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Converting Waste Agricultural Biomass into Energy Source Report on Assessment of Environmentally Sound Technologies (ESTs) for Waste Agricultural Biomass (WAB) In District Sanghar, Pakistan By: Prof. Dr. Rasool Bux Mahar Institute of Environmental Engineering & Management Mehran University of Engineering & Technology Jamshoro, Pakistan United Nations Environmental Programme International Environmental Technology Centre Osaka/Shiga, Japan
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Converting Waste Agricultural Biomass into Energy … Waste Agricultural Biomass into Energy Source Report on Assessment of Environmentally Sound Technologies (ESTs) for Waste Agricultural

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  • Converting Waste Agricultural Biomass into Energy Source

    Report on

    Assessment of Environmentally Sound

    Technologies (ESTs) for

    Waste Agricultural Biomass (WAB)

    In District Sanghar, Pakistan

    By: Prof. Dr. Rasool Bux Mahar

    Institute of Environmental Engineering & Management Mehran University of Engineering & Technology

    Jamshoro, Pakistan

    United Nations Environmental Programme International Environmental Technology Centre

    Osaka/Shiga, Japan

  • 2

    PREFACE

    Rapid increase in demand and consumption of fossil fuels and its consequent

    impact on climate change and environment has put greater emphasis on development

    of alternative and renewable sources of energy. Waste biomass, as a renewable energy

    source, presents a viable solution for meeting our energy demands. It addresses the

    climate change issues as well as reduces our dependence on fossil fuels. In developing

    countries this could be developed as a versatile source of energy for domestic as well

    as industrial/commercial purposes.

    Biomass is a broad term, which generally refers to any plant or animal matter.

    The main categories of biomass are; agriculture residues (referred to hereafter as

    waste agricultural biomass), forestry residues, wood (both from forests and firewood

    plantations), animal residues, organic wastes from cities and dwellings. The

    discussions in this guideline pertain only to waste agricultural biomass.

    In this Report district Sanghar, which is one of the largest districts of province

    Sindh, Pakistan was selected as the study area for the assessment of the technology

    for converting waste agricultural biomass (WAB) into energy/ resource.

    This report is divided into three parts. Part- I is Introduction, Part- II is

    proposed environmentally sound technologies (ESTs) for converting WAB into

    energy/resource in Sanghar and Part- III is assessment of environmentally sound

    technologies.

  • 3

    TABLE OF CONTENTS Description Page

    Preface 2 Part- I INTRODUCTION 1.1 Biomass

    6

    1.2 Biomass Energy 7 1.3 Waste Agricultural Biomass (WAB) 7 1.3.1 Field residue 7 1.3.2 Process residue 7 1.4 Why To Use Waste Agricultural Biomass? 7 1.5 Study Area 8

    1.6 Environmentally Sound Technologies (ESTs) 10 1.7 Environmental Technology Assessment (EnTA) 10 1.8 Purpose and Scope EnTA 11 1.9 Criteria for Critical Analysis of EST

    11

    Part- II PROPOSED ENVIRONMENTALLY SOUND TECHNOLOGIES (ESTS) FOR CONVERTING WAB INTO ENERGY/RESOURCE IN SANGHAR

    2.1 Proposed Technologies for District Sanghar 14 2.2 Direct Combustion 14 2.3 Biomass Pellets 16 2.3.1 Description of the Pelleting Process 17 2.3.2 Feedstock Grinding 18 2.3.3 Moisture Control 18 2.3.4 Extrusion 18 2.3.5 Cooling 19 2.3.6 Packaging 19 2.4 Energy Requirements For Pellet Manufacture 19 2.6 Composting 19 2.7 Advantages Of Composting 21 2.8 Disadvantages Of Composting 21 2.9 Composting Systems 21 2.9.1 Windrow/pile Composting Turning 22 2.9.2 Windrow/pile Composting Active Aeration, 22 2.9.3 Windrow/pile Composting Passive Aeration, 23 2.9.4 Windrow/pile Composting Static Piles, not Aerated 23 2.9.5 In-vessel Composting 24 2.9.6 Vermi-composting 24

    2.10 Gasification 24 2.11 Principle Of Operation 24 2.12 History On Gasification 27 2.13 Types Of Gasifiers 27 2.13.1 Moving Bed Gasifier 27 2.13.2 Entrained Flow Gasifier 28 2.13.3 Fluidized Bed Gasifier 29

  • 4

    2.14 Common Biomass Feedstock For Gasification 29 2.14.1 Fuel-wood 29 2.14.2 Biomass Briquettes 30 2.14.3 Agriculture Residue 30 2.15 Advantages Of Gasification 30 2.16 Disadvantages Of Gasification 31 2.17 Anaerobic Digestion 31 2.18 Principle Of Operation 32 2.18.1 Hydrolysis 32 2.18.2 Acetogenesis 32 2.18.3 Methanogenesis 32 2.19 History Of Anaerobic Digestion 33 2.20 Energy Conversion 33 2.21 Conditions And Variables Influencing AD 34 2.23 TYPES OF DIGESTERS 36 2.24 Advantages Of Anaerobic Digestion 36 2.25 Disadvantages Of Anaerobic Digestion 37

    Part- III ASSESSMENT OF ENVIRONMENTALLY SOUND TECHNOLOGIES

    3.1 Problem Statement 40 3.2 Steps By Step Assessment of ESTs 45 3.2.1 Screening tier 45 3.2.2 Scoping tier 45 3.2.3 Detailed assessment tier 47 CONCLUSION & RECOMMENDATION 50

  • 5

    PART- I

    INTRODUCTION

  • 6

    PART- I

    INTRODUCTION

    1.1 BIOMASS

    The word biomass is the combination of two Bio, which is the prefix

    indicating the action of living organisms and the Mass, which is the matter in the

    body. Biomass is the mass of living organisms and recently dead matter like wood,

    leaves, stalks, straw and other organic matter. It is accessible on a renewable basis,

    and also includes agricultural crops and their residues, animal wastes (dung), wood

    and wood residues, aquatic plants and organic portion of the municipal solid waste

    (garbage). The basic step in the constitution of the biomass is photosynthesis, which

    can be symbolized as Eq. (1.1).

    OHOOHCkJOHCO lchlorophyl 22612622 662800126 ++ ++ (1.1)

    Photosynthesis is the chemical process, in which the small portion of the

    sunlight is absorbed by chlorophyll of green plant cells, which is consumed by it to

    generate carbohydrates (sugars) from water and carbon dioxide. Fig. 1.1 indicates the

    interaction of the solar energy and the biomass. Only green plants are capable of

    photosynthesis, where as other living organisms either consumes green plants or their

    by-products and generate biomass.

    Fig. 1.1: Interaction of sun and biomass during photosynthesis

  • 7

    1.2 BIOMASS ENERGY

    The energy obtained from the floras and their residues and faunas waste is

    known as biomass energy. In other words biomass energy is the accumulation of the

    solar energy into the animals, plants and their different types of wastes. By the

    definition of the biomass the fossil fuels do not considered as biomass energy, though

    their origin is biomass. One of the reasons is that the fossil fuels are not renewable

    source of energy; second they are long term decayed organisms forming after several

    million years under certain conditions of pressure, temperature, etc.

    1.3 WASTE AGRICULTURAL BIOMASS (WAB)

    The agricultural residues are referred as the Waste Agricultural Biomass,

    which may be assorted as field residues and process residues.

    1.3.1 Field residue

    It is the matter leftover in an agricultural field after the crop has been reaped

    e.g. leaves, straw, stalks, roots etc.

    1.3.2 Process residue

    It is the matter leftover after the processing of the crop at the mills or factories

    into a valuable resource e.g. husks, sugar cane fiber (bagasse), seeds, groundnut

    shells, maize cobs etc.

