425.7449 213.0649 N-BUT-01 512.3872 0.1456 1074.5526 561.9602 281.0529 ISOBU-01 434.3596 0.1233 768.3114 333.8904 167.0069 N-PEN-01 96.8691 2.7642-02 408.0252 311.1060 155.5668 2-MET-01 245.1669 6.9902-02 894.8831 649.6690 324.8694 N-HEX-01 110.4156 3.1582-02 3029.7638 1097.4126 548.7221 2-MET-02 148.0080 4.2377-02 3097.9471 1116.2711 558.1567 N-HEP-01 55.5038 1.5846-02 4333.8031 1644.3377 822.1768 2-MET-03 84.9387 2.4422-02 4695.4054 1784.0806 892.0525 N-OCT-01 1.0911 3.1535-04 3937.1679 95.9660 47.9832 2:2:4-01 6.4849 1.8678-03 5652.8175 166.6857 83.3438 N-NON-01 4.2328 1.2286-03 2825.7149 1004.9184 502.4598 2:2:5-01 27.2699 7.8867-03 4441.4381 1669.2779 834.6429 CYCLO-01 9.8154-03 2.8088-06 842.9914 0.1716 8.5781-02 METHY-01 2.0850-02 5.9871-06 1086.0339 0.7255 0.3628 ETHYL-01 7.4867-03 2.1597-06 1672.2929 0.7179 0.3590

165

N-PRO-01 7.9565-04 2.3037-07 290.2994 0.1813 9.0664-02 CYCLO-02 1.3382 3.8153-04 9.5255 8.1869 4.0937 STREAM ID HP-RCY HYDROGEN NAP-HYD REFORM S1 METHY-02 24.6796 7.0608-03 341.4553 316.5450 158.2761 ETHYL-02 20.6712 5.9386-03 843.5354 821.9543 410.9801 N-PRO-02 10.5946 3.0566-03 1230.4592 1218.4870 609.2450 N-BUT-02 0.6140 1.7789-04 197.1136 196.2763 98.1382 BENZE-01 502.4948 0.1435 773.8478 7996.3303 3998.2369 TOLUE-01 75.2977 2.1603-02 1173.7225 3683.5826 1841.8021 M-XYL-01 12.9868 3.7429-03 186.7764 2220.3011 1110.1524 O-XYL-01 17.7880 5.1261-03 195.6252 3573.9440 1786.9746 P-XYL-01 8.7998 2.5362-03 449.8445 1448.2179 724.1102 ETHYL-03 8.2638 2.3804-03 260.5967 1203.1734 601.5879 N-PRO-03 2.8208 8.1573-04 367.4973 1065.7460 532.8734 HYDRO-01 6.5638+04 26.2601 3.3900+04 140.1835 83.2218 *** VAPOR PHASE *** VOLFLMX CUFT/HR 3.8289+05 MISSING 1.2621+05 2.9157+06 MISSING VVSTDMX CUFT/HR 7.2821+06 MISSING 3.5396+06 1.6148+06 MISSING CPMX BTU/LB-R 1.4524 MISSING 1.7895 0.4979 MISSING RHOMX LB/CUFT 0.2805 MISSING 0.3245 0.1398 MISSING MWMX 5.2951 MISSING 4.1546 90.6422 MISSING *** LIQUID PHASE *** VOLFLMX BBL/HR MISSING 0.4706 1917.2095 MISSING 739.7410 BBL/DAY MISSING 11.2946 4.6013+04 MISSING 1.7754+04 CPMX BTU/LB-R MISSING 2.0260 0.4920 MISSING 0.4451 MUMX CP MISSING 5.5187-02 0.2937 MISSING 0.3593 VLSTDMX BBL/HR MISSING 1.2330 1944.1958 MISSING 732.7211 BBL/DAY MISSING 29.5922 4.6661+04 MISSING 1.7585+04 *** DRY TOTAL *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 4616.3517 1.3387 1148.8791 75.7861 38.5624 ETHAN-01 3276.4839 0.9202 1989.4088 309.1874 155.0538 PROPA-01 1363.4828 0.3848 1789.6126 425.7449 213.0649 N-BUT-01 512.3872 0.1456 1074.5526 561.9602 281.0529 ISOBU-01 434.3596 0.1233 768.3114 333.8904 167.0069 N-PEN-01 96.8691 2.7642-02 408.0252 311.1060 155.5668 2-MET-01 245.1669 6.9902-02 894.8831 649.6690 324.8694 N-HEX-01 110.4156 3.1582-02 3029.7638 1097.4126 548.7221 2-MET-02 148.0080 4.2377-02 3097.9471 1116.2711 558.1567 N-HEP-01 55.5038 1.5846-02 4333.8031 1644.3377 822.1768 2-MET-03 84.9387 2.4422-02 4695.4054 1784.0806 892.0525 N-OCT-01 1.0911 3.1535-04 3937.1679 95.9660 47.9832 2:2:4-01 6.4849 1.8678-03 5652.8175 166.6857 83.3438 N-NON-01 4.2328 1.2286-03 2825.7149 1004.9184 502.4598 2:2:5-01 27.2699 7.8867-03 4441.4381 1669.2779 834.6429 CYCLO-01 9.8154-03 2.8088-06 842.9914 0.1716 8.5781-02 METHY-01 2.0850-02 5.9871-06 1086.0339 0.7255 0.3628 ETHYL-01 7.4867-03 2.1597-06 1672.2929 0.7179 0.3590

166

N-PRO-01 7.9565-04 2.3037-07 290.2994 0.1813 9.0664-02 CYCLO-02 1.3382 3.8153-04 9.5255 8.1869 4.0937 METHY-02 24.6796 7.0608-03 341.4553 316.5450 158.2761 STREAM ID HP-RCY HYDROGEN NAP-HYD REFORM S1 ETHYL-02 20.6712 5.9386-03 843.5354 821.9543 410.9801 N-PRO-02 10.5946 3.0566-03 1230.4592 1218.4870 609.2450 N-BUT-02 0.6140 1.7789-04 197.1136 196.2763 98.1382 BENZE-01 502.4948 0.1435 773.8478 7996.3303 3998.2369 TOLUE-01 75.2977 2.1603-02 1173.7225 3683.5826 1841.8021 M-XYL-01 12.9868 3.7429-03 186.7764 2220.3011 1110.1524 O-XYL-01 17.7880 5.1261-03 195.6252 3573.9440 1786.9746 P-XYL-01 8.7998 2.5362-03 449.8445 1448.2179 724.1102 ETHYL-03 8.2638 2.3804-03 260.5967 1203.1734 601.5879 N-PRO-03 2.8208 8.1573-04 367.4973 1065.7460 532.8734 HYDRO-01 6.5638+04 26.2601 3.3900+04 140.1835 83.2218 VLSTDMX BBL/DAY 7.7308+04 29.5922 8.3909+04 3.5141+04 1.7585+04 APISTD 250.8040 261.7006 85.6192 45.5796 45.5981 SGSTD 0.3700 0.3598 0.6517 0.7991 0.7990 WAT 11.9689 11.9045 11.2327 11.0189 11.0191 FLPT-API K MISSING MISSING MISSING 255.4952 255.3092 RVP-API N/SQM 1.7065+09 1.9135+09 8.0249+07 1.1911+06 1.3868+06

167

7.8.2. S10 S11 S12 S15 S16

STREAM ID S10 S11 S12 S15 S16 FROM : E-2 E-3 B5 B10 E-4 TO : E-3 B5 B9 E-4 F-2 SUBSTREAM: MIXED PHASE: VAPOR MIXED LIQUID LIQUID MIXED COMPONENTS: KMOL/SEC METHA-01 0.1613 0.1613 2.6498-03 1.3249-03 1.3249-03 ETHAN-01 7.7909-02 7.7909-02 6.7363-03 3.3681-03 3.3681-03 PROPA-01 3.7789-02 3.7789-02 8.9981-03 4.4991-03 4.4991-03 N-BUT-01 1.9829-02 1.9829-02 1.0373-02 5.1866-03 5.1866-03 ISOBU-01 1.3658-02 1.3658-02 5.9370-03 2.9685-03 2.9685-03 N-PEN-01 6.5473-03 6.5473-03 4.9928-03 2.4964-03 2.4964-03 2-MET-01 1.4218-02 1.4218-02 1.0323-02 5.1615-03 5.1615-03 N-HEX-01 1.7079-02 1.7079-02 1.5518-02 7.7588-03 7.7588-03 2-MET-02 1.7713-02 1.7713-02 1.5639-02 7.8197-03 7.8197-03 N-HEP-01 2.1426-02 2.1426-02 2.0727-02 1.0363-02 1.0363-02 2-MET-03 2.3383-02 2.3383-02 2.2320-02 1.1160-02 1.1160-02 N-OCT-01 1.1022-03 1.1022-03 1.0898-03 5.4490-04 5.4490-04 2:2:4-01 1.9371-03 1.9371-03 1.8645-03 9.3227-04 9.3227-04 N-NON-01 1.0422-02 1.0422-02 1.0379-02 5.1894-03 5.1894-03 2:2:5-01 1.7436-02 1.7436-02 1.7156-02 8.5780-03 8.5780-03 CYCLO-01 3.0993-06 3.0993-06 2.9316-06 1.4658-06 1.4658-06 METHY-01 1.0800-05 1.0800-05 1.0498-05 5.2490-06 5.2490-06 ETHYL-01 9.3325-06 9.3325-06 9.2362-06 4.6181-06 4.6181-06 N-PRO-01 2.1126-06 2.1126-06 2.1033-06 1.0517-06 1.0517-06 CYCLO-02 1.8708-04 1.8708-04 1.6080-04 8.0398-05 8.0398-05 METHY-02 5.6086-03 5.6086-03 5.2030-03 2.6015-03 2.6015-03 ETHYL-02 1.2147-02 1.2147-02 1.1849-02 5.9245-03 5.9245-03 N-PRO-02 1.5697-02 1.5697-02 1.5562-02 7.7808-03 7.7808-03 N-BUT-02 2.2424-03 2.2424-03 2.2354-03 1.1177-03 1.1177-03 BENZE-01 0.1767 0.1767 0.1662 8.3125-02 8.3125-02 TOLUE-01 6.5304-02 6.5304-02 6.3996-02 3.1998-02 3.1998-02 M-XYL-01 3.3553-02 3.3553-02 3.3358-02 1.6679-02 1.6679-02 O-XYL-01 5.4956-02 5.4956-02 5.4684-02 2.7342-02 2.7342-02 P-XYL-01 2.1813-02 2.1813-02 2.1682-02 1.0841-02 1.0841-02 ETHYL-03 1.8263-02 1.8263-02 1.8138-02 9.0692-03 9.0692-03 N-PRO-03 1.4143-02 1.4143-02 1.4106-02 7.0528-03 7.0528-03 HYDRO-01 2.2609 2.2609 5.7186-03 2.8593-03 2.8593-03 COMPONENTS: STD CUM/SEC METHA-01 8.6366-03 8.6366-03 1.4192-04 7.0960-05 7.0960-05 ETHAN-01 6.5998-03 6.5998-03 5.7064-04 2.8532-04 2.8532-04 PROPA-01 3.2931-03 3.2931-03 7.8413-04 3.9207-04 3.9207-04 N-BUT-01 1.9772-03 1.9772-03 1.0343-03 5.1717-04 5.1717-04 ISOBU-01 1.4139-03 1.4139-03 6.1463-04 3.0731-04 3.0731-04 N-PEN-01 7.5078-04 7.5078-04 5.7253-04 2.8626-04 2.8626-04 2-MET-01 1.6467-03 1.6467-03 1.1956-03 5.9780-04 5.9780-04 N-HEX-01 2.2226-03 2.2226-03 2.0194-03 1.0097-03 1.0097-03 2-MET-02 2.3265-03 2.3265-03 2.0542-03 1.0271-03 1.0271-03

168

N-HEP-01 3.1280-03 3.1280-03 3.0258-03 1.5129-03 1.5129-03 2-MET-03 3.4393-03 3.4393-03 3.2830-03 1.6415-03 1.6415-03 STREAM ID S10 S11 S12 S15 S16 N-OCT-01 1.7860-04 1.7860-04 1.7659-04 8.8295-05 8.8295-05 2:2:4-01 3.1866-04 3.1866-04 3.0673-04 1.5336-04 1.5336-04 N-NON-01 1.8570-03 1.8570-03 1.8492-03 9.2459-04 9.2459-04 2:2:5-01 3.1219-03 3.1219-03 3.0717-03 1.5359-03 1.5359-03 CYCLO-01 3.3376-07 3.3376-07 3.1570-07 1.5785-07 1.5785-07 METHY-01 1.3734-06 1.3734-06 1.3351-06 6.6753-07 6.6753-07 ETHYL-01 1.3349-06 1.3349-06 1.3211-06 6.6055-07 6.6055-07 N-PRO-01 3.3513-07 3.3513-07 3.3367-07 1.6683-07 1.6683-07 CYCLO-02 1.7528-05 1.7528-05 1.5066-05 7.5329-06 7.5329-06 METHY-02 6.2791-04 6.2791-04 5.8250-04 2.9125-04 2.9125-04 ETHYL-02 1.5506-03 1.5506-03 1.5125-03 7.5626-04 7.5626-04 N-PRO-02 2.2617-03 2.2617-03 2.2422-03 1.1211-03 1.1211-03 N-BUT-02 3.6230-04 3.6230-04 3.6117-04 1.8059-04 1.8059-04 BENZE-01 1.5639-02 1.5639-02 1.4715-02 7.3573-03 7.3573-03 TOLUE-01 6.9169-03 6.9169-03 6.7783-03 3.3892-03 3.3892-03 M-XYL-01 4.1095-03 4.1095-03 4.0857-03 2.0428-03 2.0428-03 O-XYL-01 6.6093-03 6.6093-03 6.5765-03 3.2883-03 3.2883-03 P-XYL-01 2.6811-03 2.6811-03 2.6649-03 1.3325-03 1.3325-03 ETHYL-03 2.2292-03 2.2292-03 2.2140-03 1.1070-03 1.1070-03 N-PRO-03 1.9663-03 1.9663-03 1.9611-03 9.8056-04 9.8056-04 HYDRO-01 0.1211 0.1211 3.0628-04 1.5314-04 1.5314-04 TOTAL CUM/SEC 0.2070 0.2070 6.4719-02 3.2359-02 3.2359-02 COMPONENTS: STD VOL FRAC METHA-01 4.1728-02 4.1728-02 2.1929-03 2.1929-03 2.1929-03 ETHAN-01 3.1887-02 3.1887-02 8.8172-03 8.8172-03 8.8172-03 PROPA-01 1.5911-02 1.5911-02 1.2116-02 1.2116-02 1.2116-02 N-BUT-01 9.5529-03 9.5529-03 1.5982-02 1.5982-02 1.5982-02 ISOBU-01 6.8313-03 6.8313-03 9.4970-03 9.4970-03 9.4970-03 N-PEN-01 3.6274-03 3.6274-03 8.8464-03 8.8464-03 8.8464-03 2-MET-01 7.9563-03 7.9563-03 1.8474-02 1.8474-02 1.8474-02 N-HEX-01 1.0739-02 1.0739-02 3.1203-02 3.1203-02 3.1203-02 2-MET-02 1.1241-02 1.1241-02 3.1740-02 3.1740-02 3.1740-02 N-HEP-01 1.5113-02 1.5113-02 4.6754-02 4.6754-02 4.6754-02 2-MET-03 1.6617-02 1.6617-02 5.0727-02 5.0727-02 5.0727-02 N-OCT-01 8.6290-04 8.6290-04 2.7286-03 2.7286-03 2.7286-03 2:2:4-01 1.5396-03 1.5396-03 4.7394-03 4.7394-03 4.7394-03 N-NON-01 8.9720-03 8.9720-03 2.8573-02 2.8573-02 2.8573-02 2:2:5-01 1.5083-02 1.5083-02 4.7463-02 4.7463-02 4.7463-02 CYCLO-01 1.6126-06 1.6126-06 4.8780-06 4.8780-06 4.8780-06 METHY-01 6.6357-06 6.6357-06 2.0629-05 2.0629-05 2.0629-05 ETHYL-01 6.4495-06 6.4495-06 2.0413-05 2.0413-05 2.0413-05 N-PRO-01 1.6192-06 1.6192-06 5.1557-06 5.1557-06 5.1557-06 CYCLO-02 8.4687-05 8.4687-05 2.3279-04 2.3279-04 2.3279-04 METHY-02 3.0338-03 3.0338-03 9.0005-03 9.0005-03 9.0005-03 ETHYL-02 7.4915-03 7.4915-03 2.3371-02 2.3371-02 2.3371-02 N-PRO-02 1.0927-02 1.0927-02 3.4645-02 3.4645-02 3.4645-02 N-BUT-02 1.7505-03 1.7505-03 5.5807-03 5.5807-03 5.5807-03 BENZE-01 7.5561-02 7.5561-02 0.2274 0.2274 0.2274 TOLUE-01 3.3419-02 3.3419-02 0.1047 0.1047 0.1047 M-XYL-01 1.9855-02 1.9855-02 6.3130-02 6.3130-02 6.3130-02 O-XYL-01 3.1933-02 3.1933-02 0.1016 0.1016 0.1016

169

STREAM ID S10 S11 S12 S15 S16 P-XYL-01 1.2954-02 1.2954-02 4.1177-02 4.1177-02 4.1177-02 ETHYL-03 1.0770-02 1.0770-02 3.4210-02 3.4210-02 3.4210-02 N-PRO-03 9.5002-03 9.5002-03 3.0302-02 3.0302-02 3.0302-02 HYDRO-01 0.5850 0.5850 4.7325-03 4.7325-03 4.7325-03 TOTAL CUM/SEC 0.2070 0.2070 6.4719-02 3.2359-02 3.2359-02 TOTAL FLOW: KMOL/SEC 3.1232 3.1232 0.5677 0.2838 0.2838 KG/SEC 64.9016 64.9016 51.3695 25.6848 25.6848 CUM/SEC 58.0577 17.4601 6.5339-02 3.2753-02 3.3055-02 STATE VARIABLES: TEMP K 959.9857 313.0000 313.0000 313.0285 200.0000 PRES N/SQM 4.3000+05 4.0000+05 2.2300+06 1.0000+06 1.0000+06 VFRAC 1.0000 0.8557 0.0 0.0 7.8950-03 LFRAC 0.0 0.1443 1.0000 1.0000 0.9921 SFRAC 0.0 0.0 0.0 0.0 0.0 ENTHALPY: J/KMOL 3.3879+07 -1.6180+07 -5.4112+07 -5.4213+07 -7.1039+07 J/KG 1.6303+06 -7.7864+05 -5.9797+05 -5.9909+05 -7.8503+05 WATT 1.0581+08 -5.0535+07 -3.0717+07 -1.5388+07 -2.0163+07 ENTROPY: J/KMOL-K -5140.8074 -9.3513+04 -4.2443+05 -4.2424+05 -4.9029+05 J/KG-K -247.3901 -4500.0966 -4690.2053 -4688.1224 -5418.0096 DENSITY: KMOL/CUM 5.3796-02 0.1789 8.6881 8.6659 8.5866 KG/CUM 1.1179 3.7171 786.2050 784.1979 777.0217 AVG MW 20.7802 20.7802 90.4921 90.4921 90.4921 MIXED SUBSTREAM PROPERTIES: *** ALL PHASES *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 4693.4765 4693.4765 77.1248 38.5624 38.5624 ETHAN-01 3586.5915 3586.5915 310.1076 155.0538 155.0538 PROPA-01 1789.6126 1789.6126 426.1298 213.0649 213.0649 N-BUT-01 1074.4929 1074.4929 562.1057 281.0529 281.0529 ISOBU-01 768.3733 768.3733 334.0137 167.0069 167.0069 N-PEN-01 408.0027 408.0027 311.1336 155.5668 155.5668 2-MET-01 894.9058 894.9058 649.7389 324.8694 324.8694 N-HEX-01 1207.8598 1207.8598 1097.4442 548.7221 548.7221 2-MET-02 1264.3215 1264.3215 1116.3135 558.1567 558.1567 N-HEP-01 1699.8573 1699.8573 1644.3535 822.1768 822.1768 2-MET-03 1869.0438 1869.0438 1784.1051 892.0525 892.0525 N-OCT-01 97.0574 97.0574 95.9663 47.9832 47.9832 2:2:4-01 173.1725 173.1725 166.6876 83.3438 83.3438 N-NON-01 1009.1524 1009.1524 1004.9196 502.4598 502.4598 2:2:5-01 1696.5557 1696.5557 1669.2858 834.6429 834.6429 CYCLO-01 0.1814 0.1814 0.1716 8.5781-02 8.5781-02 METHY-01 0.7464 0.7464 0.7255 0.3628 0.3628 ETHYL-01 0.7254 0.7254 0.7179 0.3590 0.3590 N-PRO-01 0.1821 0.1821 0.1813 9.0664-02 9.0664-02

