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    Comparative Analysis of Life Cycle Inventory

    Techniques and Development of a QuantitativeUncertainty Analysis Procedure

    Deidre Wolff

    School of Civil and Building Services Engineering

    Prof. Aidan DuffyProf. Geoff Hammond

    Nov. 29, 2013

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    Life Cycle Assessment (LCA)

    The compilation and evaluation of the inputs,

    outputs, and potential environmental impacts of

    a product system throughout its life cycle

    (ISO 14044, 2006)

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    7

    Life Cycle Assessment (LCA)

    Four Stages:

    Goal and Scope Definition

    Life Cycle Inventory (LCI)

    Life Cycle Impact

    Assessment (LCIA)

    Interpretation

    (ISO 14040)

    GoalDefinition and

    Scope

    InventoryAnalysis

    Interpretation

    ImpactAssessment

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    Motivation

    LCA is often used in decision-making processesand to inform policy

    LCA involves using expert judgement,

    assumptions, data of poor quality, allocationand weighting

    These all introduce uncertainty

    Uncertainty is often ignored in LCA studiesdue to lack of knowledge and/or time and

    budget constraints

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    What is uncertainty?

    Errors originating from inaccurate

    measurements, lack of data, and model

    assumptions (Huijbregts, 1998)

    The problem of using information that is

    unavailable, wrong, unreliable, or that shows acertain degree of variability (Heijungs, 2004)

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    Uncertainty Classification in LCA

    Parameter

    data uncertainty

    arises due to incomplete knowledge of true value of data, lack of data

    or measurement error

    Model

    unknown interactions between model formulations, due to

    simplification, derivation of characterization factors, aggregation of

    data into impact categories

    Scenario

    due to decisions made during the LCA, such as choice in system

    boundary, functional unit, allocation, weighting factors

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    LCA Overall Steps...

    Goal and Scope LCI LCIA Interpretation

    System

    Boundary

    Weighting

    Methods

    Characterization

    Factors

    ChooseImpact

    Categories

    Uncertainty

    Analysis

    Contribution/

    Sensitivity

    Analysis

    Identify

    Significant

    Issues

    FU and

    Reference

    Flow

    Allocation

    Procedure

    LCI/LCIA

    Method

    Assumptions

    Scale Data to

    FU/ Ref Flow

    Data

    Collection

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    (Reap et al, 2008)

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    Case-study: Process LCA

    Goal and Scope:

    Determine the overall Global WarmingPotential for the production of an electric kettle,using data from EcoInvent Database.

    System boundary is cradle-to-gate, includingraw material extraction and manufacturing ofthe materials used for the production of a kettle.

    The system boundary is simplified, as theoverall goal of the LCA is to quantify theuncertainty.

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    RawMaterial

    Extraction

    Transport toproduction

    facility

    Assembly of

    Electric Kettle

    Energy Input Energy Input

    Emissions to Air Emissions to Air

    Transport of

    Electric Kettle

    to Consumer

    Energy Input

    Emissions to Air

    Energy Input

    Emissions to Air

    Disposal/

    RecyclingUse Phase

    Energy InputEnergy Input

    Emissions to Air Emissions to Air

    Case-study: Process LCA

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    System Diagram

    Stainless

    Steel

    Poly-

    propylen

    e

    Silicone

    Poly-

    propylene

    Copper

    Polyamide

    Electrical

    Component

    Body ofKettle

    Stainless

    Steel

    KettleAssembly

    437 g

    0.4 g

    245.5 g 682.9g

    1038.5 g

    355.6 g

    3.5 g

    41.9 g

    310.2g

    15 g

    The emissionsassociated with energyconsumed during these

    steps has been ignoredfor simplification

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    Process LCI and LCIA ResultsEmissions to Air Quantity Unit Total Characterization Factor CO2-equivalents

    CO2 Biogenic HPD 2.79E-02 kg 3.16E-02 1 3.16E-02

    CO2 Biogenic LPD 2.58E-03 kg

    CO2 Biogenic Unspecified 1.13E-03 kg

    CO2 Fossil lower strat and upper tro 3.52E-08 kg 2.94E+00 1 2.94E+00

    CO2 Fossil unspecified 3.23E-01 kg

    CO2 Fossil HPD 2.16E+00 kg

    CO2 Fossil LPD 4.57E-01 kg

    CO2 Land Transformation, LPD 4.49E-05 kg 4.49E-05 1 4.49E-05

    SF6 LPD 4.16E-11 kg 3.65E-08 22800 8.33E-04

    SF6 Unspecified 3.65E-08 kg

    N2O LPD 7.46E-06 kg 4.19E-05 298 1.25E-02

    N2O lower strat and upper trop 3.36E-13 kg

    N2O HPD 2.67E-05 kg

    N2O Unspecified 7.77E-06 kg

    Methane biogenic LPD 8.20E-06 kg 5.40E-05 25 1.35E-03

    Methane biogenic HPD 2.72E-05 kg

    Methane biogenic Unspecified 1.86E-05 kg

    Methane fossil LPD 4.78E-03 kg 1.15E-02 25 2.87E-01

    Methane fossil lower strat and upp 5.60E-13 kg

    Methane fossil HPD 6.68E-03 kg

    Methane fossil Uspecified 3.57E-06 kg

    CF4 HPD (PFCs) 2.28E-11 kg 2.29E-07 7390 1.69E-03

    CF4 Unspecified (PFCs) 2.29E-07 kg

    C2F6 HPD (PFCs) 2.03E-10 kg 2.57E-08 12200 3.13E-04

    C2F6 Unspecified (PFCs) 2.55E-08 kg

    CHF3 HPD (HCFCs) 8.11E-12 kg 8.11E-12 14800 1.20E-07

    Total GWP: 3.277

    LCIALCI Data

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    Contribution Analysis

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    Contribution Analysis

    0.0%

    10.0%

    20.0%

    30.0%

    40.0%

    50.0%

    60.0%

    70.0%

    Polypropylene Stainless Steel Silicone

    ContributiontoOverallGWP

    (%)

    Contribution of Body Component Material toOverall GWP

    Methane (Fossil HPD)

    Methane (Fossil LPD)

    CO2 (Fossil LPD)

    CO2 (Fossil HPD)

    CO2 (Fossil Unspecified)

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    Sensitive Parameters

    Sensitive Parameter

    Contribution toOverall GWP

    (%)

    Mean Value (kgCO2-eq per

    Kettle)

    Raw EcoInvent Data

    Emission

    Kettle Part

    and

    Material

    Mean (kg) Minimum (kg)Maximum

    (kg)

    CO2(Fossil) Electrical,Polyprop.

    15.9% 0.519 1.673 1.670 1.676

    CO2(Fossil)Body,

    Polyprop.12.6% 0.410 1.673 1.670 1.676

    CO2(Fossil)

    Body,

    Stainless

    Steel

    56.5% 1.842 4.212 3.673 4.865

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    Sensitivity Analysis

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    Next Steps

    Quantify Uncertainty

    Identify scenario and model uncertainty

    Is it necessary to quantify scenario and model

    uncertainty in all cases?

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    Thank You!

    Any Questions?