    1.4 WHY TO USE WASTE AGRICULTURAL BIOMASS?

    There are several social, economical and environmental benefits of the waste

    agricultural biomass to be uses as the fuel. Following are the few important points to

    be considered;

    The waste agricultural biomass is a clean, renewable source of energy, and is

    the replacement of a non-renewable energy sources.

    It is free from worldwide price variations and supply doubts, as it is domestic

    fuel and is available on the periodic basis, hence provides the energy security.

    The use of waste agricultural biomass can substantially reduce the carbon

    emissions if managed in a suitable manner. Its management includes

    collection, processing, transportation and use for energy recovery technology.

    It will enhance energy security by utilizing locally available resources mean

    while decreasing the dependency to the fossil fuels.

  • 8

    The proper consumption of waste agricultural biomass decreased green house

    gas (GHG) emissions, achieved by decreasing the open field burning and

    methane discharges due to decomposing of the WAB available into the field.

    It will reduce the problem of waste agricultural biomass management and

    disposal.

    In addition to the environmental benefits the proper utilization of the WAB

    can potentially increases the profit to the farmers/ landowners.

    Management of the WAB creates new job opportunities.

    1.5 STUDY AREA

    The area selected for UNEP project was Sanghar district, which is one of the

    largest districts of province Sindh, Pakistan. The district Sanghar lies between 25 to

    30 North latitudes and 70 to 13 East longitudes. From the Province map of Sindh

    by districts as in Fig. 1.2, it can be observed that the district Sanghar is bordered on

    the East by India, North by Khairpur District, North-west by Nawabshah district, and

    South by Tando Allahyar, Mirpurkhas and Umerkot districts and on the West by

    Matiari district. The total area of the district is about 2439704 Acres.

    Fig. 1.2: Map of Sindh Province by districts

  • 9

    The district Sanghar principally is an agrarian district except the large part of

    Taluka Khipro and some part of Taluka Sanghar, which comes on the left side of Nara

    Canal and is known as Thar Desert. The rest of the part of the district is very fertile.

    Wheat, Cotton, Sugarcane and Rice are main crops of the district. Groundnuts,

    Vegetables, Pulses, Maize, Bananas and many other crops are also grown there.

    District Sanghar has great importance due to Political, Economic and Cultural

    causes. There exist many small industries like cotton factories, flour mills, rice mills,

    oil mills, ice factories, match factories & only one large sugar mill. People of district

    Sanghar are very hospitable. The climate there in summer is dry and hot, where as in

    winter it is dry and cold. The temperature in the region ranges from 43C to 6C in

    summer and winter respectively. The district average out receives 12mm of the

    rainfall annually.

    The district Sanghar is administratively sub-divided into six Talukas; these are

    Sanghar, Sinjhoro, Shahdadpur, Tando Adam, Jam Nawaz Ali, and Khipro as shown

    in Fig. 1.3.

    Fig. 1.3: Map of district Sanghar by Taluka

    The total area, number of dehs, number of Union Councils and population of

    each Taluka of district Sanghar is given in Table 1.1. It is to be noted that the

    population for the year 2010 was estimated by using the growth rate of 2.47%

    between the censuses of 1981 and 1998 [District Profile (2005)]. There are total 59

  • 10

    union councils are in district Sanghar. In order to get the representative data, each of

    them was considered as a unit area for the survey.

    Table 1.1: Area and population of district Sanghar by Taluka

    S# Name of taluka Area (Acre)

    No of Dehs

    No of Union

    Councils

    Population by census

    1998

    Population in 2010

    01 Sanghar 590782 69 11 262050 362459

    02 Sinjhoro 217070 88 8 196849 272275

    03 Shahdadpur 108377 47 13 327408 452860

    04 Tando Adam 107688 28 10 255941 354009

    05 Jam Nawaz Ali 115021 51 4 88908 122975

    06 Khipro 1300766 78 13 321874 445206

    Total 2439704 361 59 1453030 2009784

    1.6 ENVIRONMENTALLY SOUND TECHNOLOGIES (ESTs)

    Environmentally Sound Technologies ESTs can be defined as those

    technologies that protect the environment, are less polluting, use all resources in a

    more sustainable manner, recycle more of their waste and products and handle

    residual waste in a more sustainable manner than the technologies for which they are

    substitutes.

    ESTs include a variety of cleaner production process and pollution prevention

    technologies, as well as end-of-pipe and monitoring technologies. Apart from just

    technologies, they can be considered as total systems that may include knowledge

    and skills transfer, operating procedures, goods, services and equipment, and also

    organizational and managerial procedures.

    1.7 ENVIRONMENTAL TECHNOLOGY ASSESSMENT (EnTA)

    EnTA is conceived as a system for technology assessment focusing on not just the

    environmental performance of the various processes and components of the technology,

    but also on its cultural and socio-economic consequences. Simply put, EnTA is a system

    to facilitate the identification and selection of the best possible technology option.

  • 11

    1.8 PURPOSE AND SCOPE OF EnTA

    EnTA targets planners, decision makers in the government and private sectors,

    communities through community leaders and community-based organizations, and

    other stakeholders to enable them to arrive at an informed consensus on the proposed

    technology intervention. More specifically, the purpose of EnTA for different users is

    as described below:

    Decision makers and managers in industry To identify/recognize

    environmental implications of the proposed technology intervention,

    potentially avoiding adverse financial and legal issues

    Development planners and government sector officials To identify and thus

    address implications of technology based development and integrate it in

    planning

    Community and non-government organizations To ensure that the rights and

    responsibilities of communities are given due consideration where technology-

    based development is being planned

    Stakeholders in sustainable development To enable citizens to ensure that

    environmental outcomes are recognized and suitable modifications are

    implemented for a more positive technology-based development

    1.9 CRITERIA FOR CRITICAL ANALYSIS OF EST

    The EST criteria begin with four basic requirements:

    1. Environmental soundness

    a. Protecting the environment

    b. Less polluting and handles wastes in a more acceptable manner

    c. Uses resources in a more sustainable manner

    d. Accepts by-products and wastes as inputs

    2. Economic viability

    a. Lesser capital costs

    b. Availability of financial incentives / rebates for raising capital

    c. Lesser operating and maintenance costs

    d. Leads to additional monetary savings from operation

  • 12

    3. Social and cultural acceptability

    a. Protects and enhances social aspects

    b. Culturally acceptable and/or enhancing

    4. Characterization (of technologies) by sufficient and verified information

  • 13

    PART- II

    PROPOSED ENVIRONMENTALLY SOUND

    TECHNOLOGIES (ESTs) FOR

    CONVERTING WAB INTO

    ENERGY/RESOURCE IN SANGHAR

  • 14

    2.1 PROPOSED TECHNOLOGIES FOR DISTRICT SANGHAR

    The following five technologies are proposed for converting Waste

    Agricultural Biomass (WAB) into energy/ material source:

    1. Direct Combustion

    2. Biomass Pellets

    3. Composting

    4. Gasification

    5. Anaerobic Digestion

    2.2 DIRECT COMBUSTION

    The simplest way, and oldest way, of generating electricity from biomass is to

    burn it. This is called direct combustion. Direct combustion systems burn biomass in

    boilers to produce high pressure steam. This steam turns a turbine connected to a

    generator. As the steam causes the turbine to rotate, the generator turns and electricity

    is produced. Most of the worlds biomass power plants use direct combustion. In

    some cases, the steam from the plants is also captured to heat water and buildings.