170

CYCLO-02 9.5255 9.5255 8.1873 4.0937 4.0937 STREAM ID S10 S11 S12 S15 S16 METHY-02 341.2317 341.2317 316.5521 158.2761 158.2761 ETHYL-02 842.6315 842.6315 821.9603 410.9801 410.9801 N-PRO-02 1229.0847 1229.0847 1218.4901 609.2450 609.2450 N-BUT-02 196.8904 196.8904 196.2764 98.1382 98.1382 BENZE-01 8498.9686 8498.9686 7996.4738 3998.2369 3998.2369 TOLUE-01 3758.9018 3758.9018 3683.6042 1841.8021 1841.8021 M-XYL-01 2233.2916 2233.2916 2220.3048 1110.1524 1110.1524 O-XYL-01 3591.7372 3591.7372 3573.9491 1786.9746 1786.9746 P-XYL-01 1457.0203 1457.0203 1448.2205 724.1102 724.1102 ETHYL-03 1211.4396 1211.4396 1203.1758 601.5879 601.5879 N-PRO-03 1068.5677 1068.5677 1065.7469 532.8734 532.8734 HYDRO-01 6.5805+04 6.5805+04 166.4436 83.2218 83.2218 *** VAPOR PHASE *** VOLFLMX CUFT/HR 7.3810+06 2.2129+06 MISSING MISSING 476.2606 VVSTDMX CUFT/HR 8.8997+06 7.6159+06 MISSING MISSING 6385.3685 CPMX BTU/LB-R 0.9677 1.0219 MISSING MISSING 2.5184 RHOMX LB/CUFT 6.9787-02 7.8741-02 MISSING MISSING 0.1010 MWMX 20.7802 8.2145 MISSING MISSING 2.7050 *** LIQUID PHASE *** VOLFLMX BBL/HR MISSING 1213.5949 1479.4820 741.6343 663.6580 BBL/DAY MISSING 2.9126+04 3.5508+04 1.7799+04 1.5928+04 CPMX BTU/LB-R MISSING 0.4386 0.4451 0.4460 0.3509 MUMX CP MISSING 0.4459 0.3593 0.3592 2.7501 VLSTDMX BBL/HR MISSING 1194.7434 1465.4421 732.7211 729.9969 BBL/DAY MISSING 2.8674+04 3.5171+04 1.7585+04 1.7520+04 *** DRY TOTAL *** VLSTD BBL/DAY METHA-01 4693.4765 4693.4765 77.1248 38.5624 38.5624 ETHAN-01 3586.5915 3586.5915 310.1076 155.0538 155.0538 PROPA-01 1789.6126 1789.6126 426.1298 213.0649 213.0649 N-BUT-01 1074.4929 1074.4929 562.1057 281.0529 281.0529 ISOBU-01 768.3733 768.3733 334.0137 167.0069 167.0069 N-PEN-01 408.0027 408.0027 311.1336 155.5668 155.5668 2-MET-01 894.9058 894.9058 649.7389 324.8694 324.8694 N-HEX-01 1207.8598 1207.8598 1097.4442 548.7221 548.7221 2-MET-02 1264.3215 1264.3215 1116.3135 558.1567 558.1567 N-HEP-01 1699.8573 1699.8573 1644.3535 822.1768 822.1768 2-MET-03 1869.0438 1869.0438 1784.1051 892.0525 892.0525 N-OCT-01 97.0574 97.0574 95.9663 47.9832 47.9832 2:2:4-01 173.1725 173.1725 166.6876 83.3438 83.3438 N-NON-01 1009.1524 1009.1524 1004.9196 502.4598 502.4598 2:2:5-01 1696.5557 1696.5557 1669.2858 834.6429 834.6429 CYCLO-01 0.1814 0.1814 0.1716 8.5781-02 8.5781-02 METHY-01 0.7464 0.7464 0.7255 0.3628 0.3628 ETHYL-01 0.7254 0.7254 0.7179 0.3590 0.3590 N-PRO-01 0.1821 0.1821 0.1813 9.0664-02 9.0664-02 CYCLO-02 9.5255 9.5255 8.1873 4.0937 4.0937 METHY-02 341.2317 341.2317 316.5521 158.2761 158.2761

171

STREAM ID S10 S11 S12 S15 S16 ETHYL-02 842.6315 842.6315 821.9603 410.9801 410.9801 N-PRO-02 1229.0847 1229.0847 1218.4901 609.2450 609.2450 N-BUT-02 196.8904 196.8904 196.2764 98.1382 98.1382 BENZE-01 8498.9686 8498.9686 7996.4738 3998.2369 3998.2369 TOLUE-01 3758.9018 3758.9018 3683.6042 1841.8021 1841.8021 M-XYL-01 2233.2916 2233.2916 2220.3048 1110.1524 1110.1524 O-XYL-01 3591.7372 3591.7372 3573.9491 1786.9746 1786.9746 P-XYL-01 1457.0203 1457.0203 1448.2205 724.1102 724.1102 ETHYL-03 1211.4396 1211.4396 1203.1758 601.5879 601.5879 N-PRO-03 1068.5677 1068.5677 1065.7469 532.8734 532.8734 HYDRO-01 6.5805+04 6.5805+04 166.4436 83.2218 83.2218 VLSTDMX BBL/DAY 1.1248+05 1.1248+05 3.5171+04 1.7585+04 1.7585+04 APISTD 88.3839 88.3839 45.5981 45.5981 45.5981 SGSTD 0.6435 0.6435 0.7990 0.7990 0.7990 WAT 8.5443 8.5443 11.0191 11.0191 11.0191 FLPT-API K MISSING MISSING 255.3092 255.3092 255.3092 RVP-API N/SQM 1.9506+09 1.9506+09 1.3868+06 1.3868+06 1.3868+06

172

7.8.3. S17 S18 S19 S2 S20

STREAM ID S17 S18 S19 S2 S20 FROM : F-2 G-2 G-3 B1 E-5 TO : G-2 E-5 E-5 R1 E-6 SUBSTREAM: MIXED PHASE: VAPOR VAPOR LIQUID VAPOR MIXED COMPONENTS: KMOL/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 9.0370-05 9.0370-05 1.3249-03 3.9473-02 1.4153-03 ETHAN-01 7.7908-06 7.7908-06 3.3681-03 4.3215-02 3.3759-03 PROPA-01 1.0106-06 1.0106-06 4.4991-03 3.7789-02 4.5001-03 N-BUT-01 9.9747-08 9.9747-08 5.1866-03 1.9830-02 5.1867-03 ISOBU-01 1.1934-07 1.1934-07 2.9685-03 1.3657-02 2.9686-03 N-PEN-01 5.7866-09 5.7866-09 2.4964-03 6.5477-03 2.4964-03 2-MET-01 1.8721-08 1.8721-08 5.1615-03 1.4218-02 5.1615-03 N-HEX-01 1.8983-09 1.8983-09 7.7588-03 4.2840-02 7.7588-03 2-MET-02 3.5162-09 3.5162-09 7.8197-03 4.3402-02 7.8197-03 N-HEP-01 2.8760-10 2.8760-10 1.0363-02 5.4626-02 1.0363-02 2-MET-03 6.5433-10 6.5433-10 1.1160-02 5.8742-02 1.1160-02 N-OCT-01 1.6769-12 1.6769-12 5.4490-04 4.4711-02 5.4490-04 2:2:4-01 4.8452-11 4.8452-11 9.3227-04 6.3232-02 9.3227-04 N-NON-01 2.2252-12 2.2252-12 5.1894-03 2.9184-02 5.1894-03 2:2:5-01 8.2879-11 8.2879-11 8.5780-03 4.5647-02 8.5780-03 CYCLO-01 1.7082-13 1.7082-13 1.4658-06 1.4405-02 1.4658-06 METHY-01 1.7190-13 1.7190-13 5.2490-06 1.5714-02 5.2490-06 ETHYL-01 2.7142-14 2.7142-14 4.6181-06 2.1514-02 4.6181-06 N-PRO-01 1.3572-15 1.3572-15 1.0517-06 3.3674-03 1.0517-06 CYCLO-02 6.3328-11 6.3328-11 8.0398-05 1.8708-04 8.0398-05 METHY-02 4.9975-10 4.9975-10 2.6015-03 5.6123-03 2.6015-03 ETHYL-02 1.2708-10 1.2708-10 5.9245-03 1.2160-02 5.9245-03 N-PRO-02 1.9428-11 1.9428-11 7.7808-03 1.5714-02 7.7808-03 N-BUT-02 3.6965-13 3.6965-13 1.1177-03 2.2449-03 1.1177-03 BENZE-01 1.0346-08 1.0346-08 8.3125-02 1.6089-02 8.3125-02 TOLUE-01 4.3272-10 4.3272-10 3.1998-02 2.0391-02 3.1998-02 M-XYL-01 1.7538-11 1.7538-11 1.6679-02 2.8061-03 1.6679-02 O-XYL-01 2.2682-11 2.2682-11 2.7342-02 2.9932-03 2.7342-02 P-XYL-01 1.2651-11 1.2651-11 1.0841-02 6.7347-03 1.0841-02 ETHYL-03 1.4438-11 1.4438-11 9.0692-03 3.9286-03 9.0692-03 N-PRO-03 1.7241-12 1.7241-12 7.0528-03 4.8640-03 7.0528-03 HYDRO-01 2.1414-03 2.1414-03 2.8593-03 1.1647 5.0008-03 COMPONENTS: STD CUM/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 4.8400-06 4.8400-06 7.0960-05 2.1141-03 7.5800-05 ETHAN-01 6.5997-07 6.5997-07 2.8532-04 3.6608-03 2.8598-04 PROPA-01 8.8065-08 8.8065-08 3.9207-04 3.2931-03 3.9216-04 N-BUT-01 9.9461-09 9.9461-09 5.1717-04 1.9773-03 5.1718-04 ISOBU-01 1.2354-08 1.2354-08 3.0731-04 1.4138-03 3.0733-04 N-PEN-01 6.6355-10 6.6355-10 2.8626-04 7.5082-04 2.8626-04 2-MET-01 2.1682-09 2.1682-09 5.9780-04 1.6467-03 5.9780-04 N-HEX-01 2.4705-10 2.4705-10 1.0097-03 5.5752-03 1.0097-03 2-MET-02 4.6184-10 4.6184-10 1.0271-03 5.7006-03 1.0271-03 N-HEP-01 4.1986-11 4.1986-11 1.5129-03 7.9748-03 1.5129-03 2-MET-03 9.6243-11 9.6243-11 1.6415-03 8.6402-03 1.6415-03

173

STREAM ID S17 S18 S19 S2 S20 N-OCT-01 2.7172-13 2.7172-13 8.8295-05 7.2449-03 8.8295-05 2:2:4-01 7.9705-12 7.9705-12 1.5336-04 1.0402-02 1.5336-04 N-NON-01 3.9646-13 3.9646-13 9.2459-04 5.1997-03 9.2459-04 2:2:5-01 1.4839-11 1.4839-11 1.5359-03 8.1728-03 1.5359-03 CYCLO-01 1.8395-14 1.8395-14 1.5785-07 1.5512-03 1.5785-07 METHY-01 2.1861-14 2.1861-14 6.6753-07 1.9984-03 6.6753-07 ETHYL-01 3.8823-15 3.8823-15 6.6055-07 3.0772-03 6.6055-07 N-PRO-01 2.1531-16 2.1531-16 1.6683-07 5.3419-04 1.6683-07 CYCLO-02 5.9335-12 5.9335-12 7.5329-06 1.7528-05 7.5329-06 METHY-02 5.5950-11 5.5950-11 2.9125-04 6.2832-04 2.9125-04 ETHYL-02 1.6222-11 1.6222-11 7.5626-04 1.5522-03 7.5626-04 N-PRO-02 2.7993-12 2.7993-12 1.1211-03 2.2642-03 1.1211-03 N-BUT-02 5.9725-14 5.9725-14 1.8059-04 3.6271-04 1.8059-04 BENZE-01 9.1573-10 9.1573-10 7.3573-03 1.4240-03 7.3573-03 TOLUE-01 4.5832-11 4.5832-11 3.3892-03 2.1598-03 3.3892-03 M-XYL-01 2.1480-12 2.1480-12 2.0428-03 3.4369-04 2.0428-03 O-XYL-01 2.7278-12 2.7278-12 3.2883-03 3.5998-04 3.2883-03 P-XYL-01 1.5550-12 1.5550-12 1.3325-03 8.2777-04 1.3325-03 ETHYL-03 1.7623-12 1.7623-12 1.1070-03 4.7953-04 1.1070-03 N-PRO-03 2.3970-13 2.3970-13 9.8056-04 6.7624-04 9.8056-04 HYDRO-01 1.1469-04 1.1469-04 1.5314-04 6.2381-02 2.6783-04 TOTAL CUM/SEC 1.2031-04 1.2031-04 3.2359-02 0.1544 3.2480-02 COMPONENTS: STD VOL FRAC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 4.0231-02 4.0231-02 2.1929-03 1.3692-02 2.3338-03 ETHAN-01 5.4858-03 5.4858-03 8.8172-03 2.3709-02 8.8049-03 PROPA-01 7.3201-04 7.3201-04 1.2116-02 2.1328-02 1.2074-02 N-BUT-01 8.2673-05 8.2673-05 1.5982-02 1.2806-02 1.5923-02 ISOBU-01 1.0269-04 1.0269-04 9.4970-03 9.1564-03 9.4622-03 N-PEN-01 5.5156-06 5.5156-06 8.8464-03 4.8627-03 8.8137-03 2-MET-01 1.8023-05 1.8023-05 1.8474-02 1.0665-02 1.8406-02 N-HEX-01 2.0535-06 2.0535-06 3.1203-02 3.6108-02 3.1088-02 2-MET-02 3.8389-06 3.8389-06 3.1740-02 3.6920-02 3.1622-02 N-HEP-01 3.4900-07 3.4900-07 4.6754-02 5.1649-02 4.6580-02 2-MET-03 7.9999-07 7.9999-07 5.0727-02 5.5958-02 5.0539-02 N-OCT-01 2.2585-09 2.2585-09 2.7286-03 4.6922-02 2.7185-03 2:2:4-01 6.6252-08 6.6252-08 4.7394-03 6.7368-02 4.7218-03 N-NON-01 3.2954-09 3.2954-09 2.8573-02 3.3676-02 2.8467-02 2:2:5-01 1.2335-07 1.2335-07 4.7463-02 5.2931-02 4.7287-02 CYCLO-01 1.5290-10 1.5290-10 4.8780-06 1.0046-02 4.8599-06 METHY-01 1.8171-10 1.8171-10 2.0629-05 1.2943-02 2.0552-05 ETHYL-01 3.2270-11 3.2270-11 2.0413-05 1.9930-02 2.0337-05 N-PRO-01 1.7897-12 1.7897-12 5.1557-06 3.4597-03 5.1366-06 CYCLO-02 4.9320-08 4.9320-08 2.3279-04 1.1352-04 2.3193-04 METHY-02 4.6507-07 4.6507-07 9.0005-03 4.0693-03 8.9671-03 ETHYL-02 1.3484-07 1.3484-07 2.3371-02 1.0053-02 2.3284-02 N-PRO-02 2.3268-08 2.3268-08 3.4645-02 1.4664-02 3.4517-02 N-BUT-02 4.9644-10 4.9644-10 5.5807-03 2.3491-03 5.5600-03 BENZE-01 7.6117-06 7.6117-06 0.2274 9.2224-03 0.2265 TOLUE-01 3.8097-07 3.8097-07 0.1047 1.3988-02 0.1043 M-XYL-01 1.7855-08 1.7855-08 6.3130-02 2.2259-03 6.2896-02 O-XYL-01 2.2674-08 2.2674-08 0.1016 2.3314-03 0.1012

174

STREAM ID S17 S18 S19 S2 S20 P-XYL-01 1.2925-08 1.2925-08 4.1177-02 5.3611-03 4.1024-02 ETHYL-03 1.4648-08 1.4648-08 3.4210-02 3.1057-03 3.4083-02 N-PRO-03 1.9924-09 1.9924-09 3.0302-02 4.3797-03 3.0190-02 HYDRO-01 0.9533 0.9533 4.7325-03 0.4040 8.2461-03 TOTAL CUM/SEC 1.2031-04 1.2031-04 3.2359-02 0.1544 3.2480-02 TOTAL FLOW: KMOL/SEC 2.2409-03 2.2409-03 0.2838 1.8706 0.2861 KG/SEC 6.0615-03 6.0615-03 25.6848 64.8992 25.6908 CUM/SEC 3.7462-03 1.8414-03 3.2623-02 20.8989 3.3631-02 STATE VARIABLES: TEMP K 200.0000 311.2384 313.4240 798.0000 323.2865 PRES N/SQM 1.0000+06 3.2000+06 3.2000+06 5.9500+05 3.2000+06 VFRAC 1.0000 1.0000 0.0 1.0000 2.1721-03 LFRAC 0.0 0.0 1.0000 0.0 0.9978 SFRAC 0.0 0.0 0.0 0.0 0.0 ENTHALPY: J/KMOL -6.1850+06 -2.9525+06 -5.3956+07 -5.0352+06 -5.1857+07 J/KG -2.2865+06 -1.0915+06 -5.9625+05 -1.4513+05 -5.7745+05 WATT -1.3860+04 -6616.1603 -1.5315+07 -9.4186+06 -1.4835+07 ENTROPY: J/KMOL-K -3.2952+04 -2.9890+04 -4.2433+05 -1.0969+05 -4.1590+05 J/KG-K -1.2182+04 -1.1050+04 -4689.1616 -3161.4383 -4631.1214 DENSITY: KMOL/CUM 0.5982 1.2169 8.7005 8.9506-02 8.5063 KG/CUM 1.6180 3.2917 787.3291 3.1054 763.9066 AVG MW 2.7050 2.7050 90.4921 34.6948 89.8044 MIXED SUBSTREAM PROPERTIES: *** ALL PHASES *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 2.6302 2.6302 38.5624 1148.8791 41.1927 ETHAN-01 0.3587 0.3587 155.0538 1989.4088 155.4125 PROPA-01 4.7858-02 4.7858-02 213.0649 1789.6126 213.1127 N-BUT-01 5.4051-03 5.4051-03 281.0529 1074.5526 281.0583 ISOBU-01 6.7139-03 6.7139-03 167.0069 768.3114 167.0136 N-PEN-01 3.6060-04 3.6060-04 155.5668 408.0252 155.5672 2-MET-01 1.1783-03 1.1783-03 324.8694 894.8831 324.8706 N-HEX-01 1.3425-04 1.3425-04 548.7221 3029.7638 548.7222 2-MET-02 2.5098-04 2.5098-04 558.1567 3097.9471 558.1570 N-HEP-01 2.2817-05 2.2817-05 822.1768 4333.8031 822.1768 2-MET-03 5.2302-05 5.2302-05 892.0525 4695.4054 892.0526 N-OCT-01 1.4766-07 1.4766-07 47.9832 3937.1679 47.9832 2:2:4-01 4.3315-06 4.3315-06 83.3438 5652.8175 83.3438 N-NON-01 2.1545-07 2.1545-07 502.4598 2825.7149 502.4598 2:2:5-01 8.0642-06 8.0642-06 834.6429 4441.4381 834.6429 CYCLO-01 9.9965-09 9.9965-09 8.5781-02 842.9914 8.5781-02 METHY-01 1.1880-08 1.1880-08 0.3628 1086.0339 0.3628 ETHYL-01 2.1098-09 2.1098-09 0.3590 1672.2929 0.3590 N-PRO-01 1.1701-10 1.1701-10 9.0664-02 290.2994 9.0664-02 CYCLO-02 3.2245-06 3.2245-06 4.0937 9.5255 4.0937

175

STREAM ID S17 S18 S19 S2 S20 METHY-02 3.0405-05 3.0405-05 158.2761 341.4553 158.2761 ETHYL-02 8.8156-06 8.8156-06 410.9801 843.5354 410.9801 N-PRO-02 1.5213-06 1.5213-06 609.2450 1230.4592 609.2450 N-BUT-02 3.2457-08 3.2457-08 98.1382 197.1136 98.1382 BENZE-01 4.9764-04 4.9764-04 3998.2369 773.8478 3998.2374 TOLUE-01 2.4907-05 2.4907-05 1841.8021 1173.7225 1841.8021 M-XYL-01 1.1673-06 1.1673-06 1110.1524 186.7764 1110.1524 O-XYL-01 1.4824-06 1.4824-06 1786.9746 195.6252 1786.9746 P-XYL-01 8.4502-07 8.4502-07 724.1102 449.8445 724.1102 ETHYL-03 9.5770-07 9.5770-07 601.5879 260.5967 601.5879 N-PRO-03 1.3026-07 1.3026-07 532.8734 367.4973 532.8734 HYDRO-01 62.3274 62.3274 83.2218 3.3900+04 145.5492 *** VAPOR PHASE *** VOLFLMX CUFT/HR 476.2606 234.1057 MISSING 2.6569+06 67.3436 VVSTDMX CUFT/HR 6385.3685 6385.3685 MISSING 5.3302+06 1770.6666 CPMX BTU/LB-R 2.5184 2.6012 MISSING 0.8998 1.5680 RHOMX LB/CUFT 0.1010 0.2055 MISSING 0.1939 0.3581 MWMX 2.7050 2.7050 MISSING 34.6948 4.8904 *** LIQUID PHASE *** VOLFLMX BBL/HR MISSING MISSING 738.6848 MISSING 749.5193 BBL/DAY MISSING MISSING 1.7728+04 MISSING 1.7988+04 CPMX BTU/LB-R MISSING MISSING 0.4449 MISSING 0.4564 MUMX CP MISSING MISSING 0.3576 MISSING 0.3026 VLSTDMX BBL/HR MISSING MISSING 732.7211 MISSING 734.6650 BBL/DAY MISSING MISSING 1.7585+04 MISSING 1.7632+04 *** DRY TOTAL *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 2.6302 2.6302 38.5624 1148.8791 41.1927 ETHAN-01 0.3587 0.3587 155.0538 1989.4088 155.4125 PROPA-01 4.7858-02 4.7858-02 213.0649 1789.6126 213.1127 N-BUT-01 5.4051-03 5.4051-03 281.0529 1074.5526 281.0583 ISOBU-01 6.7139-03 6.7139-03 167.0069 768.3114 167.0136 N-PEN-01 3.6060-04 3.6060-04 155.5668 408.0252 155.5672 2-MET-01 1.1783-03 1.1783-03 324.8694 894.8831 324.8706 N-HEX-01 1.3425-04 1.3425-04 548.7221 3029.7638 548.7222 2-MET-02 2.5098-04 2.5098-04 558.1567 3097.9471 558.1570 N-HEP-01 2.2817-05 2.2817-05 822.1768 4333.8031 822.1768 2-MET-03 5.2302-05 5.2302-05 892.0525 4695.4054 892.0526 N-OCT-01 1.4766-07 1.4766-07 47.9832 3937.1679 47.9832 2:2:4-01 4.3315-06 4.3315-06 83.3438 5652.8175 83.3438 N-NON-01 2.1545-07 2.1545-07 502.4598 2825.7149 502.4598 2:2:5-01 8.0642-06 8.0642-06 834.6429 4441.4381 834.6429 CYCLO-01 9.9965-09 9.9965-09 8.5781-02 842.9914 8.5781-02 METHY-01 1.1880-08 1.1880-08 0.3628 1086.0339 0.3628 ETHYL-01 2.1098-09 2.1098-09 0.3590 1672.2929 0.3590 N-PRO-01 1.1701-10 1.1701-10 9.0664-02 290.2994 9.0664-02 CYCLO-02 3.2245-06 3.2245-06 4.0937 9.5255 4.0937 METHY-02 3.0405-05 3.0405-05 158.2761 341.4553 158.2761