    These are known as cogeneration facilities. Direct combustion processes can be used

    to convert various raw fuel materials besides wood, including municipal garbage and

    crop wastes. If they burn woody materials, these commonly take the form of

    woodchips, bark or sawdust that originates as waste by-products of forest industries.

    Although this technology is dependable and proven, its efficiency is limited.

    Direct combustion systems typically have thermal efficiencies around 20 per cent.

    These efficiencies can be increased through cogeneration. Biomass cogeneration

    refers to the combustion of a mixture of fossil fuels such as coal and biomass fuels.

    Direct combustion is the main process of converting the biomass to the useful

    form of energy. Technology for direct combustion can generate heat, electricity or

    both (Cogeneration or combined heat and power, CHP). Biomass direct combustion is

    generally based on the Rankin cycle, where a steam turbine is employed to drive the

    generator. This type of system is well developed, and available commercially around

    the world. Most bioelectricity plants today are direct-fired. In direct combustion,

    steam is generated in boilers burning solid biomass which has been suitably prepared

    (dried, baled, chipped, formed into pellets or briquettes or otherwise modified to suit

    the combustion technology). Direct combustion technologies may be divided into

    fixed bed, fluidized bed and dust combustion see Fig 2.1.

  • 15

    Fig. 2.1: Direct combustion technologies

    In fixed bed systems, the biomass fuel burns in a layer on a grate which moves

    to transport the fuel through the furnace towards ash removal. Fixed bed technologies

    are reliable and generally have relatively low investment costs compared with other

    direct combustion technologies. However, a given fixed bed boiler design can usually

    handle only a limited range of biomass fuel types.

    In fluidized bed boilers, the fuel burns in a constantly mixing suspension of

    hot, inert, granular bed material (usually silica sand or dolomite) into which

    combustion air enters from below. Because of the very effective mixing achieved,

    fluidized bed plants are very flexible in their ability to burn different biomass fuel

    types, although the fuel particle size must be relatively uniform. Fluidized bed

    systems have high investment and operating costs.

    In dust combustion, fuel in the form of small particles such as sawdust or crop

    residue shavings is injected along with air into the combustion chamber, and

    combustion takes place with the fuel in suspension.

  • 16

    2.3 BIOMASS PELLETS

    Biomass may include any fuel derived from organic matter, such as wood, oil

    crops, and agricultural & animal residues. Biomass pellets are produced from grinding

    down wood, energy crops and crop byproducts such as straw. The quality of the pellet

    will vary significantly depending on the quality of the original wood/crop etc. Fig. 2.2

    shows the biomass pellets.

    Fig. 2.2: Biomass Pellets

    Biomass pellets and briquettes are made by compressing dry sawdust or crop

    residue shreds under high pressure until the lignin softens and binds the material

    together. The combination of low moisture content (typically below 10%) and highly

    compressed material gives pellets a high volume energy density, typically three to

    four times that of uncompressed. They are also clean, consistent and flow easily,

    making them particularly attractive in domestic applications. The significantly lower

    storage requirements make them attractive to urban applications. Pellets for domestic

    and small scale applications are typically 6-8 mm diameter, while those for industrial

    applications may be 10-12 mm. Above 25 mm diameter they are known as briquettes

    and can resemble a fire-log in appearance and function, though with improved

    storage, handling, and combustion properties.

    There are two main types of pellet appliance available; these are smaller-scale

    space heaters and larger scale water heaters suitable for a range of uses from top-up

    space heating to complete space and water heating. Pellet stoves are far more efficient

    than open fires or wood burning stoves. Pellet boilers work in much the same way as

    conventional gas or oil boilers and are able to fire up automatically and be

  • 17

    controlled by time clocks etc. The ash created will be very small (

  • 18

    2.3.2 Feedstock Grinding

    Standard-sized pellet mills generally require biomass that is ground to

    particles that are no more than 3 millimeters in size. Several types of equipment are

    available to carry out this task. If the biomass is quite large and dense (e.g., wood),

    the material is first run through a chipper, and then run through a hammer mill or

    similar device to reduce the particles to the required size. Smaller and softer biomass

    (e.g., straw) can be fed directly into the hammer mill without first being chipped.

    2.3.3 Moisture Control

    Maintaining an appropriate moisture level in your feedstock is vital for overall

    quality of the final pellets. For wood, the required moisture level of the feedstock is at

    or near 15 percent. Other types of biomass have other requirementsyou may need to

    experiment a bit. Moisture can be removed from the feedstock by oven-drying or by

    blowing hot air over or through the particles. If the feedstock is too dry, moisture can

    be added by injecting steam or water into the feedstock.

    2.3.4 Extrusion

    The pellet is actually created in this step. A roller is used to compress the

    biomass against a heated metal plate called a die. The die includes several small

    holes drilled through it, which allow the biomass to be squeezed through under high

    temperature and pressure conditions. If the conditions are right, the biomass particles

    will fuse into a solid mass, thus turning into a pellet. A blade is typically used to slice

    the pellet to a predefined length as it exits the die. Some biomass tends to fuse

    together better than other biomass. Sawdust is an especially suitable feedstock for

    pelleting because the lignin that is naturally present in the wood acts as a glue to hold

    the pellet together. Grasses tend to not fuse nearly as well, and the resulting pellets are

    less dense and more easily broken. The proper combination of input material

    properties and pelleting equipment operation may minimize or eliminate this problem.

    It is also possible to add a binder material to the biomass to help it stick together, or

    to mix a fraction of sawdust, with similar results. Distillers Dry Grains (a product of

    the corn ethanol industry) are reported to improve the binding properties of some

    biomass.

  • 19

    2.3.5 Cooling

    Pellets, as they leave the die, are quite hot (~150C) and fairly soft. Therefore,

    they must be cooled and dried before they are ready for use. This is usually achieved

    by blowing air through the pellets as they sit in a metal bin. The final moisture content

    of the pellets should be no higher than 8 percent.

    2.3.6 Packaging

    Pellets are typically sold in 18-kilogram bags, which can be easily filled using

    an overhead hopper and conveyor belt arrangement. The bags should be clearly

    labeled with the type of pellet, their grade (i.e., premium or standard), and their heat

    content.

    2.4 ENERGY REQUIREMENTS FOR PELLET MANUFACTURE

    Pellet manufacture requires quite a bit of energy, both for drying damp

    feedstock and for running the various pieces of machinery. Large plants typically burn

    a portion of their feedstock to provide heat for drying, whereas smaller facilities often

    use other means. As a rule of thumb, a pelletizer requires between 50 and 100

    kilowatts of electrical demand for every ton per hour of production capacity. In

    addition, electricity is usually needed to operate any chopping, grinding, drying,

    cooling, and bagging equipment that is in use. If a reliable source of electricity is not

    available, gasoline or diesel-based equipment is available.

    2.5 ADVANTAGES OF BIOMASS PELLETS

    Biomass pellets have following advantages:

    Low moisture content, typically

  • 20

    material called compost. Composting can happen in many different ways using a

    variety of materials, methods, equipment, and scales of operation. For agricultural

    operations the common materials or feed stocks that are composted are livestock

    manures and bedding and various residual plant materials (straw, culls, on-farm

    processing wastes, etc).

    Traditionally some farmers allowed manure to pile up and it decomposed until

    they were ready to use it. Some have referred to this as composting. Composting is

    much more than just aging manure it is a science. The decomposition occurs in a

    well-managed process to obtain specific positive results a valuable product with a

    minimum of negative environmental impacts. The composting process can be viewed

    from Fig. 2.4.

    Fig 2.4: The composting process

    The nutrient content of compost will be quite different from the manure and

    other feedstock that go into the mix. As water evaporates, the carbon breaks down and

    is lost as carbon dioxide, the compost volume decreases and the phosphorous and

    most other nutrients become more concentrated. Some nitrogen will be lost during

    composting and some will convert from readily available forms (nitrate and ammonia)

    to more stable organic forms that are slowly released to crops. It has been estimated

    that less than 15% of the nitrogen in compost (that has been applied to the soil) will

    be released in the first crop year compared to 5060% for un-composted dairy

    manure. The nutrient value of compost can be highly variable depending on the

    materials being composted and the composting system used. The finished volume of

    the compost is frequently 40 60% of the original compost feedstock volume. The

    compost process reduces the volume to be handled and transported to the field

  • 21

    utilization site. It also concentrates many of the nutrients in the compost material

    compared to their concentrations in the original materials. Well-managed compost

    reduces odors and runoff moisture to reduce potential environmental hazards.

    2.7 ADVANTAGES OF COMPOSTING

    Composting has following advantages:

    Reduce/eliminate pathogens

    Reduce volume and moisture content

    Reduces viable weed seeds

    Reduces insect larvae (fly problems)

    Reduce odor

    Stabilize organic components and nutrients

    Produce a soil amendment/fertilizer

    2.8 DISADVANTAGES OF COMPOSTING

    Composting has following disadvantages:

    Pathogen control requires high temperatures and good aeration

    Often requires additional bulking material (carbon)

    Long processing time

    Poorly run processes achieve very little

    Land required for composting and storage areas

    May require large investment

    Requires more labour

    2.9 COMPOSTING SYSTEMS

    There are many different methods and types of equipment and structures

    suitable for composting. These include:

    1. Windrow/pile composting turning

    2. Windrow/pile composting active aeration

    3. Windrow/pile composting passive aeration

    4. Windrow/pile composting static pile

    5. In-vessel composting

    6. Vermi-composting

  • 22

    2.9.1 Windrow/pile Composting Turning

    There are several advantages of turning the compost windrow. Thorough

    turning will ensure that there is a uniform mix of the feedstock materials throughout

    the windrow. This reduces the likelihood of hot spots where there is overheating or

    accumulation of high moisture materials that reduce microbial activity. The frequency

    of turning can be managed to respond to changes in moisture or temperature as

    required. The moisture content of the windrow usually decreases after turning. If the

    compost has become too dry, water can be added when turning to increase the

    moisture within the windrow and to increase the composting activity of the

    microorganisms. Turning adds air spaces and oxygen in the windrow.

    Turning at regular intervals during the initial 23 weeks of composting is

    advisable to reach and maintain temperatures above 55C for 15 days. This

    temperature is known to kill most pathogens and weed seeds.

    2.9.2 Windrow/pile Composting Active Aeration,

    Static pile Active aeration of windrows requires more careful design for

    appropriate airflows, and usually a more expensive system than turned windrow

    systems. The most common design of this system is to place aeration pipes along the

    length of the windrow with adequate holes for proper airflow. The pipes and middle

    portion of the base of the windrow is then covered with a porous material such as

    wood chips. The windrow is then placed on top of the aeration bed. Proper mixing of

    the feedstock materials and optimum moisture contents are critical to success since

    these windrows are usually not turned therefore not disturbing the aeration system).

    Fans are attached to the ventilation tube and air is either blown into the windrow

    (positive pressure) or vacuumed out of the pipe (negative pressure). When using a

    negative pressure, biofilters may be needed to remove the odors from the exhausted

    air. The aerated windrows also need to be covered with an insulated blanket of

    material to allow adequate heating of the surface of the materials that need to be

    composted. This covering is frequently straw or mature compost and is 6-12 in. thick

    over the whole windrow.

    2.9.3 Windrow/pile Composting Passive Aeration,

    Static piles sometimes known as PAWS (Passive Aeration Windrow System),

    this system involves the insertion of aeration pipes into or under the pile. The

  • 23

    feedstock materials are usually piled on a bed of coarse material such as wood chips

    and/or aerated pipes to improve aeration. The air is permitted to flow passively

    through the pipes and the coarse material under the pile.

    PAWS allows better aeration than the static piles and can achieve higher

    temperatures, but can be subject to many of the same problems especially if the

    mixing is inadequate or if the feedstock materials are of improper C:N ratio or

    moisture. The aeration pipes make it difficult to turn the piles as a means of correcting

    problems such as hot spots. As a result the degree of composting may vary throughout

    the pile.

    2.9.4 Windrow/pile Composting Static Piles, not Aerated

    This is a very low management system where you pile it and leave it. While it

    is the easiest and least expensive composting system, it can also be the most

    troublesome and produce the poorest quality compost. When there is no turning of a

    windrow, the uniform mixing of feedstock materials and the moisture content going

    into the windrow are very critical. There needs to be enough void space (porosity) in

    the materials to allow air to penetrate the windrow. Water is released as the feedstock

    breaks down, but if there is insufficient airflow, this water goes to the bottom of the

    pile creating anaerobic conditions near the bottom of the pile. This problem is

    increased if the windrow is not covered to prevent the inclusion of rainwater. Under

    hot, dry weather conditions, the surface layer of the windrow can become too dry for

    microorganisms to work effectively. Turning the pile would mix it to create more

    uniform moisture content throughout the windrow.

    Windrows that are not turned and do not have mechanical aeration systems,

    frequently do not reach adequate temperatures to kill pathogens and weed seeds. This

    is especially true in anaerobic zones within the centre of the windrow, as well as near

    the surface of the windrow, where temperatures are well below the temperatures

    required for pathogen kill (55C).

    2.9.5 In-vessel Composting

    In-vessel composting systems include a group of composting methods. They

    have the greatest amount of design requirements. They range from concrete channels

    with mechanical mixers to rotating steel drum type systems. Many are continuous

    flow and designed for high capacity commercial composting operations. Frequently

  • 24

    they are contained in buildings designed for the purpose. High initial cost and

    continuous management are disadvantages. They are usually used for high volume or

    central composting systems and require a higher level of management than other

    systems discussed here. Some designs use rectangular concrete channels that may

    have aerated floors and be turned either with turners that travel on overhead rails or in

    some on-farm cases by using multiple channels and tractor-loaders to turn and move

    the material from one channel to another.

    2.9.6 Vermi-composting

    Vermi-composting is worm composting. Common worm species for this type

    of composting are Eisenia foetida and Lumbricus rubellus. These are sometimes

    called "red wigglers" or manure worms. These worms are added to the feedstock

    materials to assist in the decomposition of the organic matter and transform it into

    worm castings. This type of composting does not reach high temperatures but

    research is showing that there can be good kill of pathogens and weed seeds.

    2.10 GASIFICATION

    Gasification is a thermo-chemical process in which carbonaceous (carbon-

    rich) feed stocks such as coal or biomass are converted into a gas consisting of

    hydrogen and carbon monoxide (and lesser amounts of carbon dioxide and other trace

    gases) under oxygen depleted, high pressure, high-heat and/or steam conditions. The

    resulting gaseous compound is called Syngas.

    2.11 PRINCIPLE OF OPERATION

    Biomass gasification is a thermo-chemical conversion process in which a solid

    biomass fuel e.g. wood is converted into a combustible gas. In a biomass gasifier,

    biomass is burned in a limited amount of air. The amount of air supplied is less than

    the amount of air required for complete burning. This converts the biomass (which

    consists of carbon, hydrogen, oxygen, etc) into an inflammable mixture of gases

    known as producer gas/ wood gas.

  • 25

    Fig 2.5: A typical biomass gassifier

    The producer gas consists of carbon monoxide (CO), hydrogen (H2), and

    methane (CH4), along with carbon dioxide (CO2) and nitrogen (N2). In a gasifier

    biomass is progressively heated from the ambient temperature to a temperature of

    around 1100 oC. The main reactions which take place in a gasifier are:

    1. DRYING: Biomass fuels usually contain up to 35% moisture. When the

    biomass is heated to around 100oC, the moisture gets converted into steam.