176

STREAM ID S17 S18 S19 S2 S20 ETHYL-02 8.8156-06 8.8156-06 410.9801 843.5354 410.9801 N-PRO-02 1.5213-06 1.5213-06 609.2450 1230.4592 609.2450 N-BUT-02 3.2457-08 3.2457-08 98.1382 197.1136 98.1382 BENZE-01 4.9764-04 4.9764-04 3998.2369 773.8478 3998.2374 TOLUE-01 2.4907-05 2.4907-05 1841.8021 1173.7225 1841.8021 M-XYL-01 1.1673-06 1.1673-06 1110.1524 186.7764 1110.1524 O-XYL-01 1.4824-06 1.4824-06 1786.9746 195.6252 1786.9746 P-XYL-01 8.4502-07 8.4502-07 724.1102 449.8445 724.1102 ETHYL-03 9.5770-07 9.5770-07 601.5879 260.5967 601.5879 N-PRO-03 1.3026-07 1.3026-07 532.8734 367.4973 532.8734 HYDRO-01 62.3274 62.3274 83.2218 3.3900+04 145.5492 VLSTDMX BBL/DAY 65.3789 65.3789 1.7585+04 8.3909+04 1.7651+04 APISTD 335.0889 335.0889 45.5981 85.6192 45.6664 SGSTD 0.3032 0.3032 0.7990 0.6517 0.7987 WAT 11.5387 11.5387 11.0191 11.2327 11.0189 FLPT-API K MISSING MISSING 255.3092 MISSING 254.3637 RVP-API N/SQM 1.6698+09 1.6698+09 1.3868+06 8.0249+07 2.3168+06

177

7.8.4 S21 S22 S23 S24 S25

STREAM ID S21 S22 S23 S24 S25 FROM : E-6 E-7 E-8 E-9 E-10 TO : E-7 E-8 E-9 E-10 F-3 MAX CONV. ERROR: 0.0 0.0 6.5834-06 0.0 8.6286-10 SUBSTREAM: MIXED PHASE: MIXED MIXED MIXED MIXED MIXED COMPONENTS: KMOL/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 1.4153-03 1.4153-03 1.4153-03 1.4153-03 1.4153-03 ETHAN-01 3.3759-03 3.3759-03 3.3759-03 3.3759-03 3.3759-03 PROPA-01 4.5001-03 4.5001-03 4.5001-03 4.5001-03 4.5001-03 N-BUT-01 5.1867-03 5.1867-03 5.1867-03 5.1867-03 5.1867-03 ISOBU-01 2.9686-03 2.9686-03 2.9686-03 2.9686-03 2.9686-03 N-PEN-01 2.4964-03 2.4964-03 2.4964-03 2.4964-03 2.4964-03 2-MET-01 5.1615-03 5.1615-03 5.1615-03 5.1615-03 5.1615-03 N-HEX-01 7.7588-03 7.7588-03 7.7588-03 7.7588-03 7.7588-03 2-MET-02 7.8197-03 7.8197-03 7.8197-03 7.8197-03 7.8197-03 N-HEP-01 1.0363-02 1.0363-02 1.0363-02 1.0363-02 1.0363-02 2-MET-03 1.1160-02 1.1160-02 1.1160-02 1.1160-02 1.1160-02 N-OCT-01 5.4490-04 5.4490-04 5.4490-04 5.4490-04 5.4490-04 2:2:4-01 9.3227-04 9.3227-04 9.3227-04 9.3227-04 9.3227-04 N-NON-01 5.1894-03 5.1894-03 5.1894-03 5.1894-03 5.1894-03 2:2:5-01 8.5780-03 8.5780-03 8.5780-03 8.5780-03 8.5780-03 CYCLO-01 1.4658-06 1.4658-06 1.4658-06 1.4658-06 1.4658-06 METHY-01 5.2490-06 5.2490-06 5.2490-06 5.2490-06 5.2490-06 ETHYL-01 4.6181-06 4.6181-06 4.6181-06 4.6181-06 4.6181-06 N-PRO-01 1.0517-06 1.0517-06 1.0517-06 1.0517-06 1.0517-06 CYCLO-02 8.0398-05 8.0398-05 8.0398-05 8.0398-05 8.0398-05 METHY-02 2.6015-03 2.6015-03 2.6015-03 2.6015-03 2.6015-03 ETHYL-02 5.9245-03 5.9245-03 5.9245-03 5.9245-03 5.9245-03 N-PRO-02 7.7808-03 7.7808-03 7.7808-03 7.7808-03 7.7808-03 N-BUT-02 1.1177-03 1.1177-03 1.1177-03 1.1177-03 1.1177-03 BENZE-01 8.3125-02 8.3125-02 8.3125-02 8.3125-02 8.3125-02 TOLUE-01 3.1998-02 3.1998-02 3.1998-02 3.1998-02 3.1998-02 M-XYL-01 1.6679-02 1.6679-02 1.6679-02 1.6679-02 1.6679-02 O-XYL-01 2.7342-02 2.7342-02 2.7342-02 2.7342-02 2.7342-02 P-XYL-01 1.0841-02 1.0841-02 1.0841-02 1.0841-02 1.0841-02 ETHYL-03 9.0692-03 9.0692-03 9.0692-03 9.0692-03 9.0692-03 N-PRO-03 7.0528-03 7.0528-03 7.0528-03 7.0528-03 7.0528-03 HYDRO-01 5.0008-03 5.0008-03 5.0008-03 5.0008-03 5.0008-03 COMPONENTS: STD CUM/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 7.5800-05 7.5800-05 7.5800-05 7.5800-05 7.5800-05 ETHAN-01 2.8598-04 2.8598-04 2.8598-04 2.8598-04 2.8598-04 PROPA-01 3.9216-04 3.9216-04 3.9216-04 3.9216-04 3.9216-04 N-BUT-01 5.1718-04 5.1718-04 5.1718-04 5.1718-04 5.1718-04 ISOBU-01 3.0733-04 3.0733-04 3.0733-04 3.0733-04 3.0733-04 N-PEN-01 2.8626-04 2.8626-04 2.8626-04 2.8626-04 2.8626-04 2-MET-01 5.9780-04 5.9780-04 5.9780-04 5.9780-04 5.9780-04 N-HEX-01 1.0097-03 1.0097-03 1.0097-03 1.0097-03 1.0097-03 2-MET-02 1.0271-03 1.0271-03 1.0271-03 1.0271-03 1.0271-03

178

STREAM ID S21 S22 S23 S24 S25 N-HEP-01 1.5129-03 1.5129-03 1.5129-03 1.5129-03 1.5129-03 2-MET-03 1.6415-03 1.6415-03 1.6415-03 1.6415-03 1.6415-03 N-OCT-01 8.8295-05 8.8295-05 8.8295-05 8.8295-05 8.8295-05 2:2:4-01 1.5336-04 1.5336-04 1.5336-04 1.5336-04 1.5336-04 N-NON-01 9.2459-04 9.2459-04 9.2459-04 9.2459-04 9.2459-04 2:2:5-01 1.5359-03 1.5359-03 1.5359-03 1.5359-03 1.5359-03 CYCLO-01 1.5785-07 1.5785-07 1.5785-07 1.5785-07 1.5785-07 METHY-01 6.6753-07 6.6753-07 6.6753-07 6.6753-07 6.6753-07 ETHYL-01 6.6055-07 6.6055-07 6.6055-07 6.6055-07 6.6055-07 N-PRO-01 1.6683-07 1.6683-07 1.6683-07 1.6683-07 1.6683-07 CYCLO-02 7.5329-06 7.5329-06 7.5329-06 7.5329-06 7.5329-06 METHY-02 2.9125-04 2.9125-04 2.9125-04 2.9125-04 2.9125-04 ETHYL-02 7.5626-04 7.5626-04 7.5626-04 7.5626-04 7.5626-04 N-PRO-02 1.1211-03 1.1211-03 1.1211-03 1.1211-03 1.1211-03 N-BUT-02 1.8059-04 1.8059-04 1.8059-04 1.8059-04 1.8059-04 BENZE-01 7.3573-03 7.3573-03 7.3573-03 7.3573-03 7.3573-03 TOLUE-01 3.3892-03 3.3892-03 3.3892-03 3.3892-03 3.3892-03 M-XYL-01 2.0428-03 2.0428-03 2.0428-03 2.0428-03 2.0428-03 O-XYL-01 3.2883-03 3.2883-03 3.2883-03 3.2883-03 3.2883-03 P-XYL-01 1.3325-03 1.3325-03 1.3325-03 1.3325-03 1.3325-03 ETHYL-03 1.1070-03 1.1070-03 1.1070-03 1.1070-03 1.1070-03 N-PRO-03 9.8056-04 9.8056-04 9.8056-04 9.8056-04 9.8056-04 HYDRO-01 2.6783-04 2.6783-04 2.6783-04 2.6783-04 2.6783-04 TOTAL CUM/SEC 3.2480-02 3.2480-02 3.2480-02 3.2480-02 3.2480-02 COMPONENTS: STD VOL FRAC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 2.3338-03 2.3338-03 2.3338-03 2.3338-03 2.3338-03 ETHAN-01 8.8049-03 8.8049-03 8.8049-03 8.8049-03 8.8049-03 PROPA-01 1.2074-02 1.2074-02 1.2074-02 1.2074-02 1.2074-02 N-BUT-01 1.5923-02 1.5923-02 1.5923-02 1.5923-02 1.5923-02 ISOBU-01 9.4622-03 9.4622-03 9.4622-03 9.4622-03 9.4622-03 N-PEN-01 8.8137-03 8.8137-03 8.8137-03 8.8137-03 8.8137-03 2-MET-01 1.8406-02 1.8406-02 1.8406-02 1.8406-02 1.8406-02 N-HEX-01 3.1088-02 3.1088-02 3.1088-02 3.1088-02 3.1088-02 2-MET-02 3.1622-02 3.1622-02 3.1622-02 3.1622-02 3.1622-02 N-HEP-01 4.6580-02 4.6580-02 4.6580-02 4.6580-02 4.6580-02 2-MET-03 5.0539-02 5.0539-02 5.0539-02 5.0539-02 5.0539-02 N-OCT-01 2.7185-03 2.7185-03 2.7185-03 2.7185-03 2.7185-03 2:2:4-01 4.7218-03 4.7218-03 4.7218-03 4.7218-03 4.7218-03 N-NON-01 2.8467-02 2.8467-02 2.8467-02 2.8467-02 2.8467-02 2:2:5-01 4.7287-02 4.7287-02 4.7287-02 4.7287-02 4.7287-02 CYCLO-01 4.8599-06 4.8599-06 4.8599-06 4.8599-06 4.8599-06 METHY-01 2.0552-05 2.0552-05 2.0552-05 2.0552-05 2.0552-05 ETHYL-01 2.0337-05 2.0337-05 2.0337-05 2.0337-05 2.0337-05 N-PRO-01 5.1366-06 5.1366-06 5.1366-06 5.1366-06 5.1366-06 CYCLO-02 2.3193-04 2.3193-04 2.3193-04 2.3193-04 2.3193-04 METHY-02 8.9671-03 8.9671-03 8.9671-03 8.9671-03 8.9671-03 ETHYL-02 2.3284-02 2.3284-02 2.3284-02 2.3284-02 2.3284-02 N-PRO-02 3.4517-02 3.4517-02 3.4517-02 3.4517-02 3.4517-02 N-BUT-02 5.5600-03 5.5600-03 5.5600-03 5.5600-03 5.5600-03 BENZE-01 0.2265 0.2265 0.2265 0.2265 0.2265 TOLUE-01 0.1043 0.1043 0.1043 0.1043 0.1043

179

STREAM ID S21 S22 S23 S24 S25 M-XYL-01 6.2896-02 6.2896-02 6.2896-02 6.2896-02 6.2896-02 O-XYL-01 0.1012 0.1012 0.1012 0.1012 0.1012 P-XYL-01 4.1024-02 4.1024-02 4.1024-02 4.1024-02 4.1024-02 ETHYL-03 3.4083-02 3.4083-02 3.4083-02 3.4083-02 3.4083-02 N-PRO-03 3.0190-02 3.0190-02 3.0190-02 3.0190-02 3.0190-02 HYDRO-01 8.2461-03 8.2461-03 8.2461-03 8.2461-03 8.2461-03 TOTAL CUM/SEC 3.2480-02 3.2480-02 3.2480-02 3.2480-02 3.2480-02 TOTAL FLOW: KMOL/SEC 0.2861 0.2861 0.2861 0.2861 0.2861 KG/SEC 25.6908 25.6908 25.6908 25.6908 25.6908 CUM/SEC 2.7090-02 2.7104-02 2.7105-02 3.3108-02 3.3108-02 STATE VARIABLES: TEMP K 10.0000 12.1433 12.3014 303.0000 303.0037 PRES N/SQM 3.2000+06 3.2000+06 3.2000+06 3.2000+06 3.2000+06 VFRAC 1.7494-02 1.7507-02 1.7508-02 3.5939-03 3.5936-03 LFRAC 0.9825 0.9825 0.9825 0.9964 0.9964 SFRAC 0.0 0.0 0.0 0.0 0.0 ENTHALPY: J/KMOL -9.8222+07 -9.7693+07 -9.7656+07 -5.5261+07 -5.5261+07 J/KG -1.0937+06 -1.0878+06 -1.0874+06 -6.1535+05 -6.1535+05 WATT -2.8099+07 -2.7948+07 -2.7937+07 -1.5809+07 -1.5809+07 ENTROPY: J/KMOL-K 7.0656+06 3.3528+06 3.1308+06 -4.2677+05 -4.2676+05 J/KG-K 7.8678+04 3.7334+04 3.4862+04 -4752.1762 -4752.1541 DENSITY: KMOL/CUM 10.5601 10.5547 10.5542 8.6406 8.6406 KG/CUM 948.3404 947.8564 947.8104 775.9623 775.9603 AVG MW 89.8044 89.8044 89.8044 89.8044 89.8044 MIXED SUBSTREAM PROPERTIES: *** ALL PHASES *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 41.1927 41.1927 41.1927 41.1927 41.1927 ETHAN-01 155.4125 155.4125 155.4125 155.4125 155.4125 PROPA-01 213.1127 213.1127 213.1127 213.1127 213.1127 N-BUT-01 281.0583 281.0583 281.0583 281.0583 281.0583 ISOBU-01 167.0136 167.0136 167.0136 167.0136 167.0136 N-PEN-01 155.5672 155.5672 155.5672 155.5672 155.5672 2-MET-01 324.8706 324.8706 324.8706 324.8706 324.8706 N-HEX-01 548.7222 548.7222 548.7222 548.7222 548.7222 2-MET-02 558.1570 558.1570 558.1570 558.1570 558.1570 N-HEP-01 822.1768 822.1768 822.1768 822.1768 822.1768 2-MET-03 892.0526 892.0526 892.0526 892.0526 892.0526 N-OCT-01 47.9832 47.9832 47.9832 47.9832 47.9832 2:2:4-01 83.3438 83.3438 83.3438 83.3438 83.3438 N-NON-01 502.4598 502.4598 502.4598 502.4598 502.4598 2:2:5-01 834.6429 834.6429 834.6429 834.6429 834.6429 CYCLO-01 8.5781-02 8.5781-02 8.5781-02 8.5781-02 8.5781-02 METHY-01 0.3628 0.3628 0.3628 0.3628 0.3628 ETHYL-01 0.3590 0.3590 0.3590 0.3590 0.3590

180

STREAM ID S21 S22 S23 S24 S25 N-PRO-01 9.0664-02 9.0664-02 9.0664-02 9.0664-02 9.0664-02 CYCLO-02 4.0937 4.0937 4.0937 4.0937 4.0937 METHY-02 158.2761 158.2761 158.2761 158.2761 158.2761 ETHYL-02 410.9801 410.9801 410.9801 410.9801 410.9801 N-PRO-02 609.2450 609.2450 609.2450 609.2450 609.2450 N-BUT-02 98.1382 98.1382 98.1382 98.1382 98.1382 BENZE-01 3998.2374 3998.2374 3998.2374 3998.2374 3998.2374 TOLUE-01 1841.8021 1841.8021 1841.8021 1841.8021 1841.8021 M-XYL-01 1110.1524 1110.1524 1110.1524 1110.1524 1110.1524 O-XYL-01 1786.9746 1786.9746 1786.9746 1786.9746 1786.9746 P-XYL-01 724.1102 724.1102 724.1102 724.1102 724.1102 ETHYL-03 601.5879 601.5879 601.5879 601.5879 601.5879 N-PRO-03 532.8734 532.8734 532.8734 532.8734 532.8734 HYDRO-01 145.5492 145.5492 145.5492 145.5492 145.5492 *** VAPOR PHASE *** VOLFLMX CUFT/HR 56.5820 56.3144 56.3326 104.5278 104.5212 VVSTDMX CUFT/HR 1.4261+04 1.4271+04 1.4272+04 2929.6400 2929.4190 CPMX BTU/LB-R 1.6776 1.6069 1.5996 1.8609 1.8608 RHOMX LB/CUFT 1.4426 1.5018 1.5076 0.3084 0.3084 MWMX 2.0551 2.1277 2.1364 3.9511 3.9513 *** LIQUID PHASE *** VOLFLMX BBL/HR 603.3364 603.6972 603.7238 731.0652 731.0684 BBL/DAY 1.4480+04 1.4489+04 1.4489+04 1.7546+04 1.7546+04 CPMX BTU/LB-R 0.6770 0.6336 0.6309 0.4344 0.4344 MUMX CP 6.4853+37 3.1529+35 1.5474+35 0.3836 0.3836 VLSTDMX BBL/HR 729.3725 729.3628 729.3616 734.1708 734.1708 BBL/DAY 1.7505+04 1.7505+04 1.7505+04 1.7620+04 1.7620+04 *** DRY TOTAL *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 41.1927 41.1927 41.1927 41.1927 41.1927 ETHAN-01 155.4125 155.4125 155.4125 155.4125 155.4125 PROPA-01 213.1127 213.1127 213.1127 213.1127 213.1127 N-BUT-01 281.0583 281.0583 281.0583 281.0583 281.0583 ISOBU-01 167.0136 167.0136 167.0136 167.0136 167.0136 N-PEN-01 155.5672 155.5672 155.5672 155.5672 155.5672 2-MET-01 324.8706 324.8706 324.8706 324.8706 324.8706 N-HEX-01 548.7222 548.7222 548.7222 548.7222 548.7222 2-MET-02 558.1570 558.1570 558.1570 558.1570 558.1570 N-HEP-01 822.1768 822.1768 822.1768 822.1768 822.1768 2-MET-03 892.0526 892.0526 892.0526 892.0526 892.0526 N-OCT-01 47.9832 47.9832 47.9832 47.9832 47.9832 2:2:4-01 83.3438 83.3438 83.3438 83.3438 83.3438 N-NON-01 502.4598 502.4598 502.4598 502.4598 502.4598 2:2:5-01 834.6429 834.6429 834.6429 834.6429 834.6429 CYCLO-01 8.5781-02 8.5781-02 8.5781-02 8.5781-02 8.5781-02 METHY-01 0.3628 0.3628 0.3628 0.3628 0.3628 ETHYL-01 0.3590 0.3590 0.3590 0.3590 0.3590 N-PRO-01 9.0664-02 9.0664-02 9.0664-02 9.0664-02 9.0664-02

181

STREAM ID S21 S22 S23 S24 S25 CYCLO-02 4.0937 4.0937 4.0937 4.0937 4.0937 METHY-02 158.2761 158.2761 158.2761 158.2761 158.2761 ETHYL-02 410.9801 410.9801 410.9801 410.9801 410.9801 N-PRO-02 609.2450 609.2450 609.2450 609.2450 609.2450 N-BUT-02 98.1382 98.1382 98.1382 98.1382 98.1382 BENZE-01 3998.2374 3998.2374 3998.2374 3998.2374 3998.2374 TOLUE-01 1841.8021 1841.8021 1841.8021 1841.8021 1841.8021 M-XYL-01 1110.1524 1110.1524 1110.1524 1110.1524 1110.1524 O-XYL-01 1786.9746 1786.9746 1786.9746 1786.9746 1786.9746 P-XYL-01 724.1102 724.1102 724.1102 724.1102 724.1102 ETHYL-03 601.5879 601.5879 601.5879 601.5879 601.5879 N-PRO-03 532.8734 532.8734 532.8734 532.8734 532.8734 HYDRO-01 145.5492 145.5492 145.5492 145.5492 145.5492 VLSTDMX BBL/DAY 1.7651+04 1.7651+04 1.7651+04 1.7651+04 1.7651+04 APISTD 45.6664 45.6664 45.6664 45.6664 45.6664 SGSTD 0.7987 0.7987 0.7987 0.7987 0.7987 WAT 11.0189 11.0189 11.0189 11.0189 11.0189 FLPT-API K 254.3637 254.3637 254.3637 254.3637 254.3637 RVP-API N/SQM 2.3168+06 2.3168+06 2.3168+06 2.3168+06 2.3168+06