    2. PYROLYSIS: After drying as the biomass is heated it undergoes pyrolysis.

    Pyrolysis is the thermal decomposition of biomass fuels in the absence of

    oxygen. Biomass decomposes into solid charcoal, liquid tars and gases.

  • 26

    Fig 2.6: Pyrolysis of carbonaceous fuels & Gasification of char

    3. OXIDATION: Air is introduced in a gasifier in the oxidation zone. The

    oxidation takes place at about 700-1400 oC, in which the solid carbonized fuel

    reacts with oxygen in the air producing carbon dioxide and releasing heat.

    C+O2 = CO2 + 406 kJ/g.mol

    4. REDUCTION: At higher temperatures and under reducing conditions several

    reactions take place which results in formation of CO, H2 and CH4.

    CO2 + C = 2CO -172.6 kJ/g.mol

    C+H2O = CO + H2 -131.4 kJ/g.mol

    CO2+H2 = CO +H2O -41.2 kJ/g.mol

    C+2H2 = CH4 +75 kJ/g.mol

    Typical composition of producer gas is presented in Table 1.1. The producer

    gas so obtained is a low calorific value gas with typical higher heating value (HHV)

    in the range of 5.4-5.7 MJ/m3 (Kishore, 2008). The producer gas can be directly

    burned in a burner to provide thermal energy or it can be used as a fuel in an engine to

    provide mechanical power or electricity.

    Table 2.1 Composition of producer gas (TERI, 2006)

    Component Composition (%)

    Carbon monoxide 18 22

    Hydrogen 13 19

    Methane 1 5

    Heavier hydrocarbons 0.2 - 0.4

    Carbon dioxide 9 12

    Nitrogen 45 55

    Water vapor 4

  • 27

    2.12 HISTORY ON GASIFICATION

    Gasification is an old technology with a long history of development. The

    process was mainly used from the mid-1800s through the early-1900s to produce

    town gas from coal for heating and lighting purposes. The subsequent development

    of natural gas fields soon replaced town gas." World War II brought a resurgence of

    gasification when petroleum starved Europeans used wood gas generators to power

    vehicles. But the need for liquid fuels remained and German engineers devised a way

    to make synthetic liquid fuel from gasified coal.

    The 1970s brought The Arab Oil Embargo and the energy crisis which

    prompted the U.S. government to support industrial scale gasification projects. From

    this development came the first Integrated Gasification Combined Cycle (IGCC)

    electric generating plant. Presently, several IGCC power plants are operating

    throughout the world. And crude oil price spikes and geopolitical instabilities in major

    oil-producing countries have generated serious interest in using gasification for GTL

    (Gas to Liquid) synthetic fuel processes.

    2.13 TYPES OF GASIFIERS

    Many design variations of Gasification Reactors (Gasifiers) exist, however,

    depending upon the type of flow conditions present in the equipment, they all fall into

    one of three general categories:

    2.13.1 Moving Bed Gasifier:

    Dry carbon fuel is fed through the top of the gasifier. As it slowly drops

    through the vessel, it reacts with steam and oxygen as they flow in opposite in

    directions over the bed. The fuel goes through the process until it is completely spent

    leaving behind low temperature syngas and molten ash. Trace contaminants are later

    scrubbed from the syngas.

  • 28

    Fig 2.7: Moving Bed Gasifier

    2.13.2 Entrained Flow Gasifier:

    Fuel can be fed dry or wet (mixed with water) into the gasifier. The reactants

    (steam and oxygen) flow uni-directionally upwards through the gasifier, as the stages

    of gasification take place, until high temperature completed syngas exits the top of the

    reactor. Molten slag drops out at the bottom.

    Fig 2.8: Entrained Flow Gasifier

  • 29

    2.13.3 Fluidized Bed Gasifier:

    Steam and oxygen flow upwards through the reactor tower while fuel is

    injected into, and remains suspended in, this stream while gasification takes place.

    Moderate temperature syngas exits the while dry (un-melted) ash is evacuated at the

    bottom.

    Fig 2.9: Fluidized Bed Gasifier

    2.14 COMMON BIOMASS FEEDSTOCK FOR GASIFICATION

    A large type of biomass feedstock have been tried and tested in fixed bed

    gasifies. The chemical composition, size, bulk density, moisture content, ash

    properties are some of the important parameters that determines suitability of a

    biomass resource for use in fixed bed gasifies. The common biomass feedstock used

    in fixed-bed gasifies are:

    2.14.1 Fuel-wood

    Dried fuel-wood having moisture content less than 20 % and cut into suitable

    size is the most common biomass feedstock used for gasification. Fuel wood obtained

    from Prosopis Juliflora, eucalyptus, casurina, acacia, neem, mango have been found to

    be good gasification material.

  • 30

    2.14.2 Biomass Briquettes:

    Due to low bulk densities (50-200 kg/m3), many non-woody biomass residues

    poses problem in direct utilization in fixed-bed gasifies. Such biomass materials can

    be densified and converted into briquettes (density: 800-1200 kg/m3) and can then be

    easily used in gasifiers. Briquettes made from sawdust, coffee husk, groundnut shells,

    pulverized mustard stalk, and cotton sticks are found to be good feedstock for fixed

    bed gasifiers.

    2.14.3 Agriculture Residue:

    Several agriculture residues have been successfully used directly (without

    densification) in fixed bed gasifiers. However, it should be noted that utilization of

    some of these materials necessitates modification in the design of gasifiers which are

    designed primarily for utilization of fuelwood or biomass briquettes. Some of the

    prominent agriculture residues which have been used in fixed-bed gasifiers are:

    coconut shells, stalks such as mustard, arhar and cotton, rice husk, cashew nut shell,

    corn cob, etc.

    2.15 ADVANTAGES OF GASIFICATION

    Feedstock flexibility

    Product flexibility

    Near-zero emissions

    High efficiency

    Energy security

    Gasification plants produce significantly lower quantities of criteria air

    pollutants.

    Gasification can reduce the environmental impact of waste disposal because it

    can use waste products as feed stocks generating valuable products from

    materials that would otherwise be disposed as wastes.

    Gasification's byproducts are non-hazardous and are readily marketable.

    Gasification plants use significantly less water than traditional coal-based

    power generation, and can be designed so they recycle their process water,

    discharging none into the surrounding environment.

  • 31

    2.16 DISADVANTAGES OF GASIFICATION

    Complex multi-stage process

    Up-front processing of feedstock

    Syngas must be cleaned/purified

    Initial setup is expensive

    2.17 ANAEROBIC DIGESTION

    Anaerobic digestion is one of the most important biological methods used for

    stabilization of liquid organic sludge from sewage works, highly concentrated

    effluents from biochemical and food processes. It is becoming more common now for

    processing of livestock wastes and solid municipal wastes.

    Fig 2.10 Biogas Plant

  • 32

    2.18 PRINCIPLE OF OPERATION

    Anaerobic digestion is a natural process which takes place in the absence of

    oxygen. Controlled digestion is normally accelerated by increasing reactor

    temperature into the mesophilic range (normally for anaerobic digestion between 30-

    37C), or into the thermophilic regime (normally for thermophilic anaerobic digestion

    between 55-65C). The decomposition of organic material consists of three basic

    processes as follows;

    2.18.1 HYDROLYSIS

    The first step in anaerobic decomposition is enzymatic hydrolysis. It occurs in

    the substrate, out with the cells, by the action of extra cellular enzymes produced by

    bacteria. The result of hydrolysis is the formation of sugars from carbohydrates,

    amino acids from proteins, and fatty acids from lipids. Soluble organic compounds are

    fermented to a relatively small variety of end products. These include formate,

    acetate, propionate, butyrate, lactate, succinate, ethanol, carbon dioxide, and hydrogen

    gas.

    2.18.2 ACETOGENESIS

    Products of hydrolysis are degraded by acetogenic bacteria to their final

    metabolic products of volatile fatty acids (predominantly acetates), CO2 and

    hydrogen. During this phase a fast growth of acetogenic bacteria occurs, thus mixing

    of the substrate positively affects this process.

    2.18.3 METHANOGENESIS

    Production of methane and CO2 from intermediate products is accomplished

    by methanogenic bacteria. Approximately 70% of the methane is formed from volatile

    fatty acids. The remaining 30% is produced from hydrogen and carbon dioxide.

    Methanogenesis is critical to the entire digestion process, since it is the slowest

    biological reaction of the digestion. Overloading of the reactor, temperature changes

    or large ingresses of oxygen usually result in cessation of methane production, an

    increasing fatty acids concentration and results in the production of only CO2.

  • 33

    2.19 HISTORY OF ANAEROBIC DIGESTION

    Historical evidence indicates that the anaerobic digestion (AD) process is one

    of the oldest technologies. However, the industrialization of AD began in 1859 with

    the first digestion plant in Bombay. By 1895, biogas was recovered from a sewage

    treatment facility and used to fuel street lamps in Exeter, England. Research led by

    Buswell and others in the 1930s identified anaerobic bacteria and the conditions that

    promote methane production. As the understanding of the AD process and its benefits

    improved, more sophisticated equipments and operational techniques emerged. The

    result was the used of closed tank and heating and mixing systems to optimize AD.

    Regardless of improvements, AD suffered from the development of aerobic treatment

    and low costs of coal or petroleum. While AD was used only for the treatment of

    wastewater sludge digestion, developing countries such as India and China embraced

    the technology. Small-scale AD systems were mostly used for energy and sanitation

    purposes. Numerous failures were reported. Nevertheless, technical improvements

    and increasing energy prices have led to a diversification of the waste treated and

    larger size AD plants.

    2.20 ENERGY CONVERSION

    The anaerobic degradation of organic substances to its most reduced form,

    methane (CH4), is a microbial process. The energy released, originally stored in the

    substrate, and is predominantly recovered by the formed methane.

    33g org. material = 22g CO2 + 8g CH4 + 3g biomass

    The AD plant will provide biogas which will be used to generate two forms of

    energy, electricity and heat, in combined heat and power (CHP) units of gas engines.

    Anaerobic digestion is a proven technology but it is not a simple process. It requires

    storage space for the raw and treated material, dosing pumps, a gas tight reactor with

    heat exchanger and mixing facilities, a bio-gas reservoir, boiler and/or internal

    combustion engine with an electrical energy generator. To make the process

    economical, with a payback period of less than 5 years, a high percentage of biogas

    has to be utilised. This target is achievable in larger plants, where electrical

    energy/heat co-generation is the most practical design.

  • 34

    Table 2.2 Typical Composition of biogas gas

    COMPONENT %

    Methane, CH4 5075

    Carbon dioxide, CO2 2550

    Nitrogen, N2 010

    Hydrogen, H2 01

    Hydrogen sulfide, H2S 03

    Oxygen, O2 02

    2.21 CONDITIONS AND VARIABLES INFLUENCING AD

    There are several conditions and variables that must be applied in order to

    obtain a proper breakdown of the organic compounds. The operating parameters of

    the digester must be controlled so as to enhance the microbial activity and thus

    increase the AD efficiency. Some of these parameters are discussed briefly below;

    2.21.1 Total Solid content

    There are three different ranges of solid content: low solid (LS) AD systems

    contain less than 10% Total Solid (TS), medium solid (MS) from 15-20% and high

    solid systems (HS) range from 22-40%. When increasing the total solid content, the

    volume of the digester decreases, due to lower water requirements.

    2.22.2 Temperature

    Anaerobic digestion can occur under two main temperature ranges: i.e.

    Mesophilic conditions, between 20-45C, usually 35C and Thermophilic conditions,

    between 50-65 C, usually 55C. The optimum temperature of digestion may vary

    depending on feedstock composition and type of digester, but in most AD processes it

    should be maintained relatively constant to sustain the gas production rate.

    Thermophilic digesters are more efficient in terms of retention time, loading

    rate and nominally gas production, but they need a higher heat input and have a

    greater sensitivity to operating and environmental variables, which make the process

    more problematic than mesophilic digestion

  • 35

    The sterilization of the waste is also linked to the temperature. The higher it is

    the more effective it is in eliminating pathogens, viruses and seeds.

    2.22.3 Retention time

    Retention time is the time needed to achieve the complete degradation of the

    organic matter. The retention time varies with process parameters, such as process

    temperature and waste composition. The retention time for waste treated in a

    mesophilic digester ranges from 15 to 30 days and 12-14 days for thermophilic

    digester.

    2.22.4 pH

    The optimal pH values for the acidogenesis and methanogenesis stages are

    different. During acidogenesis, acetic, lactic and propionic acids are formed and, thus

    the pH falls. Low pH can inhibit acidogenesis and pH below 6.4 can be toxic for

    methane-forming bacteria. The optimal range for methanogenesis is between 6.6 to 7.

    An optimal pH range for all is between 6.4 and 7.2.

    2.22.5 Carbon to Nitrogen ratio (C: N)

    The relationship between the amount of carbon and nitrogen present in organic

    materials is represented by the C: N ratio. Optimum C: N ratios in anaerobic digesters

    are between 20 and 30. A high C: N ration is an indication of a rapid consumption of

    nitrogen by the methanogens and results in a lower gas production. On the other hand,

    a lower C: N ratio causes ammonia accumulation and pH values exceeding 8.5, which

    is toxic to methanogenic bacteria. Optimum C: N ratio of the feedstock materials can

    be achieved by mixing waste of low and high C: N ratio, such as organic solid waste

    mixed with sewage or animal manure.

    2.22.6 Mixing

    Mixing, within the digester, improves the contact between the micro-

    organisms and substrate and improves the bacterial population's ability to obtain

    nutrients. Mixing also prevents the formation of scum and the development of

    temperature gradients within the digester. However excessive mixing can disrupt the

    micro-organisms and therefore slow mixing is preferred.

  • 36

    In case of co-digestion, the different feedstocks should be mixed before

    entering the digester to ensure a sufficient homogeneity.

    2.22.7 Organic loading rate (OLR)/ Volatile Solids (VS)

    OLR is a measure of the biological conversion capacity of the AD system.

    Feeding the system above its sustainable OLR, results in low biogas yield due to

    accumulation of inhibiting substances in the digester slurry (i.e. fatty acids). Under

    such circumstances, the feeding rate of the system must be reduced. OLR is a

    particularly important control parameter in continuous systems. Many plants have

    reported system failure due to overloading. OLR is expressed in kg Chemical Oxygen

    Demand (COD) or Volatile Solids (VS) per cubic meter of reactor. It is linked with

    retention time for any particular feedstock and anaerobic reactor volume.

    Volatile Solids (VS) represents the organic matter in a sample which is

    measured as solid content minus ash content, as obtained by complete combustion of

    the feed wastes. VS comprise the biodegradable VS (BVS) fraction and the refractory

    VS (RVS). High VS content with low RVS is more suitable for AD.