182

7.8.5. S27 S28 S3 S30 S31

STREAM ID S27 S28 S3 S30 S31 FROM : F-3 E-10 R1 F-3 E-9 TO : E-10 E-8 B2 E-9 E-7 SUBSTREAM: MIXED PHASE: VAPOR MIXED VAPOR LIQUID MIXED COMPONENTS: KMOL/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 4.5996-05 4.5996-05 3.9473-02 1.3693-03 1.3693-03 ETHAN-01 1.9989-05 1.9989-05 4.3215-02 3.3559-03 3.3559-03 PROPA-01 8.1261-06 8.1261-06 3.7789-02 4.4919-03 4.4919-03 N-BUT-01 2.6862-06 2.6862-06 1.9830-02 5.1840-03 5.1840-03 ISOBU-01 2.1913-06 2.1913-06 1.3657-02 2.9664-03 2.9664-03 N-PEN-01 4.4357-07 4.4357-07 6.5477-03 2.4960-03 2.4960-03 2-MET-01 1.1106-06 1.1106-06 1.4218-02 5.1604-03 5.1604-03 N-HEX-01 4.4656-07 4.4656-07 4.2840-02 7.7584-03 7.7584-03 2-MET-02 5.9370-07 5.9370-07 4.3402-02 7.8191-03 7.8191-03 N-HEP-01 1.9974-07 1.9974-07 5.4626-02 1.0363-02 1.0363-02 2-MET-03 3.0553-07 3.0553-07 5.8742-02 1.1160-02 1.1160-02 N-OCT-01 3.5812-09 3.5812-09 4.4711-02 5.4490-04 5.4490-04 2:2:4-01 2.0893-08 2.0893-08 6.3232-02 9.3225-04 9.3225-04 N-NON-01 1.2689-08 1.2689-08 2.9184-02 5.1894-03 5.1894-03 2:2:5-01 8.1055-08 8.1055-08 4.5647-02 8.5779-03 8.5779-03 CYCLO-01 4.7996-11 4.7996-11 3.8461-03 1.4658-06 1.4658-06 METHY-01 8.6631-11 8.6631-11 3.6574-03 5.2489-06 5.2489-06 ETHYL-01 2.7784-11 2.7784-11 1.2073-04 4.6181-06 4.6181-06 N-PRO-01 2.6722-12 2.6722-12 8.0160-04 1.0517-06 1.0517-06 CYCLO-02 7.4930-09 7.4930-09 1.8708-04 8.0390-05 8.0390-05 METHY-02 1.1605-07 1.1605-07 5.6123-03 2.6014-03 2.6014-03 ETHYL-02 8.5608-08 8.5608-08 1.2160-02 5.9244-03 5.9244-03 N-PRO-02 3.9036-08 3.9036-08 1.5714-02 7.7807-03 7.7807-03 N-BUT-02 2.0259-09 2.0259-09 2.2449-03 1.1177-03 1.1177-03 BENZE-01 2.9844-06 2.9844-06 2.6647-02 8.3122-02 8.3122-02 TOLUE-01 3.7532-07 3.7532-07 3.2448-02 3.1998-02 3.1998-02 M-XYL-01 5.6233-08 5.6233-08 7.9495-03 1.6679-02 1.6679-02 O-XYL-01 7.8433-08 7.8433-08 8.4989-03 2.7342-02 2.7342-02 P-XYL-01 3.7971-08 3.7971-08 1.2100-02 1.0841-02 1.0841-02 ETHYL-03 3.5885-08 3.5885-08 9.3077-03 9.0691-03 9.0691-03 N-PRO-03 1.0797-08 1.0797-08 7.4297-03 7.0528-03 7.0528-03 HYDRO-01 9.0224-04 9.0224-04 1.3045 4.0985-03 4.0985-03 COMPONENTS: STD CUM/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 2.4634-06 2.4634-06 2.1141-03 7.3336-05 7.3336-05 ETHAN-01 1.6933-06 1.6933-06 3.6608-03 2.8429-04 2.8429-04 PROPA-01 7.0814-07 7.0814-07 3.2931-03 3.9145-04 3.9145-04 N-BUT-01 2.6785-07 2.6785-07 1.9773-03 5.1692-04 5.1692-04 ISOBU-01 2.2685-07 2.2685-07 1.4138-03 3.0710-04 3.0710-04 N-PEN-01 5.0864-08 5.0864-08 7.5082-04 2.8621-04 2.8621-04 2-MET-01 1.2863-07 1.2863-07 1.6467-03 5.9768-04 5.9768-04 N-HEX-01 5.8114-08 5.8114-08 5.5752-03 1.0097-03 1.0097-03 2-MET-02 7.7980-08 7.7980-08 5.7006-03 1.0270-03 1.0270-03 N-HEP-01 2.9160-08 2.9160-08 7.9748-03 1.5129-03 1.5129-03 2-MET-03 4.4939-08 4.4939-08 8.6402-03 1.6414-03 1.6414-03

183

STREAM ID S27 S28 S3 S30 S31 N-OCT-01 5.8029-10 5.8029-10 7.2449-03 8.8295-05 8.8295-05 2:2:4-01 3.4370-09 3.4370-09 1.0402-02 1.5336-04 1.5336-04 N-NON-01 2.2608-09 2.2608-09 5.1997-03 9.2459-04 9.2459-04 2:2:5-01 1.4513-08 1.4513-08 8.1728-03 1.5358-03 1.5358-03 CYCLO-01 5.1685-12 5.1685-12 4.1417-04 1.5784-07 1.5784-07 METHY-01 1.1017-11 1.1017-11 4.6513-04 6.6752-07 6.6752-07 ETHYL-01 3.9742-12 3.9742-12 1.7269-05 6.6055-07 6.6055-07 N-PRO-01 4.2391-13 4.2391-13 1.2716-04 1.6683-07 1.6683-07 CYCLO-02 7.0206-10 7.0206-10 1.7528-05 7.5322-06 7.5322-06 METHY-02 1.2993-08 1.2993-08 6.2832-04 2.9124-04 2.9124-04 ETHYL-02 1.0928-08 1.0928-08 1.5522-03 7.5625-04 7.5625-04 N-PRO-02 5.6245-09 5.6245-09 2.2642-03 1.1211-03 1.1211-03 N-BUT-02 3.2733-10 3.2733-10 3.6271-04 1.8059-04 1.8059-04 BENZE-01 2.6414-07 2.6414-07 2.3585-03 7.3570-03 7.3570-03 TOLUE-01 3.9753-08 3.9753-08 3.4368-03 3.3891-03 3.3891-03 M-XYL-01 6.8874-09 6.8874-09 9.7365-04 2.0428-03 2.0428-03 O-XYL-01 9.4326-09 9.4326-09 1.0221-03 3.2883-03 3.2883-03 P-XYL-01 4.6670-09 4.6670-09 1.4872-03 1.3325-03 1.3325-03 ETHYL-03 4.3802-09 4.3802-09 1.1361-03 1.1070-03 1.1070-03 N-PRO-03 1.5011-09 1.5011-09 1.0330-03 9.8056-04 9.8056-04 HYDRO-01 4.8322-05 4.8322-05 6.9864-02 2.1951-04 2.1951-04 TOTAL CUM/SEC 5.4453-05 5.4453-05 0.1609 3.2425-02 3.2425-02 COMPONENTS: STD VOL FRAC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 4.5239-02 4.5239-02 1.3137-02 2.2617-03 2.2617-03 ETHAN-01 3.1096-02 3.1096-02 2.2748-02 8.7675-03 8.7675-03 PROPA-01 1.3005-02 1.3005-02 2.0463-02 1.2072-02 1.2072-02 N-BUT-01 4.9188-03 4.9188-03 1.2287-02 1.5942-02 1.5942-02 ISOBU-01 4.1660-03 4.1660-03 8.7853-03 9.4711-03 9.4711-03 N-PEN-01 9.3408-04 9.3408-04 4.6656-03 8.8269-03 8.8269-03 2-MET-01 2.3622-03 2.3622-03 1.0233-02 1.8432-02 1.8432-02 N-HEX-01 1.0672-03 1.0672-03 3.4644-02 3.1138-02 3.1138-02 2-MET-02 1.4320-03 1.4320-03 3.5424-02 3.1673-02 3.1673-02 N-HEP-01 5.3550-04 5.3550-04 4.9555-02 4.6658-02 4.6658-02 2-MET-03 8.2527-04 8.2527-04 5.3690-02 5.0623-02 5.0623-02 N-OCT-01 1.0657-05 1.0657-05 4.5020-02 2.7230-03 2.7230-03 2:2:4-01 6.3118-05 6.3118-05 6.4638-02 4.7297-03 4.7297-03 N-NON-01 4.1519-05 4.1519-05 3.2311-02 2.8515-02 2.8515-02 2:2:5-01 2.6651-04 2.6651-04 5.0786-02 4.7366-02 4.7366-02 CYCLO-01 9.4916-08 9.4916-08 2.5737-03 4.8679-06 4.8679-06 METHY-01 2.0232-07 2.0232-07 2.8903-03 2.0586-05 2.0586-05 ETHYL-01 7.2983-08 7.2983-08 1.0731-04 2.0371-05 2.0371-05 N-PRO-01 7.7848-09 7.7848-09 7.9019-04 5.1452-06 5.1452-06 CYCLO-02 1.2893-05 1.2893-05 1.0892-04 2.3229-04 2.3229-04 METHY-02 2.3860-04 2.3860-04 3.9044-03 8.9818-03 8.9818-03 ETHYL-02 2.0068-04 2.0068-04 9.6455-03 2.3323-02 2.3323-02 N-PRO-02 1.0329-04 1.0329-04 1.4070-02 3.4575-02 3.4575-02 N-BUT-02 6.0113-06 6.0113-06 2.2539-03 5.5694-03 5.5694-03 BENZE-01 4.8508-03 4.8508-03 1.4656-02 0.2269 0.2269 TOLUE-01 7.3003-04 7.3003-04 2.1357-02 0.1045 0.1045 M-XYL-01 1.2648-04 1.2648-04 6.0503-03 6.3001-02 6.3001-02 O-XYL-01 1.7322-04 1.7322-04 6.3514-03 0.1014 0.1014

184

STREAM ID S27 S28 S3 S30 S31 P-XYL-01 8.5706-05 8.5706-05 9.2412-03 4.1093-02 4.1093-02 ETHYL-03 8.0440-05 8.0440-05 7.0599-03 3.4140-02 3.4140-02 N-PRO-03 2.7566-05 2.7566-05 6.4189-03 3.0241-02 3.0241-02 HYDRO-01 0.8874 0.8874 0.4341 6.7697-03 6.7697-03 TOTAL CUM/SEC 5.4453-05 5.4453-05 0.1609 3.2425-02 3.2425-02 TOTAL FLOW: KMOL/SEC 9.8828-04 9.8828-04 2.0103 0.2851 0.2851 KG/SEC 4.3812-03 4.3812-03 64.8992 25.6864 25.6864 CUM/SEC 8.4193-04 8.2816-04 21.3069 3.2674-02 2.7146-02 STATE VARIABLES: TEMP K 313.0000 308.0000 757.1306 313.0000 19.6623 PRES N/SQM 3.1000+06 3.1000+06 5.9500+05 3.1000+06 3.1000+06 VFRAC 1.0000 0.9995 1.0000 0.0 1.4574-02 LFRAC 0.0 5.2412-04 0.0 1.0000 0.9854 SFRAC 0.0 0.0 0.0 0.0 0.0 ENTHALPY: J/KMOL -6.5039+06 -6.6779+06 -4.6852+06 -5.3778+07 -9.6319+07 J/KG -1.4671+06 -1.5063+06 -1.4513+05 -5.9687+05 -1.0690+06 WATT -6427.6947 -6599.6186 -9.4186+06 -1.5331+07 -2.7459+07 ENTROPY: J/KMOL-K -3.7398+04 -3.7959+04 -1.0005+05 -4.2271+05 -2.3270+06 J/KG-K -8435.9334 -8562.3187 -3099.0919 -4691.5297 -2.5827+04 DENSITY: KMOL/CUM 1.1738 1.1933 9.4350-02 8.7253 10.5019 KG/CUM 5.2038 5.2904 3.0459 786.1520 946.2251 AVG MW 4.4332 4.4332 32.2834 90.1004 90.1004 MIXED SUBSTREAM PROPERTIES: *** ALL PHASES *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 1.3387 1.3387 1148.8791 39.8539 39.8539 ETHAN-01 0.9202 0.9202 1989.4088 154.4923 154.4923 PROPA-01 0.3848 0.3848 1789.6126 212.7279 212.7279 N-BUT-01 0.1456 0.1456 1074.5526 280.9127 280.9127 ISOBU-01 0.1233 0.1233 768.3114 166.8903 166.8903 N-PEN-01 2.7642-02 2.7642-02 408.0252 155.5395 155.5395 2-MET-01 6.9902-02 6.9902-02 894.8831 324.8007 324.8007 N-HEX-01 3.1582-02 3.1582-02 3029.7638 548.6906 548.6906 2-MET-02 4.2377-02 4.2377-02 3097.9471 558.1146 558.1146 N-HEP-01 1.5846-02 1.5846-02 4333.8031 822.1609 822.1609 2-MET-03 2.4422-02 2.4422-02 4695.4054 892.0282 892.0282 N-OCT-01 3.1535-04 3.1535-04 3937.1679 47.9828 47.9828 2:2:4-01 1.8678-03 1.8678-03 5652.8175 83.3419 83.3419 N-NON-01 1.2286-03 1.2286-03 2825.7149 502.4586 502.4586 2:2:5-01 7.8867-03 7.8867-03 4441.4381 834.6350 834.6350 CYCLO-01 2.8088-06 2.8088-06 225.0778 8.5778-02 8.5778-02 METHY-01 5.9871-06 5.9871-06 252.7688 0.3628 0.3628 ETHYL-01 2.1597-06 2.1597-06 9.3846 0.3590 0.3590 N-PRO-01 2.3037-07 2.3037-07 69.1053 9.0664-02 9.0664-02 CYCLO-02 3.8153-04 3.8153-04 9.5255 4.0933 4.0933

185

STREAM ID S27 S28 S3 S30 S31 METHY-02 7.0608-03 7.0608-03 341.4553 158.2690 158.2690 ETHYL-02 5.9386-03 5.9386-03 843.5354 410.9742 410.9742 N-PRO-02 3.0566-03 3.0566-03 1230.4592 609.2420 609.2420 N-BUT-02 1.7789-04 1.7789-04 197.1136 98.1380 98.1380 BENZE-01 0.1435 0.1435 1281.7176 3998.0939 3998.0939 TOLUE-01 2.1603-02 2.1603-02 1867.7202 1841.7805 1841.7805 M-XYL-01 3.7429-03 3.7429-03 529.1211 1110.1487 1110.1487 O-XYL-01 5.1261-03 5.1261-03 555.4541 1786.9694 1786.9694 P-XYL-01 2.5362-03 2.5362-03 808.1835 724.1077 724.1077 ETHYL-03 2.3804-03 2.3804-03 617.4140 601.5855 601.5855 N-PRO-03 8.1573-04 8.1573-04 561.3540 532.8726 532.8726 HYDRO-01 26.2601 26.2601 3.7967+04 119.2891 119.2891 *** VAPOR PHASE *** VOLFLMX CUFT/HR 107.0367 105.2785 2.7088+06 MISSING 55.1564 VVSTDMX CUFT/HR 2816.0989 2814.6229 5.7283+06 MISSING 1.1840+04 CPMX BTU/LB-R 1.6928 1.7036 0.8759 MISSING 1.0548 RHOMX LB/CUFT 0.3249 0.3269 0.1902 MISSING 2.0028 MWMX 4.4332 4.3895 32.2834 MISSING 3.3499 *** LIQUID PHASE *** VOLFLMX BBL/HR MISSING 1.3142-03 MISSING 739.8393 604.8567 BBL/DAY MISSING 3.1540-02 MISSING 1.7756+04 1.4517+04 CPMX BTU/LB-R MISSING 0.4422 MISSING 0.4451 0.5428 MUMX CP MISSING 0.3488 MISSING 0.3422 4.6029+23 VLSTDMX BBL/HR MISSING 1.3118-03 MISSING 734.2122 729.0925 BBL/DAY MISSING 3.1483-02 MISSING 1.7621+04 1.7498+04 *** DRY TOTAL *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 1.3387 1.3387 1148.8791 39.8539 39.8539 ETHAN-01 0.9202 0.9202 1989.4088 154.4923 154.4923 PROPA-01 0.3848 0.3848 1789.6126 212.7279 212.7279 N-BUT-01 0.1456 0.1456 1074.5526 280.9127 280.9127 ISOBU-01 0.1233 0.1233 768.3114 166.8903 166.8903 N-PEN-01 2.7642-02 2.7642-02 408.0252 155.5395 155.5395 2-MET-01 6.9902-02 6.9902-02 894.8831 324.8007 324.8007 N-HEX-01 3.1582-02 3.1582-02 3029.7638 548.6906 548.6906 2-MET-02 4.2377-02 4.2377-02 3097.9471 558.1146 558.1146 N-HEP-01 1.5846-02 1.5846-02 4333.8031 822.1609 822.1609 2-MET-03 2.4422-02 2.4422-02 4695.4054 892.0282 892.0282 N-OCT-01 3.1535-04 3.1535-04 3937.1679 47.9828 47.9828 2:2:4-01 1.8678-03 1.8678-03 5652.8175 83.3419 83.3419 N-NON-01 1.2286-03 1.2286-03 2825.7149 502.4586 502.4586 2:2:5-01 7.8867-03 7.8867-03 4441.4381 834.6350 834.6350 CYCLO-01 2.8088-06 2.8088-06 225.0778 8.5778-02 8.5778-02 METHY-01 5.9871-06 5.9871-06 252.7688 0.3628 0.3628 ETHYL-01 2.1597-06 2.1597-06 9.3846 0.3590 0.3590 N-PRO-01 2.3037-07 2.3037-07 69.1053 9.0664-02 9.0664-02 CYCLO-02 3.8153-04 3.8153-04 9.5255 4.0933 4.0933 METHY-02 7.0608-03 7.0608-03 341.4553 158.2690 158.2690

186

STREAM ID S27 S28 S3 S30 S31 ETHYL-02 5.9386-03 5.9386-03 843.5354 410.9742 410.9742 N-PRO-02 3.0566-03 3.0566-03 1230.4592 609.2420 609.2420 N-BUT-02 1.7789-04 1.7789-04 197.1136 98.1380 98.1380 BENZE-01 0.1435 0.1435 1281.7176 3998.0939 3998.0939 TOLUE-01 2.1603-02 2.1603-02 1867.7202 1841.7805 1841.7805 M-XYL-01 3.7429-03 3.7429-03 529.1211 1110.1487 1110.1487 O-XYL-01 5.1261-03 5.1261-03 555.4541 1786.9694 1786.9694 P-XYL-01 2.5362-03 2.5362-03 808.1835 724.1077 724.1077 ETHYL-03 2.3804-03 2.3804-03 617.4140 601.5855 601.5855 N-PRO-03 8.1573-04 8.1573-04 561.3540 532.8726 532.8726 HYDRO-01 26.2601 26.2601 3.7967+04 119.2891 119.2891 VLSTDMX BBL/DAY 29.5922 29.5922 8.7454+04 1.7621+04 1.7621+04 APISTD 261.7006 261.7006 85.6129 45.6295 45.6295 SGSTD 0.3598 0.3598 0.6517 0.7988 0.7988 WAT 11.9045 11.9045 10.7714 11.0187 11.0187 FLPT-API K MISSING MISSING MISSING 254.8113 254.8113 RVP-API N/SQM 1.9135+09 1.9135+09 9.0057+07 1.9241+06 1.9241+06

187

7.8.6. S32 S33 S34 S35 S36

STREAM ID S32 S33 S34 S35 S36 FROM : F-2 B4 R4 E-7 B7 TO : B6 R4 E-2 B6 B1 SUBSTREAM: MIXED PHASE: LIQUID VAPOR VAPOR MIXED MIXED COMPONENTS: KMOL/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 1.2346-03 3.9473-02 0.1613 1.3693-03 3.9473-02 ETHAN-01 3.3603-03 4.3215-02 7.7909-02 3.3559-03 4.3215-02 PROPA-01 4.4981-03 3.7789-02 3.7789-02 4.4919-03 3.7789-02 N-BUT-01 5.1865-03 1.9830-02 1.9829-02 5.1840-03 1.9830-02 ISOBU-01 2.9684-03 1.3657-02 1.3658-02 2.9664-03 1.3657-02 N-PEN-01 2.4964-03 6.5477-03 6.5473-03 2.4960-03 6.5477-03 2-MET-01 5.1615-03 1.4218-02 1.4218-02 5.1604-03 1.4218-02 N-HEX-01 7.7588-03 3.2885-02 1.7079-02 7.7584-03 4.2840-02 2-MET-02 7.8197-03 3.3537-02 1.7713-02 7.8191-03 4.3402-02 N-HEP-01 1.0363-02 4.1739-02 2.1426-02 1.0363-02 5.4626-02 2-MET-03 1.1160-02 4.5070-02 2.3383-02 1.1160-02 5.8742-02 N-OCT-01 5.4490-04 1.6217-02 1.1022-03 5.4490-04 4.4711-02 2:2:4-01 9.3227-04 2.4237-02 1.9371-03 9.3225-04 6.3232-02 N-NON-01 5.1894-03 2.1714-02 1.0422-02 5.1894-03 2.9184-02 2:2:5-01 8.5780-03 3.4616-02 1.7436-02 8.5779-03 4.5647-02 CYCLO-01 1.4658-06 0.0 3.0993-06 1.4658-06 1.4405-02 METHY-01 5.2490-06 0.0 1.0800-05 5.2489-06 1.5714-02 ETHYL-01 4.6181-06 0.0 9.3325-06 4.6181-06 2.1514-02 N-PRO-01 1.0517-06 0.0 2.1126-06 1.0517-06 3.3674-03 CYCLO-02 8.0397-05 1.8708-04 1.8708-04 8.0390-05 1.8708-04 METHY-02 2.6015-03 5.6123-03 5.6086-03 2.6014-03 5.6123-03 ETHYL-02 5.9245-03 1.2160-02 1.2147-02 5.9244-03 1.2160-02 N-PRO-02 7.7808-03 1.5714-02 1.5697-02 7.7807-03 1.5714-02 N-BUT-02 1.1177-03 2.2449-03 2.2424-03 1.1177-03 2.2449-03 BENZE-01 8.3125-02 5.0322-02 0.1767 8.3122-02 1.6089-02 TOLUE-01 3.1998-02 6.2679-02 6.5304-02 3.1998-02 2.0391-02 M-XYL-01 1.6679-02 2.4870-02 3.3553-02 1.6679-02 2.8061-03 O-XYL-01 2.7342-02 2.5962-02 5.4956-02 2.7342-02 2.9932-03 P-XYL-01 1.0841-02 2.8756-02 2.1813-02 1.0841-02 6.7347-03 ETHYL-03 9.0692-03 2.5878-02 1.8263-02 9.0691-03 3.9286-03 N-PRO-03 7.0528-03 2.6735-02 1.4143-02 7.0528-03 4.8640-03 HYDRO-01 7.1788-04 1.8593 2.2609 4.0985-03 1.1647 COMPONENTS: STD CUM/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 6.6120-05 2.1141-03 8.6366-03 7.3336-05 2.1141-03 ETHAN-01 2.8466-04 3.6608-03 6.5998-03 2.8429-04 3.6608-03 PROPA-01 3.9198-04 3.2931-03 3.2931-03 3.9145-04 3.2931-03 N-BUT-01 5.1716-04 1.9773-03 1.9772-03 5.1692-04 1.9773-03 ISOBU-01 3.0730-04 1.4138-03 1.4139-03 3.0710-04 1.4138-03 N-PEN-01 2.8626-04 7.5082-04 7.5078-04 2.8621-04 7.5082-04 2-MET-01 5.9780-04 1.6467-03 1.6467-03 5.9768-04 1.6467-03 N-HEX-01 1.0097-03 4.2796-03 2.2226-03 1.0097-03 5.5752-03 2-MET-02 1.0271-03 4.4049-03 2.3265-03 1.0270-03 5.7006-03

188

STREAM ID S32 S33 S34 S35 S36 N-OCT-01 8.8295-05 2.6277-03 1.7860-04 8.8295-05 7.2449-03 2:2:4-01 1.5336-04 3.9871-03 3.1866-04 1.5336-04 1.0402-02 N-NON-01 9.2459-04 3.8689-03 1.8570-03 9.2459-04 5.1997-03 2:2:5-01 1.5359-03 6.1978-03 3.1219-03 1.5358-03 8.1728-03 CYCLO-01 1.5785-07 0.0 3.3376-07 1.5784-07 1.5512-03 METHY-01 6.6753-07 0.0 1.3734-06 6.6752-07 1.9984-03 ETHYL-01 6.6055-07 0.0 1.3349-06 6.6055-07 3.0772-03 N-PRO-01 1.6683-07 0.0 3.3513-07 1.6683-07 5.3419-04 CYCLO-02 7.5329-06 1.7528-05 1.7528-05 7.5322-06 1.7528-05 METHY-02 2.9125-04 6.2832-04 6.2791-04 2.9124-04 6.2832-04 ETHYL-02 7.5626-04 1.5522-03 1.5506-03 7.5625-04 1.5522-03 N-PRO-02 1.1211-03 2.2642-03 2.2617-03 1.1211-03 2.2642-03 N-BUT-02 1.8059-04 3.6271-04 3.6230-04 1.8059-04 3.6271-04 BENZE-01 7.3573-03 4.4539-03 1.5639-02 7.3570-03 1.4240-03 TOLUE-01 3.3892-03 6.6389-03 6.9169-03 3.3891-03 2.1598-03 M-XYL-01 2.0428-03 3.0461-03 4.1095-03 2.0428-03 3.4369-04 O-XYL-01 3.2883-03 3.1223-03 6.6093-03 3.2883-03 3.5998-04 P-XYL-01 1.3325-03 3.5344-03 2.6811-03 1.3325-03 8.2777-04 ETHYL-03 1.1070-03 3.1587-03 2.2292-03 1.1070-03 4.7953-04 N-PRO-03 9.8056-04 3.7169-03 1.9663-03 9.8056-04 6.7624-04 HYDRO-01 3.8448-05 9.9579-02 0.1211 2.1951-04 6.2381-02 TOTAL CUM/SEC 3.2239-02 0.1850 0.2070 3.2425-02 0.1544 COMPONENTS: STD VOL FRAC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 2.0509-03 1.1426-02 4.1728-02 2.2617-03 1.3692-02 ETHAN-01 8.8297-03 1.9786-02 3.1887-02 8.7675-03 2.3709-02 PROPA-01 1.2159-02 1.7799-02 1.5911-02 1.2072-02 2.1328-02 N-BUT-01 1.6042-02 1.0687-02 9.5529-03 1.5942-02 1.2806-02 ISOBU-01 9.5320-03 7.6413-03 6.8313-03 9.4711-03 9.1564-03 N-PEN-01 8.8794-03 4.0580-03 3.6274-03 8.8269-03 4.8627-03 2-MET-01 1.8543-02 8.9001-03 7.9563-03 1.8432-02 1.0665-02 N-HEX-01 3.1320-02 2.3130-02 1.0739-02 3.1138-02 3.6108-02 2-MET-02 3.1858-02 2.3808-02 1.1241-02 3.1673-02 3.6920-02 N-HEP-01 4.6928-02 3.2933-02 1.5113-02 4.6658-02 5.1649-02 2-MET-03 5.0916-02 3.5830-02 1.6617-02 5.0623-02 5.5958-02 N-OCT-01 2.7388-03 1.4202-02 8.6290-04 2.7230-03 4.6922-02 2:2:4-01 4.7571-03 2.1550-02 1.5396-03 4.7297-03 6.7368-02 N-NON-01 2.8679-02 2.0910-02 8.9720-03 2.8515-02 3.3676-02 2:2:5-01 4.7640-02 3.3498-02 1.5083-02 4.7366-02 5.2931-02 CYCLO-01 4.8962-06 0.0 1.6126-06 4.8679-06 1.0046-02 METHY-01 2.0706-05 0.0 6.6357-06 2.0586-05 1.2943-02 ETHYL-01 2.0489-05 0.0 6.4495-06 2.0371-05 1.9930-02 N-PRO-01 5.1749-06 0.0 1.6192-06 5.1452-06 3.4597-03 CYCLO-02 2.3366-04 9.4736-05 8.4687-05 2.3229-04 1.1352-04 METHY-02 9.0341-03 3.3960-03 3.0338-03 8.9818-03 4.0693-03 ETHYL-02 2.3458-02 8.3894-03 7.4915-03 2.3323-02 1.0053-02 N-PRO-02 3.4774-02 1.2238-02 1.0927-02 3.4575-02 1.4664-02 N-BUT-02 5.6015-03 1.9604-03 1.7505-03 5.5694-03 2.3491-03 BENZE-01 0.2282 2.4073-02 7.5561-02 0.2269 9.2224-03 TOLUE-01 0.1051 3.5882-02 3.3419-02 0.1045 1.3988-02 M-XYL-01 6.3365-02 1.6463-02 1.9855-02 6.3001-02 2.2259-03 O-XYL-01 0.1020 1.6876-02 3.1933-02 0.1014 2.3314-03

189

STREAM ID S32 S33 S34 S35 S36 P-XYL-01 4.1331-02 1.9103-02 1.2954-02 4.1093-02 5.3611-03 ETHYL-03 3.4337-02 1.7072-02 1.0770-02 3.4140-02 3.1057-03 N-PRO-03 3.0415-02 2.0089-02 9.5002-03 3.0241-02 4.3797-03 HYDRO-01 1.1926-03 0.5382 0.5850 6.7697-03 0.4040 TOTAL CUM/SEC 3.2239-02 0.1850 0.2070 3.2425-02 0.1544 TOTAL FLOW: KMOL/SEC 0.2816 2.5652 3.1232 0.2851 1.8706 KG/SEC 25.6787 64.9017 64.9016 25.6864 64.8992 CUM/SEC 2.9309-02 37.0592 38.3252 2.7095-02 1.0774 STATE VARIABLES: TEMP K 200.0000 798.0000 677.9857 17.1479 298.1350 PRES N/SQM 1.0000+06 4.6000+05 4.6000+05 3.1000+06 3.1500+06 VFRAC 0.0 1.0000 1.0000 1.4500-02 0.6641 LFRAC 1.0000 0.0 0.0 0.9855 0.3359 SFRAC 0.0 0.0 0.0 0.0 0.0 ENTHALPY: J/KMOL -7.1555+07 1.4197+07 1.1660+07 -9.6850+07 -6.8260+07 J/KG -7.8467+05 5.6110+05 5.6110+05 -1.0749+06 -1.9674+06 WATT -2.0149+07 3.6417+07 3.6417+07 -2.7611+07 -1.2769+08 ENTROPY: J/KMOL-K -4.9393+05 -4.8551+04 -3.2990+04 -1.6870+06 -2.4826+05 J/KG-K -5416.4129 -1918.9047 -1587.5650 -1.8724+04 -7155.4264 DENSITY: KMOL/CUM 9.6077 6.9218-02 8.1493-02 10.5219 1.7362 KG/CUM 876.1302 1.7513 1.6934 948.0229 60.2379 AVG MW 91.1907 25.3013 20.7802 90.1004 34.6948 MIXED SUBSTREAM PROPERTIES: *** ALL PHASES *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 35.9322 1148.8791 4693.4765 39.8539 1148.8791 ETHAN-01 154.6951 1989.4088 3586.5915 154.4923 1989.4088 PROPA-01 213.0170 1789.6126 1789.6126 212.7279 1789.6126 N-BUT-01 281.0475 1074.5526 1074.4929 280.9127 1074.5526 ISOBU-01 167.0001 768.3114 768.3733 166.8903 768.3114 N-PEN-01 155.5665 408.0252 408.0027 155.5395 408.0252 2-MET-01 324.8683 894.8831 894.9058 324.8007 894.8831 N-HEX-01 548.7219 2325.6857 1207.8598 548.6906 3029.7638 2-MET-02 558.1565 2393.8229 1264.3215 558.1146 3097.9471 N-HEP-01 822.1767 3311.3628 1699.8573 822.1609 4333.8031 2-MET-03 892.0525 3602.5899 1869.0438 892.0282 4695.4054 N-OCT-01 47.9832 1427.9930 97.0574 47.9828 3937.1679 2:2:4-01 83.3438 2166.7699 173.1725 83.3419 5652.8175 N-NON-01 502.4598 2102.4870 1009.1524 502.4586 2825.7149 2:2:5-01 834.6429 3368.1387 1696.5557 834.6350 4441.4381 CYCLO-01 8.5781-02 MISSING 0.1814 8.5778-02 842.9914 METHY-01 0.3628 MISSING 0.7464 0.3628 1086.0339 ETHYL-01 0.3590 MISSING 0.7254 0.3590 1672.2929 N-PRO-01 9.0664-02 MISSING 0.1821 9.0664-02 290.2994 CYCLO-02 4.0937 9.5255 9.5255 4.0933 9.5255

190

STREAM ID S32 S33 S34 S35 S36 METHY-02 158.2760 341.4553 341.2317 158.2690 341.4553 ETHYL-02 410.9801 843.5355 842.6315 410.9742 843.5354 N-PRO-02 609.2450 1230.4592 1229.0847 609.2420 1230.4592 N-BUT-02 98.1382 197.1136 196.8904 98.1380 197.1136 BENZE-01 3998.2364 2420.4405 8498.9686 3998.0939 773.8478 TOLUE-01 1841.8021 3607.8267 3758.9018 1841.7805 1173.7225 M-XYL-01 1110.1524 1655.3599 2233.2916 1110.1487 186.7764 O-XYL-01 1786.9746 1696.7933 3591.7372 1786.9694 195.6252 P-XYL-01 724.1102 1920.7360 1457.0203 724.1077 449.8445 ETHYL-03 601.5879 1716.5450 1211.4396 601.5855 260.5967 N-PRO-03 532.8734 2019.9284 1068.5677 532.8726 367.4973 HYDRO-01 20.8944 5.4115+04 6.5805+04 119.2891 3.3900+04 *** VAPOR PHASE *** VOLFLMX CUFT/HR MISSING 4.7114+06 4.8724+06 50.9142 1.2621+05 VVSTDMX CUFT/HR MISSING 7.3094+06 8.8997+06 1.1779+04 3.5397+06 CPMX BTU/LB-R MISSING 0.9009 0.8360 1.2481 1.7897 RHOMX LB/CUFT MISSING 0.1093 0.1057 1.7904 0.3245 MWMX MISSING 25.3013 20.7802 2.7785 4.1542 *** LIQUID PHASE *** VOLFLMX BBL/HR 663.6580 MISSING MISSING 604.4466 1917.1346 BBL/DAY 1.5928+04 MISSING MISSING 1.4507+04 4.6011+04 CPMX BTU/LB-R 0.3509 MISSING MISSING 0.5663 0.4919 MUMX CP 2.7501 MISSING MISSING 5.3566+26 0.2940 VLSTDMX BBL/HR 729.9969 MISSING MISSING 729.1519 1944.1552 BBL/DAY 1.7520+04 MISSING MISSING 1.7500+04 4.6660+04 *** DRY TOTAL *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 35.9322 1148.8791 4693.4765 39.8539 1148.8791 ETHAN-01 154.6951 1989.4088 3586.5915 154.4923 1989.4088 PROPA-01 213.0170 1789.6126 1789.6126 212.7279 1789.6126 N-BUT-01 281.0475 1074.5526 1074.4929 280.9127 1074.5526 ISOBU-01 167.0001 768.3114 768.3733 166.8903 768.3114 N-PEN-01 155.5665 408.0252 408.0027 155.5395 408.0252 2-MET-01 324.8683 894.8831 894.9058 324.8007 894.8831 N-HEX-01 548.7219 2325.6857 1207.8598 548.6906 3029.7638 2-MET-02 558.1565 2393.8229 1264.3215 558.1146 3097.9471 N-HEP-01 822.1767 3311.3628 1699.8573 822.1609 4333.8031 2-MET-03 892.0525 3602.5899 1869.0438 892.0282 4695.4054 N-OCT-01 47.9832 1427.9930 97.0574 47.9828 3937.1679 2:2:4-01 83.3438 2166.7699 173.1725 83.3419 5652.8175 N-NON-01 502.4598 2102.4870 1009.1524 502.4586 2825.7149 2:2:5-01 834.6429 3368.1387 1696.5557 834.6350 4441.4381 CYCLO-01 8.5781-02 MISSING 0.1814 8.5778-02 842.9914 METHY-01 0.3628 MISSING 0.7464 0.3628 1086.0339 ETHYL-01 0.3590 MISSING 0.7254 0.3590 1672.2929 N-PRO-01 9.0664-02 MISSING 0.1821 9.0664-02 290.2994 CYCLO-02 4.0937 9.5255 9.5255 4.0933 9.5255 METHY-02 158.2760 341.4553 341.2317 158.2690 341.4553

191

STREAM ID S32 S33 S34 S35 S36 ETHYL-02 410.9801 843.5355 842.6315 410.9742 843.5354 N-PRO-02 609.2450 1230.4592 1229.0847 609.2420 1230.4592 N-BUT-02 98.1382 197.1136 196.8904 98.1380 197.1136 BENZE-01 3998.2364 2420.4405 8498.9686 3998.0939 773.8478 TOLUE-01 1841.8021 3607.8267 3758.9018 1841.7805 1173.7225 M-XYL-01 1110.1524 1655.3599 2233.2916 1110.1487 186.7764 O-XYL-01 1786.9746 1696.7933 3591.7372 1786.9694 195.6252 P-XYL-01 724.1102 1920.7360 1457.0203 724.1077 449.8445 ETHYL-03 601.5879 1716.5450 1211.4396 601.5855 260.5967 N-PRO-03 532.8734 2019.9284 1068.5677 532.8726 367.4973 HYDRO-01 20.8944 5.4115+04 6.5805+04 119.2891 3.3900+04 VLSTDMX BBL/DAY 1.7520+04 1.0055+05 1.1248+05 1.7621+04 8.3909+04 APISTD 45.5297 81.5204 88.3839 45.6295 85.6192 SGSTD 0.7993 0.6642 0.6435 0.7988 0.6517 WAT 11.0187 8.6934 8.5443 11.0187 11.2327 FLPT-API K 256.0759 MISSING MISSING 254.8113 MISSING RVP-API N/SQM 4.5912+05 9.7484+07 1.9506+09 1.9241+06 8.0249+07

192

7.8.7. S37 S4 S5 S6 S7

STREAM ID S37 S4 S5 S6 S7 FROM : B6 B2 R2 B3 B9 TO : E-12 R2 B3 R3 G-3 SUBSTREAM: MIXED PHASE: MIXED VAPOR VAPOR VAPOR LIQUID COMPONENTS: KMOL/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 2.6038-03 3.9473-02 3.9473-02 3.9473-02 1.3249-03 ETHAN-01 6.7163-03 4.3215-02 4.3215-02 4.3215-02 3.3681-03 PROPA-01 8.9900-03 3.7789-02 3.7789-02 3.7789-02 4.4991-03 N-BUT-01 1.0371-02 1.9830-02 1.9830-02 1.9830-02 5.1866-03 ISOBU-01 5.9348-03 1.3657-02 1.3657-02 1.3657-02 2.9685-03 N-PEN-01 4.9924-03 6.5477-03 6.5477-03 6.5477-03 2.4964-03 2-MET-01 1.0322-02 1.4218-02 1.4218-02 1.4218-02 5.1615-03 N-HEX-01 1.5517-02 4.2840-02 4.2840-02 4.2840-02 7.7588-03 2-MET-02 1.5639-02 4.3402-02 4.3402-02 4.3402-02 7.8197-03 N-HEP-01 2.0726-02 5.4626-02 5.4626-02 5.4626-02 1.0363-02 2-MET-03 2.2320-02 5.8742-02 5.8742-02 5.8742-02 1.1160-02 N-OCT-01 1.0898-03 4.4711-02 4.4711-02 4.4711-02 5.4490-04 2:2:4-01 1.8645-03 6.3232-02 6.3232-02 6.3232-02 9.3227-04 N-NON-01 1.0379-02 2.9184-02 2.9184-02 2.9184-02 5.1894-03 2:2:5-01 1.7156-02 4.5647-02 4.5647-02 4.5647-02 8.5780-03 CYCLO-01 2.9316-06 3.8461-03 0.0 0.0 1.4658-06 METHY-01 1.0498-05 3.6574-03 0.0 0.0 5.2490-06 ETHYL-01 9.2361-06 1.2073-04 0.0 0.0 4.6181-06 N-PRO-01 2.1033-06 8.0160-04 0.0 0.0 1.0517-06 CYCLO-02 1.6079-04 1.8708-04 1.8708-04 1.8708-04 8.0398-05 METHY-02 5.2028-03 5.6123-03 5.6123-03 5.6123-03 2.6015-03 ETHYL-02 1.1849-02 1.2160-02 1.2160-02 1.2160-02 5.9245-03 N-PRO-02 1.5561-02 1.5714-02 1.5714-02 1.5714-02 7.7808-03 N-BUT-02 2.2354-03 2.2449-03 2.2449-03 2.2449-03 1.1177-03 BENZE-01 0.1662 2.6647-02 3.0501-02 3.0501-02 8.3125-02 TOLUE-01 6.3995-02 3.2448-02 3.6120-02 3.6120-02 3.1998-02 M-XYL-01 3.3358-02 7.9495-03 7.9787-03 7.9787-03 1.6679-02 O-XYL-01 5.4684-02 8.4989-03 8.5300-03 8.5300-03 2.7342-02 P-XYL-01 2.1682-02 1.2100-02 1.2130-02 1.2130-02 1.0841-02 ETHYL-03 1.8138-02 9.3077-03 9.3382-03 9.3382-03 9.0692-03 N-PRO-03 1.4106-02 7.4297-03 8.2343-03 8.2343-03 7.0528-03 HYDRO-01 4.8164-03 1.3045 1.3298 1.3298 2.8593-03 COMPONENTS: STD CUM/SEC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 1.3946-04 2.1141-03 2.1141-03 2.1141-03 7.0960-05 ETHAN-01 5.6895-04 3.6608-03 3.6608-03 3.6608-03 2.8532-04 PROPA-01 7.8343-04 3.2931-03 3.2931-03 3.2931-03 3.9207-04 N-BUT-01 1.0341-03 1.9773-03 1.9773-03 1.9773-03 5.1717-04 ISOBU-01 6.1440-04 1.4138-03 1.4138-03 1.4138-03 3.0731-04 N-PEN-01 5.7248-04 7.5082-04 7.5082-04 7.5082-04 2.8626-04 2-MET-01 1.1955-03 1.6467-03 1.6467-03 1.6467-03 5.9780-04 N-HEX-01 2.0194-03 5.5752-03 5.5752-03 5.5752-03 1.0097-03 2-MET-02 2.0541-03 5.7006-03 5.7006-03 5.7006-03 1.0271-03 N-HEP-01 3.0258-03 7.9748-03 7.9748-03 7.9748-03 1.5129-03 2-MET-03 3.2829-03 8.6402-03 8.6402-03 8.6402-03 1.6415-03