    2.23 TYPES OF DIGESTERS

    Anaerobic digesters can be classified into the following three categories:

    1. single-stage

    2. multi-stage

    3. batch

    The temperature range of the digestion, mesophilic or thermophilic, as well as the

    solid content also define the type of reactor used.

    2.24 ADVANTAGES OF ANAEROBIC DIGESTION

    The methane produced by AD plants can be collected and managed in an

    environmentally sound manner, by using it as a natural gas substitute either

    directly, or in the production of hot water, steam or electricity. When

    combusted, the methane is converted to CO2, which is much less damaging as

    a greenhouse gas (methane is 21 times more powerful than CO2 as a

    greenhouse gas).

  • 37

    The methane produced in the digester will be used as an energy source. If it

    displaces oil, natural gas or coal, used for the generation of electricity, this

    waste management approach has significant greenhouse gas benefits.

    Anaerobic digestion is a net energy producing process. Surplus biogas can be

    used to generate electricity and thus defray the cost of the process. Also, the

    excess of heat can be sold for heating of large buildings and/or district heating

    purposes.

    The compost product produced through the anaerobic digestion of organic

    waste is a valuable soil amendment; when added to soil it can improve plant

    growth, reduce soil erosion and nutrient runoff, alleviate soil compaction, and

    help soil retain water. In addition, there is evidence that compost can suppress

    diseases and ward off pests.

    Compost can also reduce the need for artificial fertilizers, which are derived

    from natural gas, result in water contamination, and deplete soil health.

    Further, greenhouse gases are created during their production and nitrous

    oxide (N2O) is released during tillage. This harmful practice can be replaced,

    in part, by returning nitrogen bound in organic waste to the soil.

    The quantifiable benefits of displacing artificial fertilizer include reducing the

    significant CO2 emissions associated with their manufacture, and reducing the

    N2O emissions released through their use.

    2.25 DISADVANTAGES OF ANAEROBIC DIGESTION

    Relatively complicated process, the centralized plant has to be run by

    specialists

    Complete volatile solids destruction of the waste does not occur in anaerobic

    digester

    Possible problems resulting from explosive gas production from aerobically

    digested sludge

    Cost of construction of AD is expensive

  • 38

    Difficulty of storage of gas (corrosive)

    Significant consumption of water

    Storage of fertilizer is difficult

    Problem of management of the sludge

    Does not destroy all pathogens

    High operating cost due to temperature management

    Longer start-up time to develop necessary biomass inventory

    May require alkalinity and/or specific ion addition

    May require further treatment with an aerobic treatment process to meet

    discharge requirements

    Increased potential for production of odors and corrosive gases.

  • 39

    PART- III

    ASSESSMENT OF ENVIRONMENTALLY

    SOUND TECHNOLOGIES

  • 40

    3.1 PROBLEM STATEMENT

    Transforming biomass waste into a source of energy is very important from

    reduction of the pollution. Resource augmentation by utilizing waste biomass has

    emerged as a major issue in both developed and developing countries. There are three

    important motivational factors for converting waste biomass into a resource:

    1. Economic Benefit

    Huge costs can be avoided which are otherwise required to manage huge

    volumes of waste through conventional waste management practice, viz.: collection,

    transportation, treatment and proper disposal.

    2. Energy/ Material Production

    Waste biomass contains precious resources which could be obtained in the

    form of material or energy to reduce pressure on natural resources which are required

    to support economic development and improved living standards. This could also be

    in line with strategies for poverty alleviation through income generation activities and

    through reducing costs for obtaining energy to support livelihoods.

    3. GHG Mitigation

    These reductions take place on two accounts. Burning or decomposition of

    waste biomass produces GHG emissions and proper management of waste biomass

    would reduce these GHG emissions. So far, most of the waste biomass is left in the

    fields and to clear the land for planting next crop, farmers use open burning, which

    creates local air pollution as well as GHG emissions (CO2). The waste biomass that is

    left over the months, gets rotten and generates methane; thus creating GHG emissions.

    Hence, converting that waste biomass into an energy source, GHG emissions, which

    are caused due to open burning or from rotten waste biomass, could be avoided in

    addition to the GHG emissions which are offset due to use of this alternative energy

    source.

  • 41

    The total quantity of all the nine selected residues for district Sanghar is

    represented in Table 3.1 below. As an aggregate the total quantity of the WAB in

    district Sanghar is 2533 kilo-tons.

    Table 3.1: Total quantity of WAB in district Sanghar (kilo-tones)

    S No

    Name of Taluka

    Crop Residue

    Sang

    har

    Sinj

    horo

    Shah

    dad-

    pu

    r

    Tan

    do

    Ada

    m

    Jam

    Naw

    az

    Ali

    Khi

    pro

    TO

    TA

    L

    1 Wheat Straw 73.17 137.43 113.83 52.87 29.62 86.60 494

    2 Cotton Stalks 229.18 318.19 315.14 127.78 114.48 318.36 1423

    3 Cotton Gin Waste 10.31 14.32 14.18 5.75 5.15 14.33 64

    4 Sugarcane Tops 68.16 58.92 39.00 46.77 17.73 22.22 253

    5 Baggase 33.40 28.87 19.11 22.92 8.69 10.89 124

    6 Rice Straw 7.40 20.19 2.82 4.33 6.66 9.34 51

    7 Rice Husk 3.37 9.18 1.28 1.97 3.03 4.24 23

    8 Canola Straw 5.32 2.66 2.62 2.18 0.73 1.50 15

    9 Banana Plant 1.41 4.62 28.21 48.81 2.09 1.78 87

    TOTAL 432 594 536 313 188 469 2533

    The overall characteristics of the biomass for the selected nine residues of

    district Sanghar are represented in Table 3.2 below.

  • 42

    S

    N

    oN

    ame

    of S

    ampl

    eM

    oist

    ure

    (%)

    Vol

    atile

    at

    550

    C (

    %)

    Org

    anic

    (%

    )A

    sh

    (%)

    Den

    sity

    (k

    g/m

    3)H

    CV

    (k

    cal/k

    g)% C

    % H% N

    % O% S

    1B

    anan

    a P

    lant

    5.97

    58.9

    677

    .33

    16.7

    130

    032

    0138

    .31

    5.35

    0.39

    33.1

    80.

    10

    2B

    agga

    se3.

    1173

    .09

    92.1

    64.

    7225

    639

    1044

    .65

    5.54

    0.18

    41.7

    90.

    00

    3C

    anol

    a9.

    0962

    .40

    81.3

    89.

    5427

    835

    2539

    .66

    5.32

    0.20

    35.2

    70.

    93

    4C

    otto

    n S

    talk

    s4.

    8560

    .46

    85.1

    79.

    9812

    6336

    4942

    .84

    5.63

    0.08

    36.2

    00.

    42

    5M

    aize

    Cob

    4.58

    68.6

    888

    .70

    6.73

    904

    3792

    44.6

    96.

    161.

    0436

    .72

    0.09

    6R

    ice

    Hus

    k4.

    8058

    .44

    74.6

    220

    .58

    1010

    3418

    36.8

    55.

    551.

    7030

    .30

    0.22

    7R

    ice

    Str

    aw3.

    3360

    .20

    77.9

    318

    .75

    674

    3349

    36.3

    94.

    961.

    0135

    .35

    0.22

    8S

    aw D

    ust

    7.68

    63.7

    286

    .02

    6.30

    800

    3659

    44.3

    95.

    940.

    4135

    .16

    0.12

    9S

    ugar

    cane

    Top

    s2.

    4364

    .81

    83.9

    613

    .62

    1457

    3639

    29.9

    23.

    720.

    1550

    .03

    0.14

    10W

    heat

    Str

    aw4.

    3361

    .35

    81.0

    414

    .64

    311

    3443

    40.8

    35.

    340.