193

STREAM ID S37 S4 S5 S6 S7 N-OCT-01 1.7659-04 7.2449-03 7.2449-03 7.2449-03 8.8295-05 2:2:4-01 3.0672-04 1.0402-02 1.0402-02 1.0402-02 1.5336-04 N-NON-01 1.8492-03 5.1997-03 5.1997-03 5.1997-03 9.2459-04 2:2:5-01 3.0717-03 8.1728-03 8.1728-03 8.1728-03 1.5359-03 CYCLO-01 3.1569-07 4.1417-04 0.0 0.0 1.5785-07 METHY-01 1.3350-06 4.6513-04 0.0 0.0 6.6753-07 ETHYL-01 1.3211-06 1.7269-05 0.0 0.0 6.6055-07 N-PRO-01 3.3367-07 1.2716-04 0.0 0.0 1.6683-07 CYCLO-02 1.5065-05 1.7528-05 1.7528-05 1.7528-05 7.5329-06 METHY-02 5.8248-04 6.2832-04 6.2832-04 6.2832-04 2.9125-04 ETHYL-02 1.5125-03 1.5522-03 1.5522-03 1.5522-03 7.5626-04 N-PRO-02 2.2422-03 2.2642-03 2.2642-03 2.2642-03 1.1211-03 N-BUT-02 3.6117-04 3.6271-04 3.6271-04 3.6271-04 1.8059-04 BENZE-01 1.4714-02 2.3585-03 2.6997-03 2.6997-03 7.3573-03 TOLUE-01 6.7783-03 3.4368-03 3.8258-03 3.8258-03 3.3892-03 M-XYL-01 4.0856-03 9.7365-04 9.7722-04 9.7722-04 2.0428-03 O-XYL-01 6.5765-03 1.0221-03 1.0259-03 1.0259-03 3.2883-03 P-XYL-01 2.6649-03 1.4872-03 1.4909-03 1.4909-03 1.3325-03 ETHYL-03 2.2140-03 1.1361-03 1.1398-03 1.1398-03 1.1070-03 N-PRO-03 1.9611-03 1.0330-03 1.1448-03 1.1448-03 9.8056-04 HYDRO-01 2.5796-04 6.9864-02 7.1222-02 7.1222-02 1.5314-04 TOTAL CUM/SEC 6.4664-02 0.1609 0.1621 0.1621 3.2359-02 COMPONENTS: STD VOL FRAC WATER 0.0 0.0 0.0 0.0 0.0 METHA-01 2.1566-03 1.3137-02 1.3040-02 1.3040-02 2.1929-03 ETHAN-01 8.7985-03 2.2748-02 2.2581-02 2.2581-02 8.8172-03 PROPA-01 1.2115-02 2.0463-02 2.0313-02 2.0313-02 1.2116-02 N-BUT-01 1.5992-02 1.2287-02 1.2197-02 1.2197-02 1.5982-02 ISOBU-01 9.5014-03 8.7853-03 8.7208-03 8.7208-03 9.4970-03 N-PEN-01 8.8531-03 4.6656-03 4.6313-03 4.6313-03 8.8464-03 2-MET-01 1.8487-02 1.0233-02 1.0157-02 1.0157-02 1.8474-02 N-HEX-01 3.1229-02 3.4644-02 3.4390-02 3.4390-02 3.1203-02 2-MET-02 3.1765-02 3.5424-02 3.5164-02 3.5164-02 3.1740-02 N-HEP-01 4.6793-02 4.9555-02 4.9191-02 4.9191-02 4.6754-02 2-MET-03 5.0769-02 5.3690-02 5.3296-02 5.3296-02 5.0727-02 N-OCT-01 2.7309-03 4.5020-02 4.4689-02 4.4689-02 2.7286-03 2:2:4-01 4.7433-03 6.4638-02 6.4163-02 6.4163-02 4.7394-03 N-NON-01 2.8597-02 3.2311-02 3.2074-02 3.2074-02 2.8573-02 2:2:5-01 4.7502-02 5.0786-02 5.0413-02 5.0413-02 4.7463-02 CYCLO-01 4.8820-06 2.5737-03 0.0 0.0 4.8780-06 METHY-01 2.0646-05 2.8903-03 0.0 0.0 2.0629-05 ETHYL-01 2.0430-05 1.0731-04 0.0 0.0 2.0413-05 N-PRO-01 5.1600-06 7.9019-04 0.0 0.0 5.1557-06 CYCLO-02 2.3297-04 1.0892-04 1.0812-04 1.0812-04 2.3279-04 METHY-02 9.0079-03 3.9044-03 3.8757-03 3.8757-03 9.0005-03 ETHYL-02 2.3390-02 9.6455-03 9.5746-03 9.5746-03 2.3371-02 N-PRO-02 3.4674-02 1.4070-02 1.3966-02 1.3966-02 3.4645-02 N-BUT-02 5.5854-03 2.2539-03 2.2374-03 2.2374-03 5.5807-03 BENZE-01 0.2275 1.4656-02 1.6652-02 1.6652-02 0.2274 TOLUE-01 0.1048 2.1357-02 2.3599-02 2.3599-02 0.1047 M-XYL-01 6.3183-02 6.0503-03 6.0278-03 6.0278-03 6.3130-02 O-XYL-01 0.1017 6.3514-03 6.3278-03 6.3278-03 0.1016

194

STREAM ID S37 S4 S5 S6 S7 P-XYL-01 4.1212-02 9.2412-03 9.1964-03 9.1964-03 4.1177-02 ETHYL-03 3.4238-02 7.0599-03 7.0309-03 7.0309-03 3.4210-02 N-PRO-03 3.0328-02 6.4189-03 7.0617-03 7.0617-03 3.0302-02 HYDRO-01 3.9892-03 0.4341 0.4393 0.4393 4.7325-03 TOTAL CUM/SEC 6.4664-02 0.1609 0.1621 0.1621 3.2359-02 TOTAL FLOW: KMOL/SEC 0.5667 2.0103 2.0357 2.0357 0.2838 KG/SEC 51.3651 64.8992 64.9017 64.9017 25.6848 CUM/SEC 5.8657-02 24.2969 24.3714 26.7922 3.2669-02 STATE VARIABLES: TEMP K 100.6322 798.0000 790.4137 798.0000 313.0000 PRES N/SQM 1.0000+06 5.5000+05 5.4995+05 5.0500+05 2.2300+06 VFRAC 7.3183-03 1.0000 1.0000 1.0000 0.0 LFRAC 0.9927 0.0 0.0 0.0 1.0000 SFRAC 0.0 0.0 0.0 0.0 0.0 ENTHALPY: J/KMOL -8.4280+07 2.1913+05 2.1640+05 1.1263+06 -5.4112+07 J/KG -9.2981+05 6787.6333 6787.3689 3.5328+04 -5.9797+05 WATT -4.7760+07 4.4051+05 4.4051+05 2.2929+06 -1.5359+07 ENTROPY: J/KMOL-K -5.8207+05 -9.3086+04 -9.1655+04 -8.9799+04 -4.2443+05 J/KG-K -6421.6149 -2883.4046 -2874.8104 -2816.5960 -4690.2053 DENSITY: KMOL/CUM 9.6609 8.2739-02 8.3527-02 7.5980-02 8.6881 KG/CUM 875.6842 2.6711 2.6630 2.4224 786.2050 AVG MW 90.6422 32.2834 31.8821 31.8821 90.4921 MIXED SUBSTREAM PROPERTIES: *** ALL PHASES *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 75.7861 1148.8791 1148.8791 1148.8791 38.5624 ETHAN-01 309.1874 1989.4088 1989.4088 1989.4088 155.0538 PROPA-01 425.7449 1789.6126 1789.6126 1789.6126 213.0649 N-BUT-01 561.9602 1074.5526 1074.5526 1074.5526 281.0529 ISOBU-01 333.8904 768.3114 768.3114 768.3114 167.0069 N-PEN-01 311.1060 408.0252 408.0252 408.0252 155.5668 2-MET-01 649.6690 894.8831 894.8831 894.8831 324.8694 N-HEX-01 1097.4126 3029.7638 3029.7638 3029.7638 548.7221 2-MET-02 1116.2711 3097.9471 3097.9471 3097.9471 558.1567 N-HEP-01 1644.3377 4333.8031 4333.8031 4333.8031 822.1768 2-MET-03 1784.0806 4695.4054 4695.4054 4695.4054 892.0525 N-OCT-01 95.9660 3937.1679 3937.1679 3937.1679 47.9832 2:2:4-01 166.6857 5652.8175 5652.8175 5652.8175 83.3438 N-NON-01 1004.9184 2825.7149 2825.7149 2825.7149 502.4598 2:2:5-01 1669.2779 4441.4381 4441.4381 4441.4381 834.6429 CYCLO-01 0.1716 225.0778 MISSING MISSING 8.5781-02 METHY-01 0.7255 252.7688 MISSING MISSING 0.3628 ETHYL-01 0.7179 9.3846 MISSING MISSING 0.3590 N-PRO-01 0.1813 69.1053 MISSING MISSING 9.0664-02 CYCLO-02 8.1869 9.5255 9.5255 9.5255 4.0937

195

STREAM ID S37 S4 S5 S6 S7 METHY-02 316.5450 341.4553 341.4553 341.4553 158.2761 ETHYL-02 821.9543 843.5354 843.5354 843.5354 410.9801 N-PRO-02 1218.4870 1230.4592 1230.4592 1230.4592 609.2450 N-BUT-02 196.2763 197.1136 197.1136 197.1136 98.1382 BENZE-01 7996.3303 1281.7176 1467.1022 1467.1022 3998.2369 TOLUE-01 3683.5826 1867.7202 2079.0790 2079.0790 1841.8021 M-XYL-01 2220.3011 529.1211 531.0585 531.0585 1110.1524 O-XYL-01 3573.9440 555.4541 557.4905 557.4905 1786.9746 P-XYL-01 1448.2179 808.1835 810.2114 810.2114 724.1102 ETHYL-03 1203.1734 617.4140 619.4333 619.4333 601.5879 N-PRO-03 1065.7460 561.3540 622.1460 622.1460 532.8734 HYDRO-01 140.1835 3.7967+04 3.8705+04 3.8705+04 83.2218 *** VAPOR PHASE *** VOLFLMX CUFT/HR 440.0003 3.0889+06 3.0984+06 3.4062+06 MISSING VVSTDMX CUFT/HR 1.1817+04 5.7283+06 5.8007+06 5.8007+06 MISSING CPMX BTU/LB-R 3.3402 0.8987 0.8945 0.8985 MISSING RHOMX LB/CUFT 0.1514 0.1668 0.1662 0.1512 MISSING MWMX 2.0233 32.2834 31.8821 31.8821 MISSING *** LIQUID PHASE *** VOLFLMX BBL/HR 1249.8248 MISSING MISSING MISSING 739.7410 BBL/DAY 2.9996+04 MISSING MISSING MISSING 1.7754+04 CPMX BTU/LB-R 0.3622 MISSING MISSING MISSING 0.4451 MUMX CP 929.8739 MISSING MISSING MISSING 0.3593 VLSTDMX BBL/HR 1459.1798 MISSING MISSING MISSING 732.7211 BBL/DAY 3.5020+04 MISSING MISSING MISSING 1.7585+04 *** DRY TOTAL *** VLSTD BBL/DAY WATER MISSING MISSING MISSING MISSING MISSING METHA-01 75.7861 1148.8791 1148.8791 1148.8791 38.5624 ETHAN-01 309.1874 1989.4088 1989.4088 1989.4088 155.0538 PROPA-01 425.7449 1789.6126 1789.6126 1789.6126 213.0649 N-BUT-01 561.9602 1074.5526 1074.5526 1074.5526 281.0529 ISOBU-01 333.8904 768.3114 768.3114 768.3114 167.0069 N-PEN-01 311.1060 408.0252 408.0252 408.0252 155.5668 2-MET-01 649.6690 894.8831 894.8831 894.8831 324.8694 N-HEX-01 1097.4126 3029.7638 3029.7638 3029.7638 548.7221 2-MET-02 1116.2711 3097.9471 3097.9471 3097.9471 558.1567 N-HEP-01 1644.3377 4333.8031 4333.8031 4333.8031 822.1768 2-MET-03 1784.0806 4695.4054 4695.4054 4695.4054 892.0525 N-OCT-01 95.9660 3937.1679 3937.1679 3937.1679 47.9832 2:2:4-01 166.6857 5652.8175 5652.8175 5652.8175 83.3438 N-NON-01 1004.9184 2825.7149 2825.7149 2825.7149 502.4598 2:2:5-01 1669.2779 4441.4381 4441.4381 4441.4381 834.6429 CYCLO-01 0.1716 225.0778 MISSING MISSING 8.5781-02 METHY-01 0.7255 252.7688 MISSING MISSING 0.3628 ETHYL-01 0.7179 9.3846 MISSING MISSING 0.3590 N-PRO-01 0.1813 69.1053 MISSING MISSING 9.0664-02 CYCLO-02 8.1869 9.5255 9.5255 9.5255 4.0937 METHY-02 316.5450 341.4553 341.4553 341.4553 158.2761

196

STREAM ID S37 S4 S5 S6 S7 ETHYL-02 821.9543 843.5354 843.5354 843.5354 410.9801 N-PRO-02 1218.4870 1230.4592 1230.4592 1230.4592 609.2450 N-BUT-02 196.2763 197.1136 197.1136 197.1136 98.1382 BENZE-01 7996.3303 1281.7176 1467.1022 1467.1022 3998.2369 TOLUE-01 3683.5826 1867.7202 2079.0790 2079.0790 1841.8021 M-XYL-01 2220.3011 529.1211 531.0585 531.0585 1110.1524 O-XYL-01 3573.9440 555.4541 557.4905 557.4905 1786.9746 P-XYL-01 1448.2179 808.1835 810.2114 810.2114 724.1102 ETHYL-03 1203.1734 617.4140 619.4333 619.4333 601.5879 N-PRO-03 1065.7460 561.3540 622.1460 622.1460 532.8734 HYDRO-01 140.1835 3.7967+04 3.8705+04 3.8705+04 83.2218 VLSTDMX BBL/DAY 3.5141+04 8.7454+04 8.8101+04 8.8101+04 1.7585+04 APISTD 45.5796 85.6129 85.6133 85.6133 45.5981 SGSTD 0.7991 0.6517 0.6517 0.6517 0.7990 WAT 11.0189 10.7714 10.7277 10.7277 11.0191 FLPT-API K 255.4952 MISSING MISSING MISSING 255.3092 RVP-API N/SQM 1.1911+06 9.0057+07 8.3862+07 8.3862+07 1.3868+06

197

7.8.8. S8

STREAM ID S8 FROM : R3 TO : B4 SUBSTREAM: MIXED PHASE: VAPOR COMPONENTS: KMOL/SEC WATER 0.0 METHA-01 3.9473-02 ETHAN-01 4.3215-02 PROPA-01 3.7789-02 N-BUT-01 1.9830-02 ISOBU-01 1.3657-02 N-PEN-01 6.5477-03 2-MET-01 1.4218-02 N-HEX-01 3.2885-02 2-MET-02 3.3537-02 N-HEP-01 4.1739-02 2-MET-03 4.5070-02 N-OCT-01 1.6217-02 2:2:4-01 2.4237-02 N-NON-01 2.1714-02 2:2:5-01 3.4616-02 CYCLO-01 0.0 METHY-01 0.0 ETHYL-01 0.0 N-PRO-01 0.0 CYCLO-02 1.8708-04 METHY-02 5.6123-03 ETHYL-02 1.2160-02 N-PRO-02 1.5714-02 N-BUT-02 2.2449-03 BENZE-01 5.0322-02 TOLUE-01 6.2679-02 M-XYL-01 2.4870-02 O-XYL-01 2.5962-02 P-XYL-01 2.8756-02 ETHYL-03 2.5878-02 N-PRO-03 2.6735-02 HYDRO-01 1.8593 COMPONENTS: STD CUM/SEC WATER 0.0 METHA-01 2.1141-03 ETHAN-01 3.6608-03 PROPA-01 3.2931-03 N-BUT-01 1.9773-03 ISOBU-01 1.4138-03 N-PEN-01 7.5082-04 2-MET-01 1.6467-03 N-HEX-01 4.2796-03 2-MET-02 4.4049-03 N-HEP-01 6.0933-03 2-MET-03 6.6292-03

198

STREAM ID S8 N-OCT-01 2.6277-03 2:2:4-01 3.9871-03 N-NON-01 3.8689-03 2:2:5-01 6.1978-03 CYCLO-01 0.0 METHY-01 0.0 ETHYL-01 0.0 N-PRO-01 0.0 CYCLO-02 1.7528-05 METHY-02 6.2832-04 ETHYL-02 1.5522-03 N-PRO-02 2.2642-03 N-BUT-02 3.6271-04 BENZE-01 4.4539-03 TOLUE-01 6.6389-03 M-XYL-01 3.0461-03 O-XYL-01 3.1223-03 P-XYL-01 3.5344-03 ETHYL-03 3.1587-03 N-PRO-03 3.7169-03 HYDRO-01 9.9579-02 TOTAL CUM/SEC 0.1850 COMPONENTS: STD VOL FRAC WATER 0.0 METHA-01 1.1426-02 ETHAN-01 1.9786-02 PROPA-01 1.7799-02 N-BUT-01 1.0687-02 ISOBU-01 7.6413-03 N-PEN-01 4.0580-03 2-MET-01 8.9001-03 N-HEX-01 2.3130-02 2-MET-02 2.3808-02 N-HEP-01 3.2933-02 2-MET-03 3.5830-02 N-OCT-01 1.4202-02 2:2:4-01 2.1550-02 N-NON-01 2.0910-02 2:2:5-01 3.3498-02 CYCLO-01 0.0 METHY-01 0.0 ETHYL-01 0.0 N-PRO-01 0.0 CYCLO-02 9.4736-05 METHY-02 3.3960-03 ETHYL-02 8.3894-03 N-PRO-02 1.2238-02 N-BUT-02 1.9604-03 BENZE-01 2.4073-02 TOLUE-01 3.5882-02 M-XYL-01 1.6463-02 O-XYL-01 1.6876-02

199

STREAM ID S8 P-XYL-01 1.9103-02 ETHYL-03 1.7072-02 N-PRO-03 2.0089-02 HYDRO-01 0.5382 TOTAL CUM/SEC 0.1850 TOTAL FLOW: KMOL/SEC 2.5652 KG/SEC 64.9017 CUM/SEC 27.5807 STATE VARIABLES: TEMP K 652.2720 PRES N/SQM 5.0500+05 VFRAC 1.0000 LFRAC 0.0 SFRAC 0.0 ENTHALPY: J/KMOL 8.9386+05 J/KG 3.5329+04 WATT 2.2929+06 ENTROPY: J/KMOL-K -6.7706+04 J/KG-K -2676.0013 DENSITY: KMOL/CUM 9.3005-02 KG/CUM 2.3532 AVG MW 25.3013 MIXED SUBSTREAM PROPERTIES: *** ALL PHASES *** VLSTD BBL/DAY WATER MISSING METHA-01 1148.8791 ETHAN-01 1989.4088 PROPA-01 1789.6126 N-BUT-01 1074.5526 ISOBU-01 768.3114 N-PEN-01 408.0252 2-MET-01 894.8831 N-HEX-01 2325.6857 2-MET-02 2393.8229 N-HEP-01 3311.3628 2-MET-03 3602.5899 N-OCT-01 1427.9930 2:2:4-01 2166.7699 N-NON-01 2102.4870 2:2:5-01 3368.1387 CYCLO-01 MISSING METHY-01 MISSING ETHYL-01 MISSING N-PRO-01 MISSING CYCLO-02 9.5255

200

STREAM ID S8 METHY-02 341.4553 ETHYL-02 843.5355 N-PRO-02 1230.4592 N-BUT-02 197.1136 BENZE-01 2420.4405 TOLUE-01 3607.8267 M-XYL-01 1655.3599 O-XYL-01 1696.7933 P-XYL-01 1920.7360 ETHYL-03 1716.5450 N-PRO-03 2019.9284 HYDRO-01 5.4115+04 *** VAPOR PHASE *** VOLFLMX CUFT/HR 3.5064+06 VVSTDMX CUFT/HR 7.3094+06 CPMX BTU/LB-R 0.8199 RHOMX LB/CUFT 0.1469 MWMX 25.3013 *** LIQUID PHASE *** VOLFLMX BBL/HR MISSING BBL/DAY MISSING CPMX BTU/LB-R MISSING MUMX CP MISSING VLSTDMX BBL/HR MISSING BBL/DAY MISSING *** DRY TOTAL *** VLSTD BBL/DAY WATER MISSING METHA-01 1148.8791 ETHAN-01 1989.4088 PROPA-01 1789.6126 N-BUT-01 1074.5526 ISOBU-01 768.3114 N-PEN-01 408.0252 2-MET-01 894.8831 N-HEX-01 2325.6857 2-MET-02 2393.8229 N-HEP-01 3311.3628 2-MET-03 3602.5899 N-OCT-01 1427.9930 2:2:4-01 2166.7699 N-NON-01 2102.4870 2:2:5-01 3368.1387 CYCLO-01 MISSING METHY-01 MISSING ETHYL-01 MISSING N-PRO-01 MISSING CYCLO-02 9.5255 METHY-02 341.4553

201

STREAM ID S8 ETHYL-02 843.5355 N-PRO-02 1230.4592 N-BUT-02 197.1136 BENZE-01 2420.4405 TOLUE-01 3607.8267 M-XYL-01 1655.3599 O-XYL-01 1696.7933 P-XYL-01 1920.7360 ETHYL-03 1716.5450 N-PRO-03 2019.9284 HYDRO-01 5.4115+04 VLSTDMX BBL/DAY 1.0055+05 APISTD 81.5204 SGSTD 0.6642 WAT 8.6934 FLPT-API K MISSING RVP-API N/SQM 9.7484+07

202

CHAPTER 8: SOFT SENSOR TO

PREDICT THE OCTANE NUMBER

(RON) OF NAPHTHA REFORMATE

203

8.1. INTRODUCTION:

Soft sensors are inferential estimators, drawing conclusions from process observations

when hardware sensors are unavailable or unsuitable; they have an important auxiliary role

in sensor validation when performance declines through senescence or fault accumulation.

The non-linear behavior exhibited by many industrial processes can be usefully modelled

with the techniques of computational intelligence such as artificial neural networks (ANN).

The use of ANN has expanded to a broad range of areas including engineering, economic

and medical sectors. The ANN is a reduction technique to improve the computational

efficiency especially when large and complex structures are required to approximate and

capture highly nonlinear models.

ANN consists of a number of interconnected processing elements commonly referred as

neurons that mimic the neural activity in our brain. An ANN consists of three layers: Input,

Hidden and Output. The input layer is the layer that receives information from external

sources, and passes this information to the network for processing. The hidden Layer is a

layer of neurons that receives information from the input layer and processes them in a

hidden way. The output Layer is a layer of neurons that receives processed information and

sends output signals out of the system.

The figure below shows an example of a multilayer feed forward neural network. The

figure also shows in detail the various components that make up the individual neurons and

how data flows through the network. It can also be seen that each of the two layers uses

different transfer functions which are discussed in greater detail in the following paper.

204

Figure 25: Example of Multilayer Feed Forward Neural Network

8.2. ARTIFICIAL NEURON:

An artificial neuron is the basic element of a neural network. It consists of four basic

components that include inputs and outputs, weighting factors, bias, and activation

function. The diagram below shows the basic elements of a neuron.

Figure 26: Basic Elements of a Neuron

Neurons basically consist of inputs, which are multiplied by weights (strength of the

respective signals), and then computed by a mathematical function which determines the

activation of the neuron. Another function (which may be the identity) computes the output

of the artificial neuron (sometimes in dependence of a certain threshold). Bias values allow

205

a neural network to output a value of zero even when the input is near one. Adding a bias

allows the output of the activation function to be shifted to the left or right on the x-axis.

ANNs combine artificial neurons in order to process information.

The higher a weight of an artificial neuron is, the stronger the input which is multiplied by

it will be. Weights can also be negative, so we can say that the signal is inhibited by the

negative weight. Depending on the weights, the computation of the neuron will be

different. By adjusting the weights of an artificial neuron we can obtain the output we want

for specific inputs. But when we have an ANN of hundreds or thousands of neurons, it

would be quite complicated to find by hand all the necessary weights. But we can find

algorithms which can adjust the weights of the ANN in order to obtain the desired output

from the network. This process of adjusting the weights is called learning or training.

8.3. BACK PROPAGATION ALGORITHM:

The backpropagation algorithm is used in layered feed-forward ANNs. This means that the

artificial neurons are organized in layers, and send their signals “forward”, and then the

errors are propagated backwards. The network receives inputs by neurons in the input layer,

and the output of the network is given by the neurons on an output layer. There may be one

or more intermediate hidden layers. The backpropagation algorithm uses supervised

learning, which means that we provide the algorithm with examples of the inputs and

outputs we want the network to compute, and then the error (difference between actual and

expected results) is calculated. The idea of the backpropagation algorithm is to reduce this

error, until the ANN learns the training data. The training begins with random weights, and

the goal is to adjust them so that the error will be minimal.

8.4. SOFT SENSOR FOR THE NAPHTHA REFORMING

INDUSTRY:

Gasoline octane number is the standard measure of the anti-knock properties of a motor in

platforming processes, which is one of the important unit operations for oil refineries and

can be determined with online measurement or use (Cooperative Fuel Research) engines.

206

Online measurements of the octane number can be done using direct octane number

analyzers that are often expensive so instead soft sensors can be a more feasible option.

The number of input neurons corresponds to the number of input variables into the neural

network, and the number of output neurons is the same as the number of desired output

variables. The number of neurons in the hidden layer depends on the application of the

network. In the following paper we have fit an artificial neural network model to the

industrial data of the reforming process in order to predict the research octane number

(RON) of the reformate formed. The figure below shows the basic structure of our

multilayer feedforward neural network.

Figure 26: Basic Structure of Multilayer Feed Forward Neural Network to calculate RON

As the above figure shows we have an ANN that has three input values. These are the

weighted average inlet temperature of the reactor system (WAIT), the hydrogen to

hydrocarbon ratio and the product separator (flash separator) temperature (PST). The

output layer consists of one neuron that gives us the predicted octane number (RON) based

on the process conditions mentioned previously. The hidden layer consists of 15 neurons

and all of the layers are interconnected as described already.

207

We designed the soft sensor using MATLAB. In addition to building the soft sensor, we

also used boosting technique to improve the results and accuracy of the soft sensor.

Boosting is a general method for improving the performance of learning algorithms.

Boosting is a machine learning ensemble algorithm for reducing bias primarily and also

variance in supervised learning, and a family of machine learning algorithms which convert

weak learners to strong ones. A weak learner is defined to be a classifier which is only

slightly correlated with the true classification. In contrast, a strong learner is a classifier

that is arbitrarily well-correlated with the true classification. In machine learning, ensemble

averaging is the process of creating multiple models and combining them to produce a

desired output, as opposed to creating just one model. Frequently an ensemble of models

performs better than any individual model, because the various errors of the models

"average out."

8.5. PROCEDURE FOR DESIGNING THE ARTIFICIAL NUERAL

NETWORK:

The procedure for designing our ANN is discussed stepwise in detail below. In

MATLAB when designing a neural, it is essential to follow the following seven primary

steps.

1. Collect data

2. Create the network

3. Configure the network

4. Initialize the weights and biases

5. Train the network

6. Validate the network (post-training analysis)

7. Use the network

208

Each of the steps with respect to design of our soft sensor is discussed in detail below:

1. Collect Data

Before beginning the network design process, you first collect and prepare sample

data. It is generally difficult to incorporate prior knowledge into a neural network,

therefore the network can only be as accurate as the data that are used to train the

network. It is important that the data cover the range of inputs for which the network

will be used. Multilayer networks can be trained to generalize well within the range

of inputs for which they have been trained. However, they do not have the ability

to accurately extrapolate beyond this range, so it is important that the training data

span the full range of the input space.

The table below shows some of the data that we used to build our soft sensor.

209

2. Create the network

After the data has been collected, the next step in training a network is to create the

network object. The function “newff” creates a multilayer feedforward

backpropagation network. The function “newff” can be modelled using the

command:

net= newff (PR, [S1 S2 SN], [TF1 TF2 TFN], BTF, BLF, PF)

PR: RX2 matrix of min and max values for R input elements

SN: Size of the nth layer

TF: Transfer function of the nth layer

BTF: Backpropagation network training function

BLF: Backpropagation weight/bias learning function

PF: Performance measure

In our model we have used the log-sigmoid transfer function for the first layer and

purelin (linear) transfer function for the second layer. Both of the functions are

briefly described below.

Log-Sigmoid transfer function:

The sigmoid transfer function shown below takes the input, which may have any

value between plus and minus infinity, and squashes the output into the range 0 to

1. This transfer function is commonly used in backpropagation networks, in part

because it is differentiable. The function is represented as:

𝑓(𝑛) = 1

1 + 𝑒−𝑛

210

The linear (purelin) transfer function:

The function purelin is a neural transfer function. Linear transfer functions calculate

a layer's output from its net input.

3. Configure the network

The configure command configures the network object and also initializes the

weights and biases of the network; therefore the network is ready for training. There

are times when you might want to reinitialize the weights, or to perform a custom

initialization. Initializing weights function init details the initialization process.

You can also skip the configuration step and go directly to training the network.

The train command will automatically configure the network and initialize the

weights.

4. Initialize the weights and biases

Before training a feedforward network, you must initialize the weights and biases.

The configure command automatically initializes the weights, but you might want

to reinitialize them. You do this with the init command. This function takes a

network object as input and returns a network object with all weights and biases

initialized. Here is how a network is initialized (or reinitialized):

net = init(net);

211

5. Train the network

When the network weights and biases are initialized, the network is ready for

training. The multilayer feedforward network can be trained for function

approximation (nonlinear regression) or pattern recognition. The training process

requires a set of examples of proper network behavior—network inputs p and target

outputs t.

The process of training a neural network involves tuning the values of the weights

and biases of the network to optimize network performance. The default

performance function for feedforward networks is mean square error “mse”—the

average squared error between the network outputs a and the target outputs t.

In our particular case, we use the Levenberg-Marquardt backpropagation (trainlm)

function. trainlm is often the fastest backpropagation algorithm in the toolbox, and

is highly recommended as a first-choice supervised algorithm, although it does

require more memory than other algorithms.

In addition to this, since we are using a boosting technique in order to increase the

efficacy of our sensor. We are using the fitensemble syntax used in MATLAB to

boost our regression model.

Ensemble = fitensemble (X,Y,Method,NLearn,Learners)

Where:

X: Matrix of predictor values.

Y: Y is a numeric column vector with the same number of rows as X. Each entry

in Y is the response to the data in the corresponding row of X.

Method: ‘LSBoost’ (Boosting technique)

NLearn: Number of ensemble learning cycles.

Learners: ‘Tree’

212

6. Validate the network (post-training analysis)

After training is complete, we can check the network performance and determine if

any changes need to be made to the training process, the network architecture, or

the data sets. The summary of the results achieved can be seen below:

Figure 27: Summary of Soft Sensor Results

213

The performance results are shown below:

Figure 28: Performance Results of the Soft Sensor

214

The regression model of our neural network that predicts the RON of catalytic

naphtha reformate is shown below:

Figure 29: Regression Model of the Neural Network

215

The generalization error of a machine learning model is a function that measures

how well a learning machine generalizes to unseen data. It is measured as the

distance between the error on the training set and the test set and is averaged over

the entire set of possible training data that can be generated after every iteration of

the learning process. The plot for the generalization error for our model is shown

below:

Figure 30: Generalization Error

216

7. Use the network

The network that we designed has the ability of taking in three process conditions

that we have specified namely, the weighted average inlet temperature, hydrogen

to hydrocarbon ration and the product separator temperature, to accurately predict

the research octane number of the reformate used. This soft sensor can be used in

any refinery in the world. However, in order to increase the accuracy, each refinery

should build its own database of the process conditions and its respective RON in

order to cater to the inaccuracies that may arise due to the varying process flows.

In addition to this, further data can be added such as pressure, flowrates etc. to see

how they affect the RON of reformate. The possibilities of how many variables can

be observed and their effects on RON are endless. Soft sensors such as this can be

used by refineries across the globe to increase yields and octane number without

having to change anything real time. The process conditions that lead to optimum

yield and quality can be easily predicted helping petroleum industries save

resources, time and most of all, money.

217

CHAPTER 9: COSTING AND

INVESTMENT ANALYSIS

218

9.1. EXECUTIVE SUMMARY

PROJECT NAME: FYP FlowsheetCost

CAPACITY: 3573545195 LB/Year

REFORM @ 0.753 USD/LB

SCHEDULE: ---------------------------------------------------------------------------------------

Start Date for Engineering 1-Jan-16

Duration of EPC Phase 47 Weeks

Completion Date for Construction 2-Dec-16

Length of Start-up Period 20 Weeks

INVESTMENT: ---------------------------------------------------------------------------------------

Currency Conversion Rate 1 USD/U.S. DOLLAR

Total Project Capital Cost 41,490,500.00 USD

Total Operating Cost 2,282,440,000.00 USD/Year

Total Raw Materials Cost 2,047,680,000.00 USD/Year

Total Utilities Cost 63,188,800.00

Total Product Sales 2,874,280,000.00 USD/Year

Desired Rate of Return 20.00 Percent/'Year

P.O. Period 3.32 Year

PROJECT INFORMATION: ---------------------------------------------------------------------------------------

Economic Analysis Type IPE

Version 30.0.0

System Cost Base Date 1Q 13

Project Type Grass roots/Clear field

Design code ASME

Prepared By Nimrah Anwar, Mustafa Hassan, Haider Ali Khan

NOTES:----------------------------------------------------- ---------------------------------------------------------------------------------------

9.2. RUN SUMMARY

Project Name EPC Duration

Project Capital Cost Operating Cost IRR

FYP FlowsheetCost 47 41,490,500.00 2,282,440,000.00 78.9351

219

9.3. CASH FLOW

ITEM UNITS

TW (Number of Weeks per Period) Weeks/period 52.00

T (Number of Periods for Analysis) Period 20.00

DTEPC (Duration of EPC Phase) Period 0.90

DT (Duration of EPC Phase and Startup) Period 1.29

WORKP (Working Capital Percentage) Percent/period 5.00

OPCHG (Operating Charges) Percent/period 25.00

PLANTOVH (Plant Overhead) Percent/period 50.00

CAPT (Total Project Cost) Cost 41,490,500.00

RAWT (Total Raw Material Cost) Cost/period 2,047,680,000.00

PRODT (Total Product Sales) Cost/period 2,874,280,000.00

OPMT (Total Operating Labor and Maintenance Cost) Cost/period 1,497,890.00

UTILT (Total Utilities Cost) Cost/period 63,188,800.00

ROR (Desired Rate of Return/Interest Rate) Percent/period 20.00

AF (ROR Annuity Factor) 5.00

TAXR (Tax Rate) Percent/period 40.00

IF (ROR Interest Factor) 1.20

ECONLIFE (Economic Life of Project) Period 10.00

SALVAL (Salvage Value (Percent of Initial Capital Cost)) Percent 20.00

DEPMETH (Depreciation Method) Straight Line

DEPMETHN (Depreciation Method Id) 1.00

ESCAP (Project Capital Escalation) Percent/period 5.00

ESPROD (Products Escalation) Percent/period 5.00

ESRAW (Raw Material Escalation) Percent/period 3.50

ESLAB (Operating and Maintenance Labor Escalation) Percent/period 3.00

ESUT (Utilities Escalation) Percent/period 3.00

START (Start Period for Plant Startup) Period 1.00 PODE (Desired Payout Period (excluding EPC and Startup Phases)) Period

POD (Desired Payout Period) Period

DESRET (Desired Return on Project for Sales Forecasting) Percent/Period 10.50

END (End Period for Economic Life of Project) Period 10.00

GA (G and A Expenses) Percent/Period 8.00

DTEP (Duration of EP Phase before Start of Construction) Period 0.54

OP (Total Operating Labor Cost) Cost/period 1,008,090.00

MT (Total Maintenance Cost) Cost/period 489,800.00

220

9.3.1. Sales Over a Period of 20 Years

Sales Year 1.00 2.00

SP (Products Sales) Cost/Period - 2,254,790,000.00

SPF (Forecasted Sales Annuity Factor) - -

SF (Forecasted Sales) Cost/Period - -

S (Total Sales) Cost/Period - 2,254,790,000.00


SP (Products Sales) Cost/Period 3,327,340,000.00

3,493,710,000.00



S (Total Sales) Cost/Period 3,327,340,000.00

3,493,710,000.00



3,851,810,000.00




3,851,810,000.00



4,246,620,000.00




4,246,620,000.00



4,681,900,000.00




4,681,900,000.00

221



5,161,800,000.00




5,161,800,000.00



5,690,880,000.00




5,690,880,000.00



6,274,190,000.00




6,274,190,000.00



6,917,300,000.00




6,917,300,000.00



7,626,320,000.00




7,626,320,000.00

222

9.3.2. Expenses Over a Period of 20 Years

Expenses Year 1.00 2.00

Un-escalated Cumulative Capital Cost Cost/Period

41,490,500.00

41,490,500.00

Capital Cost Cost/period

Cumulative Capital Cost Cost/period 43,565,100.00

43,565,100.00

Expenses Year 3.00 4.00 Un-escalated Cumulative Capital Cost Cost/Period - -

Capital Cost Cost/period - -

Cumulative Capital Cost Cost/period 43,565,100.00 43,565,100.00

Expenses Year

5.00 6.00 Un-escalated Cumulative Capital Cost Cost/Period - -






43,565,100.00




Expenses Year 11.00 12.00

Un-escalated Cumulative Capital Cost Cost/Period - -



223







43,565,100.00




Expenses Year 19.00

20.00

Un-escalated Cumulative Capital Cost Cost/Period - -



224

9.3.3. Costs Over a Period of 20 Years

Costs Year 1.00 2.00

OP (Operating Costs) Cost/Period

227,112,000.00

2,444,270,000.00

Raw Materials Cost/period

203,783,000.00

2,193,520,000.00

Operating Labor Cost Cost/period

99,839.70

1,069,480.00

Maintenance Cost Cost/period

48,509.10

519,629.00

Utilities Cost/period

6,258,120.00

67,037,000.00

Operating Charges Cost/period

24,959.90

267,371.00

Plant Overhead Cost/period

74,174.40

794,556.00

Subtotal Operating Costs

Cost/period

210,289,000.00

2,263,210,000.00

G and A Costs Cost/period

16,823,100.00

181,057,000.00



2,529,440,000.00

2,617,590,000.00


2,270,300,000.00

2,349,760,000.00


1,101,570.00

1,134,610.00

Maintenance Cost Cost/period 535,218.00

551,274.00


69,048,100.00

71,119,500.00

Operating Charges Cost/period 275,392.00

283,654.00

Plant Overhead Cost/period 818,393.00

842,944.00


Cost/period

2,342,080,000.00

2,423,690,000.00


187,366,000.00

193,895,000.00

225



2,708,800,000.00

2,803,200,000.00


2,432,000,000.00

2,517,120,000.00


1,168,650.00

1,203,710.00


567,813.00

584,847.00


73,253,100.00

75,450,700.00


292,163.00

300,928.00


868,233.00

894,280.00


Cost/period

2,508,150,000.00

2,595,550,000.00


200,652,000.00

207,644,000.00



2,900,890,000.00

3,001,980,000.00


2,605,220,000.00

2,696,400,000.00


1,239,820.00

1,277,020.00


602,393.00

620,464.00


77,714,200.00

80,045,700.00


309,956.00

319,255.00


921,108.00

948,741.00


Cost/period

2,686,010,000.00

2,779,610,000.00


214,880,000.00

222,369,000.00

226



3,106,600,000.00

3,214,870,000.00


2,790,780,000.00

2,888,450,000.00


1,315,330.00

1,354,790.00


639,078.00

658,251.00


82,447,000.00

84,920,400.00


328,832.00

338,697.00


977,204.00

1,006,520.00


Cost/period

2,876,480,000.00

2,976,730,000.00


230,119,000.00

238,138,000.00



3,326,910,000.00

3,442,860,000.00


2,989,550,000.00

3,094,180,000.00


1,395,430.00

1,437,300.00


677,998.00

698,338.00


87,468,100.00

90,092,100.00


348,858.00

359,324.00


1,036,720.00

1,067,820.00


Cost/period

3,080,480,000.00

3,187,840,000.00


246,438,000.00

255,027,000.00

227



3,562,860,000.00

3,687,040,000.00


3,202,480,000.00

3,314,570,000.00


1,480,410.00

1,524,830.00


719,288.00

740,867.00


92,794,900.00

95,578,700.00


370,104.00

381,207.00


1,099,850.00

1,132,850.00


Cost/period

3,298,940,000.00

3,413,920,000.00


263,915,000.00

273,114,000.00



3,815,550,000.00

3,948,540,000.00


3,430,580,000.00

3,550,650,000.00


1,570,570.00

1,617,690.00


763,093.00

785,986.00


98,446,100.00

101,399,000.00


392,643.00

404,422.00


1,166,830.00

1,201,840.00


Cost/period

3,532,910,000.00

3,656,050,000.00


282,633,000.00

292,484,000.00

228



4,086,170,000.00

4,228,600,000.00


3,674,920,000.00

3,803,540,000.00


1,666,220.00

1,716,210.00


809,565.00

833,852.00


104,441,000.00

107,575,000.00


416,555.00

429,051.00


1,237,890.00

1,275,030.00


Cost/period

3,783,490,000.00

3,915,370,000.00


302,679,000.00

313,230,000.00



4,376,000,000.00

4,528,530,000.00


3,936,660,000.00

4,074,450,000.00


1,767,690.00

1,820,720.00


858,868.00

884,634.00


110,802,000.00

114,126,000.00


441,923.00

455,181.00


1,313,280.00

1,352,680.00


Cost/period

4,051,850,000.00

4,193,090,000.00


324,148,000.00

335,447,000.00

229

9.3.4. Revenue Over a Period of 20 Years

Revenue Year 1.00 2.00

R (Revenue) Cost/Period (272,855,000.00)

(189,479,000.00)

DEP (Depreciation Expense) Cost/Period 3,319,240.00

3,319,240.00

E (Earnings Before Taxes) Cost/Period (276,175,000.00)

(192,798,000.00)

TAX (Taxes) Cost/Period - -

NE (Net Earnings) Cost/Period (276,175,000.00)

(192,798,000.00)

TED (Total Earnings) Cost/Period (272,855,000.00)

(189,479,000.00) TEX (Total Expenses (Excludes Taxes and Depreciation)) Cost/Period 272,855,000.00

2,444,270,000.00

CF (CashFlow for Project) Cost/Period (272,855,000.00)

(189,479,000.00)