    8333

    .80

    0.24

    11C

    otto

    n G

    in W

    aste

    4.

    5558

    .07

    74.6

    820

    .77

    319

    3268

    39.8

    75.

    061.

    7027

    .47

    0.60

    Tab

    le 3

    .2: O

    vera

    ll C

    hara

    cter

    isti

    cs o

    f WA

    B

  • 43

    The available energy of all the nine residues is represented in Table 3.3. The

    total energy equivalent in district Sanghar was estimated as 38 PJ, where as the

    available energy potential was 21.5 PJ, which is equal to 56% of the total energy

    equivalent in district Sanghar. It can be observed that, by using available energy of

    waste agricultural biomass, we can generate about 1192 million units of electricity by

    installing the power plant of 150 MW. Moreover the same number of units can be

    generated if the decentralized approach is adopted for each Taluka.

    Table 3.3: Total energy potential of WAB in district Sanghar

    Nam

    e of

    T

    aluk

    a

    Sang

    har

    Sinj

    horo

    Shah

    d-ad

    pur

    Tan

    do

    Ada

    m

    Jam

    N

    awaz

    A

    li

    Khi

    pro

    TOTAL

    Total Energy Equivalent (TJ) 6528 8919 8027 4653 2833 7059 38,018

    Available Energy Equivalent (TJ) 2813 4690 4282 3235 2078 4365 21,464

    Electricity Generation (MWh) 156250 260580 237883 179742 115469 242505 1192,429

    Pant Size (MW) 20 33 30 23 15 31 151

    The true sense of the Waste Agricultural Biomass is the energy that we can

    obtained from the disposed off agricultural residues. The quantity and energy of

    disposed off WAB, that can be obtained from cotton stalks, sugarcane tops, rice straw

    and banana plant in each Taluka of district Sanghar was 1088 kilo-tons and 16,385 TJ

    respectively as shown in Table 3.4 below.

  • 44

    Table 3.4 Energy potential of disposed off WAB in district Sanghar

    Tal

    uka

    Name of Crop Residue

    QPY (tons)

    AF QDO (tons/year)

    HCV (kcal/kg)

    EDO (TJ/year)

    Cotton Stalks 229177 0.25 57294 3649 875 Sugarcane Tops 68163 1.00 68163 3639 1038 Rice Straw 7403 0.80 5923 3349 83 Banana Plant 1415 1.00 1415 3201 19 S

    angh

    ar

    Sub- total 306157 ---- 132794 ---- 2015 Cotton Stalks 318193 0.45 143187 3649 2186 Sugarcane Tops 58917 0.80 47133 3639 718 Rice Straw 20188 0.75 15141 3349 212 Banana Plant 4619 1.00 4619 3201 62 S

    injh

    oro

    Sub- total 401916 ---- 210080 ---- 3178 Cotton Stalks 315145 0.50 157572 3649 2406 Sugarcane Tops 38997 0.80 31198 3639 475 Rice Straw 2817 0.70 1972 3349 28 Banana Plant 28210 1.00 28210 3201 378

    Shah

    dadp

    ur

    Sub- total 385169 ---- 218952 ---- 3287

    Cotton Stalks 127779 0.70 89445 3649 1366 Sugarcane Tops 46770 0.80 37416 3639 570 Rice Straw 4333 0.75 3249 3349 46 Banana Plant 48814 1.00 48814 3201 654

    Tan

    do A

    dam

    Sub- total 227696 ---- 178925 ---- 2635 Cotton Stalks 114480 0.80 91584 3649 1398 Sugarcane Tops 17728 0.80 14183 3639 216 Rice Straw 6660 0.75 4995 3349 70 Banana Plant 2092 1.00 2092 3201 28

    Jam

    Naw

    az A

    li

    Sub- total 140961 ---- 112854 ---- 1712 Cotton Stalks 318356 0.65 206931 3649 3160 Sugarcane Tops 22220 0.80 17776 3639 271 Rice Straw 9335 0.80 7468 3349 105 Banana Plant 1777 1.00 1777 3201 24 K

    hipr

    o

    Sub- total 351689 ---- 233953 ---- 3559

    GRAND TOTAL 1,813,588 ---- 1,087,558 ---- 16,385 Where,QPY = Quantity of WAB per year (tons), AF = Availability Factor,

    QDO = Total Quantity of Disposed off WAB per year (tons), EDO = Energy in disposed off WAB per year (TJ)

  • 45

    3.2 STEPS BY STEP ASSESSMENT OF ESTs

    The EST criteria may be applied towards TA in a three-tiered manner:

    1. Screening tier

    2. Scoping tier

    3. Detailed assessment tier

    3.2.1 Screening tier

    The first tier could be a screening level assessment, that is based on

    elimination, using certain qualifying criteria (go / no go) that are a must for a

    technology to be classified as an EST. Table 3.5 represents the screening of all the

    four technologies. It can be viewed that all the five technologies have been screened

    out.

    Table 3.5: Tier 1 (screening) criteria applied to identified technology systems

    Technology

    Criteria

    Direct Combustion Composting Gasification Biogas

    Pallets of

    WAB Compliance with local environmental laws

    Yes Yes Yes Yes Yes

    Compliance with national environmental laws

    Yes Yes Yes Yes Yes

    Safe to use? Yes Yes Yes Yes Yes

    Provides savings on resources?

    Yes Yes Yes Yes Yes

    3.2.2 Scoping tier

    The second tier is essentially a scoping exercise and uses EST criteria and

    indicators to rank technology alternatives (e.g. based on a weighted sum technique)

    and allows short-listing of ESTs. The result of the scoping is shown in Table 3.6.

  • 46

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  • 47

    Table 3.7 shows the rankings given to the various technology systems options

    based on the results from Table 3.6. It can be observed that the ranking of the

    technologies is one to five is for biogas, gasification, pellets of biomass, composting

    and direct combustion respectively. Now for the detailed assessment tier the top three

    technologies were selected.

    Table 3.7: Ranking the technology systems from results in Tier 2

    Technology system Score Rank number

    Biogas 429 1 Gasification 338 2 Pellets of WAB 332 3 Composting 318 4 Direct Combustion 289 5

    3.2.3 Detailed assessment tier

    The third tier is the analysis of short-listed alternatives on the basis of criteria

    and indicators using a scoring/ranking framework. Of the first three ranked

    technology systems shaded in Table 3.7 were short-listed and taken for further

    assessment using the criteria in Tier 3 (detailed assessment criteria). Table 3.8 shows

    the calculations for the technology systems assessments, once again using the

    weighted sum method.

  • 48

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  • 49

    Figure 3.1 shows the star diagram by taking the results of tier 3. It can

    be observed from the star diagram that of the three technology system option, biogas

    has been found to be the most appropriate option of the three, followed by biomass

    pellets and gasification respectively.

    Figure 3.1: Star Diagram at Tier 3 Level of Assessment

  • 50

    CONCLUSION & RECOMMENDATION

    From the detail assessment of the selected technologies following three

    technologies were come out as most feasible and environmentally sound, sustainable

    and economically viable.

    1. Biogas

    2. Biomass Pellets

    3. Gasification

    From the results of Tier 3 criteria to short-listed technology systems as in

    Table 3.8, the score obtained by Biogas, Biomass Pellets and Gasification is in the

    order of 991, 912 and 670 respectively. The gasification technology is less feasible

    from the assorted technologies because of more sophistication, automation, capital

    investment, safety risk for workers and requirements of technical knowledge. On the

    other hand Biogas gasification is most feasible. The biomass pellets according to the

    score comes at the second number. For pilot scale biogas (Anaerobic Digestion) is

    recommended for pilot scale project in Sanghar.