Revenue Year 3.00

4.00

R (Revenue) Cost/Period 797,897,000.00

876,121,000.00


3,319,240.00

E (Earnings Before Taxes) Cost/Period 794,578,000.00

872,802,000.00

TAX (Taxes) Cost/Period 317,831,000.00

349,121,000.00

NE (Net Earnings) Cost/Period 476,747,000.00

523,681,000.00

TED (Total Earnings) Cost/Period 480,066,000.00

527,000,000.00 TEX (Total Expenses (Excludes Taxes and Depreciation)) Cost/Period 2,529,440,000.00

2,617,590,000.00

CF (CashFlow for Project) Cost/Period 480,066,000.00

527,000,000.00

230

Revenue Year 5.00

6.00

R (Revenue) Cost/Period 959,590,000.00

1,048,610,000.00


3,319,240.00

E (Earnings Before Taxes) Cost/Period 956,271,000.00

1,045,290,000.00


418,117,000.00


627,176,000.00



2,803,200,000.00


630,495,000.00

Revenue Year 7.00

8.00

R (Revenue) Cost/Period 1,143,510,000.00

1,244,640,000.00


3,319,240.00

E (Earnings Before Taxes) Cost/Period 1,140,200,000.00

1,241,320,000.00


496,528,000.00


744,793,000.00



3,001,980,000.00


748,112,000.00

231

Revenue Year 9.00

10.00


1,467,030,000.00


3,319,240.00


1,463,710,000.00


585,485,000.00


878,227,000.00



3,214,870,000.00


891,919,000.00

Revenue Year 11.00

12.00


1,718,930,000.00

DEP (Depreciation Expense) Cost/Period


1,718,930,000.00


687,572,000.00


1,031,360,000.00


1,031,360,000.00 TEX (Total Expenses (Excludes Taxes and Depreciation)) Cost/Period 3,326,910,000.00

3,442,860,000.00

232

Revenue Year 13.00

14.00


2,003,840,000.00



2,003,840,000.00


801,536,000.00

NE (Net Earnings) Cost/Period 1,114,220,000.00

1,202,300,000.00

TED (Total Earnings) Cost/Period 1,114,220,000.00


3,687,040,000.00

Revenue Year 15.00

16.00


2,325,650,000.00



2,325,650,000.00


930,262,000.00


1,395,390,000.00



3,948,540,000.00

233

Revenue Year 17.00

18.00


2,688,700,000.00



2,688,700,000.00

TAX (Taxes) Cost/Period 1,000,690,000.00

1,075,480,000.00


1,613,220,000.00



4,228,600,000.00

Revenue Year 19.00

20.00


3,097,790,000.00



3,097,790,000.00

TAX (Taxes) Cost/Period 1,154,870,000.00

1,239,120,000.00


1,858,670,000.00



4,528,530,000.00

234

9.3.5. Cashflow Over a Period of 20 Years

Cashflow Year -

FVI (Future Value of Cumulative Cash Inflows) Cost/Period -

PVI (Present Value of Cumulative Cash Inflows) Cost/Period -

PVOS (Present Value of Cumulative Cash Outflows, Sales) Cost/Period - PVOP (Present Value of Cumulative Cash Outfows, Products) Cost/Period -

PVO (Present Value of Cumulative Cash Outfows) -

PV (Present Value of Cash Flows) Cost/Period -

NPV (Net Present Value) Cost/Period -

IRR (Internal Rate of Return) Percent 78.94

MIRR (Modified Internal Rate of Return) Percent 21.40

NRR (Net Return Rate) Percent 12.35

Cashflow Year 1.00 2.00

FVI (Future Value of Cumulative Cash Inflows) Cost/Period - 2,254,790,000.00

PVI (Present Value of Cumulative Cash Inflows) Cost/Period - 1,565,830,000.00

PVOS (Present Value of Cumulative Cash Outflows, Sales) Cost/Period - - PVOP (Present Value of Cumulative Cash Outfows, Products) Cost/Period 227,380,000.00

1,924,790,000.00

PVO (Present Value of Cumulative Cash Outfows) 227,380,000.00 1,924,790,000.00

PV (Present Value of Cash Flows) Cost/Period (227,380,000.00)

(131,583,000.00)

NPV (Net Present Value) Cost/Period (227,380,000.00)

(358,962,000.00)


FVI (Future Value of Cumulative Cash Inflows) Cost/Period 6,033,090,000.00

10,733,400,000.00

PVI (Present Value of Cumulative Cash Inflows) Cost/Period 3,491,370,000.00

5,176,220,000.00

PVOS (Present Value of Cumulative Cash Outflows, Sales) Cost/Period - - PVOP (Present Value of Cumulative Cash Outfows, Products) Cost/Period

3,572,520,000.00

5,003,220,000.00

PVO (Present Value of Cumulative Cash Outfows) 3,572,520,000.00

5,003,220,000.00

PV (Present Value of Cash Flows) Cost/Period 277,816,000.00

254,148,000.00

NPV (Net Present Value) Cost/Period (81,146,200.00)

173,001,000.00

235


FVI (Future Value of Cumulative Cash Inflows) Cost/Period 16,548,500,000.00 23,710,000,000.00

PVI (Present Value of Cumulative Cash Inflows) Cost/Period 6,650,460,000.00 7,940,430,000.00 PVOS (Present Value of Cumulative Cash Outflows, Sales) Cost/Period - - PVOP (Present Value of Cumulative Cash Outfows, Products) Cost/Period 6,245,550,000.00 7,324,360,000.00

PVO (Present Value of Cumulative Cash Outfows) 6,245,550,000.00 7,324,360,000.00

PV (Present Value of Cash Flows) Cost/Period 231,916,000.00 211,152,000.00

NPV (Net Present Value) Cost/Period 404,918,000.00 616,069,000.00



43,242,300,000.00


10,056,800,000.00


8,261,230,000.00

9,074,870,000.00


9,074,870,000.00


173,987,000.00

236



115,175,000,000.00


12,917,700,000.00


10,928,600,000.00

11,391,900,000.00


11,391,900,000.00


115,674,000.00



178,047,000,000.00


13,867,500,000.00


11,794,300,000.00

12,143,900,000.00


12,143,900,000.00


93,643,400.00



72,301,500,000.00


11,677,100,000.00


9,781,530,000.00

10,395,300,000.00


10,395,300,000.00


142,375,000.00

NPV (Net Present Value) Cost/Period 1,139,420,000.00

1,283,470,000.00

237



403,382,000,000.00


15,151,400,000.00


12,940,800,000.00

13,140,000,000.00


13,140,000,000.00


60,594,200.00



597,212,000,000.00


15,577,700,000.00


13,313,100,000.00

13,463,600,000.00


13,463,600,000.00


48,481,700.00

Cashflow Year 15.00 16.00 FVI (Future Value of Cumulative Cash Inflows) Cost/Period

219,632,000,000.00

269,832,000,000.00

PVI (Present Value of Cumulative Cash Inflows) Cost/Period

14,255,300,000.00

14,594,700,000.00


12,447,600,000.00

12,711,500,000.00

PVO (Present Value of Cumulative Cash Outfows)

12,447,600,000.00

12,711,500,000.00


75,473,900.00

238

9.4. PROJECT SUMMARY ************************************************************************

PROJECT INFORMATION

Project Name FYP FlowsheetCost

Project Description Catalytic Naphtha Reformer

Economic Analysis Type IPE ************************************************************************

CAPITAL COST EVALUATION BASIS

Date 42,155.00

Units of Measure I-P

Currency (Cost) Symbol U.S. DOLLAR

Currency Conversion Rate USD 1.00

************************************************************************

TIME PERIOD

Period Description Year

Operating Hours per Period Hours/period 8,766.00

Number of Weeks per Period Weeks/period 52.00

Number of Periods for Analysis Period 20.00

************************************************************************

SCHEDULE

Start Date for Engineering 41,275.00

Duration of EPC Phase Weeks 47.00

Length of Start-up Period Weeks 20.00

Duration of Construction Phase Weeks 19.00

************************************************************************

239

CAPITAL COSTS PARAMETERS

Working Capital Percentage Percent/period 5.00

************************************************************************

OPERATING COSTS PARAMETERS

Operating Supplies (lump-sum) Cost/period -

Laboratory Charges (lump-sum) Cost/period -

User Entered Operating Charges (as percentage) Percent/period 25.00

Operating Charges (Percent of Operating Labor Costs) Percent/period 25.00

Plant Overhead (Percent of Operating Labor and Maintenance Costs)

Percent/period 50.00

G and A Expenses (Percent of Subtotal Operating Costs) Percent/period 8.00

************************************************************************

GENERAL INVESTMENT PARAMETERS

Tax Rate Percent/period 40.00

Interest Rate Percent/period 20.00

Economic Life of Project Period 10.00

Salvage Value (Fraction of Initial Capital Cost) Percent 20.00

Depreciation Method Straight Line

************************************************************************

240

ENGINEERING SUMMARY Cost Manhours

Basic Engineering 716,300.00 6,476.00

Detail Engineering 1,452,300.00 13,688.00

Material Procurement 548,000.00

Home Office 124,300.00 1,262.00

Total Design, Eng, Procurement Cost 2,840,900.00

************************************************************************

ESCALATION

Project Capital Escalation Percent/period 5.00

Products Escalation Percent/period 5.00

Raw Material Escalation Percent/period 3.50

Operating and Maintenance Labor Escalation Percent/period 3.00

Utilities Escalation Percent/period 3.00

************************************************************************

PROJECT RESULTS SUMMARY

Total Project Capital Cost Cost 41,490,500.00

Total Raw Materials Cost Cost/period 2,047,680,000.00

Total Products Sales Cost/period 2,874,280,000.00

Total Operating Labor and Maintenance Cost Cost/period 1,497,890.00

Total Utilities Cost Cost/period 63,188,800.00

Total Operating Cost Cost/period 2,282,440,000.00

Operating Labor Cost Cost/period 1,008,090.00

Maintenance Cost Cost/period 489,800.00

Operating Charges Cost/period 252,023.00

Plant Overhead Cost/period 748,945.00

Subtotal Operating Cost Cost/period 2,113,370,000.00

G and A Cost 169,069,000.00

************************************************************************

241

RAW MATERIALS COSTS AND PRODUCTS SALES

Raw Materials Cost per Hour Cost/Hour 233,593.00

Total Raw Materials Cost Cost/Period 2,047,680,000.00

Products Sales per Hour Cost/Hour 327,890.00

Total Products Sales Cost/Period 2,874,280,000.00

Main Product Name REFORM

Main Product Rate LB/H 407,660.00

Main Product Unit Cost USD/LB 0.75

Main Product Production Basis LB

Main Product Rate per Period LB/Year 3,573,550,000.00

Main Product Sales USD/Year 2,690,290,000.00

By-product Sales USD/Year 183,994,000.00

************************************************************************

OPERATING LABOR AND MAINTENANCE COSTS

Operating Labor

Operators per Shift 4.00

Unit Cost Cost/Operator/H 20.00

Total Operating Labor Cost Cost/period 701,280.00

Maintenance

Cost/8000 Hours 447,000.00

Total Maintenance Cost Cost/period 489,800.00

Supervision

Supervisors per Shift 1.00

242

Unit Cost Cost/Supervisor/H 35.00

Total Supervision Cost Cost/period 306,810.00 PROJECT CAPITAL SUMMARY Total Cost

Design, Eng, Procurement

Purchased Equipment Cost 19,891,600.00

Equipment Setting Cost 327,564.00

Piping Cost 2,366,970.00

Civil Cost 439,483.00

Steel Cost 95,381.20

Instrumentation Cost 1,770,590.00

Electrical Cost 675,317.00

Insulation Cost 507,805.00

Paint Cost 69,928.40

Other Cost 7,488,600.00

2,840,900.00

Subcontracts Cost -

G and A Overheads Cost 923,770.00 -

Contract Fee Cost 1,039,660.00

167,613.00

Escalation Cost - -

Contingencies Cost 6,407,400.00

541,532.00

-

Total Project Cost Cost 42,004,100.00

Adjusted Total Project Cost Cost 41,490,500.00

243

PROJECT CAPITAL SUMMARY

Construction Material

Construction Manhours

Purchased Equipment Cost 19,891,600.00


Piping Cost 1,831,110.00

17,797.00


7,043.00

Steel Cost 81,275.0 499.00

Instrumentation Cost 1,577,960.00

6,290.00


3,828.00


10,752.00

Paint Cost 23,006.90 2,098.00

Other Cost 2,511,000.00

Subcontracts Cost

G and A Overheads Cost 810,262.00

Contract Fee Cost 556,380.00

Escalation Cost -

Contingencies Cost 5,107,570.00


Construction Manpower Construction Indirects

Purchased Equipment Cost


Piping Cost 535,860.00



Instrumentation Cost 192,627.00




Other Cost 2,136,700.00

Subcontracts Cost

G and A Overheads Cost 49,406.70 64,101.00

Contract Fee Cost 137,400.00 178,265.00

Escalation Cost - -

Contingencies Cost 330,066.00 428,232.00

244


Construction Manpower Construction Indirects

Purchased Equipment Cost


Piping Cost 535,860.00



Instrumentation Cost 192,627.00




Other Cost 2,136,700.00

Subcontracts Cost

G and A Overheads Cost 49,406.70 64,101.00

Contract Fee Cost 137,400.00 178,265.00

Escalation Cost - -

Contingencies Cost 330,066.00 428,232.00

245

9.5. EQUIPMENT COST

Component Name

Component Type

Total Direct Cost

Equipment Cost

Equipment Weight

Installed Weight

(USD) (USD) LBS LBS

G-2 DGC CENTRIF 1,682,500.00

1,567,700.00

23,700.00

34,278.00

E-2 DHE TEMA EXCH

574,200.00

219,200.00

76,000.00

118,977.00

B10 DCP CENTRIF 61,200.00

10,900.00 910.00

9,709.00

B1 EFU BOX 11,004,900.00

10,284,400.00

1,644,300.00

1,738,610.00

B2 EFU BOX 1,925,500.00

1,359,800.00

246,000.00

302,344.00

B3 EFU BOX 1,127,800.00

511,400.00

75,400.00

128,545.00

B4 EFU BOX 4,326,400.00

3,511,800.00

587,600.00

676,732.00

B5-flash vessel DVT CYLINDER

207,000.00

77,700.00

38,900.00

59,935.00

E-12 DHE TEMA EXCH

610,700.00

397,500.00

132,600.00

190,961.00

E-4 DHE TEMA EXCH

49,200.00

8,100.00 460.00

4,004.00

E-5 DHE TEMA EXCH

62,100.00

10,200.00 1,200.00

8,372.00

E-6 DHE TEMA EXCH

63,200.00

11,300.00 1,400.00

8,580.00

E-9 DHE TEMA EXCH

91,600.00

23,500.00 5,900.00

17,910.00

F-3-flash vessel DVT CYLINDER

171,900.00

57,200.00

25,600.00

43,933.00

R1 DTW PACKED 435,400.00

216,500.00

16,300.00

45,663.00


224,200.00

17,400.00

47,805.00


228,200.00

18,500.00

49,946.00


293,700.00

23,600.00

58,449.00

F-2-flash vessel DVT CYLINDER

150,600.00

36,100.00

11,700.00

28,650.00

E-3 DHE TEMA EXCH

251,700.00

123,600.00

43,800.00

73,922.00

G-3 DCP CENTRIF 85,500.00

29,900.00 2,200.00

12,679.00

246

9.6. UTILITIES COST

Utilities

Description Item Code Rate Units Rate Units Cost per hr

Electricity DGC CENTRIF G-2 7.46 KW KWH 0.57815

Electricity DCP CENTRIF B10 29.84 KW KWH 2.3126

Electricity DCP CENTRIF G-3 55.95 KW KWH 4.336125

Cooling Water DHE TEMA EXCH E-2 1.168573 MMGAL MMGAL/H 140.22876



Steam @100PSI DHE TEMA EXCH E-5 1.865909 KLB KLB/H 15.188499



247

9.7. RAW MATERIAL

Raw Materials

Description Specification Basis Rate per hr Units Rate Units Cost per hr

NAP-HYD Mass Basis

515,072.77 LB LB/H

233,593.23

9.8. PRODUCTS

Products

Description Specification Basis Rate per hr Units

Rate Units Cost per hr

REFORM Mass Basis

407,659.73 LB LB/H

306,900.11

HP-RCY Mass Basis

107,397.86 LB LB/H

20,982.75

HYDROGEN Mass Basis 34.77 LB LB/H 6.79

248

CHAPTER 10: CONCLUSION AND

BIBLIOGRAPHY

249

10.1. CONCLUSION:

Our simulation is based on the latest kinetic research done on catalytic reforming

process allowing it to be applied to any refinery with minor modifications to the flow

diagram. It also includes the proposed optimization process that aims to conserve

energy by recycling heat energy through various heat exchangers. This optimization

can be customized according to any refinery based on their process design. In addition,

our soft sensor uses real time industrial data to predict the research octane number of

gasoline. The objectives achieved are all briefly discussed below:

Successful modelling and simulation of modern industrial catalytic naphtha

reformer on ASPEN PLUS is achieved with latest kinetic model consisting of

32 pseudo components and 84 reactions.

Designing of each of the equipment is done on Aspen Plus

Materials and energy balance is carried out on each component of the

simulation including reactors and flash separator.

A soft sensor is successfully developed on MATLAB that predicts RON of the

reformate.

Economic evaluation and costing of the process is also done.

Since this model is based on comprehensive kinetics of reforming reactions, it

can be applied to any catalytic reformer system with some modifications.

Acceptable agreement has been obtained between commercial values and

simulated results of the molar flow rate of pseudo components, operating

conditions and physical properties which indicate the acceptable prediction

ability of the lumped-kinetic model.

250

For future work, we aim to increase the accuracy of our simulation of the reforming

process by accounting for catalyst deactivation that occurs in the four reactors with

time. Furthermore, we aim to accurately model our flash separator (B-5) using

FOTRAN since its dynamics are rather unique and cannot be accurately modelled by

the general flash separator unit operation in Aspen Plus. Regarding the soft sensor, the

industrial data present was very limited.

Further data may be collected to train and validate the soft sensor (ANN) in order to

improve its reliability and accuracy. Soft sensors can also be customized to any refinery

by using its particular database to train the soft sensor. In addition to this, further

variables can be added to observe their effect on the research octane number such as

pressure, naphtha composition and so on. The artificial neural network can also be

trained on extended data to predict other outputs other than RON such as the gasoline

yield.

251

10.2. REFERENCES 1. Ancheyta J. Modeling and simulation of catalytic reactors for petroleum

refining. Oxford: Wiley-Blackwell, 2010.

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2004.

3. Arani H, Shokri S, Shirvani M. Dynamic Modeling and Simulation of

Catalytic Naphtha Reforming. International Journal of Chemical Engineering

and Applications (2010). doi: 10.7763/ijcea.2010.v1.28.

4. Askari A, Karimi H. SIMULATION AND MODELING OF CATALYTIC

REFORMING PROCESS. .

5. Aziz B, Jassim A. Modeling Of Industrial Catalytic Naphtha Reforming Plant

by Using Artificial Neural Network (ANN). Journal of Environmental

Science, Computer Science and Engineering & Technology 3: 2170-2185,

2015.

6. Beale M. Neural Network Toolbox Getting Started Guide [Online]. 1st ed.

MATLAB. http://es.mathworks.com/help/pdf_doc/nnet/nnet_gs.pdf [8 Jun.

2015].

7. Beale M. Neural Network Toolboxâ„¢ User's Guide [Online]. 1st ed.

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Jun. 2015].

8. Fogler H. Elements of chemical reaction engineering. Upper Saddle River,

N.J.: Prentice Hall PTR, 1999.

9. HOU W, SU H, HU Y, CHU J. Modeling, Simulation and Optimization of a

Whole Industrial Catalytic Naphtha Reforming Process on Aspen Plus

Platform. Chinese Journal of Chemical Engineering 14: 584-591, 2006.

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10. Iranshahi D, Karimi M, Amiri S, Jafari M, Rafiei R, Rahimpour M. Modeling

of naphtha reforming unit applying detailed description of kinetic in

continuous catalytic regeneration process. Chemical Engineering Research

and Design 92: 1704-1727, 2014.

11. Mohaddecy R, Sadighi S. English. Kemija u industriji 63, 2014.

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process: A review. Applied Energy 109: 79-93, 2013.

14. Sa'idi M, Mostoufi N, Sotudeh-Gharebagh R. Modelling and optimisation of

continuous catalytic regeneration process using bee colony algorithm. Can J

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15. Schefflan R. Teach yourself the basics of Aspen Plus. Hoboken, NJ: Wiley

[u.a.], 2011.

16. Shakoor Z. CATALYTIC REFORMING OF HEAVY NAPHTHA,

ANALYSIS AND SIMULATION. Diyala Journal of Engineering Sciences 4:

86-104, 2011.

17. Stagni A, Cuoci A, Frassoldati A, Faravelli T, Ranzi E. Lumping and

Reduction of Detailed Kinetic Schemes: an Effective Coupling. Industrial &

Engineering Chemistry Research 53: 9004-9016, 2014.

18. Stijepovic M, Vojvodic-Ostojic A, Milenkovic I, Linke P. Development of a

Kinetic Model for Catalytic Reforming of Naphtha and Parameter Estimation

Using Industrial Plant Data. Energy Fuels 23: 979-983, 2009.

19. Taskar U, Riggs J. Modeling and optimization of a semiregenerative catalytic

naphtha reformer. AIChE J 43: 740-753, 1997.

20. Vathi G, Chaudhuri K. Modelling and simulation of commercial catalytic

naphtha reformers. Can J Chem Eng 75: 930-937, 1997.

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21. Vezvaei H, Ordibeheshti S. Soft-Sensor for Estimation of Gasoline Octane

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FYP Thesis

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